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Home My WebLink AboutNC0038377_J15050409 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15050409 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/30/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 43 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015014671 MAYO STEAM 09-May-15 2:16 PM Erin Black MW-15-EB 2015014672 MAYO STEAM 09-May-15 2:30 PM Erin Black MW-15(05.-1.0) 2 Total Samples 2 of 43 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Margaret Galvin-Karr Date:6/30/2015 Electronic Data Deliverable (EDD) Sent Separately 3 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050409 2015014671 Collection Date: 09-May-15 2:16 PM Site:MW-15-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050409 2015014672 Collection Date: 09-May-15 2:30 PM Site:MW-15(05.-1.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Mercury in EB run out of hold time. MG-K 6/30/2015 -- Additional Information -- 5 of 43 #=CL# June 29, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92250201 92250201 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15050409 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 15, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 37 6 of 43 #=CP# CERTIFICATIONS Pace Project No.: Project: 92250201 J15050409 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 37 7 of 43 #=CP# CERTIFICATIONS Pace Project No.: Project: 92250201 J15050409 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 37 8 of 43 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92250201 J15050409 Lab ID Sample ID Matrix Date Collected Date Received 92250201001 2015014671 Water 05/09/15 14:16 05/15/15 13:00 92250201002 2015014672 Solid 05/09/15 14:30 05/15/15 13:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 37 9 of 43 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92250201 J15050409 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92250201001 2015014671 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW 92250201002 2015014672 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 37 10 of 43 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250201 J15050409 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250201001 2015014671 Chromium 0.47J ug/L 06/26/15 11:460.50EPA 6020A Nickel 0.20J ug/L 06/26/15 11:460.50EPA 6020A 92250201002 2015014672 Aluminum 8440 mg/kg 05/27/15 21:5530.9EPA 6010 Barium 64.6 mg/kg 05/27/15 21:553.1EPA 6010 Beryllium 0.24J mg/kg 05/27/15 21:550.31EPA 6010 Calcium 451 mg/kg 05/27/15 21:55155EPA 6010 Chromium 10.4 mg/kg 05/27/15 21:551.5EPA 6010 Copper 12.5 mg/kg 05/27/15 21:551.5EPA 6010 Iron 15600 mg/kg 05/27/15 21:5512.4EPA 6010 Magnesium 3760 mg/kg 05/27/15 21:55155EPA 6010 Manganese 108 mg/kg 05/27/15 21:551.5EPA 6010 Nickel 1.3J mg/kg 05/27/15 21:551.5EPA 6010 Potassium 1370 mg/kg 05/27/15 21:55309EPA 6010 Strontium 11.2 mg/kg 05/27/15 21:553.1EPA 6010 Zinc 18.9 mg/kg 05/27/15 21:556.2EPA 6010 Cobalt 3.9J mg/kg 05/27/15 17:246.2EPA 6020 Lead 4.7J mg/kg 05/27/15 17:246.2EPA 6020 Vanadium 27.1 mg/kg 05/27/15 17:246.2EPA 6020 Mercury 0.0056J mg/kg 05/26/15 20:450.010EPA 7471 Percent Moisture 19.4 %06/02/15 10:590.10ASTM D2974-87 pH at 25 Degrees C 5.2 Std. Units 05/27/15 11:200.10EPA 9045 Total Organic Carbon 1210 mg/kg 06/02/15 15:56740EPA 9060 Total Organic Carbon 1710 mg/kg 06/02/15 16:02747EPA 9060 Total Organic Carbon 1460 mg/kg 06/02/15 16:07745EPA 9060 Total Organic Carbon 2900 mg/kg 06/02/15 16:13738EPA 9060 Mean Total Organic Carbon 1820 mg/kg 06/02/15 15:56742EPA 9060 RSD%41.2 %06/02/15 15:56 1gEPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 37 11 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 6010 Date:June 29, 2015 Description:6010 MET ICP General Information: 1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. QC Batch: MPRP/24322 CH: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. • BLANK (Lab ID: 1223174) • Sodium • LCS (Lab ID: 1223175) • Sodium • MS (Lab ID: 1223176) • Sodium Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24322 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250205001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1223176) • Aluminum • Barium • Calcium • Copper • Iron • Magnesium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 37 12 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 6010 Date:June 29, 2015 Description:6010 MET ICP QC Batch: MPRP/24322 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250205001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Manganese • Potassium • Strontium • MSD (Lab ID: 1223177) • Aluminum • Barium • Calcium • Copper • Iron • Magnesium • Manganese • Potassium • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1223177) • Calcium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14866 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 37 13 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 6020 Date:June 29, 2015 Description:6020 MET ICPMS General Information: 1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24323 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250205001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1223180) • Antimony • Cobalt • Vanadium • MSD (Lab ID: 1223181) • Antimony • Arsenic • Cobalt • Lead • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 37 14 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 6020 Date:June 29, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/24323 N2: The lab does not hold TNI accreditation for this parameter. • 2015014672 (Lab ID: 92250201002) • Antimony • BLANK (Lab ID: 1223178) • Antimony • LCS (Lab ID: 1223179) • Antimony • MS (Lab ID: 1223180) • Antimony • MSD (Lab ID: 1223181) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 37 15 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 6020A Date:June 29, 2015 Description:6020A MET ICPMS General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55423 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92254832007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 2002625) • Aluminum • MSD (Lab ID: 2002626) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 37 16 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 7470A Date:June 29, 2015 Description:7470A Mercury General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015014671 (Lab ID: 92250201001) Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 37 17 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 7471 Date:June 29, 2015 Description:7471 Mercury General Information: 1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 37 18 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 9045 Date:June 29, 2015 Description:9045 pH Soil General Information: 1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37661 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1467400) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 37 19 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 9056 Date:June 29, 2015 Description:9056 IC Anions General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46586 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015014672 (Lab ID: 92250201002) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 37 20 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 9056 Date:June 29, 2015 Description:9056 IC Anions 48hr General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015014672 (Lab ID: 92250201002) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 37 21 of 43 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250201 J15050409 Method: Client:Duke Energy EPA 9060 Date:June 29, 2015 Description:Total Organic Carbon Quad General Information: 1 sample was analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/28762 1g: % RSD > 40 • 2015014672 (Lab ID: 92250201002) • RSD% This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 37 22 of 43 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250201 J15050409 Sample:2015014671 Lab ID:92250201001 Collected:05/09/15 14:16 Received:05/15/15 13:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum ND ug/L 06/26/15 11:46 7429-90-506/23/15 06:4610.0 3.0 1 Antimony ND ug/L 06/26/15 11:46 7440-36-006/23/15 06:460.50 0.15 1 Arsenic ND ug/L 06/26/15 11:46 7440-38-206/23/15 06:460.50 0.11 1 Barium ND ug/L 06/26/15 11:46 7440-39-306/23/15 06:460.30 0.081 1 Beryllium ND ug/L 06/26/15 11:46 7440-41-706/23/15 06:460.20 0.067 1 Boron ND ug/L 06/26/15 11:46 7440-42-806/23/15 06:465.0 1.1 1 Cadmium ND ug/L 06/26/15 11:46 7440-43-906/23/15 06:460.080 0.024 1 Calcium ND ug/L 06/26/15 11:46 7440-70-206/23/15 06:4640.0 16.0 1 Chromium 0.47J ug/L 06/26/15 11:46 7440-47-306/23/15 06:460.50 0.17 1 Cobalt ND ug/L 06/26/15 11:46 7440-48-406/23/15 06:460.50 0.13 1 Copper ND ug/L 06/26/15 11:46 7440-50-806/23/15 06:461.0 0.21 1 Iron ND ug/L 06/26/15 11:46 7439-89-606/23/15 06:4650.0 13.7 1 Lead ND ug/L 06/26/15 11:46 7439-92-106/23/15 06:460.10 0.046 1 Magnesium ND ug/L 06/26/15 11:46 7439-95-406/23/15 06:4610.0 3.2 1 Manganese ND ug/L 06/26/15 11:46 7439-96-506/23/15 06:460.50 0.24 1 Molybdenum ND ug/L 06/26/15 11:46 7439-98-706/23/15 06:460.50 0.094 1 Nickel 0.20J ug/L 06/26/15 11:46 7440-02-006/23/15 06:460.50 0.16 1 Potassium ND ug/L 06/26/15 11:46 7440-09-706/23/15 06:4650.0 11.7 1 Selenium ND ug/L 06/26/15 11:46 7782-49-206/23/15 06:460.50 0.20 1 Sodium ND ug/L 06/26/15 11:46 7440-23-506/23/15 06:4650.0 16.3 1 Strontium ND ug/L 06/26/15 11:46 7440-24-606/23/15 06:460.50 0.13 1 Thallium ND ug/L 06/26/15 11:46 7440-28-006/23/15 06:460.10 0.015 1 Vanadium ND ug/L 06/27/15 10:02 7440-62-206/23/15 06:461.0 0.28 1 Zinc ND ug/L 06/26/15 11:46 7440-66-606/23/15 06:465.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/21/15 20:46 7439-97-6 H306/21/15 15:050.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 37 23 of 43 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250201 J15050409 Sample:2015014672 Lab ID:92250201002 Collected:05/09/15 14:30 Received:05/15/15 13:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 8440 mg/kg 05/27/15 21:55 7429-90-505/26/15 10:3030.9 15.5 5 Barium 64.6 mg/kg 05/27/15 21:55 7440-39-305/26/15 10:303.1 1.5 5 Beryllium 0.24J mg/kg 05/27/15 21:55 7440-41-705/26/15 10:300.31 0.15 5 Boron ND mg/kg 05/27/15 21:55 7440-42-805/26/15 10:3015.5 7.7 5 Calcium 451 mg/kg 05/27/15 21:55 7440-70-205/26/15 10:3015577.4 5 Chromium 10.4 mg/kg 05/27/15 21:55 7440-47-305/26/15 10:301.5 0.77 5 Copper 12.5 mg/kg 05/27/15 21:55 7440-50-805/26/15 10:301.5 0.77 5 Iron 15600 mg/kg 05/27/15 21:55 7439-89-605/26/15 10:3012.4 6.2 5 Magnesium 3760 mg/kg 05/27/15 21:55 7439-95-405/26/15 10:3015577.4 5 Manganese 108 mg/kg 05/27/15 21:55 7439-96-505/26/15 10:301.5 0.77 5 Molybdenum ND mg/kg 05/27/15 21:55 7439-98-705/26/15 10:303.1 1.5 5 Nickel 1.3J mg/kg 05/27/15 21:55 7440-02-005/26/15 10:301.5 0.77 5 Potassium 1370 mg/kg 05/27/15 21:55 7440-09-705/26/15 10:303091555 Sodium ND mg/kg 05/27/15 21:55 7440-23-505/26/15 10:303091555 Strontium 11.2 mg/kg 05/27/15 21:55 7440-24-605/26/15 10:303.1 1.5 5 Zinc 18.9 mg/kg 05/27/15 21:55 7440-66-605/26/15 10:306.2 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/27/15 17:24 7440-36-0 N205/26/15 10:306.2 3.1 100 Arsenic ND mg/kg 05/27/15 17:24 7440-38-205/26/15 10:306.2 3.1 100 Cadmium ND mg/kg 05/27/15 17:24 7440-43-905/26/15 10:300.74 0.37 100 Cobalt 3.9J mg/kg 05/27/15 17:24 7440-48-405/26/15 10:306.2 3.1 100 Lead 4.7J mg/kg 05/27/15 17:24 7439-92-105/26/15 10:306.2 3.1 100 Selenium ND mg/kg 05/27/15 17:24 7782-49-205/26/15 10:306.2 3.1 100 Thallium ND mg/kg 05/27/15 17:24 7440-28-005/26/15 10:306.2 3.1 100 Vanadium 27.1 mg/kg 05/27/15 17:24 7440-62-205/26/15 10:306.2 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0056J mg/kg 05/26/15 20:45 7439-97-605/26/15 10:300.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.4 %06/02/15 10:590.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.2 Std. Units 05/27/15 11:200.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/21/15 01:29 16887-00-6 D3,M13051535 Sulfate ND mg/kg 05/21/15 01:29 14808-79-8 D33051535 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/21/15 01:29 14797-55-8 H330.5 15.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 37 24 of 43 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250201 J15050409 Sample:2015014672 Lab ID:92250201002 Collected:05/09/15 14:30 Received:05/15/15 13:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1210 mg/kg 06/02/15 15:56 7440-44-07403701 Total Organic Carbon 1710 mg/kg 06/02/15 16:02 7440-44-07473731 Total Organic Carbon 1460 mg/kg 06/02/15 16:07 7440-44-07453721 Total Organic Carbon 2900 mg/kg 06/02/15 16:13 7440-44-07383691 Mean Total Organic Carbon 1820 mg/kg 06/02/15 15:56 7440-44-07423711 Surrogates RSD%41.2 %06/02/15 15:56 1g1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 37 25 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13956 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92250201001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2001526 Associated Lab Samples:92250201001 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/21/15 20:42 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2001527LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.45 109 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2001528MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92254629012 2001529 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 98 80-120100 1 205ND4.9 5.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 37 26 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5767 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92250201002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1223182 Associated Lab Samples:92250201002 Matrix:Solid Analyzed Mercury mg/kg ND 0.0080 05/26/15 19:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1223183LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.075.08 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1223184MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250205001 1223185 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .0935 98 80-12082 15 20.09010.036 0.13 0.11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 37 27 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24322 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92250201002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1223174 Associated Lab Samples:92250201002 Matrix:Solid Analyzed Aluminum mg/kg ND 4.9 05/27/15 20:02 Barium mg/kg ND 0.49 05/27/15 20:02 Beryllium mg/kg ND 0.049 05/27/15 20:02 Boron mg/kg ND 2.5 05/27/15 20:02 Calcium mg/kg ND 24.5 05/27/15 20:02 Chromium mg/kg ND 0.25 05/27/15 20:02 Copper mg/kg ND 0.25 05/27/15 20:02 Iron mg/kg ND 2.0 05/27/15 20:02 Magnesium mg/kg ND 24.5 05/27/15 20:02 Manganese mg/kg ND 0.25 05/27/15 20:02 Molybdenum mg/kg ND 0.49 05/27/15 20:02 Nickel mg/kg ND 0.25 05/27/15 20:02 Potassium mg/kg ND 49.1 05/27/15 20:02 Sodium mg/kg ND 49.1 CH05/27/15 20:02 Strontium mg/kg ND 0.49 05/27/15 20:02 Zinc mg/kg ND 0.98 05/27/15 20:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1223175LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 135125 108 80-120 Barium mg/kg 13.512.5 108 80-120 Beryllium mg/kg 1.31.3 101 80-120 Boron mg/kg 121125 97 80-120 Calcium mg/kg 670626 107 80-120 Chromium mg/kg 11.612.5 93 80-120 Copper mg/kg 12.112.5 96 80-120 Iron mg/kg 131125 105 80-120 Magnesium mg/kg 625626 100 80-120 Manganese mg/kg 12.312.5 98 80-120 Molybdenum mg/kg 12.712.5 101 80-120 Nickel mg/kg 12.912.5 103 80-120 Potassium mg/kg 656626 105 80-120 Sodium mg/kg 717 CH62611580-120 Strontium mg/kg 13.612.5 109 80-120 Zinc mg/kg 64.362.6 103 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 37 28 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1223176MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250205001 1223177 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1137243075-1252870 6 2014193001260013400 Barium mg/kg M113.7 181 75-125285 15 2014.168.9 93.6 109 Beryllium mg/kg 1.37 103 75-125105 4 201.370.31 1.7 1.8 Boron mg/kg 137 92 75-12594 5 2014115.9 142 149 Calcium mg/kg M1,R1682104075-125461 29 2070781101520011400 Chromium mg/kg 13.7 124 75-125124 2 2014.113.8 30.7 31.3 Copper mg/kg M113.7 145 75-125164 7 2014.128.5 48.2 51.7 Iron mg/kg M1137210075-1252180 1 20141172002010020300 Magnesium mg/kg M168222375-125232 2 20707324047704880 Manganese mg/kg M113.7 512 75-125711 6 2014.1405 475 505 Molybdenum mg/kg 13.7 75 75-12576 4 2014.1ND 10.6 11.0 Nickel mg/kg 13.7 114 75-125118 5 2014.16.0 21.6 22.7 Potassium mg/kg M168212875-125127 2 2070750613801400 Sodium mg/kg CH68212575-125122 1 20707ND939950 Strontium mg/kg M113.7 168 75-125171 2 2014.131.8 54.8 56.1 Zinc mg/kg 68.2 110 75-125112 4 2070.722.5 97.5 102 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 37 29 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24323 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92250201002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1223178 Associated Lab Samples:92250201002 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N205/27/15 15:48 Arsenic mg/kg ND 0.051 05/27/15 15:48 Cadmium mg/kg ND 0.0061 05/27/15 15:48 Cobalt mg/kg ND 0.051 05/27/15 15:48 Lead mg/kg ND 0.051 05/27/15 15:48 Selenium mg/kg ND 0.051 05/27/15 15:48 Thallium mg/kg ND 0.051 05/27/15 15:48 Vanadium mg/kg ND 0.051 05/27/15 15:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1223179LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.5 N22.6 97 80-120 Arsenic mg/kg 2.62.6 102 80-120 Cadmium mg/kg 0.25.26 97 80-120 Cobalt mg/kg 2.52.6 98 80-120 Lead mg/kg 2.62.6 101 80-120 Selenium mg/kg 2.72.6 106 80-120 Thallium mg/kg 2.62.6 100 80-120 Vanadium mg/kg 2.52.6 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1223180MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250205001 1223181 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N22.97 42 75-12522 202.74ND ND ND Arsenic mg/kg M62.97 90 75-12567 202.74ND 4.5J 3.7J Cadmium mg/kg .297 102 75-12599 20.274ND ND ND Cobalt mg/kg M62.97 170 75-125189 1 202.7413.5 18.6 18.8 Lead mg/kg M62.97 123 75-125146 5 202.743.5J 7.2 7.5 Selenium mg/kg M62.97 82 75-12566 202.74ND 5.0J 4.4J Thallium mg/kg 2.97 81 75-12577 202.74ND 3.0J ND Vanadium mg/kg M62.97 521 75-125561 0 202.7460.5 76.0 76.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 37 30 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/55423 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92250201001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2002623 Associated Lab Samples:92250201001 Matrix:Water Analyzed Aluminum ug/L ND 10.0 06/26/15 11:41 Antimony ug/L ND 0.50 06/26/15 11:41 Arsenic ug/L ND 0.50 06/26/15 11:41 Barium ug/L ND 0.30 06/26/15 11:41 Beryllium ug/L ND 0.20 06/26/15 11:41 Boron ug/L ND 5.0 06/26/15 11:41 Cadmium ug/L ND 0.080 06/26/15 11:41 Calcium ug/L ND 40.0 06/26/15 11:41 Chromium ug/L ND 0.50 06/26/15 11:41 Cobalt ug/L ND 0.50 06/26/15 11:41 Copper ug/L ND 1.0 06/26/15 11:41 Iron ug/L ND 50.0 06/26/15 11:41 Lead ug/L ND 0.10 06/26/15 11:41 Magnesium ug/L ND 10.0 06/26/15 11:41 Manganese ug/L ND 0.50 06/26/15 11:41 Molybdenum ug/L ND 0.50 06/26/15 11:41 Nickel ug/L ND 0.50 06/26/15 11:41 Potassium ug/L ND 50.0 06/26/15 11:41 Selenium ug/L ND 0.50 06/26/15 11:41 Sodium ug/L ND 50.0 06/26/15 11:41 Strontium ug/L ND 0.50 06/26/15 11:41 Thallium ug/L ND 0.10 06/26/15 11:41 Vanadium ug/L ND 1.0 06/27/15 09:08 Zinc ug/L ND 5.0 06/26/15 11:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2002624LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 80.280 100 80-120 Antimony ug/L 78.180 98 80-120 Arsenic ug/L 79.680 100 80-120 Barium ug/L 78.680 98 80-120 Beryllium ug/L 80.780 101 80-120 Boron ug/L 79.280 99 80-120 Cadmium ug/L 79.480 99 80-120 Calcium ug/L 9831000 98 80-120 Chromium ug/L 79.580 99 80-120 Cobalt ug/L 79.880 100 80-120 Copper ug/L 78.180 98 80-120 Iron ug/L 10001000 100 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 37 31 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2002624LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 79.880 100 80-120 Magnesium ug/L 9781000 98 80-120 Manganese ug/L 79.780 100 80-120 Molybdenum ug/L 78.880 99 80-120 Nickel ug/L 80.980 101 80-120 Potassium ug/L 9631000 96 80-120 Selenium ug/L 80.580 101 80-120 Sodium ug/L 9751000 97 80-120 Strontium ug/L 78.880 99 80-120 Thallium ug/L 79.580 99 80-120 Vanadium ug/L 80.280 100 80-120 Zinc ug/L 80.280 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2002625MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92254832007 2002626 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18055875-125434 19 2080132578479 Antimony ug/L 80 97 75-12599 2 2080ND77.6 79.5 Arsenic ug/L 80 100 75-125100 1 2080ND79.8 80.2 Barium ug/L 80 98 75-12599 1 20800.60 78.7 79.9 Beryllium ug/L 80 103 75-125104 1 2080ND82.8 83.2 Boron ug/L 80 104 75-125105 0 2080ND84.1 84.3 Cadmium ug/L 80 99 75-125100 1 2080ND79.4 79.8 Calcium ug/L 1000 99 75-125104 5 20100034.3J 1020 1080 Chromium ug/L 80 99 75-125101 2 20800.31J 79.4 81.1 Cobalt ug/L 80 100 75-125101 1 2080ND80.0 80.6 Copper ug/L 80 98 75-12599 1 20800.26J 78.6 79.3 Iron ug/L 1000 108 75-125105 2 20100029613801350 Lead ug/L 80 101 75-125102 0 20800.42 81.4 81.7 Magnesium ug/L 1000 97 75-125101 4 20100013.5 986 1030 Manganese ug/L 80 100 75-125101 0 20803.3 83.6 83.7 Molybdenum ug/L 80 98 75-12599 2 2080ND78.1 79.4 Nickel ug/L 80 101 75-125103 2 20800.46J 81.0 82.6 Potassium ug/L 1000 97 75-12599 2 20100024.7J 990 1010 Selenium ug/L 80 101 75-12599 2 2080ND80.7 79.2 Sodium ug/L 1000 99 75-125100 1 201000ND10001010 Strontium ug/L 80 99 75-125100 1 2080ND79.1 80.2 Thallium ug/L 80 102 75-125102 0 2080ND81.6 81.9 Vanadium ug/L 80 102 75-125100 1 20800.36J 81.8 80.6 Zinc ug/L 80 101 75-125102 1 208016.9 97.5 98.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 37 32 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3609 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92250201002 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250201002 1229602SAMPLE DUPLICATE: Percent Moisture %18.7 4 1019.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190185002 1229603SAMPLE DUPLICATE: Percent Moisture %7.4 D615108.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190195001 1229604SAMPLE DUPLICATE: Percent Moisture %2.0 D611102.3 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190544023 1229605SAMPLE DUPLICATE: Percent Moisture %6.3 6 105.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190544041 1229606SAMPLE DUPLICATE: Percent Moisture %5.1 D611105.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190704003 1229607SAMPLE DUPLICATE: Percent Moisture %12.9 D6401019.3 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190704011 1229608SAMPLE DUPLICATE: Percent Moisture %22.6 7 1021.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 37 33 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37661 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92250201002 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250201002 1467399SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.3 1 105.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250205001 1467400SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.7 D63106.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 37 34 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46586 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92250201002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1219552 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 50.5 05/21/15 00:24 Sulfate mg/kg ND 50.5 05/21/15 00:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1219553LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 468497 94 80-120 Sulfate mg/kg 462497 93 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1219555MATRIX SPIKE SAMPLE: MSSpike Result 92250201002 Chloride mg/kg 545 M16197280-120ND Sulfate mg/kg 583619 80 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92250201002 1219554SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 37 35 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46587 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92250201002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1219557 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.1 05/21/15 00:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1219558LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 47.349.7 95 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1219560MATRIX SPIKE SAMPLE: MSSpike Result 92250201002 Nitrate as N mg/kg 55.3 H361.9 89 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92250201002 1219559SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 37 36 of 43 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250201 J15050409 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28762 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92250201002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1167261 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/02/15 07:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1167262LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 114000120000 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1167263MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249703006 1167264 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 5990 77 50-15079 3 306000ND48204980 Parameter Units MS Result % Rec Limits Qual% RecConc. 1167265MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249703007 1167266 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6030 81 50-15089 8 306010ND51105550 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 37 37 of 43 #=QL# QUALIFIERS Pace Project No.: Project: 92250201 J15050409 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14866 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS % RSD > 401g The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high.CH Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 37 38 of 43 #=QL# QUALIFIERS Pace Project No.: Project: 92250201 J15050409 ANALYTE QUALIFIERS RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 37 39 of 43 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92250201 J15050409 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92250201002 MPRP/24322 ICP/148662015014672EPA 3050 EPA 6010 92250201002 MPRP/24323 ICPM/98532015014672EPA 3050 EPA 6020 92250201001 MPRP/55423 ICPM/249912015014671EPA 3020 EPA 6020A 92250201001 MERP/13956 MERC/162322015014671EPA 7470A EPA 7470A 92250201002 MERP/5767 MERC/57522015014672EPA 7471 EPA 7471 92250201002 PMST/36092015014672ASTM D2974-87 92250201002 WET/376612015014672EPA 9045 92250201002 WETA/465862015014672EPA 9056 92250201002 WETA/465872015014672EPA 9056 92250201002 WETA/287622015014672EPA 9060 92250201002 WETA/287632015014672EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/29/2015 03:48 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 37 40 of 43 Page 36 of 37 41 of 43 Page 37 of 37 42 of 43 43 of 43