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Home My WebLink AboutNC0038377_J15020646 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15020646 Project Name:AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:3/27/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr Page 1 of 63 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015005326 MAYO STEAM 23-Feb-15 2:25 PM illegible MW-10BR (13.0-13.75) 2015005327 MAYO STEAM 23-Feb-15 1:24 PM illegible MW-10BR (0.75-1.0) 2015005328 MAYO STEAM 23-Feb-15 12:40 PM illegible Equipment Blank MW-10BR 2015005329 MAYO STEAM 11-Feb-15 11:25 AM illegible Equipment Blank MW-8BR 2015005330 MAYO STEAM 16-Feb-15 12:48 PM illegible Equipment Blank MW-8S 5 Total Samples Page 2 of 63 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:3/27/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020646 2015005326 Collection Date:23-Feb-15 2:25 PM Site:MW-10BR (13.0-13.75) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 4 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020646 2015005327 Collection Date:23-Feb-15 1:24 PM Site:MW-10BR (0.75-1.0) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 5 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020646 2015005328 Collection Date:23-Feb-15 12:40 PM Site:Equipment Blank MW-10BR Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 6 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020646 2015005329 Collection Date:11-Feb-15 11:25 AM Site:Equipment Blank MW-8BR Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 7 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020646 2015005330 Collection Date:16-Feb-15 12:48 PM Site:Equipment Blank MW-8S Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 8 of 63 #=CL# March 18, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92238879 92238879 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15020646 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 25, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 54 Page 9 of 63 #=CP# CERTIFICATIONS Pace Project No.: Project: 92238879 J15020646 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Arizona Certification #: AZ0735 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 54 Page 10 of 63 #=CP# CERTIFICATIONS Pace Project No.: Project: 92238879 J15020646 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 54 Page 11 of 63 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92238879 J15020646 Lab ID Sample ID Matrix Date Collected Date Received 92238879001 2015005326 Solid 02/23/15 14:25 02/25/15 16:35 92238879002 2015005327 Solid 02/23/15 13:24 02/25/15 16:35 92238879003 2015005326 SPLP Water 02/23/15 14:25 02/25/15 16:35 92238879004 2015005328 Water 02/23/15 12:40 02/25/15 16:35 92238879005 2015005329 Water 02/11/15 11:25 02/25/15 16:35 92238879006 2015005330 Water 02/16/15 12:48 02/25/15 16:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 54 Page 12 of 63 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92238879 J15020646 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92238879001 2015005326 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OCMB EPA 9056 1 PASI-OCMB EPA 9060 6 PASI-GTJJ 92238879002 2015005327 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OGPW EPA 9045 1 PASI-AMLS EPA 9060 6 PASI-GTJJ 92238879003 2015005326 SPLP EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MJDD 92238879004 2015005328 EPA 6010 14 PASI-MIP EPA 6020A 10 PASI-MTT3 EPA 7470 1 PASI-MLMW 92238879005 2015005329 EPA 6010 14 PASI-MIP EPA 6020A 10 PASI-MTT3 EPA 7470 1 PASI-MLMW 92238879006 2015005330 EPA 6010 14 PASI-MIP EPA 6020A 10 PASI-MTT3 EPA 7470 1 PASI-MLMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 54 Page 13 of 63 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92238879 J15020646 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92238879001 2015005326 Aluminum 18700 mg/kg 03/05/15 09:03 D4,M655.7EPA 6010 Barium 479 mg/kg 03/05/15 09:03 D3,M65.6EPA 6010 Boron 26.4J mg/kg 03/05/15 09:03 D327.8EPA 6010 Calcium 1860 mg/kg 03/05/15 09:03 D3,M6278EPA 6010 Chromium 68.3 mg/kg 03/05/15 09:03 D3,M62.8EPA 6010 Copper 18.9 mg/kg 03/05/15 09:03 D3,M62.8EPA 6010 Iron 35500 mg/kg 03/05/15 09:03 D4,M622.3EPA 6010 Magnesium 17000 mg/kg 03/05/15 09:03 D4,M6278EPA 6010 Manganese 3200 mg/kg 03/05/15 09:03 D4,M62.8EPA 6010 Nickel 50.0 mg/kg 03/05/15 09:03 D32.8EPA 6010 Potassium 14300 mg/kg 03/05/15 09:03 D4,M6557EPA 6010 Sodium 416J mg/kg 03/05/15 09:03 D3557EPA 6010 Strontium 28.4 mg/kg 03/05/15 09:03 D35.6EPA 6010 Zinc 226 mg/kg 03/05/15 09:03 D311.1EPA 6010 Arsenic 1.1 mg/kg 03/04/15 16:34 D31.1EPA 6020 Beryllium 0.55 mg/kg 03/04/15 16:34 D30.13EPA 6020 Cadmium 0.51 mg/kg 03/04/15 16:34 D30.13EPA 6020 Cobalt 22.2 mg/kg 03/04/15 16:34 D31.1EPA 6020 Lead 3.5 mg/kg 03/04/15 16:34 D31.1EPA 6020 Selenium 1.7 mg/kg 03/04/15 16:34 D31.1EPA 6020 Thallium 0.97J mg/kg 03/04/15 16:34 D31.1EPA 6020 Vanadium 46.2 mg/kg 03/04/15 16:34 D41.1EPA 6020 Percent Moisture 7.5 %03/09/15 09:500.10ASTM D2974-87 pH at 25 Degrees C 8.0 Std. Units 03/02/15 12:050.10EPA 9045 Sulfate 3.5 mg/L 03/08/15 03:202.2EPA 300.0 Nitrogen, Nitrate 0.41 mg/L 03/11/15 13:00 B,H10.22EPA 353.2 Chloride 2.9J mg/L 03/10/15 03:535.4SM 4500-Cl-E RSD%4.6 %03/06/15 08:56EPA 9060 92238879002 2015005327 Aluminum 7640 mg/kg 03/04/15 17:285.7EPA 6010 Barium 81.8 mg/kg 03/04/15 17:280.57EPA 6010 Boron 13.6J mg/kg 03/05/15 09:29 D314.2EPA 6010 Calcium 1210 mg/kg 03/04/15 17:2828.3EPA 6010 Chromium 41.9 mg/kg 03/05/15 09:29 D31.4EPA 6010 Copper 28.9 mg/kg 03/05/15 09:29 D31.4EPA 6010 Iron 18600 mg/kg 03/05/15 09:29 D411.3EPA 6010 Magnesium 5590 mg/kg 03/04/15 17:2828.3EPA 6010 Manganese 527 mg/kg 03/05/15 09:29 D31.4EPA 6010 Nickel 16.3 mg/kg 03/04/15 17:280.28EPA 6010 Potassium 2660 mg/kg 03/04/15 17:2856.7EPA 6010 Sodium 93.4 mg/kg 03/04/15 17:2856.7EPA 6010 Strontium 9.4 mg/kg 03/04/15 17:280.57EPA 6010 Zinc 61.3 mg/kg 03/04/15 17:281.1EPA 6010 Arsenic 1.4 mg/kg 03/04/15 16:37 D31.1EPA 6020 Beryllium 0.40 mg/kg 03/04/15 16:37 D30.14EPA 6020 Cadmium 0.10J mg/kg 03/04/15 16:37 D30.14EPA 6020 Cobalt 12.4 mg/kg 03/04/15 16:37 D31.1EPA 6020 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 54 Page 14 of 63 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92238879 J15020646 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92238879002 2015005327 Lead 9.8 mg/kg 03/04/15 16:37 D31.1EPA 6020 Selenium 1.4 mg/kg 03/04/15 16:37 D31.1EPA 6020 Vanadium 35.1 mg/kg 03/04/15 16:37 D41.1EPA 6020 Mercury 0.0053J mg/kg 03/04/15 12:570.0097EPA 7471 Percent Moisture 15.2 %03/09/15 09:500.10ASTM D2974-87 pH at 25 Degrees C 6.3 Std. Units 03/02/15 12:050.10EPA 9045 Total Organic Carbon 684J mg/kg 03/05/15 15:58704EPA 9060 Total Organic Carbon 675J mg/kg 03/05/15 16:04703EPA 9060 Total Organic Carbon 849 mg/kg 03/05/15 16:09711EPA 9060 Total Organic Carbon 676J mg/kg 03/05/15 16:15712EPA 9060 Mean Total Organic Carbon 721 mg/kg 03/05/15 15:58708EPA 9060 RSD%11.9 %03/05/15 15:58EPA 9060 92238879003 2015005326 SPLP Aluminum 16400 ug/L 03/12/15 15:2110.0EPA 6020A Arsenic 2.9 ug/L 03/12/15 15:210.50EPA 6020A Barium 312 ug/L 03/12/15 15:210.30EPA 6020A Beryllium 0.68 ug/L 03/12/15 15:210.20EPA 6020A Boron 39.9 ug/L 03/12/15 15:215.0EPA 6020A Cadmium 0.27 ug/L 03/12/15 15:210.080EPA 6020A Calcium 3080 ug/L 03/12/15 15:2140.0EPA 6020A Chromium 38.9 ug/L 03/12/15 15:210.50EPA 6020A Cobalt 14.9 ug/L 03/12/15 15:210.50EPA 6020A Copper 24.6 ug/L 03/12/15 15:211.0EPA 6020A Iron 28600 ug/L 03/12/15 16:18500EPA 6020A Lead 3.8 ug/L 03/12/15 15:210.10EPA 6020A Magnesium 5900 ug/L 03/12/15 15:2110.0EPA 6020A Manganese 2170 ug/L 03/12/15 16:185.0EPA 6020A Molybdenum 1.5 ug/L 03/12/15 15:210.50EPA 6020A Nickel 20.8 ug/L 03/12/15 15:210.50EPA 6020A Potassium 3830 ug/L 03/12/15 15:2150.0EPA 6020A Selenium 1.1 ug/L 03/12/15 15:210.50EPA 6020A Sodium 7050 ug/L 03/12/15 15:2150.0EPA 6020A Strontium 44.4 ug/L 03/12/15 15:210.50EPA 6020A Thallium 0.17 ug/L 03/12/15 15:210.10EPA 6020A Vanadium 49.9 ug/L 03/12/15 15:211.0EPA 6020A Zinc 107 ug/L 03/12/15 15:215.0EPA 6020A 92238879004 2015005328 Boron 963 ug/L 03/03/15 08:45150EPA 6010 Chromium 32.6 ug/L 03/02/15 18:0510.0EPA 6010 Iron 3630 ug/L 03/02/15 18:0550.0EPA 6010 Manganese 137 ug/L 03/02/15 18:055.0EPA 6010 Zinc 69.8 ug/L 03/02/15 18:0520.0EPA 6010 Cobalt 1.3 ug/L 03/02/15 12:470.50EPA 6020A Lead 8.7 ug/L 03/02/15 12:470.10EPA 6020A Strontium 1.9 ug/L 03/02/15 12:470.50EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 54 Page 15 of 63 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92238879 J15020646 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92238879005 2015005329 Cobalt 1.8 ug/L 03/02/15 12:490.50EPA 6020A 92238879006 2015005330 Iron 177 ug/L 03/02/15 18:1450.0EPA 6010 Manganese 5.5 ug/L 03/02/15 18:145.0EPA 6010 Cobalt 0.61 ug/L 03/02/15 12:520.50EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 54 Page 16 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 6010 Date:March 18, 2015 Description:6010 MET ICP General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22893 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238879001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1144537) • Aluminum • Barium • Calcium • Chromium • Copper • Iron • Magnesium • Manganese • Molybdenum • Potassium • MSD (Lab ID: 1144538) • Aluminum • Barium • Calcium • Chromium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 54 Page 17 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 6010 Date:March 18, 2015 Description:6010 MET ICP QC Batch: MPRP/22893 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238879001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Copper • Iron • Magnesium • Manganese • Molybdenum • Potassium Additional Comments: Analyte Comments: QC Batch: MPRP/22893 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015005326 (Lab ID: 92238879001) • Boron • Barium • Calcium • Chromium • Copper • Molybdenum • Sodium • Nickel • Strontium • Zinc • 2015005327 (Lab ID: 92238879002) • Boron • Chromium • Copper • Manganese D4: Sample was diluted due to the presence of high levels of target analytes. • 2015005326 (Lab ID: 92238879001) • Aluminum • Iron • Potassium • Magnesium • Manganese • 2015005327 (Lab ID: 92238879002) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 54 Page 18 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 6020 Date:March 18, 2015 Description:6020 MET ICPMS General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22894 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238666007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1144541) • Antimony • Arsenic • Selenium • MSD (Lab ID: 1144542) • Antimony • Arsenic • Lead • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 54 Page 19 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 6020 Date:March 18, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/22894 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015005326 (Lab ID: 92238879001) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • 2015005327 (Lab ID: 92238879002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1144541) • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MSD (Lab ID: 1144542) • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. • 2015005326 (Lab ID: 92238879001) • Vanadium • 2015005327 (Lab ID: 92238879002) • Vanadium • MS (Lab ID: 1144541) • Arsenic • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 54 Page 20 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 6020 Date:March 18, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/22894 D4: Sample was diluted due to the presence of high levels of target analytes. • MSD (Lab ID: 1144542) • Arsenic • Vanadium N2: The lab does not hold TNI accreditation for this parameter. • 2015005326 (Lab ID: 92238879001) • Antimony • 2015005327 (Lab ID: 92238879002) • Antimony • BLANK (Lab ID: 1144539) • Antimony • LCS (Lab ID: 1144540) • Antimony • MS (Lab ID: 1144541) • Antimony • MSD (Lab ID: 1144542) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 54 Page 21 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 6020A Date:March 18, 2015 Description:6020A MET ICPMS General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52897 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540010 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1916666) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 54 Page 22 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 7470 Date:March 18, 2015 Description:7470 Mercury General Information: 4 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 54 Page 23 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 7471 Date:March 18, 2015 Description:7471 Mercury General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5420 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35176987001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1144517) • Mercury R1: RPD value was outside control limits. • MSD (Lab ID: 1144518) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 54 Page 24 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 9045 Date:March 18, 2015 Description:9045 pH Soil General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/35950 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1400248) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 54 Page 25 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 300.0 Date:March 18, 2015 Description:300.0 IC Anions, SPLP General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 54 Page 26 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 353.2 Date:March 18, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015005326 (Lab ID: 92238879001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22179 B: Analyte was detected in the associated method blank. • BLANK for HBN 255082 [WETA/221 (Lab ID: 1407887) • Nitrogen, Nitrate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 54 Page 27 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy SM 4500-Cl-E Date:March 18, 2015 Description:4500 Chloride, SPLP General Information: 1 sample was analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 54 Page 28 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 9056 Date:March 18, 2015 Description:9056 IC Anions General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44073 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015005326 (Lab ID: 92238879001) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 54 Page 29 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 9056 Date:March 18, 2015 Description:9056 IC Anions 48hr General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015005326 (Lab ID: 92238879001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44074 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015005326 (Lab ID: 92238879001) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 54 Page 30 of 63 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92238879 J15020646 Method: Client:Duke Energy EPA 9060 Date:March 18, 2015 Description:Total Organic Carbon Quad General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 54 Page 31 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005326 Lab ID:92238879001 Collected:02/23/15 14:25 Received:02/25/15 16:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 18700 mg/kg 03/05/15 09:03 7429-90-5 D4,M603/04/15 05:3055.7 27.8 10 Barium 479 mg/kg 03/05/15 09:03 7440-39-3 D3,M603/04/15 05:305.6 2.8 10 Boron 26.4J mg/kg 03/05/15 09:03 7440-42-8 D303/04/15 05:3027.8 13.9 10 Calcium 1860 mg/kg 03/05/15 09:03 7440-70-2 D3,M603/04/15 05:3027813910 Chromium 68.3 mg/kg 03/05/15 09:03 7440-47-3 D3,M603/04/15 05:302.8 1.4 10 Copper 18.9 mg/kg 03/05/15 09:03 7440-50-8 D3,M603/04/15 05:302.8 1.4 10 Iron 35500 mg/kg 03/05/15 09:03 7439-89-6 D4,M603/04/15 05:3022.3 11.1 10 Magnesium 17000 mg/kg 03/05/15 09:03 7439-95-4 D4,M603/04/15 05:3027813910 Manganese 3200 mg/kg 03/05/15 09:03 7439-96-5 D4,M603/04/15 05:302.8 1.4 10 Molybdenum ND mg/kg 03/05/15 09:03 7439-98-7 D3,M603/04/15 05:305.6 2.8 10 Nickel 50.0 mg/kg 03/05/15 09:03 7440-02-0 D303/04/15 05:302.8 1.4 10 Potassium 14300 mg/kg 03/05/15 09:03 7440-09-7 D4,M603/04/15 05:3055727810 Sodium 416J mg/kg 03/05/15 09:03 7440-23-5 D303/04/15 05:3055727810 Strontium 28.4 mg/kg 03/05/15 09:03 7440-24-6 D303/04/15 05:305.6 2.8 10 Zinc 226 mg/kg 03/05/15 09:03 7440-66-6 D303/04/15 05:3011.1 5.6 10 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/04/15 16:34 7440-36-0 D3,N203/04/15 05:301.1 0.56 20 Arsenic 1.1 mg/kg 03/04/15 16:34 7440-38-2 D303/04/15 05:301.1 0.56 20 Beryllium 0.55 mg/kg 03/04/15 16:34 7440-41-7 D303/04/15 05:300.13 0.067 20 Cadmium 0.51 mg/kg 03/04/15 16:34 7440-43-9 D303/04/15 05:300.13 0.067 20 Cobalt 22.2 mg/kg 03/04/15 16:34 7440-48-4 D303/04/15 05:301.1 0.56 20 Lead 3.5 mg/kg 03/04/15 16:34 7439-92-1 D303/04/15 05:301.1 0.56 20 Selenium 1.7 mg/kg 03/04/15 16:34 7782-49-2 D303/04/15 05:301.1 0.56 20 Thallium 0.97J mg/kg 03/04/15 16:34 7440-28-0 D303/04/15 05:301.1 0.56 20 Vanadium 46.2 mg/kg 03/04/15 16:34 7440-62-2 D403/04/15 05:301.1 0.56 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 03/04/15 12:55 7439-97-603/04/15 06:400.0086 0.0043 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 7.5 %03/09/15 09:500.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.0 Std. Units 03/02/15 12:050.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/02/15 17:45300.0 IC Anions, SPLP Sulfate 3.5 mg/L 03/08/15 03:20 14808-79-82.2 1.1 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/02/15 17:45353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.41 mg/L 03/11/15 13:00 B,H10.22 0.22 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 03/02/15 17:454500 Chloride, SPLP Chloride 2.9J mg/L 03/10/15 03:53 16887-00-65.4 2.7 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 54 Page 32 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005326 Lab ID:92238879001 Collected:02/23/15 14:25 Received:02/25/15 16:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 03/01/15 05:00 16887-00-6 D32691345 Sulfate ND mg/kg 03/01/15 05:00 14808-79-8 D32691345 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 03/01/15 05:00 14797-55-8 D3,H326.9 13.4 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 03/06/15 08:56 7440-44-06493241 Total Organic Carbon ND mg/kg 03/06/15 09:01 7440-44-06483241 Total Organic Carbon ND mg/kg 03/06/15 09:06 7440-44-06473231 Total Organic Carbon ND mg/kg 03/06/15 09:13 7440-44-06513261 Mean Total Organic Carbon ND mg/kg 03/06/15 08:56 7440-44-06493241 Surrogates RSD%4.6 %03/06/15 08:561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 54 Page 33 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005327 Lab ID:92238879002 Collected:02/23/15 13:24 Received:02/25/15 16:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7640 mg/kg 03/04/15 17:28 7429-90-503/04/15 05:305.7 2.8 1 Barium 81.8 mg/kg 03/04/15 17:28 7440-39-303/04/15 05:300.57 0.28 1 Boron 13.6J mg/kg 03/05/15 09:29 7440-42-8 D303/04/15 05:3014.2 7.1 5 Calcium 1210 mg/kg 03/04/15 17:28 7440-70-203/04/15 05:3028.3 14.2 1 Chromium 41.9 mg/kg 03/05/15 09:29 7440-47-3 D303/04/15 05:301.4 0.71 5 Copper 28.9 mg/kg 03/05/15 09:29 7440-50-8 D303/04/15 05:301.4 0.71 5 Iron 18600 mg/kg 03/05/15 09:29 7439-89-6 D403/04/15 05:3011.3 5.7 5 Magnesium 5590 mg/kg 03/04/15 17:28 7439-95-403/04/15 05:3028.3 14.2 1 Manganese 527 mg/kg 03/05/15 09:29 7439-96-5 D303/04/15 05:301.4 0.71 5 Molybdenum ND mg/kg 03/04/15 17:28 7439-98-703/04/15 05:300.57 0.28 1 Nickel 16.3 mg/kg 03/04/15 17:28 7440-02-003/04/15 05:300.28 0.14 1 Potassium 2660 mg/kg 03/04/15 17:28 7440-09-703/04/15 05:3056.7 28.3 1 Sodium 93.4 mg/kg 03/04/15 17:28 7440-23-503/04/15 05:3056.7 28.3 1 Strontium 9.4 mg/kg 03/04/15 17:28 7440-24-603/04/15 05:300.57 0.28 1 Zinc 61.3 mg/kg 03/04/15 17:28 7440-66-603/04/15 05:301.1 0.57 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 03/04/15 16:37 7440-36-0 D3,N203/04/15 05:301.1 0.57 20 Arsenic 1.4 mg/kg 03/04/15 16:37 7440-38-2 D303/04/15 05:301.1 0.57 20 Beryllium 0.40 mg/kg 03/04/15 16:37 7440-41-7 D303/04/15 05:300.14 0.068 20 Cadmium 0.10J mg/kg 03/04/15 16:37 7440-43-9 D303/04/15 05:300.14 0.068 20 Cobalt 12.4 mg/kg 03/04/15 16:37 7440-48-4 D303/04/15 05:301.1 0.57 20 Lead 9.8 mg/kg 03/04/15 16:37 7439-92-1 D303/04/15 05:301.1 0.57 20 Selenium 1.4 mg/kg 03/04/15 16:37 7782-49-2 D303/04/15 05:301.1 0.57 20 Thallium ND mg/kg 03/04/15 16:37 7440-28-0 D303/04/15 05:301.1 0.57 20 Vanadium 35.1 mg/kg 03/04/15 16:37 7440-62-2 D403/04/15 05:301.1 0.57 20 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0053J mg/kg 03/04/15 12:57 7439-97-603/04/15 06:400.0097 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 15.2 %03/09/15 09:500.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.3 Std. Units 03/02/15 12:050.10 0.10 1 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 684J mg/kg 03/05/15 15:58 7440-44-07043521 Total Organic Carbon 675J mg/kg 03/05/15 16:04 7440-44-07033521 Total Organic Carbon 849 mg/kg 03/05/15 16:09 7440-44-07113561 Total Organic Carbon 676J mg/kg 03/05/15 16:15 7440-44-07123561 Mean Total Organic Carbon 721 mg/kg 03/05/15 15:58 7440-44-07083541 Surrogates RSD%11.9 %03/05/15 15:581 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 54 Page 34 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005326 SPLP Lab ID:92238879003 Collected:02/23/15 14:25 Received:02/25/15 16:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 16400 ug/L 03/12/15 15:21 7429-90-503/12/15 10:1210.0 1.2 1 Antimony ND ug/L 03/12/15 15:21 7440-36-003/12/15 10:120.50 0.25 1 Arsenic 2.9 ug/L 03/12/15 15:21 7440-38-203/12/15 10:120.50 0.25 1 Barium 312 ug/L 03/12/15 15:21 7440-39-303/12/15 10:120.30 0.14 1 Beryllium 0.68 ug/L 03/12/15 15:21 7440-41-703/12/15 10:120.20 0.066 1 Boron 39.9 ug/L 03/12/15 15:21 7440-42-803/12/15 10:125.0 1.0 1 Cadmium 0.27 ug/L 03/12/15 15:21 7440-43-903/12/15 10:120.080 0.033 1 Calcium 3080 ug/L 03/12/15 15:21 7440-70-203/12/15 10:1240.0 8.4 1 Chromium 38.9 ug/L 03/12/15 15:21 7440-47-303/12/15 10:120.50 0.22 1 Cobalt 14.9 ug/L 03/12/15 15:21 7440-48-403/12/15 10:120.50 0.25 1 Copper 24.6 ug/L 03/12/15 15:21 7440-50-803/12/15 10:121.0 0.22 1 Iron 28600 ug/L 03/12/15 16:18 7439-89-603/12/15 10:1250080.2 10 Lead 3.8 ug/L 03/12/15 15:21 7439-92-103/12/15 10:120.10 0.046 1 Magnesium 5900 ug/L 03/12/15 15:21 7439-95-403/12/15 10:1210.0 2.8 1 Manganese 2170 ug/L 03/12/15 16:18 7439-96-503/12/15 10:125.0 1.4 10 Molybdenum 1.5 ug/L 03/12/15 15:21 7439-98-703/12/15 10:120.50 0.24 1 Nickel 20.8 ug/L 03/12/15 15:21 7440-02-003/12/15 10:120.50 0.23 1 Potassium 3830 ug/L 03/12/15 15:21 7440-09-703/12/15 10:1250.0 8.3 1 Selenium 1.1 ug/L 03/12/15 15:21 7782-49-203/12/15 10:120.50 0.25 1 Sodium 7050 ug/L 03/12/15 15:21 7440-23-503/12/15 10:1250.0 18.2 1 Strontium 44.4 ug/L 03/12/15 15:21 7440-24-603/12/15 10:120.50 0.057 1 Thallium 0.17 ug/L 03/12/15 15:21 7440-28-003/12/15 10:120.10 0.025 1 Vanadium 49.9 ug/L 03/12/15 15:21 7440-62-203/12/15 10:121.0 0.21 1 Zinc 107 ug/L 03/12/15 15:21 7440-66-603/12/15 10:125.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/17/15 11:12 7439-97-603/16/15 11:150.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 54 Page 35 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005328 Lab ID:92238879004 Collected:02/23/15 12:40 Received:02/25/15 16:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Aluminum ND ug/L 03/02/15 18:05 7429-90-503/02/15 10:2620018.4 1 Barium ND ug/L 03/02/15 18:05 7440-39-303/02/15 10:2610.0 5.0 1 Boron 963 ug/L 03/03/15 08:45 7440-42-803/02/15 10:2615075.0 1 Calcium ND ug/L 03/02/15 18:05 7440-70-203/02/15 10:265002501 Chromium 32.6 ug/L 03/02/15 18:05 7440-47-303/02/15 10:2610.0 5.0 1 Copper ND ug/L 03/02/15 18:05 7440-50-803/02/15 10:2610.0 1.2 1 Iron 3630 ug/L 03/02/15 18:05 7439-89-603/02/15 10:2650.0 4.8 1 Magnesium ND ug/L 03/02/15 18:05 7439-95-403/02/15 10:265002501 Manganese 137 ug/L 03/02/15 18:05 7439-96-503/02/15 10:265.0 2.5 1 Molybdenum ND ug/L 03/02/15 18:05 7439-98-703/02/15 10:2615.0 2.3 1 Nickel ND ug/L 03/02/15 18:05 7440-02-003/02/15 10:2620.0 10.0 1 Potassium ND ug/L 03/02/15 18:05 7440-09-703/02/15 10:26250012501 Sodium ND ug/L 03/02/15 18:05 7440-23-503/02/15 10:2610005001 Zinc 69.8 ug/L 03/02/15 18:05 7440-66-603/02/15 10:2620.0 4.6 1 Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Antimony ND ug/L 03/02/15 12:47 7440-36-003/02/15 10:140.50 0.25 1 Arsenic ND ug/L 03/02/15 12:47 7440-38-203/02/15 10:140.50 0.25 1 Beryllium ND ug/L 03/02/15 12:47 7440-41-703/02/15 10:140.20 0.066 1 Cadmium ND ug/L 03/02/15 12:47 7440-43-903/02/15 10:140.080 0.033 1 Cobalt 1.3 ug/L 03/02/15 12:47 7440-48-403/02/15 10:140.50 0.25 1 Lead 8.7 ug/L 03/02/15 12:47 7439-92-103/02/15 10:140.10 0.046 1 Selenium ND ug/L 03/02/15 12:47 7782-49-203/02/15 10:140.50 0.25 1 Strontium 1.9 ug/L 03/02/15 12:47 7440-24-603/02/15 10:140.50 0.057 1 Thallium ND ug/L 03/02/15 12:47 7440-28-003/02/15 10:140.10 0.025 1 Vanadium ND ug/L 03/02/15 12:47 7440-62-203/02/15 10:141.0 0.21 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/04/15 12:45 7439-97-603/02/15 10:500.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 54 Page 36 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005329 Lab ID:92238879005 Collected:02/11/15 11:25 Received:02/25/15 16:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Aluminum ND ug/L 03/02/15 18:09 7429-90-503/02/15 10:2620018.4 1 Barium ND ug/L 03/02/15 18:09 7440-39-303/02/15 10:2610.0 5.0 1 Boron ND ug/L 03/03/15 08:54 7440-42-803/02/15 10:2615075.0 1 Calcium ND ug/L 03/02/15 18:09 7440-70-203/02/15 10:265002501 Chromium ND ug/L 03/02/15 18:09 7440-47-303/02/15 10:2610.0 5.0 1 Copper ND ug/L 03/02/15 18:09 7440-50-803/02/15 10:2610.0 1.2 1 Iron ND ug/L 03/02/15 18:09 7439-89-603/02/15 10:2650.0 4.8 1 Magnesium ND ug/L 03/02/15 18:09 7439-95-403/02/15 10:265002501 Manganese ND ug/L 03/02/15 18:09 7439-96-503/02/15 10:265.0 2.5 1 Molybdenum ND ug/L 03/02/15 18:09 7439-98-703/02/15 10:2615.0 2.3 1 Nickel ND ug/L 03/02/15 18:09 7440-02-003/02/15 10:2620.0 10.0 1 Potassium ND ug/L 03/02/15 18:09 7440-09-703/02/15 10:26250012501 Sodium ND ug/L 03/02/15 18:09 7440-23-503/02/15 10:2610005001 Zinc ND ug/L 03/02/15 18:09 7440-66-603/02/15 10:2620.0 4.6 1 Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Antimony ND ug/L 03/02/15 12:49 7440-36-003/02/15 10:140.50 0.25 1 Arsenic ND ug/L 03/02/15 12:49 7440-38-203/02/15 10:140.50 0.25 1 Beryllium ND ug/L 03/02/15 12:49 7440-41-703/02/15 10:140.20 0.066 1 Cadmium ND ug/L 03/02/15 12:49 7440-43-903/02/15 10:140.080 0.033 1 Cobalt 1.8 ug/L 03/02/15 12:49 7440-48-403/02/15 10:140.50 0.25 1 Lead ND ug/L 03/02/15 12:49 7439-92-103/02/15 10:140.10 0.046 1 Selenium ND ug/L 03/02/15 12:49 7782-49-203/02/15 10:140.50 0.25 1 Strontium ND ug/L 03/02/15 12:49 7440-24-603/02/15 10:140.50 0.057 1 Thallium ND ug/L 03/02/15 12:49 7440-28-003/02/15 10:140.10 0.025 1 Vanadium ND ug/L 03/02/15 12:49 7440-62-203/02/15 10:141.0 0.21 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/04/15 12:47 7439-97-603/02/15 10:500.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 54 Page 37 of 63 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92238879 J15020646 Sample:2015005330 Lab ID:92238879006 Collected:02/16/15 12:48 Received:02/25/15 16:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Aluminum ND ug/L 03/02/15 18:14 7429-90-503/02/15 10:2620018.4 1 Barium ND ug/L 03/02/15 18:14 7440-39-303/02/15 10:2610.0 5.0 1 Boron ND ug/L 03/03/15 08:58 7440-42-803/02/15 10:2615075.0 1 Calcium ND ug/L 03/02/15 18:14 7440-70-203/02/15 10:265002501 Chromium ND ug/L 03/02/15 18:14 7440-47-303/02/15 10:2610.0 5.0 1 Copper ND ug/L 03/02/15 18:14 7440-50-803/02/15 10:2610.0 1.2 1 Iron 177 ug/L 03/02/15 18:14 7439-89-603/02/15 10:2650.0 4.8 1 Magnesium ND ug/L 03/02/15 18:14 7439-95-403/02/15 10:265002501 Manganese 5.5 ug/L 03/02/15 18:14 7439-96-503/02/15 10:265.0 2.5 1 Molybdenum ND ug/L 03/02/15 18:14 7439-98-703/02/15 10:2615.0 2.3 1 Nickel ND ug/L 03/02/15 18:14 7440-02-003/02/15 10:2620.0 10.0 1 Potassium ND ug/L 03/02/15 18:14 7440-09-703/02/15 10:26250012501 Sodium ND ug/L 03/02/15 18:14 7440-23-503/02/15 10:2610005001 Zinc ND ug/L 03/02/15 18:14 7440-66-603/02/15 10:2620.0 4.6 1 Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Antimony ND ug/L 03/02/15 12:52 7440-36-003/02/15 10:140.50 0.25 1 Arsenic ND ug/L 03/02/15 12:52 7440-38-203/02/15 10:140.50 0.25 1 Beryllium ND ug/L 03/02/15 12:52 7440-41-703/02/15 10:140.20 0.066 1 Cadmium ND ug/L 03/02/15 12:52 7440-43-903/02/15 10:140.080 0.033 1 Cobalt 0.61 ug/L 03/02/15 12:52 7440-48-403/02/15 10:140.50 0.25 1 Lead ND ug/L 03/02/15 12:52 7439-92-103/02/15 10:140.10 0.046 1 Selenium ND ug/L 03/02/15 12:52 7782-49-203/02/15 10:140.50 0.25 1 Strontium ND ug/L 03/02/15 12:52 7440-24-603/02/15 10:140.50 0.057 1 Thallium ND ug/L 03/02/15 12:52 7440-28-003/02/15 10:140.10 0.025 1 Vanadium ND ug/L 03/02/15 12:52 7440-62-203/02/15 10:141.0 0.21 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 03/04/15 12:50 7439-97-603/02/15 10:500.20 0.026 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 54 Page 38 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/12854 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92238879004, 92238879005, 92238879006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1908523 Associated Lab Samples:92238879004, 92238879005, 92238879006 Matrix:Water Analyzed Mercury ug/L ND 0.20 03/04/15 12:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1908524LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.15 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1909276MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238878005 1909277 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 106 75-125101 4 205ND5.3 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 54 Page 39 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/12947 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92238879003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1916161 Associated Lab Samples:92238879003 Matrix:Water Analyzed Mercury ug/L ND 0.20 03/17/15 10:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1916162LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1916612MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92240170035 1916613 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 97 75-12597 0 205ND4.9 4.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 54 Page 40 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5420 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92238879001, 92238879002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1144515 Associated Lab Samples:92238879001, 92238879002 Matrix:Solid Analyzed Mercury mg/kg ND 0.0082 03/04/15 12:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1144516LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.083.083 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1144517MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35176987001 1144518 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg M1,R11.02 43 80-120106 27 20.8751.1 1.6 2.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 54 Page 41 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/22893 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92238879001, 92238879002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1144535 Associated Lab Samples:92238879001, 92238879002 Matrix:Solid Analyzed Aluminum mg/kg ND 5.1 03/04/15 16:22 Barium mg/kg ND 0.51 03/04/15 16:22 Boron mg/kg ND 2.5 03/04/15 16:22 Calcium mg/kg ND 25.3 03/04/15 16:22 Chromium mg/kg ND 0.25 03/04/15 16:22 Copper mg/kg ND 0.25 03/04/15 16:22 Iron mg/kg ND 2.0 03/04/15 16:22 Magnesium mg/kg ND 25.3 03/04/15 16:22 Manganese mg/kg ND 0.25 03/04/15 16:22 Molybdenum mg/kg ND 0.51 03/04/15 16:22 Nickel mg/kg ND 0.25 03/04/15 16:22 Potassium mg/kg ND 50.6 03/04/15 16:22 Sodium mg/kg ND 50.6 03/04/15 16:22 Strontium mg/kg ND 0.51 03/04/15 16:22 Zinc mg/kg ND 1.0 03/04/15 16:22 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1144536LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 123127 97 80-120 Barium mg/kg 13.012.7 102 80-120 Boron mg/kg 125127 98 80-120 Calcium mg/kg 627637 98 80-120 Chromium mg/kg 12.512.7 98 80-120 Copper mg/kg 12.312.7 97 80-120 Iron mg/kg 113127 89 80-120 Magnesium mg/kg 595637 93 80-120 Manganese mg/kg 12.612.7 99 80-120 Molybdenum mg/kg 12.412.7 97 80-120 Nickel mg/kg 12.712.7 99 80-120 Potassium mg/kg 632637 99 80-120 Sodium mg/kg 665637 104 80-120 Strontium mg/kg 12.612.7 99 80-120 Zinc mg/kg 63.963.7 100 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 54 Page 42 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1144537MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238879001 1144538 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M6135151075-1251950 3 20137187002080021400 Barium mg/kg M613.5 -1470 75-125-1700 13 2013.7479 280 245 Boron mg/kg 135 95 75-12591 2 2013726.4J 155 151 Calcium mg/kg M667517275-125163 1 20687186030202980 Chromium mg/kg M613.5 165 75-125184 3 2013.768.3 90.6 93.6 Copper mg/kg M613.5 67 75-12554 6 2013.718.9 27.9 26.4 Iron mg/kg M6135-644 75-125233 3 20137355003460035800 Magnesium mg/kg M667543975-125555 4 20687170002000020800 Manganese mg/kg M613.5 -6390 75-125-8250 12 2013.73200 2340 2070 Molybdenum mg/kg M613.5 53 75-12554 3 2013.7ND 7.9 8.1 Nickel mg/kg 13.5 85 75-125122 8 2013.750.0 61.5 66.8 Potassium mg/kg M667546875-125492 1 20687143001740017600 Sodium mg/kg 675 103 75-125104 2 20687416J11101130 Strontium mg/kg 13.5 85 75-12579 2 2013.728.4 39.9 39.2 Zinc mg/kg 67.5 110 75-125114 1 2068.7226 300 304 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 54 Page 43 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/52678 EPA 3010 EPA 6010 6010 MET Associated Lab Samples:92238879004, 92238879005, 92238879006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1908505 Associated Lab Samples:92238879004, 92238879005, 92238879006 Matrix:Water Analyzed Aluminum ug/L ND 200 03/02/15 17:24 Barium ug/L ND 10.0 03/02/15 17:24 Boron ug/L ND 150 03/03/15 08:05 Calcium ug/L ND 500 03/02/15 17:24 Chromium ug/L ND 10.0 03/02/15 17:24 Copper ug/L ND 10.0 03/02/15 17:24 Iron ug/L ND 50.0 03/02/15 17:24 Magnesium ug/L ND 500 03/02/15 17:24 Manganese ug/L ND 5.0 03/02/15 17:24 Molybdenum ug/L ND 15.0 03/02/15 17:24 Nickel ug/L ND 20.0 03/02/15 17:24 Potassium ug/L ND 2500 03/02/15 17:24 Sodium ug/L ND 1000 03/02/15 17:24 Zinc ug/L ND 20.0 03/02/15 17:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1908506LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 919010000 92 80-120 Barium ug/L 9571000 96 80-120 Boron ug/L 9091000 91 80-120 Calcium ug/L 1000010000 100 80-120 Chromium ug/L 9451000 95 80-120 Copper ug/L 9561000 96 80-120 Iron ug/L 955010000 95 80-120 Magnesium ug/L 899010000 90 80-120 Manganese ug/L 9741000 97 80-120 Molybdenum ug/L 9111000 91 80-120 Nickel ug/L 9401000 94 80-120 Potassium ug/L 965010000 96 80-120 Sodium ug/L 952010000 95 80-120 Zinc ug/L 9201000 92 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1908507MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666013 1908508 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 10000 95 75-12595 0 2010000ND95409530 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 54 Page 44 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1908507MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666013 1908508 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Barium ug/L 1000 100 75-12594 6 201000ND996942 Boron ug/L 1000 91 75-12592 1 201000ND923933 Calcium ug/L 10000 106 75-125103 3 2010000ND1070010500 Chromium ug/L 1000 98 75-12593 6 201000ND985932 Copper ug/L 1000 97 75-12592 5 20100015.5 984 936 Iron ug/L 10000 101 75-12596 5 201000072.0 10100 9690 Magnesium ug/L 10000 96 75-12590 6 2010000ND95909010 Manganese ug/L 1000 101 75-12596 6 201000ND1020960 Molybdenum ug/L 1000 95 75-12591 4 201000ND952914 Nickel ug/L 1000 98 75-12593 6 201000ND985926 Potassium ug/L 10000 97 75-12593 4 2010000ND100009620 Sodium ug/L 10000 99 75-12596 3 2010000ND99509650 Zinc ug/L 1000 98 75-12591 7 201000ND980912 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 54 Page 45 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/22894 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92238879001, 92238879002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1144539 Associated Lab Samples:92238879001, 92238879002 Matrix:Solid Analyzed Antimony mg/kg ND 0.050 N203/04/15 16:14 Arsenic mg/kg ND 0.050 03/04/15 16:14 Beryllium mg/kg ND 0.0061 03/04/15 16:14 Cadmium mg/kg ND 0.0061 03/04/15 16:14 Cobalt mg/kg ND 0.050 03/04/15 16:14 Lead mg/kg ND 0.050 03/04/15 16:14 Selenium mg/kg ND 0.050 03/04/15 16:14 Thallium mg/kg ND 0.050 03/04/15 16:14 Vanadium mg/kg ND 0.050 03/04/15 16:14 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1144540LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.6 N22.5 102 80-120 Arsenic mg/kg 2.72.5 107 80-120 Beryllium mg/kg 0.28.25 109 80-120 Cadmium mg/kg 0.27.25 104 80-120 Cobalt mg/kg 2.72.5 105 80-120 Lead mg/kg 2.62.5 103 80-120 Selenium mg/kg 2.92.5 113 80-120 Thallium mg/kg 2.62.5 101 80-120 Vanadium mg/kg 2.72.5 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1144541MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666007 1144542 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg D3,M6, N24.21 55 75-12561 12 204.38ND 3.2 3.6 Arsenic mg/kg D4,M64.21 51 75-125-79 7 204.3876.9 79.0 73.3 Beryllium mg/kg D3.421 123 75-12588 4 20.4382.4 3.0 2.8 Cadmium mg/kg D3.421 105 75-12593 4 20.4380.24 0.68 0.65 Cobalt mg/kg D34.21 97 75-12594 1 204.386.4 10.4 10.5 Lead mg/kg D3,M64.21 102 75-12552 11 204.3813.7 17.9 16.0 Selenium mg/kg D3,M64.21 66 75-12581 6 204.3811.1 13.9 14.7 Thallium mg/kg D34.21 80 75-12580 3 204.381.5J 4.8 5.0 Vanadium mg/kg D4,M64.21 95 75-125-3 8 204.3850.5 54.5 50.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 54 Page 46 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/52676 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92238879004, 92238879005, 92238879006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1908489 Associated Lab Samples:92238879004, 92238879005, 92238879006 Matrix:Water Analyzed Antimony ug/L ND 0.50 03/02/15 12:41 Arsenic ug/L ND 0.50 03/02/15 12:41 Beryllium ug/L ND 0.20 03/02/15 12:41 Cadmium ug/L ND 0.080 03/02/15 12:41 Cobalt ug/L ND 0.50 03/02/15 12:41 Lead ug/L ND 0.10 03/02/15 12:41 Selenium ug/L ND 0.50 03/02/15 12:41 Strontium ug/L ND 0.50 03/02/15 12:41 Thallium ug/L ND 0.10 03/02/15 12:41 Vanadium ug/L ND 1.0 03/02/15 12:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1908490LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 82.780 103 80-120 Arsenic ug/L 83.480 104 80-120 Beryllium ug/L 87.180 109 80-120 Cadmium ug/L 83.780 105 80-120 Cobalt ug/L 82.980 104 80-120 Lead ug/L 85.580 107 80-120 Selenium ug/L 83.180 104 80-120 Strontium ug/L 80.080 100 80-120 Thallium ug/L 86.180 108 80-120 Vanadium ug/L 86.180 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1908491MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 10296861016 1908492 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 80 107 75-125103 4 2080ND85.8 82.1 Arsenic ug/L 80 107 75-125102 4 20809.6 94.9 91.0 Beryllium ug/L 80 110 75-125106 3 2080ND88.2 85.2 Cadmium ug/L 80 109 75-125104 5 20800.12 87.4 83.5 Cobalt ug/L 80 107 75-125103 4 20801.4 86.9 83.5 Lead ug/L 80 108 75-125104 4 20800.74 87.0 83.9 Selenium ug/L 80 105 75-125101 4 2080ND84.5 81.0 Strontium ug/L 80 97 75-12585 3 2080234312301 Thallium ug/L 80 108 75-125104 4 2080ND86.2 82.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 54 Page 47 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1908491MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 10296861016 1908492 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Vanadium ug/L 80 112 75-125106 5 208015.5 105 100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 54 Page 48 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/52897 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92238879003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1916229 Associated Lab Samples:92238879003 Matrix:Water Analyzed Aluminum ug/L ND 10.0 03/12/15 15:35 Antimony ug/L ND 0.50 03/12/15 15:35 Arsenic ug/L ND 0.50 03/12/15 15:35 Barium ug/L ND 0.30 03/12/15 15:35 Beryllium ug/L ND 0.20 03/12/15 15:35 Boron ug/L ND 5.0 03/12/15 15:35 Cadmium ug/L ND 0.080 03/12/15 15:35 Calcium ug/L ND 40.0 03/12/15 15:35 Chromium ug/L ND 0.50 03/12/15 15:35 Cobalt ug/L ND 0.50 03/12/15 15:35 Copper ug/L ND 1.0 03/12/15 15:35 Iron ug/L ND 50.0 03/12/15 15:35 Lead ug/L ND 0.10 03/12/15 15:35 Magnesium ug/L ND 10.0 03/12/15 15:35 Manganese ug/L ND 0.50 03/12/15 15:35 Molybdenum ug/L ND 0.50 03/12/15 15:35 Nickel ug/L ND 0.50 03/12/15 15:35 Potassium ug/L ND 50.0 03/12/15 15:35 Selenium ug/L ND 0.50 03/12/15 15:35 Sodium ug/L ND 50.0 03/12/15 15:35 Strontium ug/L ND 0.50 03/12/15 15:35 Thallium ug/L ND 0.10 03/12/15 15:35 Vanadium ug/L ND 1.0 03/12/15 15:35 Zinc ug/L ND 5.0 03/12/15 15:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1916230LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 79.280 99 80-120 Antimony ug/L 82.080 103 80-120 Arsenic ug/L 82.280 103 80-120 Barium ug/L 83.380 104 80-120 Beryllium ug/L 79.780 100 80-120 Boron ug/L 82.080 102 80-120 Cadmium ug/L 84.380 105 80-120 Calcium ug/L 10701000 107 80-120 Chromium ug/L 84.280 105 80-120 Cobalt ug/L 87.880 110 80-120 Copper ug/L 84.180 105 80-120 Iron ug/L 10601000 106 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 54 Page 49 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1916230LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 85.180 106 80-120 Magnesium ug/L 10201000 102 80-120 Manganese ug/L 88.580 111 80-120 Molybdenum ug/L 88.380 110 80-120 Nickel ug/L 88.380 110 80-120 Potassium ug/L 10401000 104 80-120 Selenium ug/L 84.680 106 80-120 Sodium ug/L 10401000 104 80-120 Strontium ug/L 82.680 103 80-120 Thallium ug/L 91.480 114 80-120 Vanadium ug/L 87.480 109 80-120 Zinc ug/L 80.380 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1916665MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540010 1916666 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18012175-125128 4 208044.7 142 147 Antimony ug/L 80 104 75-125103 1 2080ND83.1 82.4 Arsenic ug/L 80 101 75-125102 1 2080ND81.0 81.8 Barium ug/L 80 100 75-125102 2 20803.8 84.2 85.7 Beryllium ug/L 80 101 75-12598 3 2080ND81.0 78.8 Boron ug/L 80 112 75-125103 7 2080ND93.8 87.2 Cadmium ug/L 80 106 75-125107 0 2080ND84.8 85.2 Calcium ug/L 1000 114 75-125125 2 201000390050405150 Chromium ug/L 80 103 75-125104 1 20804.2 87.0 87.7 Cobalt ug/L 80 105 75-125106 1 2080ND84.3 85.0 Copper ug/L 80 104 75-125105 1 20802.0 84.9 86.0 Iron ug/L 1000 107 75-125110 2 20100040414701500 Lead ug/L 80 106 75-125107 1 20800.47 85.4 85.8 Magnesium ug/L 1000 101 75-125105 3 20100022912401280 Manganese ug/L 80 111 75-125113 2 20808.0 96.7 98.5 Molybdenum ug/L 80 108 75-125109 1 20801.5 87.8 88.9 Nickel ug/L 80 109 75-125111 1 2080ND88.0 89.1 Potassium ug/L 1000 108 75-125111 1 201000129023702400 Selenium ug/L 80 106 75-125104 2 2080ND85.3 83.7 Sodium ug/L 1000 108 75-125121 3 201000318042504390 Strontium ug/L 80 102 75-125104 2 208021.4 103 104 Thallium ug/L 80 110 75-125109 0 2080ND87.8 87.5 Vanadium ug/L 80 109 75-125110 1 20801.8 88.9 90.1 Zinc ug/L 80 100 75-125101 1 20805.1 84.9 85.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 54 Page 50 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3315 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92238879001, 92238879002 Parameter Units Dup Result Max RPD QualifiersRPDResult 92238879001 1150025SAMPLE DUPLICATE: Percent Moisture %7.3 2 107.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 35178367003 1150026SAMPLE DUPLICATE: Percent Moisture %4.2 4 104.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 35178367013 1150027SAMPLE DUPLICATE: Percent Moisture %8.4 D615107.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 54 Page 51 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/35950 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92238879001, 92238879002 Parameter Units Dup Result Max RPD QualifiersRPDResult 92238666008 1400247SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.5 1 107.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 92239113005 1400248SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 4.4 D64104.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 54 Page 52 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22152 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92238879001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1405632 Associated Lab Samples:92238879001 Matrix:Water Analyzed Sulfate mg/L ND 2.0 03/08/15 00:17 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1405633LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 20.020 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1405634MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666005 1405635 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 36.1 101 101 036.112.8 49.4 49.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 54 Page 53 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22179 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92238879001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1407887 Associated Lab Samples:92238879001 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.23 0.020 B03/11/15 12:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1407888LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.42.5 98 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1407896MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666006 1407897 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.1 92 90-11091 0 103.10.32 3.1 3.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 54 Page 54 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22158 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92238879001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1406049 Associated Lab Samples:92238879001 Matrix:Water Analyzed Chloride mg/L ND 1.0 03/10/15 03:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1406050LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 21.220 106 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1406051MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666005 1406052 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 36.1 108 90-110107 1 1036.1ND 41.2 40.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 54 Page 55 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44073 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92238879001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1143165 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.7 03/01/15 00:43 Sulfate mg/kg ND 49.7 03/01/15 00:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1143166LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 497499 100 80-120 Sulfate mg/kg 501499 100 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1143168MATRIX SPIKE SAMPLE: MSSpike Result 92238666001 Chloride mg/kg 553574 96 80-120ND Sulfate mg/kg 586574 91 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92238666001 1143167SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 54 Page 56 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/44074 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92238879001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1143169 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 03/01/15 00:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1143170LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 52.049.9 104 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1143172MATRIX SPIKE SAMPLE: MSSpike Result 92238666001 Nitrate as N mg/kg 57.8 H357.4 101 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92238666001 1143171SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 54 Page 57 of 63 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92238879 J15020646 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27440 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92238879001, 92238879002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1123387 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 03/05/15 09:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1123388LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 110000120000 92 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1123389MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238666003 1123390 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 13100 80 50-15073 7 301310022101270011900 Parameter Units MS Result % Rec Limits Qual% RecConc. 1123391MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238878001 1123392 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7280 81 50-15084 3 307230214080108250 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 54 Page 58 of 63 #=QL# QUALIFIERS Pace Project No.: Project: 92238879 J15020646 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Sample was diluted due to the presence of high levels of target analytes.D4 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 54 Page 59 of 63 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92238879 J15020646 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92238879001 MPRP/22893 ICP/140092015005326EPA 3050 EPA 6010 92238879002 MPRP/22893 ICP/140092015005327EPA 3050 EPA 6010 92238879004 MPRP/52678 ICP/229032015005328EPA 3010 EPA 6010 92238879005 MPRP/52678 ICP/229032015005329EPA 3010 EPA 6010 92238879006 MPRP/52678 ICP/229032015005330EPA 3010 EPA 6010 92238879001 MPRP/22894 ICPM/93382015005326EPA 3050 EPA 6020 92238879002 MPRP/22894 ICPM/93382015005327EPA 3050 EPA 6020 92238879003 MPRP/52897 ICPM/234512015005326 SPLP EPA 3020 EPA 6020A 92238879004 MPRP/52676 ICPM/233612015005328EPA 3020 EPA 6020A 92238879005 MPRP/52676 ICPM/233612015005329EPA 3020 EPA 6020A 92238879006 MPRP/52676 ICPM/233612015005330EPA 3020 EPA 6020A 92238879003 MERP/12947 MERC/150612015005326 SPLP EPA 7470 EPA 7470 92238879004 MERP/12854 MERC/149352015005328EPA 7470 EPA 7470 92238879005 MERP/12854 MERC/149352015005329EPA 7470 EPA 7470 92238879006 MERP/12854 MERC/149352015005330EPA 7470 EPA 7470 92238879001 MERP/5420 MERC/54132015005326EPA 7471 EPA 7471 92238879002 MERP/5420 MERC/54132015005327EPA 7471 EPA 7471 92238879001 PMST/33152015005326ASTM D2974-87 92238879002 PMST/33152015005327ASTM D2974-87 92238879001 WET/359502015005326EPA 9045 92238879002 WET/359502015005327EPA 9045 92238879001 WETA/221522015005326EPA 300.0 92238879001 WETA/221792015005326EPA 353.2 92238879001 WETA/221582015005326SM 4500-Cl-E 92238879001 WETA/440732015005326EPA 9056 92238879001 WETA/440742015005326EPA 9056 92238879001 WETA/274402015005326EPA 9060 92238879001 WETA/274412015005326EPA 9060 92238879002 WETA/274402015005327EPA 9060 92238879002 WETA/274412015005327EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/18/2015 07:22 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 54 Page 60 of 63 Page 53 of 54 Page 61 of 63 Page 54 of 54 Page 62 of 63 Page 63 of 63