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NC0038377_J15040671 Report_20171101
13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040671 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/16/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 98 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015012319 MAYO STEAM 23-Apr-15 12:15 PM Synterra MW-07BR-EB 2015012320 MAYO STEAM 23-Apr-15 12:30 PM Synterra MW-07BR (1.0-2.0) 2015012321 MAYO STEAM 26-Apr-15 3:30 PM Synterra MW-12D-EB 2015012322 MAYO STEAM 26-Apr-15 3:45 PM Synterra MW-12D (1.0-2.0) 2015012323 MAYO STEAM 25-Apr-15 1:40 PM Synterra MW-16-EB 2015012324 MAYO STEAM 25-Apr-15 2:10 PM Synterra MW-16BR (1.0-2.0) 2015012325 MAYO STEAM 25-Apr-15 5:30 PM Synterra MW-16BR (33.0-35.0) 2015012326 MAYO STEAM 26-Apr-15 9:00 AM Synterra MW-16BR (23.0-24.0) 2015012327 MAYO STEAM 26-Apr-15 3:50 PM Synterra MW-16BR (54.5-55.5) 2015012328 MAYO STEAM 27-Apr-15 8:30 AM Synterra MW-12D (25.0-26.0) 2015012329 MAYO STEAM 27-Apr-15 8:45 AM Synterra MW-12D (34.0-35.0) 11 Total Samples 2 of 98 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012319 Collection Date: 23-Apr-15 12:15 PM Site: MW-07BR-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012320 Collection Date: 23-Apr-15 12:30 PM Site: MW-07BR (1.0-2.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012321 Collection Date: 26-Apr-15 3:30 PM Site: MW-12D-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012322 Collection Date: 26-Apr-15 3:45 PM Site: MW-12D (1.0-2.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012323 Collection Date: 25-Apr-15 1:40 PM Site: MW-16-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 8 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012324 Collection Date: 25-Apr-15 2:10 PM Site: MW-16BR (1.0-2.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 9 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012325 Collection Date: 25-Apr-15 5:30 PM Site: MW-16BR (33.0-35.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 10 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012326 Collection Date: 26-Apr-15 9:00 AM Site: MW-16BR (23.0-24.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 11 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012327 Collection Date: 26-Apr-15 3:50 PM Site: MW-16BR (54.5-55.5) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 12 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012328 Collection Date: 27-Apr-15 8:30 AM Site: MW-12D (25.0-26.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 13 of 98 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040671 2015012329 Collection Date: 27-Apr-15 8:45 AM Site: MW-12D (34.0-35.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP sulfate blank is 3.1 mg/L. Sample results at or near this level. Results are suspect. M. Galvin-Karr 6/15/2015. -- Additional Information -- 14 of 98 #=CL# June 15, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92247383 92247383 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15040671 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 28, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 82 15 of 98 #=CP# CERTIFICATIONS Pace Project No.: Project: 92247383 J15040671 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 82 16 of 98 #=CP# CERTIFICATIONS Pace Project No.: Project: 92247383 J15040671 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 82 17 of 98 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID Matrix Date Collected Date Received 92247383001 2015012319 Water 04/23/15 12:15 04/28/15 14:30 92247383002 2015012320 Solid 04/23/15 12:30 04/28/15 14:30 92247383003 2015012321 Water 04/26/15 15:30 04/28/15 14:30 92247383004 2015012322 Solid 04/26/15 15:45 04/28/15 14:30 92247383005 2015012323 Water 04/25/15 13:40 04/28/15 14:30 92247383006 2015012324 Solid 04/25/15 14:10 04/28/15 14:30 92247383007 2015012325 Solid 04/25/15 17:30 04/28/15 14:30 92247383008 2015012326 Solid 04/26/15 09:00 04/28/15 14:30 92247383009 2015012327 Solid 04/26/15 15:50 04/28/15 14:30 92247383010 2015012328 Solid 04/27/15 08:30 04/28/15 14:30 92247383011 2015012329 Solid 04/27/15 08:45 04/28/15 14:30 92247383012 2015012325 SPLP Water 04/25/15 17:30 04/28/15 14:30 92247383013 2015012326 SPLP Water 04/26/15 09:00 04/28/15 14:30 92247383014 2015012328 SPLP Water 04/27/15 08:30 04/28/15 14:30 92247383015 2015012329 SPLP Water 04/27/15 08:45 04/28/15 14:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 82 18 of 98 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92247383001 2015012319 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MJDD 92247383002 2015012320 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383003 2015012321 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MJDD 92247383004 2015012322 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383005 2015012323 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MJDD 92247383006 2015012324 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383007 2015012325 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 82 19 of 98 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383008 2015012326 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383009 2015012327 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383010 2015012328 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383011 2015012329 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 82 20 of 98 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92247383012 2015012325 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM 92247383013 2015012326 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM 92247383014 2015012328 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM 92247383015 2015012329 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 82 21 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383001 2015012319 Aluminum 7.6J ug/L 05/06/15 09:1010.0EPA 6020A Barium 0.22J ug/L 05/05/15 14:460.30EPA 6020A Calcium 68.7 ug/L 05/05/15 14:4640.0EPA 6020A Chromium 1.3 ug/L 05/05/15 14:460.50EPA 6020A Cobalt 0.50J ug/L 05/05/15 14:460.50EPA 6020A Copper 0.74J ug/L 05/05/15 14:461.0EPA 6020A Iron 166 ug/L 05/05/15 14:4650.0EPA 6020A Magnesium 19.0 ug/L 05/05/15 14:4610.0EPA 6020A Manganese 2.7 ug/L 05/05/15 14:460.50EPA 6020A Molybdenum 0.32J ug/L 05/05/15 14:460.50EPA 6020A Nickel 0.36J ug/L 05/05/15 14:460.50EPA 6020A Strontium 0.26J ug/L 05/05/15 14:460.50EPA 6020A Zinc 4.9J ug/L 05/05/15 14:465.0EPA 6020A 92247383002 2015012320 Aluminum 3080 mg/kg 05/07/15 10:3825.5EPA 6010 Barium 21.5 mg/kg 05/07/15 10:382.6EPA 6010 Beryllium 0.29 mg/kg 05/07/15 10:380.26EPA 6010 Calcium 68.5J mg/kg 05/07/15 10:38128EPA 6010 Chromium 4.1 mg/kg 05/07/15 10:381.3EPA 6010 Copper 7.0 mg/kg 05/07/15 10:381.3EPA 6010 Iron 7320 mg/kg 05/07/15 10:3810.2EPA 6010 Magnesium 437 mg/kg 05/07/15 10:38128EPA 6010 Manganese 27.7 mg/kg 05/07/15 10:381.3EPA 6010 Nickel 0.68J mg/kg 05/07/15 10:381.3EPA 6010 Potassium 315 mg/kg 05/07/15 10:38255EPA 6010 Strontium 2.0J mg/kg 05/07/15 10:382.6EPA 6010 Zinc 7.0 mg/kg 05/07/15 10:385.1EPA 6010 Lead 5.4 mg/kg 05/06/15 17:545.1EPA 6020 Vanadium 12.8 mg/kg 05/06/15 17:545.1EPA 6020 Mercury 0.0073J mg/kg 05/07/15 13:570.0086EPA 7471 Percent Moisture 2.8 %05/13/15 10:290.10ASTM D2974-87 pH at 25 Degrees C 5.6 Std. Units 04/29/15 14:500.10EPA 9045 Total Organic Carbon 485J mg/kg 05/18/15 09:33613EPA 9060 Total Organic Carbon 418J mg/kg 05/18/15 09:38618EPA 9060 Total Organic Carbon 383J mg/kg 05/18/15 09:45612EPA 9060 Total Organic Carbon 394J mg/kg 05/18/15 09:51623EPA 9060 Mean Total Organic Carbon 420J mg/kg 05/18/15 09:33617EPA 9060 RSD%10.8 %05/18/15 09:33EPA 9060 92247383003 2015012321 Aluminum 64.1 ug/L 05/06/15 09:5210.0EPA 6020A Barium 1.1 ug/L 05/05/15 14:510.30EPA 6020A Boron 7.3 ug/L 05/05/15 14:515.0EPA 6020A Calcium 971 ug/L 05/05/15 14:5140.0EPA 6020A Chromium 1.8 ug/L 05/05/15 14:510.50EPA 6020A Cobalt 7.6 ug/L 05/05/15 14:510.50EPA 6020A Copper 1.3 ug/L 05/05/15 14:511.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 82 22 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383003 2015012321 Iron 663 ug/L 05/05/15 14:5150.0EPA 6020A Lead 0.38 ug/L 05/05/15 14:510.10EPA 6020A Magnesium 39.8 ug/L 05/05/15 14:5110.0EPA 6020A Manganese 14.3 ug/L 05/05/15 14:510.50EPA 6020A Molybdenum 0.21J ug/L 05/05/15 14:510.50EPA 6020A Nickel 0.68 ug/L 05/05/15 14:510.50EPA 6020A Potassium 22.0J ug/L 05/05/15 14:5150.0EPA 6020A Sodium 20.0J ug/L 05/05/15 14:5150.0EPA 6020A Strontium 1.7 ug/L 05/05/15 14:510.50EPA 6020A Zinc 9.0 ug/L 05/05/15 14:515.0EPA 6020A 92247383004 2015012322 Aluminum 11000 mg/kg 05/07/15 10:4229.9EPA 6010 Barium 19.6 mg/kg 05/07/15 10:423.0EPA 6010 Boron 27.4 mg/kg 05/07/15 10:4215.0EPA 6010 Chromium 43.6 mg/kg 05/07/15 10:421.5EPA 6010 Copper 12.4 mg/kg 05/07/15 10:421.5EPA 6010 Iron 31200 mg/kg 05/07/15 10:4212.0EPA 6010 Magnesium 139J mg/kg 05/07/15 10:42150EPA 6010 Manganese 22.1 mg/kg 05/07/15 10:421.5EPA 6010 Nickel 0.83J mg/kg 05/07/15 10:421.5EPA 6010 Potassium 182J mg/kg 05/07/15 10:42299EPA 6010 Zinc 5.2J mg/kg 05/07/15 10:426.0EPA 6010 Arsenic 3.6J mg/kg 05/06/15 17:566.0EPA 6020 Lead 6.8 mg/kg 05/06/15 17:566.0EPA 6020 Vanadium 61.0 mg/kg 05/06/15 17:566.0EPA 6020 Mercury 0.036 mg/kg 05/07/15 13:590.0093EPA 7471 Percent Moisture 17.5 %05/13/15 10:290.10ASTM D2974-87 pH at 25 Degrees C 4.9 Std. Units 04/29/15 14:500.10EPA 9045 Total Organic Carbon 848 mg/kg 05/20/15 11:04724EPA 9060 Total Organic Carbon 979 mg/kg 05/20/15 11:10725EPA 9060 Total Organic Carbon 1460 mg/kg 05/20/15 11:16730EPA 9060 Total Organic Carbon 1170 mg/kg 05/20/15 11:23726EPA 9060 Mean Total Organic Carbon 1110 mg/kg 05/20/15 11:04726EPA 9060 RSD%23.7 %05/20/15 11:04EPA 9060 92247383005 2015012323 Aluminum 13.5 ug/L 05/06/15 09:5710.0EPA 6020A Barium 0.30 ug/L 05/05/15 14:560.30EPA 6020A Calcium 65.9 ug/L 05/05/15 14:5640.0EPA 6020A Chromium 0.58 ug/L 05/05/15 14:560.50EPA 6020A Cobalt 1.0 ug/L 05/05/15 14:560.50EPA 6020A Copper 0.44J ug/L 05/05/15 14:561.0EPA 6020A Iron 96.7 ug/L 05/05/15 14:5650.0EPA 6020A Magnesium 14.2 ug/L 05/05/15 14:5610.0EPA 6020A Manganese 1.7 ug/L 05/05/15 14:560.50EPA 6020A Molybdenum 0.14J ug/L 05/05/15 14:560.50EPA 6020A Strontium 0.15J ug/L 05/05/15 14:560.50EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 82 23 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383006 2015012324 Aluminum 5360 mg/kg 05/07/15 10:5932.4EPA 6010 Barium 95.4 mg/kg 05/07/15 10:593.2EPA 6010 Beryllium 0.40 mg/kg 05/07/15 10:590.32EPA 6010 Calcium 253 mg/kg 05/07/15 10:59162EPA 6010 Chromium 7.6 mg/kg 05/07/15 10:591.6EPA 6010 Copper 4.3 mg/kg 05/07/15 10:591.6EPA 6010 Iron 7710 mg/kg 05/07/15 10:5912.9EPA 6010 Magnesium 454 mg/kg 05/07/15 10:59162EPA 6010 Manganese 1250 mg/kg 05/07/15 10:591.6EPA 6010 Nickel 1.9 mg/kg 05/07/15 10:591.6EPA 6010 Potassium 254J mg/kg 05/07/15 10:59324EPA 6010 Strontium 3.2J mg/kg 05/07/15 10:593.2EPA 6010 Zinc 10.4 mg/kg 05/07/15 10:596.5EPA 6010 Cobalt 6.0J mg/kg 05/06/15 18:066.5EPA 6020 Lead 6.3J mg/kg 05/06/15 18:066.5EPA 6020 Vanadium 17.3 mg/kg 05/06/15 18:066.5EPA 6020 Mercury 0.012 mg/kg 05/07/15 14:020.011EPA 7471 Percent Moisture 24.9 %05/13/15 10:290.10ASTM D2974-87 pH at 25 Degrees C 5.1 Std. Units 04/29/15 14:500.10EPA 9045 Total Organic Carbon 2880 mg/kg 05/20/15 12:17800EPA 9060 Total Organic Carbon 3740 mg/kg 05/20/15 12:24796EPA 9060 Total Organic Carbon 3380 mg/kg 05/20/15 12:29804EPA 9060 Total Organic Carbon 3410 mg/kg 05/20/15 12:34801EPA 9060 Mean Total Organic Carbon 3350 mg/kg 05/20/15 12:17800EPA 9060 RSD%10.6 %05/20/15 12:17EPA 9060 92247383007 2015012325 Aluminum 9030 mg/kg 05/07/15 11:0437.6EPA 6010 Barium 131 mg/kg 05/07/15 11:043.8EPA 6010 Beryllium 0.36J mg/kg 05/07/15 11:040.38EPA 6010 Boron 16.8J mg/kg 05/07/15 11:0418.8EPA 6010 Calcium 4470 mg/kg 05/07/15 11:04188EPA 6010 Chromium 9.2 mg/kg 05/07/15 11:041.9EPA 6010 Copper 126 mg/kg 05/07/15 11:041.9EPA 6010 Iron 19100 mg/kg 05/07/15 11:0415.0EPA 6010 Magnesium 5220 mg/kg 05/07/15 11:04188EPA 6010 Manganese 1630 mg/kg 05/07/15 11:041.9EPA 6010 Molybdenum 2.9J mg/kg 05/07/15 11:043.8EPA 6010 Nickel 2.9 mg/kg 05/07/15 11:041.9EPA 6010 Potassium 2890 mg/kg 05/07/15 11:04376EPA 6010 Sodium 384 mg/kg 05/07/15 11:04376EPA 6010 Strontium 37.5 mg/kg 05/07/15 11:043.8EPA 6010 Zinc 54.6 mg/kg 05/07/15 11:047.5EPA 6010 Cobalt 12.0 mg/kg 05/06/15 18:087.5EPA 6020 Lead 3.8J mg/kg 05/06/15 18:087.5EPA 6020 Vanadium 16.3 mg/kg 05/06/15 18:087.5EPA 6020 Percent Moisture 30.7 %05/13/15 10:300.10ASTM D2974-87 pH at 25 Degrees C 8.1 Std. Units 04/29/15 14:500.10EPA 9045 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 82 24 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383007 2015012325 Sulfate 5.4 mg/L 05/14/15 19:29 B2.9EPA 300.0 RSD%3.0 %05/20/15 14:27EPA 9060 92247383008 2015012326 Aluminum 4860 mg/kg 05/07/15 11:0825.0EPA 6010 Barium 28.2 mg/kg 05/07/15 11:082.5EPA 6010 Beryllium 0.20J mg/kg 05/07/15 11:080.25EPA 6010 Boron 10.0J mg/kg 05/07/15 11:0812.5EPA 6010 Calcium 2710 mg/kg 05/07/15 11:08125EPA 6010 Chromium 2.1 mg/kg 05/07/15 11:081.3EPA 6010 Copper 5.3 mg/kg 05/07/15 11:081.3EPA 6010 Iron 10600 mg/kg 05/07/15 11:0810.0EPA 6010 Magnesium 3200 mg/kg 05/07/15 11:08125EPA 6010 Manganese 885 mg/kg 05/07/15 11:081.3EPA 6010 Nickel 1.2J mg/kg 05/07/15 11:081.3EPA 6010 Potassium 1390 mg/kg 05/07/15 11:08250EPA 6010 Sodium 182J mg/kg 05/07/15 11:08250EPA 6010 Strontium 23.3 mg/kg 05/07/15 11:082.5EPA 6010 Zinc 35.6 mg/kg 05/07/15 11:085.0EPA 6010 Cobalt 4.6J mg/kg 05/06/15 18:115.0EPA 6020 Vanadium 8.4 mg/kg 05/06/15 18:115.0EPA 6020 Percent Moisture 2.4 %05/13/15 10:300.10ASTM D2974-87 pH at 25 Degrees C 7.8 Std. Units 05/04/15 14:000.10EPA 9045 Sulfate 3.8 mg/L 05/14/15 19:43 B2.0EPA 300.0 RSD%2.7 %05/20/15 14:50EPA 9060 92247383009 2015012327 Aluminum 24500 mg/kg 05/07/15 11:1225.8EPA 6010 Barium 237 mg/kg 05/07/15 11:122.6EPA 6010 Beryllium 0.40 mg/kg 05/07/15 11:120.26EPA 6010 Boron 32.3 mg/kg 05/07/15 11:1212.9EPA 6010 Calcium 19400 mg/kg 05/07/15 11:12129EPA 6010 Chromium 37.2 mg/kg 05/07/15 11:121.3EPA 6010 Copper 26.7 mg/kg 05/07/15 11:121.3EPA 6010 Iron 38300 mg/kg 05/07/15 11:1210.3EPA 6010 Magnesium 21800 mg/kg 05/07/15 11:12129EPA 6010 Manganese 1010 mg/kg 05/07/15 11:121.3EPA 6010 Nickel 28.1 mg/kg 05/07/15 11:121.3EPA 6010 Potassium 16600 mg/kg 05/07/15 11:12258EPA 6010 Sodium 261 mg/kg 05/07/15 11:12258EPA 6010 Strontium 40.0 mg/kg 05/07/15 11:122.6EPA 6010 Zinc 101 mg/kg 05/07/15 11:125.2EPA 6010 Cobalt 19.6 mg/kg 05/06/15 18:135.2EPA 6020 Vanadium 87.0 mg/kg 05/06/15 18:135.2EPA 6020 Percent Moisture 6.5 %05/13/15 10:300.10ASTM D2974-87 pH at 25 Degrees C 9.6 Std. Units 05/04/15 14:000.10EPA 9045 RSD%12.2 %05/20/15 15:12EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 82 25 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383010 2015012328 Aluminum 3530 mg/kg 05/07/15 11:1729.9EPA 6010 Barium 67.4 mg/kg 05/07/15 11:173.0EPA 6010 Boron 9.8J mg/kg 05/07/15 11:1714.9EPA 6010 Chromium 3.2 mg/kg 05/07/15 11:171.5EPA 6010 Copper 22.4 mg/kg 05/07/15 11:171.5EPA 6010 Iron 11900 mg/kg 05/07/15 11:1712.0EPA 6010 Magnesium 1190 mg/kg 05/07/15 11:17149EPA 6010 Manganese 395 mg/kg 05/07/15 11:171.5EPA 6010 Potassium 1520 mg/kg 05/07/15 11:17299EPA 6010 Zinc 15.0 mg/kg 05/07/15 11:176.0EPA 6010 Cobalt 6.0 mg/kg 05/06/15 18:156.0EPA 6020 Lead 7.2 mg/kg 05/06/15 18:156.0EPA 6020 Vanadium 8.2 mg/kg 05/06/15 18:156.0EPA 6020 Percent Moisture 16.8 %05/13/15 10:30 D60.10ASTM D2974-87 pH at 25 Degrees C 5.9 Std. Units 05/04/15 14:000.10EPA 9045 Sulfate 3.1 mg/L 05/14/15 19:56 B2.4EPA 300.0 Nitrogen, Nitrate 0.25 mg/L 05/15/15 21:10 H10.24EPA 353.2 RSD%2.3 %05/20/15 15:35EPA 9060 92247383011 2015012329 Aluminum 4410 mg/kg 05/07/15 11:2131.3EPA 6010 Barium 81.5 mg/kg 05/07/15 11:213.1EPA 6010 Beryllium 0.25J mg/kg 05/07/15 11:210.31EPA 6010 Boron 9.2J mg/kg 05/07/15 11:2115.6EPA 6010 Chromium 1.9 mg/kg 05/07/15 11:211.6EPA 6010 Copper 19.1 mg/kg 05/07/15 11:211.6EPA 6010 Iron 10700 mg/kg 05/07/15 11:2112.5EPA 6010 Magnesium 1410 mg/kg 05/07/15 11:21156EPA 6010 Manganese 855 mg/kg 05/07/15 11:211.6EPA 6010 Nickel 1.4J mg/kg 05/07/15 11:211.6EPA 6010 Potassium 1680 mg/kg 05/07/15 11:21313EPA 6010 Strontium 4.6 mg/kg 05/07/15 11:213.1EPA 6010 Zinc 27.7 mg/kg 05/07/15 11:216.3EPA 6010 Cobalt 9.2 mg/kg 05/06/15 18:186.3EPA 6020 Lead 9.2 mg/kg 05/06/15 18:186.3EPA 6020 Vanadium 7.7 mg/kg 05/06/15 18:186.3EPA 6020 Percent Moisture 20.3 %05/13/15 10:300.10ASTM D2974-87 pH at 25 Degrees C 5.5 Std. Units 05/04/15 14:000.10EPA 9045 Sulfate 3.4 mg/L 05/14/15 20:10 B2.5EPA 300.0 RSD%1.8 %05/20/15 16:00EPA 9060 92247383012 2015012325 SPLP Aluminum 13200 ug/L 05/29/15 17:2010.0EPA 6020A Arsenic 2.8 ug/L 05/29/15 17:200.50EPA 6020A Barium 360 ug/L 05/29/15 17:200.30EPA 6020A Beryllium 0.48 ug/L 05/29/15 17:200.20EPA 6020A Boron 32.7 ug/L 05/29/15 17:205.0EPA 6020A Cadmium 0.062J ug/L 05/29/15 17:200.080EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 82 26 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383012 2015012325 SPLP Calcium 3370 ug/L 05/29/15 17:2040.0EPA 6020A Chromium 8.8 ug/L 05/29/15 17:200.50EPA 6020A Cobalt 12.7 ug/L 05/29/15 17:200.50EPA 6020A Copper 155 ug/L 05/29/15 17:201.0EPA 6020A Iron 21000 ug/L 05/29/15 17:2050.0EPA 6020A Lead 5.6 ug/L 05/29/15 17:200.10EPA 6020A Magnesium 4960 ug/L 05/29/15 17:2010.0EPA 6020A Manganese 1990 ug/L 05/31/15 10:1310.0EPA 6020A Molybdenum 10.9 ug/L 05/29/15 17:200.50EPA 6020A Nickel 4.2 ug/L 05/29/15 17:200.50EPA 6020A Potassium 3800 ug/L 05/29/15 17:2050.0EPA 6020A Selenium 2.1 ug/L 05/29/15 17:200.50EPA 6020A Sodium 3900 ug/L 05/29/15 17:2050.0EPA 6020A Strontium 47.0 ug/L 05/29/15 17:200.50EPA 6020A Thallium 0.045J ug/L 05/29/15 17:200.10EPA 6020A Vanadium 18.5 ug/L 05/29/15 17:201.0EPA 6020A Zinc 90.9 ug/L 05/29/15 17:205.0EPA 6020A 92247383013 2015012326 SPLP Aluminum 4500 ug/L 05/29/15 17:2510.0EPA 6020A Arsenic 0.19J ug/L 05/29/15 17:250.50EPA 6020A Barium 126 ug/L 05/29/15 17:250.30EPA 6020A Beryllium 0.18J ug/L 05/29/15 17:250.20EPA 6020A Boron 30.2 ug/L 05/29/15 17:255.0EPA 6020A Calcium 1140 ug/L 05/29/15 17:2540.0EPA 6020A Chromium 1.4 ug/L 05/29/15 17:250.50EPA 6020A Cobalt 2.5 ug/L 05/29/15 17:250.50EPA 6020A Copper 3.8 ug/L 05/29/15 17:251.0EPA 6020A Iron 5980 ug/L 05/29/15 17:2550.0EPA 6020A Lead 1.0 ug/L 05/29/15 17:250.10EPA 6020A Magnesium 1670 ug/L 05/29/15 17:2510.0EPA 6020A Manganese 701 ug/L 05/31/15 10:182.5EPA 6020A Molybdenum 0.96 ug/L 05/29/15 17:250.50EPA 6020A Nickel 0.92 ug/L 05/29/15 17:250.50EPA 6020A Potassium 1650 ug/L 05/29/15 17:2550.0EPA 6020A Sodium 3740 ug/L 05/29/15 17:2550.0EPA 6020A Strontium 23.8 ug/L 05/29/15 17:250.50EPA 6020A Vanadium 7.2 ug/L 05/29/15 17:251.0EPA 6020A Zinc 38.7 ug/L 05/29/15 17:255.0EPA 6020A 92247383014 2015012328 SPLP Aluminum 3.2J ug/L 05/29/15 17:4410.0EPA 6020A Barium 55.5 ug/L 05/29/15 17:440.30EPA 6020A Boron 38.0 ug/L 05/29/15 17:445.0EPA 6020A Calcium 123 ug/L 05/29/15 17:4440.0EPA 6020A Chromium 0.23J ug/L 05/29/15 17:440.50EPA 6020A Cobalt 0.19J ug/L 05/29/15 17:440.50EPA 6020A Copper 0.74J ug/L 05/29/15 17:441.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 82 27 of 98 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92247383 J15040671 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92247383014 2015012328 SPLP Lead 0.053J ug/L 05/29/15 17:440.10EPA 6020A Magnesium 137 ug/L 05/29/15 17:4410.0EPA 6020A Manganese 3.3 ug/L 05/29/15 17:440.50EPA 6020A Nickel 0.34J ug/L 05/29/15 17:440.50EPA 6020A Potassium 96.5 ug/L 05/29/15 17:4450.0EPA 6020A Sodium 1250 ug/L 05/29/15 17:4450.0EPA 6020A Strontium 2.2 ug/L 05/29/15 17:440.50EPA 6020A Zinc 25.3 ug/L 05/29/15 17:445.0EPA 6020A 92247383015 2015012329 SPLP Aluminum 5.7J ug/L 05/29/15 17:4910.0EPA 6020A Barium 64.1 ug/L 05/29/15 17:490.30EPA 6020A Boron 47.3 ug/L 05/29/15 17:495.0EPA 6020A Calcium 148 ug/L 05/29/15 17:4940.0EPA 6020A Chromium 0.47J ug/L 05/29/15 17:490.50EPA 6020A Copper 1.0 ug/L 05/29/15 17:491.0EPA 6020A Lead 0.088J ug/L 05/29/15 17:490.10EPA 6020A Magnesium 100 ug/L 05/29/15 17:4910.0EPA 6020A Manganese 2.7 ug/L 05/29/15 17:490.50EPA 6020A Nickel 0.37J ug/L 05/29/15 17:490.50EPA 6020A Potassium 151 ug/L 05/29/15 17:4950.0EPA 6020A Sodium 1330 ug/L 05/29/15 17:4950.0EPA 6020A Strontium 3.5 ug/L 05/29/15 17:490.50EPA 6020A Zinc 23.6 ug/L 05/29/15 17:495.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 82 28 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 6010 Date:June 15, 2015 Description:6010 MET ICP General Information: 8 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23950 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1203100) • Aluminum • Iron • Molybdenum • MSD (Lab ID: 1203101) • Aluminum • Barium • Calcium • Iron • Manganese • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1203101) • Calcium • Molybdenum • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 82 29 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 6010 Date:June 15, 2015 Description:6010 MET ICP Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14654 Analyte Comments: QC Batch: MPRP/23950 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1203098) • Manganese • BLANK (Lab ID: 1203098) • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 82 30 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 6020 Date:June 15, 2015 Description:6020 MET ICPMS General Information: 8 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23951 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1203104) • Arsenic • Selenium • Thallium • Vanadium • MSD (Lab ID: 1203105) • Arsenic • Lead • Selenium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 82 31 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 6020 Date:June 15, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23951 N2: The lab does not hold TNI accreditation for this parameter. • 2015012320 (Lab ID: 92247383002) • Antimony • 2015012322 (Lab ID: 92247383004) • Antimony • 2015012324 (Lab ID: 92247383006) • Antimony • 2015012325 (Lab ID: 92247383007) • Antimony • 2015012326 (Lab ID: 92247383008) • Antimony • 2015012327 (Lab ID: 92247383009) • Antimony • 2015012328 (Lab ID: 92247383010) • Antimony • 2015012329 (Lab ID: 92247383011) • Antimony • BLANK (Lab ID: 1203102) • Antimony • LCS (Lab ID: 1203103) • Antimony • MS (Lab ID: 1203104) • Antimony • MSD (Lab ID: 1203105) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 82 32 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 6020A Date:June 15, 2015 Description:6020A MET ICPMS General Information: 7 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251147009 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1977700) • Boron • MSD (Lab ID: 1977701) • Boron QC Batch: MPRP/54062 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247374001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1953030) • Aluminum • MSD (Lab ID: 1953031) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 82 33 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 7470A Date:June 15, 2015 Description:7470A Mercury General Information: 7 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 82 34 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 7471 Date:June 15, 2015 Description:7471 Mercury General Information: 8 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5678 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1203120) • Mercury • MSD (Lab ID: 1203121) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 82 35 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 9045 Date:June 15, 2015 Description:9045 pH Soil General Information: 8 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37120 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1445735) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 82 36 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 300.0 Date:June 15, 2015 Description:300.0 IC Anions, SPLP General Information: 4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22924 B: Analyte was detected in the associated method blank. • BLANK for HBN 263861 [WETA/229 (Lab ID: 1459398) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/22924 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247374003,92247911005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1459402) • Sulfate • MSD (Lab ID: 1459403) • Sulfate Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 82 37 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 353.2 Date:June 15, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015012325 (Lab ID: 92247383007) • 2015012326 (Lab ID: 92247383008) • 2015012328 (Lab ID: 92247383010) • 2015012329 (Lab ID: 92247383011) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 82 38 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy SM 4500-Cl-E Date:June 15, 2015 Description:4500 Chloride, SPLP General Information: 4 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 82 39 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46021 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015012320 (Lab ID: 92247383002) • Chloride • Sulfate • 2015012322 (Lab ID: 92247383004) • Chloride • Sulfate • 2015012324 (Lab ID: 92247383006) • Chloride • Sulfate QC Batch: WETA/46023 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015012325 (Lab ID: 92247383007) • Chloride • Sulfate • 2015012326 (Lab ID: 92247383008) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 82 40 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions Analyte Comments: QC Batch: WETA/46023 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015012327 (Lab ID: 92247383009) • Chloride • Sulfate • 2015012328 (Lab ID: 92247383010) • Chloride • Sulfate • 2015012329 (Lab ID: 92247383011) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 82 41 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions 48hr General Information: 8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015012320 (Lab ID: 92247383002) • 2015012322 (Lab ID: 92247383004) • 2015012324 (Lab ID: 92247383006) • 2015012325 (Lab ID: 92247383007) • 2015012326 (Lab ID: 92247383008) • 2015012327 (Lab ID: 92247383009) • 2015012328 (Lab ID: 92247383010) • 2015012329 (Lab ID: 92247383011) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 82 42 of 98 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92247383 J15040671 Method: Client:Duke Energy EPA 9060 Date:June 15, 2015 Description:Total Organic Carbon Quad General Information: 8 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 82 43 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012319 Lab ID:92247383001 Collected:04/23/15 12:15 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 7.6J ug/L 05/06/15 09:10 7429-90-505/01/15 11:2810.0 3.0 1 Antimony ND ug/L 05/05/15 14:46 7440-36-005/01/15 11:280.50 0.15 1 Arsenic ND ug/L 05/05/15 14:46 7440-38-205/01/15 11:280.50 0.11 1 Barium 0.22J ug/L 05/05/15 14:46 7440-39-305/01/15 11:280.30 0.081 1 Beryllium ND ug/L 05/05/15 14:46 7440-41-705/01/15 11:280.20 0.067 1 Boron ND ug/L 05/05/15 14:46 7440-42-805/01/15 11:285.0 1.1 1 Cadmium ND ug/L 05/05/15 14:46 7440-43-905/01/15 11:280.080 0.024 1 Calcium 68.7 ug/L 05/05/15 14:46 7440-70-205/01/15 11:2840.0 16.0 1 Chromium 1.3 ug/L 05/05/15 14:46 7440-47-305/01/15 11:280.50 0.17 1 Cobalt 0.50J ug/L 05/05/15 14:46 7440-48-405/01/15 11:280.50 0.13 1 Copper 0.74J ug/L 05/05/15 14:46 7440-50-805/01/15 11:281.0 0.21 1 Iron 166 ug/L 05/05/15 14:46 7439-89-605/01/15 11:2850.0 13.7 1 Lead ND ug/L 05/05/15 14:46 7439-92-105/01/15 11:280.10 0.046 1 Magnesium 19.0 ug/L 05/05/15 14:46 7439-95-405/01/15 11:2810.0 3.2 1 Manganese 2.7 ug/L 05/05/15 14:46 7439-96-505/01/15 11:280.50 0.24 1 Molybdenum 0.32J ug/L 05/05/15 14:46 7439-98-705/01/15 11:280.50 0.094 1 Nickel 0.36J ug/L 05/05/15 14:46 7440-02-005/01/15 11:280.50 0.16 1 Potassium ND ug/L 05/05/15 14:46 7440-09-705/01/15 11:2850.0 11.7 1 Selenium ND ug/L 05/05/15 14:46 7782-49-205/01/15 11:280.50 0.20 1 Sodium ND ug/L 05/05/15 14:46 7440-23-505/01/15 11:2850.0 16.3 1 Strontium 0.26J ug/L 05/05/15 14:46 7440-24-605/01/15 11:280.50 0.13 1 Thallium ND ug/L 05/05/15 14:46 7440-28-005/01/15 11:280.10 0.015 1 Vanadium ND ug/L 05/05/15 14:46 7440-62-205/01/15 11:281.0 0.28 1 Zinc 4.9J ug/L 05/05/15 14:46 7440-66-605/01/15 11:285.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 05/04/15 16:40 7439-97-605/01/15 21:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 82 44 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012320 Lab ID:92247383002 Collected:04/23/15 12:30 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3080 mg/kg 05/07/15 10:38 7429-90-505/06/15 13:5025.5 12.8 5 Barium 21.5 mg/kg 05/07/15 10:38 7440-39-305/06/15 13:502.6 1.3 5 Beryllium 0.29 mg/kg 05/07/15 10:38 7440-41-705/06/15 13:500.26 0.13 5 Boron ND mg/kg 05/07/15 10:38 7440-42-805/06/15 13:5012.8 6.4 5 Calcium 68.5J mg/kg 05/07/15 10:38 7440-70-205/06/15 13:5012863.8 5 Chromium 4.1 mg/kg 05/07/15 10:38 7440-47-305/06/15 13:501.3 0.64 5 Copper 7.0 mg/kg 05/07/15 10:38 7440-50-805/06/15 13:501.3 0.64 5 Iron 7320 mg/kg 05/07/15 10:38 7439-89-605/06/15 13:5010.2 5.1 5 Magnesium 437 mg/kg 05/07/15 10:38 7439-95-405/06/15 13:5012863.8 5 Manganese 27.7 mg/kg 05/07/15 10:38 7439-96-505/06/15 13:501.3 0.64 5 Molybdenum ND mg/kg 05/07/15 10:38 7439-98-705/06/15 13:502.6 1.3 5 Nickel 0.68J mg/kg 05/07/15 10:38 7440-02-005/06/15 13:501.3 0.64 5 Potassium 315 mg/kg 05/07/15 10:38 7440-09-705/06/15 13:502551285 Sodium ND mg/kg 05/07/15 10:38 7440-23-505/06/15 13:502551285 Strontium 2.0J mg/kg 05/07/15 10:38 7440-24-605/06/15 13:502.6 1.3 5 Zinc 7.0 mg/kg 05/07/15 10:38 7440-66-605/06/15 13:505.1 2.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 17:54 7440-36-0 N205/06/15 13:505.1 2.6 100 Arsenic ND mg/kg 05/06/15 17:54 7440-38-205/06/15 13:505.1 2.6 100 Cadmium ND mg/kg 05/06/15 17:54 7440-43-905/06/15 13:500.61 0.31 100 Cobalt ND mg/kg 05/06/15 17:54 7440-48-405/06/15 13:505.1 2.6 100 Lead 5.4 mg/kg 05/06/15 17:54 7439-92-105/06/15 13:505.1 2.6 100 Selenium ND mg/kg 05/06/15 17:54 7782-49-205/06/15 13:505.1 2.6 100 Thallium ND mg/kg 05/06/15 17:54 7440-28-005/06/15 13:505.1 2.6 100 Vanadium 12.8 mg/kg 05/06/15 17:54 7440-62-205/06/15 13:505.1 2.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0073J mg/kg 05/07/15 13:57 7439-97-605/06/15 13:450.0086 0.0043 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 2.8 %05/13/15 10:290.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.6 Std. Units 04/29/15 14:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 03:18 16887-00-6 D32571295 Sulfate ND mg/kg 05/03/15 03:18 14808-79-8 D32571295 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 03:18 14797-55-8 H325.7 12.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 82 45 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012320 Lab ID:92247383002 Collected:04/23/15 12:30 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 485J mg/kg 05/18/15 09:33 7440-44-06133071 Total Organic Carbon 418J mg/kg 05/18/15 09:38 7440-44-06183091 Total Organic Carbon 383J mg/kg 05/18/15 09:45 7440-44-06123061 Total Organic Carbon 394J mg/kg 05/18/15 09:51 7440-44-06233111 Mean Total Organic Carbon 420J mg/kg 05/18/15 09:33 7440-44-06173081 Surrogates RSD%10.8 %05/18/15 09:331 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 82 46 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012321 Lab ID:92247383003 Collected:04/26/15 15:30 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 64.1 ug/L 05/06/15 09:52 7429-90-505/01/15 11:2810.0 3.0 1 Antimony ND ug/L 05/05/15 14:51 7440-36-005/01/15 11:280.50 0.15 1 Arsenic ND ug/L 05/05/15 14:51 7440-38-205/01/15 11:280.50 0.11 1 Barium 1.1 ug/L 05/05/15 14:51 7440-39-305/01/15 11:280.30 0.081 1 Beryllium ND ug/L 05/05/15 14:51 7440-41-705/01/15 11:280.20 0.067 1 Boron 7.3 ug/L 05/05/15 14:51 7440-42-805/01/15 11:285.0 1.1 1 Cadmium ND ug/L 05/05/15 14:51 7440-43-905/01/15 11:280.080 0.024 1 Calcium 971 ug/L 05/05/15 14:51 7440-70-205/01/15 11:2840.0 16.0 1 Chromium 1.8 ug/L 05/05/15 14:51 7440-47-305/01/15 11:280.50 0.17 1 Cobalt 7.6 ug/L 05/05/15 14:51 7440-48-405/01/15 11:280.50 0.13 1 Copper 1.3 ug/L 05/05/15 14:51 7440-50-805/01/15 11:281.0 0.21 1 Iron 663 ug/L 05/05/15 14:51 7439-89-605/01/15 11:2850.0 13.7 1 Lead 0.38 ug/L 05/05/15 14:51 7439-92-105/01/15 11:280.10 0.046 1 Magnesium 39.8 ug/L 05/05/15 14:51 7439-95-405/01/15 11:2810.0 3.2 1 Manganese 14.3 ug/L 05/05/15 14:51 7439-96-505/01/15 11:280.50 0.24 1 Molybdenum 0.21J ug/L 05/05/15 14:51 7439-98-705/01/15 11:280.50 0.094 1 Nickel 0.68 ug/L 05/05/15 14:51 7440-02-005/01/15 11:280.50 0.16 1 Potassium 22.0J ug/L 05/05/15 14:51 7440-09-705/01/15 11:2850.0 11.7 1 Selenium ND ug/L 05/05/15 14:51 7782-49-205/01/15 11:280.50 0.20 1 Sodium 20.0J ug/L 05/05/15 14:51 7440-23-505/01/15 11:2850.0 16.3 1 Strontium 1.7 ug/L 05/05/15 14:51 7440-24-605/01/15 11:280.50 0.13 1 Thallium ND ug/L 05/05/15 14:51 7440-28-005/01/15 11:280.10 0.015 1 Vanadium ND ug/L 05/05/15 14:51 7440-62-205/01/15 11:281.0 0.28 1 Zinc 9.0 ug/L 05/05/15 14:51 7440-66-605/01/15 11:285.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 05/04/15 16:43 7439-97-605/01/15 21:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 82 47 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012322 Lab ID:92247383004 Collected:04/26/15 15:45 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 11000 mg/kg 05/07/15 10:42 7429-90-505/06/15 13:5029.9 15.0 5 Barium 19.6 mg/kg 05/07/15 10:42 7440-39-305/06/15 13:503.0 1.5 5 Beryllium ND mg/kg 05/07/15 10:42 7440-41-705/06/15 13:500.30 0.15 5 Boron 27.4 mg/kg 05/07/15 10:42 7440-42-805/06/15 13:5015.0 7.5 5 Calcium ND mg/kg 05/07/15 10:42 7440-70-205/06/15 13:5015074.8 5 Chromium 43.6 mg/kg 05/07/15 10:42 7440-47-305/06/15 13:501.5 0.75 5 Copper 12.4 mg/kg 05/07/15 10:42 7440-50-805/06/15 13:501.5 0.75 5 Iron 31200 mg/kg 05/07/15 10:42 7439-89-605/06/15 13:5012.0 6.0 5 Magnesium 139J mg/kg 05/07/15 10:42 7439-95-405/06/15 13:5015074.8 5 Manganese 22.1 mg/kg 05/07/15 10:42 7439-96-505/06/15 13:501.5 0.75 5 Molybdenum ND mg/kg 05/07/15 10:42 7439-98-705/06/15 13:503.0 1.5 5 Nickel 0.83J mg/kg 05/07/15 10:42 7440-02-005/06/15 13:501.5 0.75 5 Potassium 182J mg/kg 05/07/15 10:42 7440-09-705/06/15 13:502991505 Sodium ND mg/kg 05/07/15 10:42 7440-23-505/06/15 13:502991505 Strontium ND mg/kg 05/07/15 10:42 7440-24-605/06/15 13:503.0 1.5 5 Zinc 5.2J mg/kg 05/07/15 10:42 7440-66-605/06/15 13:506.0 3.0 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 17:56 7440-36-0 N205/06/15 13:506.0 3.0 100 Arsenic 3.6J mg/kg 05/06/15 17:56 7440-38-205/06/15 13:506.0 3.0 100 Cadmium ND mg/kg 05/06/15 17:56 7440-43-905/06/15 13:500.72 0.36 100 Cobalt ND mg/kg 05/06/15 17:56 7440-48-405/06/15 13:506.0 3.0 100 Lead 6.8 mg/kg 05/06/15 17:56 7439-92-105/06/15 13:506.0 3.0 100 Selenium ND mg/kg 05/06/15 17:56 7782-49-205/06/15 13:506.0 3.0 100 Thallium ND mg/kg 05/06/15 17:56 7440-28-005/06/15 13:506.0 3.0 100 Vanadium 61.0 mg/kg 05/06/15 17:56 7440-62-205/06/15 13:506.0 3.0 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.036 mg/kg 05/07/15 13:59 7439-97-605/06/15 13:450.0093 0.0046 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 17.5 %05/13/15 10:290.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 4.9 Std. Units 04/29/15 14:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 03:39 16887-00-6 D33021515 Sulfate ND mg/kg 05/03/15 03:39 14808-79-8 D33021515 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 03:39 14797-55-8 H330.2 15.1 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 82 48 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012322 Lab ID:92247383004 Collected:04/26/15 15:45 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 848 mg/kg 05/20/15 11:04 7440-44-07243621 Total Organic Carbon 979 mg/kg 05/20/15 11:10 7440-44-07253631 Total Organic Carbon 1460 mg/kg 05/20/15 11:16 7440-44-07303651 Total Organic Carbon 1170 mg/kg 05/20/15 11:23 7440-44-07263631 Mean Total Organic Carbon 1110 mg/kg 05/20/15 11:04 7440-44-07263631 Surrogates RSD%23.7 %05/20/15 11:041 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 82 49 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012323 Lab ID:92247383005 Collected:04/25/15 13:40 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 13.5 ug/L 05/06/15 09:57 7429-90-505/01/15 11:2810.0 3.0 1 Antimony ND ug/L 05/05/15 14:56 7440-36-005/01/15 11:280.50 0.15 1 Arsenic ND ug/L 05/05/15 14:56 7440-38-205/01/15 11:280.50 0.11 1 Barium 0.30 ug/L 05/05/15 14:56 7440-39-305/01/15 11:280.30 0.081 1 Beryllium ND ug/L 05/05/15 14:56 7440-41-705/01/15 11:280.20 0.067 1 Boron ND ug/L 05/05/15 14:56 7440-42-805/01/15 11:285.0 1.1 1 Cadmium ND ug/L 05/05/15 14:56 7440-43-905/01/15 11:280.080 0.024 1 Calcium 65.9 ug/L 05/05/15 14:56 7440-70-205/01/15 11:2840.0 16.0 1 Chromium 0.58 ug/L 05/05/15 14:56 7440-47-305/01/15 11:280.50 0.17 1 Cobalt 1.0 ug/L 05/05/15 14:56 7440-48-405/01/15 11:280.50 0.13 1 Copper 0.44J ug/L 05/05/15 14:56 7440-50-805/01/15 11:281.0 0.21 1 Iron 96.7 ug/L 05/05/15 14:56 7439-89-605/01/15 11:2850.0 13.7 1 Lead ND ug/L 05/05/15 14:56 7439-92-105/01/15 11:280.10 0.046 1 Magnesium 14.2 ug/L 05/05/15 14:56 7439-95-405/01/15 11:2810.0 3.2 1 Manganese 1.7 ug/L 05/05/15 14:56 7439-96-505/01/15 11:280.50 0.24 1 Molybdenum 0.14J ug/L 05/05/15 14:56 7439-98-705/01/15 11:280.50 0.094 1 Nickel ND ug/L 05/05/15 14:56 7440-02-005/01/15 11:280.50 0.16 1 Potassium ND ug/L 05/05/15 14:56 7440-09-705/01/15 11:2850.0 11.7 1 Selenium ND ug/L 05/05/15 14:56 7782-49-205/01/15 11:280.50 0.20 1 Sodium ND ug/L 05/05/15 14:56 7440-23-505/01/15 11:2850.0 16.3 1 Strontium 0.15J ug/L 05/05/15 14:56 7440-24-605/01/15 11:280.50 0.13 1 Thallium ND ug/L 05/05/15 14:56 7440-28-005/01/15 11:280.10 0.015 1 Vanadium ND ug/L 05/05/15 14:56 7440-62-205/01/15 11:281.0 0.28 1 Zinc ND ug/L 05/05/15 14:56 7440-66-605/01/15 11:285.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 05/04/15 16:45 7439-97-605/01/15 21:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 82 50 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012324 Lab ID:92247383006 Collected:04/25/15 14:10 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 5360 mg/kg 05/07/15 10:59 7429-90-505/06/15 13:5032.4 16.2 5 Barium 95.4 mg/kg 05/07/15 10:59 7440-39-305/06/15 13:503.2 1.6 5 Beryllium 0.40 mg/kg 05/07/15 10:59 7440-41-705/06/15 13:500.32 0.16 5 Boron ND mg/kg 05/07/15 10:59 7440-42-805/06/15 13:5016.2 8.1 5 Calcium 253 mg/kg 05/07/15 10:59 7440-70-205/06/15 13:5016280.9 5 Chromium 7.6 mg/kg 05/07/15 10:59 7440-47-305/06/15 13:501.6 0.81 5 Copper 4.3 mg/kg 05/07/15 10:59 7440-50-805/06/15 13:501.6 0.81 5 Iron 7710 mg/kg 05/07/15 10:59 7439-89-605/06/15 13:5012.9 6.5 5 Magnesium 454 mg/kg 05/07/15 10:59 7439-95-405/06/15 13:5016280.9 5 Manganese 1250 mg/kg 05/07/15 10:59 7439-96-505/06/15 13:501.6 0.81 5 Molybdenum ND mg/kg 05/07/15 10:59 7439-98-705/06/15 13:503.2 1.6 5 Nickel 1.9 mg/kg 05/07/15 10:59 7440-02-005/06/15 13:501.6 0.81 5 Potassium 254J mg/kg 05/07/15 10:59 7440-09-705/06/15 13:503241625 Sodium ND mg/kg 05/07/15 10:59 7440-23-505/06/15 13:503241625 Strontium 3.2J mg/kg 05/07/15 10:59 7440-24-605/06/15 13:503.2 1.6 5 Zinc 10.4 mg/kg 05/07/15 10:59 7440-66-605/06/15 13:506.5 3.2 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 18:06 7440-36-0 N205/06/15 13:506.5 3.2 100 Arsenic ND mg/kg 05/06/15 18:06 7440-38-205/06/15 13:506.5 3.2 100 Cadmium ND mg/kg 05/06/15 18:06 7440-43-905/06/15 13:500.78 0.39 100 Cobalt 6.0J mg/kg 05/06/15 18:06 7440-48-405/06/15 13:506.5 3.2 100 Lead 6.3J mg/kg 05/06/15 18:06 7439-92-105/06/15 13:506.5 3.2 100 Selenium ND mg/kg 05/06/15 18:06 7782-49-205/06/15 13:506.5 3.2 100 Thallium ND mg/kg 05/06/15 18:06 7440-28-005/06/15 13:506.5 3.2 100 Vanadium 17.3 mg/kg 05/06/15 18:06 7440-62-205/06/15 13:506.5 3.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.012 mg/kg 05/07/15 14:02 7439-97-605/06/15 13:450.011 0.0055 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 24.9 %05/13/15 10:290.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.1 Std. Units 04/29/15 14:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 04:00 16887-00-6 D33331665 Sulfate ND mg/kg 05/03/15 04:00 14808-79-8 D33331665 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 04:00 14797-55-8 H333.3 16.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 82 51 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012324 Lab ID:92247383006 Collected:04/25/15 14:10 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 2880 mg/kg 05/20/15 12:17 7440-44-08004001 Total Organic Carbon 3740 mg/kg 05/20/15 12:24 7440-44-07963981 Total Organic Carbon 3380 mg/kg 05/20/15 12:29 7440-44-08044021 Total Organic Carbon 3410 mg/kg 05/20/15 12:34 7440-44-08014011 Mean Total Organic Carbon 3350 mg/kg 05/20/15 12:17 7440-44-08004001 Surrogates RSD%10.6 %05/20/15 12:171 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 82 52 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012325 Lab ID:92247383007 Collected:04/25/15 17:30 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 9030 mg/kg 05/07/15 11:04 7429-90-505/06/15 13:5037.6 18.8 5 Barium 131 mg/kg 05/07/15 11:04 7440-39-305/06/15 13:503.8 1.9 5 Beryllium 0.36J mg/kg 05/07/15 11:04 7440-41-705/06/15 13:500.38 0.19 5 Boron 16.8J mg/kg 05/07/15 11:04 7440-42-805/06/15 13:5018.8 9.4 5 Calcium 4470 mg/kg 05/07/15 11:04 7440-70-205/06/15 13:5018894.0 5 Chromium 9.2 mg/kg 05/07/15 11:04 7440-47-305/06/15 13:501.9 0.94 5 Copper 126 mg/kg 05/07/15 11:04 7440-50-805/06/15 13:501.9 0.94 5 Iron 19100 mg/kg 05/07/15 11:04 7439-89-605/06/15 13:5015.0 7.5 5 Magnesium 5220 mg/kg 05/07/15 11:04 7439-95-405/06/15 13:5018894.0 5 Manganese 1630 mg/kg 05/07/15 11:04 7439-96-505/06/15 13:501.9 0.94 5 Molybdenum 2.9J mg/kg 05/07/15 11:04 7439-98-705/06/15 13:503.8 1.9 5 Nickel 2.9 mg/kg 05/07/15 11:04 7440-02-005/06/15 13:501.9 0.94 5 Potassium 2890 mg/kg 05/07/15 11:04 7440-09-705/06/15 13:503761885 Sodium 384 mg/kg 05/07/15 11:04 7440-23-505/06/15 13:503761885 Strontium 37.5 mg/kg 05/07/15 11:04 7440-24-605/06/15 13:503.8 1.9 5 Zinc 54.6 mg/kg 05/07/15 11:04 7440-66-605/06/15 13:507.5 3.8 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 18:08 7440-36-0 N205/06/15 13:507.5 3.8 100 Arsenic ND mg/kg 05/06/15 18:08 7440-38-205/06/15 13:507.5 3.8 100 Cadmium ND mg/kg 05/06/15 18:08 7440-43-905/06/15 13:500.90 0.45 100 Cobalt 12.0 mg/kg 05/06/15 18:08 7440-48-405/06/15 13:507.5 3.8 100 Lead 3.8J mg/kg 05/06/15 18:08 7439-92-105/06/15 13:507.5 3.8 100 Selenium ND mg/kg 05/06/15 18:08 7782-49-205/06/15 13:507.5 3.8 100 Thallium ND mg/kg 05/06/15 18:08 7440-28-005/06/15 13:507.5 3.8 100 Vanadium 16.3 mg/kg 05/06/15 18:08 7440-62-205/06/15 13:507.5 3.8 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/07/15 14:04 7439-97-605/06/15 13:450.012 0.0059 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 30.7 %05/13/15 10:300.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.1 Std. Units 04/29/15 14:500.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/07/15 03:30300.0 IC Anions, SPLP Sulfate 5.4 mg/L 05/14/15 19:29 14808-79-8 B2.9 1.4 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/07/15 03:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 05/15/15 21:08 H10.29 0.29 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/07/15 03:304500 Chloride, SPLP Chloride ND mg/L 05/14/15 05:50 16887-00-67.2 3.6 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 82 53 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012325 Lab ID:92247383007 Collected:04/25/15 17:30 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 05:47 16887-00-6 D3,M13591795 Sulfate ND mg/kg 05/03/15 05:47 14808-79-8 D33591795 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 05:47 14797-55-8 H335.9 17.9 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/20/15 14:27 7440-44-08614311 Total Organic Carbon ND mg/kg 05/20/15 14:33 7440-44-08714351 Total Organic Carbon ND mg/kg 05/20/15 14:38 7440-44-08714361 Total Organic Carbon ND mg/kg 05/20/15 14:44 7440-44-08644321 Mean Total Organic Carbon ND mg/kg 05/20/15 14:27 7440-44-08674331 Surrogates RSD%3.0 %05/20/15 14:271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 82 54 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012326 Lab ID:92247383008 Collected:04/26/15 09:00 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4860 mg/kg 05/07/15 11:08 7429-90-505/06/15 13:5025.0 12.5 5 Barium 28.2 mg/kg 05/07/15 11:08 7440-39-305/06/15 13:502.5 1.3 5 Beryllium 0.20J mg/kg 05/07/15 11:08 7440-41-705/06/15 13:500.25 0.13 5 Boron 10.0J mg/kg 05/07/15 11:08 7440-42-805/06/15 13:5012.5 6.3 5 Calcium 2710 mg/kg 05/07/15 11:08 7440-70-205/06/15 13:5012562.6 5 Chromium 2.1 mg/kg 05/07/15 11:08 7440-47-305/06/15 13:501.3 0.63 5 Copper 5.3 mg/kg 05/07/15 11:08 7440-50-805/06/15 13:501.3 0.63 5 Iron 10600 mg/kg 05/07/15 11:08 7439-89-605/06/15 13:5010.0 5.0 5 Magnesium 3200 mg/kg 05/07/15 11:08 7439-95-405/06/15 13:5012562.6 5 Manganese 885 mg/kg 05/07/15 11:08 7439-96-505/06/15 13:501.3 0.63 5 Molybdenum ND mg/kg 05/07/15 11:08 7439-98-705/06/15 13:502.5 1.3 5 Nickel 1.2J mg/kg 05/07/15 11:08 7440-02-005/06/15 13:501.3 0.63 5 Potassium 1390 mg/kg 05/07/15 11:08 7440-09-705/06/15 13:502501255 Sodium 182J mg/kg 05/07/15 11:08 7440-23-505/06/15 13:502501255 Strontium 23.3 mg/kg 05/07/15 11:08 7440-24-605/06/15 13:502.5 1.3 5 Zinc 35.6 mg/kg 05/07/15 11:08 7440-66-605/06/15 13:505.0 2.5 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 18:11 7440-36-0 N205/06/15 13:505.0 2.5 100 Arsenic ND mg/kg 05/06/15 18:11 7440-38-205/06/15 13:505.0 2.5 100 Cadmium ND mg/kg 05/06/15 18:11 7440-43-905/06/15 13:500.60 0.30 100 Cobalt 4.6J mg/kg 05/06/15 18:11 7440-48-405/06/15 13:505.0 2.5 100 Lead ND mg/kg 05/06/15 18:11 7439-92-105/06/15 13:505.0 2.5 100 Selenium ND mg/kg 05/06/15 18:11 7782-49-205/06/15 13:505.0 2.5 100 Thallium ND mg/kg 05/06/15 18:11 7440-28-005/06/15 13:505.0 2.5 100 Vanadium 8.4 mg/kg 05/06/15 18:11 7440-62-205/06/15 13:505.0 2.5 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/07/15 14:06 7439-97-605/06/15 13:450.0083 0.0042 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 2.4 %05/13/15 10:300.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.8 Std. Units 05/04/15 14:000.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/07/15 03:30300.0 IC Anions, SPLP Sulfate 3.8 mg/L 05/14/15 19:43 14808-79-8 B2.0 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/07/15 03:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 05/15/15 21:09 H10.20 0.20 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/07/15 03:304500 Chloride, SPLP Chloride ND mg/L 05/14/15 05:51 16887-00-65.1 2.6 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 82 55 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012326 Lab ID:92247383008 Collected:04/26/15 09:00 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 06:52 16887-00-6 D32561285 Sulfate ND mg/kg 05/03/15 06:52 14808-79-8 D32561285 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 06:52 14797-55-8 H325.6 12.8 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/20/15 14:50 7440-44-06193101 Total Organic Carbon ND mg/kg 05/20/15 14:56 7440-44-06193091 Total Organic Carbon ND mg/kg 05/20/15 15:01 7440-44-06133071 Total Organic Carbon ND mg/kg 05/20/15 15:07 7440-44-06133061 Mean Total Organic Carbon ND mg/kg 05/20/15 14:50 7440-44-06163081 Surrogates RSD%2.7 %05/20/15 14:501 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 82 56 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012327 Lab ID:92247383009 Collected:04/26/15 15:50 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 24500 mg/kg 05/07/15 11:12 7429-90-505/06/15 13:5025.8 12.9 5 Barium 237 mg/kg 05/07/15 11:12 7440-39-305/06/15 13:502.6 1.3 5 Beryllium 0.40 mg/kg 05/07/15 11:12 7440-41-705/06/15 13:500.26 0.13 5 Boron 32.3 mg/kg 05/07/15 11:12 7440-42-805/06/15 13:5012.9 6.4 5 Calcium 19400 mg/kg 05/07/15 11:12 7440-70-205/06/15 13:5012964.4 5 Chromium 37.2 mg/kg 05/07/15 11:12 7440-47-305/06/15 13:501.3 0.64 5 Copper 26.7 mg/kg 05/07/15 11:12 7440-50-805/06/15 13:501.3 0.64 5 Iron 38300 mg/kg 05/07/15 11:12 7439-89-605/06/15 13:5010.3 5.2 5 Magnesium 21800 mg/kg 05/07/15 11:12 7439-95-405/06/15 13:5012964.4 5 Manganese 1010 mg/kg 05/07/15 11:12 7439-96-505/06/15 13:501.3 0.64 5 Molybdenum ND mg/kg 05/07/15 11:12 7439-98-705/06/15 13:502.6 1.3 5 Nickel 28.1 mg/kg 05/07/15 11:12 7440-02-005/06/15 13:501.3 0.64 5 Potassium 16600 mg/kg 05/07/15 11:12 7440-09-705/06/15 13:502581295 Sodium 261 mg/kg 05/07/15 11:12 7440-23-505/06/15 13:502581295 Strontium 40.0 mg/kg 05/07/15 11:12 7440-24-605/06/15 13:502.6 1.3 5 Zinc 101 mg/kg 05/07/15 11:12 7440-66-605/06/15 13:505.2 2.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 18:13 7440-36-0 N205/06/15 13:505.2 2.6 100 Arsenic ND mg/kg 05/06/15 18:13 7440-38-205/06/15 13:505.2 2.6 100 Cadmium ND mg/kg 05/06/15 18:13 7440-43-905/06/15 13:500.62 0.31 100 Cobalt 19.6 mg/kg 05/06/15 18:13 7440-48-405/06/15 13:505.2 2.6 100 Lead ND mg/kg 05/06/15 18:13 7439-92-105/06/15 13:505.2 2.6 100 Selenium ND mg/kg 05/06/15 18:13 7782-49-205/06/15 13:505.2 2.6 100 Thallium ND mg/kg 05/06/15 18:13 7440-28-005/06/15 13:505.2 2.6 100 Vanadium 87.0 mg/kg 05/06/15 18:13 7440-62-205/06/15 13:505.2 2.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/07/15 14:08 7439-97-605/06/15 13:450.0089 0.0044 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 6.5 %05/13/15 10:300.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 9.6 Std. Units 05/04/15 14:000.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 07:13 16887-00-6 D32661335 Sulfate ND mg/kg 05/03/15 07:13 14808-79-8 D32661335 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 07:13 14797-55-8 H326.6 13.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 82 57 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012327 Lab ID:92247383009 Collected:04/26/15 15:50 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/20/15 15:12 7440-44-06433211 Total Organic Carbon ND mg/kg 05/20/15 15:18 7440-44-06413201 Total Organic Carbon ND mg/kg 05/20/15 15:23 7440-44-06453231 Total Organic Carbon ND mg/kg 05/20/15 15:30 7440-44-06473231 Mean Total Organic Carbon ND mg/kg 05/20/15 15:12 7440-44-06443221 Surrogates RSD%12.2 %05/20/15 15:121 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 82 58 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012328 Lab ID:92247383010 Collected:04/27/15 08:30 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3530 mg/kg 05/07/15 11:17 7429-90-505/06/15 13:5029.9 14.9 5 Barium 67.4 mg/kg 05/07/15 11:17 7440-39-305/06/15 13:503.0 1.5 5 Beryllium ND mg/kg 05/07/15 11:17 7440-41-705/06/15 13:500.30 0.15 5 Boron 9.8J mg/kg 05/07/15 11:17 7440-42-805/06/15 13:5014.9 7.5 5 Calcium ND mg/kg 05/07/15 11:17 7440-70-205/06/15 13:5014974.7 5 Chromium 3.2 mg/kg 05/07/15 11:17 7440-47-305/06/15 13:501.5 0.75 5 Copper 22.4 mg/kg 05/07/15 11:17 7440-50-805/06/15 13:501.5 0.75 5 Iron 11900 mg/kg 05/07/15 11:17 7439-89-605/06/15 13:5012.0 6.0 5 Magnesium 1190 mg/kg 05/07/15 11:17 7439-95-405/06/15 13:5014974.7 5 Manganese 395 mg/kg 05/07/15 11:17 7439-96-505/06/15 13:501.5 0.75 5 Molybdenum ND mg/kg 05/07/15 11:17 7439-98-705/06/15 13:503.0 1.5 5 Nickel ND mg/kg 05/07/15 11:17 7440-02-005/06/15 13:501.5 0.75 5 Potassium 1520 mg/kg 05/07/15 11:17 7440-09-705/06/15 13:502991495 Sodium ND mg/kg 05/07/15 11:17 7440-23-505/06/15 13:502991495 Strontium ND mg/kg 05/07/15 11:17 7440-24-605/06/15 13:503.0 1.5 5 Zinc 15.0 mg/kg 05/07/15 11:17 7440-66-605/06/15 13:506.0 3.0 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 18:15 7440-36-0 N205/06/15 13:506.0 3.0 100 Arsenic ND mg/kg 05/06/15 18:15 7440-38-205/06/15 13:506.0 3.0 100 Cadmium ND mg/kg 05/06/15 18:15 7440-43-905/06/15 13:500.72 0.36 100 Cobalt 6.0 mg/kg 05/06/15 18:15 7440-48-405/06/15 13:506.0 3.0 100 Lead 7.2 mg/kg 05/06/15 18:15 7439-92-105/06/15 13:506.0 3.0 100 Selenium ND mg/kg 05/06/15 18:15 7782-49-205/06/15 13:506.0 3.0 100 Thallium ND mg/kg 05/06/15 18:15 7440-28-005/06/15 13:506.0 3.0 100 Vanadium 8.2 mg/kg 05/06/15 18:15 7440-62-205/06/15 13:506.0 3.0 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/07/15 14:10 7439-97-605/06/15 13:450.0095 0.0047 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 16.8 %05/13/15 10:30 D60.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.9 Std. Units 05/04/15 14:000.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/07/15 03:30300.0 IC Anions, SPLP Sulfate 3.1 mg/L 05/14/15 19:56 14808-79-8 B2.4 1.2 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/07/15 03:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.25 mg/L 05/15/15 21:10 H10.24 0.24 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/07/15 03:304500 Chloride, SPLP Chloride ND mg/L 05/14/15 05:52 16887-00-66.0 3.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 82 59 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012328 Lab ID:92247383010 Collected:04/27/15 08:30 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 07:34 16887-00-6 D33011505 Sulfate ND mg/kg 05/03/15 07:34 14808-79-8 D33011505 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 07:34 14797-55-8 H330.1 15.0 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/20/15 15:35 7440-44-07233621 Total Organic Carbon ND mg/kg 05/20/15 15:41 7440-44-07193591 Total Organic Carbon ND mg/kg 05/20/15 15:48 7440-44-07243621 Total Organic Carbon ND mg/kg 05/20/15 15:53 7440-44-07193591 Mean Total Organic Carbon ND mg/kg 05/20/15 15:35 7440-44-07213611 Surrogates RSD%2.3 %05/20/15 15:351 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 82 60 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012329 Lab ID:92247383011 Collected:04/27/15 08:45 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4410 mg/kg 05/07/15 11:21 7429-90-505/06/15 13:5031.3 15.6 5 Barium 81.5 mg/kg 05/07/15 11:21 7440-39-305/06/15 13:503.1 1.6 5 Beryllium 0.25J mg/kg 05/07/15 11:21 7440-41-705/06/15 13:500.31 0.16 5 Boron 9.2J mg/kg 05/07/15 11:21 7440-42-805/06/15 13:5015.6 7.8 5 Calcium ND mg/kg 05/07/15 11:21 7440-70-205/06/15 13:5015678.2 5 Chromium 1.9 mg/kg 05/07/15 11:21 7440-47-305/06/15 13:501.6 0.78 5 Copper 19.1 mg/kg 05/07/15 11:21 7440-50-805/06/15 13:501.6 0.78 5 Iron 10700 mg/kg 05/07/15 11:21 7439-89-605/06/15 13:5012.5 6.3 5 Magnesium 1410 mg/kg 05/07/15 11:21 7439-95-405/06/15 13:5015678.2 5 Manganese 855 mg/kg 05/07/15 11:21 7439-96-505/06/15 13:501.6 0.78 5 Molybdenum ND mg/kg 05/07/15 11:21 7439-98-705/06/15 13:503.1 1.6 5 Nickel 1.4J mg/kg 05/07/15 11:21 7440-02-005/06/15 13:501.6 0.78 5 Potassium 1680 mg/kg 05/07/15 11:21 7440-09-705/06/15 13:503131565 Sodium ND mg/kg 05/07/15 11:21 7440-23-505/06/15 13:503131565 Strontium 4.6 mg/kg 05/07/15 11:21 7440-24-605/06/15 13:503.1 1.6 5 Zinc 27.7 mg/kg 05/07/15 11:21 7440-66-605/06/15 13:506.3 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 05/06/15 18:18 7440-36-0 N205/06/15 13:506.3 3.1 100 Arsenic ND mg/kg 05/06/15 18:18 7440-38-205/06/15 13:506.3 3.1 100 Cadmium ND mg/kg 05/06/15 18:18 7440-43-905/06/15 13:500.75 0.38 100 Cobalt 9.2 mg/kg 05/06/15 18:18 7440-48-405/06/15 13:506.3 3.1 100 Lead 9.2 mg/kg 05/06/15 18:18 7439-92-105/06/15 13:506.3 3.1 100 Selenium ND mg/kg 05/06/15 18:18 7782-49-205/06/15 13:506.3 3.1 100 Thallium ND mg/kg 05/06/15 18:18 7440-28-005/06/15 13:506.3 3.1 100 Vanadium 7.7 mg/kg 05/06/15 18:18 7440-62-205/06/15 13:506.3 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 05/07/15 14:17 7439-97-605/06/15 13:450.010 0.0050 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 20.3 %05/13/15 10:300.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.5 Std. Units 05/04/15 14:000.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/08/15 03:30300.0 IC Anions, SPLP Sulfate 3.4 mg/L 05/14/15 20:10 14808-79-8 B2.5 1.3 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/08/15 03:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 05/15/15 21:11 H10.25 0.25 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 05/08/15 03:304500 Chloride, SPLP Chloride ND mg/L 05/14/15 05:53 16887-00-66.3 3.1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 82 61 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012329 Lab ID:92247383011 Collected:04/27/15 08:45 Received:04/28/15 14:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/03/15 07:56 16887-00-6 D33131565 Sulfate ND mg/kg 05/03/15 07:56 14808-79-8 D33131565 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/03/15 07:56 14797-55-8 H331.3 15.6 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/20/15 16:00 7440-44-07553781 Total Organic Carbon ND mg/kg 05/20/15 16:06 7440-44-07483741 Total Organic Carbon ND mg/kg 05/20/15 16:13 7440-44-07533771 Total Organic Carbon ND mg/kg 05/20/15 16:19 7440-44-07533771 Mean Total Organic Carbon ND mg/kg 05/20/15 16:00 7440-44-07533761 Surrogates RSD%1.8 %05/20/15 16:001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 82 62 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012325 SPLP Lab ID:92247383012 Collected:04/25/15 17:30 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 13200 ug/L 05/29/15 17:20 7429-90-505/28/15 21:1210.0 3.0 1 Antimony ND ug/L 05/29/15 17:20 7440-36-005/28/15 21:120.50 0.15 1 Arsenic 2.8 ug/L 05/29/15 17:20 7440-38-205/28/15 21:120.50 0.11 1 Barium 360 ug/L 05/29/15 17:20 7440-39-305/28/15 21:120.30 0.081 1 Beryllium 0.48 ug/L 05/29/15 17:20 7440-41-705/28/15 21:120.20 0.067 1 Boron 32.7 ug/L 05/29/15 17:20 7440-42-805/28/15 21:125.0 1.1 1 Cadmium 0.062J ug/L 05/29/15 17:20 7440-43-905/28/15 21:120.080 0.024 1 Calcium 3370 ug/L 05/29/15 17:20 7440-70-205/28/15 21:1240.0 16.0 1 Chromium 8.8 ug/L 05/29/15 17:20 7440-47-305/28/15 21:120.50 0.17 1 Cobalt 12.7 ug/L 05/29/15 17:20 7440-48-405/28/15 21:120.50 0.13 1 Copper 155 ug/L 05/29/15 17:20 7440-50-805/28/15 21:121.0 0.21 1 Iron 21000 ug/L 05/29/15 17:20 7439-89-605/28/15 21:1250.0 13.7 1 Lead 5.6 ug/L 05/29/15 17:20 7439-92-105/28/15 21:120.10 0.046 1 Magnesium 4960 ug/L 05/29/15 17:20 7439-95-405/28/15 21:1210.0 3.2 1 Manganese 1990 ug/L 05/31/15 10:13 7439-96-505/28/15 21:1210.0 4.8 20 Molybdenum 10.9 ug/L 05/29/15 17:20 7439-98-705/28/15 21:120.50 0.094 1 Nickel 4.2 ug/L 05/29/15 17:20 7440-02-005/28/15 21:120.50 0.16 1 Potassium 3800 ug/L 05/29/15 17:20 7440-09-705/28/15 21:1250.0 11.7 1 Selenium 2.1 ug/L 05/29/15 17:20 7782-49-205/28/15 21:120.50 0.20 1 Sodium 3900 ug/L 05/29/15 17:20 7440-23-505/28/15 21:1250.0 16.3 1 Strontium 47.0 ug/L 05/29/15 17:20 7440-24-605/28/15 21:120.50 0.13 1 Thallium 0.045J ug/L 05/29/15 17:20 7440-28-005/28/15 21:120.10 0.015 1 Vanadium 18.5 ug/L 05/29/15 17:20 7440-62-205/28/15 21:121.0 0.28 1 Zinc 90.9 ug/L 05/29/15 17:20 7440-66-605/28/15 21:125.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 13:09 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 82 63 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012326 SPLP Lab ID:92247383013 Collected:04/26/15 09:00 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 4500 ug/L 05/29/15 17:25 7429-90-505/28/15 21:1210.0 3.0 1 Antimony ND ug/L 05/29/15 17:25 7440-36-005/28/15 21:120.50 0.15 1 Arsenic 0.19J ug/L 05/29/15 17:25 7440-38-205/28/15 21:120.50 0.11 1 Barium 126 ug/L 05/29/15 17:25 7440-39-305/28/15 21:120.30 0.081 1 Beryllium 0.18J ug/L 05/29/15 17:25 7440-41-705/28/15 21:120.20 0.067 1 Boron 30.2 ug/L 05/29/15 17:25 7440-42-805/28/15 21:125.0 1.1 1 Cadmium ND ug/L 05/29/15 17:25 7440-43-905/28/15 21:120.080 0.024 1 Calcium 1140 ug/L 05/29/15 17:25 7440-70-205/28/15 21:1240.0 16.0 1 Chromium 1.4 ug/L 05/29/15 17:25 7440-47-305/28/15 21:120.50 0.17 1 Cobalt 2.5 ug/L 05/29/15 17:25 7440-48-405/28/15 21:120.50 0.13 1 Copper 3.8 ug/L 05/29/15 17:25 7440-50-805/28/15 21:121.0 0.21 1 Iron 5980 ug/L 05/29/15 17:25 7439-89-605/28/15 21:1250.0 13.7 1 Lead 1.0 ug/L 05/29/15 17:25 7439-92-105/28/15 21:120.10 0.046 1 Magnesium 1670 ug/L 05/29/15 17:25 7439-95-405/28/15 21:1210.0 3.2 1 Manganese 701 ug/L 05/31/15 10:18 7439-96-505/28/15 21:122.5 1.2 5 Molybdenum 0.96 ug/L 05/29/15 17:25 7439-98-705/28/15 21:120.50 0.094 1 Nickel 0.92 ug/L 05/29/15 17:25 7440-02-005/28/15 21:120.50 0.16 1 Potassium 1650 ug/L 05/29/15 17:25 7440-09-705/28/15 21:1250.0 11.7 1 Selenium ND ug/L 05/29/15 17:25 7782-49-205/28/15 21:120.50 0.20 1 Sodium 3740 ug/L 05/29/15 17:25 7440-23-505/28/15 21:1250.0 16.3 1 Strontium 23.8 ug/L 05/29/15 17:25 7440-24-605/28/15 21:120.50 0.13 1 Thallium ND ug/L 05/29/15 17:25 7440-28-005/28/15 21:120.10 0.015 1 Vanadium 7.2 ug/L 05/29/15 17:25 7440-62-205/28/15 21:121.0 0.28 1 Zinc 38.7 ug/L 05/29/15 17:25 7440-66-605/28/15 21:125.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 13:11 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 82 64 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012328 SPLP Lab ID:92247383014 Collected:04/27/15 08:30 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 3.2J ug/L 05/29/15 17:44 7429-90-505/28/15 21:1210.0 3.0 1 Antimony ND ug/L 05/29/15 17:44 7440-36-005/28/15 21:120.50 0.15 1 Arsenic ND ug/L 05/29/15 17:44 7440-38-205/28/15 21:120.50 0.11 1 Barium 55.5 ug/L 05/29/15 17:44 7440-39-305/28/15 21:120.30 0.081 1 Beryllium ND ug/L 05/29/15 17:44 7440-41-705/28/15 21:120.20 0.067 1 Boron 38.0 ug/L 05/29/15 17:44 7440-42-805/28/15 21:125.0 1.1 1 Cadmium ND ug/L 05/29/15 17:44 7440-43-905/28/15 21:120.080 0.024 1 Calcium 123 ug/L 05/29/15 17:44 7440-70-205/28/15 21:1240.0 16.0 1 Chromium 0.23J ug/L 05/29/15 17:44 7440-47-305/28/15 21:120.50 0.17 1 Cobalt 0.19J ug/L 05/29/15 17:44 7440-48-405/28/15 21:120.50 0.13 1 Copper 0.74J ug/L 05/29/15 17:44 7440-50-805/28/15 21:121.0 0.21 1 Iron ND ug/L 05/29/15 17:44 7439-89-605/28/15 21:1250.0 13.7 1 Lead 0.053J ug/L 05/29/15 17:44 7439-92-105/28/15 21:120.10 0.046 1 Magnesium 137 ug/L 05/29/15 17:44 7439-95-405/28/15 21:1210.0 3.2 1 Manganese 3.3 ug/L 05/29/15 17:44 7439-96-505/28/15 21:120.50 0.24 1 Molybdenum ND ug/L 05/29/15 17:44 7439-98-705/28/15 21:120.50 0.094 1 Nickel 0.34J ug/L 05/29/15 17:44 7440-02-005/28/15 21:120.50 0.16 1 Potassium 96.5 ug/L 05/29/15 17:44 7440-09-705/28/15 21:1250.0 11.7 1 Selenium ND ug/L 05/29/15 17:44 7782-49-205/28/15 21:120.50 0.20 1 Sodium 1250 ug/L 05/29/15 17:44 7440-23-505/28/15 21:1250.0 16.3 1 Strontium 2.2 ug/L 05/29/15 17:44 7440-24-605/28/15 21:120.50 0.13 1 Thallium ND ug/L 05/29/15 17:44 7440-28-005/28/15 21:120.10 0.015 1 Vanadium ND ug/L 05/29/15 17:44 7440-62-205/28/15 21:121.0 0.28 1 Zinc 25.3 ug/L 05/29/15 17:44 7440-66-605/28/15 21:125.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 13:14 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 82 65 of 98 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92247383 J15040671 Sample:2015012329 SPLP Lab ID:92247383015 Collected:04/27/15 08:45 Received:04/28/15 14:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 5.7J ug/L 05/29/15 17:49 7429-90-505/28/15 21:1210.0 3.0 1 Antimony ND ug/L 05/29/15 17:49 7440-36-005/28/15 21:120.50 0.15 1 Arsenic ND ug/L 05/29/15 17:49 7440-38-205/28/15 21:120.50 0.11 1 Barium 64.1 ug/L 05/29/15 17:49 7440-39-305/28/15 21:120.30 0.081 1 Beryllium ND ug/L 05/29/15 17:49 7440-41-705/28/15 21:120.20 0.067 1 Boron 47.3 ug/L 05/29/15 17:49 7440-42-805/28/15 21:125.0 1.1 1 Cadmium ND ug/L 05/29/15 17:49 7440-43-905/28/15 21:120.080 0.024 1 Calcium 148 ug/L 05/29/15 17:49 7440-70-205/28/15 21:1240.0 16.0 1 Chromium 0.47J ug/L 05/29/15 17:49 7440-47-305/28/15 21:120.50 0.17 1 Cobalt ND ug/L 05/29/15 17:49 7440-48-405/28/15 21:120.50 0.13 1 Copper 1.0 ug/L 05/29/15 17:49 7440-50-805/28/15 21:121.0 0.21 1 Iron ND ug/L 05/29/15 17:49 7439-89-605/28/15 21:1250.0 13.7 1 Lead 0.088J ug/L 05/29/15 17:49 7439-92-105/28/15 21:120.10 0.046 1 Magnesium 100 ug/L 05/29/15 17:49 7439-95-405/28/15 21:1210.0 3.2 1 Manganese 2.7 ug/L 05/29/15 17:49 7439-96-505/28/15 21:120.50 0.24 1 Molybdenum ND ug/L 05/29/15 17:49 7439-98-705/28/15 21:120.50 0.094 1 Nickel 0.37J ug/L 05/29/15 17:49 7440-02-005/28/15 21:120.50 0.16 1 Potassium 151 ug/L 05/29/15 17:49 7440-09-705/28/15 21:1250.0 11.7 1 Selenium ND ug/L 05/29/15 17:49 7782-49-205/28/15 21:120.50 0.20 1 Sodium 1330 ug/L 05/29/15 17:49 7440-23-505/28/15 21:1250.0 16.3 1 Strontium 3.5 ug/L 05/29/15 17:49 7440-24-605/28/15 21:120.50 0.13 1 Thallium ND ug/L 05/29/15 17:49 7440-28-005/28/15 21:120.10 0.015 1 Vanadium ND ug/L 05/29/15 17:49 7440-62-205/28/15 21:121.0 0.28 1 Zinc 23.6 ug/L 05/29/15 17:49 7440-66-605/28/15 21:125.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/01/15 13:16 7439-97-605/30/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 82 66 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13401 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92247383001, 92247383003, 92247383005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1953012 Associated Lab Samples:92247383001, 92247383003, 92247383005 Matrix:Water Analyzed Mercury ug/L ND 0.20 05/04/15 16:06 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1953013LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1953014MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247233001 1953015 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120102 1 205ND5.1 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 82 67 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13677 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92247383012, 92247383013, 92247383014, 92247383015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1977489 Associated Lab Samples:92247383012, 92247383013, 92247383014, 92247383015 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/01/15 13:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977490LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1980282MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251147009 1980283 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120102 1 205ND5.2 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 82 68 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5678 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1203118 Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Matrix:Solid Analyzed Mercury mg/kg ND 0.0081 05/07/15 13:36 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1203119LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.083.077 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1203120MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247232001 1203121 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg M1.185 78 80-12065 11 20.1940.036 0.18 0.16 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 82 69 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23950 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1203098 Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Matrix:Solid Analyzed Aluminum mg/kg ND 5.0 05/07/15 12:04 Barium mg/kg ND 0.50 05/07/15 12:04 Beryllium mg/kg ND 0.050 05/07/15 12:04 Boron mg/kg ND 2.5 05/07/15 12:04 Calcium mg/kg ND 25.1 05/07/15 12:04 Chromium mg/kg ND 0.25 05/07/15 12:04 Copper mg/kg ND 0.25 05/07/15 12:04 Iron mg/kg ND 2.0 05/07/15 12:04 Magnesium mg/kg ND 25.1 05/07/15 12:04 Manganese mg/kg 0.20J 0.25 P805/07/15 12:04 Molybdenum mg/kg ND 0.50 05/07/15 12:04 Nickel mg/kg ND 0.25 05/07/15 12:04 Potassium mg/kg ND 50.3 05/07/15 12:04 Sodium mg/kg ND 50.3 05/07/15 12:04 Strontium mg/kg ND 0.50 05/07/15 12:04 Zinc mg/kg ND 1.0 05/07/15 12:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1203099LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 127122 104 80-120 Barium mg/kg 12.512.2 102 80-120 Beryllium mg/kg 1.31.2 103 80-120 Boron mg/kg 124122 101 80-120 Calcium mg/kg 637611 104 80-120 Chromium mg/kg 12.212.2 100 80-120 Copper mg/kg 12.212.2 100 80-120 Iron mg/kg 121122 99 80-120 Magnesium mg/kg 623611 102 80-120 Manganese mg/kg 12.812.2 105 80-120 Molybdenum mg/kg 11.812.2 96 80-120 Nickel mg/kg 12.312.2 100 80-120 Potassium mg/kg 591611 97 80-120 Sodium mg/kg 645611 106 80-120 Strontium mg/kg 12.212.2 100 80-120 Zinc mg/kg 61.961.1 101 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 82 70 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1203100MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247232001 1203101 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1303116075-1251160 1 2029689801250012400 Barium mg/kg M130.3 101 75-125128 11 2029.631.5 62.1 69.1 Beryllium mg/kg 3.08 96 75-12594 4 202.84ND 3.1 2.9 Boron mg/kg 303 95 75-12598 1 2029643.1 330 331 Calcium mg/kg M1,R1151011075-125234 24 201470492065808370 Chromium mg/kg 30.3 100 75-12597 4 2029.611.3 41.6 39.8 Copper mg/kg 30.3 95 75-12596 2 2029.63.9 32.7 32.1 Iron mg/kg M1303-324 75-125308 14 20296140001300014900 Magnesium mg/kg 1510 104 75-125106 1 20147031318901880 Manganese mg/kg M130.3 108 75-125138 6 2029.6102 135 143 Molybdenum mg/kg M1,R130.3 379 75-12598 36 2029.6168 282 196 Nickel mg/kg 30.3 108 75-125101 8 2029.62.6J 35.2 32.4 Potassium mg/kg 1510 97 75-12594 5 201470ND15901520 Sodium mg/kg 1510 100 75-12598 4 201470ND17201650 Strontium mg/kg M1,R130.3 101 75-125325 25 2029.6195 226 291 Zinc mg/kg 151 101 75-12598 6 20147ND158149 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 82 71 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23951 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1203102 Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Matrix:Solid Analyzed Antimony mg/kg ND 0.049 N205/06/15 17:35 Arsenic mg/kg ND 0.049 05/06/15 17:35 Cadmium mg/kg ND 0.0059 05/06/15 17:35 Cobalt mg/kg ND 0.049 05/06/15 17:35 Lead mg/kg ND 0.049 05/06/15 17:35 Selenium mg/kg ND 0.049 05/06/15 17:35 Thallium mg/kg ND 0.049 05/06/15 17:35 Vanadium mg/kg ND 0.049 05/06/15 17:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1203103LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.7 N22.6 105 80-120 Arsenic mg/kg 2.72.6 104 80-120 Cadmium mg/kg 0.25.26 99 80-120 Cobalt mg/kg 2.72.6 105 80-120 Lead mg/kg 2.62.6 103 80-120 Selenium mg/kg 2.82.6 108 80-120 Thallium mg/kg 2.72.6 104 80-120 Vanadium mg/kg 2.72.6 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1203104MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247232001 1203105 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg N25.68 77 75-12576 206.15ND ND ND Arsenic mg/kg M65.68 -646 75-125-129 5 206.15613 576 605 Cadmium mg/kg .568 111 75-12594 20.615ND 0.85J 0.79J Cobalt mg/kg 5.68 103 75-125106 206.15ND 8.8J 9.5J Lead mg/kg M65.68 101 75-125127 15 206.157.3J 13.1 15.2 Selenium mg/kg M65.68 55 75-12549 206.15ND 6.2J ND Thallium mg/kg M65.68 70 75-12573 206.15ND 5.8J 6.4J Vanadium mg/kg M65.68 66 75-125106 10 206.1523.4 27.2 30.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 82 72 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54062 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92247383001, 92247383003, 92247383005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1953028 Associated Lab Samples:92247383001, 92247383003, 92247383005 Matrix:Water Analyzed Aluminum ug/L 3.1J 10.0 05/05/15 13:47 Antimony ug/L ND 0.50 05/05/15 13:47 Arsenic ug/L ND 0.50 05/05/15 13:47 Barium ug/L ND 0.30 05/05/15 13:47 Beryllium ug/L ND 0.20 05/05/15 13:47 Boron ug/L ND 5.0 05/05/15 13:47 Cadmium ug/L ND 0.080 05/05/15 13:47 Calcium ug/L ND 40.0 05/05/15 13:47 Chromium ug/L ND 0.50 05/05/15 13:47 Cobalt ug/L ND 0.50 05/05/15 13:47 Copper ug/L 0.28J 1.0 05/05/15 13:47 Iron ug/L ND 50.0 05/05/15 13:47 Lead ug/L ND 0.10 05/05/15 13:47 Magnesium ug/L 3.6J 10.0 05/05/15 13:47 Manganese ug/L 0.24J 0.50 05/05/15 13:47 Molybdenum ug/L ND 0.50 05/05/15 13:47 Nickel ug/L ND 0.50 05/05/15 13:47 Potassium ug/L ND 50.0 05/05/15 13:47 Selenium ug/L ND 0.50 05/05/15 13:47 Sodium ug/L ND 50.0 05/05/15 13:47 Strontium ug/L ND 0.50 05/05/15 13:47 Thallium ug/L ND 0.10 05/05/15 13:47 Vanadium ug/L ND 1.0 05/05/15 13:47 Zinc ug/L ND 5.0 05/05/15 13:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1953029LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 80.380 100 80-120 Antimony ug/L 78.280 98 80-120 Arsenic ug/L 79.480 99 80-120 Barium ug/L 78.980 99 80-120 Beryllium ug/L 81.280 102 80-120 Boron ug/L 80.180 100 80-120 Cadmium ug/L 78.880 98 80-120 Calcium ug/L 9301000 93 80-120 Chromium ug/L 83.980 105 80-120 Cobalt ug/L 79.080 99 80-120 Copper ug/L 82.780 103 80-120 Iron ug/L 10201000 102 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 82 73 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1953029LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 82.080 103 80-120 Magnesium ug/L 10201000 102 80-120 Manganese ug/L 79.080 99 80-120 Molybdenum ug/L 78.680 98 80-120 Nickel ug/L 81.080 101 80-120 Potassium ug/L 10201000 102 80-120 Selenium ug/L 79.380 99 80-120 Sodium ug/L 9811000 98 80-120 Strontium ug/L 77.880 97 80-120 Thallium ug/L 80.280 100 80-120 Vanadium ug/L 82.480 103 80-120 Zinc ug/L 80.680 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1953030MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247374001 1953031 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18019275-125478 14 2080134014901720 Antimony ug/L 80 100 75-12596 3 2080ND79.8 77.2 Arsenic ug/L 80 99 75-12597 2 20800.91 80.0 78.2 Barium ug/L 80 97 75-12594 2 208047.7 125 123 Beryllium ug/L 80 101 75-12599 3 20800.22 81.4 79.0 Boron ug/L 80 102 75-125100 2 20801.5J 83.1 81.7 Cadmium ug/L 80 98 75-12596 2 20800.25 78.7 77.1 Calcium ug/L 1000 92 75-12581 2 201000395048704760 Chromium ug/L 80 104 75-125103 1 20801.8 84.9 83.9 Cobalt ug/L 80 98 75-12596 2 20807.4 85.6 83.9 Copper ug/L 80 103 75-12599 3 208035.4 118 115 Iron ug/L 1000 101 75-125115 6 201000104020402180 Lead ug/L 80 101 75-12598 2 208053.8 135 132 Magnesium ug/L 1000 101 75-12597 2 201000104020502010 Manganese ug/L 80 96 75-12586 3 2080229306298 Molybdenum ug/L 80 99 75-12596 3 2080ND78.9 76.5 Nickel ug/L 80 102 75-12598 3 20803.1 84.4 81.6 Potassium ug/L 1000 99 75-12598 0 20100055415401540 Selenium ug/L 80 99 75-12594 5 20801.3 80.6 76.9 Sodium ug/L 1000 98 75-12595 3 20100013911201090 Strontium ug/L 80 97 75-12594 2 20809.0 86.6 84.5 Thallium ug/L 80 103 75-125102 1 20800.046J 82.6 81.5 Vanadium ug/L 80 102 75-125101 1 20803.7 85.6 84.8 Zinc ug/L 80 100 75-12598 2 208041.7 122 120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 82 74 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54700 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92247383012, 92247383013, 92247383014, 92247383015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1977698 Associated Lab Samples:92247383012, 92247383013, 92247383014, 92247383015 Matrix:Water Analyzed Aluminum ug/L ND 10.0 05/29/15 16:47 Antimony ug/L ND 0.50 05/29/15 16:47 Arsenic ug/L ND 0.50 05/29/15 16:47 Barium ug/L ND 0.30 05/29/15 16:47 Beryllium ug/L ND 0.20 05/29/15 16:47 Boron ug/L ND 5.0 05/29/15 16:47 Cadmium ug/L ND 0.080 05/29/15 16:47 Calcium ug/L ND 40.0 05/29/15 16:47 Chromium ug/L ND 0.50 05/29/15 16:47 Cobalt ug/L ND 0.50 05/29/15 16:47 Copper ug/L ND 1.0 05/29/15 16:47 Iron ug/L ND 50.0 05/29/15 16:47 Lead ug/L ND 0.10 05/29/15 16:47 Magnesium ug/L ND 10.0 05/29/15 16:47 Manganese ug/L ND 0.50 05/29/15 16:47 Molybdenum ug/L ND 0.50 05/29/15 16:47 Nickel ug/L ND 0.50 05/29/15 16:47 Potassium ug/L ND 50.0 05/29/15 16:47 Selenium ug/L ND 0.50 05/29/15 16:47 Sodium ug/L ND 50.0 05/29/15 16:47 Strontium ug/L ND 0.50 05/29/15 16:47 Thallium ug/L ND 0.10 05/29/15 16:47 Vanadium ug/L ND 1.0 05/29/15 16:47 Zinc ug/L ND 5.0 05/29/15 16:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977699LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 85.480 107 80-120 Antimony ug/L 78.980 99 80-120 Arsenic ug/L 79.880 100 80-120 Barium ug/L 79.280 99 80-120 Beryllium ug/L 77.980 97 80-120 Boron ug/L 81.480 102 80-120 Cadmium ug/L 81.280 102 80-120 Calcium ug/L 10201000 102 80-120 Chromium ug/L 81.980 102 80-120 Cobalt ug/L 79.180 99 80-120 Copper ug/L 82.480 103 80-120 Iron ug/L 10201000 102 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 82 75 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1977699LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 77.480 97 80-120 Magnesium ug/L 10301000 103 80-120 Manganese ug/L 83.180 104 80-120 Molybdenum ug/L 79.880 100 80-120 Nickel ug/L 81.480 102 80-120 Potassium ug/L 10101000 101 80-120 Selenium ug/L 80.380 100 80-120 Sodium ug/L 9751000 97 80-120 Strontium ug/L 79.580 99 80-120 Thallium ug/L 79.080 99 80-120 Vanadium ug/L 81.780 102 80-120 Zinc ug/L 83.080 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1977700MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251147009 1977701 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 109 75-125112 1 2080230317320 Antimony ug/L 80 100 75-125101 0 2080ND80.4 80.8 Arsenic ug/L 80 102 75-125102 0 2080ND81.4 81.4 Barium ug/L 80 100 75-125101 0 20803.5 83.5 83.9 Beryllium ug/L 80 101 75-12599 2 2080ND80.8 79.0 Boron ug/L M1805675-12556 0 208039.5 84.1 84.4 Cadmium ug/L 80 104 75-125103 1 2080ND83.0 82.3 Calcium ug/L 1000 104 75-125102 2 20100022912701250 Chromium ug/L 80 102 75-125104 2 2080ND82.0 83.4 Cobalt ug/L 80 100 75-125101 0 2080ND80.4 80.6 Copper ug/L 80 104 75-125105 0 20802.1 85.6 85.8 Iron ug/L 1000 102 75-125104 1 20100013811601170 Lead ug/L 80 100 75-12599 0 20800.37 80.3 80.0 Magnesium ug/L 1000 105 75-125105 0 20100020.5 1070 1070 Manganese ug/L 80 105 75-125105 0 208015.1 98.9 99.4 Molybdenum ug/L 80 101 75-125102 1 2080ND80.9 81.7 Nickel ug/L 80 101 75-125103 2 2080ND81.5 82.9 Potassium ug/L 1000 101 75-125102 1 20100051.5 1070 1070 Selenium ug/L 80 103 75-12598 5 2080ND82.2 78.4 Sodium ug/L 1000 98 75-12596 1 201000ND10201000 Strontium ug/L 80 101 75-125101 0 20802.2 82.7 82.9 Thallium ug/L 80 105 75-125105 0 2080ND83.8 83.8 Vanadium ug/L 80 103 75-125104 1 2080ND82.6 83.3 Zinc ug/L 80 100 75-125106 5 2080ND84.0 88.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 82 76 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3554 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185823001 1211608SAMPLE DUPLICATE: Percent Moisture %76.6 7 1082.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247383010 1211609SAMPLE DUPLICATE: Percent Moisture %18.9 D6121016.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247834001 1211610SAMPLE DUPLICATE: Percent Moisture %56.6 0 1056.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247835014 1211611SAMPLE DUPLICATE: Percent Moisture %33.3 6 1035.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247827006 1211612SAMPLE DUPLICATE: Percent Moisture %13.5 7 1012.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 35187206001 1211613SAMPLE DUPLICATE: Percent Moisture %68.0 5 1065.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92248416004 1211614SAMPLE DUPLICATE: Percent Moisture %23.9 3 1024.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 82 77 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92248416014 1211615SAMPLE DUPLICATE: Percent Moisture %11.6 9 1012.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92248424009 1211616SAMPLE DUPLICATE: Percent Moisture %18.7 0 1018.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 92248424020 1211617SAMPLE DUPLICATE: Percent Moisture %38.8 0 1038.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35187430003 1211618SAMPLE DUPLICATE: Percent Moisture %27.5 9 1025.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 64 of 82 78 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37120 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92247383002, 92247383004, 92247383006, 92247383007 Parameter Units Dup Result Max RPD QualifiersRPDResult 92246794001 1445734SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 8.3 0 108.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247232003 1445735SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.0 D61106.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 65 of 82 79 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37157 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247393001 1447040SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.7 0 107.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92247393012 1447041SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.5 0 107.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 66 of 82 80 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22924 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92247383007, 92247383008, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1459398 Associated Lab Samples:92247383007, 92247383008, 92247383010, 92247383011 Matrix:Water Analyzed Sulfate mg/L 3.4 2.0 05/14/15 18:08 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1459399LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.320 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1459400MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247374003 1459401 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 22.5 94 94 022.57.1 28.3 28.3 Parameter Units MS Result % Rec Limits Qual% RecConc. 1459402MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247911005 1459403 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L M123879012327.6 47.7 48.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 67 of 82 81 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22957 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92247383007, 92247383008, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1461218 Associated Lab Samples:92247383007, 92247383008, 92247383010, 92247383011 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.18 0.020 Z205/15/15 20:50 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1461219LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1461220MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247374003 1461221 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.8 93 90-11093 0 102.80.26 2.9 2.9 Parameter Units MS Result % Rec Limits Qual% RecConc. 1461222MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247374005 1461223 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.9 94 90-11093 0 102.90.75 3.5 3.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 68 of 82 82 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22916 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92247383007, 92247383008, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1458586 Associated Lab Samples:92247383007, 92247383008, 92247383010, 92247383011 Matrix:Water Analyzed Chloride mg/L ND 1.0 05/14/15 05:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1458587LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 19.920 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1458588MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247374003 1458589 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 22.5 105 90-110102 3 1022.5ND 23.9 23.3 Parameter Units MS Result % Rec Limits Qual% RecConc. 1458590MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247911005 1458591 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 23 103 90-110102 1 1023ND24.1 23.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 69 of 82 83 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46021 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92247383002, 92247383004, 92247383006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1202076 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.8 05/02/15 19:05 Sulfate mg/kg ND 49.8 05/02/15 19:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1202077LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 486499 97 80-120 Sulfate mg/kg 481499 96 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1202079MATRIX SPIKE SAMPLE: MSSpike Result 92247232001 Chloride mg/kg 1160 M111807980-120ND Sulfate mg/kg 14401180 84 80-120449J Parameter Units Dup Result Max RPD QualifiersRPDResult 92247232001 1202078SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg 428J 20449J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 70 of 82 84 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46023 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1202084 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.7 05/03/15 05:05 Sulfate mg/kg ND 49.7 05/03/15 05:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1202085LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 506499 101 80-120 Sulfate mg/kg 502499 101 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1202087MATRIX SPIKE SAMPLE: MSSpike Result 92247383007 Chloride mg/kg 677 M17167780-120ND Sulfate mg/kg 712716 99 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92247383007 1202086SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 71 of 82 85 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46020 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92247383002, 92247383004, 92247383006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1202072 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 05/02/15 19:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1202073LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 49.049.9 98 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1202075MATRIX SPIKE SAMPLE: MSSpike Result 92247232001 Nitrate as N mg/kg 111 H31189480-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92247232001 1202074SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 72 of 82 86 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46022 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1202080 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 05/03/15 05:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1202081LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 51.149.9 102 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1202083MATRIX SPIKE SAMPLE: MSSpike Result 92247383007 Nitrate as N mg/kg 69.0 H371.6 96 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92247383007 1202082SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 73 of 82 87 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28520 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92247383002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1158740 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 05/18/15 08:42 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1158741LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 135000120000 112 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1158742MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247383002 1158743 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6150 101 50-150103 2 306150420J66406780 Parameter Units MS Result % Rec Limits Qual% RecConc. 1158744MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247835007 1158745 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 73800 73 50-15062 6 3073100108000162000153000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 74 of 82 88 of 98 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92247383 J15040671 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28567 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010, 92247383011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1160018 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 05/20/15 09:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1160019LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 120000120000 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1160020MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247383006 1160021 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 8000 91 50-15096 3 30799033501060011000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1160022MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247383004 1160023 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7270 102 50-15099 3 307270111085508310 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 75 of 82 89 of 98 #=QL# QUALIFIERS Pace Project No.: Project: 92247383 J15040671 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14654 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 76 of 82 90 of 98 #=QL# QUALIFIERS Pace Project No.: Project: 92247383 J15040671 ANALYTE QUALIFIERS Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit.P8 RPD value was outside control limits.R1 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 77 of 82 91 of 98 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92247383002 MPRP/23950 ICP/146542015012320EPA 3050 EPA 6010 92247383004 MPRP/23950 ICP/146542015012322EPA 3050 EPA 6010 92247383006 MPRP/23950 ICP/146542015012324EPA 3050 EPA 6010 92247383007 MPRP/23950 ICP/146542015012325EPA 3050 EPA 6010 92247383008 MPRP/23950 ICP/146542015012326EPA 3050 EPA 6010 92247383009 MPRP/23950 ICP/146542015012327EPA 3050 EPA 6010 92247383010 MPRP/23950 ICP/146542015012328EPA 3050 EPA 6010 92247383011 MPRP/23950 ICP/146542015012329EPA 3050 EPA 6010 92247383002 MPRP/23951 ICPM/97322015012320EPA 3050 EPA 6020 92247383004 MPRP/23951 ICPM/97322015012322EPA 3050 EPA 6020 92247383006 MPRP/23951 ICPM/97322015012324EPA 3050 EPA 6020 92247383007 MPRP/23951 ICPM/97322015012325EPA 3050 EPA 6020 92247383008 MPRP/23951 ICPM/97322015012326EPA 3050 EPA 6020 92247383009 MPRP/23951 ICPM/97322015012327EPA 3050 EPA 6020 92247383010 MPRP/23951 ICPM/97322015012328EPA 3050 EPA 6020 92247383011 MPRP/23951 ICPM/97322015012329EPA 3050 EPA 6020 92247383001 MPRP/54062 ICPM/240722015012319EPA 3020 EPA 6020A 92247383003 MPRP/54062 ICPM/240722015012321EPA 3020 EPA 6020A 92247383005 MPRP/54062 ICPM/240722015012323EPA 3020 EPA 6020A 92247383012 MPRP/54700 ICPM/245072015012325 SPLP EPA 3020 EPA 6020A 92247383013 MPRP/54700 ICPM/245072015012326 SPLP EPA 3020 EPA 6020A 92247383014 MPRP/54700 ICPM/245072015012328 SPLP EPA 3020 EPA 6020A 92247383015 MPRP/54700 ICPM/245072015012329 SPLP EPA 3020 EPA 6020A 92247383001 MERP/13401 MERC/155952015012319EPA 7470A EPA 7470A 92247383003 MERP/13401 MERC/155952015012321EPA 7470A EPA 7470A 92247383005 MERP/13401 MERC/155952015012323EPA 7470A EPA 7470A 92247383012 MERP/13677 MERC/159272015012325 SPLP EPA 7470A EPA 7470A 92247383013 MERP/13677 MERC/159272015012326 SPLP EPA 7470A EPA 7470A 92247383014 MERP/13677 MERC/159272015012328 SPLP EPA 7470A EPA 7470A 92247383015 MERP/13677 MERC/159272015012329 SPLP EPA 7470A EPA 7470A 92247383002 MERP/5678 MERC/56682015012320EPA 7471 EPA 7471 92247383004 MERP/5678 MERC/56682015012322EPA 7471 EPA 7471 92247383006 MERP/5678 MERC/56682015012324EPA 7471 EPA 7471 92247383007 MERP/5678 MERC/56682015012325EPA 7471 EPA 7471 92247383008 MERP/5678 MERC/56682015012326EPA 7471 EPA 7471 92247383009 MERP/5678 MERC/56682015012327EPA 7471 EPA 7471 92247383010 MERP/5678 MERC/56682015012328EPA 7471 EPA 7471 92247383011 MERP/5678 MERC/56682015012329EPA 7471 EPA 7471 92247383002 PMST/35542015012320ASTM D2974-87 92247383004 PMST/35542015012322ASTM D2974-87 92247383006 PMST/35542015012324ASTM D2974-87 92247383007 PMST/35542015012325ASTM D2974-87 92247383008 PMST/35542015012326ASTM D2974-87 92247383009 PMST/35542015012327ASTM D2974-87 92247383010 PMST/35542015012328ASTM D2974-87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 78 of 82 92 of 98 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92247383011 PMST/35542015012329ASTM D2974-87 92247383002 WET/371202015012320EPA 9045 92247383004 WET/371202015012322EPA 9045 92247383006 WET/371202015012324EPA 9045 92247383007 WET/371202015012325EPA 9045 92247383008 WET/371572015012326EPA 9045 92247383009 WET/371572015012327EPA 9045 92247383010 WET/371572015012328EPA 9045 92247383011 WET/371572015012329EPA 9045 92247383007 WETA/229242015012325EPA 300.0 92247383008 WETA/229242015012326EPA 300.0 92247383010 WETA/229242015012328EPA 300.0 92247383011 WETA/229242015012329EPA 300.0 92247383007 WETA/229572015012325EPA 353.2 92247383008 WETA/229572015012326EPA 353.2 92247383010 WETA/229572015012328EPA 353.2 92247383011 WETA/229572015012329EPA 353.2 92247383007 WETA/229162015012325SM 4500-Cl-E 92247383008 WETA/229162015012326SM 4500-Cl-E 92247383010 WETA/229162015012328SM 4500-Cl-E 92247383011 WETA/229162015012329SM 4500-Cl-E 92247383002 WETA/460212015012320EPA 9056 92247383004 WETA/460212015012322EPA 9056 92247383006 WETA/460212015012324EPA 9056 92247383007 WETA/460232015012325EPA 9056 92247383008 WETA/460232015012326EPA 9056 92247383009 WETA/460232015012327EPA 9056 92247383010 WETA/460232015012328EPA 9056 92247383011 WETA/460232015012329EPA 9056 92247383002 WETA/460202015012320EPA 9056 92247383004 WETA/460202015012322EPA 9056 92247383006 WETA/460202015012324EPA 9056 92247383007 WETA/460222015012325EPA 9056 92247383008 WETA/460222015012326EPA 9056 92247383009 WETA/460222015012327EPA 9056 92247383010 WETA/460222015012328EPA 9056 92247383011 WETA/460222015012329EPA 9056 92247383002 WETA/285202015012320EPA 9060 92247383002 WETA/285212015012320EPA 9060 92247383004 WETA/285672015012322EPA 9060 92247383004 WETA/285702015012322EPA 9060 92247383006 WETA/285672015012324EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 79 of 82 93 of 98 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92247383 J15040671 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92247383006 WETA/285702015012324EPA 9060 92247383007 WETA/285672015012325EPA 9060 92247383007 WETA/285702015012325EPA 9060 92247383008 WETA/285672015012326EPA 9060 92247383008 WETA/285702015012326EPA 9060 92247383009 WETA/285672015012327EPA 9060 92247383009 WETA/285702015012327EPA 9060 92247383010 WETA/285672015012328EPA 9060 92247383010 WETA/285702015012328EPA 9060 92247383011 WETA/285672015012329EPA 9060 92247383011 WETA/285702015012329EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 07:24 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 80 of 82 94 of 98 Page 81 of 82 95 of 98 Page 82 of 82 96 of 98 97 of 98 98 of 98