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HomeMy WebLinkAboutASHE BG GW FINAL Dec 2016TECHNICAL MEMORANDUM Date: December 15, 2016 File: 1026.102.19 To: John Toepfer (Duke Energy) Cc: Kathy Webb (S erra) From: Todd Plating Subject: Quantificatio of Va d Background Groundwater Samples for Statistics Calculations and Recommendation of Additional Background Wells - GW -1 Cluster for the Asheville Steam Electric Plant Proposed Preliminary Background Threshold Values (PPBTVs) for groundwater will be calculated for CAMA assessment constituents identified with concentrations greater than the 2L or IMAC at the Asheville Steam Electric Plant (Site). A summary of background well analytical results was originally presented in the Asheville Corrective Action Plan Part 1 submitted on November 20, 2015 and updated in the CSA Supplement 1 submitted August 2016. Table 1 provides a summary of existing background well data for each flow system and indicates which samples are considered for use in statistical calculations to determine concentrations of naturally occurring (background) inorganic constituents in groundwater. Well locations are presented on Figure 1. Additional sampling has been conducted since September 2016 that can be used to augment the dataset provided herein once avaialable. The following discussion quantifies the number of valid results to date within each flow zone and provides justification for including monitoring wells GW -1, GW -1D, and GW-1BR within the evaluation of PPBTVs at the Site. BACKGROUND WELL DATA ANALYSIS The current background monitoring well network consists of wells installed within four flow zones (alluvial, saprolite, transition zone, and bedrock). Samples from these wells must meet the following criteria to be considered valid for determining PPBTVs: tr Sample pH is less than or equal to (<) 8.5 standard units (S.U.); Sample turbidity is less than or equal to (<) 10.0 Nephelometric Turbidity Units (NTUs); and y Result is not a statistical outlier identified for background sample data collected through April 2016 (SynTerra, August 31,2016; CSA Supplement 1). Professional judgement can be used to retain data that does not meet these criteria (such as pH); however, the decision to retain data that does not satisfy these criteria must be documented. For Asheville, only an evaluation with pH <8.5 was conducted due to the limited occurrence of groundwater with pH between 8.5 and 9.0 S.U. Only one sample was identified with pH of 8.9 and this sample was eliminated. P: \ Duke Energy Progress.1026 \ 102. Asheville Ash Basin GW Assessment Plan \ 19.EG_CSASUP \ Statistics \ Stats Review—DEQ Request\Final BG Analytical thru 2019-09 plus GW-1.docx Quantification of Valid Background Groundwater Samples for Statistics Calculations and Recommendation of Additional Background Wells - GW -1 Cluster December 15, 2016 Asheville Steam Electric Plant Page 2 of 3 ALLUVIAL One background well (MW -10) is screened within the alluvial flow zone. Nine valid sampling events have occurred since March 2014. One sample (November 4, 2014) has been eliminated as water quality parameters were not reported by a third party who collected this sample. With the exception of a hexavalent chromium, strontium, total radium, and uranium, the alluvial background data set will satisfy the requirements for the minimum number of samples to conduct statistical analysis by the end of 2016. SAPROLITE Five background wells (AMW-3A, CB -1, CB -9, CB-09SL, and MW -24S) are screened in the saprolite flow zone. The data set will satisfy the requirements for the minimum number of samples to conduct statistical analysis for all constituents. Groundwater samples eliminated from background dataset include: 47 AMW-3A appears to be contaminated by grout as pH remains elevated after attempts to redevelop the well. 47 Four samples from CB -1 and one sample from CB-09SL were eliminated due to elevated turbidity. 17 Boron, manganese, strontium, and sulfate results from the MW -24S sample collected on April 12, 2016 have been flagged as outliers during preliminary statistical analysis. Review of laboratory analytical data packages, including duplicate analyses, have resulted in the elimination of this sample from the data set. TRANSITION ZONE One background well (CB -01D) is screened within the transition zone. Eight valid sample events have occurred since April 2015. With the exception of hexavalent chromium, total radium, and uranium, the transition zone background data set will satisfy the requirements for the minimum number of samples to conduct statistical analysis by the end of 2016. It is projected that the minimum number of background data necessary to run statistics would be achieved in July 2017 for all paramenters based upon a two month sampling frequency. BEDROCK Two wells (AMW-3B and CB-09BR) are screened in the bedrock flow zone. With the exception of nitrate, the bedrock background data set will satisfy the requirements for the minimum number of samples to conduct statistical analysis by the end of 2016. Groundwater samples eliminated from background dataset include: 47 Elevated turbidity in one sample at AMW-3B and two samples at CB-09BR. 07 Elevated pH, observed during the initial sampling event, at CB-09BR. P: \ Duke Energy Progress.1026 \ 102. Asheville Ash Basin GW Assessment Plan \ 19.EG_CSASUP \ Statistics \ Stats Review -DEQ Request\Final BG Analytical thru 2019-09 plus GW-l.docx Quantification of Valid Background Groundwater Samples for Statistics Calculations and Recommendation of Additional Background Wells - GW -1 Cluster December 15, 2016 Asheville Steam Electric Plant Page 3 of 3 47 Water quality parameters were not reported for a sample collected by a third party on November 4, 2014 at AMW-3B. RECOMMENDATION OF ADDITIONAL BACKGROUND WELLS — GW -1 CLUSTER While evaluating the background data set, the sample results from wells within the GW -1 cluster were found to exhibit background water quality characteristics and are recommended for inclusion within the determination of PPBTVs. Figure 1-80 (attached) from the CSA Supplement 1 indicates the water table elevation at well GW -1 has not been influenced by dewatering the 1982 basin. Groundwater head elevations at this location appear connected to Lake Julian as evident by the relatively stable water table and similar head elevation to the lake, approximately 2,160.70 feet. Recent water level measurements indicate similar head potential at GW -1 and GW -1D (2,159.98 feet and 2,060.06 feet, respectively) and a downward vertical gradient to GW-1BR (2,154.96). Wells PZ -26, MW -1D, and MW-1BR are located southwest of the GW -1 cluster at the edge of the CCR surface impoundment boundary. September 2016 groundwater head elevations at this location are approximately 20 feet lower than those at the GW -1 cluster in the surficial zone (PZ - 26 2,140.48 feet) and transition zone (MW -1D 2,140.20 feet), and 14 feet lower within the bedrock flow system (MW-1BR 2,140.47 feet). This data further indicates GW -1 is upgradient of the 1982 basin and acceptable to include within the background evaluation. Historical analytical data results (Table 1) of select coal ash indicator parameters for wells within the GW -1 cluster indicate values of boron, strontium, sulfate, and TDS are consistent with other background location results and similar to previously developed provisional proposed background concentrations. The inclusion of the GW -1 cluster in the statistical background evaluation would bolster the current dataset for saprolite from 46 to 65, transition zone from 8 to 13, and bedrock from 12 to 14 valid samples. Sample results that do not meet criteria described above have been flagged and eliminated from the valid count on Table 1. ATTACHMENTS: Table 1: Background Analytical Results through September 2016 Including GW -1 Figure 1: Site Layout Map Figure 1-80: Water Table Elevations Time Series Plot P: \ Duke Energy Progress.1026 \ 102. Asheville Ash Basin GW Assessment Plan \ 19.EG_CSASUP \ Statistics \ Stats Review -DEQ Request\Final BG Analytical thru 2019-09 plus GW-1.docx TABLE 1 BACKGROUND ANALYTICAL RESULTS THROUGH 2016-09 PLUS GW -1 CLUSTER ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ARDEN, NC P:\Duke Energy Progress.1026\102. Asheville Ash Basin GW Assessment Plan\19.EG_CSASUP\Statistics\Stats Review_DEQ Request\FINAL BG Analytical thru 2019-09 plus GW -1 Page 1 of 3 Analytical Parameter PN Water Level Temp Spec Coed DO ORP Eh Turbidity Antimony Arsenic Beryllium Boron Cadmium Chloride Chromium iVli Chromium Cobalt Iron Manganese Nickel Nitrate Nit N) Nitrate Selenium Sodium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Radium -226 Radium -228 Uranium -233 Uranium -234 Uranium -236 Uranium -238 Reporting Units S.U. ft Deg C u mhos mg/L mV mV NTUs ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L mg-N/L mg/L ug/L mg/L ug/L mg/L ug/L mg/L ug/L pCi/L pCi/L ug/mL ug/mL ug/mL ug/mL 15A NCAC 02L Standard 6.5-8.5 NE NE HE NE NE NE NE 1* 10 4* 700 2 250 0.07^ 10 1* 300 50 100 10 SO 20 NE NE 250 0.2* 500 0.3* NE NE NE NE NE HE Sample ID Sample Collection Date Field Parameters Analytical Results Alluvial MW -10 03/05/2014 5.4 5.72 10 72 5.94 226 NM 2.9 NA <1 NA 150 <1 4.4 NA <5 3.18 207 187 <5 NA NA <1 NA NA 0.63 <0.2 55 NA NA NA NA NA NA NA MW -10 04/17/2014 5.0 5.64 12 68 0.3 182 NM 2.9 <1 <1 NA <50 <1 8.3 NA <5 NA 1040 573 <5 0.04 0.16 <1 NA NA 0.41 <0.2 48 NA NA NA NA NA NA NA MW -10 07/23/2014 4.6 5.70 19 67 0.38 244 NM 0.93 <1 <1 NA <50 <1 8.4 NA <5 <5 598 363 15 0.1 0.42 <1 3.3 NA 0.58 <0.2 44 NA NA NA NA NA NA NA MW -10 11/04/2014 NM NM NM NM NM NM NM NM <I <1 <1 NA <1 NA NA <I 6.11 675 555 2.95 NA NA <1 3.27 NA NA <0.2 NA NA NA NA NA NA NA NA MW -10 05/12/2015 5.0 5.58 16 64 0.96 47 252 4.09 <1 <1 <1 <50 <1 8.9 NA <1 4.29 369 340 3.1 NA NA <1 4.02 24 0.3 <0.2 44 <0.3 NA NA NA NA NA NA MW -10 12/08/2015 5.4 5.79 14 74 0.4 27 232 0.69 <0.5 <0.5 0.22 <50 <0.08 12.6 0.14 '0.5 3.6 64 200 2.9 NA NA <0.5 5.09 24 <1 0.13 91 <1 NA NA NA NA NA NA MW -10 01/19/2016 5.1 5.62 8 72 0.53 481 686 0.71 <1 <1 <1 <50 <1 14 0.17 MI <1 2.99 63 185 2.78 NA NA <1 4.85 25 0.29 <0.2 40 <0.3 NA NA NA NA NA NA MW -10 04/12/2016 5.1 5.69 13 67 0.37 141 346 1.82 <1 <1 <1 150 <1 12 0.12 <1 2.12 54 B2 142 2.44 NA NA <1 4.15 24 0.43 10.2 46 10.3 1.17 <3 10.00005 10.00005 10.00005 10.0002 MW -10 07/08/2016 4.6 5.74 23 70 1.73 S 359 564 6.97 <1 11 11 150 <1 15 0.14 <1 2.95 31 175 1.86 NA NA <1 5.64 26 0.3 10.2 53 10.3 0.787 <1 10.00005 10.00005 10.00005 <0.0002 MW -10 09/13/2016 5.1 6.79 21 75 0.29 203 408 1.41 <1 11 <1 <50 <1 15 0.1 <1 4.19 220 243 2.67 NA NA <1 5.92 23 0.45 <0.2 49 10.3 4.71 <1 10.00005 <0.00005 10.00005 <0.0002 Total Count of Valid Samples 9 9 8 9 6 9 9 9 5 9 8 9 9 9 2 2 9 7 6 9 9 9 5 3 3 3 3 3 3 Saprolite AMW-3A 11/04/2014 NM NM NM NM NM NM NM NM <I <1 <I NA <I NA NA 12.4 <1 153 22 <1 NA NA <1 6.54 NA NA 10.2 NA NA NA NA NA NA NA NA AMW-3A 05/12/2015 12.1 8.17 15 2350 5.41 -189 16 15 <I <1 <3 <50 <1 1.1 NA <1 <1 110 <5 <3 NA NA <I 7J 1220 0.34 <0.2 500 8.98 NA NA NA NA NA NA CB -1 11/17/2010 4.6 47.73 14 15 NM NM NM 9.16 <0.5 <5 NA <50 <0.08 <5 NA <5 NA 1160 46.3 <5 NA 0.51 <10 NA NA <5 <0.1 <25 NA NA NA NA NA NA NA CB -1 04/12/2011 4.4 48.20 17 18 7.57 126 331 4.81 10.5 <5 NA <50 <0.08 <5 NA <5 NA 589 36.3 <5 NA 0.43 <10 NA NA <5 <0.1 <25 NA NA NA NA NA NA NA CB -1 07/19/2011 4.8 48.40 22 17 7.16 -4 201 17.6 <0.5 <5 NA 51.1 <0.08 <5 NA 81.5 NA 1330 43 53 b NA 0.43 <10 NA NA <5 <0.1 <25 NA NA NA NA NA NA NA CB -1 11/09/2011 5.4 50.47 12 19 8.36 -86 119 20.9 <0.5 6.7 NA 150 <0.08 <5 NA 8.7 NA 17800 293 12 NA 0.42 <10 NA NA <5 <0.1 93 NA NA NA NA NA NA NA CB -1 04/10/2012 4.8 49.75 15 16 9.67 -44 161 8.11 <0.5 <5 NA <50 <0.08 <5 NA <5 NA 276 28.4 <5 NA 0.41 <10 NA NA <5 <0.1 <25 NA NA NA NA NA NA NA CB -1 07/16/2012 4.6 49.09 16 20 8.65 317 522 3.65 10.5 <5 NA <50 <0.08 1.6 NA <5 NA 179 26.8 <5 NA 0.42 <10 NA NA <2 <0.1 <25 NA NA NA NA NA NA NA CB -1 11/15/2012 4.9 50.89 16 18 7.82 335 540 7.86 <0.5 <5 NA <50 <0.08 1.4 NA <5 NA 218 28.5 <5 NA 0.36 <10 NA NA <2 <0.1 <25 NA NA NA NA NA NA NA CB -1 04/03/2013 4.5 49.47 15 20 7.89 135 340 4.78 <1 <1 NA <50 <1 1.5 NA 15 NA 98 27 10 NA 0.43 <1 NA NA <0.1 <0.2 <10 NA NA NA NA NA NA NA CB -1 07/01/2013 5.3 44.71 16 24 8.75 60 265 9.2 <1 <1 NA <50 <1 1.7 NA <5 NA 2870 67 <5 NA 0.42 1.22 NA NA <0.1 <0.2 <25 NA NA NA NA NA NA NA CB -1 11/05/2013 4.5 43.93 15 18 9.4 413 618 12 <1 <1 NA <50 <1 1.6 NA <5 NA 664 33 <5 NA 0.42 <1 NA NA 0.15 <0.2 <25 NA NA NA NA NA NA NA CB -1 04/16/2014 4.4 46.05 15 17 8.3 410 615 2.8 <1 <1 NA <50 <1 1.7 NA <5 NA 152 24 <5 NA 0.42 <1 NA NA 0.18 <0.2 <25 NA NA NA NA NA NA NA CB -1 07/09/2014 4.6 46.41 16 18 8.67 387 592 3.6 <1 <1 NA <50 <1 1.7 NA <5 NA 215 26 <5 NA 0.45 <1 NA NA 0.12 10.2 <25 NA NA NA NA NA NA NA CB -1 11/03/2014 4.5 48.24 16 22 7.53 352 557 7.09 <1 <1 NA <50 <1 1.7 NA <5 NA 175 25 <5 NA 0.4 <1 NA NA 0.17 <0.2 <25 NA NA NA NA NA NA NA CB -1 04/07/2015 4.9 45.50 15 17 8.68 136 341 6.74 <1 <1 <1 <50 <1 1.6 NA <5 1.94 279 26 'S NA 0.42 <1 1.04 NA 0.36 <0.2 31 NA NA NA NA NA NA NA CB -1 07/06/2015 4.7 49.12 16 20 8.34 161 366 3.82 <1 <1 <1 <50 <1 1.7 NA <5 1.95 86 25 <5 0.4 1.8 <1 0.993 <5 0.61 <0.2 <25 <0.3 NA NA NA NA NA NA CB -1 11/03/2015 5.1 50.73 16 15 7.9 525 730 21 <I <1 <3 150 <1 1.2 NA 5 4.11 4040 91 <5 0.29 1.3 <1 0.893 B2 <5 0.4 <0.2 <25 3.03 NA NA NA NA NA NA CB -1 12/08/2015 5.1 50.76 15 15 6.4 69 274 8.8 <0.5 <0.5 <0.2 <50 <0.08 1.6 0.031 0.78 1.9 290 27 1.4 NA NA <0.5 <5 <5 <1 <0.1 33 <1 NA NA NA NA NA NA CB -1 01/20/2016 4.9 48.27 10 16 8.32 220 425 7.81 <1 <1 <1 <50 <1 2.2 10.03 <1 2.1 279 28 1.53 NA NA <1 1.03 <5 <0.1 <0.2 125 <0.3 NA NA NA NA NA NA CB -1 04/07/2016 4.9 44.14 14 17 8.22 329 534 9.74 <1 <1 <1 <50 <1 2 <0.03 <5 2.36 532 31 <5 0.4 1.8 <1 1.17 <5 0.35 10.2 <25 <0.3 14.4 <3 <0.00005 <0.00005 <0.00005 <0.0002 CB -1 07/05/2016 4.8 47.44 23 17 5.44 360 565 8.95 <1 <1 <1 <50 <1 1.9 <0.03 <5 2.39 595 32 <5 0.4 1.8 <3 1.05 <5 0.23 <0.2 <25 0.537 6.55 <1 10.00005 <0.00005 '0.00005 0.000252 CB -1 09/16/2016 4.5 49.44 16 17 7.41 306 511 6.75 <1 <1 <1 <50 <1 1.7 <0.03 <1 2.26 325 B2 26 1.59 NA NA <1 0.969 <5 <0.1 <0.2 <25 0.304 24.9 <1 <0.00005 <0.00005 <0.00005 <0.0002 CB -9 11/15/2012 5.0 37.78 15 46 1.66 399 604 8.42 10.5 <5 NA <50 10.08 6.8 NA <5 NA 2880 105 <5 NA 0.38 <10 NA NA <2 0.12 <25 NA NA NA NA NA NA NA CB -9 04/03/2013 4.9 37.18 15 40 7.8 112 317 2.01 <1 <1 NA <50 <1 6.5 NA <5 NA 370 67 <5 NA 0.33 <1 NA NA 0.2 <0.2 42 NA NA NA NA NA NA NA CB -9 07/01/2013 5.3 34.74 16 48 1.9 38 243 8.43 <1 <1 NA <50 <1 6.4 NA 6 NA 2080 92 6 NA 0.33 1.12 NA NA 0.11 <0.2 26 NA NA NA NA NA NA NA CB -9 11/05/2013 4.7 35.72 15 38 2.8 378 583 8.7 <1 <1 NA <50 <1 6.8 NA <5 NA 883 60 <5 NA 0.34 <i NA NA 0.21 <0.2 28 NA NA NA NA NA NA NA CB -9 04/16/2014 4.8 36.13 15 38 2.2 347 552 3.5 <1 <1 NA <50 <1 6.9 NA <5 NA 248 39 <5 NA 0.33 <1 NA NA 0.13 <0.2 <25 NA NA NA NA NA NA NA CB -9 07/09/2014 4.8 35.89 16 38 2.59 353 558 5.3 <1 <1 NA <50 <1 6.8 NA <5 NA 531 47 <5 NA 0.35 <1 NA NA 0.12 <0.2 28 NA NA NA NA NA NA NA CB -9 11/03/2014 4.9 37.18 15 47 2.01 228 433 8.34 <1 <1 NA <50 <1 6.9 NA <5 NA 341 41 <5 NA 0.29 '1 NA NA 0.14 10.2 26 NA NA NA NA NA NA NA CB -9 04/07/2015 5.0 37.29 16 38 2.24 114 319 8.79 <1 <1 <1 <50 <1 6.7 NA <5 1.36 653 50 <5 NA 0.29 <1 4.1 NA 0.24 <0.2 35 NA NA NA NA NA NA NA CB -9 07/06/2015 4.9 37.02 16 41 2.25 159 364 4.5 <1 <1 <1 <50 <1 6.7 NA <5 <1 158 40 '5 0.28 1.2 <S 4.06 8 0.11 <0.2 25 10.3 NA NA NA NA NA NA CB -9 09/09/2015 5.0 37.50 16 37 1.97 223 428 7.51 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA CB -9 11/02/2015 4.5 36.57 16 37 2.7 575 780 9 <1 '1 <1 150 <1 6.6 NA <5 1.64 1050 65 <5 0.25 1.1 <1 4.07 8 0.36 <0.2 <25 1.33 NA NA NA NA NA NA CB -9 12/08/2015 5.3 37.09 15 36 1.72 204 409 3.38 <0.5 <0.5 -1 <0.2 <50 <0.08 6.7 0.1 <0.5 0.8 150 34 1.2 NA NA <0.5 <5 7 <1 <0.1 43 <1 NA NA NA NA NA NA CB -9 01/21/2016 5.2 35.48 15 36 1.8 284 489 1.8 <1 <1 <1 <50 <1 6.9 0.12 <1 <1 84 36 1.28 NA NA <1 3.89 7 0.14 <0.2 125 10.3 NA NA NA NA NA NA CB -9 04/06/2016 5.1 34.71 15 37 2.21 336 541 9.33 <1 <1 <1 <50 <1 6.9 0.089 <5 1.45 739 52 <5 0.26 1.2 <1 4 7 0.25 <0.2 <25 0.763 1.8 2.18 <0.00005 <0.00005 <0.00005 0.00124 CB -9 07/05/2016 5.0 36.47 17 36 2.38 348 553 9.75 <1 <1 <1 <50 <1 7.1 0.085 <5 1.14 294 40 <5 0.26 1.2 <1 3.94 7 0.11 <0.2 <25 0.501 1.49 <1 10.00005 '0.00005 '0.00005 <0.0002 CB -9 09/14/2016 5.1 37.49 16 37 2.21 283 488 7.88 <1 <1 <1 <50 <1 6.4 0.11 <1 1.14 237 38 1.48 NA NA <1 3.91 7 0.14 <0.2 29 0.67 2.64 <1 <0.00005 <0.00005 <0.00005 <0.0002 CB -095L 04/27/2015 6.0 36.05 13 76 1.08 130 335 30.4 <I <1 <1 <50 <1 6.1 NA 2.86 1.21 475 125 2.13 NA NA <1 8.54 40 0.74 <0.2 92 0.56 NA NA NA NA NA NA CB-09SL 05/28/2015 5.8 35.98 19 59 1.59 84 289 5.97 <1 <1 <1 <50 <1 6.6 NA <1 <1 73 71 <1 NA NA <1 4.15 28 0.57 <0.2 43 <0.3 NA NA NA NA NA NA CB-09SL 09/08/2015 5.8 36.51 16 59 2.61 165 370 3 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA CB-09SL 12/08/2015 6.0 35.99 14 56 2.11 198 403 6.44 <0.5 <0.5 L3 0.29 <50 <0.08 6.2 0.2 1.3 <0.5 320 12 0.77 NA NA <0.5 <5 28 <1 <0.1 93 <1 NA NA NA NA NA NA CB-09SL 01/21/2016 5.8 34.50 9 54 2 225 430 7.1 <1 <1 <1 <50 <1 6.5 0.2 <1 <1 95 15 <1 NA NA <1 3 30 0.24 <0.2 41 <0.3 NA NA NA NA NA NA CB-09SL 04/13/2016 5.6 34.05 15 56 1.63 97 302 1.05 <1 <1 <1 <50 <1 6.3 0.25 <1 <1 23 6 <1 NA NA <1 3.25 24 0.25 <0.2 54 10.3 1.26 <3 <0.00005 <0.00005 <0.00005 <0.0002 CB-09SL 07/11/2016 5.7 35.64 17 55 1.5 129 334 9.3 <1 <1 <1 <50 <1 6.3 0.23 19.3 <1 158 13 12.4 NA NA <1 3.27 27 0.72 10.2 43 0.392 1.3 <1 10.00005 <0.00005 10.00005 0.0000788 j CB-09SL 09/14/2016 5.8 36.46 17 61 1.47 61 266 9.67 <1 <1 <1 <50 <1 6.6 0.18 MI 1.43 <1 78 7 11 NA NA <1 3.21 28 0.26 <0.2 47 0.479 1.07 11 <0.00005 <0.00005 <0.00005 0.000145 j MW -24S 05/11/2015 5.0 11.26 17 75 5.48 72 277 1.77 <1 I <1 <1 <50 <1 12 NA <1 2.05 304 170 1.16 1 NA NA <S 1 3.48 37 0.49 <0.2 54 10.3 NA NA NA NA NA NA MW -24S 06/01/2015 5.2 11.19 15 79 4.67 97 302 2.74 <1 <1 <1 <50 <1 13 NA <1 1.02 60 136 1.07 NA NA <1 3.25 36 0.62 <0.2 66 <0.3 5.78 <3 <0.00005 10.00005 <0.00005 10.0002 MW -24S 09/02/2015 5.2 11.34 18 78 5.03 193 398 0.96 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA MW -24S 12/08/2015 5.2 10.95 14 77 4.81 154 359 0.25 <0.5 <0.5 L3 0.23 <50 <0.08 13 0.3 M1 <0.5 0.78 <50 120 0.75 NA NA <0.5 <5 35 <1 <0.1 72 <1 NA NA NA NA NA NA MW -24S 01/19/2016 5.3 10.98 12 79 5.12 148 353 0.8 <1 <1 <1 <50 <1 14 0.31 <1 1.06 <10 150 1.02 NA NA <1 3.31 37 0.66 <0.2 36 <0.3 NA NA NA NA NA NA MW -24S 04/12/2016 5.2 11.30 14 81 4.66 205 410 0.75 <I <1 11 232 <1 14 0.26 <1 <1 235 B2 359 1.04 NA NA <I 3.38 228 0.74 <0.2 63 <0.3 1.76 <3 <0.00005 <0.00005 <0.00005 0.000168 j MW -245 07/08/2016 4.3 10.81 17 80 6.21 S 325 530 1.22 <1 <l <1 150 <1 14 0.26 <1 11 110 136 <1 NA NA <1 3.35 40 0.62 10.2 52 10.3 1.09 <1 10.00005 10.00005 10.00005 <0.0002 MW -24S 09/13/2016 5.3 11.76 16 81 4.9 240 445 0.85 <1 <1 <1 150 <1 14 0.27 <1 <1 <10 123 <1 NA NA <1 3.36 38 0.47 10.2 35 10.3 2.48 0.65 <0.00005 <0.00005 <0.00005 <0.0002 Total Count of Valid Samples 46 46 44 44 27 44 44 94 19 44 27 44 94 44 7 26 44 27 25 44 44 44 24 12 12 12 12 12 12 P:\Duke Energy Progress.1026\102. Asheville Ash Basin GW Assessment Plan\19.EG_CSASUP\Statistics\Stats Review_DEQ Request\FINAL BG Analytical thru 2019-09 plus GW -1 Page 1 of 3 TABLE 1 BACKGROUND ANALYTICAL RESULTS THROUGH 2016-09 PLUS GW -1 CLUSTER ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ARDEN, NC P:\Duke Energy Progress.1026\102. Asheville Ash Basin GW Assessment Plan\19.EG_CSASUP\Statistics\Stats Review_DEQ Request\FINAL BG Analytical thru 2019-09 plus GW -1 Page 2 of 3 Analytical Parameter PN Water Level Temp DO ORPLTurbidity Antimony Arsenic Beryllium Boron Cadmium Chloride Chromium iVii Chromium Cobalt Iron Manganese Nickel Nitrate it N) Nitrate Selenium Sodium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Radium -226 Radium -228 Uranium -233 Uranium -234 Uranium -236 Uranium -238 Reporting Units S.U. ft Deg C Lumhos mg/L mV ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L mg-N/L mg/L ug/L mg/L ug/L mg/L ug/L mg/L ug/L pCi/L pCi/L ug/mL ug/mL ug/mL ug/mL15A NCAC 02L Standard 6.5-8.5 NE NE NEI 1* 10 4* 700 2 250 0.07A 10 1* 300 50 100 10 SO 20 NE NE 250 0.2* 500 0.3* NE NE NE NE NE HE Sample ID Sample Collection Date Field Parameters Analytical Results Transition Zone CB -ID 04/28/2015 6.7 38.22 17 75 1.56 1 206 7.52 <1 <1 <1 <50 <1 1.3 NA 7.04 2.54 528 226 6.03 NA NA <1 5.63 25 2.7 <0.2 44 0.416 NA NA NA NA NA NA CB -1D 05/21/2015 6.4 38.36 16 57 0.8 48 253 2.83 <1 <1 <1 <50 <1 1.1 NA 1.27 1.66 589 286 2.07 NA NA <1 3.89 19 2.2 <0.2 37 0.34 NA NA NA NA NA NA CB -1D 09/08/2015 5.8 38.92 16 30 2.87 122 327 2.36 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA CB -1D 12/06/2015 6.4 39.34 15 39 1.5 -67 138 3.26 <0.5 <0.5 <0.2 <50 <0.08 1.2 '0.03 2.4 2.6 610 180 3.7 NA NA <0.5 <5 19 3.2 <0.1 67 <1 NA NA NA NA NA NA CB -ID 01/20/2016 5.8 37.24 13 31 2.12 115 320 3.67 <1 <1 <1 <50 <1 0.83 '0.03 1.83 2.34 269 151 2.72 NA NA <1 1.78 14 3.2 <0.2 <25 <0.3 NA NA NA NA NA NA CB -1D 04/13/2016 5.6 34.08 15 36 3.17 91 296 4.08 <1 <1 <1 <50 <1 0.91 <0.03 <1 3.08 231 93 4.97 NA NA <1 2.92 17 4.6 <0.2 38 <0.3 2.9 <3 <0.00005 '0.00005 <0.00005 0.0000762 j CB -1D 07/08/2016 5.1 36.70 20 30 6.53 S 213 418 9.65 <1 <1 <1 <50 <1 0.96 <0.03 <1 2.33 193 70 2.32 NA NA <1 2.48 14 2.1 <0.2 <25 <0.3 1.3 <1 <0.00005 <0.00005 <0.00005 0.000241 CB -1D 09/14/2016 5.6 38.27 17 30 5.41 222 427 9.75 <1 <1 <1 <50 <1 0.96 <0.03 1.32 2.86 79 47 4.36 NA NA <1 2.16 13 2.5 <0.2 25 0.41 2.49 <1 <0.00005 <0.00005 <0.00005 0.000252 Total Count of Valid Samples 8 8 7 7 7 7 7 7 5 1 1 7 7 7 O O 7 7 7 7 7 7 7 3 3 3 3 3 3 Bedrock AMW-3B 07/23/2014 6.5 7.97 18 88 2.89 163 NM 10.8 <1 <1 NA <50 <1 0.58 NA <5 <5 131 17 <5 0.08 0.37 <1 7.16 NA 1.7 <0.2 92 NA NA NA NA NA NA NA AM 3B 11/04/2014 NM NM NM NM NM NM NM NM <1 <I <1 NA <I NA NA <I <1 256 102 1.67 NA NA <1 8.21 NA NA <0.2 NA NA NA NA NA NA NA NA AMW-3B 05/12/2015 7.7 8.27 16 83 0.84 -69 136 6.86 <1 <1 <1 <50 <1 <2.5 NA <1 <1 47 <5 1.77 NA NA <1 6.07 60 3.3 <0.2 72 0.344 NA NA NA NA NA NA AMW-3B 12/08/2015 6.1 8.24 14 73 4.3 40 245 8.56 <0.5 <0.5 <0.2 <50 '13.08 <1 0.21 <0.5 <0.5 <50 <5 1.2 NA NA <0.5 5.55 59 1.6 <0.1 95 <1 NA NA NA NA NA NA AMW-3B 01/20/2016 6.5 8.09 10 71 4.42 62 267 3.26 <1 <1 <1 <50 <1 0.61 0.18 <1 <1 20 <5 <3 NA NA <1 5.05 58 1.3 <0.2 47 <0.3 NA NA NA NA NA NA AMW-3B 04/12/2016 6.4 8.05 14 71 4.6 69 274 1.78 <1 <1 <1 <50 <1 0.6 0.18 <1 <1 <10 B2 <5 <1 NA NA <1 5.18 56 1.1 <0.2 67 <0.3 7.41 <3 <0.00005 <0.00005 <0.00005 <0.0002 AMW-3B 07/08/2016 5.7 8.04 18 70 5.9S 312 517 6.6 <1 <1 <1 <50 <1 0.65 0.22 <1 <1 13 <5 <1 NA NA <1 5.12 57 1.1 <0.2 67 0.385 1.53 <1 <0.00005 <0.00005 <0.00005 <0.0002 AMW-3B 09/13/2016 6.5 9.12 18 71 4.56 172 377 3.37 <1 <1 <1 <50 <1 0.55 0.19 <1 <1 <10 <5 <1 NA NA <1 5.12 56 1.2 <0.2 65 0.434 0.718 <1 <0.00005 <0.00005 <0.00005 '0.0002 CB -09 BR 04/27/2015 8.9 44.46 16 185 0.49 123 328 16.2 <I <1 <I <50 <I 6.4 NA 8.25 <1 460 21 4.42 NA NA 1.56 8.39 115 3.9 <0.2 130 3.03 NA NA NA NA NA NA CB -096R 05/28/2015 6.5 48.57 16 135 0.36 69 274 10.8 <1 <1 <1 '50 <1 6.4 NA <1 <1 402 76 1.36 NA NA <1 4.76 98 1.8 <0.2 96 0.499 NA NA NA NA NA NA CB -0 BR 09/08/2015 6.3 49.19 17 105 0.84 133 338 9.89 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA CB-09BR 12/08/2015 6.6 47.95 14 100 0.55 65 270 7.06 <0.5 <0.5 L3 <0.2 <50 <0.08 6.1 0.092 1.1 <0.5 460 46 1.1 NA NA <0.5 <5 68 1.4 <0.1 83 <1 NA NA NA NA NA NA CB-09BR 01/21/2016 6.4 47.30 10 99 0.7 63 268 8.3 <1 <1 <1 <50 <1 6.4 0.068 9.08 <1 678 70 5.79 NA NA <1 3.47 71 1.2 <0.2 76 <0.3 NA NA NA NA NA NA CB-09BR 04/13/2016 6.1 46.93 15 98 0.52 57 262 8.71 <1 <1 <1 <50 <1 6.1 0.083 1.3 <1 557 57 1.42 NA NA <1 3.48 65 1.5 <0.2 82 <0.3 3.46 1.46 <0.00005 <0.00005 <0.00005 0.000114 j CB-09BR 07/12/2016 6.1 47.58 19 91 0.65 259 464 9.1 <1 <1 <1 <50 <1 6.4 0.14 1.5 <1 236 43 1.69 NA NA <1 4.27 65 1.3 <0.2 67 0.318 2.6 <1 <0.00005 <0.00005 <0.00005 <0.0002 CB-09BR 09/14/2016 6.2 48.19 16 91 0.52 121 326 9.61 <1 <1 <1 <50 <1 5.8 0.1 2.21 <1 252 39 1.66 NA NA <1 3.31 60 1.6 <0.2 75 0.602 2.28 0.609 <0.00005 '0.00005 <0.00005 0.0000846] Total Count of Valid Samples 12 12 11 11 11 11 11 11 10 11 11 11 11 11 O O 11 11 11 11 11 11 31 6 6 6 6 6 6 P:\Duke Energy Progress.1026\102. Asheville Ash Basin GW Assessment Plan\19.EG_CSASUP\Statistics\Stats Review_DEQ Request\FINAL BG Analytical thru 2019-09 plus GW -1 Page 2 of 3 TABLE 1 BACKGROUND ANALYTICAL RESULTS THROUGH 2016-09 PLUS GW -1 CLUSTER ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ARDEN, NC Prepared by: TDP Checked by: RBI Notes: Analytical Parameter PN Water Level Temp Red text indicates samples not used in determination of provisional preliminary background threshold values DO ORPLTurbidity u = Bold highlighted concentration indicates exceedance Antimony Arsenic Beryllium Boron Cadmium Chloride Chromium (VI) Chromium Cobalt Iron Manganese Nickel Nitrate (as N) Nitrate Selenium Sodium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Radium -226 Radium -228 Uranium -233 Uranium -234 Uranium -236 Uranium -238 Reporting Units S.U. ft Deg C Lumhos mg/L mV ug/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L mg-N/L mg/L ug/L mg/L ug/L mg/L ug/L mg/L ug/L pCi/L pCi/L ug/mL ug/mL ug/mL ug/mL 15A NCAC 02L Standard 6.5-8.5 NE NE NEI I. 10 4* 700 2 250 0.07A 10 1* 300 50 100 10 SO 20 NE NE 250 0.2* 500 0.3* NE NE NE NE NE NE Sample ID SampleCollection Date Field Parameters Analytical Results POTENTIAL WELLS TO INCLUDE IN BACKGROUND DATASET - JUSTIFICATION ATTACHED GW -1 Cluster Results (not included above) Saprolite GW -1 12/14/2007 4.5 20.39 14 98 NM NM NM NM <5 6.3 NA <IO <I 8.2 NA 35.7 NA 56800 NA 34.1 NA 6.3 <10 NA NA <5 0.12 50 NA NA NA NA NA NA NA GW -1 04/21/2008 3.8 19.78 I4 98 NM NM NM NM <5 <5 NA <10 <1 <5 NA <5 NA 2880 189 8.7 NA 8.2 <10 NA NA <5 <0.5 40 NA NA NA NA NA NA NA GW -1 10/13/2008 4.4 19.95 13 72 NM NM NM NM <5 <5 NA <50 <1 <5 NA <5 NA 122 74.8 5 NA 5.2 <10 NA NA <5 <0.1 54 NA NA NA NA NA NA NA GW -1 04/14/2009 4.3 19.70 14 89 NM NM NM NM <5 <5 NA <50 <1 <5 NA <5 NA 575 98.5 7.5 NA 7.7 <10 NA NA <5 <0.5 70 NA NA NA NA NA NA NA GW -1 10/16/2009 4.5 19.82 14 102 NM NM NM NM <5 <5 NA <50 <I <5 I NA <5 NA 232 100 6.5 NA 8.2 <10 NA NA <5 <0.5 74 NA NA NA NA NA NA NA GW -1 05/11/2010 3.1 19.63 13 106 NM NM NM NM <5 <5 NA <50 <1 <5 NA <5 NA 459 90.3 5 NA 8.6 <10 NA NA <5 <0.1 26 NA NA NA NA NA NA NA GW -1 11/17/2010 4.5 20.16 11 69 NM NM NM 6.32 <0.5 <5 NA <50 <0.08 <5 NA <5 NA 63.6 81 <5 NA 7.7 <10 NA NA <5 <0.1 46 NA NA NA NA NA NA NA GW -1 04/12/2011 1 4.3 19.33 1 13 1 112 5.06 49 254 7.46 <0.5 <5 I NA I <50 <5 11 <5 NA <5 I NA 248 1 138 7.1 1 NA 10.9 <10 NA NA 1 <5 <0.1 1 44 NA NA NA NA NA NA NA GW -1 07/14/2011 4.3 19.88 16 87 5.01 -84 121 2.77 <0.5 <5 NA <50 <0.08 <5 NA <5 NA 79.6 134 78 NA 7.5 <10 NA NA <5 <0.1 <25 NA NA NA NA NA NA NA GW -1 11/09/2011 4.6 20.54 14 96 4.36 1 -82 1 123 1 2.28 <0.5 <5 NA <50 <0.08 <5 NA <5 NA 102 205 5.9 NA 7.9 <10 NA NA <5 <0.1 86 NA NA NA NA NA NA NA GW -1 04/10/2012 4.6 20.03 16 104 3.95 -67 138 3.07 <0.5 <5 NA <50 <0.08 <5 NA <5 NA 96 341 5.9 NA 8 <10 NA NA <5 <0.1 64 NA NA NA NA NA NA NA GW -1 07/16/2012 4.4 19.92 16 93 2.92 297 502 7.98 <0.5 <5 NA 65.1 0.082 4.7 NA <5 NA 147 310 <5 NA 7.1 <10 NA NA <2 <0.1 57 NA NA NA NA NA NA NA GW -1 11/15/2012 4.6 20.69 15 96 2.26 348 553 5.76 <0.5 <5 NA <50 0.1 4.9 NA <5 NA 480 293 <5 NA 6 <10 NA NA 3.1 <0.1 37 NA NA NA NA NA NA NA GW -1 04/03/2013 4.5 20.68 15 93 2.48 137 342 2.57 <1 <1 NA <50 <1 5.4 NA <5 NA 31 442 <5 NA 5.9 2.04 NA NA 1.9 <0.2 69 NA NA NA NA NA NA NA GW -1 07/01/2013 4.8 20.47 17 125 3.42 12 217 2.17 <S <1 NA <50 <1 6.2 NA <5 NA 49 612 6 NA 7.1 3.32 NA NA 3.2 <0.2 80 NA NA NA NA NA NA NA GW -1 11/05/2013 4.5 20.94 1 14 1 148 2.3 436 641 3.1 <1 <1 NA <50 <1 1 7 NA <5 NA 89 737 5 1 NA 7.8 4.9 NA NA 15 <0.2 87 NA NA NA NA NA NA NA GW -1 04/17/2014 4.6 20.55 15 138 1.6 290 495 8 <1 1.25 NA <50 <1 6 NA <5 NA 275 692 <5 NA 6.4 1.47 NA NA 17 <0.2 75 NA NA NA NA NA NA NA GW -1 07/10/2014 4.4 20.14 17 154 1.5 364 569 1.9 <1 1.61 NA <50 <1 7.1 NA <5 NA 84 683 <5 NA 6.2 1.53 NA NA 24 <0.2 85 NA NA NA NA NA NA NA GW -1 11/04/2014 4.7 20.95 17 155 0.98 337 542 8.62 <1 <1 NA <50 <1 6.7 NA <5 NA 568 534 <5 NA 4.1 1.56 NA NA 27 <0.2 75 NA NA NA NA NA NA NA GW -1 04/07/2015 4.8 20.81 15 123 0.89 1 121 1 326 1 0.67 <S <1 <1 <50 <1 6.6 NA <5 4.71 15 507 <5 NA 3.2 1.6 1.09 NA 25 <0.2 83 NA NA NA NA NA NA NA GW -1 07/06/2015 4.8 20.58 19 137 1.1 263 468 4.99 <1 <1 <1 <50 <1 6.6 NA <5 4.76 101 551 <5 3 13 1.78 1.05 <5 35 <0.2 78 <0.3 NA NA NA NA NA NA GW -1 11/02/2015 5.2 20.55 17 115 1.4 541 746 0.8 <1 <1 <1 <50 <1 6.6 NA <5 3.79 26 397 <5 1.7 7.4 1.33 1.41 <5 27 0.21 67 <0.3 NA NA NA NA NA NA GW -1 12/09/2015 4.8 20.09 16 127 1.1 355 560 4.64 <0.5 0.94 0.23 <50 <0.08 6.7 1 1.2 5.6 <50 460 3.2 NA NA 1.7 <5 <5 24.5 <0.1 84 <1 L3 NA NA NA NA NA NA GW -1 01/18/2016 4.8 20.19 1 15 1 161 1.8 397 602 8.02 <1 <1 <1 <50 I <1 1 5.5 1 0.87 1.2 6.13 1 104 725 1 3.4 1 NA NA 1 1.53 1 1.13 1 <5 1 29 1 <0.2 82 <0.3 NA NA NA NA NA NA GW -1 04/05/2016 4.8 20.65 14 220 1.51 360 565 2.43 <1 1.26 <1 <50 <1 7.9 NA <5 6.92 141 1070 <5 7.3 32 2.32 1.13 <5 52 <0.2 120 10.3 NA NA NA NA NA NA GW -1 07/06/2016 4.8 20.46 22 180 0.55 366 571 2.78 <S <S <1 <50 <S 6.9 NA <5 5.06 29 668 <5 3.4 1562 2.17 1.32 <5 50 <0.2 120 <0.3 NA NA NA NA NA NA Total Count of Valid Samples (Including GW -i) 65 65 63 63 34 63 1 63 1 63 21 1 63 1 34 63 63 63 11 43 1 63 1 34 31 63 63 63 30 12 12 12 12 12 12 Transition Zone GW -01D 05/07/2015 5.4 20.66 19 63 0.38 75 280 7.3 <1 <1 <1 <50 <1 5 NA <1 7.77 951 369 2.5 NA NA <1 2.73 33 2.3 <0.2 35 0.451 NA NA NA NA NA NA GW -01D 05/28/2015 5.3 20.59 17 55 0.42 63 268 5.53 <1 <1 <1 <50 <1 5.3 NA <1 4.02 295 240 1.44 NA NA <1 2.52 29 2.9 <0.2 41 <0.3 NA NA NA NA NA NA GW -01D 09/02/2015 5.2 20.67 21 56 0.89 283 488 3.92 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA GW -011) 12/09/2015 5.3 20.19 16 37 2.3 208 413 0.12 <0.5 <0.5 <0.2 <50 <0.08 3.2 0.072 <0.5 1.7 72 72 1.3 NA NA <0.5 <5 24 1.3 <0.1 <2S <1 L3 NA NA NA NA NA NA GW -01D 01/18/2016 5.3 20.29 15 43 1.9 178 383 3.55 <1 <1 <1 <50 <1 4.2 0.091 <1 1.62 221 97 1.1 NA NA <1 2.09 25 1.4 <0.2 32 0.339 NA NA NA NA NA NA Total Count of Valid Samples (Including GW -1D) 13 13 11 11 11 11 11 11 7 11 11 11 11 11 0 0 11 11 11 11 11 11 11 3 3 3 3 3 3 Bedrock GW -0188 05/14/2015 7.0 23.71 19 162 2.42 57 <1 <1 <1 <50 <1 1.3 NA <1 <1 1780 93 <1 NA NA <1 6.02 84 8.5 <0.2 110 0.575 NA NA NA NA NA NA GW-01SR 05/27/2015 7.8 22.67 20 171 2.13 -211 <1 <1 <1 <50 <1 1.5 NA <1 <1 946 66 <1 NA NA <1 6.25 88 8.3 <0.2 110 1.08 NA NA NA NA NA NA GW-01BR 09/01/2015 9.0 22.61 19 186 0.6 -56 L6,24. NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA GW-01BR 12/09/2015 8.7 22.30 15 163 0.5 -191 <0.5 1.1 <0.2 <50 <0.08 1.7 <0.03 <0.5 <0.5 1100 56 <0.5 NA NA <0.5 8.33 98 3.7 <0.1 103 <1 L1 NA NA NA NA NA NA GW-01BR 01/18/2016 7.0 22.34 6 155 1 -81 <1 <1 <1 <50 <1 1.5 <0.03 <1 <1 1190 65 <1 NA NA <1 7.28 88 5.2 <0.2 110 0.317 NA NA NA NA NA NA Total Count of Valid Samples (Including GW-1BR) 14 1 13 13 13 13 1 13 13 11 13 13 13 13 13 1 O O 13 13 13 13 13 1 13 13 6 is 6 6 6 6 Prepared by: TDP Checked by: RBI Notes: Red text indicates samples not used in determination of provisional preliminary background threshold values (PPBTVs) - eliminated due to pH > 8.5 or turbidity >10 NTU or or pH and/or turbidity not measured u = Bold highlighted concentration indicates exceedance of the 15A NCAC 02L .0202 Standard, the IMAC, or the NC DHHS Screening Level for chromium VI. (Effective date for 15A NCAC 02L .0202 Standard and IMAC is April 1, 2013) = Value eliminated as outlier (through April 2016 analytical results) Spec Cond = Specific Conductance NA = Not analyzed umhos/cm = Micro mhos per centimeter Temp = Temperature NTU = Nephelometric turbidity unit pCi/I = picocuries per liter it = Feet NM = Not Measured mg/L = Milligram per liter DO = Dissolved oxygen NE = Not established Eh = Redox Potential S.U. = Standard Unit Deg. C = Degrees Celsius mV = Millivolts ORP = Oxidation -Reduction Potential ug/L = Microgram per liter ug/mL = microgram per milliliter mg - N/L = Milligram nitrogen per liter = NC DHHS Health Screening Level. < = Concentration not detected at or above the adjusted reporting limit * = Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. b = Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than SOX the concentration in the method blank. Analyte concentration in sample could be due to blank contamination. B2 = Target analyte was detected in blank(s) at a concentration greater than 1/2 the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. j = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. L3 = Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results may be biased high. L3 = Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias. Ml = Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable. S = Associated calibration check did not meet specified criteria. P:\Duke Energy Progress.1026\102. Asheville Ash Basin GW Assessment Plan\19.EG_CSASUP\Statistics\Stats Review_DEQ Request\FINAL BG Analytical thru 2019-09 plus GW -1 Page 3 of 3 a 0 0 0 0 N c\ -I O c -I 2,180 2,170 2,160 2,1 0 2,140 a) ,2 2,130 C O co N 2,120 W 2,110 2,100 2,090 CCB -01 CCB -Oz CB -3R —GW -01 CB -8 CB -1 and GW -1 are not influenced by basin dewatering. 21 2.08 ------ — — --- --- • • • • . Cove excavation early 2016 N _______________••''•••./_2,140.7 CB -2 -11.33 feet decrease in water level elevation b-0 a� N ON z,112.39 CB -3R - 8.7 feet decrease in water level elevation ------------------- 0 b-0 2,103.69 — — — — — — — — — — — — — — — — — — — - 3 (� CB -8 - Not influenced by 1982 basin ewatering O r-1 —1 r-1 N N N m m m d' dt C' k.0 l0 l0 l0 c -I c -I r -I N r -I ,--I O ,--I O ,--I O r-1 O r-1 —I r -I c -I r -I r-1 c -I ri ri ri ri ri ri —1 O O O O O O O O O O O O O O r -I r14 (V r4 r4 r1i r-4 N lV fV lV fV r1i N ('V ('V ('V ('V (V I'V O 1.0 r r m \ r -I t9 Ql M I, l0 M 00 O W 01 rir-1r-Ir-I \ \ r-1 \ \ \ \ \ 0 O fV O fV r-1 \ � r,r I�i r -I \ n r -I �t n r -I \ \ \ \ \ I" r -I I:zr r -I r -I O O rN-I O FIGURE 1-80 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 WATER ELEVATIONS TIME SERIES PLOT PHONE 864-421-9999 www.synterracorp.com COMPLIANCE BOUNDARY WELLS DRAWN BY: B.WILKER DATE: JULY2016 PROJECT MANAGER: T. PLATING ASHEVILLE STEAM ELECTRIC PLANT synGW ���� LAYOUT: 200 CP&L DRIVE \Duke Energy Progress.1026\102. Asheville Ash Basin [P,Assessment Plan\19.EG_CSASUP\FINALAshevil le ARDEN NORTH CAROLINA 28704 CSA Supp 1\Figures