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Home My WebLink AboutNC0038377_J15050361 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15050361 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/13/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 101 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015014547 MAYO STEAM 13-May-15 11:45 AM illegible S-02 2015014548 MAYO STEAM 13-May-15 4:05 PM illegible S-06 2015014549 MAYO STEAM 13-May-15 5:05 PM illegible S-08 2015014550 MAYO STEAM 13-May-15 12:50 PM illegible SW-CB2 2015014551 MAYO STEAM 12-May-15 11:25 AM illegible S-01 2015014552 MAYO STEAM 13-May-15 11:45 AM illegible SW-CB1 2015014553 MAYO STEAM 13-May-15 10:30 AM illegible S-04 2015014554 MAYO STEAM 13-May-15 11:05 AM illegible S-02B 2015014555 MAYO STEAM 12-May-15 2:35 PM illegible S-03 2015014556 MAYO STEAM 13-May-15 2:50 PM illegible SW-REF1 10 Total Samples 2 of 101 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014547 Collection Date: 13-May-15 11:45 AM Site:S-02 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014548 Collection Date: 13-May-15 4:05 PM Site:S-06 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014549 Collection Date: 13-May-15 5:05 PM Site:S-08 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014550 Collection Date: 13-May-15 12:50 PM Site:SW-CB2 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014551 Collection Date: 12-May-15 11:25 AM Site:S-01 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 8 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014552 Collection Date: 13-May-15 11:45 AM Site:SW-CB1 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 9 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014553 Collection Date: 13-May-15 10:30 AM Site:S-04 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 10 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014554 Collection Date: 13-May-15 11:05 AM Site:S-02B Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 11 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014555 Collection Date: 12-May-15 2:35 PM Site:S-03 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 12 of 101 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050361 2015014556 Collection Date: 13-May-15 2:50 PM Site:SW-REF1 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Chain of custody listed incorrect collection times for samples 2015014547, -551, and -556. Correct collection times obtained from Synterra field sampling records. RPD for the quadruplicate TOC determinations on sample 2015014550 exceeded requirement for RPD to be less than 40%. All other samples and QC acceptable. M. Galvin- Karr 6/12/15 -- Additional Information -- 13 of 101 #=CL# June 08, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92250058 92250058 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15050361 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 14, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 59 14 of 101 #=CP# CERTIFICATIONS Pace Project No.: Project: 92250058 J15050361 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 59 15 of 101 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID Matrix Date Collected Date Received 92250058001 2015014547 Solid 05/13/15 15:20 05/14/15 17:35 92250058002 2015014548 Solid 05/13/15 16:05 05/14/15 17:35 92250058003 2015014549 Solid 05/13/15 17:05 05/14/15 17:35 92250058004 2015014550 Solid 05/13/15 12:50 05/14/15 17:35 92250058005 2015014551 Solid 05/12/15 16:25 05/14/15 17:35 92250058006 2015014552 Solid 05/13/15 11:45 05/14/15 17:35 92250058007 2015014553 Solid 05/13/15 10:30 05/14/15 17:35 92250058008 2015014554 Solid 05/13/15 11:05 05/14/15 17:35 92250058009 2015014555 Solid 05/12/15 14:35 05/14/15 17:35 92250058010 2015014556 Solid 05/13/15 14:15 05/14/15 17:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 59 16 of 101 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92250058001 2015014547 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058002 2015014548 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058003 2015014549 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058004 2015014550 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058005 2015014551 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 59 17 of 101 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058006 2015014552 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058007 2015014553 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058008 2015014554 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058009 2015014555 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92250058010 2015014556 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 59 18 of 101 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 59 19 of 101 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250058 J15050361 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250058001 2015014547 Aluminum 3390 mg/kg 05/30/15 20:2334.0EPA 6010 Barium 49.1 mg/kg 05/30/15 20:233.4EPA 6010 Beryllium 0.25J mg/kg 05/30/15 20:230.34EPA 6010 Calcium 513 mg/kg 05/30/15 20:23170EPA 6010 Chromium 8.0 mg/kg 05/30/15 20:231.7EPA 6010 Copper 7.8 mg/kg 05/30/15 20:231.7EPA 6010 Iron 16000 mg/kg 05/30/15 20:2313.6EPA 6010 Magnesium 1580 mg/kg 05/30/15 20:23170EPA 6010 Manganese 1060 mg/kg 05/30/15 20:231.7EPA 6010 Nickel 3.2 mg/kg 05/30/15 20:231.7EPA 6010 Potassium 687 mg/kg 05/30/15 20:23340EPA 6010 Strontium 6.8 mg/kg 05/30/15 20:233.4EPA 6010 Zinc 18.7 mg/kg 05/30/15 20:236.8EPA 6010 Cobalt 16.4 mg/kg 05/29/15 11:546.8EPA 6020 Vanadium 13.3 mg/kg 05/29/15 11:546.8EPA 6020 Percent Moisture 26.9 %05/29/15 10:130.10ASTM D2974-87 pH at 25 Degrees C 6.5 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 1020 mg/kg 06/05/15 08:57813EPA 9060 Total Organic Carbon 1120 mg/kg 06/05/15 09:03818EPA 9060 Total Organic Carbon 1230 mg/kg 06/05/15 09:08825EPA 9060 Total Organic Carbon 1140 mg/kg 06/05/15 09:13820EPA 9060 Mean Total Organic Carbon 1130 mg/kg 06/05/15 08:57819EPA 9060 RSD%7.4 %06/05/15 08:57EPA 9060 92250058002 2015014548 Aluminum 7500 mg/kg 05/30/15 20:5149.5EPA 6010 Barium 80.9 mg/kg 05/30/15 20:514.9EPA 6010 Beryllium 0.37J mg/kg 05/30/15 20:510.49EPA 6010 Calcium 2010 mg/kg 05/30/15 20:51247EPA 6010 Chromium 18.5 mg/kg 05/30/15 20:512.5EPA 6010 Copper 15.9 mg/kg 05/30/15 20:512.5EPA 6010 Iron 17400 mg/kg 05/30/15 20:5119.8EPA 6010 Magnesium 3090 mg/kg 05/30/15 20:51247EPA 6010 Manganese 436 mg/kg 05/30/15 20:512.5EPA 6010 Nickel 7.4 mg/kg 05/30/15 20:512.5EPA 6010 Potassium 1230 mg/kg 05/30/15 20:51495EPA 6010 Strontium 15.5 mg/kg 05/30/15 20:514.9EPA 6010 Zinc 174 mg/kg 05/30/15 20:519.9EPA 6010 Cobalt 7.4J mg/kg 05/29/15 12:079.9EPA 6020 Lead 8.0J mg/kg 05/29/15 12:079.9EPA 6020 Vanadium 33.6 mg/kg 05/29/15 12:079.9EPA 6020 Mercury 0.0096J mg/kg 05/30/15 13:410.017EPA 7471 Percent Moisture 52.7 %05/29/15 10:130.10ASTM D2974-87 pH at 25 Degrees C 6.6 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 26100 mg/kg 06/05/15 10:031260EPA 9060 Total Organic Carbon 19800 mg/kg 06/05/15 10:101260EPA 9060 Total Organic Carbon 26300 mg/kg 06/05/15 10:151260EPA 9060 Total Organic Carbon 21700 mg/kg 06/05/15 10:211260EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 59 20 of 101 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250058 J15050361 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250058002 2015014548 Mean Total Organic Carbon 23500 mg/kg 06/05/15 10:031260EPA 9060 RSD%13.8 %06/05/15 10:03EPA 9060 92250058003 2015014549 Aluminum 2900 mg/kg 05/30/15 20:5643.6EPA 6010 Barium 179 mg/kg 05/30/15 20:564.4EPA 6010 Beryllium 0.70 mg/kg 05/30/15 20:560.44EPA 6010 Calcium 1280 mg/kg 05/30/15 20:56218EPA 6010 Chromium 4.5 mg/kg 05/30/15 20:562.2EPA 6010 Copper 4.9 mg/kg 05/30/15 20:562.2EPA 6010 Iron 10700 mg/kg 05/30/15 20:5617.5EPA 6010 Magnesium 656 mg/kg 05/30/15 20:56218EPA 6010 Manganese 7090 mg/kg 06/01/15 19:57 D410.9EPA 6010 Nickel 4.8 mg/kg 05/30/15 20:562.2EPA 6010 Potassium 310J mg/kg 05/30/15 20:56436EPA 6010 Strontium 29.2 mg/kg 05/30/15 20:564.4EPA 6010 Zinc 12.8 mg/kg 05/30/15 20:568.7EPA 6010 Cobalt 40.6 mg/kg 05/29/15 12:108.7EPA 6020 Lead 4.9J mg/kg 05/29/15 12:108.7EPA 6020 Vanadium 7.3J mg/kg 05/29/15 12:108.7EPA 6020 Mercury 0.010J mg/kg 05/30/15 13:440.014EPA 7471 Percent Moisture 43.5 %05/29/15 10:140.10ASTM D2974-87 pH at 25 Degrees C 6.8 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 3100 mg/kg 06/05/15 11:141070EPA 9060 Total Organic Carbon 2960 mg/kg 06/05/15 11:211060EPA 9060 Total Organic Carbon 2930 mg/kg 06/05/15 11:261050EPA 9060 Total Organic Carbon 5040 mg/kg 06/05/15 11:331050EPA 9060 Mean Total Organic Carbon 3510 mg/kg 06/05/15 11:141060EPA 9060 RSD%29.1 %06/05/15 11:14EPA 9060 92250058004 2015014550 Aluminum 7350 mg/kg 05/30/15 21:0055.3EPA 6010 Barium 98.2 mg/kg 05/30/15 21:005.5EPA 6010 Beryllium 0.29J mg/kg 05/30/15 21:000.55EPA 6010 Calcium 1060 mg/kg 05/30/15 21:00277EPA 6010 Chromium 13.9 mg/kg 05/30/15 21:002.8EPA 6010 Copper 9.5 mg/kg 05/30/15 21:002.8EPA 6010 Iron 11400 mg/kg 05/30/15 21:0022.1EPA 6010 Magnesium 2170 mg/kg 05/30/15 21:00277EPA 6010 Manganese 383 mg/kg 05/30/15 21:002.8EPA 6010 Nickel 5.0 mg/kg 05/30/15 21:002.8EPA 6010 Potassium 952 mg/kg 05/30/15 21:00553EPA 6010 Strontium 16.3 mg/kg 05/30/15 21:005.5EPA 6010 Zinc 31.4 mg/kg 05/30/15 21:0011.1EPA 6010 Cobalt 6.1J mg/kg 05/29/15 12:1211.1EPA 6020 Lead 7.4J mg/kg 05/29/15 12:1211.1EPA 6020 Vanadium 19.2 mg/kg 05/29/15 12:1211.1EPA 6020 Mercury 0.027 mg/kg 05/30/15 13:460.019EPA 7471 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 59 21 of 101 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250058 J15050361 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250058004 2015014550 Percent Moisture 56.5 %05/29/15 10:14 D60.10ASTM D2974-87 pH at 25 Degrees C 7.0 Std. Units 05/24/15 15:500.10EPA 9045 Sulfate 399J mg/kg 05/20/15 17:38 D3566EPA 9056 Total Organic Carbon 25900 mg/kg 06/05/15 11:385300EPA 9060 Total Organic Carbon 27000 mg/kg 06/05/15 11:435290EPA 9060 Total Organic Carbon 23900 mg/kg 06/05/15 11:495290EPA 9060 Total Organic Carbon 22300 mg/kg 06/05/15 11:545280EPA 9060 Mean Total Organic Carbon 24800 mg/kg 06/05/15 11:385290EPA 9060 RSD%8.5 %06/05/15 11:38EPA 9060 92250058005 2015014551 Aluminum 1120 mg/kg 05/30/15 21:0471.8EPA 6010 Barium 271 mg/kg 05/30/15 21:047.2EPA 6010 Boron 40.4 mg/kg 05/30/15 21:0435.9EPA 6010 Calcium 1580 mg/kg 05/30/15 21:04359EPA 6010 Chromium 5.8 mg/kg 05/30/15 21:043.6EPA 6010 Iron 247000 mg/kg 05/30/15 21:0428.7EPA 6010 Magnesium 664 mg/kg 05/30/15 21:04359EPA 6010 Manganese 511 mg/kg 05/30/15 21:043.6EPA 6010 Strontium 40.1 mg/kg 05/30/15 21:047.2EPA 6010 Zinc 227 mg/kg 05/30/15 21:0414.4EPA 6010 Arsenic 56.4 mg/kg 05/29/15 12:1514.4EPA 6020 Percent Moisture 65.5 %05/29/15 10:140.10ASTM D2974-87 pH at 25 Degrees C 6.4 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 19000 mg/kg 06/03/15 09:131760EPA 9060 Total Organic Carbon 20900 mg/kg 06/03/15 09:181730EPA 9060 Total Organic Carbon 19100 mg/kg 06/03/15 09:251750EPA 9060 Total Organic Carbon 14600 mg/kg 06/03/15 09:301730EPA 9060 Mean Total Organic Carbon 18400 mg/kg 06/03/15 09:131740EPA 9060 RSD%14.6 %06/03/15 09:13EPA 9060 92250058006 2015014552 Aluminum 6760 mg/kg 05/30/15 21:0835.6EPA 6010 Barium 53.1 mg/kg 05/30/15 21:083.6EPA 6010 Beryllium 0.38 mg/kg 05/30/15 21:080.36EPA 6010 Calcium 763 mg/kg 05/30/15 21:08178EPA 6010 Chromium 13.1 mg/kg 05/30/15 21:081.8EPA 6010 Copper 10.4 mg/kg 05/30/15 21:081.8EPA 6010 Iron 9660 mg/kg 05/30/15 21:0814.2EPA 6010 Magnesium 3070 mg/kg 05/30/15 21:08178EPA 6010 Manganese 186 mg/kg 05/30/15 21:081.8EPA 6010 Nickel 5.2 mg/kg 05/30/15 21:081.8EPA 6010 Potassium 1590 mg/kg 05/30/15 21:08356EPA 6010 Strontium 10.3 mg/kg 05/30/15 21:083.6EPA 6010 Zinc 39.6 mg/kg 05/30/15 21:087.1EPA 6010 Cobalt 4.5J mg/kg 05/29/15 12:187.1EPA 6020 Lead 3.6J mg/kg 05/29/15 12:187.1EPA 6020 Vanadium 16.5 mg/kg 05/29/15 12:187.1EPA 6020 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 59 22 of 101 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250058 J15050361 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250058006 2015014552 Mercury 0.0065J mg/kg 05/30/15 13:540.011EPA 7471 Percent Moisture 30.2 %05/29/15 10:140.10ASTM D2974-87 pH at 25 Degrees C 6.3 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 4000 mg/kg 06/05/15 12:13860EPA 9060 Total Organic Carbon 4430 mg/kg 06/05/15 12:19855EPA 9060 Total Organic Carbon 3640 mg/kg 06/05/15 12:24857EPA 9060 Total Organic Carbon 3000 mg/kg 06/05/15 12:30862EPA 9060 Mean Total Organic Carbon 3770 mg/kg 06/05/15 12:13859EPA 9060 RSD%16.1 %06/05/15 12:13EPA 9060 92250058007 2015014553 Aluminum 6190 mg/kg 05/30/15 21:1260.1EPA 6010 Barium 164 mg/kg 05/30/15 21:126.0EPA 6010 Beryllium 0.33J mg/kg 05/30/15 21:120.60EPA 6010 Boron 16.9J mg/kg 05/30/15 21:1230.1EPA 6010 Calcium 2100 mg/kg 05/30/15 21:12301EPA 6010 Chromium 15.4 mg/kg 05/30/15 21:123.0EPA 6010 Copper 12.3 mg/kg 05/30/15 21:123.0EPA 6010 Iron 101000 mg/kg 05/30/15 21:1224.1EPA 6010 Magnesium 3250 mg/kg 05/30/15 21:12301EPA 6010 Manganese 2400 mg/kg 05/30/15 21:123.0EPA 6010 Nickel 3.2 mg/kg 05/30/15 21:123.0EPA 6010 Potassium 1390 mg/kg 05/30/15 21:12601EPA 6010 Strontium 33.6 mg/kg 05/30/15 21:126.0EPA 6010 Zinc 26.6 mg/kg 05/30/15 21:1212.0EPA 6010 Arsenic 14.1 mg/kg 05/29/15 12:2012.0EPA 6020 Cobalt 14.0 mg/kg 05/29/15 12:2012.0EPA 6020 Vanadium 22.3 mg/kg 05/29/15 12:2012.0EPA 6020 Percent Moisture 57.0 %05/29/15 10:140.10ASTM D2974-87 pH at 25 Degrees C 6.9 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 10700 mg/kg 06/05/15 12:351410EPA 9060 Total Organic Carbon 12400 mg/kg 06/05/15 12:421390EPA 9060 Total Organic Carbon 14100 mg/kg 06/05/15 12:471410EPA 9060 Total Organic Carbon 14400 mg/kg 06/05/15 12:531390EPA 9060 Mean Total Organic Carbon 12900 mg/kg 06/05/15 12:351400EPA 9060 RSD%13.1 %06/05/15 12:35EPA 9060 92250058008 2015014554 Aluminum 2170 mg/kg 05/30/15 21:1631.6EPA 6010 Barium 31.8 mg/kg 05/30/15 21:163.2EPA 6010 Beryllium 0.21J mg/kg 05/30/15 21:160.32EPA 6010 Calcium 507 mg/kg 05/30/15 21:16158EPA 6010 Chromium 3.4 mg/kg 05/30/15 21:161.6EPA 6010 Copper 4.8 mg/kg 05/30/15 21:161.6EPA 6010 Iron 12700 mg/kg 05/30/15 21:1612.6EPA 6010 Magnesium 1110 mg/kg 05/30/15 21:16158EPA 6010 Manganese 427 mg/kg 05/30/15 21:161.6EPA 6010 Nickel 0.96J mg/kg 05/30/15 21:161.6EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 59 23 of 101 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250058 J15050361 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250058008 2015014554 Potassium 471 mg/kg 05/30/15 21:16316EPA 6010 Strontium 5.3 mg/kg 05/30/15 21:163.2EPA 6010 Zinc 10.7 mg/kg 05/30/15 21:166.3EPA 6010 Cobalt 4.7J mg/kg 05/29/15 12:236.3EPA 6020 Vanadium 5.8J mg/kg 05/29/15 12:236.3EPA 6020 Percent Moisture 18.9 %05/29/15 10:140.10ASTM D2974-87 pH at 25 Degrees C 6.6 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 1060 mg/kg 06/05/15 12:59736EPA 9060 Total Organic Carbon 1020 mg/kg 06/05/15 13:05735EPA 9060 Total Organic Carbon 1060 mg/kg 06/05/15 13:11745EPA 9060 Total Organic Carbon 1000 mg/kg 06/05/15 13:17740EPA 9060 Mean Total Organic Carbon 1030 mg/kg 06/05/15 12:59739EPA 9060 RSD%2.8 %06/05/15 12:59EPA 9060 92250058009 2015014555 Aluminum 5030 mg/kg 05/30/15 21:2032.5EPA 6010 Barium 38.3 mg/kg 05/30/15 21:203.2EPA 6010 Beryllium 0.44 mg/kg 05/30/15 21:200.32EPA 6010 Calcium 625 mg/kg 05/30/15 21:20162EPA 6010 Chromium 94.4 mg/kg 05/30/15 21:201.6EPA 6010 Copper 5.4 mg/kg 05/30/15 21:201.6EPA 6010 Iron 15600 mg/kg 05/30/15 21:2013.0EPA 6010 Magnesium 1140 mg/kg 05/30/15 21:20162EPA 6010 Manganese 562 mg/kg 05/30/15 21:201.6EPA 6010 Nickel 2.8 mg/kg 05/30/15 21:201.6EPA 6010 Potassium 342 mg/kg 05/30/15 21:20325EPA 6010 Strontium 10 mg/kg 05/30/15 21:203.2EPA 6010 Zinc 12.6 mg/kg 05/30/15 21:206.5EPA 6010 Cobalt 7.4 mg/kg 05/29/15 12:256.5EPA 6020 Lead 14.0 mg/kg 05/29/15 12:256.5EPA 6020 Vanadium 42.5 mg/kg 05/29/15 12:256.5EPA 6020 Percent Moisture 19.5 %05/29/15 10:150.10ASTM D2974-87 pH at 25 Degrees C 7.1 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 1280 mg/kg 06/03/15 10:22748EPA 9060 Total Organic Carbon 1320 mg/kg 06/03/15 10:28738EPA 9060 Total Organic Carbon 1440 mg/kg 06/03/15 10:33752EPA 9060 Total Organic Carbon 1120 mg/kg 06/03/15 10:39748EPA 9060 Mean Total Organic Carbon 1290 mg/kg 06/03/15 10:22747EPA 9060 RSD%10.2 %06/03/15 10:22EPA 9060 92250058010 2015014556 Aluminum 2610 mg/kg 05/30/15 21:2435.6EPA 6010 Barium 23.7 mg/kg 05/30/15 21:243.6EPA 6010 Beryllium 0.18J mg/kg 05/30/15 21:240.36EPA 6010 Calcium 335 mg/kg 05/30/15 21:24178EPA 6010 Chromium 17.3 mg/kg 05/30/15 21:241.8EPA 6010 Copper 3.3 mg/kg 05/30/15 21:241.8EPA 6010 Iron 7100 mg/kg 05/30/15 21:2414.2EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 59 24 of 101 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92250058 J15050361 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92250058010 2015014556 Magnesium 937 mg/kg 05/30/15 21:24178EPA 6010 Manganese 122 mg/kg 05/30/15 21:241.8EPA 6010 Nickel 2.4 mg/kg 05/30/15 21:241.8EPA 6010 Potassium 470 mg/kg 05/30/15 21:24356EPA 6010 Strontium 3.2J mg/kg 05/30/15 21:243.6EPA 6010 Zinc 14.8 mg/kg 05/30/15 21:247.1EPA 6010 Lead 3.7J mg/kg 05/29/15 12:287.1EPA 6020 Vanadium 15.1 mg/kg 05/29/15 12:287.1EPA 6020 Percent Moisture 26.2 %05/29/15 10:150.10ASTM D2974-87 pH at 25 Degrees C 6.4 Std. Units 05/24/15 15:500.10EPA 9045 Total Organic Carbon 7080 mg/kg 06/05/15 13:22818EPA 9060 Total Organic Carbon 5760 mg/kg 06/05/15 13:28807EPA 9060 Total Organic Carbon 4310 mg/kg 06/05/15 13:33814EPA 9060 Total Organic Carbon 3690 mg/kg 06/05/15 13:38818EPA 9060 Mean Total Organic Carbon 5210 mg/kg 06/05/15 13:22814EPA 9060 RSD%29.1 %06/05/15 13:22EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 59 25 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 6010 Date:June 08, 2015 Description:6010 MET ICP General Information: 10 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24366 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245394022 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1226123) • Aluminum • Barium • Boron • Copper • Iron • Molybdenum • MSD (Lab ID: 1226124) • Aluminum • Barium • Boron • Chromium • Copper • Iron • Manganese R1: RPD value was outside control limits. • MSD (Lab ID: 1226124) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 59 26 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 6010 Date:June 08, 2015 Description:6010 MET ICP QC Batch: MPRP/24366 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245394022 R1: RPD value was outside control limits. • Iron Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14887 Analyte Comments: QC Batch: MPRP/24366 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015014551 (Lab ID: 92250058005) • Nickel D4: Sample was diluted due to the presence of high levels of target analytes. • 2015014549 (Lab ID: 92250058003) • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 59 27 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 6020 Date:June 08, 2015 Description:6020 MET ICPMS General Information: 10 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24367 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245394022 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1226127) • Antimony • Arsenic • Selenium • Thallium • Vanadium • MSD (Lab ID: 1226128) • Antimony • Cadmium • Lead • Selenium • Thallium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 59 28 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 6020 Date:June 08, 2015 Description:6020 MET ICPMS Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 9867 Analyte Comments: QC Batch: MPRP/24367 N2: The lab does not hold TNI accreditation for this parameter. • 2015014547 (Lab ID: 92250058001) • Antimony • 2015014548 (Lab ID: 92250058002) • Antimony • 2015014549 (Lab ID: 92250058003) • Antimony • 2015014550 (Lab ID: 92250058004) • Antimony • 2015014551 (Lab ID: 92250058005) • Antimony • 2015014552 (Lab ID: 92250058006) • Antimony • 2015014553 (Lab ID: 92250058007) • Antimony • 2015014554 (Lab ID: 92250058008) • Antimony • 2015014555 (Lab ID: 92250058009) • Antimony • 2015014556 (Lab ID: 92250058010) • Antimony • BLANK (Lab ID: 1226125) • Antimony • LCS (Lab ID: 1226126) • Antimony • MS (Lab ID: 1226127) • Antimony • MSD (Lab ID: 1226128) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 59 29 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 7471 Date:June 08, 2015 Description:7471 Mercury General Information: 10 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 59 30 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 9045 Date:June 08, 2015 Description:9045 pH Soil General Information: 10 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37585 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1464536) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 59 31 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 9056 Date:June 08, 2015 Description:9056 IC Anions General Information: 10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46584 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015014547 (Lab ID: 92250058001) • Chloride • Sulfate • 2015014548 (Lab ID: 92250058002) • Chloride • Sulfate • 2015014549 (Lab ID: 92250058003) • Chloride • Sulfate • 2015014550 (Lab ID: 92250058004) • Chloride • Sulfate • 2015014551 (Lab ID: 92250058005) • Chloride • Sulfate • 2015014552 (Lab ID: 92250058006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 59 32 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 9056 Date:June 08, 2015 Description:9056 IC Anions Analyte Comments: QC Batch: WETA/46584 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015014553 (Lab ID: 92250058007) • Chloride • Sulfate • 2015014554 (Lab ID: 92250058008) • Chloride • Sulfate • 2015014555 (Lab ID: 92250058009) • Chloride • Sulfate • 2015014556 (Lab ID: 92250058010) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 59 33 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 9056 Date:June 08, 2015 Description:9056 IC Anions 48hr General Information: 10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015014547 (Lab ID: 92250058001) • 2015014548 (Lab ID: 92250058002) • 2015014549 (Lab ID: 92250058003) • 2015014550 (Lab ID: 92250058004) • 2015014551 (Lab ID: 92250058005) • 2015014552 (Lab ID: 92250058006) • 2015014553 (Lab ID: 92250058007) • 2015014554 (Lab ID: 92250058008) • 2015014555 (Lab ID: 92250058009) • 2015014556 (Lab ID: 92250058010) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 59 34 of 101 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92250058 J15050361 Method: Client:Duke Energy EPA 9060 Date:June 08, 2015 Description:Total Organic Carbon Quad General Information: 10 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 59 35 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014547 Lab ID:92250058001 Collected:05/13/15 15:20 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3390 mg/kg 05/30/15 20:23 7429-90-505/28/15 20:1034.0 17.0 5 Barium 49.1 mg/kg 05/30/15 20:23 7440-39-305/28/15 20:103.4 1.7 5 Beryllium 0.25J mg/kg 05/30/15 20:23 7440-41-705/28/15 20:100.34 0.17 5 Boron ND mg/kg 05/30/15 20:23 7440-42-805/28/15 20:1017.0 8.5 5 Calcium 513 mg/kg 05/30/15 20:23 7440-70-205/28/15 20:1017085.0 5 Chromium 8.0 mg/kg 05/30/15 20:23 7440-47-305/28/15 20:101.7 0.85 5 Copper 7.8 mg/kg 05/30/15 20:23 7440-50-805/28/15 20:101.7 0.85 5 Iron 16000 mg/kg 05/30/15 20:23 7439-89-605/28/15 20:1013.6 6.8 5 Magnesium 1580 mg/kg 05/30/15 20:23 7439-95-405/28/15 20:1017085.0 5 Manganese 1060 mg/kg 05/30/15 20:23 7439-96-505/28/15 20:101.7 0.85 5 Molybdenum ND mg/kg 05/30/15 20:23 7439-98-705/28/15 20:103.4 1.7 5 Nickel 3.2 mg/kg 05/30/15 20:23 7440-02-005/28/15 20:101.7 0.85 5 Potassium 687 mg/kg 05/30/15 20:23 7440-09-705/28/15 20:103401705 Sodium ND mg/kg 05/30/15 20:23 7440-23-505/28/15 20:103401705 Strontium 6.8 mg/kg 05/30/15 20:23 7440-24-605/28/15 20:103.4 1.7 5 Zinc 18.7 mg/kg 05/30/15 20:23 7440-66-605/28/15 20:106.8 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 11:54 7440-36-0 N205/28/15 20:106.8 3.4 100 Arsenic ND mg/kg 05/29/15 11:54 7440-38-205/28/15 20:106.8 3.4 100 Cadmium ND mg/kg 05/29/15 11:54 7440-43-905/28/15 20:100.82 0.41 100 Cobalt 16.4 mg/kg 05/29/15 11:54 7440-48-405/28/15 20:106.8 3.4 100 Lead ND mg/kg 05/29/15 11:54 7439-92-105/28/15 20:106.8 3.4 100 Selenium ND mg/kg 05/29/15 11:54 7782-49-205/28/15 20:106.8 3.4 100 Thallium ND mg/kg 05/29/15 11:54 7440-28-005/28/15 20:106.8 3.4 100 Vanadium 13.3 mg/kg 05/29/15 11:54 7440-62-205/28/15 20:106.8 3.4 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/30/15 13:37 7439-97-605/28/15 21:300.011 0.0056 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.9 %05/29/15 10:130.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.5 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 15:51 16887-00-6 D3,M13411705 Sulfate ND mg/kg 05/20/15 15:51 14808-79-8 D3,M13411705 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 15:51 14797-55-8 H334.1 17.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 59 36 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014547 Lab ID:92250058001 Collected:05/13/15 15:20 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1020 mg/kg 06/05/15 08:57 7440-44-08134071 Total Organic Carbon 1120 mg/kg 06/05/15 09:03 7440-44-08184091 Total Organic Carbon 1230 mg/kg 06/05/15 09:08 7440-44-08254131 Total Organic Carbon 1140 mg/kg 06/05/15 09:13 7440-44-08204101 Mean Total Organic Carbon 1130 mg/kg 06/05/15 08:57 7440-44-08194101 Surrogates RSD%7.4 %06/05/15 08:571 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 59 37 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014548 Lab ID:92250058002 Collected:05/13/15 16:05 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7500 mg/kg 05/30/15 20:51 7429-90-505/28/15 20:1049.5 24.7 5 Barium 80.9 mg/kg 05/30/15 20:51 7440-39-305/28/15 20:104.9 2.5 5 Beryllium 0.37J mg/kg 05/30/15 20:51 7440-41-705/28/15 20:100.49 0.25 5 Boron ND mg/kg 05/30/15 20:51 7440-42-805/28/15 20:1024.7 12.4 5 Calcium 2010 mg/kg 05/30/15 20:51 7440-70-205/28/15 20:102471245 Chromium 18.5 mg/kg 05/30/15 20:51 7440-47-305/28/15 20:102.5 1.2 5 Copper 15.9 mg/kg 05/30/15 20:51 7440-50-805/28/15 20:102.5 1.2 5 Iron 17400 mg/kg 05/30/15 20:51 7439-89-605/28/15 20:1019.8 9.9 5 Magnesium 3090 mg/kg 05/30/15 20:51 7439-95-405/28/15 20:102471245 Manganese 436 mg/kg 05/30/15 20:51 7439-96-505/28/15 20:102.5 1.2 5 Molybdenum ND mg/kg 05/30/15 20:51 7439-98-705/28/15 20:104.9 2.5 5 Nickel 7.4 mg/kg 05/30/15 20:51 7440-02-005/28/15 20:102.5 1.2 5 Potassium 1230 mg/kg 05/30/15 20:51 7440-09-705/28/15 20:104952475 Sodium ND mg/kg 05/30/15 20:51 7440-23-505/28/15 20:104952475 Strontium 15.5 mg/kg 05/30/15 20:51 7440-24-605/28/15 20:104.9 2.5 5 Zinc 174 mg/kg 05/30/15 20:51 7440-66-605/28/15 20:109.9 4.9 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:07 7440-36-0 N205/28/15 20:109.9 4.9 100 Arsenic ND mg/kg 05/29/15 12:07 7440-38-205/28/15 20:109.9 4.9 100 Cadmium ND mg/kg 05/29/15 12:07 7440-43-905/28/15 20:101.2 0.59 100 Cobalt 7.4J mg/kg 05/29/15 12:07 7440-48-405/28/15 20:109.9 4.9 100 Lead 8.0J mg/kg 05/29/15 12:07 7439-92-105/28/15 20:109.9 4.9 100 Selenium ND mg/kg 05/29/15 12:07 7782-49-205/28/15 20:109.9 4.9 100 Thallium ND mg/kg 05/29/15 12:07 7440-28-005/28/15 20:109.9 4.9 100 Vanadium 33.6 mg/kg 05/29/15 12:07 7440-62-205/28/15 20:109.9 4.9 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0096J mg/kg 05/30/15 13:41 7439-97-605/28/15 21:300.017 0.0087 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 52.7 %05/29/15 10:130.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.6 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 16:55 16887-00-6 D35172585 Sulfate ND mg/kg 05/20/15 16:55 14808-79-8 D35172585 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 16:55 14797-55-8 H351.7 25.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 59 38 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014548 Lab ID:92250058002 Collected:05/13/15 16:05 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 26100 mg/kg 06/05/15 10:03 7440-44-012606291 Total Organic Carbon 19800 mg/kg 06/05/15 10:10 7440-44-012606291 Total Organic Carbon 26300 mg/kg 06/05/15 10:15 7440-44-012606291 Total Organic Carbon 21700 mg/kg 06/05/15 10:21 7440-44-012606301 Mean Total Organic Carbon 23500 mg/kg 06/05/15 10:03 7440-44-012606291 Surrogates RSD%13.8 %06/05/15 10:031 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 59 39 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014549 Lab ID:92250058003 Collected:05/13/15 17:05 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 2900 mg/kg 05/30/15 20:56 7429-90-505/28/15 20:1043.6 21.8 5 Barium 179 mg/kg 05/30/15 20:56 7440-39-305/28/15 20:104.4 2.2 5 Beryllium 0.70 mg/kg 05/30/15 20:56 7440-41-705/28/15 20:100.44 0.22 5 Boron ND mg/kg 05/30/15 20:56 7440-42-805/28/15 20:1021.8 10.9 5 Calcium 1280 mg/kg 05/30/15 20:56 7440-70-205/28/15 20:102181095 Chromium 4.5 mg/kg 05/30/15 20:56 7440-47-305/28/15 20:102.2 1.1 5 Copper 4.9 mg/kg 05/30/15 20:56 7440-50-805/28/15 20:102.2 1.1 5 Iron 10700 mg/kg 05/30/15 20:56 7439-89-605/28/15 20:1017.5 8.7 5 Magnesium 656 mg/kg 05/30/15 20:56 7439-95-405/28/15 20:102181095 Manganese 7090 mg/kg 06/01/15 19:57 7439-96-5 D405/28/15 20:1010.9 5.5 25 Molybdenum ND mg/kg 05/30/15 20:56 7439-98-705/28/15 20:104.4 2.2 5 Nickel 4.8 mg/kg 05/30/15 20:56 7440-02-005/28/15 20:102.2 1.1 5 Potassium 310J mg/kg 05/30/15 20:56 7440-09-705/28/15 20:104362185 Sodium ND mg/kg 05/30/15 20:56 7440-23-505/28/15 20:104362185 Strontium 29.2 mg/kg 05/30/15 20:56 7440-24-605/28/15 20:104.4 2.2 5 Zinc 12.8 mg/kg 05/30/15 20:56 7440-66-605/28/15 20:108.7 4.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:10 7440-36-0 N205/28/15 20:108.7 4.4 100 Arsenic ND mg/kg 05/29/15 12:10 7440-38-205/28/15 20:108.7 4.4 100 Cadmium ND mg/kg 05/29/15 12:10 7440-43-905/28/15 20:101.0 0.52 100 Cobalt 40.6 mg/kg 05/29/15 12:10 7440-48-405/28/15 20:108.7 4.4 100 Lead 4.9J mg/kg 05/29/15 12:10 7439-92-105/28/15 20:108.7 4.4 100 Selenium ND mg/kg 05/29/15 12:10 7782-49-205/28/15 20:108.7 4.4 100 Thallium ND mg/kg 05/29/15 12:10 7440-28-005/28/15 20:108.7 4.4 100 Vanadium 7.3J mg/kg 05/29/15 12:10 7440-62-205/28/15 20:108.7 4.4 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.010J mg/kg 05/30/15 13:44 7439-97-605/28/15 21:300.014 0.0069 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 43.5 %05/29/15 10:140.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.8 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 17:16 16887-00-6 D34352185 Sulfate ND mg/kg 05/20/15 17:16 14808-79-8 D34352185 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 17:16 14797-55-8 H343.5 21.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 59 40 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014549 Lab ID:92250058003 Collected:05/13/15 17:05 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 3100 mg/kg 06/05/15 11:14 7440-44-010705341 Total Organic Carbon 2960 mg/kg 06/05/15 11:21 7440-44-010605301 Total Organic Carbon 2930 mg/kg 06/05/15 11:26 7440-44-010505271 Total Organic Carbon 5040 mg/kg 06/05/15 11:33 7440-44-010505271 Mean Total Organic Carbon 3510 mg/kg 06/05/15 11:14 7440-44-010605301 Surrogates RSD%29.1 %06/05/15 11:141 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 59 41 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014550 Lab ID:92250058004 Collected:05/13/15 12:50 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7350 mg/kg 05/30/15 21:00 7429-90-505/28/15 20:1055.3 27.7 5 Barium 98.2 mg/kg 05/30/15 21:00 7440-39-305/28/15 20:105.5 2.8 5 Beryllium 0.29J mg/kg 05/30/15 21:00 7440-41-705/28/15 20:100.55 0.28 5 Boron ND mg/kg 05/30/15 21:00 7440-42-805/28/15 20:1027.7 13.8 5 Calcium 1060 mg/kg 05/30/15 21:00 7440-70-205/28/15 20:102771385 Chromium 13.9 mg/kg 05/30/15 21:00 7440-47-305/28/15 20:102.8 1.4 5 Copper 9.5 mg/kg 05/30/15 21:00 7440-50-805/28/15 20:102.8 1.4 5 Iron 11400 mg/kg 05/30/15 21:00 7439-89-605/28/15 20:1022.1 11.1 5 Magnesium 2170 mg/kg 05/30/15 21:00 7439-95-405/28/15 20:102771385 Manganese 383 mg/kg 05/30/15 21:00 7439-96-505/28/15 20:102.8 1.4 5 Molybdenum ND mg/kg 05/30/15 21:00 7439-98-705/28/15 20:105.5 2.8 5 Nickel 5.0 mg/kg 05/30/15 21:00 7440-02-005/28/15 20:102.8 1.4 5 Potassium 952 mg/kg 05/30/15 21:00 7440-09-705/28/15 20:105532775 Sodium ND mg/kg 05/30/15 21:00 7440-23-505/28/15 20:105532775 Strontium 16.3 mg/kg 05/30/15 21:00 7440-24-605/28/15 20:105.5 2.8 5 Zinc 31.4 mg/kg 05/30/15 21:00 7440-66-605/28/15 20:1011.1 5.5 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:12 7440-36-0 N205/28/15 20:1011.1 5.5 100 Arsenic ND mg/kg 05/29/15 12:12 7440-38-205/28/15 20:1011.1 5.5 100 Cadmium ND mg/kg 05/29/15 12:12 7440-43-905/28/15 20:101.3 0.66 100 Cobalt 6.1J mg/kg 05/29/15 12:12 7440-48-405/28/15 20:1011.1 5.5 100 Lead 7.4J mg/kg 05/29/15 12:12 7439-92-105/28/15 20:1011.1 5.5 100 Selenium ND mg/kg 05/29/15 12:12 7782-49-205/28/15 20:1011.1 5.5 100 Thallium ND mg/kg 05/29/15 12:12 7440-28-005/28/15 20:1011.1 5.5 100 Vanadium 19.2 mg/kg 05/29/15 12:12 7440-62-205/28/15 20:1011.1 5.5 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.027 mg/kg 05/30/15 13:46 7439-97-605/28/15 21:300.019 0.0093 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 56.5 %05/29/15 10:14 D60.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.0 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 17:38 16887-00-6 D35662835 Sulfate 399J mg/kg 05/20/15 17:38 14808-79-8 D35662835 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 17:38 14797-55-8 H356.6 28.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 59 42 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014550 Lab ID:92250058004 Collected:05/13/15 12:50 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 25900 mg/kg 06/05/15 11:38 7440-44-0530026501 Total Organic Carbon 27000 mg/kg 06/05/15 11:43 7440-44-0529026501 Total Organic Carbon 23900 mg/kg 06/05/15 11:49 7440-44-0529026401 Total Organic Carbon 22300 mg/kg 06/05/15 11:54 7440-44-0528026401 Mean Total Organic Carbon 24800 mg/kg 06/05/15 11:38 7440-44-0529026501 Surrogates RSD%8.5 %06/05/15 11:381 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 59 43 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014551 Lab ID:92250058005 Collected:05/12/15 16:25 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1120 mg/kg 05/30/15 21:04 7429-90-505/28/15 20:1071.8 35.9 5 Barium 271 mg/kg 05/30/15 21:04 7440-39-305/28/15 20:107.2 3.6 5 Beryllium ND mg/kg 05/30/15 21:04 7440-41-705/28/15 20:100.72 0.36 5 Boron 40.4 mg/kg 05/30/15 21:04 7440-42-805/28/15 20:1035.9 17.9 5 Calcium 1580 mg/kg 05/30/15 21:04 7440-70-205/28/15 20:103591795 Chromium 5.8 mg/kg 05/30/15 21:04 7440-47-305/28/15 20:103.6 1.8 5 Copper ND mg/kg 05/30/15 21:04 7440-50-805/28/15 20:103.6 1.8 5 Iron 247000 mg/kg 05/30/15 21:04 7439-89-605/28/15 20:1028.7 14.4 5 Magnesium 664 mg/kg 05/30/15 21:04 7439-95-405/28/15 20:103591795 Manganese 511 mg/kg 05/30/15 21:04 7439-96-505/28/15 20:103.6 1.8 5 Molybdenum ND mg/kg 05/30/15 21:04 7439-98-705/28/15 20:107.2 3.6 5 Nickel ND mg/kg 06/02/15 11:30 7440-02-0 D305/28/15 20:1014.4 7.2 20 Potassium ND mg/kg 05/30/15 21:04 7440-09-705/28/15 20:107183595 Sodium ND mg/kg 05/30/15 21:04 7440-23-505/28/15 20:107183595 Strontium 40.1 mg/kg 05/30/15 21:04 7440-24-605/28/15 20:107.2 3.6 5 Zinc 227 mg/kg 05/30/15 21:04 7440-66-605/28/15 20:1014.4 7.2 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:15 7440-36-0 N205/28/15 20:1014.4 7.2 100 Arsenic 56.4 mg/kg 05/29/15 12:15 7440-38-205/28/15 20:1014.4 7.2 100 Cadmium ND mg/kg 05/29/15 12:15 7440-43-905/28/15 20:101.7 0.86 100 Cobalt ND mg/kg 05/29/15 12:15 7440-48-405/28/15 20:1014.4 7.2 100 Lead ND mg/kg 05/29/15 12:15 7439-92-105/28/15 20:1014.4 7.2 100 Selenium ND mg/kg 05/29/15 12:15 7782-49-205/28/15 20:1014.4 7.2 100 Thallium ND mg/kg 05/29/15 12:15 7440-28-005/28/15 20:1014.4 7.2 100 Vanadium ND mg/kg 05/29/15 12:15 7440-62-205/28/15 20:1014.4 7.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/30/15 13:52 7439-97-605/28/15 21:300.024 0.012 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 65.5 %05/29/15 10:140.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.4 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 17:59 16887-00-6 D37063535 Sulfate ND mg/kg 05/20/15 17:59 14808-79-8 D37063535 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 17:59 14797-55-8 H370.6 35.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 59 44 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014551 Lab ID:92250058005 Collected:05/12/15 16:25 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 19000 mg/kg 06/03/15 09:13 7440-44-017608781 Total Organic Carbon 20900 mg/kg 06/03/15 09:18 7440-44-017308651 Total Organic Carbon 19100 mg/kg 06/03/15 09:25 7440-44-017508771 Total Organic Carbon 14600 mg/kg 06/03/15 09:30 7440-44-017308671 Mean Total Organic Carbon 18400 mg/kg 06/03/15 09:13 7440-44-017408721 Surrogates RSD%14.6 %06/03/15 09:131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 59 45 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014552 Lab ID:92250058006 Collected:05/13/15 11:45 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 6760 mg/kg 05/30/15 21:08 7429-90-505/28/15 20:1035.6 17.8 5 Barium 53.1 mg/kg 05/30/15 21:08 7440-39-305/28/15 20:103.6 1.8 5 Beryllium 0.38 mg/kg 05/30/15 21:08 7440-41-705/28/15 20:100.36 0.18 5 Boron ND mg/kg 05/30/15 21:08 7440-42-805/28/15 20:1017.8 8.9 5 Calcium 763 mg/kg 05/30/15 21:08 7440-70-205/28/15 20:1017888.9 5 Chromium 13.1 mg/kg 05/30/15 21:08 7440-47-305/28/15 20:101.8 0.89 5 Copper 10.4 mg/kg 05/30/15 21:08 7440-50-805/28/15 20:101.8 0.89 5 Iron 9660 mg/kg 05/30/15 21:08 7439-89-605/28/15 20:1014.2 7.1 5 Magnesium 3070 mg/kg 05/30/15 21:08 7439-95-405/28/15 20:1017888.9 5 Manganese 186 mg/kg 05/30/15 21:08 7439-96-505/28/15 20:101.8 0.89 5 Molybdenum ND mg/kg 05/30/15 21:08 7439-98-705/28/15 20:103.6 1.8 5 Nickel 5.2 mg/kg 05/30/15 21:08 7440-02-005/28/15 20:101.8 0.89 5 Potassium 1590 mg/kg 05/30/15 21:08 7440-09-705/28/15 20:103561785 Sodium ND mg/kg 05/30/15 21:08 7440-23-505/28/15 20:103561785 Strontium 10.3 mg/kg 05/30/15 21:08 7440-24-605/28/15 20:103.6 1.8 5 Zinc 39.6 mg/kg 05/30/15 21:08 7440-66-605/28/15 20:107.1 3.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:18 7440-36-0 N205/28/15 20:107.1 3.6 100 Arsenic ND mg/kg 05/29/15 12:18 7440-38-205/28/15 20:107.1 3.6 100 Cadmium ND mg/kg 05/29/15 12:18 7440-43-905/28/15 20:100.85 0.43 100 Cobalt 4.5J mg/kg 05/29/15 12:18 7440-48-405/28/15 20:107.1 3.6 100 Lead 3.6J mg/kg 05/29/15 12:18 7439-92-105/28/15 20:107.1 3.6 100 Selenium ND mg/kg 05/29/15 12:18 7782-49-205/28/15 20:107.1 3.6 100 Thallium ND mg/kg 05/29/15 12:18 7440-28-005/28/15 20:107.1 3.6 100 Vanadium 16.5 mg/kg 05/29/15 12:18 7440-62-205/28/15 20:107.1 3.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0065J mg/kg 05/30/15 13:54 7439-97-605/28/15 21:300.011 0.0054 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 30.2 %05/29/15 10:140.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.3 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 19:03 16887-00-6 D33491755 Sulfate ND mg/kg 05/20/15 19:03 14808-79-8 D33491755 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 19:03 14797-55-8 H334.9 17.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 59 46 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014552 Lab ID:92250058006 Collected:05/13/15 11:45 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 4000 mg/kg 06/05/15 12:13 7440-44-08604301 Total Organic Carbon 4430 mg/kg 06/05/15 12:19 7440-44-08554281 Total Organic Carbon 3640 mg/kg 06/05/15 12:24 7440-44-08574291 Total Organic Carbon 3000 mg/kg 06/05/15 12:30 7440-44-08624311 Mean Total Organic Carbon 3770 mg/kg 06/05/15 12:13 7440-44-08594291 Surrogates RSD%16.1 %06/05/15 12:131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 59 47 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014553 Lab ID:92250058007 Collected:05/13/15 10:30 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 6190 mg/kg 05/30/15 21:12 7429-90-505/28/15 20:1060.1 30.1 5 Barium 164 mg/kg 05/30/15 21:12 7440-39-305/28/15 20:106.0 3.0 5 Beryllium 0.33J mg/kg 05/30/15 21:12 7440-41-705/28/15 20:100.60 0.30 5 Boron 16.9J mg/kg 05/30/15 21:12 7440-42-805/28/15 20:1030.1 15.0 5 Calcium 2100 mg/kg 05/30/15 21:12 7440-70-205/28/15 20:103011505 Chromium 15.4 mg/kg 05/30/15 21:12 7440-47-305/28/15 20:103.0 1.5 5 Copper 12.3 mg/kg 05/30/15 21:12 7440-50-805/28/15 20:103.0 1.5 5 Iron 101000 mg/kg 05/30/15 21:12 7439-89-605/28/15 20:1024.1 12.0 5 Magnesium 3250 mg/kg 05/30/15 21:12 7439-95-405/28/15 20:103011505 Manganese 2400 mg/kg 05/30/15 21:12 7439-96-505/28/15 20:103.0 1.5 5 Molybdenum ND mg/kg 05/30/15 21:12 7439-98-705/28/15 20:106.0 3.0 5 Nickel 3.2 mg/kg 05/30/15 21:12 7440-02-005/28/15 20:103.0 1.5 5 Potassium 1390 mg/kg 05/30/15 21:12 7440-09-705/28/15 20:106013015 Sodium ND mg/kg 05/30/15 21:12 7440-23-505/28/15 20:106013015 Strontium 33.6 mg/kg 05/30/15 21:12 7440-24-605/28/15 20:106.0 3.0 5 Zinc 26.6 mg/kg 05/30/15 21:12 7440-66-605/28/15 20:1012.0 6.0 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:20 7440-36-0 N205/28/15 20:1012.0 6.0 100 Arsenic 14.1 mg/kg 05/29/15 12:20 7440-38-205/28/15 20:1012.0 6.0 100 Cadmium ND mg/kg 05/29/15 12:20 7440-43-905/28/15 20:101.4 0.72 100 Cobalt 14.0 mg/kg 05/29/15 12:20 7440-48-405/28/15 20:1012.0 6.0 100 Lead ND mg/kg 05/29/15 12:20 7439-92-105/28/15 20:1012.0 6.0 100 Selenium ND mg/kg 05/29/15 12:20 7782-49-205/28/15 20:1012.0 6.0 100 Thallium ND mg/kg 05/29/15 12:20 7440-28-005/28/15 20:1012.0 6.0 100 Vanadium 22.3 mg/kg 05/29/15 12:20 7440-62-205/28/15 20:1012.0 6.0 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/30/15 13:57 7439-97-605/28/15 21:300.018 0.0092 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 57.0 %05/29/15 10:140.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.9 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 19:25 16887-00-6 D35852935 Sulfate ND mg/kg 05/20/15 19:25 14808-79-8 D35852935 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 19:25 14797-55-8 H358.5 29.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 59 48 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014553 Lab ID:92250058007 Collected:05/13/15 10:30 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 10700 mg/kg 06/05/15 12:35 7440-44-014107031 Total Organic Carbon 12400 mg/kg 06/05/15 12:42 7440-44-013906971 Total Organic Carbon 14100 mg/kg 06/05/15 12:47 7440-44-014107031 Total Organic Carbon 14400 mg/kg 06/05/15 12:53 7440-44-013906951 Mean Total Organic Carbon 12900 mg/kg 06/05/15 12:35 7440-44-014006991 Surrogates RSD%13.1 %06/05/15 12:351 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 59 49 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014554 Lab ID:92250058008 Collected:05/13/15 11:05 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 2170 mg/kg 05/30/15 21:16 7429-90-505/28/15 20:1031.6 15.8 5 Barium 31.8 mg/kg 05/30/15 21:16 7440-39-305/28/15 20:103.2 1.6 5 Beryllium 0.21J mg/kg 05/30/15 21:16 7440-41-705/28/15 20:100.32 0.16 5 Boron ND mg/kg 05/30/15 21:16 7440-42-805/28/15 20:1015.8 7.9 5 Calcium 507 mg/kg 05/30/15 21:16 7440-70-205/28/15 20:1015879.0 5 Chromium 3.4 mg/kg 05/30/15 21:16 7440-47-305/28/15 20:101.6 0.79 5 Copper 4.8 mg/kg 05/30/15 21:16 7440-50-805/28/15 20:101.6 0.79 5 Iron 12700 mg/kg 05/30/15 21:16 7439-89-605/28/15 20:1012.6 6.3 5 Magnesium 1110 mg/kg 05/30/15 21:16 7439-95-405/28/15 20:1015879.0 5 Manganese 427 mg/kg 05/30/15 21:16 7439-96-505/28/15 20:101.6 0.79 5 Molybdenum ND mg/kg 05/30/15 21:16 7439-98-705/28/15 20:103.2 1.6 5 Nickel 0.96J mg/kg 05/30/15 21:16 7440-02-005/28/15 20:101.6 0.79 5 Potassium 471 mg/kg 05/30/15 21:16 7440-09-705/28/15 20:103161585 Sodium ND mg/kg 05/30/15 21:16 7440-23-505/28/15 20:103161585 Strontium 5.3 mg/kg 05/30/15 21:16 7440-24-605/28/15 20:103.2 1.6 5 Zinc 10.7 mg/kg 05/30/15 21:16 7440-66-605/28/15 20:106.3 3.2 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:23 7440-36-0 N205/28/15 20:106.3 3.2 100 Arsenic ND mg/kg 05/29/15 12:23 7440-38-205/28/15 20:106.3 3.2 100 Cadmium ND mg/kg 05/29/15 12:23 7440-43-905/28/15 20:100.76 0.38 100 Cobalt 4.7J mg/kg 05/29/15 12:23 7440-48-405/28/15 20:106.3 3.2 100 Lead ND mg/kg 05/29/15 12:23 7439-92-105/28/15 20:106.3 3.2 100 Selenium ND mg/kg 05/29/15 12:23 7782-49-205/28/15 20:106.3 3.2 100 Thallium ND mg/kg 05/29/15 12:23 7440-28-005/28/15 20:106.3 3.2 100 Vanadium 5.8J mg/kg 05/29/15 12:23 7440-62-205/28/15 20:106.3 3.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/30/15 13:59 7439-97-605/28/15 21:300.0097 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 18.9 %05/29/15 10:140.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.6 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 19:46 16887-00-6 D33121565 Sulfate ND mg/kg 05/20/15 19:46 14808-79-8 D33121565 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 19:46 14797-55-8 H331.2 15.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 59 50 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014554 Lab ID:92250058008 Collected:05/13/15 11:05 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1060 mg/kg 06/05/15 12:59 7440-44-07363681 Total Organic Carbon 1020 mg/kg 06/05/15 13:05 7440-44-07353671 Total Organic Carbon 1060 mg/kg 06/05/15 13:11 7440-44-07453731 Total Organic Carbon 1000 mg/kg 06/05/15 13:17 7440-44-07403701 Mean Total Organic Carbon 1030 mg/kg 06/05/15 12:59 7440-44-07393691 Surrogates RSD%2.8 %06/05/15 12:591 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 59 51 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014555 Lab ID:92250058009 Collected:05/12/15 14:35 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 5030 mg/kg 05/30/15 21:20 7429-90-505/28/15 20:1032.5 16.2 5 Barium 38.3 mg/kg 05/30/15 21:20 7440-39-305/28/15 20:103.2 1.6 5 Beryllium 0.44 mg/kg 05/30/15 21:20 7440-41-705/28/15 20:100.32 0.16 5 Boron ND mg/kg 05/30/15 21:20 7440-42-805/28/15 20:1016.2 8.1 5 Calcium 625 mg/kg 05/30/15 21:20 7440-70-205/28/15 20:1016281.2 5 Chromium 94.4 mg/kg 05/30/15 21:20 7440-47-305/28/15 20:101.6 0.81 5 Copper 5.4 mg/kg 05/30/15 21:20 7440-50-805/28/15 20:101.6 0.81 5 Iron 15600 mg/kg 05/30/15 21:20 7439-89-605/28/15 20:1013.0 6.5 5 Magnesium 1140 mg/kg 05/30/15 21:20 7439-95-405/28/15 20:1016281.2 5 Manganese 562 mg/kg 05/30/15 21:20 7439-96-505/28/15 20:101.6 0.81 5 Molybdenum ND mg/kg 05/30/15 21:20 7439-98-705/28/15 20:103.2 1.6 5 Nickel 2.8 mg/kg 05/30/15 21:20 7440-02-005/28/15 20:101.6 0.81 5 Potassium 342 mg/kg 05/30/15 21:20 7440-09-705/28/15 20:103251625 Sodium ND mg/kg 05/30/15 21:20 7440-23-505/28/15 20:103251625 Strontium 10 mg/kg 05/30/15 21:20 7440-24-605/28/15 20:103.2 1.6 5 Zinc 12.6 mg/kg 05/30/15 21:20 7440-66-605/28/15 20:106.5 3.2 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:25 7440-36-0 N205/28/15 20:106.5 3.2 100 Arsenic ND mg/kg 05/29/15 12:25 7440-38-205/28/15 20:106.5 3.2 100 Cadmium ND mg/kg 05/29/15 12:25 7440-43-905/28/15 20:100.78 0.39 100 Cobalt 7.4 mg/kg 05/29/15 12:25 7440-48-405/28/15 20:106.5 3.2 100 Lead 14.0 mg/kg 05/29/15 12:25 7439-92-105/28/15 20:106.5 3.2 100 Selenium ND mg/kg 05/29/15 12:25 7782-49-205/28/15 20:106.5 3.2 100 Thallium ND mg/kg 05/29/15 12:25 7440-28-005/28/15 20:106.5 3.2 100 Vanadium 42.5 mg/kg 05/29/15 12:25 7440-62-205/28/15 20:106.5 3.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/30/15 14:01 7439-97-605/28/15 21:300.0099 0.0049 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.5 %05/29/15 10:150.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.1 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 20:08 16887-00-6 D33151575 Sulfate ND mg/kg 05/20/15 20:08 14808-79-8 D33151575 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 20:08 14797-55-8 H331.5 15.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 59 52 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014555 Lab ID:92250058009 Collected:05/12/15 14:35 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1280 mg/kg 06/03/15 10:22 7440-44-07483741 Total Organic Carbon 1320 mg/kg 06/03/15 10:28 7440-44-07383691 Total Organic Carbon 1440 mg/kg 06/03/15 10:33 7440-44-07523761 Total Organic Carbon 1120 mg/kg 06/03/15 10:39 7440-44-07483741 Mean Total Organic Carbon 1290 mg/kg 06/03/15 10:22 7440-44-07473731 Surrogates RSD%10.2 %06/03/15 10:221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 59 53 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014556 Lab ID:92250058010 Collected:05/13/15 14:15 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 2610 mg/kg 05/30/15 21:24 7429-90-505/28/15 20:1035.6 17.8 5 Barium 23.7 mg/kg 05/30/15 21:24 7440-39-305/28/15 20:103.6 1.8 5 Beryllium 0.18J mg/kg 05/30/15 21:24 7440-41-705/28/15 20:100.36 0.18 5 Boron ND mg/kg 05/30/15 21:24 7440-42-805/28/15 20:1017.8 8.9 5 Calcium 335 mg/kg 05/30/15 21:24 7440-70-205/28/15 20:1017888.9 5 Chromium 17.3 mg/kg 05/30/15 21:24 7440-47-305/28/15 20:101.8 0.89 5 Copper 3.3 mg/kg 05/30/15 21:24 7440-50-805/28/15 20:101.8 0.89 5 Iron 7100 mg/kg 05/30/15 21:24 7439-89-605/28/15 20:1014.2 7.1 5 Magnesium 937 mg/kg 05/30/15 21:24 7439-95-405/28/15 20:1017888.9 5 Manganese 122 mg/kg 05/30/15 21:24 7439-96-505/28/15 20:101.8 0.89 5 Molybdenum ND mg/kg 05/30/15 21:24 7439-98-705/28/15 20:103.6 1.8 5 Nickel 2.4 mg/kg 05/30/15 21:24 7440-02-005/28/15 20:101.8 0.89 5 Potassium 470 mg/kg 05/30/15 21:24 7440-09-705/28/15 20:103561785 Sodium ND mg/kg 05/30/15 21:24 7440-23-505/28/15 20:103561785 Strontium 3.2J mg/kg 05/30/15 21:24 7440-24-605/28/15 20:103.6 1.8 5 Zinc 14.8 mg/kg 05/30/15 21:24 7440-66-605/28/15 20:107.1 3.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/29/15 12:28 7440-36-0 N205/28/15 20:107.1 3.6 100 Arsenic ND mg/kg 05/29/15 12:28 7440-38-205/28/15 20:107.1 3.6 100 Cadmium ND mg/kg 05/29/15 12:28 7440-43-905/28/15 20:100.85 0.43 100 Cobalt ND mg/kg 05/29/15 12:28 7440-48-405/28/15 20:107.1 3.6 100 Lead 3.7J mg/kg 05/29/15 12:28 7439-92-105/28/15 20:107.1 3.6 100 Selenium ND mg/kg 05/29/15 12:28 7782-49-205/28/15 20:107.1 3.6 100 Thallium ND mg/kg 05/29/15 12:28 7440-28-005/28/15 20:107.1 3.6 100 Vanadium 15.1 mg/kg 05/29/15 12:28 7440-62-205/28/15 20:107.1 3.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/30/15 14:03 7439-97-605/28/15 21:300.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.2 %05/29/15 10:150.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.4 Std. Units 05/24/15 15:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/20/15 20:29 16887-00-6 D33331675 Sulfate ND mg/kg 05/20/15 20:29 14808-79-8 D33331675 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/20/15 20:29 14797-55-8 H333.3 16.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 59 54 of 101 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92250058 J15050361 Sample:2015014556 Lab ID:92250058010 Collected:05/13/15 14:15 Received:05/14/15 17:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 7080 mg/kg 06/05/15 13:22 7440-44-08184091 Total Organic Carbon 5760 mg/kg 06/05/15 13:28 7440-44-08074031 Total Organic Carbon 4310 mg/kg 06/05/15 13:33 7440-44-08144071 Total Organic Carbon 3690 mg/kg 06/05/15 13:38 7440-44-08184091 Mean Total Organic Carbon 5210 mg/kg 06/05/15 13:22 7440-44-08144071 Surrogates RSD%29.1 %06/05/15 13:221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 59 55 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5780 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1226134 Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Matrix:Solid Analyzed Mercury mg/kg ND 0.0080 05/30/15 13:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1226135LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.074.081 91 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1226136MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245394022 1226137 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg H3.11 81 80-12086 1 20.1020.015 0.10 0.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 59 56 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24366 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1226121 Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Matrix:Solid Analyzed Aluminum mg/kg ND 5.1 05/30/15 20:03 Barium mg/kg ND 0.51 05/30/15 20:03 Beryllium mg/kg ND 0.051 05/30/15 20:03 Boron mg/kg ND 2.6 05/30/15 20:03 Calcium mg/kg ND 25.6 05/30/15 20:03 Chromium mg/kg ND 0.26 05/30/15 20:03 Copper mg/kg ND 0.26 05/30/15 20:03 Iron mg/kg ND 2.0 05/30/15 20:03 Magnesium mg/kg ND 25.6 05/30/15 20:03 Manganese mg/kg ND 0.26 05/30/15 20:03 Molybdenum mg/kg ND 0.51 05/30/15 20:03 Nickel mg/kg ND 0.26 05/30/15 20:03 Potassium mg/kg ND 51.2 05/30/15 20:03 Sodium mg/kg ND 51.2 05/30/15 20:03 Strontium mg/kg ND 0.51 05/30/15 20:03 Zinc mg/kg ND 1.0 05/30/15 20:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1226122LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 131128 102 80-120 Barium mg/kg 13.012.8 102 80-120 Beryllium mg/kg 1.31.3 101 80-120 Boron mg/kg 125128 98 80-120 Calcium mg/kg 652641 102 80-120 Chromium mg/kg 12.312.8 96 80-120 Copper mg/kg 12.512.8 97 80-120 Iron mg/kg 128128 100 80-120 Magnesium mg/kg 626641 98 80-120 Manganese mg/kg 12.712.8 99 80-120 Molybdenum mg/kg 12.612.8 98 80-120 Nickel mg/kg 12.912.8 101 80-120 Potassium mg/kg 592641 92 80-120 Sodium mg/kg 634641 99 80-120 Strontium mg/kg 12.912.8 101 80-120 Zinc mg/kg 63.764.1 99 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 59 57 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1226123MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245394022 1226124 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1162382075-1254540 6 20161113001750018600 Barium mg/kg M116.2 148 75-125184 8 2016.140.0 64.0 69.6 Beryllium mg/kg 1.57 91 75-125100 6 201.570.60 2.1 2.2 Boron mg/kg M11624575-12550 8 20161ND75.1 81.3 Calcium mg/kg 812 87 75-12595 8 20804ND707766 Chromium mg/kg M116.2 115 75-125140 12 2016.111.7 30.4 34.2 Copper mg/kg M116.2 133 75-125146 5 2016.115.5 37.2 39.1 Iron mg/kg M1,R1162376075-1258380 22 20161240003010037500 Magnesium mg/kg 812 100 75-125113 8 2080430211101210 Manganese mg/kg M116.2 88 75-125148 18 2016.132.5 46.7 56.2 Molybdenum mg/kg M116.2 67 75-12575 9 2016.1ND 12.0 13.1 Nickel mg/kg 16.2 94 75-125102 6 2016.11.8 17.2 18.3 Potassium mg/kg 812 86 75-12596 8 20804227J925997 Sodium mg/kg 812 86 75-12594 8 20804ND699755 Strontium mg/kg 16.2 97 75-125108 9 2016.1ND 16.5 18.2 Zinc mg/kg 81.2 96 75-125107 8 2080.415.5 93.3 101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 59 58 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24367 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1226125 Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N205/29/15 11:41 Arsenic mg/kg ND 0.051 05/29/15 11:41 Cadmium mg/kg ND 0.0061 05/29/15 11:41 Cobalt mg/kg ND 0.051 05/29/15 11:41 Lead mg/kg ND 0.051 05/29/15 11:41 Selenium mg/kg ND 0.051 05/29/15 11:41 Thallium mg/kg ND 0.051 05/29/15 11:41 Vanadium mg/kg ND 0.051 05/29/15 11:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1226126LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.4 N22.6 92 80-120 Arsenic mg/kg 2.42.6 95 80-120 Cadmium mg/kg 0.25.26 100 80-120 Cobalt mg/kg 2.42.6 95 80-120 Lead mg/kg 2.32.6 92 80-120 Selenium mg/kg 2.42.6 94 80-120 Thallium mg/kg 2.42.6 96 80-120 Vanadium mg/kg 2.42.6 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1226127MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245394022 1226128 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N23.14 16 75-12522 203.27ND ND ND Arsenic mg/kg M63.14 70 75-12597 203.273.5J 5.7J 6.7 Cadmium mg/kg M6.314 84 75-12570 20.327ND ND ND Cobalt mg/kg 3.14 89 75-125102 203.27ND 4.6J 5.0J Lead mg/kg M63.14 96 75-125151 11 203.2712.8 15.9 17.7 Selenium mg/kg M63.14 31 75-12519 203.273.5J 4.5J 4.1J Thallium mg/kg M63.14 65 75-12571 203.27ND ND ND Vanadium mg/kg M63.14 157 75-125318 15 203.2728.7 33.7 39.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 59 59 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3601 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Dup Result Max RPD QualifiersRPDResult 92248729001 1226807SAMPLE DUPLICATE: Percent Moisture %31.7 4 1032.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249101012 1226808SAMPLE DUPLICATE: Percent Moisture %18.8 8 1017.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250205002 1226809SAMPLE DUPLICATE: Percent Moisture %24.1 D6611012.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250058004 1226810SAMPLE DUPLICATE: Percent Moisture %47.1 D6181056.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250183009 1226811SAMPLE DUPLICATE: Percent Moisture %20.2 D6121017.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250202004 1226812SAMPLE DUPLICATE: Percent Moisture %19.8 2 1019.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 35189696001 1226813SAMPLE DUPLICATE: Percent Moisture %18.1 1 1017.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 59 60 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 35190238001 1226814SAMPLE DUPLICATE: Percent Moisture %49.4 2 1048.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 59 61 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37585 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249710014 1464536SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.2 D61106.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250058005 1464537SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.4 0 106.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 59 62 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46584 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1219539 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 50.2 05/20/15 14:25 Sulfate mg/kg ND 50.2 05/20/15 14:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1219540LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 470490 96 80-120 Sulfate mg/kg 461490 94 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1219542MATRIX SPIKE SAMPLE: MSSpike Result 92250058001 Chloride mg/kg 623 M16807380-120ND Sulfate mg/kg 648 M16807980-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92250058001 1219541SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 59 63 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46585 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058005, 92250058006, 92250058007, 92250058008, 92250058009, 92250058010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1219545 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 05/20/15 14:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1219546LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 47.249 96 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1219548MATRIX SPIKE SAMPLE: MSSpike Result 92250058001 Nitrate as N mg/kg 60.4 H3688980-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92250058001 1219547SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 59 64 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28805 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92250058005, 92250058009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1167968 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/03/15 06:27 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1167969LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 105000120000 87 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1167970MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249681006 1167971 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6500 98 50-15096 1 306490126076007510 Parameter Units MS Result % Rec Limits Qual% RecConc. 1167972MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250058005 1167973 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 17400 110 50-150109 1 3017400184003750037300 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 59 65 of 101 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92250058 J15050361 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28847 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92250058001, 92250058002, 92250058003, 92250058004, 92250058006, 92250058007, 92250058008, 92250058010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1169294 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/05/15 08:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1169295LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 111000120000 92 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1169296MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250058001 1169297 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 8210 86 50-15094 7 308170113082108830 Parameter Units MS Result % Rec Limits Qual% RecConc. 1169298MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250058002 1169299 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 12700 119 50-150145 8 3012700235003860041800 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 59 66 of 101 #=QL# QUALIFIERS Pace Project No.: Project: 92250058 J15050361 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14887 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICPM/9867 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Sample was diluted due to the presence of high levels of target analytes.D4 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 59 67 of 101 #=QL# QUALIFIERS Pace Project No.: Project: 92250058 J15050361 ANALYTE QUALIFIERS RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 59 68 of 101 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92250058001 MPRP/24366 ICP/148872015014547EPA 3050 EPA 6010 92250058002 MPRP/24366 ICP/148872015014548EPA 3050 EPA 6010 92250058003 MPRP/24366 ICP/148872015014549EPA 3050 EPA 6010 92250058004 MPRP/24366 ICP/148872015014550EPA 3050 EPA 6010 92250058005 MPRP/24366 ICP/148872015014551EPA 3050 EPA 6010 92250058006 MPRP/24366 ICP/148872015014552EPA 3050 EPA 6010 92250058007 MPRP/24366 ICP/148872015014553EPA 3050 EPA 6010 92250058008 MPRP/24366 ICP/148872015014554EPA 3050 EPA 6010 92250058009 MPRP/24366 ICP/148872015014555EPA 3050 EPA 6010 92250058010 MPRP/24366 ICP/148872015014556EPA 3050 EPA 6010 92250058001 MPRP/24367 ICPM/98672015014547EPA 3050 EPA 6020 92250058002 MPRP/24367 ICPM/98672015014548EPA 3050 EPA 6020 92250058003 MPRP/24367 ICPM/98672015014549EPA 3050 EPA 6020 92250058004 MPRP/24367 ICPM/98672015014550EPA 3050 EPA 6020 92250058005 MPRP/24367 ICPM/98672015014551EPA 3050 EPA 6020 92250058006 MPRP/24367 ICPM/98672015014552EPA 3050 EPA 6020 92250058007 MPRP/24367 ICPM/98672015014553EPA 3050 EPA 6020 92250058008 MPRP/24367 ICPM/98672015014554EPA 3050 EPA 6020 92250058009 MPRP/24367 ICPM/98672015014555EPA 3050 EPA 6020 92250058010 MPRP/24367 ICPM/98672015014556EPA 3050 EPA 6020 92250058001 MERP/5780 MERC/57702015014547EPA 7471 EPA 7471 92250058002 MERP/5780 MERC/57702015014548EPA 7471 EPA 7471 92250058003 MERP/5780 MERC/57702015014549EPA 7471 EPA 7471 92250058004 MERP/5780 MERC/57702015014550EPA 7471 EPA 7471 92250058005 MERP/5780 MERC/57702015014551EPA 7471 EPA 7471 92250058006 MERP/5780 MERC/57702015014552EPA 7471 EPA 7471 92250058007 MERP/5780 MERC/57702015014553EPA 7471 EPA 7471 92250058008 MERP/5780 MERC/57702015014554EPA 7471 EPA 7471 92250058009 MERP/5780 MERC/57702015014555EPA 7471 EPA 7471 92250058010 MERP/5780 MERC/57702015014556EPA 7471 EPA 7471 92250058001 PMST/36012015014547ASTM D2974-87 92250058002 PMST/36012015014548ASTM D2974-87 92250058003 PMST/36012015014549ASTM D2974-87 92250058004 PMST/36012015014550ASTM D2974-87 92250058005 PMST/36012015014551ASTM D2974-87 92250058006 PMST/36012015014552ASTM D2974-87 92250058007 PMST/36012015014553ASTM D2974-87 92250058008 PMST/36012015014554ASTM D2974-87 92250058009 PMST/36012015014555ASTM D2974-87 92250058010 PMST/36012015014556ASTM D2974-87 92250058001 WET/375852015014547EPA 9045 92250058002 WET/375852015014548EPA 9045 92250058003 WET/375852015014549EPA 9045 92250058004 WET/375852015014550EPA 9045 92250058005 WET/375852015014551EPA 9045 92250058006 WET/375852015014552EPA 9045 92250058007 WET/375852015014553EPA 9045 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 59 69 of 101 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92250058008 WET/375852015014554EPA 9045 92250058009 WET/375852015014555EPA 9045 92250058010 WET/375852015014556EPA 9045 92250058001 WETA/465842015014547EPA 9056 92250058002 WETA/465842015014548EPA 9056 92250058003 WETA/465842015014549EPA 9056 92250058004 WETA/465842015014550EPA 9056 92250058005 WETA/465842015014551EPA 9056 92250058006 WETA/465842015014552EPA 9056 92250058007 WETA/465842015014553EPA 9056 92250058008 WETA/465842015014554EPA 9056 92250058009 WETA/465842015014555EPA 9056 92250058010 WETA/465842015014556EPA 9056 92250058001 WETA/465852015014547EPA 9056 92250058002 WETA/465852015014548EPA 9056 92250058003 WETA/465852015014549EPA 9056 92250058004 WETA/465852015014550EPA 9056 92250058005 WETA/465852015014551EPA 9056 92250058006 WETA/465852015014552EPA 9056 92250058007 WETA/465852015014553EPA 9056 92250058008 WETA/465852015014554EPA 9056 92250058009 WETA/465852015014555EPA 9056 92250058010 WETA/465852015014556EPA 9056 92250058001 WETA/288472015014547EPA 9060 92250058001 WETA/288502015014547EPA 9060 92250058002 WETA/288472015014548EPA 9060 92250058002 WETA/288502015014548EPA 9060 92250058003 WETA/288472015014549EPA 9060 92250058003 WETA/288502015014549EPA 9060 92250058004 WETA/288472015014550EPA 9060 92250058004 WETA/288502015014550EPA 9060 92250058005 WETA/288052015014551EPA 9060 92250058005 WETA/288082015014551EPA 9060 92250058006 WETA/288472015014552EPA 9060 92250058006 WETA/288502015014552EPA 9060 92250058007 WETA/288472015014553EPA 9060 92250058007 WETA/288502015014553EPA 9060 92250058008 WETA/288472015014554EPA 9060 92250058008 WETA/288502015014554EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 59 70 of 101 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92250058 J15050361 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92250058009 WETA/288052015014555EPA 9060 92250058009 WETA/288082015014555EPA 9060 92250058010 WETA/288472015014556EPA 9060 92250058010 WETA/288502015014556EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/08/2015 11:09 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 59 71 of 101 Page 59 of 59 72 of 101 June 10, 2015 LABORATORY REPORT NUMBER PROJECT ID Primary Data Review By Project Manager, AES 1505E38 Marge Galvin-Karr Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 J15050361 Chantelle Kanhai Project Manager, Access Analytical aamick@axs-inc.com Ashley Amick PLEASE NOTE: -Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. -AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Secondary Data Review By ATTENTION DATE CLIENT ANALYTICAL REPORT Page 1 of 16 73 of 101 Page 2 of 1674 of 101 Page 3 of 1675 of 101 10-Jun-15Date:Analytical Environmental Services, Inc. Project:J15050361 CLIENT:Duke Energy Lab Order:1505E38 CASE NARRATIVE REDOX POTENTIAL: 1505E38-001 228.6 mV 216.8 mV 202.1 Mv 1505E38-002 207.5 mV 211.0 mV 224.3 mV 1505E38-003 188.0 mV 198.8 mV 191.0 mV 1505E38-004 171.8 mV 188.5 mV 149.9 mV 1505E38-005 140.1 mV 125.7 mV 131.8 mV 1505E38-006 101.4 mV 96.7 mV 84.9 mV 1505E38-007 Page 1 of 2Page 4 of 16 76 of 101 Project:J15050361 CLIENT:Duke Energy Lab Order:1505E38 CASE NARRATIVE 103.8 mV 104.5 mV 106.5 mV 1505E38-008 54.3 mV 39.2 mV 40.7 mV 1505E38-009 79.8 mV 23.5 mV 31.7 mV 1505E38-010 198.8 mV 198.2 mV 196.3 mV Page 2 of 2Page 5 of 16 77 of 101 1505E38-001 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 3:20:00 PM S-02 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 6.2 1.0 meq/100g 207623 1 05/21/2015 22:57 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 6 of 16 78 of 101 1505E38-002 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 4:05:00 PM S-06 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 14 1.0 meq/100g 207623 1 05/21/2015 23:19 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 7 of 16 79 of 101 1505E38-003 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 5:05:00 PM S-08 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 7.2 1.0 meq/100g 207623 1 05/21/2015 23:22 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 8 of 16 80 of 101 1505E38-004 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 12:50:00 PM SW-CB2 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 13 1.0 meq/100g 207623 1 05/21/2015 23:26 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 9 of 16 81 of 101 1505E38-005 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/12/2015 4:25:00 PM S-01 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 8.9 1.0 meq/100g 207623 1 05/21/2015 23:30 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 10 of 16 82 of 101 1505E38-006 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 11:45:00 AM SW-CB1 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 6.2 1.0 meq/100g 207623 1 05/21/2015 23:33 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 11 of 16 83 of 101 1505E38-007 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 10:30:00 AM S-04 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 16 1.0 meq/100g 207623 1 05/21/2015 23:37 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 12 of 16 84 of 101 1505E38-008 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 11:05:00 AM S-02B Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 4.7 1.0 meq/100g 207623 1 05/21/2015 23:41 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 13 of 16 85 of 101 1505E38-009 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/12/2015 2:35:00 PM S-03 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 2.0 1.0 meq/100g 207623 1 05/21/2015 23:45 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 14 of 16 86 of 101 1505E38-010 10-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/13/2015 2:15:00 PM SW-REF 1 Matrix: Collection Date: Client Sample ID: J15050361 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 6.7 1.0 meq/100g 207623 1 05/21/2015 23:48 IO Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 15 of 16 87 of 101 Page 16 of 16 88 of 101 Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com May 27, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15050361) Dear Mr. Amick: Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 05/18/15. The correspondence indicated hydrometer testing for Samples S-02, S-06, S-08, SW-CB2, S-01, SW-CB1, S-04, S-02B, S-03, and SW-REF1. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Phillip A. Morrison, P.E. Laboratory Manager Geotechnical Department Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File RS/PM 89 of 101 90 of 101 91 of 101 92 of 101 93 of 101 94 of 101 95 of 101 96 of 101 97 of 101 98 of 101 99 of 101 100 of 101 101 of 101