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HomeMy WebLinkAboutNC0003425_Amend Exisitng/Pending Permit Application_20171017It (> DUKE ENERGY October 17, 2017 Paul Draovitch, P E Senor Vice President Environmental, Health & Safety 526 S Church Street Mad Code EC3XP Charlotte, NC 28202 (704)382-4303 Ms. Julie Grzyb, Supervisor RECEIVED/NNE Complex NPDES permitting Unit c�DwR Division of Water Resources O C j 19 2017 1617 Mail Service Center Raleigh, NC 27699-1617 Water Quality Permitting Section Subject: Duke Energy Progress, LLC and Duke Energy Carolinas, LLC. Asheville Steam Electric Plant NPDES Permit Number NC0000396 Mayo Steam Electric Plant NPDES Permit Number NCO038377 Roxboro Steam Electric Plant NPDES Permit Number NC0003425 Allen Steam Station NPDES Permit Number NC0004979 Belews Creek Steam Station NPDES Permit Number NCO024406 Marshall Steam Station NPDES Permit Number NC0004987 Rogers Energy Complex NPDES Permit Number NC 0005088 NPDES Permit Application Amendments Dear Ms. Grzyb, Duke Energy Progress, LLC and Duke Energy Carolinas, LLC ( hereinafter collectively referred to as "Duke Energy") hereby amends the existing and pending NPDES Permit applications for the subject facilities to add two additional freeze conditioning agents to the lists of chemicals that may be present in discharges. These facilities expect to receive shipments of coal treated with freeze conditioning agents during the winter months (November 1 through March 31). Freeze conditioning agents use will be based upon expected weather conditions during transport to ensure coal does not freeze in railcars and will be applied at an approximate rate of 2-4 pints per ton of coal. The product names used by the various coal mines which supply fuel to Duke Energy power plants could include one or more of the additional following products (SDSs enclosed): Product Name Primary Composition FCA 100 Water, distilled water, deiomzed water (65-72%) Inhibited Calcium Chloride (28-35%) FCA 207 Water, distilled water, deionized water (60-90%) Propylene Glycol (5-10%) Inhibited Calcium Chloride (25-50%) Coal pile runoff at each of these facilities flows to a treatment system (e.g., ash pond, cooling pond, coal pile runoff settling basin). However, since there is a slight potential that these chemicals could be present in the wastewater that is ultimately discharged via a permitted outfall, Duke Energy requests that these products be appended to the NPDES permit applications. Note that toxicity testing is a permit requirement at each power plant outfall which contains the coal pile runoff flow. Duke Energy appreciates the continued cooperation demonstrated by the Division of Water Resources staff in responding to its permitting needs. If you have any questions or comments regarding this information, please contact Shannon Langley at (919) 546-2439. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations Sin erely, Paul D ovitch, Senior Vice President Environmental, Health & Safety Enclosures PD/sl cc: Anne Pifer/Filenet Shannon Langley —NC15 Teresa Williams — Asheville Plant Bert Lea — Mayo Plant Robert Howard — Roxboro Plant Michael Gantt - Allen Station Keeley McCormick — Belews Creek Station Scott La Sala — Marshall Station Steve Hodges — Rogers Energy Complex Tina Woodward — EC 13 Lori Tollie — Fairfax Ops Joyce Dishmon — Dan River Combined Cycle Robert Wylie — EC 13 Brad Loveland —EC 13 Page 1/7 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/06/2015 Reviewed on 10/06/2015 Product Identifier Trade name: FCA -100 Relevant identified uses of the substance or mixture and uses advised against: Used to improve handling of bulk solids in winter Product Description Anti -Freeze Agent Details of the Supplier of the Safety Data Sheet: RECEIVEOIIJCDEWWR Man ufac turer/Supplier: Eco Solution Distributing Ilc 124 Lintel Drive OCT 19 2017 McMurray, PA 15317 Telephone (724) 941-4140 `3r Quality Emergency telephone number. Permitt,ng Section Chemtrec 800-424-9300 1 D #CCN794695 Classification of the substance or mixture: GHS07 Eye Irrit 2A H319 Causes serious eye irritation Label elements. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS) Hazard pictograms: GHS07 Signal word: Warning Hazard statements: Causes serious eye irritation Precautionary statements: Wear eye protection / face protection Wash thoroughly after handling If in eyes Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do Continue rinsing If eye irritation persists Get medical advice/attention Classification system: NFPA ratings (scale 0 - 4) *14 Health = 1 Fire = 0 Reactivity = 0 (Contd on page 2) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/06/2015 Trade name: FCA -100 HMIS-ratings (scale 0 - 4) :00111. 1 Health = 1 F W= D' Fire= 0 REACTIVITY Reactivity = 0 Page 217 Reviewed on 10/06/2015 Hazard(s) not otherwise classified (HNOC): None known 7732-18-5 C Water, distilled water, deionized water 65-72% Chemical characterization: Mixtures Description: Mixture consisting of the following components Dangerous Components: _ CAS 10043-52-4 Inhibited Calcium Chloride ______u I ! Eye Irrit _2__,H_3_1_9_ 28-35% ; RTECS EV 9800000 Description of first aid measures: After inhalation: Supply fresh air, consult doctor in case of complaints After skin contact: Generally the product does not irritate the skin Wash with soap and water After eye contact: Rinse opened eye for at least 15 minutes under running water If symptoms persist, consult a doctor After swallowing: If swallowed and symptoms occur, consult a doctor Information for doctor: Most important symptoms and effects, both acute and delayed: No further relevant information available Indication of any immediate medical attention and special treatment needed: No further relevant information available Extinguishing media: Suitable extinguishing agents: Use fire fighting measures that suit the environment Special hazards arising from the substance or mixture: No further relevant information available Advice for firefighters: Protective equipment: As in any fire, wear self-contained breathing apparatus pressure -demand (NIOSH approved or equivalent) and full protective gear to prevent contact with skin and eyes Personal precautions, protective equipment and emergency procedures: Not required Environmental precautions: Dilute with plenty of water Do not allow to enter sewers/ surface or ground water Methods and material for containment and cleaning up: Absorb with liquid -binding material (i a sand, diatomite, acid binders, universal binders, sawdust) Ensure adequate ventilation Dispose of the collected material according to regulations Reference to other sections: See Section 7 for information on safe handling (Contd on page 3) Page 3/7 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/06/2015 Reviewed on 10/06/2015 Trade name: FCA -100 See Section 8 for information on personal protection equipment See Section 13 for disposal information rmac., i ",u Handling Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace Prevent formation of aerosols Information about protection against explosions and fires: No special measures required Conditions for safe storage, including any incompatibilities: Storage Requirements to be met by storerooms and receptacles: No special requirements Information about storage in one common storage facility: Not required Further information about storage conditions: No further relevant information available Specific end use(s): No further relevant information available ab Additional information about design of technical systems: No further data, see section 7 Control parameters: Components with occupational exposure limits: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace Additional information: The lists that were valid during the creation of this SDS were used as basis Exposure controls: Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed Keep away from foodstuffs, beverages and feed Immediately remove all soiled and contaminated clothing and wash before reuse Wash hands before breaks and at the end of work Avoid contact with the eyes Avoid contact with the eyes and skin Breathing equipment: Not required Protection of hands: Not required Material of gloves: Not required Penetration time of glove material: Not applicable Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: straw-colored Odor: Odorless Odor threshold: Not determined Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: 100 °C (212 °F) (Contd on page 4) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/06/2015 Trade name: FCA -100 Flash point: Flammability (solid, gaseous): Ignition temperature: Decomposition temperature: Auto igniting: Danger of explosion: Explosion limits: Lower: Upper: Vapor pressure @ 20 °C (68 °F): Density: Relative density: Vapor density: Evaporation rate: Solubility in / Miscibility with: Page 4/7 Reviewed on 10/06/2015 100 °C (212 °F) Not applicable 0 °C (32 °F) Not determined Product is not self-igniting Product does not present an explosion hazard 00Vol % 00Vol % 23 hPa (17 mm Hg) Not determined Not determined Not determined Water: Fully miscible Partition coefficient (n-octanol/water): Not determined Viscosity: Dynamic: Kinematic: Not determined Not determined Solvent content: Organic solvents: 00% Water: 690% Other information: No further relevant information available ry Reactivity: No further relevant information available Chemical stability: Stable under normal conditions Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Possibility of hazardous reactions: No dangerous reactions known Conditions to avoid: No further relevant information available Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known Information on toxicological effects: Acute toxicity: - -- - - ---------------- - --- ---- - - LD/LC50 values that are relevant for classification: 10043-52-4 Inhibited Calcium Chloride Oral LD50 -2301 mg%kg (rat) Primary irritant effect: T On the skin: No irritating effect On the eye: Irritating effect (Contd on page 5) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(8) and GHS Rev 03 Issue date 10/06/2015 Trade name: FCA -100 Page 517 Reviewed on 10/0612015 Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations Irritant Carcinogenic categories: IARC (InternationalAgency for Research on Cancer): None of the ingredients are listed NTP (National Toxicology Program): None of the ingredients are listed - - - - -- - - - - -- -- - - - - - - OSHA -Ca (Occupational Safety & Health Administration): None of the ingredients are listed Toxicity: - - - - - - - - - - - - - - - - - - Aquatic toxicity: 10043-52-4 Inhibited Calcium Chloride- _E656_2400 hloride—EC502400 mg/I (Water flea) Persistence and degradability: No further relevant information available - - - - Behavior in environmental systems: Bioaccumulative potential: No further relevant information available Mobility in soil: No further relevant information available Additional ecological information: General notes: Do not allow undiluted product or product that has not been neutralized to reach ground water, water course or sewage system Results of PBT and vPvB assessment: PBT: Not applicable vPvB: Not applicable Other adverse effects: No further relevant information available Waste treatment methods: Recommendation: Recycle or dispose with household trash Uncleaned packagings: Recommendation: Disposal must be made according to official regulations Recommended cleansing agent: Water, if necessary with cleansing agents ,:,;°Lia UN -Number: DOT, ADR, ADN, IMDG, IATA UN proper shipping name: DOT, ADR, ADN, IMDG, IATA Transport hazard class(es): DOT, ADR, ADN, IMDG, IATA Class: Packing group: DOT, ADR, IMDG, IATA Non -Regulated Material Non -Regulated Material Non -Regulated Material Non -Regulated Material (Contd on page 6) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/06/2015 Trade name: FCA -100 Environmental hazards: Not applicable Special precautions for user: Not applicable Transport in bulk according to Annex 11 of MARPOL73178 and the IBC Code: Not applicable UN "Model Regulation": Non -Regulated Material Page 6/7 Reviewed on 10/06/2015 Safety, health and environmental regulations/legislation specific for the substance or mixture: SARA (Superfund Amendments and Reauthorization): Section 355 (extremely hazardous substances): None of the ingredients are listed Section 313 (Specific toxic chemical listings): None of the ingredients are listed TSCA (Toxic Substances Control Act): 10043-52-4 Inhibited Calcium Chloride 7732-18-5 Water, distilled water, deionized water California Proposition 65: Chemicals known to cause cancer: None of the ingredients are listed Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed Chemicals known to cause developmental toxicity: None of the ingredients are listed Carcinogenic categories: EPA (Environmental Protection Agency): None of the ingredients are listed TLV (Threshold Limit Value established by ACGIH): None of the ingredients are listed NIOSH -Ca (National Institute for Occupational Safety and Health): None of the ingredients are listed GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS) Hazard pictograms: GHS07 Signal word: Warning Hazard statements: Causes serious eye irritation (Contd on page 7) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/06/2015 Trade name: FCA -100 Page 7/7 Reviewed on 10/06/2015 Precautionary statements: Wear eye protection / face protection Wash thoroughly after handling If in eyes Rinse cautiously with water for several minutes Remove contact lenses, If present and easy to do Continue rinsing If eye irritation persists Get medical advice/attention National regulations: The product is subject to be classified according with the latest version of the regulations on hazardous substances State Right to Know: CAS 7732-18-5 Water, distilled water, deionized water CAS 10043-52-4 Inhibited Calcium Chloride RTECS EV 9800000 Corrosion Inhibitor All Ingredients are listed 65-72% Eye Irrit 2, H319 28-35% <25% Chemical safety assessment. A Chemical Safety Assessment has not been carried out The Information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of Issue Nothing herein shall be deemed to create warranty, expressed or implied, and shall not establish a legally valid contractual relationship It is the responsibility of the user to determine applicability of this Information and the suitability of the material or product for any particular purpose Date of preparation /last revision: 10/06/2015 / 2 Abbreviations and acronyms: ADR The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG International Maritime Code for Dangerous Goods DOT US Department of Transportation IATA International Air Transport Association ACGIH American Conference of Governmental Industrial Hygienists EINECS European Inventory of Existing Commercial Chemical Substances ELINCS European List of Notified Chemical Substances CAS Chemical Abstracts Service (division of the American Chemical Society) NFPA National Fire Protection Association (USA) HMIS Hazardous Materials Identification System (USA) LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent PBT Persistent, Bioaccumulative and Toxic vPvB very Persistent and very Bioaccumulative Eye Irnt 2 Serious eye damage/eye irritation, Hazard Category 2 Eye Irnt 2A Serious eye damage/eye irritation, Hazard Category 2A * Data compared to the previous version altered. SDS created by MSDS Authoring Services www msdsauthoring com +1-877-204-9106 0 Page 1/8 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03, Issue date 10/07/2015 Reviewed on 10/07/2015 Product Identifier Trade name: FCA -207 Relevant identified uses of the substance or mixture and uses advised against: Used to improve handling of bulk solids in winter Product Description Anti -Freeze Agent Details of the Supplier of the Safety Data Sheet: Manufacturer/Supplier: Eco Solution Distributing Ilc 124 Lintel Drive McMurray, PA 15317 Telephone (724) 941-4140 Emergency telephone number: Chemtrec 800-424-9300 1 D #CCN794695 RECEIVED, NICD UDWR OCT 19 2017 watur Qtuailiv Permitting SeCison I Classification of the substance or mixture: GHS07 Eye �Irrit 2A H319 Causes serious eye irritation Label elements: GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS) Hazard pictograms: GHS07 Signal word: Warning Hazard statements: Causes serious eye irritation Precautionary statements: Wear eye protection / face protection Wash thoroughly after handling If in eyes Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do Continue rinsing If eye irritation persists Get medical advice/attention Classification system: NFPA ratings (scale 0 - 4) 414 Health = 1 Fire = 0 Reactivity = 0 (Contd , on page 2) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 HMIS-ratings (scale 0 - 4) ' I Health = 1 F',' -E 01 Fire = 0 REACTIVITYKO Reactivity = 0 Page 2/8 Reviewed on 10/07/2015 Hazard(s) not otherwise classified (HNOC): None known 7732-18-5 ; Water, distilledwater, deionized water 60-90% ' Chemical characterization: Mixtures Description: Mixture consisting of the following components Dangerous Components: CAS 57-55-6_T Propylene Glycol- Skin Irnt RTECS TY 2000000 CAS 10043-52-4 Inhibited Calcium Chloride Eye Imt RTECS EV 9800000, 2, H315, Eye Irrit 213, H320 5-10% 2, H319 ---- - _ — - 25-50% Description of first aid measures: After inhalation: Supply fresh air, consult doctor In case of complaints After skin contact: Wash with soap and water After eye contact: Rinse opened eye for at least 15 minutes under running water If symptoms persist, consult a doctor After swallowing: Drink copious amounts of water and provide fresh air Immediately call a doctor Induce vomiting and call for medical help Information for doctor: Most important symptoms and effects, both acute and delayed: No further relevant information available Indication of any immediate medical attention and special treatment needed: No further relevant information available Extinguishing media: Suitable extinguishing agents: CO2, extinguishing powder or water spray Fight larger fires with water spray or alcohol resistant foam Special hazards arising from the substance or mixture: No further relevant information available Advice for firefighters: Protective equipment: As in any fire, wear self-contained breathing apparatus pressure -demand (NIOSH approved or equivalent) and full protective gear to prevent contact with skin and eyes Personal precautions, protective equipment and emergency procedures: Not required Environmental precautions: Dilute with plenty of water Do not allow to enter sewers/ surface or ground water Methods and material for containment and cleaning up: Absorb with liquid -binding material (i a sand, diatomite, acid binders, universal binders, sawdust) Ensure adequate ventilation (Contd on page 3) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 Page 3/8 Reviewed on 10/07/2015 Dispose of the collected material according to regulations Reference to other sections: See Section 7 for information on safe handling See Section 8 for information on personal protection equipment See Section 13 for disposal information 'tomC& �*" • I _ - I , Handling Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace Prevent formation of aerosols Information aboutprotection against explosions and fires: No special measures required Conditions for safe storage, including any incompatibilities: Storage Requirements to be met by storerooms and receptacles: No special requirements Information about storage in one common storage facility: Not required Further information about storage conditions: No further relevant information available Specific end use(s): No further relevant information available Additional information about design of technical systems: No further data, see section 7 Control parameters: Components with occupational exposure limits: 57-55-6 Propylene Glycol -- --------- - - -__--_ -VV-LEL Long-term value 10 mg/m3 Additional information: The lists tha-f were valid during the creation of this SDS were used as basis Exposure controls: Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed Keep away from foodstuffs, beverages and feed Immediately remove all soiled and contaminated clothing and wash before reuse Wash hands before breaks and at the end of work Avoid contact with the eyes Avoid contact with the eyes and skin Breathing equipment: Not required Protection of hands: Not required Material of gloves: Not required Penetration time of glove material: Not applicable Eye protection: 0 o Tightly sealed goggles (Contd on page 4) Page 4/8 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 Reviewed on 10/07/2015 Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: straw-colored Odor: Odorless Odor threshold: Not determined Change in condition Melting point/Melting range: Boiling point/Boiling range: Flash point: Flammability (solid, gaseous): Ignition temperature: Decomposition temperature: Auto igniting: Danger of explosion: Explosion limits: Lower: Upper: Vapor pressure @ 20 °C (68 °F): Density: Relative density: Vapor density: Evaporation rate: Solubility in / Miscibility with: Water: Not determined 100 °C (212 °F) None Not applicable 0 °C (32 °F) Not determined Product is not self-igniting Product does not present an explosion hazard 00Vol % 00Vol % 23 hPa (17 mm Hg) Not determined Not determined Not determined Fully miscible Partition coefficient (n-octanol/water): Not determined Viscosity: Dynamic: Kinematic: Solvent content: Organic solvents: Water: Solids content: Other information: Not determined Not determined 00% 650% 280% No further relevant information available Reactivity: No further relevant information available Chemical stability: Stable under normal conditions Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Possibility of hazardous reactions: No dangerous reactions known Conditions to avoid: No further relevant information available (Contd on page 5) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 Page 5/8 Reviewed on 10/07/2015 Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known Information on toxicological effects: Acute toxicity: LDILC50 values that are relevant for classification: 57-55-6 Propylene Glycol Oral LD50 Dermal LD50 Inhalative LC50/96 hours Intravenous 20000 mg/kg (rat) 20800 mg/kg (rabbit) 52930 mg/I (Pimephales) 6630 mg/kg (mouse) 6423 mg/kg (rat) 6500 mg/kg (rabbit) Primary irritant effect: On the skin: No irritating effect On the eye: Irritating effect Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations Irritant Carcinogenic categories: IARC (International Agency for Research on Cancer): None of the ingredients are listed NTP (National Toxicology Program): None of the ingredients are listed OSHA -Ca (Occupational Safety & Health Administration): None of the ingredients are listed Toxicity: Aquatic toxicity: 57-55-6 Propylene Glycol EC50 >10000 mg/I (daphnia) Persistence and degradability: No further relevant information available Behavior in environmental systems: Bioaccumulative potential: No further relevant information available Mobility in soil: No further relevant information available Additional ecological information: General notes: Do not allow undiluted product or product that has not been neutralized to reach ground water, water course or sewage system Results of PBT and vPvB assessment: PBT: Not applicable vPvB: Not applicable (Contd on page 6) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 Other adverse effects: No further relevant information available 1g" Waste treatment methods: Recommendation: Recycle or dispose with household trash Uncleaned packagings: Recommendation: Disposal must be made according to official regulations Recommended cleansing agent: Water, if necessary with cleansing agents 0,0 UN-Number.- DOT, N-Number: DOT, ADR, ADN, IMDG, IATA Non -Regulated Material UN proper shipping name: DOT, ADR, ADN, IMDG, IATA Non -Regulated Material Transport hazard class(es): Page 6/8 Reviewed on 10/07/2015 DOT, ADR, ADN, IMDG, IATA Class: Non -Regulated Material Packing group: DOT, ADR, IMDG, IATA Non -Regulated Material Environmental hazards: Not applicable Special precautions for user: Not applicable Transport in bulk according to Annex H of MARPOL73178 and the IBC Code: Not applicable UN{{"Model Regulation": Non -Regulated Material Safety, health and environmental regulations/legislation specific for the substance or mixture: SARA (Superfund Amendments and Reauthorization): Section 355 (extremely hazardous substances): - ----- - - - - - -- - - - - - - - - -- - -- - - None- of-- the- - ingredients- — --- --- are listed--- - __- Section 313 (Specific toxic chemical listings): None of the ingredients are listed TSCA (Toxic Substances Control Act): 10043-52-4 j Calcium Chloride _ ------ 7 7 3 2 -18 - 5 1 __--_7732-18-5; Water, distilled water,_deionized water California Proposition 65: Chemicals known to cause cancer: ' - None of the ingredients are listed Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed ---� - _ Chemicals known to cause reproductive toxicity for males: --- ----- -------------- ------- -- - -- -- - -- -- -- - - - ---- - None of the ingredients are listed I Chemicals known to cause developmental toxicity: None of the ingredients are listed (Contd on page 7) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 Carcinogenic categories: EPA (Environmental Protection Agency): Page 7/8 Reviewed on 10/07/2015 None of the Ingredients are listed TLV (Threshold Limit Value established by ACGIH): None of the Ingredients are listed NIOSH -Ca (National Institute for Occupational Safety and Health): None of the Ingredients are listed GHS label elements The product Is classified and labeled according to the Globally Harmonized System (GHS) Hazard pictograms: GHS07 Signal word: Warning Hazard statements: Causes serious eye Irritation Precautionary statements: Wear eye protection / face protection Wash thoroughly after handling If in eyes Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do Continue rinsing If eye irritation persists Get medical advice/attention National regulations: The product is subject to be classified according with the latest version of the regulations on hazardous substances State Right to Know: CAS 7732-18-5 Water, distilled water, deionized water 60-90% CAS 10043-52-4 Inhibited Calcium Chloride 25-50% RTECS EV 9800000 , Eye Irrit 2, H319 CAS 57-55-6 Propylene Glycol 5-10% RTECS TY 2000000 ! Skin Irrit 2, H315, Eye Irrit 213, H320 All ingredients are listed Chemical safety assessment: A Chemical Safety Assessment has not been carried out The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue Nothing herein shall be deemed to create warranty, expressed or Implied, and shall not establish a legally valid contractual relationship It Is the responsibility of the user to determine applicability of this Information and the suitability of the material or product for any particular purpose Date of preparation /last revision: 10/07/2015 13 Abbreviations and acronyms: ADR The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG International Maritime Code for Dangerous Goods DOT US Department of Transportation IATA International Air Transport Association (Contd on page 8) Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910 1200(g) and GHS Rev 03 Issue date 10/07/2015 Trade name: FCA -207 ACGIH American Conference of Governmental Industrial Hygienists EINECS European Inventory of Existing Commercial Chemical Substances ELINCS European List of Notified Chemical Substances CAS Chemical Abstracts Service (division of the American Chemical Society) NFPA National Fire Protection Association (USA) HMIS Hazardous Materials Identification System (USA) LC50 Lethal concentration, 50 percent LD50 Lethal dose, 50 percent PBT Persistent, Bioaccumulative and Toxic vPvB very Persistent and very Bioaccumulative Skin Irrit 2 Skin corrosion/irritation, Hazard Category 2 Eye Irrit 2 Serious eye damage/eye irritation, Hazard Category 2 Eye Irrit 2A Serious eye damage/eye irritation, Hazard Category 2A Eye Irrit 2B Serious eye damage/eye irritation, Hazard Category 2B * Data compared to the previous version altered. Page 8/8 Reviewed on 10/07/2015 SDS created by MSDS Authoring Services www msdsauthoring com +1-877-204-9106