NC0038377_J15030573report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15030573
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:4/15/2015
Customer Address:
Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
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Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015008082 MAYO STEAM 20-Mar-15 12:30 PM illegible MW-4
1 Total Samples
Analytical Lab
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COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:4/15/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030573
2015008082
Collection Date: 20-Mar-15 12:30 PM
Site: MW-4
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.295 mg-N/L EPA 353.2 03/24/2015 14:18 TLINN0.01 1
INORGANIC IONS BY IC
Chloride 6.6 mg/L EPA 300.0 03/26/2015 15:10N1 BGN90340.1 1
Sulfate 34 mg/L EPA 300.0 03/26/2015 15:10N1 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 03/25/2015 17:06 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 03/25/2015 18:31 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.033 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.005 1
Barium (Ba)0.005 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.05 1
Iron (Fe)0.013 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.01 1
Manganese (Mn)0.006 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 03/24/2015 12:08 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)28.4 mg/L EPA 200.7 03/24/2015 14:18M4 MHALL30.1 10
Magnesium (Mg)6.96 mg/L EPA 200.7 03/24/2015 14:18M4 MHALL30.005 1
Potassium (K)5.48 mg/L EPA 200.7 03/24/2015 14:18 MHALL30.1 1
Sodium (Na)17.8 mg/L EPA 200.7 03/24/2015 14:18M4 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.118 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.005 1
Barium (Ba)0.006 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.05 1
Iron (Fe)0.070 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.01 1
Manganese (Mn)0.015 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.005 1
Strontium (Sr)0.099 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 03/25/2015 13:07 MHALL30.005 1
Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030573
2015008082
Collection Date: 20-Mar-15 12:30 PM
Site: MW-4
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
DISSOLVED METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Molybdenum (Mo)2.30 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA0.2 1
Vanadium (V) Low Level 0.596 ug/L EPA 200.8 04/14/2015 15:36 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Copper (Cu)1.01 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Molybdenum (Mo)2.38 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA0.2 1
Vanadium (V) Low Level 0.891 ug/L EPA 200.8 04/13/2015 16:29 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 190 mg/L SM2540C 03/24/2015 11:00 AGIBBS5251
Total Carbon
TOC 0.553 mg/L SM5310C/EPA9060A 03/31/2015 16:16N1 TJA70670.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/25/2015 08:46 AGIBBS551
Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030573
This sample was stored in a refrigerator that malfunctioned causing the sample to freeze. The state was notified and
the results may be reported for compliance purposes as long as the data is flagged. Any parameter requiring
preservation at < 6C and that was tested after 3/25/2015 at 15:45 when the refrigerator was documented to be in
compliance are flagged with N1.
-- Additional Information --
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to
the spike level. The associated Laboratory Control Spike recovery was acceptable.
N1 See additional information listed below.
Analytical Lab
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Analytical Lab
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Analytical Lab
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SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QC27016Lot Number:
J15030573Project Number:
AB GW Assessment Water - MayoProject Name:
04/08/2015Date Completed:
Grant Wilton
Project Manager
*QC27016*

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QC27016
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Mayo
Project Number: J15030573
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QC27016

Project Name: AB GW Assessment Water - Mayo
Project Number: J15030573
Sample Number Sample ID Matrix Date Sampled Date Received
001 03/20/2015 12302015008082Aqueous 03/27/2015
(1 sample)
Page: 3 of 6
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QC27016

Project Name: AB GW Assessment Water - Mayo
Project Number: J15030573
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015008082 Aqueous Alkalinity SM 2320B-88 mg/L 5
001 2015008082 Aqueous Bicarbonate Alkalinity SM 2320B-88 mg/L 5
(2 detections)
Page: 4 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015008082
QC27016-001
03/20/2015 1230
03/27/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15030573
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 04/02/2015 0001 HMA 71441
1 (Bicarbonate ) SM 2320B-2011 1 04/02/2015 0001 HMA 04/02/2015 1201
1 (Carbonate Al) SM 2320B-2011 1 04/02/2015 0001 HMA 04/02/2015 1201
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 88 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 88 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015008082
QC27016-001
03/20/2015 1230
03/27/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15030573
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 03/27/2015 1940 DCS 71148
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
QC Summary
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MB
Batch:
Sample ID:QQ71441-001
71441
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 04/01/2015 220110mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - LCS
Batch:
Sample ID:QQ71441-002
71441
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 98 04/01/2015 22079810090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MS
Batch:
Sample ID:QC27016-001MS
71441
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
Limit
Sample
Amount
Dil(mg/L)(mg/L)(mg/L)
Alkalinity 180 04/02/2015 00079210070-130881
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MSD
Batch:
Sample ID:QC27016-001MD
71441
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
Limit
Sample
Amount
Dil(mg/L)(mg/L)(mg/L)
Alkalinity 180 04/02/2015 00139110070-1300.57 20881
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ71148-001
71148
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 03/27/2015 140710ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ71148-002
71148
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 150 03/27/2015 13429915070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ71148-003
71148
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 190 03/27/2015 135512815070-13026 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Analytical Lab
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