NC0038377_App B Fourth Round Analytical Rpts_20171101

Comprehensive Site Assessment Supplement 1 July 2016
Mayo Steam Electric Plant SynTerra
P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\19.EG_CSASUP\MAYO CSA Supplement 1 July
2016.docx
APPENDIX B
FOURTH ROUND MONITORING EVENT
(JANUARY 2016) LABORATORY REPORTS

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J16010048
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:1/15/2016
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Analytical Lab
Page 1 of 40
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016000243 MAYO STEAM 05-Jan-16 10:55 AM Daniel M Youngblood ABMW-02
2016000244 MAYO STEAM 05-Jan-16 1:15 PM Daniel M Youngblood ABMW-02BR
2016000245 MAYO STEAM 05-Jan-16 2:28 PM Daniel M Youngblood ABMW-4D
2016000246 MAYO STEAM 05-Jan-16 12:36 PM Daniel M Youngblood ABMW-4BR
2016000247 MAYO STEAM 05-Jan-16 10:52 AM Daniel M Youngblood ABMW-04
2016000248 MAYO STEAM 05-Jan-16 2:45 PM Daniel M Youngblood Filter Blank
2016000249 MAYO STEAM 05-Jan-16 2:45 PM Daniel M Youngblood Equipment Blank
7 Total Samples
Analytical Lab
Page 2 of 40
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:1/15/2016
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000243
Collection Date:05-Jan-16 10:55 AM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.011 mg-N/L EPA 353.2 01/07/2016 11:18 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 01/06/2016 16:45 BGN90340.5 5
Sulfate 20 mg/L EPA 300.0 01/06/2016 16:45 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 13:13M2 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/07/2016 12:58 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.005 1
Barium (Ba)0.156 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.005 1
Boron (B)7.92 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.05 1
Iron (Fe)0.415 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.01 1
Manganese (Mn)0.986 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.005 1
Strontium (Sr)1.49 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/06/2016 13:44 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)71.9 mg/L EPA 200.7 01/07/2016 12:38 FCJORDA0.01 1
Magnesium (Mg)20.0 mg/L EPA 200.7 01/07/2016 12:38M4 FCJORDA0.005 1
Potassium (K)18.3 mg/L EPA 200.7 01/07/2016 12:38 FCJORDA0.1 1
Sodium (Na)35.2 mg/L EPA 200.7 01/07/2016 12:38 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.032 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.005 1
Barium (Ba)0.173 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.005 1
Boron (B)8.44 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.05 1
Iron (Fe)0.502 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.01 1
Manganese (Mn)1.09 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.005 1
Strontium (Sr)1.61 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 10:44 FCJORDA0.005 1
Analytical Lab
Page 4 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000243
Collection Date:05-Jan-16 10:55 AM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Arsenic (As)425 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Molybdenum (Mo)1040 ug/L EPA 200.8 01/09/2016 02:10 SLS25601010
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 02:10 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 02:10 SLS25600.2 1
Vanadium (V) Low Level 1.25 ug/L EPA 200.8 01/09/2016 02:10 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Arsenic (As)394 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Molybdenum (Mo)1130 ug/L EPA 200.8 01/08/2016 12:18 SLS25601010
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 12:18 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 12:18 SLS25600.2 1
Vanadium (V) Low Level 1.42 ug/L EPA 200.8 01/08/2016 12:18 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 440 mg/L SM2540C 01/07/2016 15:07 CJELLIO251
Total Carbon
TOC 9.4 mg/L SM5310C/EPA9060A 01/07/2016 14:01 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/07/2016 10:20 CJELLIO51
Analytical Lab
Page 5 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000244
Collection Date:05-Jan-16 1:15 PM
Site:ABMW-02BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/07/2016 11:22 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 26 mg/L EPA 300.0 01/07/2016 08:19 BGN90340.5 5
Sulfate 1.3 mg/L EPA 300.0 01/07/2016 08:19 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 13:23 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/07/2016 13:00 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.005 1
Barium (Ba)0.132 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.05 1
Iron (Fe)0.697 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.01 1
Manganese (Mn)0.223 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.005 1
Strontium (Sr)1.20 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/06/2016 13:55 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)75.4 mg/L EPA 200.7 01/07/2016 12:51 FCJORDA0.01 1
Magnesium (Mg)12.4 mg/L EPA 200.7 01/07/2016 12:51 FCJORDA0.005 1
Potassium (K)5.65 mg/L EPA 200.7 01/07/2016 12:51 FCJORDA0.1 1
Sodium (Na)29.3 mg/L EPA 200.7 01/07/2016 12:51 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.075 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.005 1
Barium (Ba)0.123 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.05 1
Iron (Fe)1.10 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.01 1
Manganese (Mn)0.237 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.005 1
Strontium (Sr)1.09 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.005 1
Zinc (Zn)0.016 mg/L EPA 200.7 01/08/2016 10:48 FCJORDA0.005 1
Analytical Lab
Page 6 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000244
Collection Date:05-Jan-16 1:15 PM
Site:ABMW-02BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Arsenic (As)1.29 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Molybdenum (Mo)2.98 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 17:47 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 17:47 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/08/2016 17:47 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Arsenic (As)2.02 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Molybdenum (Mo)3.26 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 10:07 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 10:07 SLS25600.2 1
Vanadium (V) Low Level 0.315 ug/L EPA 200.8 01/08/2016 10:07 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 350 mg/L SM2540C 01/07/2016 15:07 CJELLIO251
Total Carbon
TOC 1.3 mg/L SM5310C/EPA9060A 01/07/2016 14:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 01/07/2016 10:20 CJELLIO51
Analytical Lab
Page 7 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000245
Collection Date:05-Jan-16 2:28 PM
Site:ABMW-4D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 01/07/2016 11:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 01/07/2016 08:37 BGN90340.5 5
Sulfate 0.94 mg/L EPA 300.0 01/07/2016 08:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 13:25 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/07/2016 13:12M2 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.131 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.005 1
Barium (Ba)1.28 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.005 1
Boron (B)5.06 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.05 1
Iron (Fe)65.8 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.1 10
Manganese (Mn)7.32 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.005 1
Strontium (Sr)2.63 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 01/06/2016 13:59 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)134 mg/L EPA 200.7 01/07/2016 13:04 FCJORDA0.1 10
Magnesium (Mg)38.0 mg/L EPA 200.7 01/07/2016 13:04 FCJORDA0.05 10
Potassium (K)18.4 mg/L EPA 200.7 01/07/2016 13:04 FCJORDA110
Sodium (Na)18.2 mg/L EPA 200.7 01/07/2016 13:04 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.253 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.005 1
Barium (Ba)1.08 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.005 1
Boron (B)4.01 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.05 1
Iron (Fe)72.1 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.1 10
Manganese (Mn)6.65 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.005 1
Strontium (Sr)2.07 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 10:52 FCJORDA0.005 1
Analytical Lab
Page 8 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000245
Collection Date:05-Jan-16 2:28 PM
Site:ABMW-4D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Arsenic (As)53.5 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Cobalt (Co)3.42 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Molybdenum (Mo)33.7 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 02:15 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 02:15 SLS25600.2 1
Vanadium (V) Low Level 5.77 ug/L EPA 200.8 01/09/2016 02:15 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Arsenic (As)60.9 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Cobalt (Co)3.95 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Molybdenum (Mo)39.8 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 11:12 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 11:12 SLS25600.2 1
Vanadium (V) Low Level 6.01 ug/L EPA 200.8 01/08/2016 11:12 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 630 mg/L SM2540C 01/07/2016 15:07 CJELLIO251
Total Carbon
TOC 6.5 mg/L SM5310C/EPA9060A 01/07/2016 14:01 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS 120 mg/L SM2540D 01/07/2016 10:20 CJELLIO51
Analytical Lab
Page 9 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000246
Collection Date:05-Jan-16 12:36 PM
Site:ABMW-4BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/07/2016 11:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.9 mg/L EPA 300.0 01/06/2016 19:26 BGN90340.1 1
Sulfate 21 mg/L EPA 300.0 01/06/2016 19:26 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 13:32 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/07/2016 13:19 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.005 1
Barium (Ba)0.103 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.05 1
Iron (Fe)0.014 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.01 1
Manganese (Mn)0.350 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.005 1
Strontium (Sr)1.72 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/06/2016 14:03 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)75.6 mg/L EPA 200.7 01/07/2016 13:08 FCJORDA0.01 1
Magnesium (Mg)5.36 mg/L EPA 200.7 01/07/2016 13:08 FCJORDA0.005 1
Potassium (K)8.53 mg/L EPA 200.7 01/07/2016 13:08 FCJORDA0.1 1
Sodium (Na)21.7 mg/L EPA 200.7 01/07/2016 13:08 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.080 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.005 1
Barium (Ba)0.110 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.05 1
Iron (Fe)0.295 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.01 1
Manganese (Mn)0.364 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.005 1
Strontium (Sr)1.78 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 10:56 FCJORDA0.005 1
Analytical Lab
Page 10 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000246
Collection Date:05-Jan-16 12:36 PM
Site:ABMW-4BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 18:31 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 18:31 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/08/2016 18:31 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Copper (Cu)2.09 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Molybdenum (Mo)3.94 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 11:17 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 11:17 SLS25600.2 1
Vanadium (V) Low Level 0.438 ug/L EPA 200.8 01/08/2016 11:17 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 01/07/2016 15:07 CJELLIO251
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 01/07/2016 14:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 01/07/2016 10:20 CJELLIO51
Analytical Lab
Page 11 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000247
Collection Date:05-Jan-16 10:52 AM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.011 mg-N/L EPA 353.2 01/07/2016 11:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 01/06/2016 17:56 BGN90340.5 5
Sulfate 44 mg/L EPA 300.0 01/06/2016 17:56 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 13:37 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/07/2016 13:22 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.005 1
Barium (Ba)0.495 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.005 1
Boron (B)5.65 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.05 1
Iron (Fe)2.53 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.01 1
Manganese (Mn)1.07 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.005 1
Strontium (Sr)2.64 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/06/2016 14:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)121 mg/L EPA 200.7 01/07/2016 13:12 FCJORDA0.1 10
Magnesium (Mg)33.5 mg/L EPA 200.7 01/07/2016 13:12 FCJORDA0.05 10
Potassium (K)22.8 mg/L EPA 200.7 01/07/2016 13:12 FCJORDA110
Sodium (Na)11.9 mg/L EPA 200.7 01/07/2016 13:12 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.039 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.005 1
Barium (Ba)0.472 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.005 1
Boron (B)5.36 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.05 1
Iron (Fe)2.51 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.01 1
Manganese (Mn)1.03 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.005 1
Strontium (Sr)2.54 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 11:00 FCJORDA0.005 1
Analytical Lab
Page 12 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000247
Collection Date:05-Jan-16 10:52 AM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Arsenic (As)763 ug/L EPA 200.8 01/08/2016 18:36 SLS25601010
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Cobalt (Co)1.26 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Molybdenum (Mo)424 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 18:36 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 18:36 SLS25600.2 1
Vanadium (V) Low Level 1.84 ug/L EPA 200.8 01/08/2016 18:36 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Arsenic (As)708 ug/L EPA 200.8 01/08/2016 11:21 SLS25601010
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Cobalt (Co)1.19 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Molybdenum (Mo)418 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 11:21 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 11:21 SLS25600.2 1
Vanadium (V) Low Level 1.88 ug/L EPA 200.8 01/08/2016 11:21 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 550 mg/L SM2540C 01/07/2016 15:07 CJELLIO251
Total Carbon
TOC 2.6 mg/L SM5310C/EPA9060A 01/07/2016 14:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L SM2540D 01/07/2016 10:20 CJELLIO51
Analytical Lab
Page 13 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000248
Collection Date:05-Jan-16 2:45 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/07/2016 13:24 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/06/2016 14:11 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 18:41 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 18:41 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/08/2016 18:41 SLS25600.3 1
Analytical Lab
Page 14 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000249
Collection Date:05-Jan-16 2:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/07/2016 11:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/06/2016 15:33 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/06/2016 15:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 13:40 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.013 mg/L EPA 200.7 01/07/2016 13:16 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/07/2016 13:16 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/07/2016 13:16 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/07/2016 13:16 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 11:04 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/08/2016 11:51 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/08/2016 11:51 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/08/2016 11:51 SLS25600.3 1
Analytical Lab
Page 15 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010048
2016000249
Collection Date:05-Jan-16 2:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/07/2016 15:07 CJELLIO251
Total Carbon
TOC 0.129 mg/L SM5310C/EPA9060A 01/07/2016 14:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/07/2016 10:20 CJELLIO51
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to
the spike level. The associated Laboratory Control Spike recovery was acceptable.
Analytical Lab
Page 16 of 40
#=CL#
January 12, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92281987
92281987
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010048 MAYO
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
Analytical Lab
Page 17 of 40
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92281987
J16010048 MAYO
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
Analytical Lab
Page 18 of 40
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92281987
J16010048 MAYO
Lab ID Sample ID Matrix Date Collected Date Received
92281987001 2016000243 Water 01/05/16 10:55 01/06/16 11:11
92281987002 2016000244 Water 01/05/16 13:15 01/06/16 11:11
92281987003 2016000245 Water 01/05/16 14:28 01/06/16 11:11
92281987004 2016000246 Water 01/05/16 12:36 01/06/16 11:11
92281987005 2016000247 Water 01/05/16 10:52 01/06/16 11:11
92281987006 2016000249 Water 01/05/16 14:45 01/06/16 11:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
Analytical Lab
Page 19 of 40
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92281987
J16010048 MAYO
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92281987001 2016000243 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92281987002 2016000244 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92281987003 2016000245 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92281987004 2016000246 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92281987005 2016000247 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92281987006 2016000249 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
Analytical Lab
Page 20 of 40
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92281987
J16010048 MAYO
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92281987001 2016000243
Methane 17400 ug/L 01/07/16 16:2610.0RSK 175
Alkalinity,Bicarbonate (CaCO3)335 mg/L 01/07/16 22:145.0SM 2320B
Alkalinity, Total as CaCO3 335 mg/L 01/07/16 22:145.0SM 2320B
92281987002 2016000244
Methane 288 ug/L 01/07/16 16:4210.0RSK 175
Alkalinity,Bicarbonate (CaCO3)284 mg/L 01/07/16 22:305.0SM 2320B
Alkalinity, Total as CaCO3 284 mg/L 01/07/16 22:305.0SM 2320B
92281987003 2016000245
Methane 17900 ug/L 01/07/16 16:5110.0RSK 175
Alkalinity,Bicarbonate (CaCO3)596 mg/L 01/07/16 23:035.0SM 2320B
Alkalinity, Total as CaCO3 596 mg/L 01/07/16 23:035.0SM 2320B
92281987004 2016000246
Methane 1000 ug/L 01/07/16 16:5910.0RSK 175
Alkalinity,Bicarbonate (CaCO3)243 mg/L 01/07/16 23:335.0SM 2320B
Alkalinity, Total as CaCO3 243 mg/L 01/07/16 23:335.0SM 2320B
Sulfide 3.9 mg/L 01/07/16 17:000.50SM 4500-S2D
92281987005 2016000247
Methane 8000 ug/L 01/07/16 17:0710.0RSK 175
Alkalinity,Bicarbonate (CaCO3)425 mg/L 01/07/16 23:465.0SM 2320B
Alkalinity, Total as CaCO3 425 mg/L 01/07/16 23:465.0SM 2320B
REPORT OF LABORATORY ANALYSIS
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Analytical Lab
Page 21 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92281987
J16010048 MAYO
Method:
Client:Duke Energy
RSK 175
Date:January 12, 2016
Description:RSK 175 AIR Headspace
General Information:
6 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Analytical Lab
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92281987
J16010048 MAYO
Method:
Client:Duke Energy
SM 2320B
Date:January 12, 2016
Description:2320B Alkalinity
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Analytical Lab
Page 23 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92281987
J16010048 MAYO
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 12, 2016
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42342
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92281984003,92281984013
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1642364)
• Sulfide
• MSD (Lab ID: 1642365)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Analytical Lab
Page 24 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92281987
J16010048 MAYO
Method:
Client:Duke Energy
EPA 218.7
Date:January 12, 2016
Description:Hexavalent Chromium by IC
General Information:
6 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Analytical Lab
Page 25 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281987
J16010048 MAYO
Sample:2016000243 Lab ID:92281987001 Collected:01/05/16 10:55 Received:01/06/16 11:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 17400 ug/L 01/07/16 16:26 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)335 mg/L 01/07/16 22:145.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/07/16 22:145.0 1
Alkalinity, Total as CaCO3 335 mg/L 01/07/16 22:145.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/07/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 08:34 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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[phone]
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Analytical Lab
Page 26 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281987
J16010048 MAYO
Sample:2016000244 Lab ID:92281987002 Collected:01/05/16 13:15 Received:01/06/16 11:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 288 ug/L 01/07/16 16:42 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)284 mg/L 01/07/16 22:305.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/07/16 22:305.0 1
Alkalinity, Total as CaCO3 284 mg/L 01/07/16 22:305.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/07/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 08:47 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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[phone]
Page 11 of 23
Analytical Lab
Page 27 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281987
J16010048 MAYO
Sample:2016000245 Lab ID:92281987003 Collected:01/05/16 14:28 Received:01/06/16 11:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 17900 ug/L 01/07/16 16:51 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)596 mg/L 01/07/16 23:035.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/07/16 23:035.0 1
Alkalinity, Total as CaCO3 596 mg/L 01/07/16 23:035.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/07/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 09:00 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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[phone]
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Analytical Lab
Page 28 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281987
J16010048 MAYO
Sample:2016000246 Lab ID:92281987004 Collected:01/05/16 12:36 Received:01/06/16 11:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 1000 ug/L 01/07/16 16:59 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)243 mg/L 01/07/16 23:335.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/07/16 23:335.0 1
Alkalinity, Total as CaCO3 243 mg/L 01/07/16 23:335.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 3.9 mg/L 01/07/16 17:00 18496-25-80.50 5
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 09:13 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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[phone]
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Analytical Lab
Page 29 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281987
J16010048 MAYO
Sample:2016000247 Lab ID:92281987005 Collected:01/05/16 10:52 Received:01/06/16 11:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 8000 ug/L 01/07/16 17:07 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)425 mg/L 01/07/16 23:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/07/16 23:465.0 1
Alkalinity, Total as CaCO3 425 mg/L 01/07/16 23:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/07/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 09:26 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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[phone]
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Analytical Lab
Page 30 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92281987
J16010048 MAYO
Sample:2016000249 Lab ID:92281987006 Collected:01/05/16 14:45 Received:01/06/16 11:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/07/16 17:15 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/08/16 00:035.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/08/16 00:035.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/08/16 00:035.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/07/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 09:39 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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Huntersville, NC 28078
[phone]
Page 15 of 23
Analytical Lab
Page 31 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281987
J16010048 MAYO
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24980
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2171402
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/07/16 14:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2171403LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2171404
Methane ug/L 57.260.7 94 85-1159859.6 4 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92281981010
2172103SAMPLE DUPLICATE:
Methane ug/L 3.4J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92281987001
2172104SAMPLE DUPLICATE:
Methane ug/L 19500 12 2017400
REPORT OF LABORATORY ANALYSIS
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Analytical Lab
Page 32 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281987
J16010048 MAYO
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42339
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1642346
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/07/16 17:57
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/07/16 17:57
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/07/16 17:57
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1642347LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.250 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1642348MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281984003
1642349
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 95 80-12088 1 2550233281277
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1642350MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281984013
1642351
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 85 80-12096 2 2550231274280
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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Analytical Lab
Page 33 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281987
J16010048 MAYO
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42342
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1642362
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/07/16 17:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1642363LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1642364MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281984003
1642365
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 86 90-11086 0 10.5ND 0.43 0.43
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1642366MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281984013
1642367
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 92 90-11092 0 10.5ND 0.46 0.46
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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Page 18 of 23
Analytical Lab
Page 34 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92281987
J16010048 MAYO
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/53592
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92281987001, 92281987002, 92281987003, 92281987004, 92281987005, 92281987006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1440775
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/08/16 12:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1440776LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.076.075 102 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1440777MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281984003
1440778
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M6.25 112 85-11580 5 20.251.5 1.8 1.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1440779MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92281984013
1440780
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L 1.5 98 85-11594 1 201.54.5 6.0 5.9
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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Analytical Lab
Page 35 of 40
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92281987
J16010048 MAYO
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
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Page 20 of 23
Analytical Lab
Page 36 of 40
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92281987
J16010048 MAYO
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92281987001 AIR/249802016000243RSK 175
92281987002 AIR/249802016000244RSK 175
92281987003 AIR/249802016000245RSK 175
92281987004 AIR/249802016000246RSK 175
92281987005 AIR/249802016000247RSK 175
92281987006 AIR/249802016000249RSK 175
92281987001 WET/423392016000243SM 2320B
92281987002 WET/423392016000244SM 2320B
92281987003 WET/423392016000245SM 2320B
92281987004 WET/423392016000246SM 2320B
92281987005 WET/423392016000247SM 2320B
92281987006 WET/423392016000249SM 2320B
92281987001 WET/423422016000243SM 4500-S2D
92281987002 WET/423422016000244SM 4500-S2D
92281987003 WET/423422016000245SM 4500-S2D
92281987004 WET/423422016000246SM 4500-S2D
92281987005 WET/423422016000247SM 4500-S2D
92281987006 WET/423422016000249SM 4500-S2D
92281987001 WETA/535922016000243EPA 218.7
92281987002 WETA/535922016000244EPA 218.7
92281987003 WETA/535922016000245EPA 218.7
92281987004 WETA/535922016000246EPA 218.7
92281987005 WETA/535922016000247EPA 218.7
92281987006 WETA/535922016000249EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 08:26 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 23
Analytical Lab
Page 37 of 40
Page 22 of 23
Analytical Lab
Page 38 of 40
Page 23 of 23
Analytical Lab
Page 39 of 40
Analytical Lab
Page 40 of 40
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010086
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:1/15/2016
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 67
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016000429 MAYO STEAM 06-Jan-16 9:38 AM illegible MW-3
2016000430 MAYO STEAM 06-Jan-16 12:25 PM illegible MW-2
2016000431 MAYO STEAM 06-Jan-16 10:32 AM illegible MW-08BR
2016000432 MAYO STEAM 06-Jan-16 9:38 AM illegible MW-3 Dup
2016000433 MAYO STEAM 06-Jan-16 12:10 PM illegible MW-7D
2016000434 MAYO STEAM 06-Jan-16 1:38 PM illegible MW-7BR
2016000435 MAYO STEAM 06-Jan-16 11:45 AM illegible MW-04
2016000436 MAYO STEAM 05-Jan-16 11:10 AM illegible ABMW-3
2016000437 MAYO STEAM 05-Jan-16 10:35 AM illegible ABMW-3S
2016000438 MAYO STEAM 06-Jan-16 4:45 PM illegible Filter Blank
2016000439 MAYO STEAM 06-Jan-16 4:45 PM illegible Equipment Blank
2016000440 MAYO STEAM 06-Jan-16 4:40 PM illegible CW-6
2016000441 MAYO STEAM 06-Jan-16 3:35 PM illegible CW-2
2016000442 MAYO STEAM 06-Jan-16 3:00 PM illegible CW-2D
14 Total Samples
Page 2 of 67
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:1/15/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000429
Collection Date:06-Jan-16 9:38 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.055 mg-N/L EPA 353.2 01/07/2016 13:21 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 46 mg/L EPA 300.0 01/08/2016 20:58 BGN90340.5 5
Sulfate 22 mg/L EPA 300.0 01/08/2016 20:58 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:00 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:04 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.005 1
Barium (Ba)0.058 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.005 1
Boron (B)0.911 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.01 1
Manganese (Mn)1.23 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.005 1
Strontium (Sr)0.326 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 12:32 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)26.2 mg/L EPA 200.7 01/11/2016 10:54 FCJORDA0.01 1
Magnesium (Mg)8.75 mg/L EPA 200.7 01/11/2016 10:54 FCJORDA0.005 1
Potassium (K)2.13 mg/L EPA 200.7 01/11/2016 10:54 FCJORDA0.1 1
Sodium (Na)22.8 mg/L EPA 200.7 01/11/2016 10:54 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Boron (B)0.896 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.01 1
Manganese (Mn)1.42 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Strontium (Sr)0.328 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Page 4 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000429
Collection Date:06-Jan-16 9:38 AM
Site:MW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Nickel (Ni)2.98 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:01 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:01 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 13:01 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Nickel (Ni)2.82 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 09:48 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 09:48 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 09:48 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.919 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 5 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000430
Collection Date:06-Jan-16 12:25 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.119 mg-N/L EPA 353.2 01/07/2016 13:23 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 16 mg/L EPA 300.0 01/08/2016 18:17 BGN9034110
Sulfate 18 mg/L EPA 300.0 01/08/2016 18:17 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:02 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:06 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.005 1
Barium (Ba)0.058 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.05 1
Iron (Fe)0.561 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.01 1
Manganese (Mn)0.979 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.005 1
Strontium (Sr)0.186 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/08/2016 12:43 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)17.8 mg/L EPA 200.7 01/11/2016 10:57 FCJORDA0.01 1
Magnesium (Mg)7.34 mg/L EPA 200.7 01/11/2016 10:57 FCJORDA0.005 1
Potassium (K)4.74 mg/L EPA 200.7 01/11/2016 10:57 FCJORDA0.1 1
Sodium (Na)26.7 mg/L EPA 200.7 01/11/2016 10:57 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.531 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.005 1
Barium (Ba)0.059 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.05 1
Iron (Fe)0.813 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.01 1
Manganese (Mn)1.12 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.005 1
Strontium (Sr)0.189 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:48 FCJORDA0.005 1
Page 6 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000430
Collection Date:06-Jan-16 12:25 PM
Site:MW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Cobalt (Co)3.34 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Nickel (Ni)2.62 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:06 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:06 SLS25600.2 1
Vanadium (V) Low Level 0.443 ug/L EPA 200.8 01/09/2016 13:06 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Cobalt (Co)3.81 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Nickel (Ni)2.68 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 20:04 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 20:04 SLS25600.2 1
Vanadium (V) Low Level 0.678 ug/L EPA 200.8 01/09/2016 20:04 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 1.5 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 7 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000431
Collection Date:06-Jan-16 10:32 AM
Site:MW-08BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.123 mg-N/L EPA 353.2 01/07/2016 13:24 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 130 mg/L EPA 300.0 01/08/2016 18:35 BGN9034220
Sulfate 37 mg/L EPA 300.0 01/08/2016 18:35 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:04 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:16 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.005 1
Barium (Ba)0.037 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.05 1
Iron (Fe)0.163 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.01 1
Manganese (Mn)0.748 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.005 1
Strontium (Sr)0.380 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 12:55 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)77.5 mg/L EPA 200.7 01/11/2016 11:09 FCJORDA0.01 1
Magnesium (Mg)23.3 mg/L EPA 200.7 01/11/2016 11:09M4 FCJORDA0.05 10
Potassium (K)6.02 mg/L EPA 200.7 01/11/2016 11:09 FCJORDA0.1 1
Sodium (Na)33.4 mg/L EPA 200.7 01/11/2016 11:09 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.185 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.005 1
Barium (Ba)0.034 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.05 1
Iron (Fe)0.417 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.01 1
Manganese (Mn)0.681 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.005 1
Strontium (Sr)0.372 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/08/2016 14:53 FCJORDA0.005 1
Page 8 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000431
Collection Date:06-Jan-16 10:32 AM
Site:MW-08BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Molybdenum (Mo)3.43 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Nickel (Ni)3.91 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 21:56 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 21:56 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 21:56 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Chromium (Cr)4.73 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Molybdenum (Mo)3.54 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Nickel (Ni)4.24 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 20:38 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 20:38 SLS25600.2 1
Vanadium (V) Low Level 0.432 ug/L EPA 200.8 01/09/2016 20:38 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 480 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 1.4 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 9 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000432
Collection Date:06-Jan-16 9:38 AM
Site:MW-3 Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.056 mg-N/L EPA 353.2 01/07/2016 13:25 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 46 mg/L EPA 300.0 01/08/2016 21:16 BGN9034220
Sulfate 22 mg/L EPA 300.0 01/08/2016 21:16 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:07 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:18 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.005 1
Barium (Ba)0.058 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.005 1
Boron (B)0.909 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.01 1
Manganese (Mn)1.22 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.005 1
Strontium (Sr)0.323 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)26.3 mg/L EPA 200.7 01/11/2016 11:24 FCJORDA0.01 1
Magnesium (Mg)8.84 mg/L EPA 200.7 01/11/2016 11:24 FCJORDA0.005 1
Potassium (K)2.12 mg/L EPA 200.7 01/11/2016 11:24 FCJORDA0.1 1
Sodium (Na)22.7 mg/L EPA 200.7 01/11/2016 11:24 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.005 1
Boron (B)0.889 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.01 1
Manganese (Mn)1.42 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.005 1
Strontium (Sr)0.326 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:57 FCJORDA0.005 1
Page 10 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000432
Collection Date:06-Jan-16 9:38 AM
Site:MW-3 Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Nickel (Ni)3.03 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:10 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:10 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 13:10 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Nickel (Ni)3.01 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 20:43 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 20:43 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 20:43 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.886 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 11 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000433
Collection Date:06-Jan-16 12:10 PM
Site:MW-7D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/07/2016 13:26 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 73 mg/L EPA 300.0 01/08/2016 19:10 BGN9034110
Sulfate 11 mg/L EPA 300.0 01/08/2016 19:10 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:09 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:20 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.05 1
Iron (Fe)0.010 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.01 1
Manganese (Mn)0.070 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.005 1
Strontium (Sr)0.417 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:10 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)54.1 mg/L EPA 200.7 01/11/2016 11:35 FCJORDA0.01 1
Magnesium (Mg)22.9 mg/L EPA 200.7 01/11/2016 11:35 FCJORDA0.05 10
Potassium (K)1.98 mg/L EPA 200.7 01/11/2016 11:35 FCJORDA0.1 1
Sodium (Na)32.3 mg/L EPA 200.7 01/11/2016 11:35 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.052 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.05 1
Iron (Fe)0.154 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.01 1
Manganese (Mn)0.069 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.005 1
Strontium (Sr)0.417 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 15:01 FCJORDA0.005 1
Page 12 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000433
Collection Date:06-Jan-16 12:10 PM
Site:MW-7D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:25 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:25 SLS25600.2 1
Vanadium (V) Low Level 0.678 ug/L EPA 200.8 01/09/2016 13:25 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 20:48 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 20:48 SLS25600.2 1
Vanadium (V) Low Level 0.757 ug/L EPA 200.8 01/09/2016 20:48 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 1.2 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 13 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000434
Collection Date:06-Jan-16 1:38 PM
Site:MW-7BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.098 mg-N/L EPA 353.2 01/07/2016 13:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 01/08/2016 20:40 BGN90340.2 2
Sulfate 2.3 mg/L EPA 300.0 01/08/2016 20:40 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:12 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:23 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.005 1
Barium (Ba)0.151 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.05 1
Iron (Fe)0.405 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.01 1
Manganese (Mn)0.218 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.005 1
Strontium (Sr)1.04 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:14 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)60.1 mg/L EPA 200.7 01/11/2016 11:39 FCJORDA0.1 10
Magnesium (Mg)13.5 mg/L EPA 200.7 01/11/2016 11:39 FCJORDA0.05 10
Potassium (K)4.30 mg/L EPA 200.7 01/11/2016 11:39 FCJORDA110
Sodium (Na)17.6 mg/L EPA 200.7 01/11/2016 11:39 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.017 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.005 1
Barium (Ba)0.150 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.05 1
Iron (Fe)0.422 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.01 1
Manganese (Mn)0.210 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.005 1
Strontium (Sr)1.02 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 15:05 FCJORDA0.005 1
Page 14 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000434
Collection Date:06-Jan-16 1:38 PM
Site:MW-7BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Molybdenum (Mo)2.93 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:15 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:15 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 13:15 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Molybdenum (Mo)2.98 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 20:53 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 20:53 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 20:53 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.854 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 15 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000435
Collection Date:06-Jan-16 11:45 AM
Site:MW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.322 mg-N/L EPA 353.2 01/07/2016 13:35 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.5 mg/L EPA 300.0 01/09/2016 09:43 BGN90340.1 1
Sulfate 38 mg/L EPA 300.0 01/09/2016 09:43 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:19 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:30 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.005 1
Barium (Ba)0.008 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.01 1
Manganese (Mn)0.067 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.005 1
Strontium (Sr)0.101 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.005 1
Zinc (Zn)0.058 mg/L EPA 200.7 01/08/2016 13:18 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)26.2 mg/L EPA 200.7 01/11/2016 11:43 FCJORDA0.01 1
Magnesium (Mg)7.54 mg/L EPA 200.7 01/11/2016 11:43 FCJORDA0.005 1
Potassium (K)5.80 mg/L EPA 200.7 01/11/2016 11:43 FCJORDA0.1 1
Sodium (Na)18.9 mg/L EPA 200.7 01/11/2016 11:43 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.232 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.005 1
Barium (Ba)0.009 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.05 1
Iron (Fe)0.141 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.01 1
Manganese (Mn)0.079 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.005 1
Strontium (Sr)0.095 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.005 1
Zinc (Zn)0.053 mg/L EPA 200.7 01/08/2016 15:09 FCJORDA0.005 1
Page 16 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000435
Collection Date:06-Jan-16 11:45 AM
Site:MW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Molybdenum (Mo)2.55 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Nickel (Ni)2.06 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:20 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:20 SLS25600.2 1
Vanadium (V) Low Level 0.579 ug/L EPA 200.8 01/09/2016 13:20 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Chromium (Cr)4.21 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Copper (Cu)1.66 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Molybdenum (Mo)2.80 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Nickel (Ni)3.06 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 20:57 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 20:57 SLS25600.2 1
Vanadium (V) Low Level 0.803 ug/L EPA 200.8 01/09/2016 20:57 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.717 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 17 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000436
Collection Date:05-Jan-16 11:10 AM
Site:ABMW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.011 mg-N/L EPA 353.2 01/07/2016 13:38 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 62 mg/L EPA 300.0 01/08/2016 21:34 BGN9034110
Sulfate 3.7 mg/L EPA 300.0 01/08/2016 21:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:37 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.005 1
Barium (Ba)0.277 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.005 1
Boron (B)1.77 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.05 1
Iron (Fe)22.5 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.01 1
Manganese (Mn)1.09 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.005 1
Strontium (Sr)1.60 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)62.5 mg/L EPA 200.7 01/11/2016 11:47 FCJORDA0.01 1
Magnesium (Mg)13.7 mg/L EPA 200.7 01/11/2016 11:47 FCJORDA0.005 1
Potassium (K)12.7 mg/L EPA 200.7 01/11/2016 11:47 FCJORDA0.1 1
Sodium (Na)10.3 mg/L EPA 200.7 01/11/2016 11:47 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.098 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.005 1
Barium (Ba)0.292 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.005 1
Boron (B)1.80 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.05 1
Iron (Fe)26.2 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.01 1
Manganese (Mn)1.21 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.005 1
Strontium (Sr)1.66 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 15:14 FCJORDA0.005 1
Page 18 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000436
Collection Date:05-Jan-16 11:10 AM
Site:ABMW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Arsenic (As)82.7 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Molybdenum (Mo)11.8 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/11/2016 12:53 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/11/2016 12:53 SLS25600.2 1
Vanadium (V) Low Level 0.302 ug/L EPA 200.8 01/11/2016 12:53 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Arsenic (As)79.8 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Chromium (Cr)1.29 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Molybdenum (Mo)10.6 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 21:02 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 21:02 SLS25600.2 1
Vanadium (V) Low Level 0.603 ug/L EPA 200.8 01/09/2016 21:02 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 3.0 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 43 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 19 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000437
Collection Date:05-Jan-16 10:35 AM
Site:ABMW-3S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/07/2016 13:39 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 01/09/2016 10:01 BGN90340.2 2
Sulfate 0.24 mg/L EPA 300.0 01/09/2016 10:01 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:28 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:39 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.005 1
Boron (B)1.23 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.05 1
Iron (Fe)3.70 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.01 1
Manganese (Mn)0.529 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.005 1
Strontium (Sr)0.073 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:26 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)4.06 mg/L EPA 200.7 01/11/2016 11:51 FCJORDA0.01 1
Magnesium (Mg)0.863 mg/L EPA 200.7 01/11/2016 11:51 FCJORDA0.005 1
Potassium (K)1.03 mg/L EPA 200.7 01/11/2016 11:51 FCJORDA0.1 1
Sodium (Na)17.1 mg/L EPA 200.7 01/11/2016 11:51 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.042 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.005 1
Boron (B)1.22 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.05 1
Iron (Fe)4.34 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.01 1
Manganese (Mn)0.531 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.005 1
Strontium (Sr)0.078 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 15:35 FCJORDA0.005 1
Page 20 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000437
Collection Date:05-Jan-16 10:35 AM
Site:ABMW-3S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Arsenic (As)1.28 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Cobalt (Co)3.39 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 13:59 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 13:59 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 13:59 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Arsenic (As)1.35 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Cobalt (Co)3.42 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Nickel (Ni)1.19 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 21:07 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 21:07 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 21:07 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 97 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.498 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 21 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000438
Collection Date:06-Jan-16 4:45 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:41 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:30 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 14:04 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 14:04 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 14:04 SLS25600.3 1
Page 22 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000439
Collection Date:06-Jan-16 4:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.111 mg-N/L EPA 353.2 01/07/2016 13:41 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/08/2016 16:57 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/08/2016 16:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:30 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 01/11/2016 11:55 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/11/2016 11:55 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/11/2016 11:55 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/11/2016 11:55 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 15:18 FCJORDA0.005 1
Page 23 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000439
Collection Date:06-Jan-16 4:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 21:12 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 21:12 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 21:12 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.245 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 24 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000440
Collection Date:06-Jan-16 4:40 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.182 mg-N/L EPA 353.2 01/07/2016 13:42 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 100 mg/L EPA 300.0 01/08/2016 15:10 BGN9034220
Sulfate 41 mg/L EPA 300.0 01/08/2016 15:10 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:33 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:44 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.005 1
Barium (Ba)0.044 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.05 1
Iron (Fe)1.82 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.01 1
Manganese (Mn)1.43 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.005 1
Strontium (Sr)0.332 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:41 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)107 mg/L EPA 200.7 01/11/2016 12:11 FCJORDA0.1 10
Magnesium (Mg)22.1 mg/L EPA 200.7 01/11/2016 12:11 FCJORDA0.05 10
Potassium (K)10.4 mg/L EPA 200.7 01/11/2016 12:11 FCJORDA110
Sodium (Na)39.0 mg/L EPA 200.7 01/11/2016 12:11 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.040 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.05 1
Iron (Fe)1.79 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.01 1
Manganese (Mn)1.44 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.005 1
Strontium (Sr)0.329 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 15:22 FCJORDA0.005 1
Page 25 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000440
Collection Date:06-Jan-16 4:40 PM
Site:CW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Molybdenum (Mo)3.36 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Nickel (Ni)1.03 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 14:09 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 14:09 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 14:09 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Molybdenum (Mo)3.55 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Nickel (Ni)1.10 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 21:32 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 21:32 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 21:32 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 520 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 1.7 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 26 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000441
Collection Date:06-Jan-16 3:35 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.019 mg-N/L EPA 353.2 01/07/2016 13:43 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 40 mg/L EPA 300.0 01/08/2016 15:27 BGN9034110
Sulfate 35 mg/L EPA 300.0 01/08/2016 15:27 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:35 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:46 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.005 1
Barium (Ba)0.100 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.005 1
Boron (B)0.552 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.01 1
Manganese (Mn)0.182 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.005 1
Strontium (Sr)0.177 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 01/08/2016 13:45 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.9 mg/L EPA 200.7 01/11/2016 12:14 FCJORDA0.01 1
Magnesium (Mg)6.70 mg/L EPA 200.7 01/11/2016 12:14 FCJORDA0.005 1
Potassium (K)1.79 mg/L EPA 200.7 01/11/2016 12:14 FCJORDA0.1 1
Sodium (Na)12.9 mg/L EPA 200.7 01/11/2016 12:14 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.005 1
Barium (Ba)0.099 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.005 1
Boron (B)0.539 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.01 1
Manganese (Mn)0.173 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.005 1
Strontium (Sr)0.177 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 01/08/2016 15:47 FCJORDA0.005 1
Page 27 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000441
Collection Date:06-Jan-16 3:35 PM
Site:CW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Nickel (Ni)1.58 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 14:14 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 14:14 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 14:14 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Nickel (Ni)1.49 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 10:08 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 10:08 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 10:08 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 1.2 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 28 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000442
Collection Date:06-Jan-16 3:00 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.040 mg-N/L EPA 353.2 01/07/2016 13:44 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 56 mg/L EPA 300.0 01/08/2016 15:45 BGN9034110
Sulfate 43 mg/L EPA 300.0 01/08/2016 15:45 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:37 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:49 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.005 1
Boron (B)0.507 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.01 1
Manganese (Mn)0.077 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.005 1
Strontium (Sr)0.245 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.005 1
Zinc (Zn)0.029 mg/L EPA 200.7 01/08/2016 13:49 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.4 mg/L EPA 200.7 01/11/2016 12:18 FCJORDA0.01 1
Magnesium (Mg)6.84 mg/L EPA 200.7 01/11/2016 12:18 FCJORDA0.005 1
Potassium (K)2.70 mg/L EPA 200.7 01/11/2016 12:18 FCJORDA0.1 1
Sodium (Na)23.1 mg/L EPA 200.7 01/11/2016 12:18 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.724 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.005 1
Barium (Ba)0.051 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.005 1
Boron (B)0.484 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.05 1
Iron (Fe)0.332 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.01 1
Manganese (Mn)0.148 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.005 1
Strontium (Sr)0.255 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.005 1
Zinc (Zn)0.026 mg/L EPA 200.7 01/08/2016 15:51 FCJORDA0.005 1
Page 29 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000442
Collection Date:06-Jan-16 3:00 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 14:19 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 14:19 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/09/2016 14:19 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Nickel (Ni)1.01 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/09/2016 21:51 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/09/2016 21:51 SLS25600.2 1
Vanadium (V) Low Level 0.594 ug/L EPA 200.8 01/09/2016 21:51 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 01/08/2016 15:47 CJELLIO251
Total Carbon
TOC 0.538 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 13 mg/L SM2540D 01/08/2016 09:37 CJELLIO51
Page 30 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010086
2016000442
Collection Date:06-Jan-16 3:00 PM
Site:CW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Page 31 of 67
#=CL#
January 12, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92282172
92282172
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010086
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 07, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 34
Page 32 of 67
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92282172
J16010086
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
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Arkansas Certification #: 88-0680
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Connecticut Certification #: PH-0256
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Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
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Nevada Certification #: MN_00064
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New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
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Ohio EPA #: 4150
Ohio VAP Certification #: CL101
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Pennsylvania Certification #: 68-00563
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Virginia DGS Certification #: 251
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Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 34
Page 33 of 67
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92282172
J16010086
Lab ID Sample ID Matrix Date Collected Date Received
92282172001 2016000429 Water 01/06/16 09:38 01/07/16 14:05
92282172002 2016000430 Water 01/06/16 12:25 01/07/16 14:05
92282172003 2016000431 Water 01/06/16 10:32 01/07/16 14:05
92282172004 2016000432 Water 01/06/16 09:38 01/07/16 14:05
92282172005 2016000433 Water 01/06/16 12:10 01/07/16 14:05
92282172006 2016000434 Water 01/06/16 13:38 01/07/16 14:05
92282172007 2016000435 Water 01/06/16 11:45 01/07/16 14:05
92282172008 2016000436 Water 01/05/16 11:10 01/07/16 14:05
92282172009 2016000437 Water 01/05/16 10:35 01/07/16 14:05
92282172010 2016000439 Water 01/06/16 16:45 01/07/16 14:05
92282172011 2016000440 Water 01/06/16 16:40 01/07/16 14:05
92282172012 2016000441 Water 01/06/16 15:35 01/07/16 14:05
92282172013 2016000442 Water 01/06/16 15:00 01/07/16 14:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 34
Page 34 of 67
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92282172
J16010086
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92282172001 2016000429 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172002 2016000430 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172003 2016000431 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172004 2016000432 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172005 2016000433 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172006 2016000434 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172007 2016000435 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172008 2016000436 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172009 2016000437 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172010 2016000439 RSK 175 1 PASI-MDR1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 34
Page 35 of 67
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92282172
J16010086
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172011 2016000440 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172012 2016000441 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282172013 2016000442 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 34
Page 36 of 67
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92282172
J16010086
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92282172001 2016000429
Alkalinity,Bicarbonate (CaCO3)71.0 mg/L 01/10/16 12:555.0SM 2320B
Alkalinity, Total as CaCO3 71.0 mg/L 01/10/16 12:555.0SM 2320B
Chromium, Hexavalent 0.17 ug/L 01/08/16 16:36 M10.030EPA 218.7
92282172002 2016000430
Methane 802 ug/L 01/08/16 13:0310.0RSK 175
Alkalinity,Bicarbonate (CaCO3)95.5 mg/L 01/10/16 13:345.0SM 2320B
Alkalinity, Total as CaCO3 95.5 mg/L 01/10/16 13:345.0SM 2320B
92282172003 2016000431
Methane 14.4 ug/L 01/08/16 13:1110.0RSK 175
Alkalinity,Bicarbonate (CaCO3)156 mg/L 01/10/16 13:465.0SM 2320B
Alkalinity, Total as CaCO3 156 mg/L 01/10/16 13:465.0SM 2320B
92282172004 2016000432
Alkalinity,Bicarbonate (CaCO3)69.5 mg/L 01/10/16 14:005.0SM 2320B
Alkalinity, Total as CaCO3 69.5 mg/L 01/10/16 14:005.0SM 2320B
Chromium, Hexavalent 0.17 ug/L 01/08/16 17:410.030EPA 218.7
92282172005 2016000433
Alkalinity,Bicarbonate (CaCO3)181 mg/L 01/10/16 14:125.0SM 2320B
Alkalinity, Total as CaCO3 181 mg/L 01/10/16 14:125.0SM 2320B
92282172006 2016000434
Methane 59.7 ug/L 01/08/16 14:1010.0RSK 175
Alkalinity,Bicarbonate (CaCO3)218 mg/L 01/10/16 14:265.0SM 2320B
Alkalinity, Total as CaCO3 218 mg/L 01/10/16 14:265.0SM 2320B
92282172007 2016000435
Alkalinity,Bicarbonate (CaCO3)93.2 mg/L 01/10/16 15:005.0SM 2320B
Alkalinity, Total as CaCO3 93.2 mg/L 01/10/16 15:005.0SM 2320B
Chromium, Hexavalent 0.16 ug/L 01/08/16 18:200.030EPA 218.7
92282172008 2016000436
Methane 7850 ug/L 01/08/16 14:2610.0RSK 175
Alkalinity,Bicarbonate (CaCO3)181 mg/L 01/10/16 15:135.0SM 2320B
Alkalinity, Total as CaCO3 181 mg/L 01/10/16 15:135.0SM 2320B
92282172009 2016000437
Methane 108 ug/L 01/08/16 14:3410.0RSK 175
Alkalinity,Bicarbonate (CaCO3)40.4 mg/L 01/10/16 15:285.0SM 2320B
Alkalinity, Total as CaCO3 40.4 mg/L 01/10/16 15:285.0SM 2320B
92282172011 2016000440
Methane 90.8 ug/L 01/08/16 14:5110.0RSK 175
92282172012 2016000441
Chromium, Hexavalent 0.087 ug/L 01/08/16 20:170.030EPA 218.7
92282172013 2016000442
Alkalinity,Bicarbonate (CaCO3)25.4 mg/L 01/10/16 17:485.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 34
Page 37 of 67
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92282172
J16010086
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92282172013 2016000442
Alkalinity, Total as CaCO3 25.4 mg/L 01/10/16 17:485.0SM 2320B
Chromium, Hexavalent 0.089 ug/L 01/08/16 20:300.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 7 of 34
Page 38 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282172
J16010086
Method:
Client:Duke Energy
RSK 175
Date:January 12, 2016
Description:RSK 175 AIR Headspace
General Information:
13 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 8 of 34
Page 39 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282172
J16010086
Method:
Client:Duke Energy
SM 2320B
Date:January 12, 2016
Description:2320B Alkalinity
General Information:
13 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42371
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282172001,92282172011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1643733)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1643734)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 34
Page 40 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282172
J16010086
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 12, 2016
Description:4500S2D Sulfide Water
General Information:
13 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42367
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282172001,92282172011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1643318)
• Sulfide
• MSD (Lab ID: 1643319)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 10 of 34
Page 41 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282172
J16010086
Method:
Client:Duke Energy
EPA 218.7
Date:January 12, 2016
Description:Hexavalent Chromium by IC
General Information:
13 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
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Page 11 of 34
Page 42 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000429 Lab ID:92282172001 Collected:01/06/16 09:38 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 12:55 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)71.0 mg/L 01/10/16 12:555.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 12:555.0 1
Alkalinity, Total as CaCO3 71.0 mg/L 01/10/16 12:555.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-8 M10.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.17 ug/L 01/08/16 16:36 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 34
Page 43 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000430 Lab ID:92282172002 Collected:01/06/16 12:25 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 802 ug/L 01/08/16 13:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)95.5 mg/L 01/10/16 13:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 13:345.0 1
Alkalinity, Total as CaCO3 95.5 mg/L 01/10/16 13:345.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 17:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 34
Page 44 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000431 Lab ID:92282172003 Collected:01/06/16 10:32 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 14.4 ug/L 01/08/16 13:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)156 mg/L 01/10/16 13:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 13:465.0 1
Alkalinity, Total as CaCO3 156 mg/L 01/10/16 13:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 17:28 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 34
Page 45 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000432 Lab ID:92282172004 Collected:01/06/16 09:38 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 13:19 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)69.5 mg/L 01/10/16 14:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 14:005.0 1
Alkalinity, Total as CaCO3 69.5 mg/L 01/10/16 14:005.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.17 ug/L 01/08/16 17:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 34
Page 46 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000433 Lab ID:92282172005 Collected:01/06/16 12:10 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 13:53 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)181 mg/L 01/10/16 14:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 14:125.0 1
Alkalinity, Total as CaCO3 181 mg/L 01/10/16 14:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 17:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 34
Page 47 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000434 Lab ID:92282172006 Collected:01/06/16 13:38 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 59.7 ug/L 01/08/16 14:10 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)218 mg/L 01/10/16 14:265.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 14:265.0 1
Alkalinity, Total as CaCO3 218 mg/L 01/10/16 14:265.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 18:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 34
Page 48 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000435 Lab ID:92282172007 Collected:01/06/16 11:45 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 14:18 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)93.2 mg/L 01/10/16 15:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 15:005.0 1
Alkalinity, Total as CaCO3 93.2 mg/L 01/10/16 15:005.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.16 ug/L 01/08/16 18:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 34
Page 49 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000436 Lab ID:92282172008 Collected:01/05/16 11:10 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 7850 ug/L 01/08/16 14:26 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)181 mg/L 01/10/16 15:135.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 15:135.0 1
Alkalinity, Total as CaCO3 181 mg/L 01/10/16 15:135.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 18:33 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 34
Page 50 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000437 Lab ID:92282172009 Collected:01/05/16 10:35 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 108 ug/L 01/08/16 14:34 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)40.4 mg/L 01/10/16 15:285.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 15:285.0 1
Alkalinity, Total as CaCO3 40.4 mg/L 01/10/16 15:285.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 18:46 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 34
Page 51 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000439 Lab ID:92282172010 Collected:01/06/16 16:45 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 14:43 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/10/16 15:405.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 15:405.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/10/16 15:405.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 18:59 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 34
Page 52 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000440 Lab ID:92282172011 Collected:01/06/16 16:40 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 90.8 ug/L 01/08/16 14:51 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/10/16 17:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 17:005.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/10/16 17:00 M15.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/08/16 19:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 34
Page 53 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000441 Lab ID:92282172012 Collected:01/06/16 15:35 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 14:59 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/10/16 17:395.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 17:395.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/10/16 17:395.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.087 ug/L 01/08/16 20:17 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 34
Page 54 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282172
J16010086
Sample:2016000442 Lab ID:92282172013 Collected:01/06/16 15:00 Received:01/07/16 14:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/08/16 15:07 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)25.4 mg/L 01/10/16 17:485.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/10/16 17:485.0 1
Alkalinity, Total as CaCO3 25.4 mg/L 01/10/16 17:485.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/08/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.089 ug/L 01/08/16 20:30 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 34
Page 55 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282172
J16010086
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24990
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2172145
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/08/16 09:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2172146LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2172147
Methane ug/L 57.760.7 95 85-1159959.9 4 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92281984013
2172518SAMPLE DUPLICATE:
Methane ug/L 1.2J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92282172005
2172519SAMPLE DUPLICATE:
Methane ug/L 1.6J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 34
Page 56 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282172
J16010086
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42371
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1643729
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/10/16 12:34
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/10/16 12:34
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/10/16 12:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1643730LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 47.350 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1643731MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282172001
1643732
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 93 80-12089 2 255071.0 118 116
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1643733MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282172011
1643734
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15062880-120633 1 2550ND314316
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 34
Page 57 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282172
J16010086
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42367
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1643316
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/08/16 15:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1643317LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.49.5 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1643318MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282172001
1643319
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 44 90-11044 0 10.5ND 0.22 0.22
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1643320MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282172011
1643321
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 96 90-11096 0 10.5ND 0.48 0.48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 34
Page 58 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282172
J16010086
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/53609
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92282172001, 92282172002, 92282172003, 92282172004, 92282172005, 92282172006, 92282172007,
92282172008, 92282172009, 92282172010, 92282172011, 92282172012, 92282172013
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1441880
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/08/16 16:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1441881LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.077.075 103 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1441882MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282172001
1441883
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 117 85-11580 5 20.0250.17 0.20 0.19
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1441884MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282172011
1441885
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 101 85-11599 3 20.075ND 0.076 0.074
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 34
Page 59 of 67
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92282172
J16010086
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 34
Page 60 of 67
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92282172
J16010086
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92282172001 AIR/249902016000429RSK 175
92282172002 AIR/249902016000430RSK 175
92282172003 AIR/249902016000431RSK 175
92282172004 AIR/249902016000432RSK 175
92282172005 AIR/249902016000433RSK 175
92282172006 AIR/249902016000434RSK 175
92282172007 AIR/249902016000435RSK 175
92282172008 AIR/249902016000436RSK 175
92282172009 AIR/249902016000437RSK 175
92282172010 AIR/249902016000439RSK 175
92282172011 AIR/249902016000440RSK 175
92282172012 AIR/249902016000441RSK 175
92282172013 AIR/249902016000442RSK 175
92282172001 WET/423712016000429SM 2320B
92282172002 WET/423712016000430SM 2320B
92282172003 WET/423712016000431SM 2320B
92282172004 WET/423712016000432SM 2320B
92282172005 WET/423712016000433SM 2320B
92282172006 WET/423712016000434SM 2320B
92282172007 WET/423712016000435SM 2320B
92282172008 WET/423712016000436SM 2320B
92282172009 WET/423712016000437SM 2320B
92282172010 WET/423712016000439SM 2320B
92282172011 WET/423712016000440SM 2320B
92282172012 WET/423712016000441SM 2320B
92282172013 WET/423712016000442SM 2320B
92282172001 WET/423672016000429SM 4500-S2D
92282172002 WET/423672016000430SM 4500-S2D
92282172003 WET/423672016000431SM 4500-S2D
92282172004 WET/423672016000432SM 4500-S2D
92282172005 WET/423672016000433SM 4500-S2D
92282172006 WET/423672016000434SM 4500-S2D
92282172007 WET/423672016000435SM 4500-S2D
92282172008 WET/423672016000436SM 4500-S2D
92282172009 WET/423672016000437SM 4500-S2D
92282172010 WET/423672016000439SM 4500-S2D
92282172011 WET/423672016000440SM 4500-S2D
92282172012 WET/423672016000441SM 4500-S2D
92282172013 WET/423672016000442SM 4500-S2D
92282172001 WETA/536092016000429EPA 218.7
92282172002 WETA/536092016000430EPA 218.7
92282172003 WETA/536092016000431EPA 218.7
92282172004 WETA/536092016000432EPA 218.7
92282172005 WETA/536092016000433EPA 218.7
92282172006 WETA/536092016000434EPA 218.7
92282172007 WETA/536092016000435EPA 218.7
92282172008 WETA/536092016000436EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 34
Page 61 of 67
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92282172
J16010086
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92282172009 WETA/536092016000437EPA 218.7
92282172010 WETA/536092016000439EPA 218.7
92282172011 WETA/536092016000440EPA 218.7
92282172012 WETA/536092016000441EPA 218.7
92282172013 WETA/536092016000442EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/12/2016 10:37 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 34
Page 62 of 67
Page 32 of 34
Page 63 of 67
Page 33 of 34
Page 64 of 67
Page 34 of 34
Page 65 of 67
Page 66 of 67
Page 67 of 67
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010101
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:1/15/2016
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 68
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016000520 MAYO STEAM 07-Jan-16 3:12 PM Unknown ABMW-1
2016000523 MAYO STEAM 07-Jan-16 12:50 PM Unknown MW-3BR
2016000524 MAYO STEAM 07-Jan-16 8:52 AM Unknown MW-5BR
2016000525 MAYO STEAM 07-Jan-16 1:25 PM Unknown MW-10BR
2016000526 MAYO STEAM 07-Jan-16 3:20 PM Unknown MW-11BR
2016000527 MAYO STEAM 07-Jan-16 12:35 PM Unknown MW-12S
2016000528 MAYO STEAM 07-Jan-16 3:51 PM Unknown MW-12D
2016000529 MAYO STEAM 07-Jan-16 11:35 AM Unknown MW-13BR
2016000530 MAYO STEAM 07-Jan-16 10:35 AM Unknown MW-14BR
2016000531 MAYO STEAM 07-Jan-16 9:55 AM Unknown MW-16D
2016000532 MAYO STEAM 07-Jan-16 9:20 AM Unknown MW-16S
2016000533 MAYO STEAM 07-Jan-16 9:09 AM Unknown MW-16BR
2016000534 MAYO STEAM 07-Jan-16 9:55 AM Unknown MW-16D Dup
2016000535 MAYO STEAM Filter Blank
2016000536 MAYO STEAM Equipment Blank
15 Total Samples
Page 2 of 68
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:1/15/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000520
Collection Date:07-Jan-16 3:12 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/10/2016 11:07 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 01/08/2016 22:45 BGN9034110
Sulfate 24 mg/L EPA 300.0 01/08/2016 22:45 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:40 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:51 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.275 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.005 1
Barium (Ba)0.462 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.005 1
Boron (B)6.18 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.05 1
Iron (Fe)0.157 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.01 1
Manganese (Mn)0.750 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.005 1
Strontium (Sr)1.72 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 01/08/2016 13:53 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)54.4 mg/L EPA 200.7 01/11/2016 13:15 FCJORDA0.1 10
Magnesium (Mg)32.3 mg/L EPA 200.7 01/11/2016 13:15 FCJORDA0.05 10
Potassium (K)22.8 mg/L EPA 200.7 01/11/2016 13:15 FCJORDA110
Sodium (Na)17.8 mg/L EPA 200.7 01/11/2016 13:15 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.372 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.005 1
Barium (Ba)0.502 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.005 1
Boron (B)5.84 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.05 1
Iron (Fe)0.724 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.01 1
Manganese (Mn)0.815 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.005 1
Strontium (Sr)1.79 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:13 FCJORDA0.005 1
Page 4 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000520
Collection Date:07-Jan-16 3:12 PM
Site:ABMW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)19.5 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Arsenic (As)408 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Cobalt (Co)1.57 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Molybdenum (Mo)290 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Nickel (Ni)1.22 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:09 SLS256011
Thallium (Tl) Low Level 0.387 ug/L EPA 200.8 01/10/2016 16:09 SLS25600.2 1
Vanadium (V) Low Level 79.1 ug/L EPA 200.8 01/10/2016 16:09 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)18.8 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Arsenic (As)498 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Cobalt (Co)2.06 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Molybdenum (Mo)286 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Nickel (Ni)1.36 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 20:19 SLS256011
Thallium (Tl) Low Level 0.670 ug/L EPA 200.8 01/10/2016 20:19 SLS25600.2 1
Vanadium (V) Low Level 98.7 ug/L EPA 200.8 01/10/2016 20:19 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 340 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 4.0 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 5 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000523
Collection Date:07-Jan-16 12:50 PM
Site:MW-3BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.012 mg-N/L EPA 353.2 01/10/2016 11:10 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 160 mg/L EPA 300.0 01/09/2016 02:38 BGN9034220
Sulfate 9.9 mg/L EPA 300.0 01/09/2016 02:38 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:42 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:54 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.005 1
Barium (Ba)0.043 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.05 1
Iron (Fe)0.377 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.01 1
Manganese (Mn)0.628 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.005 1
Strontium (Sr)0.404 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 13:57 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)141 mg/L EPA 200.7 01/11/2016 13:19 FCJORDA0.1 10
Magnesium (Mg)11.7 mg/L EPA 200.7 01/11/2016 13:19 FCJORDA0.05 10
Potassium (K)7.58 mg/L EPA 200.7 01/11/2016 13:19 FCJORDA110
Sodium (Na)21.9 mg/L EPA 200.7 01/11/2016 13:19 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.168 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.005 1
Barium (Ba)0.042 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.05 1
Iron (Fe)0.401 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.01 1
Manganese (Mn)0.635 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.005 1
Strontium (Sr)0.394 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:24 FCJORDA0.005 1
Page 6 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000523
Collection Date:07-Jan-16 12:50 PM
Site:MW-3BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:29 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:29 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 16:29 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Molybdenum (Mo)1.14 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 19:59 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 19:59 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 19:59 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 550 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 1.7 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 7 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000524
Collection Date:07-Jan-16 8:52 AM
Site:MW-5BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.154 mg-N/L EPA 353.2 01/10/2016 11:12 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 66 mg/L EPA 300.0 01/09/2016 02:56 BGN9034110
Sulfate 0.57 mg/L EPA 300.0 01/09/2016 02:56 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:45 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 12:56 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.05 1
Iron (Fe)8.39 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.01 1
Manganese (Mn)1.76 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.005 1
Strontium (Sr)0.208 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:01 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)89.8 mg/L EPA 200.7 01/11/2016 12:22 FCJORDA0.01 1
Magnesium (Mg)6.84 mg/L EPA 200.7 01/11/2016 12:22 FCJORDA0.005 1
Potassium (K)6.00 mg/L EPA 200.7 01/11/2016 12:22 FCJORDA0.1 1
Sodium (Na)17.9 mg/L EPA 200.7 01/11/2016 12:22 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.130 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.05 1
Iron (Fe)9.69 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.01 1
Manganese (Mn)1.88 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.005 1
Strontium (Sr)0.205 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:28 FCJORDA0.005 1
Page 8 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000524
Collection Date:07-Jan-16 8:52 AM
Site:MW-5BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Molybdenum (Mo)1.88 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:34 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:34 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 16:34 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Molybdenum (Mo)1.61 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 20:24 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 20:24 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 20:24 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 2.4 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 26 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 9 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000525
Collection Date:07-Jan-16 1:25 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.017 mg-N/L EPA 353.2 01/10/2016 11:13 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 21 mg/L EPA 300.0 01/09/2016 00:15 BGN9034110
Sulfate 90 mg/L EPA 300.0 01/09/2016 00:15 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 15:56M2 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:08M2 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.01 1
Manganese (Mn)0.090 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.005 1
Strontium (Sr)0.201 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 01/08/2016 14:05 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)28.8 mg/L EPA 200.7 01/11/2016 12:26 FCJORDA0.01 1
Magnesium (Mg)13.1 mg/L EPA 200.7 01/11/2016 12:26 FCJORDA0.005 1
Potassium (K)4.15 mg/L EPA 200.7 01/11/2016 12:26 FCJORDA0.1 1
Sodium (Na)39.5 mg/L EPA 200.7 01/11/2016 12:26 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.062 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.05 1
Iron (Fe)0.033 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.01 1
Manganese (Mn)0.103 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.005 1
Strontium (Sr)0.195 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:32 FCJORDA0.005 1
Page 10 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000525
Collection Date:07-Jan-16 1:25 PM
Site:MW-10BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Nickel (Ni)1.88 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:39 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:39 SLS25600.2 1
Vanadium (V) Low Level 1.57 ug/L EPA 200.8 01/10/2016 16:39 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Nickel (Ni)1.76 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 20:43 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 20:43 SLS25600.2 1
Vanadium (V) Low Level 1.68 ug/L EPA 200.8 01/10/2016 20:43 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 11 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000526
Collection Date:07-Jan-16 3:20 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.272 mg-N/L EPA 353.2 01/10/2016 11:15 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 16 mg/L EPA 300.0 01/09/2016 00:33 BGN90340.5 5
Sulfate 16 mg/L EPA 300.0 01/09/2016 00:33 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:03 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:15 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.078 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.005 1
Strontium (Sr)0.259 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:09 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)18.7 mg/L EPA 200.7 01/11/2016 12:30 FCJORDA0.01 1
Magnesium (Mg)3.51 mg/L EPA 200.7 01/11/2016 12:30 FCJORDA0.005 1
Potassium (K)7.93 mg/L EPA 200.7 01/11/2016 12:30 FCJORDA0.1 1
Sodium (Na)16.6 mg/L EPA 200.7 01/11/2016 12:30 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.170 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.005 1
Barium (Ba)0.024 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.05 1
Iron (Fe)0.098 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.01 1
Manganese (Mn)0.017 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.005 1
Strontium (Sr)0.253 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:36 FCJORDA0.005 1
Page 12 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000526
Collection Date:07-Jan-16 3:20 PM
Site:MW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.58 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Chromium (Cr)14.7 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Copper (Cu)8.14 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Molybdenum (Mo)7.65 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:44 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:44 SLS25600.2 1
Vanadium (V) Low Level 12.0 ug/L EPA 200.8 01/10/2016 16:44 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.90 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Arsenic (As)1.02 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Chromium (Cr)15.1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Copper (Cu)3.96 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Molybdenum (Mo)7.72 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 20:48 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 20:48 SLS25600.2 1
Vanadium (V) Low Level 12.7 ug/L EPA 200.8 01/10/2016 20:48 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 0.835 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 13 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000527
Collection Date:07-Jan-16 12:35 PM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.599 mg-N/L EPA 353.2 01/10/2016 11:16 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.1 mg/L EPA 300.0 01/09/2016 00:51 BGN90340.1 1
Sulfate 1.4 mg/L EPA 300.0 01/09/2016 00:51 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:06 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:24 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.005 1
Barium (Ba)0.010 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.05 1
Iron (Fe)0.028 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.01 1
Manganese (Mn)0.080 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.005 1
Strontium (Sr)0.018 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.005 1
Zinc (Zn)0.144 mg/L EPA 200.7 01/08/2016 14:12 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.96 mg/L EPA 200.7 01/11/2016 12:34 FCJORDA0.01 1
Magnesium (Mg)0.753 mg/L EPA 200.7 01/11/2016 12:34 FCJORDA0.005 1
Potassium (K)1.58 mg/L EPA 200.7 01/11/2016 12:34 FCJORDA0.1 1
Sodium (Na)4.76 mg/L EPA 200.7 01/11/2016 12:34 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.220 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.005 1
Barium (Ba)0.011 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.05 1
Iron (Fe)0.178 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.01 1
Manganese (Mn)0.068 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.005 1
Strontium (Sr)0.018 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.005 1
Zinc (Zn)0.157 mg/L EPA 200.7 01/10/2016 17:40 FCJORDA0.005 1
Page 14 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000527
Collection Date:07-Jan-16 12:35 PM
Site:MW-12S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Nickel (Ni)1.36 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:49 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:49 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 16:49 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Chromium (Cr)1.43 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Nickel (Ni)1.60 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 20:53 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 20:53 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 20:53 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 35 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 15 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000528
Collection Date:07-Jan-16 3:51 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.139 mg-N/L EPA 353.2 01/10/2016 11:18 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.5 mg/L EPA 300.0 01/09/2016 01:09 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 01/09/2016 01:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:13 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:26 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.01 1
Manganese (Mn)0.112 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.005 1
Strontium (Sr)0.090 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:16 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)11.7 mg/L EPA 200.7 01/11/2016 12:37 FCJORDA0.01 1
Magnesium (Mg)3.28 mg/L EPA 200.7 01/11/2016 12:37 FCJORDA0.005 1
Potassium (K)1.39 mg/L EPA 200.7 01/11/2016 12:37 FCJORDA0.1 1
Sodium (Na)8.76 mg/L EPA 200.7 01/11/2016 12:37 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.678 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.05 1
Iron (Fe)0.968 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.01 1
Manganese (Mn)0.131 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.005 1
Strontium (Sr)0.087 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/10/2016 17:44 FCJORDA0.005 1
Page 16 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000528
Collection Date:07-Jan-16 3:51 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Nickel (Ni)1.18 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:53 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:53 SLS25600.2 1
Vanadium (V) Low Level 0.386 ug/L EPA 200.8 01/10/2016 16:53 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Chromium (Cr)2.99 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Copper (Cu)1.54 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Nickel (Ni)2.23 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 20:58 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 20:58 SLS25600.2 1
Vanadium (V) Low Level 1.65 ug/L EPA 200.8 01/10/2016 20:58 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 82 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 0.184 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 47 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 17 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000529
Collection Date:07-Jan-16 11:35 AM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/10/2016 11:19 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 45 mg/L EPA 300.0 01/09/2016 01:26 BGN9034110
Sulfate 15 mg/L EPA 300.0 01/09/2016 01:26 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:18 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:29 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.005 1
Barium (Ba)0.044 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.05 1
Iron (Fe)2.47 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.01 1
Manganese (Mn)0.539 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.005 1
Strontium (Sr)0.402 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 01/08/2016 14:28 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)73.3 mg/L EPA 200.7 01/11/2016 12:41 FCJORDA0.01 1
Magnesium (Mg)12.9 mg/L EPA 200.7 01/11/2016 12:41 FCJORDA0.005 1
Potassium (K)5.12 mg/L EPA 200.7 01/11/2016 12:41 FCJORDA0.1 1
Sodium (Na)23.7 mg/L EPA 200.7 01/11/2016 12:41 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.230 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.005 1
Barium (Ba)0.042 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.05 1
Iron (Fe)2.55 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.01 1
Manganese (Mn)0.519 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.005 1
Strontium (Sr)0.389 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.005 1
Zinc (Zn)0.037 mg/L EPA 200.7 01/10/2016 17:47 FCJORDA0.005 1
Page 18 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000529
Collection Date:07-Jan-16 11:35 AM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Molybdenum (Mo)5.55 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Nickel (Ni)1.30 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 16:58 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 16:58 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 16:58 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Chromium (Cr)7.65 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Molybdenum (Mo)5.81 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Nickel (Ni)4.98 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 21:03 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 21:03 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 21:03 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 0.647 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 9.0 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 19 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000530
Collection Date:07-Jan-16 10:35 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.384 mg-N/L EPA 353.2 01/10/2016 11:20 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 01/09/2016 01:44 BGN90340.2 2
Sulfate 10 mg/L EPA 300.0 01/09/2016 01:44 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:20 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:31 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.005 1
Barium (Ba)0.017 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.01 1
Manganese (Mn)0.212 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.005 1
Strontium (Sr)0.134 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:32 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)13.0 mg/L EPA 200.7 01/11/2016 12:45 FCJORDA0.01 1
Magnesium (Mg)2.36 mg/L EPA 200.7 01/11/2016 12:45 FCJORDA0.005 1
Potassium (K)4.49 mg/L EPA 200.7 01/11/2016 12:45 FCJORDA0.1 1
Sodium (Na)37.4 mg/L EPA 200.7 01/11/2016 12:45 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.163 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.005 1
Barium (Ba)0.017 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.05 1
Iron (Fe)0.098 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.01 1
Manganese (Mn)0.199 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.005 1
Strontium (Sr)0.131 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:51 FCJORDA0.005 1
Page 20 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000530
Collection Date:07-Jan-16 10:35 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Molybdenum (Mo)3.97 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 15:50 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 15:50 SLS25600.2 1
Vanadium (V) Low Level 2.34 ug/L EPA 200.8 01/10/2016 15:50 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Copper (Cu)1.21 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Molybdenum (Mo)4.56 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 21:08 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 21:08 SLS25600.2 1
Vanadium (V) Low Level 2.45 ug/L EPA 200.8 01/10/2016 21:08 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 0.855 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 21 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000531
Collection Date:07-Jan-16 9:55 AM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)3.1 mg-N/L EPA 353.2 01/10/2016 12:51 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.8 mg/L EPA 300.0 01/09/2016 02:02 BGN90340.1 1
Sulfate 7.3 mg/L EPA 300.0 01/09/2016 02:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:22 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:34 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Barium (Ba)0.006 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.01 1
Manganese (Mn)0.017 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Strontium (Sr)0.166 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:36 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.3 mg/L EPA 200.7 01/11/2016 12:56 FCJORDA0.01 1
Magnesium (Mg)5.06 mg/L EPA 200.7 01/11/2016 12:56 FCJORDA0.005 1
Potassium (K)1.94 mg/L EPA 200.7 01/11/2016 12:56 FCJORDA0.1 1
Sodium (Na)9.62 mg/L EPA 200.7 01/11/2016 12:56 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.192 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.05 1
Iron (Fe)0.203 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.01 1
Manganese (Mn)0.028 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.005 1
Strontium (Sr)0.161 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 17:55 FCJORDA0.005 1
Page 22 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000531
Collection Date:07-Jan-16 9:55 AM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Molybdenum (Mo)5.76 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 17:03 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 17:03 SLS25600.2 1
Vanadium (V) Low Level 0.462 ug/L EPA 200.8 01/10/2016 17:03 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Molybdenum (Mo)5.86 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 21:12 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 21:12 SLS25600.2 1
Vanadium (V) Low Level 0.678 ug/L EPA 200.8 01/10/2016 21:12 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 23 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000532
Collection Date:07-Jan-16 9:20 AM
Site:MW-16S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 01/10/2016 11:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 01/09/2016 15:06 BGN90340.5 5
Sulfate 4.8 mg/L EPA 300.0 01/09/2016 15:06 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:25 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:36 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.005 1
Barium (Ba)0.044 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.05 1
Iron (Fe)0.285 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.01 1
Manganese (Mn)0.284 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.005 1
Strontium (Sr)0.118 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.005 1
Zinc (Zn)0.025 mg/L EPA 200.7 01/08/2016 14:40 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.53 mg/L EPA 200.7 01/11/2016 13:00 FCJORDA0.01 1
Magnesium (Mg)3.60 mg/L EPA 200.7 01/11/2016 13:00 FCJORDA0.005 1
Potassium (K)1.64 mg/L EPA 200.7 01/11/2016 13:00 FCJORDA0.1 1
Sodium (Na)15.6 mg/L EPA 200.7 01/11/2016 13:00 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.105 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.005 1
Barium (Ba)0.045 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.05 1
Iron (Fe)0.520 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.01 1
Manganese (Mn)0.252 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.005 1
Strontium (Sr)0.113 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 01/10/2016 18:07 FCJORDA0.005 1
Page 24 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000532
Collection Date:07-Jan-16 9:20 AM
Site:MW-16S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Cobalt (Co)2.08 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Molybdenum (Mo)2.11 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Nickel (Ni)2.95 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 17:08 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 17:08 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 17:08 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Chromium (Cr)4.57 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Cobalt (Co)2.11 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Molybdenum (Mo)2.48 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Nickel (Ni)3.83 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 21:52 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 21:52 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 21:52 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 86 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 0.316 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 25 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000533
Collection Date:07-Jan-16 9:09 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/10/2016 11:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 300.0 01/09/2016 12:42 BGN90340.1 1
Sulfate 6.2 mg/L EPA 300.0 01/09/2016 12:42 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:27 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:48 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.01 1
Manganese (Mn)0.029 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.005 1
Strontium (Sr)0.074 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.005 1
Zinc (Zn)0.025 mg/L EPA 200.7 01/08/2016 14:43 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)18.3 mg/L EPA 200.7 01/11/2016 13:04 FCJORDA0.01 1
Magnesium (Mg)2.09 mg/L EPA 200.7 01/11/2016 13:04 FCJORDA0.005 1
Potassium (K)2.20 mg/L EPA 200.7 01/11/2016 13:04 FCJORDA0.1 1
Sodium (Na)30.3 mg/L EPA 200.7 01/11/2016 13:04 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.136 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.005 1
Barium (Ba)0.009 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.05 1
Iron (Fe)0.126 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.01 1
Manganese (Mn)0.032 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.005 1
Strontium (Sr)0.074 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 18:18 FCJORDA0.005 1
Page 26 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000533
Collection Date:07-Jan-16 9:09 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.27 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Molybdenum (Mo)42.6 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 17:42 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 17:42 SLS25600.2 1
Vanadium (V) Low Level 0.666 ug/L EPA 200.8 01/10/2016 17:42 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)1.34 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Molybdenum (Mo)42.6 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 21:17 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 21:17M2 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 21:17 SLS25600.2 1
Vanadium (V) Low Level 1.06 ug/L EPA 200.8 01/10/2016 21:17 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 9.7 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS 12 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 27 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000534
Collection Date:07-Jan-16 9:55 AM
Site:MW-16D Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)3.2 mg-N/L EPA 353.2 01/10/2016 11:43 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.8 mg/L EPA 300.0 01/09/2016 13:00 BGN90340.1 1
Sulfate 7.3 mg/L EPA 300.0 01/09/2016 13:00 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:29 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:41 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.01 1
Manganese (Mn)0.018 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.005 1
Strontium (Sr)0.173 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 01/08/2016 14:47 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.5 mg/L EPA 200.7 01/11/2016 13:08 FCJORDA0.01 1
Magnesium (Mg)5.10 mg/L EPA 200.7 01/11/2016 13:08 FCJORDA0.005 1
Potassium (K)1.92 mg/L EPA 200.7 01/11/2016 13:08 FCJORDA0.1 1
Sodium (Na)9.56 mg/L EPA 200.7 01/11/2016 13:08 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.196 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.05 1
Iron (Fe)0.200 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.01 1
Manganese (Mn)0.027 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.005 1
Strontium (Sr)0.159 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 18:22 FCJORDA0.005 1
Page 28 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000534
Collection Date:07-Jan-16 9:55 AM
Site:MW-16D Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Molybdenum (Mo)5.77 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 17:47 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 17:47 SLS25600.2 1
Vanadium (V) Low Level 0.473 ug/L EPA 200.8 01/10/2016 17:47 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Molybdenum (Mo)5.95 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 21:57 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 21:57 SLS25600.2 1
Vanadium (V) Low Level 0.598 ug/L EPA 200.8 01/10/2016 21:57 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 01/13/2016 15:59 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 29 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000535
Collection Date:
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/09/2016 13:38 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/08/2016 14:51 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 17:52 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 17:52 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 17:52 SLS25600.3 1
Page 30 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000536
Collection Date:
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.012 mg-N/L EPA 353.2 01/10/2016 11:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/09/2016 11:31 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/09/2016 11:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/08/2016 16:37 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.022 mg/L EPA 200.7 01/11/2016 13:12 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/11/2016 13:12 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/11/2016 13:12 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/11/2016 13:12 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 18:26 FCJORDA0.005 1
Page 31 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010101
2016000536
Collection Date:
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 22:01 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 22:01 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 22:01 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/10/2016 14:09 CJELLIO251
Total Carbon
TOC 0.172 mg/L SM5310C/EPA9060A 01/11/2016 15:18 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 32 of 68
#=CL#
January 14, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92282353
92282353
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010101
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 08, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 35
Page 33 of 68
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92282353
J16010101
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 35
Page 34 of 68
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92282353
J16010101
Lab ID Sample ID Matrix Date Collected Date Received
92282353001 2016000520 Water 01/07/16 15:12 01/08/16 13:00
92282353002 2016000523 Water 01/07/16 12:50 01/08/16 13:00
92282353003 2016000524 Water 01/07/16 08:52 01/08/16 13:00
92282353004 2016000525 Water 01/07/16 13:25 01/08/16 13:00
92282353005 2016000526 Water 01/07/16 15:20 01/08/16 13:00
92282353006 2016000527 Water 01/07/16 12:35 01/08/16 13:00
92282353007 2016000528 Water 01/07/16 15:51 01/08/16 13:00
92282353008 2016000529 Water 01/07/16 11:35 01/08/16 13:00
92282353009 2016000530 Water 01/07/16 10:35 01/08/16 13:00
92282353010 2016000531 Water 01/07/16 09:55 01/08/16 13:00
92282353011 2016000532 Water 01/07/16 09:20 01/08/16 13:00
92282353012 2016000533 Water 01/07/16 09:07 01/08/16 13:00
92282353013 2016000534 Water 01/07/16 09:55 01/08/16 13:00
92282353014 2016000536 Water 01/07/16 00:00 01/08/16 13:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 35
Page 35 of 68
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92282353
J16010101
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92282353001 2016000520 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353002 2016000523 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353003 2016000524 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353004 2016000525 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353005 2016000526 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353006 2016000527 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353007 2016000528 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353008 2016000529 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353009 2016000530 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353010 2016000531 RSK 175 1 PASI-MDR1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 35
Page 36 of 68
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92282353
J16010101
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353011 2016000532 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353012 2016000533 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353013 2016000534 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
92282353014 2016000536 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 35
Page 37 of 68
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92282353
J16010101
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92282353001 2016000520
Methane 3680 ug/L 01/11/16 11:0310.0RSK 175
Alkalinity,Bicarbonate (CaCO3)297 mg/L 01/12/16 12:235.0SM 2320B
Alkalinity, Total as CaCO3 297 mg/L 01/12/16 12:235.0SM 2320B
92282353002 2016000523
Alkalinity,Bicarbonate (CaCO3)223 mg/L 01/12/16 12:375.0SM 2320B
Alkalinity, Total as CaCO3 223 mg/L 01/12/16 12:375.0SM 2320B
92282353003 2016000524
Methane 912 ug/L 01/11/16 11:2810.0RSK 175
Alkalinity,Bicarbonate (CaCO3)212 mg/L 01/12/16 12:505.0SM 2320B
Alkalinity, Total as CaCO3 212 mg/L 01/12/16 12:505.0SM 2320B
92282353004 2016000525
Alkalinity,Bicarbonate (CaCO3)103 mg/L 01/12/16 13:245.0SM 2320B
Alkalinity, Total as CaCO3 103 mg/L 01/12/16 13:245.0SM 2320B
92282353005 2016000526
Alkalinity,Bicarbonate (CaCO3)36.4 mg/L 01/12/16 13:375.0SM 2320B
Alkalinity, Carbonate (CaCO3)28.3 mg/L 01/12/16 13:375.0SM 2320B
Alkalinity, Total as CaCO3 64.8 mg/L 01/12/16 13:375.0SM 2320B
Chromium, Hexavalent 12.2 ug/L 01/12/16 10:023.0EPA 218.7
92282353006 2016000527
Alkalinity,Bicarbonate (CaCO3)11.1 mg/L 01/12/16 13:485.0SM 2320B
Alkalinity, Total as CaCO3 11.1 mg/L 01/12/16 13:485.0SM 2320B
Chromium, Hexavalent 0.038 ug/L 01/12/16 00:280.030EPA 218.7
92282353007 2016000528
Alkalinity,Bicarbonate (CaCO3)53.5 mg/L 01/12/16 13:575.0SM 2320B
Alkalinity, Total as CaCO3 53.5 mg/L 01/12/16 13:575.0SM 2320B
Chromium, Hexavalent 0.52 ug/L 01/12/16 10:15 M10.15EPA 218.7
92282353008 2016000529
Methane 25.9 ug/L 01/11/16 12:1010.0RSK 175
Alkalinity,Bicarbonate (CaCO3)223 mg/L 01/12/16 14:095.0SM 2320B
Alkalinity, Total as CaCO3 223 mg/L 01/12/16 14:09 M15.0SM 2320B
92282353009 2016000530
Alkalinity,Bicarbonate (CaCO3)94.8 mg/L 01/12/16 14:505.0SM 2320B
Alkalinity, Total as CaCO3 94.8 mg/L 01/12/16 14:505.0SM 2320B
92282353010 2016000531
Alkalinity,Bicarbonate (CaCO3)74.3 mg/L 01/12/16 15:035.0SM 2320B
Alkalinity, Total as CaCO3 74.3 mg/L 01/12/16 15:035.0SM 2320B
Chromium, Hexavalent 0.097 ug/L 01/12/16 02:120.030EPA 218.7
92282353011 2016000532
Alkalinity,Bicarbonate (CaCO3)49.0 mg/L 01/12/16 15:135.0SM 2320B
Alkalinity, Total as CaCO3 49.0 mg/L 01/12/16 15:135.0SM 2320B
Chromium, Hexavalent 0.083 ug/L 01/12/16 02:250.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 35
Page 38 of 68
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92282353
J16010101
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92282353012 2016000533
Alkalinity,Bicarbonate (CaCO3)103 mg/L 01/12/16 15:445.0SM 2320B
Alkalinity, Total as CaCO3 103 mg/L 01/12/16 15:445.0SM 2320B
Sulfide 1.2 mg/L 01/10/16 11:300.20SM 4500-S2D
92282353013 2016000534
Alkalinity,Bicarbonate (CaCO3)77.6 mg/L 01/12/16 15:565.0SM 2320B
Alkalinity, Total as CaCO3 77.6 mg/L 01/12/16 15:565.0SM 2320B
Chromium, Hexavalent 0.10 ug/L 01/12/16 02:510.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 35
Page 39 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282353
J16010101
Method:
Client:Duke Energy
RSK 175
Date:January 14, 2016
Description:RSK 175 AIR Headspace
General Information:
14 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: AIR/25000
R1: RPD value was outside control limits.
• DUP (Lab ID: 2173348)
• Methane
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 35
Page 40 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282353
J16010101
Method:
Client:Duke Energy
SM 2320B
Date:January 14, 2016
Description:2320B Alkalinity
General Information:
14 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42413
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92282350004,92282353008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1644935)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 41 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282353
J16010101
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 14, 2016
Description:4500S2D Sulfide Water
General Information:
14 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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Page 42 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282353
J16010101
Method:
Client:Duke Energy
EPA 218.7
Date:January 14, 2016
Description:Hexavalent Chromium by IC
General Information:
14 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
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Page 43 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000520 Lab ID:92282353001 Collected:01/07/16 15:12 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 3680 ug/L 01/11/16 11:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)297 mg/L 01/12/16 12:235.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 12:235.0 1
Alkalinity, Total as CaCO3 297 mg/L 01/12/16 12:235.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/11/16 23:23 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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[phone]
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Page 44 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000523 Lab ID:92282353002 Collected:01/07/16 12:50 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 11:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)223 mg/L 01/12/16 12:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 12:375.0 1
Alkalinity, Total as CaCO3 223 mg/L 01/12/16 12:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/11/16 23:36 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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[phone]
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Page 45 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000524 Lab ID:92282353003 Collected:01/07/16 08:52 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 912 ug/L 01/11/16 11:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)212 mg/L 01/12/16 12:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 12:505.0 1
Alkalinity, Total as CaCO3 212 mg/L 01/12/16 12:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/11/16 23:49 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 14 of 35
Page 46 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000525 Lab ID:92282353004 Collected:01/07/16 13:25 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 11:37 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)103 mg/L 01/12/16 13:245.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 13:245.0 1
Alkalinity, Total as CaCO3 103 mg/L 01/12/16 13:245.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 00:02 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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[phone]
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Page 47 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000526 Lab ID:92282353005 Collected:01/07/16 15:20 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 11:45 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)36.4 mg/L 01/12/16 13:375.0 1
Alkalinity, Carbonate (CaCO3)28.3 mg/L 01/12/16 13:375.0 1
Alkalinity, Total as CaCO3 64.8 mg/L 01/12/16 13:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 12.2 ug/L 01/12/16 10:02 18540-29-93.0 100
REPORT OF LABORATORY ANALYSIS
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Page 48 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000527 Lab ID:92282353006 Collected:01/07/16 12:35 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 11:53 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)11.1 mg/L 01/12/16 13:485.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 13:485.0 1
Alkalinity, Total as CaCO3 11.1 mg/L 01/12/16 13:485.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.038 ug/L 01/12/16 00:28 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 49 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000528 Lab ID:92282353007 Collected:01/07/16 15:51 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 12:01 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)53.5 mg/L 01/12/16 13:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 13:575.0 1
Alkalinity, Total as CaCO3 53.5 mg/L 01/12/16 13:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.52 ug/L 01/12/16 10:15 18540-29-9 M10.15 5
REPORT OF LABORATORY ANALYSIS
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Page 50 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000529 Lab ID:92282353008 Collected:01/07/16 11:35 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 25.9 ug/L 01/11/16 12:10 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)223 mg/L 01/12/16 14:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 14:095.0 1
Alkalinity, Total as CaCO3 223 mg/L 01/12/16 14:09 M15.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 01:46 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 51 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000530 Lab ID:92282353009 Collected:01/07/16 10:35 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 12:18 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)94.8 mg/L 01/12/16 14:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 14:505.0 1
Alkalinity, Total as CaCO3 94.8 mg/L 01/12/16 14:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 01:59 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 52 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000531 Lab ID:92282353010 Collected:01/07/16 09:55 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 12:46 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)74.3 mg/L 01/12/16 15:035.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 15:035.0 1
Alkalinity, Total as CaCO3 74.3 mg/L 01/12/16 15:035.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.097 ug/L 01/12/16 02:12 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 53 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000532 Lab ID:92282353011 Collected:01/07/16 09:20 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 13:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)49.0 mg/L 01/12/16 15:135.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 15:135.0 1
Alkalinity, Total as CaCO3 49.0 mg/L 01/12/16 15:135.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.083 ug/L 01/12/16 02:25 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 54 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000533 Lab ID:92282353012 Collected:01/07/16 09:07 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 13:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)103 mg/L 01/12/16 15:445.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 15:445.0 1
Alkalinity, Total as CaCO3 103 mg/L 01/12/16 15:445.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 1.2 mg/L 01/10/16 11:30 18496-25-80.20 2
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 02:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 55 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000534 Lab ID:92282353013 Collected:01/07/16 09:55 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 13:19 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)77.6 mg/L 01/12/16 15:565.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 15:565.0 1
Alkalinity, Total as CaCO3 77.6 mg/L 01/12/16 15:565.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.10 ug/L 01/12/16 02:51 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 56 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282353
J16010101
Sample:2016000536 Lab ID:92282353014 Collected:01/07/16 00:00 Received:01/08/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/11/16 13:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/12/16 16:065.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/12/16 16:065.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/12/16 16:065.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/10/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 03:04 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282353
J16010101
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25000
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013, 92282353014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2173085
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013, 92282353014
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/11/16 10:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2173086LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2173087
Methane ug/L 54.560.7 90 85-1159054.6 0 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92282353001
2173348SAMPLE DUPLICATE:
Methane ug/L 4600 R122203680
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92282353010
2173349SAMPLE DUPLICATE:
Methane ug/L 1.8J 20ND
REPORT OF LABORATORY ANALYSIS
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282353
J16010101
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42413
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013, 92282353014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1644930
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013, 92282353014
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/12/16 11:00
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/12/16 11:00
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/12/16 11:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1644931LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 47.550 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1644932MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282350004
1644933
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 95 80-12096 0 2550127175175
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1644934MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282353008
1644935
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1508080-12074 1 2550223263260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 35
Page 59 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282353
J16010101
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42390
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013, 92282353014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1644370
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006, 92282353007,
92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013, 92282353014
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/10/16 11:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1644371LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1644372MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282350002
1644373
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 101 90-110101 0 10.5ND 0.51 0.51
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1644374MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282353006
1644375
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 98 90-11098 0 10.5ND 0.49 0.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 35
Page 60 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282353
J16010101
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/53663
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92282353001, 92282353002, 92282353003, 92282353004, 92282353005, 92282353006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1443677
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/11/16 18:37
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1443678LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.076.075 101 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1443679MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282355023
1443680
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 101 85-11590 2 20.0250.087 0.11 0.11
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1443681MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282350003
1443682
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 99 85-11597 3 20.075ND 0.075 0.073
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 35
Page 61 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282353
J16010101
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/53703
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92282353007, 92282353008, 92282353009, 92282353010, 92282353011, 92282353012, 92282353013,
92282353014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1444452
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/12/16 03:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1444453LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1444454MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282353007
1444455
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.38 80 85-11597 7 20.380.52 0.82 0.89
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 35
Page 62 of 68
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92282353
J16010101
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 35
Page 63 of 68
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92282353
J16010101
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92282353001 AIR/250002016000520RSK 175
92282353002 AIR/250002016000523RSK 175
92282353003 AIR/250002016000524RSK 175
92282353004 AIR/250002016000525RSK 175
92282353005 AIR/250002016000526RSK 175
92282353006 AIR/250002016000527RSK 175
92282353007 AIR/250002016000528RSK 175
92282353008 AIR/250002016000529RSK 175
92282353009 AIR/250002016000530RSK 175
92282353010 AIR/250002016000531RSK 175
92282353011 AIR/250002016000532RSK 175
92282353012 AIR/250002016000533RSK 175
92282353013 AIR/250002016000534RSK 175
92282353014 AIR/250002016000536RSK 175
92282353001 WET/424132016000520SM 2320B
92282353002 WET/424132016000523SM 2320B
92282353003 WET/424132016000524SM 2320B
92282353004 WET/424132016000525SM 2320B
92282353005 WET/424132016000526SM 2320B
92282353006 WET/424132016000527SM 2320B
92282353007 WET/424132016000528SM 2320B
92282353008 WET/424132016000529SM 2320B
92282353009 WET/424132016000530SM 2320B
92282353010 WET/424132016000531SM 2320B
92282353011 WET/424132016000532SM 2320B
92282353012 WET/424132016000533SM 2320B
92282353013 WET/424132016000534SM 2320B
92282353014 WET/424132016000536SM 2320B
92282353001 WET/423902016000520SM 4500-S2D
92282353002 WET/423902016000523SM 4500-S2D
92282353003 WET/423902016000524SM 4500-S2D
92282353004 WET/423902016000525SM 4500-S2D
92282353005 WET/423902016000526SM 4500-S2D
92282353006 WET/423902016000527SM 4500-S2D
92282353007 WET/423902016000528SM 4500-S2D
92282353008 WET/423902016000529SM 4500-S2D
92282353009 WET/423902016000530SM 4500-S2D
92282353010 WET/423902016000531SM 4500-S2D
92282353011 WET/423902016000532SM 4500-S2D
92282353012 WET/423902016000533SM 4500-S2D
92282353013 WET/423902016000534SM 4500-S2D
92282353014 WET/423902016000536SM 4500-S2D
92282353001 WETA/536632016000520EPA 218.7
92282353002 WETA/536632016000523EPA 218.7
92282353003 WETA/536632016000524EPA 218.7
92282353004 WETA/536632016000525EPA 218.7
92282353005 WETA/536632016000526EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 35
Page 64 of 68
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92282353
J16010101
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92282353006 WETA/536632016000527EPA 218.7
92282353007 WETA/537032016000528EPA 218.7
92282353008 WETA/537032016000529EPA 218.7
92282353009 WETA/537032016000530EPA 218.7
92282353010 WETA/537032016000531EPA 218.7
92282353011 WETA/537032016000532EPA 218.7
92282353012 WETA/537032016000533EPA 218.7
92282353013 WETA/537032016000534EPA 218.7
92282353014 WETA/537032016000536EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/14/2016 06:01 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 35
Page 65 of 68
Page 34 of 35
Page 66 of 68
Page 35 of 35
Page 67 of 68
Page 68 of 68
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010140
Project Name:MAYO STEAM - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:1/20/2016
Customer Address:
Customer Name(s):Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy Webb, John Toep
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 33
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016000737 MAYO STEAM 08-Jan-16 9:45 AM Richard Jacobs BG-2
2016000738 MAYO STEAM 08-Jan-16 10:15 AM Richard Jacobs BG-1
2016000739 MAYO STEAM 08-Jan-16 Richard Jacobs Filter Blank 04
2016000740 MAYO STEAM 08-Jan-16 Richard Jacobs Equipment Blank 04
4 Total Samples
Page 2 of 33
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Therona T James Date:1/20/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000737
Collection Date:08-Jan-16 9:45 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/10/2016 12:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 33 mg/L EPA 300.0 01/11/2016 14:53 BGN90340.5 5
Sulfate 5.5 mg/L EPA 300.0 01/11/2016 14:53 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2016 13:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/13/2016 12:19 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.005 1
Barium (Ba)0.054 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.05 1
Iron (Fe)0.320 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.01 1
Manganese (Mn)0.172 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.005 1
Strontium (Sr)0.325 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 15:21 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)57.3 mg/L EPA 200.7 01/11/2016 17:46 FCJORDA0.01 1
Magnesium (Mg)12.6 mg/L EPA 200.7 01/11/2016 17:46 FCJORDA0.005 1
Potassium (K)3.40 mg/L EPA 200.7 01/11/2016 17:46 FCJORDA0.1 1
Sodium (Na)50.6 mg/L EPA 200.7 01/11/2016 17:46 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.080 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.005 1
Barium (Ba)0.058 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.05 1
Iron (Fe)0.471 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.01 1
Manganese (Mn)0.196 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.005 1
Strontium (Sr)0.350 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/11/2016 10:35 MHH71310.005 1
Page 4 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000737
Collection Date:08-Jan-16 9:45 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 19:10 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 19:10 SLS25600.2 1
Vanadium (V) Low Level 3.49 ug/L EPA 200.8 01/10/2016 19:10 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Copper (Cu)1.21 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 23:20 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 23:20 SLS25600.2 1
Vanadium (V) Low Level 4.20 ug/L EPA 200.8 01/10/2016 23:20 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 01/09/2016 15:30 CJELLIO251
Total Carbon
TOC 1.3 mg/L SM5310C/EPA9060A 01/12/2016 15:28 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 5 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000737
Collection Date:08-Jan-16 9:45 AM
Site:BG-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Page 6 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000738
Collection Date:08-Jan-16 10:15 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.643 mg-N/L EPA 353.2 01/10/2016 12:14 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 01/11/2016 14:35 BGN90340.5 5
Sulfate 0.24 mg/L EPA 300.0 01/11/2016 14:35 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2016 13:23 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/11/2016 16:41 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.005 1
Barium (Ba)0.083 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.01 1
Manganese (Mn)0.006 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.005 1
Strontium (Sr)0.161 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/10/2016 15:25 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)12.6 mg/L EPA 200.7 01/11/2016 17:50 FCJORDA0.01 1
Magnesium (Mg)3.36 mg/L EPA 200.7 01/11/2016 17:50 FCJORDA0.005 1
Potassium (K)1.39 mg/L EPA 200.7 01/11/2016 17:50 FCJORDA0.1 1
Sodium (Na)11.9 mg/L EPA 200.7 01/11/2016 17:50 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.227 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.005 1
Barium (Ba)0.087 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.05 1
Iron (Fe)0.272 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.01 1
Manganese (Mn)0.011 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.005 1
Strontium (Sr)0.166 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/11/2016 10:39 MHH71310.005 1
Page 7 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000738
Collection Date:08-Jan-16 10:15 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Nickel (Ni)1.28 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 19:15 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 19:15 SLS25600.2 1
Vanadium (V) Low Level 3.08 ug/L EPA 200.8 01/10/2016 19:15 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Nickel (Ni)1.24 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 23:24 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 23:24 SLS25600.2 1
Vanadium (V) Low Level 3.94 ug/L EPA 200.8 01/10/2016 23:24 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 01/09/2016 15:30 CJELLIO251
Total Carbon
TOC 0.558 mg/L SM5310C/EPA9060A 01/12/2016 15:28 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 8 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000738
Collection Date:08-Jan-16 10:15 AM
Site:BG-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Page 9 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000739
Collection Date:08-Jan-16
Site:Filter Blank 04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/11/2016 16:44 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/10/2016 15:28 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 19:20 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 19:20 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 19:20 SLS25600.3 1
Page 10 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000740
Collection Date:08-Jan-16
Site:Equipment Blank 04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/10/2016 11:57 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/12/2016 08:34 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/12/2016 08:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/12/2016 13:21 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.019 mg/L EPA 200.7 01/11/2016 17:53 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/11/2016 17:53 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/11/2016 17:53 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/11/2016 17:53 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/11/2016 10:43 MHH71310.005 1
Page 11 of 33
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010140
2016000740
Collection Date:08-Jan-16
Site:Equipment Blank 04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 01/10/2016 23:29 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/10/2016 23:29 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/10/2016 23:29 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/09/2016 15:30 CJELLIO251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 01/12/2016 15:28 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/10/2016 08:30 CJELLIO51
Page 12 of 33
#=CL#
January 19, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92282443
92282443
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010140
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 11, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
Page 13 of 33
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92282443
J16010140
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
Page 14 of 33
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92282443
J16010140
Lab ID Sample ID Matrix Date Collected Date Received
92282443001 2016000737 Water 01/08/16 09:45 01/11/16 12:10
92282443002 2016000738 Water 01/08/16 10:15 01/11/16 12:10
92282443003 2016000740 Water 01/08/16 00:00 01/11/16 12:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
Page 15 of 33
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92282443
J16010140
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92282443001 2016000737 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282443002 2016000738 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92282443003 2016000740 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
Page 16 of 33
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92282443
J16010140
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92282443001 2016000737
Methane 477 ug/L 01/13/16 10:4810.0RSK 175
Alkalinity,Bicarbonate (CaCO3)263 mg/L 01/13/16 01:155.0SM 2320B
Alkalinity, Total as CaCO3 263 mg/L 01/13/16 01:155.0SM 2320B
92282443002 2016000738
Alkalinity,Bicarbonate (CaCO3)51.1 mg/L 01/13/16 01:305.0SM 2320B
Alkalinity, Total as CaCO3 51.1 mg/L 01/13/16 01:305.0SM 2320B
Chromium, Hexavalent 0.20 ug/L 01/12/16 14:540.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 20
Page 17 of 33
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282443
J16010140
Method:
Client:Duke Energy
RSK 175
Date:January 19, 2016
Description:RSK 175 AIR Headspace
General Information:
3 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 20
Page 18 of 33
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282443
J16010140
Method:
Client:Duke Energy
SM 2320B
Date:January 19, 2016
Description:2320B Alkalinity
General Information:
3 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 20
Page 19 of 33
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282443
J16010140
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 19, 2016
Description:4500S2D Sulfide Water
General Information:
3 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 20
Page 20 of 33
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92282443
J16010140
Method:
Client:Duke Energy
EPA 218.7
Date:January 19, 2016
Description:Hexavalent Chromium by IC
General Information:
3 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 20
Page 21 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282443
J16010140
Sample:2016000737 Lab ID:92282443001 Collected:01/08/16 09:45 Received:01/11/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 477 ug/L 01/13/16 10:48 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)263 mg/L 01/13/16 01:155.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/13/16 01:155.0 1
Alkalinity, Total as CaCO3 263 mg/L 01/13/16 01:155.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/12/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 14:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 20
Page 22 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282443
J16010140
Sample:2016000738 Lab ID:92282443002 Collected:01/08/16 10:15 Received:01/11/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/13/16 11:05 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)51.1 mg/L 01/13/16 01:305.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/13/16 01:305.0 1
Alkalinity, Total as CaCO3 51.1 mg/L 01/13/16 01:305.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/12/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.20 ug/L 01/12/16 14:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
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Huntersville, NC 28078
[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92282443
J16010140
Sample:2016000740 Lab ID:92282443003 Collected:01/08/16 00:00 Received:01/11/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/13/16 11:13 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/13/16 01:415.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/13/16 01:415.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/13/16 01:415.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/12/16 15:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/12/16 15:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282443
J16010140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25013
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92282443001, 92282443002, 92282443003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2174179
Associated Lab Samples:92282443001, 92282443002, 92282443003
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/13/16 10:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2174180LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2174181
Methane ug/L 56.760.7 94 85-1158652.3 8 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92282551007
2174638SAMPLE DUPLICATE:
Methane ug/L 18.0 1 2017.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92282443001
2174639SAMPLE DUPLICATE:
Methane ug/L 584 20 20477
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 20
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282443
J16010140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42417
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92282443001, 92282443002, 92282443003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1644957
Associated Lab Samples:92282443001, 92282443002, 92282443003
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/12/16 23:41
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/12/16 23:41
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/12/16 23:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1644958LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.050 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1644959MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282355024
1644960
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-12099 1 255049.4 99.5 99.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282443
J16010140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42419
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92282443001, 92282443002, 92282443003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1645025
Associated Lab Samples:92282443001, 92282443002, 92282443003
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/12/16 15:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1645026LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1645027MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282443001
1645028
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 101 90-110101 0 10.5ND 0.51 0.51
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
Page 27 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92282443
J16010140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/53722
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92282443001, 92282443002, 92282443003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1445061
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/12/16 13:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1445062LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.072.075 96 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1445063MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92282443001
1445064
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 94 85-11588 7 20.075ND 0.070 0.066
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 16 of 20
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92282443
J16010140
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 17 of 20
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92282443
J16010140
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92282443001 AIR/250132016000737RSK 175
92282443002 AIR/250132016000738RSK 175
92282443003 AIR/250132016000740RSK 175
92282443001 WET/424172016000737SM 2320B
92282443002 WET/424172016000738SM 2320B
92282443003 WET/424172016000740SM 2320B
92282443001 WET/424192016000737SM 4500-S2D
92282443002 WET/424192016000738SM 4500-S2D
92282443003 WET/424192016000740SM 4500-S2D
92282443001 WETA/537222016000737EPA 218.7
92282443002 WETA/537222016000738EPA 218.7
92282443003 WETA/537222016000740EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/19/2016 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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