The URL can be used to link to this page

Home My WebLink AboutNC0038377_J15020349 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15020349 Project Name:AB GW ASSESSMENT SOIL Lab Contact: Margaret Galvin-Karr Date:3/10/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015003935 MAYO STEAM 05-Feb-15 2:30 PM illegible MW-3BR (0.8-1.2) 2015003950 MAYO STEAM 05-Feb-15 5:15 PM illegible MW 3BR (14.75-15) 2015003951 MAYO STEAM 05-Feb-15 5:15 PM illegible MW 3BR (17-18) 2015003952 MAYO STEAM 05-Feb-15 2:30 PM illegible MW 3BR (2.0-2.25) 2015003953 MAYO STEAM 11-Feb-15 3:08 PM illegible MW 8BR (25.5-26) 2015003954 MAYO STEAM 11-Feb-15 11:09 AM illegible MW 8BR (0.75-1.25) 2015003955 MAYO STEAM 11-Feb-15 3:18 PM illegible MW 8BR (30.5-31) 7 Total Samples COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:3/10/2015 Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003935 Collection Date:05-Feb-15 2:30 PM Site:MW-3BR (0.8-1.2) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003950 Collection Date:05-Feb-15 5:15 PM Site:MW 3BR (14.75-15) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003951 Collection Date:05-Feb-15 5:15 PM Site:MW 3BR (17-18) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003952 Collection Date:05-Feb-15 2:30 PM Site:MW 3BR (2.0-2.25) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003953 Collection Date:11-Feb-15 3:08 PM Site:MW 8BR (25.5-26) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003954 Collection Date:11-Feb-15 11:09 AM Site:MW 8BR (0.75-1.25) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 2015003955 Collection Date:11-Feb-15 3:18 PM Site:MW 8BR (30.5-31) Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE #=CL# March 05, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92237760 92237760 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15020349 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 65 #=CP# CERTIFICATIONS Pace Project No.: Project: 92237760 J15020349 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Arizona Certification #: AZ0735 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 New York Certification #: 11888 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 65 #=CP# CERTIFICATIONS Pace Project No.: Project: 92237760 J15020349 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 65 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92237760 J15020349 Lab ID Sample ID Matrix Date Collected Date Received 92237760001 2015003935 Solid 02/05/15 14:30 02/13/15 13:38 92237760002 2015003950 Solid 02/05/15 17:15 02/13/15 13:38 92237760003 2015003951 Solid 02/05/15 17:15 02/13/15 13:38 92237760004 2015003954 Solid 02/11/15 11:09 02/13/15 13:38 92237760005 2015003955 Solid 02/11/15 15:18 02/13/15 13:38 92237760006 2015003952 Solid 02/05/15 14:30 02/13/15 13:38 92237760007 2015003953 Solid 02/11/15 15:08 02/13/15 13:38 92237760008 2015003952 SPLP METALS Water 02/05/15 14:30 02/13/15 13:38 92237760009 2015003953 SPLP METALS Water 02/11/15 15:08 02/13/15 13:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 65 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92237760 J15020349 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92237760001 2015003935 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OHEA EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92237760002 2015003950 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OHEA EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92237760003 2015003951 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OHEA EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92237760004 2015003954 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT, DRS EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OHEA EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92237760005 2015003955 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OHEA EPA 9045 1 PASI-AMLS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 65 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92237760 J15020349 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92237760006 2015003952 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER 92237760007 2015003953 EPA 6010 15 PASI-OCKJ EPA 6020 9 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OHEA EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92237760008 2015003952 SPLP METALS EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MJDD 92237760009 2015003953 SPLP METALS EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MJDD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 65 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92237760 J15020349 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92237760001 2015003935 Aluminum 7030 mg/kg 02/20/15 17:396.0EPA 6010 Barium 57.6 mg/kg 02/20/15 17:390.60EPA 6010 Calcium 332 mg/kg 02/20/15 17:3929.8EPA 6010 Chromium 11.3 mg/kg 02/21/15 16:50 D33.0EPA 6010 Copper 6.3 mg/kg 02/21/15 16:50 D33.0EPA 6010 Iron 8480 mg/kg 02/20/15 17:392.4EPA 6010 Magnesium 2500 mg/kg 02/20/15 17:3929.8EPA 6010 Manganese 327 mg/kg 02/21/15 16:50 D33.0EPA 6010 Nickel 5.1 mg/kg 02/21/15 16:50 D33.0EPA 6010 Potassium 1070 mg/kg 02/20/15 17:3959.7EPA 6010 Strontium 5.4 mg/kg 02/20/15 17:390.60EPA 6010 Zinc 25.3 mg/kg 02/21/15 16:50 D311.9EPA 6010 Beryllium 0.34J mg/kg 02/20/15 11:26 D30.36EPA 6020 Cobalt 5.4 mg/kg 02/20/15 11:26 D33.0EPA 6020 Lead 3.3 mg/kg 02/20/15 11:26 D33.0EPA 6020 Vanadium 16.0 mg/kg 02/20/15 11:26 D33.0EPA 6020 Mercury 0.013 mg/kg 02/22/15 09:590.0093EPA 7471 Percent Moisture 16.8 %03/04/15 13:210.10ASTM D2974-87 pH at 25 Degrees C 5.0 Std. Units 02/17/15 11:50 D60.10EPA 9045 Total Organic Carbon 3280 mg/kg 02/24/15 08:46603EPA 9060 Total Organic Carbon 3450 mg/kg 02/24/15 08:52598EPA 9060 Total Organic Carbon 3480 mg/kg 02/24/15 08:58603EPA 9060 Total Organic Carbon 3660 mg/kg 02/24/15 09:04598EPA 9060 Mean Total Organic Carbon 3470 mg/kg 02/24/15 08:46601EPA 9060 RSD%4.4 %02/24/15 08:46EPA 9060 92237760002 2015003950 Aluminum 4850 mg/kg 02/20/15 17:475.1EPA 6010 Barium 74.4 mg/kg 02/20/15 17:470.51EPA 6010 Calcium 1740 mg/kg 02/20/15 17:4725.4EPA 6010 Chromium 1.5J mg/kg 02/21/15 16:54 D32.5EPA 6010 Copper 4.8 mg/kg 02/21/15 16:54 D32.5EPA 6010 Iron 7750 mg/kg 02/20/15 17:472.0EPA 6010 Magnesium 3050 mg/kg 02/20/15 17:4725.4EPA 6010 Manganese 468 mg/kg 02/21/15 16:54 D32.5EPA 6010 Potassium 3780 mg/kg 02/20/15 17:4750.9EPA 6010 Sodium 161 mg/kg 02/20/15 17:4750.9EPA 6010 Strontium 9.6 mg/kg 02/20/15 17:470.51EPA 6010 Zinc 25.4 mg/kg 02/21/15 16:54 D310.2EPA 6010 Beryllium 0.24J mg/kg 02/20/15 11:29 D30.31EPA 6020 Cobalt 4.3 mg/kg 02/20/15 11:29 D32.5EPA 6020 Lead 1.3J mg/kg 02/20/15 11:29 D32.5EPA 6020 Vanadium 7.6 mg/kg 02/20/15 11:29 D32.5EPA 6020 Percent Moisture 2.0 %03/04/15 13:210.10ASTM D2974-87 pH at 25 Degrees C 8.4 Std. Units 02/17/15 11:500.10EPA 9045 RSD%4.7 %02/24/15 09:56EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 65 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92237760 J15020349 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92237760003 2015003951 Aluminum 3230 mg/kg 02/20/15 17:515.5EPA 6010 Barium 74.5 mg/kg 02/20/15 17:510.55EPA 6010 Calcium 1490 mg/kg 02/20/15 17:5127.3EPA 6010 Copper 5.9 mg/kg 02/21/15 16:58 D32.7EPA 6010 Iron 4450 mg/kg 02/20/15 17:512.2EPA 6010 Magnesium 2040 mg/kg 02/20/15 17:5127.3EPA 6010 Manganese 459 mg/kg 02/21/15 16:58 D32.7EPA 6010 Potassium 2250 mg/kg 02/20/15 17:5154.7EPA 6010 Sodium 92.1 mg/kg 02/20/15 17:5154.7EPA 6010 Strontium 10.7 mg/kg 02/20/15 17:510.55EPA 6010 Zinc 14.1 mg/kg 02/21/15 16:58 D310.9EPA 6010 Beryllium 0.16J mg/kg 02/20/15 11:41 D30.33EPA 6020 Cobalt 3.6 mg/kg 02/20/15 11:41 D32.7EPA 6020 Vanadium 4.4 mg/kg 02/20/15 11:41 D32.7EPA 6020 Percent Moisture 10.4 %03/04/15 13:210.10ASTM D2974-87 pH at 25 Degrees C 8.6 Std. Units 02/17/15 11:500.10EPA 9045 RSD%5.9 %02/24/15 10:20EPA 9060 92237760004 2015003954 Aluminum 14500 mg/kg 02/21/15 17:03 D3127EPA 6010 Barium 147 mg/kg 02/21/15 17:03 D312.7EPA 6010 Calcium 1120 mg/kg 02/21/15 17:03 D3634EPA 6010 Chromium 62.2 mg/kg 02/21/15 17:03 D36.3EPA 6010 Copper 34.7 mg/kg 02/21/15 17:03 D36.3EPA 6010 Iron 24700 mg/kg 02/21/15 17:03 D350.7EPA 6010 Magnesium 10500 mg/kg 02/21/15 17:03 D3634EPA 6010 Manganese 1230 mg/kg 02/21/15 17:03 D36.3EPA 6010 Nickel 29.4 mg/kg 02/21/15 17:03 D36.3EPA 6010 Potassium 6590 mg/kg 02/21/15 17:03 D31270EPA 6010 Strontium 13.2 mg/kg 02/21/15 17:03 D312.7EPA 6010 Zinc 88.9 mg/kg 02/21/15 17:03 D325.4EPA 6010 Beryllium 0.82 mg/kg 02/20/15 11:44 D30.38EPA 6020 Cobalt 21.3 mg/kg 02/20/15 11:44 D33.2EPA 6020 Lead 8.9 mg/kg 02/20/15 11:44 D33.2EPA 6020 Vanadium 50.6 mg/kg 02/20/15 11:44 D43.2EPA 6020 Percent Moisture 19.5 %03/04/15 13:210.10ASTM D2974-87 pH at 25 Degrees C 6.0 Std. Units 02/18/15 11:300.10EPA 9045 RSD%25.0 %02/24/15 10:43EPA 9060 92237760005 2015003955 Aluminum 8330 mg/kg 02/21/15 17:07 D3106EPA 6010 Barium 130 mg/kg 02/20/15 18:420.53EPA 6010 Calcium 883 mg/kg 02/20/15 18:4226.5EPA 6010 Chromium 67.1 mg/kg 02/21/15 17:07 D35.3EPA 6010 Copper 19.8 mg/kg 02/21/15 17:07 D35.3EPA 6010 Iron 11400 mg/kg 02/20/15 18:422.1EPA 6010 Magnesium 6370 mg/kg 02/20/15 18:4226.5EPA 6010 Manganese 875 mg/kg 02/21/15 17:07 D35.3EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 65 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92237760 J15020349 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92237760005 2015003955 Nickel 24.0 mg/kg 02/21/15 17:07 D35.3EPA 6010 Potassium 2700 mg/kg 02/20/15 18:4253.1EPA 6010 Sodium 68.7 mg/kg 02/20/15 18:4253.1EPA 6010 Strontium 9.9 mg/kg 02/20/15 18:420.53EPA 6010 Zinc 29.0 mg/kg 02/21/15 17:07 D321.2EPA 6010 Beryllium 0.24J mg/kg 02/20/15 11:47 D30.32EPA 6020 Cobalt 7.4 mg/kg 02/20/15 11:47 D32.7EPA 6020 Lead 3.4 mg/kg 02/20/15 11:47 D32.7EPA 6020 Vanadium 25.2 mg/kg 02/20/15 11:47 D42.7EPA 6020 Percent Moisture 6.6 %03/04/15 13:210.10ASTM D2974-87 pH at 25 Degrees C 6.9 Std. Units 02/19/15 10:250.10EPA 9045 RSD%5.7 %02/24/15 11:04EPA 9060 92237760006 2015003952 Sulfate 2.6 mg/L 02/21/15 19:242.0EPA 300.0 Nitrogen, Nitrate 0.27 mg/L 02/20/15 21:33 P40.20EPA 353.2 92237760007 2015003953 Aluminum 23700 mg/kg 02/20/15 18:465.5EPA 6010 Barium 193 mg/kg 02/20/15 18:460.55EPA 6010 Boron 31.0J mg/kg 02/21/15 17:11 D354.5EPA 6010 Calcium 3740 mg/kg 02/20/15 18:4627.3EPA 6010 Chromium 419 mg/kg 02/21/15 17:11 D35.5EPA 6010 Copper 45.7 mg/kg 02/21/15 17:11 D35.5EPA 6010 Iron 31300 mg/kg 02/21/15 17:11 D343.6EPA 6010 Magnesium 29900 mg/kg 02/21/15 17:11 D3545EPA 6010 Manganese 933 mg/kg 02/21/15 17:11 D35.5EPA 6010 Nickel 157 mg/kg 02/21/15 17:11 D35.5EPA 6010 Potassium 5450 mg/kg 02/20/15 18:4654.5EPA 6010 Sodium 173 mg/kg 02/20/15 18:4654.5EPA 6010 Strontium 33.6 mg/kg 02/20/15 18:460.55EPA 6010 Zinc 59.4 mg/kg 02/21/15 17:11 D321.8EPA 6010 Beryllium 0.39 mg/kg 02/20/15 11:50 D30.33EPA 6020 Cobalt 32.9 mg/kg 02/20/15 11:50 D42.7EPA 6020 Lead 2.0J mg/kg 02/20/15 11:50 D32.7EPA 6020 Vanadium 75.8 mg/kg 02/20/15 11:50 D42.7EPA 6020 Percent Moisture 8.4 %03/04/15 13:210.10ASTM D2974-87 pH at 25 Degrees C 7.4 Std. Units 02/22/15 14:100.10EPA 9045 Sulfate 2.8 mg/L 02/21/15 19:382.2EPA 300.0 Nitrogen, Nitrate 0.29 mg/L 02/20/15 21:34 P40.22EPA 353.2 RSD%1.8 %02/24/15 11:27EPA 9060 92237760008 2015003952 SPLP METALS Aluminum 8440 ug/L 02/25/15 09:0710.0EPA 6020A Arsenic 0.67 ug/L 02/25/15 09:070.50EPA 6020A Barium 96.5 ug/L 02/25/15 09:070.30EPA 6020A Beryllium 0.42 ug/L 02/25/15 09:070.20EPA 6020A Boron 7.8 ug/L 02/25/15 09:075.0EPA 6020A Calcium 1160 ug/L 02/25/15 09:0740.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 65 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92237760 J15020349 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92237760008 2015003952 SPLP METALS Chromium 7.2 ug/L 02/25/15 09:070.50EPA 6020A Cobalt 1.7 ug/L 02/25/15 09:070.50EPA 6020A Copper 5.0 ug/L 02/25/15 09:071.0EPA 6020A Iron 6500 ug/L 02/25/15 09:0750.0EPA 6020A Lead 3.2 ug/L 02/25/15 09:070.10EPA 6020A Magnesium 1580 ug/L 02/25/15 09:0710.0EPA 6020A Manganese 72.8 ug/L 02/25/15 09:070.50EPA 6020A Nickel 3.2 ug/L 02/25/15 09:070.50EPA 6020A Potassium 738 ug/L 02/25/15 09:0750.0EPA 6020A Sodium 3220 ug/L 02/25/15 09:0750.0EPA 6020A Strontium 18.7 ug/L 02/25/15 09:070.50EPA 6020A Vanadium 11.6 ug/L 02/25/15 09:071.0EPA 6020A Zinc 23.1 ug/L 02/25/15 09:075.0EPA 6020A 92237760009 2015003953 SPLP METALS Aluminum 53900 ug/L 02/25/15 09:50100EPA 6020A Arsenic 0.82 ug/L 02/25/15 09:160.50EPA 6020A Barium 702 ug/L 02/25/15 09:503.0EPA 6020A Beryllium 0.78 ug/L 02/25/15 09:160.20EPA 6020A Cadmium 0.24 ug/L 02/25/15 10:100.080EPA 6020A Calcium 12800 ug/L 02/25/15 09:1640.0EPA 6020A Chromium 858 ug/L 02/25/15 09:505.0EPA 6020A Cobalt 83.7 ug/L 02/25/15 09:160.50EPA 6020A Copper 161 ug/L 02/25/15 09:161.0EPA 6020A Iron 93400 ug/L 02/25/15 09:50500EPA 6020A Lead 5.7 ug/L 02/25/15 09:160.10EPA 6020A Magnesium 58200 ug/L 02/25/15 09:50100EPA 6020A Manganese 3410 ug/L 02/25/15 09:505.0EPA 6020A Nickel 311 ug/L 02/25/15 09:160.50EPA 6020A Potassium 6360 ug/L 02/25/15 09:1650.0EPA 6020A Sodium 3740 ug/L 02/25/15 09:1650.0EPA 6020A Strontium 169 ug/L 02/25/15 09:160.50EPA 6020A Thallium 0.28 ug/L 02/25/15 09:160.10EPA 6020A Vanadium 166 ug/L 02/25/15 09:161.0EPA 6020A Zinc 118 ug/L 02/25/15 09:165.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6010 Date:March 05, 2015 Description:6010 MET ICP General Information: 6 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22732 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1134160) • Aluminum • Iron • Manganese • MSD (Lab ID: 1134161) • Aluminum • Iron • Manganese Additional Comments: Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015003935 (Lab ID: 92237760001) • Chromium • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6010 Date:March 05, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015003935 (Lab ID: 92237760001) • Manganese • Molybdenum • Nickel • Zinc • 2015003950 (Lab ID: 92237760002) • Boron • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc • 2015003951 (Lab ID: 92237760003) • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc • 2015003953 (Lab ID: 92237760007) • Boron • Chromium • Copper • Iron • Magnesium • Manganese • Molybdenum • Nickel • Zinc • 2015003954 (Lab ID: 92237760004) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6010 Date:March 05, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015003954 (Lab ID: 92237760004) • Nickel • Strontium • Zinc • 2015003955 (Lab ID: 92237760005) • Aluminum • Boron • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6020 Date:March 05, 2015 Description:6020 MET ICPMS General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22733 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1134164) • Antimony • Cadmium • Selenium • MSD (Lab ID: 1134165) • Antimony Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6020 Date:March 05, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/22733 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015003935 (Lab ID: 92237760001) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015003950 (Lab ID: 92237760002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015003951 (Lab ID: 92237760003) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • 2015003953 (Lab ID: 92237760007) • Arsenic • Beryllium • Cadmium • Lead • Antimony • Selenium • Thallium • 2015003954 (Lab ID: 92237760004) • Arsenic • Beryllium • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6020 Date:March 05, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/22733 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015003954 (Lab ID: 92237760004) • Lead • Antimony • Selenium • Thallium • 2015003955 (Lab ID: 92237760005) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1134164) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1134165) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium D4: Sample was diluted due to the presence of high levels of target analytes. • 2015003953 (Lab ID: 92237760007) • Cobalt • Vanadium • 2015003954 (Lab ID: 92237760004) • Vanadium • 2015003955 (Lab ID: 92237760005) • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6020 Date:March 05, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/22733 N2: The lab does not hold TNI accreditation for this parameter. • 2015003935 (Lab ID: 92237760001) • Antimony • 2015003950 (Lab ID: 92237760002) • Antimony • 2015003951 (Lab ID: 92237760003) • Antimony • 2015003953 (Lab ID: 92237760007) • Antimony • 2015003954 (Lab ID: 92237760004) • Antimony • 2015003955 (Lab ID: 92237760005) • Antimony • BLANK (Lab ID: 1134162) • Antimony • LCS (Lab ID: 1134163) • Antimony • MS (Lab ID: 1134164) • Antimony • MSD (Lab ID: 1134165) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 6020A Date:March 05, 2015 Description:6020A MET ICPMS General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52559 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238285008 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1905180) • Aluminum R1: RPD value was outside control limits. • MSD (Lab ID: 1905180) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 7470 Date:March 05, 2015 Description:7470 Mercury General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 7471 Date:March 05, 2015 Description:7471 Mercury General Information: 6 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 9045 Date:March 05, 2015 Description:9045 pH Soil General Information: 6 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 300.0 Date:March 05, 2015 Description:300.0 IC Anions, SPLP General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 353.2 Date:March 05, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. P4: Sample field preservation does not meet EPA or method recommendations for this analysis. • 2015003952 (Lab ID: 92237760006) • 2015003953 (Lab ID: 92237760007) Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy SM 4500-Cl-E Date:March 05, 2015 Description:4500 Chloride, SPLP General Information: 2 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 9056 Date:March 05, 2015 Description:9056 IC Anions General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/43649 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015003935 (Lab ID: 92237760001) • Chloride • 2015003950 (Lab ID: 92237760002) • Chloride • Sulfate • 2015003951 (Lab ID: 92237760003) • Chloride • 2015003953 (Lab ID: 92237760007) • Chloride • Sulfate • 2015003954 (Lab ID: 92237760004) • Chloride • Sulfate • 2015003955 (Lab ID: 92237760005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 9056 Date:March 05, 2015 Description:9056 IC Anions 48hr General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015003935 (Lab ID: 92237760001) • 2015003950 (Lab ID: 92237760002) • 2015003951 (Lab ID: 92237760003) • 2015003953 (Lab ID: 92237760007) • 2015003954 (Lab ID: 92237760004) • 2015003955 (Lab ID: 92237760005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 65 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92237760 J15020349 Method: Client:Duke Energy EPA 9060 Date:March 05, 2015 Description:Total Organic Carbon Quad General Information: 6 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003935 Lab ID:92237760001 Collected:02/05/15 14:30 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7030 mg/kg 02/20/15 17:39 7429-90-502/18/15 15:486.0 3.0 1 Barium 57.6 mg/kg 02/20/15 17:39 7440-39-302/18/15 15:480.60 0.30 1 Boron ND mg/kg 02/20/15 17:39 7440-42-802/18/15 15:483.0 1.5 1 Calcium 332 mg/kg 02/20/15 17:39 7440-70-202/18/15 15:4829.8 14.9 1 Chromium 11.3 mg/kg 02/21/15 16:50 7440-47-3 D302/18/15 15:483.0 1.5 10 Copper 6.3 mg/kg 02/21/15 16:50 7440-50-8 D302/18/15 15:483.0 1.5 10 Iron 8480 mg/kg 02/20/15 17:39 7439-89-602/18/15 15:482.4 1.2 1 Magnesium 2500 mg/kg 02/20/15 17:39 7439-95-402/18/15 15:4829.8 14.9 1 Manganese 327 mg/kg 02/21/15 16:50 7439-96-5 D302/18/15 15:483.0 1.5 10 Molybdenum ND mg/kg 02/21/15 16:50 7439-98-7 D302/18/15 15:486.0 3.0 10 Nickel 5.1 mg/kg 02/21/15 16:50 7440-02-0 D302/18/15 15:483.0 1.5 10 Potassium 1070 mg/kg 02/20/15 17:39 7440-09-702/18/15 15:4859.7 29.8 1 Sodium ND mg/kg 02/20/15 17:39 7440-23-502/18/15 15:4859.7 29.8 1 Strontium 5.4 mg/kg 02/20/15 17:39 7440-24-602/18/15 15:480.60 0.30 1 Zinc 25.3 mg/kg 02/21/15 16:50 7440-66-6 D302/18/15 15:4811.9 6.0 10 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 02/20/15 11:26 7440-36-0 D3,N202/18/15 15:483.0 1.5 50 Arsenic ND mg/kg 02/20/15 11:26 7440-38-2 D302/18/15 15:483.0 1.5 50 Beryllium 0.34J mg/kg 02/20/15 11:26 7440-41-7 D302/18/15 15:480.36 0.18 50 Cadmium ND mg/kg 02/20/15 11:26 7440-43-9 D302/18/15 15:480.36 0.18 50 Cobalt 5.4 mg/kg 02/20/15 11:26 7440-48-4 D302/18/15 15:483.0 1.5 50 Lead 3.3 mg/kg 02/20/15 11:26 7439-92-1 D302/18/15 15:483.0 1.5 50 Selenium ND mg/kg 02/20/15 11:26 7782-49-2 D302/18/15 15:483.0 1.5 50 Thallium ND mg/kg 02/20/15 11:26 7440-28-0 D302/18/15 15:483.0 1.5 50 Vanadium 16.0 mg/kg 02/20/15 11:26 7440-62-2 D302/18/15 15:483.0 1.5 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.013 mg/kg 02/22/15 09:59 7439-97-602/18/15 17:580.0093 0.0046 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 16.8 %03/04/15 13:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.0 Std. Units 02/17/15 11:50 D60.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 02/16/15 09:40 16887-00-6 D3,M12991505 Sulfate ND mg/kg 02/16/15 09:40 14808-79-82991505 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 02/16/15 09:40 14797-55-8 H329.9 15.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003935 Lab ID:92237760001 Collected:02/05/15 14:30 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 3280 mg/kg 02/24/15 08:46 7440-44-06033021 Total Organic Carbon 3450 mg/kg 02/24/15 08:52 7440-44-05982991 Total Organic Carbon 3480 mg/kg 02/24/15 08:58 7440-44-06033021 Total Organic Carbon 3660 mg/kg 02/24/15 09:04 7440-44-05982991 Mean Total Organic Carbon 3470 mg/kg 02/24/15 08:46 7440-44-06013001 Surrogates RSD%4.4 %02/24/15 08:461 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003950 Lab ID:92237760002 Collected:02/05/15 17:15 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4850 mg/kg 02/20/15 17:47 7429-90-502/18/15 15:485.1 2.5 1 Barium 74.4 mg/kg 02/20/15 17:47 7440-39-302/18/15 15:480.51 0.25 1 Boron ND mg/kg 02/21/15 16:54 7440-42-8 D302/18/15 15:4825.4 12.7 10 Calcium 1740 mg/kg 02/20/15 17:47 7440-70-202/18/15 15:4825.4 12.7 1 Chromium 1.5J mg/kg 02/21/15 16:54 7440-47-3 D302/18/15 15:482.5 1.3 10 Copper 4.8 mg/kg 02/21/15 16:54 7440-50-8 D302/18/15 15:482.5 1.3 10 Iron 7750 mg/kg 02/20/15 17:47 7439-89-602/18/15 15:482.0 1.0 1 Magnesium 3050 mg/kg 02/20/15 17:47 7439-95-402/18/15 15:4825.4 12.7 1 Manganese 468 mg/kg 02/21/15 16:54 7439-96-5 D302/18/15 15:482.5 1.3 10 Molybdenum ND mg/kg 02/21/15 16:54 7439-98-7 D302/18/15 15:485.1 2.5 10 Nickel ND mg/kg 02/21/15 16:54 7440-02-0 D302/18/15 15:482.5 1.3 10 Potassium 3780 mg/kg 02/20/15 17:47 7440-09-702/18/15 15:4850.9 25.4 1 Sodium 161 mg/kg 02/20/15 17:47 7440-23-502/18/15 15:4850.9 25.4 1 Strontium 9.6 mg/kg 02/20/15 17:47 7440-24-602/18/15 15:480.51 0.25 1 Zinc 25.4 mg/kg 02/21/15 16:54 7440-66-6 D302/18/15 15:4810.2 5.1 10 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 02/20/15 11:29 7440-36-0 D3,N202/18/15 15:482.5 1.3 50 Arsenic ND mg/kg 02/20/15 11:29 7440-38-2 D302/18/15 15:482.5 1.3 50 Beryllium 0.24J mg/kg 02/20/15 11:29 7440-41-7 D302/18/15 15:480.31 0.15 50 Cadmium ND mg/kg 02/20/15 11:29 7440-43-9 D302/18/15 15:480.31 0.15 50 Cobalt 4.3 mg/kg 02/20/15 11:29 7440-48-4 D302/18/15 15:482.5 1.3 50 Lead 1.3J mg/kg 02/20/15 11:29 7439-92-1 D302/18/15 15:482.5 1.3 50 Selenium ND mg/kg 02/20/15 11:29 7782-49-2 D302/18/15 15:482.5 1.3 50 Thallium ND mg/kg 02/20/15 11:29 7440-28-0 D302/18/15 15:482.5 1.3 50 Vanadium 7.6 mg/kg 02/20/15 11:29 7440-62-2 D302/18/15 15:482.5 1.3 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 02/22/15 10:01 7439-97-602/18/15 17:580.0081 0.0040 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 2.0 %03/04/15 13:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.4 Std. Units 02/17/15 11:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 02/16/15 10:46 16887-00-6 D32551285 Sulfate ND mg/kg 02/16/15 10:46 14808-79-8 D32551285 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 02/16/15 10:46 14797-55-8 H325.5 12.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003950 Lab ID:92237760002 Collected:02/05/15 17:15 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 02/24/15 09:56 7440-44-06043021 Total Organic Carbon ND mg/kg 02/24/15 10:03 7440-44-05972991 Total Organic Carbon ND mg/kg 02/24/15 10:09 7440-44-06043021 Total Organic Carbon ND mg/kg 02/24/15 10:14 7440-44-05982991 Mean Total Organic Carbon ND mg/kg 02/24/15 09:56 7440-44-06013001 Surrogates RSD%4.7 %02/24/15 09:561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003951 Lab ID:92237760003 Collected:02/05/15 17:15 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3230 mg/kg 02/20/15 17:51 7429-90-502/18/15 15:485.5 2.7 1 Barium 74.5 mg/kg 02/20/15 17:51 7440-39-302/18/15 15:480.55 0.27 1 Boron ND mg/kg 02/20/15 17:51 7440-42-802/18/15 15:482.7 1.4 1 Calcium 1490 mg/kg 02/20/15 17:51 7440-70-202/18/15 15:4827.3 13.7 1 Chromium ND mg/kg 02/21/15 16:58 7440-47-3 D302/18/15 15:482.7 1.4 10 Copper 5.9 mg/kg 02/21/15 16:58 7440-50-8 D302/18/15 15:482.7 1.4 10 Iron 4450 mg/kg 02/20/15 17:51 7439-89-602/18/15 15:482.2 1.1 1 Magnesium 2040 mg/kg 02/20/15 17:51 7439-95-402/18/15 15:4827.3 13.7 1 Manganese 459 mg/kg 02/21/15 16:58 7439-96-5 D302/18/15 15:482.7 1.4 10 Molybdenum ND mg/kg 02/21/15 16:58 7439-98-7 D302/18/15 15:485.5 2.7 10 Nickel ND mg/kg 02/21/15 16:58 7440-02-0 D302/18/15 15:482.7 1.4 10 Potassium 2250 mg/kg 02/20/15 17:51 7440-09-702/18/15 15:4854.7 27.3 1 Sodium 92.1 mg/kg 02/20/15 17:51 7440-23-502/18/15 15:4854.7 27.3 1 Strontium 10.7 mg/kg 02/20/15 17:51 7440-24-602/18/15 15:480.55 0.27 1 Zinc 14.1 mg/kg 02/21/15 16:58 7440-66-6 D302/18/15 15:4810.9 5.5 10 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 02/20/15 11:41 7440-36-0 D3,N202/18/15 15:482.7 1.4 50 Arsenic ND mg/kg 02/20/15 11:41 7440-38-2 D302/18/15 15:482.7 1.4 50 Beryllium 0.16J mg/kg 02/20/15 11:41 7440-41-7 D302/18/15 15:480.33 0.16 50 Cadmium ND mg/kg 02/20/15 11:41 7440-43-9 D302/18/15 15:480.33 0.16 50 Cobalt 3.6 mg/kg 02/20/15 11:41 7440-48-4 D302/18/15 15:482.7 1.4 50 Lead ND mg/kg 02/20/15 11:41 7439-92-1 D302/18/15 15:482.7 1.4 50 Selenium ND mg/kg 02/20/15 11:41 7782-49-2 D302/18/15 15:482.7 1.4 50 Thallium ND mg/kg 02/20/15 11:41 7440-28-0 D302/18/15 15:482.7 1.4 50 Vanadium 4.4 mg/kg 02/20/15 11:41 7440-62-2 D302/18/15 15:482.7 1.4 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 02/22/15 10:03 7439-97-602/18/15 17:580.0091 0.0045 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 10.4 %03/04/15 13:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.6 Std. Units 02/17/15 11:500.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 02/16/15 11:08 16887-00-6 D32801405 Sulfate ND mg/kg 02/16/15 11:08 14808-79-82801405 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 02/16/15 11:08 14797-55-8 H328.0 14.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003951 Lab ID:92237760003 Collected:02/05/15 17:15 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 02/24/15 10:20 7440-44-06003001 Total Organic Carbon ND mg/kg 02/24/15 10:25 7440-44-06033021 Total Organic Carbon ND mg/kg 02/24/15 10:30 7440-44-05962981 Total Organic Carbon ND mg/kg 02/24/15 10:36 7440-44-05962981 Mean Total Organic Carbon ND mg/kg 02/24/15 10:20 7440-44-05992991 Surrogates RSD%5.9 %02/24/15 10:201 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003954 Lab ID:92237760004 Collected:02/11/15 11:09 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 14500 mg/kg 02/21/15 17:03 7429-90-5 D302/18/15 15:4812763.4 20 Barium 147 mg/kg 02/21/15 17:03 7440-39-3 D302/18/15 15:4812.7 6.3 20 Boron ND mg/kg 02/21/15 17:03 7440-42-8 D302/18/15 15:4863.4 31.7 20 Calcium 1120 mg/kg 02/21/15 17:03 7440-70-2 D302/18/15 15:4863431720 Chromium 62.2 mg/kg 02/21/15 17:03 7440-47-3 D302/18/15 15:486.3 3.2 20 Copper 34.7 mg/kg 02/21/15 17:03 7440-50-8 D302/18/15 15:486.3 3.2 20 Iron 24700 mg/kg 02/21/15 17:03 7439-89-6 D302/18/15 15:4850.7 25.4 20 Magnesium 10500 mg/kg 02/21/15 17:03 7439-95-4 D302/18/15 15:4863431720 Manganese 1230 mg/kg 02/21/15 17:03 7439-96-5 D302/18/15 15:486.3 3.2 20 Molybdenum ND mg/kg 02/21/15 17:03 7439-98-7 D302/18/15 15:4812.7 6.3 20 Nickel 29.4 mg/kg 02/21/15 17:03 7440-02-0 D302/18/15 15:486.3 3.2 20 Potassium 6590 mg/kg 02/21/15 17:03 7440-09-7 D302/18/15 15:48127063420 Sodium ND mg/kg 02/21/15 17:03 7440-23-5 D302/18/15 15:48127063420 Strontium 13.2 mg/kg 02/21/15 17:03 7440-24-6 D302/18/15 15:4812.7 6.3 20 Zinc 88.9 mg/kg 02/21/15 17:03 7440-66-6 D302/18/15 15:4825.4 12.7 20 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 02/20/15 11:44 7440-36-0 D3,N202/18/15 15:483.2 1.6 50 Arsenic ND mg/kg 02/20/15 11:44 7440-38-2 D302/18/15 15:483.2 1.6 50 Beryllium 0.82 mg/kg 02/20/15 11:44 7440-41-7 D302/18/15 15:480.38 0.19 50 Cadmium ND mg/kg 02/23/15 12:04 7440-43-9 D302/18/15 15:480.38 0.19 50 Cobalt 21.3 mg/kg 02/20/15 11:44 7440-48-4 D302/18/15 15:483.2 1.6 50 Lead 8.9 mg/kg 02/20/15 11:44 7439-92-1 D302/18/15 15:483.2 1.6 50 Selenium ND mg/kg 02/20/15 11:44 7782-49-2 D302/18/15 15:483.2 1.6 50 Thallium ND mg/kg 02/20/15 11:44 7440-28-0 D302/18/15 15:483.2 1.6 50 Vanadium 50.6 mg/kg 02/20/15 11:44 7440-62-2 D402/18/15 15:483.2 1.6 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 02/22/15 10:05 7439-97-602/18/15 17:580.0096 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.5 %03/04/15 13:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.0 Std. Units 02/18/15 11:300.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 02/16/15 11:31 16887-00-6 D33091545 Sulfate ND mg/kg 02/16/15 11:31 14808-79-8 D33091545 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 02/16/15 11:31 14797-55-8 H330.9 15.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003954 Lab ID:92237760004 Collected:02/11/15 11:09 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 02/24/15 10:43 7440-44-06003001 Total Organic Carbon ND mg/kg 02/24/15 10:48 7440-44-05982991 Total Organic Carbon ND mg/kg 02/24/15 10:53 7440-44-06023011 Total Organic Carbon ND mg/kg 02/24/15 10:59 7440-44-05962981 Mean Total Organic Carbon ND mg/kg 02/24/15 10:43 7440-44-05993001 Surrogates RSD%25.0 %02/24/15 10:431 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003955 Lab ID:92237760005 Collected:02/11/15 15:18 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 8330 mg/kg 02/21/15 17:07 7429-90-5 D302/18/15 15:4810653.1 20 Barium 130 mg/kg 02/20/15 18:42 7440-39-302/18/15 15:480.53 0.27 1 Boron ND mg/kg 02/21/15 17:07 7440-42-8 D302/18/15 15:4853.1 26.5 20 Calcium 883 mg/kg 02/20/15 18:42 7440-70-202/18/15 15:4826.5 13.3 1 Chromium 67.1 mg/kg 02/21/15 17:07 7440-47-3 D302/18/15 15:485.3 2.7 20 Copper 19.8 mg/kg 02/21/15 17:07 7440-50-8 D302/18/15 15:485.3 2.7 20 Iron 11400 mg/kg 02/20/15 18:42 7439-89-602/18/15 15:482.1 1.1 1 Magnesium 6370 mg/kg 02/20/15 18:42 7439-95-402/18/15 15:4826.5 13.3 1 Manganese 875 mg/kg 02/21/15 17:07 7439-96-5 D302/18/15 15:485.3 2.7 20 Molybdenum ND mg/kg 02/21/15 17:07 7439-98-7 D302/18/15 15:4810.6 5.3 20 Nickel 24.0 mg/kg 02/21/15 17:07 7440-02-0 D302/18/15 15:485.3 2.7 20 Potassium 2700 mg/kg 02/20/15 18:42 7440-09-702/18/15 15:4853.1 26.5 1 Sodium 68.7 mg/kg 02/20/15 18:42 7440-23-502/18/15 15:4853.1 26.5 1 Strontium 9.9 mg/kg 02/20/15 18:42 7440-24-602/18/15 15:480.53 0.27 1 Zinc 29.0 mg/kg 02/21/15 17:07 7440-66-6 D302/18/15 15:4821.2 10.6 20 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 02/20/15 11:47 7440-36-0 D3,N202/18/15 15:482.7 1.3 50 Arsenic ND mg/kg 02/20/15 11:47 7440-38-2 D302/18/15 15:482.7 1.3 50 Beryllium 0.24J mg/kg 02/20/15 11:47 7440-41-7 D302/18/15 15:480.32 0.16 50 Cadmium ND mg/kg 02/20/15 11:47 7440-43-9 D302/18/15 15:480.32 0.16 50 Cobalt 7.4 mg/kg 02/20/15 11:47 7440-48-4 D302/18/15 15:482.7 1.3 50 Lead 3.4 mg/kg 02/20/15 11:47 7439-92-1 D302/18/15 15:482.7 1.3 50 Selenium ND mg/kg 02/20/15 11:47 7782-49-2 D302/18/15 15:482.7 1.3 50 Thallium ND mg/kg 02/20/15 11:47 7440-28-0 D302/18/15 15:482.7 1.3 50 Vanadium 25.2 mg/kg 02/20/15 11:47 7440-62-2 D402/18/15 15:482.7 1.3 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 02/22/15 10:08 7439-97-602/18/15 17:580.0082 0.0041 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 6.6 %03/04/15 13:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.9 Std. Units 02/19/15 10:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 02/16/15 11:53 16887-00-6 D32671345 Sulfate ND mg/kg 02/16/15 11:53 14808-79-8 D32671345 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 02/16/15 11:53 14797-55-8 H326.7 13.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003955 Lab ID:92237760005 Collected:02/11/15 15:18 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 02/24/15 11:04 7440-44-05993001 Total Organic Carbon ND mg/kg 02/24/15 11:11 7440-44-05972981 Total Organic Carbon ND mg/kg 02/24/15 11:16 7440-44-05982991 Total Organic Carbon ND mg/kg 02/24/15 11:22 7440-44-06013001 Mean Total Organic Carbon ND mg/kg 02/24/15 11:04 7440-44-05992991 Surrogates RSD%5.7 %02/24/15 11:041 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003952 Lab ID:92237760006 Collected:02/05/15 14:30 Received:02/13/15 13:38 Matrix:Solid Results reported on a "wet-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/18/15 16:35300.0 IC Anions, SPLP Sulfate 2.6 mg/L 02/21/15 19:24 14808-79-82.0 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/18/15 16:35353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.27 mg/L 02/20/15 21:33 P40.20 0.20 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 02/18/15 16:354500 Chloride, SPLP Chloride ND mg/L 02/21/15 01:50 16887-00-65.0 2.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003953 Lab ID:92237760007 Collected:02/11/15 15:08 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 23700 mg/kg 02/20/15 18:46 7429-90-502/18/15 15:485.5 2.7 1 Barium 193 mg/kg 02/20/15 18:46 7440-39-302/18/15 15:480.55 0.27 1 Boron 31.0J mg/kg 02/21/15 17:11 7440-42-8 D302/18/15 15:4854.5 27.3 20 Calcium 3740 mg/kg 02/20/15 18:46 7440-70-202/18/15 15:4827.3 13.6 1 Chromium 419 mg/kg 02/21/15 17:11 7440-47-3 D302/18/15 15:485.5 2.7 20 Copper 45.7 mg/kg 02/21/15 17:11 7440-50-8 D302/18/15 15:485.5 2.7 20 Iron 31300 mg/kg 02/21/15 17:11 7439-89-6 D302/18/15 15:4843.6 21.8 20 Magnesium 29900 mg/kg 02/21/15 17:11 7439-95-4 D302/18/15 15:4854527320 Manganese 933 mg/kg 02/21/15 17:11 7439-96-5 D302/18/15 15:485.5 2.7 20 Molybdenum ND mg/kg 02/21/15 17:11 7439-98-7 D302/18/15 15:4810.9 5.5 20 Nickel 157 mg/kg 02/21/15 17:11 7440-02-0 D302/18/15 15:485.5 2.7 20 Potassium 5450 mg/kg 02/20/15 18:46 7440-09-702/18/15 15:4854.5 27.3 1 Sodium 173 mg/kg 02/20/15 18:46 7440-23-502/18/15 15:4854.5 27.3 1 Strontium 33.6 mg/kg 02/20/15 18:46 7440-24-602/18/15 15:480.55 0.27 1 Zinc 59.4 mg/kg 02/21/15 17:11 7440-66-6 D302/18/15 15:4821.8 10.9 20 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 02/20/15 11:50 7440-36-0 D3,N202/18/15 15:482.7 1.4 50 Arsenic ND mg/kg 02/20/15 11:50 7440-38-2 D302/18/15 15:482.7 1.4 50 Beryllium 0.39 mg/kg 02/20/15 11:50 7440-41-7 D302/18/15 15:480.33 0.16 50 Cadmium ND mg/kg 02/20/15 11:50 7440-43-9 D302/18/15 15:480.33 0.16 50 Cobalt 32.9 mg/kg 02/20/15 11:50 7440-48-4 D402/18/15 15:482.7 1.4 50 Lead 2.0J mg/kg 02/20/15 11:50 7439-92-1 D302/18/15 15:482.7 1.4 50 Selenium ND mg/kg 02/20/15 11:50 7782-49-2 D302/18/15 15:482.7 1.4 50 Thallium ND mg/kg 02/20/15 11:50 7440-28-0 D302/18/15 15:482.7 1.4 50 Vanadium 75.8 mg/kg 02/20/15 11:50 7440-62-2 D402/18/15 15:482.7 1.4 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 02/22/15 10:10 7439-97-602/18/15 17:580.0089 0.0044 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 8.4 %03/04/15 13:210.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.4 Std. Units 02/22/15 14:100.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/18/15 16:35300.0 IC Anions, SPLP Sulfate 2.8 mg/L 02/21/15 19:38 14808-79-82.2 1.1 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/18/15 16:35353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.29 mg/L 02/20/15 21:34 P40.22 0.22 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 02/18/15 16:354500 Chloride, SPLP Chloride ND mg/L 02/21/15 01:51 16887-00-65.5 2.7 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003953 Lab ID:92237760007 Collected:02/11/15 15:08 Received:02/13/15 13:38 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 02/16/15 12:15 16887-00-6 D32721365 Sulfate ND mg/kg 02/16/15 12:15 14808-79-8 D32721365 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 02/16/15 12:15 14797-55-8 H327.2 13.6 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 02/24/15 11:27 7440-44-05972981 Total Organic Carbon ND mg/kg 02/24/15 11:33 7440-44-05972991 Total Organic Carbon ND mg/kg 02/24/15 11:38 7440-44-05972991 Total Organic Carbon ND mg/kg 02/24/15 11:45 7440-44-05982991 Mean Total Organic Carbon ND mg/kg 02/24/15 11:27 7440-44-05972991 Surrogates RSD%1.8 %02/24/15 11:271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003952 SPLP METALS Lab ID:92237760008 Collected:02/05/15 14:30 Received:02/13/15 13:38 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 8440 ug/L 02/25/15 09:07 7429-90-502/24/15 22:1810.0 1.2 1 Antimony ND ug/L 02/25/15 09:07 7440-36-002/24/15 22:180.50 0.25 1 Arsenic 0.67 ug/L 02/25/15 09:07 7440-38-202/24/15 22:180.50 0.25 1 Barium 96.5 ug/L 02/25/15 09:07 7440-39-302/24/15 22:180.30 0.14 1 Beryllium 0.42 ug/L 02/25/15 09:07 7440-41-702/24/15 22:180.20 0.066 1 Boron 7.8 ug/L 02/25/15 09:07 7440-42-802/24/15 22:185.0 1.0 1 Cadmium ND ug/L 02/25/15 09:07 7440-43-902/24/15 22:180.080 0.033 1 Calcium 1160 ug/L 02/25/15 09:07 7440-70-202/24/15 22:1840.0 8.4 1 Chromium 7.2 ug/L 02/25/15 09:07 7440-47-302/24/15 22:180.50 0.22 1 Cobalt 1.7 ug/L 02/25/15 09:07 7440-48-402/24/15 22:180.50 0.25 1 Copper 5.0 ug/L 02/25/15 09:07 7440-50-802/24/15 22:181.0 0.22 1 Iron 6500 ug/L 02/25/15 09:07 7439-89-602/24/15 22:1850.0 8.0 1 Lead 3.2 ug/L 02/25/15 09:07 7439-92-102/24/15 22:180.10 0.046 1 Magnesium 1580 ug/L 02/25/15 09:07 7439-95-402/24/15 22:1810.0 2.8 1 Manganese 72.8 ug/L 02/25/15 09:07 7439-96-502/24/15 22:180.50 0.14 1 Molybdenum ND ug/L 02/25/15 09:07 7439-98-702/24/15 22:180.50 0.24 1 Nickel 3.2 ug/L 02/25/15 09:07 7440-02-002/24/15 22:180.50 0.23 1 Potassium 738 ug/L 02/25/15 09:07 7440-09-702/24/15 22:1850.0 8.3 1 Selenium ND ug/L 02/25/15 09:07 7782-49-202/24/15 22:180.50 0.25 1 Sodium 3220 ug/L 02/25/15 09:07 7440-23-502/24/15 22:1850.0 18.2 1 Strontium 18.7 ug/L 02/25/15 09:07 7440-24-602/24/15 22:180.50 0.057 1 Thallium ND ug/L 02/25/15 09:07 7440-28-002/24/15 22:180.10 0.025 1 Vanadium 11.6 ug/L 02/25/15 09:07 7440-62-202/24/15 22:181.0 0.21 1 Zinc 23.1 ug/L 02/25/15 09:07 7440-66-602/24/15 22:185.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 02/25/15 17:11 7439-97-602/24/15 17:301.2 0.16 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 65 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92237760 J15020349 Sample:2015003953 SPLP METALS Lab ID:92237760009 Collected:02/11/15 15:08 Received:02/13/15 13:38 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 53900 ug/L 02/25/15 09:50 7429-90-502/24/15 22:1810011.5 10 Antimony ND ug/L 02/25/15 09:16 7440-36-002/24/15 22:180.50 0.25 1 Arsenic 0.82 ug/L 02/25/15 09:16 7440-38-202/24/15 22:180.50 0.25 1 Barium 702 ug/L 02/25/15 09:50 7440-39-302/24/15 22:183.0 1.4 10 Beryllium 0.78 ug/L 02/25/15 09:16 7440-41-702/24/15 22:180.20 0.066 1 Boron ND ug/L 02/25/15 09:16 7440-42-802/24/15 22:185.0 1.0 1 Cadmium 0.24 ug/L 02/25/15 10:10 7440-43-902/24/15 22:180.080 0.033 1 Calcium 12800 ug/L 02/25/15 09:16 7440-70-202/24/15 22:1840.0 8.4 1 Chromium 858 ug/L 02/25/15 09:50 7440-47-302/24/15 22:185.0 2.2 10 Cobalt 83.7 ug/L 02/25/15 09:16 7440-48-402/24/15 22:180.50 0.25 1 Copper 161 ug/L 02/25/15 09:16 7440-50-802/24/15 22:181.0 0.22 1 Iron 93400 ug/L 02/25/15 09:50 7439-89-602/24/15 22:1850080.2 10 Lead 5.7 ug/L 02/25/15 09:16 7439-92-102/24/15 22:180.10 0.046 1 Magnesium 58200 ug/L 02/25/15 09:50 7439-95-402/24/15 22:1810028.5 10 Manganese 3410 ug/L 02/25/15 09:50 7439-96-502/24/15 22:185.0 1.4 10 Molybdenum ND ug/L 02/25/15 09:16 7439-98-702/24/15 22:180.50 0.24 1 Nickel 311 ug/L 02/25/15 09:16 7440-02-002/24/15 22:180.50 0.23 1 Potassium 6360 ug/L 02/25/15 09:16 7440-09-702/24/15 22:1850.0 8.3 1 Selenium ND ug/L 02/25/15 09:16 7782-49-202/24/15 22:180.50 0.25 1 Sodium 3740 ug/L 02/25/15 09:16 7440-23-502/24/15 22:1850.0 18.2 1 Strontium 169 ug/L 02/25/15 09:16 7440-24-602/24/15 22:180.50 0.057 1 Thallium 0.28 ug/L 02/25/15 09:16 7440-28-002/24/15 22:180.10 0.025 1 Vanadium 166 ug/L 02/25/15 09:16 7440-62-202/24/15 22:181.0 0.21 1 Zinc 118 ug/L 02/25/15 09:16 7440-66-602/24/15 22:185.0 2.5 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 02/25/15 17:14 7439-97-602/24/15 17:301.2 0.16 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/12810 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92237760008, 92237760009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1905056 Associated Lab Samples:92237760008, 92237760009 Matrix:Water Analyzed Mercury ug/L ND 0.20 02/25/15 16:39 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1905057LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.45 107 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1905794MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238285007 1905795 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 111 75-125109 1 205ND5.5 5.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5386 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1134154 Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Matrix:Solid Analyzed Mercury mg/kg ND 0.0082 02/22/15 09:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1134155LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.082.08 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1134156MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237650015 1134157 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .126 98 80-12092 1 20.1320.036 0.16 0.16 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/22732 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1134158 Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Matrix:Solid Analyzed Aluminum mg/kg ND 5.0 02/21/15 15:20 Barium mg/kg ND 0.50 02/21/15 15:20 Boron mg/kg ND 2.5 02/21/15 15:20 Calcium mg/kg ND 25.2 02/21/15 15:20 Chromium mg/kg ND 0.25 02/21/15 15:20 Copper mg/kg ND 0.25 02/21/15 15:20 Iron mg/kg ND 2.0 02/21/15 15:20 Magnesium mg/kg ND 25.2 02/21/15 15:20 Manganese mg/kg ND 0.25 02/21/15 15:20 Molybdenum mg/kg ND 0.50 02/21/15 15:20 Nickel mg/kg ND 0.25 02/21/15 15:20 Potassium mg/kg ND 50.4 02/21/15 15:20 Sodium mg/kg ND 50.4 02/21/15 15:20 Strontium mg/kg ND 0.50 02/21/15 15:20 Zinc mg/kg ND 1.0 02/21/15 15:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1134159LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 124124 100 80-120 Barium mg/kg 12.512.4 101 80-120 Boron mg/kg 126124 102 80-120 Calcium mg/kg 612619 99 80-120 Chromium mg/kg 12.212.4 98 80-120 Copper mg/kg 12.212.4 99 80-120 Iron mg/kg 118124 96 80-120 Magnesium mg/kg 623619 101 80-120 Manganese mg/kg 12.512.4 101 80-120 Molybdenum mg/kg 12.612.4 102 80-120 Nickel mg/kg 12.612.4 102 80-120 Potassium mg/kg 608619 98 80-120 Sodium mg/kg 612619 99 80-120 Strontium mg/kg 12.712.4 103 80-120 Zinc mg/kg 63.361.9 102 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1134160MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237739001 1134161 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1129199075-1251900 0 20135276053105320 Barium mg/kg 12.9 117 75-125112 0 2013.56.0 21.0 21.0 Boron mg/kg 129 91 75-12586 1 201353.5 120 119 Calcium mg/kg 642 100 75-12594 2 2067319.0J 664 651 Chromium mg/kg 12.9 97 75-12595 2 2013.53.4 15.8 16.2 Copper mg/kg 12.9 101 75-12597 0 2013.51.9 14.9 14.9 Iron mg/kg M112944075-125464 1 20135347040404100 Magnesium mg/kg 642 112 75-125104 2 20673106822809 Manganese mg/kg M112.9 69 75-12560 3 2013.522.7 31.6 30.8 Molybdenum mg/kg 12.9 84 75-12585 6 2013.5ND 10.8 11.5 Nickel mg/kg 12.9 103 75-125104 5 2013.51.0 14.2 15.0 Potassium mg/kg 642 100 75-12599 3 2067362.3 702 725 Sodium mg/kg 642 100 75-12595 0 20673ND647646 Strontium mg/kg 12.9 100 75-125102 6 2013.50.52 13.4 14.2 Zinc mg/kg 64.2 101 75-125100 3 2067.32.8 67.6 69.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/22733 EPA 3050 EPA 6020 6020 MET Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1134162 Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N202/20/15 10:43 Arsenic mg/kg ND 0.051 02/20/15 10:43 Beryllium mg/kg ND 0.0061 02/20/15 10:43 Cadmium mg/kg ND 0.0061 02/20/15 10:43 Cobalt mg/kg ND 0.051 02/20/15 10:43 Lead mg/kg ND 0.051 02/20/15 10:43 Selenium mg/kg ND 0.051 02/20/15 10:43 Thallium mg/kg ND 0.051 02/20/15 10:43 Vanadium mg/kg ND 0.051 02/20/15 10:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1134163LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.4 N22.5 94 80-120 Arsenic mg/kg 2.52.5 100 80-120 Beryllium mg/kg 0.25.25 100 80-120 Cadmium mg/kg 0.25.25 98 80-120 Cobalt mg/kg 2.62.5 103 80-120 Lead mg/kg 2.62.5 102 80-120 Selenium mg/kg 2.52.5 98 80-120 Thallium mg/kg 2.52.5 100 80-120 Vanadium mg/kg 2.52.5 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1134164MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237739001 1134165 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg D3,M6, N2 2.66 56 75-12564 202.66ND 1.5J 1.7J Arsenic mg/kg D32.66 92 75-12589 4 202.66ND 3.1 3.0 Beryllium mg/kg D3.266 87 75-125100 7 20.2660.17J 0.40 0.43 Cadmium mg/kg D3,M6.266 127 75-12589 20.266ND 0.34 0.23J Cobalt mg/kg D32.66 103 75-12599 5 202.661.4J 4.1 4.0 Lead mg/kg D32.66 109 75-125104 3 202.663.4 6.3 6.1 Selenium mg/kg D3,M62.66 68 75-12579 202.66ND 2.5J 2.7 Thallium mg/kg D32.66 87 75-12581 202.66ND 2.7 2.5J Vanadium mg/kg D32.66 117 75-125102 4 202.668.4 11.6 11.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/52559 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92237760008, 92237760009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1905028 Associated Lab Samples:92237760008, 92237760009 Matrix:Water Analyzed Aluminum ug/L ND 10.0 02/25/15 08:41 Antimony ug/L ND 0.50 02/25/15 08:41 Arsenic ug/L ND 0.50 02/25/15 08:41 Barium ug/L ND 0.30 02/25/15 08:41 Beryllium ug/L ND 0.20 02/25/15 08:41 Boron ug/L ND 5.0 02/25/15 08:41 Cadmium ug/L ND 0.080 02/25/15 08:41 Calcium ug/L ND 40.0 02/25/15 08:41 Chromium ug/L ND 0.50 02/25/15 08:41 Cobalt ug/L ND 0.50 02/25/15 08:41 Copper ug/L ND 1.0 02/25/15 08:41 Iron ug/L ND 50.0 02/25/15 08:41 Lead ug/L ND 0.10 02/25/15 08:41 Magnesium ug/L ND 10.0 02/25/15 08:41 Manganese ug/L ND 0.50 02/25/15 08:41 Molybdenum ug/L ND 0.50 02/25/15 08:41 Nickel ug/L ND 0.50 02/25/15 08:41 Potassium ug/L ND 50.0 02/25/15 08:41 Selenium ug/L ND 0.50 02/25/15 08:41 Sodium ug/L ND 50.0 02/25/15 08:41 Strontium ug/L ND 0.50 02/25/15 08:41 Thallium ug/L ND 0.10 02/25/15 08:41 Vanadium ug/L ND 1.0 02/25/15 08:41 Zinc ug/L ND 5.0 02/25/15 08:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1905029LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 79.880 100 80-120 Antimony ug/L 80.080 100 80-120 Arsenic ug/L 80.480 100 80-120 Barium ug/L 79.180 99 80-120 Beryllium ug/L 75.480 94 80-120 Boron ug/L 77.080 96 80-120 Cadmium ug/L 80.680 101 80-120 Calcium ug/L 9691000 97 80-120 Chromium ug/L 85.180 106 80-120 Cobalt ug/L 84.380 105 80-120 Copper ug/L 88.080 110 80-120 Iron ug/L 10401000 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1905029LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 83.880 105 80-120 Magnesium ug/L 10301000 103 80-120 Manganese ug/L 84.680 106 80-120 Molybdenum ug/L 82.480 103 80-120 Nickel ug/L 84.980 106 80-120 Potassium ug/L 10201000 102 80-120 Selenium ug/L 80.180 100 80-120 Sodium ug/L 10401000 104 80-120 Strontium ug/L 78.580 98 80-120 Thallium ug/L 84.480 105 80-120 Vanadium ug/L 83.580 104 80-120 Zinc ug/L 86.180 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1905179MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92238285008 1905180 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M1,R18010275-125127 21 2080ND84.5 105 Antimony ug/L 80 104 75-125104 0 2080ND83.3 83.6 Arsenic ug/L 80 105 75-125106 1 2080ND83.9 84.6 Barium ug/L 80 103 75-125103 0 2080ND82.1 82.3 Beryllium ug/L 80 97 75-12596 1 2080ND77.8 76.8 Boron ug/L 80 100 75-125100 1 2080ND81.1 80.4 Cadmium ug/L 80 103 75-125104 1 2080ND82.3 82.9 Calcium ug/L 1000 102 75-125103 1 201000ND10301040 Chromium ug/L 80 110 75-125112 2 2080ND88.0 90.0 Cobalt ug/L 80 109 75-125111 2 2080ND87.4 88.8 Copper ug/L 80 113 75-125114 1 2080ND90.9 92.1 Iron ug/L 1000 106 75-125108 2 201000ND10601090 Lead ug/L 80 78 75-12579 1 208024.4 86.8 87.5 Magnesium ug/L 1000 108 75-125111 2 201000ND10801110 Manganese ug/L 80 110 75-125113 2 2080ND88.0 90.2 Molybdenum ug/L 80 106 75-125109 2 2080ND85.2 87.0 Nickel ug/L 80 110 75-125112 2 2080ND88.3 89.8 Potassium ug/L 1000 105 75-125108 3 201000ND10501080 Selenium ug/L 80 101 75-125101 0 2080ND80.9 80.6 Sodium ug/L 1000 108 75-125109 2 201000ND10801100 Strontium ug/L 80 102 75-125103 1 2080ND81.4 82.5 Thallium ug/L 80 110 75-125110 0 2080ND87.7 88.1 Vanadium ug/L 80 107 75-125109 2 2080ND86.0 87.7 Zinc ug/L 80 108 75-125110 2 2080ND88.0 90.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3302 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237650001 1146078SAMPLE DUPLICATE: Percent Moisture %9.4 4 109.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237650011 1146084SAMPLE DUPLICATE: Percent Moisture %3.9 D625105.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237760002 1146085SAMPLE DUPLICATE: Percent Moisture %1.9 10 102.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 35177074004 1146086SAMPLE DUPLICATE: Percent Moisture %24.4 2 1023.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92238666008 1146087SAMPLE DUPLICATE: Percent Moisture %43.8 7 1040.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/35731 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92237760001, 92237760002, 92237760003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237760001 1392421SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 4.9 1 105.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237650009 1392422SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.1 2 105.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/35750 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92237760004 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237746005 1393147SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.6 7 106.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237650012 1393148SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 9.1 1 109.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/35767 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92237760005 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237903003 1393405SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.5 1 105.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237903009 1393406SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.0 1 105.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/35836 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92237760007 Parameter Units Dup Result Max RPD QualifiersRPDResult 92237746017 1395969SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.5 2 107.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 92238285001 1395970SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.6 1 107.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21979 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92237760006, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1395669 Associated Lab Samples:92237760006, 92237760007 Matrix:Water Analyzed Sulfate mg/L ND 2.0 02/21/15 14:50 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1395670LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.020 95 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1395671MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237650008 1395672 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 23.9 101 102 123.912.7 36.9 37.1 Parameter Units MS Result % Rec Limits Qual% RecConc. 1395673MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237746019 1395674 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20 97 96 0205.7 25.1 25.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21986 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92237760006, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1395834 Associated Lab Samples:92237760006, 92237760007 Matrix:Water Analyzed Nitrogen, Nitrate mg/L ND 0.020 02/20/15 21:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1395835LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1395836MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92236923006 1395837 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L P42.5 96 90-11096 0 102.5ND 2.4 2.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/21977 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92237760006, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1395491 Associated Lab Samples:92237760006, 92237760007 Matrix:Water Analyzed Chloride mg/L ND 1.0 02/21/15 01:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1395492LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 20.720 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1395493MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237650008 1395494 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 23.9 102 90-110100 2 1023.9ND 24.7 24.2 Parameter Units MS Result % Rec Limits Qual% RecConc. 1395495MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237746019 1395496 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 20 97 90-11097 0 1020ND20.0 20.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/43649 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1131956 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 50.1 02/16/15 08:55 Sulfate mg/kg ND 50.1 02/16/15 08:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1131957LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 481501 96 80-120 Sulfate mg/kg 482501 96 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1131959MATRIX SPIKE SAMPLE: MSSpike Result 92237760001 Chloride mg/kg 550 M15967580-120ND Sulfate mg/kg 596596 86 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92237760001 1131958SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/43650 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1131960 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 02/16/15 08:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1131961LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.850.1 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1131963MATRIX SPIKE SAMPLE: MSSpike Result 92237760001 Nitrate as N mg/kg 57.2 H359.6 96 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92237760001 1131962SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 65 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92237760 J15020349 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27309 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1119367 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 02/24/15 08:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1119368LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 114000120000 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1119369MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92237760001 1119370 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 5990 119 50-150126 4 30602034701060011100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 65 #=QL# QUALIFIERS Pace Project No.: Project: 92237760 J15020349 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Sample was diluted due to the presence of high levels of target analytes.D4 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Sample field preservation does not meet EPA or method recommendations for this analysis.P4 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 65 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92237760 J15020349 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92237760001 MPRP/22732 ICP/139102015003935EPA 3050 EPA 6010 92237760002 MPRP/22732 ICP/139102015003950EPA 3050 EPA 6010 92237760003 MPRP/22732 ICP/139102015003951EPA 3050 EPA 6010 92237760004 MPRP/22732 ICP/139102015003954EPA 3050 EPA 6010 92237760005 MPRP/22732 ICP/139102015003955EPA 3050 EPA 6010 92237760007 MPRP/22732 ICP/139102015003953EPA 3050 EPA 6010 92237760001 MPRP/22733 ICPM/92782015003935EPA 3050 EPA 6020 92237760002 MPRP/22733 ICPM/92782015003950EPA 3050 EPA 6020 92237760003 MPRP/22733 ICPM/92782015003951EPA 3050 EPA 6020 92237760004 MPRP/22733 ICPM/92782015003954EPA 3050 EPA 6020 92237760005 MPRP/22733 ICPM/92782015003955EPA 3050 EPA 6020 92237760007 MPRP/22733 ICPM/92782015003953EPA 3050 EPA 6020 92237760008 MPRP/52559 ICPM/233242015003952 SPLP METALS EPA 3020 EPA 6020A 92237760009 MPRP/52559 ICPM/233242015003953 SPLP METALS EPA 3020 EPA 6020A 92237760008 MERP/12810 MERC/148742015003952 SPLP METALS EPA 7470 EPA 7470 92237760009 MERP/12810 MERC/148742015003953 SPLP METALS EPA 7470 EPA 7470 92237760001 MERP/5386 MERC/53802015003935EPA 7471 EPA 7471 92237760002 MERP/5386 MERC/53802015003950EPA 7471 EPA 7471 92237760003 MERP/5386 MERC/53802015003951EPA 7471 EPA 7471 92237760004 MERP/5386 MERC/53802015003954EPA 7471 EPA 7471 92237760005 MERP/5386 MERC/53802015003955EPA 7471 EPA 7471 92237760007 MERP/5386 MERC/53802015003953EPA 7471 EPA 7471 92237760001 PMST/33022015003935ASTM D2974-87 92237760002 PMST/33022015003950ASTM D2974-87 92237760003 PMST/33022015003951ASTM D2974-87 92237760004 PMST/33022015003954ASTM D2974-87 92237760005 PMST/33022015003955ASTM D2974-87 92237760007 PMST/33022015003953ASTM D2974-87 92237760001 WET/357312015003935EPA 9045 92237760002 WET/357312015003950EPA 9045 92237760003 WET/357312015003951EPA 9045 92237760004 WET/357502015003954EPA 9045 92237760005 WET/357672015003955EPA 9045 92237760007 WET/358362015003953EPA 9045 92237760006 WETA/219792015003952EPA 300.0 92237760007 WETA/219792015003953EPA 300.0 92237760006 WETA/219862015003952EPA 353.2 92237760007 WETA/219862015003953EPA 353.2 92237760006 WETA/219772015003952SM 4500-Cl-E 92237760007 WETA/219772015003953SM 4500-Cl-E 92237760001 WETA/436492015003935EPA 9056 92237760002 WETA/436492015003950EPA 9056 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 65 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92237760 J15020349 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92237760003 WETA/436492015003951EPA 9056 92237760004 WETA/436492015003954EPA 9056 92237760005 WETA/436492015003955EPA 9056 92237760007 WETA/436492015003953EPA 9056 92237760001 WETA/436502015003935EPA 9056 92237760002 WETA/436502015003950EPA 9056 92237760003 WETA/436502015003951EPA 9056 92237760004 WETA/436502015003954EPA 9056 92237760005 WETA/436502015003955EPA 9056 92237760007 WETA/436502015003953EPA 9056 92237760001 WETA/273092015003935EPA 9060 92237760001 WETA/273102015003935EPA 9060 92237760002 WETA/273092015003950EPA 9060 92237760002 WETA/273102015003950EPA 9060 92237760003 WETA/273092015003951EPA 9060 92237760003 WETA/273102015003951EPA 9060 92237760004 WETA/273092015003954EPA 9060 92237760004 WETA/273102015003954EPA 9060 92237760005 WETA/273092015003955EPA 9060 92237760005 WETA/273102015003955EPA 9060 92237760007 WETA/273092015003953EPA 9060 92237760007 WETA/273102015003953EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 03/05/2015 11:54 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 65 Page 64 of 65 Page 65 of 65