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Home My WebLink AboutNC0038377_J15050212 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15050212 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/9/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 60 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015013898 MAYO STEAM 07-May-15 11:50 AM Erin Black SB-7-EB 2015013900 MAYO STEAM 07-May-15 12:20 PM Erin Black SB-7 (1.0-2.0) 2015013901 MAYO STEAM 07-May-15 12:45 PM Erin Black SB-7 (4.5-7.5) 3 Total Samples 2 of 60 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 60 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050212 2015013898 Collection Date: 07-May-15 11:50 AM Site:SB-7-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 60 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050212 2015013900 Collection Date: 07-May-15 12:20 PM Site:SB-7 (1.0-2.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 60 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050212 2015013901 Collection Date: 07-May-15 12:45 PM Site:SB-7 (4.5-7.5) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 60 #=CL# June 04, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92249061 92249061 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15050212 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 08, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 53 7 of 60 #=CP# CERTIFICATIONS Pace Project No.: Project: 92249061 J15050212 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 53 8 of 60 #=CP# CERTIFICATIONS Pace Project No.: Project: 92249061 J15050212 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 53 9 of 60 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92249061 J15050212 Lab ID Sample ID Matrix Date Collected Date Received 92249061001 2015013898 Water 05/07/15 11:50 05/08/15 11:55 92249061002 2015013900 Solid 05/07/15 12:20 05/08/15 11:55 92249061003 2015013901 Solid 05/07/15 12:45 05/08/15 11:55 92249061004 2015013900 SPLP Water 05/07/15 12:20 05/08/15 11:55 92249061005 2015013901 SPLP Water 05/07/15 12:45 05/08/15 11:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 53 10 of 60 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92249061 J15050212 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92249061001 2015013898 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM 92249061002 2015013900 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92249061003 2015013901 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92249061004 2015013900 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470A 1 PASI-MDM 92249061005 2015013901 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470A 1 PASI-MDM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 53 11 of 60 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92249061 J15050212 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92249061001 2015013898 Aluminum 20.5 ug/L 05/18/15 13:5510.0EPA 6020A Barium 0.35 ug/L 05/18/15 13:550.30EPA 6020A Calcium 337 ug/L 05/18/15 13:5540.0EPA 6020A Chromium 2.2 ug/L 05/18/15 13:550.50EPA 6020A Copper 0.67J ug/L 05/18/15 13:551.0EPA 6020A Iron 105 ug/L 05/18/15 13:5550.0EPA 6020A Magnesium 5.9J ug/L 05/18/15 13:5510.0EPA 6020A Manganese 1.3 ug/L 05/18/15 13:550.50EPA 6020A Molybdenum 19.3 ug/L 05/18/15 13:550.50EPA 6020A Nickel 0.35J ug/L 05/18/15 13:550.50EPA 6020A Potassium 48.1J ug/L 05/18/15 13:5550.0EPA 6020A Sodium 16.9J ug/L 05/18/15 13:5550.0EPA 6020A Strontium 0.68 ug/L 05/18/15 13:550.50EPA 6020A Zinc 2.5J ug/L 05/18/15 13:555.0EPA 6020A 92249061002 2015013900 Aluminum 9000 mg/kg 05/22/15 18:54 M129.1EPA 6010 Barium 68.8 mg/kg 05/22/15 18:54 M12.9EPA 6010 Beryllium 0.46 mg/kg 05/22/15 18:540.29EPA 6010 Calcium 301 mg/kg 05/22/15 18:54145EPA 6010 Chromium 11.4 mg/kg 05/22/15 18:541.5EPA 6010 Copper 7.7 mg/kg 05/22/15 18:541.5EPA 6010 Iron 9460 mg/kg 05/22/15 18:54 M111.6EPA 6010 Magnesium 1110 mg/kg 05/22/15 18:54145EPA 6010 Manganese 693 mg/kg 05/22/15 18:54 M11.5EPA 6010 Nickel 4.2 mg/kg 05/22/15 18:541.5EPA 6010 Potassium 534 mg/kg 05/22/15 18:54291EPA 6010 Strontium 5.7 mg/kg 05/22/15 18:542.9EPA 6010 Zinc 21.4 mg/kg 05/22/15 18:545.8EPA 6010 Cobalt 5.9 mg/kg 05/22/15 19:485.8EPA 6020 Lead 5.4J mg/kg 05/22/15 19:48 M65.8EPA 6020 Vanadium 17.6 mg/kg 05/22/15 19:48 M65.8EPA 6020 Mercury 0.037 mg/kg 05/21/15 13:020.0096EPA 7471 Percent Moisture 13.0 %05/20/15 10:340.10ASTM D2974-87 pH at 25 Degrees C 5.1 Std. Units 05/18/15 15:450.10EPA 9045 Sulfate 5.2 mg/L 05/22/15 18:08 B2.3EPA 300.0 Nitrogen, Nitrate 0.31 mg/L 05/28/15 20:31 H10.23EPA 353.2 Total Organic Carbon 1650 mg/kg 06/02/15 16:19686EPA 9060 Total Organic Carbon 1600 mg/kg 06/02/15 16:25694EPA 9060 Total Organic Carbon 1620 mg/kg 06/02/15 16:30694EPA 9060 Total Organic Carbon 1570 mg/kg 06/02/15 16:36690EPA 9060 Mean Total Organic Carbon 1610 mg/kg 06/02/15 16:19691EPA 9060 RSD%2.2 %06/02/15 16:19EPA 9060 92249061003 2015013901 Aluminum 2020 mg/kg 05/22/15 19:0630.0EPA 6010 Barium 15.5 mg/kg 05/22/15 19:063.0EPA 6010 Beryllium 0.21J mg/kg 05/22/15 19:060.30EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 53 12 of 60 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92249061 J15050212 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92249061003 2015013901 Calcium 154 mg/kg 05/22/15 19:06150EPA 6010 Chromium 8.2 mg/kg 05/22/15 19:061.5EPA 6010 Copper 4.4 mg/kg 05/22/15 19:061.5EPA 6010 Iron 6040 mg/kg 05/22/15 19:0612.0EPA 6010 Magnesium 387 mg/kg 05/22/15 19:06150EPA 6010 Manganese 226 mg/kg 05/22/15 19:061.5EPA 6010 Nickel 1.4J mg/kg 05/22/15 19:061.5EPA 6010 Potassium 266J mg/kg 05/22/15 19:06300EPA 6010 Strontium 2.9J mg/kg 05/22/15 19:063.0EPA 6010 Zinc 6.5 mg/kg 05/22/15 19:066.0EPA 6010 Vanadium 8.2 mg/kg 05/22/15 19:556.0EPA 6020 Mercury 0.011 mg/kg 05/21/15 13:090.0092EPA 7471 Percent Moisture 17.2 %05/20/15 10:340.10ASTM D2974-87 pH at 25 Degrees C 6.4 Std. Units 05/18/15 15:450.10EPA 9045 Sulfate 5.7 mg/L 05/22/15 18:21 B2.4EPA 300.0 Nitrogen, Nitrate 0.29 mg/L 05/28/15 20:33 H10.24EPA 353.2 Total Organic Carbon 922 mg/kg 06/02/15 16:54722EPA 9060 Total Organic Carbon 918 mg/kg 06/02/15 16:59722EPA 9060 Total Organic Carbon 963 mg/kg 06/02/15 17:05728EPA 9060 Total Organic Carbon 736 mg/kg 06/02/15 17:12723EPA 9060 Mean Total Organic Carbon 885 mg/kg 06/02/15 16:54724EPA 9060 RSD%11.4 %06/02/15 16:54EPA 9060 92249061004 2015013900 SPLP Aluminum 133 ug/L 05/28/15 18:0110.0EPA 6020A Barium 126 ug/L 05/28/15 18:010.30EPA 6020A Boron 77.5 ug/L 05/28/15 18:015.0EPA 6020A Calcium 870 ug/L 05/28/15 18:0140.0EPA 6020A Chromium 0.37J ug/L 05/28/15 18:010.50EPA 6020A Copper 0.85J ug/L 05/28/15 18:011.0EPA 6020A Iron 61.7 ug/L 05/28/15 18:0150.0EPA 6020A Lead 0.054J ug/L 05/28/15 18:010.10EPA 6020A Magnesium 270 ug/L 05/28/15 18:0110.0EPA 6020A Manganese 9.3 ug/L 05/28/15 18:010.50EPA 6020A Nickel 0.35J ug/L 05/28/15 18:010.50EPA 6020A Potassium 318 ug/L 05/28/15 18:0150.0EPA 6020A Sodium 1410 ug/L 05/28/15 18:0150.0EPA 6020A Strontium 16.8 ug/L 05/28/15 18:010.50EPA 6020A Zinc 60.6 ug/L 05/28/15 18:015.0EPA 6020A 92249061005 2015013901 SPLP Aluminum 18200 ug/L 05/28/15 18:2410.0EPA 6020A Arsenic 2.0 ug/L 05/28/15 18:240.50EPA 6020A Barium 252 ug/L 05/28/15 18:240.30EPA 6020A Beryllium 0.66 ug/L 05/28/15 18:240.20EPA 6020A Boron 63.7 ug/L 05/28/15 18:245.0EPA 6020A Cadmium 0.028J ug/L 05/28/15 18:240.080EPA 6020A Calcium 1890 ug/L 05/28/15 18:2440.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 53 13 of 60 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92249061 J15050212 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92249061005 2015013901 SPLP Chromium 19.9 ug/L 05/28/15 18:240.50EPA 6020A Cobalt 4.5 ug/L 05/28/15 18:240.50EPA 6020A Copper 15.3 ug/L 05/28/15 18:241.0EPA 6020A Iron 17300 ug/L 05/28/15 18:2450.0EPA 6020A Lead 5.7 ug/L 05/28/15 18:240.10EPA 6020A Magnesium 1920 ug/L 05/28/15 18:2410.0EPA 6020A Manganese 491 ug/L 05/29/15 08:012.5EPA 6020A Molybdenum 1.1 ug/L 05/28/15 18:240.50EPA 6020A Nickel 9.5 ug/L 05/28/15 18:240.50EPA 6020A Potassium 1820 ug/L 05/28/15 18:2450.0EPA 6020A Selenium 0.24J ug/L 05/28/15 18:240.50EPA 6020A Sodium 2270 ug/L 05/28/15 18:2450.0EPA 6020A Strontium 34.2 ug/L 05/28/15 18:240.50EPA 6020A Thallium 0.12 ug/L 05/28/15 18:240.10EPA 6020A Vanadium 32.0 ug/L 05/28/15 18:241.0EPA 6020A Zinc 92.3 ug/L 05/28/15 18:245.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 53 14 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 6010 Date:June 04, 2015 Description:6010 MET ICP General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24249 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1218699) • Aluminum • Barium • Iron • Manganese • MSD (Lab ID: 1218700) • Aluminum • Barium • Iron • Manganese Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14828 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 53 15 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 6020 Date:June 04, 2015 Description:6020 MET ICPMS General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24250 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1218705) • Antimony • Arsenic • Selenium • Vanadium • MSD (Lab ID: 1218706) • Antimony • Arsenic • Lead • Selenium • Thallium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 53 16 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 6020 Date:June 04, 2015 Description:6020 MET ICPMS Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 9829 Analyte Comments: QC Batch: MPRP/24250 N2: The lab does not hold TNI accreditation for this parameter. • 2015013900 (Lab ID: 92249061002) • Antimony • 2015013901 (Lab ID: 92249061003) • Antimony • BLANK (Lab ID: 1218703) • Antimony • LCS (Lab ID: 1218704) • Antimony • MS (Lab ID: 1218705) • Antimony • MSD (Lab ID: 1218706) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 53 17 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 6020A Date:June 04, 2015 Description:6020A MET ICPMS General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54425 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1966605) • Aluminum • MSD (Lab ID: 1966606) • Aluminum QC Batch: MPRP/54657 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250515004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1975922) • Aluminum • Calcium • Iron • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 53 18 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 6020A Date:June 04, 2015 Description:6020A MET ICPMS QC Batch: MPRP/54657 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250515004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1975923) • Aluminum • Calcium • Iron • Magnesium • Manganese • Sodium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 53 19 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 7470A Date:June 04, 2015 Description:7470A Mercury General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 53 20 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 7471 Date:June 04, 2015 Description:7471 Mercury General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 53 21 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 9045 Date:June 04, 2015 Description:9045 pH Soil General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37491 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1460370) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 53 22 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 300.0 Date:June 04, 2015 Description:300.0 IC Anions, SPLP General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23020 B: Analyte was detected in the associated method blank. • BLANK for HBN 264920 [WETA/230 (Lab ID: 1465540) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 53 23 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 353.2 Date:June 04, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015013900 (Lab ID: 92249061002) • 2015013901 (Lab ID: 92249061003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 53 24 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy SM 4500-Cl-E Date:June 04, 2015 Description:4500 Chloride, SPLP General Information: 2 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23132 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061003,92249703005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1472685) • Chloride • MSD (Lab ID: 1472686) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 53 25 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 9056 Date:June 04, 2015 Description:9056 IC Anions General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46476 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015013900 (Lab ID: 92249061002) • Chloride • 2015013901 (Lab ID: 92249061003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 53 26 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 9056 Date:June 04, 2015 Description:9056 IC Anions 48hr General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015013900 (Lab ID: 92249061002) • 2015013901 (Lab ID: 92249061003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 53 27 of 60 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92249061 J15050212 Method: Client:Duke Energy EPA 9060 Date:June 04, 2015 Description:Total Organic Carbon Quad General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 53 28 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013898 Lab ID:92249061001 Collected:05/07/15 11:50 Received:05/08/15 11:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 20.5 ug/L 05/18/15 13:55 7429-90-505/15/15 10:1710.0 3.0 1 Antimony ND ug/L 05/18/15 13:55 7440-36-005/15/15 10:170.50 0.15 1 Arsenic ND ug/L 05/18/15 13:55 7440-38-205/15/15 10:170.50 0.11 1 Barium 0.35 ug/L 05/18/15 13:55 7440-39-305/15/15 10:170.30 0.081 1 Beryllium ND ug/L 05/18/15 13:55 7440-41-705/15/15 10:170.20 0.067 1 Boron ND ug/L 05/18/15 13:55 7440-42-805/15/15 10:175.0 1.1 1 Cadmium ND ug/L 05/18/15 13:55 7440-43-905/15/15 10:170.080 0.024 1 Calcium 337 ug/L 05/18/15 13:55 7440-70-205/15/15 10:1740.0 16.0 1 Chromium 2.2 ug/L 05/18/15 13:55 7440-47-305/15/15 10:170.50 0.17 1 Cobalt ND ug/L 05/18/15 13:55 7440-48-405/15/15 10:170.50 0.13 1 Copper 0.67J ug/L 05/18/15 13:55 7440-50-805/15/15 10:171.0 0.21 1 Iron 105 ug/L 05/18/15 13:55 7439-89-605/15/15 10:1750.0 13.7 1 Lead ND ug/L 05/18/15 13:55 7439-92-105/15/15 10:170.10 0.046 1 Magnesium 5.9J ug/L 05/18/15 13:55 7439-95-405/15/15 10:1710.0 3.2 1 Manganese 1.3 ug/L 05/18/15 13:55 7439-96-505/15/15 10:170.50 0.24 1 Molybdenum 19.3 ug/L 05/18/15 13:55 7439-98-705/15/15 10:170.50 0.094 1 Nickel 0.35J ug/L 05/18/15 13:55 7440-02-005/15/15 10:170.50 0.16 1 Potassium 48.1J ug/L 05/18/15 13:55 7440-09-705/15/15 10:1750.0 11.7 1 Selenium ND ug/L 05/18/15 13:55 7782-49-205/15/15 10:170.50 0.20 1 Sodium 16.9J ug/L 05/18/15 13:55 7440-23-505/15/15 10:1750.0 16.3 1 Strontium 0.68 ug/L 05/18/15 13:55 7440-24-605/15/15 10:170.50 0.13 1 Thallium ND ug/L 05/18/15 13:55 7440-28-005/15/15 10:170.10 0.015 1 Vanadium ND ug/L 05/18/15 13:55 7440-62-205/15/15 10:171.0 0.28 1 Zinc 2.5J ug/L 05/18/15 13:55 7440-66-605/15/15 10:175.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 05/15/15 10:58 7439-97-605/15/15 09:100.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 53 29 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013900 Lab ID:92249061002 Collected:05/07/15 12:20 Received:05/08/15 11:55 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 9000 mg/kg 05/22/15 18:54 7429-90-5 M105/20/15 14:4529.1 14.5 5 Barium 68.8 mg/kg 05/22/15 18:54 7440-39-3 M105/20/15 14:452.9 1.5 5 Beryllium 0.46 mg/kg 05/22/15 18:54 7440-41-705/20/15 14:450.29 0.15 5 Boron ND mg/kg 05/22/15 18:54 7440-42-805/20/15 14:4514.5 7.3 5 Calcium 301 mg/kg 05/22/15 18:54 7440-70-205/20/15 14:4514572.7 5 Chromium 11.4 mg/kg 05/22/15 18:54 7440-47-305/20/15 14:451.5 0.73 5 Copper 7.7 mg/kg 05/22/15 18:54 7440-50-805/20/15 14:451.5 0.73 5 Iron 9460 mg/kg 05/22/15 18:54 7439-89-6 M105/20/15 14:4511.6 5.8 5 Magnesium 1110 mg/kg 05/22/15 18:54 7439-95-405/20/15 14:4514572.7 5 Manganese 693 mg/kg 05/22/15 18:54 7439-96-5 M105/20/15 14:451.5 0.73 5 Molybdenum ND mg/kg 05/22/15 18:54 7439-98-705/20/15 14:452.9 1.5 5 Nickel 4.2 mg/kg 05/22/15 18:54 7440-02-005/20/15 14:451.5 0.73 5 Potassium 534 mg/kg 05/22/15 18:54 7440-09-705/20/15 14:452911455 Sodium ND mg/kg 05/22/15 18:54 7440-23-505/20/15 14:452911455 Strontium 5.7 mg/kg 05/22/15 18:54 7440-24-605/20/15 14:452.9 1.5 5 Zinc 21.4 mg/kg 05/22/15 18:54 7440-66-605/20/15 14:455.8 2.9 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/22/15 19:48 7440-36-0 M6,N205/20/15 14:455.8 2.9 100 Arsenic ND mg/kg 05/22/15 19:48 7440-38-2 M605/20/15 14:455.8 2.9 100 Cadmium ND mg/kg 05/22/15 19:48 7440-43-905/20/15 14:450.70 0.35 100 Cobalt 5.9 mg/kg 05/22/15 19:48 7440-48-405/20/15 14:455.8 2.9 100 Lead 5.4J mg/kg 05/22/15 19:48 7439-92-1 M605/20/15 14:455.8 2.9 100 Selenium ND mg/kg 05/22/15 19:48 7782-49-2 M605/20/15 14:455.8 2.9 100 Thallium ND mg/kg 05/22/15 19:48 7440-28-0 M605/20/15 14:455.8 2.9 100 Vanadium 17.6 mg/kg 05/22/15 19:48 7440-62-2 M605/20/15 14:455.8 2.9 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.037 mg/kg 05/21/15 13:02 7439-97-605/20/15 14:500.0096 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 13.0 %05/20/15 10:340.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.1 Std. Units 05/18/15 15:450.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/14/15 03:45300.0 IC Anions, SPLP Sulfate 5.2 mg/L 05/22/15 18:08 14808-79-8 B2.3 1.1 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/14/15 03:45353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.31 mg/L 05/28/15 20:31 H10.23 0.23 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/14/15 03:454500 Chloride, SPLP Chloride ND mg/L 05/21/15 05:26 16887-00-65.7 2.9 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 53 30 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013900 Lab ID:92249061002 Collected:05/07/15 12:20 Received:05/08/15 11:55 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/16/15 18:57 16887-00-6 D32861435 Sulfate ND mg/kg 05/16/15 18:57 14808-79-82861435 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/16/15 18:57 14797-55-8 H328.6 14.3 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1650 mg/kg 06/02/15 16:19 7440-44-06863431 Total Organic Carbon 1600 mg/kg 06/02/15 16:25 7440-44-06943471 Total Organic Carbon 1620 mg/kg 06/02/15 16:30 7440-44-06943471 Total Organic Carbon 1570 mg/kg 06/02/15 16:36 7440-44-06903451 Mean Total Organic Carbon 1610 mg/kg 06/02/15 16:19 7440-44-06913451 Surrogates RSD%2.2 %06/02/15 16:191 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 53 31 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013901 Lab ID:92249061003 Collected:05/07/15 12:45 Received:05/08/15 11:55 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 2020 mg/kg 05/22/15 19:06 7429-90-505/20/15 14:4530.0 15.0 5 Barium 15.5 mg/kg 05/22/15 19:06 7440-39-305/20/15 14:453.0 1.5 5 Beryllium 0.21J mg/kg 05/22/15 19:06 7440-41-705/20/15 14:450.30 0.15 5 Boron ND mg/kg 05/22/15 19:06 7440-42-805/20/15 14:4515.0 7.5 5 Calcium 154 mg/kg 05/22/15 19:06 7440-70-205/20/15 14:4515075.0 5 Chromium 8.2 mg/kg 05/22/15 19:06 7440-47-305/20/15 14:451.5 0.75 5 Copper 4.4 mg/kg 05/22/15 19:06 7440-50-805/20/15 14:451.5 0.75 5 Iron 6040 mg/kg 05/22/15 19:06 7439-89-605/20/15 14:4512.0 6.0 5 Magnesium 387 mg/kg 05/22/15 19:06 7439-95-405/20/15 14:4515075.0 5 Manganese 226 mg/kg 05/22/15 19:06 7439-96-505/20/15 14:451.5 0.75 5 Molybdenum ND mg/kg 05/22/15 19:06 7439-98-705/20/15 14:453.0 1.5 5 Nickel 1.4J mg/kg 05/22/15 19:06 7440-02-005/20/15 14:451.5 0.75 5 Potassium 266J mg/kg 05/22/15 19:06 7440-09-705/20/15 14:453001505 Sodium ND mg/kg 05/22/15 19:06 7440-23-505/20/15 14:453001505 Strontium 2.9J mg/kg 05/22/15 19:06 7440-24-605/20/15 14:453.0 1.5 5 Zinc 6.5 mg/kg 05/22/15 19:06 7440-66-605/20/15 14:456.0 3.0 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/22/15 19:55 7440-36-0 N205/20/15 14:456.0 3.0 100 Arsenic ND mg/kg 05/22/15 19:55 7440-38-205/20/15 14:456.0 3.0 100 Cadmium ND mg/kg 05/22/15 19:55 7440-43-905/20/15 14:450.72 0.36 100 Cobalt ND mg/kg 05/22/15 19:55 7440-48-405/20/15 14:456.0 3.0 100 Lead ND mg/kg 05/22/15 19:55 7439-92-105/20/15 14:456.0 3.0 100 Selenium ND mg/kg 05/22/15 19:55 7782-49-205/20/15 14:456.0 3.0 100 Thallium ND mg/kg 05/22/15 19:55 7440-28-005/20/15 14:456.0 3.0 100 Vanadium 8.2 mg/kg 05/22/15 19:55 7440-62-205/20/15 14:456.0 3.0 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.011 mg/kg 05/21/15 13:09 7439-97-605/20/15 14:500.0092 0.0046 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 17.2 %05/20/15 10:340.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.4 Std. Units 05/18/15 15:450.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/14/15 03:45300.0 IC Anions, SPLP Sulfate 5.7 mg/L 05/22/15 18:21 14808-79-8 B2.4 1.2 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/14/15 03:45353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.29 mg/L 05/28/15 20:33 H10.24 0.24 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/14/15 03:454500 Chloride, SPLP Chloride ND mg/L 06/04/15 06:41 16887-00-66.0 3.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 53 32 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013901 Lab ID:92249061003 Collected:05/07/15 12:45 Received:05/08/15 11:55 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/16/15 20:01 16887-00-6 D33001505 Sulfate ND mg/kg 05/16/15 20:01 14808-79-8 D33001505 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/16/15 20:01 14797-55-8 H330.0 15.0 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 922 mg/kg 06/02/15 16:54 7440-44-07223611 Total Organic Carbon 918 mg/kg 06/02/15 16:59 7440-44-07223611 Total Organic Carbon 963 mg/kg 06/02/15 17:05 7440-44-07283641 Total Organic Carbon 736 mg/kg 06/02/15 17:12 7440-44-07233611 Mean Total Organic Carbon 885 mg/kg 06/02/15 16:54 7440-44-07243621 Surrogates RSD%11.4 %06/02/15 16:541 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 53 33 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013900 SPLP Lab ID:92249061004 Collected:05/07/15 12:20 Received:05/08/15 11:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 133 ug/L 05/28/15 18:01 7429-90-505/28/15 10:2610.0 3.0 1 Antimony ND ug/L 05/28/15 18:01 7440-36-005/28/15 10:260.50 0.15 1 Arsenic ND ug/L 05/28/15 18:01 7440-38-205/28/15 10:260.50 0.11 1 Barium 126 ug/L 05/28/15 18:01 7440-39-305/28/15 10:260.30 0.081 1 Beryllium ND ug/L 05/28/15 18:01 7440-41-705/28/15 10:260.20 0.067 1 Boron 77.5 ug/L 05/28/15 18:01 7440-42-805/28/15 10:265.0 1.1 1 Cadmium ND ug/L 05/28/15 18:01 7440-43-905/28/15 10:260.080 0.024 1 Calcium 870 ug/L 05/28/15 18:01 7440-70-205/28/15 10:2640.0 16.0 1 Chromium 0.37J ug/L 05/28/15 18:01 7440-47-305/28/15 10:260.50 0.17 1 Cobalt ND ug/L 05/28/15 18:01 7440-48-405/28/15 10:260.50 0.13 1 Copper 0.85J ug/L 05/28/15 18:01 7440-50-805/28/15 10:261.0 0.21 1 Iron 61.7 ug/L 05/28/15 18:01 7439-89-605/28/15 10:2650.0 13.7 1 Lead 0.054J ug/L 05/28/15 18:01 7439-92-105/28/15 10:260.10 0.046 1 Magnesium 270 ug/L 05/28/15 18:01 7439-95-405/28/15 10:2610.0 3.2 1 Manganese 9.3 ug/L 05/28/15 18:01 7439-96-505/28/15 10:260.50 0.24 1 Molybdenum ND ug/L 05/28/15 18:01 7439-98-705/28/15 10:260.50 0.094 1 Nickel 0.35J ug/L 05/28/15 18:01 7440-02-005/28/15 10:260.50 0.16 1 Potassium 318 ug/L 05/28/15 18:01 7440-09-705/28/15 10:2650.0 11.7 1 Selenium ND ug/L 05/28/15 18:01 7782-49-205/28/15 10:260.50 0.20 1 Sodium 1410 ug/L 05/28/15 18:01 7440-23-505/28/15 10:2650.0 16.3 1 Strontium 16.8 ug/L 05/28/15 18:01 7440-24-605/28/15 10:260.50 0.13 1 Thallium ND ug/L 05/28/15 18:01 7440-28-005/28/15 10:260.10 0.015 1 Vanadium ND ug/L 05/28/15 18:01 7440-62-205/28/15 10:261.0 0.28 1 Zinc 60.6 ug/L 05/28/15 18:01 7440-66-605/28/15 10:265.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 13:38 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 53 34 of 60 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92249061 J15050212 Sample:2015013901 SPLP Lab ID:92249061005 Collected:05/07/15 12:45 Received:05/08/15 11:55 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 18200 ug/L 05/28/15 18:24 7429-90-505/28/15 10:2610.0 3.0 1 Antimony ND ug/L 05/28/15 18:24 7440-36-005/28/15 10:260.50 0.15 1 Arsenic 2.0 ug/L 05/28/15 18:24 7440-38-205/28/15 10:260.50 0.11 1 Barium 252 ug/L 05/28/15 18:24 7440-39-305/28/15 10:260.30 0.081 1 Beryllium 0.66 ug/L 05/28/15 18:24 7440-41-705/28/15 10:260.20 0.067 1 Boron 63.7 ug/L 05/28/15 18:24 7440-42-805/28/15 10:265.0 1.1 1 Cadmium 0.028J ug/L 05/28/15 18:24 7440-43-905/28/15 10:260.080 0.024 1 Calcium 1890 ug/L 05/28/15 18:24 7440-70-205/28/15 10:2640.0 16.0 1 Chromium 19.9 ug/L 05/28/15 18:24 7440-47-305/28/15 10:260.50 0.17 1 Cobalt 4.5 ug/L 05/28/15 18:24 7440-48-405/28/15 10:260.50 0.13 1 Copper 15.3 ug/L 05/28/15 18:24 7440-50-805/28/15 10:261.0 0.21 1 Iron 17300 ug/L 05/28/15 18:24 7439-89-605/28/15 10:2650.0 13.7 1 Lead 5.7 ug/L 05/28/15 18:24 7439-92-105/28/15 10:260.10 0.046 1 Magnesium 1920 ug/L 05/28/15 18:24 7439-95-405/28/15 10:2610.0 3.2 1 Manganese 491 ug/L 05/29/15 08:01 7439-96-505/28/15 10:262.5 1.2 5 Molybdenum 1.1 ug/L 05/28/15 18:24 7439-98-705/28/15 10:260.50 0.094 1 Nickel 9.5 ug/L 05/28/15 18:24 7440-02-005/28/15 10:260.50 0.16 1 Potassium 1820 ug/L 05/28/15 18:24 7440-09-705/28/15 10:2650.0 11.7 1 Selenium 0.24J ug/L 05/28/15 18:24 7782-49-205/28/15 10:260.50 0.20 1 Sodium 2270 ug/L 05/28/15 18:24 7440-23-505/28/15 10:2650.0 16.3 1 Strontium 34.2 ug/L 05/28/15 18:24 7440-24-605/28/15 10:260.50 0.13 1 Thallium 0.12 ug/L 05/28/15 18:24 7440-28-005/28/15 10:260.10 0.015 1 Vanadium 32.0 ug/L 05/28/15 18:24 7440-62-205/28/15 10:261.0 0.28 1 Zinc 92.3 ug/L 05/28/15 18:24 7440-66-605/28/15 10:265.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 13:41 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 53 35 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13557 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92249061001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1966620 Associated Lab Samples:92249061001 Matrix:Water Analyzed Mercury ug/L ND 0.20 05/15/15 10:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1966621LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.95 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1966707MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249477011 1966708 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 94 80-12097 3 205ND4.7 4.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 53 36 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13677 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92249061004, 92249061005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1977489 Associated Lab Samples:92249061004, 92249061005 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/01/15 13:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977490LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1980282MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251147009 1980283 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120102 1 205ND5.2 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 53 37 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5748 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1218709 Associated Lab Samples:92249061002, 92249061003 Matrix:Solid Analyzed Mercury mg/kg ND 0.0081 05/21/15 12:58 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1218710LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.080.08 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1218711MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249061002 1218712 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .0954 94 80-12086 7 20.09430.037 0.13 0.12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 53 38 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24249 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1218697 Associated Lab Samples:92249061002, 92249061003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.1 05/22/15 18:46 Barium mg/kg ND 0.51 05/22/15 18:46 Beryllium mg/kg ND 0.051 05/22/15 18:46 Boron mg/kg ND 2.5 05/22/15 18:46 Calcium mg/kg ND 25.5 05/22/15 18:46 Chromium mg/kg ND 0.25 05/22/15 18:46 Copper mg/kg ND 0.25 05/22/15 18:46 Iron mg/kg ND 2.0 05/22/15 18:46 Magnesium mg/kg ND 25.5 05/22/15 18:46 Manganese mg/kg ND 0.25 05/22/15 18:46 Molybdenum mg/kg ND 0.51 05/22/15 18:46 Nickel mg/kg ND 0.25 05/22/15 18:46 Potassium mg/kg ND 50.9 05/22/15 18:46 Sodium mg/kg ND 50.9 05/22/15 18:46 Strontium mg/kg ND 0.51 05/22/15 18:46 Zinc mg/kg ND 1.0 05/22/15 18:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1218698LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 131130 101 80-120 Barium mg/kg 13.213 102 80-120 Beryllium mg/kg 1.31.3 103 80-120 Boron mg/kg 131130 101 80-120 Calcium mg/kg 653649 101 80-120 Chromium mg/kg 13.213 102 80-120 Copper mg/kg 12.913 100 80-120 Iron mg/kg 131130 101 80-120 Magnesium mg/kg 649649 100 80-120 Manganese mg/kg 13.113 101 80-120 Molybdenum mg/kg 12.813 98 80-120 Nickel mg/kg 13.013 101 80-120 Potassium mg/kg 635649 98 80-120 Sodium mg/kg 671649 104 80-120 Strontium mg/kg 12.813 99 80-120 Zinc mg/kg 65.764.9 101 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 53 39 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1218699MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249061002 1218700 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1149315075-1253180 0 2015190001370013800 Barium mg/kg M114.9 142 75-125133 2 2015.168.8 90.2 88.7 Beryllium mg/kg 1.49 92 75-12595 2 201.490.46 1.8 1.9 Boron mg/kg 149 84 75-12587 3 20151ND128132 Calcium mg/kg 749 104 75-125104 0 2075130110801080 Chromium mg/kg 14.9 98 75-125110 7 2015.111.4 26.1 27.9 Copper mg/kg 14.9 96 75-125100 3 2015.17.7 22.0 22.8 Iron mg/kg M114938475-125687 4 2015194601000010500 Magnesium mg/kg 749 104 75-125105 0 20751111018901900 Manganese mg/kg M114.9 -182 75-125241 9 2015.1693 665 729 Molybdenum mg/kg 14.9 79 75-12582 4 2015.1ND 12.1 12.7 Nickel mg/kg 14.9 100 75-125102 2 2015.14.2 19.2 19.5 Potassium mg/kg 749 113 75-125116 2 2075153413801410 Sodium mg/kg 749 93 75-12587 7 20751ND754704 Strontium mg/kg 14.9 103 75-125104 0 2015.15.7 21.2 21.3 Zinc mg/kg 74.9 98 75-125100 2 2075.121.4 94.7 96.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 53 40 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24250 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1218703 Associated Lab Samples:92249061002, 92249061003 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N205/22/15 19:44 Arsenic mg/kg ND 0.051 05/22/15 19:44 Cadmium mg/kg ND 0.0061 05/22/15 19:44 Cobalt mg/kg ND 0.051 05/22/15 19:44 Lead mg/kg ND 0.051 05/22/15 19:44 Selenium mg/kg ND 0.051 05/22/15 19:44 Thallium mg/kg ND 0.051 05/22/15 19:44 Vanadium mg/kg ND 0.051 05/22/15 19:44 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1218704LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.5 N22.5 102 80-120 Arsenic mg/kg 2.62.5 103 80-120 Cadmium mg/kg 0.25.25 100 80-120 Cobalt mg/kg 2.52.5 102 80-120 Lead mg/kg 2.52.5 101 80-120 Selenium mg/kg 2.52.5 101 80-120 Thallium mg/kg 2.52.5 103 80-120 Vanadium mg/kg 2.52.5 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1218705MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249061002 1218706 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N22.87 63 75-12552 202.87ND ND ND Arsenic mg/kg M62.87 68 75-12555 202.87ND 3.3J 3.0J Cadmium mg/kg .287 112 75-12580 20.287ND ND ND Cobalt mg/kg 2.87 101 75-12579 7 202.875.9 8.8 8.2 Lead mg/kg M62.87 93 75-12569 8 202.875.4J 8.0 7.4 Selenium mg/kg M62.87 29 75-12527 202.87ND 3.1J 3.0J Thallium mg/kg M62.87 85 75-12574 202.87ND 2.9J ND Vanadium mg/kg M62.87 74 75-12511 9 202.8717.6 19.7 17.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 53 41 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54425 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92249061001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1966603 Associated Lab Samples:92249061001 Matrix:Water Analyzed Aluminum ug/L ND 10.0 05/18/15 13:36 Antimony ug/L ND 0.50 05/18/15 13:36 Arsenic ug/L ND 0.50 05/18/15 13:36 Barium ug/L ND 0.30 05/18/15 13:36 Beryllium ug/L ND 0.20 05/18/15 13:36 Boron ug/L ND 5.0 05/18/15 13:36 Cadmium ug/L ND 0.080 05/18/15 13:36 Calcium ug/L ND 40.0 05/18/15 13:36 Chromium ug/L ND 0.50 05/18/15 13:36 Cobalt ug/L ND 0.50 05/18/15 13:36 Copper ug/L ND 1.0 05/18/15 13:36 Iron ug/L ND 50.0 05/18/15 13:36 Lead ug/L ND 0.10 05/18/15 13:36 Magnesium ug/L ND 10.0 05/18/15 13:36 Manganese ug/L ND 0.50 05/18/15 13:36 Molybdenum ug/L ND 0.50 05/18/15 13:36 Nickel ug/L ND 0.50 05/18/15 13:36 Potassium ug/L ND 50.0 05/18/15 13:36 Selenium ug/L ND 0.50 05/18/15 13:36 Sodium ug/L ND 50.0 05/18/15 13:36 Strontium ug/L ND 0.50 05/18/15 13:36 Thallium ug/L ND 0.10 05/18/15 13:36 Vanadium ug/L ND 1.0 05/18/15 13:36 Zinc ug/L ND 5.0 05/18/15 13:36 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1966604LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 75.680 94 80-120 Antimony ug/L 77.880 97 80-120 Arsenic ug/L 76.480 96 80-120 Barium ug/L 76.080 95 80-120 Beryllium ug/L 76.980 96 80-120 Boron ug/L 73.180 91 80-120 Cadmium ug/L 77.080 96 80-120 Calcium ug/L 10201000 102 80-120 Chromium ug/L 77.480 97 80-120 Cobalt ug/L 75.880 95 80-120 Copper ug/L 75.680 95 80-120 Iron ug/L 9511000 95 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 53 42 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1966604LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 78.280 98 80-120 Magnesium ug/L 9271000 93 80-120 Manganese ug/L 76.880 96 80-120 Molybdenum ug/L 77.080 96 80-120 Nickel ug/L 76.580 96 80-120 Potassium ug/L 9541000 95 80-120 Selenium ug/L 73.880 92 80-120 Sodium ug/L 9261000 93 80-120 Strontium ug/L 76.480 96 80-120 Thallium ug/L 80.480 100 80-120 Vanadium ug/L 76.980 96 80-120 Zinc ug/L 75.680 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1966605MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249061001 1966606 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18013075-125136 4 208020.5 124 129 Antimony ug/L 80 96 75-12596 0 2080ND77.0 76.7 Arsenic ug/L 80 95 75-12594 2 2080ND76.1 75.0 Barium ug/L 80 92 75-12593 1 20800.35 74.2 74.6 Beryllium ug/L 80 97 75-12596 1 2080ND77.9 76.9 Boron ug/L 80 89 75-12596 7 2080ND71.9 77.2 Cadmium ug/L 80 95 75-12595 0 2080ND76.2 76.2 Calcium ug/L 1000 103 75-12599 3 20100033713701330 Chromium ug/L 80 96 75-12596 0 20802.2 78.8 79.1 Cobalt ug/L 80 94 75-12594 0 2080ND75.4 75.2 Copper ug/L 80 95 75-12595 0 20800.67J 76.3 76.6 Iron ug/L 1000 95 75-12595 0 20100010510601060 Lead ug/L 80 97 75-12597 0 2080ND77.5 77.6 Magnesium ug/L 1000 99 75-12596 3 2010005.9J 994 966 Manganese ug/L 80 95 75-12595 0 20801.3 77.1 77.4 Molybdenum ug/L 80 95 75-12594 1 208019.3 95.0 94.4 Nickel ug/L 80 96 75-12596 0 20800.35J 77.0 76.8 Potassium ug/L 1000 94 75-12593 2 20100048.1J 989 974 Selenium ug/L 80 93 75-12590 3 2080ND74.5 72.4 Sodium ug/L 1000 90 75-12593 4 20100016.9J 915 950 Strontium ug/L 80 94 75-12595 1 20800.68 76.0 76.8 Thallium ug/L 80 99 75-125100 0 2080ND79.5 79.8 Vanadium ug/L 80 95 75-12595 1 2080ND75.9 76.6 Zinc ug/L 80 93 75-12592 1 20802.5J 77.2 76.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 53 43 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54657 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92249061004, 92249061005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1975920 Associated Lab Samples:92249061004, 92249061005 Matrix:Water Analyzed Aluminum ug/L ND 10.0 05/29/15 07:58 Antimony ug/L ND 0.50 05/29/15 07:58 Arsenic ug/L ND 0.50 05/29/15 07:58 Barium ug/L ND 0.30 05/29/15 07:58 Beryllium ug/L ND 0.20 05/29/15 07:58 Boron ug/L ND 5.0 05/29/15 07:58 Cadmium ug/L ND 0.080 05/29/15 07:58 Calcium ug/L ND 40.0 05/29/15 07:58 Chromium ug/L ND 0.50 05/29/15 07:58 Cobalt ug/L ND 0.50 05/29/15 07:58 Copper ug/L ND 1.0 05/29/15 07:58 Iron ug/L ND 50.0 05/29/15 07:58 Lead ug/L ND 0.10 05/29/15 07:58 Magnesium ug/L ND 10.0 05/29/15 07:58 Manganese ug/L ND 0.50 05/29/15 07:58 Molybdenum ug/L ND 0.50 05/29/15 07:58 Nickel ug/L ND 0.50 05/29/15 07:58 Potassium ug/L ND 50.0 05/29/15 07:58 Selenium ug/L ND 0.50 05/29/15 07:58 Sodium ug/L ND 50.0 05/29/15 07:58 Strontium ug/L ND 0.50 05/29/15 07:58 Thallium ug/L ND 0.10 05/29/15 07:58 Vanadium ug/L ND 1.0 05/29/15 07:58 Zinc ug/L ND 5.0 05/29/15 07:58 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1975921LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 80.880 101 80-120 Antimony ug/L 80.380 100 80-120 Arsenic ug/L 80.180 100 80-120 Barium ug/L 79.680 99 80-120 Beryllium ug/L 84.480 106 80-120 Boron ug/L 83.780 105 80-120 Cadmium ug/L 82.280 103 80-120 Calcium ug/L 9431000 94 80-120 Chromium ug/L 83.780 105 80-120 Cobalt ug/L 82.380 103 80-120 Copper ug/L 86.380 108 80-120 Iron ug/L 10401000 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 53 44 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1975921LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 82.580 103 80-120 Magnesium ug/L 10101000 101 80-120 Manganese ug/L 84.480 106 80-120 Molybdenum ug/L 81.380 102 80-120 Nickel ug/L 83.280 104 80-120 Potassium ug/L 10101000 101 80-120 Selenium ug/L 81.680 102 80-120 Sodium ug/L 9961000 100 80-120 Strontium ug/L 80.480 100 80-120 Thallium ug/L 83.480 104 80-120 Vanadium ug/L 82.480 103 80-120 Zinc ug/L 83.080 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1975922MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92250515004 1975923 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M180209075-1251880 3 2080498066506480 Antimony ug/L 80 98 75-12596 2 2080ND78.3 76.8 Arsenic ug/L 80 100 75-12598 2 20800.31J 80.2 78.7 Barium ug/L 80 101 75-125100 1 208014.4 95.1 94.3 Beryllium ug/L 80 107 75-125106 1 2080ND85.5 84.7 Boron ug/L 80 110 75-125107 2 2080ND88.7 86.7 Cadmium ug/L 80 104 75-125104 0 2080ND83.0 83.4 Calcium ug/L M1100023675-125233 1 201000422065906550 Chromium ug/L 80 109 75-125107 1 208080.3 168 166 Cobalt ug/L 80 106 75-125105 1 20802.9 87.6 86.8 Copper ug/L 80 109 75-125107 2 208012.2 99.7 98.0 Iron ug/L M1100029175-125259 2 201000158001880018400 Lead ug/L 80 104 75-125104 0 20800.39 83.4 83.5 Magnesium ug/L M1100017975-125175 1 201000205038503800 Manganese ug/L M18014675-125141 1 2080163280276 Molybdenum ug/L 80 103 75-125101 1 208014.4 96.4 95.3 Nickel ug/L 80 106 75-125103 2 20805.7 90.4 88.5 Potassium ug/L 1000 106 75-125103 2 20100039514601420 Selenium ug/L 80 102 75-125101 1 2080ND81.9 81.2 Sodium ug/L M1100012475-125153 12 20100090321402430 Strontium ug/L 80 114 75-125111 2 208029.7 121 118 Thallium ug/L 80 106 75-125106 1 2080ND85.0 84.4 Vanadium ug/L 80 112 75-125111 1 208015.3 105 104 Zinc ug/L 80 105 75-125102 3 20809.7 94.0 91.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 53 45 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3581 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92249061002, 92249061003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92248767001 1218747SAMPLE DUPLICATE: Percent Moisture %19.4 D6121017.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249477001 1218748SAMPLE DUPLICATE: Percent Moisture %10.5 4 1010.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249077002 1218749SAMPLE DUPLICATE: Percent Moisture %24.9 2 1025.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249681005 1218750SAMPLE DUPLICATE: Percent Moisture %30.5 2 1031.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249710007 1218751SAMPLE DUPLICATE: Percent Moisture %28.1 5 1029.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249710016 1218752SAMPLE DUPLICATE: Percent Moisture %4.8 9 104.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 53 46 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37491 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92249061002, 92249061003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249101011 1460370SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.7 D63106.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 92249077002 1460371SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.5 0 105.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 53 47 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23020 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1465540 Associated Lab Samples:92249061002, 92249061003 Matrix:Water Analyzed Sulfate mg/L 3.1 2.0 05/22/15 12:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1465541LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.720 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1465542MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92248135006 1465543 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 31.9 104 104 031.912.6 45.6 45.8 Parameter Units MS Result % Rec Limits Qual% RecConc. 1465544MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92248773012 1465545 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 25.3 99 100 025.35.4 30.6 30.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 53 48 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23082 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1470182 Associated Lab Samples:92249061002, 92249061003 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.14 0.020 Z205/28/15 20:01 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1470183LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1470184MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92248135006 1470185 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H149790-11095 1 1040.39 4.2 4.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1470186MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92248135012 1470187 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.1 98 90-11098 0 103.10.31 3.3 3.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 53 49 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23009 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92249061002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1464494 Associated Lab Samples:92249061002 Matrix:Water Analyzed Chloride mg/L ND 1.0 05/21/15 05:11 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1464495LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 19.920 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1464496MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92248135006 1464497 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 31.9 101 90-110100 1 1031.9ND 33.1 32.7 Parameter Units MS Result % Rec Limits Qual% RecConc. 1464498MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92248773012 1464499 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 25.3 97 90-11097 0 1025.3ND 24.9 25.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 53 50 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23132 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1472681 Associated Lab Samples:92249061003 Matrix:Water Analyzed Chloride mg/L ND 1.0 06/04/15 06:39 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1472682LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 21.020 105 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1472683MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249061003 1472684 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 24.2 109 90-110110 0 1024.2ND 27.1 27.1 Parameter Units MS Result % Rec Limits Qual% RecConc. 1472685MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249703005 1472686 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L M12011490-110115 1 1020ND23.1 23.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 53 51 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46476 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1216279 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.8 05/16/15 17:10 Sulfate mg/kg ND 49.8 05/16/15 17:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1216280LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 482495 97 80-120 Sulfate mg/kg 482495 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1216282MATRIX SPIKE SAMPLE: MSSpike Result 92249061002 Chloride mg/kg 534567 94 80-120ND Sulfate mg/kg 606567 90 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92249061002 1216281SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 53 52 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46475 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1216275 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 05/16/15 17:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1216276LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.849.5 99 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1216278MATRIX SPIKE SAMPLE: MSSpike Result 92249061002 Nitrate as N mg/kg 55.6 H356.7 98 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92249061002 1216277SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 53 53 of 60 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92249061 J15050212 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28762 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92249061002, 92249061003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1167261 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/02/15 07:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1167262LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 114000120000 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1167263MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249703006 1167264 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 5990 77 50-15079 3 306000ND48204980 Parameter Units MS Result % Rec Limits Qual% RecConc. 1167265MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92249703007 1167266 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6030 81 50-15089 8 306010ND51105550 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 53 54 of 60 #=QL# QUALIFIERS Pace Project No.: Project: 92249061 J15050212 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14828 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICPM/9829 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 53 55 of 60 #=QL# QUALIFIERS Pace Project No.: Project: 92249061 J15050212 ANALYTE QUALIFIERS Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 53 56 of 60 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92249061 J15050212 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92249061002 MPRP/24249 ICP/148282015013900EPA 3050 EPA 6010 92249061003 MPRP/24249 ICP/148282015013901EPA 3050 EPA 6010 92249061002 MPRP/24250 ICPM/98292015013900EPA 3050 EPA 6020 92249061003 MPRP/24250 ICPM/98292015013901EPA 3050 EPA 6020 92249061001 MPRP/54425 ICPM/243152015013898EPA 3020 EPA 6020A 92249061004 MPRP/54657 ICPM/244942015013900 SPLP EPA 3020 EPA 6020A 92249061005 MPRP/54657 ICPM/244942015013901 SPLP EPA 3020 EPA 6020A 92249061001 MERP/13557 MERC/157372015013898EPA 7470A EPA 7470A 92249061004 MERP/13677 MERC/159272015013900 SPLP EPA 7470A EPA 7470A 92249061005 MERP/13677 MERC/159272015013901 SPLP EPA 7470A EPA 7470A 92249061002 MERP/5748 MERC/57352015013900EPA 7471 EPA 7471 92249061003 MERP/5748 MERC/57352015013901EPA 7471 EPA 7471 92249061002 PMST/35812015013900ASTM D2974-87 92249061003 PMST/35812015013901ASTM D2974-87 92249061002 WET/374912015013900EPA 9045 92249061003 WET/374912015013901EPA 9045 92249061002 WETA/230202015013900EPA 300.0 92249061003 WETA/230202015013901EPA 300.0 92249061002 WETA/230822015013900EPA 353.2 92249061003 WETA/230822015013901EPA 353.2 92249061002 WETA/230092015013900SM 4500-Cl-E 92249061003 WETA/231322015013901SM 4500-Cl-E 92249061002 WETA/464762015013900EPA 9056 92249061003 WETA/464762015013901EPA 9056 92249061002 WETA/464752015013900EPA 9056 92249061003 WETA/464752015013901EPA 9056 92249061002 WETA/287622015013900EPA 9060 92249061002 WETA/287632015013900EPA 9060 92249061003 WETA/287622015013901EPA 9060 92249061003 WETA/287632015013901EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/04/2015 03:07 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 53 57 of 60 Page 52 of 53 58 of 60 Page 53 of 53 59 of 60 60 of 60