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Home My WebLink AboutNC0038377_J15040385 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040385 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/8/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 58 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015011113 MAYO STEAM 14-Apr-15 2:30 PM illegible MW-11 EB 2015011114 MAYO STEAM 14-Apr-15 2:50 PM illegible MW-11BR 0-2 2015011115 MAYO STEAM 15-Apr-15 12:30 PM illegible MW-11BR 30-32 3 Total Samples 2 of 58 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 58 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040385 2015011113 Collection Date: 14-Apr-15 2:30 PM Site:MW-11 EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 58 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040385 2015011114 Collection Date: 14-Apr-15 2:50 PM Site:MW-11BR 0-2 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 58 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040385 2015011115 Collection Date: 15-Apr-15 12:30 PM Site:MW-11BR 30-32 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Sample 2015011115: Blank for sulfate by method 300.0 is 3.4 mg/L. Sulfate result for this sample is 3.0 mg/L. Result is suspect. M. Galvin-Karr 6/6/2015 -- Additional Information -- 6 of 58 #=CL# May 13, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92246033 92246033 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15040385 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 51 7 of 58 #=CP# CERTIFICATIONS Pace Project No.: Project: 92246033 J15040385 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 51 8 of 58 #=CP# CERTIFICATIONS Pace Project No.: Project: 92246033 J15040385 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 51 9 of 58 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92246033 J15040385 Lab ID Sample ID Matrix Date Collected Date Received 92246033001 2015011113 Water 04/14/15 14:30 04/17/15 12:40 92246033002 2015011114 Solid 04/14/15 14:50 04/17/15 12:40 92246033003 2015011115 Solid 04/15/15 12:30 04/17/15 12:40 92246033004 2015011115 SPLP Water 04/15/15 12:30 04/17/15 12:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 51 10 of 58 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92246033 J15040385 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92246033001 2015011113 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW 92246033002 2015011114 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92246033003 2015011115 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92246033004 2015011115 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470A 1 PASI-MJDD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 51 11 of 58 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92246033 J15040385 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92246033001 2015011113 Aluminum 36.3 ug/L 04/23/15 19:2710.0EPA 6020A Barium 1.2 ug/L 04/23/15 19:270.30EPA 6020A Calcium 417 ug/L 04/23/15 19:2740.0EPA 6020A Chromium 0.52 ug/L 04/23/15 19:270.50EPA 6020A Cobalt 1.2 ug/L 04/23/15 19:270.50EPA 6020A Copper 1.9 ug/L 04/23/15 19:271.0EPA 6020A Iron 121 ug/L 04/23/15 19:2750.0EPA 6020A Lead 0.15 ug/L 04/23/15 19:270.10EPA 6020A Magnesium 27.4 ug/L 04/23/15 19:2710.0EPA 6020A Manganese 4.1 ug/L 04/23/15 19:270.50EPA 6020A Molybdenum 0.73 ug/L 04/23/15 19:270.50EPA 6020A Potassium 122 ug/L 04/23/15 19:2750.0EPA 6020A Sodium 108 ug/L 04/23/15 19:2750.0EPA 6020A Strontium 0.81 ug/L 04/23/15 19:270.50EPA 6020A Zinc 9.4 ug/L 04/23/15 19:275.0EPA 6020A Mercury 0.030J ug/L 04/23/15 20:530.20EPA 7470A 92246033002 2015011114 Aluminum 19700 mg/kg 04/29/15 09:1037.6EPA 6010 Barium 43.1 mg/kg 04/29/15 09:103.8EPA 6010 Calcium 1690 mg/kg 04/29/15 09:10188EPA 6010 Chromium 22.6 mg/kg 04/29/15 09:101.9EPA 6010 Copper 59.1 mg/kg 04/29/15 09:101.9EPA 6010 Iron 52900 mg/kg 04/29/15 09:1015.1EPA 6010 Magnesium 1590 mg/kg 04/29/15 09:10188EPA 6010 Manganese 52.6 mg/kg 04/29/15 09:101.9EPA 6010 Nickel 1.4J mg/kg 04/29/15 09:101.9EPA 6010 Strontium 18.6 mg/kg 04/29/15 09:103.8EPA 6010 Zinc 17.2 mg/kg 04/29/15 09:107.5EPA 6010 Cobalt 6.4J mg/kg 04/27/15 23:517.5EPA 6020 Lead 6.1J mg/kg 04/27/15 23:517.5EPA 6020 Vanadium 208 mg/kg 04/27/15 23:517.5EPA 6020 Mercury 0.13 mg/kg 04/26/15 19:350.012EPA 7471 Percent Moisture 31.6 %04/30/15 14:21 D60.10ASTM D2974-87 pH at 25 Degrees C 5.2 Std. Units 04/23/15 10:000.10EPA 9045 Total Organic Carbon 3010 mg/kg 05/11/15 21:38883EPA 9060 Total Organic Carbon 2910 mg/kg 05/11/15 21:44874EPA 9060 Total Organic Carbon 2840 mg/kg 05/11/15 21:51875EPA 9060 Total Organic Carbon 3030 mg/kg 05/11/15 21:59878EPA 9060 Mean Total Organic Carbon 2950 mg/kg 05/11/15 21:38878EPA 9060 RSD%3.0 %05/11/15 21:38EPA 9060 92246033003 2015011115 Aluminum 15000 mg/kg 04/29/15 09:1426.3EPA 6010 Barium 179 mg/kg 04/29/15 09:142.6EPA 6010 Calcium 4700 mg/kg 04/29/15 09:14131EPA 6010 Chromium 2.3 mg/kg 04/29/15 09:141.3EPA 6010 Copper 363 mg/kg 04/29/15 09:141.3EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 51 12 of 58 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92246033 J15040385 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92246033003 2015011115 Iron 44000 mg/kg 04/29/15 09:1410.5EPA 6010 Magnesium 12200 mg/kg 04/29/15 09:14131EPA 6010 Manganese 212 mg/kg 04/29/15 09:141.3EPA 6010 Nickel 16.2 mg/kg 04/29/15 09:141.3EPA 6010 Potassium 5870 mg/kg 04/29/15 09:14263EPA 6010 Strontium 23.7 mg/kg 04/29/15 09:142.6EPA 6010 Zinc 64.7 mg/kg 04/29/15 09:145.3EPA 6010 Cobalt 40.9 mg/kg 04/27/15 23:535.3EPA 6020 Vanadium 191 mg/kg 04/27/15 23:535.3EPA 6020 Percent Moisture 2.5 %04/30/15 14:210.10ASTM D2974-87 pH at 25 Degrees C 7.4 Std. Units 04/23/15 10:000.10EPA 9045 Sulfate 3.0 mg/L 04/29/15 17:46 B2.1EPA 300.0 RSD%3.9 %05/12/15 09:30EPA 9060 92246033004 2015011115 SPLP Aluminum 13100 ug/L 05/04/15 16:4910.0EPA 6020A Arsenic 1.5 ug/L 05/04/15 16:490.50EPA 6020A Barium 350 ug/L 05/04/15 16:490.30EPA 6020A Beryllium 0.18J ug/L 05/04/15 16:490.20EPA 6020A Boron 52.2 ug/L 05/04/15 16:495.0EPA 6020A Cadmium 0.14 ug/L 05/04/15 16:490.080EPA 6020A Calcium 4600 ug/L 05/04/15 16:4940.0EPA 6020A Chromium 4.0 ug/L 05/04/15 16:490.50EPA 6020A Cobalt 26.5 ug/L 05/04/15 16:490.50EPA 6020A Copper 617 ug/L 05/05/15 16:15200EPA 6020A Iron 49600 ug/L 05/05/15 16:1510000EPA 6020A Lead 1.0 ug/L 05/04/15 16:490.10EPA 6020A Magnesium 7320 ug/L 05/04/15 16:4910.0EPA 6020A Manganese 231 ug/L 05/04/15 16:490.50EPA 6020A Molybdenum 4.4 ug/L 05/04/15 16:490.50EPA 6020A Nickel 14.2 ug/L 05/04/15 16:490.50EPA 6020A Potassium 2590 ug/L 05/04/15 16:4950.0EPA 6020A Sodium 2180 ug/L 05/04/15 16:4950.0EPA 6020A Strontium 29.4 ug/L 05/04/15 16:490.50EPA 6020A Thallium 0.046J ug/L 05/04/15 16:490.10EPA 6020A Vanadium 213 ug/L 05/04/15 16:491.0EPA 6020A Zinc 179 ug/L 05/04/15 16:495.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 51 13 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 6010 Date:May 13, 2015 Description:6010 MET ICP General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23799 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246059001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1193768) • Aluminum • Barium • Boron • Iron • Molybdenum • MSD (Lab ID: 1193769) • Aluminum • Barium • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1193769) • Aluminum • Barium • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 51 14 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 6010 Date:May 13, 2015 Description:6010 MET ICP Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 51 15 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 6020 Date:May 13, 2015 Description:6020 MET ICPMS General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23800 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246059001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1193774) • Antimony • Arsenic • Cadmium • Selenium • Vanadium • MSD (Lab ID: 1193775) • Antimony • Arsenic • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 51 16 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 6020 Date:May 13, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23800 N2: The lab does not hold TNI accreditation for this parameter. • 2015011114 (Lab ID: 92246033002) • Antimony • 2015011115 (Lab ID: 92246033003) • Antimony • BLANK (Lab ID: 1193772) • Antimony • LCS (Lab ID: 1193773) • Antimony • MS (Lab ID: 1193774) • Antimony • MSD (Lab ID: 1193775) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 51 17 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 6020A Date:May 13, 2015 Description:6020A MET ICPMS General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53822 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246088001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1945457) • Aluminum • MSD (Lab ID: 1945458) • Aluminum QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1954383) • Aluminum • Calcium • Iron • Magnesium • MSD (Lab ID: 1954384) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 51 18 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 6020A Date:May 13, 2015 Description:6020A MET ICPMS QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Aluminum • Calcium • Iron • Magnesium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 51 19 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 7470A Date:May 13, 2015 Description:7470A Mercury General Information: 2 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 51 20 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 7471 Date:May 13, 2015 Description:7471 Mercury General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 51 21 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 9045 Date:May 13, 2015 Description:9045 pH Soil General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 51 22 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 300.0 Date:May 13, 2015 Description:300.0 IC Anions, SPLP General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22735 B: Analyte was detected in the associated method blank. • BLANK for HBN 261569 [WETA/227 (Lab ID: 1445696) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 51 23 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 353.2 Date:May 13, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015011115 (Lab ID: 92246033003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 51 24 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy SM 4500-Cl-E Date:May 13, 2015 Description:4500 Chloride, SPLP General Information: 1 sample was analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 51 25 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 9056 Date:May 13, 2015 Description:9056 IC Anions General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45717 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015011114 (Lab ID: 92246033002) • Chloride • Sulfate • 2015011115 (Lab ID: 92246033003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 51 26 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 9056 Date:May 13, 2015 Description:9056 IC Anions 48hr General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015011114 (Lab ID: 92246033002) • 2015011115 (Lab ID: 92246033003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 51 27 of 58 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92246033 J15040385 Method: Client:Duke Energy EPA 9060 Date:May 13, 2015 Description:Total Organic Carbon Quad General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 51 28 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92246033 J15040385 Sample:2015011113 Lab ID:92246033001 Collected:04/14/15 14:30 Received:04/17/15 12:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 36.3 ug/L 04/23/15 19:27 7429-90-504/22/15 14:5510.0 3.0 1 Antimony ND ug/L 04/23/15 19:27 7440-36-004/22/15 14:550.50 0.15 1 Arsenic ND ug/L 04/23/15 19:27 7440-38-204/22/15 14:550.50 0.11 1 Barium 1.2 ug/L 04/23/15 19:27 7440-39-304/22/15 14:550.30 0.081 1 Beryllium ND ug/L 04/23/15 19:27 7440-41-704/22/15 14:550.20 0.067 1 Boron ND ug/L 04/23/15 19:27 7440-42-804/22/15 14:555.0 1.1 1 Cadmium ND ug/L 04/23/15 19:27 7440-43-904/22/15 14:550.080 0.024 1 Calcium 417 ug/L 04/23/15 19:27 7440-70-204/22/15 14:5540.0 16.0 1 Chromium 0.52 ug/L 04/23/15 19:27 7440-47-304/22/15 14:550.50 0.17 1 Cobalt 1.2 ug/L 04/23/15 19:27 7440-48-404/22/15 14:550.50 0.13 1 Copper 1.9 ug/L 04/23/15 19:27 7440-50-804/22/15 14:551.0 0.21 1 Iron 121 ug/L 04/23/15 19:27 7439-89-604/22/15 14:5550.0 13.7 1 Lead 0.15 ug/L 04/23/15 19:27 7439-92-104/22/15 14:550.10 0.046 1 Magnesium 27.4 ug/L 04/23/15 19:27 7439-95-404/22/15 14:5510.0 3.2 1 Manganese 4.1 ug/L 04/23/15 19:27 7439-96-504/22/15 14:550.50 0.24 1 Molybdenum 0.73 ug/L 04/23/15 19:27 7439-98-704/22/15 14:550.50 0.094 1 Nickel ND ug/L 04/23/15 19:27 7440-02-004/22/15 14:550.50 0.16 1 Potassium 122 ug/L 04/23/15 19:27 7440-09-704/22/15 14:5550.0 11.7 1 Selenium ND ug/L 04/23/15 19:27 7782-49-204/22/15 14:550.50 0.20 1 Sodium 108 ug/L 04/23/15 19:27 7440-23-504/22/15 14:5550.0 16.3 1 Strontium 0.81 ug/L 04/23/15 19:27 7440-24-604/22/15 14:550.50 0.13 1 Thallium ND ug/L 04/23/15 19:27 7440-28-004/22/15 14:550.10 0.015 1 Vanadium ND ug/L 04/23/15 19:27 7440-62-204/22/15 14:551.0 0.28 1 Zinc 9.4 ug/L 04/23/15 19:27 7440-66-604/22/15 14:555.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury 0.030J ug/L 04/23/15 20:53 7439-97-604/22/15 17:550.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 51 29 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92246033 J15040385 Sample:2015011114 Lab ID:92246033002 Collected:04/14/15 14:50 Received:04/17/15 12:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 19700 mg/kg 04/29/15 09:10 7429-90-504/25/15 19:0037.6 18.8 5 Barium 43.1 mg/kg 04/29/15 09:10 7440-39-304/25/15 19:003.8 1.9 5 Beryllium ND mg/kg 04/29/15 09:10 7440-41-704/25/15 19:000.38 0.19 5 Boron ND mg/kg 04/29/15 09:10 7440-42-804/25/15 19:0018.8 9.4 5 Calcium 1690 mg/kg 04/29/15 09:10 7440-70-204/25/15 19:0018894.1 5 Chromium 22.6 mg/kg 04/29/15 09:10 7440-47-304/25/15 19:001.9 0.94 5 Copper 59.1 mg/kg 04/29/15 09:10 7440-50-804/25/15 19:001.9 0.94 5 Iron 52900 mg/kg 04/29/15 09:10 7439-89-604/25/15 19:0015.1 7.5 5 Magnesium 1590 mg/kg 04/29/15 09:10 7439-95-404/25/15 19:0018894.1 5 Manganese 52.6 mg/kg 04/29/15 09:10 7439-96-504/25/15 19:001.9 0.94 5 Molybdenum ND mg/kg 04/29/15 09:10 7439-98-704/25/15 19:003.8 1.9 5 Nickel 1.4J mg/kg 04/29/15 09:10 7440-02-004/25/15 19:001.9 0.94 5 Potassium ND mg/kg 04/29/15 09:10 7440-09-704/25/15 19:003761885 Sodium ND mg/kg 04/29/15 09:10 7440-23-504/25/15 19:003761885 Strontium 18.6 mg/kg 04/29/15 09:10 7440-24-604/25/15 19:003.8 1.9 5 Zinc 17.2 mg/kg 04/29/15 09:10 7440-66-604/25/15 19:007.5 3.8 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/27/15 23:51 7440-36-0 N204/25/15 19:007.5 3.7 100 Arsenic ND mg/kg 04/27/15 23:51 7440-38-204/25/15 19:007.5 3.7 100 Cadmium ND mg/kg 04/27/15 23:51 7440-43-904/25/15 19:000.89 0.45 100 Cobalt 6.4J mg/kg 04/27/15 23:51 7440-48-404/25/15 19:007.5 3.7 100 Lead 6.1J mg/kg 04/27/15 23:51 7439-92-104/25/15 19:007.5 3.7 100 Selenium ND mg/kg 04/27/15 23:51 7782-49-204/25/15 19:007.5 3.7 100 Thallium ND mg/kg 04/27/15 23:51 7440-28-004/25/15 19:007.5 3.7 100 Vanadium 208 mg/kg 04/27/15 23:51 7440-62-204/25/15 19:007.5 3.7 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.13 mg/kg 04/26/15 19:35 7439-97-604/25/15 19:200.012 0.0060 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 31.6 %04/30/15 14:21 D60.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.2 Std. Units 04/23/15 10:000.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/23/15 18:23 16887-00-6 D3,M13541775 Sulfate ND mg/kg 04/23/15 18:23 14808-79-8 D3,M13541775 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/23/15 18:23 14797-55-8 H335.4 17.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 51 30 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92246033 J15040385 Sample:2015011114 Lab ID:92246033002 Collected:04/14/15 14:50 Received:04/17/15 12:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 3010 mg/kg 05/11/15 21:38 7440-44-08834421 Total Organic Carbon 2910 mg/kg 05/11/15 21:44 7440-44-08744371 Total Organic Carbon 2840 mg/kg 05/11/15 21:51 7440-44-08754381 Total Organic Carbon 3030 mg/kg 05/11/15 21:59 7440-44-08784391 Mean Total Organic Carbon 2950 mg/kg 05/11/15 21:38 7440-44-08784391 Surrogates RSD%3.0 %05/11/15 21:381 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 51 31 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92246033 J15040385 Sample:2015011115 Lab ID:92246033003 Collected:04/15/15 12:30 Received:04/17/15 12:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 15000 mg/kg 04/29/15 09:14 7429-90-504/25/15 19:0026.3 13.1 5 Barium 179 mg/kg 04/29/15 09:14 7440-39-304/25/15 19:002.6 1.3 5 Beryllium ND mg/kg 04/29/15 09:14 7440-41-704/25/15 19:000.26 0.13 5 Boron ND mg/kg 04/29/15 09:14 7440-42-804/25/15 19:0013.1 6.6 5 Calcium 4700 mg/kg 04/29/15 09:14 7440-70-204/25/15 19:0013165.7 5 Chromium 2.3 mg/kg 04/29/15 09:14 7440-47-304/25/15 19:001.3 0.66 5 Copper 363 mg/kg 04/29/15 09:14 7440-50-804/25/15 19:001.3 0.66 5 Iron 44000 mg/kg 04/29/15 09:14 7439-89-604/25/15 19:0010.5 5.3 5 Magnesium 12200 mg/kg 04/29/15 09:14 7439-95-404/25/15 19:0013165.7 5 Manganese 212 mg/kg 04/29/15 09:14 7439-96-504/25/15 19:001.3 0.66 5 Molybdenum ND mg/kg 04/29/15 09:14 7439-98-704/25/15 19:002.6 1.3 5 Nickel 16.2 mg/kg 04/29/15 09:14 7440-02-004/25/15 19:001.3 0.66 5 Potassium 5870 mg/kg 04/29/15 09:14 7440-09-704/25/15 19:002631315 Sodium ND mg/kg 04/29/15 09:14 7440-23-504/25/15 19:002631315 Strontium 23.7 mg/kg 04/29/15 09:14 7440-24-604/25/15 19:002.6 1.3 5 Zinc 64.7 mg/kg 04/29/15 09:14 7440-66-604/25/15 19:005.3 2.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/27/15 23:53 7440-36-0 N204/25/15 19:005.3 2.6 100 Arsenic ND mg/kg 04/27/15 23:53 7440-38-204/25/15 19:005.3 2.6 100 Cadmium ND mg/kg 04/27/15 23:53 7440-43-904/25/15 19:000.63 0.32 100 Cobalt 40.9 mg/kg 04/27/15 23:53 7440-48-404/25/15 19:005.3 2.6 100 Lead ND mg/kg 04/27/15 23:53 7439-92-104/25/15 19:005.3 2.6 100 Selenium ND mg/kg 04/27/15 23:53 7782-49-204/25/15 19:005.3 2.6 100 Thallium ND mg/kg 04/27/15 23:53 7440-28-004/25/15 19:005.3 2.6 100 Vanadium 191 mg/kg 04/27/15 23:53 7440-62-204/25/15 19:005.3 2.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/26/15 19:37 7439-97-604/25/15 19:200.0084 0.0042 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 2.5 %04/30/15 14:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.4 Std. Units 04/23/15 10:000.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/20/15 00:00300.0 IC Anions, SPLP Sulfate 3.0 mg/L 04/29/15 17:46 14808-79-8 B2.1 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/20/15 00:00353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/29/15 21:10 H10.21 0.21 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/20/15 00:004500 Chloride, SPLP Chloride ND mg/L 04/30/15 01:51 16887-00-65.1 2.6 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 51 32 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92246033 J15040385 Sample:2015011115 Lab ID:92246033003 Collected:04/15/15 12:30 Received:04/17/15 12:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/23/15 19:27 16887-00-6 D32571285 Sulfate ND mg/kg 04/23/15 19:27 14808-79-8 D32571285 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/23/15 19:27 14797-55-8 H325.7 12.8 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/12/15 09:30 7440-44-06143071 Total Organic Carbon ND mg/kg 05/12/15 09:36 7440-44-06113061 Total Organic Carbon ND mg/kg 05/12/15 09:42 7440-44-06203101 Total Organic Carbon ND mg/kg 05/12/15 09:49 7440-44-06113061 Mean Total Organic Carbon ND mg/kg 05/12/15 09:30 7440-44-06143071 Surrogates RSD%3.9 %05/12/15 09:301 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 51 33 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92246033 J15040385 Sample:2015011115 SPLP Lab ID:92246033004 Collected:04/15/15 12:30 Received:04/17/15 12:40 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 13100 ug/L 05/04/15 16:49 7429-90-505/04/15 08:4910.0 3.0 1 Antimony ND ug/L 05/04/15 16:49 7440-36-005/04/15 08:490.50 0.15 1 Arsenic 1.5 ug/L 05/04/15 16:49 7440-38-205/04/15 08:490.50 0.11 1 Barium 350 ug/L 05/04/15 16:49 7440-39-305/04/15 08:490.30 0.081 1 Beryllium 0.18J ug/L 05/04/15 16:49 7440-41-705/04/15 08:490.20 0.067 1 Boron 52.2 ug/L 05/04/15 16:49 7440-42-805/04/15 08:495.0 1.1 1 Cadmium 0.14 ug/L 05/04/15 16:49 7440-43-905/04/15 08:490.080 0.024 1 Calcium 4600 ug/L 05/04/15 16:49 7440-70-205/04/15 08:4940.0 16.0 1 Chromium 4.0 ug/L 05/04/15 16:49 7440-47-305/04/15 08:490.50 0.17 1 Cobalt 26.5 ug/L 05/04/15 16:49 7440-48-405/04/15 08:490.50 0.13 1 Copper 617 ug/L 05/05/15 16:15 7440-50-805/04/15 08:4920042.8 200 Iron 49600 ug/L 05/05/15 16:15 7439-89-605/04/15 08:49100002740200 Lead 1.0 ug/L 05/04/15 16:49 7439-92-105/04/15 08:490.10 0.046 1 Magnesium 7320 ug/L 05/04/15 16:49 7439-95-405/04/15 08:4910.0 3.2 1 Manganese 231 ug/L 05/04/15 16:49 7439-96-505/04/15 08:490.50 0.24 1 Molybdenum 4.4 ug/L 05/04/15 16:49 7439-98-705/04/15 08:490.50 0.094 1 Nickel 14.2 ug/L 05/04/15 16:49 7440-02-005/04/15 08:490.50 0.16 1 Potassium 2590 ug/L 05/04/15 16:49 7440-09-705/04/15 08:4950.0 11.7 1 Selenium ND ug/L 05/04/15 16:49 7782-49-205/04/15 08:490.50 0.20 1 Sodium 2180 ug/L 05/04/15 16:49 7440-23-505/04/15 08:4950.0 16.3 1 Strontium 29.4 ug/L 05/04/15 16:49 7440-24-605/04/15 08:490.50 0.13 1 Thallium 0.046J ug/L 05/04/15 16:49 7440-28-005/04/15 08:490.10 0.015 1 Vanadium 213 ug/L 05/04/15 16:49 7440-62-205/04/15 08:491.0 0.28 1 Zinc 179 ug/L 05/04/15 16:49 7440-66-605/04/15 08:495.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 05/04/15 20:36 7439-97-605/04/15 12:000.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 51 34 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13313 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92246033001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1945566 Associated Lab Samples:92246033001 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/23/15 20:16 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1945567LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.15 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1945568MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246044001 1945569 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120104 1 205ND5.2 5.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 51 35 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13418 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92246033004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1954385 Associated Lab Samples:92246033004 Matrix:Water Analyzed Mercury ug/L ND 0.20 05/04/15 20:27 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1954386LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.85 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1954387MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247835002 1954388 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120103 0 205ND5.1 5.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 51 36 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5633 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92246033002, 92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1193779 Associated Lab Samples:92246033002, 92246033003 Matrix:Solid Analyzed Mercury mg/kg ND 0.0082 04/26/15 19:13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1193780LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.080.083 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1193781MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246059001 1193782 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .0898 96 80-12099 3 20.0910.011 0.097 0.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 51 37 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23799 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92246033002, 92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1193766 Associated Lab Samples:92246033002, 92246033003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.1 04/29/15 08:25 Barium mg/kg ND 0.51 04/29/15 08:25 Beryllium mg/kg ND 0.051 04/29/15 08:25 Boron mg/kg ND 2.5 04/29/15 08:25 Calcium mg/kg ND 25.4 04/29/15 08:25 Chromium mg/kg ND 0.25 04/29/15 08:25 Copper mg/kg ND 0.25 04/29/15 08:25 Iron mg/kg ND 2.0 04/29/15 08:25 Magnesium mg/kg ND 25.4 04/29/15 08:25 Manganese mg/kg ND 0.25 04/29/15 08:25 Molybdenum mg/kg ND 0.51 04/29/15 08:25 Nickel mg/kg ND 0.25 04/29/15 08:25 Potassium mg/kg ND 50.9 04/29/15 08:25 Sodium mg/kg ND 50.9 04/29/15 08:25 Strontium mg/kg ND 0.51 04/29/15 08:25 Zinc mg/kg ND 1.0 04/29/15 08:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1193767LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 128127 101 80-120 Barium mg/kg 12.712.7 100 80-120 Beryllium mg/kg 1.21.3 96 80-120 Boron mg/kg 121127 95 80-120 Calcium mg/kg 651635 103 80-120 Chromium mg/kg 11.512.7 90 80-120 Copper mg/kg 11.812.7 93 80-120 Iron mg/kg 128127 101 80-120 Magnesium mg/kg 623635 98 80-120 Manganese mg/kg 12.412.7 98 80-120 Molybdenum mg/kg 12.312.7 97 80-120 Nickel mg/kg 12.612.7 99 80-120 Potassium mg/kg 629635 99 80-120 Sodium mg/kg 641635 101 80-120 Strontium mg/kg 12.912.7 101 80-120 Zinc mg/kg 63.463.5 100 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 51 38 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1193768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246059001 1193769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1,R1146132075-1252770 29 20140386058007750 Barium mg/kg M1,R114.6 65 75-125131 25 201421.6 31.1 40.1 Beryllium mg/kg 1.52 78 75-12592 12 201.4ND 1.2 1.4 Boron mg/kg M11467275-12580 6 20140ND107114 Calcium mg/kg 731 84 75-12598 10 20702ND665738 Chromium mg/kg 14.6 76 75-12598 17 20142.8 13.9 16.6 Copper mg/kg 14.6 76 75-12590 12 20141.0J 12.1 13.7 Iron mg/kg M1,R114616675-125621 30 20140151017602390 Magnesium mg/kg 731 84 75-125106 15 20702127J744868 Manganese mg/kg 14.6 86 75-125107 12 20145.3 17.9 20.3 Molybdenum mg/kg M114.6 74 75-12582 6 2014ND11.1 11.8 Nickel mg/kg 14.6 84 75-125100 13 20140.80J 13.0 14.8 Potassium mg/kg 731 84 75-12597 9 20702ND682748 Sodium mg/kg 731 80 75-12589 6 20702ND584623 Strontium mg/kg 14.6 85 75-125101 12 2014ND13.7 15.5 Zinc mg/kg 73.1 82 75-12595 11 2070.2ND 61.8 68.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 51 39 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23800 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92246033002, 92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1193772 Associated Lab Samples:92246033002, 92246033003 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N204/27/15 23:26 Arsenic mg/kg ND 0.051 04/27/15 23:26 Cadmium mg/kg ND 0.0061 04/27/15 23:26 Cobalt mg/kg ND 0.051 04/27/15 23:26 Lead mg/kg ND 0.051 04/27/15 23:26 Selenium mg/kg ND 0.051 04/27/15 23:26 Thallium mg/kg ND 0.051 04/27/15 23:26 Vanadium mg/kg ND 0.051 04/27/15 23:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1193773LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.4 N22.5 94 80-120 Arsenic mg/kg 2.42.5 97 80-120 Cadmium mg/kg 0.23.25 91 80-120 Cobalt mg/kg 2.42.5 94 80-120 Lead mg/kg 2.42.5 94 80-120 Selenium mg/kg 2.42.5 97 80-120 Thallium mg/kg 2.42.5 96 80-120 Vanadium mg/kg 2.42.5 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1193774MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246059001 1193775 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N23.03 59 75-12558 202.92ND ND ND Arsenic mg/kg M63.03 73 75-12569 202.92ND ND ND Cadmium mg/kg M6.303 66 75-125102 20.292ND ND ND Cobalt mg/kg 3.03 98 75-12597 202.92ND 3.4J 3.4J Lead mg/kg 3.03 105 75-125109 1 202.924.1J 7.3 7.3 Selenium mg/kg M63.03 55 75-12550 202.92ND ND ND Thallium mg/kg 3.03 81 75-12581 202.92ND ND ND Vanadium mg/kg M63.03 168 75-125183 3 202.926.2 11.2 11.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 51 40 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53822 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92246033001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1945455 Associated Lab Samples:92246033001 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/23/15 17:17 Antimony ug/L ND 0.50 04/23/15 17:17 Arsenic ug/L ND 0.50 04/23/15 17:17 Barium ug/L ND 0.30 04/23/15 17:17 Beryllium ug/L ND 0.20 04/23/15 17:17 Boron ug/L 1.6J 5.0 04/23/15 17:17 Cadmium ug/L ND 0.080 04/23/15 17:17 Calcium ug/L ND 40.0 04/23/15 17:17 Chromium ug/L ND 0.50 04/23/15 17:17 Cobalt ug/L ND 0.50 04/23/15 17:17 Copper ug/L 0.46J 1.0 04/23/15 17:17 Iron ug/L ND 50.0 04/23/15 17:17 Lead ug/L ND 0.10 04/23/15 17:17 Magnesium ug/L ND 10.0 04/23/15 17:17 Manganese ug/L ND 0.50 04/23/15 17:17 Molybdenum ug/L ND 0.50 04/23/15 17:17 Nickel ug/L 0.38J 0.50 04/23/15 17:17 Potassium ug/L ND 50.0 04/23/15 17:17 Selenium ug/L ND 0.50 04/23/15 17:17 Sodium ug/L ND 50.0 04/23/15 17:17 Strontium ug/L ND 0.50 04/23/15 17:17 Thallium ug/L 0.016J 0.10 04/23/15 17:17 Vanadium ug/L ND 1.0 04/23/15 17:17 Zinc ug/L ND 5.0 04/23/15 17:17 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1945456LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 83.680 105 80-120 Antimony ug/L 77.280 97 80-120 Arsenic ug/L 77.480 97 80-120 Barium ug/L 77.080 96 80-120 Beryllium ug/L 78.980 99 80-120 Boron ug/L 82.380 103 80-120 Cadmium ug/L 77.880 97 80-120 Calcium ug/L 10101000 101 80-120 Chromium ug/L 79.680 99 80-120 Cobalt ug/L 77.780 97 80-120 Copper ug/L 81.680 102 80-120 Iron ug/L 9551000 96 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 51 41 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1945456LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 80.480 101 80-120 Magnesium ug/L 9701000 97 80-120 Manganese ug/L 79.480 99 80-120 Molybdenum ug/L 76.680 96 80-120 Nickel ug/L 77.980 97 80-120 Potassium ug/L 9741000 97 80-120 Selenium ug/L 77.980 97 80-120 Sodium ug/L 9381000 94 80-120 Strontium ug/L 76.480 95 80-120 Thallium ug/L 83.180 104 80-120 Vanadium ug/L 78.380 98 80-120 Zinc ug/L 80.880 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1945457MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246088001 1945458 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18013775-125135 1 208036.8 146 145 Antimony ug/L 80 99 75-12599 0 2080ND79.6 79.2 Arsenic ug/L 80 99 75-12599 0 20800.12J 79.5 79.6 Barium ug/L 80 100 75-125102 2 20801.1 81.5 82.8 Beryllium ug/L 80 98 75-12599 1 2080ND78.6 79.4 Boron ug/L 80 105 75-125104 1 2080ND84.7 84.2 Cadmium ug/L 80 102 75-125102 1 2080ND82.0 81.4 Calcium ug/L 1000 109 75-125111 2 20100013812301250 Chromium ug/L 80 105 75-125106 1 20800.46J 84.4 85.2 Cobalt ug/L 80 102 75-125103 1 2080ND81.5 82.2 Copper ug/L 80 106 75-125106 0 20800.84J 85.9 85.9 Iron ug/L 1000 99 75-125100 1 20100012211101130 Lead ug/L 80 104 75-125106 2 20800.080J 83.6 85.0 Magnesium ug/L 1000 101 75-125104 3 20100026.8 1040 1070 Manganese ug/L 80 103 75-125104 1 20802.8 85.5 86.0 Molybdenum ug/L 80 100 75-125101 1 2080ND79.9 80.9 Nickel ug/L 80 102 75-125103 1 20800.21J 81.6 82.7 Potassium ug/L 1000 102 75-125102 1 20100040.2J 1060 1060 Selenium ug/L 80 103 75-125103 0 2080ND82.1 82.1 Sodium ug/L 1000 98 75-125100 2 20100053.4 1030 1050 Strontium ug/L 80 99 75-125101 1 20800.88 80.5 81.4 Thallium ug/L 80 110 75-125112 2 2080ND88.1 89.6 Vanadium ug/L 80 103 75-125103 0 2080ND82.7 82.7 Zinc ug/L 80 103 75-125104 1 20802.6J 85.0 85.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 51 42 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54102 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92246033004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1954381 Associated Lab Samples:92246033004 Matrix:Water Analyzed Aluminum ug/L ND 10.0 05/04/15 16:41 Antimony ug/L ND 0.50 05/04/15 16:41 Arsenic ug/L ND 0.50 05/04/15 16:41 Barium ug/L ND 0.30 05/04/15 16:41 Beryllium ug/L ND 0.20 05/04/15 16:41 Boron ug/L ND 5.0 05/04/15 16:41 Cadmium ug/L ND 0.080 05/04/15 16:41 Calcium ug/L ND 40.0 05/04/15 16:41 Chromium ug/L ND 0.50 05/04/15 16:41 Cobalt ug/L ND 0.50 05/04/15 16:41 Copper ug/L ND 1.0 05/05/15 16:04 Iron ug/L ND 50.0 05/04/15 16:41 Lead ug/L ND 0.10 05/04/15 16:41 Magnesium ug/L ND 10.0 05/04/15 16:41 Manganese ug/L ND 0.50 05/04/15 16:41 Molybdenum ug/L ND 0.50 05/04/15 16:41 Nickel ug/L ND 0.50 05/04/15 16:41 Potassium ug/L ND 50.0 05/04/15 16:41 Selenium ug/L ND 0.50 05/04/15 16:41 Sodium ug/L ND 50.0 05/04/15 16:41 Strontium ug/L ND 0.50 05/04/15 16:41 Thallium ug/L ND 0.10 05/04/15 16:41 Vanadium ug/L ND 1.0 05/04/15 16:41 Zinc ug/L ND 5.0 05/04/15 16:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1954382LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 81.480 102 80-120 Antimony ug/L 81.880 102 80-120 Arsenic ug/L 78.780 98 80-120 Barium ug/L 93.080 116 80-120 Beryllium ug/L 82.980 104 80-120 Boron ug/L 83.980 105 80-120 Cadmium ug/L 84.880 106 80-120 Calcium ug/L 11001000 110 80-120 Chromium ug/L 80.780 101 80-120 Cobalt ug/L 82.380 103 80-120 Copper ug/L 84.580 106 80-120 Iron ug/L 11001000 110 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 51 43 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1954382LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 79.980 100 80-120 Magnesium ug/L 10301000 103 80-120 Manganese ug/L 78.380 98 80-120 Molybdenum ug/L 80.080 100 80-120 Nickel ug/L 84.880 106 80-120 Potassium ug/L 9751000 97 80-120 Selenium ug/L 88.180 110 80-120 Sodium ug/L 9971000 100 80-120 Strontium ug/L 85.280 107 80-120 Thallium ug/L 91.280 114 80-120 Vanadium ug/L 81.080 101 80-120 Zinc ug/L 85.980 107 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1954383MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247835001 1954384 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M180225075-1252180 1 2080251043104250 Antimony ug/L 80 91 75-12595 4 20800.43J 73.3 76.3 Arsenic ug/L 80 100 75-125103 3 20800.27J 80.4 82.5 Barium ug/L 80 112 75-125120 6 208017.0 107 113 Beryllium ug/L 80 112 75-125115 3 2080ND89.4 92.4 Boron ug/L 80 122 75-125121 1 20804.4J 102 101 Cadmium ug/L 80 107 75-125111 3 20800.063J 85.9 88.8 Calcium ug/L M1100016475-125170 1 201000211037503810 Chromium ug/L 80 106 75-125110 3 208017.4 102 105 Cobalt ug/L 80 96 75-12599 4 20802.1 78.7 81.6 Copper ug/L 80 99 75-125102 3 20809.1 88.0 91.0 Iron ug/L M1100020175-125226 2 20100082001020010500 Lead ug/L 80 99 75-125100 2 20800.51 79.4 80.8 Magnesium ug/L M1100014175-125144 1 20100099024002430 Manganese ug/L 80 112 75-125121 4 208078.0 168 175 Molybdenum ug/L 80 102 75-125106 4 20804.8 86.2 89.6 Nickel ug/L 80 109 75-125113 3 20804.6 92.2 95.4 Potassium ug/L 1000 88 75-12594 4 20100077516601720 Selenium ug/L 80 113 75-125114 1 2080ND90.4 91.2 Sodium ug/L 1000 107 75-125113 4 20100060316701730 Strontium ug/L 80 105 75-125111 5 208013.3 97.3 102 Thallium ug/L M18012275-125128 4 2080ND98.0 102 Vanadium ug/L 80 108 75-125111 2 20809.9 96.3 98.5 Zinc ug/L 80 107 75-125111 3 208012.2 97.8 101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 51 44 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3517 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92246033002, 92246033003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92246033002 1199589SAMPLE DUPLICATE: Percent Moisture %28.5 D6111031.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185176001 1199590SAMPLE DUPLICATE: Percent Moisture %4.5 8 104.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 92246632007 1199591SAMPLE DUPLICATE: Percent Moisture %13.2 D6181015.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185410006 1199592SAMPLE DUPLICATE: Percent Moisture %1.1 D646101.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185410015 1199593SAMPLE DUPLICATE: Percent Moisture %1.7 D649101.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185412002 1199594SAMPLE DUPLICATE: Percent Moisture %2.4 10 102.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185412013 1199595SAMPLE DUPLICATE: Percent Moisture %2.1 2 102.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 51 45 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 35185412029 1199596SAMPLE DUPLICATE: Percent Moisture %3.0 5 102.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35185412038 1199597SAMPLE DUPLICATE: Percent Moisture %2.7 D617102.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 51 46 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36969 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92246033002, 92246033003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92246075024 1439466SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.6 1 106.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92246088011 1439467SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.5 0 107.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 51 47 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22735 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1445696 Associated Lab Samples:92246033003 Matrix:Water Analyzed Sulfate mg/L 3.4 2.0 04/29/15 13:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1445697LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.420 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1445698MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352011 1445699 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 23.9 91 90 123.91.7J 23.5 23.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1445700MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637002 1445701 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20 101 102 02011.0 31.2 31.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 51 48 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22748 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1446743 Associated Lab Samples:92246033003 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.15 0.020 Z204/29/15 20:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1446744LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.62.5 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446745MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352011 1446746 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H1310390-110103 0 103ND3.3 3.3 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446747MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352012 1446748 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.2 102 90-110102 0 103.2ND 3.5 3.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 51 49 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22743 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1446034 Associated Lab Samples:92246033003 Matrix:Water Analyzed Chloride mg/L ND 1.0 04/30/15 01:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1446035LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 21.120 106 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446036MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352011 1446037 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 23.9 102 90-110101 1 1023.9ND 24.6 24.4 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446038MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637002 1446039 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 20 103 90-110101 1 1020ND22.3 22.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 51 50 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45717 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92246033002, 92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1192868 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.7 04/23/15 17:19 Sulfate mg/kg ND 49.7 04/23/15 17:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1192869LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 484507 95 80-120 Sulfate mg/kg 484507 95 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1192871MATRIX SPIKE SAMPLE: MSSpike Result 92246033002 Chloride mg/kg 657 M17067480-120ND Sulfate mg/kg 680 M17067980-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92246033002 1192870SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 51 51 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45719 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92246033002, 92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1192877 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 04/23/15 17:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1192878LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 49.450.7 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1192880MATRIX SPIKE SAMPLE: MSSpike Result 92246033002 Nitrate as N mg/kg 65.2 H370.6 92 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92246033002 1192879SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 51 52 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92246033 J15040385 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28413 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92246033002, 92246033003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1154316 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 05/11/15 09:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1154317LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 118000120000 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1154318MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245627013 1154319 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 74100 79 50-150118 12 3074500175000234000263000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1154320MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247019006 1154321 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6950 81 50-15080 1 306920524J61306060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 51 53 of 58 #=QL# QUALIFIERS Pace Project No.: Project: 92246033 J15040385 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 51 54 of 58 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92246033 J15040385 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92246033002 MPRP/23799 ICP/145462015011114EPA 3050 EPA 6010 92246033003 MPRP/23799 ICP/145462015011115EPA 3050 EPA 6010 92246033002 MPRP/23800 ICPM/96752015011114EPA 3050 EPA 6020 92246033003 MPRP/23800 ICPM/96752015011115EPA 3050 EPA 6020 92246033001 MPRP/53822 ICPM/239122015011113EPA 3020 EPA 6020A 92246033004 MPRP/54102 ICPM/240742015011115 SPLP EPA 3020 EPA 6020A 92246033001 MERP/13313 MERC/154792015011113EPA 7470A EPA 7470A 92246033004 MERP/13418 MERC/156012015011115 SPLP EPA 7470A EPA 7470A 92246033002 MERP/5633 MERC/56272015011114EPA 7471 EPA 7471 92246033003 MERP/5633 MERC/56272015011115EPA 7471 EPA 7471 92246033002 PMST/35172015011114ASTM D2974-87 92246033003 PMST/35172015011115ASTM D2974-87 92246033002 WET/369692015011114EPA 9045 92246033003 WET/369692015011115EPA 9045 92246033003 WETA/227352015011115EPA 300.0 92246033003 WETA/227482015011115EPA 353.2 92246033003 WETA/227432015011115SM 4500-Cl-E 92246033002 WETA/457172015011114EPA 9056 92246033003 WETA/457172015011115EPA 9056 92246033002 WETA/457192015011114EPA 9056 92246033003 WETA/457192015011115EPA 9056 92246033002 WETA/284132015011114EPA 9060 92246033002 WETA/284142015011114EPA 9060 92246033003 WETA/284132015011115EPA 9060 92246033003 WETA/284142015011115EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/13/2015 07:40 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 51 55 of 58 Page 50 of 51 56 of 58 Page 51 of 51 57 of 58 58 of 58