NC0004987_Amend Exisitng/Pending Permit Application_20171017

(� DUKE
ENERGY
October 17, 2017
Ms. Julie Grzyb, Supervisor
Complex NPDES permitting Unit
Division of Water Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
Paul Draovitch, P E
Senior Vice President
Environmental, Health & Safety
526 S Church Street
Mail Code EC3XP
Charlotte, NC 28202
[phone]
RECEIVED/NCDEQ/®WR
OCT 19 2017
water Quawy
Permitting Section
Subject: Duke Energy Progress, LLC and Duke Energy Carolinas, LLC.
Asheville Steam Electric Plant NPDES Permit Number NC0000396
Mayo Steam Electric Plant NPDES Permit Number NCO038377
Roxboro Steam Electric Plant NPDES Permit Number NC0003425
Allen Steam Station NPDES Permit Number NC0004979
Belews Creek Steam Station NPDES Permit Number NCO024406
Marshall Steam Station NPDES Permit Number NC0004987
Rogers Energy Complex NPDES Permit Number NC 0005088
NPDES Permit Application Amendments
Dear Ms. Grzyb,
Duke Energy Progress, LLC and Duke Energy Carolinas, LLC ( hereinafter collectively referred
to as "Duke Energy") hereby amends the existing and pending NPDES Permit applications for
the subject facilities to add two additional freeze conditioning agents to the lists of chemicals that
may be present in discharges.
These facilities expect to receive shipments of coal treated with freeze conditioning agents
during the winter months (November 1 through March 31). Freeze conditioning agents use will
be based upon expected weather conditions during transport to ensure coal does not freeze in
railcars and will be applied at an approximate rate of 2-4 pints per ton of coal. The product
names used by the various coal mines which supply fuel to Duke Energy power plants could
include one or more of the additional following products (SDSs enclosed):
Product Name Primary Composition
FCA 100 Water, distilled water, deionized water (65-72%)
Inhibited Calcium Chloride (28-35%)
FCA 207 Water, distilled water, deionized water (60-90%)
Propylene Glycol (5-10%)
Inhibited Calcium Chloride (25-50%)
Coal pile runoff at each of these facilities flows to a treatment system (e.g., ash pond, cooling
pond, coal pile runoff settling basin). However, since there is a slight potential that these
chemicals could be present in the wastewater that is ultimately discharged via a permitted outfall,

Duke Energy requests that these products be appended to the NPDES permit applications. Note
that toxicity testing is a permit requirement at each power plant outfall which contains the coal
pile runoff flow.
Duke Energy appreciates the continued cooperation demonstrated by the Division of Water
Resources staff in responding to its permitting needs. If you have any questions or comments
regarding this information, please contact Shannon Langley at [phone].
I certify, under penalty of law, that this document and all attachments were prepared under my direction
or supervision in accordance with a system designed to assure that qualified personnel properly gather
and evaluate the information submitted Based on my enquiry of the person or persons who manage the
system, or those persons directly responsible for gathering the information, the information submitted is,
to the best of my knowledge and belief, true, accurate, and complete I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment
for knowing violations
Sin erely,
Paul D ovitch, Senior Vice President
Environmental, Health & Safety
Enclosures
PD/sl
cc: Anne Pifer/Filenet
Shannon Langley —NC15
Teresa Williams — Asheville Plant
Bert Lea — Mayo Plant
Robert Howard — Roxboro Plant
Michael Gantt - Allen Station
Keeley McCormick — Belews Creek Station
Scott La Sala — Marshall Station
Steve Hodges — Rogers Energy Complex
Tina Woodward — EC 13
Lori Tollie — Fairfax Ops
Joyce Dishmon — Dan River Combined Cycle
Robert Wylie — EC 13
Brad Loveland —EC 13

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015
Product Identifier
Trade name: FCA -100
Relevant identified uses of the substance or mixture and uses advised against.
Used to improve handling of bulk solids in winter
Product Description Anti -Freeze Agent
Page 1/7
Reviewed on 10/06/2015
Details of the Supplier of the Safety Data Sheet: Rr�CIeED/��UD���
Man ufac turer/Supplier.
Eco Solution Distributing Ilc
124 Lintel Drive OCT 1, 9 2017
McMurray, PA 15317
Telephone [phone] wfva°'�t
Emergency telephone number: PC,rmi`"irig Section
Chemtrec 800-424-9300
1 D #CCN794695
Classification of the substance or mixture:
' I GHS07
Eye Irnt 2A H319 Causes serious eye irritation
Label elements:
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms:
GHS07
Signal word: Warning
Hazard statements:
Causes serious eye irritation
Precautionary statements:
Wear eye protection / face protection
Wash thoroughly after handling
If in eyes Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do
Continue rinsing
If eye irritation persists Get medical advice/attention
Classification system:
NFPA ratings (scale 0 - 4)
Health = 1
Fire = 0
Reactivity = 0
(Contd on page 2)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015
Trade name: FCA -100
HMIS-ratings (scale 0 - 4)
Health = 1
K° Fire = 0
REACTIVITY]O Reactivity= 0
Page 217
Reviewed on 10/06/2015
Hazard(s) not otherwise classified (HNOC): None known
" @lam flkts�a Cog)
7732-18-5 i Water, distilled water, deionized water 65-72%
Chemical characterization: Mixtures
Description: Mixture consisting of the following components
Dangerous Components:
CAS 10043-52-4__ Inhibited Calcium Chloride- < Eye Irnt 2, H319 28-35%!
RTECS EV 9800000
* z;- %=c
Description of first aid measures:
After inhalation: Supply fresh air, consult doctor in case of complaints
After skin contact:
Generally the product does not irritate the skin
Wash with soap and water
After eye contact:
Rinse opened eye for at least 15 minutes under running water If symptoms persist, consult a doctor
After swallowing: If swallowed and symptoms occur, consult a doctor
Information for doctor:
Most important symptoms and effects, both acute and delayed: No further relevant information available
Indication of any immediate medical attention and special treatment needed:
No further relevant information available
Extinguishing media:
Suitable extinguishing agents: Use fire fighting measures that suit the environment
Special hazards arising from the substance or mixture: No further relevant information available
Advice for firefighters:
Protective equipment:
As in any fire, wear self-contained breathing apparatus pressure -demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes
Personal precautions, protective equipment and emergency procedures: Not required
Environmental precautions:
Dilute with plenty of water
Do not allow to enter sewers/ surface or ground water
Methods and material for containment and cleaning up:
Absorb with liquid -binding material (i a sand, diatomite, acid binders, universal binders, sawdust)
Ensure adequate ventilation
Dispose of the collected material according to regulations
Reference to other sections:
See Section 7 for information on safe handling
(Contd on page 3)

Page 3/7
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015 Reviewed on 10/06/2015
Trade name: FCA -100
See Section 8 for information on personal protection equipment
See Section 13 for disposal information
Handling
Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace
Prevent formation of aerosols
Information about protection against explosions and fires: No special measures required
Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles: No special requirements
Information about storage in one common storage facility: Not required
Further information about storage conditions: No further relevant information available
Specific end use(s): No further relevant information available
Additional information about design of technical systems: No further data, see section 7
Control parameters:
Components with occupational exposure limits:
The product does not contain any relevant quantities of materials with critical values that have to be monitored
at the workplace
Additional information: The lists that were valid during the creation of this SDS were used as basis
Exposure controls:
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed
Keep away from foodstuffs, beverages and feed
Immediately remove all soiled and contaminated clothing and wash before reuse
Wash hands before breaks and at the end of work
Avoid contact with the eyes
Avoid contact with the eyes and skin
Breathing equipment: Not required
Protection of hands: Not required
Material of gloves: Not required
Penetration time of glove material: Not applicable
Information on basic physical and chemical properties
General Information
Appearance:
Form:
Liquid
Color:
straw-colored
Odor:
Odorless
Odor threshold:
Not determined
Change in condition
Melting point/Melting range:
Not determined
Boiling point/Boiling range:
100 °C (212 °F)
(Contd on page 4)

Page 4/7
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015
Trade name: FCA -100
Flash point:
Flammability (solid, gaseous):
Ignition temperature:
Decomposition temperature:
Auto igniting:
Danger of explosion:
Explosion limits:
Lower:
Upper:
Vapor pressure @ 20 °C (68 °F):
Density:
Relative density:
Vapor density:
Evaporation rate:
Solubility in / Miscibility with:
Reviewed on 10/06/2015
100 °C (212 °F)
Not applicable
0 °C (32 °F)
Not determined
Product is not self-igniting
Product does not present an explosion hazard
00Vol %
00Vol %
23 hPa (17 mm Hg)
Not determined
Not determined
Not determined
Water: Fully miscible
Partition coefficient (n-octanol/water): Not determined
Viscosity:
Dynamic:
Kinematic:
Not determined
Not determined
Solvent content:
Organic solvents: 00%
Water: 690%
Other information: No further relevant information available
Reactivity: No further relevant information available
Chemical stability: Stable under normal conditions
Thermal decomposition /conditions to be avoided: No decomposition if used according to specifications
Possibility of hazardous reactions: No dangerous reactions known
Conditions to avoid: No further relevant information available
Incompatible materials: No further relevant information available
Hazardous decomposition products: No dangerous decomposition products known
ait t
Information on toxicological effects:
Acute toxicity:
LD/L650 values that are relevant for classification:
r 10043-5241nhi61ted Calcium Chloride
Oral- I -b50 -2301 mg/kg (rat)
- - - -- -- --- -- - - - -- - - - -- - -
Primary irritant effect: -- -
On the skin: No irritating effect
On the eye: Irritating effect
(Contd on page 5)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015
Trade name: FCA -100
Page 5/7
Reviewed on 10/06/2015
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations
Irritant
Carcinogenic categories:
IARC (International Agency for Research on Cancer): - -
None of the ingredients are listed
NTP (National Toxicology Program):
-- Na- ---- -
---- - ---------liste---- - -- - -- -- - - - - -- -- - - - - - - - - - -,
None oft ingredients are d
OSHA -Ca (Occupational Safety & Health Administration): _
None of the ingredients are listed
EJ
Toxicity:
Aquatic toxicity: -
f0043-52-4lnhiblted Calcium Chloride
ECbO , 2400 mg%I (Water flea) _ -
Persistence and degradability: No further relevant information available
Behavior in environmental systems:
Bioaccumulative potential: No further relevant information available
Mobility in soil: No further relevant information available
Additional ecological information:
General notes:
Do not allow undiluted product or product that has not been neutralized to reach ground water, water course
or sewage system
Results of PBT and vPvB assessment:
PBT: Not applicable
vPvB: Not applicable
Other adverse effects: No further relevant information available
Waste treatment methods:
Recommendation: Recycle or dispose with household trash
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations
Recommended cleansing agent: Water, if necessary with cleansing agents
UN -Number:
DOT, ADR, ADN, IMDG, IATA
UN proper shipping name:
DOT, ADR, ADN, IMDG, IATA
Transport hazard class(es):
DOT, ADR, ADN, IMDG, IATA
Class:
Packing group:
DOT, ADR, IMDG, IATA
Non -Regulated Material
Non -Regulated Material
Non -Regulated Material
Non -Regulated Material
(Contd on page 6)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015
Trade name: FCA -100
Environmental hazards: Not applicable
Special precautions for user: Not applicable
Transport in bulk according to Annex 11 of
MARPOL73178 and the IBC Code: Not applicable
UN "Model Regulation": Non -Regulated Material
Page 6/7
Reviewed on 10106/2015
Safety, health and environmental regulations/legislation specific for the substance or mixture:
SARA (Superfund Amendments and Reauthorization):
Section 355 (extremely hazardous substances):
None of the ingredients are listed
Section 313 (Specific toxic chemical listings):
None of the ingredients are listed
TSCA (Toxic Substances Control Act):
10043-52-4 Inhibited Calcium Chloride
7732-18-5 Water, distilled water, deionized water
California Proposition 65:
Chemicals known to cause cancer:
None of the ingredients are listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed
Chemicals known to cause developmental toxicity:
None of the ingredients are listed
Carcinogenic categories:
EPA (Environmental Protection Agency):
None of the ingredients are listed
TLV (Threshold Limit Value established by ACGIH):
None of the ingredients are listed
NIOSH -Ca (National Institute for Occupational Safety and Health):
None of the ingredients are listed
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms:
GHS07
Signal word: Warning
Hazard statements:
Causes serious eye irritation
(Contd on page 7)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/06/2015
Trade name: FCA -100
Page 7/7
Reviewed on 10/06/2015
Precautionary statements:
Wear eye protection / face protection
Wash thoroughly after handling
If in eyes Rinse cautiously with water for several minutes Remove contact lenses, If present and easy to do
Continue rinsing
If eye irritation persists Get medical advice/attention
National regulations:
The product is subject to be classified according with the latest version of the regulations on hazardous
substances
State Right to Know:
CAS 7732-18-5 Water, distilled water, deionized water
CAS 10043-52-4 Inhibited Calcium Chloride
RTECS EV 9800000
Corrosion Inhibitor
All Ingredients are listed
65-72%
Eye Irrit 2, H319 28-35%
<25%
Chemical safety assessment: A Chemical Safety Assessment has not been carried out
The information and recommendations In this safety data sheet are, to the best of our knowledge, accurate as
of the date of Issue Nothing herein shall be deemed to create warranty, expressed or Implied, and shall not
establish a legally valid contractual relationship It Is the responsibility of the user to determine applicability of
this information and the suitability of the material or product for any particular purpose
Date of preparation /last revision: 10/06/2015 / 2
Abbreviations and acronyms:
ADR The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG International Maritime Code for Dangerous Goods
DOT US Department of Transportation
IATA International Air Transport Association
ACGIH American Conference of Governmental Industrial Hygienists
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
CAS Chemical Abstracts Service (division of the American Chemical Society)
NFPA National Fire Protection Association (USA)
HMIS Hazardous Materials Identification System (USA)
LC50 Lethal concentration, 50 percent
LD50 Lethal dose, 50 percent
PBT Persistent, Bioaccumulative and Toxic
vPvB very Persistent and very Bioaccumulative
Eye Irrit 2 Serious eye damage/eye irritation, Hazard Category 2
Eye Irrit 2A Serious eye damage/eye irritation, Hazard Category 2A
* Data compared to the previous version altered.
SDS created by MSDS Authoring Services www msdsauthoring com [phone]

E
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Product Identifier
Trade name: FCA -207
Relevant identified uses of the substance or mixture and uses advised against:
Used to improve handling of bulk solids in winter
Product Description Anti -Freeze Agent
Details of the Supplier of the Safety Data Sheet:
Man ufac turer/Supplier:
Eco Solution Distributing Ilc
124 Lintel Drive
McMurray, PA 15317
Telephone [phone]
Emergency telephone number:
Chemtrec 800-424-9300
1 D #CCN794695
Page 1/8
Reviewed on 10/07/2015
RECEDED,/NIC,I)E CtI WR
Classification of the substance or mixture:
GHS07
Eye Irrit 2A H319 Causes serious eye irritation
Label elements:
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms:
�o
GHS07
OCT 19 2017
Water Quality
Permitting Sec(ior�
Signal word: Warning
Hazard statements:
Causes serious eye irritation
Precautionary statements
Wear eye protection / face protection
Wash thoroughly after handling
If in eyes Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do
Continue rinsing
If eye irritation persists Get medical advice/attention
Classification system:
NFPA ratings (scale 0 - 4)
Health = 1
'0>Fire = 0
Reactivity= 0
(Contd on page 2)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
HMIS-ratings (scale 0 - 4)
' Health = 1
`a'- 0 Fire= 0
REACTIVITY ❑0 Reactivity = 0
Page 218
Reviewed on 10/07/2015
Hazard(s) not otherwise classified (HNOC): None known
7732-18-5 Water, distilled water, deionized water 160-90%
Chemical characterization: Mixtures
Description: Mixture consisting of the following components
Dangerous Components:
CAS 57-55-6 ^Propylene GlycolSkrn Irnt 2, H315, Eye Irnt 2B, H320 5-10%
RTECS TY 2000000,
-- -- - 0 4_3 — —---------- - ----- < Y ---- ----- - - --- — — - - -- - %--
CAS 10043-52-4 Inhibited Calcium Chlonde E e Irnt 2, H319 25-50%
RTECS EV 9800000,
Description of first aid measures:
After inhalation: Supply fresh air, consult doctor in case of complaints
After skin contact: Wash with soap and water
After eye contact:
Rinse opened eye for at least 15 minutes under running water If symptoms persist, consult a doctor
After swallowing:
Drink copious amounts of water and provide fresh air Immediately call a doctor
Induce vomiting and call for medical help
Information for doctor:
Most important symptoms and effects, both acute and delayed: No further relevant information available
Indication of any immediate medical attention and special treatment needed:
No further relevant information available
Extinguishing media:
Suitable extinguishing agents:
CO,, extinguishing powder or water spray Fight larger fires with water spray or alcohol resistant foam
Special hazards arising from the substance or mixture: No further relevant information available
Advice for firefighters:
Protective equipment:
As in any fire, wear self-contained breathing apparatus pressure -demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes
Personal precautions, protective equipment and emergency procedures: Not required
Environmental precautions:
Dilute with plenty of water
Do not allow to enter sewers/ surface or ground water
Methods and material for containment and cleaning up:
Absorb with liquid -binding material (i a sand, diatomite, acid binders, universal binders, sawdust)
Ensure adequate ventilation
(Contd on page 3)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
Dispose of the collected material according to regulations
Reference to other sections:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment
See Section 13 for disposal information
Page 3/8
Reviewed on 10/07/2015
Handling
Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace
Prevent formation of aerosols
Information about protection against explosions and fires: No special measures required
Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles: No special requirements
Information about storage in one common storage facility: Not required
Further information about storage conditions: No further relevant information available
Specific end use(s): No further relevant information available
-
Additional information about design of technical systems: No further data, see section 7
Control parameters:
Components with occupational exposure limits:
- - - - - -- -- -- -- - -------- ---------
57-55-6 Propylene Glycol
--- - --- -- -- --- --- -- - J o Mg/ --- -- - - - - -- -- - -- - _ - - - -
WEEL Long-term value 10 mg/m'
Additional information: The lists that -were valid during the creation of this SDS were used as basis
Exposure controls:
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed
Keep away from foodstuffs, beverages and feed
Immediately remove all soiled and contaminated clothing and wash before reuse
Wash hands before breaks and at the end of work
Avoid contact with the eyes
Avoid contact with the eyes and skin
Breathing equipment: Not required
Protection of hands: Not required
Material of gloves: Not required
Penetration time of glove material: Not applicable
Eye protection:
0 o Tightly sealed goggles
(Contd on page 4)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
Page 4/8
Reviewed on 10/07/2015
10 69D A 0_1 + 1° a _ -
�x
Information on basic physical and chemical properties
General Information
Appearance:
Form:
Liquid
Color:
straw-colored
Odor:
Odorless
Odor threshold:
Not determined
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Flash point:
Flammability (solid, gaseous):
Ignition temperature:
Decomposition temperature:
Auto igniting:
Danger of explosion:
Explosion limits:
Lower:
Upper:
Vapor pressure @ 20 °C (68 °F):
Density:
Relative density:
Vapor density:
Evaporation rate:
Solubility in / Miscibility with:
Water:
Not determined
100 °C (212 °F)
None
Not applicable
0 °C (32 °F)
Not determined
Product is not self-igniting
Product does not present an explosion hazard
00Vol %
00Vol %
23 hPa (17 mm Hg)
Not determined
Not determined
Not determined
Fully miscible
Partition coefficient (n-octanol/water): Not determined
Viscosity:
Dynamic:
Kinematic:
Solvent content:
Organic solvents:
Water:
Solids content:
Other information:
Not determined
Not determined
00%
650%
280%
No further relevant information available
Reactivity: No further relevant information available
Chemical stability: Stable under normal conditions
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications
Possibility of hazardous reactions: No dangerous reactions known
Conditions to avoid: No further relevant information available
(Contd on page 5)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
Page 5/8
Reviewed on 10/07/2015
Incompatible materials: No further relevant information available
Hazardous decomposition products: No dangerous decomposition products known
Information on toxicological effects:
Acute toxicity:
L511050 values that are relevant for classification:
57-55-6 Propylene Glycol - -
Oral LD50 20000 mg/kg (rat)
Dermal LD50 20800 mg/kg (rabbit)
Inhalative LC50/96 hours, 52930 mg/I (Pimephales)
Intravenous 6630 mg/kg (mouse)
6423 mg/kg (rat)
6500 mg/kg (rabbit)
Primary irritant -effect: - -
On the skin: No irritating effect
On the eye: Irritating effect
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations
Irritant
Carcinogenic categories:
IARC (International Agency forR-esearch on Cancer):
None of the ingredients are listed — - —
NTP (National Toxicology Program): -
None of the ingredients are listed
OSHA -Ca (Occupational Safety & Health Administration):
__—None of the ingredients are fisted -- - _ - - - - - - - _ - _-_- -_ _ _ - --I
Toxicity:
Aquatic toxicity:
57-55-6 Propylene Glycol
T Persistence and degradability: No further relevant information available
Behavior in environmental systems:
Bioaccumulative potential: No further relevant information available
Mobility in soil: No further relevant information available
Additional ecological information:
General notes:
Do not allow undiluted product or product that has not been neutralized to reach ground water, water course
or sewage system
Results of PBT and vPvB assessment:
PBT: Not applicable
vPvB: Not applicable
(Contd on page 6)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
Other adverse effects: No further relevant information available
Waste treatment methods:
Recommendation: Recycle or dispose with household trash
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations
Recommended cleansing agent: Water, if necessary with cleansing agents
UN -Number:
DOT, ADR, ADN, IMDG, IATA Non -Regulated Material
UN proper shipping name:
DOT, ADR, ADN, IMDG, IATA Non -Regulated Material
Transport hazard class(es):
DOT, ADR, ADN, IMDG, IATA
Class: Non -Regulated Material
Packing group:
DOT, ADR, IMDG, IATA Non -Regulated Material
Environmental hazards: Not applicable
Special precautions for user: Not applicable
Transport in bulk according to Annex H of
MARPOL73178 and the IBC Code: Not applicable
UN "Model Regulation": Non -Regulated Material
Page 6/8
Reviewed on 10107/2015
Safety, health and environmental regulations/legislation specific for the substance or mixture:
SARA (Superfund Amendments and Reauthorization):
- Section 355 (extremely hazardous substances):
- e Nonof the ingredients are listed _
Section 313 (Specific toxic chemical listings):
—_ -- _-_- _ -__-_ .- -__- --_
- None of the ingredients are listed
TSCA (Toxic Substances Control Act): -
10043-52-4 Calcium Chloride-�
7732-18-5 ' Water, distilled water, deionized water
-- -- - - - - - - - --- -- --- - -- -- - -
California Proposition- 65: -
- -Chemicals- - known --to --cause- --- ----cancer-- --:- ---- - ------- -- -- - --- — - - -- --- -- - - - - -
None of the ingredients are listed
Chemicals known to cause reproductive toxicity for females: T
None of the ingredients are listed-- -
Chemicals known to cause reproductive toxicity for males:
_N -- -- --- - 9 - - -a --------- -- — -- — -- ---- -- -- - -- - - — - -
one of the in redients re listed
Chemicals known to cause developmental toxicity:
None of the ingredients are listed
(Contd on page 7)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
Carcinogenic categories:
EPA (Environmental Protection Agency):
None of the Ingredients are listed
TLV (Threshold Limit Value established by ACGIH):
None of the Ingredients are listed
NIOSH -Ca (National Institute for Occupational Safety and Health):
None of the Ingredients are listed
Page 7/8
Reviewed on 10/07/2015
GHS label elements
The product Is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms:
1
GHS07
Signal word: Warning
Hazard statements:
Causes serious eye Irritation
Precautionary statements:
Wear eye protection / face protection
Wash thoroughly after handling
If in eyes Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do
Continue rinsing
If eye irritation persists Get medical advice/attention
National regulations:
The product is subject to be classified according with the latest version of the regulations on hazardous
substances
State Right to Know:
CAS 7732-18-5 Water, distilled water, deionized water 60-90%
CAS 10043-52-4 Inhibited Calcium Chloride 25-50%
RTECS EV 9800000 , Eye Irrit 2, H319
CAS 57-55-6 Propylene Glycol 5-10%
RTECS TY 2000000 , Skin Irrit 2, H315, Eye Irrit 2B, H320
All ingredients are listed
Chemical safety assessment: A Chemical Safety Assessment has not been carried out
The Information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as
of the date of Issue Nothing herein shall be deemed to create warranty, expressed or Implied, and shall not
establish a legally valid contractual relationship It Is the responsibility of the user to determine applicability of
this Information and the suitability of the material or product for any particular purpose
Date of preparation / last revision: 10/07/2015 13
Abbreviations and acronyms:
ADR The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG International Maritime Code for Dangerous Goods
DOT US Department of Transportation
IATA International Air Transport Association
(Contd on page 8)

Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03
Issue date 10/07/2015
Trade name: FCA -207
ACGIH American Conference of Governmental Industrial Hygienists
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
CAS Chemical Abstracts Service (division of the American Chemical Society)
NFPA National Fire Protection Association (USA)
HMIS Hazardous Materials Identification System (USA)
LC50 Lethal concentration, 50 percent
LD50 Lethal dose, 50 percent
PBT Persistent, Bioaccumulative and Toxic
vPvB very Persistent and very Bioaccumulative
Skin Irrit 2 Skin corrosion/irritation, Hazard Category 2
Eye Irrit 2 Serious eye damage/eye irritation, Hazard Category 2
Eye Irrit 2A Serious eye damage/eye irritation, Hazard Category 2A
Eye Irrit 2B Serious eye damage/eye irritation, Hazard Category 2B
Page 8/8
Reviewed on 10/07/2015
* Data compared to the previous version altered.
SDS created by MSDS Authoring Services www msdsauthonng com [phone]