NC0038377_J15030555 Report_20171101

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15030555
Project Name:AB GW ASSESSMENT SOIL
Lab Contact:Margaret Galvin-Karr
Date:4/22/2015
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Margaret Galvin-Karr
Page 1 of 125
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015007996 MAYO STEAM 18-Mar-15 3:35 PM illegible Well MAY-AB2(18-20)
2015007997 MAYO STEAM 18-Mar-15 3:50 PM illegible Well MAY-AB2(32.9-33.7)
2015007998 MAYO STEAM 18-Mar-15 9:30 AM illegible Well MAY-AB3(4-5)
2015007999 MAYO STEAM 17-Mar-15 3:45 PM illegible Well MAY-AB4(53-55)
2015008000 MAYO STEAM 18-Mar-15 2:30 PM illegible Well MAY-AB2(4-5)
2015008001 MAYO STEAM 17-Mar-15 1:05 PM illegible Well MAY-AB4(4-5)
2015008002 MAYO STEAM 18-Mar-15 12:20 PM illegible Well MAY-AB3(21.6-23.4)
2015008003 MAYO STEAM 18-Mar-15 1:15 PM illegible Well MAY-AB3(41.7-42.5)
2015008004 MAYO STEAM 17-Mar-15 3:30 PM illegible Well MAY-AB4(33-35)
2015008005 MAYO STEAM 17-Mar-15 3:30 PM illegible Well MAY-AB4(33-35)-DUP
2015008006 MAYO STEAM 19-Mar-15 9:20 AM illegible Well MAY-AB1(4-5)
2015008007 MAYO STEAM 19-Mar-15 12:30 PM illegible Well MAY-AB1(48-50)
2015008008 MAYO STEAM 19-Mar-15 12:40 PM illegible Well MAY-AB1(34.3-35.0)
2015008009 MAYO STEAM 19-Mar-15 9:00 AM illegible Well AB-1EB
2015008010 MAYO STEAM 18-Mar-15 8:50 AM illegible Well AB-3EB
2015008011 MAYO STEAM 17-Mar-15 12:35 PM illegible Well AB-4EB
2015008012 MAYO STEAM 18-Mar-15 4:00 PM illegible Well AB-2EB
17 Total Samples
Page 2 of 125
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/22/2015
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015007996
Collection Date:18-Mar-15 3:35 PM
Site:Well MAY-AB2(18-20)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 4 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015007997
Collection Date:18-Mar-15 3:50 PM
Site:Well MAY-AB2(32.9-33.7)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 5 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015007998
Collection Date:18-Mar-15 9:30 AM
Site:Well MAY-AB3(4-5)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 6 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015007999
Collection Date:17-Mar-15 3:45 PM
Site:Well MAY-AB4(53-55)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 7 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008000
Collection Date:18-Mar-15 2:30 PM
Site:Well MAY-AB2(4-5)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 8 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008001
Collection Date:17-Mar-15 1:05 PM
Site:Well MAY-AB4(4-5)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 9 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008002
Collection Date:18-Mar-15 12:20 PM
Site:Well MAY-AB3(21.6-23.4)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 10 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008003
Collection Date:18-Mar-15 1:15 PM
Site:Well MAY-AB3(41.7-42.5)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 11 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008004
Collection Date:17-Mar-15 3:30 PM
Site:Well MAY-AB4(33-35)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 12 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008005
Collection Date:17-Mar-15 3:30 PM
Site:Well MAY-AB4(33-35)-DUP
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 13 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008006
Collection Date:19-Mar-15 9:20 AM
Site:Well MAY-AB1(4-5)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 14 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008007
Collection Date:19-Mar-15 12:30 PM
Site:Well MAY-AB1(48-50)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 15 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008008
Collection Date:19-Mar-15 12:40 PM
Site:Well MAY-AB1(34.3-35.0)
Matrix:SOIL
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 16 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008009
Collection Date:19-Mar-15 9:00 AM
Site:Well AB-1EB
Matrix:OTHER
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 17 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008010
Collection Date:18-Mar-15 8:50 AM
Site:Well AB-3EB
Matrix:OTHER
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 18 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008011
Collection Date:17-Mar-15 12:35 PM
Site:Well AB-4EB
Matrix:OTHER
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 19 of 125
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
2015008012
Collection Date:18-Mar-15 4:00 PM
Site:Well AB-2EB
Matrix:OTHER
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 20 of 125
#=CL#
April 08, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92242381
92242381
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J150305555
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 23, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Marge Galvin-Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 104
Page 21 of 125
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92242381
J150305555
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 104
Page 22 of 125
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92242381
J150305555
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 104
Page 23 of 125
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID Matrix Date Collected Date Received
92242381001 2015007996 Solid 03/18/15 15:33 03/23/15 15:04
92242381002 2015007999 Solid 03/17/15 15:45 03/23/15 15:04
92242381003 2015008002 Solid 03/18/15 12:20 03/23/15 15:04
92242381004 2015008007 Solid 03/19/15 12:30 03/23/15 15:04
92242381005 2015007997 Solid 03/18/15 15:50 03/23/15 15:04
92242381006 2015007998 Solid 03/18/15 09:30 03/23/15 15:04
92242381007 2015008000 Solid 03/18/15 14:30 03/23/15 15:04
92242381008 2015008001 Solid 03/17/15 13:05 03/23/15 15:04
92242381009 2015008003 Solid 03/18/15 13:15 03/23/15 15:04
92242381010 2015008004 Solid 03/17/15 15:30 03/23/15 15:04
92242381011 2015008005 Solid 03/17/15 15:30 03/23/15 15:04
92242381012 2015008006 Solid 03/19/15 09:20 03/23/15 15:04
92242381013 2015008008 Solid 03/19/15 12:40 03/23/15 15:04
92242381014 2015008009 Water 03/19/15 09:00 03/23/15 15:04
92242381015 2015008010 Water 03/18/15 08:50 03/23/15 15:04
92242381016 2015008011 Water 03/17/15 12:35 03/23/15 15:04
92242381017 2015008012 Water 03/18/15 16:00 03/23/15 15:04
92242381018 2015007996 SPLP Water 03/18/15 15:35 03/23/15 15:04
92242381019 2015007999 SPLP Water 03/17/15 15:45 03/23/15 15:04
92242381020 2015008002 SPLP Water 03/18/15 12:20 03/23/15 15:04
92242381021 2015008007 SPLP Water 03/18/15 12:30 03/23/15 15:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 104
Page 24 of 125
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92242381001 2015007996 EPA 6010 16 PASI-OTAP
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-ASER
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381002 2015007999 EPA 6010 16 PASI-OTAP
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-ASER
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381003 2015008002 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-ASER
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381004 2015008007 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 104
Page 25 of 125
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 9045 1 PASI-AMLS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-ASER
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381005 2015007997 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381006 2015007998 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381007 2015008000 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OCMB
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381008 2015008001 EPA 6010 16 PASI-OCKJ, TAP
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OCMB
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 104
Page 26 of 125
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 9056 1 PASI-OCMB
EPA 9060 6 PASI-GTJJ
92242381009 2015008003 EPA 6010 16 PASI-OCKJ, TAP
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OAIS
EPA 9056 1 PASI-OAIS
EPA 9060 6 PASI-GTJJ
92242381010 2015008004 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OAIS
EPA 9056 1 PASI-OAIS
EPA 9060 6 PASI-GTJJ
92242381011 2015008005 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OAIS
EPA 9056 1 PASI-OAIS
EPA 9060 6 PASI-GTJJ
92242381012 2015008006 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OAIS
EPA 9056 1 PASI-OAIS
EPA 9060 6 PASI-GTJJ
92242381013 2015008008 EPA 6010 16 PASI-OCKJ
EPA 6020 8 PASI-OCRT
EPA 7471 1 PASI-OHEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 104
Page 27 of 125
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
ASTM D2974-87 1 PASI-ORPM
EPA 9045 1 PASI-AMLS
EPA 9056 2 PASI-OAIS
EPA 9056 1 PASI-OAIS
EPA 9060 6 PASI-GTJJ
92242381014 2015008009 EPA 6020A 24 PASI-MTT3
EPA 7470 1 PASI-MDM
92242381015 2015008010 EPA 6020A 24 PASI-MTT3
EPA 7470 1 PASI-MDM
92242381016 2015008011 EPA 6020A 24 PASI-MTT3
EPA 7470 1 PASI-MDM
92242381017 2015008012 EPA 6020A 24 PASI-MTT3
EPA 7470 1 PASI-MDM
92242381018 2015007996 SPLP EPA 6020A 24 PASI-MRJS
EPA 7470 1 PASI-MJDD
92242381019 2015007999 SPLP EPA 6020A 24 PASI-MRJS
EPA 7470 1 PASI-MJDD
92242381020 2015008002 SPLP EPA 6020A 24 PASI-MRJS
EPA 7470 1 PASI-MJDD
92242381021 2015008007 SPLP EPA 6020A 24 PASI-MRJS
EPA 7470 1 PASI-MJDD
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 104
Page 28 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381001 2015007996
Aluminum 3200 mg/kg 04/02/15 09:35 M17.7EPA 6010
Barium 44.1 mg/kg 04/02/15 09:35 M10.77EPA 6010
Beryllium 0.73 mg/kg 04/02/15 09:350.077EPA 6010
Boron 7.3 mg/kg 04/02/15 09:353.9EPA 6010
Calcium 551 mg/kg 04/02/15 09:3538.7EPA 6010
Chromium 10.6 mg/kg 04/02/15 09:350.39EPA 6010
Copper 10.6 mg/kg 04/02/15 09:350.39EPA 6010
Iron 2840 mg/kg 04/02/15 09:35 M13.1EPA 6010
Magnesium 212 mg/kg 04/02/15 09:3538.7EPA 6010
Manganese 24.1 mg/kg 04/02/15 09:35 M10.39EPA 6010
Molybdenum 0.53J mg/kg 04/02/15 09:350.77EPA 6010
Nickel 7.2 mg/kg 04/02/15 09:350.39EPA 6010
Potassium 396 mg/kg 04/02/15 09:35 M177.4EPA 6010
Sodium 81.5 mg/kg 04/02/15 09:3577.4EPA 6010
Strontium 25.4 mg/kg 04/02/15 09:35 M10.77EPA 6010
Zinc 10.5 mg/kg 04/02/15 09:351.5EPA 6010
Arsenic 3.3J mg/kg 03/31/15 21:42 D33.9EPA 6020
Cobalt 4.5 mg/kg 03/31/15 21:42 D33.9EPA 6020
Lead 7.4 mg/kg 03/31/15 21:42 D33.9EPA 6020
Vanadium 16.9 mg/kg 03/31/15 21:42 D33.9EPA 6020
Percent Moisture 33.9 %04/01/15 16:190.10ASTM D2974-87
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10EPA 9045
Sulfate 17.8 mg/L 04/01/15 20:10 B,D315.1EPA 300.0
Nitrogen, Nitrate 308 mg/L 03/31/15 19:26 B,H115.1EPA 353.2
Sulfate 200J mg/kg 03/28/15 11:06 D3378EPA 9056
Total Organic Carbon 25300 mg/kg 04/03/15 12:072660EPA 9060
Total Organic Carbon 25200 mg/kg 04/03/15 12:142650EPA 9060
Total Organic Carbon 26400 mg/kg 04/03/15 12:202620EPA 9060
Total Organic Carbon 16700 mg/kg 04/03/15 12:272610EPA 9060
Mean Total Organic Carbon 23400 mg/kg 04/03/15 12:072640EPA 9060
RSD%19.3 %04/03/15 12:07EPA 9060
92242381002 2015007999
Aluminum 8960 mg/kg 04/02/15 09:468.6EPA 6010
Barium 67.3 mg/kg 04/02/15 09:460.86EPA 6010
Beryllium 2.3 mg/kg 04/02/15 09:460.086EPA 6010
Boron 25.5 mg/kg 04/02/15 09:464.3EPA 6010
Calcium 1100 mg/kg 04/02/15 09:4642.8EPA 6010
Chromium 24.5 mg/kg 04/02/15 09:460.43EPA 6010
Copper 33.1 mg/kg 04/02/15 09:460.43EPA 6010
Iron 2860 mg/kg 04/02/15 09:463.4EPA 6010
Magnesium 497 mg/kg 04/02/15 09:4642.8EPA 6010
Manganese 13.6 mg/kg 04/02/15 09:460.43EPA 6010
Molybdenum 1.2 mg/kg 04/02/15 09:460.86EPA 6010
Nickel 18.5 mg/kg 04/02/15 09:460.43EPA 6010
Potassium 1230 mg/kg 04/02/15 09:4685.6EPA 6010
Sodium 119 mg/kg 04/02/15 09:4685.6EPA 6010
Strontium 60.6 mg/kg 04/02/15 09:460.86EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 104
Page 29 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381002 2015007999
Zinc 19.0 mg/kg 04/02/15 09:461.7EPA 6010
Arsenic 10 mg/kg 03/31/15 21:58 D34.3EPA 6020
Cobalt 12.9 mg/kg 03/31/15 21:58 D3,M64.3EPA 6020
Lead 14.5 mg/kg 03/31/15 21:58 D3,M64.3EPA 6020
Vanadium 64.7 mg/kg 03/31/15 21:58 D4,M64.3EPA 6020
Percent Moisture 39.9 %04/01/15 16:190.10ASTM D2974-87
pH at 25 Degrees C 7.8 Std. Units 03/25/15 11:500.10EPA 9045
Sulfate 12.6 mg/L 04/01/15 20:24 B,D36.7EPA 300.0
Nitrogen, Nitrate 333 mg/L 03/31/15 19:27 B,H116.6EPA 353.2
Total Organic Carbon 19600 mg/kg 04/03/15 13:193870EPA 9060
Total Organic Carbon 19400 mg/kg 04/03/15 13:263940EPA 9060
Total Organic Carbon 18500 mg/kg 04/03/15 13:323870EPA 9060
Total Organic Carbon 26500 mg/kg 04/03/15 13:383940EPA 9060
Mean Total Organic Carbon 21000 mg/kg 04/03/15 13:193900EPA 9060
RSD%17.6 %04/03/15 13:19EPA 9060
92242381003 2015008002
Aluminum 3760 mg/kg 04/01/15 21:216.7EPA 6010
Barium 41.1 mg/kg 04/01/15 21:210.67EPA 6010
Beryllium 0.93 mg/kg 04/01/15 21:210.067EPA 6010
Boron 7.3 mg/kg 04/01/15 21:213.4EPA 6010
Calcium 581 mg/kg 04/01/15 21:2133.6EPA 6010
Chromium 13.3 mg/kg 04/01/15 21:210.34EPA 6010
Copper 12.9 mg/kg 04/01/15 21:210.34EPA 6010
Iron 2470 mg/kg 04/01/15 21:212.7EPA 6010
Magnesium 204 mg/kg 04/01/15 21:2133.6EPA 6010
Manganese 14.1 mg/kg 04/01/15 21:210.34EPA 6010
Molybdenum 0.59J mg/kg 04/01/15 21:210.67EPA 6010
Nickel 6.8 mg/kg 04/01/15 21:210.34EPA 6010
Potassium 451 mg/kg 04/01/15 21:2167.2EPA 6010
Sodium 63.0J mg/kg 04/01/15 21:2167.2EPA 6010
Strontium 20.6 mg/kg 04/01/15 21:210.67EPA 6010
Zinc 8.2 mg/kg 04/01/15 21:211.3EPA 6010
Arsenic 3.3J mg/kg 03/31/15 22:05 D33.4EPA 6020
Cobalt 4.0 mg/kg 03/31/15 22:05 D33.4EPA 6020
Lead 5.2 mg/kg 03/31/15 22:05 D33.4EPA 6020
Vanadium 15.0 mg/kg 03/31/15 22:05 D33.4EPA 6020
Percent Moisture 27.6 %04/01/15 16:190.10ASTM D2974-87
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10EPA 9045
Sulfate 19.9 mg/L 04/01/15 20:38 B,D313.8EPA 300.0
Nitrogen, Nitrate 236 mg/L 03/31/15 19:28 B,H113.8EPA 353.2
Sulfate 326J mg/kg 03/28/15 11:49 D3350EPA 9056
Total Organic Carbon 10800 mg/kg 04/03/15 13:44834EPA 9060
Total Organic Carbon 14800 mg/kg 04/03/15 13:49822EPA 9060
Total Organic Carbon 23100 mg/kg 04/03/15 13:55826EPA 9060
Total Organic Carbon 11700 mg/kg 04/03/15 14:02824EPA 9060
Mean Total Organic Carbon 15100 mg/kg 04/03/15 13:44826EPA 9060
RSD%37.1 %04/03/15 13:44EPA 9060
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 104
Page 30 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381004 2015008007
Aluminum 3060 mg/kg 04/01/15 21:257.0EPA 6010
Barium 34.7 mg/kg 04/01/15 21:250.70EPA 6010
Beryllium 0.64 mg/kg 04/01/15 21:250.070EPA 6010
Boron 5.9 mg/kg 04/01/15 21:253.5EPA 6010
Calcium 483 mg/kg 04/01/15 21:2535.0EPA 6010
Chromium 8.0 mg/kg 04/01/15 21:250.35EPA 6010
Copper 8.0 mg/kg 04/01/15 21:250.35EPA 6010
Iron 1820 mg/kg 04/01/15 21:252.8EPA 6010
Magnesium 180 mg/kg 04/01/15 21:2535.0EPA 6010
Manganese 9.4 mg/kg 04/01/15 21:250.35EPA 6010
Molybdenum 0.63J mg/kg 04/01/15 21:250.70EPA 6010
Nickel 5.4 mg/kg 04/01/15 21:250.35EPA 6010
Potassium 367 mg/kg 04/01/15 21:2570.0EPA 6010
Sodium 55.0J mg/kg 04/01/15 21:2570.0EPA 6010
Strontium 17.9 mg/kg 04/01/15 21:250.70EPA 6010
Zinc 6.8 mg/kg 04/01/15 21:251.4EPA 6010
Arsenic 2.6J mg/kg 03/31/15 22:08 D33.5EPA 6020
Cobalt 3.4J mg/kg 03/31/15 22:08 D33.5EPA 6020
Lead 4.0 mg/kg 03/31/15 22:08 D33.5EPA 6020
Vanadium 13.7 mg/kg 03/31/15 22:08 D33.5EPA 6020
Percent Moisture 30.7 %04/01/15 16:200.10ASTM D2974-87
pH at 25 Degrees C 7.3 Std. Units 03/30/15 12:550.10EPA 9045
Sulfate 11.8 mg/L 04/02/15 11:14 B,D35.8EPA 300.0
Nitrogen, Nitrate 180 mg/L 03/31/15 18:44 B,H18.7EPA 353.2
Total Organic Carbon 49000 mg/kg 04/03/15 14:083100EPA 9060
Total Organic Carbon 30100 mg/kg 04/03/15 14:153110EPA 9060
Total Organic Carbon 43500 mg/kg 04/03/15 14:223140EPA 9060
Total Organic Carbon 34500 mg/kg 04/03/15 14:303100EPA 9060
Mean Total Organic Carbon 39300 mg/kg 04/03/15 14:083110EPA 9060
RSD%21.7 %04/03/15 14:08EPA 9060
92242381005 2015007997
Aluminum 3460 mg/kg 04/01/15 21:297.8EPA 6010
Barium 51.8 mg/kg 04/01/15 21:290.78EPA 6010
Beryllium 0.78 mg/kg 04/01/15 21:290.078EPA 6010
Boron 7.7 mg/kg 04/01/15 21:293.9EPA 6010
Calcium 632 mg/kg 04/01/15 21:2938.9EPA 6010
Chromium 10.2 mg/kg 04/01/15 21:290.39EPA 6010
Copper 11.7 mg/kg 04/01/15 21:290.39EPA 6010
Iron 2420 mg/kg 04/01/15 21:293.1EPA 6010
Magnesium 231 mg/kg 04/01/15 21:2938.9EPA 6010
Manganese 22.6 mg/kg 04/01/15 21:290.39EPA 6010
Molybdenum 0.54J mg/kg 04/01/15 21:290.78EPA 6010
Nickel 7.2 mg/kg 04/01/15 21:290.39EPA 6010
Potassium 402 mg/kg 04/01/15 21:2977.7EPA 6010
Sodium 92.2 mg/kg 04/01/15 21:2977.7EPA 6010
Strontium 28.9 mg/kg 04/01/15 21:290.78EPA 6010
Zinc 10.1 mg/kg 04/01/15 21:291.6EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 104
Page 31 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381005 2015007997
Arsenic 3.4J mg/kg 03/31/15 22:10 D33.9EPA 6020
Cobalt 4.7 mg/kg 03/31/15 22:10 D33.9EPA 6020
Lead 5.3 mg/kg 03/31/15 22:10 D33.9EPA 6020
Vanadium 16.7 mg/kg 03/31/15 22:10 D33.9EPA 6020
Percent Moisture 32.3 %04/01/15 16:200.10ASTM D2974-87
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10EPA 9045
Sulfate 216J mg/kg 03/28/15 12:32 D3362EPA 9056
Total Organic Carbon 16200 mg/kg 04/03/15 14:362380EPA 9060
Total Organic Carbon 17800 mg/kg 04/03/15 14:422340EPA 9060
Total Organic Carbon 15200 mg/kg 04/03/15 14:482380EPA 9060
Total Organic Carbon 14200 mg/kg 04/03/15 14:572320EPA 9060
Mean Total Organic Carbon 15800 mg/kg 04/03/15 14:362350EPA 9060
RSD%9.5 %04/03/15 14:36EPA 9060
92242381006 2015007998
Aluminum 863 mg/kg 04/01/15 21:336.7EPA 6010
Barium 38.7 mg/kg 04/01/15 21:330.67EPA 6010
Beryllium 0.20 mg/kg 04/01/15 21:330.067EPA 6010
Boron 2.6J mg/kg 04/01/15 21:333.3EPA 6010
Calcium 377 mg/kg 04/01/15 21:3333.3EPA 6010
Chromium 2.0 mg/kg 04/01/15 21:330.33EPA 6010
Copper 3.0 mg/kg 04/01/15 21:330.33EPA 6010
Iron 1010 mg/kg 04/01/15 21:332.7EPA 6010
Magnesium 58.1 mg/kg 04/01/15 21:3333.3EPA 6010
Manganese 11.9 mg/kg 04/01/15 21:330.33EPA 6010
Molybdenum 0.38J mg/kg 04/01/15 21:330.67EPA 6010
Nickel 2.6 mg/kg 04/01/15 21:330.33EPA 6010
Potassium 110 mg/kg 04/01/15 21:3366.7EPA 6010
Strontium 8.0 mg/kg 04/01/15 21:330.67EPA 6010
Zinc 2.1 mg/kg 04/01/15 21:331.3EPA 6010
Vanadium 2.9J mg/kg 03/31/15 22:12 D33.3EPA 6020
Percent Moisture 21.6 %04/01/15 16:210.10ASTM D2974-87
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10EPA 9045
Total Organic Carbon 6380 mg/kg 04/03/15 15:031110EPA 9060
Total Organic Carbon 7810 mg/kg 04/03/15 15:091120EPA 9060
Total Organic Carbon 5960 mg/kg 04/03/15 15:151120EPA 9060
Total Organic Carbon 6370 mg/kg 04/03/15 15:211120EPA 9060
Mean Total Organic Carbon 6630 mg/kg 04/03/15 15:031120EPA 9060
RSD%12.3 %04/03/15 15:03EPA 9060
92242381007 2015008000
Aluminum 281 mg/kg 04/01/15 21:378.8EPA 6010
Barium 9.9 mg/kg 04/01/15 21:370.88EPA 6010
Beryllium 0.091 mg/kg 04/01/15 21:370.088EPA 6010
Calcium 70.7 mg/kg 04/01/15 21:3744.1EPA 6010
Chromium 0.86 mg/kg 04/01/15 21:370.44EPA 6010
Copper 1.2 mg/kg 04/01/15 21:370.44EPA 6010
Iron 320 mg/kg 04/01/15 21:373.5EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 104
Page 32 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381007 2015008000
Magnesium 25.4J mg/kg 04/01/15 21:3744.1EPA 6010
Manganese 1.7 mg/kg 04/01/15 21:370.44EPA 6010
Nickel 1.1 mg/kg 04/01/15 21:370.44EPA 6010
Strontium 2.9 mg/kg 04/01/15 21:370.88EPA 6010
Zinc 1.1J mg/kg 04/01/15 21:371.8EPA 6010
Percent Moisture 41.2 %04/01/15 16:210.10ASTM D2974-87
pH at 25 Degrees C 6.3 Std. Units 03/30/15 12:550.10EPA 9045
Total Organic Carbon 11400 mg/kg 04/03/15 15:421030EPA 9060
Total Organic Carbon 19400 mg/kg 04/03/15 15:521020EPA 9060
Total Organic Carbon 10300 mg/kg 04/03/15 15:591020EPA 9060
Total Organic Carbon 8260 mg/kg 04/03/15 16:051010EPA 9060
Mean Total Organic Carbon 12300 mg/kg 04/03/15 15:421020EPA 9060
RSD%39.4 %04/03/15 15:42EPA 9060
92242381008 2015008001
Aluminum 485 mg/kg 04/01/15 21:417.0EPA 6010
Barium 16.9 mg/kg 04/02/15 10:11 D33.5EPA 6010
Beryllium 0.14 mg/kg 04/01/15 21:410.070EPA 6010
Calcium 199 mg/kg 04/01/15 21:4134.9EPA 6010
Chromium 1.9 mg/kg 04/01/15 21:410.35EPA 6010
Copper 2.8 mg/kg 04/02/15 10:11 D31.7EPA 6010
Iron 554 mg/kg 04/01/15 21:412.8EPA 6010
Magnesium 36.2 mg/kg 04/01/15 21:4134.9EPA 6010
Manganese 37.7 mg/kg 04/01/15 21:410.35EPA 6010
Molybdenum 0.38J mg/kg 04/01/15 21:410.70EPA 6010
Nickel 2.1 mg/kg 04/01/15 21:410.35EPA 6010
Potassium 63.7J mg/kg 04/01/15 21:4169.9EPA 6010
Strontium 4.7 mg/kg 04/01/15 21:410.70EPA 6010
Percent Moisture 28.0 %04/01/15 16:210.10ASTM D2974-87
pH at 25 Degrees C 6.6 Std. Units 03/25/15 11:500.10EPA 9045
Total Organic Carbon 16800 mg/kg 04/03/15 16:10828EPA 9060
Total Organic Carbon 16000 mg/kg 04/03/15 16:17827EPA 9060
Total Organic Carbon 10900 mg/kg 04/03/15 16:28837EPA 9060
Total Organic Carbon 14200 mg/kg 04/03/15 16:35833EPA 9060
Mean Total Organic Carbon 14500 mg/kg 04/03/15 16:10831EPA 9060
RSD%18.3 %04/03/15 16:10EPA 9060
92242381009 2015008003
Aluminum 13900 mg/kg 04/01/15 21:456.9EPA 6010
Barium 83.2 mg/kg 04/01/15 21:450.69EPA 6010
Beryllium 3.1 mg/kg 04/02/15 10:15 D30.35EPA 6010
Boron 32.9 mg/kg 04/02/15 10:15 D317.3EPA 6010
Calcium 1080 mg/kg 04/01/15 21:4534.6EPA 6010
Chromium 54.7 mg/kg 04/02/15 10:15 D31.7EPA 6010
Copper 43.4 mg/kg 04/02/15 10:15 D31.7EPA 6010
Iron 3020 mg/kg 04/01/15 21:452.8EPA 6010
Magnesium 541 mg/kg 04/01/15 21:4534.6EPA 6010
Manganese 69.4 mg/kg 04/02/15 10:15 D31.7EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 104
Page 33 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381009 2015008003
Molybdenum 1.4 mg/kg 04/01/15 21:450.69EPA 6010
Nickel 22.5 mg/kg 04/01/15 21:450.35EPA 6010
Potassium 1650 mg/kg 04/01/15 21:4569.2EPA 6010
Sodium 155 mg/kg 04/01/15 21:4569.2EPA 6010
Strontium 83.7 mg/kg 04/01/15 21:450.69EPA 6010
Zinc 36.4 mg/kg 04/01/15 21:451.4EPA 6010
Arsenic 11.2 mg/kg 03/31/15 22:19 D33.5EPA 6020
Cobalt 17.7 mg/kg 03/31/15 22:19 D33.5EPA 6020
Lead 21.9 mg/kg 03/31/15 22:19 D33.5EPA 6020
Vanadium 88.1 mg/kg 03/31/15 22:19 D43.5EPA 6020
Percent Moisture 24.7 %04/01/15 16:220.10ASTM D2974-87
pH at 25 Degrees C 6.4 Std. Units 03/25/15 11:500.10EPA 9045
Total Organic Carbon 9330 mg/kg 04/03/15 16:425670EPA 9060
Total Organic Carbon 7650 mg/kg 04/03/15 16:485810EPA 9060
Total Organic Carbon 8290 mg/kg 04/03/15 16:545860EPA 9060
Total Organic Carbon 8680 mg/kg 04/03/15 16:595890EPA 9060
Mean Total Organic Carbon 8490 mg/kg 04/03/15 16:425810EPA 9060
RSD%8.3 %04/03/15 16:42EPA 9060
92242381010 2015008004
Aluminum 9620 mg/kg 04/01/15 21:497.1EPA 6010
Barium 80.9 mg/kg 04/01/15 21:490.71EPA 6010
Beryllium 2.6 mg/kg 04/01/15 21:490.071EPA 6010
Boron 31.3 mg/kg 04/01/15 21:493.5EPA 6010
Calcium 1150 mg/kg 04/01/15 21:4935.4EPA 6010
Chromium 31.9 mg/kg 04/01/15 21:490.35EPA 6010
Copper 33.3 mg/kg 04/01/15 21:490.35EPA 6010
Iron 3290 mg/kg 04/01/15 21:492.8EPA 6010
Magnesium 388 mg/kg 04/01/15 21:4935.4EPA 6010
Manganese 21.1 mg/kg 04/01/15 21:490.35EPA 6010
Molybdenum 1.6 mg/kg 04/01/15 21:490.71EPA 6010
Nickel 18.7 mg/kg 04/01/15 21:490.35EPA 6010
Potassium 895 mg/kg 04/01/15 21:4970.9EPA 6010
Sodium 102 mg/kg 04/01/15 21:4970.9EPA 6010
Strontium 53.0 mg/kg 04/01/15 21:490.71EPA 6010
Zinc 24.0 mg/kg 04/01/15 21:491.4EPA 6010
Arsenic 13.4 mg/kg 04/02/15 16:09 D33.5EPA 6020
Cobalt 13.6 mg/kg 03/31/15 22:29 D33.5EPA 6020
Lead 17.8 mg/kg 04/02/15 16:09 D33.5EPA 6020
Vanadium 63.6 mg/kg 03/31/15 22:29 D43.5EPA 6020
Percent Moisture 28.8 %04/01/15 16:230.10ASTM D2974-87
pH at 25 Degrees C 8.0 Std. Units 03/25/15 11:500.10EPA 9045
Total Organic Carbon 16700 mg/kg 04/03/15 17:063390EPA 9060
Total Organic Carbon 18700 mg/kg 04/03/15 17:123440EPA 9060
Total Organic Carbon 17300 mg/kg 04/03/15 17:193500EPA 9060
Total Organic Carbon 25100 mg/kg 04/03/15 17:253450EPA 9060
Mean Total Organic Carbon 19400 mg/kg 04/03/15 17:063450EPA 9060
RSD%19.8 %04/03/15 17:06EPA 9060
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 104
Page 34 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381011 2015008005
Aluminum 13400 mg/kg 04/01/15 21:546.2EPA 6010
Barium 96.9 mg/kg 04/01/15 21:540.62EPA 6010
Beryllium 3.1 mg/kg 04/01/15 21:540.062EPA 6010
Boron 36.4 mg/kg 04/01/15 21:543.1EPA 6010
Calcium 1520 mg/kg 04/01/15 21:5431.1EPA 6010
Chromium 39.4 mg/kg 04/01/15 21:540.31EPA 6010
Copper 40.6 mg/kg 04/01/15 21:540.31EPA 6010
Iron 3320 mg/kg 04/01/15 21:542.5EPA 6010
Magnesium 603 mg/kg 04/01/15 21:5431.1EPA 6010
Manganese 15.8 mg/kg 04/01/15 21:540.31EPA 6010
Molybdenum 2.0 mg/kg 04/01/15 21:540.62EPA 6010
Nickel 25.7 mg/kg 04/01/15 21:540.31EPA 6010
Potassium 1560 mg/kg 04/01/15 21:5462.1EPA 6010
Sodium 158 mg/kg 04/01/15 21:5462.1EPA 6010
Strontium 78.8 mg/kg 04/01/15 21:540.62EPA 6010
Zinc 39.0 mg/kg 04/01/15 21:541.2EPA 6010
Arsenic 17.0 mg/kg 04/02/15 16:113.1EPA 6020
Cadmium 0.30J mg/kg 04/02/15 16:110.37EPA 6020
Cobalt 19.7 mg/kg 03/31/15 22:31 D33.1EPA 6020
Lead 25.5 mg/kg 04/02/15 16:113.1EPA 6020
Vanadium 112 mg/kg 03/31/15 22:31 D43.1EPA 6020
Percent Moisture 21.5 %04/01/15 16:230.10ASTM D2974-87
pH at 25 Degrees C 7.8 Std. Units 03/25/15 11:500.10EPA 9045
Total Organic Carbon 22500 mg/kg 04/06/15 07:403700EPA 9060
Total Organic Carbon 12400 mg/kg 04/06/15 07:463730EPA 9060
Total Organic Carbon 19200 mg/kg 04/06/15 07:523790EPA 9060
Total Organic Carbon 14200 mg/kg 04/06/15 07:573780EPA 9060
Mean Total Organic Carbon 17100 mg/kg 04/06/15 07:403750EPA 9060
RSD%27.1 %04/06/15 07:40EPA 9060
92242381012 2015008006
Aluminum 859 mg/kg 04/01/15 21:586.2EPA 6010
Barium 38.6 mg/kg 04/01/15 21:580.62EPA 6010
Beryllium 0.26 mg/kg 04/01/15 21:580.062EPA 6010
Calcium 248 mg/kg 04/01/15 21:5830.8EPA 6010
Chromium 2.2 mg/kg 04/01/15 21:580.31EPA 6010
Copper 4.8 mg/kg 04/01/15 21:580.31EPA 6010
Iron 1100 mg/kg 04/01/15 21:582.5EPA 6010
Magnesium 65.1 mg/kg 04/01/15 21:5830.8EPA 6010
Manganese 17.7 mg/kg 04/01/15 21:580.31EPA 6010
Molybdenum 0.42J mg/kg 04/01/15 21:580.62EPA 6010
Nickel 3.3 mg/kg 04/01/15 21:580.31EPA 6010
Potassium 116 mg/kg 04/01/15 21:5861.5EPA 6010
Strontium 11.0 mg/kg 04/01/15 21:580.62EPA 6010
Zinc 4.5 mg/kg 04/01/15 21:581.2EPA 6010
Vanadium 2.7J mg/kg 03/31/15 22:33 D33.1EPA 6020
Percent Moisture 19.9 %04/01/15 16:240.10ASTM D2974-87
pH at 25 Degrees C 6.2 Std. Units 03/30/15 12:550.10EPA 9045
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 104
Page 35 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381012 2015008006
Total Organic Carbon 14300 mg/kg 04/06/15 08:49747EPA 9060
Total Organic Carbon 9190 mg/kg 04/06/15 08:55748EPA 9060
Total Organic Carbon 11400 mg/kg 04/06/15 09:00757EPA 9060
Total Organic Carbon 8370 mg/kg 04/06/15 09:06745EPA 9060
Mean Total Organic Carbon 10800 mg/kg 04/06/15 08:49749EPA 9060
RSD%24.6 %04/06/15 08:49EPA 9060
92242381013 2015008008
Aluminum 3530 mg/kg 04/01/15 22:147.7EPA 6010
Barium 34.6 mg/kg 04/01/15 22:140.77EPA 6010
Beryllium 0.96 mg/kg 04/01/15 22:140.077EPA 6010
Boron 9.2 mg/kg 04/01/15 22:143.9EPA 6010
Calcium 517 mg/kg 04/01/15 22:1438.7EPA 6010
Chromium 10.6 mg/kg 04/01/15 22:140.39EPA 6010
Copper 12.1 mg/kg 04/01/15 22:140.39EPA 6010
Iron 2230 mg/kg 04/01/15 22:143.1EPA 6010
Magnesium 206 mg/kg 04/01/15 22:1438.7EPA 6010
Manganese 9.4 mg/kg 04/01/15 22:140.39EPA 6010
Molybdenum 0.55J mg/kg 04/01/15 22:140.77EPA 6010
Nickel 7.0 mg/kg 04/01/15 22:140.39EPA 6010
Potassium 436 mg/kg 04/01/15 22:1477.3EPA 6010
Sodium 53.9J mg/kg 04/01/15 22:1477.3EPA 6010
Strontium 19.5 mg/kg 04/01/15 22:140.77EPA 6010
Zinc 8.5 mg/kg 04/01/15 22:141.5EPA 6010
Arsenic 2.9J mg/kg 04/02/15 16:153.9EPA 6020
Cobalt 4.2 mg/kg 03/31/15 22:35 D33.9EPA 6020
Lead 4.8 mg/kg 04/02/15 16:153.9EPA 6020
Vanadium 19.0 mg/kg 03/31/15 22:35 D33.9EPA 6020
Percent Moisture 34.2 %04/01/15 16:240.10ASTM D2974-87
pH at 25 Degrees C 7.2 Std. Units 03/30/15 12:550.10EPA 9045
Total Organic Carbon 14400 mg/kg 04/06/15 09:111800EPA 9060
Total Organic Carbon 18800 mg/kg 04/06/15 09:181820EPA 9060
Total Organic Carbon 23100 mg/kg 04/06/15 09:231820EPA 9060
Total Organic Carbon 15800 mg/kg 04/06/15 09:301810EPA 9060
Mean Total Organic Carbon 18000 mg/kg 04/06/15 09:111810EPA 9060
RSD%21.3 %04/06/15 09:11EPA 9060
92242381014 2015008009
Barium 0.44 ug/L 03/28/15 15:370.30EPA 6020A
Chromium 1.5 ug/L 03/28/15 15:370.50EPA 6020A
Iron 93.2 ug/L 03/28/15 15:3750.0EPA 6020A
Manganese 1.2 ug/L 03/28/15 15:370.50EPA 6020A
92242381015 2015008010
Calcium 46.3 ug/L 03/28/15 15:4040.0EPA 6020A
Chromium 0.60 ug/L 03/28/15 15:400.50EPA 6020A
Manganese 1.3 ug/L 03/28/15 15:400.50EPA 6020A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 104
Page 36 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381016 2015008011
Barium 1.8 ug/L 03/28/15 15:430.30EPA 6020A
Calcium 85.2 ug/L 03/28/15 15:4340.0EPA 6020A
Chromium 2.7 ug/L 03/28/15 15:430.50EPA 6020A
Iron 169 ug/L 03/28/15 15:4350.0EPA 6020A
Magnesium 12.0 ug/L 03/28/15 15:4310.0EPA 6020A
Manganese 4.3 ug/L 03/28/15 15:430.50EPA 6020A
Molybdenum 0.95 ug/L 03/28/15 15:430.50EPA 6020A
Nickel 1.1 ug/L 03/28/15 15:430.50EPA 6020A
Strontium 0.59 ug/L 03/28/15 15:430.50EPA 6020A
92242381017 2015008012
Barium 0.40 ug/L 03/28/15 15:460.30EPA 6020A
Calcium 124 ug/L 03/28/15 15:4640.0EPA 6020A
Chromium 1.6 ug/L 03/28/15 15:460.50EPA 6020A
Iron 66.4 ug/L 03/28/15 15:4650.0EPA 6020A
Magnesium 14.6 ug/L 03/28/15 15:4610.0EPA 6020A
Manganese 3.1 ug/L 03/28/15 15:460.50EPA 6020A
Molybdenum 0.88 ug/L 03/28/15 15:460.50EPA 6020A
Sodium 94.2 ug/L 03/28/15 15:4650.0EPA 6020A
Strontium 0.53 ug/L 03/28/15 15:460.50EPA 6020A
92242381018 2015007996 SPLP
Aluminum 152 ug/L 04/06/15 08:5310.0EPA 6020A
Antimony 5.0 ug/L 04/06/15 08:530.50EPA 6020A
Arsenic 3.5 ug/L 04/06/15 08:530.50EPA 6020A
Barium 308 ug/L 04/06/15 08:530.30EPA 6020A
Boron 119 ug/L 04/06/15 08:535.0EPA 6020A
Calcium 3060 ug/L 04/06/15 08:5340.0EPA 6020A
Chromium 1.8 ug/L 04/06/15 08:530.50EPA 6020A
Cobalt 0.89 ug/L 04/06/15 08:530.50EPA 6020A
Copper 3.0 ug/L 04/06/15 08:531.0EPA 6020A
Lead 0.73 ug/L 04/06/15 08:530.10EPA 6020A
Magnesium 688 ug/L 04/06/15 08:5310.0EPA 6020A
Manganese 148 ug/L 04/06/15 08:530.50EPA 6020A
Molybdenum 2.2 ug/L 04/06/15 08:530.50EPA 6020A
Nickel 4.4 ug/L 04/06/15 08:530.50EPA 6020A
Potassium 643 ug/L 04/06/15 08:5350.0EPA 6020A
Selenium 1.9 ug/L 04/06/15 08:530.50EPA 6020A
Sodium 2110 ug/L 04/06/15 08:5350.0EPA 6020A
Strontium 37.2 ug/L 04/06/15 08:530.50EPA 6020A
Thallium 0.11 ug/L 04/06/15 08:530.10EPA 6020A
Vanadium 72.6 ug/L 04/06/15 08:531.0EPA 6020A
Zinc 159 ug/L 04/06/15 08:535.0EPA 6020A
92242381019 2015007999 SPLP
Aluminum 330 ug/L 04/06/15 08:5810.0EPA 6020A
Antimony 3.4 ug/L 04/06/15 08:580.50EPA 6020A
Arsenic 27.0 ug/L 04/06/15 08:580.50EPA 6020A
Barium 346 ug/L 04/06/15 08:580.30EPA 6020A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 104
Page 37 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381019 2015007999 SPLP
Boron 208 ug/L 04/06/15 10:2625.0EPA 6020A
Calcium 2940 ug/L 04/06/15 08:5840.0EPA 6020A
Chromium 1.3 ug/L 04/06/15 08:580.50EPA 6020A
Copper 8.0 ug/L 04/06/15 08:581.0EPA 6020A
Lead 0.68 ug/L 04/06/15 08:580.10EPA 6020A
Magnesium 617 ug/L 04/06/15 08:5810.0EPA 6020A
Manganese 19.5 ug/L 04/06/15 08:580.50EPA 6020A
Molybdenum 6.6 ug/L 04/06/15 08:580.50EPA 6020A
Nickel 0.76 ug/L 04/06/15 08:580.50EPA 6020A
Potassium 1040 ug/L 04/06/15 08:5850.0EPA 6020A
Sodium 1590 ug/L 04/06/15 08:5850.0EPA 6020A
Strontium 89.0 ug/L 04/06/15 08:580.50EPA 6020A
Vanadium 120 ug/L 04/06/15 08:581.0EPA 6020A
Zinc 157 ug/L 04/06/15 08:585.0EPA 6020A
92242381020 2015008002 SPLP
Aluminum 122 ug/L 04/06/15 09:0310.0EPA 6020A
Arsenic 1.1 ug/L 04/06/15 09:030.50EPA 6020A
Barium 303 ug/L 04/06/15 09:030.30EPA 6020A
Boron 133 ug/L 04/06/15 09:035.0EPA 6020A
Calcium 5870 ug/L 04/06/15 09:0340.0EPA 6020A
Chromium 2.4 ug/L 04/06/15 09:030.50EPA 6020A
Cobalt 0.54 ug/L 04/06/15 09:030.50EPA 6020A
Copper 2.9 ug/L 04/06/15 09:031.0EPA 6020A
Lead 0.73 ug/L 04/06/15 09:030.10EPA 6020A
Magnesium 455 ug/L 04/06/15 09:0310.0EPA 6020A
Manganese 53.7 ug/L 04/06/15 09:030.50EPA 6020A
Molybdenum 9.2 ug/L 04/06/15 09:030.50EPA 6020A
Nickel 2.2 ug/L 04/06/15 09:030.50EPA 6020A
Potassium 679 ug/L 04/06/15 09:0350.0EPA 6020A
Sodium 1750 ug/L 04/06/15 09:0350.0EPA 6020A
Strontium 39.2 ug/L 04/06/15 09:030.50EPA 6020A
Vanadium 2.5 ug/L 04/06/15 09:031.0EPA 6020A
Zinc 160 ug/L 04/06/15 09:035.0EPA 6020A
92242381021 2015008007 SPLP
Aluminum 252 ug/L 04/06/15 09:0810.0EPA 6020A
Antimony 7.1 ug/L 04/06/15 09:080.50EPA 6020A
Arsenic 11.9 ug/L 04/06/15 09:080.50EPA 6020A
Barium 285 ug/L 04/06/15 09:080.30EPA 6020A
Boron 127 ug/L 04/06/15 09:085.0EPA 6020A
Calcium 4500 ug/L 04/06/15 09:0840.0EPA 6020A
Chromium 1.6 ug/L 04/06/15 09:080.50EPA 6020A
Cobalt 0.92 ug/L 04/06/15 09:080.50EPA 6020A
Copper 4.6 ug/L 04/06/15 09:081.0EPA 6020A
Lead 0.89 ug/L 04/06/15 09:080.10EPA 6020A
Magnesium 475 ug/L 04/06/15 09:0810.0EPA 6020A
Manganese 43.0 ug/L 04/06/15 09:080.50EPA 6020A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 104
Page 38 of 125
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92242381
J150305555
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92242381021 2015008007 SPLP
Molybdenum 4.3 ug/L 04/06/15 09:080.50EPA 6020A
Nickel 2.0 ug/L 04/06/15 09:080.50EPA 6020A
Potassium 657 ug/L 04/06/15 09:0850.0EPA 6020A
Selenium 1.5 ug/L 04/06/15 09:080.50EPA 6020A
Sodium 1600 ug/L 04/06/15 09:0850.0EPA 6020A
Strontium 50.8 ug/L 04/06/15 09:080.50EPA 6020A
Thallium 0.23 ug/L 04/06/15 09:080.10EPA 6020A
Vanadium 134 ug/L 04/06/15 09:081.0EPA 6020A
Zinc 150 ug/L 04/06/15 09:085.0EPA 6020A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 104
Page 39 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6010
Date:April 08, 2015
Description:6010 MET ICP
General Information:
13 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23322
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242381001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1169014)
• Aluminum
• Barium
• Iron
• Strontium
• MSD (Lab ID: 1169015)
• Aluminum
• Barium
• Iron
• Manganese
• Potassium
• Strontium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 104
Page 40 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6010
Date:April 08, 2015
Description:6010 MET ICP
Analyte Comments:
QC Batch: MPRP/23322
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015008001 (Lab ID: 92242381008)
• Barium
• Copper
• Zinc
• 2015008003 (Lab ID: 92242381009)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 104
Page 41 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6020
Date:April 08, 2015
Description:6020 MET ICPMS
General Information:
13 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23323
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242381002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1169018)
• Antimony
• Cobalt
• Lead
• Vanadium
• MSD (Lab ID: 1169019)
• Antimony
• Cobalt
• Lead
• Selenium
• Vanadium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1169019)
• Selenium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 104
Page 42 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6020
Date:April 08, 2015
Description:6020 MET ICPMS
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23323
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015007996 (Lab ID: 92242381001)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015007997 (Lab ID: 92242381005)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015007998 (Lab ID: 92242381006)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015007999 (Lab ID: 92242381002)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• 2015008000 (Lab ID: 92242381007)
• Arsenic
• Cadmium
• Cobalt
• Lead
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 104
Page 43 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6020
Date:April 08, 2015
Description:6020 MET ICPMS
Analyte Comments:
QC Batch: MPRP/23323
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015008000 (Lab ID: 92242381007)
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015008001 (Lab ID: 92242381008)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015008002 (Lab ID: 92242381003)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015008003 (Lab ID: 92242381009)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• 2015008004 (Lab ID: 92242381010)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• 2015008005 (Lab ID: 92242381011)
• Cobalt
• 2015008006 (Lab ID: 92242381012)
• Cobalt
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 104
Page 44 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6020
Date:April 08, 2015
Description:6020 MET ICPMS
Analyte Comments:
QC Batch: MPRP/23323
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015008006 (Lab ID: 92242381012)
• Vanadium
• 2015008007 (Lab ID: 92242381004)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• 2015008008 (Lab ID: 92242381013)
• Cobalt
• Vanadium
• MS (Lab ID: 1169018)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• MSD (Lab ID: 1169019)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
D4: Sample was diluted due to the presence of high levels of target analytes.
• 2015007999 (Lab ID: 92242381002)
• Vanadium
• 2015008003 (Lab ID: 92242381009)
• Vanadium
• 2015008004 (Lab ID: 92242381010)
• Vanadium
• 2015008005 (Lab ID: 92242381011)
• Vanadium
• MS (Lab ID: 1169018)
• Vanadium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 104
Page 45 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6020
Date:April 08, 2015
Description:6020 MET ICPMS
Analyte Comments:
QC Batch: MPRP/23323
D4: Sample was diluted due to the presence of high levels of target analytes.
• MSD (Lab ID: 1169019)
• Vanadium
N2: The lab does not hold TNI accreditation for this parameter.
• 2015007996 (Lab ID: 92242381001)
• Antimony
• 2015007997 (Lab ID: 92242381005)
• Antimony
• 2015007998 (Lab ID: 92242381006)
• Antimony
• 2015007999 (Lab ID: 92242381002)
• Antimony
• 2015008000 (Lab ID: 92242381007)
• Antimony
• 2015008001 (Lab ID: 92242381008)
• Antimony
• 2015008002 (Lab ID: 92242381003)
• Antimony
• 2015008003 (Lab ID: 92242381009)
• Antimony
• 2015008004 (Lab ID: 92242381010)
• Antimony
• 2015008005 (Lab ID: 92242381011)
• Antimony
• 2015008006 (Lab ID: 92242381012)
• Antimony
• 2015008007 (Lab ID: 92242381004)
• Antimony
• 2015008008 (Lab ID: 92242381013)
• Antimony
• BLANK (Lab ID: 1169016)
• Antimony
• LCS (Lab ID: 1169017)
• Antimony
• MS (Lab ID: 1169018)
• Antimony
• MSD (Lab ID: 1169019)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 104
Page 46 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 6020A
Date:April 08, 2015
Description:6020A MET ICPMS
General Information:
8 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 104
Page 47 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 7470
Date:April 08, 2015
Description:7470 Mercury
General Information:
8 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 104
Page 48 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 7471
Date:April 08, 2015
Description:7471 Mercury
General Information:
13 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MERP/5528
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35180845003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1169345)
• Mercury
• MSD (Lab ID: 1169346)
• Mercury
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 104
Page 49 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 9045
Date:April 08, 2015
Description:9045 pH Soil
General Information:
13 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/36413
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1418511)
• pH at 25 Degrees C
• DUP (Lab ID: 1418512)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 104
Page 50 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 300.0
Date:April 08, 2015
Description:300.0 IC Anions, SPLP
General Information:
4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22392
B: Analyte was detected in the associated method blank.
• BLANK for HBN 257605 [WETA/223 (Lab ID: 1422994)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/22392
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015007996 (Lab ID: 92242381001)
• Sulfate
• 2015007999 (Lab ID: 92242381002)
• Sulfate
• 2015008002 (Lab ID: 92242381003)
• Sulfate
• 2015008007 (Lab ID: 92242381004)
• Sulfate
• BLANK (Lab ID: 1422994)
• Sulfate
• MS (Lab ID: 1422996)
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 104
Page 51 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 300.0
Date:April 08, 2015
Description:300.0 IC Anions, SPLP
Analyte Comments:
QC Batch: WETA/22392
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• MS (Lab ID: 1422998)
• Sulfate
• MSD (Lab ID: 1422997)
• Sulfate
• MSD (Lab ID: 1422999)
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 104
Page 52 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 353.2
Date:April 08, 2015
Description:353.2 Nitrogen, NO2/NO3, SPLP
General Information:
4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H1: Analysis conducted outside the EPA method holding time.
• 2015007996 (Lab ID: 92242381001)
• 2015007999 (Lab ID: 92242381002)
• 2015008002 (Lab ID: 92242381003)
• 2015008007 (Lab ID: 92242381004)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22398
B: Analyte was detected in the associated method blank.
• BLANK for HBN 257673 [WETA/223 (Lab ID: 1423321)
• Nitrogen, Nitrate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/22398
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241508005,92242371020
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1423323)
• Nitrogen, Nitrate
• MS (Lab ID: 1423325)
• Nitrogen, Nitrate
• MSD (Lab ID: 1423324)
• Nitrogen, Nitrate
• MSD (Lab ID: 1423326)
• Nitrogen, Nitrate
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 104
Page 53 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 353.2
Date:April 08, 2015
Description:353.2 Nitrogen, NO2/NO3, SPLP
Analyte Comments:
QC Batch: WETA/22398
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1423321)
• Nitrogen, Nitrate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 104
Page 54 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
SM 4500-Cl-E
Date:April 08, 2015
Description:4500 Chloride, SPLP
General Information:
4 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/22399
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015007999 (Lab ID: 92242381002)
• Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 104
Page 55 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 9056
Date:April 08, 2015
Description:9056 IC Anions
General Information:
13 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/44900
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015007996 (Lab ID: 92242381001)
• Chloride
• Sulfate
• 2015007997 (Lab ID: 92242381005)
• Chloride
• Sulfate
• 2015007998 (Lab ID: 92242381006)
• Chloride
• Sulfate
• 2015007999 (Lab ID: 92242381002)
• Chloride
• Sulfate
• 2015008000 (Lab ID: 92242381007)
• Chloride
• Sulfate
• 2015008001 (Lab ID: 92242381008)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 104
Page 56 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 9056
Date:April 08, 2015
Description:9056 IC Anions
Analyte Comments:
QC Batch: WETA/44900
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015008002 (Lab ID: 92242381003)
• Chloride
• Sulfate
• 2015008007 (Lab ID: 92242381004)
• Chloride
• Sulfate
QC Batch: WETA/44904
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015008003 (Lab ID: 92242381009)
• Chloride
• Sulfate
• 2015008004 (Lab ID: 92242381010)
• Chloride
• Sulfate
• 2015008005 (Lab ID: 92242381011)
• Chloride
• Sulfate
• 2015008006 (Lab ID: 92242381012)
• Chloride
• Sulfate
• 2015008008 (Lab ID: 92242381013)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 104
Page 57 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 9056
Date:April 08, 2015
Description:9056 IC Anions 48hr
General Information:
13 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3: Sample was received or analysis requested beyond the recognized method holding time.
• 2015007996 (Lab ID: 92242381001)
• 2015007997 (Lab ID: 92242381005)
• 2015007998 (Lab ID: 92242381006)
• 2015007999 (Lab ID: 92242381002)
• 2015008000 (Lab ID: 92242381007)
• 2015008001 (Lab ID: 92242381008)
• 2015008002 (Lab ID: 92242381003)
• 2015008003 (Lab ID: 92242381009)
• 2015008004 (Lab ID: 92242381010)
• 2015008005 (Lab ID: 92242381011)
• 2015008006 (Lab ID: 92242381012)
• 2015008007 (Lab ID: 92242381004)
• 2015008008 (Lab ID: 92242381013)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/44899
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015007996 (Lab ID: 92242381001)
• Nitrate as N
• 2015007997 (Lab ID: 92242381005)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 104
Page 58 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 9056
Date:April 08, 2015
Description:9056 IC Anions 48hr
Analyte Comments:
QC Batch: WETA/44899
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015007998 (Lab ID: 92242381006)
• Nitrate as N
• 2015007999 (Lab ID: 92242381002)
• Nitrate as N
• 2015008000 (Lab ID: 92242381007)
• Nitrate as N
• 2015008001 (Lab ID: 92242381008)
• Nitrate as N
• 2015008002 (Lab ID: 92242381003)
• Nitrate as N
• 2015008007 (Lab ID: 92242381004)
• Nitrate as N
QC Batch: WETA/44903
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2015008003 (Lab ID: 92242381009)
• Nitrate as N
• 2015008004 (Lab ID: 92242381010)
• Nitrate as N
• 2015008005 (Lab ID: 92242381011)
• Nitrate as N
• 2015008008 (Lab ID: 92242381013)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 104
Page 59 of 125
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92242381
J150305555
Method:
Client:Duke Energy
EPA 9060
Date:April 08, 2015
Description:Total Organic Carbon Quad
General Information:
13 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 104
Page 60 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007996 Lab ID:92242381001 Collected:03/18/15 15:33 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 3200 mg/kg 04/02/15 09:35 7429-90-5 M103/29/15 16:047.7 3.9 1
Barium 44.1 mg/kg 04/02/15 09:35 7440-39-3 M103/29/15 16:040.77 0.39 1
Beryllium 0.73 mg/kg 04/02/15 09:35 7440-41-703/29/15 16:040.077 0.039 1
Boron 7.3 mg/kg 04/02/15 09:35 7440-42-803/29/15 16:043.9 1.9 1
Calcium 551 mg/kg 04/02/15 09:35 7440-70-203/29/15 16:0438.7 19.4 1
Chromium 10.6 mg/kg 04/02/15 09:35 7440-47-303/29/15 16:040.39 0.19 1
Copper 10.6 mg/kg 04/02/15 09:35 7440-50-803/29/15 16:040.39 0.19 1
Iron 2840 mg/kg 04/02/15 09:35 7439-89-6 M103/29/15 16:043.1 1.5 1
Magnesium 212 mg/kg 04/02/15 09:35 7439-95-403/29/15 16:0438.7 19.4 1
Manganese 24.1 mg/kg 04/02/15 09:35 7439-96-5 M103/29/15 16:040.39 0.19 1
Molybdenum 0.53J mg/kg 04/02/15 09:35 7439-98-703/29/15 16:040.77 0.39 1
Nickel 7.2 mg/kg 04/02/15 09:35 7440-02-003/29/15 16:040.39 0.19 1
Potassium 396 mg/kg 04/02/15 09:35 7440-09-7 M103/29/15 16:0477.4 38.7 1
Sodium 81.5 mg/kg 04/02/15 09:35 7440-23-503/29/15 16:0477.4 38.7 1
Strontium 25.4 mg/kg 04/02/15 09:35 7440-24-6 M103/29/15 16:040.77 0.39 1
Zinc 10.5 mg/kg 04/02/15 09:35 7440-66-603/29/15 16:041.5 0.77 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 21:42 7440-36-0 D3,N203/29/15 16:043.9 1.9 50
Arsenic 3.3J mg/kg 03/31/15 21:42 7440-38-2 D303/29/15 16:043.9 1.9 50
Cadmium ND mg/kg 03/31/15 21:42 7440-43-9 D303/29/15 16:040.46 0.23 50
Cobalt 4.5 mg/kg 03/31/15 21:42 7440-48-4 D303/29/15 16:043.9 1.9 50
Lead 7.4 mg/kg 03/31/15 21:42 7439-92-1 D303/29/15 16:043.9 1.9 50
Selenium ND mg/kg 03/31/15 21:42 7782-49-2 D303/29/15 16:043.9 1.9 50
Thallium ND mg/kg 03/31/15 21:42 7440-28-0 D303/29/15 16:043.9 1.9 50
Vanadium 16.9 mg/kg 03/31/15 21:42 7440-62-2 D303/29/15 16:043.9 1.9 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:06 7439-97-603/31/15 10:200.012 0.0060 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 33.9 %04/01/15 16:190.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00300.0 IC Anions, SPLP
Sulfate 17.8 mg/L 04/01/15 20:10 14808-79-8 B,D315.1 7.6 5
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate 308 mg/L 03/31/15 19:26 B,H115.1 15.1 50
Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/26/15 00:004500 Chloride, SPLP
Chloride ND mg/L 03/31/15 15:30 16887-00-67.6 3.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 104
Page 61 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007996 Lab ID:92242381001 Collected:03/18/15 15:33 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 11:06 16887-00-6 D33781895
Sulfate 200J mg/kg 03/28/15 11:06 14808-79-8 D33781895
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 11:06 14797-55-8 D3,H337.8 18.9 5
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 25300 mg/kg 04/03/15 12:07 7440-44-0266013301
Total Organic Carbon 25200 mg/kg 04/03/15 12:14 7440-44-0265013301
Total Organic Carbon 26400 mg/kg 04/03/15 12:20 7440-44-0262013101
Total Organic Carbon 16700 mg/kg 04/03/15 12:27 7440-44-0261013101
Mean Total Organic Carbon 23400 mg/kg 04/03/15 12:07 7440-44-0264013201
Surrogates
RSD%19.3 %04/03/15 12:071
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 104
Page 62 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007999 Lab ID:92242381002 Collected:03/17/15 15:45 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 8960 mg/kg 04/02/15 09:46 7429-90-503/29/15 16:048.6 4.3 1
Barium 67.3 mg/kg 04/02/15 09:46 7440-39-303/29/15 16:040.86 0.43 1
Beryllium 2.3 mg/kg 04/02/15 09:46 7440-41-703/29/15 16:040.086 0.043 1
Boron 25.5 mg/kg 04/02/15 09:46 7440-42-803/29/15 16:044.3 2.1 1
Calcium 1100 mg/kg 04/02/15 09:46 7440-70-203/29/15 16:0442.8 21.4 1
Chromium 24.5 mg/kg 04/02/15 09:46 7440-47-303/29/15 16:040.43 0.21 1
Copper 33.1 mg/kg 04/02/15 09:46 7440-50-803/29/15 16:040.43 0.21 1
Iron 2860 mg/kg 04/02/15 09:46 7439-89-603/29/15 16:043.4 1.7 1
Magnesium 497 mg/kg 04/02/15 09:46 7439-95-403/29/15 16:0442.8 21.4 1
Manganese 13.6 mg/kg 04/02/15 09:46 7439-96-503/29/15 16:040.43 0.21 1
Molybdenum 1.2 mg/kg 04/02/15 09:46 7439-98-703/29/15 16:040.86 0.43 1
Nickel 18.5 mg/kg 04/02/15 09:46 7440-02-003/29/15 16:040.43 0.21 1
Potassium 1230 mg/kg 04/02/15 09:46 7440-09-703/29/15 16:0485.6 42.8 1
Sodium 119 mg/kg 04/02/15 09:46 7440-23-503/29/15 16:0485.6 42.8 1
Strontium 60.6 mg/kg 04/02/15 09:46 7440-24-603/29/15 16:040.86 0.43 1
Zinc 19.0 mg/kg 04/02/15 09:46 7440-66-603/29/15 16:041.7 0.86 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 21:58 7440-36-0 D3,M6,
N2
03/29/15 16:044.3 2.1 50
Arsenic 10 mg/kg 03/31/15 21:58 7440-38-2 D303/29/15 16:044.3 2.1 50
Cadmium ND mg/kg 03/31/15 21:58 7440-43-9 D303/29/15 16:040.51 0.26 50
Cobalt 12.9 mg/kg 03/31/15 21:58 7440-48-4 D3,M603/29/15 16:044.3 2.1 50
Lead 14.5 mg/kg 03/31/15 21:58 7439-92-1 D3,M603/29/15 16:044.3 2.1 50
Selenium ND mg/kg 03/31/15 21:58 7782-49-2 D3,M6,
R103/29/15 16:044.3 2.1 50
Thallium ND mg/kg 03/31/15 21:58 7440-28-0 D303/29/15 16:044.3 2.1 50
Vanadium 64.7 mg/kg 03/31/15 21:58 7440-62-2 D4,M603/29/15 16:044.3 2.1 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:09 7439-97-603/31/15 10:200.014 0.0068 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 39.9 %04/01/15 16:190.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.8 Std. Units 03/25/15 11:500.10 0.10 1
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00300.0 IC Anions, SPLP
Sulfate 12.6 mg/L 04/01/15 20:24 14808-79-8 B,D36.7 3.3 2
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate 333 mg/L 03/31/15 19:27 B,H116.6 16.6 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 104
Page 63 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007999 Lab ID:92242381002 Collected:03/17/15 15:45 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/26/15 00:004500 Chloride, SPLP
Chloride ND mg/L 03/31/15 15:55 16887-00-6 D341.6 20.8 5
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 11:27 16887-00-6 D34182095
Sulfate ND mg/kg 03/28/15 11:27 14808-79-8 D34182095
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 11:27 14797-55-8 D3,H341.8 20.9 5
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 19600 mg/kg 04/03/15 13:19 7440-44-0387019301
Total Organic Carbon 19400 mg/kg 04/03/15 13:26 7440-44-0394019701
Total Organic Carbon 18500 mg/kg 04/03/15 13:32 7440-44-0387019301
Total Organic Carbon 26500 mg/kg 04/03/15 13:38 7440-44-0394019701
Mean Total Organic Carbon 21000 mg/kg 04/03/15 13:19 7440-44-0390019501
Surrogates
RSD%17.6 %04/03/15 13:191
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 104
Page 64 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008002 Lab ID:92242381003 Collected:03/18/15 12:20 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 3760 mg/kg 04/01/15 21:21 7429-90-503/29/15 16:046.7 3.4 1
Barium 41.1 mg/kg 04/01/15 21:21 7440-39-303/29/15 16:040.67 0.34 1
Beryllium 0.93 mg/kg 04/01/15 21:21 7440-41-703/29/15 16:040.067 0.034 1
Boron 7.3 mg/kg 04/01/15 21:21 7440-42-803/29/15 16:043.4 1.7 1
Calcium 581 mg/kg 04/01/15 21:21 7440-70-203/29/15 16:0433.6 16.8 1
Chromium 13.3 mg/kg 04/01/15 21:21 7440-47-303/29/15 16:040.34 0.17 1
Copper 12.9 mg/kg 04/01/15 21:21 7440-50-803/29/15 16:040.34 0.17 1
Iron 2470 mg/kg 04/01/15 21:21 7439-89-603/29/15 16:042.7 1.3 1
Magnesium 204 mg/kg 04/01/15 21:21 7439-95-403/29/15 16:0433.6 16.8 1
Manganese 14.1 mg/kg 04/01/15 21:21 7439-96-503/29/15 16:040.34 0.17 1
Molybdenum 0.59J mg/kg 04/01/15 21:21 7439-98-703/29/15 16:040.67 0.34 1
Nickel 6.8 mg/kg 04/01/15 21:21 7440-02-003/29/15 16:040.34 0.17 1
Potassium 451 mg/kg 04/01/15 21:21 7440-09-703/29/15 16:0467.2 33.6 1
Sodium 63.0J mg/kg 04/01/15 21:21 7440-23-503/29/15 16:0467.2 33.6 1
Strontium 20.6 mg/kg 04/01/15 21:21 7440-24-603/29/15 16:040.67 0.34 1
Zinc 8.2 mg/kg 04/01/15 21:21 7440-66-603/29/15 16:041.3 0.67 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:05 7440-36-0 D3,N203/29/15 16:043.4 1.7 50
Arsenic 3.3J mg/kg 03/31/15 22:05 7440-38-2 D303/29/15 16:043.4 1.7 50
Cadmium ND mg/kg 03/31/15 22:05 7440-43-9 D303/29/15 16:040.40 0.20 50
Cobalt 4.0 mg/kg 03/31/15 22:05 7440-48-4 D303/29/15 16:043.4 1.7 50
Lead 5.2 mg/kg 03/31/15 22:05 7439-92-1 D303/29/15 16:043.4 1.7 50
Selenium ND mg/kg 03/31/15 22:05 7782-49-2 D303/29/15 16:043.4 1.7 50
Thallium ND mg/kg 03/31/15 22:05 7440-28-0 D303/29/15 16:043.4 1.7 50
Vanadium 15.0 mg/kg 03/31/15 22:05 7440-62-2 D303/29/15 16:043.4 1.7 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:11 7439-97-603/31/15 10:200.011 0.0054 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 27.6 %04/01/15 16:190.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00300.0 IC Anions, SPLP
Sulfate 19.9 mg/L 04/01/15 20:38 14808-79-8 B,D313.8 6.9 5
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate 236 mg/L 03/31/15 19:28 B,H113.8 13.8 50
Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/26/15 00:004500 Chloride, SPLP
Chloride ND mg/L 03/31/15 15:32 16887-00-66.9 3.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 104
Page 65 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008002 Lab ID:92242381003 Collected:03/18/15 12:20 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 11:49 16887-00-6 D33501755
Sulfate 326J mg/kg 03/28/15 11:49 14808-79-8 D33501755
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 11:49 14797-55-8 D3,H335.0 17.5 5
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 10800 mg/kg 04/03/15 13:44 7440-44-08344171
Total Organic Carbon 14800 mg/kg 04/03/15 13:49 7440-44-08224111
Total Organic Carbon 23100 mg/kg 04/03/15 13:55 7440-44-08264131
Total Organic Carbon 11700 mg/kg 04/03/15 14:02 7440-44-08244121
Mean Total Organic Carbon 15100 mg/kg 04/03/15 13:44 7440-44-08264131
Surrogates
RSD%37.1 %04/03/15 13:441
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 104
Page 66 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008007 Lab ID:92242381004 Collected:03/19/15 12:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 3060 mg/kg 04/01/15 21:25 7429-90-503/29/15 16:047.0 3.5 1
Barium 34.7 mg/kg 04/01/15 21:25 7440-39-303/29/15 16:040.70 0.35 1
Beryllium 0.64 mg/kg 04/01/15 21:25 7440-41-703/29/15 16:040.070 0.035 1
Boron 5.9 mg/kg 04/01/15 21:25 7440-42-803/29/15 16:043.5 1.7 1
Calcium 483 mg/kg 04/01/15 21:25 7440-70-203/29/15 16:0435.0 17.5 1
Chromium 8.0 mg/kg 04/01/15 21:25 7440-47-303/29/15 16:040.35 0.17 1
Copper 8.0 mg/kg 04/01/15 21:25 7440-50-803/29/15 16:040.35 0.17 1
Iron 1820 mg/kg 04/01/15 21:25 7439-89-603/29/15 16:042.8 1.4 1
Magnesium 180 mg/kg 04/01/15 21:25 7439-95-403/29/15 16:0435.0 17.5 1
Manganese 9.4 mg/kg 04/01/15 21:25 7439-96-503/29/15 16:040.35 0.17 1
Molybdenum 0.63J mg/kg 04/01/15 21:25 7439-98-703/29/15 16:040.70 0.35 1
Nickel 5.4 mg/kg 04/01/15 21:25 7440-02-003/29/15 16:040.35 0.17 1
Potassium 367 mg/kg 04/01/15 21:25 7440-09-703/29/15 16:0470.0 35.0 1
Sodium 55.0J mg/kg 04/01/15 21:25 7440-23-503/29/15 16:0470.0 35.0 1
Strontium 17.9 mg/kg 04/01/15 21:25 7440-24-603/29/15 16:040.70 0.35 1
Zinc 6.8 mg/kg 04/01/15 21:25 7440-66-603/29/15 16:041.4 0.70 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:08 7440-36-0 D3,N203/29/15 16:043.5 1.7 50
Arsenic 2.6J mg/kg 03/31/15 22:08 7440-38-2 D303/29/15 16:043.5 1.7 50
Cadmium ND mg/kg 03/31/15 22:08 7440-43-9 D303/29/15 16:040.42 0.21 50
Cobalt 3.4J mg/kg 03/31/15 22:08 7440-48-4 D303/29/15 16:043.5 1.7 50
Lead 4.0 mg/kg 03/31/15 22:08 7439-92-1 D303/29/15 16:043.5 1.7 50
Selenium ND mg/kg 03/31/15 22:08 7782-49-2 D303/29/15 16:043.5 1.7 50
Thallium ND mg/kg 03/31/15 22:08 7440-28-0 D303/29/15 16:043.5 1.7 50
Vanadium 13.7 mg/kg 03/31/15 22:08 7440-62-2 D303/29/15 16:043.5 1.7 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:13 7439-97-603/31/15 10:200.011 0.0057 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 30.7 %04/01/15 16:200.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.3 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/26/15 00:00300.0 IC Anions, SPLP
Sulfate 11.8 mg/L 04/02/15 11:14 14808-79-8 B,D35.8 2.9 2
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/26/15 00:00353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate 180 mg/L 03/31/15 18:44 B,H18.7 8.7 30
Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/26/15 00:004500 Chloride, SPLP
Chloride ND mg/L 03/31/15 15:34 16887-00-67.2 3.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 104
Page 67 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008007 Lab ID:92242381004 Collected:03/19/15 12:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 12:10 16887-00-6 D33521765
Sulfate ND mg/kg 03/28/15 12:10 14808-79-8 D33521765
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 12:10 14797-55-8 D3,H335.2 17.6 5
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 49000 mg/kg 04/03/15 14:08 7440-44-0310015501
Total Organic Carbon 30100 mg/kg 04/03/15 14:15 7440-44-0311015501
Total Organic Carbon 43500 mg/kg 04/03/15 14:22 7440-44-0314015701
Total Organic Carbon 34500 mg/kg 04/03/15 14:30 7440-44-0310015501
Mean Total Organic Carbon 39300 mg/kg 04/03/15 14:08 7440-44-0311015601
Surrogates
RSD%21.7 %04/03/15 14:081
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 104
Page 68 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007997 Lab ID:92242381005 Collected:03/18/15 15:50 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 3460 mg/kg 04/01/15 21:29 7429-90-503/29/15 16:047.8 3.9 1
Barium 51.8 mg/kg 04/01/15 21:29 7440-39-303/29/15 16:040.78 0.39 1
Beryllium 0.78 mg/kg 04/01/15 21:29 7440-41-703/29/15 16:040.078 0.039 1
Boron 7.7 mg/kg 04/01/15 21:29 7440-42-803/29/15 16:043.9 1.9 1
Calcium 632 mg/kg 04/01/15 21:29 7440-70-203/29/15 16:0438.9 19.4 1
Chromium 10.2 mg/kg 04/01/15 21:29 7440-47-303/29/15 16:040.39 0.19 1
Copper 11.7 mg/kg 04/01/15 21:29 7440-50-803/29/15 16:040.39 0.19 1
Iron 2420 mg/kg 04/01/15 21:29 7439-89-603/29/15 16:043.1 1.6 1
Magnesium 231 mg/kg 04/01/15 21:29 7439-95-403/29/15 16:0438.9 19.4 1
Manganese 22.6 mg/kg 04/01/15 21:29 7439-96-503/29/15 16:040.39 0.19 1
Molybdenum 0.54J mg/kg 04/01/15 21:29 7439-98-703/29/15 16:040.78 0.39 1
Nickel 7.2 mg/kg 04/01/15 21:29 7440-02-003/29/15 16:040.39 0.19 1
Potassium 402 mg/kg 04/01/15 21:29 7440-09-703/29/15 16:0477.7 38.9 1
Sodium 92.2 mg/kg 04/01/15 21:29 7440-23-503/29/15 16:0477.7 38.9 1
Strontium 28.9 mg/kg 04/01/15 21:29 7440-24-603/29/15 16:040.78 0.39 1
Zinc 10.1 mg/kg 04/01/15 21:29 7440-66-603/29/15 16:041.6 0.78 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:10 7440-36-0 D3,N203/29/15 16:043.9 1.9 50
Arsenic 3.4J mg/kg 03/31/15 22:10 7440-38-2 D303/29/15 16:043.9 1.9 50
Cadmium ND mg/kg 03/31/15 22:10 7440-43-9 D303/29/15 16:040.47 0.23 50
Cobalt 4.7 mg/kg 03/31/15 22:10 7440-48-4 D303/29/15 16:043.9 1.9 50
Lead 5.3 mg/kg 03/31/15 22:10 7439-92-1 D303/29/15 16:043.9 1.9 50
Selenium ND mg/kg 03/31/15 22:10 7782-49-2 D303/29/15 16:043.9 1.9 50
Thallium ND mg/kg 03/31/15 22:10 7440-28-0 D303/29/15 16:043.9 1.9 50
Vanadium 16.7 mg/kg 03/31/15 22:10 7440-62-2 D303/29/15 16:043.9 1.9 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:15 7439-97-603/31/15 10:200.012 0.0058 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 32.3 %04/01/15 16:200.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 12:32 16887-00-6 D33621815
Sulfate 216J mg/kg 03/28/15 12:32 14808-79-8 D33621815
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 12:32 14797-55-8 D3,H336.2 18.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 104
Page 69 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007997 Lab ID:92242381005 Collected:03/18/15 15:50 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 16200 mg/kg 04/03/15 14:36 7440-44-0238011901
Total Organic Carbon 17800 mg/kg 04/03/15 14:42 7440-44-0234011701
Total Organic Carbon 15200 mg/kg 04/03/15 14:48 7440-44-0238011901
Total Organic Carbon 14200 mg/kg 04/03/15 14:57 7440-44-0232011601
Mean Total Organic Carbon 15800 mg/kg 04/03/15 14:36 7440-44-0235011801
Surrogates
RSD%9.5 %04/03/15 14:361
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 104
Page 70 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007998 Lab ID:92242381006 Collected:03/18/15 09:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 863 mg/kg 04/01/15 21:33 7429-90-503/29/15 16:046.7 3.3 1
Barium 38.7 mg/kg 04/01/15 21:33 7440-39-303/29/15 16:040.67 0.33 1
Beryllium 0.20 mg/kg 04/01/15 21:33 7440-41-703/29/15 16:040.067 0.033 1
Boron 2.6J mg/kg 04/01/15 21:33 7440-42-803/29/15 16:043.3 1.7 1
Calcium 377 mg/kg 04/01/15 21:33 7440-70-203/29/15 16:0433.3 16.7 1
Chromium 2.0 mg/kg 04/01/15 21:33 7440-47-303/29/15 16:040.33 0.17 1
Copper 3.0 mg/kg 04/01/15 21:33 7440-50-803/29/15 16:040.33 0.17 1
Iron 1010 mg/kg 04/01/15 21:33 7439-89-603/29/15 16:042.7 1.3 1
Magnesium 58.1 mg/kg 04/01/15 21:33 7439-95-403/29/15 16:0433.3 16.7 1
Manganese 11.9 mg/kg 04/01/15 21:33 7439-96-503/29/15 16:040.33 0.17 1
Molybdenum 0.38J mg/kg 04/01/15 21:33 7439-98-703/29/15 16:040.67 0.33 1
Nickel 2.6 mg/kg 04/01/15 21:33 7440-02-003/29/15 16:040.33 0.17 1
Potassium 110 mg/kg 04/01/15 21:33 7440-09-703/29/15 16:0466.7 33.3 1
Sodium ND mg/kg 04/01/15 21:33 7440-23-503/29/15 16:0466.7 33.3 1
Strontium 8.0 mg/kg 04/01/15 21:33 7440-24-603/29/15 16:040.67 0.33 1
Zinc 2.1 mg/kg 04/01/15 21:33 7440-66-603/29/15 16:041.3 0.67 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:12 7440-36-0 D3,N203/29/15 16:043.3 1.7 50
Arsenic ND mg/kg 03/31/15 22:12 7440-38-2 D303/29/15 16:043.3 1.7 50
Cadmium ND mg/kg 03/31/15 22:12 7440-43-9 D303/29/15 16:040.40 0.20 50
Cobalt ND mg/kg 03/31/15 22:12 7440-48-4 D303/29/15 16:043.3 1.7 50
Lead ND mg/kg 03/31/15 22:12 7439-92-1 D303/29/15 16:043.3 1.7 50
Selenium ND mg/kg 03/31/15 22:12 7782-49-2 D303/29/15 16:043.3 1.7 50
Thallium ND mg/kg 03/31/15 22:12 7440-28-0 D303/29/15 16:043.3 1.7 50
Vanadium 2.9J mg/kg 03/31/15 22:12 7440-62-2 D303/29/15 16:043.3 1.7 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:17 7439-97-603/31/15 10:200.0097 0.0049 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 21.6 %04/01/15 16:210.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.4 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 12:53 16887-00-6 D33221615
Sulfate ND mg/kg 03/28/15 12:53 14808-79-8 D33221615
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 12:53 14797-55-8 D3,H332.2 16.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 104
Page 71 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007998 Lab ID:92242381006 Collected:03/18/15 09:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 6380 mg/kg 04/03/15 15:03 7440-44-011105561
Total Organic Carbon 7810 mg/kg 04/03/15 15:09 7440-44-011205581
Total Organic Carbon 5960 mg/kg 04/03/15 15:15 7440-44-011205591
Total Organic Carbon 6370 mg/kg 04/03/15 15:21 7440-44-011205621
Mean Total Organic Carbon 6630 mg/kg 04/03/15 15:03 7440-44-011205591
Surrogates
RSD%12.3 %04/03/15 15:031
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 104
Page 72 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008000 Lab ID:92242381007 Collected:03/18/15 14:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 281 mg/kg 04/01/15 21:37 7429-90-503/29/15 16:048.8 4.4 1
Barium 9.9 mg/kg 04/01/15 21:37 7440-39-303/29/15 16:040.88 0.44 1
Beryllium 0.091 mg/kg 04/01/15 21:37 7440-41-703/29/15 16:040.088 0.044 1
Boron ND mg/kg 04/01/15 21:37 7440-42-803/29/15 16:044.4 2.2 1
Calcium 70.7 mg/kg 04/01/15 21:37 7440-70-203/29/15 16:0444.1 22.1 1
Chromium 0.86 mg/kg 04/01/15 21:37 7440-47-303/29/15 16:040.44 0.22 1
Copper 1.2 mg/kg 04/01/15 21:37 7440-50-803/29/15 16:040.44 0.22 1
Iron 320 mg/kg 04/01/15 21:37 7439-89-603/29/15 16:043.5 1.8 1
Magnesium 25.4J mg/kg 04/01/15 21:37 7439-95-403/29/15 16:0444.1 22.1 1
Manganese 1.7 mg/kg 04/01/15 21:37 7439-96-503/29/15 16:040.44 0.22 1
Molybdenum ND mg/kg 04/01/15 21:37 7439-98-703/29/15 16:040.88 0.44 1
Nickel 1.1 mg/kg 04/01/15 21:37 7440-02-003/29/15 16:040.44 0.22 1
Potassium ND mg/kg 04/01/15 21:37 7440-09-703/29/15 16:0488.3 44.1 1
Sodium ND mg/kg 04/01/15 21:37 7440-23-503/29/15 16:0488.3 44.1 1
Strontium 2.9 mg/kg 04/01/15 21:37 7440-24-603/29/15 16:040.88 0.44 1
Zinc 1.1J mg/kg 04/01/15 21:37 7440-66-603/29/15 16:041.8 0.88 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:14 7440-36-0 D3,N203/29/15 16:044.4 2.2 50
Arsenic ND mg/kg 03/31/15 22:14 7440-38-2 D303/29/15 16:044.4 2.2 50
Cadmium ND mg/kg 03/31/15 22:14 7440-43-9 D303/29/15 16:040.53 0.26 50
Cobalt ND mg/kg 03/31/15 22:14 7440-48-4 D303/29/15 16:044.4 2.2 50
Lead ND mg/kg 03/31/15 22:14 7439-92-1 D303/29/15 16:044.4 2.2 50
Selenium ND mg/kg 03/31/15 22:14 7782-49-2 D303/29/15 16:044.4 2.2 50
Thallium ND mg/kg 03/31/15 22:14 7440-28-0 D303/29/15 16:044.4 2.2 50
Vanadium ND mg/kg 03/31/15 22:14 7440-62-2 D303/29/15 16:044.4 2.2 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:19 7439-97-603/31/15 10:200.014 0.0070 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 41.2 %04/01/15 16:210.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.3 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 13:15 16887-00-6 D34162085
Sulfate ND mg/kg 03/28/15 13:15 14808-79-8 D34162085
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 13:15 14797-55-8 D3,H341.6 20.8 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 104
Page 73 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008000 Lab ID:92242381007 Collected:03/18/15 14:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 11400 mg/kg 04/03/15 15:42 7440-44-010305131
Total Organic Carbon 19400 mg/kg 04/03/15 15:52 7440-44-010205101
Total Organic Carbon 10300 mg/kg 04/03/15 15:59 7440-44-010205101
Total Organic Carbon 8260 mg/kg 04/03/15 16:05 7440-44-010105071
Mean Total Organic Carbon 12300 mg/kg 04/03/15 15:42 7440-44-010205101
Surrogates
RSD%39.4 %04/03/15 15:421
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 104
Page 74 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008001 Lab ID:92242381008 Collected:03/17/15 13:05 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 485 mg/kg 04/01/15 21:41 7429-90-503/29/15 16:047.0 3.5 1
Barium 16.9 mg/kg 04/02/15 10:11 7440-39-3 D303/29/15 16:043.5 1.7 5
Beryllium 0.14 mg/kg 04/01/15 21:41 7440-41-703/29/15 16:040.070 0.035 1
Boron ND mg/kg 04/01/15 21:41 7440-42-803/29/15 16:043.5 1.7 1
Calcium 199 mg/kg 04/01/15 21:41 7440-70-203/29/15 16:0434.9 17.5 1
Chromium 1.9 mg/kg 04/01/15 21:41 7440-47-303/29/15 16:040.35 0.17 1
Copper 2.8 mg/kg 04/02/15 10:11 7440-50-8 D303/29/15 16:041.7 0.87 5
Iron 554 mg/kg 04/01/15 21:41 7439-89-603/29/15 16:042.8 1.4 1
Magnesium 36.2 mg/kg 04/01/15 21:41 7439-95-403/29/15 16:0434.9 17.5 1
Manganese 37.7 mg/kg 04/01/15 21:41 7439-96-503/29/15 16:040.35 0.17 1
Molybdenum 0.38J mg/kg 04/01/15 21:41 7439-98-703/29/15 16:040.70 0.35 1
Nickel 2.1 mg/kg 04/01/15 21:41 7440-02-003/29/15 16:040.35 0.17 1
Potassium 63.7J mg/kg 04/01/15 21:41 7440-09-703/29/15 16:0469.9 34.9 1
Sodium ND mg/kg 04/01/15 21:41 7440-23-503/29/15 16:0469.9 34.9 1
Strontium 4.7 mg/kg 04/01/15 21:41 7440-24-603/29/15 16:040.70 0.35 1
Zinc ND mg/kg 04/02/15 10:11 7440-66-6 D303/29/15 16:047.0 3.5 5
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:17 7440-36-0 D3,N203/29/15 16:043.5 1.7 50
Arsenic ND mg/kg 03/31/15 22:17 7440-38-2 D303/29/15 16:043.5 1.7 50
Cadmium ND mg/kg 03/31/15 22:17 7440-43-9 D303/29/15 16:040.42 0.21 50
Cobalt ND mg/kg 03/31/15 22:17 7440-48-4 D303/29/15 16:043.5 1.7 50
Lead ND mg/kg 03/31/15 22:17 7439-92-1 D303/29/15 16:043.5 1.7 50
Selenium ND mg/kg 03/31/15 22:17 7782-49-2 D303/29/15 16:043.5 1.7 50
Thallium ND mg/kg 03/31/15 22:17 7440-28-0 D303/29/15 16:043.5 1.7 50
Vanadium ND mg/kg 03/31/15 22:17 7440-62-2 D303/29/15 16:043.5 1.7 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:39 7439-97-603/31/15 11:550.011 0.0055 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 28.0 %04/01/15 16:210.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.6 Std. Units 03/25/15 11:500.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/28/15 13:36 16887-00-6 D33441725
Sulfate ND mg/kg 03/28/15 13:36 14808-79-8 D33441725
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/28/15 13:36 14797-55-8 D3,H334.4 17.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 104
Page 75 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008001 Lab ID:92242381008 Collected:03/17/15 13:05 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 16800 mg/kg 04/03/15 16:10 7440-44-08284141
Total Organic Carbon 16000 mg/kg 04/03/15 16:17 7440-44-08274141
Total Organic Carbon 10900 mg/kg 04/03/15 16:28 7440-44-08374181
Total Organic Carbon 14200 mg/kg 04/03/15 16:35 7440-44-08334171
Mean Total Organic Carbon 14500 mg/kg 04/03/15 16:10 7440-44-08314161
Surrogates
RSD%18.3 %04/03/15 16:101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 104
Page 76 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008003 Lab ID:92242381009 Collected:03/18/15 13:15 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 13900 mg/kg 04/01/15 21:45 7429-90-503/29/15 16:046.9 3.5 1
Barium 83.2 mg/kg 04/01/15 21:45 7440-39-303/29/15 16:040.69 0.35 1
Beryllium 3.1 mg/kg 04/02/15 10:15 7440-41-7 D303/29/15 16:040.35 0.17 5
Boron 32.9 mg/kg 04/02/15 10:15 7440-42-8 D303/29/15 16:0417.3 8.6 5
Calcium 1080 mg/kg 04/01/15 21:45 7440-70-203/29/15 16:0434.6 17.3 1
Chromium 54.7 mg/kg 04/02/15 10:15 7440-47-3 D303/29/15 16:041.7 0.86 5
Copper 43.4 mg/kg 04/02/15 10:15 7440-50-8 D303/29/15 16:041.7 0.86 5
Iron 3020 mg/kg 04/01/15 21:45 7439-89-603/29/15 16:042.8 1.4 1
Magnesium 541 mg/kg 04/01/15 21:45 7439-95-403/29/15 16:0434.6 17.3 1
Manganese 69.4 mg/kg 04/02/15 10:15 7439-96-5 D303/29/15 16:041.7 0.86 5
Molybdenum 1.4 mg/kg 04/01/15 21:45 7439-98-703/29/15 16:040.69 0.35 1
Nickel 22.5 mg/kg 04/01/15 21:45 7440-02-003/29/15 16:040.35 0.17 1
Potassium 1650 mg/kg 04/01/15 21:45 7440-09-703/29/15 16:0469.2 34.6 1
Sodium 155 mg/kg 04/01/15 21:45 7440-23-503/29/15 16:0469.2 34.6 1
Strontium 83.7 mg/kg 04/01/15 21:45 7440-24-603/29/15 16:040.69 0.35 1
Zinc 36.4 mg/kg 04/01/15 21:45 7440-66-603/29/15 16:041.4 0.69 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 03/31/15 22:19 7440-36-0 D3,N203/29/15 16:043.5 1.7 50
Arsenic 11.2 mg/kg 03/31/15 22:19 7440-38-2 D303/29/15 16:043.5 1.7 50
Cadmium ND mg/kg 03/31/15 22:19 7440-43-9 D303/29/15 16:040.42 0.21 50
Cobalt 17.7 mg/kg 03/31/15 22:19 7440-48-4 D303/29/15 16:043.5 1.7 50
Lead 21.9 mg/kg 03/31/15 22:19 7439-92-1 D303/29/15 16:043.5 1.7 50
Selenium ND mg/kg 03/31/15 22:19 7782-49-2 D303/29/15 16:043.5 1.7 50
Thallium ND mg/kg 03/31/15 22:19 7440-28-0 D303/29/15 16:043.5 1.7 50
Vanadium 88.1 mg/kg 03/31/15 22:19 7440-62-2 D403/29/15 16:043.5 1.7 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:45 7439-97-603/31/15 11:550.011 0.0055 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 24.7 %04/01/15 16:220.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.4 Std. Units 03/25/15 11:500.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/29/15 13:00 16887-00-6 D3,M13321665
Sulfate ND mg/kg 03/29/15 13:00 14808-79-8 D33321665
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/29/15 13:00 14797-55-8 D3,H333.2 16.6 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 104
Page 77 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008003 Lab ID:92242381009 Collected:03/18/15 13:15 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 9330 mg/kg 04/03/15 16:42 7440-44-0567028401
Total Organic Carbon 7650 mg/kg 04/03/15 16:48 7440-44-0581029101
Total Organic Carbon 8290 mg/kg 04/03/15 16:54 7440-44-0586029301
Total Organic Carbon 8680 mg/kg 04/03/15 16:59 7440-44-0589029401
Mean Total Organic Carbon 8490 mg/kg 04/03/15 16:42 7440-44-0581029001
Surrogates
RSD%8.3 %04/03/15 16:421
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 104
Page 78 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008004 Lab ID:92242381010 Collected:03/17/15 15:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 9620 mg/kg 04/01/15 21:49 7429-90-503/29/15 16:047.1 3.5 1
Barium 80.9 mg/kg 04/01/15 21:49 7440-39-303/29/15 16:040.71 0.35 1
Beryllium 2.6 mg/kg 04/01/15 21:49 7440-41-703/29/15 16:040.071 0.035 1
Boron 31.3 mg/kg 04/01/15 21:49 7440-42-803/29/15 16:043.5 1.8 1
Calcium 1150 mg/kg 04/01/15 21:49 7440-70-203/29/15 16:0435.4 17.7 1
Chromium 31.9 mg/kg 04/01/15 21:49 7440-47-303/29/15 16:040.35 0.18 1
Copper 33.3 mg/kg 04/01/15 21:49 7440-50-803/29/15 16:040.35 0.18 1
Iron 3290 mg/kg 04/01/15 21:49 7439-89-603/29/15 16:042.8 1.4 1
Magnesium 388 mg/kg 04/01/15 21:49 7439-95-403/29/15 16:0435.4 17.7 1
Manganese 21.1 mg/kg 04/01/15 21:49 7439-96-503/29/15 16:040.35 0.18 1
Molybdenum 1.6 mg/kg 04/01/15 21:49 7439-98-703/29/15 16:040.71 0.35 1
Nickel 18.7 mg/kg 04/01/15 21:49 7440-02-003/29/15 16:040.35 0.18 1
Potassium 895 mg/kg 04/01/15 21:49 7440-09-703/29/15 16:0470.9 35.4 1
Sodium 102 mg/kg 04/01/15 21:49 7440-23-503/29/15 16:0470.9 35.4 1
Strontium 53.0 mg/kg 04/01/15 21:49 7440-24-603/29/15 16:040.71 0.35 1
Zinc 24.0 mg/kg 04/01/15 21:49 7440-66-603/29/15 16:041.4 0.71 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 04/02/15 16:09 7440-36-0 D3,N203/29/15 16:043.5 1.8 50
Arsenic 13.4 mg/kg 04/02/15 16:09 7440-38-2 D303/29/15 16:043.5 1.8 50
Cadmium ND mg/kg 04/02/15 16:09 7440-43-9 D303/29/15 16:040.43 0.21 50
Cobalt 13.6 mg/kg 03/31/15 22:29 7440-48-4 D303/29/15 16:043.5 1.8 50
Lead 17.8 mg/kg 04/02/15 16:09 7439-92-1 D303/29/15 16:043.5 1.8 50
Selenium ND mg/kg 04/02/15 16:09 7782-49-2 D303/29/15 16:043.5 1.8 50
Thallium ND mg/kg 04/02/15 16:09 7440-28-0 D303/29/15 16:043.5 1.8 50
Vanadium 63.6 mg/kg 03/31/15 22:29 7440-62-2 D403/29/15 16:043.5 1.8 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:50 7439-97-603/31/15 11:550.011 0.0053 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 28.8 %04/01/15 16:230.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 8.0 Std. Units 03/25/15 11:500.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/29/15 14:04 16887-00-6 D33501755
Sulfate ND mg/kg 03/29/15 14:04 14808-79-8 D33501755
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/29/15 14:04 14797-55-8 D3,H335.0 17.5 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 104
Page 79 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008004 Lab ID:92242381010 Collected:03/17/15 15:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 16700 mg/kg 04/03/15 17:06 7440-44-0339016901
Total Organic Carbon 18700 mg/kg 04/03/15 17:12 7440-44-0344017201
Total Organic Carbon 17300 mg/kg 04/03/15 17:19 7440-44-0350017501
Total Organic Carbon 25100 mg/kg 04/03/15 17:25 7440-44-0345017301
Mean Total Organic Carbon 19400 mg/kg 04/03/15 17:06 7440-44-0345017201
Surrogates
RSD%19.8 %04/03/15 17:061
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 104
Page 80 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008005 Lab ID:92242381011 Collected:03/17/15 15:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 13400 mg/kg 04/01/15 21:54 7429-90-503/29/15 16:046.2 3.1 1
Barium 96.9 mg/kg 04/01/15 21:54 7440-39-303/29/15 16:040.62 0.31 1
Beryllium 3.1 mg/kg 04/01/15 21:54 7440-41-703/29/15 16:040.062 0.031 1
Boron 36.4 mg/kg 04/01/15 21:54 7440-42-803/29/15 16:043.1 1.6 1
Calcium 1520 mg/kg 04/01/15 21:54 7440-70-203/29/15 16:0431.1 15.5 1
Chromium 39.4 mg/kg 04/01/15 21:54 7440-47-303/29/15 16:040.31 0.16 1
Copper 40.6 mg/kg 04/01/15 21:54 7440-50-803/29/15 16:040.31 0.16 1
Iron 3320 mg/kg 04/01/15 21:54 7439-89-603/29/15 16:042.5 1.2 1
Magnesium 603 mg/kg 04/01/15 21:54 7439-95-403/29/15 16:0431.1 15.5 1
Manganese 15.8 mg/kg 04/01/15 21:54 7439-96-503/29/15 16:040.31 0.16 1
Molybdenum 2.0 mg/kg 04/01/15 21:54 7439-98-703/29/15 16:040.62 0.31 1
Nickel 25.7 mg/kg 04/01/15 21:54 7440-02-003/29/15 16:040.31 0.16 1
Potassium 1560 mg/kg 04/01/15 21:54 7440-09-703/29/15 16:0462.1 31.1 1
Sodium 158 mg/kg 04/01/15 21:54 7440-23-503/29/15 16:0462.1 31.1 1
Strontium 78.8 mg/kg 04/01/15 21:54 7440-24-603/29/15 16:040.62 0.31 1
Zinc 39.0 mg/kg 04/01/15 21:54 7440-66-603/29/15 16:041.2 0.62 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 04/02/15 16:11 7440-36-0 N203/29/15 16:043.1 1.6 50
Arsenic 17.0 mg/kg 04/02/15 16:11 7440-38-203/29/15 16:043.1 1.6 50
Cadmium 0.30J mg/kg 04/02/15 16:11 7440-43-903/29/15 16:040.37 0.19 50
Cobalt 19.7 mg/kg 03/31/15 22:31 7440-48-4 D303/29/15 16:043.1 1.6 50
Lead 25.5 mg/kg 04/02/15 16:11 7439-92-103/29/15 16:043.1 1.6 50
Selenium ND mg/kg 04/02/15 16:11 7782-49-203/29/15 16:043.1 1.6 50
Thallium ND mg/kg 04/02/15 16:11 7440-28-003/29/15 16:043.1 1.6 50
Vanadium 112 mg/kg 03/31/15 22:31 7440-62-2 D403/29/15 16:043.1 1.6 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:52 7439-97-603/31/15 11:550.010 0.0051 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 21.5 %04/01/15 16:230.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.8 Std. Units 03/25/15 11:500.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/29/15 14:25 16887-00-6 D33141575
Sulfate ND mg/kg 03/29/15 14:25 14808-79-8 D33141575
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/29/15 14:25 14797-55-8 D3,H331.4 15.7 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 104
Page 81 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008005 Lab ID:92242381011 Collected:03/17/15 15:30 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 22500 mg/kg 04/06/15 07:40 7440-44-0370018501
Total Organic Carbon 12400 mg/kg 04/06/15 07:46 7440-44-0373018601
Total Organic Carbon 19200 mg/kg 04/06/15 07:52 7440-44-0379018901
Total Organic Carbon 14200 mg/kg 04/06/15 07:57 7440-44-0378018901
Mean Total Organic Carbon 17100 mg/kg 04/06/15 07:40 7440-44-0375018701
Surrogates
RSD%27.1 %04/06/15 07:401
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 104
Page 82 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008006 Lab ID:92242381012 Collected:03/19/15 09:20 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 859 mg/kg 04/01/15 21:58 7429-90-503/29/15 16:046.2 3.1 1
Barium 38.6 mg/kg 04/01/15 21:58 7440-39-303/29/15 16:040.62 0.31 1
Beryllium 0.26 mg/kg 04/01/15 21:58 7440-41-703/29/15 16:040.062 0.031 1
Boron ND mg/kg 04/01/15 21:58 7440-42-803/29/15 16:043.1 1.5 1
Calcium 248 mg/kg 04/01/15 21:58 7440-70-203/29/15 16:0430.8 15.4 1
Chromium 2.2 mg/kg 04/01/15 21:58 7440-47-303/29/15 16:040.31 0.15 1
Copper 4.8 mg/kg 04/01/15 21:58 7440-50-803/29/15 16:040.31 0.15 1
Iron 1100 mg/kg 04/01/15 21:58 7439-89-603/29/15 16:042.5 1.2 1
Magnesium 65.1 mg/kg 04/01/15 21:58 7439-95-403/29/15 16:0430.8 15.4 1
Manganese 17.7 mg/kg 04/01/15 21:58 7439-96-503/29/15 16:040.31 0.15 1
Molybdenum 0.42J mg/kg 04/01/15 21:58 7439-98-703/29/15 16:040.62 0.31 1
Nickel 3.3 mg/kg 04/01/15 21:58 7440-02-003/29/15 16:040.31 0.15 1
Potassium 116 mg/kg 04/01/15 21:58 7440-09-703/29/15 16:0461.5 30.8 1
Sodium ND mg/kg 04/01/15 21:58 7440-23-503/29/15 16:0461.5 30.8 1
Strontium 11.0 mg/kg 04/01/15 21:58 7440-24-603/29/15 16:040.62 0.31 1
Zinc 4.5 mg/kg 04/01/15 21:58 7440-66-603/29/15 16:041.2 0.62 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 04/02/15 16:13 7440-36-0 N203/29/15 16:043.1 1.5 50
Arsenic ND mg/kg 04/02/15 16:13 7440-38-203/29/15 16:043.1 1.5 50
Cadmium ND mg/kg 04/02/15 16:13 7440-43-903/29/15 16:040.37 0.18 50
Cobalt ND mg/kg 03/31/15 22:33 7440-48-4 D303/29/15 16:043.1 1.5 50
Lead ND mg/kg 04/02/15 16:13 7439-92-103/29/15 16:043.1 1.5 50
Selenium ND mg/kg 04/02/15 16:13 7782-49-203/29/15 16:043.1 1.5 50
Thallium ND mg/kg 04/02/15 16:13 7440-28-003/29/15 16:043.1 1.5 50
Vanadium 2.7J mg/kg 03/31/15 22:33 7440-62-2 D303/29/15 16:043.1 1.5 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 13:54 7439-97-603/31/15 11:550.0096 0.0048 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 19.9 %04/01/15 16:240.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 6.2 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/29/15 14:47 16887-00-6 D33111565
Sulfate ND mg/kg 03/29/15 14:47 14808-79-8 D33111565
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/29/15 14:47 14797-55-8 H331.1 15.6 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 104
Page 83 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008006 Lab ID:92242381012 Collected:03/19/15 09:20 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 14300 mg/kg 04/06/15 08:49 7440-44-07473741
Total Organic Carbon 9190 mg/kg 04/06/15 08:55 7440-44-07483741
Total Organic Carbon 11400 mg/kg 04/06/15 09:00 7440-44-07573781
Total Organic Carbon 8370 mg/kg 04/06/15 09:06 7440-44-07453721
Mean Total Organic Carbon 10800 mg/kg 04/06/15 08:49 7440-44-07493751
Surrogates
RSD%24.6 %04/06/15 08:491
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 64 of 104
Page 84 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008008 Lab ID:92242381013 Collected:03/19/15 12:40 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP
Aluminum 3530 mg/kg 04/01/15 22:14 7429-90-503/29/15 16:047.7 3.9 1
Barium 34.6 mg/kg 04/01/15 22:14 7440-39-303/29/15 16:040.77 0.39 1
Beryllium 0.96 mg/kg 04/01/15 22:14 7440-41-703/29/15 16:040.077 0.039 1
Boron 9.2 mg/kg 04/01/15 22:14 7440-42-803/29/15 16:043.9 1.9 1
Calcium 517 mg/kg 04/01/15 22:14 7440-70-203/29/15 16:0438.7 19.3 1
Chromium 10.6 mg/kg 04/01/15 22:14 7440-47-303/29/15 16:040.39 0.19 1
Copper 12.1 mg/kg 04/01/15 22:14 7440-50-803/29/15 16:040.39 0.19 1
Iron 2230 mg/kg 04/01/15 22:14 7439-89-603/29/15 16:043.1 1.5 1
Magnesium 206 mg/kg 04/01/15 22:14 7439-95-403/29/15 16:0438.7 19.3 1
Manganese 9.4 mg/kg 04/01/15 22:14 7439-96-503/29/15 16:040.39 0.19 1
Molybdenum 0.55J mg/kg 04/01/15 22:14 7439-98-703/29/15 16:040.77 0.39 1
Nickel 7.0 mg/kg 04/01/15 22:14 7440-02-003/29/15 16:040.39 0.19 1
Potassium 436 mg/kg 04/01/15 22:14 7440-09-703/29/15 16:0477.3 38.7 1
Sodium 53.9J mg/kg 04/01/15 22:14 7440-23-503/29/15 16:0477.3 38.7 1
Strontium 19.5 mg/kg 04/01/15 22:14 7440-24-603/29/15 16:040.77 0.39 1
Zinc 8.5 mg/kg 04/01/15 22:14 7440-66-603/29/15 16:041.5 0.77 1
Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS
Antimony ND mg/kg 04/02/15 16:15 7440-36-0 N203/29/15 16:043.9 1.9 50
Arsenic 2.9J mg/kg 04/02/15 16:15 7440-38-203/29/15 16:043.9 1.9 50
Cadmium ND mg/kg 04/02/15 16:15 7440-43-903/29/15 16:040.46 0.23 50
Cobalt 4.2 mg/kg 03/31/15 22:35 7440-48-4 D303/29/15 16:043.9 1.9 50
Lead 4.8 mg/kg 04/02/15 16:15 7439-92-103/29/15 16:043.9 1.9 50
Selenium ND mg/kg 04/02/15 16:15 7782-49-203/29/15 16:043.9 1.9 50
Thallium ND mg/kg 04/02/15 16:15 7440-28-003/29/15 16:043.9 1.9 50
Vanadium 19.0 mg/kg 03/31/15 22:35 7440-62-2 D303/29/15 16:043.9 1.9 50
Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury
Mercury ND mg/kg 04/01/15 14:00 7439-97-603/31/15 11:550.012 0.0062 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 34.2 %04/01/15 16:240.10 0.10 1
Analytical Method: EPA 90459045 pH Soil
pH at 25 Degrees C 7.2 Std. Units 03/30/15 12:550.10 0.10 1
Analytical Method: EPA 90569056 IC Anions
Chloride ND mg/kg 03/29/15 15:08 16887-00-6 D33791905
Sulfate ND mg/kg 03/29/15 15:08 14808-79-8 D33791905
Analytical Method: EPA 90569056 IC Anions 48hr
Nitrate as N ND mg/kg 03/29/15 15:08 14797-55-8 D3,H337.9 19.0 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 104
Page 85 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008008 Lab ID:92242381013 Collected:03/19/15 12:40 Received:03/23/15 15:04 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 9060Total Organic Carbon Quad
Total Organic Carbon 14400 mg/kg 04/06/15 09:11 7440-44-018008981
Total Organic Carbon 18800 mg/kg 04/06/15 09:18 7440-44-018209111
Total Organic Carbon 23100 mg/kg 04/06/15 09:23 7440-44-018209081
Total Organic Carbon 15800 mg/kg 04/06/15 09:30 7440-44-018109071
Mean Total Organic Carbon 18000 mg/kg 04/06/15 09:11 7440-44-018109061
Surrogates
RSD%21.3 %04/06/15 09:111
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 66 of 104
Page 86 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008009 Lab ID:92242381014 Collected:03/19/15 09:00 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum ND ug/L 03/28/15 15:37 7429-90-503/27/15 12:2510.0 1.2 1
Antimony ND ug/L 03/28/15 15:37 7440-36-003/27/15 12:250.50 0.25 1
Arsenic ND ug/L 03/28/15 15:37 7440-38-203/27/15 12:250.50 0.25 1
Barium 0.44 ug/L 03/28/15 15:37 7440-39-303/27/15 12:250.30 0.14 1
Beryllium ND ug/L 03/28/15 15:37 7440-41-703/27/15 12:250.20 0.066 1
Boron ND ug/L 03/28/15 15:37 7440-42-803/27/15 12:255.0 1.0 1
Cadmium ND ug/L 03/28/15 15:37 7440-43-903/27/15 12:250.080 0.033 1
Calcium ND ug/L 03/28/15 15:37 7440-70-203/27/15 12:2540.0 8.4 1
Chromium 1.5 ug/L 03/28/15 15:37 7440-47-303/27/15 12:250.50 0.22 1
Cobalt ND ug/L 03/28/15 15:37 7440-48-403/27/15 12:250.50 0.25 1
Copper ND ug/L 03/28/15 15:37 7440-50-803/27/15 12:251.0 0.22 1
Iron 93.2 ug/L 03/28/15 15:37 7439-89-603/27/15 12:2550.0 8.0 1
Lead ND ug/L 03/28/15 15:37 7439-92-103/27/15 12:250.10 0.046 1
Magnesium ND ug/L 03/28/15 15:37 7439-95-403/27/15 12:2510.0 2.8 1
Manganese 1.2 ug/L 03/28/15 15:37 7439-96-503/27/15 12:250.50 0.14 1
Molybdenum ND ug/L 03/28/15 15:37 7439-98-703/27/15 12:250.50 0.24 1
Nickel ND ug/L 03/28/15 15:37 7440-02-003/27/15 12:250.50 0.23 1
Potassium ND ug/L 03/28/15 15:37 7440-09-703/27/15 12:2550.0 8.3 1
Selenium ND ug/L 03/28/15 15:37 7782-49-203/27/15 12:250.50 0.25 1
Sodium ND ug/L 03/28/15 15:37 7440-23-503/27/15 12:2550.0 18.2 1
Strontium ND ug/L 03/28/15 15:37 7440-24-603/27/15 12:250.50 0.057 1
Thallium ND ug/L 03/28/15 15:37 7440-28-003/27/15 12:250.10 0.025 1
Vanadium ND ug/L 03/28/15 15:37 7440-62-203/27/15 12:251.0 0.21 1
Zinc ND ug/L 03/28/15 15:37 7440-66-603/27/15 12:255.0 2.5 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/30/15 10:53 7439-97-603/28/15 13:550.20 0.026 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 67 of 104
Page 87 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008010 Lab ID:92242381015 Collected:03/18/15 08:50 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum ND ug/L 03/28/15 15:40 7429-90-503/27/15 12:2510.0 1.2 1
Antimony ND ug/L 03/28/15 15:40 7440-36-003/27/15 12:250.50 0.25 1
Arsenic ND ug/L 03/28/15 15:40 7440-38-203/27/15 12:250.50 0.25 1
Barium ND ug/L 03/28/15 15:40 7440-39-303/27/15 12:250.30 0.14 1
Beryllium ND ug/L 03/28/15 15:40 7440-41-703/27/15 12:250.20 0.066 1
Boron ND ug/L 03/28/15 15:40 7440-42-803/27/15 12:255.0 1.0 1
Cadmium ND ug/L 03/28/15 15:40 7440-43-903/27/15 12:250.080 0.033 1
Calcium 46.3 ug/L 03/28/15 15:40 7440-70-203/27/15 12:2540.0 8.4 1
Chromium 0.60 ug/L 03/28/15 15:40 7440-47-303/27/15 12:250.50 0.22 1
Cobalt ND ug/L 03/28/15 15:40 7440-48-403/27/15 12:250.50 0.25 1
Copper ND ug/L 03/28/15 15:40 7440-50-803/27/15 12:251.0 0.22 1
Iron ND ug/L 03/28/15 15:40 7439-89-603/27/15 12:2550.0 8.0 1
Lead ND ug/L 03/28/15 15:40 7439-92-103/27/15 12:250.10 0.046 1
Magnesium ND ug/L 03/28/15 15:40 7439-95-403/27/15 12:2510.0 2.8 1
Manganese 1.3 ug/L 03/28/15 15:40 7439-96-503/27/15 12:250.50 0.14 1
Molybdenum ND ug/L 03/28/15 15:40 7439-98-703/27/15 12:250.50 0.24 1
Nickel ND ug/L 03/28/15 15:40 7440-02-003/27/15 12:250.50 0.23 1
Potassium ND ug/L 03/28/15 15:40 7440-09-703/27/15 12:2550.0 8.3 1
Selenium ND ug/L 03/28/15 15:40 7782-49-203/27/15 12:250.50 0.25 1
Sodium ND ug/L 03/28/15 15:40 7440-23-503/27/15 12:2550.0 18.2 1
Strontium ND ug/L 03/28/15 15:40 7440-24-603/27/15 12:250.50 0.057 1
Thallium ND ug/L 03/28/15 15:40 7440-28-003/27/15 12:250.10 0.025 1
Vanadium ND ug/L 03/28/15 15:40 7440-62-203/27/15 12:251.0 0.21 1
Zinc ND ug/L 03/28/15 15:40 7440-66-603/27/15 12:255.0 2.5 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/30/15 10:56 7439-97-603/28/15 13:550.20 0.026 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 68 of 104
Page 88 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008011 Lab ID:92242381016 Collected:03/17/15 12:35 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum ND ug/L 03/28/15 15:43 7429-90-503/27/15 12:2510.0 1.2 1
Antimony ND ug/L 03/28/15 15:43 7440-36-003/27/15 12:250.50 0.25 1
Arsenic ND ug/L 03/28/15 15:43 7440-38-203/27/15 12:250.50 0.25 1
Barium 1.8 ug/L 03/28/15 15:43 7440-39-303/27/15 12:250.30 0.14 1
Beryllium ND ug/L 03/28/15 15:43 7440-41-703/27/15 12:250.20 0.066 1
Boron ND ug/L 03/28/15 15:43 7440-42-803/27/15 12:255.0 1.0 1
Cadmium ND ug/L 03/28/15 15:43 7440-43-903/27/15 12:250.080 0.033 1
Calcium 85.2 ug/L 03/28/15 15:43 7440-70-203/27/15 12:2540.0 8.4 1
Chromium 2.7 ug/L 03/28/15 15:43 7440-47-303/27/15 12:250.50 0.22 1
Cobalt ND ug/L 03/28/15 15:43 7440-48-403/27/15 12:250.50 0.25 1
Copper ND ug/L 03/28/15 15:43 7440-50-803/27/15 12:251.0 0.22 1
Iron 169 ug/L 03/28/15 15:43 7439-89-603/27/15 12:2550.0 8.0 1
Lead ND ug/L 03/28/15 15:43 7439-92-103/27/15 12:250.10 0.046 1
Magnesium 12.0 ug/L 03/28/15 15:43 7439-95-403/27/15 12:2510.0 2.8 1
Manganese 4.3 ug/L 03/28/15 15:43 7439-96-503/27/15 12:250.50 0.14 1
Molybdenum 0.95 ug/L 03/28/15 15:43 7439-98-703/27/15 12:250.50 0.24 1
Nickel 1.1 ug/L 03/28/15 15:43 7440-02-003/27/15 12:250.50 0.23 1
Potassium ND ug/L 03/28/15 15:43 7440-09-703/27/15 12:2550.0 8.3 1
Selenium ND ug/L 03/28/15 15:43 7782-49-203/27/15 12:250.50 0.25 1
Sodium ND ug/L 03/28/15 15:43 7440-23-503/27/15 12:2550.0 18.2 1
Strontium 0.59 ug/L 03/28/15 15:43 7440-24-603/27/15 12:250.50 0.057 1
Thallium ND ug/L 03/28/15 15:43 7440-28-003/27/15 12:250.10 0.025 1
Vanadium ND ug/L 03/28/15 15:43 7440-62-203/27/15 12:251.0 0.21 1
Zinc ND ug/L 03/28/15 15:43 7440-66-603/27/15 12:255.0 2.5 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/30/15 10:58 7439-97-603/28/15 13:550.20 0.026 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 69 of 104
Page 89 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008012 Lab ID:92242381017 Collected:03/18/15 16:00 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum ND ug/L 03/28/15 15:46 7429-90-503/27/15 12:2510.0 1.2 1
Antimony ND ug/L 03/28/15 15:46 7440-36-003/27/15 12:250.50 0.25 1
Arsenic ND ug/L 03/28/15 15:46 7440-38-203/27/15 12:250.50 0.25 1
Barium 0.40 ug/L 03/28/15 15:46 7440-39-303/27/15 12:250.30 0.14 1
Beryllium ND ug/L 03/28/15 15:46 7440-41-703/27/15 12:250.20 0.066 1
Boron ND ug/L 03/28/15 15:46 7440-42-803/27/15 12:255.0 1.0 1
Cadmium ND ug/L 03/28/15 15:46 7440-43-903/27/15 12:250.080 0.033 1
Calcium 124 ug/L 03/28/15 15:46 7440-70-203/27/15 12:2540.0 8.4 1
Chromium 1.6 ug/L 03/28/15 15:46 7440-47-303/27/15 12:250.50 0.22 1
Cobalt ND ug/L 03/28/15 15:46 7440-48-403/27/15 12:250.50 0.25 1
Copper ND ug/L 03/28/15 15:46 7440-50-803/27/15 12:251.0 0.22 1
Iron 66.4 ug/L 03/28/15 15:46 7439-89-603/27/15 12:2550.0 8.0 1
Lead ND ug/L 03/28/15 15:46 7439-92-103/27/15 12:250.10 0.046 1
Magnesium 14.6 ug/L 03/28/15 15:46 7439-95-403/27/15 12:2510.0 2.8 1
Manganese 3.1 ug/L 03/28/15 15:46 7439-96-503/27/15 12:250.50 0.14 1
Molybdenum 0.88 ug/L 03/28/15 15:46 7439-98-703/27/15 12:250.50 0.24 1
Nickel ND ug/L 03/28/15 15:46 7440-02-003/27/15 12:250.50 0.23 1
Potassium ND ug/L 03/28/15 15:46 7440-09-703/27/15 12:2550.0 8.3 1
Selenium ND ug/L 03/28/15 15:46 7782-49-203/27/15 12:250.50 0.25 1
Sodium 94.2 ug/L 03/28/15 15:46 7440-23-503/27/15 12:2550.0 18.2 1
Strontium 0.53 ug/L 03/28/15 15:46 7440-24-603/27/15 12:250.50 0.057 1
Thallium ND ug/L 03/28/15 15:46 7440-28-003/27/15 12:250.10 0.025 1
Vanadium ND ug/L 03/28/15 15:46 7440-62-203/27/15 12:251.0 0.21 1
Zinc ND ug/L 03/28/15 15:46 7440-66-603/27/15 12:255.0 2.5 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 03/30/15 11:01 7439-97-603/28/15 13:550.20 0.026 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 70 of 104
Page 90 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007996 SPLP Lab ID:92242381018 Collected:03/18/15 15:35 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum 152 ug/L 04/06/15 08:53 7429-90-504/03/15 12:5210.0 3.0 1
Antimony 5.0 ug/L 04/06/15 08:53 7440-36-004/03/15 12:520.50 0.15 1
Arsenic 3.5 ug/L 04/06/15 08:53 7440-38-204/03/15 12:520.50 0.11 1
Barium 308 ug/L 04/06/15 08:53 7440-39-304/03/15 12:520.30 0.081 1
Beryllium ND ug/L 04/06/15 08:53 7440-41-704/03/15 12:520.20 0.067 1
Boron 119 ug/L 04/06/15 08:53 7440-42-804/03/15 12:525.0 1.1 1
Cadmium ND ug/L 04/06/15 08:53 7440-43-904/03/15 12:520.080 0.024 1
Calcium 3060 ug/L 04/06/15 08:53 7440-70-204/03/15 12:5240.0 16.0 1
Chromium 1.8 ug/L 04/06/15 08:53 7440-47-304/03/15 12:520.50 0.17 1
Cobalt 0.89 ug/L 04/06/15 08:53 7440-48-404/03/15 12:520.50 0.13 1
Copper 3.0 ug/L 04/06/15 08:53 7440-50-804/03/15 12:521.0 0.21 1
Iron ND ug/L 04/06/15 08:53 7439-89-604/03/15 12:5250.0 13.7 1
Lead 0.73 ug/L 04/06/15 08:53 7439-92-104/03/15 12:520.10 0.046 1
Magnesium 688 ug/L 04/06/15 08:53 7439-95-404/03/15 12:5210.0 3.2 1
Manganese 148 ug/L 04/06/15 08:53 7439-96-504/03/15 12:520.50 0.24 1
Molybdenum 2.2 ug/L 04/06/15 08:53 7439-98-704/03/15 12:520.50 0.094 1
Nickel 4.4 ug/L 04/06/15 08:53 7440-02-004/03/15 12:520.50 0.16 1
Potassium 643 ug/L 04/06/15 08:53 7440-09-704/03/15 12:5250.0 11.7 1
Selenium 1.9 ug/L 04/06/15 08:53 7782-49-204/03/15 12:520.50 0.20 1
Sodium 2110 ug/L 04/06/15 08:53 7440-23-504/03/15 12:5250.0 16.3 1
Strontium 37.2 ug/L 04/06/15 08:53 7440-24-604/03/15 12:520.50 0.13 1
Thallium 0.11 ug/L 04/06/15 08:53 7440-28-004/03/15 12:520.10 0.015 1
Vanadium 72.6 ug/L 04/06/15 08:53 7440-62-204/03/15 12:521.0 0.28 1
Zinc 159 ug/L 04/06/15 08:53 7440-66-604/03/15 12:525.0 2.4 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 04/06/15 19:07 7439-97-604/04/15 17:200.20 0.022 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 71 of 104
Page 91 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015007999 SPLP Lab ID:92242381019 Collected:03/17/15 15:45 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum 330 ug/L 04/06/15 08:58 7429-90-504/03/15 12:5210.0 3.0 1
Antimony 3.4 ug/L 04/06/15 08:58 7440-36-004/03/15 12:520.50 0.15 1
Arsenic 27.0 ug/L 04/06/15 08:58 7440-38-204/03/15 12:520.50 0.11 1
Barium 346 ug/L 04/06/15 08:58 7440-39-304/03/15 12:520.30 0.081 1
Beryllium ND ug/L 04/06/15 08:58 7440-41-704/03/15 12:520.20 0.067 1
Boron 208 ug/L 04/06/15 10:26 7440-42-804/03/15 12:5225.0 5.6 5
Cadmium ND ug/L 04/06/15 08:58 7440-43-904/03/15 12:520.080 0.024 1
Calcium 2940 ug/L 04/06/15 08:58 7440-70-204/03/15 12:5240.0 16.0 1
Chromium 1.3 ug/L 04/06/15 08:58 7440-47-304/03/15 12:520.50 0.17 1
Cobalt ND ug/L 04/06/15 08:58 7440-48-404/03/15 12:520.50 0.13 1
Copper 8.0 ug/L 04/06/15 08:58 7440-50-804/03/15 12:521.0 0.21 1
Iron ND ug/L 04/06/15 08:58 7439-89-604/03/15 12:5250.0 13.7 1
Lead 0.68 ug/L 04/06/15 08:58 7439-92-104/03/15 12:520.10 0.046 1
Magnesium 617 ug/L 04/06/15 08:58 7439-95-404/03/15 12:5210.0 3.2 1
Manganese 19.5 ug/L 04/06/15 08:58 7439-96-504/03/15 12:520.50 0.24 1
Molybdenum 6.6 ug/L 04/06/15 08:58 7439-98-704/03/15 12:520.50 0.094 1
Nickel 0.76 ug/L 04/06/15 08:58 7440-02-004/03/15 12:520.50 0.16 1
Potassium 1040 ug/L 04/06/15 08:58 7440-09-704/03/15 12:5250.0 11.7 1
Selenium ND ug/L 04/06/15 08:58 7782-49-204/03/15 12:520.50 0.20 1
Sodium 1590 ug/L 04/06/15 08:58 7440-23-504/03/15 12:5250.0 16.3 1
Strontium 89.0 ug/L 04/06/15 08:58 7440-24-604/03/15 12:520.50 0.13 1
Thallium ND ug/L 04/06/15 08:58 7440-28-004/03/15 12:520.10 0.015 1
Vanadium 120 ug/L 04/06/15 08:58 7440-62-204/03/15 12:521.0 0.28 1
Zinc 157 ug/L 04/06/15 08:58 7440-66-604/03/15 12:525.0 2.4 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 04/06/15 19:10 7439-97-604/04/15 17:200.20 0.022 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 72 of 104
Page 92 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008002 SPLP Lab ID:92242381020 Collected:03/18/15 12:20 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum 122 ug/L 04/06/15 09:03 7429-90-504/03/15 12:5210.0 3.0 1
Antimony ND ug/L 04/06/15 09:03 7440-36-004/03/15 12:520.50 0.15 1
Arsenic 1.1 ug/L 04/06/15 09:03 7440-38-204/03/15 12:520.50 0.11 1
Barium 303 ug/L 04/06/15 09:03 7440-39-304/03/15 12:520.30 0.081 1
Beryllium ND ug/L 04/06/15 09:03 7440-41-704/03/15 12:520.20 0.067 1
Boron 133 ug/L 04/06/15 09:03 7440-42-804/03/15 12:525.0 1.1 1
Cadmium ND ug/L 04/06/15 09:03 7440-43-904/03/15 12:520.080 0.024 1
Calcium 5870 ug/L 04/06/15 09:03 7440-70-204/03/15 12:5240.0 16.0 1
Chromium 2.4 ug/L 04/06/15 09:03 7440-47-304/03/15 12:520.50 0.17 1
Cobalt 0.54 ug/L 04/06/15 09:03 7440-48-404/03/15 12:520.50 0.13 1
Copper 2.9 ug/L 04/06/15 09:03 7440-50-804/03/15 12:521.0 0.21 1
Iron ND ug/L 04/06/15 09:03 7439-89-604/03/15 12:5250.0 13.7 1
Lead 0.73 ug/L 04/06/15 09:03 7439-92-104/03/15 12:520.10 0.046 1
Magnesium 455 ug/L 04/06/15 09:03 7439-95-404/03/15 12:5210.0 3.2 1
Manganese 53.7 ug/L 04/06/15 09:03 7439-96-504/03/15 12:520.50 0.24 1
Molybdenum 9.2 ug/L 04/06/15 09:03 7439-98-704/03/15 12:520.50 0.094 1
Nickel 2.2 ug/L 04/06/15 09:03 7440-02-004/03/15 12:520.50 0.16 1
Potassium 679 ug/L 04/06/15 09:03 7440-09-704/03/15 12:5250.0 11.7 1
Selenium ND ug/L 04/06/15 09:03 7782-49-204/03/15 12:520.50 0.20 1
Sodium 1750 ug/L 04/06/15 09:03 7440-23-504/03/15 12:5250.0 16.3 1
Strontium 39.2 ug/L 04/06/15 09:03 7440-24-604/03/15 12:520.50 0.13 1
Thallium ND ug/L 04/06/15 09:03 7440-28-004/03/15 12:520.10 0.015 1
Vanadium 2.5 ug/L 04/06/15 09:03 7440-62-204/03/15 12:521.0 0.28 1
Zinc 160 ug/L 04/06/15 09:03 7440-66-604/03/15 12:525.0 2.4 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 04/06/15 19:12 7439-97-604/04/15 17:200.20 0.022 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 73 of 104
Page 93 of 125
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92242381
J150305555
Sample:2015008007 SPLP Lab ID:92242381021 Collected:03/18/15 12:30 Received:03/23/15 15:04 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS
Aluminum 252 ug/L 04/06/15 09:08 7429-90-504/03/15 12:5210.0 3.0 1
Antimony 7.1 ug/L 04/06/15 09:08 7440-36-004/03/15 12:520.50 0.15 1
Arsenic 11.9 ug/L 04/06/15 09:08 7440-38-204/03/15 12:520.50 0.11 1
Barium 285 ug/L 04/06/15 09:08 7440-39-304/03/15 12:520.30 0.081 1
Beryllium ND ug/L 04/06/15 09:08 7440-41-704/03/15 12:520.20 0.067 1
Boron 127 ug/L 04/06/15 09:08 7440-42-804/03/15 12:525.0 1.1 1
Cadmium ND ug/L 04/06/15 09:08 7440-43-904/03/15 12:520.080 0.024 1
Calcium 4500 ug/L 04/06/15 09:08 7440-70-204/03/15 12:5240.0 16.0 1
Chromium 1.6 ug/L 04/06/15 09:08 7440-47-304/03/15 12:520.50 0.17 1
Cobalt 0.92 ug/L 04/06/15 09:08 7440-48-404/03/15 12:520.50 0.13 1
Copper 4.6 ug/L 04/06/15 09:08 7440-50-804/03/15 12:521.0 0.21 1
Iron ND ug/L 04/06/15 09:08 7439-89-604/03/15 12:5250.0 13.7 1
Lead 0.89 ug/L 04/06/15 09:08 7439-92-104/03/15 12:520.10 0.046 1
Magnesium 475 ug/L 04/06/15 09:08 7439-95-404/03/15 12:5210.0 3.2 1
Manganese 43.0 ug/L 04/06/15 09:08 7439-96-504/03/15 12:520.50 0.24 1
Molybdenum 4.3 ug/L 04/06/15 09:08 7439-98-704/03/15 12:520.50 0.094 1
Nickel 2.0 ug/L 04/06/15 09:08 7440-02-004/03/15 12:520.50 0.16 1
Potassium 657 ug/L 04/06/15 09:08 7440-09-704/03/15 12:5250.0 11.7 1
Selenium 1.5 ug/L 04/06/15 09:08 7782-49-204/03/15 12:520.50 0.20 1
Sodium 1600 ug/L 04/06/15 09:08 7440-23-504/03/15 12:5250.0 16.3 1
Strontium 50.8 ug/L 04/06/15 09:08 7440-24-604/03/15 12:520.50 0.13 1
Thallium 0.23 ug/L 04/06/15 09:08 7440-28-004/03/15 12:520.10 0.015 1
Vanadium 134 ug/L 04/06/15 09:08 7440-62-204/03/15 12:521.0 0.28 1
Zinc 150 ug/L 04/06/15 09:08 7440-66-604/03/15 12:525.0 2.4 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 04/06/15 19:14 7439-97-604/04/15 17:200.20 0.022 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 74 of 104
Page 94 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/13084
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92242381014, 92242381015, 92242381016, 92242381017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1927067
Associated Lab Samples:92242381014, 92242381015, 92242381016, 92242381017
Matrix:Water
Analyzed
Mercury ug/L ND 0.20 03/30/15 10:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1927068LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 5.15 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1927069MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242371022
1927070
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 5 98 75-125100 1 205ND4.9 5.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 75 of 104
Page 95 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/13139
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92242381018, 92242381019, 92242381020, 92242381021
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932636
Associated Lab Samples:92242381018, 92242381019, 92242381020, 92242381021
Matrix:Water
Analyzed
Mercury ug/L ND 0.20 04/06/15 18:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932637LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 5.85 116 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932638MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92239540007
1932639
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L H31510775-125106 1 2015ND16.1 16.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 76 of 104
Page 96 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/5528
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1169343
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007
Matrix:Solid
Analyzed
Mercury mg/kg ND 0.0081 04/01/15 12:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1169344LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.080.083 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1169345MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35180845003
1169346
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg M1.0937 76 80-12074 4 20.09020.023 0.094 0.090
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 77 of 104
Page 97 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MERP/5529
EPA 7471
EPA 7471
7471 Mercury
Associated Lab Samples:92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1169347
Associated Lab Samples:92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Matrix:Solid
Analyzed
Mercury mg/kg ND 0.0077 04/01/15 13:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1169348LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.084.081 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1169349MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242381008
1169350
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg .107 94 80-12093 2 20.106ND 0.10 0.099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 78 of 104
Page 98 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/23322
EPA 3050
EPA 6010
6010 MET Solid
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1169012
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Matrix:Solid
Analyzed
Aluminum mg/kg ND 5.2 04/02/15 09:26
Barium mg/kg ND 0.52 04/02/15 09:26
Beryllium mg/kg ND 0.052 04/02/15 09:26
Boron mg/kg ND 2.6 04/02/15 09:26
Calcium mg/kg ND 25.8 04/02/15 09:26
Chromium mg/kg ND 0.26 04/02/15 09:26
Copper mg/kg ND 0.26 04/02/15 09:26
Iron mg/kg ND 2.1 04/02/15 09:26
Magnesium mg/kg ND 25.8 04/02/15 09:26
Manganese mg/kg ND 0.26 04/02/15 09:26
Molybdenum mg/kg ND 0.52 04/02/15 09:26
Nickel mg/kg ND 0.26 04/02/15 09:26
Potassium mg/kg ND 51.5 04/02/15 09:26
Sodium mg/kg ND 51.5 04/02/15 09:26
Strontium mg/kg ND 0.52 04/02/15 09:26
Zinc mg/kg ND 1.0 04/02/15 09:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1169013LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum mg/kg 121123 99 80-120
Barium mg/kg 12.812.3 104 80-120
Beryllium mg/kg 1.31.2 105 80-120
Boron mg/kg 125123 101 80-120
Calcium mg/kg 643614 105 80-120
Chromium mg/kg 12.412.3 101 80-120
Copper mg/kg 12.812.3 104 80-120
Iron mg/kg 123123 100 80-120
Magnesium mg/kg 618614 101 80-120
Manganese mg/kg 12.712.3 103 80-120
Molybdenum mg/kg 12.112.3 99 80-120
Nickel mg/kg 12.512.3 102 80-120
Potassium mg/kg 656614 107 80-120
Sodium mg/kg 663614 108 80-120
Strontium mg/kg 12.612.3 102 80-120
Zinc mg/kg 63.661.4 104 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 79 of 104
Page 99 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1169014MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242381001
1169015
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum mg/kg M119186875-125839 0 20195320048504830
Barium mg/kg M119.1 133 75-125143 4 2019.544.1 69.4 72.0
Beryllium mg/kg 1.97 107 75-125101 3 201.970.73 2.8 2.7
Boron mg/kg 191 91 75-12591 3 201957.3 181 186
Calcium mg/kg 950 106 75-125112 6 2097655115501640
Chromium mg/kg 19.1 94 75-12588 3 2019.510.6 28.5 27.6
Copper mg/kg 19.1 103 75-125104 3 2019.510.6 30.1 30.9
Iron mg/kg M11915275-12513 3 20195284029402870
Magnesium mg/kg 950 99 75-125109 10 2097621211501280
Manganese mg/kg M119.1 91 75-12572 8 2019.524.1 41.4 38.1
Molybdenum mg/kg 19.1 90 75-12591 3 2019.50.53J 17.6 18.2
Nickel mg/kg 19.1 102 75-125103 2 2019.57.2 26.6 27.2
Potassium mg/kg M195012375-125131 6 2097639615701670
Sodium mg/kg 950 104 75-125113 10 2097681.5 1070 1180
Strontium mg/kg M119.1 134 75-125134 1 2019.525.4 50.8 51.5
Zinc mg/kg 95 97 75-12597 2 2097.610.5 102 105
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 80 of 104
Page 100 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/23323
EPA 3050
EPA 6020
6020 MET SOLID
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1169016
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Matrix:Solid
Analyzed
Antimony mg/kg ND 0.052 N203/31/15 21:37
Arsenic mg/kg ND 0.052 03/31/15 21:37
Cadmium mg/kg ND 0.0062 03/31/15 21:37
Cobalt mg/kg ND 0.052 03/31/15 21:37
Lead mg/kg ND 0.052 03/31/15 21:37
Selenium mg/kg ND 0.052 03/31/15 21:37
Thallium mg/kg ND 0.052 03/31/15 21:37
Vanadium mg/kg ND 0.052 03/31/15 21:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1169017LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony mg/kg 2.5 N22.4 103 80-120
Arsenic mg/kg 2.52.4 105 80-120
Cadmium mg/kg 0.27.24 111 80-120
Cobalt mg/kg 2.52.4 106 80-120
Lead mg/kg 2.52.4 105 80-120
Selenium mg/kg 2.32.4 97 80-120
Thallium mg/kg 2.62.4 111 80-120
Vanadium mg/kg 2.42.4 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1169018MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242381002
1169019
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony mg/kg D3,M6,
N2
4.16 61 75-12566 204.33ND 4.0J 4.3J
Arsenic mg/kg D34.16 121 75-125121 1 204.3310 15.0 15.1
Cadmium mg/kg D3.416 107 75-125106 0 20.433ND 0.58 0.58
Cobalt mg/kg D3,M64.16 157 75-125155 0 204.3312.9 19.5 19.6
Lead mg/kg D3,M64.16 183 75-125175 1 204.3314.5 22.2 22.0
Selenium mg/kg D3,M6,
R14.16 95 75-12566 22 204.33ND 5.7 4.5
Thallium mg/kg D34.16 87 75-12596 204.33ND 4.0J 4.5
Vanadium mg/kg D4,M64.16 271 75-125240 1 204.3364.7 76.0 75.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 81 of 104
Page 101 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/53216
EPA 3020
EPA 6020A
6020A Water UPD4
Associated Lab Samples:92242381014, 92242381015, 92242381016, 92242381017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1926640
Associated Lab Samples:92242381014, 92242381015, 92242381016, 92242381017
Matrix:Water
Analyzed
Aluminum ug/L ND 10.0 03/28/15 14:55
Antimony ug/L ND 0.50 03/28/15 14:55
Arsenic ug/L ND 0.50 03/28/15 14:55
Barium ug/L ND 0.30 03/28/15 14:55
Beryllium ug/L ND 0.20 03/28/15 14:55
Boron ug/L ND 5.0 03/28/15 14:55
Cadmium ug/L ND 0.080 03/28/15 14:55
Calcium ug/L ND 40.0 03/28/15 14:55
Chromium ug/L ND 0.50 03/28/15 14:55
Cobalt ug/L ND 0.50 03/28/15 14:55
Copper ug/L ND 1.0 03/28/15 14:55
Iron ug/L ND 50.0 03/28/15 14:55
Lead ug/L ND 0.10 03/28/15 14:55
Magnesium ug/L ND 10.0 03/28/15 14:55
Manganese ug/L ND 0.50 03/28/15 14:55
Molybdenum ug/L ND 0.50 03/28/15 14:55
Nickel ug/L ND 0.50 03/28/15 14:55
Potassium ug/L ND 50.0 03/28/15 14:55
Selenium ug/L ND 0.50 03/28/15 14:55
Sodium ug/L ND 50.0 03/28/15 14:55
Strontium ug/L ND 0.50 03/28/15 14:55
Thallium ug/L ND 0.10 03/28/15 14:55
Vanadium ug/L ND 1.0 03/28/15 14:55
Zinc ug/L ND 5.0 03/28/15 14:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1926641LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum ug/L 84.480 105 80-120
Antimony ug/L 81.080 101 80-120
Arsenic ug/L 81.280 102 80-120
Barium ug/L 80.380 100 80-120
Beryllium ug/L 83.580 104 80-120
Boron ug/L 85.280 107 80-120
Cadmium ug/L 84.680 106 80-120
Calcium ug/L 10901000 109 80-120
Chromium ug/L 86.880 108 80-120
Cobalt ug/L 84.780 106 80-120
Copper ug/L 88.780 111 80-120
Iron ug/L 11001000 110 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 82 of 104
Page 102 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1926641LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 86.180 108 80-120
Magnesium ug/L 10801000 108 80-120
Manganese ug/L 86.780 108 80-120
Molybdenum ug/L 83.380 104 80-120
Nickel ug/L 86.380 108 80-120
Potassium ug/L 10701000 107 80-120
Selenium ug/L 81.480 102 80-120
Sodium ug/L 10801000 108 80-120
Strontium ug/L 80.480 100 80-120
Thallium ug/L 87.480 109 80-120
Vanadium ug/L 84.880 106 80-120
Zinc ug/L 86.380 108 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1926978MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92241477016
1926979
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum ug/L 80 111 75-125111 0 2080ND94.1 94.1
Antimony ug/L 80 104 75-125101 3 2080ND83.4 81.0
Arsenic ug/L 80 105 75-125102 3 2080ND83.9 81.8
Barium ug/L 80 101 75-12599 2 2080ND81.0 79.5
Beryllium ug/L 80 104 75-125103 1 2080ND83.6 82.5
Boron ug/L 80 109 75-125108 1 2080ND87.7 87.2
Cadmium ug/L 80 107 75-125106 1 2080ND85.9 85.2
Calcium ug/L 1000 102 75-12599 3 20100045.8 1070 1030
Chromium ug/L 80 108 75-125108 0 2080ND86.7 86.6
Cobalt ug/L 80 109 75-125107 2 2080ND87.2 85.6
Copper ug/L 80 113 75-125111 2 2080ND91.1 89.2
Iron ug/L 1000 109 75-125109 1 201000ND11301120
Lead ug/L 80 109 75-125107 2 2080ND87.5 85.6
Magnesium ug/L 1000 109 75-125108 0 201000ND10901090
Manganese ug/L 80 108 75-125107 1 20800.67 87.4 86.6
Molybdenum ug/L 80 104 75-125102 1 2080ND83.4 82.3
Nickel ug/L 80 110 75-125108 1 20800.54 88.3 87.2
Potassium ug/L 1000 108 75-125105 2 201000ND10901060
Selenium ug/L 80 101 75-125100 1 2080ND81.2 80.0
Sodium ug/L 1000 108 75-125106 1 201000ND11001090
Strontium ug/L 80 101 75-125100 1 2080ND81.1 80.5
Thallium ug/L 80 109 75-125107 1 2080ND86.8 85.7
Vanadium ug/L 80 106 75-125105 1 2080ND85.0 83.9
Zinc ug/L 80 104 75-125104 0 2080ND86.8 86.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 83 of 104
Page 103 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/53349
EPA 3020
EPA 6020A
6020A Water UPD4
Associated Lab Samples:92242381018, 92242381019, 92242381020, 92242381021
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1931408
Associated Lab Samples:92242381018, 92242381019, 92242381020, 92242381021
Matrix:Water
Analyzed
Aluminum ug/L ND 10.0 04/06/15 07:50
Antimony ug/L ND 0.50 04/06/15 07:50
Arsenic ug/L ND 0.50 04/06/15 07:50
Barium ug/L ND 0.30 04/06/15 07:50
Beryllium ug/L ND 0.20 04/06/15 07:50
Boron ug/L ND 5.0 04/06/15 07:50
Cadmium ug/L ND 0.080 04/06/15 07:50
Calcium ug/L ND 40.0 04/06/15 07:50
Chromium ug/L ND 0.50 04/06/15 07:50
Cobalt ug/L ND 0.50 04/06/15 07:50
Copper ug/L ND 1.0 04/06/15 07:50
Iron ug/L ND 50.0 04/06/15 07:50
Lead ug/L ND 0.10 04/06/15 07:50
Magnesium ug/L ND 10.0 04/06/15 07:50
Manganese ug/L ND 0.50 04/06/15 07:50
Molybdenum ug/L ND 0.50 04/06/15 07:50
Nickel ug/L ND 0.50 04/06/15 07:50
Potassium ug/L ND 50.0 04/06/15 07:50
Selenium ug/L ND 0.50 04/06/15 07:50
Sodium ug/L ND 50.0 04/06/15 07:50
Strontium ug/L ND 0.50 04/06/15 07:50
Thallium ug/L ND 0.10 04/06/15 07:50
Vanadium ug/L ND 1.0 04/06/15 07:50
Zinc ug/L ND 5.0 04/06/15 07:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1931409LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum ug/L 85.580 107 80-120
Antimony ug/L 80.180 100 80-120
Arsenic ug/L 80.580 101 80-120
Barium ug/L 80.480 101 80-120
Beryllium ug/L 80.580 101 80-120
Boron ug/L 82.680 103 80-120
Cadmium ug/L 81.680 102 80-120
Calcium ug/L 9551000 96 80-120
Chromium ug/L 82.780 103 80-120
Cobalt ug/L 79.780 100 80-120
Copper ug/L 78.780 98 80-120
Iron ug/L 10401000 104 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 84 of 104
Page 104 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1931409LABORATORY CONTROL SAMPLE:
LCSSpike
Lead ug/L 82.280 103 80-120
Magnesium ug/L 9781000 98 80-120
Manganese ug/L 81.380 102 80-120
Molybdenum ug/L 79.280 99 80-120
Nickel ug/L 80.280 100 80-120
Potassium ug/L 10201000 102 80-120
Selenium ug/L 80.180 100 80-120
Sodium ug/L 10001000 100 80-120
Strontium ug/L 79.980 100 80-120
Thallium ug/L 80.480 101 80-120
Vanadium ug/L 80.080 100 80-120
Zinc ug/L 84.480 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1931410MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92243088001
1931411
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum ug/L 80 113 75-125108 4 2080ND94.2 90.2
Antimony ug/L 80 98 75-125101 3 2080ND78.6 81.2
Arsenic ug/L 80 100 75-125103 3 2080ND80.0 82.5
Barium ug/L 80 100 75-125100 1 2080ND79.8 80.3
Beryllium ug/L 80 103 75-125101 2 2080ND82.4 80.6
Boron ug/L 80 104 75-125100 4 2080ND83.9 81.0
Cadmium ug/L 80 101 75-125102 0 2080ND81.0 81.3
Calcium ug/L 1000 88 75-12595 8 201000ND882953
Chromium ug/L 80 102 75-125104 1 2080ND81.8 82.8
Cobalt ug/L 80 100 75-12599 0 2080ND79.9 79.6
Copper ug/L 80 99 75-12599 0 2080ND79.3 79.0
Iron ug/L 1000 103 75-125104 1 201000ND10301040
Lead ug/L 80 102 75-125103 2 2080ND81.4 82.8
Magnesium ug/L 1000 96 75-12598 2 201000ND959978
Manganese ug/L 80 101 75-125103 1 2080ND81.1 82.1
Molybdenum ug/L 80 99 75-12599 0 2080ND79.0 78.9
Nickel ug/L 80 101 75-125100 1 2080ND80.5 79.6
Potassium ug/L 1000 103 75-125103 0 201000ND10301030
Selenium ug/L 80 102 75-125101 1 2080ND81.5 80.8
Sodium ug/L 1000 101 75-125100 1 201000ND10101000
Strontium ug/L 80 100 75-125100 0 2080ND79.9 79.8
Thallium ug/L 80 103 75-125105 2 2080ND82.6 83.8
Vanadium ug/L 80 100 75-125100 0 2080ND79.7 80.0
Zinc ug/L 80 105 75-125104 1 2080ND85.3 84.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 85 of 104
Page 105 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/3404
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008, 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92241996005
1171652SAMPLE DUPLICATE:
Percent Moisture %22.3 6 1020.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242647007
1171653SAMPLE DUPLICATE:
Percent Moisture %9.0 D66310
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242647020
1171654SAMPLE DUPLICATE:
Percent Moisture %25.5 D62910
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242381009
1171655SAMPLE DUPLICATE:
Percent Moisture %24.6 0 1024.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 86 of 104
Page 106 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/36413
EPA 9045
EPA 9045
9045 pH
Associated Lab Samples:92242381002, 92242381008, 92242381009, 92242381010, 92242381011
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92241965001
1418511SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 7.6 D62107.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242371021
1418512SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 9.2 D62109.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 87 of 104
Page 107 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/36450
EPA 9045
EPA 9045
9045 pH
Associated Lab Samples:92242381001, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007, 92242381012,
92242381013
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242374004
1419698SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 5.2 0 105.2
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242504013
1419699SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 8.0 0 107.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 88 of 104
Page 108 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/22392
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1422994
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004
Matrix:Water
Analyzed
Sulfate mg/L 10.2 4.0 D304/02/15 11:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1422995LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 19.220 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1422996MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242374008
1422997
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L D324.3 84 84 024.316.7 37.2 37.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1422998MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242502011
1422999
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate mg/L D327.7 99 99 027.79.7 37.0 37.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 89 of 104
Page 109 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/22398
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1423321
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004
Matrix:Water
Analyzed
Nitrogen, Nitrate mg/L 355 2.0 P803/31/15 19:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1423322LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 2.42.5 95 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1423323MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92241508005
1423324
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L H1,M63.3 -104 90-110-65 0 103.3391 387 389
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1423325MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242371020
1423326
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L H1,M63.1 -55 90-110-95 0 103.1371 370 368
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 90 of 104
Page 110 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/22399
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1423399
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004
Matrix:Water
Analyzed
Chloride mg/L ND 1.0 03/31/15 15:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1423400LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 20.620 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1423401MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92241965003
1423402
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride mg/L 29.5 105 90-110105 0 1029.5ND 32.1 32.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1423403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242381003
1423404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride mg/L 27.6 107 90-110105 2 1027.6ND 29.6 29.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 91 of 104
Page 111 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/44900
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1168433
Associated Lab Samples:
Matrix:Solid
Analyzed
Chloride mg/kg ND 50.0 03/28/15 01:02
Sulfate mg/kg ND 50.0 03/28/15 01:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1168434LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/kg 464495 94 80-120
Sulfate mg/kg 468495 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1168436MATRIX SPIKE SAMPLE:
MSSpike
Result
92242373003
Chloride mg/kg 418491 85 80-120ND
Sulfate mg/kg 916 M14916280-120612
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242373003
1168435SAMPLE DUPLICATE:
Chloride mg/kg ND 20ND
Sulfate mg/kg 510 18 20612
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 92 of 104
Page 112 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/44904
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1168486
Associated Lab Samples:
Matrix:Solid
Analyzed
Chloride mg/kg ND 49.8 03/29/15 12:17
Sulfate mg/kg ND 49.8 03/29/15 12:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1168487LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/kg 482496 97 80-120
Sulfate mg/kg 485496 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1168489MATRIX SPIKE SAMPLE:
MSSpike
Result
92242381009
Chloride mg/kg 641 M16607880-120ND
Sulfate mg/kg 796660 109 80-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242381009
1168488SAMPLE DUPLICATE:
Chloride mg/kg ND 20ND
Sulfate mg/kg ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 93 of 104
Page 113 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/44899
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1168425
Associated Lab Samples:
Matrix:Solid
Analyzed
Nitrate as N mg/kg ND 5.0 03/28/15 01:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1168426LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrate as N mg/kg 48.549.5 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1168428MATRIX SPIKE SAMPLE:
MSSpike
Result
92242373003
Nitrate as N mg/kg 42.2 H349.1 86 80-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242373003
1168427SAMPLE DUPLICATE:
Nitrate as N mg/kg ND H320ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 94 of 104
Page 114 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/44903
EPA 9056
EPA 9056
9056 IC Anions
Associated Lab Samples:92242381009, 92242381010, 92242381011, 92242381012, 92242381013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1168482
Associated Lab Samples:
Matrix:Solid
Analyzed
Nitrate as N mg/kg ND 5.0 03/29/15 12:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1168483LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrate as N mg/kg 50.749.6 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1168485MATRIX SPIKE SAMPLE:
MSSpike
Result
92242381009
Nitrate as N mg/kg 65.7 H3669780-120ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92242381009
1168484SAMPLE DUPLICATE:
Nitrate as N mg/kg ND H320ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 95 of 104
Page 115 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/27838
EPA 9060
EPA 9060
9060 TOC Average
Associated Lab Samples:92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008, 92242381009, 92242381010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1135827
Associated Lab Samples:
Matrix:Solid
Analyzed
Mean Total Organic Carbon mg/kg ND 600 04/03/15 11:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1135828LABORATORY CONTROL SAMPLE:
LCSSpike
Mean Total Organic Carbon mg/kg 117000120000 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1135829MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242381001
1135830
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mean Total Organic Carbon mg/kg 26300 75 50-15084 6 3026300234004300045500
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 96 of 104
Page 116 of 125
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92242381
J150305555
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/27846
EPA 9060
EPA 9060
9060 TOC Average
Associated Lab Samples:92242381011, 92242381012, 92242381013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1136263
Associated Lab Samples:
Matrix:Solid
Analyzed
Mean Total Organic Carbon mg/kg ND 600 04/06/15 06:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1136264LABORATORY CONTROL SAMPLE:
LCSSpike
Mean Total Organic Carbon mg/kg 120000120000 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1136265MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242381011
1136266
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mean Total Organic Carbon mg/kg 37700 94 50-150111 12 3037600171005230058900
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1136267MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92242502005
1136268
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mean Total Organic Carbon mg/kg 70600 95 50-15099 1 307010071100138000140000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 97 of 104
Page 117 of 125
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92242381
J150305555
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - Green BayPASI-G
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Sample was diluted due to the presence of high levels of target analytes.D4
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
Analysis conducted outside the EPA method holding time.H1
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
The lab does not hold TNI accreditation for this parameter.N2
Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.P8
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 98 of 104
Page 118 of 125
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92242381001 MPRP/23322 ICP/142642015007996EPA 3050 EPA 6010
92242381002 MPRP/23322 ICP/142642015007999EPA 3050 EPA 6010
92242381003 MPRP/23322 ICP/142642015008002EPA 3050 EPA 6010
92242381004 MPRP/23322 ICP/142642015008007EPA 3050 EPA 6010
92242381005 MPRP/23322 ICP/142642015007997EPA 3050 EPA 6010
92242381006 MPRP/23322 ICP/142642015007998EPA 3050 EPA 6010
92242381007 MPRP/23322 ICP/142642015008000EPA 3050 EPA 6010
92242381008 MPRP/23322 ICP/142642015008001EPA 3050 EPA 6010
92242381009 MPRP/23322 ICP/142642015008003EPA 3050 EPA 6010
92242381010 MPRP/23322 ICP/142642015008004EPA 3050 EPA 6010
92242381011 MPRP/23322 ICP/142642015008005EPA 3050 EPA 6010
92242381012 MPRP/23322 ICP/142642015008006EPA 3050 EPA 6010
92242381013 MPRP/23322 ICP/142642015008008EPA 3050 EPA 6010
92242381001 MPRP/23323 ICPM/95032015007996EPA 3050 EPA 6020
92242381002 MPRP/23323 ICPM/95032015007999EPA 3050 EPA 6020
92242381003 MPRP/23323 ICPM/95032015008002EPA 3050 EPA 6020
92242381004 MPRP/23323 ICPM/95032015008007EPA 3050 EPA 6020
92242381005 MPRP/23323 ICPM/95032015007997EPA 3050 EPA 6020
92242381006 MPRP/23323 ICPM/95032015007998EPA 3050 EPA 6020
92242381007 MPRP/23323 ICPM/95032015008000EPA 3050 EPA 6020
92242381008 MPRP/23323 ICPM/95032015008001EPA 3050 EPA 6020
92242381009 MPRP/23323 ICPM/95032015008003EPA 3050 EPA 6020
92242381010 MPRP/23323 ICPM/95032015008004EPA 3050 EPA 6020
92242381011 MPRP/23323 ICPM/95032015008005EPA 3050 EPA 6020
92242381012 MPRP/23323 ICPM/95032015008006EPA 3050 EPA 6020
92242381013 MPRP/23323 ICPM/95032015008008EPA 3050 EPA 6020
92242381014 MPRP/53216 ICPM/235812015008009EPA 3020 EPA 6020A
92242381015 MPRP/53216 ICPM/235812015008010EPA 3020 EPA 6020A
92242381016 MPRP/53216 ICPM/235812015008011EPA 3020 EPA 6020A
92242381017 MPRP/53216 ICPM/235812015008012EPA 3020 EPA 6020A
92242381018 MPRP/53349 ICPM/236722015007996 SPLP EPA 3020 EPA 6020A
92242381019 MPRP/53349 ICPM/236722015007999 SPLP EPA 3020 EPA 6020A
92242381020 MPRP/53349 ICPM/236722015008002 SPLP EPA 3020 EPA 6020A
92242381021 MPRP/53349 ICPM/236722015008007 SPLP EPA 3020 EPA 6020A
92242381014 MERP/13084 MERC/152002015008009EPA 7470 EPA 7470
92242381015 MERP/13084 MERC/152002015008010EPA 7470 EPA 7470
92242381016 MERP/13084 MERC/152002015008011EPA 7470 EPA 7470
92242381017 MERP/13084 MERC/152002015008012EPA 7470 EPA 7470
92242381018 MERP/13139 MERC/152542015007996 SPLP EPA 7470 EPA 7470
92242381019 MERP/13139 MERC/152542015007999 SPLP EPA 7470 EPA 7470
92242381020 MERP/13139 MERC/152542015008002 SPLP EPA 7470 EPA 7470
92242381021 MERP/13139 MERC/152542015008007 SPLP EPA 7470 EPA 7470
92242381001 MERP/5528 MERC/55192015007996EPA 7471 EPA 7471
92242381002 MERP/5528 MERC/55192015007999EPA 7471 EPA 7471
92242381003 MERP/5528 MERC/55192015008002EPA 7471 EPA 7471
92242381004 MERP/5528 MERC/55192015008007EPA 7471 EPA 7471
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 99 of 104
Page 119 of 125
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92242381005 MERP/5528 MERC/55192015007997EPA 7471 EPA 7471
92242381006 MERP/5528 MERC/55192015007998EPA 7471 EPA 7471
92242381007 MERP/5528 MERC/55192015008000EPA 7471 EPA 7471
92242381008 MERP/5529 MERC/55202015008001EPA 7471 EPA 7471
92242381009 MERP/5529 MERC/55202015008003EPA 7471 EPA 7471
92242381010 MERP/5529 MERC/55202015008004EPA 7471 EPA 7471
92242381011 MERP/5529 MERC/55202015008005EPA 7471 EPA 7471
92242381012 MERP/5529 MERC/55202015008006EPA 7471 EPA 7471
92242381013 MERP/5529 MERC/55202015008008EPA 7471 EPA 7471
92242381001 PMST/34042015007996ASTM D2974-87
92242381002 PMST/34042015007999ASTM D2974-87
92242381003 PMST/34042015008002ASTM D2974-87
92242381004 PMST/34042015008007ASTM D2974-87
92242381005 PMST/34042015007997ASTM D2974-87
92242381006 PMST/34042015007998ASTM D2974-87
92242381007 PMST/34042015008000ASTM D2974-87
92242381008 PMST/34042015008001ASTM D2974-87
92242381009 PMST/34042015008003ASTM D2974-87
92242381010 PMST/34042015008004ASTM D2974-87
92242381011 PMST/34042015008005ASTM D2974-87
92242381012 PMST/34042015008006ASTM D2974-87
92242381013 PMST/34042015008008ASTM D2974-87
92242381001 WET/364502015007996EPA 9045
92242381002 WET/364132015007999EPA 9045
92242381003 WET/364502015008002EPA 9045
92242381004 WET/364502015008007EPA 9045
92242381005 WET/364502015007997EPA 9045
92242381006 WET/364502015007998EPA 9045
92242381007 WET/364502015008000EPA 9045
92242381008 WET/364132015008001EPA 9045
92242381009 WET/364132015008003EPA 9045
92242381010 WET/364132015008004EPA 9045
92242381011 WET/364132015008005EPA 9045
92242381012 WET/364502015008006EPA 9045
92242381013 WET/364502015008008EPA 9045
92242381001 WETA/223922015007996EPA 300.0
92242381002 WETA/223922015007999EPA 300.0
92242381003 WETA/223922015008002EPA 300.0
92242381004 WETA/223922015008007EPA 300.0
92242381001 WETA/223982015007996EPA 353.2
92242381002 WETA/223982015007999EPA 353.2
92242381003 WETA/223982015008002EPA 353.2
92242381004 WETA/223982015008007EPA 353.2
92242381001 WETA/223992015007996SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 100 of 104
Page 120 of 125
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92242381002 WETA/223992015007999SM 4500-Cl-E
92242381003 WETA/223992015008002SM 4500-Cl-E
92242381004 WETA/223992015008007SM 4500-Cl-E
92242381001 WETA/449002015007996EPA 9056
92242381002 WETA/449002015007999EPA 9056
92242381003 WETA/449002015008002EPA 9056
92242381004 WETA/449002015008007EPA 9056
92242381005 WETA/449002015007997EPA 9056
92242381006 WETA/449002015007998EPA 9056
92242381007 WETA/449002015008000EPA 9056
92242381008 WETA/449002015008001EPA 9056
92242381009 WETA/449042015008003EPA 9056
92242381010 WETA/449042015008004EPA 9056
92242381011 WETA/449042015008005EPA 9056
92242381012 WETA/449042015008006EPA 9056
92242381013 WETA/449042015008008EPA 9056
92242381001 WETA/448992015007996EPA 9056
92242381002 WETA/448992015007999EPA 9056
92242381003 WETA/448992015008002EPA 9056
92242381004 WETA/448992015008007EPA 9056
92242381005 WETA/448992015007997EPA 9056
92242381006 WETA/448992015007998EPA 9056
92242381007 WETA/448992015008000EPA 9056
92242381008 WETA/448992015008001EPA 9056
92242381009 WETA/449032015008003EPA 9056
92242381010 WETA/449032015008004EPA 9056
92242381011 WETA/449032015008005EPA 9056
92242381012 WETA/449032015008006EPA 9056
92242381013 WETA/449032015008008EPA 9056
92242381001 WETA/278382015007996EPA 9060
92242381001 WETA/278412015007996EPA 9060
92242381002 WETA/278382015007999EPA 9060
92242381002 WETA/278412015007999EPA 9060
92242381003 WETA/278382015008002EPA 9060
92242381003 WETA/278412015008002EPA 9060
92242381004 WETA/278382015008007EPA 9060
92242381004 WETA/278412015008007EPA 9060
92242381005 WETA/278382015007997EPA 9060
92242381005 WETA/278412015007997EPA 9060
92242381006 WETA/278382015007998EPA 9060
92242381006 WETA/278412015007998EPA 9060
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 101 of 104
Page 121 of 125
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92242381
J150305555
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92242381007 WETA/278382015008000EPA 9060
92242381007 WETA/278412015008000EPA 9060
92242381008 WETA/278382015008001EPA 9060
92242381008 WETA/278412015008001EPA 9060
92242381009 WETA/278382015008003EPA 9060
92242381009 WETA/278412015008003EPA 9060
92242381010 WETA/278382015008004EPA 9060
92242381010 WETA/278412015008004EPA 9060
92242381011 WETA/278462015008005EPA 9060
92242381011 WETA/278472015008005EPA 9060
92242381012 WETA/278462015008006EPA 9060
92242381012 WETA/278472015008006EPA 9060
92242381013 WETA/278462015008008EPA 9060
92242381013 WETA/278472015008008EPA 9060
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/08/2015 12:54 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 102 of 104
Page 122 of 125
Page 103 of 104
Page 123 of 125
Page 104 of 104
Page 124 of 125
Page 125 of 125