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Home My WebLink AboutNC0038377_J15060059 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060059 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:7/6/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 59 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015016946 MAYO STEAM 31-May-15 10:30 AM Erin Black ABMW-2BR-EB 2015016947 MAYO STEAM 31-May-15 11:15 AM Erin Black ABMW-2BR (45.0-45.5) 2015016948 MAYO STEAM 31-May-15 4:15 PM Erin Black ABMW-2BR (57.5-58.0) 3 Total Samples 2 of 59 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Margaret Galvin-Karr Date:7/6/2015 Electronic Data Deliverable (EDD) Sent Separately 3 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060059 2015016946 Collection Date: 31-May-15 10:30 AM Site:ABMW-2BR-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060059 2015016947 Collection Date: 31-May-15 11:15 AM Site:ABMW-2BR (45.0-45.5) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060059 2015016948 Collection Date: 31-May-15 4:15 PM Site:ABMW-2BR (57.5-58.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP sulfate blank is 2.3 mg/L. Associated sample results are less than 10 times this number and are therefore suspect. MG-K 7/6/15 -- Additional Information -- 6 of 59 #=CL# July 03, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92252534 92252534 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15060059 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 02, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 52 7 of 59 #=CP# CERTIFICATIONS Pace Project No.: Project: 92252534 J15060059 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 52 8 of 59 #=CP# CERTIFICATIONS Pace Project No.: Project: 92252534 J15060059 Asheville Certification IDs West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 52 9 of 59 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92252534 J15060059 Lab ID Sample ID Matrix Date Collected Date Received 92252534001 2015016946 Water 05/31/15 10:30 06/02/15 16:30 92252534002 2015016947 Solid 05/31/15 11:15 06/02/15 16:30 92252534003 2015016948 Solid 05/31/15 16:15 06/02/15 16:30 92252534004 2015016947 SPLP Water 05/31/15 11:15 06/02/15 16:30 92252534005 2015016948 SPLP Water 05/31/15 16:15 06/02/15 16:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 52 10 of 59 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92252534 J15060059 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92252534001 2015016946 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW 92252534002 2015016947 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OCMB EPA 9056 1 PASI-OCMB EPA 9060 6 PASI-GTJJ 92252534003 2015016948 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OCMB EPA 9056 1 PASI-OCMB EPA 9060 6 PASI-GTJJ 92252534004 2015016947 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW 92252534005 2015016948 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 52 11 of 59 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92252534 J15060059 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92252534001 2015016946 Aluminum 3.8J ug/L 06/10/15 11:4310.0EPA 6020A Calcium 19.5J ug/L 06/10/15 11:4340.0EPA 6020A Cobalt 0.26J ug/L 06/10/15 11:430.50EPA 6020A Iron 18.0J ug/L 06/10/15 11:4350.0EPA 6020A Magnesium 3.5J ug/L 06/10/15 11:4310.0EPA 6020A Manganese 0.37J ug/L 06/10/15 11:430.50EPA 6020A 92252534002 2015016947 Aluminum 6900 mg/kg 06/10/15 15:18 M130.0EPA 6010 Barium 92.2 mg/kg 06/10/15 15:18 M13.0EPA 6010 Beryllium 0.44 mg/kg 06/10/15 15:180.30EPA 6010 Calcium 1640 mg/kg 06/10/15 15:18150EPA 6010 Chromium 8.0 mg/kg 06/10/15 15:181.5EPA 6010 Copper 72.7 mg/kg 06/10/15 15:18 M11.5EPA 6010 Iron 18300 mg/kg 06/10/15 15:18 M112.0EPA 6010 Magnesium 4170 mg/kg 06/10/15 15:18150EPA 6010 Manganese 579 mg/kg 06/10/15 15:18 M11.5EPA 6010 Nickel 4.8 mg/kg 06/10/15 15:181.5EPA 6010 Potassium 329 mg/kg 06/10/15 15:18300EPA 6010 Sodium 353 mg/kg 06/10/15 15:18300EPA 6010 Strontium 23.2 mg/kg 06/10/15 15:183.0EPA 6010 Zinc 39.8 mg/kg 06/10/15 15:186.0EPA 6010 Cobalt 6.0J mg/kg 06/10/15 10:58 M66.0EPA 6020 Lead 3.1J mg/kg 06/10/15 10:586.0EPA 6020 Vanadium 30.3 mg/kg 06/10/15 10:58 M66.0EPA 6020 Percent Moisture 14.2 %06/10/15 08:150.10ASTM D2974-87 pH at 25 Degrees C 7.8 Std. Units 06/10/15 12:300.10EPA 9045 Sulfate 3.1 mg/L 06/16/15 16:28 B2.3EPA 300.0 RSD%8.2 %06/25/15 10:20EPA 9060 92252534003 2015016948 Aluminum 20200 mg/kg 06/10/15 15:3025.5EPA 6010 Barium 41.2 mg/kg 06/10/15 15:302.6EPA 6010 Beryllium 0.26 mg/kg 06/10/15 15:300.26EPA 6010 Calcium 7340 mg/kg 06/10/15 15:30128EPA 6010 Chromium 56.7 mg/kg 06/10/15 15:301.3EPA 6010 Copper 81.7 mg/kg 06/10/15 15:301.3EPA 6010 Iron 43400 mg/kg 06/10/15 15:3010.2EPA 6010 Magnesium 17600 mg/kg 06/10/15 15:30128EPA 6010 Manganese 782 mg/kg 06/10/15 15:301.3EPA 6010 Nickel 53.5 mg/kg 06/10/15 15:301.3EPA 6010 Potassium 360 mg/kg 06/10/15 15:30255EPA 6010 Sodium 303 mg/kg 06/10/15 15:30255EPA 6010 Strontium 49.4 mg/kg 06/10/15 15:302.6EPA 6010 Zinc 102 mg/kg 06/10/15 15:305.1EPA 6010 Cobalt 37.4 mg/kg 06/10/15 11:055.1EPA 6020 Vanadium 84.9 mg/kg 06/10/15 11:055.1EPA 6020 Percent Moisture 4.9 %06/10/15 08:150.10ASTM D2974-87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 52 12 of 59 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92252534 J15060059 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92252534003 2015016948 pH at 25 Degrees C 7.4 Std. Units 06/10/15 12:300.10EPA 9045 Sulfate 2.4 mg/L 06/16/15 16:42 B2.1EPA 300.0 RSD%5.2 %06/25/15 10:43EPA 9060 92252534004 2015016947 SPLP Aluminum 20000 ug/L 07/01/15 01:2310.0EPA 6020A Arsenic 6.1 ug/L 07/01/15 01:230.50EPA 6020A Barium 542 ug/L 07/02/15 09:063.0EPA 6020A Beryllium 1.3 ug/L 07/01/15 01:230.20EPA 6020A Boron 65.9 ug/L 07/01/15 01:235.0EPA 6020A Cadmium 0.085 ug/L 07/01/15 01:230.080EPA 6020A Calcium 5660 ug/L 07/01/15 01:2340.0EPA 6020A Chromium 15.6 ug/L 07/01/15 01:230.50EPA 6020A Cobalt 12.0 ug/L 07/01/15 01:230.50EPA 6020A Copper 171 ug/L 07/01/15 01:231.0EPA 6020A Iron 34200 ug/L 07/02/15 09:06500EPA 6020A Lead 5.6 ug/L 07/01/15 01:230.10EPA 6020A Magnesium 10500 ug/L 07/01/15 01:2310.0EPA 6020A Manganese 1240 ug/L 07/02/15 09:065.0EPA 6020A Molybdenum 2.7 ug/L 07/01/15 01:230.50EPA 6020A Nickel 12.0 ug/L 07/01/15 01:230.50EPA 6020A Potassium 1520 ug/L 07/01/15 01:2350.0EPA 6020A Selenium 7.5 ug/L 07/01/15 01:230.50EPA 6020A Sodium 5580 ug/L 07/01/15 01:2350.0EPA 6020A Strontium 101 ug/L 07/01/15 01:230.50EPA 6020A Thallium 0.037J ug/L 07/01/15 01:230.10EPA 6020A Vanadium 69.0 ug/L 07/01/15 01:231.0EPA 6020A Zinc 199 ug/L 07/01/15 01:235.0EPA 6020A 92252534005 2015016948 SPLP Aluminum 17200 ug/L 07/01/15 01:2810.0EPA 6020A Arsenic 0.35J ug/L 07/01/15 01:280.50EPA 6020A Barium 291 ug/L 07/01/15 01:280.30EPA 6020A Beryllium 0.27 ug/L 07/01/15 01:280.20EPA 6020A Boron 49.7 ug/L 07/01/15 01:285.0EPA 6020A Cadmium 0.059J ug/L 07/01/15 01:280.080EPA 6020A Calcium 5840 ug/L 07/01/15 01:2840.0EPA 6020A Chromium 58.9 ug/L 07/01/15 01:280.50EPA 6020A Cobalt 39.4 ug/L 07/01/15 01:280.50EPA 6020A Copper 66.0 ug/L 07/01/15 01:281.0EPA 6020A Iron 40200 ug/L 07/02/15 09:10250EPA 6020A Lead 0.97 ug/L 07/01/15 01:280.10EPA 6020A Magnesium 12900 ug/L 07/01/15 01:2810.0EPA 6020A Manganese 912 ug/L 07/02/15 09:102.5EPA 6020A Molybdenum 1.2 ug/L 07/01/15 01:280.50EPA 6020A Nickel 48.6 ug/L 07/01/15 01:280.50EPA 6020A Potassium 590 ug/L 07/01/15 01:2850.0EPA 6020A Sodium 4130 ug/L 07/01/15 01:2850.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 52 13 of 59 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92252534 J15060059 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92252534005 2015016948 SPLP Strontium 53.0 ug/L 07/01/15 01:280.50EPA 6020A Vanadium 114 ug/L 07/01/15 01:281.0EPA 6020A Zinc 176 ug/L 07/01/15 01:285.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 52 14 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 6010 Date:July 03, 2015 Description:6010 MET ICP General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24583 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252534002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1235380) • Aluminum • Barium • Iron • Manganese • MSD (Lab ID: 1235381) • Aluminum • Barium • Copper • Iron • Manganese Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 52 15 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 6010 Date:July 03, 2015 Description:6010 MET ICP Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 15013 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 52 16 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 6020 Date:July 03, 2015 Description:6020 MET ICPMS General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24584 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252534002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1235384) • Antimony • Cadmium • Vanadium • MSD (Lab ID: 1235385) • Antimony • Cadmium • Cobalt • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 52 17 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 6020 Date:July 03, 2015 Description:6020 MET ICPMS Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 9967 Analyte Comments: QC Batch: MPRP/24584 N2: The lab does not hold TNI accreditation for this parameter. • 2015016947 (Lab ID: 92252534002) • Antimony • 2015016948 (Lab ID: 92252534003) • Antimony • BLANK (Lab ID: 1235382) • Antimony • LCS (Lab ID: 1235383) • Antimony • MS (Lab ID: 1235384) • Antimony • MSD (Lab ID: 1235385) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 52 18 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 6020A Date:July 03, 2015 Description:6020A MET ICPMS General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55040 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252908015 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1989131) • Aluminum • MSD (Lab ID: 1989132) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 52 19 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 7470A Date:July 03, 2015 Description:7470A Mercury General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 52 20 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 7471 Date:July 03, 2015 Description:7471 Mercury General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 52 21 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 9045 Date:July 03, 2015 Description:9045 pH Soil General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 52 22 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 300.0 Date:July 03, 2015 Description:300.0 IC Anions, SPLP General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23324 B: Analyte was detected in the associated method blank. • BLANK for HBN 268289 [WETA/233 (Lab ID: 1485896) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 52 23 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 353.2 Date:July 03, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015016947 (Lab ID: 92252534002) • 2015016948 (Lab ID: 92252534003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 52 24 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy SM 4500-Cl-E Date:July 03, 2015 Description:4500 Chloride, SPLP General Information: 2 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23354 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252532003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1487999) • Chloride • MSD (Lab ID: 1488000) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 52 25 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 9056 Date:July 03, 2015 Description:9056 IC Anions General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47029 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015016947 (Lab ID: 92252534002) • Chloride • Sulfate • 2015016948 (Lab ID: 92252534003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 52 26 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 9056 Date:July 03, 2015 Description:9056 IC Anions 48hr General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015016947 (Lab ID: 92252534002) • 2015016948 (Lab ID: 92252534003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47028 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015016947 (Lab ID: 92252534002) • Nitrate as N • 2015016948 (Lab ID: 92252534003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 52 27 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92252534 J15060059 Method: Client:Duke Energy EPA 9060 Date:July 03, 2015 Description:Total Organic Carbon Quad General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 52 28 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016946 Lab ID:92252534001 Collected:05/31/15 10:30 Received:06/02/15 16:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 3.8J ug/L 06/10/15 11:43 7429-90-506/10/15 08:5010.0 3.0 1 Antimony ND ug/L 06/10/15 11:43 7440-36-006/10/15 08:500.50 0.15 1 Arsenic ND ug/L 06/10/15 11:43 7440-38-206/10/15 08:500.50 0.11 1 Barium ND ug/L 06/10/15 11:43 7440-39-306/10/15 08:500.30 0.081 1 Beryllium ND ug/L 06/10/15 11:43 7440-41-706/10/15 08:500.20 0.067 1 Boron ND ug/L 06/10/15 11:43 7440-42-806/10/15 08:505.0 1.1 1 Cadmium ND ug/L 06/10/15 11:43 7440-43-906/10/15 08:500.080 0.024 1 Calcium 19.5J ug/L 06/10/15 11:43 7440-70-206/10/15 08:5040.0 16.0 1 Chromium ND ug/L 06/10/15 11:43 7440-47-306/10/15 08:500.50 0.17 1 Cobalt 0.26J ug/L 06/10/15 11:43 7440-48-406/10/15 08:500.50 0.13 1 Copper ND ug/L 06/10/15 11:43 7440-50-806/10/15 08:501.0 0.21 1 Iron 18.0J ug/L 06/10/15 11:43 7439-89-606/10/15 08:5050.0 13.7 1 Lead ND ug/L 06/10/15 11:43 7439-92-106/10/15 08:500.10 0.046 1 Magnesium 3.5J ug/L 06/10/15 11:43 7439-95-406/10/15 08:5010.0 3.2 1 Manganese 0.37J ug/L 06/10/15 11:43 7439-96-506/10/15 08:500.50 0.24 1 Molybdenum ND ug/L 06/10/15 11:43 7439-98-706/10/15 08:500.50 0.094 1 Nickel ND ug/L 06/10/15 11:43 7440-02-006/10/15 08:500.50 0.16 1 Potassium ND ug/L 06/10/15 11:43 7440-09-706/10/15 08:5050.0 11.7 1 Selenium ND ug/L 06/10/15 11:43 7782-49-206/10/15 08:500.50 0.20 1 Sodium ND ug/L 06/10/15 11:43 7440-23-506/10/15 08:5050.0 16.3 1 Strontium ND ug/L 06/10/15 11:43 7440-24-606/10/15 08:500.50 0.13 1 Thallium ND ug/L 06/10/15 11:43 7440-28-006/10/15 08:500.10 0.015 1 Vanadium ND ug/L 06/10/15 11:43 7440-62-206/10/15 08:501.0 0.28 1 Zinc ND ug/L 06/10/15 11:43 7440-66-606/10/15 08:505.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/05/15 14:05 7439-97-606/05/15 08:050.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 52 29 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016947 Lab ID:92252534002 Collected:05/31/15 11:15 Received:06/02/15 16:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 6900 mg/kg 06/10/15 15:18 7429-90-5 M106/08/15 16:0830.0 15.0 5 Barium 92.2 mg/kg 06/10/15 15:18 7440-39-3 M106/08/15 16:083.0 1.5 5 Beryllium 0.44 mg/kg 06/10/15 15:18 7440-41-706/08/15 16:080.30 0.15 5 Boron ND mg/kg 06/10/15 15:18 7440-42-806/08/15 16:0815.0 7.5 5 Calcium 1640 mg/kg 06/10/15 15:18 7440-70-206/08/15 16:0815075.1 5 Chromium 8.0 mg/kg 06/10/15 15:18 7440-47-306/08/15 16:081.5 0.75 5 Copper 72.7 mg/kg 06/10/15 15:18 7440-50-8 M106/08/15 16:081.5 0.75 5 Iron 18300 mg/kg 06/10/15 15:18 7439-89-6 M106/08/15 16:0812.0 6.0 5 Magnesium 4170 mg/kg 06/10/15 15:18 7439-95-406/08/15 16:0815075.1 5 Manganese 579 mg/kg 06/10/15 15:18 7439-96-5 M106/08/15 16:081.5 0.75 5 Molybdenum ND mg/kg 06/10/15 15:18 7439-98-706/08/15 16:083.0 1.5 5 Nickel 4.8 mg/kg 06/10/15 15:18 7440-02-006/08/15 16:081.5 0.75 5 Potassium 329 mg/kg 06/10/15 15:18 7440-09-706/08/15 16:083001505 Sodium 353 mg/kg 06/10/15 15:18 7440-23-506/08/15 16:083001505 Strontium 23.2 mg/kg 06/10/15 15:18 7440-24-606/08/15 16:083.0 1.5 5 Zinc 39.8 mg/kg 06/10/15 15:18 7440-66-606/08/15 16:086.0 3.0 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/10/15 10:58 7440-36-0 M6,N206/08/15 16:086.0 3.0 100 Arsenic ND mg/kg 06/10/15 10:58 7440-38-206/08/15 16:086.0 3.0 100 Cadmium ND mg/kg 06/10/15 10:58 7440-43-9 M606/08/15 16:080.72 0.36 100 Cobalt 6.0J mg/kg 06/10/15 10:58 7440-48-4 M606/08/15 16:086.0 3.0 100 Lead 3.1J mg/kg 06/10/15 10:58 7439-92-106/08/15 16:086.0 3.0 100 Selenium ND mg/kg 06/10/15 10:58 7782-49-2 M606/08/15 16:086.0 3.0 100 Thallium ND mg/kg 06/10/15 10:58 7440-28-006/08/15 16:086.0 3.0 100 Vanadium 30.3 mg/kg 06/10/15 10:58 7440-62-2 M606/08/15 16:086.0 3.0 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/09/15 12:20 7439-97-606/08/15 16:220.0096 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 14.2 %06/10/15 08:150.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.8 Std. Units 06/10/15 12:300.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/04/15 02:10300.0 IC Anions, SPLP Sulfate 3.1 mg/L 06/16/15 16:28 14808-79-8 B2.3 1.2 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/04/15 02:10353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 06/18/15 17:12 H10.23 0.23 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 06/04/15 02:104500 Chloride, SPLP Chloride ND mg/L 06/18/15 04:55 16887-00-65.8 2.9 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 52 30 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016947 Lab ID:92252534002 Collected:05/31/15 11:15 Received:06/02/15 16:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/06/15 12:16 16887-00-6 D32891455 Sulfate ND mg/kg 06/06/15 12:16 14808-79-8 D32891455 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/06/15 12:16 14797-55-8 D3,H328.9 14.5 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 06/25/15 10:20 7440-44-07003501 Total Organic Carbon ND mg/kg 06/25/15 10:27 7440-44-06993501 Total Organic Carbon ND mg/kg 06/25/15 10:32 7440-44-06943471 Total Organic Carbon ND mg/kg 06/25/15 10:38 7440-44-07043521 Mean Total Organic Carbon ND mg/kg 06/25/15 10:20 7440-44-06993501 Surrogates RSD%8.2 %06/25/15 10:201 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 52 31 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016948 Lab ID:92252534003 Collected:05/31/15 16:15 Received:06/02/15 16:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 20200 mg/kg 06/10/15 15:30 7429-90-506/08/15 16:0825.5 12.8 5 Barium 41.2 mg/kg 06/10/15 15:30 7440-39-306/08/15 16:082.6 1.3 5 Beryllium 0.26 mg/kg 06/10/15 15:30 7440-41-706/08/15 16:080.26 0.13 5 Boron ND mg/kg 06/10/15 15:30 7440-42-806/08/15 16:0812.8 6.4 5 Calcium 7340 mg/kg 06/10/15 15:30 7440-70-206/08/15 16:0812863.8 5 Chromium 56.7 mg/kg 06/10/15 15:30 7440-47-306/08/15 16:081.3 0.64 5 Copper 81.7 mg/kg 06/10/15 15:30 7440-50-806/08/15 16:081.3 0.64 5 Iron 43400 mg/kg 06/10/15 15:30 7439-89-606/08/15 16:0810.2 5.1 5 Magnesium 17600 mg/kg 06/10/15 15:30 7439-95-406/08/15 16:0812863.8 5 Manganese 782 mg/kg 06/10/15 15:30 7439-96-506/08/15 16:081.3 0.64 5 Molybdenum ND mg/kg 06/10/15 15:30 7439-98-706/08/15 16:082.6 1.3 5 Nickel 53.5 mg/kg 06/10/15 15:30 7440-02-006/08/15 16:081.3 0.64 5 Potassium 360 mg/kg 06/10/15 15:30 7440-09-706/08/15 16:082551285 Sodium 303 mg/kg 06/10/15 15:30 7440-23-506/08/15 16:082551285 Strontium 49.4 mg/kg 06/10/15 15:30 7440-24-606/08/15 16:082.6 1.3 5 Zinc 102 mg/kg 06/10/15 15:30 7440-66-606/08/15 16:085.1 2.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/10/15 11:05 7440-36-0 N206/08/15 16:085.1 2.6 100 Arsenic ND mg/kg 06/10/15 11:05 7440-38-206/08/15 16:085.1 2.6 100 Cadmium ND mg/kg 06/10/15 11:05 7440-43-906/08/15 16:080.61 0.31 100 Cobalt 37.4 mg/kg 06/10/15 11:05 7440-48-406/08/15 16:085.1 2.6 100 Lead ND mg/kg 06/10/15 11:05 7439-92-106/08/15 16:085.1 2.6 100 Selenium ND mg/kg 06/10/15 11:05 7782-49-206/08/15 16:085.1 2.6 100 Thallium ND mg/kg 06/10/15 11:05 7440-28-006/08/15 16:085.1 2.6 100 Vanadium 84.9 mg/kg 06/10/15 11:05 7440-62-206/08/15 16:085.1 2.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/09/15 12:26 7439-97-606/08/15 16:220.0087 0.0043 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 4.9 %06/10/15 08:150.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.4 Std. Units 06/10/15 12:300.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/04/15 02:10300.0 IC Anions, SPLP Sulfate 2.4 mg/L 06/16/15 16:42 14808-79-8 B2.1 1.1 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/04/15 02:10353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 06/18/15 17:14 H10.21 0.21 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 06/04/15 02:104500 Chloride, SPLP Chloride ND mg/L 06/18/15 05:00 16887-00-65.3 2.6 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 52 32 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016948 Lab ID:92252534003 Collected:05/31/15 16:15 Received:06/02/15 16:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/06/15 12:38 16887-00-6 D32631315 Sulfate ND mg/kg 06/06/15 12:38 14808-79-8 D32631315 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/06/15 12:38 14797-55-8 D3,H326.3 13.1 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 06/25/15 10:43 7440-44-06353181 Total Organic Carbon ND mg/kg 06/25/15 10:49 7440-44-06323161 Total Organic Carbon ND mg/kg 06/25/15 10:54 7440-44-06343171 Total Organic Carbon ND mg/kg 06/25/15 11:00 7440-44-06353171 Mean Total Organic Carbon ND mg/kg 06/25/15 10:43 7440-44-06343171 Surrogates RSD%5.2 %06/25/15 10:431 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 52 33 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016947 SPLP Lab ID:92252534004 Collected:05/31/15 11:15 Received:06/02/15 16:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 20000 ug/L 07/01/15 01:23 7429-90-506/29/15 10:2110.0 3.0 1 Antimony ND ug/L 07/01/15 01:23 7440-36-006/29/15 10:210.50 0.15 1 Arsenic 6.1 ug/L 07/01/15 01:23 7440-38-206/29/15 10:210.50 0.11 1 Barium 542 ug/L 07/02/15 09:06 7440-39-306/29/15 10:213.0 0.81 10 Beryllium 1.3 ug/L 07/01/15 01:23 7440-41-706/29/15 10:210.20 0.067 1 Boron 65.9 ug/L 07/01/15 01:23 7440-42-806/29/15 10:215.0 1.1 1 Cadmium 0.085 ug/L 07/01/15 01:23 7440-43-906/29/15 10:210.080 0.024 1 Calcium 5660 ug/L 07/01/15 01:23 7440-70-206/29/15 10:2140.0 16.0 1 Chromium 15.6 ug/L 07/01/15 01:23 7440-47-306/29/15 10:210.50 0.17 1 Cobalt 12.0 ug/L 07/01/15 01:23 7440-48-406/29/15 10:210.50 0.13 1 Copper 171 ug/L 07/01/15 01:23 7440-50-806/29/15 10:211.0 0.21 1 Iron 34200 ug/L 07/02/15 09:06 7439-89-606/29/15 10:2150013710 Lead 5.6 ug/L 07/01/15 01:23 7439-92-106/29/15 10:210.10 0.046 1 Magnesium 10500 ug/L 07/01/15 01:23 7439-95-406/29/15 10:2110.0 3.2 1 Manganese 1240 ug/L 07/02/15 09:06 7439-96-506/29/15 10:215.0 2.4 10 Molybdenum 2.7 ug/L 07/01/15 01:23 7439-98-706/29/15 10:210.50 0.094 1 Nickel 12.0 ug/L 07/01/15 01:23 7440-02-006/29/15 10:210.50 0.16 1 Potassium 1520 ug/L 07/01/15 01:23 7440-09-706/29/15 10:2150.0 11.7 1 Selenium 7.5 ug/L 07/01/15 01:23 7782-49-206/29/15 10:210.50 0.20 1 Sodium 5580 ug/L 07/01/15 01:23 7440-23-506/29/15 10:2150.0 16.3 1 Strontium 101 ug/L 07/01/15 01:23 7440-24-606/29/15 10:210.50 0.13 1 Thallium 0.037J ug/L 07/01/15 01:23 7440-28-006/29/15 10:210.10 0.015 1 Vanadium 69.0 ug/L 07/01/15 01:23 7440-62-206/29/15 10:211.0 0.28 1 Zinc 199 ug/L 07/01/15 01:23 7440-66-606/29/15 10:215.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 07/01/15 18:10 7439-97-606/29/15 14:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 52 34 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92252534 J15060059 Sample:2015016948 SPLP Lab ID:92252534005 Collected:05/31/15 16:15 Received:06/02/15 16:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 17200 ug/L 07/01/15 01:28 7429-90-506/29/15 10:2110.0 3.0 1 Antimony ND ug/L 07/01/15 01:28 7440-36-006/29/15 10:210.50 0.15 1 Arsenic 0.35J ug/L 07/01/15 01:28 7440-38-206/29/15 10:210.50 0.11 1 Barium 291 ug/L 07/01/15 01:28 7440-39-306/29/15 10:210.30 0.081 1 Beryllium 0.27 ug/L 07/01/15 01:28 7440-41-706/29/15 10:210.20 0.067 1 Boron 49.7 ug/L 07/01/15 01:28 7440-42-806/29/15 10:215.0 1.1 1 Cadmium 0.059J ug/L 07/01/15 01:28 7440-43-906/29/15 10:210.080 0.024 1 Calcium 5840 ug/L 07/01/15 01:28 7440-70-206/29/15 10:2140.0 16.0 1 Chromium 58.9 ug/L 07/01/15 01:28 7440-47-306/29/15 10:210.50 0.17 1 Cobalt 39.4 ug/L 07/01/15 01:28 7440-48-406/29/15 10:210.50 0.13 1 Copper 66.0 ug/L 07/01/15 01:28 7440-50-806/29/15 10:211.0 0.21 1 Iron 40200 ug/L 07/02/15 09:10 7439-89-606/29/15 10:2125068.5 5 Lead 0.97 ug/L 07/01/15 01:28 7439-92-106/29/15 10:210.10 0.046 1 Magnesium 12900 ug/L 07/01/15 01:28 7439-95-406/29/15 10:2110.0 3.2 1 Manganese 912 ug/L 07/02/15 09:10 7439-96-506/29/15 10:212.5 1.2 5 Molybdenum 1.2 ug/L 07/01/15 01:28 7439-98-706/29/15 10:210.50 0.094 1 Nickel 48.6 ug/L 07/01/15 01:28 7440-02-006/29/15 10:210.50 0.16 1 Potassium 590 ug/L 07/01/15 01:28 7440-09-706/29/15 10:2150.0 11.7 1 Selenium ND ug/L 07/01/15 01:28 7782-49-206/29/15 10:210.50 0.20 1 Sodium 4130 ug/L 07/01/15 01:28 7440-23-506/29/15 10:2150.0 16.3 1 Strontium 53.0 ug/L 07/01/15 01:28 7440-24-606/29/15 10:210.50 0.13 1 Thallium ND ug/L 07/01/15 01:28 7440-28-006/29/15 10:210.10 0.015 1 Vanadium 114 ug/L 07/01/15 01:28 7440-62-206/29/15 10:211.0 0.28 1 Zinc 176 ug/L 07/01/15 01:28 7440-66-606/29/15 10:215.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 07/01/15 18:13 7439-97-606/29/15 14:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 52 35 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13774 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92252534001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1985612 Associated Lab Samples:92252534001 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/05/15 13:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1985613LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.35 105 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1985614MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246833005 1985615 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L H159380-12091 1 2050.77 5.4 5.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 52 36 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/14018 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92252534004, 92252534005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2006739 Associated Lab Samples:92252534004, 92252534005 Matrix:Water Analyzed Mercury ug/L ND 0.20 07/01/15 17:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2006740LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.95 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2007452MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92255755005 2007453 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120105 2 205ND5.2 5.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 52 37 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5828 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1235386 Associated Lab Samples:92252534002, 92252534003 Matrix:Solid Analyzed Mercury mg/kg ND 0.0078 06/09/15 12:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1235387LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.080.079 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1235388MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252534002 1235389 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .0932 97 80-12096 2 20.0944ND 0.092 0.093 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 52 38 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24583 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1235378 Associated Lab Samples:92252534002, 92252534003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.2 06/10/15 15:10 Barium mg/kg ND 0.52 06/10/15 15:10 Beryllium mg/kg ND 0.052 06/10/15 15:10 Boron mg/kg ND 2.6 06/10/15 15:10 Calcium mg/kg ND 26.0 06/10/15 15:10 Chromium mg/kg ND 0.26 06/10/15 15:10 Copper mg/kg ND 0.26 06/10/15 15:10 Iron mg/kg ND 2.1 06/10/15 15:10 Magnesium mg/kg ND 26.0 06/10/15 15:10 Manganese mg/kg ND 0.26 06/10/15 15:10 Molybdenum mg/kg ND 0.52 06/10/15 15:10 Nickel mg/kg ND 0.26 06/10/15 15:10 Potassium mg/kg ND 52.0 06/10/15 15:10 Sodium mg/kg ND 52.0 06/10/15 15:10 Strontium mg/kg ND 0.52 06/10/15 15:10 Zinc mg/kg ND 1.0 06/10/15 15:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1235379LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 135128 105 80-120 Barium mg/kg 13.812.8 107 80-120 Beryllium mg/kg 1.41.3 105 80-120 Boron mg/kg 134128 105 80-120 Calcium mg/kg 686641 107 80-120 Chromium mg/kg 13.412.8 104 80-120 Copper mg/kg 13.312.8 104 80-120 Iron mg/kg 135128 105 80-120 Magnesium mg/kg 680641 106 80-120 Manganese mg/kg 13.712.8 107 80-120 Molybdenum mg/kg 13.012.8 102 80-120 Nickel mg/kg 13.512.8 105 80-120 Potassium mg/kg 685641 107 80-120 Sodium mg/kg 709641 111 80-120 Strontium mg/kg 13.512.8 106 80-120 Zinc mg/kg 67.364.1 105 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 52 39 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1235380MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252534002 1235381 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M114885275-125964 1 20141690081608260 Barium mg/kg M114.8 3 75-1252 0 2014.192.2 92.6 92.4 Beryllium mg/kg 1.52 92 75-12596 1 201.40.44 1.8 1.8 Boron mg/kg 148 92 75-12593 5 20141ND136130 Calcium mg/kg 740 93 75-12579 6 20704164023302200 Chromium mg/kg 14.8 85 75-12596 4 2014.18.0 20.6 21.5 Copper mg/kg M114.8 96 75-125129 4 2014.172.7 86.9 90.7 Iron mg/kg M1148-605 75-125133 6 20141183001740018500 Magnesium mg/kg 740 91 75-12577 3 20704417048404710 Manganese mg/kg M114.8 -558 75-125-509 2 2014.1579 496 507 Molybdenum mg/kg 14.8 88 75-12589 4 2014.1ND 13.2 12.7 Nickel mg/kg 14.8 97 75-125101 1 2014.14.8 19.2 19.0 Potassium mg/kg 740 92 75-12597 1 2070432910101010 Sodium mg/kg 740 96 75-125104 2 2070435310701090 Strontium mg/kg 14.8 93 75-12593 2 2014.123.2 36.9 36.3 Zinc mg/kg 74 97 75-12597 3 2070.439.8 112 108 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 52 40 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24584 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1235382 Associated Lab Samples:92252534002, 92252534003 Matrix:Solid Analyzed Antimony mg/kg ND 0.050 N206/10/15 10:54 Arsenic mg/kg ND 0.050 06/10/15 10:54 Cadmium mg/kg ND 0.0060 06/10/15 10:54 Cobalt mg/kg ND 0.050 06/10/15 10:54 Lead mg/kg ND 0.050 06/10/15 10:54 Selenium mg/kg ND 0.050 06/10/15 10:54 Thallium mg/kg ND 0.050 06/10/15 10:54 Vanadium mg/kg ND 0.050 06/10/15 10:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1235383LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.7 N22.5 108 80-120 Arsenic mg/kg 2.72.5 105 80-120 Cadmium mg/kg 0.27.25 106 80-120 Cobalt mg/kg 2.72.5 106 80-120 Lead mg/kg 2.72.5 107 80-120 Selenium mg/kg 2.72.5 107 80-120 Thallium mg/kg 2.72.5 107 80-120 Vanadium mg/kg 2.72.5 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1235384MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252534002 1235385 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N22.8 64 75-12556 202.8ND ND ND Arsenic mg/kg 2.8 94 75-12595 202.8ND 3.9J 4.0J Cadmium mg/kg M6.28 61 75-12555 20.28ND ND ND Cobalt mg/kg M62.8 101 75-12569 11 202.86.0J 8.8 7.9 Lead mg/kg 2.8 82 75-12577 202.83.1J 5.4J 5.3J Selenium mg/kg M62.8 86 75-12570 202.8ND 4.3J 3.9J Thallium mg/kg 2.8 95 75-12593 202.8ND 2.8J ND Vanadium mg/kg M62.8 140 75-12553 7 202.830.3 34.3 31.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 52 41 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/55040 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92252534001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1989129 Associated Lab Samples:92252534001 Matrix:Water Analyzed Aluminum ug/L ND 10.0 06/10/15 11:38 Antimony ug/L ND 0.50 06/10/15 11:38 Arsenic ug/L ND 0.50 06/10/15 11:38 Barium ug/L ND 0.30 06/10/15 11:38 Beryllium ug/L ND 0.20 06/10/15 11:38 Boron ug/L ND 5.0 06/10/15 11:38 Cadmium ug/L ND 0.080 06/10/15 11:38 Calcium ug/L ND 40.0 06/10/15 11:38 Chromium ug/L ND 0.50 06/10/15 11:38 Cobalt ug/L ND 0.50 06/10/15 11:38 Copper ug/L ND 1.0 06/10/15 11:38 Iron ug/L ND 50.0 06/10/15 11:38 Lead ug/L ND 0.10 06/10/15 11:38 Magnesium ug/L ND 10.0 06/10/15 11:38 Manganese ug/L ND 0.50 06/10/15 11:38 Molybdenum ug/L ND 0.50 06/10/15 11:38 Nickel ug/L ND 0.50 06/10/15 11:38 Potassium ug/L ND 50.0 06/10/15 11:38 Selenium ug/L ND 0.50 06/10/15 11:38 Sodium ug/L ND 50.0 06/10/15 11:38 Strontium ug/L ND 0.50 06/10/15 11:38 Thallium ug/L ND 0.10 06/10/15 11:38 Vanadium ug/L ND 1.0 06/10/15 11:38 Zinc ug/L ND 5.0 06/10/15 11:38 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989130LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 79.780 100 80-120 Antimony ug/L 76.780 96 80-120 Arsenic ug/L 76.880 96 80-120 Barium ug/L 76.780 96 80-120 Beryllium ug/L 83.080 104 80-120 Boron ug/L 74.680 93 80-120 Cadmium ug/L 79.680 99 80-120 Calcium ug/L 10101000 101 80-120 Chromium ug/L 78.680 98 80-120 Cobalt ug/L 76.680 96 80-120 Copper ug/L 77.480 97 80-120 Iron ug/L 10001000 100 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 52 42 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989130LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 77.380 97 80-120 Magnesium ug/L 9761000 98 80-120 Manganese ug/L 77.880 97 80-120 Molybdenum ug/L 76.980 96 80-120 Nickel ug/L 76.280 95 80-120 Potassium ug/L 9451000 94 80-120 Selenium ug/L 77.680 97 80-120 Sodium ug/L 9651000 96 80-120 Strontium ug/L 76.780 96 80-120 Thallium ug/L 81.680 102 80-120 Vanadium ug/L 78.280 98 80-120 Zinc ug/L 78.280 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1989131MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252908015 1989132 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18013675-125132 2 2080103212208 Antimony ug/L 80 96 75-12596 0 2080ND77.2 77.2 Arsenic ug/L 80 95 75-12595 0 2080ND75.9 75.8 Barium ug/L 80 97 75-12596 1 20802.3 79.8 79.2 Beryllium ug/L 80 103 75-125101 1 2080ND82.2 81.1 Boron ug/L 80 99 75-12592 8 20801.9J 81.2 75.1 Cadmium ug/L 80 100 75-125101 1 2080ND79.8 80.4 Calcium ug/L 1000 102 75-12592 9 20100014811701060 Chromium ug/L 80 100 75-125100 0 20800.58 80.4 80.5 Cobalt ug/L 80 96 75-12596 0 2080ND77.0 77.0 Copper ug/L 80 97 75-12598 0 20802.2 80.2 80.2 Iron ug/L 1000 101 75-125101 0 20100019912101210 Lead ug/L 80 97 75-12597 0 20800.14 77.6 77.4 Magnesium ug/L 1000 99 75-12598 0 20100044.4 1030 1030 Manganese ug/L 80 100 75-12597 2 20804.2 83.9 82.1 Molybdenum ug/L 80 96 75-12597 1 20800.32J 76.8 77.6 Nickel ug/L 80 96 75-12595 1 20800.60 77.2 76.6 Potassium ug/L 1000 98 75-12596 2 20100017211501130 Selenium ug/L 80 97 75-12598 1 2080ND77.5 78.6 Sodium ug/L 1000 96 75-12598 1 20100029312601270 Strontium ug/L 80 95 75-12597 2 20800.55 76.7 78.4 Thallium ug/L 80 102 75-125102 0 2080ND81.7 81.4 Vanadium ug/L 80 99 75-12597 1 2080ND79.0 78.0 Zinc ug/L 80 98 75-12599 1 20803.5J 81.9 82.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 52 43 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/55571 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92252534004, 92252534005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2006731 Associated Lab Samples:92252534004, 92252534005 Matrix:Water Analyzed Aluminum ug/L ND 10.0 07/01/15 00:15 Antimony ug/L ND 0.50 07/01/15 00:15 Arsenic ug/L ND 0.50 07/01/15 00:15 Barium ug/L ND 0.30 07/01/15 00:15 Beryllium ug/L ND 0.20 07/01/15 00:15 Boron ug/L ND 5.0 07/01/15 00:15 Cadmium ug/L ND 0.080 07/01/15 00:15 Calcium ug/L ND 40.0 07/02/15 07:11 Chromium ug/L ND 0.50 07/01/15 00:15 Cobalt ug/L ND 0.50 07/01/15 00:15 Copper ug/L ND 1.0 07/02/15 07:11 Iron ug/L ND 50.0 07/01/15 00:15 Lead ug/L ND 0.10 07/01/15 00:15 Magnesium ug/L ND 10.0 07/01/15 00:15 Manganese ug/L ND 0.50 07/01/15 00:15 Molybdenum ug/L ND 0.50 07/01/15 00:15 Nickel ug/L ND 0.50 07/01/15 00:15 Potassium ug/L ND 50.0 07/01/15 00:15 Selenium ug/L ND 0.50 07/01/15 00:15 Sodium ug/L ND 50.0 07/01/15 00:15 Strontium ug/L ND 0.50 07/01/15 00:15 Thallium ug/L ND 0.10 07/01/15 00:15 Vanadium ug/L ND 1.0 07/01/15 00:15 Zinc ug/L ND 5.0 07/01/15 00:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2006732LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 76.180 95 80-120 Antimony ug/L 76.280 95 80-120 Arsenic ug/L 77.580 97 80-120 Barium ug/L 79.180 99 80-120 Beryllium ug/L 82.080 103 80-120 Boron ug/L 87.180 109 80-120 Cadmium ug/L 77.980 97 80-120 Calcium ug/L 10301000 103 80-120 Chromium ug/L 78.180 98 80-120 Cobalt ug/L 78.480 98 80-120 Copper ug/L 77.480 97 80-120 Iron ug/L 9761000 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 52 44 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2006732LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 77.080 96 80-120 Magnesium ug/L 9641000 96 80-120 Manganese ug/L 78.480 98 80-120 Molybdenum ug/L 76.880 96 80-120 Nickel ug/L 78.280 98 80-120 Potassium ug/L 9791000 98 80-120 Selenium ug/L 78.280 98 80-120 Sodium ug/L 9941000 99 80-120 Strontium ug/L 77.380 97 80-120 Thallium ug/L 76.680 96 80-120 Vanadium ug/L 78.680 98 80-120 Zinc ug/L 77.280 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2007450MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92255755020 2007451 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 111 75-125110 0 20805.6J 94.1 93.8 Antimony ug/L 80 98 75-12596 2 2080ND78.5 76.7 Arsenic ug/L 80 101 75-12597 4 2080ND81.1 77.9 Barium ug/L 80 101 75-12599 2 20800.26J 80.8 79.3 Beryllium ug/L 80 100 75-125101 1 2080ND79.8 80.6 Boron ug/L 80 104 75-125101 3 2080ND84.4 81.9 Cadmium ug/L 80 101 75-12599 2 2080ND80.7 79.4 Calcium ug/L 1000 103 75-125101 2 20100076.6 1100 1090 Chromium ug/L 80 101 75-12599 3 2080ND81.2 79.1 Cobalt ug/L 80 103 75-12598 4 2080ND82.2 78.6 Copper ug/L 80 102 75-12598 4 20800.32J 81.9 78.9 Iron ug/L 1000 101 75-12598 3 20100014.7J 1030 996 Lead ug/L 80 99 75-12597 3 2080ND79.3 77.2 Magnesium ug/L 1000 102 75-12599 3 2010007.9J 1030 1000 Manganese ug/L 80 102 75-125100 2 20800.42J 81.6 80.2 Molybdenum ug/L 80 100 75-12598 2 2080ND80.0 78.7 Nickel ug/L 80 105 75-125100 4 2080ND84.0 80.4 Potassium ug/L 1000 104 75-125101 3 20100018.5J 1050 1030 Selenium ug/L 80 103 75-12598 4 2080ND82.1 78.6 Sodium ug/L 1000 104 75-12597 6 20100031.9J 1070 1010 Strontium ug/L 80 100 75-12599 1 20800.50 80.6 79.8 Thallium ug/L 80 101 75-12599 2 2080ND81.1 79.2 Vanadium ug/L 80 102 75-12599 3 2080ND82.0 79.4 Zinc ug/L 80 106 75-12594 10 20808.0 92.6 83.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 52 45 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3629 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92252534002, 92252534003 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190066001 1237772SAMPLE DUPLICATE: Percent Moisture %4.0 D623105.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191549001 1237773SAMPLE DUPLICATE: Percent Moisture %20.1 7 1021.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191958002 1237774SAMPLE DUPLICATE: Percent Moisture %20.2 0 1020.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 35192020007 1237775SAMPLE DUPLICATE: Percent Moisture %22.6 6 1024.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 35192120002 1237776SAMPLE DUPLICATE: Percent Moisture %10.2 D6191012.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 52 46 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37953 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92252534002, 92252534003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92253145001 1478381SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.8 0 105.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92252534003 1478382SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.4 0 107.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 52 47 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23324 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1485896 Associated Lab Samples:92252534002, 92252534003 Matrix:Water Analyzed Sulfate mg/L 2.3 2.0 06/16/15 15:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1485897LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.620 98 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1485898MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252532003 1485899 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20 98 99 1206.3 26.0 26.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 52 48 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23372 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1488925 Associated Lab Samples:92252534002, 92252534003 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.14 0.020 Z206/18/15 17:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1488926LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1488927MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252532003 1488928 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.5 98 90-11097 1 102.5ND 2.6 2.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 52 49 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23354 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1487997 Associated Lab Samples:92252534002, 92252534003 Matrix:Water Analyzed Chloride mg/L ND 1.0 06/18/15 04:51 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1487998LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 19.820 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1487999MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252532003 1488000 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L M1208690-11086 0 1020ND17.3 17.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 52 50 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/47029 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1233607 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.8 06/06/15 06:55 Sulfate mg/kg ND 49.8 06/06/15 06:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1233608LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 510496 103 80-120 Sulfate mg/kg 507496 102 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1233610MATRIX SPIKE SAMPLE: MSSpike Result 92252369001 Chloride mg/kg 1240 M113107680-120ND Sulfate mg/kg 13001310 84 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92252369001 1233609SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 52 51 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/47028 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1233603 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 06/06/15 06:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1233604LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 52.749.6 106 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1233606MATRIX SPIKE SAMPLE: MSSpike Result 92252369001 Nitrate as N mg/kg 123 H31319280-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92252369001 1233605SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 52 52 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92252534 J15060059 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/29146 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92252534002, 92252534003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1180915 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/25/15 07:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1180916LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 111000120000 93 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1180917MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252370001 1180918 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 10700 100 50-15090 5 3010700131002380022800 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 52 53 of 59 #=QL# QUALIFIERS Pace Project No.: Project: 92252534 J15060059 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/15013 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICPM/9967 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Analysis conducted outside the recognized method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 52 54 of 59 #=QL# QUALIFIERS Pace Project No.: Project: 92252534 J15060059 ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 52 55 of 59 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92252534 J15060059 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92252534002 MPRP/24583 ICP/150132015016947EPA 3050 EPA 6010 92252534003 MPRP/24583 ICP/150132015016948EPA 3050 EPA 6010 92252534002 MPRP/24584 ICPM/99672015016947EPA 3050 EPA 6020 92252534003 MPRP/24584 ICPM/99672015016948EPA 3050 EPA 6020 92252534001 MPRP/55040 ICPM/247312015016946EPA 3020 EPA 6020A 92252534004 MPRP/55571 ICPM/251092015016947 SPLP EPA 3020 EPA 6020A 92252534005 MPRP/55571 ICPM/251092015016948 SPLP EPA 3020 EPA 6020A 92252534001 MERP/13774 MERC/160242015016946EPA 7470A EPA 7470A 92252534004 MERP/14018 MERC/163642015016947 SPLP EPA 7470A EPA 7470A 92252534005 MERP/14018 MERC/163642015016948 SPLP EPA 7470A EPA 7470A 92252534002 MERP/5828 MERC/58132015016947EPA 7471 EPA 7471 92252534003 MERP/5828 MERC/58132015016948EPA 7471 EPA 7471 92252534002 PMST/36292015016947ASTM D2974-87 92252534003 PMST/36292015016948ASTM D2974-87 92252534002 WET/379532015016947EPA 9045 92252534003 WET/379532015016948EPA 9045 92252534002 WETA/233242015016947EPA 300.0 92252534003 WETA/233242015016948EPA 300.0 92252534002 WETA/233722015016947EPA 353.2 92252534003 WETA/233722015016948EPA 353.2 92252534002 WETA/233542015016947SM 4500-Cl-E 92252534003 WETA/233542015016948SM 4500-Cl-E 92252534002 WETA/470292015016947EPA 9056 92252534003 WETA/470292015016948EPA 9056 92252534002 WETA/470282015016947EPA 9056 92252534003 WETA/470282015016948EPA 9056 92252534002 WETA/291462015016947EPA 9060 92252534002 WETA/291472015016947EPA 9060 92252534003 WETA/291462015016948EPA 9060 92252534003 WETA/291472015016948EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/03/2015 08:29 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 52 56 of 59 Page 51 of 52 57 of 59 Page 52 of 52 58 of 59 59 of 59