NC0003425_Chemical Products and Company Identification_19991019

MAR -@9-2000 16:46 FROM POWELL MOUNTAIN LAE TO 11311354625'-�0 P.Bc
Asphalt MUtsr�, ince lAq�E
A t Ae wow
cvav*w
Shet Page
Data e
: 2
I Ra t erial Safety Rev.Date
10/19/99
�s
1. CSBMiCAL PRODUCT MW Coma= I XWrXZ%CATION
AAphalt XS terials, Zne.
5400 treat) 86th street
TnaianapoLis, IN 46268
C01ffA1iY CpptAM: Douglas A_ crozier
gpNg� >SR:
017)s75-4670
ffi4It666TG'Y�
CHEMTREC 1800)424-9300 28 hours
Safely office (317)97S-4674 office hours
Pit0VOCT UPOVE: HES fied
C�tTCAL JFA Y:� llSi lAMip4o3pzeum hydrocarbon and water
ZDV
gyvosyms :I HYDROCARBON EMULSIONS
2. comp bSir=CRfMEMSMATIC6 ON ING MS'S
CONCEKiRAT ION
pps LIMN PERCENT BY VOLLK
INGREDIENT NA►E
45 to 75
PETROLEUM RESIOUE5. PiiOPRIETARY
25 to 5b
WAY tR
D.Sto3
METAL TALLATE, PRWUTARY
wi i�tesidsia �ulsioas: Smulsif ied Petroleum residues are a
Potrole
complex mixture of Nigh molecular "eight hydrocarbons produced from crude
petroleum in suspensiop with water_ sition varies depending on the
e specifications of the final product.
source of crude and Lh
3- - RAZ*15 1Dg==yTCATZON
sm
mot emulsified hydrocarbons can cause thermal burns.
hermal burns-
equ
pHot emulsifed prr�ollongeO contact canacause irritationt
bOlas can causetand ddezmatitis_Fr enC or
P!MT2o"
Product has low order of acute oral toxicitY.
�aTanN
Vapors and F1im�Te �ane�3useirritation
dizziness naLsal
nausea,
real-story tract -
Extended exp

MAR -,09-2000 16:46 FROM POWELL MOUNTAIN LAB TO 1919546259_ P.0"r'
lia t1eria 1 S a f e t Da to Shea t Page: 2
Rev. Rate
�3 10/19/99
I 4. PIRST Am 3Mh3URES j
HHoott or, Cold material - Gently flush with large amounts of water_ Call a
physician immediately.
Holt Material - Gently flush with cool water. Call a physician
Cold Material - Remove emulsified hydrocarbons with waterless nand cleaner
and wash wiCh soap and water. If irritation occurs, call a physician_
ZHGBa ll0ii
If ingested, call a doctor immediately, and follow directions.
�Ai.A?Iozx
Move person to fresh air immediately. If not breathing give artificial
resuscitation. Immediately call a physician.
5 _ FRE PIQi{TIN6 D�ASViGS3
FAAkDtAHLE PROPER2IffiS�
PLASS OIIiT: N _A _ F
AOT02 ONz z35000ra 700
14NMR SX WSiVX LIiQIT (%),- N.A.
UPPER EXPLOSIVE LIMIT (9) : N.A_
i
RZTIRG[12S82Yi MMMA
Foam, Carbon Dioxide, Dry Chemical, and water Spray may all be suitable in
eztingdishing fires involving this product. Avoid using water streams to
prevent, frothing. Use water spray to cool exposed surfaces.
6. X�C1�ZNTAL RELEASE DOASUJtES
Stop source of leak. Eliminate sources of ignition. Contain by diking or
impouni4ing. Absorbents can be used to contain spill. After containment,
emulsified hydrocarbons can be collected for disposal. Advise authorities if
productl has entered a sewer or water source_ Assure conformity with local,
state. and federal governmental regulations for disposal.
. $A,=wNG AbID STORAGE
RAa3DLXM Am STOR&OR PRsac•-AVnPlis
When ophning covers and outlet cap on storage tanks, use faceshield and
gloves to avoid possible injury from pressurized resin. Hydrogen sulfide can
be generated and accumulated in storage tank3 and bulk transport
compartments- Stay upwind and vent storage hatches before unloading. Keep
heatingjunits and flues in storage tanks covered with at least 12 inches of
hydrocarbons. Do not overheat.
Sapty Container warning: Rmpty containers retain residue (liquid and/or
vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, FIELD, BRAZE, SOLDER,
DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER
S0URCES'OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
I a. =POS SE c0WM0LS/PRR50 [AL PROTECTION I
z;M6D78B1t33M CQ=Tko
Local or general exhaust reauired if in an enclosed area to remain below the
TLV.
EWFACE PLg=_—lIDDT
Safely goggles or chemical splash goggles if splashing is anticipated.

MAR -09-2000 16:46 FROM POWELL MOUNTAIN LAB TO 19195462550 P.0
Xataria1 5 a f a ty Data Sheet Page: 3
Rev. Date
RES 10/19/99
9. ="BU Z CONMOLS/FMSONAL PROTBCTTCN - continued
SICDsf PROTSCTxOiF
Oil impervious gloves, such as Neoprene, if frequent or prolonged contact is
expected.
RBsP ORY PH CTI
If high vapors are expected, use respirator approved for organic vapors.
Observe respirator protection factor criteria cited in ANSI 288.2 (1960)
Self contained breathing appararus should be used for fire fighting.
OTffitJGBMMAL PAOTDCTI(W
wear body covering clothes to avoid prolonged or repeated exposure_ Launder
before reuse.
'J. PBYSICAL MW CEMUCAL PROPSRTZ85
APRgAg"CS
Light Broom Liquid
M
Characteristic Petroleum odor
BASIC
3R0IL3XQ POM: 212 ° F
MMT IHG PO=T: N.A.'F
�i
VAPOPPXSSDR8: <lmm H9@77'F
VAPOR DMFSITY (AIR -.1) : a,. 0
SPBCZFIG MAVT?Y: 0.96-1.05
SOLIIHILZTY (H2O): Completely
p8: 10 '
10. STABILIW im RBACT1ViTY
STJOILITy- Stable
ZgCO�PATIHLF M�TSR3ALS
Strong Oxidizers
HAZARDOHS RN fMOSITZPM PRODUCTS
Fumes, Smoke, Carbon Monoxide, Hydrogen Sulfide, Sulfur Dioxide,
Aldehydes, and Hydrocarbons
HAZARDOUS POLMMIZXTION: Will not occur
II . TC a=o QZCAL nwo mmTION
1QsCSLLXiiBdaS TOXICOLOGICAL Iffi�OReOi?IOmi
HitUwmz The Internatioaal Agency for Research on Cancer has determined that
there is sufficient evidence far the carcinogenicity of extracts of
steam -refined bitumens, air -refined bitumens and pooled mixtures of steam -
and air -refined bitumens in experimental animals. )hydrocarbon emulsion
products, properly handled as outlined in this MSDS, are not expected to
cause cancer in humans_ Skin contact, breathing of mists, fumes, or vapors
sbould be reduced to a minimum to avoid any ill effects. Chronic health
effects would not be expected as long as good hygiene and proper safety
Precautions are practiced.

MAR -09-2000 16:47 FROM POWELL MOUNTAIN LAB TO 19195462590 P.09
Material S a f ety Data Sheet Page: 4
Bev. Date
� IO/19/99
.4y Emp AL IE8OI�TYDii
May cause fouling of macer_ blay be toxic to aquatic animals.
13. DZSPOSAL C=93 D13L4TLC=
Waste or co"aminated hydrocarbon is normally disposed in a special waste or
industrial landfill. Comsider recycling into pavement mixtures whenever
possible-
24.
ossible_
14. TRAXSPOVT nE rOftaTZon
PROPER S=PP3= BUIEt (Not considered a DOT -hazardous material)
SARI, TITZB IZI - XAZ'W CX.ASSES.- Acute Health Hazard
16. Oft numowm=I=
=?.a ARD HArM - HEATH- 1 Slight
• FIRB_ 0 Negligible
REACTIVITY: 0 Negligible
k=&=ONXRY WIPEL (OSBA)
N RNINC ;- AOT EKJ SIFIBD PETROLBUM RESIDUE
May produce minor burns on contact
hMDS ZD8NTMCliTICB CODE/YMISBS: o AMI -403
PREPARED BY: Douglas A_ lozier
P1 V u z [phone]
Rgmwam IO
Information supplied by ]Lathony 3. Kriech, Heritage Research Group
DISCLAUM Or X&UM2D AM 7IM33CD
Although reasonable care has been taken int the preparation of this document,
we extend no warranties and make no representations as to the accuracy or
c9ff9leteness of the information contained therein, and assume no
responsibility regardiAg the suitability of this information for the user's
intended purposes or for the consequences of its use_ Each individual should
make a determination as to the suitability of the information for their
particular purpose(s).
Asphalt Naterials, Inc.

MAR -0.9-2000 16:48 FROM POWELL MOUNTAIN LAB TO 19195462594 P.11
/lilt, 1 i pm Reseamh Gro
.,. WCVGGPOW CDl VWW 7901 W. Monis Street Indienapobs, IN 46231 USA
317-243-0811 a 4W2985 (FAX)
August 25, 1999
Mike Kelly, President
Asphalt Materials, Inc.
P.O. Box 68123
Indianapolis IN 46268
Dear Mike:
i
You asked me about reporting requirements for HES Binder under the Toxics Release Inventory
(W. HES'Binder contains no compounds reportable under TRI.
Sin 1y,
'Anthony _ h
Director Of Research
AJK/ckc

MAR -N9-2000 16:48 FROM POWELL MOUNTAIN LAB TO 19195462590 P.is
7901 W Morris Street
317-243-0811
Mike Kelly, President
Asphalt Materials, Inc.
5400 W. 86* Street
P.O. Box 68123
Indianapolis, IN 46268-0123
Dear Mike.'
• IndiargpoGs, IN 46231 USA -
4W2985 (FAX)
October 11, 1999
Please finds, enclosed the information you requested on HES Emulsion produced at Asphalt
Materials, Inc. at Elizabethtown, Kentucky. Included with this letter are the leachability studies
conducted on HES. I have also included sulfur forms.
l3ES Emntsion
By weight
Sulfur Forms Organic Sulfur (Thiophenes)
0.770/6
Sulfur Forms Other Organic Sulfur (Sulfones)
0.04%
Total Sulfur
0.81%
I hope this information is helpful. Please let me know if there is anything else.
S irIC y
Anthony(l,�riech
AJK/ckc
Enclosures

MAR -09-2000 16:48 FROM POWELL MOUNTAIN LAB
TO 19195462590 P.14-
Heritage
.la
Heritage Research GrouR
7801 W. Monis Street D Indianapolis, IN 46231 U.S.A.
317-243-0811 0 485-2985 (FAX)
LEACHABILITY
OF
HES EN LSION
September 30, 1999
Anthony J. Kriech

MAR -09-2000 16:49
Introduction
FROM POWELL MOUNTAIN LAB TO 19195462590 P.1c
Heritage Research has completed a study of leachability of HITS Emulsion from Asphalt
Materials, Inc. (AMID Elizabethtown, Kentucky.
This product is used as a coal binder.
Sampling and Analytical
HES Emulsion was obtained from AMI in Elizabethtown, Kentucky. This product is a coal
binder emulsion. The emulsion residue was submitted for the following tests to our commercial
laboratory Heritage Environmental Services, LLC in Indianapolis, Indiana, USA, an EPA
certified laboratory. The test methods used in this evaluation are listed below;
Test Mcthods
Test
Method/Procedure
TCLP Procedure
SW 846-1311
Volatiles
SW 946-8240
Semi -Volatiles 0C/MS
SW 846-3510
Polynuclear Aromatic Hydrocarbons
SW 846-8310
Metals
SW 846.3010
The leachate results on metals are summarized in Table A. The leachate volatiles are listed in
Table B. The leachate semivolatiles are listed in Table C. The polynuclear aromatic compounds
(PACs) are presented in Table D_
TABLE A
TCLP for Metals (mo)
Description
PetroTsc
Det Limit
BARIUM
BDL
0.05
CADMIUM
BDL
0.05
CHROMIUM
BDL
0.05
LEAD
BDL
025
SILVER
BDL
0.05
ARSENIC
BDL
0.05
SELENIUM
BDL
0.05

MAR -09-2000 16:49 FROM POWELL MOUNTAIN LAB
TABLE B
Volat& Orgmica (451L)
TO 19195462590 P. i_
Description
PetmTac
Det. Li®it
BENZENE
BDL
50
C.AR13ON TETRACHLORIDE
BDL
50
CHLOROBENZENE
BDL
50
CHLOROFORM
BDL
50
1,2-DICH%OROETHANE
BDL
50
1,1-DICHLOROETHYLENE
BDL
50
Nffi- 'HYL ETHYL KETONE
BDL
100
TETRACHLOROETHYLENE
BDL
50
TRICHLOROETHYLENE
BDL
50
VINYL CHLORIDE I
BDL
100
TABLE C
TCLP Sem%Volati3e Ownks 4LF)L)
Description
PetroTac '
Det. Limit
1,4 -DICHLOROBENZENE
IHEXACHLOROBENZENE
BDL
50
2,4-DI4ITROTOLUENE
BDL
50
BDL
50
HEXACBLOROBUFADIENE
BDL
50
HEXACHLOROETHANE
BDL
50
NITROBENZENE
BDL
50
PYRIDINE
BDL
250
2 -METE -[YL PHENOL
BDL
50
3 -METHYL PHENOL
BDL
50
4-METIM PHENOL
BDL
50
PENTACHLOROPHENOL
BDL
250
.2,4,5 -TRICHLOROPHENOL
BDL
50
2,4,6 -TRICHLOROPHENOL
BDL
50

MAR•709-2000 16.49 FROM POWELL MOUNTAIN LAB TO 19195462590 F.1 -
TABLE D
Potynndear Aromatic Hydrocarbons by HPLC (JAWL)
Description
Pet4r+aTac
Det. Limit
NAPHTHALENE
IFLUORENE
BDL
50
ACENAPHTHYLENE
BDL
50
ACENAPHTHENE
BDL
50
BDL
50
PHENANTHRENE
BDL
50
ANTHRACENE
BDL
50
FLUORANTHENE
BDL
50
PYRENE
BDL
50
BENZ (A) ANTHRACENE
BDL
50
CHRYSENE
BDL
50
BENZO (B) FLUORANTHENE
BDL
50
BENZO (K) FLUORANTM&
BDL
50
BENZO (A) PYRENE
BDL
50
DIBENZO (A,H) ANTHRACENE
BDL
50
BENZO (G,H,I) PERYLENE
BDL
50
INDENO (1,2,3 -CD) PYRENE
BDL
50
Comments
1. No metals leached above the detection level.
2. No volatiles were found in the leachate above the detection level_
I The semi -volatiles were not found above the level of detection
4. "lice PACs were not found above the level of detection
Conclusions
This study found that HES Emulsion residue had no leachable compounds of concern above the
limit of detection. Based on this testing, HES Emulsion properly used would not be expected to
leach measurable compounds of concern.
This study does not preclude the need to use good engineering practices in locating and storing
HES Emulsion. HES Emulsion should not be stored near bodies of water without secondary
containment because liquid emulsions are water miscible before reacting with coal. Liquid
emulsions can foul water supplies temporarily. Proper use of HES Emulsion should provide an
environmentolly safe material for coal applications.