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Home My WebLink AboutNC0038377_J15050632 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15050632 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/18/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 55 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015015768 MAYO STEAM 19-May-15 2:15 PM illegible ABMW-3EB 2015015769 MAYO STEAM 20-May-15 3:20 PM illegible ABMW-3SEB 2015015770 MAYO STEAM 20-May-15 2:15 PM illegible ABMW-3S(51.0-53.0) 3 Total Samples 2 of 55 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 55 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050632 2015015768 Collection Date: 19-May-15 2:15 PM Site:ABMW-3EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 55 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050632 2015015769 Collection Date: 20-May-15 3:20 PM Site:ABMW-3SEB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 55 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050632 2015015770 Collection Date: 20-May-15 2:15 PM Site:ABMW-3S(51.0-53.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 55 #=CL# June 15, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92251236 92251236 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15050632 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 22, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 48 7 of 55 #=CP# CERTIFICATIONS Pace Project No.: Project: 92251236 J15050632 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 48 8 of 55 #=CP# CERTIFICATIONS Pace Project No.: Project: 92251236 J15050632 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 48 9 of 55 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92251236 J15050632 Lab ID Sample ID Matrix Date Collected Date Received 92251236001 2015015768 Water 05/19/15 14:15 05/22/15 14:40 92251236002 2015015769 Water 05/20/15 15:20 05/22/15 14:40 92251236003 2015015770 Solid 05/20/15 14:15 05/22/15 14:40 92251236004 2015015770 SPLP Water 05/20/15 14:15 05/22/15 14:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 48 10 of 55 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92251236 J15050632 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92251236001 2015015768 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MJDD 92251236002 2015015769 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MJDD 92251236003 2015015770 EPA 6010 17 PASI-OCKJ EPA 6020 7 PASI-OCRT EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OCMB EPA 9056 1 PASI-OCMB EPA 9060 6 PASI-GTJJ 92251236004 2015015770 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470A 1 PASI-MLMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 48 11 of 55 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92251236 J15050632 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92251236001 2015015768 Aluminum 18.1 ug/L 05/29/15 18:0310.0EPA 6020A Barium 0.70 ug/L 05/29/15 18:030.30EPA 6020A Calcium 134 ug/L 05/29/15 18:0340.0EPA 6020A Chromium 1.2 ug/L 05/29/15 18:030.50EPA 6020A Cobalt 3.3 ug/L 05/29/15 18:030.50EPA 6020A Iron 186 ug/L 05/29/15 18:0350.0EPA 6020A Lead 0.070J ug/L 05/29/15 18:030.10EPA 6020A Magnesium 9.9J ug/L 05/29/15 18:0310.0EPA 6020A Manganese 7.0 ug/L 05/29/15 18:030.50EPA 6020A Molybdenum 0.27J ug/L 05/29/15 18:030.50EPA 6020A Potassium 29.3J ug/L 05/29/15 18:0350.0EPA 6020A Strontium 0.16J ug/L 05/29/15 18:030.50EPA 6020A Zinc 3.6J ug/L 05/29/15 18:035.0EPA 6020A 92251236002 2015015769 Aluminum 41.7 ug/L 05/29/15 18:4110.0EPA 6020A Barium 1.5 ug/L 05/29/15 18:410.30EPA 6020A Boron 2.3J ug/L 05/29/15 18:415.0EPA 6020A Calcium 298 ug/L 05/29/15 18:4140.0EPA 6020A Chromium 2.1 ug/L 05/29/15 18:410.50EPA 6020A Cobalt 61.1 ug/L 05/29/15 18:410.50EPA 6020A Copper 1.1 ug/L 05/29/15 18:411.0EPA 6020A Iron 321 ug/L 05/29/15 18:4150.0EPA 6020A Magnesium 59.5 ug/L 05/29/15 18:4110.0EPA 6020A Manganese 9.9 ug/L 05/29/15 18:410.50EPA 6020A Molybdenum 0.32J ug/L 05/29/15 18:410.50EPA 6020A Nickel 0.64 ug/L 05/29/15 18:410.50EPA 6020A Potassium 90.1 ug/L 05/29/15 18:4150.0EPA 6020A Sodium 182 ug/L 05/29/15 18:4150.0EPA 6020A Strontium 0.80 ug/L 05/29/15 18:410.50EPA 6020A Zinc 5.2 ug/L 05/29/15 18:415.0EPA 6020A 92251236003 2015015770 Aluminum 10600 mg/kg 06/04/15 01:3534.0EPA 6010 Barium 56.1 mg/kg 06/04/15 01:353.4EPA 6010 Beryllium 0.90 mg/kg 06/04/15 01:350.34EPA 6010 Chromium 1.3J mg/kg 06/04/15 01:351.7EPA 6010 Copper 9.0 mg/kg 06/04/15 01:351.7EPA 6010 Iron 16900 mg/kg 06/04/15 01:3513.6EPA 6010 Magnesium 4210 mg/kg 06/04/15 01:35170EPA 6010 Manganese 319 mg/kg 06/04/15 01:351.7EPA 6010 Potassium 2980 mg/kg 06/04/15 01:35340EPA 6010 Strontium 3.3J mg/kg 06/04/15 01:353.4EPA 6010 Zinc 27.7 mg/kg 06/04/15 01:356.8EPA 6010 Cobalt 6.6J mg/kg 06/03/15 19:566.8EPA 6020 Vanadium 28.8 mg/kg 06/03/15 19:566.8EPA 6020 Mercury 0.021 mg/kg 06/03/15 18:180.010EPA 7471 Percent Moisture 24.6 %06/05/15 09:170.10ASTM D2974-87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 48 12 of 55 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92251236 J15050632 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92251236003 2015015770 pH at 25 Degrees C 5.9 Std. Units 06/03/15 12:00 H10.10EPA 9045 Sulfate 3.0 mg/L 06/10/15 10:13 B2.7EPA 300.0 RSD%1.6 %06/12/15 09:11EPA 9060 92251236004 2015015770 SPLP Aluminum 268 ug/L 06/10/15 16:0910.0EPA 6020A Arsenic 0.17J ug/L 06/10/15 16:090.50EPA 6020A Barium 80.2 ug/L 06/10/15 16:090.30EPA 6020A Boron 85.6 ug/L 06/10/15 16:095.0EPA 6020A Calcium 170 ug/L 06/10/15 16:0940.0EPA 6020A Chromium 0.55 ug/L 06/10/15 16:090.50EPA 6020A Cobalt 0.15J ug/L 06/10/15 16:090.50EPA 6020A Copper 0.54J ug/L 06/10/15 16:091.0EPA 6020A Iron 95.1 ug/L 06/10/15 16:0950.0EPA 6020A Lead 0.072J ug/L 06/10/15 16:090.10EPA 6020A Magnesium 40.8 ug/L 06/10/15 16:0910.0EPA 6020A Manganese 4.8 ug/L 06/10/15 16:090.50EPA 6020A Nickel 0.18J ug/L 06/10/15 16:090.50EPA 6020A Potassium 102 ug/L 06/10/15 16:0950.0EPA 6020A Sodium 1870 ug/L 06/10/15 16:0950.0EPA 6020A Strontium 3.2 ug/L 06/10/15 16:090.50EPA 6020A Vanadium 0.61J ug/L 06/10/15 16:091.0EPA 6020A Zinc 56.7 ug/L 06/10/15 16:095.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 48 13 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 6010 Date:June 15, 2015 Description:6010 MET ICP General Information: 1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24465 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251157007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1229849) • Aluminum • Iron • Manganese • MSD (Lab ID: 1229850) • Aluminum • Iron Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14943 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 48 14 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 6020 Date:June 15, 2015 Description:6020 MET ICPMS General Information: 1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24466 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251157007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1229856) • Arsenic • Thallium • MSD (Lab ID: 1229857) • Thallium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 9902 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 48 15 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 6020 Date:June 15, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/24466 N2: The lab does not hold TNI accreditation for this parameter. • 2015015770 (Lab ID: 92251236003) • Antimony • BLANK (Lab ID: 1229854) • Antimony • LCS (Lab ID: 1229855) • Antimony • MS (Lab ID: 1229856) • Antimony • MSD (Lab ID: 1229857) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 48 16 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 6020A Date:June 15, 2015 Description:6020A MET ICPMS General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251147009 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1977700) • Boron • MSD (Lab ID: 1977701) • Boron QC Batch: MPRP/55041 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253352007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1989780) • Aluminum • MSD (Lab ID: 1989781) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 48 17 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 7470A Date:June 15, 2015 Description:7470A Mercury General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 48 18 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 7471 Date:June 15, 2015 Description:7471 Mercury General Information: 1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 48 19 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 9045 Date:June 15, 2015 Description:9045 pH Soil General Information: 1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015015770 (Lab ID: 92251236003) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 48 20 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 300.0 Date:June 15, 2015 Description:300.0 IC Anions, SPLP General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23222 B: Analyte was detected in the associated method blank. • BLANK for HBN 267287 [WETA/232 (Lab ID: 1479817) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 48 21 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 353.2 Date:June 15, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015015770 (Lab ID: 92251236003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 48 22 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy SM 4500-Cl-E Date:June 15, 2015 Description:4500 Chloride, SPLP General Information: 1 sample was analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 48 23 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46803 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015015770 (Lab ID: 92251236003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 48 24 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions 48hr General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015015770 (Lab ID: 92251236003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46804 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015015770 (Lab ID: 92251236003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 48 25 of 55 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251236 J15050632 Method: Client:Duke Energy EPA 9060 Date:June 15, 2015 Description:Total Organic Carbon Quad General Information: 1 sample was analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 48 26 of 55 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251236 J15050632 Sample:2015015768 Lab ID:92251236001 Collected:05/19/15 14:15 Received:05/22/15 14:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 18.1 ug/L 05/29/15 18:03 7429-90-505/28/15 21:1210.0 3.0 1 Antimony ND ug/L 05/29/15 18:03 7440-36-005/28/15 21:120.50 0.15 1 Arsenic ND ug/L 05/29/15 18:03 7440-38-205/28/15 21:120.50 0.11 1 Barium 0.70 ug/L 05/29/15 18:03 7440-39-305/28/15 21:120.30 0.081 1 Beryllium ND ug/L 05/29/15 18:03 7440-41-705/28/15 21:120.20 0.067 1 Boron ND ug/L 05/29/15 18:03 7440-42-805/28/15 21:125.0 1.1 1 Cadmium ND ug/L 05/29/15 18:03 7440-43-905/28/15 21:120.080 0.024 1 Calcium 134 ug/L 05/29/15 18:03 7440-70-205/28/15 21:1240.0 16.0 1 Chromium 1.2 ug/L 05/29/15 18:03 7440-47-305/28/15 21:120.50 0.17 1 Cobalt 3.3 ug/L 05/29/15 18:03 7440-48-405/28/15 21:120.50 0.13 1 Copper ND ug/L 05/29/15 18:03 7440-50-805/28/15 21:121.0 0.21 1 Iron 186 ug/L 05/29/15 18:03 7439-89-605/28/15 21:1250.0 13.7 1 Lead 0.070J ug/L 05/29/15 18:03 7439-92-105/28/15 21:120.10 0.046 1 Magnesium 9.9J ug/L 05/29/15 18:03 7439-95-405/28/15 21:1210.0 3.2 1 Manganese 7.0 ug/L 05/29/15 18:03 7439-96-505/28/15 21:120.50 0.24 1 Molybdenum 0.27J ug/L 05/29/15 18:03 7439-98-705/28/15 21:120.50 0.094 1 Nickel ND ug/L 05/29/15 18:03 7440-02-005/28/15 21:120.50 0.16 1 Potassium 29.3J ug/L 05/29/15 18:03 7440-09-705/28/15 21:1250.0 11.7 1 Selenium ND ug/L 05/29/15 18:03 7782-49-205/28/15 21:120.50 0.20 1 Sodium ND ug/L 05/29/15 18:03 7440-23-505/28/15 21:1250.0 16.3 1 Strontium 0.16J ug/L 05/29/15 18:03 7440-24-605/28/15 21:120.50 0.13 1 Thallium ND ug/L 05/29/15 18:03 7440-28-005/28/15 21:120.10 0.015 1 Vanadium ND ug/L 05/29/15 18:03 7440-62-205/28/15 21:121.0 0.28 1 Zinc 3.6J ug/L 05/29/15 18:03 7440-66-605/28/15 21:125.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 19:57 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 48 27 of 55 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251236 J15050632 Sample:2015015769 Lab ID:92251236002 Collected:05/20/15 15:20 Received:05/22/15 14:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 41.7 ug/L 05/29/15 18:41 7429-90-505/28/15 21:1210.0 3.0 1 Antimony ND ug/L 05/29/15 18:41 7440-36-005/28/15 21:120.50 0.15 1 Arsenic ND ug/L 05/29/15 18:41 7440-38-205/28/15 21:120.50 0.11 1 Barium 1.5 ug/L 05/29/15 18:41 7440-39-305/28/15 21:120.30 0.081 1 Beryllium ND ug/L 05/29/15 18:41 7440-41-705/28/15 21:120.20 0.067 1 Boron 2.3J ug/L 05/29/15 18:41 7440-42-805/28/15 21:125.0 1.1 1 Cadmium ND ug/L 05/29/15 18:41 7440-43-905/28/15 21:120.080 0.024 1 Calcium 298 ug/L 05/29/15 18:41 7440-70-205/28/15 21:1240.0 16.0 1 Chromium 2.1 ug/L 05/29/15 18:41 7440-47-305/28/15 21:120.50 0.17 1 Cobalt 61.1 ug/L 05/29/15 18:41 7440-48-405/28/15 21:120.50 0.13 1 Copper 1.1 ug/L 05/29/15 18:41 7440-50-805/28/15 21:121.0 0.21 1 Iron 321 ug/L 05/29/15 18:41 7439-89-605/28/15 21:1250.0 13.7 1 Lead ND ug/L 05/29/15 18:41 7439-92-105/28/15 21:120.10 0.046 1 Magnesium 59.5 ug/L 05/29/15 18:41 7439-95-405/28/15 21:1210.0 3.2 1 Manganese 9.9 ug/L 05/29/15 18:41 7439-96-505/28/15 21:120.50 0.24 1 Molybdenum 0.32J ug/L 05/29/15 18:41 7439-98-705/28/15 21:120.50 0.094 1 Nickel 0.64 ug/L 05/29/15 18:41 7440-02-005/28/15 21:120.50 0.16 1 Potassium 90.1 ug/L 05/29/15 18:41 7440-09-705/28/15 21:1250.0 11.7 1 Selenium ND ug/L 05/29/15 18:41 7782-49-205/28/15 21:120.50 0.20 1 Sodium 182 ug/L 05/29/15 18:41 7440-23-505/28/15 21:1250.0 16.3 1 Strontium 0.80 ug/L 05/29/15 18:41 7440-24-605/28/15 21:120.50 0.13 1 Thallium ND ug/L 05/29/15 18:41 7440-28-005/28/15 21:120.10 0.015 1 Vanadium ND ug/L 05/29/15 18:41 7440-62-205/28/15 21:121.0 0.28 1 Zinc 5.2 ug/L 05/29/15 18:41 7440-66-605/28/15 21:125.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 20:04 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 48 28 of 55 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251236 J15050632 Sample:2015015770 Lab ID:92251236003 Collected:05/20/15 14:15 Received:05/22/15 14:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 10600 mg/kg 06/04/15 01:35 7429-90-506/02/15 20:2034.0 17.0 5 Barium 56.1 mg/kg 06/04/15 01:35 7440-39-306/02/15 20:203.4 1.7 5 Beryllium 0.90 mg/kg 06/04/15 01:35 7440-41-706/02/15 20:200.34 0.17 5 Boron ND mg/kg 06/04/15 01:35 7440-42-806/02/15 20:2017.0 8.5 5 Calcium ND mg/kg 06/04/15 01:35 7440-70-206/02/15 20:2017084.9 5 Chromium 1.3J mg/kg 06/04/15 01:35 7440-47-306/02/15 20:201.7 0.85 5 Copper 9.0 mg/kg 06/04/15 01:35 7440-50-806/02/15 20:201.7 0.85 5 Iron 16900 mg/kg 06/04/15 01:35 7439-89-606/02/15 20:2013.6 6.8 5 Magnesium 4210 mg/kg 06/04/15 01:35 7439-95-406/02/15 20:2017084.9 5 Manganese 319 mg/kg 06/04/15 01:35 7439-96-506/02/15 20:201.7 0.85 5 Molybdenum ND mg/kg 06/04/15 01:35 7439-98-706/02/15 20:203.4 1.7 5 Nickel ND mg/kg 06/04/15 01:35 7440-02-006/02/15 20:201.7 0.85 5 Potassium 2980 mg/kg 06/04/15 01:35 7440-09-706/02/15 20:203401705 Selenium ND mg/kg 06/04/15 01:35 7782-49-206/02/15 20:205.1 2.5 5 Sodium ND mg/kg 06/04/15 01:35 7440-23-506/02/15 20:203401705 Strontium 3.3J mg/kg 06/04/15 01:35 7440-24-606/02/15 20:203.4 1.7 5 Zinc 27.7 mg/kg 06/04/15 01:35 7440-66-606/02/15 20:206.8 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/03/15 19:56 7440-36-0 N206/02/15 20:206.8 3.4 100 Arsenic ND mg/kg 06/03/15 19:56 7440-38-206/02/15 20:206.8 3.4 100 Cadmium ND mg/kg 06/03/15 19:56 7440-43-906/02/15 20:200.81 0.41 100 Cobalt 6.6J mg/kg 06/03/15 19:56 7440-48-406/02/15 20:206.8 3.4 100 Lead ND mg/kg 06/03/15 19:56 7439-92-106/02/15 20:206.8 3.4 100 Thallium ND mg/kg 06/03/15 19:56 7440-28-006/02/15 20:206.8 3.4 100 Vanadium 28.8 mg/kg 06/03/15 19:56 7440-62-206/02/15 20:206.8 3.4 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.021 mg/kg 06/03/15 18:18 7439-97-606/02/15 20:300.010 0.0052 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 24.6 %06/05/15 09:170.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.9 Std. Units 06/03/15 12:00 H10.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/28/15 04:30300.0 IC Anions, SPLP Sulfate 3.0 mg/L 06/10/15 10:13 14808-79-8 B2.7 1.3 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/28/15 04:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 06/09/15 17:53 H10.27 0.27 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/28/15 04:304500 Chloride, SPLP Chloride ND mg/L 06/06/15 07:37 16887-00-66.6 3.3 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 48 29 of 55 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251236 J15050632 Sample:2015015770 Lab ID:92251236003 Collected:05/20/15 14:15 Received:05/22/15 14:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/29/15 15:01 16887-00-6 D33381695 Sulfate ND mg/kg 05/29/15 15:01 14808-79-8 D33381695 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/29/15 15:01 14797-55-8 D3,H333.8 16.9 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 06/12/15 09:11 7440-44-07893951 Total Organic Carbon ND mg/kg 06/12/15 09:17 7440-44-07953981 Total Organic Carbon ND mg/kg 06/12/15 09:22 7440-44-08014001 Total Organic Carbon ND mg/kg 06/12/15 09:28 7440-44-07923961 Mean Total Organic Carbon ND mg/kg 06/12/15 09:11 7440-44-07943971 Surrogates RSD%1.6 %06/12/15 09:111 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 48 30 of 55 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251236 J15050632 Sample:2015015770 SPLP Lab ID:92251236004 Collected:05/20/15 14:15 Received:05/22/15 14:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 268 ug/L 06/10/15 16:09 7429-90-506/10/15 11:3210.0 3.0 1 Antimony ND ug/L 06/10/15 16:09 7440-36-006/10/15 11:320.50 0.15 1 Arsenic 0.17J ug/L 06/10/15 16:09 7440-38-206/10/15 11:320.50 0.11 1 Barium 80.2 ug/L 06/10/15 16:09 7440-39-306/10/15 11:320.30 0.081 1 Beryllium ND ug/L 06/10/15 16:09 7440-41-706/10/15 11:320.20 0.067 1 Boron 85.6 ug/L 06/10/15 16:09 7440-42-806/10/15 11:325.0 1.1 1 Cadmium ND ug/L 06/10/15 16:09 7440-43-906/10/15 11:320.080 0.024 1 Calcium 170 ug/L 06/10/15 16:09 7440-70-206/10/15 11:3240.0 16.0 1 Chromium 0.55 ug/L 06/10/15 16:09 7440-47-306/10/15 11:320.50 0.17 1 Cobalt 0.15J ug/L 06/10/15 16:09 7440-48-406/10/15 11:320.50 0.13 1 Copper 0.54J ug/L 06/10/15 16:09 7440-50-806/10/15 11:321.0 0.21 1 Iron 95.1 ug/L 06/10/15 16:09 7439-89-606/10/15 11:3250.0 13.7 1 Lead 0.072J ug/L 06/10/15 16:09 7439-92-106/10/15 11:320.10 0.046 1 Magnesium 40.8 ug/L 06/10/15 16:09 7439-95-406/10/15 11:3210.0 3.2 1 Manganese 4.8 ug/L 06/10/15 16:09 7439-96-506/10/15 11:320.50 0.24 1 Molybdenum ND ug/L 06/10/15 16:09 7439-98-706/10/15 11:320.50 0.094 1 Nickel 0.18J ug/L 06/10/15 16:09 7440-02-006/10/15 11:320.50 0.16 1 Potassium 102 ug/L 06/10/15 16:09 7440-09-706/10/15 11:3250.0 11.7 1 Selenium ND ug/L 06/10/15 16:09 7782-49-206/10/15 11:320.50 0.20 1 Sodium 1870 ug/L 06/10/15 16:09 7440-23-506/10/15 11:3250.0 16.3 1 Strontium 3.2 ug/L 06/10/15 16:09 7440-24-606/10/15 11:320.50 0.13 1 Thallium ND ug/L 06/10/15 16:09 7440-28-006/10/15 11:320.10 0.015 1 Vanadium 0.61J ug/L 06/10/15 16:09 7440-62-206/10/15 11:321.0 0.28 1 Zinc 56.7 ug/L 06/10/15 16:09 7440-66-606/10/15 11:325.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/10/15 15:00 7439-97-606/10/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 48 31 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13678 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92251236001, 92251236002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1977493 Associated Lab Samples:92251236001, 92251236002 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/01/15 19:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977494LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.85 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1977495MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251236001 1977496 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 100 80-12099 1 205ND5.0 5.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 48 32 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13814 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92251236004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1989756 Associated Lab Samples:92251236004 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/10/15 14:06 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989757LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1989758MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253195001 1989759 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 110 80-120106 4 205ND5.5 5.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 48 33 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5803 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1229879 Associated Lab Samples:92251236003 Matrix:Solid Analyzed Mercury mg/kg ND 0.0080 06/03/15 17:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1229880LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.081.082 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1229881MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251157007 1229882 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .142 101 80-120102 3 20.144ND 0.15 0.15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 48 34 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24465 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1229847 Associated Lab Samples:92251236003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.0 06/03/15 23:37 Barium mg/kg ND 0.50 06/03/15 23:37 Beryllium mg/kg ND 0.050 06/03/15 23:37 Boron mg/kg ND 2.5 06/03/15 23:37 Calcium mg/kg ND 25.0 06/03/15 23:37 Chromium mg/kg ND 0.25 06/03/15 23:37 Copper mg/kg ND 0.25 06/03/15 23:37 Iron mg/kg ND 2.0 06/03/15 23:37 Magnesium mg/kg ND 25.0 06/03/15 23:37 Manganese mg/kg ND 0.25 06/03/15 23:37 Molybdenum mg/kg ND 0.50 06/03/15 23:37 Nickel mg/kg ND 0.25 06/03/15 23:37 Potassium mg/kg ND 49.9 06/03/15 23:37 Selenium mg/kg ND 0.75 06/03/15 23:37 Sodium mg/kg ND 49.9 06/03/15 23:37 Strontium mg/kg ND 0.50 06/03/15 23:37 Zinc mg/kg ND 1.0 06/03/15 23:37 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1229848LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 112127 88 80-120 Barium mg/kg 11.412.7 90 80-120 Beryllium mg/kg 1.11.3 89 80-120 Boron mg/kg 113127 89 80-120 Calcium mg/kg 571635 90 80-120 Chromium mg/kg 11.312.7 89 80-120 Copper mg/kg 11.112.7 88 80-120 Iron mg/kg 111127 87 80-120 Magnesium mg/kg 567635 89 80-120 Manganese mg/kg 11.412.7 89 80-120 Molybdenum mg/kg 11.112.7 87 80-120 Nickel mg/kg 11.412.7 89 80-120 Potassium mg/kg 557635 88 80-120 Selenium mg/kg 10.612.7 84 80-120 Sodium mg/kg 572635 90 80-120 Strontium mg/kg 11.112.7 87 80-120 Zinc mg/kg 56.063.5 88 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 48 35 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1229849MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251157007 1229850 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M123114975-125341 17 20228195022902720 Barium mg/kg 23.1 79 75-125112 12 2022.838.2 56.5 63.7 Beryllium mg/kg 2.31 84 75-12595 10 202.310.43J 2.4 2.6 Boron mg/kg 231 85 75-12593 8 20228ND202219 Calcium mg/kg 1150 85 75-125116 16 20114095719402280 Chromium mg/kg 23.1 83 75-12597 12 2022.84.3 23.4 26.3 Copper mg/kg 23.1 84 75-12596 10 2022.84.8 24.2 26.7 Iron mg/kg M1231-176 75-12515 17 20228277023602800 Magnesium mg/kg 1150 87 75-12599 11 201140160J11601290 Manganese mg/kg M123.1 74 75-12594 13 2022.815.6 32.6 37.1 Molybdenum mg/kg 23.1 82 75-12592 8 2022.84.9 23.8 25.9 Nickel mg/kg 23.1 87 75-125100 11 2022.84.4 24.6 27.3 Potassium mg/kg 1150 87 75-12598 9 201140ND11801280 Selenium mg/kg 23.1 80 75-12590 10 2022.8ND 18.4 20.5 Sodium mg/kg 1150 92 75-12595 2 201140ND11401160 Strontium mg/kg 23.1 79 75-125117 16 2022.829.7 48.0 56.4 Zinc mg/kg 115 85 75-12595 9 20114ND101111 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 48 36 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24466 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1229854 Associated Lab Samples:92251236003 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N206/03/15 18:24 Arsenic mg/kg ND 0.051 06/03/15 18:24 Cadmium mg/kg ND 0.0061 06/03/15 18:24 Cobalt mg/kg ND 0.051 06/03/15 18:24 Lead mg/kg ND 0.051 06/03/15 18:24 Thallium mg/kg ND 0.051 06/03/15 18:24 Vanadium mg/kg ND 0.051 06/03/15 18:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1229855LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.4 N22.5 93 80-120 Arsenic mg/kg 2.42.5 95 80-120 Cadmium mg/kg 0.22.25 87 80-120 Cobalt mg/kg 2.42.5 94 80-120 Lead mg/kg 2.32.5 90 80-120 Thallium mg/kg 2.42.5 92 80-120 Vanadium mg/kg 2.42.5 93 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1229856MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251157007 1229857 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg N24.45 88 75-12576 204.63ND ND ND Arsenic mg/kg M64.45 73 75-12582 3 204.6313.2 16.5 17.0 Cadmium mg/kg .445 102 75-125100 20.463ND ND ND Cobalt mg/kg 4.45 99 75-12582 204.63ND 6.2J 5.6J Lead mg/kg 4.45 93 75-12582 204.63ND 5.2J 4.8J Thallium mg/kg M64.45 64 75-12563 204.63ND ND ND Vanadium mg/kg 4.45 114 75-12576 204.634.8J 10 8.4J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 48 37 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54700 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92251236001, 92251236002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1977698 Associated Lab Samples:92251236001, 92251236002 Matrix:Water Analyzed Aluminum ug/L ND 10.0 05/29/15 16:47 Antimony ug/L ND 0.50 05/29/15 16:47 Arsenic ug/L ND 0.50 05/29/15 16:47 Barium ug/L ND 0.30 05/29/15 16:47 Beryllium ug/L ND 0.20 05/29/15 16:47 Boron ug/L ND 5.0 05/29/15 16:47 Cadmium ug/L ND 0.080 05/29/15 16:47 Calcium ug/L ND 40.0 05/29/15 16:47 Chromium ug/L ND 0.50 05/29/15 16:47 Cobalt ug/L ND 0.50 05/29/15 16:47 Copper ug/L ND 1.0 05/29/15 16:47 Iron ug/L ND 50.0 05/29/15 16:47 Lead ug/L ND 0.10 05/29/15 16:47 Magnesium ug/L ND 10.0 05/29/15 16:47 Manganese ug/L ND 0.50 05/29/15 16:47 Molybdenum ug/L ND 0.50 05/29/15 16:47 Nickel ug/L ND 0.50 05/29/15 16:47 Potassium ug/L ND 50.0 05/29/15 16:47 Selenium ug/L ND 0.50 05/29/15 16:47 Sodium ug/L ND 50.0 05/29/15 16:47 Strontium ug/L ND 0.50 05/29/15 16:47 Thallium ug/L ND 0.10 05/29/15 16:47 Vanadium ug/L ND 1.0 05/29/15 16:47 Zinc ug/L ND 5.0 05/29/15 16:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977699LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 85.480 107 80-120 Antimony ug/L 78.980 99 80-120 Arsenic ug/L 79.880 100 80-120 Barium ug/L 79.280 99 80-120 Beryllium ug/L 77.980 97 80-120 Boron ug/L 81.480 102 80-120 Cadmium ug/L 81.280 102 80-120 Calcium ug/L 10201000 102 80-120 Chromium ug/L 81.980 102 80-120 Cobalt ug/L 79.180 99 80-120 Copper ug/L 82.480 103 80-120 Iron ug/L 10201000 102 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 48 38 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977699LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 77.480 97 80-120 Magnesium ug/L 10301000 103 80-120 Manganese ug/L 83.180 104 80-120 Molybdenum ug/L 79.880 100 80-120 Nickel ug/L 81.480 102 80-120 Potassium ug/L 10101000 101 80-120 Selenium ug/L 80.380 100 80-120 Sodium ug/L 9751000 97 80-120 Strontium ug/L 79.580 99 80-120 Thallium ug/L 79.080 99 80-120 Vanadium ug/L 81.780 102 80-120 Zinc ug/L 83.080 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1977700MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251147009 1977701 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 109 75-125112 1 2080230317320 Antimony ug/L 80 100 75-125101 0 2080ND80.4 80.8 Arsenic ug/L 80 102 75-125102 0 2080ND81.4 81.4 Barium ug/L 80 100 75-125101 0 20803.5 83.5 83.9 Beryllium ug/L 80 101 75-12599 2 2080ND80.8 79.0 Boron ug/L M1805675-12556 0 208039.5 84.1 84.4 Cadmium ug/L 80 104 75-125103 1 2080ND83.0 82.3 Calcium ug/L 1000 104 75-125102 2 20100022912701250 Chromium ug/L 80 102 75-125104 2 2080ND82.0 83.4 Cobalt ug/L 80 100 75-125101 0 2080ND80.4 80.6 Copper ug/L 80 104 75-125105 0 20802.1 85.6 85.8 Iron ug/L 1000 102 75-125104 1 20100013811601170 Lead ug/L 80 100 75-12599 0 20800.37 80.3 80.0 Magnesium ug/L 1000 105 75-125105 0 20100020.5 1070 1070 Manganese ug/L 80 105 75-125105 0 208015.1 98.9 99.4 Molybdenum ug/L 80 101 75-125102 1 2080ND80.9 81.7 Nickel ug/L 80 101 75-125103 2 2080ND81.5 82.9 Potassium ug/L 1000 101 75-125102 1 20100051.5 1070 1070 Selenium ug/L 80 103 75-12598 5 2080ND82.2 78.4 Sodium ug/L 1000 98 75-12596 1 201000ND10201000 Strontium ug/L 80 101 75-125101 0 20802.2 82.7 82.9 Thallium ug/L 80 105 75-125105 0 2080ND83.8 83.8 Vanadium ug/L 80 103 75-125104 1 2080ND82.6 83.3 Zinc ug/L 80 100 75-125106 5 2080ND84.0 88.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 48 39 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/55041 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92251236004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1989137 Associated Lab Samples:92251236004 Matrix:Water Analyzed Aluminum ug/L ND 10.0 06/10/15 15:28 Antimony ug/L ND 0.50 06/10/15 15:28 Arsenic ug/L ND 0.50 06/10/15 15:28 Barium ug/L ND 0.30 06/10/15 15:28 Beryllium ug/L ND 0.20 06/10/15 15:28 Boron ug/L ND 5.0 06/10/15 15:28 Cadmium ug/L ND 0.080 06/10/15 15:28 Calcium ug/L ND 40.0 06/10/15 15:28 Chromium ug/L ND 0.50 06/10/15 15:28 Cobalt ug/L ND 0.50 06/10/15 15:28 Copper ug/L ND 1.0 06/10/15 15:28 Iron ug/L ND 50.0 06/10/15 15:28 Lead ug/L ND 0.10 06/10/15 15:28 Magnesium ug/L ND 10.0 06/10/15 15:28 Manganese ug/L ND 0.50 06/10/15 15:28 Molybdenum ug/L 0.13J 0.50 06/10/15 15:28 Nickel ug/L ND 0.50 06/10/15 15:28 Potassium ug/L ND 50.0 06/10/15 15:28 Selenium ug/L ND 0.50 06/10/15 15:28 Sodium ug/L ND 50.0 06/10/15 15:28 Strontium ug/L ND 0.50 06/10/15 15:28 Thallium ug/L ND 0.10 06/10/15 15:28 Vanadium ug/L ND 1.0 06/10/15 15:28 Zinc ug/L ND 5.0 06/10/15 15:28 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989138LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 76.980 96 80-120 Antimony ug/L 77.380 97 80-120 Arsenic ug/L 78.280 98 80-120 Barium ug/L 81.980 102 80-120 Beryllium ug/L 81.780 102 80-120 Boron ug/L 79.680 99 80-120 Cadmium ug/L 79.180 99 80-120 Calcium ug/L 9851000 98 80-120 Chromium ug/L 79.980 100 80-120 Cobalt ug/L 84.780 106 80-120 Copper ug/L 81.580 102 80-120 Iron ug/L 10401000 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 48 40 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989138LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 79.980 100 80-120 Magnesium ug/L 9891000 99 80-120 Manganese ug/L 75.880 95 80-120 Molybdenum ug/L 77.780 97 80-120 Nickel ug/L 79.380 99 80-120 Potassium ug/L 9321000 93 80-120 Selenium ug/L 78.980 99 80-120 Sodium ug/L 10301000 103 80-120 Strontium ug/L 76.180 95 80-120 Thallium ug/L 84.780 106 80-120 Vanadium ug/L 77.680 97 80-120 Zinc ug/L 81.380 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1989780MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253352007 1989781 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18013675-125135 1 208037.2 146 145 Antimony ug/L 80 98 75-12598 0 2080ND78.6 78.8 Arsenic ug/L 80 102 75-125102 0 2080ND81.5 81.7 Barium ug/L 80 96 75-12598 2 20800.67 77.2 78.9 Beryllium ug/L 80 105 75-125104 1 2080ND83.8 82.9 Boron ug/L 80 94 75-12599 5 20801.4J 76.5 80.3 Cadmium ug/L 80 99 75-125101 3 2080ND78.8 81.1 Calcium ug/L 1000 94 75-125104 8 20100016211001200 Chromium ug/L 80 98 75-125101 3 20800.33J 78.7 81.2 Cobalt ug/L 80 99 75-125100 1 2080ND79.0 79.9 Copper ug/L 80 102 75-125103 2 20800.95J 82.2 83.6 Iron ug/L 1000 107 75-125111 3 20100061.6 1130 1170 Lead ug/L 80 98 75-125100 2 20800.10 78.4 79.9 Magnesium ug/L 1000 98 75-125100 2 20100028.0 1010 1030 Manganese ug/L 80 93 75-12597 4 20801.9 76.6 79.4 Molybdenum ug/L 80 98 75-12599 0 20800.095J 78.6 78.9 Nickel ug/L 80 100 75-125100 1 20800.17J 79.8 80.3 Potassium ug/L 1000 99 75-125100 1 20100022.2J 1010 1030 Selenium ug/L 80 104 75-125103 1 2080ND83.2 82.2 Sodium ug/L 1000 89 75-12591 2 20100048.7J 940 955 Strontium ug/L 80 96 75-12597 2 20800.94 77.4 78.9 Thallium ug/L 80 105 75-125107 1 2080ND84.1 85.3 Vanadium ug/L 80 95 75-12598 3 2080ND76.5 78.9 Zinc ug/L 80 102 75-125101 1 20808.1 89.3 88.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 48 41 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3618 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92251236003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250709001 1233279SAMPLE DUPLICATE: Percent Moisture %15.4 4 1016.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250709013 1233280SAMPLE DUPLICATE: Percent Moisture %26.5 4 1027.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190598001 1233281SAMPLE DUPLICATE: Percent Moisture %23.7 3 10 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190619004 1233282SAMPLE DUPLICATE: Percent Moisture %4.1 2 104.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191337002 1233283SAMPLE DUPLICATE: Percent Moisture %4.4 D615103.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191350005 1233284SAMPLE DUPLICATE: Percent Moisture %18.4 D6271024.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191350014 1233285SAMPLE DUPLICATE: Percent Moisture %13.3 9 1012.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 48 42 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37801 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92251236003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92251251005 1472050SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.9 H32106.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 92251242018 1472051SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.5 H31105.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 48 43 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23222 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1479817 Associated Lab Samples:92251236003 Matrix:Water Analyzed Sulfate mg/L 3.2 2.0 06/09/15 22:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1479818LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.120 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1479819MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251132016 1479820 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 31.9 96 93 231.98.0 38.7 37.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 48 44 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23223 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1480060 Associated Lab Samples:92251236003 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.18 0.020 Z206/09/15 17:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1480061LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.42.5 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1480062MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250709003 1480063 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.6 93 90-11093 0 103.6ND 3.6 3.6 Parameter Units MS Result % Rec Limits Qual% RecConc. 1480064MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250709005 1480065 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.5 92 90-11092 0 103.5ND 3.4 3.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 48 45 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23153 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1474736 Associated Lab Samples:92251236003 Matrix:Water Analyzed Chloride mg/L ND 1.0 06/06/15 07:23 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1474737LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 19.920 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1474738MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250515002 1474739 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 23.8 92 90-11092 0 1023.8ND 24.3 24.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1474762MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250709003 1474763 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 28.8 91 90-11090 1 1028.8ND 27.1 26.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 48 46 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46803 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1226976 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.5 05/29/15 06:56 Sulfate mg/kg ND 49.5 05/29/15 06:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1226977LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 489499 98 80-120 Sulfate mg/kg 478499 96 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1226979MATRIX SPIKE SAMPLE: MSSpike Result 92251251005 Chloride mg/kg 474 H15269080-120ND Sulfate mg/kg 508 H15268480-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92251251005 1226978SAMPLE DUPLICATE: Chloride mg/kg ND H120ND Sulfate mg/kg ND H120ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 48 47 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46804 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1226986 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 05/29/15 06:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1226987LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.449.9 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1226989MATRIX SPIKE SAMPLE: MSSpike Result 92251251005 Nitrate as N mg/kg 48.1 H352.6 92 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92251251005 1226988SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 48 48 of 55 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251236 J15050632 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28987 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92251236003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1173951 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/12/15 08:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1173952LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 105000120000 87 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1173953MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251236003 1173954 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7920 83 50-15095 12 307920ND68907800 Parameter Units MS Result % Rec Limits Qual% RecConc. 1173955MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251877001 1173956 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7830 88 50-15088 1 307800772J76607620 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 48 49 of 55 #=QL# QUALIFIERS Pace Project No.: Project: 92251236 J15050632 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14943 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICPM/9902 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 48 50 of 55 #=QL# QUALIFIERS Pace Project No.: Project: 92251236 J15050632 ANALYTE QUALIFIERS Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 48 51 of 55 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92251236 J15050632 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92251236003 MPRP/24465 ICP/149432015015770EPA 3050 EPA 6010 92251236003 MPRP/24466 ICPM/99022015015770EPA 3050 EPA 6020 92251236001 MPRP/54700 ICPM/245072015015768EPA 3020 EPA 6020A 92251236002 MPRP/54700 ICPM/245072015015769EPA 3020 EPA 6020A 92251236004 MPRP/55041 ICPM/247382015015770 SPLP EPA 3020 EPA 6020A 92251236001 MERP/13678 MERC/159262015015768EPA 7470A EPA 7470A 92251236002 MERP/13678 MERC/159262015015769EPA 7470A EPA 7470A 92251236004 MERP/13814 MERC/160862015015770 SPLP EPA 7470A EPA 7470A 92251236003 MERP/5803 MERC/57902015015770EPA 7471 EPA 7471 92251236003 PMST/36182015015770ASTM D2974-87 92251236003 WET/378012015015770EPA 9045 92251236003 WETA/232222015015770EPA 300.0 92251236003 WETA/232232015015770EPA 353.2 92251236003 WETA/231532015015770SM 4500-Cl-E 92251236003 WETA/468032015015770EPA 9056 92251236003 WETA/468042015015770EPA 9056 92251236003 WETA/289872015015770EPA 9060 92251236003 WETA/289882015015770EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 01:39 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 48 52 of 55 Page 47 of 48 53 of 55 Page 48 of 48 54 of 55 55 of 55