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HomeMy WebLinkAboutNC0024406_Settlement Agreement Activity_20170918eDUKE �, ENERGY® Mr Jeff Poupart, Section Chief NC DWR Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 Dear Mr. Poupart, RECEIVEMCDEWWR SEP 222017 September 18, 2017 Water Quality Permitting Section Subject: Settlement Agreement activity Asheville and Belews Creek stations In accordance with Condition II. B of the September 29, 2015 Settlement Agreement between Duke Energy and the North Carolina Department of Environmental Quality, Duke Energy is required to implement accelerated groundwater remediation at the Asheville and Belews Creek stations. Plans have been developed and work is underway to comply with this requirement Duke anticipates a need to begin groundwater extraction in support of accelerated remediation in the fourth quarter of 2017 in order to comply with the agreement. It currently appears that this may occur before renewed NPDES permits will be finalized for either site Until NPDES permits can be finalized, Duke Energy request written concurrence of our previously discussed understanding that groundwater extracted for the purpose of complying with the terms of the subject agreement, can be routed to the ash basin system and/or released through permitted outfalls under existing NPDES permit coverage. This follows the approach in the Settlement Agreement, where discharge to either the ash basin or a permitted outfall is explicitly authorized/recognized at Sutton The release of this water will not significantly change the characteristics of the discharge and will not result in flow volumes in excess of volumes previously released. Maximum Design flows for extracted groundwater at Asheville are 0.1296 MGD. The well data that is most applicable for evaluation of what is to be extracted at Asheville is found in well EXT-Olon the attached. The design flows for the groundwater extraction system at Belews Creek are 0 072 MGD. The well data that is most applicable for evaluation of what is to be extracted at Belews is found in well cluster GWA-20 on the attached. Both the Asheville and Belews Creek systems can operate in a variable mode and will not operate if there is no yield in the well. If no permitting pathway for the release of extracted groundwater is allowed, Duke Energy's ability to implement expedited groundwater remediation at these sites will be materially impaired. Thank you for your attention to this request. If there are any questions about this matter, please contact me at (919)546-2439 or shannon.lanaley, a,duke-energy.com. Sincerely, E. Shannon Langley Lead Environmental Specialist Attachment Ce. Richard Baker w/attachment via email Joyce Dishmon/Filenet w/attachment via email Tina Woodward/Filenet w/attachment via email Anne Pifer Table 1-1 Summary of Select Constituent Analytical Data in Area of Interest Belews Creek Steam Station Duke Energy Carolinas, LLC, Belews Creek, NC Notes: Nrepareo Dy: tsuw l.necKeo: Uut * Analytical data provided by HDR, Inc. Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard. < = Concentration not detected at or above the reporting limit j = Indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. mg/L = Milligram per liter ug/L = Microgram per liter P:\Duke Energy Progress. 1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\Table 1-1 Data Summary AOI Page 1 of 1 Analytical Parameter Boron Chloride Selenium TDS Reporting Units ug/L mg/L ug/L mg/L 15A NCAC 02L Standard 700 250 20 500 Sample ID Sample Collection Date Analytical Results AB -1S 9/20/2016 14,900 458 8.4 1,260 AB -1D 9/20/2016 13,000 459 13.8 1,250 AB-1BR 5/13/2016 12,100 0.4 <5 1.1 GWA-1BR 9/28/2016 <50 2.9 <0.5 113 GWA-1D 9/22/2016 26.93 50.7 0.5 190 GWA-1S 9/21/2016 428 51.5 0.41 J 94 GWA-IOD 9/21/2016 <50 21.7 <0.5 228 GWA-10S 9/21/2016 84.2 66.1 31.8 153 GWA-11D 9/21/2016 69.4 203 <0.5 576 GWA-11S 9/21/2016 379 157 7.3 441 GWA-18D 9/21/2016 <50 7.9 <0.5 94 GWA-18S 4/27/2016 28 J 21.5 0.53 125 GWA-18SA 6/8/2016 112 56.6 0.71 169 GWA-19BR 9/26/2016 28.6 J 5.9 0.52 83 GWA-19SA 9/21/2016 1,880 202 36.8 379 GWA-19D 4/28/2016 <50 3 0.31 J 90 GWA-19S 5/11/2016 1,320 157 30.9 299 GWA-20SA 9/21/2016 11,300 486 3 1,240 GWA-20BR 6/20/2016 51 26.4 0.59 191 GWA-20D 9/21/2016 8,700 471 0.83 1,120 GWA-21D 9/21/2016 125 190 <0.5 545 GWA-21S 9/21/2016 126 150 6.3 267 GWA-27BR 6/16/2016 <50 6 <5 145 GWA-27D 6/16/2016 5,420 393 <5 990 GWA-27S 6/17/2016 155 51.9 5.8 108 GWA-30D 9/22/2016 <50 3.6 <0.5 146 GWA-30S 9/22/2016 <50 3.9 <0.5 48 GWA-31D 9/22/2016 <50 1.9 <0.5 97 GWA-31S 9/22/2016 <50 2.5 <0.5 <25 S-2 10/18/2016 236 74 <1 220 S-3 10/18/2016 <50 4.9 <1 120 S-4 10/18/2016 <50 82 <1 270 S-5 10/18/2016 <50 1 3.4 <1 120 Notes: Nrepareo Dy: tsuw l.necKeo: Uut * Analytical data provided by HDR, Inc. Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard. < = Concentration not detected at or above the reporting limit j = Indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. mg/L = Milligram per liter ug/L = Microgram per liter P:\Duke Energy Progress. 1026\20. BELEWS CREEK\04. CCP Accelerated Rem, Interim Action Plan - Design & Dev\30 PERCENT DESIGN\Table 1-1 Data Summary AOI Page 1 of 1 TABLE 2-2 BENCHMARK DATA ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ARDEN, NC r -Bold highlighted concentration indicates exceed..., of the 15A NCAC 02L Standard, Aspens,, 2, April 1, 2013. u -Bold 'n if concentration Indiutas exceed.... the 15A NUC 028/EPA Human Health Criteria, 2016(NC), 2016(EPA). Bold highlighted 111-11tion Indio,- exceed,... than the 15A NGC 02B/EPA Ecological Crit,.,, 2016(NC), 2016(EPA). Temp - Temperature ORP - Oxidation -Redd- Potential S.V. = Sundard Unit ..h. -on = Micro mhos per centimeter DIS - Dissolved mg - N/L = Milligram nitrogen per liter NE = Not establish. Spa, Cold = Specific Conduct — Eh - Redox Potential R = Fast mV = Millivolts TOT= Total ug/L = Miacyram per lhar NA = Not analyzed DO - D,,wl,,d oxygen DUP = Duplicate Deg C = Ogees CNllos NTU = Nephelomatim turbidity unit PCVI = pl—nea pe, In., mg/L =Milligram par liter NM - Not measure = NC 011115 Heaith Scuening Level. = Concentration not detected at or above the ,eportinq limit = interim Maximum Allowable C.ncentratians ([MAGI) of the 15A NGC 02L Standard, Appendix 1, April 1, 2013. B Target Inalyte detect. in method blank at or above the reporting limit. Ll - Analyte recovery In the laboratory control sample (LCS) was above QC limits. Results may be bias. high. B] - Target analyte detected In method blank at or above the ,p -ng limit T,ryet analyte...—t-- in —pl.was greater than 10X the concentration in the method blank. Analyte concentration in sample is not affected by blank .onUmination. L3 = Analyte ....very in the laboratory control sample (LCS) .,.d,d QC limits. Analyte pm..... below reporting limits in associated samples. Results unaffeded by high bias. 82 = Target analyte was detected in blank(,) at a conu.tmtio. gnat.. than 1/2 the reporting limit but lass than the reporting limit. Analyte concentration in sample is valid and may be used for.ompliance pu,p.— 41 = Mat.. spike recovery was high: the assauted laboratory Control Spike (La) was acceptable. CL =The continuing calibration for this compound is o,tilde of Pace Analytical acceptance limits. M2 - Malri. spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. CR = The dissolved metal result was gm,- than the total metal result for this element. R—R, were..nfirme by ra... lysis. M3 = Mat.. spike recovery was oots,de laboratory control limits due to nu 1. mtertemnces. D3 - Sample was dlluled due to the presence of high levels of non -target analytes or other matrix interference. Me - The spike mc,v value w,a unusable since the analyte concentration In the sample was disprop-I... te to the spike level. ) = indicates concentatm, mp—d! below Practical Quantitation Limit (PQL), hot above Method Detedion Limit (MDL) and lh—finned conuntration is estimate. NI = This sample was Inadvertently college wdh sample running through the Pow cell and should be considemd invalid baud on possible contamination from the flow cell. Hl = Analysis conducted outside the EPA method holding time. N2 = The lab does not hold accred Ration for this parameter. 5 = Assalatod calibration check did not meet specified crit,,,. .. �®®®®m®®®®®®®®®m■mmm®mmm®m.®mmmmmma®m®mm.®®m ��m•®a®mm�®o®aom®ommo®mommom®mm.om.momo�a®mm.mom ��m.m.®®®m®®mm.oom®ommmmm■ommmmm,mm.om.momi■v■m.®mm.mmm, ��®®mem•m®�®o®®om®ommomm■v�■mom®om.mm.mmmo®®®omom ��m•m.m■m.mm�®®m.m��ommommmmm■mmmmmm,mm.mm.mommm.®mm.mmm ��®m.mmmm�m.m.m•m■om.mommom®o®momm,mm.om.momom.m.momom ��®■�m�mm�m.m■m■mt�om.mommomm•o®mommsmm.om.moimo■m.m•momom ���m.m.m®mm®®mem•®om.mommom®om.mommamm.o®mmmo■®m.momom ��m.®mm•mm�m.mom■m■ommommom.®ommmamm.m.mmmmmm000mmo ��®mm®m®�m.m.®m•om.m.om.m.om.m.om.m.om.®mm.omm.m■�om.®®m.m.mm■ ��m•m.a�mmm®mo®m■om.mommomm.om.mom®mm.om.mmmom®m.m.mom ��m.m•m�mmm�m.®®m•o®mommomm.o®®mm®m®o®mmmo®®m.m.mom ��m•m•mmmmmm.mm®o®mo®mom®om.®om®mm.o®momom.®m.m.mom ��m.m.m��m�®m®®m•om.®ommomm.om.mom®mm.om.momo®®m.m.mom ��m■m.®m�mm®m.am®om.mommom®om.mom®mm.om.momomm•m.omo® ��m.m.®®mem®®mmmm.mommomm.©�■mommmm.o®momom.m•m.omom ��®m.mm•mm�®®ommommommmm.mmmmmomm.®mmmoomoommmo ��m■m.®®m®�m.am•m•mm.m.om.m.mm.m.om.m.om.msmm.mm.m.om•o®®m.m.m.om• ��m.m.am•m®�m®®m•om.mommomm•©m.mom®mm.om.momo®®m.m.mmm ��m.m.®®mm®m.®m•mmmmo®mmmm.o®mommom®om.�■omom.®m.m.mmm ��m.m.m®mm®m•am•mommommomm.om.mommsomom.momo®®m.�mom ��m.m.mm•m®�®®mmm®mo®mmmm.mmmommmm.mm.mmmmm.®m.�mmm ��m.m.o®®m®m.ammo®momm.omm•ommommmm.o�mmmo®m•momom ��m.m.m®m�mm.ammmm.momm.o®m.o®mommmm.mmmmmom.m•mm®mm• ��®®©®m®�m.®m•m•om.m.©m.m.o®m.om.m.om.m,m.m.omm.om.o®®mm.m.om• ��®®om•mm�m.am®mmmmmmomm.o®mom®mm.ommmmo®®m.m.m.mm• ��m.m.®msmm®®®m•oom.mommo®mo®oomm,moo�©omom.®m.m.mom ��m.m.®m,mm®®®m®mmmmom.omm•momommmm■ommmmommoomom ��®m.mm,mm�m.®m•oom.mommom.00®oom�mom�ommom.®m.m.00m ��®m.mm•mm®m®ommomm®oom.mmm.mo®m®mm®ommommm.mmo® ��m•m•®m•®mm®®0000mo®mo®mom.m©mamoom.00momo®omo® ��m•m•®®®mmm®mm0omm®mo®mm0m•ommm•mmm•ommommm•mmm® ��®m.®m•mm®m®000moo®oo®oom.omma®omm.ommmom®mom® ��®m.mm.mmmm®mmmomm®mo®mom.mmmm®oom.00mommmmmoo ��m.m.mm•mmmm®0000mo®momoo®oomomom®ommomo®moo® �� ®m.mm•mm®m.®mmmommmooamm®mmmmmmmommmmmmm•mmo® ��®m•mm•mm�m•m•®m•om•®o®mom•m•o®mm®®mm•om.momo®m•m•omom ��m•m.mm�mm®m.om•m■mm■m.mm•mmmm•mm.m•mm.m�mm.om.m.om•mm•®®m.mm® ��m.m•mm•mm�m•®m■m■m•m•®m•®®®®m•®m•®m•m•mam•m•om.momo®®m•m•m•o® .. ®®®�mmm®�®®®®mom®m•®m■m®®�®m®�®moo®® �o®®o®®�® ®®m®®m®m®®m®�mmommmm®�mmm®mm®®mmmm®mmmm®® m®®®©m®m®®®®mmm®m•mmm®®m•mm®mmm®m•mmmm®m•mm®® ��m.o®m•mm®m.moo0mmommommo®mmmommom.mommm,omm.mom ��mo®m•mm�®®m•mo�mommomm•ommoomamm•om•momomm•m•omom• ��m.omm•mm�®®m•mmmmommomm.mm•®mmmamm.om.®mmmm.m•m•mmom ��m•mmmmm�m®m•oo®mommommo®oommsmoom•oomo�m•m•omom ��m■omm•m®mm•®m•000momommmm®momm•mommommmm.m•m•000m ��m•mmm•mm�®®m•00000moomoo®omom•oomm•ommom•m•om.00m ���m®®®mmo®000®mommmmmo®mommmoom.00mmm•amomom ��mo®m,mmm®®000®mommomoom.ommamoom.ommom.o�omom ��®mmmsam®m.®mmoo®ommmm®om.mommom.m�mmmmm.m• omom ��mmmm�®®®®®o®ommommomm.om.momomm.o�mmmom.m•�so®om ��momm�®®®m®moommmmmmmoom.00mmmomm.ommo�m• omom ��m.momam®®m.®®oomoomoomoomomo®oom�ommom.m.�000m ��m.m®®mo®m.®mmommomommmom.mommmomm•oomom.m• omom ��m.om®®mm®moommmom.mom.momommomoom.mmmo®o0000m ��m.mam�m�®®®om®mom.00moom.omm®oomm.ommo�m.m.000m ��m.mem•oma®®mmoamomoommmmmmmmmoommmmom.m•m.omom r -Bold highlighted concentration indicates exceed..., of the 15A NCAC 02L Standard, Aspens,, 2, April 1, 2013. u -Bold 'n if concentration Indiutas exceed.... the 15A NUC 028/EPA Human Health Criteria, 2016(NC), 2016(EPA). Bold highlighted 111-11tion Indio,- exceed,... than the 15A NGC 02B/EPA Ecological Crit,.,, 2016(NC), 2016(EPA). Temp - Temperature ORP - Oxidation -Redd- Potential S.V. = Sundard Unit ..h. -on = Micro mhos per centimeter DIS - Dissolved mg - N/L = Milligram nitrogen per liter NE = Not establish. Spa, Cold = Specific Conduct — Eh - Redox Potential R = Fast mV = Millivolts TOT= Total ug/L = Miacyram per lhar NA = Not analyzed DO - D,,wl,,d oxygen DUP = Duplicate Deg C = Ogees CNllos NTU = Nephelomatim turbidity unit PCVI = pl—nea pe, In., mg/L =Milligram par liter NM - Not measure = NC 011115 Heaith Scuening Level. = Concentration not detected at or above the ,eportinq limit = interim Maximum Allowable C.ncentratians ([MAGI) of the 15A NGC 02L Standard, Appendix 1, April 1, 2013. B Target Inalyte detect. in method blank at or above the reporting limit. Ll - Analyte recovery In the laboratory control sample (LCS) was above QC limits. Results may be bias. high. B] - Target analyte detected In method blank at or above the ,p -ng limit T,ryet analyte...—t-- in —pl.was greater than 10X the concentration in the method blank. Analyte concentration in sample is not affected by blank .onUmination. L3 = Analyte ....very in the laboratory control sample (LCS) .,.d,d QC limits. Analyte pm..... below reporting limits in associated samples. Results unaffeded by high bias. 82 = Target analyte was detected in blank(,) at a conu.tmtio. gnat.. than 1/2 the reporting limit but lass than the reporting limit. Analyte concentration in sample is valid and may be used for.ompliance pu,p.— 41 = Mat.. spike recovery was high: the assauted laboratory Control Spike (La) was acceptable. CL =The continuing calibration for this compound is o,tilde of Pace Analytical acceptance limits. M2 - Malri. spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. CR = The dissolved metal result was gm,- than the total metal result for this element. R—R, were..nfirme by ra... lysis. M3 = Mat.. spike recovery was oots,de laboratory control limits due to nu 1. mtertemnces. D3 - Sample was dlluled due to the presence of high levels of non -target analytes or other matrix interference. Me - The spike mc,v value w,a unusable since the analyte concentration In the sample was disprop-I... te to the spike level. ) = indicates concentatm, mp—d! below Practical Quantitation Limit (PQL), hot above Method Detedion Limit (MDL) and lh—finned conuntration is estimate. NI = This sample was Inadvertently college wdh sample running through the Pow cell and should be considemd invalid baud on possible contamination from the flow cell. Hl = Analysis conducted outside the EPA method holding time. N2 = The lab does not hold accred Ration for this parameter. 5 = Assalatod calibration check did not meet specified crit,,,. P:\ Ouke Energy Pr.gma.1026\02ASHEVILLE PLANT\43.11—of Design Report & Modeling\Desig. Rpt (60)\Tzlies\Tabk 2-2 Benchmark D.—ls, Pal;.• 4 of 6 TABLE 2-2 BENCHMARK DATA ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ARDEN, NC -.1 hipht.ht.d concentatlon I —b—.cadnu a the SSA.CAC 021 Sunda., Appadl. 2, I'M 1, 2013. - Bold highlighted —1-1111W Indiutw wce.dan<e the ISA NGC 028/EPA Human Hulth C.wla, 2016(.[), 2016(EPA). O - Bold hlphliphud concatration Indiula acadanc. eh.. Me 15A NGC 026/EPA Ecobplul C,lttM., 2016(NC). 2016(EPA). Temp - T—p.r.tuu DRP - D,id.ton-Redbd,m Potential S.U. - Sunda. U'd umha/cm - Micro mha pw —ti— DIS - Disulved mp - N/L - Whip— ndre pw Idw Spw Coad - Sp.ci6c Conii.d. a Eh - Reda P-41 R - FM mV - MIIllvdh TOT- Taul up/L - Mli,"— par IN., DO - Dksulv.d e.yp.n DUP - Duplicau Deg C - Depress Cds4us M = N.ph.1him.t6c -likilty unN pCIA - plcpc.MM par Ilur "A = Milllgum pw Iitr - NC DHHS Hulth Scraping Leal. < - Concentration not detected at Dr atoll th, reporting 1 -ft - Intwim Maximum Allowable Cacentutions (IMAC.) a th. 15A NGC 021- Standard, Append,. 1, APMI 1, 2013. B = Target analyte d—OW In method blink at a above u, reporting limit. 01 - Targd analyte delated ,n method blink at 1, .b - the reporting IImA. Target analyte uncantr.tion in amp. was grater than 10% Ne cenuntratlon In the method blink. Malyte concentr.Uon in ample I. not 0... by blank conumina0on. B2 = T.rgd .alyt, was d.t.ated In blank(') at ncantralion gmltw than 1/2 Me reporting I,mlt but lea than the r.p.Ming IimR. Malyte concentration In sample is valid and may to lad for compliance purposes. CL = Th. centinuinq ollbralion for tM. comp d n Dobie. d Pace Aalytical .cc.phna. limas. CR - The diiIi metal resuh was grater than th. total maul resuk for —.lament. Results ane canfirmM by .aalyzis. D3 - Sample was diluted due to the pm—c, of high 1-1k of non-twgd.n.lytw or oth,r —d. 1—il ace. 1 - Indiuta cm ... tntbn reported baba Pre —i Quanett.tbn Llmll (PQL), but .bore M.hod Nl.ba Umit (MDL) and th—f—concentration Is estimated. Ml -Malys,. conducted —id. th. 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O - Bold hlphliphud concatration Indiula acadanc. eh.. Me 15A NGC 026/EPA Ecobplul C,lttM., 2016(NC). 2016(EPA). Temp - T—p.r.tuu DRP - D,id.ton-Redbd,m Potential S.U. - Sunda. U'd umha/cm - Micro mha pw —ti— DIS - Disulved mp - N/L - Whip— ndre pw Idw Spw Coad - Sp.ci6c Conii.d. a Eh - Reda P-41 R - FM mV - MIIllvdh TOT- Taul up/L - Mli,"— par IN., DO - Dksulv.d e.yp.n DUP - Duplicau Deg C - Depress Cds4us M = N.ph.1him.t6c -likilty unN pCIA - plcpc.MM par Ilur "A = Milllgum pw Iitr - NC DHHS Hulth Scraping Leal. < - Concentration not detected at Dr atoll th, reporting 1 -ft - Intwim Maximum Allowable Cacentutions (IMAC.) a th. 15A NGC 021- Standard, Append,. 1, APMI 1, 2013. B = Target analyte d—OW In method blink at a above u, reporting limit. 01 - Targd analyte delated ,n method blink at 1, .b - the reporting IImA. Target analyte uncantr.tion in amp. was grater than 10% Ne cenuntratlon In the method blink. Malyte concentr.Uon in ample I. not 0... by blank conumina0on. B2 = T.rgd .alyt, was d.t.ated In blank(') at ncantralion gmltw than 1/2 Me reporting I,mlt but lea than the r.p.Ming IimR. Malyte concentration In sample is valid and may to lad for compliance purposes. CL = Th. centinuinq ollbralion for tM. comp d n Dobie. d Pace Aalytical .cc.phna. limas. CR - The diiIi metal resuh was grater than th. total maul resuk for —.lament. Results ane canfirmM by .aalyzis. D3 - Sample was diluted due to the pm—c, of high 1-1k of non-twgd.n.lytw or oth,r —d. 1—il ace. 1 - Indiuta cm ... tntbn reported baba Pre —i Quanett.tbn Llmll (PQL), but .bore M.hod Nl.ba Umit (MDL) and th—f—concentration Is estimated. Ml -Malys,. conducted —id. th. EPA method holding time. P:\ Dtlbe Eriwgy Progress.1026\02.A.5HEVR.I.E PLA.N,T\U.B.sa If Deign Report & Mudding\ Deign Rpt (60)\Tabb\Tabk 2-2 Berth—A Deh..l'. NE Not at,bl,sned HA = Not .ea lY.ed NM = Not masured Ll - A 1. 1 recovery ,n the laboratory —blIl sample (LCS) was above QC I—, Results may be b,.sad kph. U = Malyte rwwery In the 1.1, tory contra ample (LCS) ucaded QC limits. Malyte preance below reporting limih in —c—d umpks. Results unaffected by high bus. MI = Matri.'Pik. ncovery was high: the .ssoci.ted Laboratory Control Spike (LCS) was wupuble. M2 - Matrll splke ncovery was Low: the .sswi.lId Laboratory Control Spike (LCS) oras .cc.phbh. M3 - M011I spike rwoyery was ouhb. laboratory control limits due to m.tri. inurhrencw. M. - Th. spike recovery value w.....able sin. the analyte concentration In the umple was diswoportbate to the dike Iwel. MI - This ample was inadvMently l*lbRed with sample running through the flow cdl and should It considered inv.11d bead on p*,kll* ..nhm,natbn frem the III, cell. M2 - The lab door not hold 111—ttull k, this par.metw. 5 . A..—d calibrathih chat did net meet .;I d critw,a. Prt ..d By JU Checked By'. 6Qy( TABLE 2-2 BENCHMARK DATA ASHEVILLE STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ARDEN, NC Prepared BY HER Checked BY AM flauu Bold hiphlipMed concentration indicates .zceedanca of the 15A NGC 03L Standab, Appendix 2. April 1, 2013. r� -Bold M1i9hllphted concentration mdiutes ...ehil,— the ISA NCAC 02B/EPA Human H.aleh [riled., 2016(W), 2016(EPA). Bold highlighted conuntration indicates ezceedanc< than the 15A NUC 02B/EPA Ecological Cnie-, 2016(NC), 2016(EPA). Temp • Temperature ORP . Oxklatlp-Reduction Potential S.U. • Standard Unit umhu/cm • Micro mhu per centimeter DIS . Diuelved mg - WL • MUligram nd,o n1, per liter NE = Not established Spec Cond • Spulfic Conductance Eh • Redox Potential R • Pelt mV • MlllwPh. TOT• Total ugfL ` Mc "— per In., NA •Not analysed DO • Dil," oxygen CUP • Dupliute Dep C • Degree Celli,, NRI • NephelpmeMc turbk Ny unit PCi/I . pkocurlin, per Mer meg/L • Mdllgram per Ilter Net •Not measured • NC DMMS Hwlth SI—mg Level. < . Ce,ce,tratlon not din—d .t P, b— be repowin9 limen • 1-1.1 Maximum Allow.bh Concentrat— (IMACI) el the 15A NCAC 02L Standard, Append,, 1, Ap611, 2013. B • Target analyte detected In methed blank A P, above the rp—lg limit LI • AnalYte recevery in Me Iaborat, ry control ample (I-CS)was above QC Iinn- Reewts m.y he biased high. BI - Taroat .milt. d. -.d In method Welk .1 or .Wove Me nep-in9 IImN. Target analyte...— r.tion in .amps was grater than 10%Me <once,tutlon In the method blank. Analyte conuntration in ample is not affected by blank centemin,hen. l3 . Analyte r.cov.ry In the laboulory toluol umpe (LCS) —.eh ed QC limits. Analyte prIhe.t. below ­—glimits In asuceted s.mphl. Result. unaNMed by 1,191, bias. B2 • T.N. analyte w.. detected In blank(.) at • conc.ntr.tide greeter Man 1/2 the ,p,M,g limit but leu the, the rportin9 limn. Analyte ce,canttelion In —pi, is valid and may Pit —d fm 1—ph.... purposes. MI • Metrix spike recovery was high'. Me associated IaWxalory Control S,Ik. (La)was ac—.bi.. CL • The untin1119 ullbieten for this compound h outeld. of Pace Analytical accptance Vette. M2 • M.W.spike recover, was Low In. associated laboratory Control Spike (LCS) wa. accptebl.. ter than e l medal melt for the mRpwere eleent. ulte confirmed by r.analYYs. CR • The di..dved metal rewk was graMfeta M3 =Matrix spike ncowry wes ..We laboratory ce,trel limos it.. to ..tri. ineM.re,c.s. D3 - Semple was diluted it.. to M. in,—. d high I..l. of nu-t.rpet analytes or he, maMz ihti 1.-- Me . The spike recovery value was unusable sets the an.lyt. concentr.tlon in the sampe was disprportbnate to the spike level. I • Ind— cencentntlon reported bebw Punka' Q.—eeten Umd (PQL), but above Method Detection Limb (MDL) and theretore --retie is estimated. NI •This sample was inadvertenth collected with ample ru nninp through the Row cell and shpts be tonsid—it invalid bawd en p—ibe contamination from the flow cell. Hl • Analysis conducted whW. the EPA method hokling time. N2 = The lab doe not hold accreditation for thi. p-— ­S = Asuciated uIib,.,.. check dig not met -IW criteria. 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April 1, 2013. r� -Bold M1i9hllphted concentration mdiutes ...ehil,— the ISA NCAC 02B/EPA Human H.aleh [riled., 2016(W), 2016(EPA). Bold highlighted conuntration indicates ezceedanc< than the 15A NUC 02B/EPA Ecological Cnie-, 2016(NC), 2016(EPA). Temp • Temperature ORP . Oxklatlp-Reduction Potential S.U. • Standard Unit umhu/cm • Micro mhu per centimeter DIS . Diuelved mg - WL • MUligram nd,o n1, per liter NE = Not established Spec Cond • Spulfic Conductance Eh • Redox Potential R • Pelt mV • MlllwPh. TOT• Total ugfL ` Mc "— per In., NA •Not analysed DO • Dil," oxygen CUP • Dupliute Dep C • Degree Celli,, NRI • NephelpmeMc turbk Ny unit PCi/I . pkocurlin, per Mer meg/L • Mdllgram per Ilter Net •Not measured • NC DMMS Hwlth SI—mg Level. < . Ce,ce,tratlon not din—d .t P, b— be repowin9 limen • 1-1.1 Maximum Allow.bh Concentrat— (IMACI) el the 15A NCAC 02L Standard, Append,, 1, Ap611, 2013. B • Target analyte detected In methed blank A P, above the rp—lg limit LI • AnalYte recevery in Me Iaborat, ry control ample (I-CS)was above QC Iinn- Reewts m.y he biased high. BI - Taroat .milt. d. -.d In method Welk .1 or .Wove Me nep-in9 IImN. Target analyte...— r.tion in .amps was grater than 10%Me <once,tutlon In the method blank. Analyte conuntration in ample is not affected by blank centemin,hen. l3 . Analyte r.cov.ry In the laboulory toluol umpe (LCS) —.eh ed QC limits. Analyte prIhe.t. below ­—glimits In asuceted s.mphl. Result. unaNMed by 1,191, bias. B2 • T.N. analyte w.. detected In blank(.) at • conc.ntr.tide greeter Man 1/2 the ,p,M,g limit but leu the, the rportin9 limn. Analyte ce,canttelion In —pi, is valid and may Pit —d fm 1—ph.... purposes. MI • Metrix spike recovery was high'. Me associated IaWxalory Control S,Ik. (La)was ac—.bi.. CL • The untin1119 ullbieten for this compound h outeld. of Pace Analytical accptance Vette. M2 • M.W.spike recover, was Low In. associated laboratory Control Spike (LCS) wa. accptebl.. ter than e l medal melt for the mRpwere eleent. ulte confirmed by r.analYYs. CR • The di..dved metal rewk was graMfeta M3 =Matrix spike ncowry wes ..We laboratory ce,trel limos it.. to ..tri. ineM.re,c.s. D3 - Semple was diluted it.. to M. in,—. d high I..l. of nu-t.rpet analytes or he, maMz ihti 1.-- Me . The spike recovery value was unusable sets the an.lyt. concentr.tlon in the sampe was disprportbnate to the spike level. I • Ind— cencentntlon reported bebw Punka' Q.—eeten Umd (PQL), but above Method Detection Limb (MDL) and theretore --retie is estimated. NI •This sample was inadvertenth collected with ample ru nninp through the Row cell and shpts be tonsid—it invalid bawd en p—ibe contamination from the flow cell. Hl • Analysis conducted whW. the EPA method hokling time. N2 = The lab doe not hold accreditation for thi. p-— ­S = Asuciated uIib,.,.. check dig not met -IW criteria. PA Duke E -W Pro9ress.IW02.ASHEVILU PLANEl43.11.els of Dog, Reput k Madding\ Lytsign Rpt (60)\ Tablo\T" 2-2 Benchmark L1te.xbx