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Home My WebLink AboutNC0038377_J15030202 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15030202 Project Name:AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:4/6/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr Page 1 of 113 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015006511 MAYO STEAM 03-Mar-15 3:24 PM illegible SB-2 (0.5-2.0) 2015006512 MAYO STEAM 03-Mar-15 3:52 PM illegible SB-2 (11.0-12.5) 2015006513 MAYO STEAM 03-Mar-15 3:58 PM illegible SB-2EB 2015006514 MAYO STEAM 04-Mar-15 10:15 AM illegible SB-5 (1.0-2.0) 2015006515 MAYO STEAM 04-Mar-15 10:25 AM illegible SB-5 (2.3-3.3) 2015006516 MAYO STEAM 04-Mar-15 11:10 AM illegible SB-5(8.0-9.0) 2015006517 MAYO STEAM 04-Mar-15 10:02 AM illegible SB-5EB 2015006518 MAYO STEAM 04-Mar-15 1:10 PM illegible SB-6 (1.0-2.0) 2015006519 MAYO STEAM 04-Mar-15 12:39 PM illegible SB-6EB 2015006520 MAYO STEAM 04-Mar-15 2:47 PM illegible SB-3 (5.0-6.0) 2015006521 MAYO STEAM 04-Mar-15 3:05 PM illegible SB-3 (17.0-18.5) 2015006522 MAYO STEAM 04-Mar-15 2:16 PM illegible SB-3EB 2015006523 MAYO STEAM 04-Mar-15 4:25 PM illegible SB-1 (1.0-2.0) 2015006524 MAYO STEAM 04-Mar-15 4:45 PM illegible SB-1 (13.5-14.5) 2015006525 MAYO STEAM 04-Mar-15 5:30 PM illegible SB-1EB 15 Total Samples Page 2 of 113 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:4/6/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006511 Collection Date:03-Mar-15 3:24 PM Site: SB-2 (0.5-2.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 4 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006512 Collection Date:03-Mar-15 3:52 PM Site: SB-2 (11.0-12.5) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 5 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006513 Collection Date:03-Mar-15 3:58 PM Site: SB-2EB Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 6 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006514 Collection Date:04-Mar-15 10:15 AM Site: SB-5 (1.0-2.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 7 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006515 Collection Date:04-Mar-15 10:25 AM Site: SB-5 (2.3-3.3) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 8 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006516 Collection Date:04-Mar-15 11:10 AM Site: SB-5(8.0-9.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 9 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006517 Collection Date:04-Mar-15 10:02 AM Site: SB-5EB Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 10 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006518 Collection Date:04-Mar-15 1:10 PM Site: SB-6 (1.0-2.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 11 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006519 Collection Date:04-Mar-15 12:39 PM Site: SB-6EB Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 12 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006520 Collection Date:04-Mar-15 2:47 PM Site: SB-3 (5.0-6.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 13 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006521 Collection Date:04-Mar-15 3:05 PM Site: SB-3 (17.0-18.5) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 14 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006522 Collection Date:04-Mar-15 2:16 PM Site: SB-3EB Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 15 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006523 Collection Date:04-Mar-15 4:25 PM Site: SB-1 (1.0-2.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 16 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006524 Collection Date:04-Mar-15 4:45 PM Site: SB-1 (13.5-14.5) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 17 of 113 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030202 2015006525 Collection Date:04-Mar-15 5:30 PM Site: SB-1EB Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 18 of 113 #=CL# March 30, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92240158 92240158 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15030202 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 94 Page 19 of 113 #=CP# CERTIFICATIONS Pace Project No.: Project: 92240158 J15030202 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 94 Page 20 of 113 #=CP# CERTIFICATIONS Pace Project No.: Project: 92240158 J15030202 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 94 Page 21 of 113 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID Matrix Date Collected Date Received 92240158001 2015006511 Solid 03/03/15 15:24 03/06/15 14:15 92240158002 2015006512 Solid 03/03/15 15:52 03/06/15 14:15 92240158003 2015006514 Solid 03/04/15 10:15 03/06/15 14:15 92240158004 2015006518 Solid 03/04/15 13:10 03/06/15 14:15 92240158005 2015006520 Solid 03/04/15 14:47 03/06/15 14:15 92240158006 2015006523 Solid 03/04/15 16:25 03/06/15 14:15 92240158007 2015006515 Solid 03/04/15 10:25 03/06/15 14:15 92240158008 2015006516 Solid 03/04/15 11:10 03/06/15 14:15 92240158009 2015006521 Solid 03/04/15 15:05 03/06/15 14:15 92240158010 2015006524 Solid 03/04/15 16:45 03/06/15 14:15 92240158011 2015006513 Water 03/03/15 15:58 03/06/15 14:15 92240158012 2015006517 Water 03/04/15 10:02 03/06/15 14:15 92240158013 2015006519 Water 03/04/15 12:39 03/06/15 14:15 92240158014 2015006522 Water 03/04/15 14:16 03/06/15 14:15 92240158015 2015006525 Water 03/04/15 17:30 03/06/15 14:15 92240158016 2015006515 SPLP Water 03/04/15 10:25 03/06/15 14:15 92240158017 2015006516 SPLP Water 03/04/15 11:10 03/06/15 14:15 92240158018 2015006521 SPLP Water 03/04/15 15:05 03/06/15 14:15 92240158019 2015006524 SPLP Water 03/04/15 16:45 03/06/15 14:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 94 Page 22 of 113 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92240158001 2015006511 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158002 2015006512 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158003 2015006514 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158004 2015006518 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158005 2015006520 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 94 Page 23 of 113 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158006 2015006523 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158007 2015006515 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ADMN EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158008 2015006516 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ADMN EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158009 2015006521 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 94 Page 24 of 113 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ADMN EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158010 2015006524 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ADMN EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92240158011 2015006513 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MDM 92240158012 2015006517 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MDM 92240158013 2015006519 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MDM 92240158014 2015006522 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MDM 92240158015 2015006525 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MDM 92240158016 2015006515 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MDM 92240158017 2015006516 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MDM 92240158018 2015006521 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MDM 92240158019 2015006524 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MDM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 94 Page 25 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158001 2015006511 Aluminum 10200 mg/kg 03/17/15 09:548.0EPA 6010 Barium 65.7 mg/kg 03/17/15 09:540.80EPA 6010 Beryllium 0.52 mg/kg 03/17/15 13:53 D30.40EPA 6010 Boron 16.3J mg/kg 03/17/15 13:53 D319.9EPA 6010 Calcium 227 mg/kg 03/17/15 09:5439.9EPA 6010 Chromium 12.9 mg/kg 03/17/15 13:53 D32.0EPA 6010 Copper 22.8 mg/kg 03/17/15 13:53 D32.0EPA 6010 Iron 18300 mg/kg 03/17/15 09:543.2EPA 6010 Magnesium 2420 mg/kg 03/17/15 09:5439.9EPA 6010 Manganese 365 mg/kg 03/17/15 13:53 D32.0EPA 6010 Nickel 1.7 mg/kg 03/17/15 09:540.40EPA 6010 Potassium 2020 mg/kg 03/17/15 09:5479.8EPA 6010 Strontium 4.3 mg/kg 03/17/15 09:540.80EPA 6010 Zinc 27.3 mg/kg 03/17/15 09:541.6EPA 6010 Arsenic 1.9 mg/kg 03/17/15 11:51 D31.6EPA 6020 Cadmium 0.13J mg/kg 03/17/15 11:51 D30.19EPA 6020 Cobalt 6.4 mg/kg 03/17/15 11:51 D31.6EPA 6020 Lead 7.5 mg/kg 03/17/15 11:51 D31.6EPA 6020 Selenium 1.3J mg/kg 03/17/15 11:51 D31.6EPA 6020 Vanadium 44.8 mg/kg 03/17/15 11:51 D41.6EPA 6020 Mercury 0.020 mg/kg 03/17/15 13:270.012EPA 7471 Percent Moisture 35.5 %03/16/15 15:260.10ASTM D2974-87 pH at 25 Degrees C 5.3 Std. Units 03/12/15 15:550.10EPA 9045 Total Organic Carbon 3450 mg/kg 03/13/15 10:12928EPA 9060 Total Organic Carbon 3640 mg/kg 03/13/15 10:17929EPA 9060 Total Organic Carbon 3880 mg/kg 03/13/15 10:23922EPA 9060 Total Organic Carbon 4020 mg/kg 03/13/15 10:29935EPA 9060 Mean Total Organic Carbon 3750 mg/kg 03/13/15 10:12929EPA 9060 RSD%6.7 %03/13/15 10:12EPA 9060 92240158002 2015006512 Aluminum 5930 mg/kg 03/17/15 09:596.1EPA 6010 Barium 31.3 mg/kg 03/17/15 09:590.61EPA 6010 Beryllium 0.39 mg/kg 03/17/15 09:590.061EPA 6010 Boron 7.8 mg/kg 03/17/15 09:593.1EPA 6010 Calcium 22.2J mg/kg 03/17/15 09:5930.7EPA 6010 Chromium 10.8 mg/kg 03/17/15 09:590.31EPA 6010 Copper 5.5 mg/kg 03/17/15 09:590.31EPA 6010 Iron 10300 mg/kg 03/17/15 09:592.5EPA 6010 Magnesium 1070 mg/kg 03/17/15 09:5930.7EPA 6010 Manganese 69.4 mg/kg 03/17/15 09:590.31EPA 6010 Molybdenum 0.89 mg/kg 03/17/15 09:590.61EPA 6010 Nickel 0.91 mg/kg 03/17/15 09:590.31EPA 6010 Potassium 800 mg/kg 03/17/15 09:5961.5EPA 6010 Sodium 30.9J mg/kg 03/17/15 09:5961.5EPA 6010 Strontium 1.1 mg/kg 03/17/15 09:590.61EPA 6010 Zinc 14.9 mg/kg 03/17/15 09:591.2EPA 6010 Arsenic 1.5 mg/kg 03/17/15 11:53 D31.2EPA 6020 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 94 Page 26 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158002 2015006512 Cobalt 1.6 mg/kg 03/17/15 11:53 D31.2EPA 6020 Lead 4.8 mg/kg 03/17/15 11:53 D31.2EPA 6020 Selenium 0.85J mg/kg 03/17/15 11:53 D31.2EPA 6020 Vanadium 23.8 mg/kg 03/17/15 11:53 D31.2EPA 6020 Percent Moisture 19.2 %03/16/15 15:270.10ASTM D2974-87 pH at 25 Degrees C 6.0 Std. Units 03/12/15 15:550.10EPA 9045 Total Organic Carbon 386J mg/kg 03/13/15 11:32743EPA 9060 Total Organic Carbon 387J mg/kg 03/13/15 11:38747EPA 9060 RSD%5.2 %03/13/15 11:25EPA 9060 92240158003 2015006514 Aluminum 5320 mg/kg 03/17/15 13:58 D334.0EPA 6010 Barium 47.1 mg/kg 03/17/15 13:58 D33.4EPA 6010 Beryllium 0.36 mg/kg 03/17/15 13:58 D30.34EPA 6010 Calcium 313 mg/kg 03/17/15 13:58 D3170EPA 6010 Copper 11.1 mg/kg 03/17/15 13:58 D31.7EPA 6010 Iron 8280 mg/kg 03/17/15 13:58 D313.6EPA 6010 Magnesium 1940 mg/kg 03/17/15 13:58 D3170EPA 6010 Manganese 406 mg/kg 03/17/15 13:58 D31.7EPA 6010 Potassium 1730 mg/kg 03/17/15 13:58 D3340EPA 6010 Strontium 4.2 mg/kg 03/17/15 13:58 D33.4EPA 6010 Zinc 36.3 mg/kg 03/17/15 13:58 D36.8EPA 6010 Arsenic 1.8 mg/kg 03/17/15 11:56 D31.4EPA 6020 Cadmium 0.12J mg/kg 03/17/15 11:56 D30.16EPA 6020 Cobalt 2.8 mg/kg 03/17/15 11:56 D31.4EPA 6020 Lead 5.4 mg/kg 03/17/15 11:56 D31.4EPA 6020 Selenium 1.9 mg/kg 03/17/15 11:56 D31.4EPA 6020 Vanadium 6.8 mg/kg 03/17/15 11:56 D31.4EPA 6020 Percent Moisture 26.5 %03/16/15 15:290.10ASTM D2974-87 pH at 25 Degrees C 6.0 Std. Units 03/12/15 15:550.10EPA 9045 Total Organic Carbon 503J mg/kg 03/13/15 11:49816EPA 9060 Total Organic Carbon 573J mg/kg 03/13/15 11:55813EPA 9060 Total Organic Carbon 484J mg/kg 03/13/15 12:01823EPA 9060 Total Organic Carbon 445J mg/kg 03/13/15 12:06819EPA 9060 Mean Total Organic Carbon 502J mg/kg 03/13/15 11:49818EPA 9060 RSD%10.6 %03/13/15 11:49EPA 9060 92240158004 2015006518 Aluminum 2510 mg/kg 03/17/15 10:076.4EPA 6010 Barium 54.8 mg/kg 03/17/15 10:070.64EPA 6010 Beryllium 0.17 mg/kg 03/17/15 10:070.064EPA 6010 Boron 2.9J mg/kg 03/17/15 10:073.2EPA 6010 Chromium 0.74 mg/kg 03/17/15 10:070.32EPA 6010 Copper 13.1 mg/kg 03/17/15 10:070.32EPA 6010 Iron 3920 mg/kg 03/17/15 10:072.6EPA 6010 Magnesium 816 mg/kg 03/17/15 10:0732.1EPA 6010 Manganese 192 mg/kg 03/17/15 10:070.32EPA 6010 Nickel 0.55 mg/kg 03/17/15 10:070.32EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 94 Page 27 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158004 2015006518 Potassium 801 mg/kg 03/17/15 10:0764.2EPA 6010 Sodium 67.2 mg/kg 03/17/15 10:0764.2EPA 6010 Strontium 4.1 mg/kg 03/17/15 10:070.64EPA 6010 Zinc 14.7 mg/kg 03/17/15 10:071.3EPA 6010 Arsenic 1.2J mg/kg 03/17/15 12:05 D31.3EPA 6020 Cobalt 2.5 mg/kg 03/17/15 12:05 D31.3EPA 6020 Lead 4.2 mg/kg 03/17/15 12:05 D31.3EPA 6020 Selenium 0.90J mg/kg 03/17/15 12:05 D31.3EPA 6020 Vanadium 2.7 mg/kg 03/17/15 12:05 D31.3EPA 6020 Percent Moisture 20.3 %03/16/15 15:290.10ASTM D2974-87 pH at 25 Degrees C 5.9 Std. Units 03/12/15 15:550.10EPA 9045 RSD%4.7 %03/13/15 12:11EPA 9060 92240158005 2015006520 Aluminum 5030 mg/kg 03/17/15 10:125.3EPA 6010 Barium 55.2 mg/kg 03/17/15 10:120.53EPA 6010 Beryllium 0.15 mg/kg 03/17/15 10:120.053EPA 6010 Boron 5.7 mg/kg 03/17/15 10:122.6EPA 6010 Calcium 1420 mg/kg 03/17/15 10:1226.4EPA 6010 Chromium 20.7 mg/kg 03/17/15 10:120.26EPA 6010 Copper 14.0 mg/kg 03/17/15 10:120.26EPA 6010 Iron 8070 mg/kg 03/17/15 10:122.1EPA 6010 Magnesium 3810 mg/kg 03/17/15 10:1226.4EPA 6010 Manganese 348 mg/kg 03/17/15 10:120.26EPA 6010 Molybdenum 1.1 mg/kg 03/17/15 10:120.53EPA 6010 Nickel 7.7 mg/kg 03/17/15 10:120.26EPA 6010 Potassium 2950 mg/kg 03/17/15 10:1252.7EPA 6010 Sodium 104 mg/kg 03/17/15 10:1252.7EPA 6010 Strontium 11.0 mg/kg 03/17/15 10:120.53EPA 6010 Zinc 30.8 mg/kg 03/17/15 10:121.1EPA 6010 Arsenic 0.64J mg/kg 03/17/15 12:07 D31.1EPA 6020 Cadmium 0.094J mg/kg 03/17/15 12:07 D30.13EPA 6020 Cobalt 4.9 mg/kg 03/17/15 12:07 D31.1EPA 6020 Lead 2.4 mg/kg 03/17/15 12:07 D31.1EPA 6020 Vanadium 15.0 mg/kg 03/17/15 12:07 D31.1EPA 6020 Mercury 0.0096 mg/kg 03/17/15 13:360.0087EPA 7471 Percent Moisture 8.5 %03/16/15 15:300.10ASTM D2974-87 pH at 25 Degrees C 8.6 Std. Units 03/12/15 15:550.10EPA 9045 RSD%5.0 %03/13/15 12:35EPA 9060 92240158006 2015006523 Aluminum 7030 mg/kg 03/17/15 10:167.0EPA 6010 Barium 49.6 mg/kg 03/17/15 10:160.70EPA 6010 Beryllium 0.24 mg/kg 03/17/15 10:160.070EPA 6010 Boron 9.6 mg/kg 03/17/15 10:163.5EPA 6010 Calcium 655 mg/kg 03/17/15 10:1635.0EPA 6010 Chromium 15.7 mg/kg 03/17/15 10:160.35EPA 6010 Copper 8.8 mg/kg 03/17/15 10:160.35EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 94 Page 28 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158006 2015006523 Iron 12400 mg/kg 03/17/15 10:162.8EPA 6010 Magnesium 1670 mg/kg 03/17/15 10:1635.0EPA 6010 Manganese 104 mg/kg 03/17/15 10:160.35EPA 6010 Nickel 2.5 mg/kg 03/17/15 10:160.35EPA 6010 Potassium 881 mg/kg 03/17/15 10:1670.1EPA 6010 Sodium 35.4J mg/kg 03/17/15 10:1670.1EPA 6010 Strontium 6.0 mg/kg 03/17/15 10:160.70EPA 6010 Zinc 14.5 mg/kg 03/17/15 10:161.4EPA 6010 Arsenic 1.2J mg/kg 03/17/15 12:10 D31.4EPA 6020 Cobalt 3.7 mg/kg 03/17/15 12:10 D31.4EPA 6020 Lead 9.6 mg/kg 03/17/15 12:10 D31.4EPA 6020 Vanadium 28.3 mg/kg 03/17/15 12:10 D31.4EPA 6020 Mercury 0.033 mg/kg 03/17/15 13:380.011EPA 7471 Percent Moisture 30.6 %03/16/15 15:310.10ASTM D2974-87 pH at 25 Degrees C 6.3 Std. Units 03/12/15 15:550.10EPA 9045 Total Organic Carbon 9710 mg/kg 03/13/15 12:56858EPA 9060 Total Organic Carbon 7400 mg/kg 03/13/15 13:03866EPA 9060 Total Organic Carbon 7310 mg/kg 03/13/15 13:10866EPA 9060 Total Organic Carbon 11800 mg/kg 03/13/15 13:15864EPA 9060 Mean Total Organic Carbon 9060 mg/kg 03/13/15 12:56863EPA 9060 RSD%23.8 %03/13/15 12:56EPA 9060 92240158007 2015006515 Aluminum 3510 mg/kg 03/17/15 14:02 D327.1EPA 6010 Barium 40.9 mg/kg 03/17/15 14:02 D32.7EPA 6010 Beryllium 0.35 mg/kg 03/17/15 14:02 D30.27EPA 6010 Calcium 189 mg/kg 03/17/15 14:02 D3135EPA 6010 Copper 3.9 mg/kg 03/17/15 14:02 D31.4EPA 6010 Iron 6670 mg/kg 03/17/15 14:02 D310.8EPA 6010 Magnesium 1660 mg/kg 03/17/15 14:02 D3135EPA 6010 Manganese 393 mg/kg 03/17/15 14:02 D31.4EPA 6010 Potassium 1550 mg/kg 03/17/15 14:02 D3271EPA 6010 Strontium 5.2 mg/kg 03/17/15 14:02 D32.7EPA 6010 Zinc 31.6 mg/kg 03/17/15 14:02 D35.4EPA 6010 Arsenic 1.1 mg/kg 03/17/15 12:12 D31.1EPA 6020 Cadmium 0.091J mg/kg 03/17/15 12:12 D30.13EPA 6020 Cobalt 1.7 mg/kg 03/17/15 12:12 D31.1EPA 6020 Lead 5.5 mg/kg 03/17/15 12:12 D31.1EPA 6020 Selenium 1.2 mg/kg 03/17/15 12:12 D31.1EPA 6020 Vanadium 5.9 mg/kg 03/17/15 12:12 D31.1EPA 6020 Percent Moisture 9.3 %03/16/15 15:310.10ASTM D2974-87 pH at 25 Degrees C 5.9 Std. Units 03/12/15 15:550.10EPA 9045 Sulfate 3.1 mg/L 03/19/15 21:192.2EPA 300.0 Nitrogen, Nitrate 0.34 mg/L 03/18/15 16:43 B,H10.22EPA 353.2 Total Organic Carbon 364J mg/kg 03/13/15 13:42662EPA 9060 Total Organic Carbon 443J mg/kg 03/13/15 13:48663EPA 9060 Total Organic Carbon 354J mg/kg 03/13/15 13:53662EPA 9060 Total Organic Carbon 360J mg/kg 03/13/15 13:59659EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 94 Page 29 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158007 2015006515 Mean Total Organic Carbon 380J mg/kg 03/13/15 13:42661EPA 9060 RSD%11.1 %03/13/15 13:42EPA 9060 92240158008 2015006516 Aluminum 1480 mg/kg 03/17/15 10:255.5EPA 6010 Barium 22.2 mg/kg 03/17/15 10:250.55EPA 6010 Beryllium 0.50 mg/kg 03/17/15 14:06 D30.27EPA 6010 Calcium 81.4 mg/kg 03/17/15 10:2527.5EPA 6010 Copper 43.8 mg/kg 03/17/15 14:06 D31.4EPA 6010 Iron 5790 mg/kg 03/17/15 10:252.2EPA 6010 Magnesium 368 mg/kg 03/17/15 10:2527.5EPA 6010 Manganese 195 mg/kg 03/17/15 14:06 D31.4EPA 6010 Molybdenum 0.36J mg/kg 03/17/15 10:250.55EPA 6010 Potassium 111 mg/kg 03/17/15 10:2554.9EPA 6010 Sodium 46.7J mg/kg 03/17/15 10:2554.9EPA 6010 Strontium 3.1 mg/kg 03/17/15 10:250.55EPA 6010 Zinc 12.3 mg/kg 03/17/15 10:251.1EPA 6010 Arsenic 1.0J mg/kg 03/17/15 12:14 D31.1EPA 6020 Cobalt 2.2 mg/kg 03/17/15 12:14 D31.1EPA 6020 Lead 11.8 mg/kg 03/17/15 12:14 D31.1EPA 6020 Selenium 0.87J mg/kg 03/17/15 12:14 D31.1EPA 6020 Vanadium 4.8 mg/kg 03/17/15 12:14 D31.1EPA 6020 Percent Moisture 9.5 %03/16/15 15:320.10ASTM D2974-87 pH at 25 Degrees C 6.5 Std. Units 03/12/15 15:550.10EPA 9045 Sulfate 4.1 mg/L 03/19/15 21:322.2EPA 300.0 Nitrogen, Nitrate 0.32 mg/L 03/18/15 16:44 B,H10.22EPA 353.2 RSD%2.8 %03/13/15 14:04EPA 9060 92240158009 2015006521 Aluminum 11800 mg/kg 03/17/15 10:307.5EPA 6010 Barium 51.4 mg/kg 03/17/15 10:300.75EPA 6010 Beryllium 0.26 mg/kg 03/17/15 10:300.075EPA 6010 Boron 12.9 mg/kg 03/17/15 10:303.8EPA 6010 Calcium 208 mg/kg 03/17/15 10:3037.6EPA 6010 Chromium 35.6 mg/kg 03/17/15 10:300.38EPA 6010 Copper 15.5 mg/kg 03/17/15 10:300.38EPA 6010 Iron 18100 mg/kg 03/17/15 10:303.0EPA 6010 Magnesium 4250 mg/kg 03/17/15 10:3037.6EPA 6010 Manganese 120 mg/kg 03/17/15 10:300.38EPA 6010 Nickel 10.9 mg/kg 03/17/15 10:300.38EPA 6010 Potassium 2410 mg/kg 03/17/15 10:3075.2EPA 6010 Sodium 40.9J mg/kg 03/17/15 10:3075.2EPA 6010 Strontium 4.4 mg/kg 03/17/15 10:300.75EPA 6010 Zinc 32.4 mg/kg 03/17/15 10:301.5EPA 6010 Arsenic 1.6 mg/kg 03/17/15 12:16 D31.5EPA 6020 Cobalt 5.2 mg/kg 03/17/15 12:16 D31.5EPA 6020 Lead 8.2 mg/kg 03/17/15 12:16 D31.5EPA 6020 Vanadium 38.4 mg/kg 03/17/15 12:16 D41.5EPA 6020 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 94 Page 30 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158009 2015006521 Percent Moisture 30.3 %03/16/15 15:330.10ASTM D2974-87 pH at 25 Degrees C 4.9 Std. Units 03/12/15 15:550.10EPA 9045 Sulfate 4.0 mg/L 03/19/15 21:462.9EPA 300.0 Chloride 26.1 mg/L 03/19/15 21:097.2SM 4500-Cl-E Total Organic Carbon 4430 mg/kg 03/13/15 14:35859EPA 9060 Total Organic Carbon 2910 mg/kg 03/13/15 14:41863EPA 9060 Total Organic Carbon 2580 mg/kg 03/13/15 14:47868EPA 9060 Total Organic Carbon 2720 mg/kg 03/13/15 14:54858EPA 9060 Mean Total Organic Carbon 3160 mg/kg 03/13/15 14:35862EPA 9060 RSD%27.1 %03/13/15 14:35EPA 9060 92240158010 2015006524 Aluminum 4960 mg/kg 03/17/15 10:476.4EPA 6010 Barium 61.5 mg/kg 03/17/15 10:470.64EPA 6010 Beryllium 0.56 mg/kg 03/17/15 14:11 D30.32EPA 6010 Calcium 270 mg/kg 03/17/15 10:4731.8EPA 6010 Copper 20.6 mg/kg 03/17/15 14:11 D31.6EPA 6010 Iron 8490 mg/kg 03/17/15 10:472.5EPA 6010 Magnesium 2440 mg/kg 03/17/15 10:4731.8EPA 6010 Manganese 678 mg/kg 03/17/15 14:11 D31.6EPA 6010 Potassium 1550 mg/kg 03/17/15 10:4763.6EPA 6010 Sodium 40.7J mg/kg 03/17/15 10:4763.6EPA 6010 Strontium 8.3 mg/kg 03/17/15 10:470.64EPA 6010 Zinc 13.2 mg/kg 03/17/15 14:11 D36.4EPA 6010 Arsenic 1.2J mg/kg 03/17/15 12:19 D31.3EPA 6020 Cobalt 8.9 mg/kg 03/17/15 12:19 D31.3EPA 6020 Lead 2.9 mg/kg 03/17/15 12:19 D31.3EPA 6020 Selenium 1.4 mg/kg 03/17/15 12:19 D31.3EPA 6020 Vanadium 17.8 mg/kg 03/17/15 12:19 D31.3EPA 6020 Percent Moisture 21.6 %03/16/15 15:330.10ASTM D2974-87 pH at 25 Degrees C 5.5 Std. Units 03/12/15 15:550.10EPA 9045 Sulfate 3.0 mg/L 03/19/15 21:592.5EPA 300.0 Nitrogen, Nitrate 0.38 mg/L 03/18/15 16:49 H10.25EPA 353.2 Total Organic Carbon 433J mg/kg 03/13/15 14:59768EPA 9060 Mean Total Organic Carbon 385J mg/kg 03/13/15 14:59764EPA 9060 RSD%8.5 %03/13/15 14:59EPA 9060 92240158011 2015006513 Aluminum 46.7 ug/L 03/13/15 20:2410.0EPA 6020A Barium 4.4 ug/L 03/13/15 20:240.30EPA 6020A Calcium 160 ug/L 03/13/15 20:2440.0EPA 6020A Chromium 5.9 ug/L 03/13/15 20:240.50EPA 6020A Iron 451 ug/L 03/13/15 20:2450.0EPA 6020A Lead 0.28 ug/L 03/13/15 20:240.10EPA 6020A Magnesium 17.4 ug/L 03/13/15 20:2410.0EPA 6020A Manganese 6.4 ug/L 03/13/15 20:240.50EPA 6020A Molybdenum 2.1 ug/L 03/13/15 20:240.50EPA 6020A Nickel 1.8 ug/L 03/13/15 20:240.50EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 94 Page 31 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158011 2015006513 Strontium 1.8 ug/L 03/13/15 20:240.50EPA 6020A Zinc 34.2 ug/L 03/13/15 20:245.0EPA 6020A 92240158012 2015006517 Aluminum 23.0 ug/L 03/13/15 20:2910.0EPA 6020A Barium 1.1 ug/L 03/13/15 20:290.30EPA 6020A Calcium 136 ug/L 03/13/15 20:2940.0EPA 6020A Chromium 1.3 ug/L 03/13/15 20:290.50EPA 6020A Iron 139 ug/L 03/13/15 20:2950.0EPA 6020A Lead 0.12 ug/L 03/13/15 20:290.10EPA 6020A Magnesium 12.2 ug/L 03/13/15 20:2910.0EPA 6020A Manganese 3.5 ug/L 03/13/15 20:290.50EPA 6020A Molybdenum 0.68 ug/L 03/13/15 20:290.50EPA 6020A Nickel 0.66 ug/L 03/13/15 20:290.50EPA 6020A Strontium 1.0 ug/L 03/13/15 20:290.50EPA 6020A 92240158013 2015006519 Aluminum 18.8 ug/L 03/13/15 20:3410.0EPA 6020A Barium 1.0 ug/L 03/13/15 20:340.30EPA 6020A Calcium 98.9 ug/L 03/13/15 20:3440.0EPA 6020A Chromium 1.9 ug/L 03/13/15 20:340.50EPA 6020A Iron 173 ug/L 03/13/15 20:3450.0EPA 6020A Lead 0.26 ug/L 03/13/15 20:340.10EPA 6020A Manganese 4.3 ug/L 03/13/15 20:340.50EPA 6020A Molybdenum 0.67 ug/L 03/13/15 20:340.50EPA 6020A Nickel 0.98 ug/L 03/13/15 20:340.50EPA 6020A Strontium 0.66 ug/L 03/13/15 20:340.50EPA 6020A Zinc 7.2 ug/L 03/13/15 20:345.0EPA 6020A 92240158014 2015006522 Aluminum 49.3 ug/L 03/13/15 20:3810.0EPA 6020A Barium 2.0 ug/L 03/13/15 20:380.30EPA 6020A Calcium 132 ug/L 03/13/15 20:3840.0EPA 6020A Chromium 5.1 ug/L 03/13/15 20:380.50EPA 6020A Copper 1.1 ug/L 03/13/15 20:381.0EPA 6020A Iron 495 ug/L 03/13/15 20:3850.0EPA 6020A Lead 0.36 ug/L 03/13/15 20:380.10EPA 6020A Magnesium 16.5 ug/L 03/13/15 20:3810.0EPA 6020A Manganese 7.9 ug/L 03/13/15 20:380.50EPA 6020A Molybdenum 1.1 ug/L 03/13/15 20:380.50EPA 6020A Nickel 2.3 ug/L 03/13/15 20:380.50EPA 6020A Sodium 50.6 ug/L 03/13/15 20:3850.0EPA 6020A Strontium 1.2 ug/L 03/13/15 20:380.50EPA 6020A Zinc 18.3 ug/L 03/13/15 20:385.0EPA 6020A 92240158015 2015006525 Aluminum 180 ug/L 03/13/15 20:4310.0EPA 6020A Barium 4.8 ug/L 03/13/15 20:430.30EPA 6020A Calcium 308 ug/L 03/13/15 20:4340.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 94 Page 32 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158015 2015006525 Chromium 33.7 ug/L 03/13/15 20:430.50EPA 6020A Copper 4.6 ug/L 03/13/15 20:431.0EPA 6020A Iron 1360 ug/L 03/13/15 20:4350.0EPA 6020A Lead 0.40 ug/L 03/13/15 20:430.10EPA 6020A Magnesium 76.3 ug/L 03/13/15 20:4310.0EPA 6020A Manganese 18.7 ug/L 03/13/15 20:430.50EPA 6020A Molybdenum 4.1 ug/L 03/13/15 20:430.50EPA 6020A Nickel 4.6 ug/L 03/13/15 20:430.50EPA 6020A Potassium 109 ug/L 03/13/15 20:4350.0EPA 6020A Sodium 118 ug/L 03/13/15 20:4350.0EPA 6020A Strontium 2.3 ug/L 03/13/15 20:430.50EPA 6020A Vanadium 4.5 ug/L 03/13/15 20:431.0EPA 6020A Zinc 12.1 ug/L 03/13/15 20:435.0EPA 6020A 92240158016 2015006515 SPLP Aluminum 3590 ug/L 03/27/15 14:2510.0EPA 6020A Arsenic 0.76 ug/L 03/27/15 14:250.50EPA 6020A Barium 34.5 ug/L 03/27/15 14:250.30EPA 6020A Beryllium 0.27 ug/L 03/27/15 14:250.20EPA 6020A Boron 9.9 ug/L 03/27/15 14:255.0EPA 6020A Calcium 966 ug/L 03/27/15 14:2540.0EPA 6020A Chromium 1.7 ug/L 03/27/15 14:250.50EPA 6020A Copper 1.7 ug/L 03/27/15 14:251.0EPA 6020A Iron 1270 ug/L 03/27/15 14:2550.0EPA 6020A Lead 1.1 ug/L 03/27/15 14:250.10EPA 6020A Magnesium 306 ug/L 03/27/15 14:2510.0EPA 6020A Manganese 64.8 ug/L 03/27/15 14:250.50EPA 6020A Nickel 0.91 ug/L 03/27/15 14:250.50EPA 6020A Potassium 931 ug/L 03/27/15 14:2550.0EPA 6020A Sodium 2920 ug/L 03/27/15 14:2550.0EPA 6020A Strontium 13.6 ug/L 03/27/15 14:250.50EPA 6020A Vanadium 1.9 ug/L 03/27/15 14:251.0EPA 6020A Zinc 5.4 ug/L 03/27/15 14:255.0EPA 6020A 92240158017 2015006516 SPLP Aluminum 195 ug/L 03/27/15 14:2810.0EPA 6020A Barium 1.7 ug/L 03/27/15 14:280.30EPA 6020A Boron 72.0 ug/L 03/27/15 14:285.0EPA 6020A Calcium 202 ug/L 03/27/15 14:2840.0EPA 6020A Chromium 0.90 ug/L 03/27/15 14:280.50EPA 6020A Iron 73.0 ug/L 03/27/15 14:2850.0EPA 6020A Magnesium 215 ug/L 03/27/15 14:2810.0EPA 6020A Manganese 3.2 ug/L 03/27/15 14:280.50EPA 6020A Potassium 696 ug/L 03/27/15 14:2850.0EPA 6020A Sodium 5620 ug/L 03/27/15 14:2850.0EPA 6020A Strontium 1.4 ug/L 03/27/15 14:280.50EPA 6020A 92240158018 2015006521 SPLP Aluminum 132000 ug/L 03/27/15 14:46250EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 94 Page 33 of 113 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92240158 J15030202 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92240158018 2015006521 SPLP Arsenic 12.3 ug/L 03/27/15 14:312.5EPA 6020A Barium 377 ug/L 03/27/15 14:311.5EPA 6020A Beryllium 2.6 ug/L 03/27/15 14:311.0EPA 6020A Boron 75.8 ug/L 03/27/15 14:3125.0EPA 6020A Calcium 2170 ug/L 03/27/15 14:31200EPA 6020A Chromium 269 ug/L 03/27/15 14:312.5EPA 6020A Cobalt 24.3 ug/L 03/27/15 14:312.5EPA 6020A Copper 112 ug/L 03/27/15 14:315.0EPA 6020A Iron 109000 ug/L 03/27/15 14:31250EPA 6020A Lead 62.1 ug/L 03/27/15 14:310.50EPA 6020A Magnesium 6500 ug/L 03/27/15 14:3150.0EPA 6020A Manganese 250 ug/L 03/27/15 14:312.5EPA 6020A Molybdenum 2.7 ug/L 03/27/15 14:312.5EPA 6020A Nickel 48.6 ug/L 03/27/15 14:312.5EPA 6020A Potassium 5200 ug/L 03/27/15 14:31250EPA 6020A Sodium 4560 ug/L 03/27/15 14:31250EPA 6020A Strontium 38.2 ug/L 03/27/15 14:312.5EPA 6020A Thallium 0.60 ug/L 03/27/15 14:310.50EPA 6020A Vanadium 277 ug/L 03/27/15 14:315.0EPA 6020A Zinc 132 ug/L 03/27/15 14:3125.0EPA 6020A 92240158019 2015006524 SPLP Aluminum 3030 ug/L 03/27/15 14:3410.0EPA 6020A Barium 38.8 ug/L 03/27/15 14:340.30EPA 6020A Beryllium 0.30 ug/L 03/27/15 14:340.20EPA 6020A Boron 18.1 ug/L 03/27/15 14:345.0EPA 6020A Calcium 407 ug/L 03/27/15 14:3440.0EPA 6020A Chromium 1.1 ug/L 03/27/15 14:340.50EPA 6020A Cobalt 2.5 ug/L 03/27/15 14:340.50EPA 6020A Copper 4.4 ug/L 03/27/15 14:341.0EPA 6020A Iron 3140 ug/L 03/27/15 14:3450.0EPA 6020A Lead 0.69 ug/L 03/27/15 14:340.10EPA 6020A Magnesium 175 ug/L 03/27/15 14:3410.0EPA 6020A Manganese 313 ug/L 03/27/15 14:340.50EPA 6020A Nickel 0.57 ug/L 03/27/15 14:340.50EPA 6020A Potassium 414 ug/L 03/27/15 14:3450.0EPA 6020A Sodium 2300 ug/L 03/27/15 14:3450.0EPA 6020A Strontium 12.1 ug/L 03/27/15 14:340.50EPA 6020A Vanadium 7.0 ug/L 03/27/15 14:341.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 94 Page 34 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6010 Date:March 30, 2015 Description:6010 MET ICP General Information: 10 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23094 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1157067) • Aluminum • Iron • MSD (Lab ID: 1157068) • Aluminum • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1157068) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 94 Page 35 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6010 Date:March 30, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/23094 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006511 (Lab ID: 92240158001) • Boron • Beryllium • Chromium • Copper • Manganese • 2015006514 (Lab ID: 92240158003) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • 2015006515 (Lab ID: 92240158007) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • 2015006516 (Lab ID: 92240158008) • Boron • Beryllium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 94 Page 36 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6010 Date:March 30, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/23094 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006516 (Lab ID: 92240158008) • Chromium • Copper • Manganese • 2015006524 (Lab ID: 92240158010) • Boron • Beryllium • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 94 Page 37 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020 Date:March 30, 2015 Description:6020 MET ICPMS General Information: 10 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23095 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1157071) • Antimony • Arsenic • Cobalt • Vanadium • MSD (Lab ID: 1157072) • Antimony • Arsenic • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 94 Page 38 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020 Date:March 30, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23095 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006511 (Lab ID: 92240158001) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • 2015006512 (Lab ID: 92240158002) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015006514 (Lab ID: 92240158003) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015006515 (Lab ID: 92240158007) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015006516 (Lab ID: 92240158008) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 94 Page 39 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020 Date:March 30, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23095 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006516 (Lab ID: 92240158008) • Vanadium • 2015006518 (Lab ID: 92240158004) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015006520 (Lab ID: 92240158005) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015006521 (Lab ID: 92240158009) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • 2015006523 (Lab ID: 92240158006) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015006524 (Lab ID: 92240158010) • Arsenic • Cadmium • Cobalt • Lead • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 94 Page 40 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020 Date:March 30, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23095 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006524 (Lab ID: 92240158010) • Selenium • Thallium • Vanadium • MS (Lab ID: 1157071) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MSD (Lab ID: 1157072) • Arsenic • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. • 2015006511 (Lab ID: 92240158001) • Vanadium • 2015006521 (Lab ID: 92240158009) • Vanadium • MS (Lab ID: 1157071) • Vanadium • MSD (Lab ID: 1157072) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. • 2015006511 (Lab ID: 92240158001) • Antimony • 2015006512 (Lab ID: 92240158002) • Antimony • 2015006514 (Lab ID: 92240158003) • Antimony • 2015006515 (Lab ID: 92240158007) • Antimony • 2015006516 (Lab ID: 92240158008) • Antimony • 2015006518 (Lab ID: 92240158004) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 94 Page 41 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020 Date:March 30, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23095 N2: The lab does not hold TNI accreditation for this parameter. • 2015006520 (Lab ID: 92240158005) • Antimony • 2015006521 (Lab ID: 92240158009) • Antimony • 2015006523 (Lab ID: 92240158006) • Antimony • 2015006524 (Lab ID: 92240158010) • Antimony • BLANK (Lab ID: 1157069) • Antimony • LCS (Lab ID: 1157070) • Antimony • MS (Lab ID: 1157071) • Antimony • MSD (Lab ID: 1157072) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 94 Page 42 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020A Date:March 30, 2015 Description:6020A MET ICPMS General Information: 9 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52931 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92240320006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1917522) • Aluminum • Calcium • Sodium • MSD (Lab ID: 1917523) • Aluminum QC Batch: MPRP/53205 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1926431) • Aluminum • MSD (Lab ID: 1926432) • Aluminum REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 94 Page 43 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 6020A Date:March 30, 2015 Description:6020A MET ICPMS QC Batch: MPRP/53205 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1926432) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 94 Page 44 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 7470 Date:March 30, 2015 Description:7470 Mercury General Information: 9 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/13071 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242374012 R1: RPD value was outside control limits. • MSD (Lab ID: 1926033) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 94 Page 45 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 7471 Date:March 30, 2015 Description:7471 Mercury General Information: 10 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5474 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1157679) • Mercury • MSD (Lab ID: 1157680) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 94 Page 46 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 9045 Date:March 30, 2015 Description:9045 pH Soil General Information: 10 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 94 Page 47 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 300.0 Date:March 30, 2015 Description:300.0 IC Anions, SPLP General Information: 4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 94 Page 48 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 353.2 Date:March 30, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015006515 (Lab ID: 92240158007) • 2015006516 (Lab ID: 92240158008) • 2015006521 (Lab ID: 92240158009) • 2015006524 (Lab ID: 92240158010) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22256 B: Analyte was detected in the associated method blank. • BLANK for HBN 256042 [WETA/222 (Lab ID: 1413768) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 94 Page 49 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy SM 4500-Cl-E Date:March 30, 2015 Description:4500 Chloride, SPLP General Information: 4 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 94 Page 50 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 9056 Date:March 30, 2015 Description:9056 IC Anions General Information: 10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44508 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006511 (Lab ID: 92240158001) • Chloride • Sulfate • 2015006512 (Lab ID: 92240158002) • Chloride • Sulfate • 2015006514 (Lab ID: 92240158003) • Chloride • Sulfate • 2015006518 (Lab ID: 92240158004) • Chloride • Sulfate QC Batch: WETA/44515 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006521 (Lab ID: 92240158009) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 94 Page 51 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 9056 Date:March 30, 2015 Description:9056 IC Anions Analyte Comments: QC Batch: WETA/44515 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006524 (Lab ID: 92240158010) • Chloride • Sulfate QC Batch: WETA/44533 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006515 (Lab ID: 92240158007) • Chloride • Sulfate • 2015006516 (Lab ID: 92240158008) • Chloride • Sulfate • 2015006520 (Lab ID: 92240158005) • Chloride • Sulfate • 2015006523 (Lab ID: 92240158006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 94 Page 52 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 9056 Date:March 30, 2015 Description:9056 IC Anions 48hr General Information: 10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015006511 (Lab ID: 92240158001) • 2015006512 (Lab ID: 92240158002) • 2015006514 (Lab ID: 92240158003) • 2015006515 (Lab ID: 92240158007) • 2015006516 (Lab ID: 92240158008) • 2015006518 (Lab ID: 92240158004) • 2015006520 (Lab ID: 92240158005) • 2015006521 (Lab ID: 92240158009) • 2015006523 (Lab ID: 92240158006) • 2015006524 (Lab ID: 92240158010) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44509 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006511 (Lab ID: 92240158001) • Nitrate as N • 2015006512 (Lab ID: 92240158002) • Nitrate as N • 2015006514 (Lab ID: 92240158003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 94 Page 53 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 9056 Date:March 30, 2015 Description:9056 IC Anions 48hr Analyte Comments: QC Batch: WETA/44509 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006518 (Lab ID: 92240158004) • Nitrate as N QC Batch: WETA/44514 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006521 (Lab ID: 92240158009) • Nitrate as N • 2015006524 (Lab ID: 92240158010) • Nitrate as N QC Batch: WETA/44534 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015006515 (Lab ID: 92240158007) • Nitrate as N • 2015006516 (Lab ID: 92240158008) • Nitrate as N • 2015006520 (Lab ID: 92240158005) • Nitrate as N • 2015006523 (Lab ID: 92240158006) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 94 Page 54 of 113 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92240158 J15030202 Method: Client:Duke Energy EPA 9060 Date:March 30, 2015 Description:Total Organic Carbon Quad General Information: 10 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 94 Page 55 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006511 Lab ID:92240158001 Collected:03/03/15 15:24 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 10200 mg/kg 03/17/15 09:54 7429-90-503/16/15 12:278.0 4.0 1 Barium 65.7 mg/kg 03/17/15 09:54 7440-39-303/16/15 12:270.80 0.40 1 Beryllium 0.52 mg/kg 03/17/15 13:53 7440-41-7 D303/16/15 12:270.40 0.20 5 Boron 16.3J mg/kg 03/17/15 13:53 7440-42-8 D303/16/15 12:2719.9 10 5 Calcium 227 mg/kg 03/17/15 09:54 7440-70-203/16/15 12:2739.9 19.9 1 Chromium 12.9 mg/kg 03/17/15 13:53 7440-47-3 D303/16/15 12:272.0 1.0 5 Copper 22.8 mg/kg 03/17/15 13:53 7440-50-8 D303/16/15 12:272.0 1.0 5 Iron 18300 mg/kg 03/17/15 09:54 7439-89-603/16/15 12:273.2 1.6 1 Magnesium 2420 mg/kg 03/17/15 09:54 7439-95-403/16/15 12:2739.9 19.9 1 Manganese 365 mg/kg 03/17/15 13:53 7439-96-5 D303/16/15 12:272.0 1.0 5 Molybdenum ND mg/kg 03/17/15 09:54 7439-98-703/16/15 12:270.80 0.40 1 Nickel 1.7 mg/kg 03/17/15 09:54 7440-02-003/16/15 12:270.40 0.20 1 Potassium 2020 mg/kg 03/17/15 09:54 7440-09-703/16/15 12:2779.8 39.9 1 Sodium ND mg/kg 03/17/15 09:54 7440-23-503/16/15 12:2779.8 39.9 1 Strontium 4.3 mg/kg 03/17/15 09:54 7440-24-603/16/15 12:270.80 0.40 1 Zinc 27.3 mg/kg 03/17/15 09:54 7440-66-603/16/15 12:271.6 0.80 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 11:51 7440-36-0 D3,N203/16/15 12:271.6 0.80 20 Arsenic 1.9 mg/kg 03/17/15 11:51 7440-38-2 D303/16/15 12:271.6 0.80 20 Cadmium 0.13J mg/kg 03/17/15 11:51 7440-43-9 D303/16/15 12:270.19 0.096 20 Cobalt 6.4 mg/kg 03/17/15 11:51 7440-48-4 D303/16/15 12:271.6 0.80 20 Lead 7.5 mg/kg 03/17/15 11:51 7439-92-1 D303/16/15 12:271.6 0.80 20 Selenium 1.3J mg/kg 03/17/15 11:51 7782-49-2 D303/16/15 12:271.6 0.80 20 Thallium ND mg/kg 03/17/15 11:51 7440-28-0 D303/16/15 12:271.6 0.80 20 Vanadium 44.8 mg/kg 03/17/15 11:51 7440-62-2 D403/16/15 12:271.6 0.80 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.020 mg/kg 03/17/15 13:27 7439-97-603/17/15 06:130.012 0.0060 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 35.5 %03/16/15 15:260.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.3 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/13/15 16:38 16887-00-6 D33921965 Sulfate ND mg/kg 03/13/15 16:38 14808-79-8 D33921965 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/13/15 16:38 14797-55-8 D3,H339.2 19.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 94 Page 56 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006511 Lab ID:92240158001 Collected:03/03/15 15:24 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 3450 mg/kg 03/13/15 10:12 7440-44-09284641 Total Organic Carbon 3640 mg/kg 03/13/15 10:17 7440-44-09294651 Total Organic Carbon 3880 mg/kg 03/13/15 10:23 7440-44-09224611 Total Organic Carbon 4020 mg/kg 03/13/15 10:29 7440-44-09354671 Mean Total Organic Carbon 3750 mg/kg 03/13/15 10:12 7440-44-09294641 Surrogates RSD%6.7 %03/13/15 10:121 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 94 Page 57 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006512 Lab ID:92240158002 Collected:03/03/15 15:52 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 5930 mg/kg 03/17/15 09:59 7429-90-503/16/15 12:276.1 3.1 1 Barium 31.3 mg/kg 03/17/15 09:59 7440-39-303/16/15 12:270.61 0.31 1 Beryllium 0.39 mg/kg 03/17/15 09:59 7440-41-703/16/15 12:270.061 0.031 1 Boron 7.8 mg/kg 03/17/15 09:59 7440-42-803/16/15 12:273.1 1.5 1 Calcium 22.2J mg/kg 03/17/15 09:59 7440-70-203/16/15 12:2730.7 15.4 1 Chromium 10.8 mg/kg 03/17/15 09:59 7440-47-303/16/15 12:270.31 0.15 1 Copper 5.5 mg/kg 03/17/15 09:59 7440-50-803/16/15 12:270.31 0.15 1 Iron 10300 mg/kg 03/17/15 09:59 7439-89-603/16/15 12:272.5 1.2 1 Magnesium 1070 mg/kg 03/17/15 09:59 7439-95-403/16/15 12:2730.7 15.4 1 Manganese 69.4 mg/kg 03/17/15 09:59 7439-96-503/16/15 12:270.31 0.15 1 Molybdenum 0.89 mg/kg 03/17/15 09:59 7439-98-703/16/15 12:270.61 0.31 1 Nickel 0.91 mg/kg 03/17/15 09:59 7440-02-003/16/15 12:270.31 0.15 1 Potassium 800 mg/kg 03/17/15 09:59 7440-09-703/16/15 12:2761.5 30.7 1 Sodium 30.9J mg/kg 03/17/15 09:59 7440-23-503/16/15 12:2761.5 30.7 1 Strontium 1.1 mg/kg 03/17/15 09:59 7440-24-603/16/15 12:270.61 0.31 1 Zinc 14.9 mg/kg 03/17/15 09:59 7440-66-603/16/15 12:271.2 0.61 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 11:53 7440-36-0 D3,N203/16/15 12:271.2 0.61 20 Arsenic 1.5 mg/kg 03/17/15 11:53 7440-38-2 D303/16/15 12:271.2 0.61 20 Cadmium ND mg/kg 03/17/15 11:53 7440-43-9 D303/16/15 12:270.15 0.074 20 Cobalt 1.6 mg/kg 03/17/15 11:53 7440-48-4 D303/16/15 12:271.2 0.61 20 Lead 4.8 mg/kg 03/17/15 11:53 7439-92-1 D303/16/15 12:271.2 0.61 20 Selenium 0.85J mg/kg 03/17/15 11:53 7782-49-2 D303/16/15 12:271.2 0.61 20 Thallium ND mg/kg 03/17/15 11:53 7440-28-0 D303/16/15 12:271.2 0.61 20 Vanadium 23.8 mg/kg 03/17/15 11:53 7440-62-2 D303/16/15 12:271.2 0.61 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:29 7439-97-603/17/15 06:130.0096 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.2 %03/16/15 15:270.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.0 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/13/15 17:00 16887-00-6 D33091555 Sulfate ND mg/kg 03/13/15 17:00 14808-79-8 D33091555 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/13/15 17:00 14797-55-8 D3,H330.9 15.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 94 Page 58 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006512 Lab ID:92240158002 Collected:03/03/15 15:52 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 03/13/15 11:25 7440-44-07493751 Total Organic Carbon 386J mg/kg 03/13/15 11:32 7440-44-07433711 Total Organic Carbon 387J mg/kg 03/13/15 11:38 7440-44-07473731 Total Organic Carbon ND mg/kg 03/13/15 11:44 7440-44-07483741 Mean Total Organic Carbon ND mg/kg 03/13/15 11:25 7440-44-07473731 Surrogates RSD%5.2 %03/13/15 11:251 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 94 Page 59 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006514 Lab ID:92240158003 Collected:03/04/15 10:15 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 5320 mg/kg 03/17/15 13:58 7429-90-5 D303/16/15 12:2734.0 17.0 5 Barium 47.1 mg/kg 03/17/15 13:58 7440-39-3 D303/16/15 12:273.4 1.7 5 Beryllium 0.36 mg/kg 03/17/15 13:58 7440-41-7 D303/16/15 12:270.34 0.17 5 Boron ND mg/kg 03/17/15 13:58 7440-42-8 D303/16/15 12:2717.0 8.5 5 Calcium 313 mg/kg 03/17/15 13:58 7440-70-2 D303/16/15 12:2717085.1 5 Chromium ND mg/kg 03/17/15 13:58 7440-47-3 D303/16/15 12:271.7 0.85 5 Copper 11.1 mg/kg 03/17/15 13:58 7440-50-8 D303/16/15 12:271.7 0.85 5 Iron 8280 mg/kg 03/17/15 13:58 7439-89-6 D303/16/15 12:2713.6 6.8 5 Magnesium 1940 mg/kg 03/17/15 13:58 7439-95-4 D303/16/15 12:2717085.1 5 Manganese 406 mg/kg 03/17/15 13:58 7439-96-5 D303/16/15 12:271.7 0.85 5 Molybdenum ND mg/kg 03/17/15 13:58 7439-98-7 D303/16/15 12:273.4 1.7 5 Nickel ND mg/kg 03/17/15 13:58 7440-02-0 D303/16/15 12:271.7 0.85 5 Potassium 1730 mg/kg 03/17/15 13:58 7440-09-7 D303/16/15 12:273401705 Sodium ND mg/kg 03/17/15 13:58 7440-23-5 D303/16/15 12:273401705 Strontium 4.2 mg/kg 03/17/15 13:58 7440-24-6 D303/16/15 12:273.4 1.7 5 Zinc 36.3 mg/kg 03/17/15 13:58 7440-66-6 D303/16/15 12:276.8 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 11:56 7440-36-0 D3,N203/16/15 12:271.4 0.68 20 Arsenic 1.8 mg/kg 03/17/15 11:56 7440-38-2 D303/16/15 12:271.4 0.68 20 Cadmium 0.12J mg/kg 03/17/15 11:56 7440-43-9 D303/16/15 12:270.16 0.082 20 Cobalt 2.8 mg/kg 03/17/15 11:56 7440-48-4 D303/16/15 12:271.4 0.68 20 Lead 5.4 mg/kg 03/17/15 11:56 7439-92-1 D303/16/15 12:271.4 0.68 20 Selenium 1.9 mg/kg 03/17/15 11:56 7782-49-2 D303/16/15 12:271.4 0.68 20 Thallium ND mg/kg 03/17/15 11:56 7440-28-0 D303/16/15 12:271.4 0.68 20 Vanadium 6.8 mg/kg 03/17/15 11:56 7440-62-2 D303/16/15 12:271.4 0.68 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:31 7439-97-603/17/15 06:130.011 0.0054 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.5 %03/16/15 15:290.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.0 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/13/15 17:22 16887-00-6 D33461735 Sulfate ND mg/kg 03/13/15 17:22 14808-79-8 D33461735 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/13/15 17:22 14797-55-8 D3,H334.6 17.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 94 Page 60 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006514 Lab ID:92240158003 Collected:03/04/15 10:15 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 503J mg/kg 03/13/15 11:49 7440-44-08164081 Total Organic Carbon 573J mg/kg 03/13/15 11:55 7440-44-08134061 Total Organic Carbon 484J mg/kg 03/13/15 12:01 7440-44-08234121 Total Organic Carbon 445J mg/kg 03/13/15 12:06 7440-44-08194101 Mean Total Organic Carbon 502J mg/kg 03/13/15 11:49 7440-44-08184091 Surrogates RSD%10.6 %03/13/15 11:491 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 94 Page 61 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006518 Lab ID:92240158004 Collected:03/04/15 13:10 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 2510 mg/kg 03/17/15 10:07 7429-90-503/16/15 12:276.4 3.2 1 Barium 54.8 mg/kg 03/17/15 10:07 7440-39-303/16/15 12:270.64 0.32 1 Beryllium 0.17 mg/kg 03/17/15 10:07 7440-41-703/16/15 12:270.064 0.032 1 Boron 2.9J mg/kg 03/17/15 10:07 7440-42-803/16/15 12:273.2 1.6 1 Calcium ND mg/kg 03/17/15 10:07 7440-70-203/16/15 12:2732.1 16.1 1 Chromium 0.74 mg/kg 03/17/15 10:07 7440-47-303/16/15 12:270.32 0.16 1 Copper 13.1 mg/kg 03/17/15 10:07 7440-50-803/16/15 12:270.32 0.16 1 Iron 3920 mg/kg 03/17/15 10:07 7439-89-603/16/15 12:272.6 1.3 1 Magnesium 816 mg/kg 03/17/15 10:07 7439-95-403/16/15 12:2732.1 16.1 1 Manganese 192 mg/kg 03/17/15 10:07 7439-96-503/16/15 12:270.32 0.16 1 Molybdenum ND mg/kg 03/17/15 10:07 7439-98-703/16/15 12:270.64 0.32 1 Nickel 0.55 mg/kg 03/17/15 10:07 7440-02-003/16/15 12:270.32 0.16 1 Potassium 801 mg/kg 03/17/15 10:07 7440-09-703/16/15 12:2764.2 32.1 1 Sodium 67.2 mg/kg 03/17/15 10:07 7440-23-503/16/15 12:2764.2 32.1 1 Strontium 4.1 mg/kg 03/17/15 10:07 7440-24-603/16/15 12:270.64 0.32 1 Zinc 14.7 mg/kg 03/17/15 10:07 7440-66-603/16/15 12:271.3 0.64 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:05 7440-36-0 D3,N203/16/15 12:271.3 0.63 20 Arsenic 1.2J mg/kg 03/17/15 12:05 7440-38-2 D303/16/15 12:271.3 0.63 20 Cadmium ND mg/kg 03/17/15 12:05 7440-43-9 D303/16/15 12:270.15 0.075 20 Cobalt 2.5 mg/kg 03/17/15 12:05 7440-48-4 D303/16/15 12:271.3 0.63 20 Lead 4.2 mg/kg 03/17/15 12:05 7439-92-1 D303/16/15 12:271.3 0.63 20 Selenium 0.90J mg/kg 03/17/15 12:05 7782-49-2 D303/16/15 12:271.3 0.63 20 Thallium ND mg/kg 03/17/15 12:05 7440-28-0 D303/16/15 12:271.3 0.63 20 Vanadium 2.7 mg/kg 03/17/15 12:05 7440-62-2 D303/16/15 12:271.3 0.63 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:33 7439-97-603/17/15 06:130.0093 0.0046 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 20.3 %03/16/15 15:290.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.9 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/13/15 17:44 16887-00-6 D33091545 Sulfate ND mg/kg 03/13/15 17:44 14808-79-8 D33091545 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/13/15 17:44 14797-55-8 D3,H330.9 15.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 94 Page 62 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006518 Lab ID:92240158004 Collected:03/04/15 13:10 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 03/13/15 12:11 7440-44-07563781 Total Organic Carbon ND mg/kg 03/13/15 12:17 7440-44-07583791 Total Organic Carbon ND mg/kg 03/13/15 12:23 7440-44-07483741 Total Organic Carbon ND mg/kg 03/13/15 12:29 7440-44-07533771 Mean Total Organic Carbon ND mg/kg 03/13/15 12:11 7440-44-07543771 Surrogates RSD%4.7 %03/13/15 12:111 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 94 Page 63 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006520 Lab ID:92240158005 Collected:03/04/15 14:47 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 5030 mg/kg 03/17/15 10:12 7429-90-503/16/15 12:275.3 2.6 1 Barium 55.2 mg/kg 03/17/15 10:12 7440-39-303/16/15 12:270.53 0.26 1 Beryllium 0.15 mg/kg 03/17/15 10:12 7440-41-703/16/15 12:270.053 0.026 1 Boron 5.7 mg/kg 03/17/15 10:12 7440-42-803/16/15 12:272.6 1.3 1 Calcium 1420 mg/kg 03/17/15 10:12 7440-70-203/16/15 12:2726.4 13.2 1 Chromium 20.7 mg/kg 03/17/15 10:12 7440-47-303/16/15 12:270.26 0.13 1 Copper 14.0 mg/kg 03/17/15 10:12 7440-50-803/16/15 12:270.26 0.13 1 Iron 8070 mg/kg 03/17/15 10:12 7439-89-603/16/15 12:272.1 1.1 1 Magnesium 3810 mg/kg 03/17/15 10:12 7439-95-403/16/15 12:2726.4 13.2 1 Manganese 348 mg/kg 03/17/15 10:12 7439-96-503/16/15 12:270.26 0.13 1 Molybdenum 1.1 mg/kg 03/17/15 10:12 7439-98-703/16/15 12:270.53 0.26 1 Nickel 7.7 mg/kg 03/17/15 10:12 7440-02-003/16/15 12:270.26 0.13 1 Potassium 2950 mg/kg 03/17/15 10:12 7440-09-703/16/15 12:2752.7 26.4 1 Sodium 104 mg/kg 03/17/15 10:12 7440-23-503/16/15 12:2752.7 26.4 1 Strontium 11.0 mg/kg 03/17/15 10:12 7440-24-603/16/15 12:270.53 0.26 1 Zinc 30.8 mg/kg 03/17/15 10:12 7440-66-603/16/15 12:271.1 0.53 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:07 7440-36-0 D3,N203/16/15 12:271.1 0.53 20 Arsenic 0.64J mg/kg 03/17/15 12:07 7440-38-2 D303/16/15 12:271.1 0.53 20 Cadmium 0.094J mg/kg 03/17/15 12:07 7440-43-9 D303/16/15 12:270.13 0.063 20 Cobalt 4.9 mg/kg 03/17/15 12:07 7440-48-4 D303/16/15 12:271.1 0.53 20 Lead 2.4 mg/kg 03/17/15 12:07 7439-92-1 D303/16/15 12:271.1 0.53 20 Selenium ND mg/kg 03/17/15 12:07 7782-49-2 D303/16/15 12:271.1 0.53 20 Thallium ND mg/kg 03/17/15 12:07 7440-28-0 D303/16/15 12:271.1 0.53 20 Vanadium 15.0 mg/kg 03/17/15 12:07 7440-62-2 D303/16/15 12:271.1 0.53 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0096 mg/kg 03/17/15 13:36 7439-97-603/17/15 06:130.0087 0.0044 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 8.5 %03/16/15 15:300.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.6 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/14/15 19:08 16887-00-6 D32721365 Sulfate ND mg/kg 03/14/15 19:08 14808-79-8 D32721365 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/14/15 19:08 14797-55-8 D3,H327.2 13.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 94 Page 64 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006520 Lab ID:92240158005 Collected:03/04/15 14:47 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 03/13/15 12:35 7440-44-06603301 Total Organic Carbon ND mg/kg 03/13/15 12:40 7440-44-06513251 Total Organic Carbon ND mg/kg 03/13/15 12:46 7440-44-06593301 Total Organic Carbon ND mg/kg 03/13/15 12:51 7440-44-06563281 Mean Total Organic Carbon ND mg/kg 03/13/15 12:35 7440-44-06573281 Surrogates RSD%5.0 %03/13/15 12:351 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 94 Page 65 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006523 Lab ID:92240158006 Collected:03/04/15 16:25 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7030 mg/kg 03/17/15 10:16 7429-90-503/16/15 12:277.0 3.5 1 Barium 49.6 mg/kg 03/17/15 10:16 7440-39-303/16/15 12:270.70 0.35 1 Beryllium 0.24 mg/kg 03/17/15 10:16 7440-41-703/16/15 12:270.070 0.035 1 Boron 9.6 mg/kg 03/17/15 10:16 7440-42-803/16/15 12:273.5 1.8 1 Calcium 655 mg/kg 03/17/15 10:16 7440-70-203/16/15 12:2735.0 17.5 1 Chromium 15.7 mg/kg 03/17/15 10:16 7440-47-303/16/15 12:270.35 0.18 1 Copper 8.8 mg/kg 03/17/15 10:16 7440-50-803/16/15 12:270.35 0.18 1 Iron 12400 mg/kg 03/17/15 10:16 7439-89-603/16/15 12:272.8 1.4 1 Magnesium 1670 mg/kg 03/17/15 10:16 7439-95-403/16/15 12:2735.0 17.5 1 Manganese 104 mg/kg 03/17/15 10:16 7439-96-503/16/15 12:270.35 0.18 1 Molybdenum ND mg/kg 03/17/15 10:16 7439-98-703/16/15 12:270.70 0.35 1 Nickel 2.5 mg/kg 03/17/15 10:16 7440-02-003/16/15 12:270.35 0.18 1 Potassium 881 mg/kg 03/17/15 10:16 7440-09-703/16/15 12:2770.1 35.0 1 Sodium 35.4J mg/kg 03/17/15 10:16 7440-23-503/16/15 12:2770.1 35.0 1 Strontium 6.0 mg/kg 03/17/15 10:16 7440-24-603/16/15 12:270.70 0.35 1 Zinc 14.5 mg/kg 03/17/15 10:16 7440-66-603/16/15 12:271.4 0.70 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:10 7440-36-0 D3,N203/16/15 12:271.4 0.70 20 Arsenic 1.2J mg/kg 03/17/15 12:10 7440-38-2 D303/16/15 12:271.4 0.70 20 Cadmium ND mg/kg 03/17/15 12:10 7440-43-9 D303/16/15 12:270.17 0.084 20 Cobalt 3.7 mg/kg 03/17/15 12:10 7440-48-4 D303/16/15 12:271.4 0.70 20 Lead 9.6 mg/kg 03/17/15 12:10 7439-92-1 D303/16/15 12:271.4 0.70 20 Selenium ND mg/kg 03/17/15 12:10 7782-49-2 D303/16/15 12:271.4 0.70 20 Thallium ND mg/kg 03/17/15 12:10 7440-28-0 D303/16/15 12:271.4 0.70 20 Vanadium 28.3 mg/kg 03/17/15 12:10 7440-62-2 D303/16/15 12:271.4 0.70 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.033 mg/kg 03/17/15 13:38 7439-97-603/17/15 06:130.011 0.0057 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 30.6 %03/16/15 15:310.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.3 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/14/15 20:12 16887-00-6 D33621815 Sulfate ND mg/kg 03/14/15 20:12 14808-79-8 D33621815 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/14/15 20:12 14797-55-8 D3,H336.2 18.1 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 94 Page 66 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006523 Lab ID:92240158006 Collected:03/04/15 16:25 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 9710 mg/kg 03/13/15 12:56 7440-44-08584291 Total Organic Carbon 7400 mg/kg 03/13/15 13:03 7440-44-08664331 Total Organic Carbon 7310 mg/kg 03/13/15 13:10 7440-44-08664331 Total Organic Carbon 11800 mg/kg 03/13/15 13:15 7440-44-08644321 Mean Total Organic Carbon 9060 mg/kg 03/13/15 12:56 7440-44-08634321 Surrogates RSD%23.8 %03/13/15 12:561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 94 Page 67 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006515 Lab ID:92240158007 Collected:03/04/15 10:25 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3510 mg/kg 03/17/15 14:02 7429-90-5 D303/16/15 12:2727.1 13.5 5 Barium 40.9 mg/kg 03/17/15 14:02 7440-39-3 D303/16/15 12:272.7 1.4 5 Beryllium 0.35 mg/kg 03/17/15 14:02 7440-41-7 D303/16/15 12:270.27 0.14 5 Boron ND mg/kg 03/17/15 14:02 7440-42-8 D303/16/15 12:2713.5 6.8 5 Calcium 189 mg/kg 03/17/15 14:02 7440-70-2 D303/16/15 12:2713567.7 5 Chromium ND mg/kg 03/17/15 14:02 7440-47-3 D303/16/15 12:271.4 0.68 5 Copper 3.9 mg/kg 03/17/15 14:02 7440-50-8 D303/16/15 12:271.4 0.68 5 Iron 6670 mg/kg 03/17/15 14:02 7439-89-6 D303/16/15 12:2710.8 5.4 5 Magnesium 1660 mg/kg 03/17/15 14:02 7439-95-4 D303/16/15 12:2713567.7 5 Manganese 393 mg/kg 03/17/15 14:02 7439-96-5 D303/16/15 12:271.4 0.68 5 Molybdenum ND mg/kg 03/17/15 14:02 7439-98-7 D303/16/15 12:272.7 1.4 5 Nickel ND mg/kg 03/17/15 14:02 7440-02-0 D303/16/15 12:271.4 0.68 5 Potassium 1550 mg/kg 03/17/15 14:02 7440-09-7 D303/16/15 12:272711355 Sodium ND mg/kg 03/17/15 14:02 7440-23-5 D303/16/15 12:272711355 Strontium 5.2 mg/kg 03/17/15 14:02 7440-24-6 D303/16/15 12:272.7 1.4 5 Zinc 31.6 mg/kg 03/17/15 14:02 7440-66-6 D303/16/15 12:275.4 2.7 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:12 7440-36-0 D3,N203/16/15 12:271.1 0.54 20 Arsenic 1.1 mg/kg 03/17/15 12:12 7440-38-2 D303/16/15 12:271.1 0.54 20 Cadmium 0.091J mg/kg 03/17/15 12:12 7440-43-9 D303/16/15 12:270.13 0.065 20 Cobalt 1.7 mg/kg 03/17/15 12:12 7440-48-4 D303/16/15 12:271.1 0.54 20 Lead 5.5 mg/kg 03/17/15 12:12 7439-92-1 D303/16/15 12:271.1 0.54 20 Selenium 1.2 mg/kg 03/17/15 12:12 7782-49-2 D303/16/15 12:271.1 0.54 20 Thallium ND mg/kg 03/17/15 12:12 7440-28-0 D303/16/15 12:271.1 0.54 20 Vanadium 5.9 mg/kg 03/17/15 12:12 7440-62-2 D303/16/15 12:271.1 0.54 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:40 7439-97-603/17/15 06:130.0086 0.0043 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 9.3 %03/16/15 15:310.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.9 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15300.0 IC Anions, SPLP Sulfate 3.1 mg/L 03/19/15 21:19 14808-79-82.2 1.1 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.34 mg/L 03/18/15 16:43 B,H10.22 0.22 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/16/15 14:154500 Chloride, SPLP Chloride ND mg/L 03/19/15 21:08 16887-00-65.5 2.8 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 94 Page 68 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006515 Lab ID:92240158007 Collected:03/04/15 10:25 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/14/15 20:34 16887-00-6 D32711355 Sulfate ND mg/kg 03/14/15 20:34 14808-79-8 D32711355 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/14/15 20:34 14797-55-8 D3,H327.1 13.5 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 364J mg/kg 03/13/15 13:42 7440-44-06623311 Total Organic Carbon 443J mg/kg 03/13/15 13:48 7440-44-06633321 Total Organic Carbon 354J mg/kg 03/13/15 13:53 7440-44-06623311 Total Organic Carbon 360J mg/kg 03/13/15 13:59 7440-44-06593301 Mean Total Organic Carbon 380J mg/kg 03/13/15 13:42 7440-44-06613311 Surrogates RSD%11.1 %03/13/15 13:421 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 94 Page 69 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006516 Lab ID:92240158008 Collected:03/04/15 11:10 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1480 mg/kg 03/17/15 10:25 7429-90-503/16/15 12:275.5 2.7 1 Barium 22.2 mg/kg 03/17/15 10:25 7440-39-303/16/15 12:270.55 0.27 1 Beryllium 0.50 mg/kg 03/17/15 14:06 7440-41-7 D303/16/15 12:270.27 0.14 5 Boron ND mg/kg 03/17/15 14:06 7440-42-8 D303/16/15 12:2713.7 6.9 5 Calcium 81.4 mg/kg 03/17/15 10:25 7440-70-203/16/15 12:2727.5 13.7 1 Chromium ND mg/kg 03/17/15 14:06 7440-47-3 D303/16/15 12:271.4 0.69 5 Copper 43.8 mg/kg 03/17/15 14:06 7440-50-8 D303/16/15 12:271.4 0.69 5 Iron 5790 mg/kg 03/17/15 10:25 7439-89-603/16/15 12:272.2 1.1 1 Magnesium 368 mg/kg 03/17/15 10:25 7439-95-403/16/15 12:2727.5 13.7 1 Manganese 195 mg/kg 03/17/15 14:06 7439-96-5 D303/16/15 12:271.4 0.69 5 Molybdenum 0.36J mg/kg 03/17/15 10:25 7439-98-703/16/15 12:270.55 0.27 1 Nickel ND mg/kg 03/17/15 10:25 7440-02-003/16/15 12:270.27 0.14 1 Potassium 111 mg/kg 03/17/15 10:25 7440-09-703/16/15 12:2754.9 27.5 1 Sodium 46.7J mg/kg 03/17/15 10:25 7440-23-503/16/15 12:2754.9 27.5 1 Strontium 3.1 mg/kg 03/17/15 10:25 7440-24-603/16/15 12:270.55 0.27 1 Zinc 12.3 mg/kg 03/17/15 10:25 7440-66-603/16/15 12:271.1 0.55 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:14 7440-36-0 D3,N203/16/15 12:271.1 0.55 20 Arsenic 1.0J mg/kg 03/17/15 12:14 7440-38-2 D303/16/15 12:271.1 0.55 20 Cadmium ND mg/kg 03/17/15 12:14 7440-43-9 D303/16/15 12:270.13 0.066 20 Cobalt 2.2 mg/kg 03/17/15 12:14 7440-48-4 D303/16/15 12:271.1 0.55 20 Lead 11.8 mg/kg 03/17/15 12:14 7439-92-1 D303/16/15 12:271.1 0.55 20 Selenium 0.87J mg/kg 03/17/15 12:14 7782-49-2 D303/16/15 12:271.1 0.55 20 Thallium ND mg/kg 03/17/15 12:14 7440-28-0 D303/16/15 12:271.1 0.55 20 Vanadium 4.8 mg/kg 03/17/15 12:14 7440-62-2 D303/16/15 12:271.1 0.55 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:42 7439-97-603/17/15 06:130.0093 0.0046 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 9.5 %03/16/15 15:320.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.5 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15300.0 IC Anions, SPLP Sulfate 4.1 mg/L 03/19/15 21:32 14808-79-82.2 1.1 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.32 mg/L 03/18/15 16:44 B,H10.22 0.22 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/16/15 14:154500 Chloride, SPLP Chloride ND mg/L 03/19/15 21:09 16887-00-65.5 2.8 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 94 Page 70 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006516 Lab ID:92240158008 Collected:03/04/15 11:10 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/14/15 20:55 16887-00-6 D32721365 Sulfate ND mg/kg 03/14/15 20:55 14808-79-8 D32721365 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/14/15 20:55 14797-55-8 D3,H327.2 13.6 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 03/13/15 14:04 7440-44-06643321 Total Organic Carbon ND mg/kg 03/13/15 14:17 7440-44-06673331 Total Organic Carbon ND mg/kg 03/13/15 14:22 7440-44-06623311 Total Organic Carbon ND mg/kg 03/13/15 14:29 7440-44-06633321 Mean Total Organic Carbon ND mg/kg 03/13/15 14:04 7440-44-06643321 Surrogates RSD%2.8 %03/13/15 14:041 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 94 Page 71 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006521 Lab ID:92240158009 Collected:03/04/15 15:05 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 11800 mg/kg 03/17/15 10:30 7429-90-503/16/15 12:277.5 3.8 1 Barium 51.4 mg/kg 03/17/15 10:30 7440-39-303/16/15 12:270.75 0.38 1 Beryllium 0.26 mg/kg 03/17/15 10:30 7440-41-703/16/15 12:270.075 0.038 1 Boron 12.9 mg/kg 03/17/15 10:30 7440-42-803/16/15 12:273.8 1.9 1 Calcium 208 mg/kg 03/17/15 10:30 7440-70-203/16/15 12:2737.6 18.8 1 Chromium 35.6 mg/kg 03/17/15 10:30 7440-47-303/16/15 12:270.38 0.19 1 Copper 15.5 mg/kg 03/17/15 10:30 7440-50-803/16/15 12:270.38 0.19 1 Iron 18100 mg/kg 03/17/15 10:30 7439-89-603/16/15 12:273.0 1.5 1 Magnesium 4250 mg/kg 03/17/15 10:30 7439-95-403/16/15 12:2737.6 18.8 1 Manganese 120 mg/kg 03/17/15 10:30 7439-96-503/16/15 12:270.38 0.19 1 Molybdenum ND mg/kg 03/17/15 10:30 7439-98-703/16/15 12:270.75 0.38 1 Nickel 10.9 mg/kg 03/17/15 10:30 7440-02-003/16/15 12:270.38 0.19 1 Potassium 2410 mg/kg 03/17/15 10:30 7440-09-703/16/15 12:2775.2 37.6 1 Sodium 40.9J mg/kg 03/17/15 10:30 7440-23-503/16/15 12:2775.2 37.6 1 Strontium 4.4 mg/kg 03/17/15 10:30 7440-24-603/16/15 12:270.75 0.38 1 Zinc 32.4 mg/kg 03/17/15 10:30 7440-66-603/16/15 12:271.5 0.75 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:16 7440-36-0 D3,N203/16/15 12:271.5 0.75 20 Arsenic 1.6 mg/kg 03/17/15 12:16 7440-38-2 D303/16/15 12:271.5 0.75 20 Cadmium ND mg/kg 03/17/15 12:16 7440-43-9 D303/16/15 12:270.18 0.090 20 Cobalt 5.2 mg/kg 03/17/15 12:16 7440-48-4 D303/16/15 12:271.5 0.75 20 Lead 8.2 mg/kg 03/17/15 12:16 7439-92-1 D303/16/15 12:271.5 0.75 20 Selenium ND mg/kg 03/17/15 12:16 7782-49-2 D303/16/15 12:271.5 0.75 20 Thallium ND mg/kg 03/17/15 12:16 7440-28-0 D303/16/15 12:271.5 0.75 20 Vanadium 38.4 mg/kg 03/17/15 12:16 7440-62-2 D403/16/15 12:271.5 0.75 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:44 7439-97-603/17/15 06:130.012 0.0059 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 30.3 %03/16/15 15:330.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 4.9 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15300.0 IC Anions, SPLP Sulfate 4.0 mg/L 03/19/15 21:46 14808-79-82.9 1.4 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 03/18/15 16:48 H10.29 0.29 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/16/15 14:154500 Chloride, SPLP Chloride 26.1 mg/L 03/19/15 21:09 16887-00-67.2 3.6 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 94 Page 72 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006521 Lab ID:92240158009 Collected:03/04/15 15:05 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/13/15 16:23 16887-00-6 D33601805 Sulfate ND mg/kg 03/13/15 16:23 14808-79-8 D33601805 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/13/15 16:23 14797-55-8 D3,H336.0 18.0 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 4430 mg/kg 03/13/15 14:35 7440-44-08594291 Total Organic Carbon 2910 mg/kg 03/13/15 14:41 7440-44-08634311 Total Organic Carbon 2580 mg/kg 03/13/15 14:47 7440-44-08684341 Total Organic Carbon 2720 mg/kg 03/13/15 14:54 7440-44-08584291 Mean Total Organic Carbon 3160 mg/kg 03/13/15 14:35 7440-44-08624311 Surrogates RSD%27.1 %03/13/15 14:351 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 94 Page 73 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006524 Lab ID:92240158010 Collected:03/04/15 16:45 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4960 mg/kg 03/17/15 10:47 7429-90-503/16/15 12:276.4 3.2 1 Barium 61.5 mg/kg 03/17/15 10:47 7440-39-303/16/15 12:270.64 0.32 1 Beryllium 0.56 mg/kg 03/17/15 14:11 7440-41-7 D303/16/15 12:270.32 0.16 5 Boron ND mg/kg 03/17/15 14:11 7440-42-8 D303/16/15 12:2715.9 7.9 5 Calcium 270 mg/kg 03/17/15 10:47 7440-70-203/16/15 12:2731.8 15.9 1 Chromium ND mg/kg 03/17/15 14:11 7440-47-3 D303/16/15 12:271.6 0.79 5 Copper 20.6 mg/kg 03/17/15 14:11 7440-50-8 D303/16/15 12:271.6 0.79 5 Iron 8490 mg/kg 03/17/15 10:47 7439-89-603/16/15 12:272.5 1.3 1 Magnesium 2440 mg/kg 03/17/15 10:47 7439-95-403/16/15 12:2731.8 15.9 1 Manganese 678 mg/kg 03/17/15 14:11 7439-96-5 D303/16/15 12:271.6 0.79 5 Molybdenum ND mg/kg 03/17/15 14:11 7439-98-7 D303/16/15 12:273.2 1.6 5 Nickel ND mg/kg 03/17/15 14:11 7440-02-0 D303/16/15 12:271.6 0.79 5 Potassium 1550 mg/kg 03/17/15 10:47 7440-09-703/16/15 12:2763.6 31.8 1 Sodium 40.7J mg/kg 03/17/15 10:47 7440-23-503/16/15 12:2763.6 31.8 1 Strontium 8.3 mg/kg 03/17/15 10:47 7440-24-603/16/15 12:270.64 0.32 1 Zinc 13.2 mg/kg 03/17/15 14:11 7440-66-6 D303/16/15 12:276.4 3.2 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/17/15 12:19 7440-36-0 D3,N203/16/15 12:271.3 0.64 20 Arsenic 1.2J mg/kg 03/17/15 12:19 7440-38-2 D303/16/15 12:271.3 0.64 20 Cadmium ND mg/kg 03/17/15 12:19 7440-43-9 D303/16/15 12:270.15 0.076 20 Cobalt 8.9 mg/kg 03/17/15 12:19 7440-48-4 D303/16/15 12:271.3 0.64 20 Lead 2.9 mg/kg 03/17/15 12:19 7439-92-1 D303/16/15 12:271.3 0.64 20 Selenium 1.4 mg/kg 03/17/15 12:19 7782-49-2 D303/16/15 12:271.3 0.64 20 Thallium ND mg/kg 03/17/15 12:19 7440-28-0 D303/16/15 12:271.3 0.64 20 Vanadium 17.8 mg/kg 03/17/15 12:19 7440-62-2 D303/16/15 12:271.3 0.64 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/17/15 13:51 7439-97-603/17/15 06:130.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 21.6 %03/16/15 15:330.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.5 Std. Units 03/12/15 15:550.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/16/15 14:15300.0 IC Anions, SPLP Sulfate 3.0 mg/L 03/19/15 21:59 14808-79-82.5 1.3 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/16/15 14:15353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.38 mg/L 03/18/15 16:49 H10.25 0.25 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/16/15 14:154500 Chloride, SPLP Chloride ND mg/L 03/19/15 21:10 16887-00-66.4 3.2 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 94 Page 74 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006524 Lab ID:92240158010 Collected:03/04/15 16:45 Received:03/06/15 14:15 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/13/15 17:27 16887-00-6 D33121565 Sulfate ND mg/kg 03/13/15 17:27 14808-79-8 D33121565 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/13/15 17:27 14797-55-8 D3,H331.2 15.6 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 433J mg/kg 03/13/15 14:59 7440-44-07683841 Total Organic Carbon ND mg/kg 03/13/15 15:05 7440-44-07613811 Total Organic Carbon ND mg/kg 03/13/15 15:10 7440-44-07683841 Total Organic Carbon ND mg/kg 03/13/15 15:16 7440-44-07593801 Mean Total Organic Carbon 385J mg/kg 03/13/15 14:59 7440-44-07643821 Surrogates RSD%8.5 %03/13/15 14:591 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 94 Page 75 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006513 Lab ID:92240158011 Collected:03/03/15 15:58 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 46.7 ug/L 03/13/15 20:24 7429-90-503/13/15 13:0410.0 1.2 1 Antimony ND ug/L 03/13/15 20:24 7440-36-003/13/15 13:040.50 0.25 1 Arsenic ND ug/L 03/13/15 20:24 7440-38-203/13/15 13:040.50 0.25 1 Barium 4.4 ug/L 03/13/15 20:24 7440-39-303/13/15 13:040.30 0.14 1 Beryllium ND ug/L 03/13/15 20:24 7440-41-703/13/15 13:040.20 0.066 1 Boron ND ug/L 03/13/15 20:24 7440-42-803/13/15 13:045.0 1.0 1 Cadmium ND ug/L 03/13/15 20:24 7440-43-903/13/15 13:040.080 0.033 1 Calcium 160 ug/L 03/13/15 20:24 7440-70-203/13/15 13:0440.0 8.4 1 Chromium 5.9 ug/L 03/13/15 20:24 7440-47-303/13/15 13:040.50 0.22 1 Cobalt ND ug/L 03/13/15 20:24 7440-48-403/13/15 13:040.50 0.25 1 Copper ND ug/L 03/13/15 20:24 7440-50-803/13/15 13:041.0 0.22 1 Iron 451 ug/L 03/13/15 20:24 7439-89-603/13/15 13:0450.0 8.0 1 Lead 0.28 ug/L 03/13/15 20:24 7439-92-103/13/15 13:040.10 0.046 1 Magnesium 17.4 ug/L 03/13/15 20:24 7439-95-403/13/15 13:0410.0 2.8 1 Manganese 6.4 ug/L 03/13/15 20:24 7439-96-503/13/15 13:040.50 0.14 1 Molybdenum 2.1 ug/L 03/13/15 20:24 7439-98-703/13/15 13:040.50 0.24 1 Nickel 1.8 ug/L 03/13/15 20:24 7440-02-003/13/15 13:040.50 0.23 1 Potassium ND ug/L 03/13/15 20:24 7440-09-703/13/15 13:0450.0 8.3 1 Selenium ND ug/L 03/13/15 20:24 7782-49-203/13/15 13:040.50 0.25 1 Sodium ND ug/L 03/13/15 20:24 7440-23-503/13/15 13:0450.0 18.2 1 Strontium 1.8 ug/L 03/13/15 20:24 7440-24-603/13/15 13:040.50 0.057 1 Thallium ND ug/L 03/13/15 20:24 7440-28-003/13/15 13:040.10 0.025 1 Vanadium ND ug/L 03/13/15 20:24 7440-62-203/13/15 13:041.0 0.21 1 Zinc 34.2 ug/L 03/13/15 20:24 7440-66-603/13/15 13:045.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/16/15 11:04 7439-97-603/15/15 14:300.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 94 Page 76 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006517 Lab ID:92240158012 Collected:03/04/15 10:02 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 23.0 ug/L 03/13/15 20:29 7429-90-503/13/15 13:0410.0 1.2 1 Antimony ND ug/L 03/13/15 20:29 7440-36-003/13/15 13:040.50 0.25 1 Arsenic ND ug/L 03/13/15 20:29 7440-38-203/13/15 13:040.50 0.25 1 Barium 1.1 ug/L 03/13/15 20:29 7440-39-303/13/15 13:040.30 0.14 1 Beryllium ND ug/L 03/13/15 20:29 7440-41-703/13/15 13:040.20 0.066 1 Boron ND ug/L 03/13/15 20:29 7440-42-803/13/15 13:045.0 1.0 1 Cadmium ND ug/L 03/13/15 20:29 7440-43-903/13/15 13:040.080 0.033 1 Calcium 136 ug/L 03/13/15 20:29 7440-70-203/13/15 13:0440.0 8.4 1 Chromium 1.3 ug/L 03/13/15 20:29 7440-47-303/13/15 13:040.50 0.22 1 Cobalt ND ug/L 03/13/15 20:29 7440-48-403/13/15 13:040.50 0.25 1 Copper ND ug/L 03/13/15 20:29 7440-50-803/13/15 13:041.0 0.22 1 Iron 139 ug/L 03/13/15 20:29 7439-89-603/13/15 13:0450.0 8.0 1 Lead 0.12 ug/L 03/13/15 20:29 7439-92-103/13/15 13:040.10 0.046 1 Magnesium 12.2 ug/L 03/13/15 20:29 7439-95-403/13/15 13:0410.0 2.8 1 Manganese 3.5 ug/L 03/13/15 20:29 7439-96-503/13/15 13:040.50 0.14 1 Molybdenum 0.68 ug/L 03/13/15 20:29 7439-98-703/13/15 13:040.50 0.24 1 Nickel 0.66 ug/L 03/13/15 20:29 7440-02-003/13/15 13:040.50 0.23 1 Potassium ND ug/L 03/13/15 20:29 7440-09-703/13/15 13:0450.0 8.3 1 Selenium ND ug/L 03/13/15 20:29 7782-49-203/13/15 13:040.50 0.25 1 Sodium ND ug/L 03/13/15 20:29 7440-23-503/13/15 13:0450.0 18.2 1 Strontium 1.0 ug/L 03/13/15 20:29 7440-24-603/13/15 13:040.50 0.057 1 Thallium ND ug/L 03/13/15 20:29 7440-28-003/13/15 13:040.10 0.025 1 Vanadium ND ug/L 03/13/15 20:29 7440-62-203/13/15 13:041.0 0.21 1 Zinc ND ug/L 03/13/15 20:29 7440-66-603/13/15 13:045.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/16/15 11:06 7439-97-603/15/15 14:300.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 94 Page 77 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006519 Lab ID:92240158013 Collected:03/04/15 12:39 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 18.8 ug/L 03/13/15 20:34 7429-90-503/13/15 13:0410.0 1.2 1 Antimony ND ug/L 03/13/15 20:34 7440-36-003/13/15 13:040.50 0.25 1 Arsenic ND ug/L 03/13/15 20:34 7440-38-203/13/15 13:040.50 0.25 1 Barium 1.0 ug/L 03/13/15 20:34 7440-39-303/13/15 13:040.30 0.14 1 Beryllium ND ug/L 03/13/15 20:34 7440-41-703/13/15 13:040.20 0.066 1 Boron ND ug/L 03/13/15 20:34 7440-42-803/13/15 13:045.0 1.0 1 Cadmium ND ug/L 03/13/15 20:34 7440-43-903/13/15 13:040.080 0.033 1 Calcium 98.9 ug/L 03/13/15 20:34 7440-70-203/13/15 13:0440.0 8.4 1 Chromium 1.9 ug/L 03/13/15 20:34 7440-47-303/13/15 13:040.50 0.22 1 Cobalt ND ug/L 03/13/15 20:34 7440-48-403/13/15 13:040.50 0.25 1 Copper ND ug/L 03/13/15 20:34 7440-50-803/13/15 13:041.0 0.22 1 Iron 173 ug/L 03/13/15 20:34 7439-89-603/13/15 13:0450.0 8.0 1 Lead 0.26 ug/L 03/13/15 20:34 7439-92-103/13/15 13:040.10 0.046 1 Magnesium ND ug/L 03/13/15 20:34 7439-95-403/13/15 13:0410.0 2.8 1 Manganese 4.3 ug/L 03/13/15 20:34 7439-96-503/13/15 13:040.50 0.14 1 Molybdenum 0.67 ug/L 03/13/15 20:34 7439-98-703/13/15 13:040.50 0.24 1 Nickel 0.98 ug/L 03/13/15 20:34 7440-02-003/13/15 13:040.50 0.23 1 Potassium ND ug/L 03/13/15 20:34 7440-09-703/13/15 13:0450.0 8.3 1 Selenium ND ug/L 03/13/15 20:34 7782-49-203/13/15 13:040.50 0.25 1 Sodium ND ug/L 03/13/15 20:34 7440-23-503/13/15 13:0450.0 18.2 1 Strontium 0.66 ug/L 03/13/15 20:34 7440-24-603/13/15 13:040.50 0.057 1 Thallium ND ug/L 03/13/15 20:34 7440-28-003/13/15 13:040.10 0.025 1 Vanadium ND ug/L 03/13/15 20:34 7440-62-203/13/15 13:041.0 0.21 1 Zinc 7.2 ug/L 03/13/15 20:34 7440-66-603/13/15 13:045.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/16/15 11:09 7439-97-603/15/15 14:300.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 94 Page 78 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006522 Lab ID:92240158014 Collected:03/04/15 14:16 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 49.3 ug/L 03/13/15 20:38 7429-90-503/13/15 13:0410.0 1.2 1 Antimony ND ug/L 03/13/15 20:38 7440-36-003/13/15 13:040.50 0.25 1 Arsenic ND ug/L 03/13/15 20:38 7440-38-203/13/15 13:040.50 0.25 1 Barium 2.0 ug/L 03/13/15 20:38 7440-39-303/13/15 13:040.30 0.14 1 Beryllium ND ug/L 03/13/15 20:38 7440-41-703/13/15 13:040.20 0.066 1 Boron ND ug/L 03/13/15 20:38 7440-42-803/13/15 13:045.0 1.0 1 Cadmium ND ug/L 03/13/15 20:38 7440-43-903/13/15 13:040.080 0.033 1 Calcium 132 ug/L 03/13/15 20:38 7440-70-203/13/15 13:0440.0 8.4 1 Chromium 5.1 ug/L 03/13/15 20:38 7440-47-303/13/15 13:040.50 0.22 1 Cobalt ND ug/L 03/13/15 20:38 7440-48-403/13/15 13:040.50 0.25 1 Copper 1.1 ug/L 03/13/15 20:38 7440-50-803/13/15 13:041.0 0.22 1 Iron 495 ug/L 03/13/15 20:38 7439-89-603/13/15 13:0450.0 8.0 1 Lead 0.36 ug/L 03/13/15 20:38 7439-92-103/13/15 13:040.10 0.046 1 Magnesium 16.5 ug/L 03/13/15 20:38 7439-95-403/13/15 13:0410.0 2.8 1 Manganese 7.9 ug/L 03/13/15 20:38 7439-96-503/13/15 13:040.50 0.14 1 Molybdenum 1.1 ug/L 03/13/15 20:38 7439-98-703/13/15 13:040.50 0.24 1 Nickel 2.3 ug/L 03/13/15 20:38 7440-02-003/13/15 13:040.50 0.23 1 Potassium ND ug/L 03/13/15 20:38 7440-09-703/13/15 13:0450.0 8.3 1 Selenium ND ug/L 03/13/15 20:38 7782-49-203/13/15 13:040.50 0.25 1 Sodium 50.6 ug/L 03/13/15 20:38 7440-23-503/13/15 13:0450.0 18.2 1 Strontium 1.2 ug/L 03/13/15 20:38 7440-24-603/13/15 13:040.50 0.057 1 Thallium ND ug/L 03/13/15 20:38 7440-28-003/13/15 13:040.10 0.025 1 Vanadium ND ug/L 03/13/15 20:38 7440-62-203/13/15 13:041.0 0.21 1 Zinc 18.3 ug/L 03/13/15 20:38 7440-66-603/13/15 13:045.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/16/15 11:11 7439-97-603/15/15 14:300.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 94 Page 79 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006525 Lab ID:92240158015 Collected:03/04/15 17:30 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 180 ug/L 03/13/15 20:43 7429-90-503/13/15 13:0410.0 1.2 1 Antimony ND ug/L 03/13/15 20:43 7440-36-003/13/15 13:040.50 0.25 1 Arsenic ND ug/L 03/13/15 20:43 7440-38-203/13/15 13:040.50 0.25 1 Barium 4.8 ug/L 03/13/15 20:43 7440-39-303/13/15 13:040.30 0.14 1 Beryllium ND ug/L 03/13/15 20:43 7440-41-703/13/15 13:040.20 0.066 1 Boron ND ug/L 03/13/15 20:43 7440-42-803/13/15 13:045.0 1.0 1 Cadmium ND ug/L 03/13/15 20:43 7440-43-903/13/15 13:040.080 0.033 1 Calcium 308 ug/L 03/13/15 20:43 7440-70-203/13/15 13:0440.0 8.4 1 Chromium 33.7 ug/L 03/13/15 20:43 7440-47-303/13/15 13:040.50 0.22 1 Cobalt ND ug/L 03/13/15 20:43 7440-48-403/13/15 13:040.50 0.25 1 Copper 4.6 ug/L 03/13/15 20:43 7440-50-803/13/15 13:041.0 0.22 1 Iron 1360 ug/L 03/13/15 20:43 7439-89-603/13/15 13:0450.0 8.0 1 Lead 0.40 ug/L 03/13/15 20:43 7439-92-103/13/15 13:040.10 0.046 1 Magnesium 76.3 ug/L 03/13/15 20:43 7439-95-403/13/15 13:0410.0 2.8 1 Manganese 18.7 ug/L 03/13/15 20:43 7439-96-503/13/15 13:040.50 0.14 1 Molybdenum 4.1 ug/L 03/13/15 20:43 7439-98-703/13/15 13:040.50 0.24 1 Nickel 4.6 ug/L 03/13/15 20:43 7440-02-003/13/15 13:040.50 0.23 1 Potassium 109 ug/L 03/13/15 20:43 7440-09-703/13/15 13:0450.0 8.3 1 Selenium ND ug/L 03/13/15 20:43 7782-49-203/13/15 13:040.50 0.25 1 Sodium 118 ug/L 03/13/15 20:43 7440-23-503/13/15 13:0450.0 18.2 1 Strontium 2.3 ug/L 03/13/15 20:43 7440-24-603/13/15 13:040.50 0.057 1 Thallium ND ug/L 03/13/15 20:43 7440-28-003/13/15 13:040.10 0.025 1 Vanadium 4.5 ug/L 03/13/15 20:43 7440-62-203/13/15 13:041.0 0.21 1 Zinc 12.1 ug/L 03/13/15 20:43 7440-66-603/13/15 13:045.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/16/15 11:14 7439-97-603/15/15 14:300.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 94 Page 80 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006515 SPLP Lab ID:92240158016 Collected:03/04/15 10:25 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 3590 ug/L 03/27/15 14:25 7429-90-503/26/15 19:0110.0 1.2 1 Antimony ND ug/L 03/27/15 14:25 7440-36-003/26/15 19:010.50 0.25 1 Arsenic 0.76 ug/L 03/27/15 14:25 7440-38-203/26/15 19:010.50 0.25 1 Barium 34.5 ug/L 03/27/15 14:25 7440-39-303/26/15 19:010.30 0.14 1 Beryllium 0.27 ug/L 03/27/15 14:25 7440-41-703/26/15 19:010.20 0.066 1 Boron 9.9 ug/L 03/27/15 14:25 7440-42-803/26/15 19:015.0 1.0 1 Cadmium ND ug/L 03/27/15 14:25 7440-43-903/26/15 19:010.080 0.033 1 Calcium 966 ug/L 03/27/15 14:25 7440-70-203/26/15 19:0140.0 8.4 1 Chromium 1.7 ug/L 03/27/15 14:25 7440-47-303/26/15 19:010.50 0.22 1 Cobalt ND ug/L 03/27/15 14:25 7440-48-403/26/15 19:010.50 0.25 1 Copper 1.7 ug/L 03/27/15 14:25 7440-50-803/26/15 19:011.0 0.22 1 Iron 1270 ug/L 03/27/15 14:25 7439-89-603/26/15 19:0150.0 8.0 1 Lead 1.1 ug/L 03/27/15 14:25 7439-92-103/26/15 19:010.10 0.046 1 Magnesium 306 ug/L 03/27/15 14:25 7439-95-403/26/15 19:0110.0 2.8 1 Manganese 64.8 ug/L 03/27/15 14:25 7439-96-503/26/15 19:010.50 0.14 1 Molybdenum ND ug/L 03/27/15 14:25 7439-98-703/26/15 19:010.50 0.24 1 Nickel 0.91 ug/L 03/27/15 14:25 7440-02-003/26/15 19:010.50 0.23 1 Potassium 931 ug/L 03/27/15 14:25 7440-09-703/26/15 19:0150.0 8.3 1 Selenium ND ug/L 03/27/15 14:25 7782-49-203/26/15 19:010.50 0.25 1 Sodium 2920 ug/L 03/27/15 14:25 7440-23-503/26/15 19:0150.0 18.2 1 Strontium 13.6 ug/L 03/27/15 14:25 7440-24-603/26/15 19:010.50 0.057 1 Thallium ND ug/L 03/27/15 14:25 7440-28-003/26/15 19:010.10 0.025 1 Vanadium 1.9 ug/L 03/27/15 14:25 7440-62-203/26/15 19:011.0 0.21 1 Zinc 5.4 ug/L 03/27/15 14:25 7440-66-603/26/15 19:015.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/27/15 12:51 7439-97-603/26/15 19:100.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 94 Page 81 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006516 SPLP Lab ID:92240158017 Collected:03/04/15 11:10 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 195 ug/L 03/27/15 14:28 7429-90-503/26/15 19:0110.0 1.2 1 Antimony ND ug/L 03/27/15 14:28 7440-36-003/26/15 19:010.50 0.25 1 Arsenic ND ug/L 03/27/15 14:28 7440-38-203/26/15 19:010.50 0.25 1 Barium 1.7 ug/L 03/27/15 14:28 7440-39-303/26/15 19:010.30 0.14 1 Beryllium ND ug/L 03/27/15 14:28 7440-41-703/26/15 19:010.20 0.066 1 Boron 72.0 ug/L 03/27/15 14:28 7440-42-803/26/15 19:015.0 1.0 1 Cadmium ND ug/L 03/27/15 14:28 7440-43-903/26/15 19:010.080 0.033 1 Calcium 202 ug/L 03/27/15 14:28 7440-70-203/26/15 19:0140.0 8.4 1 Chromium 0.90 ug/L 03/27/15 14:28 7440-47-303/26/15 19:010.50 0.22 1 Cobalt ND ug/L 03/27/15 14:28 7440-48-403/26/15 19:010.50 0.25 1 Copper ND ug/L 03/27/15 14:28 7440-50-803/26/15 19:011.0 0.22 1 Iron 73.0 ug/L 03/27/15 14:28 7439-89-603/26/15 19:0150.0 8.0 1 Lead ND ug/L 03/27/15 14:28 7439-92-103/26/15 19:010.10 0.046 1 Magnesium 215 ug/L 03/27/15 14:28 7439-95-403/26/15 19:0110.0 2.8 1 Manganese 3.2 ug/L 03/27/15 14:28 7439-96-503/26/15 19:010.50 0.14 1 Molybdenum ND ug/L 03/27/15 14:28 7439-98-703/26/15 19:010.50 0.24 1 Nickel ND ug/L 03/27/15 14:28 7440-02-003/26/15 19:010.50 0.23 1 Potassium 696 ug/L 03/27/15 14:28 7440-09-703/26/15 19:0150.0 8.3 1 Selenium ND ug/L 03/27/15 14:28 7782-49-203/26/15 19:010.50 0.25 1 Sodium 5620 ug/L 03/27/15 14:28 7440-23-503/26/15 19:0150.0 18.2 1 Strontium 1.4 ug/L 03/27/15 14:28 7440-24-603/26/15 19:010.50 0.057 1 Thallium ND ug/L 03/27/15 14:28 7440-28-003/26/15 19:010.10 0.025 1 Vanadium ND ug/L 03/27/15 14:28 7440-62-203/26/15 19:011.0 0.21 1 Zinc ND ug/L 03/27/15 14:28 7440-66-603/26/15 19:015.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/27/15 12:59 7439-97-603/26/15 19:100.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 64 of 94 Page 82 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006521 SPLP Lab ID:92240158018 Collected:03/04/15 15:05 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 132000 ug/L 03/27/15 14:46 7429-90-503/26/15 19:0125028.8 5 Antimony ND ug/L 03/27/15 14:31 7440-36-003/26/15 19:012.5 1.2 1 Arsenic 12.3 ug/L 03/27/15 14:31 7440-38-203/26/15 19:012.5 1.2 1 Barium 377 ug/L 03/27/15 14:31 7440-39-303/26/15 19:011.5 0.70 1 Beryllium 2.6 ug/L 03/27/15 14:31 7440-41-703/26/15 19:011.0 0.33 1 Boron 75.8 ug/L 03/27/15 14:31 7440-42-803/26/15 19:0125.0 5.1 1 Cadmium ND ug/L 03/27/15 14:31 7440-43-903/26/15 19:010.40 0.16 1 Calcium 2170 ug/L 03/27/15 14:31 7440-70-203/26/15 19:0120041.9 1 Chromium 269 ug/L 03/27/15 14:31 7440-47-303/26/15 19:012.5 1.1 1 Cobalt 24.3 ug/L 03/27/15 14:31 7440-48-403/26/15 19:012.5 1.2 1 Copper 112 ug/L 03/27/15 14:31 7440-50-803/26/15 19:015.0 1.1 1 Iron 109000 ug/L 03/27/15 14:31 7439-89-603/26/15 19:0125040.1 1 Lead 62.1 ug/L 03/27/15 14:31 7439-92-103/26/15 19:010.50 0.23 1 Magnesium 6500 ug/L 03/27/15 14:31 7439-95-403/26/15 19:0150.0 14.2 1 Manganese 250 ug/L 03/27/15 14:31 7439-96-503/26/15 19:012.5 0.68 1 Molybdenum 2.7 ug/L 03/27/15 14:31 7439-98-703/26/15 19:012.5 1.2 1 Nickel 48.6 ug/L 03/27/15 14:31 7440-02-003/26/15 19:012.5 1.2 1 Potassium 5200 ug/L 03/27/15 14:31 7440-09-703/26/15 19:0125041.7 1 Selenium ND ug/L 03/27/15 14:31 7782-49-203/26/15 19:012.5 1.2 1 Sodium 4560 ug/L 03/27/15 14:31 7440-23-503/26/15 19:0125091.2 1 Strontium 38.2 ug/L 03/27/15 14:31 7440-24-603/26/15 19:012.5 0.28 1 Thallium 0.60 ug/L 03/27/15 14:31 7440-28-003/26/15 19:010.50 0.12 1 Vanadium 277 ug/L 03/27/15 14:31 7440-62-203/26/15 19:015.0 1.1 1 Zinc 132 ug/L 03/27/15 14:31 7440-66-603/26/15 19:0125.0 12.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/27/15 13:02 7439-97-603/26/15 19:100.60 0.078 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 65 of 94 Page 83 of 113 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92240158 J15030202 Sample:2015006524 SPLP Lab ID:92240158019 Collected:03/04/15 16:45 Received:03/06/15 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 3030 ug/L 03/27/15 14:34 7429-90-503/26/15 19:0110.0 1.2 1 Antimony ND ug/L 03/27/15 14:34 7440-36-003/26/15 19:010.50 0.25 1 Arsenic ND ug/L 03/27/15 14:34 7440-38-203/26/15 19:010.50 0.25 1 Barium 38.8 ug/L 03/27/15 14:34 7440-39-303/26/15 19:010.30 0.14 1 Beryllium 0.30 ug/L 03/27/15 14:34 7440-41-703/26/15 19:010.20 0.066 1 Boron 18.1 ug/L 03/27/15 14:34 7440-42-803/26/15 19:015.0 1.0 1 Cadmium ND ug/L 03/27/15 14:34 7440-43-903/26/15 19:010.080 0.033 1 Calcium 407 ug/L 03/27/15 14:34 7440-70-203/26/15 19:0140.0 8.4 1 Chromium 1.1 ug/L 03/27/15 14:34 7440-47-303/26/15 19:010.50 0.22 1 Cobalt 2.5 ug/L 03/27/15 14:34 7440-48-403/26/15 19:010.50 0.25 1 Copper 4.4 ug/L 03/27/15 14:34 7440-50-803/26/15 19:011.0 0.22 1 Iron 3140 ug/L 03/27/15 14:34 7439-89-603/26/15 19:0150.0 8.0 1 Lead 0.69 ug/L 03/27/15 14:34 7439-92-103/26/15 19:010.10 0.046 1 Magnesium 175 ug/L 03/27/15 14:34 7439-95-403/26/15 19:0110.0 2.8 1 Manganese 313 ug/L 03/27/15 14:34 7439-96-503/26/15 19:010.50 0.14 1 Molybdenum ND ug/L 03/27/15 14:34 7439-98-703/26/15 19:010.50 0.24 1 Nickel 0.57 ug/L 03/27/15 14:34 7440-02-003/26/15 19:010.50 0.23 1 Potassium 414 ug/L 03/27/15 14:34 7440-09-703/26/15 19:0150.0 8.3 1 Selenium ND ug/L 03/27/15 14:34 7782-49-203/26/15 19:010.50 0.25 1 Sodium 2300 ug/L 03/27/15 14:34 7440-23-503/26/15 19:0150.0 18.2 1 Strontium 12.1 ug/L 03/27/15 14:34 7440-24-603/26/15 19:010.50 0.057 1 Thallium ND ug/L 03/27/15 14:34 7440-28-003/26/15 19:010.10 0.025 1 Vanadium 7.0 ug/L 03/27/15 14:34 7440-62-203/26/15 19:011.0 0.21 1 Zinc ND ug/L 03/27/15 14:34 7440-66-603/26/15 19:015.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/27/15 13:04 7439-97-603/26/15 19:100.60 0.078 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 66 of 94 Page 84 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/12966 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92240158011, 92240158012, 92240158013, 92240158014, 92240158015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1917931 Associated Lab Samples:92240158011, 92240158012, 92240158013, 92240158014, 92240158015 Matrix:Water Analyzed Mercury ug/L ND 0.20 03/16/15 10:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1917932LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1917933MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92240164007 1917934 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 99 75-12585 15 205ND4.9 4.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 67 of 94 Page 85 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13071 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92240158016, 92240158017, 92240158018, 92240158019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1926030 Associated Lab Samples:92240158016, 92240158017, 92240158018, 92240158019 Matrix:Water Analyzed Mercury ug/L ND 0.20 03/27/15 12:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1926031LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.95 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1926032MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242374012 1926033 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L R158375-125102 21 205ND4.2 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 68 of 94 Page 86 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5474 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1157677 Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Matrix:Solid Analyzed Mercury mg/kg ND 0.0084 03/17/15 12:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1157678LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.081.079 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1157679MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540004 1157680 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg M1.0988 77 80-12074 4 20.09630.050 0.13 0.12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 69 of 94 Page 87 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23094 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1157065 Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Matrix:Solid Analyzed Aluminum mg/kg ND 5.0 03/17/15 08:02 Barium mg/kg ND 0.50 03/17/15 08:02 Beryllium mg/kg ND 0.050 03/17/15 08:02 Boron mg/kg ND 2.5 03/17/15 08:02 Calcium mg/kg ND 25.1 03/17/15 08:02 Chromium mg/kg ND 0.25 03/17/15 08:02 Copper mg/kg ND 0.25 03/17/15 08:02 Iron mg/kg ND 2.0 03/17/15 08:02 Magnesium mg/kg ND 25.1 03/17/15 08:02 Manganese mg/kg ND 0.25 03/17/15 08:02 Molybdenum mg/kg ND 0.50 03/17/15 08:02 Nickel mg/kg ND 0.25 03/17/15 08:02 Potassium mg/kg ND 50.1 03/17/15 08:02 Sodium mg/kg ND 50.1 03/17/15 08:02 Strontium mg/kg ND 0.50 03/17/15 08:02 Zinc mg/kg ND 1.0 03/17/15 08:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1157066LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 132127 103 80-120 Barium mg/kg 13.112.7 103 80-120 Beryllium mg/kg 1.21.3 98 80-120 Boron mg/kg 123127 97 80-120 Calcium mg/kg 646637 101 80-120 Chromium mg/kg 12.812.7 101 80-120 Copper mg/kg 12.612.7 99 80-120 Iron mg/kg 124127 98 80-120 Magnesium mg/kg 648637 102 80-120 Manganese mg/kg 12.412.7 97 80-120 Molybdenum mg/kg 12.312.7 96 80-120 Nickel mg/kg 12.712.7 99 80-120 Potassium mg/kg 614637 96 80-120 Sodium mg/kg 651637 102 80-120 Strontium mg/kg 12.412.7 98 80-120 Zinc mg/kg 63.363.7 99 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 70 of 94 Page 88 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1157067MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540001 1157068 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1,R1131118075-125756 23 20124144029902380 Barium mg/kg 13.1 117 75-125108 10 2012.45.1 20.5 18.5 Beryllium mg/kg 1.3 93 75-12596 2 201.20.033J 1.3 1.2 Boron mg/kg 131 89 75-12593 1 201241.5J 118 117 Calcium mg/kg 657 100 75-125102 3 2062235.3 689 668 Chromium mg/kg 13.1 101 75-125101 5 2012.42.0 15.2 14.5 Copper mg/kg 13.1 98 75-12599 4 2012.40.96 13.8 13.3 Iron mg/kg M113127875-125-2 17 20124196023201960 Magnesium mg/kg 657 107 75-125107 5 2062243.3 743 710 Manganese mg/kg 13.1 101 75-12597 8 2012.42.2 15.4 14.2 Molybdenum mg/kg 13.1 85 75-12588 2 2012.4ND 11.2 10.9 Nickel mg/kg 13.1 103 75-125100 8 2012.40.70 14.2 13.1 Potassium mg/kg 657 97 75-12598 4 2062233.7J 669 645 Sodium mg/kg 657 99 75-125101 3 20622ND658636 Strontium mg/kg 13.1 97 75-12599 4 2012.40.29J 13.1 12.6 Zinc mg/kg 65.7 98 75-12597 6 2062.23.6 67.9 64.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 71 of 94 Page 89 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23095 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1157069 Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Matrix:Solid Analyzed Antimony mg/kg ND 0.050 N203/17/15 11:05 Arsenic mg/kg ND 0.050 03/17/15 11:05 Cadmium mg/kg ND 0.0060 03/17/15 11:05 Cobalt mg/kg ND 0.050 03/17/15 11:05 Lead mg/kg ND 0.050 03/17/15 11:05 Selenium mg/kg ND 0.050 03/17/15 11:05 Thallium mg/kg ND 0.050 03/17/15 11:05 Vanadium mg/kg ND 0.050 03/17/15 11:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1157070LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.5 N22.5 99 80-120 Arsenic mg/kg 2.72.5 106 80-120 Cadmium mg/kg 0.25.25 99 80-120 Cobalt mg/kg 2.72.5 106 80-120 Lead mg/kg 2.52.5 101 80-120 Selenium mg/kg 2.72.5 108 80-120 Thallium mg/kg 2.52.5 99 80-120 Vanadium mg/kg 2.62.5 103 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1157071MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540002 1157072 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg D3,M6, N2 2.5 38 75-12534 202.5ND 0.99 0.91J Arsenic mg/kg D3,M62.5 67 75-12573 3 202.53.9 5.5 5.7 Cadmium mg/kg D3.25 103 75-125102 0 20.250.071J 0.33 0.33 Cobalt mg/kg D3,M62.5 57 75-125123 14 202.59.8 11.2 12.8 Lead mg/kg D32.5 85 75-125105 10 202.53.0 5.1 5.6 Selenium mg/kg D32.5 98 75-125100 2 202.50.83J 3.3 3.3 Thallium mg/kg D32.5 94 75-12596 3 202.50.64J 2.9 3.0 Vanadium mg/kg D4,M62.5 -84 75-125177 19 202.532.2 30.2 36.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 72 of 94 Page 90 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/52931 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92240158011, 92240158012, 92240158013, 92240158014, 92240158015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1917520 Associated Lab Samples:92240158011, 92240158012, 92240158013, 92240158014, 92240158015 Matrix:Water Analyzed Aluminum ug/L ND 10.0 03/16/15 09:43 Antimony ug/L ND 0.50 03/16/15 09:43 Arsenic ug/L ND 0.50 03/16/15 09:43 Barium ug/L ND 0.30 03/16/15 09:43 Beryllium ug/L ND 0.20 03/16/15 09:43 Boron ug/L ND 5.0 03/16/15 09:43 Cadmium ug/L ND 0.080 03/16/15 09:43 Calcium ug/L ND 40.0 03/16/15 09:43 Chromium ug/L ND 0.50 03/16/15 09:43 Cobalt ug/L ND 0.50 03/16/15 09:43 Copper ug/L ND 1.0 03/16/15 09:43 Iron ug/L ND 50.0 03/16/15 09:43 Lead ug/L ND 0.10 03/16/15 09:43 Magnesium ug/L ND 10.0 03/16/15 09:43 Manganese ug/L ND 0.50 03/16/15 09:43 Molybdenum ug/L ND 0.50 03/16/15 09:43 Nickel ug/L ND 0.50 03/16/15 09:43 Potassium ug/L ND 50.0 03/16/15 09:43 Selenium ug/L ND 0.50 03/16/15 09:43 Sodium ug/L ND 50.0 03/16/15 09:43 Strontium ug/L ND 0.50 03/16/15 09:43 Thallium ug/L ND 0.10 03/16/15 09:43 Vanadium ug/L ND 1.0 03/16/15 09:43 Zinc ug/L ND 5.0 03/16/15 09:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1917521LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 76.980 96 80-120 Antimony ug/L 79.480 99 80-120 Arsenic ug/L 79.080 99 80-120 Barium ug/L 80.780 101 80-120 Beryllium ug/L 82.880 104 80-120 Boron ug/L 81.180 101 80-120 Cadmium ug/L 80.080 100 80-120 Calcium ug/L 10001000 100 80-120 Chromium ug/L 79.980 100 80-120 Cobalt ug/L 80.880 101 80-120 Copper ug/L 77.480 97 80-120 Iron ug/L 10401000 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 73 of 94 Page 91 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1917521LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 80.980 101 80-120 Magnesium ug/L 10101000 101 80-120 Manganese ug/L 80.380 100 80-120 Molybdenum ug/L 79.580 99 80-120 Nickel ug/L 80.480 100 80-120 Potassium ug/L 10401000 104 80-120 Selenium ug/L 80.680 101 80-120 Sodium ug/L 9881000 99 80-120 Strontium ug/L 79.680 100 80-120 Thallium ug/L 79.180 99 80-120 Vanadium ug/L 80.680 101 80-120 Zinc ug/L 78.980 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1917522MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92240320006 1917523 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18023875-125274 8 2080168359387 Antimony ug/L 80 101 75-12598 3 2080ND80.9 78.9 Arsenic ug/L 80 100 75-12598 2 2080ND79.9 78.5 Barium ug/L 80 104 75-125101 2 208020.0 103 101 Beryllium ug/L 80 105 75-125106 1 2080ND84.1 85.0 Boron ug/L 80 117 75-125117 0 2080138232231 Cadmium ug/L 80 101 75-125100 2 2080ND81.1 79.6 Calcium ug/L M1100015175-125122 3 201000746089708670 Chromium ug/L 80 101 75-125100 1 2080ND81.4 80.3 Cobalt ug/L 80 103 75-125101 2 2080ND82.7 81.1 Copper ug/L 80 99 75-12598 1 2080ND79.8 79.0 Iron ug/L 1000 113 75-125113 0 20100049916301630 Lead ug/L 80 103 75-125102 1 20800.29 82.3 81.8 Magnesium ug/L 1000 118 75-125112 2 201000272039103840 Manganese ug/L 80 104 75-125102 2 208039.8 123 121 Molybdenum ug/L 80 101 75-12599 2 2080ND81.1 79.4 Nickel ug/L 80 102 75-125100 3 2080ND82.1 80.0 Potassium ug/L 1000 117 75-125110 3 201000147026402570 Selenium ug/L 80 102 75-125101 1 2080ND81.8 80.9 Sodium ug/L M1100014275-125123 3 201000577071907000 Strontium ug/L 80 103 75-125100 2 208047.2 130 127 Thallium ug/L 80 104 75-125103 1 2080ND83.1 82.3 Vanadium ug/L 80 103 75-125102 1 2080ND83.2 82.7 Zinc ug/L 80 103 75-125104 0 2080ND84.2 84.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 74 of 94 Page 92 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53205 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92240158016, 92240158017, 92240158018, 92240158019 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1926005 Associated Lab Samples:92240158016, 92240158017, 92240158018, 92240158019 Matrix:Water Analyzed Aluminum ug/L ND 10.0 03/27/15 13:48 Antimony ug/L ND 0.50 03/27/15 13:48 Arsenic ug/L ND 0.50 03/27/15 13:48 Barium ug/L ND 0.30 03/27/15 13:48 Beryllium ug/L ND 0.20 03/27/15 13:48 Boron ug/L ND 5.0 03/27/15 13:48 Cadmium ug/L ND 0.080 03/27/15 13:48 Calcium ug/L ND 40.0 03/27/15 13:48 Chromium ug/L ND 0.50 03/27/15 13:48 Cobalt ug/L ND 0.50 03/27/15 13:48 Copper ug/L ND 1.0 03/27/15 13:48 Iron ug/L ND 50.0 03/27/15 13:48 Lead ug/L ND 0.10 03/27/15 13:48 Magnesium ug/L ND 10.0 03/27/15 13:48 Manganese ug/L ND 0.50 03/27/15 13:48 Molybdenum ug/L ND 0.50 03/27/15 13:48 Nickel ug/L ND 0.50 03/27/15 13:48 Potassium ug/L ND 50.0 03/27/15 13:48 Selenium ug/L ND 0.50 03/27/15 13:48 Sodium ug/L ND 50.0 03/27/15 13:48 Strontium ug/L ND 0.50 03/27/15 13:48 Thallium ug/L ND 0.10 03/27/15 13:48 Vanadium ug/L ND 1.0 03/27/15 13:48 Zinc ug/L ND 5.0 03/27/15 13:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1926006LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 90.180 113 80-120 Antimony ug/L 81.480 102 80-120 Arsenic ug/L 81.980 102 80-120 Barium ug/L 86.180 108 80-120 Beryllium ug/L 81.980 102 80-120 Boron ug/L 84.780 106 80-120 Cadmium ug/L 86.880 108 80-120 Calcium ug/L 11001000 110 80-120 Chromium ug/L 87.480 109 80-120 Cobalt ug/L 85.980 107 80-120 Copper ug/L 85.180 106 80-120 Iron ug/L 11201000 112 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 75 of 94 Page 93 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1926006LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 85.080 106 80-120 Magnesium ug/L 10501000 105 80-120 Manganese ug/L 89.480 112 80-120 Molybdenum ug/L 84.480 105 80-120 Nickel ug/L 87.280 109 80-120 Potassium ug/L 10801000 108 80-120 Selenium ug/L 82.680 103 80-120 Sodium ug/L 10801000 108 80-120 Strontium ug/L 84.280 105 80-120 Thallium ug/L 88.780 111 80-120 Vanadium ug/L 86.880 108 80-120 Zinc ug/L 87.780 110 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1926431MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242374012 1926432 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M1,R18016675-125344 55 208057.4 190 332 Antimony ug/L 80 100 75-125100 0 2080ND79.8 80.0 Arsenic ug/L 80 101 75-125101 0 2080ND80.6 80.6 Barium ug/L 80 107 75-125105 1 20802.2 87.7 86.6 Beryllium ug/L 80 103 75-125102 2 2080ND82.7 81.4 Boron ug/L 80 108 75-125107 1 2080ND88.3 87.1 Cadmium ug/L 80 109 75-125109 0 2080ND87.1 87.1 Calcium ug/L 1000 106 75-125110 3 20100010211701200 Chromium ug/L 80 109 75-125108 1 20801.5 88.9 87.7 Cobalt ug/L 80 109 75-125108 1 2080ND87.1 86.2 Copper ug/L 80 107 75-125105 2 20801.3 86.6 85.2 Iron ug/L M1100011375-125131 10 20100055316801870 Lead ug/L 80 105 75-125103 2 20800.12 83.8 82.4 Magnesium ug/L 1000 107 75-125106 0 20100029.0 1100 1090 Manganese ug/L 80 111 75-125110 1 208013.6 102 101 Molybdenum ug/L 80 104 75-125104 0 2080ND83.0 83.2 Nickel ug/L 80 109 75-125108 1 20801.3 88.8 87.6 Potassium ug/L 1000 106 75-125106 0 201000ND11001100 Selenium ug/L 80 104 75-125104 0 2080ND82.9 82.9 Sodium ug/L 1000 108 75-125106 2 20100010811901170 Strontium ug/L 80 104 75-125103 1 20800.95 84.1 83.3 Thallium ug/L 80 110 75-125108 1 2080ND87.8 86.6 Vanadium ug/L 80 107 75-125105 1 2080ND85.8 84.6 Zinc ug/L 80 106 75-125105 1 208026.6 111 111 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 76 of 94 Page 94 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3347 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Dup Result Max RPD QualifiersRPDResult 35178663001 1157598SAMPLE DUPLICATE: Percent Moisture %23.3 2 1023.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92240158001 1157600SAMPLE DUPLICATE: Percent Moisture %35.2 1 1035.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 92239540004 1157619SAMPLE DUPLICATE: Percent Moisture %19.1 4 1020.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 77 of 94 Page 95 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36142 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Dup Result Max RPD QualifiersRPDResult 92240170008 1407673SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.7 3 105.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92240158003 1407674SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.1 1 106.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 78 of 94 Page 96 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22270 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1415171 Associated Lab Samples:92240158007, 92240158008, 92240158009, 92240158010 Matrix:Water Analyzed Sulfate mg/L ND 2.0 03/19/15 18:22 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1415172LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 18.720 94 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1415173MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540001 1415174 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 24 93 93 0243.5 25.8 25.8 Parameter Units MS Result % Rec Limits Qual% RecConc. 1415175MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92240158010 1415176 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 25.5 93 93 025.53.0 26.8 26.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 79 of 94 Page 97 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22256 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1413768 Associated Lab Samples:92240158007, 92240158008, 92240158009, 92240158010 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.22 0.020 B03/18/15 16:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1413769LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1413770MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540001 1413771 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H139590-11095 0 1030.41 3.3 3.3 Parameter Units MS Result % Rec Limits Qual% RecConc. 1413772MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540002 1413773 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.9 98 90-11098 0 102.90.33 3.2 3.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 80 of 94 Page 98 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22273 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1415463 Associated Lab Samples:92240158007, 92240158008, 92240158009, 92240158010 Matrix:Water Analyzed Chloride mg/L ND 1.0 03/19/15 20:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1415464LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 20.420 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1415465MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540003 1415466 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 23.9 101 90-110101 0 1023.9ND 24.7 24.6 Parameter Units MS Result % Rec Limits Qual% RecConc. 1415467MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239543006 1415468 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 24.7 102 90-110101 1 1024.75.7J 31.0 30.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 81 of 94 Page 99 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44508 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1155640 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 50.6 03/13/15 12:56 Sulfate mg/kg ND 50.6 03/13/15 12:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1155641LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 471504 94 80-120 Sulfate mg/kg 466504 92 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1155643MATRIX SPIKE SAMPLE: MSSpike Result 92239540001 Chloride mg/kg 423 M15006980-120ND Sulfate mg/kg 458 M15007880-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92239540001 1155642SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 82 of 94 Page 100 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44515 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1155845 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 48.9 03/13/15 15:40 Sulfate mg/kg ND 48.9 03/13/15 15:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1155846LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 477500 95 80-120 Sulfate mg/kg 480500 96 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1155848MATRIX SPIKE SAMPLE: MSSpike Result 92240158009 Chloride mg/kg 602717 84 80-120ND Sulfate mg/kg 610717 85 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92240158009 1155847SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 83 of 94 Page 101 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44533 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92240158005, 92240158006, 92240158007, 92240158008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1156870 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 50.0 03/14/15 18:25 Sulfate mg/kg ND 50.0 03/14/15 18:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1156871LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 498500 100 80-120 Sulfate mg/kg 500500 100 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1156873MATRIX SPIKE SAMPLE: MSSpike Result 92240158005 Chloride mg/kg 531544 98 80-120ND Sulfate mg/kg 547544 89 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92240158005 1156872SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 84 of 94 Page 102 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44509 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1155644 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.1 03/13/15 12:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1155645LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 47.950.4 95 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1155647MATRIX SPIKE SAMPLE: MSSpike Result 92239540001 Nitrate as N mg/kg 43.8 H3508580-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92239540001 1155646SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 85 of 94 Page 103 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44514 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1155832 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 4.9 03/13/15 15:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1155833LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 50.250 100 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1155835MATRIX SPIKE SAMPLE: MSSpike Result 92240158009 Nitrate as N mg/kg 61.0 H371.7 85 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92240158009 1155834SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 86 of 94 Page 104 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44534 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92240158005, 92240158006, 92240158007, 92240158008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1156874 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 03/14/15 18:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1156875LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 52.250 104 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1156877MATRIX SPIKE SAMPLE: MSSpike Result 92240158005 Nitrate as N mg/kg 55.7 H354.4 102 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92240158005 1156876SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 87 of 94 Page 105 of 113 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92240158 J15030202 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27544 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92240158001, 92240158002, 92240158003, 92240158004, 92240158005, 92240158006, 92240158007, 92240158008, 92240158009, 92240158010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1126431 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 03/13/15 09:23 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1126432LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 112000120000 93 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1126433MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92240158001 1126434 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 9270 104 50-150101 2 30928037501330013100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 88 of 94 Page 106 of 113 #=QL# QUALIFIERS Pace Project No.: Project: 92240158 J15030202 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Sample was diluted due to the presence of high levels of target analytes.D4 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 89 of 94 Page 107 of 113 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92240158001 MPRP/23094 ICP/141332015006511EPA 3050 EPA 6010 92240158002 MPRP/23094 ICP/141332015006512EPA 3050 EPA 6010 92240158003 MPRP/23094 ICP/141332015006514EPA 3050 EPA 6010 92240158004 MPRP/23094 ICP/141332015006518EPA 3050 EPA 6010 92240158005 MPRP/23094 ICP/141332015006520EPA 3050 EPA 6010 92240158006 MPRP/23094 ICP/141332015006523EPA 3050 EPA 6010 92240158007 MPRP/23094 ICP/141332015006515EPA 3050 EPA 6010 92240158008 MPRP/23094 ICP/141332015006516EPA 3050 EPA 6010 92240158009 MPRP/23094 ICP/141332015006521EPA 3050 EPA 6010 92240158010 MPRP/23094 ICP/141332015006524EPA 3050 EPA 6010 92240158001 MPRP/23095 ICPM/94202015006511EPA 3050 EPA 6020 92240158002 MPRP/23095 ICPM/94202015006512EPA 3050 EPA 6020 92240158003 MPRP/23095 ICPM/94202015006514EPA 3050 EPA 6020 92240158004 MPRP/23095 ICPM/94202015006518EPA 3050 EPA 6020 92240158005 MPRP/23095 ICPM/94202015006520EPA 3050 EPA 6020 92240158006 MPRP/23095 ICPM/94202015006523EPA 3050 EPA 6020 92240158007 MPRP/23095 ICPM/94202015006515EPA 3050 EPA 6020 92240158008 MPRP/23095 ICPM/94202015006516EPA 3050 EPA 6020 92240158009 MPRP/23095 ICPM/94202015006521EPA 3050 EPA 6020 92240158010 MPRP/23095 ICPM/94202015006524EPA 3050 EPA 6020 92240158011 MPRP/52931 ICPM/234622015006513EPA 3020 EPA 6020A 92240158012 MPRP/52931 ICPM/234622015006517EPA 3020 EPA 6020A 92240158013 MPRP/52931 ICPM/234622015006519EPA 3020 EPA 6020A 92240158014 MPRP/52931 ICPM/234622015006522EPA 3020 EPA 6020A 92240158015 MPRP/52931 ICPM/234622015006525EPA 3020 EPA 6020A 92240158016 MPRP/53205 ICPM/235722015006515 SPLP EPA 3020 EPA 6020A 92240158017 MPRP/53205 ICPM/235722015006516 SPLP EPA 3020 EPA 6020A 92240158018 MPRP/53205 ICPM/235722015006521 SPLP EPA 3020 EPA 6020A 92240158019 MPRP/53205 ICPM/235722015006524 SPLP EPA 3020 EPA 6020A 92240158011 MERP/12966 MERC/150512015006513EPA 7470 EPA 7470 92240158012 MERP/12966 MERC/150512015006517EPA 7470 EPA 7470 92240158013 MERP/12966 MERC/150512015006519EPA 7470 EPA 7470 92240158014 MERP/12966 MERC/150512015006522EPA 7470 EPA 7470 92240158015 MERP/12966 MERC/150512015006525EPA 7470 EPA 7470 92240158016 MERP/13071 MERC/151832015006515 SPLP EPA 7470 EPA 7470 92240158017 MERP/13071 MERC/151832015006516 SPLP EPA 7470 EPA 7470 92240158018 MERP/13071 MERC/151832015006521 SPLP EPA 7470 EPA 7470 92240158019 MERP/13071 MERC/151832015006524 SPLP EPA 7470 EPA 7470 92240158001 MERP/5474 MERC/54642015006511EPA 7471 EPA 7471 92240158002 MERP/5474 MERC/54642015006512EPA 7471 EPA 7471 92240158003 MERP/5474 MERC/54642015006514EPA 7471 EPA 7471 92240158004 MERP/5474 MERC/54642015006518EPA 7471 EPA 7471 92240158005 MERP/5474 MERC/54642015006520EPA 7471 EPA 7471 92240158006 MERP/5474 MERC/54642015006523EPA 7471 EPA 7471 92240158007 MERP/5474 MERC/54642015006515EPA 7471 EPA 7471 92240158008 MERP/5474 MERC/54642015006516EPA 7471 EPA 7471 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 90 of 94 Page 108 of 113 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92240158009 MERP/5474 MERC/54642015006521EPA 7471 EPA 7471 92240158010 MERP/5474 MERC/54642015006524EPA 7471 EPA 7471 92240158001 PMST/33472015006511ASTM D2974-87 92240158002 PMST/33472015006512ASTM D2974-87 92240158003 PMST/33472015006514ASTM D2974-87 92240158004 PMST/33472015006518ASTM D2974-87 92240158005 PMST/33472015006520ASTM D2974-87 92240158006 PMST/33472015006523ASTM D2974-87 92240158007 PMST/33472015006515ASTM D2974-87 92240158008 PMST/33472015006516ASTM D2974-87 92240158009 PMST/33472015006521ASTM D2974-87 92240158010 PMST/33472015006524ASTM D2974-87 92240158001 WET/361422015006511EPA 9045 92240158002 WET/361422015006512EPA 9045 92240158003 WET/361422015006514EPA 9045 92240158004 WET/361422015006518EPA 9045 92240158005 WET/361422015006520EPA 9045 92240158006 WET/361422015006523EPA 9045 92240158007 WET/361422015006515EPA 9045 92240158008 WET/361422015006516EPA 9045 92240158009 WET/361422015006521EPA 9045 92240158010 WET/361422015006524EPA 9045 92240158007 WETA/222702015006515EPA 300.0 92240158008 WETA/222702015006516EPA 300.0 92240158009 WETA/222702015006521EPA 300.0 92240158010 WETA/222702015006524EPA 300.0 92240158007 WETA/222562015006515EPA 353.2 92240158008 WETA/222562015006516EPA 353.2 92240158009 WETA/222562015006521EPA 353.2 92240158010 WETA/222562015006524EPA 353.2 92240158007 WETA/222732015006515SM 4500-Cl-E 92240158008 WETA/222732015006516SM 4500-Cl-E 92240158009 WETA/222732015006521SM 4500-Cl-E 92240158010 WETA/222732015006524SM 4500-Cl-E 92240158001 WETA/445082015006511EPA 9056 92240158002 WETA/445082015006512EPA 9056 92240158003 WETA/445082015006514EPA 9056 92240158004 WETA/445082015006518EPA 9056 92240158005 WETA/445332015006520EPA 9056 92240158006 WETA/445332015006523EPA 9056 92240158007 WETA/445332015006515EPA 9056 92240158008 WETA/445332015006516EPA 9056 92240158009 WETA/445152015006521EPA 9056 92240158010 WETA/445152015006524EPA 9056 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 91 of 94 Page 109 of 113 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92240158 J15030202 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92240158001 WETA/445092015006511EPA 9056 92240158002 WETA/445092015006512EPA 9056 92240158003 WETA/445092015006514EPA 9056 92240158004 WETA/445092015006518EPA 9056 92240158005 WETA/445342015006520EPA 9056 92240158006 WETA/445342015006523EPA 9056 92240158007 WETA/445342015006515EPA 9056 92240158008 WETA/445342015006516EPA 9056 92240158009 WETA/445142015006521EPA 9056 92240158010 WETA/445142015006524EPA 9056 92240158001 WETA/275442015006511EPA 9060 92240158001 WETA/275452015006511EPA 9060 92240158002 WETA/275442015006512EPA 9060 92240158002 WETA/275452015006512EPA 9060 92240158003 WETA/275442015006514EPA 9060 92240158003 WETA/275452015006514EPA 9060 92240158004 WETA/275442015006518EPA 9060 92240158004 WETA/275452015006518EPA 9060 92240158005 WETA/275442015006520EPA 9060 92240158005 WETA/275452015006520EPA 9060 92240158006 WETA/275442015006523EPA 9060 92240158006 WETA/275452015006523EPA 9060 92240158007 WETA/275442015006515EPA 9060 92240158007 WETA/275452015006515EPA 9060 92240158008 WETA/275442015006516EPA 9060 92240158008 WETA/275452015006516EPA 9060 92240158009 WETA/275442015006521EPA 9060 92240158009 WETA/275452015006521EPA 9060 92240158010 WETA/275442015006524EPA 9060 92240158010 WETA/275452015006524EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/30/2015 02:56 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 92 of 94 Page 110 of 113 Page 93 of 94 Page 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