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Home My WebLink AboutDuke-Mayo Soil_20171005DUE Analytical Laboratory ENERGY Y 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Vendor QC Data Review Summary Report Order Number: J17070462 Project Name: MAYO STEAM - AB GW ASSESS SOIL(2017 SUPPLEMENTAL SOIL TESTING Customer Name(s): Bryan Moeller, Tim Hunsucker, Jerry Wylie,Fred Holt, Brandon Russo, Kathy We Lab Contact: Peggy Kendall Phone: 980-875-5848 do=corn, dc=duke-energy, do=ent, dc=nam,ou=Accounts, ou=Personal, ou=PNTransitional, " I cn=MA05125 (154363) Report Authorized By: 1 agree to specified portions ofthis Date: 8/10/2017 document. (Signature) 2017.08.10 15:23:20 -04'00' Mary Ann Ogle Program Comments: Please review all vendor data for case narratives with explanations of quality control failures and data qualifiers. Analytical lab Page 1 of 130 Any analytical tests or individual analytes within a test flagged with a qualifier indicate a deviation from the method quality system or quality control requirement. Certified vendor results and QC qualifiers can be found in the vendor lab final report. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Vendor Data Review Criteria: This vendor data package has been reviewed at the Duke Analytical Laboratory for the following applicable criteria: • Required QC samples collected and analyzed • Required tests performed for all samples • Vendor Laboratory utilized required test methods for all analyses • Vendor Laboratory met all requested Reporting Limits (RL) • QC Results reviewed for outlying recovery values Case Narrative: The MS/MSD recoveries for Al, Ba, Ca, Cr, Fe, Mo, Ni, Na, Sb and Zn failed recoveries on BFSB-2 (4-5). Al and Fe failed due to elevated sample concentrations. Al , B, As, Sb were detected in the method blank at 13 mg/Kg, 1.3 mg/Kg, 0.11 mg/kg 0.51 mg/Kg respectively. Concentrations in the sample that are < 1 OX the blank levels may be the result of contamination. The equipment blank contained 0.18 mg/L Fe and 0.0019 mg/L Sb. Analytical lab Page 2 of 130 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Peggy Kendall Project Name: J17070462 Project Number: J17070462 Lot Number:SG19027 Date Completed:08/08/2017 08/08/2017 9:18 AM Approved and released by: Project Manager: Grant Wilton LABORATORY ACCREDITATION XFCXXXIXiX BUREAU adlvision of A -S -X qe �' ACCREDITED iSonEc 1708 The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 1 of 127 Analytical lab Page 3 of 130 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: SG19027 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals Analysis - Method 6010D Aluminum, Boron, Iron, Molybdenum, Nickel and Sodium were recovered outside the control limit in the MS associated with batch 46955. Aluminum, Barium, Boron, Calcium, Chromium, Magnesium, Molybdenum, Nickel, Sodium and Zinc were recovered outside the control limit in the MSD. Since the LCS and Method Blank were within control limits it was determined that matrix interference caused the MS/MSD to fail. Sample -005: The sample was analyzed for Boron, Molybdenum and Nickel at a 5X dilution due to matrix interference (low internal standard recoveries). The reporting limits were raised accordingly. Sample -014, -016: The samples were analyzed for Boron and Molybdenum at a 5X dilution due to matrix interference (low internal standard recoveries). The reporting limits were raised accordingly. Sample -017: The sample was analyzed for Boron at a 5X dilution due to matrix interference (low internal standard recoveries). The reporting limits were raised accordingly. Metals Analysis - Method 60208 Antimony was recovered below the control limit in the MS/MSD associated with batch 47212. Since the LCS and Method Blank were within control limits it was determined that matrix interference caused the MS/MSD to fail. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 2 of 127 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: SG19027 Project Name: J17070462 Project Number: J17070462 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017024561 Solid 07/18/20171050 07/19/2017 002 2017024562 Solid 07/18/20171050 07/19/2017 003 2017024563 Solid 07/18/20171050 07/19/2017 004 2017024564 Solid 07/18/20171125 07/19/2017 005 2017024565 Solid 07/18/20171125 07/19/2017 006 2017024566 Solid 07/18/20171155 07/19/2017 007 2017024567 Solid 07/18/20171155 07/19/2017 008 2017024568 Solid 07/18/20171155 07/19/2017 009 2017024569 Solid 07/18/2017 0915 07/19/2017 010 2017024570 Solid 07/18/2017 0915 07/19/2017 011 2017024571 Solid 07/18/2017 0915 07/19/2017 012 2017024572 Solid 07/18/20171435 07/19/2017 013 2017024573 Solid 07/18/20171435 07/19/2017 014 2017024574 Solid 07/18/20171510 07/19/2017 015 2017024575 Aqueous 07/18/20171040 07/19/2017 016 2017024576 Solid 07/18/20171510 07/19/2017 017 2017024577 Solid 07/18/20171510 07/19/2017 (17 samples) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3 of 127 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 127 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary Duke Energy Lot Number: SG19027 Project Name: J17070462 Project Number: J17070462 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017024561 Solid Chloride (soluble) 9056A 4.4 J mg/kg 12 001 2017024561 Solid Nitrate - N (soluble) 9056A 0.056 J mg/kg 12 001 2017024561 Solid Aluminum 6010D 21000 BS mg/kg 13 001 2017024561 Solid Barium 6010D 55 S mg/kg 13 001 2017024561 Solid Calcium 6010D 69 JS mg/kg 13 001 2017024561 Solid Chromium 6010D 3.3 S mg/kg 13 001 2017024561 Solid Copper 6010D 7.1 mg/kg 13 001 2017024561 Solid Iron 6010D 16000 S mg/kg 13 001 2017024561 Solid Magnesium 6010D 4600 mg/kg 13 001 2017024561 Solid Manganese 6010D 190 mg/kg 13 001 2017024561 Solid Nickel 6010D 0.86 JS mg/kg 13 001 2017024561 Solid Potassium 6010D 3200 mg/kg 13 001 2017024561 Solid Sodium 6010D 160 JS mg/kg 13 001 2017024561 Solid Strontium 6010D 4.8 mg/kg 13 001 2017024561 Solid Zinc 6010D 40 S mg/kg 13 001 2017024561 Solid Arsenic 6020B 0.49 BJ mg/kg 14 001 2017024561 Solid Beryllium 6020B 0.50 mg/kg 14 001 2017024561 Solid Cobalt 6020B 6.1 mg/kg 14 001 2017024561 Solid Lead 6020B 7.0 mg/kg 14 001 2017024561 Solid Selenium 6020B 0.66 J mg/kg 14 001 2017024561 Solid Thallium 6020B 0.17 mg/kg 14 001 2017024561 Solid Vanadium 6020B 36 mg/kg 14 002 2017024562 Solid Chloride (soluble) 9056A 8.8 J mg/kg 16 002 2017024562 Solid Nitrate - N (soluble) 9056A 0.071 J mg/kg 16 002 2017024562 Solid Aluminum 6010D 16000 B mg/kg 17 002 2017024562 Solid Barium 6010D 80 mg/kg 17 002 2017024562 Solid Calcium 6010D 430 mg/kg 17 002 2017024562 Solid Chromium 6010D 34 mg/kg 17 002 2017024562 Solid Copper 6010D 26 mg/kg 17 002 2017024562 Solid Iron 6010D 15000 mg/kg 17 002 2017024562 Solid Magnesium 6010D 4700 mg/kg 17 002 2017024562 Solid Manganese 6010D 210 mg/kg 17 002 2017024562 Solid Molybdenum 6010D 1.0 J mg/kg 17 002 2017024562 Solid Nickel 6010D 7.4 mg/kg 17 002 2017024562 Solid Potassium 6010D 3100 mg/kg 17 002 2017024562 Solid Sodium 6010D 73 J mg/kg 17 002 2017024562 Solid Strontium 6010D 10 mg/kg 17 002 2017024562 Solid Zinc 6010D 32 mg/kg 17 002 2017024562 Solid Antimony 6020B 0.12 J mg/kg 18 002 2017024562 Solid Arsenic 6020B 0.53 B mg/kg 18 002 2017024562 Solid Beryllium 6020B 0.53 mg/kg 18 002 2017024562 Solid Cobalt 6020B 8.8 mg/kg 18 002 2017024562 Solid Lead 6020B 4.4 mg/kg 18 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 127 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2017024562 Solid Selenium 6020B 0.72 J mg/kg 18 002 2017024562 Solid Thallium 6020B 0.11 J mg/kg 18 002 2017024562 Solid Vanadium 6020B 42 mg/kg 18 003 2017024563 Solid Chloride (soluble) 9056A 51 mg/kg 20 003 2017024563 Solid Nitrate - N (soluble) 9056A 0.33 mg/kg 20 003 2017024563 Solid Aluminum 6010D 11000 B mg/kg 21 003 2017024563 Solid Barium 6010D 34 mg/kg 21 003 2017024563 Solid Calcium 6010D 220 J mg/kg 21 003 2017024563 Solid Chromium 6010D 1.4 mg/kg 21 003 2017024563 Solid Copper 6010D 5.0 mg/kg 21 003 2017024563 Solid Iron 6010D 7900 mg/kg 21 003 2017024563 Solid Magnesium 6010D 1800 mg/kg 21 003 2017024563 Solid Manganese 6010D 120 mg/kg 21 003 2017024563 Solid Potassium 6010D 1800 mg/kg 21 003 2017024563 Solid Sodium 6010D 180 J mg/kg 21 003 2017024563 Solid Strontium 6010D 10 mg/kg 21 003 2017024563 Solid Zinc 6010D 21 mg/kg 21 003 2017024563 Solid Arsenic 6020B 0.55 B mg/kg 22 003 2017024563 Solid Beryllium 6020B 0.41 mg/kg 22 003 2017024563 Solid Cobalt 6020B 3.5 mg/kg 22 003 2017024563 Solid Lead 6020B 6.6 mg/kg 22 003 2017024563 Solid Selenium 6020B 0.71 J mg/kg 22 003 2017024563 Solid Thallium 6020B 0.10 J mg/kg 22 003 2017024563 Solid Vanadium 6020B 15 mg/kg 22 004 2017024564 Solid Chloride (soluble) 9056A 42 mg/kg 24 004 2017024564 Solid Nitrate - N (soluble) 9056A 0.36 mg/kg 24 004 2017024564 Solid Aluminum 6010D 28000 B mg/kg 25 004 2017024564 Solid Barium 6010D 140 mg/kg 25 004 2017024564 Solid Calcium 6010D 1200 J mg/kg 25 004 2017024564 Solid Chromium 6010D 36 mg/kg 25 004 2017024564 Solid Copper 6010D 18 mg/kg 25 004 2017024564 Solid Iron 6010D 43000 mg/kg 25 004 2017024564 Solid Magnesium 6010D 18000 mg/kg 25 004 2017024564 Solid Manganese 6010D 570 mg/kg 25 004 2017024564 Solid Nickel 6010D 23 mg/kg 25 004 2017024564 Solid Potassium 6010D 11000 mg/kg 25 004 2017024564 Solid Sodium 6010D 1400 mg/kg 25 004 2017024564 Solid Strontium 6010D 30 mg/kg 25 004 2017024564 Solid Zinc 6010D 190 mg/kg 25 004 2017024564 Solid Arsenic 6020B 0.58 B mg/kg 26 004 2017024564 Solid Beryllium 60208 0.78 mg/kg 26 004 2017024564 Solid Cobalt 6020B 21 mg/kg 26 004 2017024564 Solid Lead 6020B 8.3 mg/kg 26 004 2017024564 Solid Selenium 6020B 2.6 mg/kg 26 004 2017024564 Solid Thallium 6020B 0.33 mg/kg 26 004 2017024564 Solid Vanadium 6020B 100 mg/kg 26 005 2017024565 Solid Chloride (soluble) 9056A 2.1 J mg/kg 28 005 2017024565 Solid Nitrate - N (soluble) 9056A 0.038 J mg/kg 28 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5 of 127 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 005 2017024565 Solid Aluminum 6010D 18000 B mg/kg 29 005 2017024565 Solid Barium 6010D 150 8.9 mg/kg 29 005 2017024565 Solid Calcium 6010D 1100 J mg/kg 29 005 2017024565 Solid Chromium 6010D 1.3 J mg/kg 29 005 2017024565 Solid Copper 6010D 6.8 1.0 mg/kg 29 005 2017024565 Solid Iron 6010D 25000 17 mg/kg 29 005 2017024565 Solid Magnesium 6010D 8300 8.4 mg/kg 29 005 2017024565 Solid Manganese 6010D 770 1.3 mg/kg 29 005 2017024565 Solid Potassium 6010D 5500 0.083 mg/kg 29 005 2017024565 Solid Sodium 6010D 460 J mg/kg 29 005 2017024565 Solid Strontium 6010D 28 16 mg/kg 29 005 2017024565 Solid Zinc 6010D 110 24000 mg/kg 29 005 2017024565 Solid Arsenic 6020B 0.34 BJ mg/kg 30 005 2017024565 Solid Beryllium 6020B 0.68 840 mg/kg 30 005 2017024565 Solid Cobalt 6020B 16 3.4 mg/kg 30 005 2017024565 Solid Lead 6020B 2.6 84 mg/kg 30 005 2017024565 Solid Selenium 6020B 1.1 mg/kg 30 005 2017024565 Solid Thallium 6020B 0.075 J mg/kg 30 005 2017024565 Solid Vanadium 6020B 13 mg/kg 30 006 2017024566 Solid Chloride (soluble) 9056A 13 mg/kg 32 006 2017024566 Solid Nitrate - N (soluble) 9056A 0.080 J mg/kg 32 006 2017024566 Solid Aluminum 6010D 31000 B mg/kg 33 006 2017024566 Solid Barium 6010D 69 mg/kg 33 006 2017024566 Solid Calcium 6010D 260 J mg/kg 33 006 2017024566 Solid Chromium 6010D 12 mg/kg 33 006 2017024566 Solid Copper 6010D 50 mg/kg 33 006 2017024566 Solid Iron 6010D 27000 mg/kg 33 006 2017024566 Solid Magnesium 6010D 2500 mg/kg 33 006 2017024566 Solid Manganese 6010D 120 mg/kg 33 006 2017024566 Solid Molybdenum 6010D 0.81 J mg/kg 33 006 2017024566 Solid Nickel 6010D 1.3 J mg/kg 33 006 2017024566 Solid Potassium 6010D 1100 mg/kg 33 006 2017024566 Solid Sodium 6010D 96 J mg/kg 33 006 2017024566 Solid Strontium 6010D 8.9 mg/kg 33 006 2017024566 Solid Zinc 6010D 34 mg/kg 33 006 2017024566 Solid Arsenic 6020B 1.6 B mg/kg 34 006 2017024566 Solid Beryllium 6020B 1.0 mg/kg 34 006 2017024566 Solid Cobalt 6020B 17 mg/kg 34 006 2017024566 Solid Lead 6020B 8.4 mg/kg 34 006 2017024566 Solid Selenium 6020B 1.3 J mg/kg 34 006 2017024566 Solid Thallium 6020B 0.083 J mg/kg 34 006 2017024566 Solid Vanadium 6020B 94 mg/kg 34 007 2017024567 Solid Chloride (soluble) 9056A 16 mg/kg 36 007 2017024567 Solid Aluminum 6010D 24000 B mg/kg 37 007 2017024567 Solid Barium 6010D 210 mg/kg 37 007 2017024567 Solid Calcium 6010D 840 mg/kg 37 007 2017024567 Solid Chromium 6010D 3.4 mg/kg 37 007 2017024567 Solid Copper 6010D 84 mg/kg 37 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 127 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 007 2017024567 Solid Iron 6010D 22000 24 mg/kg 37 007 2017024567 Solid Magnesium 6010D 6600 4.6 mg/kg 37 007 2017024567 Solid Manganese 6010D 310 2.1 mg/kg 37 007 2017024567 Solid Nickel 6010D 2.1 J mg/kg 37 007 2017024567 Solid Potassium 6010D 4100 160 mg/kg 37 007 2017024567 Solid Sodium 6010D 260 J mg/kg 37 007 2017024567 Solid Strontium 6010D 17 0.095 mg/kg 37 007 2017024567 Solid Zinc 6010D 54 23000 mg/kg 37 007 2017024567 Solid Arsenic 6020B 0.60 B mg/kg 38 007 2017024567 Solid Beryllium 6020B 1.1 470 mg/kg 38 007 2017024567 Solid Cobalt 6020B 24 40 mg/kg 38 007 2017024567 Solid Lead 6020B 8.8 22 mg/kg 38 007 2017024567 Solid Selenium 6020B 1.7 27000 mg/kg 38 007 2017024567 Solid Thallium 6020B 0.084 J mg/kg 38 007 2017024567 Solid Vanadium 6020B 69 240 mg/kg 38 008 2017024568 Solid Chloride (soluble) 9056A 6.0 J mg/kg 40 008 2017024568 Solid Nitrate - N (soluble) 9056A 0.089 J mg/kg 40 008 2017024568 Solid Aluminum 6010D 36000 B mg/kg 41 008 2017024568 Solid Barium 6010D 270 mg/kg 41 008 2017024568 Solid Calcium 6010D 2800 mg/kg 41 008 2017024568 Solid Chromium 6010D 10 mg/kg 41 008 2017024568 Solid Copper 6010D 68 mg/kg 41 008 2017024568 Solid Iron 6010D 42000 mg/kg 41 008 2017024568 Solid Magnesium 6010D 13000 mg/kg 41 008 2017024568 Solid Manganese 6010D 130 mg/kg 41 008 2017024568 Solid Nickel 6010D 4.3 mg/kg 41 008 2017024568 Solid Potassium 6010D 5600 mg/kg 41 008 2017024568 Solid Sodium 6010D 540 J mg/kg 41 008 2017024568 Solid Strontium 6010D 49 mg/kg 41 008 2017024568 Solid Zinc 6010D 94 mg/kg 41 008 2017024568 Solid Arsenic 6020B 0.58 BJ mg/kg 42 008 2017024568 Solid Beryllium 6020B 2.2 mg/kg 42 008 2017024568 Solid Cobalt 6020B 24 mg/kg 42 008 2017024568 Solid Lead 6020B 4.6 mg/kg 42 008 2017024568 Solid Selenium 6020B 2.1 mg/kg 42 008 2017024568 Solid Thallium 6020B 0.11 J mg/kg 42 008 2017024568 Solid Vanadium 6020B 160 mg/kg 42 009 2017024569 Solid Chloride (soluble) 9056A 1.7 J mg/kg 44 009 2017024569 Solid Nitrate - N (soluble) 9056A 0.095 J mg/kg 44 009 2017024569 Solid Aluminum 6010D 23000 B mg/kg 45 009 2017024569 Solid Barium 6010D 41 mg/kg 45 009 2017024569 Solid Calcium 6010D 470 mg/kg 45 009 2017024569 Solid Chromium 6010D 40 mg/kg 45 009 2017024569 Solid Copper 6010D 22 mg/kg 45 009 2017024569 Solid Iron 6010D 27000 mg/kg 45 009 2017024569 Solid Magnesium 6010D 980 mg/kg 45 009 2017024569 Solid Manganese 6010D 240 mg/kg 45 009 2017024569 Solid Molybdenum 6010D 1.0 J mg/kg 45 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 127 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 009 2017024569 Solid Nickel 6010D 4.3 0.96 mg/kg 45 009 2017024569 Solid Potassium 6010D 490 0.12 mg/kg 45 009 2017024569 Solid Strontium 6010D 9.8 120 mg/kg 45 009 2017024569 Solid Zinc 6010D 37 0.029 mg/kg 45 009 2017024569 Solid Arsenic 6020B 2.6 B mg/kg 46 009 2017024569 Solid Beryllium 6020B 0.40 0.037 mg/kg 46 009 2017024569 Solid Cobalt 6020B 17 32000 mg/kg 46 009 2017024569 Solid Lead 6020B 14 250 mg/kg 46 009 2017024569 Solid Selenium 6020B 0.62 J mg/kg 46 009 2017024569 Solid Thallium 6020B 0.20 6.1 mg/kg 46 009 2017024569 Solid Vanadium 6020B 130 11 mg/kg 46 009 2017024569 Solid Mercury 7471B 0.050 J mg/kg 47 010 2017024570 Solid Chloride (soluble) 9056A 1.8 J mg/kg 48 010 2017024570 Solid Nitrate - N (soluble) 9056A 0.043 J mg/kg 48 010 2017024570 Solid Aluminum 6010D 38000 B mg/kg 49 010 2017024570 Solid Barium 6010D 53 3800 mg/kg 49 010 2017024570 Solid Calcium 6010D 540 mg/kg 49 010 2017024570 Solid Chromium 6010D 20 mg/kg 49 010 2017024570 Solid Copper 6010D 33 mg/kg 49 010 2017024570 Solid Iron 6010D 36000 mg/kg 49 010 2017024570 Solid Magnesium 6010D 2100 mg/kg 49 010 2017024570 Solid Manganese 6010D 280 mg/kg 49 010 2017024570 Solid Molybdenum 6010D 1.2 J mg/kg 49 010 2017024570 Solid Nickel 6010D 7.4 mg/kg 49 010 2017024570 Solid Potassium 6010D 480 mg/kg 49 010 2017024570 Solid Strontium 6010D 10 mg/kg 49 010 2017024570 Solid Zinc 6010D 45 mg/kg 49 010 2017024570 Solid Arsenic 6020B 2.0 B mg/kg 50 010 2017024570 Solid Beryllium 6020B 0.44 mg/kg 50 010 2017024570 Solid Cadmium 6020B 0.019 J mg/kg 50 010 2017024570 Solid Cobalt 6020B 12 mg/kg 50 010 2017024570 Solid Lead 6020B 19 mg/kg 50 010 2017024570 Solid Selenium 6020B 0.96 J mg/kg 50 010 2017024570 Solid Thallium 6020B 0.12 J mg/kg 50 010 2017024570 Solid Vanadium 6020B 120 mg/kg 50 010 2017024570 Solid Mercury 7471B 0.029 J mg/kg 51 011 2017024571 Solid Chloride (soluble) 9056A 1.3 J mg/kg 52 011 2017024571 Solid Nitrate - N (soluble) 9056A 0.037 J mg/kg 52 011 2017024571 Solid Aluminum 6010D 32000 B mg/kg 53 011 2017024571 Solid Barium 6010D 250 mg/kg 53 011 2017024571 Solid Calcium 6010D 3100 mg/kg 53 011 2017024571 Solid Chromium 6010D 6.1 mg/kg 53 011 2017024571 Solid Copper 6010D 11 mg/kg 53 011 2017024571 Solid Iron 6010D 31000 mg/kg 53 011 2017024571 Solid Magnesium 6010D 12000 mg/kg 53 011 2017024571 Solid Manganese 6010D 1200 mg/kg 53 011 2017024571 Solid Nickel 6010D 9.1 mg/kg 53 011 2017024571 Solid Potassium 6010D 3800 mg/kg 53 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 127 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 011 2017024571 Solid Strontium 6010D 54 30 mg/kg 53 011 2017024571 Solid Zinc 6010D 71 2.0 mg/kg 53 011 2017024571 Solid Antimony 6020B 0.30 J mg/kg 54 011 2017024571 Solid Arsenic 6020B 0.34 BJ mg/kg 54 011 2017024571 Solid Beryllium 6020B 0.80 83 mg/kg 54 011 2017024571 Solid Cobalt 6020B 38 4300 mg/kg 54 011 2017024571 Solid Lead 6020B 7.3 630 mg/kg 54 011 2017024571 Solid Selenium 6020B 1.6 58 mg/kg 54 011 2017024571 Solid Thallium 6020B 0.11 J mg/kg 54 011 2017024571 Solid Vanadium 6020B 110 23000 mg/kg 54 012 2017024572 Solid Chloride (soluble) 9056A 2.1 J mg/kg 56 012 2017024572 Solid Nitrate - N (soluble) 9056A 0.052 J mg/kg 56 012 2017024572 Solid Aluminum 6010D 10000 B mg/kg 57 012 2017024572 Solid Barium 6010D 120 1900 mg/kg 57 012 2017024572 Solid Calcium 6010D 2500 500 mg/kg 57 012 2017024572 Solid Chromium 6010D 4.6 19 mg/kg 57 012 2017024572 Solid Copper 6010D 17 mg/kg 57 012 2017024572 Solid Iron 6010D 11000 mg/kg 57 012 2017024572 Solid Magnesium 6010D 3900 mg/kg 57 012 2017024572 Solid Manganese 6010D 200 mg/kg 57 012 2017024572 Solid Molybdenum 6010D 0.60 J mg/kg 57 012 2017024572 Solid Nickel 6010D 3.6 mg/kg 57 012 2017024572 Solid Potassium 6010D 2500 mg/kg 57 012 2017024572 Solid Sodium 6010D 67 J mg/kg 57 012 2017024572 Solid Strontium 6010D 46 mg/kg 57 012 2017024572 Solid Zinc 6010D 25 mg/kg 57 012 2017024572 Solid Arsenic 6020B 0.34 BJ mg/kg 58 012 2017024572 Solid Beryllium 6020B 0.39 mg/kg 58 012 2017024572 Solid Cobalt 6020B 4.7 mg/kg 58 012 2017024572 Solid Lead 6020B 3.0 mg/kg 58 012 2017024572 Solid Selenium 6020B 0.32 J mg/kg 58 012 2017024572 Solid Thallium 6020B 0.14 mg/kg 58 012 2017024572 Solid Vanadium 6020B 30 mg/kg 58 013 2017024573 Solid Chloride (soluble) 9056A 2.0 J mg/kg 60 013 2017024573 Solid Nitrate - N (soluble) 9056A 0.085 J mg/kg 60 013 2017024573 Solid Aluminum 6010D 20000 B mg/kg 61 013 2017024573 Solid Barium 6010D 83 mg/kg 61 013 2017024573 Solid Calcium 6010D 4300 mg/kg 61 013 2017024573 Solid Chromium 6010D 630 mg/kg 61 013 2017024573 Solid Copper 6010D 58 mg/kg 61 013 2017024573 Solid Iron 6010D 25000 mg/kg 61 013 2017024573 Solid Magnesium 6010D 23000 mg/kg 61 013 2017024573 Solid Manganese 6010D 410 mg/kg 61 013 2017024573 Solid Molybdenum 6010D 0.53 J mg/kg 61 013 2017024573 Solid Nickel 6010D 130 mg/kg 61 013 2017024573 Solid Potassium 6010D 1900 mg/kg 61 013 2017024573 Solid Sodium 6010D 500 mg/kg 61 013 2017024573 Solid Strontium 6010D 19 mg/kg 61 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9 of 127 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 013 2017024573 Solid Zinc 6010D 44 mg/kg 013 2017024573 Solid Arsenic 6020B 0.33 BJ mg/kg 013 2017024573 Solid Beryllium 6020B 0.17 mg/kg 013 2017024573 Solid Cobalt 6020B 24 mg/kg 013 2017024573 Solid Lead 6020B 0.43 mg/kg 013 2017024573 Solid Thallium 6020B 0.039 J mg/kg 013 2017024573 Solid Vanadium 6020B 45 mg/kg 014 2017024574 Solid Chloride (soluble) 9056A 29 mg/kg 014 2017024574 Solid Nitrate - N (soluble) 9056A 0.33 mg/kg 014 2017024574 Solid Aluminum 6010D 40000 B mg/kg 014 2017024574 Solid Barium 6010D 350 mg/kg 014 2017024574 Solid Calcium 6010D 2400 mg/kg 014 2017024574 Solid Chromium 6010D 61 mg/kg 014 2017024574 Solid Copper 6010D 58 mg/kg 014 2017024574 Solid Iron 6010D 46000 mg/kg 014 2017024574 Solid Magnesium 6010D 15000 mg/kg 014 2017024574 Solid Manganese 6010D 450 mg/kg 014 2017024574 Solid Nickel 6010D 61 mg/kg 014 2017024574 Solid Potassium 6010D 3500 mg/kg 014 2017024574 Solid Sodium 6010D 2600 mg/kg 014 2017024574 Solid Strontium 6010D 60 mg/kg 014 2017024574 Solid Zinc 6010D 130 mg/kg 014 2017024574 Solid Arsenic 6020B 3.5 B mg/kg 014 2017024574 Solid Beryllium 6020B 1.5 mg/kg 014 2017024574 Solid Cobalt 6020B 81 mg/kg 014 2017024574 Solid Lead 6020B 9.0 mg/kg 014 2017024574 Solid Selenium 6020B 2.7 mg/kg 014 2017024574 Solid Thallium 6020B 0.23 mg/kg 014 2017024574 Solid Vanadium 6020B 140 mg/kg 015 2017024575 Aqueous Iron 6010D 0.18 mg/L 015 2017024575 Aqueous Manganese 6010D 0.0019 J mg/L 016 2017024576 Solid Chloride (soluble) 9056A 7.9 J mg/kg 016 2017024576 Solid Nitrate - N (soluble) 9056A 0.14 J mg/kg 016 2017024576 Solid Aluminum 6010D 50000 B mg/kg 016 2017024576 Solid Barium 6010D 520 mg/kg 016 2017024576 Solid Calcium 6010D 4900 mg/kg 016 2017024576 Solid Chromium 6010D 440 mg/kg 016 2017024576 Solid Copper 6010D 21 mg/kg 016 2017024576 Solid Iron 6010D 69000 mg/kg 016 2017024576 Solid Magnesium 6010D 40000 mg/kg 016 2017024576 Solid Manganese 6010D 2900 mg/kg 016 2017024576 Solid Nickel 6010D 140 mg/kg 016 2017024576 Solid Potassium 6010D 16000 mg/kg 016 2017024576 Solid Sodium 6010D 550 J mg/kg 016 2017024576 Solid Strontium 6010D 69 mg/kg 016 2017024576 Solid Zinc 6010D 330 mg/kg 016 2017024576 Solid Arsenic 6020B 1.8 B mg/kg 016 2017024576 Solid Beryllium 6020B 0.95 mg/kg Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 127 61 62 62 62 62 62 62 64 64 65 65 65 65 65 65 65 65 65 65 65 65 65 66 66 66 66 66 66 66 68 68 71 71 72 72 72 72 72 72 72 72 72 72 72 72 72 73 73 Detection Summary (Continued) Lot Number: SG19027 Sample Sample ID Matrix Parameter Method Result Q Units Page 016 2017024576 Solid Cadmium 6020B 0.24 mg/kg 73 016 2017024576 Solid Cobalt 6020B 37 mg/kg 73 016 2017024576 Solid Lead 6020B 5.3 mg/kg 73 016 2017024576 Solid Selenium 6020B 1.7 mg/kg 73 016 2017024576 Solid Thallium 6020B 0.56 mg/kg 73 016 2017024576 Solid Vanadium 6020B 110 mg/kg 73 017 2017024577 Solid Chloride (soluble) 9056A 3.2 J mg/kg 75 017 2017024577 Solid Nitrate - N (soluble) 9056A 0.092 J mg/kg 75 017 2017024577 Solid Aluminum 6010D 33000 B mg/kg 76 017 2017024577 Solid Barium 6010D 490 mg/kg 76 017 2017024577 Solid Calcium 6010D 2400 mg/kg 76 017 2017024577 Solid Chromium 6010D 70 mg/kg 76 017 2017024577 Solid Copper 6010D 94 mg/kg 76 017 2017024577 Solid Iron 6010D 69000 mg/kg 76 017 2017024577 Solid Magnesium 6010D 27000 mg/kg 76 017 2017024577 Solid Manganese 6010D 3100 mg/kg 76 017 2017024577 Solid Molybdenum 6010D 1.9 J mg/kg 76 017 2017024577 Solid Nickel 6010D 53 mg/kg 76 017 2017024577 Solid Potassium 6010D 19000 mg/kg 76 017 2017024577 Solid Sodium 6010D 88 J mg/kg 76 017 2017024577 Solid Strontium 6010D 38 mg/kg 76 017 2017024577 Solid Zinc 6010D 260 mg/kg 76 017 2017024577 Solid Arsenic 6020B 1.6 B mg/kg 77 017 2017024577 Solid Beryllium 6020B 1.0 mg/kg 77 017 2017024577 Solid Cadmium 6020B 0.22 mg/kg 77 017 2017024577 Solid Cobalt 6020B 34 mg/kg 77 017 2017024577 Solid Lead 6020B 5.3 mg/kg 77 017 2017024577 Solid Selenium 6020B 0.98 J mg/kg 77 017 2017024577 Solid Thallium 6020B 0.79 mg/kg 77 017 2017024577 Solid Vanadium 6020B 170 mg/kg 77 (361 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-001 Description: 2017024561 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 86.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 1848 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 1848 TAF 47784 1 (pH) 9045D 1 07/20/2017 1534 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 1848 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 4.4 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.056 J 0.23 0.028 mg/kg 1 pH 9045D 6.08 su 1 Sulfate (soluble) 9056A ND 12 5.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-001 Description: 2017024561 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 86.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0135 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 1 07/28/2017 2040 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 07/30/2017 1617 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 21000 BS 20 7.4 mg/kg 1 Barium 7440-39-3 6010D 55 S 1.3 0.32 mg/kg 1 Boron 7440-42-8 6010D ND S 2.5 0.98 mg/kg 1 Calcium 7440-70-2 6010D 69 JS 250 31 mg/kg 1 Chromium 7440-47-3 6010D 3.3 S 0.49 0.12 mg/kg 3 Copper 7440-50-8 6010D 7.1 0.49 0.22 mg/kg 1 Iron 7439-89-6 6010D 16000 S 4.9 2.2 mg/kg 1 Magnesium 7439-95-4 6010D 4600 250 31 mg/kg 1 Manganese 7439-96-5 6010D 190 0.74 0.29 mg/kg 1 Molybdenum 7439-98-7 6010D ND S 2.0 0.49 mg/kg 1 Nickel 7440-02-0 6010D 0.86 JS 2.0 0.52 mg/kg 1 Potassium 7440-09-7 6010D 3200 250 31 mg/kg 1 Sodium 7440-23-5 6010D 160 JS 250 31 mg/kg 1 Strontium 7440-24-6 6010D 4.8 0.98 0.25 mg/kg 4 Zinc 7440-66-6 6010D 40 S 2.5 0.62 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-001 Description: 2017024561 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 86.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0409 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 1937 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND S 0.55 0.11 mg/kg 2 Arsenic 7440-38-2 6020B 0.49 BJ 0.55 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.50 0.11 0.022 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.027 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 6.1 0.77 0.27 mg/kg 1 Lead 7439-92-1 6020B 7.0 0.27 0.055 mg/kg 1 Selenium 7782-49-2 6020B 0.66 J 1.4 0.27 mg/kg 1 Thallium 7440-28-0 6020B 0.17 0.14 0.029 mg/kg 1 Vanadium 7440-62-2 6020B 36 1.4 0.27 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-001 Description: 2017024561 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 86.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2255 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.086 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-002 Description: 2017024562 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 1913 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 1913 TAF 47784 1 (pH) 9045D 1 07/20/2017 1536 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 1913 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 8.8 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.071 J 0.23 0.028 mg/kg 1 pH 9045D 6.25 su 1 Sulfate (soluble) 9056A ND 11 5.6 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-002 Description: 2017024562 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0158 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 1 07/28/2017 2112 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 07/30/2017 1644 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 16000 B 22 8.2 mg/kg 1 Barium 7440-39-3 6010D 80 1.4 0.36 mg/kg 1 Boron 7440-42-8 6010D ND 2.7 1.1 mg/kg 1 Calcium 7440-70-2 6010D 430 270 34 mg/kg 1 Chromium 7440-47-3 6010D 34 0.55 0.14 mg/kg 3 Copper 7440-50-8 6010D 26 0.55 0.25 mg/kg 1 Iron 7439-89-6 6010D 15000 5.5 2.5 mg/kg 1 Magnesium 7439-95-4 6010D 4700 270 34 mg/kg 1 Manganese 7439-96-5 6010D 210 0.82 0.32 mg/kg 1 Molybdenum 7439-98-7 6010D 1.0 J 2.2 0.55 mg/kg 1 Nickel 7440-02-0 6010D 7.4 2.2 0.57 mg/kg 1 Potassium 7440-09-7 6010D 3100 270 34 mg/kg 1 Sodium 7440-23-5 6010D 73 J 270 34 mg/kg 1 Strontium 7440-24-6 6010D 10 1.1 0.27 mg/kg 4 Zinc 7440-66-6 6010D 32 2.7 0.68 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-002 Description: 2017024562 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0436 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2018 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.12 J 0.49 0.098 mg/kg 2 Arsenic 7440-38-2 6020B 0.53 B 0.49 0.098 mg/kg 1 Beryllium 7440-41-7 6020B 0.53 0.098 0.020 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.024 0.0098 mg/kg 1 Cobalt 7440-48-4 6020B 8.8 0.69 0.24 mg/kg 1 Lead 7439-92-1 6020B 4.4 0.24 0.049 mg/kg 1 Selenium 7782-49-2 6020B 0.72 J 1.3 0.24 mg/kg 1 Thallium 7440-28-0 6020B 0.11 J 0.13 0.025 mg/kg 1 Vanadium 7440-62-2 6020B 42 1.3 0.24 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-002 Description: 2017024562 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2302 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.082 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-003 Description: 2017024563 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 1938 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 1938 TAF 47784 1 (pH) 9045D 1 07/20/2017 1538 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 1938 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 20 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 51 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.33 0.23 0.028 mg/kg 1 pH 9045D 6.21 su 1 Sulfate (soluble) 9056A ND 11 5.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 20 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-003 Description: 2017024563 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0203 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 1 07/28/2017 2117 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 07/30/2017 1648 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 11000 B 22 8.3 mg/kg 1 Barium 7440-39-3 6010D 34 1.4 0.36 mg/kg 1 Boron 7440-42-8 6010D ND 2.8 1.1 mg/kg 1 Calcium 7440-70-2 6010D 220 J 280 34 mg/kg 1 Chromium 7440-47-3 6010D 1.4 0.55 0.14 mg/kg 3 Copper 7440-50-8 6010D 5.0 0.55 0.25 mg/kg 1 Iron 7439-89-6 6010D 7900 5.5 2.5 mg/kg 1 Magnesium 7439-95-4 6010D 1800 280 34 mg/kg 1 Manganese 7439-96-5 6010D 120 0.83 0.33 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.2 0.55 mg/kg 1 Nickel 7440-02-0 6010D ND 2.2 0.58 mg/kg 1 Potassium 7440-09-7 6010D 1800 280 34 mg/kg 1 Sodium 7440-23-5 6010D 180 J 280 34 mg/kg 1 Strontium 7440-24-6 6010D 10 1.1 0.28 mg/kg 4 Zinc 7440-66-6 6010D 21 2.8 0.69 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-003 Description: 2017024563 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0442 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2024 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.50 0.10 mg/kg 2 Arsenic 7440-38-2 6020B 0.55 B 0.50 0.10 mg/kg 1 Beryllium 7440-41-7 6020B 0.41 0.10 0.020 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.025 0.010 mg/kg 1 Cobalt 7440-48-4 6020B 3.5 0.70 0.25 mg/kg 1 Lead 7439-92-1 6020B 6.6 0.25 0.050 mg/kg 1 Selenium 7782-49-2 6020B 0.71 J 1.3 0.25 mg/kg 1 Thallium 7440-28-0 6020B 0.10 J 0.13 0.026 mg/kg 1 Vanadium 7440-62-2 6020B 15 1.3 0.25 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-003 Description: 2017024563 Matrix: Solid Date Sampled:07/18/2017 1050 Project Name: J17070462 % Solids: 88.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2304 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.088 0.021 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 23 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-004 Description: 2017024564 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 91.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2003 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 2003 TAF 47784 1 (pH) 9045D 1 07/20/2017 1540 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 2003 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 24 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 42 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.36 0.22 0.027 mg/kg 1 pH 9045D 6.17 su 1 Sulfate (soluble) 9056A ND 11 5.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 24 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-004 Description: 2017024564 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 91.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3050B 601 OD 5 07/27/2017 2201 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 5 07/28/2017 2121 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 5 07/30/2017 1653 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 28000 B 100 38 mg/kg 2 Barium 7440-39-3 6010D 140 6.6 1.7 mg/kg 2 Boron 7440-42-8 6010D ND 13 5.1 mg/kg 2 Calcium 7440-70-2 6010D 1200 J 1300 160 mg/kg 2 Chromium 7440-47-3 6010D 36 2.6 0.64 mg/kg 3 Copper 7440-50-8 6010D 18 2.6 1.1 mg/kg 2 Iron 7439-89-6 6010D 43000 26 12 mg/kg 2 Magnesium 7439-95-4 6010D 18000 1300 160 mg/kg 2 Manganese 7439-96-5 6010D 570 3.8 1.5 mg/kg 2 Molybdenum 7439-98-7 6010D ND 10 2.6 mg/kg 2 Nickel 7440-02-0 6010D 23 10 2.7 mg/kg 2 Potassium 7440-09-7 6010D 11000 1300 160 mg/kg 2 Sodium 7440-23-5 6010D 1400 1300 160 mg/kg 2 Strontium 7440-24-6 6010D 30 5.1 1.3 mg/kg 4 Zinc 7440-66-6 6010D 190 13 3.2 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-004 Description: 2017024564 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 91.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0447 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2030 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.52 0.10 mg/kg 2 Arsenic 7440-38-2 6020B 0.58 B 0.52 0.10 mg/kg 1 Beryllium 7440-41-7 6020B 0.78 0.10 0.021 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.026 0.010 mg/kg 1 Cobalt 7440-48-4 6020B 21 0.72 0.26 mg/kg 1 Lead 7439-92-1 6020B 8.3 0.26 0.052 mg/kg 1 Selenium 7782-49-2 6020B 2.6 1.3 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.33 0.13 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 100 1.3 0.26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-004 Description: 2017024564 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 91.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2306 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.083 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 27 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-005 Description: 2017024565 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 94.9 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2028 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 2028 TAF 47784 1 (pH) 9045D 1 07/20/2017 1541 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 2028 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 28 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.1 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.038 J 0.21 0.026 mg/kg 1 pH 9045D 7.00 su 1 Sulfate (soluble) 9056A ND 11 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 28 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-005 Description: 2017024565 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 94.9 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3050B 601 OD 5 07/27/2017 2206 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 5 07/28/2017 2126 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 5 07/30/2017 1657 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 18000 B 98 37 mg/kg 2 Barium 7440-39-3 6010D 150 6.4 1.6 mg/kg 2 Boron 7440-42-8 6010D ND 12 4.9 mg/kg 2 Calcium 7440-70-2 6010D 1100 J 1200 150 mg/kg 2 Chromium 7440-47-3 6010D 1.3 J 2.4 0.61 mg/kg 3 Copper 7440-50-8 6010D 6.8 2.4 1.1 mg/kg 2 Iron 7439-89-6 6010D 25000 24 11 mg/kg 2 Magnesium 7439-95-4 6010D 8300 1200 150 mg/kg 2 Manganese 7439-96-5 6010D 770 3.7 1.4 mg/kg 2 Molybdenum 7439-98-7 6010D ND 9.8 2.4 mg/kg 2 Nickel 7440-02-0 6010D ND 9.8 2.6 mg/kg 2 Potassium 7440-09-7 6010D 5500 1200 150 mg/kg 2 Sodium 7440-23-5 6010D 460 J 1200 150 mg/kg 2 Strontium 7440-24-6 6010D 28 4.9 1.2 mg/kg 4 Zinc 7440-66-6 6010D 110 12 3.1 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-005 Description: 2017024565 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 94.9 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0503 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2036 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.39 0.078 mg/kg 2 Arsenic 7440-38-2 6020B 0.34 BJ 0.39 0.078 mg/kg 1 Beryllium 7440-41-7 6020B 0.68 0.078 0.016 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.020 0.0078 mg/kg 1 Cobalt 7440-48-4 6020B 16 0.55 0.20 mg/kg 1 Lead 7439-92-1 6020B 2.6 0.20 0.039 mg/kg 1 Selenium 7782-49-2 6020B 1.1 1.0 0.20 mg/kg 1 Thallium 7440-28-0 6020B 0.075 J 0.10 0.020 mg/kg 1 Vanadium 7440-62-2 6020B 13 1.0 0.20 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-005 Description: 2017024565 Matrix: Solid Date Sampled:07/18/2017 1125 Project Name: J17070462 % Solids: 94.9 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2309 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.080 0.019 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 31 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-006 Description: 2017024566 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2053 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 2053 TAF 47784 1 (pH) 9045D 1 07/20/2017 1542 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 2053 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 32 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 13 13 1.3 mg/kg 1 Nitrate - N (soluble) 9056A 0.080 J 0.26 0.032 mg/kg 1 pH 9045D 6.83 su 1 Sulfate (soluble) 9056A ND 13 6.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 32 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-006 Description: 2017024566 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0226 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 1 07/28/2017 2130 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 07/30/2017 1701 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 31000 B 25 9.5 mg/kg 1 Barium 7440-39-3 6010D 69 1.6 0.41 mg/kg 1 Boron 7440-42-8 6010D ND 3.2 1.3 mg/kg 1 Calcium 7440-70-2 6010D 260 J 320 40 mg/kg 1 Chromium 7440-47-3 6010D 12 0.63 0.16 mg/kg 3 Copper 7440-50-8 6010D 50 0.63 0.29 mg/kg 1 Iron 7439-89-6 6010D 27000 6.3 2.9 mg/kg 1 Magnesium 7439-95-4 6010D 2500 320 40 mg/kg 1 Manganese 7439-96-5 6010D 120 0.95 0.38 mg/kg 1 Molybdenum 7439-98-7 6010D 0.81 J 2.5 0.63 mg/kg 1 Nickel 7440-02-0 6010D 1.3 J 2.5 0.67 mg/kg 1 Potassium 7440-09-7 6010D 1100 320 40 mg/kg 1 Sodium 7440-23-5 6010D 96 J 320 40 mg/kg 1 Strontium 7440-24-6 6010D 8.9 1.3 0.32 mg/kg 4 Zinc 7440-66-6 6010D 34 3.2 0.79 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-006 Description: 2017024566 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0508 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2042 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.58 0.12 mg/kg 2 Arsenic 7440-38-2 6020B 1.6 B 0.58 0.12 mg/kg 1 Beryllium 7440-41-7 6020B 1.0 0.12 0.023 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.029 0.012 mg/kg 1 Cobalt 7440-48-4 6020B 17 0.81 0.29 mg/kg 1 Lead 7439-92-1 6020B 8.4 0.29 0.058 mg/kg 1 Selenium 7782-49-2 6020B 1.3 J 1.5 0.29 mg/kg 1 Thallium 7440-28-0 6020B 0.083 J 0.15 0.030 mg/kg 1 Vanadium 7440-62-2 6020B 94 1.5 0.29 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-006 Description: 2017024566 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2311 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.10 0.024 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 35 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-007 Description: 2017024567 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2118 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 2118 TAF 47784 1 (pH) 9045D 1 07/20/2017 1542 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 2118 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 36 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 16 13 1.3 mg/kg 1 Nitrate - N (soluble) 9056A ND 0.26 0.032 mg/kg 1 pH 9045D 6.62 su 1 Sulfate (soluble) 9056A ND 13 6.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 36 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-007 Description: 2017024567 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0230 CJZ 07/19/2017 1706 46955 2 3050B 601 OD 2 07/27/2017 2215 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 2 07/28/2017 2135 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 2 07/30/2017 1706 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 24000 B 49 19 mg/kg 2 Barium 7440-39-3 6010D 210 3.2 0.80 mg/kg 2 Boron 7440-42-8 6010D ND 3.1 1.2 mg/kg 1 Calcium 7440-70-2 6010D 840 620 77 mg/kg 2 Chromium 7440-47-3 6010D 3.4 0.62 0.15 mg/kg 1 Copper 7440-50-8 6010D 84 0.62 0.28 mg/kg 1 Iron 7439-89-6 6010D 22000 12 5.6 mg/kg 2 Magnesium 7439-95-4 6010D 6600 620 77 mg/kg 2 Manganese 7439-96-5 6010D 310 0.93 0.37 mg/kg 1 Molybdenum 7439-98-7 6010D ND 4.9 1.2 mg/kg 2 Nickel 7440-02-0 6010D 2.1 J 4.9 1.3 mg/kg 2 Potassium 7440-09-7 6010D 4100 620 77 mg/kg 2 Sodium 7440-23-5 6010D 260 J 620 77 mg/kg 2 Strontium 7440-24-6 6010D 17 2.5 0.62 mg/kg 4 Zinc 7440-66-6 6010D 54 6.2 1.5 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-007 Description: 2017024567 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0514 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2047 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.60 0.12 mg/kg 2 Arsenic 7440-38-2 6020B 0.60 B 0.60 0.12 mg/kg 1 Beryllium 7440-41-7 6020B 1.1 0.12 0.024 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.030 0.012 mg/kg 1 Cobalt 7440-48-4 6020B 24 0.84 0.30 mg/kg 1 Lead 7439-92-1 6020B 8.8 0.30 0.060 mg/kg 1 Selenium 7782-49-2 6020B 1.7 1.6 0.30 mg/kg 1 Thallium 7440-28-0 6020B 0.084 J 0.16 0.031 mg/kg 1 Vanadium 7440-62-2 6020B 69 1.6 0.30 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-007 Description: 2017024567 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 77.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2317 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.095 0.023 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 39 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-008 Description: 2017024568 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 71.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2323 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 2323 TAF 47784 1 (pH) 9045D 1 07/20/2017 1543 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 2323 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 40 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 6.0 J 14 1.4 mg/kg 1 Nitrate - N (soluble) 9056A 0.089 J 0.28 0.034 mg/kg 1 pH 9045D 6.72 su 1 Sulfate (soluble) 9056A ND 14 7.0 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 40 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-008 Description: 2017024568 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 71.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0235 CJZ 07/19/2017 1706 46955 2 3050B 601 OD 2 07/27/2017 2219 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 2 07/28/2017 2139 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 2 07/30/2017 1710 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 41 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 36000 B 51 19 mg/kg 2 Barium 7440-39-3 6010D 270 3.3 0.84 mg/kg 2 Boron 7440-42-8 6010D ND 3.2 1.3 mg/kg 1 Calcium 7440-70-2 6010D 2800 640 80 mg/kg 2 Chromium 7440-47-3 6010D 10 0.64 0.16 mg/kg 1 Copper 7440-50-8 6010D 68 0.64 0.29 mg/kg 1 Iron 7439-89-6 6010D 42000 13 5.8 mg/kg 2 Magnesium 7439-95-4 6010D 13000 640 80 mg/kg 2 Manganese 7439-96-5 6010D 130 0.96 0.38 mg/kg 1 Molybdenum 7439-98-7 6010D ND 2.6 0.64 mg/kg 1 Nickel 7440-02-0 6010D 4.3 2.6 0.67 mg/kg 1 Potassium 7440-09-7 6010D 5600 640 80 mg/kg 2 Sodium 7440-23-5 6010D 540 J 640 80 mg/kg 2 Strontium 7440-24-6 6010D 49 2.6 0.64 mg/kg 4 Zinc 7440-66-6 6010D 94 6.4 1.6 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 41 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-008 Description: 2017024568 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 71.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0519 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2053 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 42 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.67 0.13 mg/kg 2 Arsenic 7440-38-2 6020B 0.58 BJ 0.67 0.13 mg/kg 1 Beryllium 7440-41-7 6020B 2.2 0.13 0.027 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.034 0.013 mg/kg 1 Cobalt 7440-48-4 6020B 24 0.94 0.34 mg/kg 1 Lead 7439-92-1 6020B 4.6 0.34 0.067 mg/kg 1 Selenium 7782-49-2 6020B 2.1 1.8 0.34 mg/kg 1 Thallium 7440-28-0 6020B 0.11 J 0.18 0.035 mg/kg 1 Vanadium 7440-62-2 6020B 160 1.8 0.34 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 42 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-008 Description: 2017024568 Matrix: Solid Date Sampled:07/18/2017 1155 Project Name: J17070462 % Solids: 71.6 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2319 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.11 0.028 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 43 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-009 Description: 2017024569 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 84.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2348 TAF 47777 1 (Nitrate - N ) 9056A 1 07/26/2017 2348 TAF 47784 1 (pH) 9045D 1 07/20/2017 1544 MSG 47109 1 (Sulfate (sol) 9056A 1 07/26/2017 2348 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 44 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 1.7 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.095 J 0.24 0.029 mg/kg 1 pH 9045D 6.19 su 1 Sulfate (soluble) 9056A ND 12 5.9 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 44 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-009 Description: 2017024569 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 84.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0240 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 1 07/28/2017 2153 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 07/30/2017 1715 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 45 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 23000 B 23 8.8 mg/kg 1 Barium 7440-39-3 6010D 41 1.5 0.38 mg/kg 1 Boron 7440-42-8 6010D ND 2.9 1.2 mg/kg 1 Calcium 7440-70-2 6010D 470 290 36 mg/kg 1 Chromium 7440-47-3 6010D 40 0.58 0.15 mg/kg 3 Copper 7440-50-8 6010D 22 0.58 0.26 mg/kg 1 Iron 7439-89-6 6010D 27000 5.8 2.7 mg/kg 1 Magnesium 7439-95-4 6010D 980 290 36 mg/kg 1 Manganese 7439-96-5 6010D 240 0.88 0.35 mg/kg 1 Molybdenum 7439-98-7 6010D 1.0 J 2.3 0.58 mg/kg 1 Nickel 7440-02-0 6010D 4.3 2.3 0.61 mg/kg 1 Potassium 7440-09-7 6010D 490 290 36 mg/kg 1 Sodium 7440-23-5 6010D ND 290 36 mg/kg 1 Strontium 7440-24-6 6010D 9.8 1.2 0.29 mg/kg 4 Zinc 7440-66-6 6010D 37 2.9 0.73 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 45 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-009 Description: 2017024569 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 84.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0525 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2059 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 46 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.53 0.11 mg/kg 2 Arsenic 7440-38-2 6020B 2.6 B 0.53 0.11 mg/kg 1 Beryllium 7440-41-7 6020B 0.40 0.11 0.021 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.026 0.011 mg/kg 1 Cobalt 7440-48-4 6020B 17 0.74 0.26 mg/kg 1 Lead 7439-92-1 6020B 14 0.26 0.053 mg/kg 1 Selenium 7782-49-2 6020B 0.62 J 1.4 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.20 0.14 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 130 1.4 0.26 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 46 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-009 Description: 2017024569 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 84.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2321 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 0.050 J 0.091 0.022 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 47 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-010 Description: 2017024570 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 81.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 0013 TAF 47777 1 (Nitrate - N ) 9056A 1 07/27/2017 0013 TAF 47784 1 (pH) 9045D 1 07/20/2017 1545 MSG 47109 1 (Sulfate (sol) 9056A 1 07/27/2017 0013 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 48 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 1.8 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.043 J 0.24 0.030 mg/kg 1 pH 9045D 5.81 su 1 Sulfate (soluble) 9056A ND 12 6.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 48 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-010 Description: 2017024570 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 81.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0244 CJZ 07/19/2017 1706 46955 2 3050B 601 OD 2 07/27/2017 2228 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 2 07/28/2017 2158 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 07/30/2017 1719 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 49 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 38000 B 42 16 mg/kg 2 Barium 7440-39-3 6010D 53 1.4 0.34 mg/kg 1 Boron 7440-42-8 6010D ND 5.3 2.1 mg/kg 2 Calcium 7440-70-2 6010D 540 270 33 mg/kg 1 Chromium 7440-47-3 6010D 20 1.1 0.27 mg/kg 3 Copper 7440-50-8 6010D 33 1.1 0.48 mg/kg 2 Iron 7439-89-6 6010D 36000 11 4.8 mg/kg 2 Magnesium 7439-95-4 6010D 2100 530 66 mg/kg 2 Manganese 7439-96-5 6010D 280 1.6 0.63 mg/kg 2 Molybdenum 7439-98-7 6010D 1.2 J 2.1 0.53 mg/kg 1 Nickel 7440-02-0 6010D 7.4 4.2 1.1 mg/kg 2 Potassium 7440-09-7 6010D 480 270 33 mg/kg 1 Sodium 7440-23-5 6010D ND 270 33 mg/kg 1 Strontium 7440-24-6 6010D 10 1.1 0.27 mg/kg 4 Zinc 7440-66-6 6010D 45 5.3 1.3 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 49 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-010 Description: 2017024570 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 81.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0530 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2105 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 50 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.50 0.099 mg/kg 2 Arsenic 7440-38-2 6020B 2.0 B 0.50 0.099 mg/kg 1 Beryllium 7440-41-7 6020B 0.44 0.099 0.020 mg/kg 1 Cadmium 7440-43-9 6020B 0.019 J 0.025 0.0099 mg/kg 1 Cobalt 7440-48-4 6020B 12 0.70 0.25 mg/kg 1 Lead 7439-92-1 6020B 19 0.25 0.050 mg/kg 1 Selenium 7782-49-2 6020B 0.96 J 1.3 0.25 mg/kg 1 Thallium 7440-28-0 6020B 0.12 J 0.13 0.026 mg/kg 1 Vanadium 7440-62-2 6020B 120 1.3 0.25 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 50 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-010 Description: 2017024570 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 81.7 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2324 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 0.029 J 0.10 0.024 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 51 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-011 Description: 2017024571 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 78.1 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 0038 TAF 47777 1 (Nitrate - N ) 9056A 1 07/27/2017 0038 TAF 47784 1 (pH) 9045D 1 07/20/2017 1547 MSG 47109 1 (Sulfate (sol) 9056A 1 07/27/2017 0038 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 52 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 1.3 J 13 1.3 mg/kg 1 Nitrate - N (soluble) 9056A 0.037 J 0.26 0.031 mg/kg 1 pH 9045D 7.72 su 1 Sulfate (soluble) 9056A ND 13 6.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 52 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-011 Description: 2017024571 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 78.1 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3050B 601 OD 2 07/27/2017 2233 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 2 07/28/2017 2202 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 5 07/30/2017 1723 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 53 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 32000 B 45 17 mg/kg 2 Barium 7440-39-3 6010D 250 2.9 0.74 mg/kg 2 Boron 7440-42-8 6010D ND 5.7 2.3 mg/kg 2 Calcium 7440-70-2 6010D 3100 570 71 mg/kg 2 Chromium 7440-47-3 6010D 6.1 1.1 0.28 mg/kg 3 Copper 7440-50-8 6010D 11 1.1 0.51 mg/kg 2 Iron 7439-89-6 6010D 31000 11 5.1 mg/kg 2 Magnesium 7439-95-4 6010D 12000 570 71 mg/kg 2 Manganese 7439-96-5 6010D 1200 1.7 0.67 mg/kg 2 Molybdenum 7439-98-7 6010D ND 4.5 1.1 mg/kg 2 Nickel 7440-02-0 6010D 9.1 4.5 1.2 mg/kg 2 Potassium 7440-09-7 6010D 3800 570 71 mg/kg 2 Sodium 7440-23-5 6010D ND 570 71 mg/kg 2 Strontium 7440-24-6 6010D 54 5.7 1.4 mg/kg 4 Zinc 7440-66-6 6010D 71 5.7 1.4 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 53 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-011 Description: 2017024571 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 78.1 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0535 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2123 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 54 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.30 J 0.51 0.10 mg/kg 2 Arsenic 7440-38-2 6020B 0.34 BJ 0.51 0.10 mg/kg 1 Beryllium 7440-41-7 6020B 0.80 0.10 0.021 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.026 0.010 mg/kg 1 Cobalt 7440-48-4 6020B 38 0.72 0.26 mg/kg 1 Lead 7439-92-1 6020B 7.3 0.26 0.051 mg/kg 1 Selenium 7782-49-2 6020B 1.6 1.3 0.26 mg/kg 1 Thallium 7440-28-0 6020B 0.11 J 0.13 0.027 mg/kg 1 Vanadium 7440-62-2 6020B 110 1.3 0.26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 54 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-011 Description: 2017024571 Matrix: Solid Date Sampled:07/18/2017 0915 Project Name: J17070462 % Solids: 78.1 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2326 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.10 0.024 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 55 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-012 Description: 2017024572 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 94.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/27/2017 0103 TAF 47777 1 (Nitrate - N ) 9056A 1 07/27/2017 0103 TAF 47784 1 (pH) 9045D 1 07/20/2017 1548 MSG 47109 1 (Sulfate (sol) 9056A 1 07/27/2017 0103 TAF 47786 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 56 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.1 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.052 J 0.21 0.026 mg/kg 1 pH 9045D 7.65 su 1 Sulfate (soluble) 9056A ND 11 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 56 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-012 Description: 2017024572 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 94.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0253 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 1 07/28/2017 2207 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 08/07/2017 1312 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 57 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 10000 B 20 7.7 mg/kg 1 Barium 7440-39-3 6010D 120 1.3 0.33 mg/kg 1 Boron 7440-42-8 6010D ND 2.6 1.0 mg/kg 1 Calcium 7440-70-2 6010D 2500 260 32 mg/kg 1 Chromium 7440-47-3 6010D 4.6 0.51 0.13 mg/kg 3 Copper 7440-50-8 6010D 17 0.51 0.23 mg/kg 1 Iron 7439-89-6 6010D 11000 5.1 2.3 mg/kg 1 Magnesium 7439-95-4 6010D 3900 260 32 mg/kg 1 Manganese 7439-96-5 6010D 200 0.77 0.30 mg/kg 1 Molybdenum 7439-98-7 6010D 0.60 J 2.0 0.51 mg/kg 1 Nickel 7440-02-0 6010D 3.6 2.0 0.54 mg/kg 1 Potassium 7440-09-7 6010D 2500 260 32 mg/kg 1 Sodium 7440-23-5 6010D 67 J 260 32 mg/kg 1 Strontium 7440-24-6 6010D 46 1.0 0.26 mg/kg 4 Zinc 7440-66-6 6010D 25 2.6 0.64 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 57 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-012 Description: 2017024572 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 94.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0541 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2128 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 58 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.47 0.093 mg/kg 2 Arsenic 7440-38-2 6020B 0.34 BJ 0.47 0.093 mg/kg 1 Beryllium 7440-41-7 6020B 0.39 0.093 0.019 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.023 0.0093 mg/kg 1 Cobalt 7440-48-4 6020B 4.7 0.65 0.23 mg/kg 1 Lead 7439-92-1 6020B 3.0 0.23 0.047 mg/kg 1 Selenium 7782-49-2 6020B 0.32 J 1.2 0.23 mg/kg 1 Thallium 7440-28-0 6020B 0.14 0.12 0.024 mg/kg 1 Vanadium 7440-62-2 6020B 30 1.2 0.23 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 58 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-012 Description: 2017024572 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 94.5 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2328 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.085 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 59 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-013 Description: 2017024573 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 95.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 1800 TAF 47788 1 (Nitrate - N ) 9056A 1 07/26/2017 1800 TAF 47789 1 (pH) 9045D 1 07/20/2017 1628 MSG 47114 1 (Sulfate (sol) 9056A 1 07/26/2017 1800 TAF 47790 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 60 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 2.0 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.085 J 0.21 0.026 mg/kg 1 pH 9045D 7.11 su 1 Sulfate (soluble) 9056A ND 11 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 60 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-013 Description: 2017024573 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 95.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 07/28/2017 0258 CJZ 07/19/2017 1706 46955 2 3050B 601 OD 2 07/27/2017 2251 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 2 07/28/2017 2211 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 1 08/07/2017 1326 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 61 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 20000 B 17 6.3 mg/kg 1 Barium 7440-39-3 6010D 83 1.1 0.27 mg/kg 1 Boron 7440-42-8 6010D ND 4.2 1.7 mg/kg 2 Calcium 7440-70-2 6010D 4300 210 26 mg/kg 1 Chromium 7440-47-3 6010D 630 0.84 0.21 mg/kg 3 Copper 7440-50-8 6010D 58 0.84 0.38 mg/kg 2 Iron 7439-89-6 6010D 25000 8.4 3.8 mg/kg 2 Magnesium 7439-95-4 6010D 23000 420 53 mg/kg 2 Manganese 7439-96-5 6010D 410 1.3 0.50 mg/kg 2 Molybdenum 7439-98-7 6010D 0.53 J 1.7 0.42 mg/kg 1 Nickel 7440-02-0 6010D 130 3.4 0.89 mg/kg 2 Potassium 7440-09-7 6010D 1900 210 26 mg/kg 1 Sodium 7440-23-5 6010D 500 210 26 mg/kg 1 Strontium 7440-24-6 6010D 19 0.84 0.21 mg/kg 4 Zinc 7440-66-6 6010D 44 4.2 1.1 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 61 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-013 Description: 2017024573 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 95.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0546 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2134 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 62 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.42 0.084 mg/kg 2 Arsenic 7440-38-2 6020B 0.33 BJ 0.42 0.084 mg/kg 1 Beryllium 7440-41-7 6020B 0.17 0.084 0.017 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.021 0.0084 mg/kg 1 Cobalt 7440-48-4 6020B 24 0.59 0.21 mg/kg 1 Lead 7439-92-1 6020B 0.43 0.21 0.042 mg/kg 1 Selenium 7782-49-2 6020B ND 1.1 0.21 mg/kg 1 Thallium 7440-28-0 6020B 0.039 J 0.11 0.022 mg/kg 1 Vanadium 7440-62-2 6020B 45 1.1 0.21 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 62 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-013 Description: 2017024573 Matrix: Solid Date Sampled:07/18/2017 1435 Project Name: J17070462 % Solids: 95.2 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2330 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.083 0.020 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 63 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-014 Description: 2017024574 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 82.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 1912 TAF 47788 1 (Nitrate - N ) 9056A 1 07/26/2017 1912 TAF 47789 1 (pH) 9045D 1 07/20/2017 1630 MSG 47114 1 (Sulfate (sol) 9056A 1 07/26/2017 1912 TAF 47790 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 64 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 29 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.33 0.24 0.030 mg/kg 1 pH 9045D 6.81 su 1 Sulfate (soluble) 9056A ND 12 6.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 64 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-014 Description: 2017024574 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 82.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3050B 601 OD 2 07/27/2017 2256 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 5 08/04/2017 1526 MJI 07/19/2017 1706 46955 5 3050B 601 OD 5 08/07/2017 1330 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 65 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 40000 B 120 43 mg/kg 4 Barium 7440-39-3 6010D 350 7.5 1.9 mg/kg 4 Boron 7440-42-8 6010D ND 5.8 2.3 mg/kg 2 Calcium 7440-70-2 6010D 2400 1400 180 mg/kg 4 Chromium 7440-47-3 6010D 61 2.9 0.72 mg/kg 4 Copper 7440-50-8 6010D 58 1.2 0.52 mg/kg 2 Iron 7439-89-6 6010D 46000 29 13 mg/kg 4 Magnesium 7439-95-4 6010D 15000 1400 180 mg/kg 4 Manganese 7439-96-5 6010D 450 1.7 0.68 mg/kg 2 Molybdenum 7439-98-7 6010D ND 12 2.9 mg/kg 4 Nickel 7440-02-0 6010D 61 12 3.0 mg/kg 4 Potassium 7440-09-7 6010D 3500 1400 180 mg/kg 4 Sodium 7440-23-5 6010D 2600 1400 180 mg/kg 4 Strontium 7440-24-6 6010D 60 5.8 1.4 mg/kg 5 Zinc 7440-66-6 6010D 130 14 3.6 mg/kg 4 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 65 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-014 Description: 2017024574 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 82.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0551 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2140 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 66 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.50 0.10 mg/kg 2 Arsenic 7440-38-2 6020B 3.5 B 0.50 0.10 mg/kg 1 Beryllium 7440-41-7 6020B 1.5 0.10 0.020 mg/kg 1 Cadmium 7440-43-9 6020B ND 0.025 0.010 mg/kg 1 Cobalt 7440-48-4 6020B 81 0.70 0.25 mg/kg 1 Lead 7439-92-1 6020B 9.0 0.25 0.050 mg/kg 1 Selenium 7782-49-2 6020B 2.7 1.3 0.25 mg/kg 1 Thallium 7440-28-0 6020B 0.23 0.13 0.026 mg/kg 1 Vanadium 7440-62-2 6020B 140 1.3 0.25 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 66 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-014 Description: 2017024574 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 82.3 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2332 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.10 0.024 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 67 of 127 ICP -AES Metals Client: Duke Energy Laboratory ID: SG19027-015 Description: 2017024575 Matrix: Aqueous Date Sampled:07/18/2017 1040 Project Name: J17070462 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 601 OD 1 07/25/20171547 CJZ 07/19/20171631 46953 2 3005A 601 OD 1 07/27/2017 2107 CJZ 07/19/2017 1631 46953 3 3005A 601 OD 1 07/30/20171511 CJZ 07/19/20171631 46953 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 68 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D ND 0.40 0.10 mg/L 1 Barium 7440-39-3 6010D ND 0.025 0.0031 mg/L 1 Boron 7440-42-8 6010D ND 0.050 0.020 mg/L 1 Calcium 7440-70-2 6010D ND 5.0 0.63 mg/L 1 Chromium 7440-47-3 6010D ND 0.010 0.0013 mg/L 1 Copper 7440-50-8 6010D ND 0.010 0.0020 mg/L 1 Iron 7439-89-6 6010D 0.18 0.10 0.040 mg/L 2 Magnesium 7439-95-4 6010D ND 5.0 0.63 mg/L 1 Manganese 7439-96-5 6010D 0.0019 J 0.015 0.0019 mg/L 1 Molybdenum 7439-98-7 6010D ND 0.040 0.0050 mg/L 1 Nickel 7440-02-0 6010D ND 0.040 0.0050 mg/L 1 Potassium 7440-09-7 6010D ND 5.0 0.63 mg/L 1 Sodium 7440-23-5 6010D ND 5.0 0.63 mg/L 1 Strontium 7440-24-6 6010D ND 0.010 0.0025 mg/L 3 Zinc 7440-66-6 6010D ND 0.020 0.0025 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 68 of 127 ICP -MS Metals Client: Duke Energy Laboratory ID: SG19027-015 Description: 2017024575 Matrix: Aqueous Date Sampled:07/18/2017 1040 Project Name: J17070462 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 07/26/2017 1614 BNW 07/20/2017 0953 47006 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 69 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.13 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 0.63 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.13 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 1.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 69 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-015 Description: 2017024575 Matrix: Aqueous Date Sampled:07/18/2017 1040 Project Name: J17070462 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 7470A 1 07/19/2017 2305 SLS 07/19/2017 1937 46988 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00010 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 70 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-016 Description: 2017024576 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 86.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 1936 TAF 47788 1 (Nitrate - N ) 9056A 1 07/26/2017 1936 TAF 47789 1 (pH) 9045D 1 07/20/2017 1631 MSG 47114 1 (Sulfate (sol) 9056A 1 07/26/2017 1936 TAF 47790 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 71 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 7.9 J 12 1.2 mg/kg 1 Nitrate - N (soluble) 9056A 0.14 J 0.23 0.028 mg/kg 1 pH 9045D 6.66 su 1 Sulfate (soluble) 9056A ND 12 5.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 71 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-016 Description: 2017024576 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 86.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3050B 601 OD 5 07/27/2017 2300 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 5 07/28/2017 2220 CJZ 07/19/2017 1706 46955 4 3050B 601 OD 5 08/07/2017 1335 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 72 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 50000 B 100 38 mg/kg 2 Barium 7440-39-3 6010D 520 6.6 1.6 mg/kg 2 Boron 7440-42-8 6010D ND 13 5.0 mg/kg 2 Calcium 7440-70-2 6010D 4900 1300 160 mg/kg 2 Chromium 7440-47-3 6010D 440 2.5 0.63 mg/kg 3 Copper 7440-50-8 6010D 21 2.5 1.1 mg/kg 2 Iron 7439-89-6 6010D 69000 25 11 mg/kg 2 Magnesium 7439-95-4 6010D 40000 1300 160 mg/kg 2 Manganese 7439-96-5 6010D 2900 3.8 1.5 mg/kg 2 Molybdenum 7439-98-7 6010D ND 10 2.5 mg/kg 2 Nickel 7440-02-0 6010D 140 10 2.6 mg/kg 2 Potassium 7440-09-7 6010D 16000 1300 160 mg/kg 2 Sodium 7440-23-5 6010D 550 J 1300 160 mg/kg 2 Strontium 7440-24-6 6010D 69 5.0 1.3 mg/kg 4 Zinc 7440-66-6 6010D 330 13 3.1 mg/kg 3 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 72 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-016 Description: 2017024576 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 86.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0608 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2146 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 73 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.48 0.097 mg/kg 2 Arsenic 7440-38-2 6020B 1.8 B 0.48 0.097 mg/kg 1 Beryllium 7440-41-7 6020B 0.95 0.097 0.019 mg/kg 1 Cadmium 7440-43-9 6020B 0.24 0.024 0.0097 mg/kg 1 Cobalt 7440-48-4 6020B 37 0.68 0.24 mg/kg 1 Lead 7439-92-1 6020B 5.3 0.24 0.048 mg/kg 1 Selenium 7782-49-2 6020B 1.7 1.3 0.24 mg/kg 1 Thallium 7440-28-0 6020B 0.56 0.13 0.025 mg/kg 1 Vanadium 7440-62-2 6020B 110 1.3 0.24 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 73 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-016 Description: 2017024576 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 86.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2335 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.090 0.022 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 74 of 127 Inorganic non-metals Client: Duke Energy Laboratory ID: SG19027-017 Description: 2017024577 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 90.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Chloride (so) 9056A 1 07/26/2017 2000 TAF 47788 1 (Nitrate - N ) 9056A 1 07/26/2017 2000 TAF 47789 1 (pH) 9045D 1 07/20/2017 1632 MSG 47114 1 (Sulfate (sol) 9056A 1 07/26/2017 2000 TAF 47790 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 75 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloride (soluble) 9056A 3.2 J 11 1.1 mg/kg 1 Nitrate - N (soluble) 9056A 0.092 J 0.22 0.027 mg/kg 1 pH 9045D 6.81 su 1 Sulfate (soluble) 9056A ND 11 5.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 75 of 127 ICP -AES Client: Duke Energy Laboratory ID: SG19027-017 Description: 2017024577 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 90.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 2 07/27/2017 2305 CJZ 07/19/2017 1706 46955 2 3050B 601 OD 5 07/28/2017 2225 CJZ 07/19/2017 1706 46955 3 3050B 601 OD 2 08/07/2017 1339 CJZ 07/19/2017 1706 46955 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 76 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 33000 B 43 16 mg/kg 1 Barium 7440-39-3 6010D 490 2.8 0.69 mg/kg 1 Boron 7440-42-8 6010D ND 13 5.3 mg/kg 2 Calcium 7440-70-2 6010D 2400 530 67 mg/kg 1 Chromium 7440-47-3 6010D 70 2.7 0.67 mg/kg 2 Copper 7440-50-8 6010D 94 2.7 1.2 mg/kg 2 Iron 7439-89-6 6010D 69000 27 12 mg/kg 2 Magnesium 7439-95-4 6010D 27000 1300 170 mg/kg 2 Manganese 7439-96-5 6010D 3100 4.0 1.6 mg/kg 2 Molybdenum 7439-98-7 6010D 1.9 J 4.3 1.1 mg/kg 1 Nickel 7440-02-0 6010D 53 11 2.8 mg/kg 2 Potassium 7440-09-7 6010D 19000 530 67 mg/kg 1 Sodium 7440-23-5 6010D 88 J 530 67 mg/kg 1 Strontium 7440-24-6 6010D 38 2.1 0.53 mg/kg 3 Zinc 7440-66-6 6010D 260 13 3.3 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 76 of 127 ICP -MS Client: Duke Energy Laboratory ID: SG19027-017 Description: 2017024577 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 90.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6020B 1 07/27/2017 0613 BNW 07/21/2017 1844 47212 2 3050B 6020B 1 07/27/2017 2152 BNW 07/21/2017 1844 47212 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 77 of 127 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 0.46 0.093 mg/kg 2 Arsenic 7440-38-2 6020B 1.6 B 0.46 0.093 mg/kg 1 Beryllium 7440-41-7 6020B 1.0 0.093 0.019 mg/kg 1 Cadmium 7440-43-9 6020B 0.22 0.023 0.0093 mg/kg 1 Cobalt 7440-48-4 6020B 34 0.65 0.23 mg/kg 1 Lead 7439-92-1 6020B 5.3 0.23 0.046 mg/kg 1 Selenium 7782-49-2 6020B 0.98 J 1.2 0.23 mg/kg 1 Thallium 7440-28-0 6020B 0.79 0.12 0.024 mg/kg 1 Vanadium 7440-62-2 6020B 170 1.2 0.23 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 77 of 127 CVAA Client: Duke Energy Laboratory ID: SG19027-017 Description: 2017024577 Matrix: Solid Date Sampled:07/18/2017 1510 Project Name: J17070462 % Solids: 90.4 07/19/2017 2323 Date Received: 07/19/2017 Project Number: J17070462 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/21/2017 2337 SLS 07/21/2017 2142 47214 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.081 0.019 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 78 of 127 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: SG19027 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 79 of 127 Inorganic non-metals - Duplicate Sample ID: SG19O27-003DU Matrix: Solid Batch:47109 Analytical Method: 9045D Sample Amount Result % RPD Parameter (su) (mg/kg) Q Dil % RPD Limit Analysis Date pH 6.21 6.23 1 0.32 20 07/20/20171540 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 80 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - Duplicate Sample ID: SG19O27-013DU Matrix: Solid Batch:47114 Analytical Method: 9045D Sample Amount Result % RPD Parameter (su) (mg/kg) Q Dil % RPD Limit Analysis Date pH 7.11 7.00 1 1.6 20 07/20/20171629 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 81 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MB Sample ID: SQ47777-001 Matrix: Solid Batch:47777 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride (soluble) ND 1 10 1.0 mg/kg 07/26/2017 1322 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 82 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - LCS Sample ID: SQ47777-002 Matrix: Solid Batch:47777 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 20 20 1 100 80-120 07/26/2017 1257 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 83 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MS Sample ID: SG19O27-OO7MS Matrix: Solid Batch:47777 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 16 200 210 1 97 80-120 07/26/2017 2143 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 84 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MSD Sample ID: SG19O27-OO7MD Matrix: Solid Batch:47777 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride (soluble) 16 200 210 1 99 1.3 80-120 20 07/26/2017 2258 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 85 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MB Sample ID: SQ47784-001 Matrix: Solid Batch:47784 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N (soluble) ND 1 0.20 0.025 mg/kg 07/26/2017 1322 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 86 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - LCS Sample ID: SQ47784-002 Matrix: Solid Batch:47784 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.80 0.79 1 98 87-111 07/26/2017 1257 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 87 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MS Sample ID: SG19O27-OO7MS Matrix: Solid Batch:47784 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) ND 8.0 7.9 1 98 87-111 07/26/2017 2143 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 88 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MSD Sample ID: SG19O27-OO7MD Matrix: Solid Batch:47784 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Nitrate - N (soluble) ND 8.0 7.9 1 99 0.58 87-111 20 07/26/2017 2258 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 89 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MB Sample ID: SQ47786-001 Matrix: Solid Batch:47786 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate (soluble) ND 1 10 5.0 mg/kg 07/26/2017 1322 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 90 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - LCS Sample ID: SQ47786-002 Matrix: Solid Batch:47786 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) 20 20 1 100 80-120 07/26/2017 1257 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 91 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MS Sample ID: SG19O27-OO7MS Matrix: Solid Batch:47786 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) ND 200 190 1 95 80-120 07/26/2017 2143 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 92 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MSD Sample ID: SG19O27-OO7MD Matrix: Solid Batch:47786 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate (soluble) ND 200 190 1 96 0.95 80-120 20 07/26/2017 2258 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 93 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MB Sample ID: SQ47788-001 Matrix: Solid Batch:47788 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride (soluble) ND 1 10 1.0 mg/kg 07/26/2017 1712 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 94 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - LCS Sample ID: SQ47788-002 Matrix: Solid Batch:47788 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 20 20 1 100 80-120 07/26/2017 1736 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 95 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MS Sample ID: SG19O27-013MS Matrix: Solid Batch:47788 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Chloride (soluble) 2.0 200 200 1 99 80-120 07/26/2017 1824 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 96 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MSD Sample ID: SG19O27-013MD Matrix: Solid Batch:47788 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride (soluble) 2.0 200 200 1 100 1.5 80-120 20 07/26/2017 1848 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 97 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MB Sample ID: SQ47789-001 Matrix: Solid Batch:47789 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N (soluble) ND 1 0.20 0.025 mg/kg 07/26/2017 1712 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 98 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - LCS Sample ID: SQ47789-002 Matrix: Solid Batch:47789 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.80 0.79 1 98 87-111 07/26/2017 1736 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 99 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MS Sample ID: SG19O27-013MS Matrix: Solid Batch:47789 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Nitrate - N (soluble) 0.085 8.0 7.3 1 90 87-111 07/26/2017 1824 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 100 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MSD Sample ID: SG19O27-013MD Matrix: Solid Batch:47789 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Nitrate - N (soluble) 0.085 8.0 7.5 1 93 3.0 87-111 20 07/26/2017 1848 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 101 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MB Sample ID: SQ47790-001 Matrix: Solid Batch:47790 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate (soluble) ND 1 10 5.0 mg/kg 07/26/2017 1712 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 102 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - LCS Sample ID: SQ4779O-002 Matrix: Solid Batch:47790 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) 20 19 1 97 80-120 07/26/2017 1736 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 103 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MS Sample ID: SG19O27-013MS Matrix: Solid Batch:47790 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Sulfate (soluble) ND 200 190 1 96 80-120 07/26/2017 1824 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 104 of 127 QC Data for Lot Number: SG19027 Inorganic non-metals - MSD Sample ID: SG19O27-013MD Matrix: Solid Batch:47790 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate (soluble) ND 200 200 1 98 1.7 80-120 20 07/26/2017 1848 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 105 of 127 QC Data for Lot Number: SG19027 ICP -AES Metals - MB Sample ID: SQ46953-001 Matrix: Aqueous Batch:46953 Prep Method: 3005A Analytical Method: 6010D Prep Date: 07/19/2017 1631 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 0.40 0.10 mg/L 07/25/20171418 Barium ND 1 0.025 0.0031 mg/L 07/25/20171418 Boron ND 1 0.050 0.020 mg/L 07/25/20171418 Calcium ND 1 5.0 0.63 mg/L 07/25/20171418 Chromium ND 1 0.010 0.0013 mg/L 07/25/20171418 Copper ND 1 0.010 0.0020 mg/L 07/25/20171418 Iron ND 1 0.10 0.040 mg/L 07/28/2017 2343 Magnesium ND 1 5.0 0.63 mg/L 07/25/20171418 Manganese ND 1 0.015 0.0019 mg/L 07/25/20171418 Molybdenum ND 1 0.040 0.0050 mg/L 07/25/20171418 Nickel ND 1 0.040 0.0050 mg/L 07/25/20171418 Potassium ND 1 5.0 0.63 mg/L 07/25/20171418 Sodium ND 1 5.0 0.63 mg/L 07/25/20171418 Strontium ND 1 0.010 0.0025 mg/L 07/30/20171440 Zinc ND 1 0.020 0.0025 mg/L 07/25/20171418 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 106 of 127 QC Data for Lot Number: SG19027 ICP -AES Metals - LCS Sample ID: SQ46953-002 Matrix: Aqueous Batch:46953 Prep Method: 3OO5A Analytical Method: 6010D Prep Date: 07/19/2017 1631 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Aluminum 20 21 1 107 80-120 07/25/20171423 Barium 2.0 2.1 1 103 80-120 07/25/20171423 Boron 0.40 0.43 1 109 80-120 07/25/20171423 Calcium 40 41 1 103 80-120 07/25/20171423 Chromium 2.0 2.1 1 104 80-120 07/25/20171423 Copper 2.0 2.1 1 105 80-120 07/25/20171423 Iron 20 20 1 98 80-120 07/28/2017 2348 Magnesium 40 42 1 104 80-120 07/25/20171423 Manganese 2.0 2.1 1 107 80-120 07/25/20171423 Molybdenum 2.0 2.0 1 101 80-120 07/25/20171423 Nickel 2.0 2.1 1 104 80-120 07/25/20171423 Potassium 40 41 1 104 80-120 07/25/20171423 Sodium 40 42 1 105 80-120 07/25/20171423 Strontium 1.0 1.0 1 103 80-120 07/30/20171445 Zinc 2.0 2.1 1 104 80-120 07/25/20171423 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 107 of 127 QC Data for Lot Number: SG19027 ICP -AES - MB Sample ID: SQ46955-001 Matrix: Solid Batch:46955 Prep Method: 30508 Analytical Method: 6010D Prep Date: 07/19/2017 1706 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum 13 J 1 20 7.5 mg/kg 07/27/2017 2111 Barium ND 1 1.3 0.33 mg/kg 07/27/2017 2111 Boron 1.3 J 1 2.5 1.0 mg/kg 07/27/2017 2111 Calcium ND 1 250 31 mg/kg 07/27/2017 2111 Chromium ND 1 0.50 0.13 mg/kg 07/28/20171531 Copper ND 1 0.50 0.23 mg/kg 07/27/2017 2111 Iron ND 1 5.0 2.3 mg/kg 07/27/2017 2111 Magnesium ND 1 250 31 mg/kg 07/27/2017 2111 Manganese ND 1 0.75 0.30 mg/kg 07/27/2017 2111 Molybdenum ND 1 2.0 0.50 mg/kg 07/27/2017 2111 Nickel ND 1 2.0 0.53 mg/kg 07/27/2017 2111 Potassium ND 1 250 31 mg/kg 07/27/2017 2111 Sodium ND 1 250 31 mg/kg 07/27/2017 2111 Strontium ND 1 1.0 0.25 mg/kg 07/30/20171608 Zinc ND 1 2.5 0.63 mg/kg 07/28/20171531 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 108 of 127 QC Data for Lot Number: SG19027 ICP -AES - LCS Sample ID: SQ46955-002 Matrix: Solid Batch:46955 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 07/19/2017 1706 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Aluminum 1000 1100 1 109 80-120 07/27/2017 2116 Barium 500 500 1 101 80-120 07/27/2017 2116 Boron 50 51 1 101 80-120 07/27/2017 2116 Calcium 2000 2200 1 111 80-120 07/27/2017 2116 Chromium 250 270 1 108 80-120 07/28/20171536 Copper 100 110 1 107 80-120 07/27/2017 2116 Iron 1000 1100 1 109 80-120 07/27/2017 2116 Magnesium 2000 2100 1 107 80-120 07/27/2017 2116 Manganese 100 110 1 112 80-120 07/27/2017 2116 Molybdenum 100 110 1 114 80-120 07/27/2017 2116 Nickel 100 110 1 110 80-120 07/27/2017 2116 Potassium 2000 2000 1 99 80-120 07/27/2017 2116 Sodium 2000 1900 1 97 80-120 07/27/2017 2116 Strontium 50 55 1 111 80-120 07/30/20171613 Zinc 100 110 1 106 80-120 07/28/20171536 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 109 of 127 QC Data for Lot Number: SG19027 ICP -AES - MS Sample ID: SG19O27-OOlMS Matrix: Solid Batch:46955 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 07/19/2017 1706 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Aluminum 21000 1100 29000 N 1 717 75-125 07/28/2017 0140 Barium 55 560 480 1 75 75-125 07/28/2017 0140 Boron ND 56 38 N 1 67 75-125 07/28/2017 0140 Calcium 69 2200 1700 1 75 75-125 07/28/2017 0140 Chromium 3.3 280 220 1 78 75-125 07/28/2017 2044 Copper 7.1 110 100 1 84 75-125 07/28/2017 0140 Iron 16000 1100 19000 N 1 213 75-125 07/28/2017 0140 Magnesium 4600 2200 6300 1 75 75-125 07/28/2017 0140 Manganese 190 110 280 1 76 75-125 07/28/2017 0140 Molybdenum ND 110 70 N 1 62 75-125 07/28/2017 0140 Nickel 0.86 110 78 N 1 69 75-125 07/28/2017 0140 Potassium 3200 2200 5000 1 81 75-125 07/28/2017 0140 Sodium 160 2200 1800 N 1 72 75-125 07/28/2017 0140 Strontium 4.8 56 54 1 88 75-125 07/30/20171622 Zinc 40 110 120 1 75 75-125 07/28/2017 2044 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 110 of 127 QC Data for Lot Number: SG19027 ICP -AES - MSD Sample ID: SG19O27-OOlMD Matrix: Solid Batch:46955 Prep Method: 3O5OB Analytical Method: 6010D Prep Date: 07/19/2017 1706 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 21000 1100 30000 N 1 877 5.2 75-125 20 07/28/2017 0144 Barium 55 550 450 N 1 73 5.5 75-125 20 07/28/2017 0144 Boron ND 55 35 N 1 64 8.5 75-125 20 07/28/2017 0144 Calcium 69 2200 1600 N 1 72 5.6 75-125 20 07/28/2017 0144 Chromium 3.3 270 210 N 1 74 7.5 75-125 20 07/28/2017 2058 Copper 7.1 110 95 1 81 6.1 75-125 20 07/28/2017 0144 Iron 16000 1100 20000 N 1 352 7.4 75-125 20 07/28/2017 0144 Magnesium 4600 2200 6600 1 91 4.7 75-125 20 07/28/2017 0144 Manganese 190 110 290 1 88 4.1 75-125 20 07/28/2017 0144 Molybdenum ND 110 60 N 1 55 14 75-125 20 07/28/2017 0144 Nickel 0.86 110 72 N 1 65 8.3 75-125 20 07/28/2017 0144 Potassium 3200 2200 5200 1 89 2.4 75-125 20 07/28/2017 0144 Sodium 160 2200 1700 N 1 69 5.6 75-125 20 07/28/2017 0144 Strontium 4.8 55 51 1 85 6.4 75-125 20 07/30/20171626 Zinc 40 110 120 N 1 74 3.4 75-125 20 07/28/2017 2058 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 111 of 127 QC Data for Lot Number: SG19027 ICP -MS Metals - MB Sample ID: SQ47006-001 Matrix: Aqueous Batch:47006 Prep Method: 3005A Analytical Method: 6020B Prep Date: 07/20/2017 953 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 0.51 J 1 2.0 0.50 ug/L 07/26/20171419 Arsenic ND 1 2.0 1.3 ug/L 07/26/20171419 Beryllium ND 1 0.40 0.13 ug/L 07/26/20171419 Cadmium ND 1 0.50 0.13 ug/L 07/26/20171419 Cobalt ND 1 5.0 0.63 ug/L 07/26/20171419 Lead ND 1 1.0 0.25 ug/L 07/26/20171419 Selenium ND 1 5.0 1.3 ug/L 07/26/20171419 Thallium ND 1 0.50 0.13 ug/L 07/26/20171419 Vanadium ND 1 5.0 1.5 ug/L 07/26/20171419 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 112 of 127 QC Data for Lot Number: SG19027 ICP -MS Metals - LCS Sample ID: SQ47OO6-002 Matrix: Aqueous Batch:47006 Prep Method: 3OO5A Analytical Method: 60208 Prep Date: 07/20/2017 953 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 98 1 98 80-120 07/26/20171424 Arsenic 100 100 1 103 80-120 07/26/20171424 Beryllium 100 100 1 104 80-120 07/26/20171424 Cadmium 100 97 1 97 80-120 07/26/20171424 Cobalt 100 97 1 97 80-120 07/26/20171424 Lead 100 99 1 99 80-120 07/26/20171424 Selenium 100 99 1 99 80-120 07/26/20171424 Thallium 100 96 1 96 80-120 07/26/20171424 Vanadium 100 96 1 96 80-120 07/26/20171424 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 113 of 127 QC Data for Lot Number: SG19027 ICP -MS - MB Sample ID: SQ47212-001 Matrix: Solid Batch:47212 Prep Method: 3050B Analytical Method: 6020B Prep Date: 07/21/2017 1844 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 0.50 0.10 mg/kg 07/27/20171925 Arsenic 0.11 J 1 0.50 0.10 mg/kg 07/27/2017 0359 Beryllium ND 1 0.10 0.020 mg/kg 07/27/2017 0359 Cadmium ND 1 0.025 0.010 mg/kg 07/27/2017 0359 Cobalt ND 1 0.70 0.25 mg/kg 07/27/2017 0359 Lead ND 1 0.25 0.050 mg/kg 07/27/2017 0359 Selenium ND 1 1.3 0.25 mg/kg 07/27/2017 0359 Thallium ND 1 0.13 0.026 mg/kg 07/27/2017 0359 Vanadium ND 1 1.3 0.25 mg/kg 07/27/2017 0359 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 114 of 127 QC Data for Lot Number: SG19027 ICP -MS - LCS Sample ID: SQ47212-002 Matrix: Solid Batch:47212 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 07/21/2017 1844 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Antimony 50 48 1 95 80-120 07/27/20171931 Arsenic 50 51 1 103 80-120 07/27/2017 0404 Beryllium 50 52 1 105 80-120 07/27/2017 0404 Cadmium 50 49 1 98 80-120 07/27/2017 0404 Cobalt 50 50 1 100 80-120 07/27/2017 0404 Lead 50 51 1 102 80-120 07/27/2017 0404 Selenium 50 46 1 93 80-120 07/27/2017 0404 Thallium 50 49 1 98 80-120 07/27/2017 0404 Vanadium 50 51 1 102 80-120 07/27/2017 0404 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 115 of 127 QC Data for Lot Number: SG19027 ICP -MS - MS Sample ID: SG19O27-OOlMS Matrix: Solid Batch:47212 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 07/21/2017 1844 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Antimony ND 56 19 N 1 34 75-125 07/27/20171943 Arsenic 0.49 56 51 1 89 75-125 07/27/2017 0415 Beryllium 0.50 56 53 1 94 75-125 07/27/2017 0415 Cadmium ND 56 54 1 95 75-125 07/27/2017 0415 Cobalt 6.1 56 57 1 91 75-125 07/27/2017 0415 Lead 7.0 56 66 1 105 75-125 07/27/2017 0415 Selenium 0.66 56 49 1 87 75-125 07/27/2017 0415 Thallium 0.17 56 52 1 92 75-125 07/27/2017 0415 Vanadium 36 56 97 1 109 75-125 07/27/2017 0415 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 116 of 127 QC Data for Lot Number: SG19027 ICP -MS - MSD Sample ID: SG19O27-OOlMD Matrix: Solid Batch:47212 Prep Method: 3O5OB Analytical Method: 6020B Prep Date: 07/21/2017 1844 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 52 15 N,+ 1 28 25 75-125 20 07/27/20171949 Arsenic 0.49 52 45 1 85 12 75-125 20 07/27/2017 0420 Beryllium 0.50 52 48 1 91 9.0 75-125 20 07/27/2017 0420 Cadmium ND 52 49 1 94 8.2 75-125 20 07/27/2017 0420 Cobalt 6.1 52 54 1 91 5.5 75-125 20 07/27/2017 0420 Lead 7.0 52 61 1 103 8.0 75-125 20 07/27/2017 0420 Selenium 0.66 52 46 1 86 7.7 75-125 20 07/27/2017 0420 Thallium 0.17 52 48 1 91 8.6 75-125 20 07/27/2017 0420 Vanadium 36 52 87 1 97 11 75-125 20 07/27/2017 0420 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 117 of 127 QC Data for Lot Number: SG19027 CVAA - MB Sample ID: SQ46988-001 Matrix: Aqueous Batch:46988 Prep Method: 7470A Analytical Method: 7470A Prep Date: 07/19/2017 1937 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00010 0.000091 mg/L 07/19/2017 2210 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 118 of 127 QC Data for Lot Number: SG19027 CVAA - LCS Sample ID: SQ46988-002 Matrix: Aqueous Batch:46988 Prep Method: 747OA Analytical Method: 7470A Prep Date: 07/19/2017 1937 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0021 1 104 80-120 07/19/2017 2212 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 119 of 127 QC Data for Lot Number: SG19027 CVAA - MB Sample ID: SQ47214-001 Matrix: Solid Batch:47214 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 2142 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.083 0.020 mg/kg 07/21/20172251 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 120 of 127 QC Data for Lot Number: SG19027 CVAA - LCS Sample ID: SQ47214-002 Matrix: Solid Batch:47214 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 2142 Spike Amount Result % Rec Parameter (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Mercury 0.83 0.88 1 106 80-120 07/21/20172253 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 121 of 127 QC Data for Lot Number: SG19027 CVAA - MS Sample ID: SG19O27-OOlMS Matrix: Solid Batch:47214 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 2142 Sample Spike Amount Amount Result % Rec Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec Limit Analysis Date Mercury ND 0.86 0.94 1 109 80-120 07/21/20172257 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 122 of 127 QC Data for Lot Number: SG19027 CVAA - MSD Sample ID: SG19O27-OOlMD Matrix: Solid Batch:47214 Prep Method: 74716 Analytical Method: 74718 Prep Date: 07/21/2017 2142 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/kg) (mg/kg) (mg/kg) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury ND 0.90 1.0 1 116 11 80-120 20 07/21/20172300 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 123 of 127 QC Data for Lot Number: SG19027 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 124 of 127 SHEALY ENVIRONMENTAL SERVICES, INC. i ti „ ... 1 5�/1 .mow 0, t w 7 LL11 13 4 a � r 7 ti f_ 04. — Vj` Cr IX IWr 9� v II 6 I' C 4 a � i � p IF P-1 IMF 40 5 41 LL or i C. Qa�y3 v i e � y ra LU �.El i Tar Ck ,I II 1 „ ; I Wai a:Vgl4} 81�N�ildd4 wU}�'lure.• iS J�YwYce, ! �di f-� ....F ... .I-...._�.,-.. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 125 of 127 SHEALY ENVIRONMENTAL SERVICES, INC. I v4 Y C5 l l I � .. ._....._.._ . — a Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 126 of 127 SHEALY ENVIRONMENTAL SERVICES, INC. Sheoly trnvlronmeluid Hervmm, in,. ❑moment liun-aff-. Mr -01)] C'•r-li NC 1 cifl f_frPecgevc L�rrAe l]�nG7.�017 Sample. Re -.Apt Checklist (.SRC) { licnt: 2 Cooler lnspucd byld. ' 1 rte -L -) moo+ A, Means ofreceipL Ct ESI ❑ C'•lient ❑ UPS (3Fedl'X 2,011er_.— Yr.s ❑ No fir` 1. Wcrc crusted)• scats present on the coolc.,O Yes ❑ No 7 NA 2 1f cu51ody seal swere prescni, wi' re. they intact and unbroken'! — pH strip 10: y _ Cl strip ID: . - C.00€cr Tfltbriginal tamperatrlre upOti r>er-ChpVDerived (u)rrected) te--mperaiure upriti receipt: f ffC r , "C r 1 1 _°C Metliod: :i Ten, -erratum BI oak rm—Against Elcttles IR Gun ID: Cz Ili Gun C"oTinnnion Factor. Metb4,4L ofcoo:anl; t~ `et Icc 1 Blue lee ❑ Dry lee ❑ Noi1e Yrs ❑ 1 N 22. was we quok, nom er u Sample PreservatiM, { usi be WTR[etcd far any satmplea($) incuri'ectlW preserved or wilh+ heads ce.) sanlrle(s) were rc IvO incvrrmily preserved and werz adjusted acwrdingl}' in sample rc ei41n4 with_ (liz5 }a, ll dC3 HCl, NaOH) tisinllg Sly 9 -- �. 5arn}ile(s) _ wcrG r eived witli Fiul ales >6' tin I. in diameter. Sarnples(s) _ _ were veceived v, -illi TRIC > 0_5 rnpl- (If 921 is No) and were zd'usted acc,ordin ly iii sain )k rcc� fi tiaK]iiim thiosulfate (Na] -'O-') vAth Sheat ID: SC I)rinking Water Projec- Salriple(:) pl-L ,,er[flad ID Lir. e 2 by Date; SarrrpleLs] wcle Not reit ived at Fi ex 2 ;itid were arl'tisted accordin LLi11g SRO Sam Ule labels applied by; L C Verified by-. Date. _ C'�rimm�:nt�: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 127 of 127 ;. 1fLVIlipertltalre Of arty 4X0let' exceeded b.O"C. ttific Project ManagerNoLired YeS ttirr ❑ N, ❑ PKI viasNotifi�qhon 1 Jfar to -face circle one)- yes ❑ No r-1 qA-o- 4. Is the conimtycoial caurict'q packing slip attached W tins fornii? YcsNo = 7. w21 -e cep -t custody proceou[cs(l lltiquislid[I°r oeived) rutlovxd7 Nu M 6, Were sample 105 listed on the CLIC:? Yes P, f o ❑ 7. ',Fere sate le IDs listed on all sarn rle cori�inryrs'? 'ties ,rr" No ❑ 8. Was collection Atte & Cmc listed on the COO Yt,s W Na 13 9. ';:iq coAccakm date & time listed on all sarnPle meta ners? 10, Oid all container label inf )rrnatioll ND. clme, tim.e? aree with the COC' No ❑ 1 I. �Tv'�cre 1:ests to ere performed listed 011, Llic COC? !Yel 12. Did all samplesarrive in rl� proper (-witailters f w each test nndo in good voiidkion ATo (unbrokell, lids on, cb4-)? .m_. Yes o El13, 'as rate sem Ievolurri �tvailablel ' jr, 1 ire ill Saul les received within his tihr hold 419 tir7let or 4T~ hours, wllicllever cOme8 �lr3t? { ❑ , 15. Were any sasiiples containersmisairrar"excess (circle ane)samfles Not listed ran COC? VC5 ❑ la �,� u No o NA - 16. Wire bubbleR prf-4 �"pea-sig"° (14"err 6n3m in diameter) in stly'ri0.4 �' els'? yq - 1;rr t7 NA ri 17_ Were all f RO;mclOSl nntrierit samples recciyet{ at a pH of <:2 _r yes n Tia C3 Nr l$. Were all eyanicle samples received at a rl-T { 12 and sulfide samples received sit a H>9? 19. Fere all applkable 14H3/r .TisayaniJe1VllerloliBNA (< 0.5mg/L) samples free~ Kf residual Yes ❑ Nej - NA cblririnc? Y-ts ❑ Na d (i_ 4"ere :olleerirxi tcrrilr-ramres doc.tmi:nt-Ed un the COC fbr SIC' ian>plus? 2 L. Wort: L6ient remarkshequests (I. r4_ requ:3trd dilutions, MS!MsD do -igliations, etc..-) Yes ❑ No In NA-�- ourilwly tirarl5vribed from the CDC. into time co>nmtnt 5ectior3 ill = h S -d -ken trom the oantainer label? Yrs ❑ 1 N 22. was we quok, nom er u Sample PreservatiM, { usi be WTR[etcd far any satmplea($) incuri'ectlW preserved or wilh+ heads ce.) sanlrle(s) were rc IvO incvrrmily preserved and werz adjusted acwrdingl}' in sample rc ei41n4 with_ (liz5 }a, ll dC3 HCl, NaOH) tisinllg Sly 9 -- �. 5arn}ile(s) _ wcrG r eived witli Fiul ales >6' tin I. in diameter. Sarnples(s) _ _ were veceived v, -illi TRIC > 0_5 rnpl- (If 921 is No) and were zd'usted acc,ordin ly iii sain )k rcc� fi tiaK]iiim thiosulfate (Na] -'O-') vAth Sheat ID: SC I)rinking Water Projec- Salriple(:) pl-L ,,er[flad ID Lir. e 2 by Date; SarrrpleLs] wcle Not reit ived at Fi ex 2 ;itid were arl'tisted accordin LLi11g SRO Sam Ule labels applied by; L C Verified by-. Date. _ C'�rimm�:nt�: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 127 of 127 Analytical lab , 1 - A 30 i ag o CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Ana"al Laboratory Services I I Analytical Laborato Use On ILIE _ P11a111 Cade MCat73h2 iEl+tllsling 74051 MaWx: SOIL r#C Papa 1 f 1 Samples awi inglinp SC DISTRIBUTION F IIAVI !11•[�c 1111 13339 Hagen Ferry Rs From 0 : ' 4-1 � 1 +'-, llunteraville, W_C_ 28478 �4.... - --. - - 1 ORIG INi4_tffLAB. I 7. IIP 1980) 875'sm 4 SAa1PLE PROGAALM Gro m yOPY to CLIENT Fait: �9dCF9753+tB—.—.-----.[.... Water ilF+riebsWtm+ AB 'iraulyrlrlrateCJ4Saes8ltle11#^'JAI '2I�n°ti4No: -. ,• Plant_ 417 Supplemental Testing) i�HEAL � PiGFtA44�cta_ Revision t (7-17-17} i3 Gaoler Tem C 3N refit 4Pf4x No Q 02101.3 "p s$rv_:1=H Lr1- AB GW 20H C7. 3=H. _ 4=4 5r a +1 e- .�_—........_.,.. 5.J9uslnass Urik: f 6]Pt 10: _ iaMaN Gude= m � 81Ow ,ting u . 6p4cUviw Id: tarron no stffMEto carnfSlraLe �� m � } 1 � G pMMELailt, When speelllc a,stiwnting has bourt e7tablI51%&d and is not Indicated above q o we nand the follawinT 1] Enter correct accounting In all 5 mr•anunting fields above, 4r 4 � C17 qt' 2 Ptov1de Correct accounting furOggating Unit and PMCeEr s 16. 12*' ---'- �nau arae+ 1=Cj ry COI lection Information E < o ay I 1141 1b IG [des No. "Sam le I•Yosc riort or ID Data Tlme si nat 0 ►° � — {{�I'J ti �.,.� •gam rr 2.4943 E - - -s - - ;.._ T3� r r 3 CL 5f3 Ll -d u - 9 - s- - r- Gx . �:. �� . -5A 4, -- NO. YdATM EQUffamEm RAINK ti PER DAY) I :E1 I 1--k-4-4— Aff 7]"Im' rlsrtad erI]/iirrrims . i 77 ues . ided Tumarraund _._ Rahnqulahed By ;ristefilma;fPaiel TeaMn +e}+� I Accepted llata+T inx �Ished�Y - :iXacafllmf Pi*7 DWs •, 9e$saaledm-ock oven l By :C}stedTinne 9edJLr�cked y D�huRian■ •48K ?4'1Cornrnenl4 ; tlEUds H!F6ana: A1, II'*,5,.CA, Cr, cµ Pw,'Ima, Mm. Mo. NI. K, Na, Sr, Zm M.I.I. by G.02e: 6t, Ars-: Ba, cd, Co., Ph, Se, T1, V tig bV 7471 pH, nSoli+I* Ar)irsrfs r9 Nttrste-H Silo Analytical lab Page 130 of 130 a . ; - 1 7 ................................ . .......... ....... ---------- ...... ...... ...... CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM .... Ana -.. al Laboratory I Anal -cal Laboratory Us On T . ..... . . . . . . .............. ................. . ..... . ............................ y �Se!y�ices ODUKE "P Code M803A2 I Bu 11diw 7406) SOIL i of i 13339 Hagam Ferry Rd sampki V�ljimiriry sj:�� DISTRIBUTION '. ; ORIGINAL 1c) LAB, ENERU T, (goo) 875-624:S SAMPLE PROGRAM rw,,d COPY to CLIENT Lt" 7�7j3 aAA mler, NPDE7,6 Ev� I)f'rO)Kt N4kfft AB Groundwater Assessment - Sail Plard ff SGltari HEALY Revi,-.ton 1 (T-17-17) (2017 Supplemental Soil Testing) RCRAV&we— a A)ch— 41FM NO: 021013 AB GW 2 HIJ. 3= ,e I 4 H 'L = 9 6=Noi e 4 5wwdrwe L* &J"Dct 10: 71MR11 c4de: u jr �t �i� � 8 [ Y V 9)Adiiolk� JU to 5113 r to ro[nplle kd wro"Ill Ural an e 3C ........ ... When spodfln account!" h as bean eStablithaNd and is not Incitcalled AbU. L' westeed tilafollowing: 1) Enter correct ar.r.ounjinr 1 in all 5 accounting flellC6 ittOV41, Of 2 Proviciff tormm-1*c�ournj!a for Operstiri g U ni I and Prnr.r,;* ID. 4 -22 0 I USE ONLY *--!:kR U ... __ "Chem "Collection Infom-iaton !:kFl U ...... _.. I "L gh ID Desktop No, 13SMITIple DeSCription or IDp 4. D1. Fn.. Signatura ------e-* KL Ar E z2Requested Tunnlar"nd I ................ 14 13ft&_ '? wvs- -48 Hr 24 -%AHrl Ikda1,. Cast A11 AM" n. cp F Ll I I Ar '7 Rli,.Aqh&d try rj;Dmwmme; jA�ld A -mi JA, 3 1 0� � pted aatelTlilc 7/lq/1?09 LxetmtTlme S*Alledyl-ck DparwA OV :DabLn1ma MEW9 Hy 011}: Al. 13k Ek C4, Cr, Cu, F4, Mg, Mft Mo, N1, K, Na, Sr, Zn Metals by 602D: Sb, As, Ug'L Cd, Co, P'll), Se, 11. V Ha bV 7471 P41 %Solid . Animas: C1. Nitfate-N. E04 z2Requested Tunnlar"nd I ................ 14 13ft&_ '? wvs- -48 Hr 24 -%AHrl Ikda1,. Cast A11 AM"