The URL can be used to link to this page

Home My WebLink AboutNC0038377_J15060206 Report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060206 Project Name:MAYO STEAM - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:7/6/2015 Customer Address: Customer Name(s):Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 64 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015017618 MAYO STEAM 02-Jun-15 9:35 AM Erin Black ABMW-1-EB 2015017619 MAYO STEAM 02-Jun-15 10:01 AM Erin Black ABMW-1(1.0-1.5) 2015017620 MAYO STEAM 02-Jun-15 11:30 AM Erin Black ABMW-1(11.5-12.0) 2015017621 MAYO STEAM 02-Jun-15 11:20 AM Erin Black AVMW-1(13.0-13.5) 4 Total Samples 2 of 64 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Margaret Galvin-Karr Date:7/6/2015 Electronic Data Deliverable (EDD) Sent Separately 3 of 64 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 2015017618 Collection Date: 02-Jun-15 9:35 AM Site:ABMW-1-EB Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 64 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 2015017619 Collection Date: 02-Jun-15 10:01 AM Site:ABMW-1(1.0-1.5) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 64 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 2015017620 Collection Date: 02-Jun-15 11:30 AM Site:ABMW-1(11.5-12.0) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 64 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 2015017621 Collection Date: 02-Jun-15 11:20 AM Site:AVMW-1(13.0-13.5) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 of 64 #=CL# July 06, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92253195 92253195 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15060206 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 05, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 56 8 of 64 #=CP# CERTIFICATIONS Pace Project No.: Project: 92253195 J15060206 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 56 9 of 64 #=CP# CERTIFICATIONS Pace Project No.: Project: 92253195 J15060206 Charlotte Certification IDs Kentucky UST Certification #: 84 West Virginia Certification #: 357 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 56 10 of 64 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92253195 J15060206 Lab ID Sample ID Matrix Date Collected Date Received 92253195001 2015017618 Water 06/02/15 09:35 06/05/15 14:45 92253195002 2015017619 Solid 06/02/15 10:01 06/05/15 14:45 92253195003 2015017620 Solid 06/02/15 11:30 06/05/15 14:45 92253195004 2015017621 Solid 06/02/15 11:20 06/05/15 14:45 92253195005 2015017619 SPLP Water 06/02/15 10:01 06/05/15 14:45 92253195006 2015017620 SPLP Water 06/02/15 11:30 06/05/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 56 11 of 64 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92253195 J15060206 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92253195001 2015017618 EPA 6020A 24 PASI-MTT3 EPA 7470A 1 PASI-MLMW 92253195002 2015017619 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-CSLJ EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 Modified 4 PASI-GTJJ 92253195003 2015017620 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-CSLJ EPA 9045 1 PASI-AMLS EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 Modified 4 PASI-GTJJ 92253195004 2015017621 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-CSLJ EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 Modified 4 PASI-GTJJ 92253195005 2015017619 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW 92253195006 2015017620 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 56 12 of 64 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92253195 J15060206 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92253195001 2015017618 Aluminum 13.9 ug/L 06/10/15 16:5610.0EPA 6020A Barium 0.22J ug/L 06/10/15 16:560.30EPA 6020A Cadmium 0.031J ug/L 06/10/15 16:560.080EPA 6020A Calcium 70.1 ug/L 06/10/15 16:5640.0EPA 6020A Chromium 0.26J ug/L 06/10/15 16:560.50EPA 6020A Copper 0.77J ug/L 06/10/15 16:561.0EPA 6020A Iron 22.2J ug/L 06/10/15 16:5650.0EPA 6020A Lead 0.095J ug/L 06/10/15 16:560.10EPA 6020A Magnesium 7.5J ug/L 06/10/15 16:5610.0EPA 6020A Manganese 0.34J ug/L 06/10/15 16:560.50EPA 6020A Potassium 16.1J ug/L 06/11/15 07:5450.0EPA 6020A Sodium 45.5J ug/L 06/10/15 16:5650.0EPA 6020A Strontium 0.17J ug/L 06/10/15 16:560.50EPA 6020A Zinc 5.5 ug/L 06/10/15 16:565.0EPA 6020A 92253195002 2015017619 Aluminum 6960 mg/kg 06/15/15 01:2343.3EPA 6010 Barium 150 mg/kg 06/15/15 01:234.3EPA 6010 Beryllium 2.1 mg/kg 06/15/15 01:230.43EPA 6010 Boron 27.4 mg/kg 06/15/15 01:2321.7EPA 6010 Calcium 2070 mg/kg 06/15/15 01:23217EPA 6010 Chromium 25.0 mg/kg 06/15/15 01:232.2EPA 6010 Copper 37.9 mg/kg 06/15/15 01:232.2EPA 6010 Iron 2240 mg/kg 06/15/15 01:2317.3EPA 6010 Magnesium 561 mg/kg 06/15/15 01:23217EPA 6010 Manganese 18.4 mg/kg 06/15/15 01:232.2EPA 6010 Nickel 14.3 mg/kg 06/15/15 01:232.2EPA 6010 Potassium 1010 mg/kg 06/15/15 01:23433EPA 6010 Strontium 71.8 mg/kg 06/15/15 01:234.3EPA 6010 Zinc 18.8 mg/kg 06/15/15 01:238.7EPA 6010 Arsenic 16.6 mg/kg 06/13/15 16:208.7EPA 6020 Cobalt 7.6J mg/kg 06/13/15 16:208.7EPA 6020 Lead 13.0 mg/kg 06/13/15 16:208.7EPA 6020 Vanadium 39.3 mg/kg 06/13/15 16:208.7EPA 6020 Percent Moisture 40.8 %07/06/15 09:450.10ASTM D2974-87 pH at 25 Degrees C 10.4 Std. Units 06/14/15 15:000.10EPA 9045 Sulfate 19.9 mg/L 06/16/15 17:22 B3.4EPA 300.0 RPD%17.2 %06/27/15 17:220.10EPA 9060 Modified Total Organic Carbon 77800 mg/kg 06/27/15 17:225940EPA 9060 Modified Total Organic Carbon 92400 mg/kg 06/27/15 17:286070EPA 9060 Modified Mean Total Organic Carbon 85100 mg/kg 06/27/15 17:226000EPA 9060 Modified 92253195003 2015017620 Aluminum 7960 mg/kg 06/15/15 01:3939.2EPA 6010 Barium 152 mg/kg 06/15/15 01:393.9EPA 6010 Beryllium 1.9 mg/kg 06/15/15 01:390.39EPA 6010 Boron 27.4 mg/kg 06/15/15 01:3919.6EPA 6010 Calcium 2260 mg/kg 06/15/15 01:39196EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 56 13 of 64 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92253195 J15060206 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92253195003 2015017620 Chromium 26.9 mg/kg 06/15/15 01:392.0EPA 6010 Copper 34.6 mg/kg 06/15/15 01:392.0EPA 6010 Iron 2710 mg/kg 06/15/15 01:3915.7EPA 6010 Magnesium 712 mg/kg 06/15/15 01:39196EPA 6010 Manganese 31.3 mg/kg 06/15/15 01:392.0EPA 6010 Nickel 14.6 mg/kg 06/15/15 01:392.0EPA 6010 Potassium 1100 mg/kg 06/15/15 01:39392EPA 6010 Strontium 111 mg/kg 06/15/15 01:393.9EPA 6010 Zinc 21.9 mg/kg 06/15/15 01:397.8EPA 6010 Arsenic 26.2 mg/kg 06/13/15 16:257.8EPA 6020 Cobalt 8.3 mg/kg 06/13/15 16:257.8EPA 6020 Lead 13.5 mg/kg 06/13/15 16:257.8EPA 6020 Vanadium 46.2 mg/kg 06/13/15 16:257.8EPA 6020 Percent Moisture 34.7 %07/06/15 09:450.10ASTM D2974-87 pH at 25 Degrees C 8.2 Std. Units 06/14/15 15:000.10EPA 9045 Sulfate 4.1 mg/L 06/16/15 18:03 B3.1EPA 300.0 RPD%10.2 %06/27/15 17:580.10EPA 9060 Modified Total Organic Carbon 46700 mg/kg 06/27/15 17:583680EPA 9060 Modified Total Organic Carbon 51700 mg/kg 06/27/15 18:053700EPA 9060 Modified Mean Total Organic Carbon 49200 mg/kg 06/27/15 17:583690EPA 9060 Modified 92253195004 2015017621 Aluminum 7090 mg/kg 06/15/15 01:4430.9EPA 6010 Barium 53.8 mg/kg 06/15/15 01:443.1EPA 6010 Beryllium 0.23J mg/kg 06/15/15 01:440.31EPA 6010 Calcium 410 mg/kg 06/15/15 01:44155EPA 6010 Chromium 3.7 mg/kg 06/15/15 01:441.5EPA 6010 Copper 4.1 mg/kg 06/15/15 01:441.5EPA 6010 Iron 8770 mg/kg 06/15/15 01:4412.4EPA 6010 Magnesium 1190 mg/kg 06/15/15 01:44155EPA 6010 Manganese 92.2 mg/kg 06/15/15 01:441.5EPA 6010 Nickel 1.4J mg/kg 06/15/15 01:441.5EPA 6010 Potassium 1350 mg/kg 06/15/15 01:44309EPA 6010 Strontium 10.8 mg/kg 06/15/15 01:443.1EPA 6010 Zinc 12.7 mg/kg 06/15/15 01:446.2EPA 6010 Vanadium 11.9 mg/kg 06/13/15 16:286.2EPA 6020 Mercury 0.011 mg/kg 06/16/15 12:420.010EPA 7471 Percent Moisture 19.7 %07/06/15 09:450.10ASTM D2974-87 pH at 25 Degrees C 4.9 Std. Units 06/14/15 15:000.10EPA 9045 RPD%27.8 %06/28/15 08:560.10EPA 9060 Modified Total Organic Carbon 6520 mg/kg 06/28/15 08:56744EPA 9060 Modified Total Organic Carbon 4930 mg/kg 06/28/15 09:03751EPA 9060 Modified Mean Total Organic Carbon 5730 mg/kg 06/28/15 08:56747EPA 9060 Modified 92253195005 2015017619 SPLP Aluminum 234 ug/L 07/01/15 01:1010.0EPA 6020A Antimony 2.0 ug/L 07/01/15 01:100.50EPA 6020A Arsenic 39.6 ug/L 07/01/15 01:100.50EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 56 14 of 64 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92253195 J15060206 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92253195005 2015017619 SPLP Barium 37.1 ug/L 07/01/15 01:100.30EPA 6020A Boron 659 ug/L 07/02/15 08:4225.0EPA 6020A Calcium 23100 ug/L 07/02/15 08:42200EPA 6020A Chromium 18.3 ug/L 07/01/15 01:100.50EPA 6020A Copper 0.65J ug/L 07/01/15 01:101.0EPA 6020A Iron 24.3J ug/L 07/01/15 01:1050.0EPA 6020A Lead 0.16 ug/L 07/01/15 01:100.10EPA 6020A Magnesium 58.0 ug/L 07/01/15 01:1010.0EPA 6020A Manganese 2.6 ug/L 07/01/15 01:100.50EPA 6020A Molybdenum 8.0 ug/L 07/01/15 01:100.50EPA 6020A Nickel 0.26J ug/L 07/01/15 01:100.50EPA 6020A Potassium 98.8 ug/L 07/01/15 01:1050.0EPA 6020A Selenium 0.55 ug/L 07/01/15 01:100.50EPA 6020A Sodium 1180 ug/L 07/01/15 01:1050.0EPA 6020A Strontium 150 ug/L 07/01/15 01:100.50EPA 6020A Vanadium 120 ug/L 07/01/15 01:101.0EPA 6020A Zinc 6.0 ug/L 07/01/15 01:105.0EPA 6020A 92253195006 2015017620 SPLP Aluminum 921 ug/L 07/01/15 01:1410.0EPA 6020A Antimony 4.6 ug/L 07/01/15 01:140.50EPA 6020A Arsenic 143 ug/L 07/01/15 01:140.50EPA 6020A Barium 149 ug/L 07/01/15 01:140.30EPA 6020A Beryllium 0.45 ug/L 07/01/15 01:140.20EPA 6020A Boron 155 ug/L 07/01/15 01:145.0EPA 6020A Cadmium 0.074J ug/L 07/01/15 01:140.080EPA 6020A Calcium 6460 ug/L 07/01/15 01:1440.0EPA 6020A Chromium 15.7 ug/L 07/01/15 01:140.50EPA 6020A Cobalt 0.83 ug/L 07/01/15 01:140.50EPA 6020A Copper 10.8 ug/L 07/01/15 01:141.0EPA 6020A Iron 302 ug/L 07/01/15 01:1450.0EPA 6020A Lead 1.9 ug/L 07/01/15 01:140.10EPA 6020A Magnesium 1580 ug/L 07/01/15 01:1410.0EPA 6020A Manganese 8.1 ug/L 07/01/15 01:140.50EPA 6020A Molybdenum 4.4 ug/L 07/01/15 01:140.50EPA 6020A Nickel 2.6 ug/L 07/01/15 01:140.50EPA 6020A Potassium 304 ug/L 07/01/15 01:1450.0EPA 6020A Selenium 0.96 ug/L 07/01/15 01:140.50EPA 6020A Sodium 1620 ug/L 07/01/15 01:1450.0EPA 6020A Strontium 192 ug/L 07/01/15 01:140.50EPA 6020A Thallium 0.31 ug/L 07/01/15 01:140.10EPA 6020A Vanadium 107 ug/L 07/01/15 01:141.0EPA 6020A Zinc 10.6 ug/L 07/01/15 01:145.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 56 15 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 6010 Date:July 06, 2015 Description:6010 MET ICP General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24673 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253145025 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1240561) • Aluminum • Barium • Beryllium • Calcium • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium • Strontium • Zinc • MSD (Lab ID: 1240563) • Aluminum • Barium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 56 16 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 6010 Date:July 06, 2015 Description:6010 MET ICP QC Batch: MPRP/24673 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253145025 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Beryllium • Calcium • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium • Strontium • Zinc Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 15063 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 56 17 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 6020 Date:July 06, 2015 Description:6020 MET ICPMS General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24674 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253145025 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1240566) • Antimony • Cadmium • Cobalt • Selenium • Vanadium • MSD (Lab ID: 1240567) • Antimony • Cadmium • Cobalt • Lead • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 56 18 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 6020 Date:July 06, 2015 Description:6020 MET ICPMS Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 10002 Analyte Comments: QC Batch: MPRP/24674 N2: The lab does not hold TNI accreditation for this parameter. • 2015017619 (Lab ID: 92253195002) • Antimony • 2015017620 (Lab ID: 92253195003) • Antimony • 2015017621 (Lab ID: 92253195004) • Antimony • BLANK (Lab ID: 1240564) • Antimony • LCS (Lab ID: 1240565) • Antimony • MS (Lab ID: 1240566) • Antimony • MSD (Lab ID: 1240567) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 56 19 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 6020A Date:July 06, 2015 Description:6020A MET ICPMS General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55069 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253161011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1989762) • Aluminum • MSD (Lab ID: 1989763) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 56 20 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 7470A Date:July 06, 2015 Description:7470A Mercury General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 56 21 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 7471 Date:July 06, 2015 Description:7471 Mercury General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 56 22 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 9045 Date:July 06, 2015 Description:9045 pH Soil General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/38033 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1481715) • pH at 25 Degrees C • DUP (Lab ID: 1481716) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 56 23 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 300.0 Date:July 06, 2015 Description:300.0 IC Anions, SPLP General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23324 B: Analyte was detected in the associated method blank. • BLANK for HBN 268289 [WETA/233 (Lab ID: 1485896) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 56 24 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 353.2 Date:July 06, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015017619 (Lab ID: 92253195002) • 2015017620 (Lab ID: 92253195003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 56 25 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy SM 4500-Cl-E Date:July 06, 2015 Description:4500 Chloride, SPLP General Information: 2 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23354 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252532003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1487999) • Chloride • MSD (Lab ID: 1488000) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 56 26 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 9056 Date:July 06, 2015 Description:9056 IC Anions General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47190 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015017619 (Lab ID: 92253195002) • Chloride • Sulfate • 2015017620 (Lab ID: 92253195003) • Chloride • Sulfate • 2015017621 (Lab ID: 92253195004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 56 27 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 9056 Date:July 06, 2015 Description:9056 IC Anions 48hr General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015017619 (Lab ID: 92253195002) • 2015017620 (Lab ID: 92253195003) • 2015017621 (Lab ID: 92253195004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 56 28 of 64 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92253195 J15060206 Method: Client:Duke Energy EPA 9060 Modified Date:July 06, 2015 Description:Total Organic Carbon General Information: 3 samples were analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 56 29 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017618 Lab ID:92253195001 Collected:06/02/15 09:35 Received:06/05/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 13.9 ug/L 06/10/15 16:56 7429-90-506/10/15 09:2410.0 3.0 1 Antimony ND ug/L 06/10/15 16:56 7440-36-006/10/15 09:240.50 0.15 1 Arsenic ND ug/L 06/10/15 16:56 7440-38-206/10/15 09:240.50 0.11 1 Barium 0.22J ug/L 06/10/15 16:56 7440-39-306/10/15 09:240.30 0.081 1 Beryllium ND ug/L 06/10/15 16:56 7440-41-706/10/15 09:240.20 0.067 1 Boron ND ug/L 06/10/15 16:56 7440-42-806/10/15 09:245.0 1.1 1 Cadmium 0.031J ug/L 06/10/15 16:56 7440-43-906/10/15 09:240.080 0.024 1 Calcium 70.1 ug/L 06/10/15 16:56 7440-70-206/10/15 09:2440.0 16.0 1 Chromium 0.26J ug/L 06/10/15 16:56 7440-47-306/10/15 09:240.50 0.17 1 Cobalt ND ug/L 06/10/15 16:56 7440-48-406/10/15 09:240.50 0.13 1 Copper 0.77J ug/L 06/10/15 16:56 7440-50-806/10/15 09:241.0 0.21 1 Iron 22.2J ug/L 06/10/15 16:56 7439-89-606/10/15 09:2450.0 13.7 1 Lead 0.095J ug/L 06/10/15 16:56 7439-92-106/10/15 09:240.10 0.046 1 Magnesium 7.5J ug/L 06/10/15 16:56 7439-95-406/10/15 09:2410.0 3.2 1 Manganese 0.34J ug/L 06/10/15 16:56 7439-96-506/10/15 09:240.50 0.24 1 Molybdenum ND ug/L 06/10/15 16:56 7439-98-706/10/15 09:240.50 0.094 1 Nickel ND ug/L 06/10/15 16:56 7440-02-006/10/15 09:240.50 0.16 1 Potassium 16.1J ug/L 06/11/15 07:54 7440-09-706/10/15 09:2450.0 11.7 1 Selenium ND ug/L 06/10/15 16:56 7782-49-206/10/15 09:240.50 0.20 1 Sodium 45.5J ug/L 06/10/15 16:56 7440-23-506/10/15 09:2450.0 16.3 1 Strontium 0.17J ug/L 06/10/15 16:56 7440-24-606/10/15 09:240.50 0.13 1 Thallium ND ug/L 06/10/15 16:56 7440-28-006/10/15 09:240.10 0.015 1 Vanadium ND ug/L 06/10/15 16:56 7440-62-206/10/15 09:241.0 0.28 1 Zinc 5.5 ug/L 06/10/15 16:56 7440-66-606/10/15 09:245.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 06/10/15 14:31 7439-97-606/10/15 10:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 56 30 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017619 Lab ID:92253195002 Collected:06/02/15 10:01 Received:06/05/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 6960 mg/kg 06/15/15 01:23 7429-90-506/12/15 16:1643.3 21.7 5 Barium 150 mg/kg 06/15/15 01:23 7440-39-306/12/15 16:164.3 2.2 5 Beryllium 2.1 mg/kg 06/15/15 01:23 7440-41-706/12/15 16:160.43 0.22 5 Boron 27.4 mg/kg 06/15/15 01:23 7440-42-806/12/15 16:1621.7 10.8 5 Calcium 2070 mg/kg 06/15/15 01:23 7440-70-206/12/15 16:162171085 Chromium 25.0 mg/kg 06/15/15 01:23 7440-47-306/12/15 16:162.2 1.1 5 Copper 37.9 mg/kg 06/15/15 01:23 7440-50-806/12/15 16:162.2 1.1 5 Iron 2240 mg/kg 06/15/15 01:23 7439-89-606/12/15 16:1617.3 8.7 5 Magnesium 561 mg/kg 06/15/15 01:23 7439-95-406/12/15 16:162171085 Manganese 18.4 mg/kg 06/15/15 01:23 7439-96-506/12/15 16:162.2 1.1 5 Molybdenum ND mg/kg 06/15/15 01:23 7439-98-706/12/15 16:164.3 2.2 5 Nickel 14.3 mg/kg 06/15/15 01:23 7440-02-006/12/15 16:162.2 1.1 5 Potassium 1010 mg/kg 06/15/15 01:23 7440-09-706/12/15 16:164332175 Sodium ND mg/kg 06/15/15 01:23 7440-23-506/12/15 16:164332175 Strontium 71.8 mg/kg 06/15/15 01:23 7440-24-606/12/15 16:164.3 2.2 5 Zinc 18.8 mg/kg 06/15/15 01:23 7440-66-606/12/15 16:168.7 4.3 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/13/15 16:20 7440-36-0 N206/12/15 16:168.7 4.3 100 Arsenic 16.6 mg/kg 06/13/15 16:20 7440-38-206/12/15 16:168.7 4.3 100 Cadmium ND mg/kg 06/13/15 16:20 7440-43-906/12/15 16:161.0 0.52 100 Cobalt 7.6J mg/kg 06/13/15 16:20 7440-48-406/12/15 16:168.7 4.3 100 Lead 13.0 mg/kg 06/13/15 16:20 7439-92-106/12/15 16:168.7 4.3 100 Selenium ND mg/kg 06/13/15 16:20 7782-49-206/12/15 16:168.7 4.3 100 Thallium ND mg/kg 06/13/15 16:20 7440-28-006/12/15 16:168.7 4.3 100 Vanadium 39.3 mg/kg 06/13/15 16:20 7440-62-206/12/15 16:168.7 4.3 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/16/15 12:31 7439-97-606/12/15 16:300.014 0.0068 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 40.8 %07/06/15 09:450.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 10.4 Std. Units 06/14/15 15:000.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/08/15 00:00300.0 IC Anions, SPLP Sulfate 19.9 mg/L 06/16/15 17:22 14808-79-8 B3.4 1.7 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/08/15 00:00353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 06/18/15 17:17 H10.34 0.34 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 06/08/15 00:004500 Chloride, SPLP Chloride ND mg/L 06/18/15 05:02 16887-00-68.4 4.2 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 56 31 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017619 Lab ID:92253195002 Collected:06/02/15 10:01 Received:06/05/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/11/15 05:04 16887-00-6 D34252135 Sulfate ND mg/kg 06/11/15 05:04 14808-79-8 D34252135 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/11/15 05:04 14797-55-8 H342.5 21.3 5 Analytical Method: EPA 9060 ModifiedTotal Organic Carbon Surrogates RPD%17.2 %06/27/15 17:220.10 0.10 1 Total Organic Carbon 77800 mg/kg 06/27/15 17:22 7440-44-0594029701 Total Organic Carbon 92400 mg/kg 06/27/15 17:28 7440-44-0607030301 Mean Total Organic Carbon 85100 mg/kg 06/27/15 17:22 7440-44-0600030001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 56 32 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017620 Lab ID:92253195003 Collected:06/02/15 11:30 Received:06/05/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7960 mg/kg 06/15/15 01:39 7429-90-506/12/15 16:1639.2 19.6 5 Barium 152 mg/kg 06/15/15 01:39 7440-39-306/12/15 16:163.9 2.0 5 Beryllium 1.9 mg/kg 06/15/15 01:39 7440-41-706/12/15 16:160.39 0.20 5 Boron 27.4 mg/kg 06/15/15 01:39 7440-42-806/12/15 16:1619.6 9.8 5 Calcium 2260 mg/kg 06/15/15 01:39 7440-70-206/12/15 16:1619698.1 5 Chromium 26.9 mg/kg 06/15/15 01:39 7440-47-306/12/15 16:162.0 0.98 5 Copper 34.6 mg/kg 06/15/15 01:39 7440-50-806/12/15 16:162.0 0.98 5 Iron 2710 mg/kg 06/15/15 01:39 7439-89-606/12/15 16:1615.7 7.8 5 Magnesium 712 mg/kg 06/15/15 01:39 7439-95-406/12/15 16:1619698.1 5 Manganese 31.3 mg/kg 06/15/15 01:39 7439-96-506/12/15 16:162.0 0.98 5 Molybdenum ND mg/kg 06/15/15 01:39 7439-98-706/12/15 16:163.9 2.0 5 Nickel 14.6 mg/kg 06/15/15 01:39 7440-02-006/12/15 16:162.0 0.98 5 Potassium 1100 mg/kg 06/15/15 01:39 7440-09-706/12/15 16:163921965 Sodium ND mg/kg 06/15/15 01:39 7440-23-506/12/15 16:163921965 Strontium 111 mg/kg 06/15/15 01:39 7440-24-606/12/15 16:163.9 2.0 5 Zinc 21.9 mg/kg 06/15/15 01:39 7440-66-606/12/15 16:167.8 3.9 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/13/15 16:25 7440-36-0 N206/12/15 16:167.8 3.9 100 Arsenic 26.2 mg/kg 06/13/15 16:25 7440-38-206/12/15 16:167.8 3.9 100 Cadmium ND mg/kg 06/13/15 16:25 7440-43-906/12/15 16:160.94 0.47 100 Cobalt 8.3 mg/kg 06/13/15 16:25 7440-48-406/12/15 16:167.8 3.9 100 Lead 13.5 mg/kg 06/13/15 16:25 7439-92-106/12/15 16:167.8 3.9 100 Selenium ND mg/kg 06/13/15 16:25 7782-49-206/12/15 16:167.8 3.9 100 Thallium ND mg/kg 06/13/15 16:25 7440-28-006/12/15 16:167.8 3.9 100 Vanadium 46.2 mg/kg 06/13/15 16:25 7440-62-206/12/15 16:167.8 3.9 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/16/15 12:39 7439-97-606/12/15 16:300.013 0.0064 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 34.7 %07/06/15 09:450.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.2 Std. Units 06/14/15 15:000.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/08/15 00:00300.0 IC Anions, SPLP Sulfate 4.1 mg/L 06/16/15 18:03 14808-79-8 B3.1 1.5 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/08/15 00:00353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 06/18/15 17:18 H10.31 0.31 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 06/08/15 00:004500 Chloride, SPLP Chloride ND mg/L 06/19/15 05:18 16887-00-67.7 3.8 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 56 33 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017620 Lab ID:92253195003 Collected:06/02/15 11:30 Received:06/05/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/11/15 05:25 16887-00-6 D33811915 Sulfate ND mg/kg 06/11/15 05:25 14808-79-8 D33811915 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/11/15 05:25 14797-55-8 H338.1 19.1 5 Analytical Method: EPA 9060 ModifiedTotal Organic Carbon Surrogates RPD%10.2 %06/27/15 17:580.10 0.10 1 Total Organic Carbon 46700 mg/kg 06/27/15 17:58 7440-44-0368018401 Total Organic Carbon 51700 mg/kg 06/27/15 18:05 7440-44-0370018501 Mean Total Organic Carbon 49200 mg/kg 06/27/15 17:58 7440-44-0369018401 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 56 34 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017621 Lab ID:92253195004 Collected:06/02/15 11:20 Received:06/05/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 7090 mg/kg 06/15/15 01:44 7429-90-506/12/15 16:1630.9 15.5 5 Barium 53.8 mg/kg 06/15/15 01:44 7440-39-306/12/15 16:163.1 1.5 5 Beryllium 0.23J mg/kg 06/15/15 01:44 7440-41-706/12/15 16:160.31 0.15 5 Boron ND mg/kg 06/15/15 01:44 7440-42-806/12/15 16:1615.5 7.7 5 Calcium 410 mg/kg 06/15/15 01:44 7440-70-206/12/15 16:1615577.4 5 Chromium 3.7 mg/kg 06/15/15 01:44 7440-47-306/12/15 16:161.5 0.77 5 Copper 4.1 mg/kg 06/15/15 01:44 7440-50-806/12/15 16:161.5 0.77 5 Iron 8770 mg/kg 06/15/15 01:44 7439-89-606/12/15 16:1612.4 6.2 5 Magnesium 1190 mg/kg 06/15/15 01:44 7439-95-406/12/15 16:1615577.4 5 Manganese 92.2 mg/kg 06/15/15 01:44 7439-96-506/12/15 16:161.5 0.77 5 Molybdenum ND mg/kg 06/15/15 01:44 7439-98-706/12/15 16:163.1 1.5 5 Nickel 1.4J mg/kg 06/15/15 01:44 7440-02-006/12/15 16:161.5 0.77 5 Potassium 1350 mg/kg 06/15/15 01:44 7440-09-706/12/15 16:163091555 Sodium ND mg/kg 06/15/15 01:44 7440-23-506/12/15 16:163091555 Strontium 10.8 mg/kg 06/15/15 01:44 7440-24-606/12/15 16:163.1 1.5 5 Zinc 12.7 mg/kg 06/15/15 01:44 7440-66-606/12/15 16:166.2 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/13/15 16:28 7440-36-0 N206/12/15 16:166.2 3.1 100 Arsenic ND mg/kg 06/13/15 16:28 7440-38-206/12/15 16:166.2 3.1 100 Cadmium ND mg/kg 06/13/15 16:28 7440-43-906/12/15 16:160.74 0.37 100 Cobalt ND mg/kg 06/13/15 16:28 7440-48-406/12/15 16:166.2 3.1 100 Lead ND mg/kg 06/13/15 16:28 7439-92-106/12/15 16:166.2 3.1 100 Selenium ND mg/kg 06/13/15 16:28 7782-49-206/12/15 16:166.2 3.1 100 Thallium ND mg/kg 06/13/15 16:28 7440-28-006/12/15 16:166.2 3.1 100 Vanadium 11.9 mg/kg 06/13/15 16:28 7440-62-206/12/15 16:166.2 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.011 mg/kg 06/16/15 12:42 7439-97-606/12/15 16:300.010 0.0050 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.7 %07/06/15 09:450.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 4.9 Std. Units 06/14/15 15:000.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/11/15 05:47 16887-00-6 D33161585 Sulfate ND mg/kg 06/11/15 05:47 14808-79-8 D33161585 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/11/15 05:47 14797-55-8 H331.6 15.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 56 35 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017621 Lab ID:92253195004 Collected:06/02/15 11:20 Received:06/05/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060 ModifiedTotal Organic Carbon Surrogates RPD%27.8 %06/28/15 08:560.10 0.10 1 Total Organic Carbon 6520 mg/kg 06/28/15 08:56 7440-44-07443721 Total Organic Carbon 4930 mg/kg 06/28/15 09:03 7440-44-07513751 Mean Total Organic Carbon 5730 mg/kg 06/28/15 08:56 7440-44-07473741 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 56 36 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017619 SPLP Lab ID:92253195005 Collected:06/02/15 10:01 Received:06/05/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 234 ug/L 07/01/15 01:10 7429-90-506/29/15 10:2110.0 3.0 1 Antimony 2.0 ug/L 07/01/15 01:10 7440-36-006/29/15 10:210.50 0.15 1 Arsenic 39.6 ug/L 07/01/15 01:10 7440-38-206/29/15 10:210.50 0.11 1 Barium 37.1 ug/L 07/01/15 01:10 7440-39-306/29/15 10:210.30 0.081 1 Beryllium ND ug/L 07/01/15 01:10 7440-41-706/29/15 10:210.20 0.067 1 Boron 659 ug/L 07/02/15 08:42 7440-42-806/29/15 10:2125.0 5.6 5 Cadmium ND ug/L 07/01/15 01:10 7440-43-906/29/15 10:210.080 0.024 1 Calcium 23100 ug/L 07/02/15 08:42 7440-70-206/29/15 10:2120080.0 5 Chromium 18.3 ug/L 07/01/15 01:10 7440-47-306/29/15 10:210.50 0.17 1 Cobalt ND ug/L 07/01/15 01:10 7440-48-406/29/15 10:210.50 0.13 1 Copper 0.65J ug/L 07/01/15 01:10 7440-50-806/29/15 10:211.0 0.21 1 Iron 24.3J ug/L 07/01/15 01:10 7439-89-606/29/15 10:2150.0 13.7 1 Lead 0.16 ug/L 07/01/15 01:10 7439-92-106/29/15 10:210.10 0.046 1 Magnesium 58.0 ug/L 07/01/15 01:10 7439-95-406/29/15 10:2110.0 3.2 1 Manganese 2.6 ug/L 07/01/15 01:10 7439-96-506/29/15 10:210.50 0.24 1 Molybdenum 8.0 ug/L 07/01/15 01:10 7439-98-706/29/15 10:210.50 0.094 1 Nickel 0.26J ug/L 07/01/15 01:10 7440-02-006/29/15 10:210.50 0.16 1 Potassium 98.8 ug/L 07/01/15 01:10 7440-09-706/29/15 10:2150.0 11.7 1 Selenium 0.55 ug/L 07/01/15 01:10 7782-49-206/29/15 10:210.50 0.20 1 Sodium 1180 ug/L 07/01/15 01:10 7440-23-506/29/15 10:2150.0 16.3 1 Strontium 150 ug/L 07/01/15 01:10 7440-24-606/29/15 10:210.50 0.13 1 Thallium ND ug/L 07/01/15 01:10 7440-28-006/29/15 10:210.10 0.015 1 Vanadium 120 ug/L 07/01/15 01:10 7440-62-206/29/15 10:211.0 0.28 1 Zinc 6.0 ug/L 07/01/15 01:10 7440-66-606/29/15 10:215.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 07/01/15 18:03 7439-97-606/29/15 14:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 56 37 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92253195 J15060206 Sample:2015017620 SPLP Lab ID:92253195006 Collected:06/02/15 11:30 Received:06/05/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 921 ug/L 07/01/15 01:14 7429-90-506/29/15 10:2110.0 3.0 1 Antimony 4.6 ug/L 07/01/15 01:14 7440-36-006/29/15 10:210.50 0.15 1 Arsenic 143 ug/L 07/01/15 01:14 7440-38-206/29/15 10:210.50 0.11 1 Barium 149 ug/L 07/01/15 01:14 7440-39-306/29/15 10:210.30 0.081 1 Beryllium 0.45 ug/L 07/01/15 01:14 7440-41-706/29/15 10:210.20 0.067 1 Boron 155 ug/L 07/01/15 01:14 7440-42-806/29/15 10:215.0 1.1 1 Cadmium 0.074J ug/L 07/01/15 01:14 7440-43-906/29/15 10:210.080 0.024 1 Calcium 6460 ug/L 07/01/15 01:14 7440-70-206/29/15 10:2140.0 16.0 1 Chromium 15.7 ug/L 07/01/15 01:14 7440-47-306/29/15 10:210.50 0.17 1 Cobalt 0.83 ug/L 07/01/15 01:14 7440-48-406/29/15 10:210.50 0.13 1 Copper 10.8 ug/L 07/01/15 01:14 7440-50-806/29/15 10:211.0 0.21 1 Iron 302 ug/L 07/01/15 01:14 7439-89-606/29/15 10:2150.0 13.7 1 Lead 1.9 ug/L 07/01/15 01:14 7439-92-106/29/15 10:210.10 0.046 1 Magnesium 1580 ug/L 07/01/15 01:14 7439-95-406/29/15 10:2110.0 3.2 1 Manganese 8.1 ug/L 07/01/15 01:14 7439-96-506/29/15 10:210.50 0.24 1 Molybdenum 4.4 ug/L 07/01/15 01:14 7439-98-706/29/15 10:210.50 0.094 1 Nickel 2.6 ug/L 07/01/15 01:14 7440-02-006/29/15 10:210.50 0.16 1 Potassium 304 ug/L 07/01/15 01:14 7440-09-706/29/15 10:2150.0 11.7 1 Selenium 0.96 ug/L 07/01/15 01:14 7782-49-206/29/15 10:210.50 0.20 1 Sodium 1620 ug/L 07/01/15 01:14 7440-23-506/29/15 10:2150.0 16.3 1 Strontium 192 ug/L 07/01/15 01:14 7440-24-606/29/15 10:210.50 0.13 1 Thallium 0.31 ug/L 07/01/15 01:14 7440-28-006/29/15 10:210.10 0.015 1 Vanadium 107 ug/L 07/01/15 01:14 7440-62-206/29/15 10:211.0 0.28 1 Zinc 10.6 ug/L 07/01/15 01:14 7440-66-606/29/15 10:215.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 07/01/15 18:06 7439-97-606/29/15 14:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 56 38 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13814 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92253195001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1989756 Associated Lab Samples:92253195001 Matrix:Water Analyzed Mercury ug/L ND 0.20 06/10/15 14:06 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989757LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1989758MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253195001 1989759 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 110 80-120106 4 205ND5.5 5.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 56 39 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/14018 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92253195005, 92253195006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2006739 Associated Lab Samples:92253195005, 92253195006 Matrix:Water Analyzed Mercury ug/L ND 0.20 07/01/15 17:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2006740LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.95 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2007452MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92255755005 2007453 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 80-120105 2 205ND5.2 5.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 56 40 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5849 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1240633 Associated Lab Samples:92253195002, 92253195003, 92253195004 Matrix:Solid Analyzed Mercury mg/kg ND 0.0078 06/16/15 12:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1240634LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.084.078 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1240635MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253145025 1240636 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .0954 106 80-120105 3 20.093ND 0.10 0.097 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 56 41 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24673 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1240559 Associated Lab Samples:92253195002, 92253195003, 92253195004 Matrix:Solid Analyzed Aluminum mg/kg ND 4.9 06/15/15 00:48 Barium mg/kg ND 0.49 06/15/15 00:48 Beryllium mg/kg ND 0.049 06/15/15 00:48 Boron mg/kg ND 2.4 06/15/15 00:48 Calcium mg/kg ND 24.4 06/15/15 00:48 Chromium mg/kg ND 0.24 06/15/15 00:48 Copper mg/kg ND 0.24 06/15/15 00:48 Iron mg/kg 1.5J 1.9 06/15/15 00:48 Magnesium mg/kg ND 24.4 06/15/15 00:48 Manganese mg/kg ND 0.24 06/15/15 00:48 Molybdenum mg/kg ND 0.49 06/15/15 00:48 Nickel mg/kg ND 0.24 06/15/15 00:48 Potassium mg/kg ND 48.7 06/15/15 00:48 Sodium mg/kg ND 48.7 06/15/15 00:48 Strontium mg/kg ND 0.49 06/15/15 00:48 Zinc mg/kg ND 0.97 06/15/15 00:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1240560LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 126128 99 80-120 Barium mg/kg 12.912.8 101 80-120 Beryllium mg/kg 1.31.3 101 80-120 Boron mg/kg 124128 97 80-120 Calcium mg/kg 644639 101 80-120 Chromium mg/kg 12.712.8 100 80-120 Copper mg/kg 12.212.8 95 80-120 Iron mg/kg 128128 100 80-120 Magnesium mg/kg 641639 100 80-120 Manganese mg/kg 12.612.8 98 80-120 Molybdenum mg/kg 12.412.8 97 80-120 Nickel mg/kg 12.812.8 100 80-120 Potassium mg/kg 645639 101 80-120 Sodium mg/kg 669639 105 80-120 Strontium mg/kg 12.512.8 98 80-120 Zinc mg/kg 63.063.9 99 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 56 42 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1240561MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253145025 1240563 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1158-1320 75-125-1830 4 20146179001580015200 Barium mg/kg M115.8 355 75-125134 12 2014.6260 316 280 Beryllium mg/kg M11.57 61 75-12565 0 201.451.9 2.8 2.8 Boron mg/kg 158 79 75-12578 8 20146ND124115 Calcium mg/kg M17902075-1252 4 20733332034703330 Chromium mg/kg 15.8 75 75-12585 2 2014.614.9 26.9 27.4 Copper mg/kg 15.8 89 75-12579 11 2014.68.6 22.7 20.2 Iron mg/kg M1158-4470 75-125-4740 1 20146258001870018800 Magnesium mg/kg M1790-342 75-125-451 5 20733140001130010700 Manganese mg/kg M115.8 -600 75-125-817 4 2014.6694 599 574 Molybdenum mg/kg M115.8 73 75-12574 6 2014.6ND 11.6 10.9 Nickel mg/kg M115.8 65 75-12565 4 2014.610.8 21.1 20.3 Potassium mg/kg M1790-164 75-125-237 4 20733118001050010100 Sodium mg/kg 790 93 75-12593 7 20733ND823768 Strontium mg/kg M115.8 58 75-12550 6 2014.622.8 32.0 30.2 Zinc mg/kg M1793875-12535 3 2073.3125 155 151 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 56 43 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24674 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1240564 Associated Lab Samples:92253195002, 92253195003, 92253195004 Matrix:Solid Analyzed Antimony mg/kg ND 0.050 N206/13/15 16:08 Arsenic mg/kg ND 0.050 06/13/15 16:08 Cadmium mg/kg ND 0.0060 06/13/15 16:08 Cobalt mg/kg ND 0.050 06/13/15 16:08 Lead mg/kg ND 0.050 06/13/15 16:08 Selenium mg/kg ND 0.050 06/13/15 16:08 Thallium mg/kg ND 0.050 06/13/15 16:08 Vanadium mg/kg ND 0.050 06/13/15 16:08 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1240565LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.5 N22.6 96 80-120 Arsenic mg/kg 2.62.6 102 80-120 Cadmium mg/kg 0.25.26 99 80-120 Cobalt mg/kg 2.62.6 101 80-120 Lead mg/kg 2.62.6 101 80-120 Selenium mg/kg 2.52.6 96 80-120 Thallium mg/kg 2.72.6 104 80-120 Vanadium mg/kg 2.62.6 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1240566MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253145025 1240567 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N23.14 52 75-12557 203.14ND ND ND Arsenic mg/kg 3.14 82 75-12579 203.14ND 3.2J ND Cadmium mg/kg M6.314 51 75-12541 20.314ND ND ND Cobalt mg/kg M63.14 64 75-12567 1 203.147.5 9.5 9.6 Lead mg/kg M63.14 118 75-12574 203.14ND 5.9J 4.5J Selenium mg/kg M63.14 63 75-12549 203.14ND ND ND Thallium mg/kg 3.14 91 75-12593 203.14ND 3.3J 3.4J Vanadium mg/kg M63.14 48 75-125115 2 203.1484.5 86.0 88.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 56 44 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/55069 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92253195001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1989760 Associated Lab Samples:92253195001 Matrix:Water Analyzed Aluminum ug/L ND 10.0 06/10/15 16:43 Antimony ug/L ND 0.50 06/10/15 16:43 Arsenic ug/L ND 0.50 06/10/15 16:43 Barium ug/L ND 0.30 06/10/15 16:43 Beryllium ug/L ND 0.20 06/10/15 16:43 Boron ug/L ND 5.0 06/10/15 16:43 Cadmium ug/L ND 0.080 06/10/15 16:43 Calcium ug/L ND 40.0 06/10/15 16:43 Chromium ug/L ND 0.50 06/10/15 16:43 Cobalt ug/L ND 0.50 06/10/15 16:43 Copper ug/L ND 1.0 06/10/15 16:43 Iron ug/L ND 50.0 06/10/15 16:43 Lead ug/L ND 0.10 06/10/15 16:43 Magnesium ug/L ND 10.0 06/10/15 16:43 Manganese ug/L ND 0.50 06/10/15 16:43 Molybdenum ug/L ND 0.50 06/10/15 16:43 Nickel ug/L ND 0.50 06/10/15 16:43 Potassium ug/L ND 50.0 06/11/15 07:45 Selenium ug/L ND 0.50 06/10/15 16:43 Sodium ug/L ND 50.0 06/10/15 16:43 Strontium ug/L ND 0.50 06/10/15 16:43 Thallium ug/L ND 0.10 06/10/15 16:43 Vanadium ug/L ND 1.0 06/10/15 16:43 Zinc ug/L ND 5.0 06/10/15 16:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989761LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 77.980 97 80-120 Antimony ug/L 76.480 96 80-120 Arsenic ug/L 77.680 97 80-120 Barium ug/L 81.380 102 80-120 Beryllium ug/L 80.880 101 80-120 Boron ug/L 78.380 98 80-120 Cadmium ug/L 77.280 96 80-120 Calcium ug/L 9551000 95 80-120 Chromium ug/L 79.480 99 80-120 Cobalt ug/L 84.980 106 80-120 Copper ug/L 81.380 102 80-120 Iron ug/L 10301000 103 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 56 45 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1989761LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 78.180 98 80-120 Magnesium ug/L 9851000 98 80-120 Manganese ug/L 75.280 94 80-120 Molybdenum ug/L 77.280 97 80-120 Nickel ug/L 78.980 99 80-120 Potassium ug/L 10201000 102 80-120 Selenium ug/L 78.980 99 80-120 Sodium ug/L 10101000 101 80-120 Strontium ug/L 75.380 94 80-120 Thallium ug/L 82.980 104 80-120 Vanadium ug/L 77.280 96 80-120 Zinc ug/L 80.880 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1989762MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253161011 1989763 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18020075-125215 4 2080173333345 Antimony ug/L 80 95 75-12595 0 2080ND76.3 76.2 Arsenic ug/L 80 100 75-12599 1 2080ND79.7 78.9 Barium ug/L 80 96 75-12595 0 20801.2 77.8 77.6 Beryllium ug/L 80 104 75-125100 3 2080ND82.9 80.1 Boron ug/L 80 96 75-12593 3 2080ND76.6 74.2 Cadmium ug/L 80 98 75-12598 0 2080ND78.1 78.0 Calcium ug/L 1000 102 75-125100 2 20100016811801170 Chromium ug/L 80 99 75-12599 0 20801.9 80.9 81.0 Cobalt ug/L 80 97 75-12597 0 2080ND78.1 77.8 Copper ug/L 80 101 75-125101 0 20801.2 82.0 82.2 Iron ug/L 1000 109 75-125109 0 20100033314201420 Lead ug/L 80 98 75-12597 1 20800.053J 78.4 77.7 Magnesium ug/L 1000 100 75-12598 3 20100042.1 1050 1020 Manganese ug/L 80 94 75-12594 0 20805.3 80.8 80.4 Molybdenum ug/L 80 96 75-12598 2 20800.39J 77.2 78.7 Nickel ug/L 80 99 75-12598 1 20800.32J 79.7 79.1 Potassium ug/L 1000 98 75-125100 2 20100039.0J 1010 1040 Selenium ug/L 80 104 75-12598 6 2080ND83.5 78.3 Sodium ug/L 1000 89 75-12588 1 20100033.9J 928 915 Strontium ug/L 80 96 75-12594 1 20801.2 77.6 76.7 Thallium ug/L 80 105 75-125103 1 2080ND83.9 82.8 Vanadium ug/L 80 95 75-12596 1 2080ND76.5 77.2 Zinc ug/L 80 104 75-12599 5 2080ND84.9 80.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 56 46 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/55571 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92253195005, 92253195006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2006731 Associated Lab Samples:92253195005, 92253195006 Matrix:Water Analyzed Aluminum ug/L ND 10.0 07/01/15 00:15 Antimony ug/L ND 0.50 07/01/15 00:15 Arsenic ug/L ND 0.50 07/01/15 00:15 Barium ug/L ND 0.30 07/01/15 00:15 Beryllium ug/L ND 0.20 07/01/15 00:15 Boron ug/L ND 5.0 07/01/15 00:15 Cadmium ug/L ND 0.080 07/01/15 00:15 Calcium ug/L ND 40.0 07/02/15 07:11 Chromium ug/L ND 0.50 07/01/15 00:15 Cobalt ug/L ND 0.50 07/01/15 00:15 Copper ug/L ND 1.0 07/02/15 07:11 Iron ug/L ND 50.0 07/01/15 00:15 Lead ug/L ND 0.10 07/01/15 00:15 Magnesium ug/L ND 10.0 07/01/15 00:15 Manganese ug/L ND 0.50 07/01/15 00:15 Molybdenum ug/L ND 0.50 07/01/15 00:15 Nickel ug/L ND 0.50 07/01/15 00:15 Potassium ug/L ND 50.0 07/01/15 00:15 Selenium ug/L ND 0.50 07/01/15 00:15 Sodium ug/L ND 50.0 07/01/15 00:15 Strontium ug/L ND 0.50 07/01/15 00:15 Thallium ug/L ND 0.10 07/01/15 00:15 Vanadium ug/L ND 1.0 07/01/15 00:15 Zinc ug/L ND 5.0 07/01/15 00:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2006732LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 76.180 95 80-120 Antimony ug/L 76.280 95 80-120 Arsenic ug/L 77.580 97 80-120 Barium ug/L 79.180 99 80-120 Beryllium ug/L 82.080 103 80-120 Boron ug/L 87.180 109 80-120 Cadmium ug/L 77.980 97 80-120 Calcium ug/L 10301000 103 80-120 Chromium ug/L 78.180 98 80-120 Cobalt ug/L 78.480 98 80-120 Copper ug/L 77.480 97 80-120 Iron ug/L 9761000 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 56 47 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2006732LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 77.080 96 80-120 Magnesium ug/L 9641000 96 80-120 Manganese ug/L 78.480 98 80-120 Molybdenum ug/L 76.880 96 80-120 Nickel ug/L 78.280 98 80-120 Potassium ug/L 9791000 98 80-120 Selenium ug/L 78.280 98 80-120 Sodium ug/L 9941000 99 80-120 Strontium ug/L 77.380 97 80-120 Thallium ug/L 76.680 96 80-120 Vanadium ug/L 78.680 98 80-120 Zinc ug/L 77.280 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 2007450MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92255755020 2007451 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 111 75-125110 0 20805.6J 94.1 93.8 Antimony ug/L 80 98 75-12596 2 2080ND78.5 76.7 Arsenic ug/L 80 101 75-12597 4 2080ND81.1 77.9 Barium ug/L 80 101 75-12599 2 20800.26J 80.8 79.3 Beryllium ug/L 80 100 75-125101 1 2080ND79.8 80.6 Boron ug/L 80 104 75-125101 3 2080ND84.4 81.9 Cadmium ug/L 80 101 75-12599 2 2080ND80.7 79.4 Calcium ug/L 1000 103 75-125101 2 20100076.6 1100 1090 Chromium ug/L 80 101 75-12599 3 2080ND81.2 79.1 Cobalt ug/L 80 103 75-12598 4 2080ND82.2 78.6 Copper ug/L 80 102 75-12598 4 20800.32J 81.9 78.9 Iron ug/L 1000 101 75-12598 3 20100014.7J 1030 996 Lead ug/L 80 99 75-12597 3 2080ND79.3 77.2 Magnesium ug/L 1000 102 75-12599 3 2010007.9J 1030 1000 Manganese ug/L 80 102 75-125100 2 20800.42J 81.6 80.2 Molybdenum ug/L 80 100 75-12598 2 2080ND80.0 78.7 Nickel ug/L 80 105 75-125100 4 2080ND84.0 80.4 Potassium ug/L 1000 104 75-125101 3 20100018.5J 1050 1030 Selenium ug/L 80 103 75-12598 4 2080ND82.1 78.6 Sodium ug/L 1000 104 75-12597 6 20100031.9J 1070 1010 Strontium ug/L 80 100 75-12599 1 20800.50 80.6 79.8 Thallium ug/L 80 101 75-12599 2 2080ND81.1 79.2 Vanadium ug/L 80 102 75-12599 3 2080ND82.0 79.4 Zinc ug/L 80 106 75-12594 10 20808.0 92.6 83.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 56 48 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/7948 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Dup Result Max RPD QualifiersRPDResult 92251982001 1478682SAMPLE DUPLICATE: Percent Moisture %26.1 19 2531.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 92253195004 1478683SAMPLE DUPLICATE: Percent Moisture %19.4 2 2519.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 56 49 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/38033 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Dup Result Max RPD QualifiersRPDResult 92253352003 1481715SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.0 D63107.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92253161005 1481716SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.0 D68105.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 56 50 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23324 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92253195002, 92253195003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1485896 Associated Lab Samples:92253195002, 92253195003 Matrix:Water Analyzed Sulfate mg/L 2.3 2.0 06/16/15 15:20 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1485897LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.620 98 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1485898MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252532003 1485899 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20 98 99 1206.3 26.0 26.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 56 51 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23372 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92253195002, 92253195003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1488925 Associated Lab Samples:92253195002, 92253195003 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.14 0.020 Z206/18/15 17:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1488926LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1488927MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252532003 1488928 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.5 98 90-11097 1 102.5ND 2.6 2.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 56 52 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23354 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92253195002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1487997 Associated Lab Samples:92253195002 Matrix:Water Analyzed Chloride mg/L ND 1.0 06/18/15 04:51 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1487998LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 19.820 99 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1487999MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252532003 1488000 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L M1208690-11086 0 1020ND17.3 17.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 56 53 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/23374 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92253195003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1489297 Associated Lab Samples:92253195003 Matrix:Water Analyzed Chloride mg/L ND 1.0 06/19/15 05:16 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1489298LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 20.320 102 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1489299MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253890015 1489300 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 45.6 109 90-110109 0 1045.6ND 49.6 49.7 Parameter Units MS Result % Rec Limits Qual% RecConc. 1489301MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92254310001 1489302 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L H328.1 101 90-110101 0 1028.1ND 29.5 29.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 56 54 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/47190 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1238041 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.9 06/11/15 08:38 Sulfate mg/kg ND 49.9 06/11/15 08:38 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1238042LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 472502 94 80-120 Sulfate mg/kg 470502 94 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1238044MATRIX SPIKE SAMPLE: MSSpike Result 92253145022 Chloride mg/kg 576653 88 80-120ND Sulfate mg/kg 656653 85 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92253145022 1238043SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 56 55 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/47192 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1238051 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 06/11/15 08:38 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1238052LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 49.450.2 98 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1238054MATRIX SPIKE SAMPLE: MSSpike Result 92253145022 Nitrate as N mg/kg 60.8 H365.3 91 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92253145022 1238053SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 56 56 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92253195 J15060206 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/29243 EPA 9060 Modified EPA 9060 Modified 9060 TOC Average Associated Lab Samples:92253195002, 92253195003, 92253195004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1184234 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/27/15 16:37 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1184235LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 116000120000 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1184236MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253195003 1184237 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 37200 123 50-150119 2 3037200492009510093500 Parameter Units MS Result % Rec Limits Qual% RecConc. 1184238MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92253195002 1184239 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 62800 102 50-150100 2 306190085100149000147000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 56 57 of 64 #=QL# QUALIFIERS Pace Project No.: Project: 92253195 J15060206 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICPM/10002 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICP/15063 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 56 58 of 64 #=QL# QUALIFIERS Pace Project No.: Project: 92253195 J15060206 ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 56 59 of 64 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92253195 J15060206 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92253195002 MPRP/24673 ICP/150632015017619EPA 3050 EPA 6010 92253195003 MPRP/24673 ICP/150632015017620EPA 3050 EPA 6010 92253195004 MPRP/24673 ICP/150632015017621EPA 3050 EPA 6010 92253195002 MPRP/24674 ICPM/100022015017619EPA 3050 EPA 6020 92253195003 MPRP/24674 ICPM/100022015017620EPA 3050 EPA 6020 92253195004 MPRP/24674 ICPM/100022015017621EPA 3050 EPA 6020 92253195001 MPRP/55069 ICPM/247392015017618EPA 3020 EPA 6020A 92253195005 MPRP/55571 ICPM/251092015017619 SPLP EPA 3020 EPA 6020A 92253195006 MPRP/55571 ICPM/251092015017620 SPLP EPA 3020 EPA 6020A 92253195001 MERP/13814 MERC/160862015017618EPA 7470A EPA 7470A 92253195005 MERP/14018 MERC/163642015017619 SPLP EPA 7470A EPA 7470A 92253195006 MERP/14018 MERC/163642015017620 SPLP EPA 7470A EPA 7470A 92253195002 MERP/5849 MERC/58382015017619EPA 7471 EPA 7471 92253195003 MERP/5849 MERC/58382015017620EPA 7471 EPA 7471 92253195004 MERP/5849 MERC/58382015017621EPA 7471 EPA 7471 92253195002 PMST/79482015017619ASTM D2974-87 92253195003 PMST/79482015017620ASTM D2974-87 92253195004 PMST/79482015017621ASTM D2974-87 92253195002 WET/380332015017619EPA 9045 92253195003 WET/380332015017620EPA 9045 92253195004 WET/380332015017621EPA 9045 92253195002 WETA/233242015017619EPA 300.0 92253195003 WETA/233242015017620EPA 300.0 92253195002 WETA/233722015017619EPA 353.2 92253195003 WETA/233722015017620EPA 353.2 92253195002 WETA/233542015017619SM 4500-Cl-E 92253195003 WETA/233742015017620SM 4500-Cl-E 92253195002 WETA/471902015017619EPA 9056 92253195003 WETA/471902015017620EPA 9056 92253195004 WETA/471902015017621EPA 9056 92253195002 WETA/471922015017619EPA 9056 92253195003 WETA/471922015017620EPA 9056 92253195004 WETA/471922015017621EPA 9056 92253195002 WETA/292432015017619EPA 9060 Modified 92253195002 WETA/292492015017619EPA 9060 Modified 92253195003 WETA/292432015017620EPA 9060 Modified 92253195003 WETA/292492015017620EPA 9060 Modified 92253195004 WETA/292432015017621EPA 9060 Modified 92253195004 WETA/292492015017621EPA 9060 Modified REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 56 60 of 64 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92253195 J15060206 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 07/06/2015 01:32 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 56 61 of 64 Page 55 of 56 62 of 64 Page 56 of 56 63 of 64 64 of 64