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HomeMy WebLinkAboutNC0038377_J15040305 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040305 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/5/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 1 of 66 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015010590 MAYO STEAM 12-Apr-15 2:30 PM illegible MW-13BR (0-2) 2015010591 MAYO STEAM 13-Apr-15 2:30 PM illegible MW-13BR (52-54) 2015010592 MAYO STEAM 13-Apr-15 2:30 PM illegible MW13BR (52-54) Dup 2015010593 MAYO STEAM 08-Apr-15 1:52 PM illegible MW-09BR-EB 2015010594 MAYO STEAM 12-Apr-15 2:15 PM illegible MW-13BR-EB 5 Total Samples 2 2 of 66 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Anne Pifer Date:5/26/2015 Electronic Data Deliverable (EDD) Sent Separately 3 3 of 66 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 2015010590 Collection Date: 12-Apr-15 2:30 PM Site:MW-13BR (0-2) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 4 of 66 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 2015010591 Collection Date: 13-Apr-15 2:30 PM Site:MW-13BR (52-54) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 5 of 66 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 2015010592 Collection Date: 13-Apr-15 2:30 PM Site:MW13BR (52-54) Dup Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 6 of 66 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 2015010593 Collection Date: 08-Apr-15 1:52 PM Site:MW-09BR-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 7 of 66 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 2015010594 Collection Date: 12-Apr-15 2:15 PM Site:MW-13BR-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 8 8 of 66 #=CL# May 29, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92245417 92245417 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15040305 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 57 9 9 of 66 #=CP# CERTIFICATIONS Pace Project No.: Project: 92245417 J15040305 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 57 10 10 of 66 #=CP# CERTIFICATIONS Pace Project No.: Project: 92245417 J15040305 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 57 11 11 of 66 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92245417 J15040305 Lab ID Sample ID Matrix Date Collected Date Received 92245417001 2015010590 Solid 04/12/15 14:30 04/14/15 15:00 92245417002 2015010591 Solid 04/13/15 14:30 04/14/15 15:00 92245417003 2015010592 Solid 04/13/15 14:30 04/14/15 15:00 92245417004 2015010593 Water 04/08/15 13:52 04/14/15 15:00 92245417005 2015010594 Water 04/12/15 14:15 04/14/15 15:00 92245417006 2015010590 SPLP Water 04/12/15 14:30 04/14/15 15:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 57 12 12 of 66 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92245417 J15040305 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92245417001 2015010590 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-OKAM EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245417002 2015010591 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-OKAM EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245417003 2015010592 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-OKAM EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245417004 2015010593 EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MLMW 92245417005 2015010594 EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MLMW 92245417006 2015010590 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470A 1 PASI-MJDD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 57 13 13 of 66 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245417 J15040305 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245417001 2015010590 Aluminum 15500 mg/kg 04/20/15 18:036.5EPA 6010 Barium 72.9 mg/kg 04/20/15 18:030.65EPA 6010 Beryllium 0.33 mg/kg 04/20/15 18:030.065EPA 6010 Calcium 38.1 mg/kg 04/20/15 18:0332.6EPA 6010 Chromium 6.1 mg/kg 04/20/15 18:030.33EPA 6010 Copper 10.9 mg/kg 04/20/15 18:030.33EPA 6010 Iron 19600 mg/kg 04/20/15 18:032.6EPA 6010 Magnesium 1840 mg/kg 04/20/15 18:0332.6EPA 6010 Manganese 82.8 mg/kg 04/20/15 18:030.33EPA 6010 Molybdenum 0.42J mg/kg 04/20/15 18:030.65EPA 6010 Nickel 0.53 mg/kg 04/20/15 18:030.33EPA 6010 Potassium 1360 mg/kg 04/20/15 18:0365.1EPA 6010 Strontium 1.8 mg/kg 04/20/15 18:030.65EPA 6010 Zinc 25.4 mg/kg 04/20/15 18:031.3EPA 6010 Lead 6.2J mg/kg 04/26/15 09:376.5EPA 6020 Vanadium 32.4 mg/kg 04/26/15 09:376.5EPA 6020 Mercury 0.029 mg/kg 04/22/15 10:220.010EPA 7471 Percent Moisture 26.2 %04/21/15 15:510.10ASTM D2974-87 pH at 25 Degrees C 4.9 Std. Units 05/29/15 12:40 H60.10EPA 9045 Sulfate 6.1 mg/L 04/29/15 14:49 B2.7EPA 300.0 Nitrogen, Nitrate 0.35 mg/L 04/29/15 20:57 H10.27EPA 353.2 Total Organic Carbon 1360 mg/kg 05/05/15 07:57810EPA 9060 Total Organic Carbon 1190 mg/kg 05/05/15 08:02813EPA 9060 Total Organic Carbon 1260 mg/kg 05/05/15 08:09809EPA 9060 Total Organic Carbon 1030 mg/kg 05/05/15 08:15808EPA 9060 Mean Total Organic Carbon 1210 mg/kg 05/05/15 07:57810EPA 9060 RSD%11.3 %05/05/15 07:57EPA 9060 92245417002 2015010591 Aluminum 4770 mg/kg 04/20/15 18:405.1EPA 6010 Barium 62.3 mg/kg 04/20/15 18:400.51EPA 6010 Beryllium 0.19 mg/kg 04/20/15 18:400.051EPA 6010 Calcium 2300 mg/kg 04/20/15 18:4025.3EPA 6010 Chromium 9.2 mg/kg 04/20/15 18:400.25EPA 6010 Copper 48.4 mg/kg 04/20/15 18:400.25EPA 6010 Iron 10400 mg/kg 04/20/15 18:402.0EPA 6010 Magnesium 2370 mg/kg 04/20/15 18:4025.3EPA 6010 Manganese 789 mg/kg 04/21/15 09:582.5EPA 6010 Molybdenum 0.75 mg/kg 04/20/15 18:400.51EPA 6010 Nickel 5.8 mg/kg 04/20/15 18:400.25EPA 6010 Potassium 1780 mg/kg 04/20/15 18:4050.6EPA 6010 Sodium 133 mg/kg 04/20/15 18:4050.6EPA 6010 Strontium 17.6 mg/kg 04/20/15 18:400.51EPA 6010 Zinc 26.8 mg/kg 04/20/15 18:401.0EPA 6010 Cobalt 6.6 mg/kg 04/26/15 09:395.1EPA 6020 Vanadium 13.1 mg/kg 04/26/15 09:395.1EPA 6020 Percent Moisture 4.6 %04/21/15 15:520.10ASTM D2974-87 pH at 25 Degrees C 8.3 Std. Units 05/29/15 12:40 H60.10EPA 9045 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 57 14 14 of 66 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245417 J15040305 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245417002 2015010591 RSD%8.2 %05/05/15 09:08EPA 9060 92245417003 2015010592 Aluminum 4630 mg/kg 04/20/15 18:445.9EPA 6010 Barium 61.5 mg/kg 04/20/15 18:440.59EPA 6010 Beryllium 0.19 mg/kg 04/20/15 18:440.059EPA 6010 Calcium 2250 mg/kg 04/20/15 18:4429.3EPA 6010 Chromium 8.7 mg/kg 04/20/15 18:440.29EPA 6010 Copper 38.7 mg/kg 04/20/15 18:440.29EPA 6010 Iron 10200 mg/kg 04/20/15 18:442.3EPA 6010 Magnesium 2730 mg/kg 04/20/15 18:4429.3EPA 6010 Manganese 803 mg/kg 04/21/15 10:022.9EPA 6010 Molybdenum 0.74 mg/kg 04/20/15 18:440.59EPA 6010 Nickel 8.7 mg/kg 04/20/15 18:440.29EPA 6010 Potassium 1570 mg/kg 04/20/15 18:4458.7EPA 6010 Sodium 108 mg/kg 04/20/15 18:4458.7EPA 6010 Strontium 18.1 mg/kg 04/20/15 18:440.59EPA 6010 Zinc 30.8 mg/kg 04/20/15 18:441.2EPA 6010 Cobalt 7.2 mg/kg 04/26/15 09:425.9EPA 6020 Vanadium 13.9 mg/kg 04/26/15 09:425.9EPA 6020 Percent Moisture 15.6 %04/21/15 15:530.10ASTM D2974-87 pH at 25 Degrees C 8.4 Std. Units 05/29/15 12:40 H60.10EPA 9045 RSD%6.1 %05/05/15 09:32EPA 9060 92245417004 2015010593 Aluminum 83.2 ug/L 04/17/15 14:5010.0EPA 6020A Arsenic 0.14J ug/L 04/17/15 14:500.50EPA 6020A Barium 4.4 ug/L 04/17/15 14:500.30EPA 6020A Boron 35.7 ug/L 04/17/15 14:505.0EPA 6020A Calcium 445 ug/L 04/17/15 14:5040.0EPA 6020A Chromium 3.9 ug/L 04/17/15 14:500.50EPA 6020A Cobalt 29.1 ug/L 04/17/15 14:500.50EPA 6020A Copper 13.7 ug/L 04/17/15 14:501.0EPA 6020A Iron 7230 ug/L 04/17/15 14:5050.0EPA 6020A Lead 0.44 ug/L 04/17/15 14:500.10EPA 6020A Magnesium 67.6 ug/L 04/17/15 14:5010.0EPA 6020A Manganese 61.7 ug/L 04/17/15 14:500.50EPA 6020A Molybdenum 5.7 ug/L 04/17/15 14:500.50EPA 6020A Nickel 2.3 ug/L 04/17/15 14:500.50EPA 6020A Potassium 41.1J ug/L 04/17/15 14:5050.0EPA 6020A Sodium 132 ug/L 04/17/15 14:5050.0EPA 6020A Strontium 1.4 ug/L 04/17/15 14:500.50EPA 6020A Zinc 12.9 ug/L 04/17/15 14:505.0EPA 6020A 92245417005 2015010594 Aluminum 44.7 ug/L 04/17/15 14:5310.0EPA 6020A Barium 0.66 ug/L 04/17/15 14:530.30EPA 6020A Boron 1.5J ug/L 04/17/15 14:535.0EPA 6020A Calcium 157 ug/L 04/17/15 14:5340.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 57 15 15 of 66 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245417 J15040305 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245417005 2015010594 Chromium 1.0 ug/L 04/17/15 14:530.50EPA 6020A Copper 1.7 ug/L 04/17/15 14:531.0EPA 6020A Iron 181 ug/L 04/17/15 14:5350.0EPA 6020A Lead 0.20 ug/L 04/17/15 14:530.10EPA 6020A Magnesium 30.7 ug/L 04/17/15 14:5310.0EPA 6020A Manganese 4.8 ug/L 04/17/15 14:530.50EPA 6020A Molybdenum 0.21J ug/L 04/17/15 14:530.50EPA 6020A Nickel 0.42J ug/L 04/17/15 14:530.50EPA 6020A Potassium 23.4J ug/L 04/17/15 14:5350.0EPA 6020A Sodium 23.7J ug/L 04/17/15 14:5350.0EPA 6020A Strontium 0.60 ug/L 04/17/15 14:530.50EPA 6020A Zinc 11.6 ug/L 04/17/15 14:535.0EPA 6020A 92245417006 2015010590 SPLP Aluminum 9.4J ug/L 05/04/15 16:4610.0EPA 6020A Barium 93.6 ug/L 05/04/15 16:460.30EPA 6020A Boron 42.2 ug/L 05/04/15 16:465.0EPA 6020A Calcium 354 ug/L 05/04/15 16:4640.0EPA 6020A Chromium 0.38J ug/L 05/04/15 16:460.50EPA 6020A Cobalt 0.20J ug/L 05/04/15 16:460.50EPA 6020A Copper 0.44J ug/L 05/05/15 16:121.0EPA 6020A Lead 0.047J ug/L 05/04/15 16:460.10EPA 6020A Magnesium 547 ug/L 05/04/15 16:4610.0EPA 6020A Manganese 3.0 ug/L 05/04/15 16:460.50EPA 6020A Potassium 117 ug/L 05/04/15 16:4650.0EPA 6020A Sodium 1200 ug/L 05/04/15 16:4650.0EPA 6020A Strontium 6.0 ug/L 05/04/15 16:460.50EPA 6020A Zinc 48.8 ug/L 05/04/15 16:465.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 57 16 16 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 6010 Date:May 29, 2015 Description:6010 MET ICP General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086014 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188105) • Aluminum • Barium • Boron • Chromium • Iron • Manganese • Molybdenum • MSD (Lab ID: 1188106) • Aluminum • Barium • Boron • Iron • Manganese • Molybdenum R1: RPD value was outside control limits. • MSD (Lab ID: 1188106) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 57 17 17 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 6010 Date:May 29, 2015 Description:6010 MET ICP QC Batch: MPRP/23700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086014 R1: RPD value was outside control limits. • Manganese Additional Comments: Batch Comments: Samples on this batch were diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14486 Analyte Comments: QC Batch: MPRP/23700 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1188105) • Iron • MSD (Lab ID: 1188106) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 57 18 18 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 6020 Date:May 29, 2015 Description:6020 MET ICPMS General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23701 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244601001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188109) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Thallium • Vanadium • MSD (Lab ID: 1188110) • Antimony • Arsenic • Cadmium • Cobalt • Lead REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 57 19 19 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 6020 Date:May 29, 2015 Description:6020 MET ICPMS QC Batch: MPRP/23701 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244601001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Selenium • Thallium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23701 N2: The lab does not hold TNI accreditation for this parameter. • 2015010590 (Lab ID: 92245417001) • Antimony • 2015010591 (Lab ID: 92245417002) • Antimony • 2015010592 (Lab ID: 92245417003) • Antimony • BLANK (Lab ID: 1188107) • Antimony • LCS (Lab ID: 1188108) • Antimony • MS (Lab ID: 1188109) • Antimony • MSD (Lab ID: 1188110) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 57 20 20 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 6020A Date:May 29, 2015 Description:6020A MET ICPMS General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1954383) • Aluminum • Calcium • Iron • Magnesium • MSD (Lab ID: 1954384) • Aluminum • Calcium • Iron • Magnesium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 57 21 21 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 7470 Date:May 29, 2015 Description:7470 Mercury General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 57 22 22 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 7470A Date:May 29, 2015 Description:7470A Mercury General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 57 23 23 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 7471 Date:May 29, 2015 Description:7471 Mercury General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 57 24 24 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 9045 Date:May 29, 2015 Description:9045 pH Soil General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H6: Analysis initiated outside of the 15 minute EPA recommended holding time. • 2015010590 (Lab ID: 92245417001) • 2015010591 (Lab ID: 92245417002) • 2015010592 (Lab ID: 92245417003) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 57 25 25 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 300.0 Date:May 29, 2015 Description:300.0 IC Anions, SPLP General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22735 B: Analyte was detected in the associated method blank. • BLANK for HBN 261569 [WETA/227 (Lab ID: 1445696) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 57 26 26 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 353.2 Date:May 29, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015010590 (Lab ID: 92245417001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 57 27 27 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy SM 4500-Cl-E Date:May 29, 2015 Description:4500 Chloride, SPLP General Information: 1 sample was analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 57 28 28 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 9056 Date:May 29, 2015 Description:9056 IC Anions General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45547 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015010590 (Lab ID: 92245417001) • Chloride • Sulfate QC Batch: WETA/45549 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015010591 (Lab ID: 92245417002) • Chloride • Sulfate • 2015010592 (Lab ID: 92245417003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 57 29 29 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 9056 Date:May 29, 2015 Description:9056 IC Anions 48hr General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015010590 (Lab ID: 92245417001) • 2015010591 (Lab ID: 92245417002) • 2015010592 (Lab ID: 92245417003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 57 30 30 of 66 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245417 J15040305 Method: Client:Duke Energy EPA 9060 Date:May 29, 2015 Description:Total Organic Carbon Quad General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 57 31 31 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010590 Lab ID:92245417001 Collected:04/12/15 14:30 Received:04/14/15 15:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 15500 mg/kg 04/20/15 18:03 7429-90-504/20/15 03:506.5 3.3 1 Barium 72.9 mg/kg 04/20/15 18:03 7440-39-304/20/15 03:500.65 0.33 1 Beryllium 0.33 mg/kg 04/20/15 18:03 7440-41-704/20/15 03:500.065 0.033 1 Boron ND mg/kg 04/21/15 09:50 7440-42-804/20/15 03:5016.3 8.1 5 Calcium 38.1 mg/kg 04/20/15 18:03 7440-70-204/20/15 03:5032.6 16.3 1 Chromium 6.1 mg/kg 04/20/15 18:03 7440-47-304/20/15 03:500.33 0.16 1 Copper 10.9 mg/kg 04/20/15 18:03 7440-50-804/20/15 03:500.33 0.16 1 Iron 19600 mg/kg 04/20/15 18:03 7439-89-604/20/15 03:502.6 1.3 1 Magnesium 1840 mg/kg 04/20/15 18:03 7439-95-404/20/15 03:5032.6 16.3 1 Manganese 82.8 mg/kg 04/20/15 18:03 7439-96-504/20/15 03:500.33 0.16 1 Molybdenum 0.42J mg/kg 04/20/15 18:03 7439-98-704/20/15 03:500.65 0.33 1 Nickel 0.53 mg/kg 04/20/15 18:03 7440-02-004/20/15 03:500.33 0.16 1 Potassium 1360 mg/kg 04/20/15 18:03 7440-09-704/20/15 03:5065.1 32.6 1 Sodium ND mg/kg 04/20/15 18:03 7440-23-504/20/15 03:5065.1 32.6 1 Strontium 1.8 mg/kg 04/20/15 18:03 7440-24-604/20/15 03:500.65 0.33 1 Zinc 25.4 mg/kg 04/20/15 18:03 7440-66-604/20/15 03:501.3 0.65 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 09:37 7440-36-0 N204/20/15 03:506.5 3.3 100 Arsenic ND mg/kg 04/26/15 09:37 7440-38-204/20/15 03:506.5 3.3 100 Cadmium ND mg/kg 04/26/15 09:37 7440-43-904/20/15 03:500.78 0.39 100 Cobalt ND mg/kg 04/26/15 09:37 7440-48-404/20/15 03:506.5 3.3 100 Lead 6.2J mg/kg 04/26/15 09:37 7439-92-104/20/15 03:506.5 3.3 100 Selenium ND mg/kg 04/26/15 09:37 7782-49-204/20/15 03:506.5 3.3 100 Thallium ND mg/kg 04/26/15 09:37 7440-28-004/20/15 03:506.5 3.3 100 Vanadium 32.4 mg/kg 04/26/15 09:37 7440-62-204/20/15 03:506.5 3.3 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.029 mg/kg 04/22/15 10:22 7439-97-604/21/15 14:550.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.2 %04/21/15 15:510.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 4.9 Std. Units 05/29/15 12:40 H60.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15300.0 IC Anions, SPLP Sulfate 6.1 mg/L 04/29/15 14:49 14808-79-8 B2.7 1.4 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.35 mg/L 04/29/15 20:57 H10.27 0.27 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/16/15 03:154500 Chloride, SPLP Chloride ND mg/L 04/30/15 01:42 16887-00-66.8 3.4 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 57 32 32 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010590 Lab ID:92245417001 Collected:04/12/15 14:30 Received:04/14/15 15:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/18/15 19:48 16887-00-6 D33341675 Sulfate ND mg/kg 04/18/15 19:48 14808-79-8 D33341675 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/18/15 19:48 14797-55-8 H333.4 16.7 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1360 mg/kg 05/05/15 07:57 7440-44-08104051 Total Organic Carbon 1190 mg/kg 05/05/15 08:02 7440-44-08134071 Total Organic Carbon 1260 mg/kg 05/05/15 08:09 7440-44-08094041 Total Organic Carbon 1030 mg/kg 05/05/15 08:15 7440-44-08084041 Mean Total Organic Carbon 1210 mg/kg 05/05/15 07:57 7440-44-08104051 Surrogates RSD%11.3 %05/05/15 07:571 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 57 33 33 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010591 Lab ID:92245417002 Collected:04/13/15 14:30 Received:04/14/15 15:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4770 mg/kg 04/20/15 18:40 7429-90-504/20/15 03:505.1 2.5 1 Barium 62.3 mg/kg 04/20/15 18:40 7440-39-304/20/15 03:500.51 0.25 1 Beryllium 0.19 mg/kg 04/20/15 18:40 7440-41-704/20/15 03:500.051 0.025 1 Boron ND mg/kg 04/20/15 18:40 7440-42-804/20/15 03:502.5 1.3 1 Calcium 2300 mg/kg 04/20/15 18:40 7440-70-204/20/15 03:5025.3 12.7 1 Chromium 9.2 mg/kg 04/20/15 18:40 7440-47-304/20/15 03:500.25 0.13 1 Copper 48.4 mg/kg 04/20/15 18:40 7440-50-804/20/15 03:500.25 0.13 1 Iron 10400 mg/kg 04/20/15 18:40 7439-89-604/20/15 03:502.0 1.0 1 Magnesium 2370 mg/kg 04/20/15 18:40 7439-95-404/20/15 03:5025.3 12.7 1 Manganese 789 mg/kg 04/21/15 09:58 7439-96-504/20/15 03:502.5 1.3 10 Molybdenum 0.75 mg/kg 04/20/15 18:40 7439-98-704/20/15 03:500.51 0.25 1 Nickel 5.8 mg/kg 04/20/15 18:40 7440-02-004/20/15 03:500.25 0.13 1 Potassium 1780 mg/kg 04/20/15 18:40 7440-09-704/20/15 03:5050.6 25.3 1 Sodium 133 mg/kg 04/20/15 18:40 7440-23-504/20/15 03:5050.6 25.3 1 Strontium 17.6 mg/kg 04/20/15 18:40 7440-24-604/20/15 03:500.51 0.25 1 Zinc 26.8 mg/kg 04/20/15 18:40 7440-66-604/20/15 03:501.0 0.51 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 09:39 7440-36-0 N204/20/15 03:505.1 2.5 100 Arsenic ND mg/kg 04/26/15 09:39 7440-38-204/20/15 03:505.1 2.5 100 Cadmium ND mg/kg 04/26/15 09:39 7440-43-904/20/15 03:500.61 0.30 100 Cobalt 6.6 mg/kg 04/26/15 09:39 7440-48-404/20/15 03:505.1 2.5 100 Lead ND mg/kg 04/26/15 09:39 7439-92-104/20/15 03:505.1 2.5 100 Selenium ND mg/kg 04/26/15 09:39 7782-49-204/20/15 03:505.1 2.5 100 Thallium ND mg/kg 04/26/15 09:39 7440-28-004/20/15 03:505.1 2.5 100 Vanadium 13.1 mg/kg 04/26/15 09:39 7440-62-204/20/15 03:505.1 2.5 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/22/15 10:28 7439-97-604/21/15 14:550.0088 0.0044 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 4.6 %04/21/15 15:520.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.3 Std. Units 05/29/15 12:40 H60.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/18/15 21:35 16887-00-6 D32661335 Sulfate ND mg/kg 04/18/15 21:35 14808-79-8 D32661335 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/18/15 21:35 14797-55-8 H326.6 13.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 57 34 34 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010591 Lab ID:92245417002 Collected:04/13/15 14:30 Received:04/14/15 15:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/05/15 09:08 7440-44-06323161 Total Organic Carbon ND mg/kg 05/05/15 09:13 7440-44-06303151 Total Organic Carbon ND mg/kg 05/05/15 09:19 7440-44-06253131 Total Organic Carbon ND mg/kg 05/05/15 09:25 7440-44-06303151 Mean Total Organic Carbon ND mg/kg 05/05/15 09:08 7440-44-06293151 Surrogates RSD%8.2 %05/05/15 09:081 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 57 35 35 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010592 Lab ID:92245417003 Collected:04/13/15 14:30 Received:04/14/15 15:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4630 mg/kg 04/20/15 18:44 7429-90-504/20/15 03:505.9 2.9 1 Barium 61.5 mg/kg 04/20/15 18:44 7440-39-304/20/15 03:500.59 0.29 1 Beryllium 0.19 mg/kg 04/20/15 18:44 7440-41-704/20/15 03:500.059 0.029 1 Boron ND mg/kg 04/20/15 18:44 7440-42-804/20/15 03:502.9 1.5 1 Calcium 2250 mg/kg 04/20/15 18:44 7440-70-204/20/15 03:5029.3 14.7 1 Chromium 8.7 mg/kg 04/20/15 18:44 7440-47-304/20/15 03:500.29 0.15 1 Copper 38.7 mg/kg 04/20/15 18:44 7440-50-804/20/15 03:500.29 0.15 1 Iron 10200 mg/kg 04/20/15 18:44 7439-89-604/20/15 03:502.3 1.2 1 Magnesium 2730 mg/kg 04/20/15 18:44 7439-95-404/20/15 03:5029.3 14.7 1 Manganese 803 mg/kg 04/21/15 10:02 7439-96-504/20/15 03:502.9 1.5 10 Molybdenum 0.74 mg/kg 04/20/15 18:44 7439-98-704/20/15 03:500.59 0.29 1 Nickel 8.7 mg/kg 04/20/15 18:44 7440-02-004/20/15 03:500.29 0.15 1 Potassium 1570 mg/kg 04/20/15 18:44 7440-09-704/20/15 03:5058.7 29.3 1 Sodium 108 mg/kg 04/20/15 18:44 7440-23-504/20/15 03:5058.7 29.3 1 Strontium 18.1 mg/kg 04/20/15 18:44 7440-24-604/20/15 03:500.59 0.29 1 Zinc 30.8 mg/kg 04/20/15 18:44 7440-66-604/20/15 03:501.2 0.59 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 09:42 7440-36-0 N204/20/15 03:505.9 2.9 100 Arsenic ND mg/kg 04/26/15 09:42 7440-38-204/20/15 03:505.9 2.9 100 Cadmium ND mg/kg 04/26/15 09:42 7440-43-904/20/15 03:500.70 0.35 100 Cobalt 7.2 mg/kg 04/26/15 09:42 7440-48-404/20/15 03:505.9 2.9 100 Lead ND mg/kg 04/26/15 09:42 7439-92-104/20/15 03:505.9 2.9 100 Selenium ND mg/kg 04/26/15 09:42 7782-49-204/20/15 03:505.9 2.9 100 Thallium ND mg/kg 04/26/15 09:42 7440-28-004/20/15 03:505.9 2.9 100 Vanadium 13.9 mg/kg 04/26/15 09:42 7440-62-204/20/15 03:505.9 2.9 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/22/15 10:33 7439-97-604/21/15 14:550.0092 0.0046 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 15.6 %04/21/15 15:530.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.4 Std. Units 05/29/15 12:40 H60.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/18/15 21:56 16887-00-6 D32961485 Sulfate ND mg/kg 04/18/15 21:56 14808-79-8 D32961485 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/18/15 21:56 14797-55-8 H329.6 14.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 57 36 36 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010592 Lab ID:92245417003 Collected:04/13/15 14:30 Received:04/14/15 15:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/05/15 09:32 7440-44-07163581 Total Organic Carbon ND mg/kg 05/05/15 09:37 7440-44-07183591 Total Organic Carbon ND mg/kg 05/05/15 09:44 7440-44-07103551 Total Organic Carbon ND mg/kg 05/05/15 09:50 7440-44-07093551 Mean Total Organic Carbon ND mg/kg 05/05/15 09:32 7440-44-07133571 Surrogates RSD%6.1 %05/05/15 09:321 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 57 37 37 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010593 Lab ID:92245417004 Collected:04/08/15 13:52 Received:04/14/15 15:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 83.2 ug/L 04/17/15 14:50 7429-90-504/17/15 08:5610.0 3.0 1 Antimony ND ug/L 04/17/15 14:50 7440-36-004/17/15 08:560.50 0.15 1 Arsenic 0.14J ug/L 04/17/15 14:50 7440-38-204/17/15 08:560.50 0.11 1 Barium 4.4 ug/L 04/17/15 14:50 7440-39-304/17/15 08:560.30 0.081 1 Beryllium ND ug/L 04/17/15 14:50 7440-41-704/17/15 08:560.20 0.067 1 Boron 35.7 ug/L 04/17/15 14:50 7440-42-804/17/15 08:565.0 1.1 1 Cadmium ND ug/L 04/17/15 14:50 7440-43-904/17/15 08:560.080 0.024 1 Calcium 445 ug/L 04/17/15 14:50 7440-70-204/17/15 08:5640.0 16.0 1 Chromium 3.9 ug/L 04/17/15 14:50 7440-47-304/17/15 08:560.50 0.17 1 Cobalt 29.1 ug/L 04/17/15 14:50 7440-48-404/17/15 08:560.50 0.13 1 Copper 13.7 ug/L 04/17/15 14:50 7440-50-804/17/15 08:561.0 0.21 1 Iron 7230 ug/L 04/17/15 14:50 7439-89-604/17/15 08:5650.0 13.7 1 Lead 0.44 ug/L 04/17/15 14:50 7439-92-104/17/15 08:560.10 0.046 1 Magnesium 67.6 ug/L 04/17/15 14:50 7439-95-404/17/15 08:5610.0 3.2 1 Manganese 61.7 ug/L 04/17/15 14:50 7439-96-504/17/15 08:560.50 0.24 1 Molybdenum 5.7 ug/L 04/17/15 14:50 7439-98-704/17/15 08:560.50 0.094 1 Nickel 2.3 ug/L 04/17/15 14:50 7440-02-004/17/15 08:560.50 0.16 1 Potassium 41.1J ug/L 04/17/15 14:50 7440-09-704/17/15 08:5650.0 11.7 1 Selenium ND ug/L 04/17/15 14:50 7782-49-204/17/15 08:560.50 0.20 1 Sodium 132 ug/L 04/17/15 14:50 7440-23-504/17/15 08:5650.0 16.3 1 Strontium 1.4 ug/L 04/17/15 14:50 7440-24-604/17/15 08:560.50 0.13 1 Thallium ND ug/L 04/17/15 14:50 7440-28-004/17/15 08:560.10 0.015 1 Vanadium ND ug/L 04/17/15 14:50 7440-62-204/17/15 08:561.0 0.28 1 Zinc 12.9 ug/L 04/17/15 14:50 7440-66-604/17/15 08:565.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/19/15 18:02 7439-97-604/17/15 13:500.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 57 38 38 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010594 Lab ID:92245417005 Collected:04/12/15 14:15 Received:04/14/15 15:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 44.7 ug/L 04/17/15 14:53 7429-90-504/17/15 08:5610.0 3.0 1 Antimony ND ug/L 04/17/15 14:53 7440-36-004/17/15 08:560.50 0.15 1 Arsenic ND ug/L 04/17/15 14:53 7440-38-204/17/15 08:560.50 0.11 1 Barium 0.66 ug/L 04/17/15 14:53 7440-39-304/17/15 08:560.30 0.081 1 Beryllium ND ug/L 04/17/15 14:53 7440-41-704/17/15 08:560.20 0.067 1 Boron 1.5J ug/L 04/17/15 14:53 7440-42-804/17/15 08:565.0 1.1 1 Cadmium ND ug/L 04/17/15 14:53 7440-43-904/17/15 08:560.080 0.024 1 Calcium 157 ug/L 04/17/15 14:53 7440-70-204/17/15 08:5640.0 16.0 1 Chromium 1.0 ug/L 04/17/15 14:53 7440-47-304/17/15 08:560.50 0.17 1 Cobalt ND ug/L 04/17/15 14:53 7440-48-404/17/15 08:560.50 0.13 1 Copper 1.7 ug/L 04/17/15 14:53 7440-50-804/17/15 08:561.0 0.21 1 Iron 181 ug/L 04/17/15 14:53 7439-89-604/17/15 08:5650.0 13.7 1 Lead 0.20 ug/L 04/17/15 14:53 7439-92-104/17/15 08:560.10 0.046 1 Magnesium 30.7 ug/L 04/17/15 14:53 7439-95-404/17/15 08:5610.0 3.2 1 Manganese 4.8 ug/L 04/17/15 14:53 7439-96-504/17/15 08:560.50 0.24 1 Molybdenum 0.21J ug/L 04/17/15 14:53 7439-98-704/17/15 08:560.50 0.094 1 Nickel 0.42J ug/L 04/17/15 14:53 7440-02-004/17/15 08:560.50 0.16 1 Potassium 23.4J ug/L 04/17/15 14:53 7440-09-704/17/15 08:5650.0 11.7 1 Selenium ND ug/L 04/17/15 14:53 7782-49-204/17/15 08:560.50 0.20 1 Sodium 23.7J ug/L 04/17/15 14:53 7440-23-504/17/15 08:5650.0 16.3 1 Strontium 0.60 ug/L 04/17/15 14:53 7440-24-604/17/15 08:560.50 0.13 1 Thallium ND ug/L 04/17/15 14:53 7440-28-004/17/15 08:560.10 0.015 1 Vanadium ND ug/L 04/17/15 14:53 7440-62-204/17/15 08:561.0 0.28 1 Zinc 11.6 ug/L 04/17/15 14:53 7440-66-604/17/15 08:565.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/19/15 18:04 7439-97-604/17/15 13:500.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 57 39 39 of 66 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245417 J15040305 Sample:2015010590 SPLP Lab ID:92245417006 Collected:04/12/15 14:30 Received:04/14/15 15:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 9.4J ug/L 05/04/15 16:46 7429-90-505/04/15 08:4910.0 3.0 1 Antimony ND ug/L 05/04/15 16:46 7440-36-005/04/15 08:490.50 0.15 1 Arsenic ND ug/L 05/04/15 16:46 7440-38-205/04/15 08:490.50 0.11 1 Barium 93.6 ug/L 05/04/15 16:46 7440-39-305/04/15 08:490.30 0.081 1 Beryllium ND ug/L 05/04/15 16:46 7440-41-705/04/15 08:490.20 0.067 1 Boron 42.2 ug/L 05/04/15 16:46 7440-42-805/04/15 08:495.0 1.1 1 Cadmium ND ug/L 05/04/15 16:46 7440-43-905/04/15 08:490.080 0.024 1 Calcium 354 ug/L 05/04/15 16:46 7440-70-205/04/15 08:4940.0 16.0 1 Chromium 0.38J ug/L 05/04/15 16:46 7440-47-305/04/15 08:490.50 0.17 1 Cobalt 0.20J ug/L 05/04/15 16:46 7440-48-405/04/15 08:490.50 0.13 1 Copper 0.44J ug/L 05/05/15 16:12 7440-50-805/04/15 08:491.0 0.21 1 Iron ND ug/L 05/04/15 16:46 7439-89-605/04/15 08:4950.0 13.7 1 Lead 0.047J ug/L 05/04/15 16:46 7439-92-105/04/15 08:490.10 0.046 1 Magnesium 547 ug/L 05/04/15 16:46 7439-95-405/04/15 08:4910.0 3.2 1 Manganese 3.0 ug/L 05/04/15 16:46 7439-96-505/04/15 08:490.50 0.24 1 Molybdenum ND ug/L 05/04/15 16:46 7439-98-705/04/15 08:490.50 0.094 1 Nickel ND ug/L 05/04/15 16:46 7440-02-005/04/15 08:490.50 0.16 1 Potassium 117 ug/L 05/04/15 16:46 7440-09-705/04/15 08:4950.0 11.7 1 Selenium ND ug/L 05/04/15 16:46 7782-49-205/04/15 08:490.50 0.20 1 Sodium 1200 ug/L 05/04/15 16:46 7440-23-505/04/15 08:4950.0 16.3 1 Strontium 6.0 ug/L 05/04/15 16:46 7440-24-605/04/15 08:490.50 0.13 1 Thallium ND ug/L 05/04/15 16:46 7440-28-005/04/15 08:490.10 0.015 1 Vanadium ND ug/L 05/04/15 16:46 7440-62-205/04/15 08:491.0 0.28 1 Zinc 48.8 ug/L 05/04/15 16:46 7440-66-605/04/15 08:495.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 05/04/15 20:34 7439-97-605/04/15 12:000.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 57 40 40 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13262 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92245417004, 92245417005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1941653 Associated Lab Samples:92245417004, 92245417005 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/19/15 17:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1941654LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.95 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1941655MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 10302585001 1941656 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 98 75-12596 2 205ND4.9 4.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 57 41 41 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13418 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92245417006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1954385 Associated Lab Samples:92245417006 Matrix:Water Analyzed Mercury ug/L ND 0.20 05/04/15 20:27 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1954386LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.85 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1954387MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247835002 1954388 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120103 0 205ND5.1 5.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 57 42 42 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5609 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92245417001, 92245417002, 92245417003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1189243 Associated Lab Samples:92245417001, 92245417002, 92245417003 Matrix:Solid Analyzed Mercury mg/kg ND 0.0084 04/22/15 10:13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1189244LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.076.082 92 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1189389MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245417001 1189390 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .108 80 80-12080 2 20.1110.029 0.11 0.12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 57 43 43 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23700 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92245417001, 92245417002, 92245417003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188103 Associated Lab Samples:92245417001, 92245417002, 92245417003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.0 04/20/15 15:03 Barium mg/kg ND 0.50 04/20/15 15:03 Beryllium mg/kg ND 0.050 04/20/15 15:03 Boron mg/kg ND 2.5 04/20/15 15:03 Calcium mg/kg ND 25.1 04/20/15 15:03 Chromium mg/kg ND 0.25 04/20/15 15:03 Copper mg/kg ND 0.25 04/20/15 15:03 Iron mg/kg ND 2.0 04/20/15 15:03 Magnesium mg/kg ND 25.1 04/20/15 15:03 Manganese mg/kg ND 0.25 04/20/15 15:03 Molybdenum mg/kg ND 0.50 04/20/15 15:03 Nickel mg/kg ND 0.25 04/20/15 15:03 Potassium mg/kg ND 50.2 04/20/15 15:03 Sodium mg/kg ND 50.2 04/20/15 15:03 Strontium mg/kg ND 0.50 04/20/15 15:03 Zinc mg/kg ND 1.0 04/20/15 15:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188104LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 128123 104 80-120 Barium mg/kg 12.812.3 104 80-120 Beryllium mg/kg 1.31.2 103 80-120 Boron mg/kg 124123 101 80-120 Calcium mg/kg 653616 106 80-120 Chromium mg/kg 12.512.3 102 80-120 Copper mg/kg 12.212.3 99 80-120 Iron mg/kg 128123 104 80-120 Magnesium mg/kg 641616 104 80-120 Manganese mg/kg 12.712.3 103 80-120 Molybdenum mg/kg 12.412.3 100 80-120 Nickel mg/kg 12.812.3 104 80-120 Potassium mg/kg 634616 103 80-120 Sodium mg/kg 661616 107 80-120 Strontium mg/kg 12.612.3 102 80-120 Zinc mg/kg 63.861.6 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 57 44 44 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1188105MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245086014 1188106 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1168172075-1252080 6 2017796201250013300 Barium mg/kg M116.8 170 75-125159 1 2017.733.7 62.3 61.8 Beryllium mg/kg 1.65 85 75-12584 3 201.790.21 1.6 1.7 Boron mg/kg M11686775-12565 2 20177ND113115 Calcium mg/kg 841 88 75-12590 6 20885102842898 Chromium mg/kg M116.8 55 75-12591 19 2017.724.2 33.4 40.3 Copper mg/kg 16.8 92 75-12599 7 2017.715.4 30.8 32.9 Iron mg/kg E,M1168-8640 75-125-5690 14 20177435002900033400 Magnesium mg/kg 841 118 75-125109 1 20885112021102080 Manganese mg/kg M1,R116.8 302 75-125662 23 2017.7203 254 320 Molybdenum mg/kg M116.8 60 75-12555 4 2017.7ND 10.2 9.9 Nickel mg/kg 16.8 95 75-12593 3 2017.72.3 18.2 18.8 Potassium mg/kg 841 122 75-125116 0 2088579318201820 Sodium mg/kg 841 95 75-12595 6 20885ND796843 Strontium mg/kg 16.8 90 75-12590 5 2017.72.2 17.3 18.1 Zinc mg/kg 84.1 91 75-12591 5 2088.511.6 87.8 92.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 57 45 45 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23701 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92245417001, 92245417002, 92245417003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188107 Associated Lab Samples:92245417001, 92245417002, 92245417003 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N204/26/15 09:21 Arsenic mg/kg ND 0.051 04/26/15 09:21 Cadmium mg/kg ND 0.0061 04/26/15 09:21 Cobalt mg/kg ND 0.051 04/26/15 09:21 Lead mg/kg ND 0.051 04/26/15 09:21 Selenium mg/kg ND 0.051 04/26/15 09:21 Thallium mg/kg ND 0.051 04/26/15 09:21 Vanadium mg/kg ND 0.051 04/26/15 09:21 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188108LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.6 N22.5 101 80-120 Arsenic mg/kg 2.62.5 104 80-120 Cadmium mg/kg 0.25.25 100 80-120 Cobalt mg/kg 2.72.5 106 80-120 Lead mg/kg 2.62.5 103 80-120 Selenium mg/kg 2.72.5 107 80-120 Thallium mg/kg 2.62.5 103 80-120 Vanadium mg/kg 2.72.5 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1188109MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92244601001 1188110 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N22.4 176 75-125174 202.5ND 4.6J 4.6J Arsenic mg/kg M62.4 212 75-125157 202.5ND 5.6 4.3J Cadmium mg/kg M6.24 359 75-125390 10 20.25ND 0.97 1.1 Cobalt mg/kg M62.4 600 75-125626 6 202.5ND 15.5 16.6 Lead mg/kg M62.4 536 75-125547 3 202.5ND 17.8 18.4 Selenium mg/kg M62.4 113 75-12559 202.5ND 3.0J ND Thallium mg/kg M62.4 504 75-125492 0 202.5ND 12.8 12.9 Vanadium mg/kg M62.4 2980 75-1253190 9 202.5ND 72.9 80.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 57 46 46 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53693 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92245417004, 92245417005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1941663 Associated Lab Samples:92245417004, 92245417005 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/17/15 13:59 Antimony ug/L ND 0.50 04/17/15 13:59 Arsenic ug/L ND 0.50 04/17/15 13:59 Barium ug/L ND 0.30 04/17/15 13:59 Beryllium ug/L ND 0.20 04/17/15 13:59 Boron ug/L ND 5.0 04/17/15 13:59 Cadmium ug/L ND 0.080 04/17/15 13:59 Calcium ug/L ND 40.0 04/17/15 13:59 Chromium ug/L ND 0.50 04/17/15 13:59 Cobalt ug/L ND 0.50 04/17/15 13:59 Copper ug/L ND 1.0 04/17/15 13:59 Iron ug/L ND 50.0 04/17/15 13:59 Lead ug/L ND 0.10 04/17/15 13:59 Magnesium ug/L ND 10.0 04/17/15 13:59 Manganese ug/L ND 0.50 04/17/15 13:59 Molybdenum ug/L ND 0.50 04/17/15 13:59 Nickel ug/L ND 0.50 04/17/15 13:59 Potassium ug/L ND 50.0 04/17/15 13:59 Selenium ug/L ND 0.50 04/17/15 13:59 Sodium ug/L ND 50.0 04/17/15 13:59 Strontium ug/L ND 0.50 04/17/15 13:59 Thallium ug/L ND 0.10 04/17/15 13:59 Vanadium ug/L ND 1.0 04/17/15 13:59 Zinc ug/L ND 5.0 04/17/15 13:59 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1941664LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 82.380 103 80-120 Antimony ug/L 80.880 101 80-120 Arsenic ug/L 81.280 102 80-120 Barium ug/L 80.280 100 80-120 Beryllium ug/L 86.280 108 80-120 Boron ug/L 87.180 109 80-120 Cadmium ug/L 84.680 106 80-120 Calcium ug/L 10101000 101 80-120 Chromium ug/L 85.180 106 80-120 Cobalt ug/L 84.680 106 80-120 Copper ug/L 79.780 100 80-120 Iron ug/L 10501000 105 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 57 47 47 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1941664LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 84.280 105 80-120 Magnesium ug/L 10201000 102 80-120 Manganese ug/L 85.380 107 80-120 Molybdenum ug/L 80.980 101 80-120 Nickel ug/L 85.080 106 80-120 Potassium ug/L 10201000 102 80-120 Selenium ug/L 82.680 103 80-120 Sodium ug/L 10101000 101 80-120 Strontium ug/L 81.180 101 80-120 Thallium ug/L 85.280 107 80-120 Vanadium ug/L 83.980 105 80-120 Zinc ug/L 84.880 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1941683MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245394017 1941684 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 111 75-125110 0 208012.3 101 101 Antimony ug/L 80 103 75-125101 1 2080ND82.3 81.2 Arsenic ug/L 80 104 75-125102 1 2080ND82.8 81.7 Barium ug/L 80 103 75-125103 0 20800.23J 82.5 82.6 Beryllium ug/L 80 110 75-125111 0 2080ND88.3 88.6 Boron ug/L 80 111 75-125111 0 2080ND88.6 88.7 Cadmium ug/L 80 107 75-125106 1 2080ND85.8 84.8 Calcium ug/L 1000 103 75-125101 2 20100016912001180 Chromium ug/L 80 109 75-125108 1 2080ND87.7 86.6 Cobalt ug/L 80 108 75-125107 1 2080ND86.6 85.9 Copper ug/L 80 102 75-125100 1 20800.41J 81.7 80.6 Iron ug/L 1000 107 75-125106 1 20100037.9J 1110 1100 Lead ug/L 80 110 75-125108 2 2080ND88.0 86.6 Magnesium ug/L 1000 107 75-125106 1 2010009.9J 1080 1070 Manganese ug/L 80 110 75-125109 1 20800.38J 88.4 87.4 Molybdenum ug/L 80 103 75-125101 2 20800.30J 82.7 80.8 Nickel ug/L 80 109 75-125108 1 2080ND87.3 86.2 Potassium ug/L 1000 105 75-125103 2 20100023.6J 1080 1060 Selenium ug/L 80 108 75-125106 2 2080ND86.0 84.5 Sodium ug/L 1000 106 75-125104 2 20100030.6J 1090 1070 Strontium ug/L 80 104 75-125102 2 20800.36J 83.9 82.2 Thallium ug/L 80 110 75-125107 2 2080ND87.7 86.0 Vanadium ug/L 80 108 75-125107 1 2080ND86.2 85.3 Zinc ug/L 80 107 75-125106 1 2080ND87.6 86.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 57 48 48 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54102 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92245417006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1954381 Associated Lab Samples:92245417006 Matrix:Water Analyzed Aluminum ug/L ND 10.0 05/04/15 16:41 Antimony ug/L ND 0.50 05/04/15 16:41 Arsenic ug/L ND 0.50 05/04/15 16:41 Barium ug/L ND 0.30 05/04/15 16:41 Beryllium ug/L ND 0.20 05/04/15 16:41 Boron ug/L ND 5.0 05/04/15 16:41 Cadmium ug/L ND 0.080 05/04/15 16:41 Calcium ug/L ND 40.0 05/04/15 16:41 Chromium ug/L ND 0.50 05/04/15 16:41 Cobalt ug/L ND 0.50 05/04/15 16:41 Copper ug/L ND 1.0 05/05/15 16:04 Iron ug/L ND 50.0 05/04/15 16:41 Lead ug/L ND 0.10 05/04/15 16:41 Magnesium ug/L ND 10.0 05/04/15 16:41 Manganese ug/L ND 0.50 05/04/15 16:41 Molybdenum ug/L ND 0.50 05/04/15 16:41 Nickel ug/L ND 0.50 05/04/15 16:41 Potassium ug/L ND 50.0 05/04/15 16:41 Selenium ug/L ND 0.50 05/04/15 16:41 Sodium ug/L ND 50.0 05/04/15 16:41 Strontium ug/L ND 0.50 05/04/15 16:41 Thallium ug/L ND 0.10 05/04/15 16:41 Vanadium ug/L ND 1.0 05/04/15 16:41 Zinc ug/L ND 5.0 05/04/15 16:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1954382LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 81.480 102 80-120 Antimony ug/L 81.880 102 80-120 Arsenic ug/L 78.780 98 80-120 Barium ug/L 93.080 116 80-120 Beryllium ug/L 82.980 104 80-120 Boron ug/L 83.980 105 80-120 Cadmium ug/L 84.880 106 80-120 Calcium ug/L 11001000 110 80-120 Chromium ug/L 80.780 101 80-120 Cobalt ug/L 82.380 103 80-120 Copper ug/L 84.580 106 80-120 Iron ug/L 11001000 110 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 57 49 49 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1954382LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 79.980 100 80-120 Magnesium ug/L 10301000 103 80-120 Manganese ug/L 78.380 98 80-120 Molybdenum ug/L 80.080 100 80-120 Nickel ug/L 84.880 106 80-120 Potassium ug/L 9751000 97 80-120 Selenium ug/L 88.180 110 80-120 Sodium ug/L 9971000 100 80-120 Strontium ug/L 85.280 107 80-120 Thallium ug/L 91.280 114 80-120 Vanadium ug/L 81.080 101 80-120 Zinc ug/L 85.980 107 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1954383MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247835001 1954384 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M180225075-1252180 1 2080251043104250 Antimony ug/L 80 91 75-12595 4 20800.43J 73.3 76.3 Arsenic ug/L 80 100 75-125103 3 20800.27J 80.4 82.5 Barium ug/L 80 112 75-125120 6 208017.0 107 113 Beryllium ug/L 80 112 75-125115 3 2080ND89.4 92.4 Boron ug/L 80 122 75-125121 1 20804.4J 102 101 Cadmium ug/L 80 107 75-125111 3 20800.063J 85.9 88.8 Calcium ug/L M1100016475-125170 1 201000211037503810 Chromium ug/L 80 106 75-125110 3 208017.4 102 105 Cobalt ug/L 80 96 75-12599 4 20802.1 78.7 81.6 Copper ug/L 80 99 75-125102 3 20809.1 88.0 91.0 Iron ug/L M1100020175-125226 2 20100082001020010500 Lead ug/L 80 99 75-125100 2 20800.51 79.4 80.8 Magnesium ug/L M1100014175-125144 1 20100099024002430 Manganese ug/L 80 112 75-125121 4 208078.0 168 175 Molybdenum ug/L 80 102 75-125106 4 20804.8 86.2 89.6 Nickel ug/L 80 109 75-125113 3 20804.6 92.2 95.4 Potassium ug/L 1000 88 75-12594 4 20100077516601720 Selenium ug/L 80 113 75-125114 1 2080ND90.4 91.2 Sodium ug/L 1000 107 75-125113 4 20100060316701730 Strontium ug/L 80 105 75-125111 5 208013.3 97.3 102 Thallium ug/L M18012275-125128 4 2080ND98.0 102 Vanadium ug/L 80 108 75-125111 2 20809.9 96.3 98.5 Zinc ug/L 80 107 75-125111 3 208012.2 97.8 101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 57 50 50 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3462 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92245417001, 92245417002, 92245417003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245417001 1189700SAMPLE DUPLICATE: Percent Moisture %26.1 0 1026.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245394003 1189701SAMPLE DUPLICATE: Percent Moisture %24.7 2 1024.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245394012 1189702SAMPLE DUPLICATE: Percent Moisture %18.8 1 1018.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184627020 1189703SAMPLE DUPLICATE: Percent Moisture %9.3 9 1010.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 57 51 51 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/31102 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92245417001, 92245417002, 92245417003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245417001 1227314SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 4.9 H61204.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 57 52 52 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22735 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92245417001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1445696 Associated Lab Samples:92245417001 Matrix:Water Analyzed Sulfate mg/L 3.4 2.0 04/29/15 13:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1445697LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.420 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1445698MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352011 1445699 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 23.9 91 90 123.91.7J 23.5 23.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1445700MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637002 1445701 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20 101 102 02011.0 31.2 31.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 57 53 53 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22748 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92245417001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1446743 Associated Lab Samples:92245417001 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.15 0.020 Z204/29/15 20:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1446744LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.62.5 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446745MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352011 1446746 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H1310390-110103 0 103ND3.3 3.3 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446747MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352012 1446748 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.2 102 90-110102 0 103.2ND 3.5 3.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 57 54 54 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22743 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92245417001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1446034 Associated Lab Samples:92245417001 Matrix:Water Analyzed Chloride mg/L ND 1.0 04/30/15 01:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1446035LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 21.120 106 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446036MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245352011 1446037 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 23.9 102 90-110101 1 1023.9ND 24.6 24.4 Parameter Units MS Result % Rec Limits Qual% RecConc. 1446038MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637002 1446039 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 20 103 90-110101 1 1020ND22.3 22.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 57 55 55 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45547 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245417001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1187883 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.4 04/18/15 10:53 Sulfate mg/kg ND 49.4 04/18/15 10:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1187884LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 469493 95 80-120 Sulfate mg/kg 469493 95 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1187886MATRIX SPIKE SAMPLE: MSSpike Result 92245394002 Chloride mg/kg 576587 80 80-120ND Sulfate mg/kg 646587 90 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245394002 1187885SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 57 56 56 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45549 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245417002, 92245417003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1187892 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.9 04/18/15 20:52 Sulfate mg/kg ND 49.9 04/18/15 20:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1187893LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 485500 97 80-120 Sulfate mg/kg 484500 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1187895MATRIX SPIKE SAMPLE: MSSpike Result 92245417003 Chloride mg/kg 556590 94 80-120ND Sulfate mg/kg 578590 98 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245417003 1187894SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 57 57 57 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45546 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245417001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1187879 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 4.9 04/18/15 10:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1187880LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 47.949.3 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1187882MATRIX SPIKE SAMPLE: MSSpike Result 92245394002 Nitrate as N mg/kg 60.2 H358.7 103 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245394002 1187881SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 57 58 58 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45548 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245417002, 92245417003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1187887 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 04/18/15 20:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1187888LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 50.350 101 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1187890MATRIX SPIKE SAMPLE: MSSpike Result 92245417003 Nitrate as N mg/kg 55.5 H3599480-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245417003 1187889SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 57 59 59 of 66 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245417 J15040305 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28317 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92245417001, 92245417002, 92245417003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1151665 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 05/05/15 06:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1151666LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 112000120000 93 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1151667MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245417001 1151668 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 8070 83 50-15087 5 308150121078808310 Parameter Units MS Result % Rec Limits Qual% RecConc. 1151669MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92246050004 1151670 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7910 85 50-15086 1 307920697J74207490 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 57 60 60 of 66 #=QL# QUALIFIERS Pace Project No.: Project: 92245417 J15040305 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14486 Samples on this batch were diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Analyte concentration exceeded the calibration range. The reported result is estimated.E Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Analysis initiated outside of the 15 minute EPA recommended holding time.H6 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 57 61 61 of 66 #=QL# QUALIFIERS Pace Project No.: Project: 92245417 J15040305 ANALYTE QUALIFIERS The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 57 62 62 of 66 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92245417 J15040305 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92245417001 MPRP/23700 ICP/144862015010590EPA 3050 EPA 6010 92245417002 MPRP/23700 ICP/144862015010591EPA 3050 EPA 6010 92245417003 MPRP/23700 ICP/144862015010592EPA 3050 EPA 6010 92245417001 MPRP/23701 ICPM/96342015010590EPA 3050 EPA 6020 92245417002 MPRP/23701 ICPM/96342015010591EPA 3050 EPA 6020 92245417003 MPRP/23701 ICPM/96342015010592EPA 3050 EPA 6020 92245417004 MPRP/53693 ICPM/238402015010593EPA 3020 EPA 6020A 92245417005 MPRP/53693 ICPM/238402015010594EPA 3020 EPA 6020A 92245417006 MPRP/54102 ICPM/240742015010590 SPLP EPA 3020 EPA 6020A 92245417004 MERP/13262 MERC/154142015010593EPA 7470 EPA 7470 92245417005 MERP/13262 MERC/154142015010594EPA 7470 EPA 7470 92245417006 MERP/13418 MERC/156012015010590 SPLP EPA 7470A EPA 7470A 92245417001 MERP/5609 MERC/55992015010590EPA 7471 EPA 7471 92245417002 MERP/5609 MERC/55992015010591EPA 7471 EPA 7471 92245417003 MERP/5609 MERC/55992015010592EPA 7471 EPA 7471 92245417001 PMST/34622015010590ASTM D2974-87 92245417002 PMST/34622015010591ASTM D2974-87 92245417003 PMST/34622015010592ASTM D2974-87 92245417001 WET/311022015010590EPA 9045 92245417002 WET/311022015010591EPA 9045 92245417003 WET/311022015010592EPA 9045 92245417001 WETA/227352015010590EPA 300.0 92245417001 WETA/227482015010590EPA 353.2 92245417001 WETA/227432015010590SM 4500-Cl-E 92245417001 WETA/455472015010590EPA 9056 92245417002 WETA/455492015010591EPA 9056 92245417003 WETA/455492015010592EPA 9056 92245417001 WETA/455462015010590EPA 9056 92245417002 WETA/455482015010591EPA 9056 92245417003 WETA/455482015010592EPA 9056 92245417001 WETA/283172015010590EPA 9060 92245417001 WETA/283182015010590EPA 9060 92245417002 WETA/283172015010591EPA 9060 92245417002 WETA/283182015010591EPA 9060 92245417003 WETA/283172015010592EPA 9060 92245417003 WETA/283182015010592EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/29/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 57 63 63 of 66 Page 56 of 57 64 64 of 66 Page 57 of 57 65 65 of 66 66 66 of 66