The URL can be used to link to this page

Home My WebLink AboutNC0038377_J15030550report_2017110113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15030550 Project Name:MAYO STEAM - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:4/15/2015 Customer Address: Customer Name(s): Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 43 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015007981 MAYO STEAM 19-Mar-15 10:52 AM illegible MW-3BR 2015007983 MAYO STEAM 19-Mar-15 11:50 AM illegible Equipment Blank 2015007984 MAYO STEAM 19-Mar-15 2:00 PM illegible MW-3 2015007985 MAYO STEAM 19-Mar-15 5:40 PM illegible MW-2 2015007986 MAYO STEAM 19-Mar-15 11:50 AM illegible Filter Blank 5 Total Samples Analytical Lab Page 2 of 43 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:4/15/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007981 Collection Date: 19-Mar-15 10:52 AM Site: MW-3BR Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 03/25/2015 18:01 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.005 1 Barium (Ba)0.045 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.05 1 Iron (Fe)0.521 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.01 1 Manganese (Mn)0.714 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.005 1 Strontium (Sr)0.403 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/24/2015 12:01 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Molybdenum (Mo)1.60 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 14:03 JAHERMA0.3 1 Analytical Lab Page 4 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007983 Collection Date: 19-Mar-15 11:50 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 03/24/2015 16:04 TLINN0.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 03/24/2015 22:32 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 03/24/2015 22:32 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 03/31/2015 16:29 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)< 0.01 mg/L EPA 200.7 03/24/2015 14:22M4 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 03/24/2015 14:22M4 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 03/24/2015 14:22 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 03/24/2015 14:22M4 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/25/2015 13:14 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/13/2015 15:24 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 5 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007983 Collection Date: 19-Mar-15 11:50 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 03/24/2015 11:00 AGIBBS5251 Total Carbon TOC 0.104 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 03/23/2015 14:45 AGIBBS551 Analytical Lab Page 6 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007984 Collection Date: 19-Mar-15 2:00 PM Site: MW-3 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.070 mg-N/L EPA 353.2 03/24/2015 16:05 TLINN0.01 1 INORGANIC IONS BY IC Chloride 47 mg/L EPA 300.0 03/25/2015 00:56 BGN9034110 Sulfate 21 mg/L EPA 300.0 03/25/2015 00:56 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 03/31/2015 16:31 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 03/25/2015 18:03 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.005 1 Barium (Ba)0.054 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.005 1 Boron (B)0.815 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.01 1 Manganese (Mn)0.827 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.005 1 Strontium (Sr)0.331 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/24/2015 12:04 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)27.9 mg/L EPA 200.7 03/24/2015 14:37M4 MHALL30.1 10 Magnesium (Mg)8.83 mg/L EPA 200.7 03/24/2015 14:37 MHALL30.005 1 Potassium (K)1.84 mg/L EPA 200.7 03/24/2015 14:37 MHALL30.1 1 Sodium (Na)22.0 mg/L EPA 200.7 03/24/2015 14:37M4 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.034 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.005 1 Barium (Ba)0.056 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.005 1 Boron (B)0.847 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.05 1 Iron (Fe)0.034 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.01 1 Manganese (Mn)0.880 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.005 1 Strontium (Sr)0.336 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/25/2015 12:21 MHALL30.005 1 Analytical Lab Page 7 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007984 Collection Date: 19-Mar-15 2:00 PM Site: MW-3 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Nickel (Ni)2.06 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 14:08 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Nickel (Ni)2.22 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/13/2015 15:30 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 190 mg/L SM2540C 03/24/2015 11:00 AGIBBS5251 Total Carbon TOC 0.875 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 03/23/2015 14:45 AGIBBS551 Analytical Lab Page 8 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007985 Collection Date: 19-Mar-15 5:40 PM Site: MW-2 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.190 mg-N/L EPA 353.2 03/24/2015 16:06 TLINN0.01 1 INORGANIC IONS BY IC Chloride 15 mg/L EPA 300.0 03/25/2015 01:14 BGN9034110 Sulfate 18 mg/L EPA 300.0 03/25/2015 01:14 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 03/31/2015 17:05 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 03/25/2015 18:05 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.074 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.005 1 Barium (Ba)0.053 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.05 1 Iron (Fe)0.389 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.01 1 Manganese (Mn)0.836 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.005 1 Strontium (Sr)0.186 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/24/2015 12:31 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)18.6 mg/L EPA 200.7 03/24/2015 14:49M4 MHALL30.01 1 Magnesium (Mg)7.31 mg/L EPA 200.7 03/24/2015 14:49 MHALL30.005 1 Potassium (K)4.44 mg/L EPA 200.7 03/24/2015 14:49 MHALL30.1 1 Sodium (Na)27.7 mg/L EPA 200.7 03/24/2015 14:49M4 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.834 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.005 1 Barium (Ba)0.055 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.05 1 Iron (Fe)0.756 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.01 1 Manganese (Mn)0.833 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.005 1 Strontium (Sr)0.184 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/25/2015 12:25 MHALL30.005 1 Analytical Lab Page 9 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007985 Collection Date: 19-Mar-15 5:40 PM Site: MW-2 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Cobalt (Co)2.64 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Nickel (Ni)1.94 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA0.2 1 Vanadium (V) Low Level 0.973 ug/L EPA 200.8 04/14/2015 14:13 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Cobalt (Co)2.78 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Nickel (Ni)2.31 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA0.2 1 Vanadium (V) Low Level 1.68 ug/L EPA 200.8 04/13/2015 15:35 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 200 mg/L SM2540C 03/24/2015 11:00 AGIBBS5251 Total Carbon TOC 1.5 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L SM2540D 03/23/2015 14:45 AGIBBS551 Analytical Lab Page 10 of 43 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030550 2015007986 Collection Date: 19-Mar-15 11:50 AM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 03/25/2015 18:08 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/24/2015 12:12 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 14:18 JAHERMA0.3 1 These sample were stored in a refrigerator that malfunctioned causing the sample to freeze. The state was notified and the results may be reported for compliance purposes as long as the data is flagged. Any parameter requiring preservation at < 6C and that was tested after 3/25/2015 at 15:45 when the refrigerator was documented to be in compliance are flagged with N1. -- Additional Information -- Qualifiers: M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. N1 See additional information listed below. Analytical Lab Page 11 of 43 Analytical Lab Page 12 of 43 Analytical Lab Page 13 of 43 Analytical Lab Page 14 of 43 Analytical Lab Page 15 of 43 Analytical Lab Page 16 of 43 Analytical Lab Page 17 of 43 Analytical Lab Page 18 of 43 Analytical Lab Page 19 of 43 Analytical Lab Page 20 of 43 Analytical Lab Page 21 of 43 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QC23046Lot Number: J15030550Project Number: AB GW Assessment Water - MayoProject Name: 03/31/2015Date Completed: Grant Wilton Project Manager *QC23046* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QC23046 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Mayo Project Number: J15030550 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QC23046 Project Name: AB GW Assessment Water - Mayo Project Number: J15030550 Sample Number Sample ID Matrix Date Sampled Date Received 001 03/19/2015 11502015007983Aqueous 03/23/2015 002 03/19/2015 14002015007984Aqueous 03/23/2015 003 03/19/2015 17402015007985Aqueous 03/23/2015 (3 samples) Page: 3 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QC23046 Project Name: AB GW Assessment Water - Mayo Project Number: J15030550 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2015007984 Aqueous Alkalinity SM 2320B-61 mg/L 7 002 2015007984 Aqueous Bicarbonate Alkalinity SM 2320B-61 mg/L 7 003 2015007985 Aqueous Alkalinity SM 2320B-89 mg/L 9 003 2015007985 Aqueous Bicarbonate Alkalinity SM 2320B-89 mg/L 9 003 2015007985 Aqueous Methane RSK - 175 780 ug/L 10 (5 detections) Page: 4 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015007983 QC23046-001 03/19/2015 1150 03/23/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030550 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/30/2015 1722 BWS 71282 1 (Bicarbonate ) SM 2320B-2011 1 03/30/2015 1722 BWS 03/30/2015 1722 1 (Carbonate Al) SM 2320B-2011 1 03/30/2015 1722 BWS 03/30/2015 1722 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015007983 QC23046-001 03/19/2015 1150 03/23/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030550 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/27/2015 1955 DCS 71148 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015007984 QC23046-002 03/19/2015 1400 03/23/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030550 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/30/2015 1739 BWS 71282 1 (Bicarbonate ) SM 2320B-2011 1 03/30/2015 1739 BWS 03/30/2015 1739 1 (Carbonate Al) SM 2320B-2011 1 03/30/2015 1739 BWS 03/30/2015 1739 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 61 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 61 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015007984 QC23046-002 03/19/2015 1400 03/23/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030550 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/27/2015 2008 DCS 71148 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015007985 QC23046-003 03/19/2015 1740 03/23/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030550 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/30/2015 1744 BWS 71282 1 (Bicarbonate ) SM 2320B-2011 1 03/30/2015 1744 BWS 03/30/2015 1744 1 (Carbonate Al) SM 2320B-2011 1 03/30/2015 1744 BWS 03/30/2015 1744 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 89 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 89 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015007985 QC23046-003 03/19/2015 1740 03/23/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030550 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 2 03/27/2015 2055 DCS 71295 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 780 2ug/L20 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ71282-001 71282 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 03/30/2015 150810mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ71282-002 71282 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 95 03/30/2015 15149510090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ71148-001 71148 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 03/27/2015 140710ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ71148-002 71148 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 150 03/27/2015 13429915070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ71148-003 71148 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 190 03/27/2015 135512815070-13026 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ71295-001 71295 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 03/27/2015 140710ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ71295-002 71295 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 150 03/27/2015 13429915070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ71295-003 71295 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 190 03/27/2015 135512815070-13026 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC23046 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Analytical Lab Page 43 of 43