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HomeMy WebLinkAboutDuke-Roxboro Soil_20170808lab DUKE Analytical Laboratory Pagey1iof1139 ENERGY Y Order Number: Project Name: Customer Name(s): Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Vendor QC Data Review Summary Report J17070433 ROXBORO - AB GW ASSESS SOIL(2017 SUPPLEMENTAL SOIL TESTING) Bryan Moeller,Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John To Peggy Kendall Phone: 980-875-5848 Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: • Required QC samples collected and analyzed • Required tests performed for all samples • Vendor Laboratory utilized required test methods for all analyses • Vendor Laboratory met all requested Reporting Limits (RL) • QC Results reviewed for outlying recovery values Case Narrative: Aluminum, Barium, Boron, Calcium, Chromium, Iron, Molybdenum, Nickel , Antimony and Zinc were recovered outside the control limit in the MS/MSD on BGSB-2 (4-5) Al and Fe failed MS recovery due to sample concentration. Antimony was detected in the Method blank at 0.16 mg/Kg. Sample concentrations <1.6 mg/kg may be affected by lab contamination. dc=com,dc=duke-energy, do=ent, r �fjf � ( dc=nam,ou=Accounts, ou= A05125 (1= 363) sitional, cn=MA05125 (154363) 1 agree to specified portions of this document. 2017.08.11 14:33:05 -04'00' Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: • Required QC samples collected and analyzed • Required tests performed for all samples • Vendor Laboratory utilized required test methods for all analyses • Vendor Laboratory met all requested Reporting Limits (RL) • QC Results reviewed for outlying recovery values Case Narrative: Aluminum, Barium, Boron, Calcium, Chromium, Iron, Molybdenum, Nickel , Antimony and Zinc were recovered outside the control limit in the MS/MSD on BGSB-2 (4-5) Al and Fe failed MS recovery due to sample concentration. Antimony was detected in the Method blank at 0.16 mg/Kg. Sample concentrations <1.6 mg/kg may be affected by lab contamination. Analytical lab Page 2 of 139 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Peggy Kendall Project Name: J17070433 Project Number: J17070433 Lot Number:SG20031 Date Completed:08/08/2017 08/09/2017 10:13 AM Approved and released by: Project Manager: Grant Wilton LABORATORY ACCREDITATION XFCXXXIXiX BUREAU adlvision of A -S -X qe �' ACCREDITED iSonEc 1708 The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 1 of 136 Analytical lab Page 3 of 139 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: SG20031 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals Analysis - Method 6010D Aluminum, Barium, Boron, Calcium, Chromium, Iron, Molybdenum, Nickel and Zinc were recovered outside the control limit in the MS associated with batch 47096. Aluminum, Barium, Boron, Calcium, Chromium, Iron, Molybdenum and Nickel were recovered outside the control limit in the MSD. Since the LCS and Method Blank were within control limits it was determined that matrix interference caused the MS/MSD to fail. Sample -001: The sample was analyzed for Boron at a 2X dilution due to matrix interference (low internal standard recoveries). The reporting limits were raised accordingly. Sample -008: The sample was analyzed for Sodium at a 2X dilution due to matrix interference (low internal standard recoveries). The reporting limits were raised accordingly. Sample -019: The sample was analyzed for Boron at a 2X dilution due to matrix interference (low internal standard recoveries). The reporting limits were raised accordingly. Metals Analysis - Method 60208 Antimony was recovered below the control limit in the MS/MSD associated with batch 47097. Since the LCS and Method Blank were within control limits it was determined that matrix interference caused the MS/MSD to fail. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 2 of 136 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: SG20031 Project Name: J17070433 Project Number: J17070433 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017024362 Solid 07/18/20171720 07/20/2017 002 2017024736 Solid 07/18/20171720 07/20/2017 003 2017024737 Solid 07/19/2017 0903 07/20/2017 004 2017024738 Solid 07/19/2017 0903 07/20/2017 005 2017024739 Solid 07/19/2017 0903 07/20/2017 006 2017024740 Solid 07/19/2017 0903 07/20/2017 007 2017024741 Solid 07/19/2017 0903 07/20/2017 008 2017024742 Solid 07/19/20171125 07/20/2017 009 2017024743 Solid 07/19/20171125 07/20/2017 010 2017024744 Solid 07/19/20171125 07/20/2017 011 2017024745 Solid 07/19/20171125 07/20/2017 012 2017024746 Aqueous 07/19/2017 0908 07/20/2017 013 2017024747 Solid 07/19/20171230 07/20/2017 014 2017024748 Solid 07/19/20171230 07/20/2017 015 2017024749 Solid 07/19/20171230 07/20/2017 016 2017024750 Solid 07/19/20171230 07/20/2017 017 2017024751 Solid 07/19/20171230 07/20/2017 018 2017024752 Solid 07/19/20171230 07/20/2017 019 2017024753 Solid 07/19/20171340 07/20/2017 (19 samples) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3 of 136 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 136 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary Duke Energy Lot Number: SG20031 Project Name: J17070433 Project Number: J17070433 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017024362 Solid Chloride (soluble) 9056A 3.0 J mg/kg 13 001 2017024362 Solid Nitrate - N (soluble) 9056A 0.16 J mg/kg 13 001 2017024362 Solid Aluminum 6010D 31000 S mg/kg 14 001 2017024362 Solid Barium 6010D 110 S mg/kg 14 001 2017024362 Solid Calcium 6010D 2000 S mg/kg 14 001 2017024362 Solid Chromium 6010D 39 S mg/kg 14 001 2017024362 Solid Copper 6010D 74 mg/kg 14 001 2017024362 Solid Iron 6010D 35000 S mg/kg 14 001 2017024362 Solid Magnesium 6010D 12000 mg/kg 14 001 2017024362 Solid Manganese 6010D 200 S mg/kg 14 001 2017024362 Solid Molybdenum 6010D 0.63 JS mg/kg 14 001 2017024362 Solid Nickel 6010D 18 S mg/kg 14 001 2017024362 Solid Potassium 6010D 1900 S mg/kg 14 001 2017024362 Solid Sodium 6010D 700 mg/kg 14 001 2017024362 Solid Strontium 6010D 29 S mg/kg 14 001 2017024362 Solid Zinc 6010D 51 S mg/kg 14 001 2017024362 Solid Arsenic 6020B 1.1 mg/kg 15 001 2017024362 Solid Beryllium 6020B 0.51 mg/kg 15 001 2017024362 Solid Cobalt 6020B 19 mg/kg 15 001 2017024362 Solid Lead 6020B 5.1 mg/kg 15 001 2017024362 Solid Selenium 6020B 1.2 J mg/kg 15 001 2017024362 Solid Thallium 6020B 0.093 J mg/kg 15 001 2017024362 Solid Vanadium 6020B 120 mg/kg 15 002 2017024736 Solid Chloride (soluble) 9056A 7.2 J mg/kg 17 002 2017024736 Solid Nitrate - N (soluble) 9056A 0.12 J mg/kg 17 002 2017024736 Solid Aluminum 6010D 9000 mg/kg 18 002 2017024736 Solid Barium 6010D 33 mg/kg 18 002 2017024736 Solid Calcium 6010D 460 mg/kg 18 002 2017024736 Solid Chromium 6010D 4.5 mg/kg 18 002 2017024736 Solid Copper 6010D 11 mg/kg 18 002 2017024736 Solid Iron 6010D 7100 mg/kg 18 002 2017024736 Solid Magnesium 6010D 1600 mg/kg 18 002 2017024736 Solid Manganese 6010D 46 mg/kg 18 002 2017024736 Solid Nickel 6010D 2.1 mg/kg 18 002 2017024736 Solid Potassium 6010D 540 mg/kg 18 002 2017024736 Solid Sodium 6010D 220 J mg/kg 18 002 2017024736 Solid Strontium 6010D 7.9 mg/kg 18 002 2017024736 Solid Zinc 6010D 11 mg/kg 18 002 2017024736 Solid Arsenic 6020B 0.50 mg/kg 19 002 2017024736 Solid Beryllium 6020B 0.29 mg/kg 19 002 2017024736 Solid Cobalt 6020B 5.5 mg/kg 19 002 2017024736 Solid Lead 6020B 2.3 mg/kg 19 002 2017024736 Solid Selenium 6020B 0.30 J mg/kg 19 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2017024736 Solid Thallium 6020B 0.062 J mg/kg 19 002 2017024736 Solid Vanadium 6020B 31 950 mg/kg 19 003 2017024737 Solid Chloride (soluble) 9056A 7.1 J mg/kg 21 003 2017024737 Solid Nitrate - N (soluble) 9056A 0.28 1.3 mg/kg 21 003 2017024737 Solid Sulfate (soluble) 9056A 7.6 J mg/kg 21 003 2017024737 Solid Aluminum 6010D 18000 120 mg/kg 22 003 2017024737 Solid Barium 6010D 48 4.6 mg/kg 22 003 2017024737 Solid Calcium 6010D 610 16 mg/kg 22 003 2017024737 Solid Chromium 6010D 15 0.21 mg/kg 22 003 2017024737 Solid Copper 6010D 14 0.49 mg/kg 22 003 2017024737 Solid Iron 6010D 15000 0.37 mg/kg 22 003 2017024737 Solid Magnesium 6010D 1800 2.2 mg/kg 22 003 2017024737 Solid Manganese 6010D 47 3.6 mg/kg 22 003 2017024737 Solid Nickel 6010D 4.0 0.37 mg/kg 22 003 2017024737 Solid Potassium 6010D 440 0.055 mg/kg 22 003 2017024737 Solid Sodium 6010D 110 J mg/kg 22 003 2017024737 Solid Strontium 6010D 9.9 mg/kg 22 003 2017024737 Solid Zinc 6010D 23 mg/kg 22 003 2017024737 Solid Arsenic 6020B 0.91 mg/kg 23 003 2017024737 Solid Beryllium 6020B 0.31 mg/kg 23 003 2017024737 Solid Cobalt 6020B 5.0 mg/kg 23 003 2017024737 Solid Lead 6020B 5.3 mg/kg 23 003 2017024737 Solid Selenium 6020B 0.65 J mg/kg 23 003 2017024737 Solid Thallium 6020B 0.10 J mg/kg 23 003 2017024737 Solid Vanadium 6020B 47 mg/kg 23 004 2017024738 Solid Chloride (soluble) 9056A 1.8 J mg/kg 25 004 2017024738 Solid Nitrate - N (soluble) 9056A 0.057 J mg/kg 25 004 2017024738 Solid Aluminum 6010D 9300 mg/kg 26 004 2017024738 Solid Barium 6010D 23 mg/kg 26 004 2017024738 Solid Calcium 6010D 230 mg/kg 26 004 2017024738 Solid Chromium 6010D 6.9 mg/kg 26 004 2017024738 Solid Copper 6010D 10 mg/kg 26 004 2017024738 Solid Iron 6010D 9700 mg/kg 26 004 2017024738 Solid Magnesium 6010D 950 mg/kg 26 004 2017024738 Solid Manganese 6010D 39 mg/kg 26 004 2017024738 Solid Nickel 6010D 1.3 J mg/kg 26 004 2017024738 Solid Potassium 6010D 430 mg/kg 26 004 2017024738 Solid Sodium 6010D 120 J mg/kg 26 004 2017024738 Solid Strontium 6010D 4.6 mg/kg 26 004 2017024738 Solid Zinc 6010D 16 mg/kg 26 004 2017024738 Solid Antimony 6020B 0.21 BJ mg/kg 27 004 2017024738 Solid Arsenic 6020B 0.49 mg/kg 27 004 2017024738 Solid Beryllium 6020B 0.37 mg/kg 27 004 2017024738 Solid Cobalt 6020B 2.2 mg/kg 27 004 2017024738 Solid Lead 6020B 3.6 mg/kg 27 004 2017024738 Solid Selenium 6020B 0.37 J mg/kg 27 004 2017024738 Solid Thallium 6020B 0.055 J mg/kg 27 004 2017024738 Solid Vanadium 6020B 19 mg/kg 27 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 005 2017024739 Solid Chloride (soluble) 9056A 2.2 J mg/kg 29 005 2017024739 Solid Nitrate - N (soluble) 9056A 0.071 J mg/kg 29 005 2017024739 Solid Aluminum 6010D 11000 360 mg/kg 30 005 2017024739 Solid Barium 6010D 29 270 mg/kg 30 005 2017024739 Solid Calcium 6010D 580 8.6 mg/kg 30 005 2017024739 Solid Chromium 6010D 4.3 40 mg/kg 30 005 2017024739 Solid Copper 6010D 13 0.71 mg/kg 30 005 2017024739 Solid Iron 6010D 12000 1.2 mg/kg 30 005 2017024739 Solid Magnesium 6010D 1400 4.3 mg/kg 30 005 2017024739 Solid Manganese 6010D 82 3.4 mg/kg 30 005 2017024739 Solid Nickel 6010D 1.6 J mg/kg 30 005 2017024739 Solid Potassium 6010D 560 0.045 mg/kg 30 005 2017024739 Solid Sodium 6010D 210 J mg/kg 30 005 2017024739 Solid Strontium 6010D 9.0 2.7 mg/kg 30 005 2017024739 Solid Zinc 6010D 39 0.065 mg/kg 30 005 2017024739 Solid Antimony 6020B 0.096 BJ mg/kg 31 005 2017024739 Solid Arsenic 6020B 0.58 mg/kg 31 005 2017024739 Solid Beryllium 6020B 0.55 mg/kg 31 005 2017024739 Solid Cobalt 6020B 3.3 mg/kg 31 005 2017024739 Solid Lead 6020B 5.0 mg/kg 31 005 2017024739 Solid Selenium 6020B 0.38 J mg/kg 31 005 2017024739 Solid Thallium 6020B 0.050 J mg/kg 31 005 2017024739 Solid Vanadium 6020B 20 mg/kg 31 006 2017024740 Solid Chloride (soluble) 9056A 5.3 J mg/kg 33 006 2017024740 Solid Nitrate - N (soluble) 9056A 0.14 J mg/kg 33 006 2017024740 Solid Aluminum 6010D 8400 mg/kg 34 006 2017024740 Solid Barium 6010D 22 mg/kg 34 006 2017024740 Solid Calcium 6010D 660 mg/kg 34 006 2017024740 Solid Chromium 6010D 5.2 mg/kg 34 006 2017024740 Solid Copper 6010D 19 mg/kg 34 006 2017024740 Solid Iron 6010D 9900 mg/kg 34 006 2017024740 Solid Magnesium 6010D 960 mg/kg 34 006 2017024740 Solid Manganese 6010D 73 mg/kg 34 006 2017024740 Solid Nickel 6010D 1.8 J mg/kg 34 006 2017024740 Solid Potassium 6010D 360 mg/kg 34 006 2017024740 Solid Sodium 6010D 270 mg/kg 34 006 2017024740 Solid Strontium 6010D 8.6 mg/kg 34 006 2017024740 Solid Zinc 6010D 40 mg/kg 34 006 2017024740 Solid Arsenic 6020B 0.71 mg/kg 35 006 2017024740 Solid Beryllium 6020B 1.2 mg/kg 35 006 2017024740 Solid Cobalt 6020B 4.3 mg/kg 35 006 2017024740 Solid Lead 6020B 3.4 mg/kg 35 006 2017024740 Solid Selenium 6020B 0.74 J mg/kg 35 006 2017024740 Solid Thallium 6020B 0.045 J mg/kg 35 006 2017024740 Solid Vanadium 6020B 30 mg/kg 35 007 2017024741 Solid Chloride (soluble) 9056A 2.7 J mg/kg 37 007 2017024741 Solid Nitrate - N (soluble) 9056A 0.065 J mg/kg 37 007 2017024741 Solid Aluminum 6010D 4600 mg/kg 38 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 007 2017024741 Solid Barium 6010D 26 mg/kg 38 007 2017024741 Solid Calcium 6010D 480 mg/kg 38 007 2017024741 Solid Chromium 6010D 1.8 mg/kg 38 007 2017024741 Solid Copper 6010D 5.6 mg/kg 38 007 2017024741 Solid Iron 6010D 7200 mg/kg 38 007 2017024741 Solid Magnesium 6010D 980 mg/kg 38 007 2017024741 Solid Manganese 6010D 61 mg/kg 38 007 2017024741 Solid Potassium 6010D 600 mg/kg 38 007 2017024741 Solid Sodium 6010D 150 J mg/kg 38 007 2017024741 Solid Strontium 6010D 10 mg/kg 38 007 2017024741 Solid Zinc 6010D 27 mg/kg 38 007 2017024741 Solid Arsenic 6020B 0.24 J mg/kg 39 007 2017024741 Solid Beryllium 6020B 0.40 mg/kg 39 007 2017024741 Solid Cobalt 6020B 1.6 mg/kg 39 007 2017024741 Solid Lead 60208 2.7 mg/kg 39 007 2017024741 Solid Selenium 6020B 1.0 mg/kg 39 007 2017024741 Solid Thallium 6020B 0.030 J mg/kg 39 007 2017024741 Solid Vanadium 6020B 9.6 mg/kg 39 008 2017024742 Solid Chloride (soluble) 9056A 6.0 J mg/kg 41 008 2017024742 Solid Nitrate - N (soluble) 9056A 0.32 mg/kg 41 008 2017024742 Solid Sulfate (soluble) 9056A 19 mg/kg 41 008 2017024742 Solid Aluminum 6010D 25000 mg/kg 42 008 2017024742 Solid Barium 6010D 48 mg/kg 42 008 2017024742 Solid Boron 6010D 2.7 mg/kg 42 008 2017024742 Solid Calcium 6010D 720 mg/kg 42 008 2017024742 Solid Chromium 6010D 22 mg/kg 42 008 2017024742 Solid Copper 6010D 15 mg/kg 42 008 2017024742 Solid Iron 6010D 21000 mg/kg 42 008 2017024742 Solid Magnesium 6010D 960 mg/kg 42 008 2017024742 Solid Manganese 6010D 78 mg/kg 42 008 2017024742 Solid Molybdenum 6010D 0.58 J mg/kg 42 008 2017024742 Solid Nickel 6010D 3.3 mg/kg 42 008 2017024742 Solid Potassium 6010D 260 J mg/kg 42 008 2017024742 Solid Strontium 6010D 11 mg/kg 42 008 2017024742 Solid Zinc 6010D 19 mg/kg 42 008 2017024742 Solid Arsenic 6020B 1.1 mg/kg 43 008 2017024742 Solid Beryllium 6020B 0.40 mg/kg 43 008 2017024742 Solid Cobalt 6020B 3.9 mg/kg 43 008 2017024742 Solid Lead 6020B 7.9 mg/kg 43 008 2017024742 Solid Selenium 6020B 0.31 J mg/kg 43 008 2017024742 Solid Thallium 60208 0.16 mg/kg 43 008 2017024742 Solid Vanadium 6020B 64 mg/kg 43 008 2017024742 Solid Mercury 7471B 0.030 J mg/kg 44 009 2017024743 Solid Chloride (soluble) 9056A 2.8 J mg/kg 45 009 2017024743 Solid Nitrate - N (soluble) 9056A 0.066 J mg/kg 45 009 2017024743 Solid Aluminum 6010D 24000 mg/kg 46 009 2017024743 Solid Barium 6010D 160 mg/kg 46 009 2017024743 Solid Boron 6010D 1.1 J mg/kg 46 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 009 2017024743 Solid Calcium 6010D 1100 mg/kg 46 009 2017024743 Solid Chromium 6010D 7.4 mg/kg 46 009 2017024743 Solid Copper 6010D 32 mg/kg 46 009 2017024743 Solid Iron 6010D 19000 mg/kg 46 009 2017024743 Solid Magnesium 6010D 5400 mg/kg 46 009 2017024743 Solid Manganese 6010D 120 mg/kg 46 009 2017024743 Solid Nickel 6010D 4.4 mg/kg 46 009 2017024743 Solid Potassium 6010D 3000 mg/kg 46 009 2017024743 Solid Sodium 6010D 320 mg/kg 46 009 2017024743 Solid Strontium 6010D 31 mg/kg 46 009 2017024743 Solid Zinc 6010D 31 mg/kg 46 009 2017024743 Solid Arsenic 6020B 0.45 J mg/kg 47 009 2017024743 Solid Beryllium 6020B 0.34 mg/kg 47 009 2017024743 Solid Cobalt 6020B 8.5 mg/kg 47 009 2017024743 Solid Lead 6020B 2.1 mg/kg 47 009 2017024743 Solid Selenium 6020B 0.57 J mg/kg 47 009 2017024743 Solid Thallium 6020B 0.10 J mg/kg 47 009 2017024743 Solid Vanadium 6020B 48 mg/kg 47 010 2017024744 Solid Chloride (soluble) 9056A 29 mg/kg 49 010 2017024744 Solid Nitrate - N (soluble) 9056A 0.47 mg/kg 49 010 2017024744 Solid Sulfate (soluble) 9056A 28 mg/kg 49 010 2017024744 Solid Aluminum 6010D 27000 mg/kg 50 010 2017024744 Solid Barium 6010D 97 mg/kg 50 010 2017024744 Solid Boron 6010D 1.2 J mg/kg 50 010 2017024744 Solid Calcium 6010D 590 mg/kg 50 010 2017024744 Solid Chromium 6010D 9.0 mg/kg 50 010 2017024744 Solid Copper 6010D 69 mg/kg 50 010 2017024744 Solid Iron 6010D 22000 mg/kg 50 010 2017024744 Solid Magnesium 6010D 5100 mg/kg 50 010 2017024744 Solid Manganese 6010D 97 mg/kg 50 010 2017024744 Solid Molybdenum 6010D 0.61 J mg/kg 50 010 2017024744 Solid Nickel 6010D 4.2 mg/kg 50 010 2017024744 Solid Potassium 6010D 1600 mg/kg 50 010 2017024744 Solid Sodium 6010D 180 J mg/kg 50 010 2017024744 Solid Strontium 6010D 16 mg/kg 50 010 2017024744 Solid Zinc 6010D 31 mg/kg 50 010 2017024744 Solid Arsenic 6020B 0.39 J mg/kg 51 010 2017024744 Solid Beryllium 6020B 0.26 mg/kg 51 010 2017024744 Solid Cobalt 6020B 6.6 mg/kg 51 010 2017024744 Solid Lead 6020B 4.5 mg/kg 51 010 2017024744 Solid Selenium 6020B 0.53 J mg/kg 51 010 2017024744 Solid Thallium 6020B 0.049 J mg/kg 51 010 2017024744 Solid Vanadium 6020B 54 mg/kg 51 011 2017024745 Solid Chloride (soluble) 9056A 2.2 J mg/kg 53 011 2017024745 Solid Nitrate - N (soluble) 9056A 0.095 J mg/kg 53 011 2017024745 Solid Aluminum 6010D 13000 mg/kg 54 011 2017024745 Solid Barium 6010D 110 mg/kg 54 011 2017024745 Solid Calcium 6010D 2000 mg/kg 54 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 011 2017024745 Solid Chromium 6010D 3.8 160 mg/kg 54 011 2017024745 Solid Copper 6010D 69 0.62 mg/kg 54 011 2017024745 Solid Iron 6010D 15000 1.7 mg/kg 54 011 2017024745 Solid Magnesium 6010D 4300 3000 mg/kg 54 011 2017024745 Solid Manganese 6010D 110 91 mg/kg 54 011 2017024745 Solid Nickel 6010D 3.4 7.7 mg/kg 54 011 2017024745 Solid Potassium 6010D 2300 53 mg/kg 54 011 2017024745 Solid Sodium 6010D 330 0.44 mg/kg 54 011 2017024745 Solid Strontium 6010D 29 0.50 mg/kg 54 011 2017024745 Solid Zinc 6010D 34 4.6 mg/kg 54 011 2017024745 Solid Arsenic 6020B 0.13 J mg/kg 55 011 2017024745 Solid Beryllium 6020B 0.59 0.35 mg/kg 55 011 2017024745 Solid Cobalt 6020B 8.0 0.10 mg/kg 55 011 2017024745 Solid Lead 6020B 1.1 43 mg/kg 55 011 2017024745 Solid Selenium 6020B 0.74 J mg/kg 55 011 2017024745 Solid Thallium 6020B 0.040 J mg/kg 55 011 2017024745 Solid Vanadium 6020B 45 mg/kg 55 012 2017024746 Aqueous Chromium 6010D 0.0014 J mg/L 57 012 2017024746 Aqueous Iron 6010D 0.58 mg/L 57 012 2017024746 Aqueous Manganese 6010D 0.0032 J mg/L 57 012 2017024746 Aqueous Zinc 6010D 0.0084 J mg/L 57 013 2017024747 Solid Chloride (soluble) 9056A 7.9 J mg/kg 60 013 2017024747 Solid Nitrate - N (soluble) 9056A 0.47 mg/kg 60 013 2017024747 Solid Sulfate (soluble) 9056A 13 mg/kg 60 013 2017024747 Solid Aluminum 6010D 28000 mg/kg 61 013 2017024747 Solid Barium 6010D 130 mg/kg 61 013 2017024747 Solid Boron 6010D 1.4 J mg/kg 61 013 2017024747 Solid Calcium 6010D 160 J mg/kg 61 013 2017024747 Solid Chromium 6010D 4.3 mg/kg 61 013 2017024747 Solid Copper 6010D 38 mg/kg 61 013 2017024747 Solid Iron 6010D 21000 mg/kg 61 013 2017024747 Solid Magnesium 6010D 4000 mg/kg 61 013 2017024747 Solid Manganese 6010D 160 mg/kg 61 013 2017024747 Solid Molybdenum 6010D 0.62 J mg/kg 61 013 2017024747 Solid Nickel 6010D 1.7 J mg/kg 61 013 2017024747 Solid Potassium 6010D 3000 mg/kg 61 013 2017024747 Solid Sodium 6010D 91 J mg/kg 61 013 2017024747 Solid Strontium 6010D 7.7 mg/kg 61 013 2017024747 Solid Zinc 6010D 53 mg/kg 61 013 2017024747 Solid Arsenic 6020B 0.44 J mg/kg 62 013 2017024747 Solid Beryllium 6020B 0.50 mg/kg 62 013 2017024747 Solid Cobalt 6020B 4.6 mg/kg 62 013 2017024747 Solid Lead 6020B 3.8 mg/kg 62 013 2017024747 Solid Selenium 6020B 0.35 J mg/kg 62 013 2017024747 Solid Thallium 6020B 0.10 J mg/kg 62 013 2017024747 Solid Vanadium 6020B 43 mg/kg 62 014 2017024748 Solid Chloride (soluble) 9056A 11 J mg/kg 64 014 2017024748 Solid Nitrate - N (soluble) 9056A 0.080 J mg/kg 64 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 014 2017024748 Solid Aluminum 6010D 31000 mg/kg 65 014 2017024748 Solid Barium 6010D 120 mg/kg 65 014 2017024748 Solid Boron 6010D 1.3 J mg/kg 65 014 2017024748 Solid Calcium 6010D 250 J mg/kg 65 014 2017024748 Solid Chromium 6010D 4.1 mg/kg 65 014 2017024748 Solid Copper 6010D 29 mg/kg 65 014 2017024748 Solid Iron 6010D 21000 mg/kg 65 014 2017024748 Solid Magnesium 6010D 4100 mg/kg 65 014 2017024748 Solid Manganese 6010D 360 mg/kg 65 014 2017024748 Solid Nickel 6010D 1.9 J mg/kg 65 014 2017024748 Solid Potassium 6010D 2500 mg/kg 65 014 2017024748 Solid Sodium 6010D 130 J mg/kg 65 014 2017024748 Solid Strontium 6010D 10 mg/kg 65 014 2017024748 Solid Zinc 6010D 54 mg/kg 65 014 2017024748 Solid Arsenic 6020B 0.60 mg/kg 66 014 2017024748 Solid Beryllium 6020B 0.57 mg/kg 66 014 2017024748 Solid Cobalt 6020B 28 mg/kg 66 014 2017024748 Solid Lead 6020B 5.6 mg/kg 66 014 2017024748 Solid Selenium 6020B 1.1 J mg/kg 66 014 2017024748 Solid Thallium 6020B 0.083 J mg/kg 66 014 2017024748 Solid Vanadium 6020B 36 mg/kg 66 015 2017024749 Solid Chloride (soluble) 9056A 45 mg/kg 68 015 2017024749 Solid Nitrate - N (soluble) 9056A 0.35 mg/kg 68 015 2017024749 Solid Aluminum 6010D 16000 mg/kg 69 015 2017024749 Solid Barium 6010D 77 mg/kg 69 015 2017024749 Solid Calcium 6010D 460 mg/kg 69 015 2017024749 Solid Chromium 6010D 4.1 mg/kg 69 015 2017024749 Solid Copper 6010D 60 mg/kg 69 015 2017024749 Solid Iron 6010D 14000 mg/kg 69 015 2017024749 Solid Magnesium 6010D 2700 mg/kg 69 015 2017024749 Solid Manganese 6010D 110 mg/kg 69 015 2017024749 Solid Nickel 6010D 2.0 mg/kg 69 015 2017024749 Solid Potassium 6010D 1400 mg/kg 69 015 2017024749 Solid Sodium 6010D 98 J mg/kg 69 015 2017024749 Solid Strontium 6010D 14 mg/kg 69 015 2017024749 Solid Zinc 6010D 23 mg/kg 69 015 2017024749 Solid Antimony 6020B 0.27 BJ mg/kg 70 015 2017024749 Solid Arsenic 6020B 0.40 J mg/kg 70 015 2017024749 Solid Beryllium 6020B 0.96 mg/kg 70 015 2017024749 Solid Cobalt 6020B 8.7 mg/kg 70 015 2017024749 Solid Lead 6020B 2.4 mg/kg 70 015 2017024749 Solid Selenium 6020B 1.1 J mg/kg 70 015 2017024749 Solid Thallium 6020B 0.047 J mg/kg 70 015 2017024749 Solid Vanadium 6020B 39 mg/kg 70 016 2017024750 Solid Chloride (soluble) 9056A 5.5 J mg/kg 72 016 2017024750 Solid Nitrate - N (soluble) 9056A 0.064 J mg/kg 72 016 2017024750 Solid Aluminum 6010D 21000 mg/kg 73 016 2017024750 Solid Barium 6010D 220 mg/kg 73 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 016 2017024750 Solid Boron 6010D 1.2 J mg/kg 73 016 2017024750 Solid Calcium 6010D 1100 0.12 mg/kg 73 016 2017024750 Solid Chromium 6010D 2.0 0.71 mg/kg 73 016 2017024750 Solid Copper 6010D 90 8.9 mg/kg 73 016 2017024750 Solid Iron 6010D 23000 1.4 mg/kg 73 016 2017024750 Solid Magnesium 6010D 5900 0.33 mg/kg 73 016 2017024750 Solid Manganese 6010D 310 0.10 mg/kg 73 016 2017024750 Solid Potassium 6010D 5500 37 mg/kg 73 016 2017024750 Solid Sodium 6010D 90 J mg/kg 73 016 2017024750 Solid Strontium 6010D 21 0.038 mg/kg 73 016 2017024750 Solid Zinc 6010D 43 14000 mg/kg 73 016 2017024750 Solid Arsenic 6020B 0.42 J mg/kg 74 016 2017024750 Solid Beryllium 6020B 0.74 0.98 mg/kg 74 016 2017024750 Solid Cobalt 6020B 14 850 mg/kg 74 016 2017024750 Solid Lead 6020B 1.9 3.0 mg/kg 74 016 2017024750 Solid Selenium 6020B 0.99 J mg/kg 74 016 2017024750 Solid Thallium 6020B 0.12 J mg/kg 74 016 2017024750 Solid Vanadium 6020B 36 mg/kg 74 017 2017024751 Solid Chloride (soluble) 9056A 3.9 J mg/kg 76 017 2017024751 Solid Nitrate - N (soluble) 9056A 0.054 J mg/kg 76 017 2017024751 Solid Aluminum 6010D 19000 mg/kg 77 017 2017024751 Solid Barium 6010D 130 mg/kg 77 017 2017024751 Solid Calcium 6010D 1200 mg/kg 77 017 2017024751 Solid Chromium 6010D 7.3 mg/kg 77 017 2017024751 Solid Copper 6010D 6.6 mg/kg 77 017 2017024751 Solid Iron 6010D 17000 mg/kg 77 017 2017024751 Solid Magnesium 6010D 6600 mg/kg 77 017 2017024751 Solid Manganese 6010D 230 mg/kg 77 017 2017024751 Solid Nickel 6010D 3.3 mg/kg 77 017 2017024751 Solid Potassium 6010D 6500 mg/kg 77 017 2017024751 Solid Sodium 6010D 100 J mg/kg 77 017 2017024751 Solid Strontium 6010D 23 mg/kg 77 017 2017024751 Solid Zinc 6010D 36 mg/kg 77 017 2017024751 Solid Arsenic 6020B 0.12 J mg/kg 78 017 2017024751 Solid Beryllium 6020B 0.71 mg/kg 78 017 2017024751 Solid Cobalt 6020B 8.9 mg/kg 78 017 2017024751 Solid Lead 6020B 1.4 mg/kg 78 017 2017024751 Solid Selenium 6020B 0.33 J mg/kg 78 017 2017024751 Solid Thallium 6020B 0.10 J mg/kg 78 017 2017024751 Solid Vanadium 6020B 37 mg/kg 78 018 2017024752 Solid Chloride (soluble) 9056A 1.3 J mg/kg 80 018 2017024752 Solid Nitrate - N (soluble) 9056A 0.038 J mg/kg 80 018 2017024752 Solid Aluminum 6010D 14000 mg/kg 81 018 2017024752 Solid Barium 6010D 130 mg/kg 81 018 2017024752 Solid Boron 6010D 0.98 J mg/kg 81 018 2017024752 Solid Calcium 6010D 850 mg/kg 81 018 2017024752 Solid Chromium 6010D 3.0 mg/kg 81 018 2017024752 Solid Copper 6010D 2.5 mg/kg 81 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 136 Detection Summary (Continued) Lot Number: SG20031 Sample Sample ID Matrix Parameter Method Result Q Units Page 018 2017024752 Solid Iron 6010D 15000 mg/kg 81 018 2017024752 Solid Magnesium 6010D 5000 mg/kg 81 018 2017024752 Solid Manganese 6010D 270 mg/kg 81 018 2017024752 Solid Nickel 6010D 2.2 mg/kg 81 018 2017024752 Solid Potassium 6010D 5300 mg/kg 81 018 2017024752 Solid Sodium 6010D 96 J mg/kg 81 018 2017024752 Solid Strontium 6010D 18 mg/kg 81 018 2017024752 Solid Zinc 6010D 35 mg/kg 81 018 2017024752 Solid Arsenic 6020B 0.20 J mg/kg 82 018 2017024752 Solid Beryllium 6020B 0.54 mg/kg 82 018 2017024752 Solid Cobalt 6020B 7.1 mg/kg 82 018 2017024752 Solid Lead 6020B 1.2 mg/kg 82 018 2017024752 Solid Selenium 6020B 0.49 J mg/kg 82 018 2017024752 Solid Thallium 6020B 0.11 mg/kg 82 018 2017024752 Solid Vanadium 6020B 32 mg/kg 82 019 2017024753 Solid Chloride (soluble) 9056A 2.6 J mg/kg 84 019 2017024753 Solid Nitrate - N (soluble) 9056A 0.17 J mg/kg 84 019 2017024753 Solid Aluminum 6010D 16000 mg/kg 85 019 2017024753 Solid Barium 6010D 55 mg/kg 85 019 2017024753 Solid Calcium 6010D 1000 mg/kg 85 019 2017024753 Solid Chromium 6010D 34 mg/kg 85 019 2017024753 Solid Copper 6010D 14 mg/kg 85 019 2017024753 Solid Iron 6010D 27000 mg/kg 85 019 2017024753 Solid Magnesium 6010D 980 mg/kg 85 019 2017024753 Solid Manganese 6010D 700 mg/kg 85 019 2017024753 Solid Molybdenum 6010D 0.54 J mg/kg 85 019 2017024753 Solid Nickel 6010D 4.4 mg/kg 85 019 2017024753 Solid Potassium 6010D 240 mg/kg 85 019 2017024753 Solid Sodium 6010D 50 J mg/kg 85 019 2017024753 Solid Strontium 6010D 8.3 mg/kg 85 019 2017024753 Solid Zinc 6010D 24 mg/kg 85 019 2017024753 Solid Arsenic 6020B 3.2 mg/kg 86 019 2017024753 Solid Beryllium 6020B 0.70 mg/kg 86 019 2017024753 Solid Cadmium 6020B 0.064 mg/kg 86 019 2017024753 Solid Cobalt 6020B 44 mg/kg 86 019 2017024753 Solid Lead 6020B 14 mg/kg 86 019 2017024753 Solid Selenium 6020B 0.83 J mg/kg 86 019 2017024753 Solid Thallium 6020B 0.095 J mg/kg 86 019 2017024753 Solid Vanadium 6020B 77 mg/kg 86 019 2017024753 Solid Mercury 7471B 0.051 J mg/kg 87 (419 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-001 Description: 2017024362 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 87.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2024 TAF 47788 1 (Nitrate - N ) 9056A 1 07/26/2017 2024 TAF 47789 1 (pH) 9045D 1 07/20/2017 1632 MSG 47114 1 (Sulfate (sol) 9056A 1 07/26/2017 2024 TAF 47790 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 3.0 J 11 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.16 J 0.23 0.028 mg/kg 1 pH 9045D 6.78 su 1 Sulfate (soluble) 9056A ND 11 5.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-001 Description: 2017024362 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 87.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0248 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/04/2017 1553 MJI 07/20/2017 1906 47096 3 3050B 601 OD 1 08/07/2017 1457 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 31000 S 46 17 mg/kg 2 Barium 7440-39-3 6010D 110 S 1.5 0.37 mg/kg 1 Boron 7440-42-8 6010D ND S 5.7 2.3 mg/kg 2 Calcium 7440-70-2 6010D 2000 S 290 36 mg/kg 1 Chromium 7440-47-3 6010D 39 S 1.1 0.29 mg/kg 2 Copper 7440-50-8 6010D 74 1.1 0.52 mg/kg 2 Iron 7439-89-6 6010D 35000 S 11 5.2 mg/kg 2 Magnesium 7439-95-4 6010D 12000 570 72 mg/kg 2 Manganese 7439-96-5 6010D 200 S 1.7 0.68 mg/kg 2 Molybdenum 7439-98-7 6010D 0.63 JS 2.3 0.57 mg/kg 1 Nickel 7440-02-0 6010D 18 S 4.6 1.2 mg/kg 2 Potassium 7440-09-7 6010D 1900 S 290 36 mg/kg 1 Sodium 7440-23-5 6010D 700 570 72 mg/kg 2 Strontium 7440-24-6 6010D 29 S 1.1 0.29 mg/kg 3 Zinc 7440-66-6 6010D 51 S 5.7 1.4 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-001 Description: 2017024362 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 87.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1725 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND S 0.48 0.096 mg/kg 1 Arsenic 7440-38-2 6020B 1.1 0.48 0.096 mg/kg 1 Beryllium 7440-41-7 6020B 0.51 0.096 0.019 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.024 0.0096 mg/kg 1 Cobalt 7440-48-4 6020B 19 0.67 0.24 mg/kg 1 Lead 7439-92-1 6020B 5.1 0.24 0.048 mg/kg 1 Selenium 7782-49-2 6020B 1.2 J 1.3 0.24 mg/kg 1 Thallium 7440-28-0 6020B 0.093 J 0.13 0.025 mg/kg 1 Vanadium 7440-62-2 6020B 120 1.3 0.24 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-001 Description: 2017024362 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 87.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1551 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.092 0.022 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-002 Description: 2017024736 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 94.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2048 TAF 47788 1 (Nitrate - N ) 9056A 1 07/26/2017 2048 TAF 47789 1 (pH) 9045D 1 07/20/2017 1633 MSG 47114 1 (Sulfate (sol) 9056A 1 07/26/2017 2048 TAF 47790 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 7.2 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.12 J 0.21 0.026 mg/kg 1 pH 9045D 7.43 su 1 Sulfate (soluble) 9056A ND 11 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-002 Description: 2017024736 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 94.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0320 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1603 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 9000 20 7.4 mg/kg 1 Barium 7440-39-3 6010D 33 1.3 0.32 mg/kg 1 Boron 7440-42-8 6010D ND 2.5 0.98 mg/kg 1 Calcium 7440-70-2 6010D 460 250 31 mg/kg 1 Chromium 7440-47-3 6010D 4.5 0.49 0.12 mg/kg 1 Copper 7440-50-8 6010D 11 0.49 0.22 mg/kg 1 Iron 7439-89-6 6010D 7100 4.9 2.2 mg/kg 1 Magnesium 7439-95-4 6010D 1600 250 31 mg/kg 1 Manganese 7439-96-5 6010D 46 0.74 0.29 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.0 0.49 mg/kg 1 Nickel 7440-02-0 6010D 2.1 2.0 0.52 mg/kg 1 Potassium 7440-09-7 6010D 540 250 31 mg/kg 1 Sodium 7440-23-5 6010D 220 J 250 31 mg/kg 1 Strontium 7440-24-6 6010D 7.9 0.98 0.25 mg/kg 2 Zinc 7440-66-6 6010D 11 2.5 0.61 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-002 Description: 2017024736 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 94.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1754 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.44 0.088 mg/kg 1 Arsenic 7440-38-2 6020B 0.50 0.44 0.088 mg/kg 1 Beryllium 7440-41-7 6020B 0.29 0.088 0.018 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.022 0.0088 mg/kg 1 Cobalt 7440-48-4 6020B 5.5 0.62 0.22 mg/kg 1 Lead 7439-92-1 6020B 2.3 0.22 0.044 mg/kg 1 Selenium 7782-49-2 6020B 0.30 J 1.1 0.22 mg/kg 1 Thallium 7440-28-0 6020B 0.062 J 0.11 0.023 mg/kg 1 Vanadium 7440-62-2 6020B 31 1.1 0.22 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-002 Description: 2017024736 Matrix: Solid Date Sampled:07/18/2017 1720 Project Name: J17070433 % Solids: 94.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1553 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.087 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 20 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-003 Description: 2017024737 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 90.4 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1344 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1344 TAF 47889 1 (pH) 9045D 1 07/20/2017 1635 MSG 47114 1 (Sulfate (Sol) 9056A 1 07/27/2017 1344 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 7.1 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.28 0.22 0.027 mg/kg 1 pH 9045D 7.18 su 1 Sulfate (soluble) 9056A 7.6 J 11 5.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-003 Description: 2017024737 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 90.4 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0325 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1608 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 18000 21 8.0 mg/kg 1 Barium 7440-39-3 6010D 48 1.4 0.35 mg/kg 1 Boron 7440-42-8 6010D ND 2.7 1.1 mg/kg 1 Calcium 7440-70-2 6010D 610 270 33 mg/kg 1 Chromium 7440-47-3 6010D 15 0.53 0.13 mg/kg 1 Copper 7440-50-8 6010D 14 0.53 0.24 mg/kg 1 Iron 7439-89-6 6010D 15000 5.3 2.4 mg/kg 1 Magnesium 7439-95-4 6010D 1800 270 33 mg/kg 1 Manganese 7439-96-5 6010D 47 0.80 0.32 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.1 0.53 mg/kg 1 Nickel 7440-02-0 6010D 4.0 2.1 0.56 mg/kg 1 Potassium 7440-09-7 6010D 440 270 33 mg/kg 1 Sodium 7440-23-5 6010D 110 J 270 33 mg/kg 1 Strontium 7440-24-6 6010D 9.9 1.1 0.27 mg/kg 2 Zinc 7440-66-6 6010D 23 2.7 0.67 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-003 Description: 2017024737 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 90.4 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1800 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 23 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.50 0.10 mg/kg 1 Arsenic 7440-38-2 6020B 0.91 0.50 0.10 mg/kg 1 Beryllium 7440-41-7 6020B 0.31 0.10 0.020 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.025 0.010 mg/kg 1 Cobalt 7440-48-4 6020B 5.0 0.71 0.25 mg/kg 1 Lead 7439-92-1 6020B 5.3 0.25 0.050 mg/kg 1 Selenium 7782-49-2 6020B 0.65 J 1.3 0.25 mg/kg 1 Thallium 7440-28-0 6020B 0.10 J 0.13 0.026 mg/kg 1 Vanadium 7440-62-2 6020B 47 1.3 0.25 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 23 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-003 Description: 2017024737 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 90.4 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1555 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.080 0.019 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 24 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-004 Description: 2017024738 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 94.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1409 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1409 TAF 47889 1 (pH) 9045D 1 07/20/2017 1635 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1409 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 1.8 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.057 J 0.21 0.026 mg/kg 1 pH 9045D 7.11 su 1 Sulfate (soluble) 9056A ND 11 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-004 Description: 2017024738 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 94.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0329 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1612 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 9300 15 5.7 mg/kg 1 Barium 7440-39-3 6010D 23 1.0 0.25 mg/kg 1 Boron 7440-42-8 6010D ND 1.9 0.77 mg/kg 1 Calcium 7440-70-2 6010D 230 190 24 mg/kg 1 Chromium 7440-47-3 6010D 6.9 0.38 0.096 mg/kg 1 Copper 7440-50-8 6010D 10 0.38 0.17 mg/kg 1 Iron 7439-89-6 6010D 9700 3.8 1.7 mg/kg 1 Magnesium 7439-95-4 6010D 950 190 24 mg/kg 1 Manganese 7439-96-5 6010D 39 0.57 0.23 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.5 0.38 mg/kg 1 Nickel 7440-02-0 6010D 1.3 J 1.5 0.40 mg/kg 1 Potassium 7440-09-7 6010D 430 190 24 mg/kg 1 Sodium 7440-23-5 6010D 120 J 190 24 mg/kg 1 Strontium 7440-24-6 6010D 4.6 0.77 0.19 mg/kg 2 Zinc 7440-66-6 6010D 16 1.9 0.48 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-004 Description: 2017024738 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 94.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1818 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 27 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.21 BJ 0.38 0.076 mg/kg 1 Arsenic 7440-38-2 6020B 0.49 0.38 0.076 mg/kg 1 Beryllium 7440-41-7 6020B 0.37 0.076 0.015 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.019 0.0076 mg/kg 1 Cobalt 7440-48-4 6020B 2.2 0.53 0.19 mg/kg 1 Lead 7439-92-1 6020B 3.6 0.19 0.038 mg/kg 1 Selenium 7782-49-2 6020B 0.37 J 0.99 0.19 mg/kg 1 Thallium 7440-28-0 6020B 0.055 J 0.099 0.020 mg/kg 1 Vanadium 7440-62-2 6020B 19 0.99 0.19 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 27 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-004 Description: 2017024738 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 94.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1558 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.086 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 28 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-005 Description: 2017024739 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 81.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1434 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1434 TAF 47889 1 (pH) 9045D 1 07/20/2017 1636 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1434 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.2 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.071 J 0.25 0.030 mg/kg 1 pH 9045D 6.98 su 1 Sulfate (soluble) 9056A ND 12 6.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-005 Description: 2017024739 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 81.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0334 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1617 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 11000 23 8.6 mg/kg 1 Barium 7440-39-3 6010D 29 1.5 0.37 mg/kg 1 Boron 7440-42-8 6010D ND 2.9 1.1 mg/kg 1 Calcium 7440-70-2 6010D 580 290 36 mg/kg 1 Chromium 7440-47-3 6010D 4.3 0.57 0.14 mg/kg 1 Copper 7440-50-8 6010D 13 0.57 0.26 mg/kg 1 Iron 7439-89-6 6010D 12000 5.7 2.6 mg/kg 1 Magnesium 7439-95-4 6010D 1400 290 36 mg/kg 1 Manganese 7439-96-5 6010D 82 0.86 0.34 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.3 0.57 mg/kg 1 Nickel 7440-02-0 6010D 1.6 J 2.3 0.60 mg/kg 1 Potassium 7440-09-7 6010D 560 290 36 mg/kg 1 Sodium 7440-23-5 6010D 210 J 290 36 mg/kg 1 Strontium 7440-24-6 6010D 9.0 1.1 0.29 mg/kg 2 Zinc 7440-66-6 6010D 39 2.9 0.72 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-005 Description: 2017024739 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 81.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1823 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 31 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.096 BJ 0.39 0.078 mg/kg 1 Arsenic 7440-38-2 6020B 0.58 0.39 0.078 mg/kg 1 Beryllium 7440-41-7 6020B 0.55 0.078 0.016 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.020 0.0078 mg/kg 1 Cobalt 7440-48-4 6020B 3.3 0.55 0.20 mg/kg 1 Lead 7439-92-1 6020B 5.0 0.20 0.039 mg/kg 1 Selenium 7782-49-2 6020B 0.38 J 1.0 0.20 mg/kg 1 Thallium 7440-28-0 6020B 0.050 J 0.10 0.020 mg/kg 1 Vanadium 7440-62-2 6020B 20 1.0 0.20 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 31 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-005 Description: 2017024739 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 81.3 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1600 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.088 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 32 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-006 Description: 2017024740 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 93.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1459 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1459 TAF 47889 1 (pH) 9045D 1 07/20/2017 1637 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1459 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 5.3 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.14 J 0.21 0.026 mg/kg 1 pH 9045D 7.69 su 1 Sulfate (soluble) 9056A ND 11 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-006 Description: 2017024740 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 93.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0338 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1621 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 8400 19 7.3 mg/kg 1 Barium 7440-39-3 6010D 22 1.3 0.32 mg/kg 1 Boron 7440-42-8 6010D ND 2.4 0.97 mg/kg 1 Calcium 7440-70-2 6010D 660 240 30 mg/kg 1 Chromium 7440-47-3 6010D 5.2 0.48 0.12 mg/kg 1 Copper 7440-50-8 6010D 19 0.48 0.22 mg/kg 1 Iron 7439-89-6 6010D 9900 4.8 2.2 mg/kg 1 Magnesium 7439-95-4 6010D 960 240 30 mg/kg 1 Manganese 7439-96-5 6010D 73 0.73 0.29 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.9 0.48 mg/kg 1 Nickel 7440-02-0 6010D 1.8 J 1.9 0.51 mg/kg 1 Potassium 7440-09-7 6010D 360 240 30 mg/kg 1 Sodium 7440-23-5 6010D 270 240 30 mg/kg 1 Strontium 7440-24-6 6010D 8.6 0.97 0.24 mg/kg 2 Zinc 7440-66-6 6010D 40 2.4 0.61 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-006 Description: 2017024740 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 93.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1829 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 35 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.47 0.094 mg/kg 1 Arsenic 7440-38-2 6020B 0.71 0.47 0.094 mg/kg 1 Beryllium 7440-41-7 6020B 1.2 0.094 0.019 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.024 0.0094 mg/kg 1 Cobalt 7440-48-4 6020B 4.3 0.66 0.24 mg/kg 1 Lead 7439-92-1 6020B 3.4 0.24 0.047 mg/kg 1 Selenium 7782-49-2 6020B 0.74 J 1.2 0.24 mg/kg 1 Thallium 7440-28-0 6020B 0.045 J 0.12 0.024 mg/kg 1 Vanadium 7440-62-2 6020B 30 1.2 0.24 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 35 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-006 Description: 2017024740 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 93.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1602 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.076 0.018 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 36 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-007 Description: 2017024741 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 97.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1525 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1525 TAF 47889 1 (pH) 9045D 1 07/20/2017 1638 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1525 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.7 J 10 1.0 mg/kg 1 Nitrate - N (soluble) 9056A 0.065 J 0.21 0.025 mg/kg 1 pH 9045D 8.76 su 1 Sulfate (soluble) 9056A ND 10 5.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-007 Description: 2017024741 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 97.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0342 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/08/2017 1404 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 4600 17 6.4 mg/kg 1 Barium 7440-39-3 6010D 26 1.1 0.28 mg/kg 1 Boron 7440-42-8 6010D ND 2.1 0.85 mg/kg 1 Calcium 7440-70-2 6010D 480 210 26 mg/kg 1 Chromium 7440-47-3 6010D 1.8 0.42 0.11 mg/kg 1 Copper 7440-50-8 6010D 5.6 0.42 0.19 mg/kg 1 Iron 7439-89-6 6010D 7200 4.2 1.9 mg/kg 1 Magnesium 7439-95-4 6010D 980 210 26 mg/kg 1 Manganese 7439-96-5 6010D 61 0.64 0.25 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.7 0.42 mg/kg 1 Nickel 7440-02-0 6010D ND 1.7 0.45 mg/kg 1 Potassium 7440-09-7 6010D 600 210 26 mg/kg 1 Sodium 7440-23-5 6010D 150 J 210 26 mg/kg 1 Strontium 7440-24-6 6010D 10 1.7 0.42 mg/kg 2 Zinc 7440-66-6 6010D 27 2.1 0.53 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-007 Description: 2017024741 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 97.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1835 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 39 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.40 0.081 mg/kg 1 Arsenic 7440-38-2 6020B 0.24 J 0.40 0.081 mg/kg 1 Beryllium 7440-41-7 6020B 0.40 0.081 0.016 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.020 0.0081 mg/kg 1 Cobalt 7440-48-4 6020B 1.6 0.56 0.20 mg/kg 1 Lead 7439-92-1 6020B 2.7 0.20 0.040 mg/kg 1 Selenium 7782-49-2 6020B 1.0 1.0 0.20 mg/kg 1 Thallium 7440-28-0 6020B 0.030 J 0.10 0.021 mg/kg 1 Vanadium 7440-62-2 6020B 9.6 1.0 0.20 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 39 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-007 Description: 2017024741 Matrix: Solid Date Sampled:07/19/2017 0903 Project Name: J17070433 % Solids: 97.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1604 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.084 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 40 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-008 Description: 2017024742 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 83.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1550 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1550 TAF 47889 1 (pH) 9045D 1 07/20/2017 1640 MSG 47114 1 (Sulfate (Sol) 9056A 1 07/27/2017 1550 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 41 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 6.0 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.32 0.24 0.029 mg/kg 1 pH 9045D 6.03 su 1 Sulfate (soluble) 9056A 19 12 6.0 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 41 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-008 Description: 2017024742 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 83.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0347 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/04/2017 1615 MJI 07/20/2017 1906 47096 3 3050B 601 OD 1 08/07/2017 1630 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 42 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 25000 43 16 mg/kg 2 Barium 7440-39-3 6010D 48 1.4 0.35 mg/kg 1 Boron 7440-42-8 6010D 2.7 2.7 1.1 mg/kg 1 Calcium 7440-70-2 6010D 720 270 33 mg/kg 1 Chromium 7440-47-3 6010D 22 0.53 0.13 mg/kg 1 Copper 7440-50-8 6010D 15 1.1 0.48 mg/kg 2 Iron 7439-89-6 6010D 21000 5.3 2.4 mg/kg 1 Magnesium 7439-95-4 6010D 960 270 33 mg/kg 1 Manganese 7439-96-5 6010D 78 0.80 0.32 mg/kg 1 Molybdenum 7439-98-7 6010D 0.58 J 2.1 0.53 mg/kg 1 Nickel 7440-02-0 6010D 3.3 2.1 0.56 mg/kg 1 Potassium 7440-09-7 6010D 260 J 270 33 mg/kg 1 Sodium 7440-23-5 6010D ND 530 67 mg/kg 2 Strontium 7440-24-6 6010D 11 1.1 0.27 mg/kg 3 Zinc 7440-66-6 6010D 19 5.3 1.3 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 42 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-008 Description: 2017024742 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 83.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1841 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 43 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.53 0.11 mg/kg 1 Arsenic 7440-38-2 6020B 1.1 0.53 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.40 0.11 0.021 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.026 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 3.9 0.74 0.26 mg/kg 1 Lead 7439-92-1 6020B 7.9 0.26 0.053 mg/kg 1 Selenium 7782-49-2 6020B 0.31 J 1.4 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.16 0.14 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 64 1.4 0.26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 43 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-008 Description: 2017024742 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 83.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1606 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 0.030 J 0.087 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 44 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-009 Description: 2017024743 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 92.5 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1615 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1615 TAF 47889 1 (pH) 9045D 1 07/20/2017 1642 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1615 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 45 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.8 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.066 J 0.22 0.026 mg/kg 1 pH 9045D 6.1 su 1 Sulfate (soluble) 9056A ND 11 5.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 45 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-009 Description: 2017024743 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 92.5 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0352 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1635 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 46 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 24000 20 7.7 mg/kg 1 Barium 7440-39-3 6010D 160 1.3 0.33 mg/kg 1 Boron 7440-42-8 6010D 1.1 J 2.6 1.0 mg/kg 1 Calcium 7440-70-2 6010D 1100 260 32 mg/kg 1 Chromium 7440-47-3 6010D 7.4 0.51 0.13 mg/kg 1 Copper 7440-50-8 6010D 32 0.51 0.23 mg/kg 1 Iron 7439-89-6 6010D 19000 5.1 2.3 mg/kg 1 Magnesium 7439-95-4 6010D 5400 260 32 mg/kg 1 Manganese 7439-96-5 6010D 120 0.77 0.30 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.0 0.51 mg/kg 1 Nickel 7440-02-0 6010D 4.4 2.0 0.54 mg/kg 1 Potassium 7440-09-7 6010D 3000 260 32 mg/kg 1 Sodium 7440-23-5 6010D 320 260 32 mg/kg 1 Strontium 7440-24-6 6010D 31 1.0 0.26 mg/kg 2 Zinc 7440-66-6 6010D 31 2.6 0.64 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 46 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-009 Description: 2017024743 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 92.5 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1847 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 47 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.52 0.10 mg/kg 1 Arsenic 7440-38-2 6020B 0.45 J 0.52 0.10 mg/kg 1 Beryllium 7440-41-7 6020B 0.34 0.10 0.021 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.026 0.010 mg/kg 1 Cobalt 7440-48-4 6020B 8.5 0.73 0.26 mg/kg 1 Lead 7439-92-1 6020B 2.1 0.26 0.052 mg/kg 1 Selenium 7782-49-2 6020B 0.57 J 1.3 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.10 J 0.13 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 48 1.3 0.26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 47 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-009 Description: 2017024743 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 92.5 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1613 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.089 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 48 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-010 Description: 2017024744 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 90.2 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1820 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1820 TAF 47889 1 (pH) 9045D 1 07/20/2017 1643 MSG 47114 1 (Sulfate (Sol) 9056A 1 07/27/2017 1820 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 49 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 29 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.47 0.22 0.027 mg/kg 1 pH 9045D 5.4 su 1 Sulfate (soluble) 9056A 28 11 5.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 49 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-010 Description: 2017024744 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 90.2 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0356 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/04/2017 1620 MJI 07/20/2017 1906 47096 3 3050B 601 OD 1 08/07/2017 1648 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 50 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 27000 42 16 mg/kg 2 Barium 7440-39-3 6010D 97 1.4 0.34 mg/kg 1 Boron 7440-42-8 6010D 1.2 J 2.6 1.1 mg/kg 1 Calcium 7440-70-2 6010D 590 260 33 mg/kg 1 Chromium 7440-47-3 6010D 9.0 0.53 0.13 mg/kg 1 Copper 7440-50-8 6010D 69 1.1 0.48 mg/kg 2 Iron 7439-89-6 6010D 22000 5.3 2.4 mg/kg 1 Magnesium 7439-95-4 6010D 5100 260 33 mg/kg 1 Manganese 7439-96-5 6010D 97 0.79 0.31 mg/kg 1 Molybdenum 7439-98-7 6010D 0.61 J 2.1 0.53 mg/kg 1 Nickel 7440-02-0 6010D 4.2 2.1 0.55 mg/kg 1 Potassium 7440-09-7 6010D 1600 260 33 mg/kg 1 Sodium 7440-23-5 6010D 180 J 530 66 mg/kg 2 Strontium 7440-24-6 6010D 16 1.1 0.26 mg/kg 3 Zinc 7440-66-6 6010D 31 5.3 1.3 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 50 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-010 Description: 2017024744 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 90.2 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1853 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 51 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.53 0.11 mg/kg 1 Arsenic 7440-38-2 6020B 0.39 J 0.53 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.26 0.11 0.021 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.026 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 6.6 0.74 0.26 mg/kg 1 Lead 7439-92-1 6020B 4.5 0.26 0.053 mg/kg 1 Selenium 7782-49-2 6020B 0.53 J 1.4 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.049 J 0.14 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 54 1.4 0.26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 51 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-010 Description: 2017024744 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 90.2 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1615 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.084 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 52 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-011 Description: 2017024745 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 95.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1845 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1845 TAF 47889 1 (pH) 9045D 1 07/20/2017 1644 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1845 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 53 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.2 J 10 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.095 J 0.21 0.026 mg/kg 1 pH 9045D 6.54 su 1 Sulfate (soluble) 9056A ND 10 5.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 53 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-011 Description: 2017024745 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 95.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0401 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1653 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 54 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 13000 17 6.3 mg/kg 1 Barium 7440-39-3 6010D 110 1.1 0.27 mg/kg 1 Boron 7440-42-8 6010D ND 2.1 0.84 mg/kg 1 Calcium 7440-70-2 6010D 2000 210 26 mg/kg 1 Chromium 7440-47-3 6010D 3.8 0.42 0.10 mg/kg 1 Copper 7440-50-8 6010D 69 0.42 0.19 mg/kg 1 Iron 7439-89-6 6010D 15000 4.2 1.9 mg/kg 1 Magnesium 7439-95-4 6010D 4300 210 26 mg/kg 1 Manganese 7439-96-5 6010D 110 0.63 0.25 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.7 0.42 mg/kg 1 Nickel 7440-02-0 6010D 3.4 1.7 0.44 mg/kg 1 Potassium 7440-09-7 6010D 2300 210 26 mg/kg 1 Sodium 7440-23-5 6010D 330 210 26 mg/kg 1 Strontium 7440-24-6 6010D 29 0.84 0.21 mg/kg 2 Zinc 7440-66-6 6010D 34 2.1 0.52 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 54 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-011 Description: 2017024745 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 95.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1858 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 55 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.47 0.094 mg/kg 1 Arsenic 7440-38-2 6020B 0.13 J 0.47 0.094 mg/kg 1 Beryllium 7440-41-7 6020B 0.59 0.094 0.019 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.024 0.0094 mg/kg 1 Cobalt 7440-48-4 6020B 8.0 0.66 0.24 mg/kg 1 Lead 7439-92-1 6020B 1.1 0.24 0.047 mg/kg 1 Selenium 7782-49-2 6020B 0.74 J 1.2 0.24 mg/kg 1 Thallium 7440-28-0 6020B 0.040 J 0.12 0.025 mg/kg 1 Vanadium 7440-62-2 6020B 45 1.2 0.24 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 55 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-011 Description: 2017024745 Matrix: Solid Date Sampled:07/19/2017 1125 Project Name: J17070433 % Solids: 95.8 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1622 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.084 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 56 of 136 ICP -AES Metals Client: Duke Energy Laboratory ID: SG20031-012 Description: 2017024746 Matrix: Aqueous Date Sampled:07/19/2017 0908 Project Name: J17070433 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 601 OD 1 07/30/2017 0022 DDD 07/20/2017 1725 47095 2 3005A 601 OD 1 08/07/2017 1407 CJZ 07/20/2017 1725 47095 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 57 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D ND 0.40 0.10 mg/L 1 Barium 7440-39-3 6010D ND 0.025 0.0031 mg/L 1 Boron 7440-42-8 6010D ND 0.050 0.020 mg/L 1 Calcium 7440-70-2 6010D ND 5.0 0.63 mg/L 1 Chromium 7440-47-3 6010D 0.0014 J 0.010 0.0013 mg/L 1 Copper 7440-50-8 6010D ND 0.010 0.0020 mg/L 1 Iron 7439-89-6 6010D 0.58 0.10 0.040 mg/L 1 Magnesium 7439-95-4 6010D ND 5.0 0.63 mg/L 1 Manganese 7439-96-5 6010D 0.0032 J 0.015 0.0019 mg/L 1 Molybdenum 7439-98-7 6010D ND 0.040 0.0050 mg/L 1 Nickel 7440-02-0 6010D ND 0.040 0.0050 mg/L 1 Potassium 7440-09-7 6010D ND 5.0 0.63 mg/L 1 Sodium 7440-23-5 6010D ND 5.0 0.63 mg/L 1 Strontium 7440-24-6 6010D ND 0.010 0.0025 mg/L 2 Zinc 7440-66-6 6010D 0.0084 J 0.020 0.0025 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 57 of 136 ICP -MS Metals Client: Duke Energy Laboratory ID: SG20031-012 Description: 2017024746 Matrix: Aqueous Date Sampled:07/19/2017 0908 Project Name: J17070433 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 07/28/2017 1234 BNW 07/26/2017 1647 47571 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 58 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.13 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 0.63 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.13 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 1.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 58 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-012 Description: 2017024746 Matrix: Aqueous Date Sampled:07/19/2017 0908 Project Name: J17070433 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 7470A 1 07/26/2017 1732 COH 07/26/2017 1153 47504 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00010 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 59 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-013 Description: 2017024747 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 80.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1910 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1910 TAF 47889 1 (pH) 9045D 1 07/20/2017 1645 MSG 47114 1 (Sulfate (Sol) 9056A 1 07/27/2017 1910 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 60 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 7.9 J 12 1.3 mg/kg 1 Nitrate - N (soluble) 9056A 0.47 0.25 0.031 mg/kg 1 pH 9045D 5.53 su 1 Sulfate (soluble) 9056A 13 12 6.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 60 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-013 Description: 2017024747 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 80.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0414 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/04/2017 1633 MJI 07/20/2017 1906 47096 3 3050B 601 OD 1 08/07/2017 1658 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 61 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 28000 45 17 mg/kg 2 Barium 7440-39-3 6010D 130 1.5 0.37 mg/kg 1 Boron 7440-42-8 6010D 1.4 J 2.8 1.1 mg/kg 1 Calcium 7440-70-2 6010D 160 J 280 35 mg/kg 1 Chromium 7440-47-3 6010D 4.3 0.57 0.14 mg/kg 1 Copper 7440-50-8 6010D 38 1.1 0.51 mg/kg 2 Iron 7439-89-6 6010D 21000 5.7 2.6 mg/kg 1 Magnesium 7439-95-4 6010D 4000 280 35 mg/kg 1 Manganese 7439-96-5 6010D 160 0.85 0.34 mg/kg 1 Molybdenum 7439-98-7 6010D 0.62 J 2.3 0.57 mg/kg 1 Nickel 7440-02-0 6010D 1.7 J 2.3 0.60 mg/kg 1 Potassium 7440-09-7 6010D 3000 280 35 mg/kg 1 Sodium 7440-23-5 6010D 91 J 570 71 mg/kg 2 Strontium 7440-24-6 6010D 7.7 1.1 0.28 mg/kg 3 Zinc 7440-66-6 6010D 53 5.7 1.4 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 61 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-013 Description: 2017024747 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 80.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1904 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 62 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.59 0.12 mg/kg 1 Arsenic 7440-38-2 6020B 0.44 J 0.59 0.12 mg/kg 1 Beryllium 7440-41-7 6020B 0.50 0.12 0.024 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.030 0.012 mg/kg 1 Cobalt 7440-48-4 6020B 4.6 0.83 0.30 mg/kg 1 Lead 7439-92-1 6020B 3.8 0.30 0.059 mg/kg 1 Selenium 7782-49-2 6020B 0.35 J 1.5 0.30 mg/kg 1 Thallium 7440-28-0 6020B 0.10 J 0.15 0.031 mg/kg 1 Vanadium 7440-62-2 6020B 43 1.5 0.30 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 62 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-013 Description: 2017024747 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 80.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1624 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.10 0.025 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 63 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID:SG20031-014 Description: 2017024748 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 81.6 07/21/2017 2345 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 1935 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 1935 TAF 47889 1 (pH) 9045D 1 07/20/2017 1646 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 1935 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 64 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 11 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.080 J 0.25 0.030 mg/kg 1 pH 9045D 5.65 su 1 Sulfate (soluble) 9056A ND 12 6.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 64 of 136 ICP -AES Client: Duke Energy Laboratory ID:SG20031-014 Description: 2017024748 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 81.6 07/21/2017 2345 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0419 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/04/2017 1637 MJI 07/20/2017 1906 47096 3 3050B 601 OD 1 08/07/2017 1702 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 65 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 31000 43 16 mg/kg 2 Barium 7440-39-3 6010D 120 1.4 0.35 mg/kg 1 Boron 7440-42-8 6010D 1.3 J 2.7 1.1 mg/kg 1 Calcium 7440-70-2 6010D 250 J 270 33 mg/kg 1 Chromium 7440-47-3 6010D 4.1 0.53 0.13 mg/kg 1 Copper 7440-50-8 6010D 29 1.1 0.48 mg/kg 2 Iron 7439-89-6 6010D 21000 5.3 2.4 mg/kg 1 Magnesium 7439-95-4 6010D 4100 270 33 mg/kg 1 Manganese 7439-96-5 6010D 360 0.80 0.31 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.1 0.53 mg/kg 1 Nickel 7440-02-0 6010D 1.9 J 2.1 0.56 mg/kg 1 Potassium 7440-09-7 6010D 2500 270 33 mg/kg 1 Sodium 7440-23-5 6010D 130 J 530 66 mg/kg 2 Strontium 7440-24-6 6010D 10 1.1 0.27 mg/kg 3 Zinc 7440-66-6 6010D 54 5.3 1.3 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 65 of 136 ICP -MS Client: Duke Energy Laboratory ID:SG20031-014 Description: 2017024748 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 81.6 07/21/2017 2345 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1910 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 66 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.56 0.11 mg/kg 1 Arsenic 7440-38-2 6020B 0.60 0.56 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.57 0.11 0.022 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.028 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 28 0.78 0.28 mg/kg 1 Lead 7439-92-1 6020B 5.6 0.28 0.056 mg/kg 1 Selenium 7782-49-2 6020B 1.1 J 1.5 0.28 mg/kg 1 Thallium 7440-28-0 6020B 0.083 J 0.15 0.029 mg/kg 1 Vanadium 7440-62-2 6020B 36 1.5 0.28 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 66 of 136 CVAA Client: Duke Energy Laboratory ID:SG20031-014 Description: 2017024748 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 81.6 07/21/2017 2345 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1626 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.097 0.023 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 67 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-015 Description: 2017024749 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 87.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 2000 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 2000 TAF 47889 1 (pH) 9045D 1 07/20/2017 1647 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 2000 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 68 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 45 11 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.35 0.23 0.028 mg/kg 1 pH 9045D 5.3 su 1 Sulfate (soluble) 9056A ND 11 5.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 68 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-015 Description: 2017024749 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 87.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0424 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1707 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 69 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 16000 19 7.3 mg/kg 1 Barium 7440-39-3 6010D 77 1.3 0.31 mg/kg 1 Boron 7440-42-8 6010D ND 2.4 0.97 mg/kg 1 Calcium 7440-70-2 6010D 460 240 30 mg/kg 1 Chromium 7440-47-3 6010D 4.1 0.48 0.12 mg/kg 1 Copper 7440-50-8 6010D 60 0.48 0.22 mg/kg 1 Iron 7439-89-6 6010D 14000 4.8 2.2 mg/kg 1 Magnesium 7439-95-4 6010D 2700 240 30 mg/kg 1 Manganese 7439-96-5 6010D 110 0.73 0.29 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.9 0.48 mg/kg 1 Nickel 7440-02-0 6010D 2.0 1.9 0.51 mg/kg 1 Potassium 7440-09-7 6010D 1400 240 30 mg/kg 1 Sodium 7440-23-5 6010D 98 J 240 30 mg/kg 1 Strontium 7440-24-6 6010D 14 0.97 0.24 mg/kg 2 Zinc 7440-66-6 6010D 23 2.4 0.60 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 69 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-015 Description: 2017024749 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 87.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1928 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 70 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.27 BJ 0.48 0.096 mg/kg 1 Arsenic 7440-38-2 6020B 0.40 J 0.48 0.096 mg/kg 1 Beryllium 7440-41-7 6020B 0.96 0.096 0.019 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.024 0.0096 mg/kg 1 Cobalt 7440-48-4 6020B 8.7 0.67 0.24 mg/kg 1 Lead 7439-92-1 6020B 2.4 0.24 0.048 mg/kg 1 Selenium 7782-49-2 6020B 1.1 J 1.3 0.24 mg/kg 1 Thallium 7440-28-0 6020B 0.047 J 0.13 0.025 mg/kg 1 Vanadium 7440-62-2 6020B 39 1.3 0.24 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 70 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-015 Description: 2017024749 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 87.0 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1628 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.091 0.022 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 71 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-016 Description: 2017024750 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 82.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 2025 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 2025 TAF 47889 1 (pH) 9045D 1 07/20/2017 1648 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 2025 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 72 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 5.5 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.064 J 0.24 0.030 mg/kg 1 pH 9045D 7.63 su 1 Sulfate (soluble) 9056A ND 12 6.0 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 72 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-016 Description: 2017024750 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 82.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0428 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1711 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 73 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 21000 22 8.2 mg/kg 1 Barium 7440-39-3 6010D 220 1.4 0.35 mg/kg 1 Boron 7440-42-8 6010D 1.2 J 2.7 1.1 mg/kg 1 Calcium 7440-70-2 6010D 1100 270 34 mg/kg 1 Chromium 7440-47-3 6010D 2.0 0.54 0.14 mg/kg 1 Copper 7440-50-8 6010D 90 0.54 0.24 mg/kg 1 Iron 7439-89-6 6010D 23000 5.4 2.5 mg/kg 1 Magnesium 7439-95-4 6010D 5900 270 34 mg/kg 1 Manganese 7439-96-5 6010D 310 0.82 0.32 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.2 0.54 mg/kg 1 Nickel 7440-02-0 6010D ND 2.2 0.57 mg/kg 1 Potassium 7440-09-7 6010D 5500 270 34 mg/kg 1 Sodium 7440-23-5 6010D 90 J 270 34 mg/kg 1 Strontium 7440-24-6 6010D 21 1.1 0.27 mg/kg 2 Zinc 7440-66-6 6010D 43 2.7 0.68 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 73 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-016 Description: 2017024750 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 82.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1934 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 74 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.56 0.11 mg/kg 1 Arsenic 7440-38-2 6020B 0.42 J 0.56 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.74 0.11 0.022 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.028 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 14 0.78 0.28 mg/kg 1 Lead 7439-92-1 6020B 1.9 0.28 0.056 mg/kg 1 Selenium 7782-49-2 6020B 0.99 J 1.4 0.28 mg/kg 1 Thallium 7440-28-0 6020B 0.12 J 0.14 0.029 mg/kg 1 Vanadium 7440-62-2 6020B 36 1.4 0.28 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 74 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-016 Description: 2017024750 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 82.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1630 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.095 0.023 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 75 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-017 Description: 2017024751 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 86.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 2050 TAF 47885 1 (Nitrate - N ) 9056A 1 07/27/2017 2050 TAF 47889 1 (pH) 9045D 1 07/20/2017 1649 MSG 47114 1 (Sulfate (sol) 9056A 1 07/27/2017 2050 TAF 47887 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 76 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 3.9 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.054 J 0.23 0.028 mg/kg 1 pH 9045D 7.55 su 1 Sulfate (soluble) 9056A ND 12 5.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 76 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-017 Description: 2017024751 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 86.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0433 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1716 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 77 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 19000 22 8.4 mg/kg 1 Barium 7440-39-3 6010D 130 1.5 0.36 mg/kg 1 Boron 7440-42-8 6010D ND 2.8 1.1 mg/kg 1 Calcium 7440-70-2 6010D 1200 280 35 mg/kg 1 Chromium 7440-47-3 6010D 7.3 0.56 0.14 mg/kg 1 Copper 7440-50-8 6010D 6.6 0.56 0.25 mg/kg 1 Iron 7439-89-6 6010D 17000 5.6 2.6 mg/kg 1 Magnesium 7439-95-4 6010D 6600 280 35 mg/kg 1 Manganese 7439-96-5 6010D 230 0.84 0.33 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.2 0.56 mg/kg 1 Nickel 7440-02-0 6010D 3.3 2.2 0.59 mg/kg 1 Potassium 7440-09-7 6010D 6500 280 35 mg/kg 1 Sodium 7440-23-5 6010D 100 J 280 35 mg/kg 1 Strontium 7440-24-6 6010D 23 1.1 0.28 mg/kg 2 Zinc 7440-66-6 6010D 36 2.8 0.70 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 77 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-017 Description: 2017024751 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 86.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1939 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 78 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.54 0.11 mg/kg 1 Arsenic 7440-38-2 6020B 0.12 J 0.54 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.71 0.11 0.022 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.027 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 8.9 0.76 0.27 mg/kg 1 Lead 7439-92-1 6020B 1.4 0.27 0.054 mg/kg 1 Selenium 7782-49-2 6020B 0.33 J 1.4 0.27 mg/kg 1 Thallium 7440-28-0 6020B 0.10 J 0.14 0.028 mg/kg 1 Vanadium 7440-62-2 6020B 37 1.4 0.27 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 78 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-017 Description: 2017024751 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 86.7 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1632 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.095 0.023 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 79 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-018 Description: 2017024752 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 91.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 2255 TAF 47886 1 (Nitrate - N ) 9056A 1 07/27/2017 2255 TAF 47890 1 (pH) 9045D 1 07/20/2017 1843 MSG 47116 1 (Sulfate (sol) 9056A 1 07/27/2017 2255 TAF 47888 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 80 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 1.3 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.038 J 0.22 0.027 mg/kg 1 pH 9045D 6.42 su 1 Sulfate (soluble) 9056A ND 11 5.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 80 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-018 Description: 2017024752 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 91.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0438 DDD 07/20/2017 1906 47096 2 3050B 601 OD 1 08/07/2017 1721 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 81 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 14000 18 6.7 mg/kg 1 Barium 7440-39-3 6010D 130 1.2 0.29 mg/kg 1 Boron 7440-42-8 6010D 0.98 J 2.2 0.90 mg/kg 1 Calcium 7440-70-2 6010D 850 220 28 mg/kg 1 Chromium 7440-47-3 6010D 3.0 0.45 0.11 mg/kg 1 Copper 7440-50-8 6010D 2.5 0.45 0.20 mg/kg 1 Iron 7439-89-6 6010D 15000 4.5 2.0 mg/kg 1 Magnesium 7439-95-4 6010D 5000 220 28 mg/kg 1 Manganese 7439-96-5 6010D 270 0.67 0.27 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.8 0.45 mg/kg 1 Nickel 7440-02-0 6010D 2.2 1.8 0.47 mg/kg 1 Potassium 7440-09-7 6010D 5300 220 28 mg/kg 1 Sodium 7440-23-5 6010D 96 J 220 28 mg/kg 1 Strontium 7440-24-6 6010D 18 0.90 0.22 mg/kg 2 Zinc 7440-66-6 6010D 35 2.2 0.56 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 81 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-018 Description: 2017024752 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 91.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1945 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 82 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.43 0.086 mg/kg 1 Arsenic 7440-38-2 6020B 0.20 J 0.43 0.086 mg/kg 1 Beryllium 7440-41-7 6020B 0.54 0.086 0.017 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.022 0.0086 mg/kg 1 Cobalt 7440-48-4 6020B 7.1 0.60 0.22 mg/kg 1 Lead 7439-92-1 6020B 1.2 0.22 0.043 mg/kg 1 Selenium 7782-49-2 6020B 0.49 J 1.1 0.22 mg/kg 1 Thallium 7440-28-0 6020B 0.11 0.11 0.022 mg/kg 1 Vanadium 7440-62-2 6020B 32 1.1 0.22 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 82 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-018 Description: 2017024752 Matrix: Solid Date Sampled:07/19/2017 1230 Project Name: J17070433 % Solids: 91.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1639 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.083 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 83 of 136 Inorganic non-metals Client: Duke Energy Laboratory ID: SG20031-019 Description: 2017024753 Matrix: Solid Date Sampled:07/19/2017 1340 Project Name: J17070433 % Solids: 88.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 2320 TAF 47886 1 (Nitrate - N ) 9056A 1 07/27/2017 2320 TAF 47890 1 (pH) 9045D 1 07/20/2017 1845 MSG 47116 1 (Sulfate (sol) 9056A 1 07/27/2017 2320 TAF 47888 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 84 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.6 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.17 J 0.23 0.028 mg/kg 1 pH 9045D 4.9 su 1 Sulfate (soluble) 9056A ND 11 5.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 84 of 136 ICP -AES Client: Duke Energy Laboratory ID: SG20031-019 Description: 2017024753 Matrix: Solid Date Sampled:07/19/2017 1340 Project Name: J17070433 % Solids: 88.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/30/2017 0442 DDD 07/20/2017 1906 47096 2 3050B 601 OD 2 08/04/2017 1642 MJI 07/20/2017 1906 47096 3 3050B 601 OD 1 08/07/2017 1725 CJZ 07/20/2017 1906 47096 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 85 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 16000 19 7.2 mg/kg 1 Barium 7440-39-3 6010D 55 1.2 0.31 mg/kg 1 Boron 7440-42-8 6010D ND 4.8 1.9 mg/kg 2 Calcium 7440-70-2 6010D 1000 240 30 mg/kg 1 Chromium 7440-47-3 6010D 34 0.96 0.24 mg/kg 2 Copper 7440-50-8 6010D 14 0.96 0.43 mg/kg 2 Iron 7439-89-6 6010D 27000 9.6 4.4 mg/kg 2 Magnesium 7439-95-4 6010D 980 480 60 mg/kg 2 Manganese 7439-96-5 6010D 700 1.4 0.57 mg/kg 2 Molybdenum 7439-98-7 6010D 0.54 J 1.9 0.48 mg/kg 1 Nickel 7440-02-0 6010D 4.4 3.8 1.0 mg/kg 2 Potassium 7440-09-7 6010D 240 240 30 mg/kg 1 Sodium 7440-23-5 6010D 50 J 240 30 mg/kg 1 Strontium 7440-24-6 6010D 8.3 0.96 0.24 mg/kg 3 Zinc 7440-66-6 6010D 24 2.4 0.60 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 85 of 136 ICP -MS Client: Duke Energy Laboratory ID: SG20031-019 Description: 2017024753 Matrix: Solid Date Sampled:07/19/2017 1340 Project Name: J17070433 % Solids: 88.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/28/2017 1951 BNW 07/20/2017 1849 47097 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 86 of 136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.54 0.11 mg/kg 1 Arsenic 7440-38-2 6020B 3.2 0.54 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.70 0.11 0.021 mg/kg 1 Cadmium 7440-43-9 6020B 0.064 0.027 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 44 0.75 0.27 mg/kg 1 Lead 7439-92-1 6020B 14 0.27 0.054 mg/kg 1 Selenium 7782-49-2 6020B 0.83 J 1.4 0.27 mg/kg 1 Thallium 7440-28-0 6020B 0.095 J 0.14 0.028 mg/kg 1 Vanadium 7440-62-2 6020B 77 1.4 0.27 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 86 of 136 CVAA Client: Duke Energy Laboratory ID: SG20031-019 Description: 2017024753 Matrix: Solid Date Sampled:07/19/2017 1340 Project Name: J17070433 % Solids: 88.1 07/20/2017 2238 Date Received: 07/20/2017 Project Number: J17070433 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 07/21/2017 1641 COH 07/21/2017 1425 47136 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 0.051 J 0.094 0.023 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 87 of 136 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: SG20031 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 88 of 136 Inorganic non-metals - Duplicate Sample ID: SG20031-OO8DU Matrix: Solid Batch:47114 Analytical Method: 9045D Sample Amount Result % RPD Parameter (su) (mg/L) Q Dil % RPD Limit Analysis Date pH 6.03 6.04 1 0.17 20 07/20/20171642 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 89 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - Duplicate Sample ID: SG20031-018DU Matrix: Solid Batch:47116 Analytical Method: 9045D Sample Amount Result % RPD Parameter (su) (mg/L) Q Dil % RPD Limit Analysis Date pH 6.42 6.6 1 2.8 20 07/20/20171844 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 90 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47788-001 Matrix: Solid Batch:47788 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride (soluble) ND 1 10 1.0 mg/kg 07/26/2017 1712 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 91 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47788-002 Matrix: Solid Batch:47788 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 20 20 1 100 80-120 07/26/2017 1736 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 92 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47789-001 Matrix: Solid Batch:47789 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N (soluble) ND 1 0.20 0.025 mg/kg 07/26/2017 1712 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 93 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47789-002 Matrix: Solid Batch:47789 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.80 0.79 1 98 87-111 07/26/2017 1736 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 94 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47790-001 Matrix: Solid Batch:47790 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate (soluble) ND 1 10 5.0 mg/kg 07/26/2017 1712 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 95 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ4779O-002 Matrix: Solid Batch:47790 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) 20 19 1 97 80-120 07/26/2017 1736 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 96 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47885-001 Matrix: Solid Batch:47885 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride (soluble) ND 1 10 1.0 mg/kg 07/27/2017 1254 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 97 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47885-002 Matrix: Solid Batch:47885 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 20 20 1 101 80-120 07/27/2017 1319 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 98 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MS Sample ID: SG20031-OO9MS Matrix: Solid Batch:47885 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 2.8 200 220 1 106 80-120 07/27/2017 1640 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 99 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MSD Sample ID: SG20031-OO9MD Matrix: Solid Batch:47885 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride (soluble) 2.8 200 220 1 107 0.20 80-120 20 07/27/2017 1755 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 100 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47886-001 Matrix: Solid Batch:47886 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride (soluble) ND 1 10 1.0 mg/kg 07/27/2017 2205 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 101 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47886-002 Matrix: Solid Batch:47886 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 20 20 1 101 80-120 07/27/2017 2230 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 102 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47887-001 Matrix: Solid Batch:47887 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate (soluble) ND 1 10 5.0 mg/kg 07/27/2017 1254 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 103 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47887-002 Matrix: Solid Batch:47887 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) 20 20 1 101 80-120 07/27/2017 1319 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 104 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MS Sample ID: SG20031-OO9MS Matrix: Solid Batch:47887 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) ND 200 210 1 106 80-120 07/27/2017 1640 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 105 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MSD Sample ID: SG20031-OO9MD Matrix: Solid Batch:47887 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate (soluble) ND 200 210 1 105 0.44 80-120 20 07/27/2017 1755 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 106 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47888-001 Matrix: Solid Batch:47888 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate (soluble) ND 1 10 5.0 mg/kg 07/27/2017 2205 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 107 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47888-002 Matrix: Solid Batch:47888 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) 20 20 1 101 80-120 07/27/2017 2230 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 108 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47889-001 Matrix: Solid Batch:47889 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N (soluble) ND 1 0.20 0.025 mg/kg 07/27/2017 1254 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 109 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ47889-002 Matrix: Solid Batch:47889 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.80 0.78 1 98 87-111 07/27/2017 1319 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 110 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MS Sample ID: SG20031-OO9MS Matrix: Solid Batch:47889 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.066 8.0 8.0 1 99 87-111 07/27/2017 1640 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 111 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MSD Sample ID: SG20031-OO9MD Matrix: Solid Batch:47889 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Nitrate - N (soluble) 0.066 8.0 7.8 1 97 2.2 87-111 20 07/27/2017 1755 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 112 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - MB Sample ID: SQ47890-001 Matrix: Solid Batch:47890 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N (soluble) ND 1 0.20 0.025 mg/kg 07/27/2017 2205 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 113 of 136 QC Data for Lot Number: SG20031 Inorganic non-metals - LCS Sample ID: SQ4789O-002 Matrix: Solid Batch:47890 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.80 0.81 1 101 87-111 07/27/2017 2230 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 114 of 136 QC Data for Lot Number: SG20031 ICP -AES Metals - MB Sample ID: SQ47095-001 Matrix: Aqueous Batch:47095 Prep Method: 3005A Analytical Method: 6010D Prep Date: 07/20/2017 1725 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 0.40 0.10 mg/L 07/30/2017 0013 Barium ND 1 0.025 0.0031 mg/L 07/30/2017 0013 Boron ND 1 0.050 0.020 mg/L 07/30/2017 0013 Calcium ND 1 5.0 0.63 mg/L 07/30/2017 0013 Chromium ND 1 0.010 0.0013 mg/L 07/30/2017 0013 Copper ND 1 0.010 0.0020 mg/L 07/30/2017 0013 Iron ND 1 0.10 0.040 mg/L 07/30/2017 0013 Magnesium ND 1 5.0 0.63 mg/L 07/30/2017 0013 Manganese ND 1 0.015 0.0019 mg/L 07/30/2017 0013 Molybdenum ND 1 0.040 0.0050 mg/L 07/30/2017 0013 Nickel ND 1 0.040 0.0050 mg/L 07/30/2017 0013 Potassium ND 1 5.0 0.63 mg/L 07/30/2017 0013 Sodium ND 1 5.0 0.63 mg/L 07/30/2017 0013 Strontium ND 1 0.010 0.0025 mg/L 08/07/20171358 Zinc ND 1 0.020 0.0025 mg/L 07/30/2017 0013 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 115 of 136 QC Data for Lot Number: SG20031 ICP -AES Metals - LCS Sample ID: SQ47O95-002 Matrix: Aqueous Batch:47095 Prep Method: 3OO5A Analytical Method: 6010D Prep Date: 07/20/2017 1725 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Aluminum 20 21 1 103 80-120 07/30/2017 0018 Barium 2.0 2.1 1 104 80-120 07/30/2017 0018 Boron 0.40 0.44 1 110 80-120 07/30/2017 0018 Calcium 40 41 1 104 80-120 07/30/2017 0018 Chromium 2.0 2.1 1 103 80-120 07/30/2017 0018 Copper 2.0 2.1 1 104 80-120 07/30/2017 0018 Iron 20 21 1 104 80-120 07/30/2017 0018 Magnesium 40 41 1 101 80-120 07/30/2017 0018 Manganese 2.0 2.1 1 104 80-120 07/30/2017 0018 Molybdenum 2.0 2.1 1 105 80-120 07/30/2017 0018 Nickel 2.0 2.2 1 109 80-120 07/30/2017 0018 Potassium 40 42 1 104 80-120 07/30/2017 0018 Sodium 40 42 1 105 80-120 07/30/2017 0018 Strontium 1.0 1.0 1 102 80-120 08/07/20171403 Zinc 2.0 2.2 1 108 80-120 07/30/2017 0018 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 116 of 136 QC Data for Lot Number: SG20031 ICP -AES - MB Sample ID: SQ47096-001 Matrix: Solid Batch:47096 Prep Method: 3050B Analytical Method: 6010D Prep Date: 07/20/2017 1906 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 20 7.5 mg/kg 07/30/2017 0239 Barium ND 1 1.3 0.33 mg/kg 07/30/2017 0239 Boron ND 1 2.5 1.0 mg/kg 07/30/2017 0239 Calcium ND 1 250 31 mg/kg 07/30/2017 0239 Chromium ND 1 0.50 0.13 mg/kg 07/30/2017 0239 Copper ND 1 0.50 0.23 mg/kg 07/30/2017 0239 Iron ND 1 5.0 2.3 mg/kg 07/30/2017 0239 Magnesium ND 1 250 31 mg/kg 07/30/2017 0239 Manganese ND 1 0.75 0.30 mg/kg 07/30/2017 0239 Molybdenum ND 1 2.0 0.50 mg/kg 07/30/2017 0239 Nickel ND 1 2.0 0.53 mg/kg 07/30/2017 0239 Potassium ND 1 250 31 mg/kg 07/30/2017 0239 Sodium ND 1 250 31 mg/kg 07/30/2017 0239 Strontium ND 1 1.0 0.25 mg/kg 08/07/20171448 Zinc ND 1 2.5 0.63 mg/kg 07/30/2017 0239 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 117 of 136 QC Data for Lot Number: SG20031 ICP -AES - LCS Sample ID: SQ47O96-002 Matrix: Solid Batch:47096 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 07/20/2017 1906 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Aluminum 1000 1100 1 107 80-120 07/30/2017 0243 Barium 500 540 1 109 80-120 07/30/2017 0243 Boron 50 47 1 95 80-120 07/30/2017 0243 Calcium 2000 2100 1 105 80-120 07/30/2017 0243 Chromium 250 260 1 102 80-120 07/30/2017 0243 Copper 100 110 1 106 80-120 07/30/2017 0243 Iron 1000 1100 1 105 80-120 07/30/2017 0243 Magnesium 2000 2000 1 102 80-120 07/30/2017 0243 Manganese 100 110 1 106 80-120 07/30/2017 0243 Molybdenum 100 110 1 108 80-120 07/30/2017 0243 Nickel 100 110 1 108 80-120 07/30/2017 0243 Potassium 2000 2100 1 106 80-120 07/30/2017 0243 Sodium 2000 2100 1 107 80-120 07/30/2017 0243 Strontium 50 52 1 104 80-120 08/07/20171453 Zinc 100 110 1 107 80-120 07/30/2017 0243 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 118 of 136 QC Data for Lot Number: SG20031 ICP -AES - MS Sample ID: SG20031-OOlMS Matrix: Solid Batch:47096 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 07/20/2017 1906 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Aluminum 31000 1100 37000 N 2 542 75-125 08/04/20171557 Barium 110 530 470 N 1 68 75-125 07/30/2017 0253 Boron ND 53 37 N 2 69 75-125 08/04/20171557 Calcium 2000 2100 3400 N 1 66 75-125 07/30/2017 0253 Chromium 39 270 230 N 2 71 75-125 08/04/20171557 Copper 74 110 160 2 77 75-125 08/04/20171557 Iron 35000 1100 35000 N 2 57 75-125 08/04/20171557 Magnesium 12000 2100 14000 2 85 75-125 08/04/20171557 Manganese 200 110 290 2 80 75-125 08/04/20171557 Molybdenum 0.63 110 63 N 1 58 75-125 07/30/2017 0253 Nickel 18 110 88 N 2 66 75-125 08/04/20171557 Potassium 1900 2100 3400 N 1 71 75-125 07/30/2017 0253 Sodium 700 2100 2300 2 77 75-125 08/04/20171557 Strontium 29 53 67 N 1 71 75-125 08/07/20171502 Zinc 51 110 130 N 2 72 75-125 08/04/20171557 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 119 of 136 QC Data for Lot Number: SG20031 ICP -AES - MSD Sample ID: SG20031-OOlMD Matrix: Solid Batch:47096 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 07/20/2017 1906 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 31000 1000 35000 N 2 392 4.9 75-125 20 08/04/20171602 Barium 110 510 480 N 1 73 2.2 75-125 20 07/30/2017 0257 Boron ND 51 36 N 2 70 3.0 75-125 20 08/04/20171602 Calcium 2000 2000 3400 N 1 70 1.0 75-125 20 07/30/2017 0257 Chromium 39 260 220 N 2 72 2.3 75-125 20 08/04/20171602 Copper 74 100 160 2 85 3.2 75-125 20 08/04/20171602 Iron 35000 1000 35000 N 2 33 0.74 75-125 20 08/04/20171602 Magnesium 12000 2000 14000 2 100 1.8 75-125 20 08/04/20171602 Manganese 200 100 280 N 2 72 4.1 75-125 20 08/04/20171602 Molybdenum 0.63 100 62 N 1 60 0.96 75-125 20 07/30/2017 0257 Nickel 18 100 89 N 2 69 0.47 75-125 20 08/04/20171602 Potassium 1900 2000 3600 1 83 5.3 75-125 20 07/30/2017 0257 Sodium 700 2000 2300 2 80 0.25 75-125 20 08/04/20171602 Strontium 29 51 66 N 1 72 1.5 75-125 20 08/07/20171554 Zinc 51 100 130 2 78 2.1 75-125 20 08/04/20171602 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 120 of 136 QC Data for Lot Number: SG20031 ICP -MS - MB Sample ID: SQ47097-001 Matrix: Solid Batch:47097 Prep Method: 3050B Analytical Method: 6020B Prep Date: 07/20/2017 1849 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 0.16 J 1 0.50 0.10 mg/kg 07/28/20171713 Arsenic ND 1 0.50 0.10 mg/kg 07/28/20171713 Beryllium ND 1 0.10 0.020 mg/kg 07/28/20171713 Cadmium ND 1 0.025 0.010 mg/kg 07/28/20171713 Cobalt ND 1 0.70 0.25 mg/kg 07/28/20171713 Lead ND 1 0.25 0.050 mg/kg 07/28/20171713 Selenium ND 1 1.3 0.25 mg/kg 07/28/20171713 Thallium ND 1 0.13 0.026 mg/kg 07/28/20171713 Vanadium ND 1 1.3 0.25 mg/kg 07/28/20171713 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 121 of 136 QC Data for Lot Number: SG20031 ICP -MS - LCS Sample ID: SQ47O97-002 Matrix: Solid Batch:47097 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 07/20/2017 1849 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Antimony 50 49 1 98 80-120 07/28/20171719 Arsenic 50 48 1 96 80-120 07/28/20171719 Beryllium 50 53 1 106 80-120 07/28/20171719 Cadmium 50 48 1 96 80-120 07/28/20171719 Cobalt 50 51 1 102 80-120 07/28/20171719 Lead 50 50 1 99 80-120 07/28/20171719 Selenium 50 42 1 83 80-120 07/28/20171719 Thallium 50 49 1 98 80-120 07/28/20171719 Vanadium 50 52 1 104 80-120 07/28/20171719 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 122 of 136 QC Data for Lot Number: SG20031 ICP -MS - MS Sample ID: SG20031-OOlMS Matrix: Solid Batch:47097 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 07/20/2017 1849 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Antimony ND 56 26 N 1 47 75-125 07/28/20171731 Arsenic 1.1 56 60 1 105 75-125 07/28/20171731 Beryllium 0.51 56 51 1 91 75-125 07/28/20171731 Cadmium ND 56 57 1 102 75-125 07/28/20171731 Cobalt 19 56 83 1 116 75-125 07/28/20171731 Lead 5.1 56 68 1 114 75-125 07/28/20171731 Selenium 1.2 56 51 1 89 75-125 07/28/20171731 Thallium 0.093 56 63 1 113 75-125 07/28/20171731 Vanadium 120 56 170 1 90 75-125 07/28/20171731 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 123 of 136 QC Data for Lot Number: SG20031 ICP -MS - MSD Sample ID: SG20031-OOlMD Matrix: Solid Batch:47097 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 07/20/2017 1849 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 52 19 N,+ 1 37 32 75-125 20 07/28/20171737 Arsenic 1.1 52 53 1 100 12 75-125 20 07/28/20171737 Beryllium 0.51 52 46 1 88 11 75-125 20 07/28/20171737 Cadmium ND 52 50 1 97 13 75-125 20 07/28/20171737 Cobalt 19 52 74 1 106 12 75-125 20 07/28/20171737 Lead 5.1 52 61 1 109 11 75-125 20 07/28/20171737 Selenium 1.2 52 46 1 87 9.6 75-125 20 07/28/20171737 Thallium 0.093 52 56 1 108 13 75-125 20 07/28/20171737 Vanadium 120 52 160 1 87 3.1 75-125 20 07/28/20171737 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 124 of 136 QC Data for Lot Number: SG20031 ICP -MS Metals - MB Sample ID: SQ47571-001 Matrix: Aqueous Batch:47571 Prep Method: 3005A Analytical Method: 6020B Prep Date: 07/26/2017 1647 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 07/28/20171222 Arsenic ND 1 2.0 1.3 ug/L 07/28/20171222 Beryllium ND 1 0.40 0.13 ug/L 07/28/20171222 Cadmium ND 1 0.50 0.13 ug/L 07/28/20171222 Cobalt ND 1 5.0 0.63 ug/L 07/28/20171222 Lead ND 1 1.0 0.25 ug/L 07/28/20171222 Selenium ND 1 5.0 1.3 ug/L 07/28/20171222 Thallium ND 1 0.50 0.13 ug/L 07/28/20171222 Vanadium ND 1 5.0 1.5 ug/L 07/28/20171222 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 125 of 136 QC Data for Lot Number: SG20031 ICP -MS Metals - LCS Sample ID: SQ47571-002 Matrix: Aqueous Batch:47571 Prep Method: 3OO5A Analytical Method: 60208 Prep Date: 07/26/2017 1647 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 100 80-120 07/28/20171228 Arsenic 100 100 1 104 80-120 07/28/20171228 Beryllium 100 110 1 109 80-120 07/28/20171228 Cadmium 100 100 1 100 80-120 07/28/20171228 Cobalt 100 100 1 102 80-120 07/28/20171228 Lead 100 98 1 98 80-120 07/28/20171228 Selenium 100 97 1 97 80-120 07/28/20171228 Thallium 100 96 1 96 80-120 07/28/20171228 Vanadium 100 100 1 103 80-120 07/28/20171228 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 126 of 136 QC Data for Lot Number: SG20031 CVAA - MB Sample ID: SQ47136-001 Matrix: Solid Batch:47136 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 1425 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.083 0.020 mg/kg 07/21/20171547 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 127 of 136 QC Data for Lot Number: SG20031 CVAA - LCS Sample ID: SQ47136-002 Matrix: Solid Batch:47136 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 1425 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Mercury 0.83 0.82 1 98 80-120 07/21/20171549 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 128 of 136 QC Data for Lot Number: SG20031 CVAA - MS Sample ID: SG20031-01OMS Matrix: Solid Batch:47136 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 1425 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Mercury ND 0.89 0.93 1 104 80-120 07/21/20171617 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 129 of 136 QC Data for Lot Number: SG20031 CVAA - MSD Sample ID: SG20031-01OMD Matrix: Solid Batch:47136 Prep Method: 74716 Analytical Method: 74716 Prep Date: 07/21/2017 1425 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury ND 0.92 0.86 1 93 8.2 80-120 20 07/21/20171619 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 130 of 136 QC Data for Lot Number: SG20031 CVAA - MB Sample ID: SQ47504-001 Matrix: Aqueous Batch:47504 Prep Method: 7470A Analytical Method: 7470A Prep Date: 07/26/2017 1153 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00010 0.000091 mg/L 07/26/20171630 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 131 of 136 QC Data for Lot Number: SG20031 CVAA - LCS Sample ID: SQ475O4-002 Matrix: Aqueous Batch:47504 Prep Method: 747OA Analytical Method: 7470A Prep Date: 07/26/2017 1153 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0021 1 104 80-120 07/26/20171632 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 132 of 136 QC Data for Lot Number: SG20031 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 133 of 136 SHEALY ENVIRONMENTAL SERVICES, INC. w q _ Q 7 3LLJ ,fly �liae I t � mm G � i-ocod0 kr 3 V�r�J a l i C L ^ d Z �� c+ 3 LLQ T j�ke LL.1 y' ]484. :wwnp4 ig4WAdddd■ YWldwo3 aLJNL1Mfk5 a LLJ s sx c o + T ........ _..... �!- Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 134 of 136 W01 No MEIN OEM NONE El No I NONE JIME MEIN NONNI son 11111000021 MEN ■ eoveeeaee�e■■�� �. ��ooevooedo■� � w q _ Q 7 3LLJ ,fly �liae I t � mm G � i-ocod0 kr 3 V�r�J a l i C L ^ d Z �� c+ 3 LLQ T j�ke LL.1 y' ]484. :wwnp4 ig4WAdddd■ YWldwo3 aLJNL1Mfk5 a LLJ s sx c o + T ........ _..... �!- Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 134 of 136 W01 SHEALY ENVIRONMENTAL SERVICES, INC. �-f �r �J4: 0 v sin -- malW }} I 1 I �I I C ILL fl= Ed' Is ► _ 3Zk In 21 i l � 3 y Imo ' Ftj I LLJ jj i s fa F LU _ tw.- C e jg6p m Lui r -W1. appdaAdIP ung i ■LJ L g !li 12 �I a, ialumno Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 135 of 136 I- I c � &llIB�IJL i w c iV wed 2 `41 - s d --� i I P p i, .. - { lip , I IN �J4: 0 v sin -- malW }} I 1 I �I I C ILL fl= Ed' Is ► _ 3Zk In 21 i l � 3 y Imo ' Ftj I LLJ jj i s fa F LU _ tw.- C e jg6p m Lui r -W1. appdaAdIP ung i ■LJ L g !li 12 �I a, ialumno Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 135 of 136 I- SHEALY ENVIRONMENTAL SERVICES, INC. 31hnly Luvifoomcmud'Wr" .Inc DwLment hl unbtvr Pd EU Lt'C Sample Rvwipt Checklist (SRS') �= y lien: Cgoler ltlspectcd byldate' za '� G�Lc� �; 1a1 EfRctircdWX'Oi M17 lrxpiry Dass 011".2023 Mitansoafreceipt; ❑ SESI Tient ❑ UPS 0 .COX ❑ othcr � _ - Yes ❑ No 1. Dose CtL5L4mly seals preSCIA vn the coder'' Yes 11 No 13 N ', If cusTody seals were rcxent, vwere th intut and unhmken? pR strip IDD: .- Cl strip M. Cooler 'Ori RELI MMP tate upon receipuDvrived (carrerted) temperature upon mw6pv c 1 F uc ° J ,r c� lvlclhod., o Temperature 131ai1-t14 d Against B+ca] IR GLsn LCI, IR Gun CcSrttr tion Facxor: r� Iv OhDd of coolant; Wet Ice ❑ Blase Ice ❑ Dry lee ❑ None 3. If tem Perature of any c;r„►Icr exceeded 6.0'C, was Proj"I Manager Not &cd? `Yes ❑ No o N AX PM +w'as NWfied by , hanc 1 email 1 (ace -to -face (Circle one). Yrs ❑ No ❑ 4. Is the crx'nmerciaLl courier's 1 slip attached to LhiA foffn? Yes >w10 ❑ 5, Were propercttstcrdy procedures(reli uishaJ!r�L:t­ived) followed? ycS,n No p 6. Were: swnplc II3s listed on the C(?t_'? Y Nu ❑ ?, Were sample TOs listed on Al sample conlainersi - y,� N. ❑ 8, 1A 5' s collection data & time listed on the COCA Yes Ma ❑ 9. )was w1lec ion data & tide I`Iswd w all sample trnitainers? YesX No ❑ lip. Did all container label information (ID, date, time) agree Rith the COC7 Yes No ❑ 11. Were tests to be performed Iisted on the iD4O 12, Did all samples arrive in t11e pry cunjainers for each test anUcrr in good cvndilion NQ ❑ (unbroken lids oiti, ett)? Y No 1113- VWas adequate sam le volume available? ye9 No 11l4. Were all wm les ruwived %within hit the holding time er 48 hours, whichever comes first? Yes ❑ N 15- W ere any samples containcrs missing'excess (circle one) sartiples Not listed on COC? Yes ❑ No u NAe 16.- Were buklessent>" a-si " ('f4"or 6mmr. in diameter) in any VOA vials? Y No t7 NA ❑ 17. Were all DI((3imeialslnutrient samples received at a pH of t 2? _ ❑ No 0 NAJ& 1 S. Were all Cyanide smn les recei-'ed ata EH x 12 and sulfide Samples rc"ived at a ISH > 9? 19, Wcre al] applicable NH3i1` N-1cyanidelphenol,1B'N,A (< G-SmgIL) samples free of residual Yes ❑ NQ ri A ch lorirle? Yes ❑ ']a [3 Iti2i 20. Were ccrllccticm JeMperItUres doct4menled rant the COC fort NCS 8,r1n1 les? 21. Were clletst remarkslregve5.ts (Le- requested dilutiveis, A'1SJMSD designations, Or;--- VC5 ❑ No Q r ctly transcribed from the COC into Che comment section in LEMS? YLS 0 Na L- Was the quote number used taken from Cite container label? Sample Yr rvatioil (Must be cornplated frsr any sample() is wmec-d ' resrrvcd or with heads sec.) &Umple(s) were rived iincnrrectly preserved and were adjusted acCerdi.ngly in sample maivinwith (HI SOA, HNO3, HCl, NaOHl usigg SR E m le(s) were received void' bubbles >6 mm in diameter. _ &aonplts(5) were recrivetl with TRC > 0.5 m j'L (If #21 is No) and w Wiusted acoordin l itl SaMpI a MXMO& with sodium thiosulfalte as !} with Shealy 1D: SC Drinking Water Pmjert Sarnplc(s) pH verified to be: < Z by .. —Date, Sark Its were t reccived 2 and w i re adjusled accordingly using SRO Sample 1ahels ap lied by; Verified by.Late; CDmmc nes: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 136 of 136 Analytical lab Page 136 of 9 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM -cal LaboratM Servic e -s Anallylical Laborrato"ry Us An h Only .. ........ W, Y, I Maki Code PG03A2 (Bulldiirpa?4015� SOIL DUKE samples Or�n, rV $C�i DISTRIBUTION 10339 Ha-pers Forry Rd cxi 111-1VIC431 rr� Huntemwille, N. C. 280TO 1 0 Rif il NAL t. LAB. SAMPLE F"RAW G,,d COPY to CLIENT ENERGY, 0 (98101875-5245 NPI)ES . .............. I .......... .............. --.- ..........98 - — - — - -.9.....,---.5..-- 01her 2)"Ons No: vflua Rant_ AB G ro undwater Assessme nt - foil j Revision 1 (7-17-17) (2017 Suppllemental Sail Testing) Slif-ALY Cooler Tomp (C I 41Fam NoHC - AD GVV f-YN I i PC 5021013 '�� 0'.­� > I)M211 Code: 49" 0 4 31kC9F*" Unk: 6jp"C[ KI: 19 IE: cust,omer to I;-oinpluto all MF -S 41 §U3 gAvIiAly RD: I C1 er po. WATER EQUIPMENT BLANK [1 Rf:R DAY) !gUgM#t: when r&p4rlflc oc"m"ng has; N -w amt*Wksh" and Is not Indicrked ab we X- C 4'Ac 'r- /X/(. We need the (0116IMmg- 1� Enter correct ;1CCOLIntirka In alf! 6 aLcounfing fleAft sriova. or 49 21 Provide correct arcouriting fnT I)F> raflng Unit AM Prix:eSS 113. CL ZF Z ...`2Chern "Cotlection InfonnatiOn Data Time Signature ........ 113 Desktop No. Sample Dear-ription or ID J-) AAIS-Y Ra5a t9 C 7- -,3,) A JLa -j f-YN I 42I - 19 IE: §U3 WATER EQUIPMENT BLANK [1 Rf:R DAY) X- C 4'Ac 'r- /X/(. Dff1iN1Tkm Dptr 11 ay MeRah By 681 6; Al, ®a,103, Cm, Cr, Cu, Fe. Ma- Mn. Mo. Pa, K. Na, Sr, Z. V.Fql� Lay 6M: 5b, A., 5e. rd, Co. ", sd, 1%V "I kFV 747t A..inn* CA, "Raquested Turnaround 14 Days '7 DkwE, -48 Hr Analytical lab _.�,..,..,.-----' t,.,,. ,,,,,• d ----- ........a. ....,°;.. 9 a CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM __Z 0 1lnalytlea� I. abor8t41 Sllvic� Ana tical Lalrora#o kJsa Dn DUKEIdo® �Ccdo lAGU3l13 fau6ding 741}5) Manu_ SOIL alc� P+°° i pi 1 3 13339 Hager* Font Rd � �n=1 �t"� 0 _ ; C5 N e,--- j� Wunteravllle, N. C. 28078 � C]R GI A4.Lto I.AB. 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