NC0038377_J15060648report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15060648
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:6/30/2015
Customer Address:
Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 48
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015020139 MAYO STEAM 17-Jun-15 4:30 PM illegible ABMW-3S
2015020140 MAYO STEAM 17-Jun-15 5:25 PM illegible ABMW-3
2015020141 MAYO STEAM 17-Jun-15 3:45 PM illegible ABMW-2
2015020142 MAYO STEAM 17-Jun-15 5:25 PM illegible ABMW-2BR
2015020143 MAYO STEAM 17-Jun-15 2:10 PM Filter Blank
2015020144 MAYO STEAM 17-Jun-15 2:10 PM Equipment Blank
6 Total Samples
Analytical Lab
Page 2 of 48
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:6/30/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020139
Collection Date: 17-Jun-15 4:30 PM
Site: ABMW-3S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/24/2015 14:45M2 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 6.9 mg/L EPA 300.0 06/23/2015 14:48 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 06/23/2015 14:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:10 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:50 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.005 1
Boron (B)1.07 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.05 1
Iron (Fe)2.49 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.01 1
Manganese (Mn)0.463 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.005 1
Strontium (Sr)0.058 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 06/22/2015 09:44 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)4.78 mg/L EPA 200.7 06/22/2015 12:03 FCJORDA0.01 1
Magnesium (Mg)0.695 mg/L EPA 200.7 06/22/2015 12:03 FCJORDA0.005 1
Potassium (K)0.605 mg/L EPA 200.7 06/22/2015 12:03 FCJORDA0.1 1
Sodium (Na)19.4 mg/L EPA 200.7 06/22/2015 12:03 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.005 1
Barium (Ba)0.025 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.005 1
Boron (B)1.10 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.05 1
Iron (Fe)2.63 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.01 1
Manganese (Mn)0.478 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.005 1
Strontium (Sr)0.059 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 06/24/2015 11:01 MHH71310.005 1
Analytical Lab
Page 4 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020139
Collection Date: 17-Jun-15 4:30 PM
Site: ABMW-3S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Arsenic (As)1.17 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Cobalt (Co)3.96 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Nickel (Ni)1.05 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 15:13 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 15:13 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 15:13 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Arsenic (As)1.04 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Cobalt (Co)3.98 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 16:47 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 16:47 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 16:47 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 1.0 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/19/2015 07:45 AGIBBS551
Analytical Lab
Page 5 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020140
Collection Date: 17-Jun-15 5:25 PM
Site: ABMW-3
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.016 mg-N/L EPA 353.2 06/24/2015 15:32 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 76 mg/L EPA 300.0 06/23/2015 12:20 BGN9034110
Sulfate 42 mg/L EPA 300.0 06/23/2015 12:20 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:17 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:58 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.018 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.005 1
Barium (Ba)0.200 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.005 1
Boron (B)1.96 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.05 1
Iron (Fe)3.87 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.01 1
Manganese (Mn)0.451 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.005 1
Strontium (Sr)1.17 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 09:55 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)54.5 mg/L EPA 200.7 06/22/2015 12:14 FCJORDA0.01 1
Magnesium (Mg)11.9 mg/L EPA 200.7 06/22/2015 12:14 FCJORDA0.005 1
Potassium (K)10.2 mg/L EPA 200.7 06/22/2015 12:14 FCJORDA0.1 1
Sodium (Na)10.8 mg/L EPA 200.7 06/22/2015 12:14 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.119 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.005 1
Barium (Ba)0.200 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.005 1
Boron (B)1.94 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.05 1
Iron (Fe)3.89 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.01 1
Manganese (Mn)0.451 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.005 1
Strontium (Sr)1.17 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/24/2015 10:50 MHH71310.005 1
Analytical Lab
Page 6 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020140
Collection Date: 17-Jun-15 5:25 PM
Site: ABMW-3
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Arsenic (As)197 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Molybdenum (Mo)75.1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Nickel (Ni)3.16 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 14:23 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 14:23 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 14:23 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Arsenic (As)193 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Molybdenum (Mo)75.6 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Nickel (Ni)2.69 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 17:09 SLS256011
Thallium (Tl) Low Level 0.289 ug/L EPA 200.8 06/26/2015 17:09 SLS25600.2 1
Vanadium (V) Low Level 0.680 ug/L EPA 200.8 06/26/2015 17:09 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 350 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 4.1 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 9.0 mg/L SM2540D 06/19/2015 07:45 AGIBBS551
Analytical Lab
Page 7 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020141
Collection Date: 17-Jun-15 3:45 PM
Site: ABMW-2
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.103 mg-N/L EPA 353.2 06/24/2015 15:33 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 06/23/2015 12:37 BGN9034110
Sulfate 36 mg/L EPA 300.0 06/23/2015 12:37 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:19 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 15:00 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.023 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.005 1
Barium (Ba)0.149 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.005 1
Boron (B)8.10 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.05 1
Iron (Fe)0.172 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.01 1
Manganese (Mn)0.957 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.005 1
Strontium (Sr)1.54 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 10:06 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)82.2 mg/L EPA 200.7 06/22/2015 12:18 FCJORDA0.01 1
Magnesium (Mg)27.0 mg/L EPA 200.7 06/22/2015 12:18 FCJORDA0.05 10
Potassium (K)15.2 mg/L EPA 200.7 06/22/2015 12:18 FCJORDA0.1 1
Sodium (Na)13.4 mg/L EPA 200.7 06/22/2015 12:18 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.061 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.005 1
Barium (Ba)0.173 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.005 1
Boron (B)9.20 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.05 1
Iron (Fe)0.356 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.01 1
Manganese (Mn)1.11 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.005 1
Strontium (Sr)1.78 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/24/2015 11:05 MHH71310.005 1
Analytical Lab
Page 8 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020141
Collection Date: 17-Jun-15 3:45 PM
Site: ABMW-2
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Arsenic (As)874 ug/L EPA 200.8 06/26/2015 15:57 SLS25601010
Beryllium (Be)1.22 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Molybdenum (Mo)1620 ug/L EPA 200.8 06/26/2015 15:57 SLS25601010
Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 15:57 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 15:57 SLS25600.2 1
Vanadium (V) Low Level 2.59 ug/L EPA 200.8 06/26/2015 15:57 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Arsenic (As)1020 ug/L EPA 200.8 06/26/2015 18:14 SLS2560110
Beryllium (Be)1.42 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Molybdenum (Mo)1830 ug/L EPA 200.8 06/26/2015 18:14 SLS25601010
Nickel (Ni)1.12 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 18:14 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 18:14 SLS25600.2 1
Vanadium (V) Low Level 3.53 ug/L EPA 200.8 06/26/2015 18:14 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 450 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 11 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.5 5
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/19/2015 07:45 AGIBBS551
Analytical Lab
Page 9 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020142
Collection Date: 17-Jun-15 5:25 PM
Site: ABMW-2BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.223 mg-N/L EPA 353.2 06/24/2015 15:43M2 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 27 mg/L EPA 300.0 06/23/2015 12:53 BGN9034110
Sulfate 12 mg/L EPA 300.0 06/23/2015 12:53 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:21 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 15:02 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.005 1
Barium (Ba)0.154 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.05 1
Iron (Fe)0.024 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.01 1
Manganese (Mn)0.146 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.005 1
Strontium (Sr)1.24 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 10:10 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)81.5 mg/L EPA 200.7 06/22/2015 12:22 FCJORDA0.01 1
Magnesium (Mg)13.2 mg/L EPA 200.7 06/22/2015 12:22 FCJORDA0.005 1
Potassium (K)4.38 mg/L EPA 200.7 06/22/2015 12:22 FCJORDA0.1 1
Sodium (Na)26.0 mg/L EPA 200.7 06/22/2015 12:22 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.064 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.005 1
Barium (Ba)0.159 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.05 1
Iron (Fe)0.107 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.01 1
Manganese (Mn)0.149 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.005 1
Strontium (Sr)1.27 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/24/2015 11:09 MHH71310.005 1
Analytical Lab
Page 10 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020142
Collection Date: 17-Jun-15 5:25 PM
Site: ABMW-2BR
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Molybdenum (Mo)5.76 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 15:20 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 15:20 SLS25600.2 1
Vanadium (V) Low Level 0.658 ug/L EPA 200.8 06/26/2015 15:20 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Molybdenum (Mo)5.67 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 17:16 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 17:16 SLS25600.2 1
Vanadium (V) Low Level 0.873 ug/L EPA 200.8 06/26/2015 17:16 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 0.949 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/19/2015 07:45 AGIBBS551
Analytical Lab
Page 11 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020143
Collection Date: 17-Jun-15 2:10 PM
Site: Filter Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 15:05 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 06/22/2015 10:22 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 15:28 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 15:28 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 15:28 SLS25600.3 1
Analytical Lab
Page 12 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020144
Collection Date: 17-Jun-15 2:10 PM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.021 mg-N/L EPA 353.2 06/24/2015 15:08 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 06/23/2015 13:09 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 06/23/2015 13:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:24 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.010 mg/L EPA 200.7 06/22/2015 12:26 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/22/2015 12:26 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 06/22/2015 12:26 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 06/22/2015 12:26 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/24/2015 11:12 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/26/2015 17:23 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/26/2015 17:23 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/26/2015 17:23 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
Analytical Lab
Page 13 of 48
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060648
2015020144
Collection Date: 17-Jun-15 2:10 PM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 0.371 mg/L SM5310C/EPA9060A 06/28/2015 09:30 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/19/2015 07:45 AGIBBS551
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Analytical Lab
Page 14 of 48
Analytical Lab
Page 15 of 48
Analytical Lab
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Analytical Lab
Page 17 of 48
Analytical Lab
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Page 19 of 48
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SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QF19015Lot Number:
J15060648Project Number:
AB GW Assessment Water -MayoProject Name:
06/26/2015Date Completed:
Grant Wilton
Project Manager
*QF19015*

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QF19015
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water -Mayo
Project Number: J15060648
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF19015

Project Name: AB GW Assessment Water -Mayo
Project Number: J15060648
Sample Number Sample ID Matrix Date Sampled Date Received
001 06/17/2015 16302015020139Aqueous 06/19/2015
002 06/17/2015 17252015020140Aqueous 06/19/2015
003 06/17/2015 15452015020141Aqueous 06/19/2015
004 06/17/2015 17252015020142Aqueous 06/19/2015
006 06/17/20152015020144Aqueous 06/19/2015
(5 samples)
Page: 3 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF19015

Project Name: AB GW Assessment Water -Mayo
Project Number: J15060648
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015020139 Aqueous Alkalinity SM 2320B-51 mg/L 5
001 2015020139 Aqueous Bicarbonate Alkalinity SM 2320B-51 mg/L 5
001 2015020139 Aqueous Methane RSK - 175 38 ug/L 6
002 2015020140 Aqueous Alkalinity SM 2320B-80 mg/L 7
002 2015020140 Aqueous Bicarbonate Alkalinity SM 2320B-80 mg/L 7
002 2015020140 Aqueous Methane RSK - 175 4400 ug/L 8
003 2015020141 Aqueous Alkalinity SM 2320B-290 mg/L 9
003 2015020141 Aqueous Bicarbonate Alkalinity SM 2320B-290 mg/L 9
003 2015020141 Aqueous Methane RSK - 175 3100 ug/L 10
004 2015020142 Aqueous Alkalinity SM 2320B-260 mg/L 11
004 2015020142 Aqueous Bicarbonate Alkalinity SM 2320B-260 mg/L 11
(11 detections)
Page: 4 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020139
QF19015-001
06/17/2015 1630
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/24/2015 2039 HMA 77997
1 (Bicarbonate ) SM 2320B-2011 1 06/24/2015 2039 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/24/2015 2039 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 51 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 51 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020139
QF19015-001
06/17/2015 1630
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 1038 DCS 78114
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 38 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020140
QF19015-002
06/17/2015 1725
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/24/2015 2045 HMA 77997
1 (Bicarbonate ) SM 2320B-2011 1 06/24/2015 2045 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/24/2015 2045 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 80 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 80 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020140
QF19015-002
06/17/2015 1725
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 10 06/26/2015 0951 DCS 78230
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 4400 2ug/L100
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020141
QF19015-003
06/17/2015 1545
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/24/2015 2107 HMA 77997
1 (Bicarbonate ) SM 2320B-2011 1 06/24/2015 2107 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/24/2015 2107 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 290 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 290 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020141
QF19015-003
06/17/2015 1545
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 20 06/26/2015 1002 DCS 78230
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 3100 2ug/L200
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020142
QF19015-004
06/17/2015 1725
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/24/2015 2114 HMA 77997
1 (Bicarbonate ) SM 2320B-2011 1 06/24/2015 2114 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/24/2015 2114 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 260 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 260 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020142
QF19015-004
06/17/2015 1725
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 1206 DCS 78114
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020144
QF19015-006
06/17/2015
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/24/2015 2126 HMA 77997
1 (Bicarbonate ) SM 2320B-2011 1 06/24/2015 2126 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/24/2015 2126 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 14
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020144
QF19015-006
06/17/2015
06/19/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060648
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 1219 DCS 78114
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 14
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
QC Summary
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MB
Batch:
Sample ID:QQ77997-001
77997
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 06/24/2015 182910mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - LCS
Batch:
Sample ID:QQ77997-002
77997
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 100 06/24/2015 183410310090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ78114-001
78114
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/25/2015 090710ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ78114-002
78114
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 110 06/25/2015 08477315070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ78114-003
78114
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/25/2015 08577315070-1300.79 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ78230-001
78230
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/26/2015 092710ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ78230-002
78230
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 110 06/26/2015 08587315070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ78230-003
78230
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/26/2015 09127315070-1300.13 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF19015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Analytical Lab
Page 48 of 48