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Home My WebLink About2017-J17070719 Riverbend Soil Analytical ResultsDUKE Analytical Laboratory Page 1I of047 " ENERGY. Order Number: Project Name: Customer Name(s): Lab Contact: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Vendor QC Data Review Summary Report J17070719 RIVERBEND - AB GW ASSESS SOIL(2017 SUPPLEMENTAL SOIL TESTING) Tim Hunsucker,Sean DeNeale,B Moeller,J Toepfer, K Webb, M McDade, B Rus Peggy Kendall Phone: 980-875-5848 Report Authorized By: pe Date: 8/11/2017 (Signature) nr Mary Ann Ogle Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: • Required QC samples collected and analyzed • Required tests performed for all samples • Vendor Laboratory utilized required test methods for all analyses • Vendor Laboratory met all requested Reporting Limits (RL) • QC Results reviewed for outlying recovery values Case Narrative: The equipment blank contained 0.18 mg/L Al, 0.0018 mg/L Cr, 0.21 mg/L Fe, 0.87 mg/L Mg, 0.0069 mg/L Mn, 0.89 mg/L K and 1.0 mg/L Na. Any sample concentrations < 10 X the blank concentration maybe affected by contamination in the field. Antimony (22%) and Vanadium (131%) were recovered outside the control limit (75-125%) in the MS/MSD on BGSB-6(4-5) REVISION Page 2 of 47 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Peggy Kendall Project Name: Riverbend - AB GW Assessment 2017 Project Number: J17070719 Lot Number:SG31009 Date Completed:08/09/2017 08/10/2017 9:45 AM Approved and released by: Project Manager: Grant Wilton LABORATORY ACCREDITATION XFCXXXIXiX BUREAU adlvision of A -S -X qe �' ACCREDITED iSonEc 1708 The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 1 of 45 REVISION Page 3 of 47 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: SG31009 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals Analysis - Method 60208 Antimony was recovered outside the control limit in the MS associated with batch 48110. Antimony and Vanadium were recovered outside the control limit in the MS/MSD. Since the LCS and Method Blank were within control limits it was determined that matrix interference caused the MS/MSD to fail. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 2 of 45 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: SG31009 Project Name: Riverbend - AB GW Assessment 2017 Project Number: J17070719 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017025965 Solid 07/28/2017 0906 07/31/2017 002 2017025966 Solid 07/28/2017 0908 07/31/2017 003 2017025967 Solid 07/28/2017 0910 07/31/2017 004 2017025968 Aqueous 07/28/2017 0915 07/31/2017 (4 samples) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3 of 45 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 45 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary Duke Energy Lot Number: SG31009 Project Name: Riverbend - AB GW Assessment 2017 Project Number: J17070719 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017025965 Solid Chloride (soluble) 9056A 2.8 J mg/kg 6 001 2017025965 Solid Nitrate - N (soluble) 9056A 0.64 mg/kg 6 001 2017025965 Solid Aluminum 6010D 18000 mg/kg 7 001 2017025965 Solid Barium 6010D 12 mg/kg 7 001 2017025965 Solid Calcium 6010D 240 mg/kg 7 001 2017025965 Solid Chromium 6010D 13 mg/kg 7 001 2017025965 Solid Copper 6010D 18 mg/kg 7 001 2017025965 Solid Iron 6010D 18000 mg/kg 7 001 2017025965 Solid Magnesium 6010D 490 mg/kg 7 001 2017025965 Solid Manganese 6010D 23 mg/kg 7 001 2017025965 Solid Nickel 6010D 3.0 mg/kg 7 001 2017025965 Solid Potassium 6010D 200 mg/kg 7 001 2017025965 Solid Strontium 6010D 4.7 mg/kg 7 001 2017025965 Solid Zinc 6010D 7.8 mg/kg 7 001 2017025965 Solid Antimony 6020B 0.15 JS mg/kg 8 001 2017025965 Solid Arsenic 6020B 1.5 mg/kg 8 001 2017025965 Solid Beryllium 6020B 0.37 mg/kg 8 001 2017025965 Solid Cadmium 6020B 0.015 J mg/kg 8 001 2017025965 Solid Cobalt 6020B 2.2 mg/kg 8 001 2017025965 Solid Lead 6020B 4.9 mg/kg 8 001 2017025965 Solid Selenium 6020B 0.41 J mg/kg 8 001 2017025965 Solid Thallium 60208 0.058 J mg/kg 8 001 2017025965 Solid Vanadium 6020B 51 S mg/kg 8 001 2017025965 Solid Mercury 7471B 0.032 J mg/kg 9 002 2017025966 Solid Chloride (soluble) 9056A 1.9 J mg/kg 10 002 2017025966 Solid Nitrate - N (soluble) 9056A 0.084 J mg/kg 10 002 2017025966 Solid Aluminum 6010D 13000 mg/kg 11 002 2017025966 Solid Barium 6010D 33 mg/kg 11 002 2017025966 Solid Chromium 6010D 12 mg/kg 11 002 2017025966 Solid Copper 6010D 16 mg/kg 11 002 2017025966 Solid Iron 6010D 15000 mg/kg 11 002 2017025966 Solid Magnesium 6010D 320 mg/kg 11 002 2017025966 Solid Manganese 6010D 150 mg/kg 11 002 2017025966 Solid Molybdenum 6010D 0.54 J mg/kg 11 002 2017025966 Solid Nickel 6010D 3.1 mg/kg 11 002 2017025966 Solid Potassium 6010D 230 mg/kg 11 002 2017025966 Solid Strontium 6010D 0.40 J mg/kg 11 002 2017025966 Solid Zinc 6010D 5.3 mg/kg 11 002 2017025966 Solid Arsenic 6020B 0.49 J mg/kg 12 002 2017025966 Solid Beryllium 6020B 0.46 mg/kg 12 002 2017025966 Solid Cadmium 6020B 0.023 J mg/kg 12 002 2017025966 Solid Cobalt 6020B 5.8 mg/kg 12 002 2017025966 Solid Lead 6020B 1.6 mg/kg 12 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 45 Detection Summary (Continued) Lot Number: SG31009 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2017025966 Solid Selenium 6020B 0.41 J mg/kg 12 002 2017025966 Solid Thallium 6020B 0.068 J mg/kg 12 002 2017025966 Solid Vanadium 6020B 40 mg/kg 12 002 2017025966 Solid Mercury 7471B 0.050 J mg/kg 13 003 2017025967 Solid Chloride (soluble) 9056A 2.5 J mg/kg 14 003 2017025967 Solid Nitrate - N (soluble) 9056A 0.085 J mg/kg 14 003 2017025967 Solid Aluminum 6010D 17000 mg/kg 15 003 2017025967 Solid Barium 6010D 240 mg/kg 15 003 2017025967 Solid Boron 6010D 1.0 J mg/kg 15 003 2017025967 Solid Chromium 6010D 7.9 mg/kg 15 003 2017025967 Solid Copper 6010D 44 mg/kg 15 003 2017025967 Solid Iron 6010D 20000 mg/kg 15 003 2017025967 Solid Magnesium 6010D 320 mg/kg 15 003 2017025967 Solid Manganese 6010D 2800 mg/kg 15 003 2017025967 Solid Nickel 6010D 7.2 mg/kg 15 003 2017025967 Solid Potassium 6010D 290 mg/kg 15 003 2017025967 Solid Strontium 6010D 0.44 J mg/kg 15 003 2017025967 Solid Zinc 6010D 9.0 mg/kg 15 003 2017025967 Solid Arsenic 6020B 1.4 mg/kg 16 003 2017025967 Solid Beryllium 6020B 1.5 mg/kg 16 003 2017025967 Solid Cadmium 6020B 0.032 mg/kg 16 003 2017025967 Solid Cobalt 6020B 33 mg/kg 16 003 2017025967 Solid Lead 6020B 2.1 mg/kg 16 003 2017025967 Solid Selenium 6020B 0.75 J mg/kg 16 003 2017025967 Solid Thallium 6020B 0.058 J mg/kg 16 003 2017025967 Solid Vanadium 6020B 110 mg/kg 16 004 2017025968 Aqueous Aluminum 6010D 0.18 J mg/L 18 004 2017025968 Aqueous Chromium 6010D 0.0018 J mg/L 18 004 2017025968 Aqueous Iron 6010D 0.21 mg/L 18 004 2017025968 Aqueous Magnesium 6010D 0.87 J mg/L 18 004 2017025968 Aqueous Manganese 6010D 0.0069 J mg/L 18 004 2017025968 Aqueous Potassium 6010D 0.89 J mg/L 18 004 2017025968 Aqueous Sodium 6010D 1.0 J mg/L 18 (76 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5 of 45 Inorganic non-metals Client: Duke Energy Laboratory ID: SG31009-001 Description: 2017025965 Matrix: Solid Date Sampled:07/28/2017 0906 Project Name: Riverbend - AB GW % Solids: 80.2 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 08/05/2017 0702 TAF 48357 1 (Nitrate - N ) 9056A 1 08/05/2017 0702 TAF 48354 1 (pH) 9045D 1 08/01/2017 1749 MSG 48114 1 (Sulfate (sol) 9056A 1 08/05/2017 0702 TAF 48355 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.8 J 12 1.3 mg/kg 1 Nitrate - N (soluble) 9056A 0.64 0.25 0.031 mg/kg 1 pH 9045D 4.61 su 1 Sulfate (soluble) 9056A ND 12 6.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 45 ICP -AES Client: Duke Energy Laboratory ID: SG31009-001 Description: 2017025965 Matrix: Solid Date Sampled:07/28/2017 0906 Project Name: Riverbend - AB GW % Solids: 80.2 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 08/07/2017 0003 CJZ 08/01/2017 0937 48029 2 3050B 601 OD 1 08/08/2017 1804 CJZ 08/01/2017 0937 48029 3 3050B 601 OD 5 08/09/2017 1449 CJZ 08/01/2017 0937 48029 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 18000 65 24 mg/kg 3 Barium 7440-39-3 6010D 12 0.85 0.21 mg/kg 1 Boron 7440-42-8 6010D ND 1.6 0.65 mg/kg 1 Calcium 7440-70-2 6010D 240 160 20 mg/kg 2 Chromium 7440-47-3 6010D 13 0.33 0.082 mg/kg 1 Copper 7440-50-8 6010D 18 0.33 0.15 mg/kg 1 Iron 7439-89-6 6010D 18000 16 7.4 mg/kg 3 Magnesium 7439-95-4 6010D 490 160 20 mg/kg 2 Manganese 7439-96-5 6010D 23 0.49 0.19 mg/kg 1 Molybdenum 7439-98-7 6010D ND 1.3 0.33 mg/kg 1 Nickel 7440-02-0 6010D 3.0 1.3 0.34 mg/kg 1 Potassium 7440-09-7 6010D 200 160 20 mg/kg 2 Sodium 7440-23-5 6010D ND 160 20 mg/kg 1 Strontium 7440-24-6 6010D 4.7 0.65 0.16 mg/kg 2 Zinc 7440-66-6 6010D 7.8 1.6 0.41 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 45 ICP -MS Client: Duke Energy Laboratory ID: SG31009-001 Description: 2017025965 Matrix: Solid Date Sampled:07/28/2017 0906 Project Name: Riverbend - AB GW % Solids: 80.2 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 08/02/2017 1802 BNW 08/01/2017 1747 48110 2 3050B 6020B 1 08/03/2017 1825 BNW 08/01/2017 1747 48110 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.15 JS 0.53 0.11 mg/kg 2 Arsenic 7440-38-2 6020B 1.5 0.53 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.37 0.11 0.021 mg/kg 2 Cadmium 7440-43-9 6020B 0.015 J 0.026 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 2.2 0.74 0.26 mg/kg 1 Lead 7439-92-1 6020B 4.9 0.26 0.053 mg/kg 1 Selenium 7782-49-2 6020B 0.41 J 1.4 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.058 J 0.14 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 51 S 1.4 0.26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 45 CVAA Client: Duke Energy Laboratory ID: SG31009-001 Description: 2017025965 Matrix: Solid Date Sampled:07/28/2017 0906 Project Name: Riverbend - AB GW % Solids: 80.2 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 08/03/2017 0012 SLS 08/02/2017 2232 48241 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 0.032 J 0.10 0.025 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9 of 45 Inorganic non-metals Client: Duke Energy Laboratory ID: SG31009-002 Description: 2017025966 Matrix: Solid Date Sampled:07/28/2017 0908 Project Name: Riverbend - AB GW % Solids: 79.0 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 08/05/2017 0726 TAF 48357 1 (Nitrate - N ) 9056A 1 08/05/2017 0726 TAF 48354 1 (pH) 9045D 1 08/01/2017 1751 MSG 48114 1 (Sulfate (sol) 9056A 1 08/05/2017 0726 TAF 48355 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 1.9 J 13 1.3 mg/kg 1 Nitrate - N (soluble) 9056A 0.084 J 0.25 0.031 mg/kg 1 pH 9045D 4.47 su 1 Sulfate (soluble) 9056A ND 13 6.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 45 ICP -AES Client: Duke Energy Laboratory ID: SG31009-002 Description: 2017025966 Matrix: Solid Date Sampled:07/28/2017 0908 Project Name: Riverbend - AB GW % Solids: 79.0 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 08/07/2017 0016 CJZ 08/01/2017 0937 48029 2 3050B 601 OD 1 08/08/2017 1809 CJZ 08/01/2017 0937 48029 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 13000 16 5.9 mg/kg 2 Barium 7440-39-3 6010D 33 1.0 0.26 mg/kg 1 Boron 7440-42-8 6010D ND 2.0 0.79 mg/kg 1 Calcium 7440-70-2 6010D ND 200 25 mg/kg 2 Chromium 7440-47-3 6010D 12 0.39 0.099 mg/kg 1 Copper 7440-50-8 6010D 16 0.39 0.18 mg/kg 1 Iron 7439-89-6 6010D 15000 3.9 1.8 mg/kg 2 Magnesium 7439-95-4 6010D 320 200 25 mg/kg 2 Manganese 7439-96-5 6010D 150 0.59 0.23 mg/kg 1 Molybdenum 7439-98-7 6010D 0.54 J 1.6 0.39 mg/kg 1 Nickel 7440-02-0 6010D 3.1 1.6 0.41 mg/kg 1 Potassium 7440-09-7 6010D 230 200 25 mg/kg 2 Sodium 7440-23-5 6010D ND 200 25 mg/kg 1 Strontium 7440-24-6 6010D 0.40 J 0.79 0.20 mg/kg 2 Zinc 7440-66-6 6010D 5.3 2.0 0.49 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 45 ICP -MS Client: Duke Energy Laboratory ID: SG31009-002 Description: 2017025966 Matrix: Solid Date Sampled:07/28/2017 0908 Project Name: Riverbend - AB GW % Solids: 79.0 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 08/02/2017 1831 BNW 08/01/2017 1747 48110 2 3050B 6020B 1 08/03/2017 1855 BNW 08/01/2017 1747 48110 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.62 0.12 mg/kg 2 Arsenic 7440-38-2 6020B 0.49 J 0.62 0.12 mg/kg 1 Beryllium 7440-41-7 6020B 0.46 0.12 0.025 mg/kg 2 Cadmium 7440-43-9 6020B 0.023 J 0.031 0.012 mg/kg 1 Cobalt 7440-48-4 6020B 5.8 0.86 0.31 mg/kg 1 Lead 7439-92-1 6020B 1.6 0.31 0.062 mg/kg 1 Selenium 7782-49-2 6020B 0.41 J 1.6 0.31 mg/kg 1 Thallium 7440-28-0 6020B 0.068 J 0.16 0.032 mg/kg 1 Vanadium 7440-62-2 6020B 40 1.6 0.31 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 45 CVAA Client: Duke Energy Laboratory ID: SG31009-002 Description: 2017025966 Matrix: Solid Date Sampled:07/28/2017 0908 Project Name: Riverbend - AB GW % Solids: 79.0 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 08/03/2017 0014 SLS 08/02/2017 2232 48241 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 0.050 J 0.097 0.023 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 45 Inorganic non-metals Client: Duke Energy Laboratory ID: SG31009-003 Description: 2017025967 Matrix: Solid Date Sampled:07/28/2017 0910 Project Name: Riverbend - AB GW % Solids: 77.3 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 08/05/2017 0750 TAF 48357 1 (Nitrate - N ) 9056A 1 08/05/2017 0750 TAF 48354 1 (pH) 9045D 1 08/01/2017 1752 MSG 48114 1 (Sulfate (sol) 9056A 1 08/05/2017 0750 TAF 48355 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.5 J 13 1.3 mg/kg 1 Nitrate - N (soluble) 9056A 0.085 J 0.26 0.032 mg/kg 1 pH 9045D 4.41 su 1 Sulfate (soluble) 9056A ND 13 6.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 45 ICP -AES Client: Duke Energy Laboratory ID: SG31009-003 Description: 2017025967 Matrix: Solid Date Sampled:07/28/2017 0910 Project Name: Riverbend - AB GW % Solids: 77.3 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 08/07/2017 0020 CJZ 08/01/2017 0937 48029 2 3050B 601 OD 5 08/06/2017 2344 CJZ 08/01/2017 0937 48029 3 3050B 601 OD 1 08/08/2017 1813 CJZ 08/01/2017 0937 48029 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 17000 19 7.0 mg/kg 3 Barium 7440-39-3 6010D 240 1.2 0.30 mg/kg 1 Boron 7440-42-8 6010D 1.0 J 2.3 0.93 mg/kg 1 Calcium 7440-70-2 6010D ND 230 29 mg/kg 3 Chromium 7440-47-3 6010D 7.9 2.3 0.58 mg/kg 2 Copper 7440-50-8 6010D 44 0.47 0.21 mg/kg 1 Iron 7439-89-6 6010D 20000 4.7 2.1 mg/kg 3 Magnesium 7439-95-4 6010D 320 230 29 mg/kg 3 Manganese 7439-96-5 6010D 2800 3.5 1.4 mg/kg 2 Molybdenum 7439-98-7 6010D ND 1.9 0.47 mg/kg 1 Nickel 7440-02-0 6010D 7.2 1.9 0.49 mg/kg 1 Potassium 7440-09-7 6010D 290 230 29 mg/kg 3 Sodium 7440-23-5 6010D ND 230 29 mg/kg 1 Strontium 7440-24-6 6010D 0.44 J 0.93 0.23 mg/kg 3 Zinc 7440-66-6 6010D 9.0 2.3 0.58 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 45 ICP -MS Client: Duke Energy Laboratory ID: SG31009-003 Description: 2017025967 Matrix: Solid Date Sampled:07/28/2017 0910 Project Name: Riverbend - AB GW % Solids: 77.3 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 08/02/2017 1837 BNW 08/01/2017 1747 48110 2 3050B 6020B 1 08/03/2017 1901 BNW 08/01/2017 1747 48110 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.56 0.11 mg/kg 2 Arsenic 7440-38-2 6020B 1.4 0.56 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 1.5 0.11 0.023 mg/kg 2 Cadmium 7440-43-9 6020B 0.032 0.028 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 33 0.79 0.28 mg/kg 1 Lead 7439-92-1 6020B 2.1 0.28 0.056 mg/kg 1 Selenium 7782-49-2 6020B 0.75 J 1.5 0.28 mg/kg 1 Thallium 7440-28-0 6020B 0.058 J 0.15 0.029 mg/kg 1 Vanadium 7440-62-2 6020B 110 1.5 0.28 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 45 CVAA Client: Duke Energy Laboratory ID: SG31009-003 Description: 2017025967 Matrix: Solid Date Sampled:07/28/2017 0910 Project Name: Riverbend - AB GW % Solids: 77.3 07/31/2017 2106 Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 08/03/2017 0016 SLS 08/02/2017 2232 48241 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.099 0.024 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 45 ICP -AES Metals Client: Duke Energy Laboratory ID: SG31009-004 Description: 2017025968 Matrix: Aqueous Date Sampled:07/28/2017 0915 Project Name: Riverbend - AB GW Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 601 OD 1 08/07/2017 1910 CJZ 08/03/2017 1017 48258 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 0.18 J 0.40 0.10 mg/L 1 Barium 7440-39-3 6010D ND 0.025 0.0031 mg/L 1 Boron 7440-42-8 6010D ND 0.050 0.020 mg/L 1 Calcium 7440-70-2 6010D ND 5.0 0.63 mg/L 1 Chromium 7440-47-3 6010D 0.0018 J 0.010 0.0013 mg/L 1 Copper 7440-50-8 6010D ND 0.010 0.0020 mg/L 1 Iron 7439-89-6 6010D 0.21 0.10 0.040 mg/L 1 Magnesium 7439-95-4 6010D 0.87 J 5.0 0.63 mg/L 1 Manganese 7439-96-5 6010D 0.0069 J 0.015 0.0019 mg/L 1 Molybdenum 7439-98-7 6010D ND 0.040 0.0050 mg/L 1 Nickel 7440-02-0 6010D ND 0.040 0.0050 mg/L 1 Potassium 7440-09-7 6010D 0.89 J 5.0 0.63 mg/L 1 Sodium 7440-23-5 6010D 1.0 J 5.0 0.63 mg/L 1 Strontium 7440-24-6 6010D ND 0.010 0.0025 mg/L 1 Zinc 7440-66-6 6010D ND 0.020 0.0025 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 45 ICP -MS Metals Client: Duke Energy Laboratory ID: SG31009-004 Description: 2017025968 Matrix: Aqueous Date Sampled:07/28/2017 0915 Project Name: Riverbend - AB GW Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 08/02/2017 1623 BNW 08/01/2017 0851 48028 2 3005A 6020B 1 08/07/2017 1251 BNW 08/01/2017 0851 48028 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 45 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 2 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.13 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 0.63 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.13 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 1.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 45 CVAA Client: Duke Energy Laboratory ID: SG31009-004 Description: 2017025968 Matrix: Aqueous Date Sampled:07/28/2017 0915 Project Name: Riverbend - AB GW Date Received: 07/31/2017 Project Number: J17070719 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 7470A 7470A 1 08/01/2017 2326 SLS 08/01/2017 1009 48044 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00010 0.000091 mg/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 20 of 45 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: SG31009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 45 Inorganic non-metals - Duplicate Sample ID: SG31OO9-003DU Matrix: Solid Batch:48114 Analytical Method: 9045D Sample Amount Result % RPD Parameter (su) (mg/kg) Q Dil % RPD Limit Analysis Date pH 4.41 4.4 1 0.23 20 08/01/20171753 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 45 QC Data for Lot Number: SG31009 Inorganic non-metals - MB Sample ID: SQ48354-001 Matrix: Solid Batch:48354 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N (soluble) ND 1 0.20 0.025 mg/kg 08/04/2017 2013 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 23 of 45 QC Data for Lot Number: SG31009 Inorganic non-metals - LCS Sample ID: SQ48354-002 Matrix: Solid Batch:48354 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.80 0.78 1 98 87-111 08/04/2017 2037 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 24 of 45 QC Data for Lot Number: SG31009 Inorganic non-metals - MB Sample ID: SQ48355-001 Matrix: Solid Batch:48355 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate (soluble) ND 1 10 5.0 mg/kg 08/04/2017 2013 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 45 QC Data for Lot Number: SG31009 Inorganic non-metals - LCS Sample ID: SQ48355-002 Matrix: Solid Batch:48355 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) 20 20 1 99 80-120 08/04/2017 2037 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 45 QC Data for Lot Number: SG31009 Inorganic non-metals - MB Sample ID: SQ48357-001 Matrix: Solid Batch:48357 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride (soluble) ND 1 10 1.0 mg/kg 08/04/2017 2013 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 27 of 45 QC Data for Lot Number: SG31009 Inorganic non-metals - LCS Sample ID: SQ48357-002 Matrix: Solid Batch:48357 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 20 20 1 100 80-120 08/04/2017 2037 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 28 of 45 QC Data for Lot Number: SG31009 ICP -MS Metals - MB Sample ID: SQ48028-001 Matrix: Aqueous Batch:48028 Prep Method: 3005A Analytical Method: 6020B Prep Date: 08/01/2017 851 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 0.53 J 1 2.0 0.50 ug/L 08/02/20171501 Arsenic ND 1 2.0 1.3 ug/L 08/02/20171501 Beryllium ND 1 0.40 0.13 ug/L 08/02/20171501 Cadmium ND 1 0.50 0.13 ug/L 08/02/20171501 Cobalt ND 1 5.0 0.63 ug/L 08/02/20171501 Lead ND 1 1.0 0.25 ug/L 08/02/20171501 Selenium ND 1 5.0 1.3 ug/L 08/02/20171501 Thallium ND 1 0.50 0.13 ug/L 08/02/20171501 Vanadium ND 1 5.0 1.5 ug/L 08/02/20171501 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 45 QC Data for Lot Number: SG31009 ICP -MS Metals - LCS Sample ID: SQ48O28-002 Matrix: Aqueous Batch:48028 Prep Method: 3OO5A Analytical Method: 6020B Prep Date: 08/01/2017 851 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 96 1 96 80-120 08/02/20171507 Arsenic 100 100 1 104 80-120 08/02/20171507 Beryllium 100 110 1 111 80-120 08/02/20171507 Cadmium 100 96 1 96 80-120 08/02/20171507 Cobalt 100 98 1 98 80-120 08/02/20171507 Lead 100 94 1 94 80-120 08/02/20171507 Selenium 100 100 1 102 80-120 08/02/20171507 Thallium 100 92 1 92 80-120 08/02/20171507 Vanadium 100 96 1 96 80-120 08/02/20171507 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 45 QC Data for Lot Number: SG31009 ICP -AES - MB Sample ID: SQ48029-001 Matrix: Solid Batch:48029 Prep Method: 3050B Analytical Method: 6010D Prep Date: 08/01/2017 937 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 20 7.5 mg/kg 08/03/20171955 Barium ND 1 1.3 0.33 mg/kg 08/03/20171955 Boron ND 1 2.5 1.0 mg/kg 08/03/20171955 Calcium ND 1 250 31 mg/kg 08/03/20171955 Chromium ND 1 0.50 0.13 mg/kg 08/03/20171955 Copper ND 1 0.50 0.23 mg/kg 08/03/20171955 Iron ND 1 5.0 2.3 mg/kg 08/08/20171746 Magnesium ND 1 250 31 mg/kg 08/08/20171746 Manganese ND 1 0.75 0.30 mg/kg 08/03/20171955 Molybdenum ND 1 2.0 0.50 mg/kg 08/03/20171955 Nickel ND 1 2.0 0.53 mg/kg 08/03/20171955 Potassium ND 1 250 31 mg/kg 08/03/20171955 Sodium ND 1 250 31 mg/kg 08/03/20171955 Strontium ND 1 1.0 0.25 mg/kg 08/08/20171746 Zinc ND 1 2.5 0.63 mg/kg 08/03/20171955 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 31 of 45 QC Data for Lot Number: SG31009 ICP -AES - LCS Sample ID: SQ48O29-002 Matrix: Solid Batch:48029 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 08/01/2017 937 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Aluminum 1000 930 1 93 80-120 08/03/2017 2000 Barium 500 470 1 95 80-120 08/03/2017 2000 Boron 50 43 1 87 80-120 08/03/2017 2000 Calcium 2000 1900 1 93 80-120 08/03/2017 2000 Chromium 250 230 1 93 80-120 08/03/2017 2000 Copper 100 95 1 95 80-120 08/03/2017 2000 Iron 1000 990 1 99 80-120 08/08/20171751 Magnesium 2000 2000 1 98 80-120 08/08/20171751 Manganese 100 95 1 95 80-120 08/03/2017 2000 Molybdenum 100 100 1 100 80-120 08/03/2017 2000 Nickel 100 98 1 98 80-120 08/03/2017 2000 Potassium 2000 1900 1 94 80-120 08/03/2017 2000 Sodium 2000 1900 1 96 80-120 08/03/2017 2000 Strontium 50 50 1 100 80-120 08/08/20171751 Zinc 100 95 1 95 80-120 08/03/2017 2000 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 32 of 45 QC Data for Lot Number: SG31009 ICP -MS - MB Sample ID: SQ48110-001 Matrix: Solid Batch:48110 Prep Method: 3050B Analytical Method: 6020B Prep Date: 08/01/2017 1747 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 0.25 J 1 0.50 0.10 mg/kg 08/03/20171814 Arsenic 0.17 J 1 0.50 0.10 mg/kg 08/02/20171750 Beryllium ND 1 0.10 0.020 mg/kg 08/03/20171814 Cadmium 0.019 J 1 0.025 0.010 mg/kg 08/02/20171750 Cobalt ND 1 0.70 0.25 mg/kg 08/02/20171750 Lead ND 1 0.25 0.050 mg/kg 08/02/20171750 Selenium ND 1 1.3 0.25 mg/kg 08/02/20171750 Thallium ND 1 0.13 0.026 mg/kg 08/02/20171750 Vanadium ND 1 1.3 0.25 mg/kg 08/02/20171750 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 45 QC Data for Lot Number: SG31009 ICP -MS - LCS Sample ID: SQ4811O-002 Matrix: Solid Batch:48110 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 08/01/2017 1747 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Antimony 50 47 1 95 80-120 08/03/20171820 Arsenic 50 55 1 111 80-120 08/02/20171756 Beryllium 50 53 1 106 80-120 08/03/20171820 Cadmium 50 53 1 106 80-120 08/02/20171756 Cobalt 50 57 1 115 80-120 08/02/20171756 Lead 50 57 1 114 80-120 08/02/20171756 Selenium 50 48 1 97 80-120 08/02/20171756 Thallium 50 56 1 113 80-120 08/02/20171756 Vanadium 50 59 1 117 80-120 08/02/20171756 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 45 QC Data for Lot Number: SG31009 ICP -MS - MS Sample ID: SG31OO9-OOlMS Matrix: Solid Batch:48110 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 08/01/2017 1747 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Antimony 0.15 56 12 N 1 22 75-125 08/03/20171831 Arsenic 1.5 56 56 1 96 75-125 08/02/20171808 Beryllium 0.37 56 54 1 95 75-125 08/03/20171831 Cadmium 0.015 56 51 1 90 75-125 08/02/20171808 Lead 4.9 56 62 1 100 75-125 08/02/20171808 Thallium 0.058 56 56 1 99 75-125 08/02/20171808 Vanadium 51 56 110 1 109 75-125 08/02/20171808 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 35 of 45 QC Data for Lot Number: SG31009 ICP -MS - MSD Sample ID: SG31OO9-OOlMD Matrix: Solid Batch:48110 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 08/01/2017 1747 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony 0.15 56 12 N 1 22 0.70 75-125 20 08/03/20171837 Arsenic 1.5 56 59 1 102 5.4 75-125 20 08/02/20171814 Beryllium 0.37 56 55 1 97 2.6 75-125 20 08/03/20171837 Cadmium 0.015 56 54 1 96 5.5 75-125 20 08/02/20171814 Lead 4.9 56 68 1 111 9.1 75-125 20 08/02/20171814 Thallium 0.058 56 63 1 112 12 75-125 20 08/02/20171814 Vanadium 51 56 130 N 1 135 12 75-125 20 08/02/20171814 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 36 of 45 QC Data for Lot Number: SG31009 ICP -AES Metals - MB Sample ID: SQ48258-001 Matrix: Aqueous Batch:48258 Prep Method: 3005A Analytical Method: 6010D Prep Date: 08/03/2017 1017 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 0.40 0.10 mg/L 08/07/20171838 Barium ND 1 0.025 0.0031 mg/L 08/07/20171838 Boron ND 1 0.050 0.020 mg/L 08/07/20171838 Calcium 0.64 J 1 5.0 0.63 mg/L 08/07/20171838 Chromium ND 1 0.010 0.0013 mg/L 08/08/20171832 Copper ND 1 0.010 0.0020 mg/L 08/07/20171838 Iron ND 1 0.10 0.040 mg/L 08/07/20171838 Magnesium 0.88 J 1 5.0 0.63 mg/L 08/07/20171838 Manganese ND 1 0.015 0.0019 mg/L 08/07/20171838 Molybdenum ND 1 0.040 0.0050 mg/L 08/07/20171838 Nickel ND 1 0.040 0.0050 mg/L 08/07/20171838 Potassium 0.83 J 1 5.0 0.63 mg/L 08/07/20171838 Sodium 1.0 J 1 5.0 0.63 mg/L 08/07/20171838 Strontium ND 1 0.010 0.0025 mg/L 08/07/20171838 Zinc ND 1 0.020 0.0025 mg/L 08/07/20171838 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 45 QC Data for Lot Number: SG31009 ICP -AES Metals - LCS Sample ID: SQ48258-002 Matrix: Aqueous Batch:48258 Prep Method: 3OO5A Analytical Method: 6010D Prep Date: 08/03/2017 1017 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Aluminum 20 19 1 94 80-120 08/07/20171843 Barium 2.0 2.0 1 98 80-120 08/07/20171843 Boron 0.40 0.46 1 115 80-120 08/07/20171843 Calcium 40 38 1 95 80-120 08/07/20171843 Chromium 2.0 2.1 1 105 80-120 08/08/20171836 Copper 2.0 2.2 1 112 80-120 08/07/20171843 Iron 20 19 1 94 80-120 08/07/20171843 Magnesium 40 38 1 96 80-120 08/07/20171843 Manganese 2.0 2.1 1 106 80-120 08/07/20171843 Molybdenum 2.0 2.0 1 100 80-120 08/07/20171843 Nickel 2.0 2.1 1 107 80-120 08/07/20171843 Potassium 40 38 1 94 80-120 08/07/20171843 Sodium 40 37 1 93 80-120 08/07/20171843 Strontium 1.0 0.98 1 98 80-120 08/07/20171843 Zinc 2.0 2.1 1 107 80-120 08/07/20171843 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 45 QC Data for Lot Number: SG31009 CVAA - MB Sample ID: SQ48044-001 Matrix: Aqueous Batch:48044 Prep Method: 7470A Analytical Method: 7470A Prep Date: 08/01/2017 1009 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00010 0.000091 mg/L 08/01/20172320 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 39 of 45 QC Data for Lot Number: SG31009 CVAA - LCS Sample ID: SQ48O44-002 Matrix: Aqueous Batch:48044 Prep Method: 747OA Analytical Method: 7470A Prep Date: 08/01/2017 1009 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0019 1 96 80-120 08/01/20172322 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 40 of 45 QC Data for Lot Number: SG31009 CVAA - MB Sample ID: SQ48241-001 Matrix: Solid Batch:48241 Prep Method: 7471B Analytical Method: 7471B Prep Date: 08/02/2017 2232 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.083 0.020 mg/kg 08/02/2017 2338 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 41 of 45 QC Data for Lot Number: SG31009 CVAA - LCS Sample ID: SQ48241-002 Matrix: Solid Batch:48241 Prep Method: 7471B Analytical Method: 7471B Prep Date: 08/02/2017 2232 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Mercury 0.83 0.87 1 104 80-120 08/02/2017 2340 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 42 of 45 QC Data for Lot Number: SG31009 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 43 of 45 LU Se LU LJJ 014 m h I v 'i4 i'' ael mgr; - ti a LL I� a eat �a16, LU Se LU LJJ I I I ° a I ,! ! p '% ! f FI •E Fy I I r 1 I I �° ! Ill - o Li 4 �13 Rj '• 13 4 49 La ff Aal ` z o uel en �Inumra» a�g,aoldala d uwa ay,� i I m m v � sC: I I I ° a I ,! ! p '% ! f FI •E Fy I I r 1 I I �° ! Ill - o Li 4 �13 Rj '• 13 4 49 La ff Aal ` z o uel en �Inumra» a�g,aoldala d uwa ay,� i I m m SHEALY ENVIRONMENTAL SERVICES, INC. ,die&y hir,inin-non-al Inc DgtyrnecL Kurnbvr MEN C'lirn(. t>U1p _ Fzgeelu L uf I EffwiycNu 1170` iL?Ol 1°)rriry nw. (7L)V2022 S'amplle Receipt CheekList (SRC) t:utalce In4p ted hylcla<�,� Uot #: ('`n l orris of receipt: _ S>:S1 ❑ Clikalt E 11-1,fi IcedRx +JfhelAi'� Yes ❑ No i _ Vlrere c.LLslAkly -.4HIs pnsmt on the wa[er? Yes No 7 'dA " 2. If cilstod}' seals acre prt aclit, were then intact al)II unbruks°n? pl I strip) IT)- -7 ,] Cl strip I.D. Coulcr DiOrig�nal ternperamra upon receipt-Derived (milli P,/�L�) I.�LIrpUELLLurc LLpan receipt ,+ a 6C. 1. to A, c l oG +r t cc d MettLod' u Temperature Blank a-Agoinst Bot -des IR Oun EES; 6o 11R Ciuii Ct)j-tk+:t1Un 1~aclor. aC MvttlQd of Wo Lunt; dWet Ice r Ahn-- Tc.s ❑ Lliy lee ® Now yrs El Tin n N. ,t l 3_ Ix Ierrp"- um of any cooler exceeded ECIC., was 1h"oieet.Nlatt er Notif ed? PM was loth cd Im. phone i einaiil i fate-Iu-facx (circle one)_ Yes u NLl ri ,d,%.a- 4, Is the uommcrcial courier's p loin slip attadiedto this Unarm? 5. Wuru propu custody p eciurac'(-&Iiiiquishadfreoeived'1 follow4ud? Y *3 Q Yes)Er— Na ❑ 6. WL`r4 sumplc IDs listed on the ?. Vere :wimple TDt Iisted on all .sample ctlntainerV.? S. Was ealketinn date k time Iislcd onthe COC'_) 9_ )Ala x calicution date & ti;Ine listed on all sample containers? Yc - No ❑ Y4 No ❑ Nu ❑ Yes ycs,, No ❑ 10. Did all contairrcr labcl information (ID- date, Tillie) Iuu jsdth the COC? 11. Wcrc tcsts tc% he performrd lislcd on the COC . 12. Did all samples arrive in the proper c ontxiners for each test andlor in Eaod uindilioTt No ❑ yr% Nn , (unbrokeli, lids on, eU,)'? Vest'" NO 7 11 Was udtx[nnlm xarnpk ve1unie art lalble.1 14, V1+crc .all sarnpla;; receiwrd within L/-, the holding Ow or 48 hours_ +hfiichever r'oules first2 15. Were kmy sLampUes containers missingle_riccss (circle one) saw p] -_r3 Not listed on COC:? 16. 'Weer lllrbhlrs pin5mit >"pea -size" (°t,"or 6rrurl in diameter'I in anv VOA vials`•` Yc�; a Nezr' NU'0— No ❑ Yes ❑ Ycr, a ]SIA Ycs gl No ❑ NA u I e. VL'cm all 1]110imel-11 O.utriczr, samples recelvt J a1 n pH of No n N yus ❑ 18- 4k'are all cyanide samples re iv;d at a pH > 12 and sultidi- �ampIus received at a pH = 9? yf-q I i Na ri , 19. X14= all applicable NH3.+`fKN:L;yanli(Ir, phrnolfBNA (-;:0_5taWL) sampks free ofra~ idioal (Worine? 2U. Were crpllectinn krmparatl-Lres documents VIL Ilan COC for NC,ambles? yQs ❑ No ❑ N,' YC3 C • No ❑ ltiA,�r 21. We a client remarkshvqucsts (Le, requested dilULI 11b, MSrl'r+IS0 designariaw, ctc... j c4orruclly Irranscribcd from the C)OC: into the cemaLnLnt sectina1 in i.IMS? Ycs ❑ NW 22. _W-15; thO uatc. number used Lakm kuLn the ccantaincT label^ Sample EIrrfiexvatiew (MUst be coanplewd for duly ana, le(s) inomectlL preserved or witty beadspra:ce) sample(q) wGrc rcccived incon-eLtlu prmcrved and were1uslyd accordingly in s2lmplc rceciving• With (H2SOd, HNU!i, HCI, NaOH) using SR .# sample(s) m5mL receiviad with bubbles >6 chin in diameter_ Sa)uples(s) wEre received with TRC > 0.5 mgiL- (If #21 is No) and Nvene ad-usted acctardingly in saris le m° Lvinr, with sodium thiosuilfate (NaaS204i wifli Shealy IR _C' Prinking Water Project Sarl,p1L(ti) pH v(xifiod to be < 2 by fDmiz: Stam le(s _ Not received al a p1lT u < 2 and were aLdjwted amQrdingly using S€t4 Sample lahels applied Nte;_ 7-3f , Curuliivnk�; Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 45 of 45 REVISION Page 47 of 47 _ CHAIN ID = CUSTODY R__E_COR_D_A___N_D_AN_ RLYSIS RE �U_EST FOR— _ A _ _ _ _ Pa le i of I )UKE - nalytical Laboratory Services i Anal cal Laboratory Use Only ! efamillMail CodeMGOlA2laulINlnal'405) i i Matrix: SOIL rI I: -i ENE RGY 713Ue Halters I°erry RUl7 Tv�� 3'inpl°' Ste_ DISTRIBUTION i Ori Rall from DI1 V "1ltulters7illl, N. c, 1130113I QRIGIIJIILIO AB, s (150) 11V5.5115 i i r Z �' iy® IIAIIIPY PnOO I.AM SM014 i COP r to CLIENT 6)9usin on Init: I_ax:f`8g� 81.6 4348 r /n� o I A-' _1 Z 1} Molar RIDES j 8 0.cUrity ID: 'ie)Process ID — — --- — —I ty1 no Important: When specific ive need the following: 2) Provide correct accounting accounting has been established and Is not Indicated above 1) Enter correct accounting In all 5 accounting fields above, or for Operating Unit and Process ID. _ 011 Ver _ j '►l'r°Iect I lame AB 13round Nater Assessment -Soil tjPbone No: a, SHEALY 2 � PIhnl ,_ ! RDVlliDiI 1 (11-17-17) $ _ e r (.01 I Suppleinental Soil resting) — G PO 50 ? IU 13 Cooler Tem C R:RA Waste_ I 3jCllint t1}I"ealMr Pe "I'rM.: B17RCDl�rl�t�_�B;i, c ' 1E ro i -- S A13 G N ! 21H oa 1111 ' Ir1Ii3 WATER EQUIPMENT BLANK (1 PER DAY) c 0 U c o ac p # c 45 6)9usin on Init: 6IPro(act o: tr)Mall Code: r /n� o e) Operating Unit: 8 0.cUrity ID: 'ie)Process ID Important: When specific ive need the following: 2) Provide correct accounting accounting has been established and Is not Indicated above 1) Enter correct accounting In all 5 accounting fields above, or for Operating Unit and Process ID. r-------------- 1 12Chem i IADUSE 0ILY i a, "ILab 19 i r Desktop No. "Sam le Description or ID a 0 1 fiDl ibS ! s —$ is — G j 1107 o I I 0 u 1 I� i ie !Q �n a m B17RCDl�rl�t�_�B;i, c ' 1E ro i -- 1 I I I oN 1 I Ir1Ii3 WATER EQUIPMENT BLANK (1 PER DAY) By M m "Requested rumuroulld Dal me 14 Days sW V" Datamine -r Deis Opened sy - Detemme •fB lir Metals By 6010: Al, Be, S. Cs, Cr, Cu, Fe, Mg, Mn, Mo, NI, K, Na, Sr, Zn Metals by 6020: Sb, As, Be, Cd, Co, Pb, Se, 71, V Hg by 7471 oH. %Salida. Anions: Cl. Nitrate -N. 504 Ll C�►h�rner tmm1lel# Se ell a, d C a m B17RCDl�rl�t�_�B;i, c oN c 0 U c o ac p # c 45 =I Jon c U) 12X1 1 0 r "Coll a ction I if ermation N to Tim 61 Italuse V-0 70Y . '/). v I m "Requested rumuroulld Dal me 14 Days sW V" Datamine -r Deis Opened sy - Detemme •fB lir Metals By 6010: Al, Be, S. Cs, Cr, Cu, Fe, Mg, Mn, Mo, NI, K, Na, Sr, Zn Metals by 6020: Sb, As, Be, Cd, Co, Pb, Se, 71, V Hg by 7471 oH. %Salida. Anions: Cl. Nitrate -N. 504 Ll