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Home My WebLink AboutNC0005088_Submittal of Analytical Results_20170815DUKE ENERGY® Julie Grzyb, Supervisor Complex NPDES Permitting Unit NC Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 August 15, 2017 RECEIVED/NCDEQ/DWR AUG 17 2017 Water Quality Permitting Section Subject: Submittal of analytical results AOW's identified during Spring evaluation Duke Energy Facilities Duke Energy has completed the Spring 2017 semi-annual Area of Wetness (AOW) inspections at it NC facilities. As required in the Plan for Identification of New Discharges (DIPs) for the various facilities, the spring inspections were completed during the months of April and May. In completing those inspections, new areas of wetness were identified at five of the inspected facilities. Follow-up AOW sampling occurred, where applicable, in accordance with the Standard Operating Procedure for Seep Sampling, prepared by Duke Energy (March 24, 2016). Specific details for the five sites with newly identified AOW's are provided below along with attached analytical results for any AOW's with enough flow to be sampled. Rogers Energy Complex (Cliffside), NC0005088 - Reported to NCDEQ on April 19, 2017. Two AOWs, with coordinates, reported as Areas C and D. Area C was sampled (analytical results attached). Area D could not be sampled at the time of the inspection due to insufficient flow. Cape Fear (NC0003433)- Reported to NCDEQ on April 25, 2017. Four AOWs, with coordinates, reported as Areas A, B, C and D. Due to insufficient flow, none of the four AOWs could be sampled during the inspection. Belews Creek Steam Station (NC0024406)- Reported to NCDEQ on May 17, 2017. One new AOW, with coordinates, was initially reported as Area AA. Area AA was changed to a S-16 designation and was sampled (analytical results attached). Riverbend (NC000496I)- Reported to NCDEQ on May 18, 2017. One new AOW, with coordinates, was reported as S-23. S-23 could not be sampled at the time of the inspection due to insufficient flow. Roxboro Steam Plant (NC003425)- Reported to NCDEQ on May 23, 2017. Four AOWs, with coordinates, reported as AOWs S-20, S-21, S-22 and S-23. AOW S-21 was sampled (analytical results attached). The remaining three AOWs could not be sampled at the time of the inspection due to insufficient flow. Further information, relative to the new AOWs at Roxboro, was submitted to the Division of Water Resources on July 13, 2017 in support of its NPDES renewal application. Where applicable, requests for permit coverage have been made under appropriate signatory submittal. Should further discussions/submittals be required to address any permitting issues associated with the new AOWs and their respective NPDES permits please let us know. If there are any questions about this matter please feel free to contact me at (919) 546-2439 or shannon.langleyckduke-energy.com. Sincerely, E. Shannon Langley Lead Environmental Specialist Attachments Cc: Sergei Chernikov —DWR w/attachments via email Jeff Poupart — DWR w/attachments via email Chris Hallman — Duke Energy w/attachments via email Ross Hartfield — Duke Energy w/attachments via email Robert Wylie — Duke Energy w/attachments via email Joyce Dishmon — Duke Energy w/attachments via email Steve Cahoon — Duke Energy w/attachments via email Brad Loveland — Duke Energy w/attachments via email Lori Tollie — Duke Energy w/attachments via email Eurika Rogers/Filenet - Duke Energy w/attachments via email Attachment Analytical results from identified AOW's Spring 2017 evaluation Analytical lab DUKE E RGYa Analytical Laboratory Page 1of54 Order Number: Protect Name Customer Name(s) Customer Address Lab Contact Report Authorized By. (Signature) Program Comments: 13339 Hagers Ferry Road Huntersvllle, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone 980-875-5245 Fax 980-875-4349 Order Summary Report J17040410 101119al-iIWM0419�T �[��►��1 Ross Hartfield, Tim Hunsucker, Kathy Webb, Brandon Russo 573 Duke Power Rd Mad Code Clliffside Steam Station Mooresboro, NC 28024 Mary Ann Ogle Phone 980-875-5274 Mary Ann Ogle Date: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report Data Flags & Calculations: 4/28/2017 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading All results are reported on a dry weight basis unless otherwise noted Subcontracted data included on the Duke Certificate of Analysis is to be used as information only Certified vendor results can be found in the subcontracted lab final report Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative An estimation of the uncertainty of measurement for the results in the report is available upon request This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory Please contact the Analytical laboratory with any questions The order of individual sections within this report is as follows Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification - The Analytical Laboratory holds the following State Certifications North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005 Contact the Analytical Laboratory for definitive information about the certification status of specific methods Sample ID's & Descriptions: Analytical lab Page 2 of 54 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017012819 CLIFFSIDE 13 -Apr -17 930 AM Synterra S-18 2017012820 CLIFFSIDE 13 -Apr -17 11 30 AM Synterra Area C 2017012821 CLIFFSIDE 13 -Apr -17 1 20 PM Synterra S-31 2017012822 CLIFFSIDE 13 -Apr -17 3 20 PM Synterra S-19 2017012823 CLIFFSIDE 13 -Apr -17 3 45 PM Synterra S -19A 2017012824 CLIFFSIDE 13 -Apr -17 9 00 AM Synterra S-2 6 Total Samples Technical Validation Review Checklist: COC and pdf report are In agreement with sample totals 0 Yes ❑ No and analyses (compliance programs and procedures) All Results are less than the laboratory reporting limits ❑ Yes 0 No All laboratory QA/QC requirements are acceptable 0 Yes ❑ No Report Sections Included: ❑� Job Summary Report Sample Identification ❑d Technical Validation of Data Package ❑� Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Analytical lab Page 3 of 54 ❑� Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑� Chain of Custody ❑d Electronic Data Deliverable (EDD) Sent Separatel Reviewed By Mary Ann Ogle Date 4/28/2017 Analytical lab Certificate of Laboratory Analysis Page 4 of 54 This report shall not be reproduced, except in full Order # A7040410 Site S-18 Sample #: 2017012819 Collection Date 13 -Apr -17 9 30 AM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 20 Vendor Parameter Complete TLINN 5 NITRITE + NITRATE (COLORIMETRIC) 04/21/2017 16 13 BGN9034 Nitrite + Nitrate (Colonmetnc) < 0.2 mg-N/L 02 INORGANIC IONS BY IC EPA 300 0 04/21/2017 16 13 BGN9034 Chloride 43 mg/L 05 Fluoride < 0 5 mg/L 05 Sulfate 330 mg/L 5 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 04/21/2017 13 55 Vendor Parameter Complete EPA 200 7 04/21/2017 13 55 TOTAL RECOVERABLE METALS BY ICP 1 EPA 200 7 Aluminum (AI) 0 069 mg/L 0 005 Barium (Ba) 0 020 mg/L 0 005 Boron (B) 0.815 mg/L 005 Calcium (Ca) 962 mg/L M4 001 Iron (Fe) 1.20 mg/L 001 Magnesium (Mg) 331 mg/L M4 0 005 Manganese (Mn) 256 mg/L 0 005 Potassium (K) 502 mg/L 01 Sodium (Na) 547 mg/L 005 Total Hardness (Ca and Mg) 376 mg/L 019 04/20/2017 17 52 CWSPEN3 (CaCO3) EPA 200 8 Zinc (Zn) < 0.005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS CWSPEN3 1 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L. 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 14.9 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 02 DF Method Analysis Date/Time Analyst 1 EPA 1664B 04/24/2017 10 45 CJELLIO Vendor Method V SHEALY 20 EPA 353 2 04/20/2017 15 05 TLINN 5 EPA 300 0 04/21/2017 16 13 BGN9034 5 EPA 300 0 04/21/2017 16 13 BGN9034 50 EPA 300 0 04/21/2017 16 13 BGN9034 Vendor Method V SHEALY 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 7 04/21/2017 13 55 SLS2560 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 1 EPA 200 8 04/20/2017 17 52 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 5 of 54 This report shall not be reproduced, except In full Order # A7040410 Site S-18 Collection Date 13 -Apr -17 9 30 AM Sample #: Matrix 2017012819 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 6.50 SI Units 1 Field Work Temperature 17.0 °C 1 Field Work Specific Conductance 740 us/cm 1 Field Work Turbidity 09 NTU 1 Field Work Flow 00320 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 580 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17040410 Site Area C Sample #: 2017012820 Collection Date 13 -Apr -17 11 30 AM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) V SHEALY Vendor Parameter Complete 04/19/2017 13 11 TLINN NITRITE + NITRATE (COLORIMETRIC) EPA 300 0 04/21/2017 16 30 Nitrite + Nitrate (Colorimetric) 079 mg-N/L 001 INORGANIC IONS BY IC 1 EPA 300 0 04/21/2017 16 30 Chloride 26 mg/L 01 Fluoride < 0 1 mg/L 01 Sulfate 0.80 mg/L 01 MERCURY IN WATER - (Analysis Performed by Shealy Labs) EPA 200 7 Vendor Parameter Complete 1 EPA 200 7 TOTAL RECOVERABLE METALS BY ICP SLS2560 1 Aluminum (AI) 0 018 mg/L 0 005 Barium (Ba) 0 021 mg/L 0 005 Boron (B) < 0 05 mg/L 005 Calcium (Ca) 1.38 mg/L 001 Iron (Fe) 0.017 mg/L 001 Magnesium (Mg) 0 774 mg/L 0 005 Manganese (Mn) < 0 005 mg/L 0 005 Potassium (K) 1 57 mg/L 01 Sodium (Na) 3.02 mg/L 005 Total Hardness (Ca and Mg) 6.64 mg/L 019 EPA 200 8 04/20/2017 18 46 (CaCO3) 1 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS 04/20/2017 18 46 CWSPEN3 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) <1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) <1 ug/L. 1 Selenium (Se) <1 ug/L 1 Thallium (TI) Low Level < 0 2 ug/L B3 0 2 Analytical lab Page 6 of 54 DF Method Analysis Date/Time Analyst 1 EPA 1664B 04/24/2017 10 45 CJELLIO Vendor Method V SHEALY 1 EPA 353 2 04/19/2017 13 11 TLINN 1 EPA 300 0 04/21/2017 16 30 BGN9034 1 EPA 300 0 04/21/2017 16 30 BGN9034 1 EPA 300 0 04/21/2017 16 30 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 7 04/21/2017 13 30 SLS2560 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 1 EPA 200 8 04/20/2017 18 46 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 7 of 54 This report shall not be reproduced, except in full Order # A 7040410 Site Area C Collection Date 13 -Apr -17 11 30 AM Sample #: Matrix 2017012820 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst Field Parameters (certification not covered under DPAL certification) pH 5.20 SI Units 1 Field Work Temperature 15.0 °C 1 Field Work Specific Conductance 37.0 us/cm 1 Field Work Turbidity 0.4 NTU 1 Field Work Flow 0.0060 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 37 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except In full. Order # A7040410 Site S-31 Collection Date 13 -Apr -17 1 20 PM Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) EPA 1664B Vendor Parameter Complete Vendor Method NITRITE + NITRATE (COLORIMETRIC) V_SHEALY 1 Nitrite + Nitrate (Colorimetric) 0.07 mg-N/L 001 INORGANIC IONS BY IC 04/21/2017 16 47 BGN9034 1 Chloride 61 mg/L 1 Fluoride < 0.1 mg/L 01 Sulfate 70 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) SLS2560 Vendor Parameter Complete 04/21/2017 13 42 SLS2560 TOTAL RECOVERABLE METALS BY ICP EPA 200 7 04/21/2017 13 42 Aluminum (Al) 0.054 mg/L 0 005 Barium (Ba) 0.036 mg/L 0 005 Boron (B) 1.21 mg/L 005 Calcium (Ca) 403 mg/L 001 Iron (Fe) 0.027 mg/L 001 Magnesium (Mg) 7.65 mg/L 0 005 Manganese (Mn) 1.67 mg/L 0 005 Potassium (K) 339 mg/L 01 Sodium (Na) 12.0 mg/L 005 Total Hardness (Ca and Mg) 132 mg/L 019 CWSPEN3 1 (CaCO3) 04/20/2017 18 00 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS 1 EPA 200 8 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 02 Sample #: 2017012821 Matrix NPDES Analytical lab Page 8 of 54 DF Method Analysis Date/Time Analyst 1 EPA 1664B 04/24/2017 10 45 CJELLIO Vendor Method V_SHEALY 1 EPA 353 2 04/19/2017 13 12 TLINN 10 EPA 300 0 04/21/2017 16 47 BGN9034 1 EPA 300 0 04/21/2017 16 47 BGN9034 10 EPA 300 0 04/21/2017 16 47 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SL32560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 7 04/21/2017 13 42 SLS2560 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 1 EPA 200 8 04/20/2017 18 00 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 9 of 54 This report shall not be reproduced, except /n full Order # J17040410 Site S-31 Collection Date 13 -Apr -17 1 20 PM Sample #: Matrix 2017012821 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst Field Parameters (certification not covered under DPAL certification) pH 6.50 SI Units 1 Field Work Temperature 223 °C 1 Field Work Specific Conductance 380 us/cm 1 Field Work Turbidity 07 NTU 1 Field Work Flow 00010 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 290 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 10 of 54 This report shall not be reproduced, except in full Order # A7040410 Site S-19 Collection Date 13 -Apr -17 3 20 PM Sample #: Matrix 2017012822 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 16648 04/24/2017 10 45 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0 01 mg-N/L 001 1 EPA 353 2 04/19/2017 13 13 TLINN INORGANIC IONS BY IC Chloride 5.1 mg/L 05 5 EPA 300 0 04/21/2017 17 04 BGN9034 Fluoride < 0 1 mg/L 01 1 EPA 300 0 04/21/2017 17 04 BGN9034 Sulfate 38 mg/L 05 5 EPA 300 0 04/21/2017 17 04 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0 021 mg/L 0 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 Barium (Ba) 0 052 mg/L 0 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 Boron (B) 0 078 mg/L 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 Calcium (Ca) 397 mg/L 001 1 EPA 200 7 04/21/2017 13 46 SLS2560 Iron (Fe) 0 086 mg/L 001 1 EPA 200 7 04/21/2017 13 46 SLS2560 Magnesium (Mg) 170 mg/L 0 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 Manganese (Mn) 0 265 mg/L 0 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 Potassium (K) 279 mg/L 01 1 EPA 200 7 04/21/2017 13 46 SLS2560 Sodium (Na) 397 mg/L 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 Total Hardness (Ca and Mg) 169 mg/L 019 1 EPA 200 7 04/21/2017 13 46 SLS2560 (CaCO3) Zinc (Zn) < 0.005 mg/L 0 005 1 EPA 200 7 04/21/2017 13 46 SLS2560 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Arsenic (As) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Cadmium (Cd) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Chromium (Cr) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Copper (Cu) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Lead (Pb) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Molybdenum (Mo) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Nickel (Ni) 126 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Selenium (Se) <1 ug/L 1 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Thallium (TI) Low Level < 0 2 ug/L B3 02 1 EPA 200 8 04/20/2017 18 31 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 11 of 54 This report shall not be reproduced, except in full Order # A7040410 Site S-19 Collection Date 13 -Apr -17 3 20 PM Sample #: Matrix 2017012822 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 5.80 SI Units 1 Field Work Temperature 18.3 °C 1 Field Work Specific Conductance 286 us/cm 1 Field Work Turbidity 0.5 NTU 1 Field Work Flow 00020 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 210 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17040410 Site S -19A Sample #: 2017012823 Collection Date 13 -Apr -17 3 45 PM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 5 Vendor Parameter Complete TLINN 2 NITRITE + NITRATE (COLORIMETRIC) 04/21/2017 17 21 BGN9034 Nitrite + Nitrate (Colonmetnc) < 0.05 mg-N/L 005 INORGANIC IONS BY IC EPA 300 0 04/21/2017 17 21 BGN9034 Chloride 5.1 mg/L 02 Fluoride < 0.2 mg/L 02 Sulfate 83 mg/L. 2 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 04/21/2017 13 51 Vendor Parameter Complete EPA 200 7 04/21/2017 13 51 TOTAL RECOVERABLE METALS BY ICP 1 EPA 200 7 Aluminum (AI) 0.028 mg/L 0 005 Barium (Ba) 0.040 mg/L 0 005 Boron (B) 0.121 mg/L 005 Calcium (Ca) 64.9 mg/L 001 Iron (Fe) 0.287 mg/L 001 Magnesium (Mg) 238 mg/L 0 005 Manganese (Mn) 1.55 mg/L. 0 005 Potassium (K) 201 mg/L 01 Sodium (Na) 3.57 mg/L 005 Total Hardness (Ca and Mg) 260 mg/L 019 04/20/2017 18 38 CWSPEN3 (CaCO3) EPA 200 8 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS CWSPEN3 1 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 2.90 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L B3 02 Analytical lab Page 12 of 54 DF Method Analysis Date/Time Analyst 1 EPA 1664B 04/24/2017 10 45 CJELLIO Vendor Method V_SHEALY 5 EPA 353 2 04/20/2017 15 00 TLINN 2 EPA 300 0 04/21/2017 17 21 BGN9034 2 EPA 300 0 04/21/2017 17 21 BGN9034 20 EPA 300 0 04/21/2017 17 21 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 7 04/21/2017 13 51 SLS2560 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 1 EPA 200 8 04/20/2017 18 38 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 13 of 54 This report shall not be reproduced, except in full Order # A 7040410 Site S-1 9A Collection Date 13 -Apr -17 3 45 PM Sample #: Matrix 2017012823 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 640 SI Units 1 Field Work Temperature 17.2 °C 1 Field Work Specific Conductance 483 us/cm 1 Field Work Turbidity 1 37 NTU 1 Field Work Flow 00070 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 300 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 14 of 54 This report shall not be reproduced, except In full Order # J17040410 Site S-2 Collection Date 13 -Apr -17 9 00 AM Sample #: Matrix 2017012824 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 04/24/2017 10 45 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitnte + Nitrate (Colonmetnc) < 0.1 mg-N/L 01 10 EPA 353 2 04/19/2017 13 33 TLINN INORGANIC IONS BY IC Chloride 4.4 mg/L 05 5 EPA 300 0 04/21/2017 17 38 BGN9034 Fluoride < 0.5 mg/L 05 5 EPA 300 0 04/21/2017 17 38 BGN9034 Sulfate 180 mg/L 25 25 EPA 300 0 04/21/2017 17 38 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0 170 mg/L. 0 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 Barium (Ba) 0 031 mg/L 0 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 Boron (B) 0.445 mg/L 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 Calcium (Ca) 659 mg/L 001 1 EPA 200 7 04/21/2017 14 07 SLS2560 Iron (Fe) 135 mg/L 001 1 EPA 200 7 04/21/2017 14 07 SLS2560 Magnesium (Mg) 23.0 mg/L 0 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 Manganese (Mn) 1.69 mg/L 0 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 Potassium (K) 408 mg/L 01 1 EPA 200 7 04/21/2017 14 07 SLS2560 Sodium (Na) 473 mg/L 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 Total Hardness (Ca and Mg) 259 mg/L 019 1 EPA 200 7 04/21/2017 14 07 SLS2560 (CaCO3) Zinc (Zn) 0.005 mg/L 0 005 1 EPA 200 7 04/21/2017 14 07 SLS2560 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Arsenic (As) <1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Copper (Cu) <1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Lead (Pb) <1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Molybdenum (Mo) <1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Nickel (Ni) 815 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Selenium (Se) <1 ug/L 1 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Thallium (TI) Low Level < 0 2 ug/L B3 02 1 EPA 200 8 04/20/2017 19 17 CWSPEN3 Certificate of Laboratory Analysis Analytical lab y Page 15 of 54 This report shall not be reproduced, except in full Order # J17040410 Site S-2 Collection Date 13 -Apr -17 9 00 AM Sample #: Matrix 2017012824 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 670 SI Units 1 Field Work Temperature 14.5 °C 1 Field Work Specific Conductance 395 us/cm 1 Field Work Turbidity 294 NTU 1 Field Work Flow 00720 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 380 mg/L 25 1 SM2540C 04/20/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 5 mg/L 5 1 SM2540D 04/20/2017 10 00 MGIGANT Qualifiers: B3 Target analyte was detected in Continuing Calibration Blank (CCB) at a concentration greater than % the reporting limit, but less than the reporting limit M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level The associated Laboratory Control Spike recovery was acceptable Analytical lab Certificate of Laboratory Analysis Page 16 of 54 Th/s report shall not be reproduced, except /n full Order # J17040410 Level II QC Summary Q17040560 1664—SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Blank # 1 Parameter Measured Final Oil and Grease 0 LCS #1 Parameter Measured Final Oil and Grease 337 MS #1 Parameter Measured Final Oil and Grease 31 9 Units Dd RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL - Units Dd Spike % Recovery LCL UCL Qualifier mg/L 1 361673 933 78 114 - Parent Sample J17030191 -- 2017007594 Units Dd Spike % Recovery LCL UCL Qualifier mg/L 1 351426 88 78 114 - Antical lab Certificate of Laboratory Analysis Page 17 of 54 This report shall not be reproduced, except In full Order # J17040410 Level II QC Summary Q17040534 C NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00007 00007 mg-N/L 1 001 < 1/2 RDL - (Colorimetric) Blank # 2 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00011 -00011 mg-N/L 1 001 < 1/2 RDL - (Colorimetric) Blank # 3 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00001 -00001 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 4 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -00002 -00002 mg-N/L 1 001 < 1/2 RDL - (Colorimetric) Blank # 5 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00048 00048 mg-N/L 1 001 < 1/2 RDL (Colorimetric) LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 303 303 mg-N/L 10 301 101 90 110 (Colorimetric) LCS # 2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 301 301 mg-N/L 10 301 999 90 110 (Colorimetric) LCS # 3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 3 3 mg-N/L 10 301 996 90 110 - (Colorimetric) LCS # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 296 296 mg-N/L 10 301 982 90 110 - (Colorimetric) LCS # 5 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 306 306 mg-N/L 10 301 102 90 110 - (Colorimetric) Certificate of Laboratory Analysis Analytical lab y Page 18 of 54 This report shall not be reproduced, except in full Order # 717040410 Level II QC Summary Q17040534 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS #I Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 225 225 mg-N/L 10 25 954 90 110 (Colorimetric) MSD #1 Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 227 227 mg-N/L 10 25 961 90 110 0 84 - (Colorimetric) MS #2 Parent Sample J17040410 -- 2017012824 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 236 236 mg-N/L 10 25 972 90 110 - (Colorimetric) MSD # 2 Parent Sample J17040410 -- 2017012824 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 235 235 mg-N/L 10 25 967 90 110 051 (Colorimetric) MS #3 Parent Sample J17040387 -- 2017012687 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 346 0 346 mg -NIL 1 025 964 90 110 - (Colorimetric) MSD #3 Parent Sample J17040387 -- 2017012687 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 347 0 347 mg-N/L 1 025 965 90 110 00865 - (Colorimetnc) MS #4 Parent Sample J17040409 -- 2017012813 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 231 692 mg -NIL 30 75 966 90 110 - (Colorimetric) MSD #4 Parent Sample J17040409 -- 2017012813 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 231 692 mg-N/L 30 75 965 90 110 00867 - (Colonmetnc) MS #5 Parent Sample J17040409 -- 2017012814 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 228 228 mg -NIL 10 25 944 90 110 (Colorimetric) MSD # 5 Parent Sample J17040409 -- 2017012814 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 229 229 mg-N/L 10 25 94 9 90 110 0 569 - (Colorimetric) Analytical lab Certificate of Laboratory Analysis Page 19 of 54 This report shall not be reproduced, except in full Order # J17040410 Level II QC Summary Q17040534 C NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS 96 Parameter Measured Final Nitrite + Nitrate 0 234 468 (Colorimetric) MSD #6 Parameter Measured Final Nitrite + Nitrate 0 233 467 (Colorimetric) MS #7 Parameter Measured Final Nitrite + Nitrate 0 233 466 (Colorimetric) MSD #7 Parameter Measured Final Nitrite + Nitrate 0 233 465 (Colorimetric) MS #8 Parameter Measured Final Nitrite + Nitrate 0 235 1 18 (Colorimetric) MSD # 8 Parameter Measured Final Nitrite + Nitrate 0 235 1 17 (Colorimetric) Parent Sample J17040409 -- 2017012815 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 20 5 955 90 110 Parent Sample J17040409 -- 2017012815 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 20 5 953 90 110 0 171 Parent Sample J17040410 -- 2017012819 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 20 5 962 90 110 Parent Sample J17040410 -- 2017012819 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 20 5 961 90 110 0129 - Parent Sample J17040410 -- 2017012823 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 5 1 25 954 90 110 - Parent Sample J17040410 -- 2017012823 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 5 1 25 952 90 110 0 213 - Analytical lab Certificate of Laboratory Analysis Page 20 of 54 This report shall not be reproduced, except in full Order # J17040410 Level II QC Summary Q17040509 Dionex INORGANIC IONS BY IC Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration LCL Chloride 00466 00466 mg/L 1 01 < 1/2 RDL 25 125 Fluoride 00485 00485 mg/L 1 01 < 1/2 RDL 126 mg/L Sulfate 00136 00136 mg/L 1 01 < 1/2 RDL Sulfate 863 IS #I mg/L 25 125 101 80 120 039 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Chloride 577 144 mg/L 25 125 100 80 120 Fluoride 5 125 mg/L 25 125 99 80 120 Sulfate 861 215 mg/L 25 125 100 80 120 ISD # 1 IS #2 ISD # 2 LCS #1 Qualifier Qualifier Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 579 145 mg/L 25 125 101 80 120 0 271 Fluoride 503 126 mg/L 25 125 995 80 120 0 531 Sulfate 863 216 mg/L 25 125 101 80 120 039 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 778 15600 mg/L 2000 10000 102 80 120 - Fluoride 502 10000 mg/L 2000 10000 993 80 120 - Sulfate 568 11400 mg/L 2000 10000 100 80 120 - Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 778 15600 mg/L 2000 10000 102 80 120 00571 - Fluoride 502 10000 mg/L 2000 10000 994 80 120 00845 Sulfate 568 11400 mg/L 2000 10000 100 80 120 017 - Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 507 507 mg/L 1 5 101 90 110 Fluoride 497 497 mg/L 1 5 994 90 110 - Sulfate 504 504 mg/L 1 5 101 90 110 - lab Certificate of Laboratory Analysis Page2l1 of 54 This report shall not be reproduced, except in full Order # J17040410 Level II QC Summary Q17040440 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Blank # 1 Measured Final Units Dil Spike Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Aluminum (AI) -00011 mg/L 1 0 005 < 1/2 RDL Barium (Ba) -00009 mg/L 1 0 005 < 1/2 RDL Boron (B) -00002 mg/L 1 005 < 1/2 RDL Calcium (Ca) -00026 mg/L 1 001 < 1/2 RDL Iron (Fe) -00015 mg/L 1 001 < 1/2 RDL Magnesium (Mg) -0001 mg/L 1 0 005 < 1/2 RDL - Manganese (Mn) -00008 mg/L 1 0 005 < 1/2 RDL - Potassium (K) -00132 mg/L 1 01 < 1/2 RDL - Sodium (Na) -00068 mg/L 1 005 < 1/2 RDL - Zinc (Zn) -00004 mg/L 1 0 005 < 1/2 RDL - LCS # 1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 477 mg/L 1 5 954 85 115 Barium (Ba) 483 mg/L 1 5 966 85 115 - Boron (B) 496 mg/L 1 5 992 85 115 - Calcium (Ca) 497 mg/L 1 5 994 85 115 - Iron (Fe) 492 mg/L 1 5 985 85 115 - Magnesium (Mg) 495 mg/L 1 5 991 85 115 - Manganese (Mn) 482 mg/L 1 5 964 85 115 - Potassium (K) 474 mg/L 1 5 948 85 115 - Sodium (Na) 491 mg/L 1 5 983 85 115 - Zinc (Zn) 475 mg/L 1 5 95 85 115 - MS #I Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 528 528 mg/L 1 5 100 70 130 Barium (Ba) 511 511 mg/L 1 5 102 70 130 - Boron (B) 531 531 mg/L 1 5 103 70 130 - Calcium (Ca) 166 166 mg/L 1 5 110 70 130 - Iron (Fe) 729 729 mg/L 1 5 104 70 130 - Magnesium (Mg) 763 763 mg/L 1 5 101 70 130 - Manganese (Mn) 514 514 mg/L 1 5 101 70 130 - Potassium (K) 722 722 mg/L 1 5 101 70 130 - Sodium (Na) 131 131 mg/L 1 5 106 70 130 - Zinc (Zn) 489 489 mg/L 1 5 976 70 130 - MSD #1 Parent Sample J17040409 -- 2017012812 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Aluminum (AI) 4 89 489 mg/L 1 5 923 70 130 803 - Certificate of Laboratory Analysis This report shall not be reproduced, except In full Order # A 7040410 Level II QC Summary Q17040440 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Iua1.y W&I Parameter Measured Final Units Dil Spike Barium (Ba) 465 465 mg/L 1 5 Boron (B) 491 491 mg/L 1 5 Calcium (Ca) 156 156 mg/L 1 5 Iron (Fe) 673 673 mg/L 1 5 Magnesium (Mg) 713 713 mg/L 1 5 Manganese (Mn) 469 469 mg/L 1 5 Potassium (K) 673 673 mg/L 1 5 Sodium (Na) 123 123 mg/L 1 5 Zinc (Zn) 451 451 mg/L 1 5 MS #2 414 414 mg/L 1 5 Parameter Measured Final Units Dil Spike Aluminum (AI) 495 495 mg/L 1 5 Barium (Ba) 492 492 mg/L 1 5 Boron (B) 59 59 mg/L 1 5 Calcium (Ca) 102 102 mg/L 1 5 Iron (Fe) 613 613 mg/L 1 5 Magnesium (Mg) 383 383 mg/L 1 5 Manganese (Mn) 741 741 mg/L 1 5 Potassium (K) 101 101 mg/L 1 5 Sodium (Na) 107 107 mg/L 1 5 Zinc (Zn) 462 462 mg/L 1 5 MSD # 2 Parameter Measured Final Units Dil Spike Aluminum (AI) 444 444 mg/L 1 5 Barium (Ba) 439 439 mg/L 1 5 Boron (B) 526 526 mg/L 1 5 Calcium (Ca) 973 973 mg/L 1 5 Iron (Fe) 556 556 mg/L 1 5 Magnesium (Mg) 368 368 mg/L 1 5 Manganese (Mn) 681 681 mg/L 1 5 Potassium (K) 937 937 mg/L 1 5 Sodium (Na) 997 997 mg/L 1 5 Zinc (Zn) 414 414 mg/L 1 5 Analytical lab Page 22 of 54 Parent Sample J17040409 -- 2017012812 % Recovery LCL UCL RPD Qualifier 924 70 130 945 - 94 8 70 130 796 - 89 9 70 130 203 - 92 5 70 130 11 5 - 91 70 130 104 - 92 1 70 130 941 - 90 8 70 130 102 - 89 7 70 130 168 - 90 1 70 130 799 - Parent Sample J17040410 -- 2017012819 % Recovery LCL UCL Qualifier 976 70 130 979 70 130 102 70 130 114 70 130 985 70 130 - 105 70 130 - 97 70 130 - 101 70 130 - 105 70 130 - 92 4 70 130 - Parent Sample J17040410 -- 2017012819 % Recovery LCL UCL RPD Qualifier 874 70 130 11 873 70 130 114 - 88 9 70 130 134 - 23 2 70 130 132 - 87 1 70 130 123 - 74 5 70 130 338 - 84 9 70 130 133 - 86 9 70 130 149 - 90 1 70 130 149 - 82 7 70 130 11 1 - Analytical lab Certificate of Laboratory Analysis Page 23 of 54 This report shall not be reproduced, except in full Order # A7040410 Level II QC Summary Q17040449 IMS_TRM TOTAL RECOVERABLE METALS BY ICP -MS Blank # 1 Measured Final Units Dil Spike % Recovery Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Antimony (Sb) 0 009 0 009 ug/L 1 1 < 1/2 RDL - Arsenic (As) 0 017 0 017 ug/L 1 1 < 1/2 RDL - Cadmium (Cd) 0 002 0 002 ug/L 1 1 < 1/2 RDL - Chromium (Cr) -0008 -0008 ug/L 1 1 < 1/2 RDL - Copper (Cu) -0015 -0015 ug/L 1 1 < 1/2 RDL - Lead (Pb) 0 0 ug/L 1 1 < 1/2 RDL - Molybdenum (Mo) 0 012 0 012 ug/L 1 1 < 1/2 RDL - Nickel (Ni) -0017 -0017 ug/L 1 1 < 1/2 RDL - Selenium (Se) -0039 -0039 ug/L 1 1 < 1/2 RDL - Thallwm (TI) Low Level -0029 -0029 ug/L 1 02 < 1/2 RDL - LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 497 497 ug/L 1 50 993 85 115 - Arsenic (As) 493 493 ug/L 1 50 986 85 115 - Cadmium (Cd) 502 502 ug/L 1 50 100 85 115 - Chromium (Cr) 491 491 ug/L 1 50 982 85 115 - Copper (Cu) 497 49 7 ug/L 1 50 993 85 115 - Lead (Pb) 499 499 ug/L 1 50 997 85 115 - Molybdenum (Mo) 51 51 ug/L 1 50 102 85 115 - Nickel (Ni) 501 501 ug/L 1 50 100 85 115 - Selenium (Se) 49 3 49 3 ug/L 1 50 986 85 115 - Thallwm (TI) Low Level 48 2 48 2 ug/L 1 50 964 85 115 - MS #1 Parent Sample J17040409 -- 2017012815 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 493 49 3 ug/L 1 50 982 70 130 - Arsenic (As) 51 1 51 1 ug/L 1 50 978 70 130 - Cadmium (Cd) 485 485 ug/L 1 50 96 9 70 130 - Chromium (Cr) 486 486 ug/L 1 50 96 70 130 - Copper(Cu) 48 48 ug/L 1 50 947 70 130 - Lead (Pb) 502 502 ug/L 1 50 995 70 130 - Molybdenum (Mo) 573 573 ug/L 1 50 996 70 130 - Nickel (Ni) 51 3 51 3 ug/L 1 50 963 70 130 - Selenium (Se) 481 481 ug/L 1 50 954 70 130 - Thallium (TI) Low Level 466 466 ug/L 1 50 93 70 130 - MSD #1 Parent Sample J17040409 -- 2017012815 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 478 478 ug/L 1 50 951 70 130 3 21 -0 -It CULO a a 0 �I w 7 0 00 N_ O o d rn m v 00 rn n rn 0 o rn O CD JI O O O O O O O O O CD c,, U n � C:) C:) o o 0 0 0 � J C a r- m rn LO m CO rn r U O m m m m m m m CA m 0 Y O O O O O O O O O CO U') CO CO t0 Cfi l0 tf7 l0 ui ❑lrrrrrrrrr C m m m m m m m m m m r v v N co (o v- v U- v V� v v U m ti C� M U.) O CO CO (U d E E U E E NS dc 3 a) 0 N U E OEOJZJ O Q �U ^" o A m � L EI 4= CD �J N_ O C) O cqO CD J O O O O 1-:1 O 1-:1 O O O V 1 r 1 ro J C Q. 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Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention. Mary Ann Ogle Project Name Cliffside NPDES AOW Project Number J17040410 Lot Number SD14062 Date Completed 04/26/2017 Date Revised 04/26/2017 Grant Wilton Project Manager LABORATORY ACCREDITATION BUREAU N Q tiQ f \� � i .y4L5.��fYE�Ll.1°[IN35 This report shall not be reproduced, except In Its entirety, without the written approval of Shealy Environmental Services, Inc The following non -paginated documents are considered part of this report Chain of Custody Record and Sample Receipt Checklist Shealy Environmental Services, Inc Page: 1 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No 32010 NELAC No E87653 NC DENR No 329 NC Field Parameters No 5639 Case Narrative Duke Energy Lot Number: SD14062 Project Name: Cliffside NPDES AOW Project Number: J17040410 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented in the header information associated with each sample All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page REVISION 1 Shealy Environmental Services, Inc Page. 2 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: SD14062 Project Name: Cliffside NPDES AOW Project Number: J17040410 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017012819 Aqueous 04/13/2017 0930 04/14/2017 002 2017012820 Aqueous 04/13/20171130 04/14/2017 003 2017012821 Aqueous 04/13/20171320 04/14/2017 004 2017012822 Aqueous 04/13/20171520 04/14/2017 005 2017012823 Aqueous 04/13/20171545 04/14/2017 006 2017012824 Aqueous 04/13/2017 0900 04/14/2017 (6 samples) Shealy Environmental Services, Inc Page: 3 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: SD14062 Project Name: Cliffside NPDES AOW Project Number: J17040410 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017012819 Aqueous Alkalinity SM 2320B- 63 mg/L 5 001 2017012819 Aqueous Bicarbonate Alkalinity SM 2320B- 63 mg/L 5 001 2017012819 Aqueous Mercury (CVAFS) 1631E 0 595 ng/L 6 002 2017012820 Aqueous Mercury (CVAFS) 1631E 0 513 ng/L 8 003 2017012821 Aqueous Mercury (CVAFS) 1631E 347 ng/L 10 004 2017012822 Aqueous Alkalinity SM 232013- 130 mg/L 11 004 2017012822 Aqueous Bicarbonate Alkalinity SM 2320B- 130 mg/L 11 004 2017012822 Aqueous Mercury (CVAFS) 1631E 0 545 ng/L 12 005 2017012823 Aqueous Alkalinity SM 2320B- 180 mg/L 13 005 2017012823 Aqueous Bicarbonate Alkalinity SM 23206- 180 mg/L 13 005 2017012823 Aqueous Mercury (CVAFS) 1631E 0 673 ng/L 14 006 2017012824 Aqueous Alkalinity SM 23206- 81 mg/L 15 006 2017012824 Aqueous Bicarbonate Alkalinity SM 23206- 81 mg/L 15 006 2017012824 Aqueous Mercury (CVAFS) 1631E 0 557 ng/L 16 (14 detections) Shealy Environmental Services, Inc Page: 4 Of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SD14062-001 Description 2017012819 Matrix Aqueous Date Sampled 04/13/2017 0930 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1619 BWS 39707 1 (Bicarbonate ) SM 23208-2011 1 04/17/2017 1619 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1619 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 63 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 63 10 mg/L 1 Carbonate Alkalinity SM 23208-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-001 Description 2017012819 Matrix Aqueous Date Sampled 04/13/2017 0930 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 1946 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 0 595 0 500 ng/1- 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 6 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SD14062-002 Description 2017012820 Matrix Aqueous Date Sampled 04/13/2017 1130 Protect Name Cliffside NPDES AOW Date Received 04/14/2017 Protect Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1642 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1642 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1642 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page. 7 Of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page. 7 Of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-002 Description 2017012820 Matrix Aqueous Date Sampled 04/13/2017 1130 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2002 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 0 513 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 8 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-003 Description 2017012821 Matrix Aqueous Date Sampled 04/13/2017 1320 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1648 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1648 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1648 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 23208-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-003 Description 2017012821 Matrix Aqueous Date Sampled 04113/2017 1 320 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 04/20/20172008 COH 04/18/20171331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 347 0.500 ng/L 1 PQL = Practical quantitation limit 8 = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 10 Of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-004 Description 2017012822 Matrix Aqueous Date Sampled 04/13/2017 1520 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1654 BWS 39707 1 (Bicarbonate ) SM 23208-2011 1 04/17/2017 1654 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1654 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 130 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 130 10 mg/L 1 Carbonate Alkalinity SM 23208-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-004 Description 2017012822 Matrix Aqueous Date Sampled 04/13/2017 1520 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2013 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0.545 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result - PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page. 12 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-005 Description 2017012823 Matrix Aqueous Date Sampled 04/13/2017 1545 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 04/17/2017 1701 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1701 BWS 1 (Carbonate Al) SM 2320B-2011 1 04/17/2017 1701 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 180 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page- 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-005 Description 2017012823 Matrix Aqueous Date Sampled 04/13/2017 1545 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2018 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0 673 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page. 14 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Inorganic non-metals Client Duke Energy Laboratory ID SD14062-006 Description 2017012824 Matrix Aqueous Date Sampled 04/13/2017 0900 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/17/2017 1707 BWS 39707 1 (Bicarbonate ) SM 2320B-2011 1 04/17/2017 1707 BWS 1 (Carbonate AI) SM 2320B-2011 1 04/17/2017 1707 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 15 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab conn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 81 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 81 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 15 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab conn Mercury (CVAFS) Client Duke Energy Laboratory ID SD14062-006 Description 2017012824 Matrix Aqueous Date Sampled 04/13/2017 0900 Project Name Cliffside NPDES AOW Date Received 04/14/2017 Project Number J17040410 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/20/2017 2024 COH 04/18/2017 1331 39701 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 0.557 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page: 16 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn QC Summary Shealy Environmental Services, Inc QC Data for Lot Number: SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - MB Sample ID SQ39707-001 Matrix Aqueous Batch 39707 Analytical Method. SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 04/17/20171533 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of cntena Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number, SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Sample ID SQ39707-002 Batch:39707 Analytical Method SM 2320B-2011 Inorganic non-metals - LCS Matrix Aqueous Spike Amount Result % Rec Parameter (mg/L) (mg1L) Q Dill % Rec Limit Analysis Date Alkalinity 100 97 1 97 90-110 04/17/20171527 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - Duplicate SamplelD SD14062-001DU Matrix Aqueous Batch 39707 Analytical Method- SM 2320B-2011 Sample Amount Result % RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date Alkalinity 63 64 1 058 20 04/17/2017 1624 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number: SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MB Sample ID SQ39701-001 Matrix. Aqueous Batch -39701 Prep Method 1631E Analytical Method. 1631E Prep Date 04/18/2017 1331 Parameter Result Q DII PQL Units Analysis Date Mercury (CVAFS) ND 1 0 500 ng/L 04/20/2017 1831 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - LCS Sample ID- SQ39701-002 Matrix: Aqueous Batch:39701 Prep Method- 1631E Analytical Method: 1631E Prep Date: 04/18/2017 1331 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 500 471 1 94 75-125 04/20/2017 1836 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number- SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Sample ID- SD14062-001MS Batch 39701 Mercury (CVAFS) - MS Matrix Aqueous Prep Method 1631E Analytical Method 1631E Prep Date 04/18/2017 1331 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 0 595 500 491 1 86 71-125 04/20/2017 1951 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL += RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note. Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SD14062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) - MSD Sample ID: SD14062-001 MD Matrix: Aqueous Batch 39701 Prep Method: 1631E Analytical Method* 1631E Prep Date: 04/18/2017 1331 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 0 595 500 47 1 82 44 71-125 24 04/20/2017 1957 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL += RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number. SDI 4062 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com c) of (n N c $empleOesCNptlCrtOrID Cuabmorroca la nu rarrvc do?.vaa nsm Q c L _L .,n }• 0, (D iaD,y3 ?Daps m i'f�"�W 4rj .�� f�•r rl�-g y �" m Vi o '� [/, r -S` 1 In t q • g e U Greer N ..... _ - - - - 'Add Co&tY.UIkPPb ' CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM 23 n o 1 Duke Enefgy 1w�a1r..IMSsr,awanttuel A-1011,01Leboralary _ _ _ kt E^t*9Y AnYjtwal Lahmamry r Dn1 . Anil• Lzbomary Ord?f ii 1Lt Uaa OMV�- --- -• • _'- `---- --- - -- -- - n `. rV g o 3 r unnaarbP rrNPDE6 a,iS�al fly, -.,M I awtlon ID CiP5Locatiun _ so CaisrinnlnlprmaWn Delo j Cbwn o1 Cus:otly d SAfN%9 Loy '---_. .......�;. a c g.tra ITW!l768T8 �•..lN9ft!foae WWanr!%G 1119.11STis, %IJYfI� Qeq� - - ORIGINAL to LF SAwPLE PROGRAM S D''0�` 2 � cl) .. ._ _L-___ r+ry..,wM1 NPUES-aU'N - no�.�o lr --, ` ^� r1_ r:rtmylhx Lnil.v,%vs--_ WOES r uST_e +�'+,I-�, �''. •=nI--.'p Q`C7C VDi Client GJ474 J 5-f i r /� Fiflration (l) 45 UM] - y �yury 61f "J S LL 13:4 7C� ln�y $� Unfiilureti Ntri... Busmos3 Uoln "^'• :,a.la r< - O 0 - - - _ & n_•3C7Yat1Y0 .`rCa IN le8 ImHE- {}.0 J5-4- _ Na = E 3 r a.n,o, e.t,•ir a uu,tca• Cw"alnortlolurne CrALj 1250 20" Hd 3Qtl .." EJEL6 MEIrSUREMEN?S AO SOG N �'"• I ConhlRltr Teae HOSE fled „e, _ crr Z N 9 N c $empleOesCNptlCrtOrID Cuabmorroca la nu rarrvc do?.vaa nsm Q c L _L .,n }• a iaD,y3 ?Daps m i'f�"�W 4rj .�� f�•r rl�-g y �" m Vi o '� [/, r -S` 1 In t q • g e U Greer N ..... _ - - - - 'Add Co&tY.UIkPPb 0 I` I O L:1'c n `. rV g tag ane onto 1 I sa ID I awtlon ID CiP5Locatiun _ CaisrinnlnlprmaWn Delo -7 TIMM I �1 anut L S c - O � m , rn ^ Y I F I m !] O Z ,p Z a - 3� °i O I- QIG y w GJ474 J 5-f i r /� �yury 61f "J S LL 13:4 7C� ln�y x� Z� a��xFr + J . {}.0 J5-4- _ T -4 ` C� .." t. r 0 oa1-7 3 Z �3z� _(-Z2.3 X�t�-5 _Z°+ f5� f k`= GWa r I "r-- - — a w , E N 3 - o 3 t8 I I g Field olank —' Tnp Blank ,A ro aw �— Dalt£'env - vif� e! - Dawnrm -- 4 oDakM�me () J/7 r 3eakir /lr0(Y?uod 9y ELEAMEHT$ by ICP -MS Mieldlted•TRMJ, As, Cd, Cr, Cu.hNu, N4 P/ h, Sb, Ge ELEMENTS by ECP gDlpsted TMJ- A1, Ga. Ida, % fe, Mg, Mrt, K. Na, 2n F ty .-�-��1rf�i •� N c R�4aatcd Turnar par►{ .- Q �l��f iaD,y3 ?Daps �• �al,Trrj,11M r i'f�"�W 4rj .�� f�•r rl�-g y • v •0.9 Hr_ UatorE'uno +,!'1IL%1j a�0o Methad)TI Ilya lovell Total Rardr.oss g e U Greer coy Tan PLimsuckor Gn eltcel EDD result 'Add Co&tY.UIkPPb SHEALY ENVIRONMENTAL SERVICES, INC. Snead Cnvirurmzatal ServYciti, Inc Dcc.11McatNambcr, MIX0�BC°-08 Fqg ItfI Efecuve Dote, iF3i'9 X017 hyP -..V nmr as+a^02022 Sample Receipt Checklist (S1ltQ I � � Client:__ l�?Gf%c- � 1x:140 ConlcrInspectedbv/date: r {' ,r' Lot .9- 40 -t- Meansrifrecv-ipl: ❑ SESI 0i 1 n Client ❑ UPS ❑ FedEx Yes CI N0,40--custody-1^1, Were seals present an the cool arli Yres ❑ No a I NA ❑ 2. If custody seals we,e preseul, wcru they intact and unbroken? pH strip ID: Cl strip ID' Cooler 1DfOrigindl tcrnperailurc upon receipt -'De: ived (corrected) temperwtuce upon receipt: i f -"1 rl °C I tX v� tV GQC r 7C i aC Method: ❑ Temperature BlankiD Against Bottles IR Gun ID: lit Quji Correction Factor: Method ofwolat5t:,01VVct Ice CI iilue Wt. ❑ Dry Ice Oar- one G.L. jjFy .1 J No o NA ❑ 3. If temperanrre ofany coolere, ed i 6,17°C, �«s Project Manager Notified? I'M way Noftlied br: p houeGMail1'1=ace-to -face (circiconv.), *e C-5 © No NA 4. Is the commercial courier's pmhing,%lip attached to this forin? Ycs,ial- No r- 5. Were propc.'r custody procedures (relin rushed+received) followed? Yes pr NO ❑ 6. Were sarnplc 1Ds listed on the COC? Yes is -' No ❑ 7. "Nere sample ids lislud on all sample conminers? Yes C?� No ❑ S. Was collection date & time listed on the COC? Yes Nr, ❑ 9. Was collection date & time listed on all sample enrririncrs? V--Sw No ❑ 10. Did rill container label inf6miation (ID, date, time) agree with the CLIC? Yes No o 11. Were tests to be perfomied listed an the C'oC? Y %z �` Nn n 12. Did all samples ari ivy. in the proper containers for each test and,'ar in gcuad condition (unbroken, lids on, etc.)? Y' No ❑ 13. Was aJe,luutc sample volume available? Y't Nob 14. %Vere all sAmples received within Va aic bolding time or 48 bouts, %Nhichever comes first? Yes ❑ 1 No e-- .15. Wise any samples containers missinglexcess (circle one) samples riot hst.d on Coco Yes [I No ❑ NA -d- 16, Wdo bubbles present - "pen -size" ('l,"or Smm in (fiamctet} in any VOA vials? Y"cs ❑ No ID NA . 17 Were all DkO+nteWsMutricia hamples received at a pH of ` 2? Yc, C1 No ❑ NA V 18. Were all cyanidc samples taceived at n pH > 12 and sulfide samples received at rt pH =- 9? Ylts a No :1 NA ef'- 19. Were all applicable NHYI LNicyanidciphcnolBNA (E O,Stng,L) samples free of mAdual chlorine? Yes ❑ No ❑ ',NA!;),' 1 20. Werc collection temperatures documented on the COC for NC samples? Ycs 13 No 11 NA 21, it m, client tern3rkslrequescq (i_c, requested dilutions, MS: h4SD designfdinns, C tc..) corre tiv transcribed from the COC into the commont section in L1MS? Yes ❑ No n 2F.. Was the quote number u`cd taken from the container label? snrnple Preservation (Must bu cum lewd for any snmple(s) incorrect], preserved or %N�itli headspace,) Sarnplc(s) sample recrivin with werc received incorrzatly preserved and ware adjusted accardingly in H2SO4. HNOi, FIC'.1, NaOH) using SR # were rec-cived with bubbles z-6 nim in diameter.. Sanipltcs(s) _ wtirc received with TRC > 0.5 rn&L (Ir 921 i�% No) and •.acre ad'usted accordingly in sample receiving With sodium thiosulf3te (Na2SzfJy) with Shealy ID: SC Drinking %Vater Prc:jzct Sarnple(s) PH verified to be < 2 hV _ Dalc; Sam ple(s Wem Not received at a pl i of'-- 2 rind were adjusted accordingly 015111- sm Sample lebrls applied b � Verified by: Date: Conunenls. Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com --- - ---------_---------- Sampla Description or 10 CHAIN OF CUSTODY RECORD ANU ANALYSIS REQUEST FORM ------- ------ _ - 11 --- I- - - _._ - __ - - _.. Analytical lab Duke Energy i Duke Enetgy Aitatyww Labotatory j Analytical Labor4ituty Use Ottly i I Page 54 of 54 AnaWical Laboratory chain 01 cummay a S'Almole Lou M.M c� Manua J.%wd'.2 ?�j N C JW,17# INA147s"" i ;()fd*f N Matrix NPOES Losw 0 -00A time ! ! 117-fle I qJ141114 oqq SC SAN"Ite PRWRAM pa" CO —3- DISiRIBUT*N "!CMAL to LAS COPY WCUENT 130WA wow NMES i vendorI on_ ow"Waw_ LAST COC REV DATE stc" wasto .,11 E A LY PO 5021013 Firtration [0-45 um) tl Unfliftered -7 Pro.-Orvative lea i.0 I.. NA Container Volume (MLI 1250 2006 250 300 250 FIELD MEASUREMENTS 40 500 contalfwq type RDPE ptl PLT PL I 110pt Glass E LL (n Cs ;3 4u nn��vhadvd laces.. ;i 0 LL U W a CL — C ] ID W Callov"n btformalkm E 0 Doe Time ftnature 0 0 U Z 0.- Z CL I > Ja 2 2 Aq Ws7 1,4z, 0 0 Field Olank Inp Blank 2 :U TOTAL cunlon,w 1. �%q n K dat" botow 10W At yltj "Q ad '41 Wetted ofty R"Imquished 13YDsteMnw AccepteT. d 110DsIeMnie SO4MOCkOd By DxWTinm So*jedLLvk,5Pft*d 031 DatePTptte ELEMENTS by ICP -MS lbigostvd-TRM): As, Cd, Cr, Cts. Mb, NI, Pb, Sb, So 46RC Method) TI (low I*v*Q TOUI Hardness ELEMENTS try ICP f0,j9*nt(7r1TRM0- AI, Ca, 9a,B,Fe. M9,Mn, K,Na, Zn Please rnpy 'rim Hi rns k trkcw r n oxrtif FOD "LlIN 4 Sampla Description or 10 LAB UGE OWL v Localion 10 GPS Location 01:1115 WM_1 7__ Rif Q '14 Do" 0 z7- 1 9 7 Days E '48 Hr 0 ar '01tw Aod Cost WIl Apply 130WA wow NMES i vendorI on_ ow"Waw_ LAST COC REV DATE stc" wasto .,11 E A LY PO 5021013 Firtration [0-45 um) tl Unfliftered -7 Pro.-Orvative lea i.0 I.. NA Container Volume (MLI 1250 2006 250 300 250 FIELD MEASUREMENTS 40 500 contalfwq type RDPE ptl PLT PL I 110pt Glass E LL (n Cs ;3 4u nn��vhadvd laces.. ;i 0 LL U W a CL — C ] ID W Callov"n btformalkm E 0 Doe Time ftnature 0 0 U Z 0.- Z CL I > Ja 2 2 Aq Ws7 1,4z, 0 0 Field Olank Inp Blank 2 :U TOTAL cunlon,w 1. �%q n K dat" botow 10W At yltj "Q ad '41 Wetted ofty R"Imquished 13YDsteMnw AccepteT. d 110DsIeMnie SO4MOCkOd By DxWTinm So*jedLLvk,5Pft*d 031 DatePTptte ELEMENTS by ICP -MS lbigostvd-TRM): As, Cd, Cr, Cts. Mb, NI, Pb, Sb, So 46RC Method) TI (low I*v*Q TOUI Hardness ELEMENTS try ICP f0,j9*nt(7r1TRM0- AI, Ca, 9a,B,Fe. M9,Mn, K,Na, Zn Please rnpy 'rim Hi rns k trkcw r n oxrtif FOD "LlIN 4 Tool Requested Turnaround as 0 Q '14 Do" 0 7 Days E '48 Hr 0 ar '01tw Aod Cost WIl Apply Tool 0 0 0 0 0 0 0 Tool DUKE Analytical Laboratory Page 1 of 36 ENERGY, Order Number: Project Name Customer Name(s) Customer Address Lab Contact Report Authorized By (Signature) Program Comments: 13339 Hagers Ferry Road Huntersvllle, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone 980-875-5245 Fax 980-875-4349 Order Summary Report J17060014 BELEWS - NPDES - AOW Ross Hartfield, Tim Hunsucker,Chns Suttel, Chris Hallman, Kathy Webb, Brando 3195 Pine Hall Rd Mailcode Belews Steam Station Belews Creek, NC 28012 Mary Ann Ogle Phone 980-875-5274 Mary Ann Ogle Date: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report Data Flags & Calculations: 6/18/2017 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading All results are reported on a dry weight basis unless otherwise noted Subcontracted data included on the Duke Certificate of Analysis is to be used as information only Certified vendor results can be found in the subcontracted lab final report Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative An estimation of the uncertainty of measurement for the results in the report is available upon request This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory Please contact the Analytical laboratory with any questions The order of individual sections within this report is as follows Job Summary Report Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory OC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005 Contact the Analytical Laboratory for definitive information about the certification status of specific methods Sample ID's & Descriptions: Page 2 of 36 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017018245 BELEWS 31 -May -17 12 45 PM Daniel Youngblood S-16 2017018246 BELEWS 31 -May -17 1 50 PM Daniel Youngblood FIELD BLANK 2017018247 BELEWS 31 -May -17 1 50 PM Daniel Youngblood Trip Blank 3 Total Samples Technical Validation Review Checklist: COC and pdf report are in agreement with sample totals Yes ❑ No and analyses (compliance programs and procedures) All Results are less than the laboratory reporting limits ❑ Yes ❑� No All laboratory QA/QC requirements are acceptable 0 Yes ❑ No Report Sections Included: d❑ Job Summary Report Sample Identification Technical Validation of Data Package d❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 36 d❑ Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separatel Reviewed By Peggy Kendall Date 6/18/2017 Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17060014 Site S-16 Sample #: 2017018245 Collection Date 31 -May -17 12 45 PM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) EPA 1664B Vendor Parameter Complete Vendor Method NITRITE + NITRATE (COLORIMETRIC) V_SHEALY 1 Nitrite + Nitrate (Colonmetric) < 0.01 mg-N/L 001 INORGANIC IONS BY IC 06/02/2017 12 02 BGN9034 1 Chloride 2.0 mg/L 01 Fluoride < 0 1 mg/L 01 Sulfate 1.1 mg/L 01 MERCURY IN WATER - (Analysis Performed by Shealy Labs) MHH7131 Vendor Parameter Complete 06/12/2017 11 01 MHH7131 TOTAL RECOVERABLE METALS BY ICP EPA 200 7 06/12/2017 11 01 Aluminum (Al) 2.40 mg/L 0 025 Barium (Ba) 0.025 mg/L 0 005 Boron (B) < 0.05 mg/L 005 Calcium (Ca) 1.85 mg/L 001 Iron (Fe) 1 44 mg/L 001 Magnesium (Mg) 1.48 mg/L 0 005 Manganese (Mn) 0 033 mg/L 0 005 Potassium (K) 1.72 mg/L 01 Sodium (Na) 431 mg/L b2,b4, 005 Total Hardness (Ca and Mg) 10.7 mg/L 06/09/2017 16 42 CWSPEN3 1 (CaCO3) 06/09/2017 16 42 Zinc (Zn) 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS 1 EPA 200 8 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 02 Page 4 of 36 DF Method Analysis Date/Time Analyst 1 EPA 1664B 06/07/2017 09 45 CJELLIO Vendor Method V_SHEALY 1 EPA 353 2 06/07/2017 13 39 JASTOWE 1 EPA 300 0 06/02/2017 12 02 BGN9034 1 EPA 300 0 06/02/2017 12 02 BGN9034 1 EPA 300 0 06/02/2017 12 02 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 7 06/12/2017 11 01 MHH7131 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 1 EPA 200 8 06/09/2017 16 42 CWSPEN3 Certificate of Laboratory Analysis Page 5 of 36 This report shall not be reproduced, except in full Order # J17060014 Site S-16 Collection Date 31 -May -17 12 45 PM Sample #: Matrix 2017018245 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 7.30 SI Units 1 Field Work Temperature 20.0 °C 1 Field Work Specific Conductance 66.9 us/cm 1 Field Work Turbidity 35.4 NTU 1 Field Work Flow NM cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 59 mg/L 25 1 SM2540C 06/05/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 34 mg/L 5 1 SM2540D 06/02/2017 10 00 MGIGANT Certificate of Laboratory Analysis Page 6 of 36 This report shall not be reproduced, except in full Order # J17060014 Site FIELD BLANK Sample #: 2017018246 Collection Date 31 -May -17 1 50 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Method Analysis Date/Time Analyst Vendor Method V_SHEALY Site Trip Blank Collection Date 31 -May -17 1 50 PM Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17060014 Sample #: 2017018247 Matrix NPDES Page 7 of 36 Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY Qualifiers: 132 Target analyte was detected in Method Blank(s) at a concentration greater than '/z the reporting limit but less than the reporting limit Analyte concentration in sample is valid and maybe used for compliance purposes 134 Continuing Calibration Blank (CCB) is greater than Reporting Limit (RL) Certificate of Laboratory Analysis Page 8 of 36 Th►s report shall not be reproduced, except ►n full Order # A 7060014 Level II QC Summary Q17060122 1664—SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Blank # 1 Parameter Measured Final Oil and Grease 00923 LCS #1 Parameter Measured Final Oil and Grease 335 MS #1 Parameter Measured Final Oil and Grease 31 2 Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 357207 937 78 114 Parent Sample J17040194 -- 2017011694 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 330333 93 78 114 Certificate of Laboratory Analysis Page 9 of 36 This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060147 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00021 00021 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 2 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00026 00026 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 3 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00036 00036 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 4 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 00018 00018 mg-N/L 1 001 < 1/2 RDL (Colorimetric) LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 299 299 mg-N/L 10 301 992 90 110 (Colorimetric) LCS # 2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 299 299 mg-N/L 10 301 993 90 110 (Colorimetric) LCS #3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 297 297 mg-N/L 10 301 988 90 110 (Colorimetric) LCS # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 299 299 mg-N/L 10 301 994 90 110 (Colorimetric) MS #1 Parent Sample J17050155 -- 2017015216 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 311 0 311 mg-N/L 1 025 98 90 110 (Colorimetric) MSD #1 Parent Sample J17050155 -- 2017015216 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 312 0 312 mg-N/L 1 025 983 90 110 0 193 (Colorimetric) Certificate of Laboratory Analysis Page 10 of 36 This report shall not be reproduced, except in full. Order # J17060014 Level II QC Summary Q17060147 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS #2 Parameter Measured Final Nitrite + Nitrate 0 336 0 336 (Colorimetric) MSD #2 Parameter Measured Final Nitrite + Nitrate 0 324 0 324 (Colorimetric) MS #3 Parent Sample J17050777 -- 2017018040 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 1 025 103 90 110 Parent Sample J17050777 -- 2017018040 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 1 025 978 90 110 358 Parameter Measured Final Units Nitrite + Nitrate 0 245 0 245 mg-N/L (Colorimetric) MSD #3 Parameter Measured Final Nitrite + Nitrate 0 245 0 245 (Colorimetric) MS #4 Parameter Measured Final Nitrite + Nitrate 0 259 0 259 (Colorimetric) MSD #4 Parameter Measured Final Nitrite + Nitrate 0 259 0 259 (Colorimetric) Units mg-N/L Parent Sample J17060014 -- 2017018245 Dil Spike % Recovery LCL UCL Qualifier 1 025 96 90 110 Parent Sample J17060014 -- 2017018245 Dil Spike % Recovery LCL UCL RPD Qualifier 1 025 96 90 110 00408 - Parent Sample J17050190 -- 2017015339 Units Dil Spike % Recovery LCL UCL Qualifier mg-N/L 1 025 989 90 110 Parent Sample J17050190 -- 2017015339 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 1 025 99 90 110 0 116 Certificate of Laboratory Analysis Page 11 of 36 This report shall not be reproduced, except In full Order # J17060014 Level II QC Summary Q17060036 Dionex INORGANIC IONS BY IC Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration LCL Chloride 00329 00329 mg/L 1 0 1 < 1/2 RDL 1 5 Fluoride 00348 00348 mg/L 1 01 < 1/2 RDL 51 mg/L Sulfate 00045 00045 mg/L 1 01 < 1/2 RDL Sulfate 622 IS #1 mg/L 1 5 102 80 120 0 211 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Chloride 704 704 mg/L 1 5 100 80 120 Fluoride 509 509 mg/L 1 5 100 80 120 Sulfate 621 621 mg/L 1 5 102 80 120 ISD #1 IS #2 ISD #2 LCS #1 Qualifier Qualifier Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 704 704 mg/L 1 5 100 80 120 0 167 Fluoride 51 51 mg/L 1 5 101 80 120 0 329 Sulfate 622 622 mg/L 1 5 102 80 120 0 211 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 587 293 mg/L 5 25 103 80 120 Fluoride 518 259 mg/L 5 25 103 80 120 Sulfate 685 343 mg/L 5 25 102 80 120 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 59 295 mg/L 5 25 104 80 120 0 583 Fluoride 522 261 mg/L 5 25 103 80 120 0 719 Sulfate 69 345 mg/L 5 25 103 80 120 0 952 Parameter Measured Final Units DO Spike % Recovery LCL UCL Qualifier Chloride 499 499 mg/L 1 5 997 90 110 Fluoride 503 503 mg/L 1 5 101 90 110 Sulfate 497 497 mg/L 1 5 994 90 110 Certificate of Laboratory Analysis Page 12 of 36 This report shall not be reproduced, except in full Order # J17060014 Level II QC Summary Q17060212 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Blank #I Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Aluminum (AI) UCL Qualifier 00002 mg/L 1 0 005 < 1/2 RDL Barium (Ba) 0000242 0000242 mg/L 1 0 005 < 1/2 RDL Boron (B) -000943 -000943 mg/L 1 005 < 1/2 RDL Calcium (Ca) 000329 000329 mg/L 1 001 < 1/2 RDL Iron (Fe) 000192 000192 mg/L 1 001 < 1/2 RDL Magnesium (Mg) 00012 00012 mg/L 1 0 005 < 1/2 RDL Manganese (Mn) 000046 000046 mg/L 1 0 005 < 1/2 RDL Potassium (K) -00104 -00104 mg/L 1 01 < 1/2 RDL Sodium (Na) 00274 00274 mg/L 1 005 > 1/2 RDL b2,b4 Zinc (Zn) 000096 000096 mg/L 1 0 005 < 1/2 RDL LCS # 1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (AI) 479 mg/L 1 5 958 85 115 Barium (Ba) 49 49 mg/L 1 5 979 85 115 Boron (B) 489 489 mg/L 1 5 978 85 115 Calcium (Ca) 489 489 mg/L 1 5 978 85 115 Iron (Fe) 49 49 mg/L 1 5 979 85 115 Magnesium (Mg) 487 487 mg/L 1 5 973 85 115 Manganese (Mn) 49 49 mg/L 1 5 98 85 115 Potassium (K) 482 482 mg/L 1 5 964 85 115 Sodium (Na) 483 483 mg/L 1 5 965 85 115 Zinc (Zn) 49 49 mg/L 1 5 98 85 115 MS #1 Parent Sample J17060014 -- 2017018245 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Aluminum (Al) 564 282 mg/L 1 25 103 70 130 Barium (Ba) 503 503 mg/L 1 5 100 70 130 Boron (B) 501 501 mg/L 1 5 100 70 130 Calcium (Ca) 683 683 mg/L 1 5 998 70 130 Iron (Fe) 649 649 mg/L 1 5 101 70 130 Magnesium (Mg) 642 642 mg/L 1 5 988 70 130 Manganese (Mn) 504 504 mg/L 1 5 100 70 130 Potassium (K) 67 67 mg/L 1 5 995 70 130 Sodium (Na) 916 916 mg/L 1 5 971 70 130 Zinc (Zn) 5 5 mg/L 1 5 999 70 130 MSD # 1 Parent Sample J17060014 -- 2017018245 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Aluminum (AI) 532 266 mg/L 1 25 968 70 130 64 Certificate of Laboratory Analysis This report shall not be reproduced, except /n full Order # J17060014 Level II QC Summary Q17060212 ICP_TRM TOTAL RECOVERABLE METALS BY ICP MSD #1 Parameter Measured Final Units Dil Spike Barium (Ba) 475 475 mg/L 1 5 Boron (B) 464 464 mg/L 1 5 Calcium (Ca) 651 651 mg/L 1 5 Iron (Fe) 62 62 mg/L 1 5 Magnesium (Mg) 616 616 mg/L 1 5 Manganese (Mn) 476 476 mg/L 1 5 Potassium (K) 64 64 mg/L 1 5 Sodium (Na) 882 882 mg/L 1 5 Zinc (Zn) 472 472 mg/L 1 5 Qualifiers: Page 13 of 36 Parent Sample J17060014 -- 2017018245 % Recovery LCL UCL RPD Qualifier 945 70 130 584 929 70 130 766 934 70 130 663 953 70 130 595 937 70 130 532 945 70 130 575 936 70 130 615 903 70 130 73 943 70 130 575 B2 Target analyte was detected in Method Blank(s) at a concentration greater than 1/2 the reporting limit but less than the reporting limit Analyte concentration in sample is valid and maybe used for compliance purposes B4 Continuing Calibration Blank (CCB) is greater than Reporting Limit (RL) Certificate of Laboratory Analysis Page 14 of 36 This report shall not be reproduced, except In full Order # J17060014 Level II QC Summary Q17060220 IMS_TRM TOTAL RECOVERABLE METALS BY ICP -MS Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Antimony (Sb) -0033 -0033 ug/L 1 1 < 1/2 RDL Arsenic (As) 0 016 0 016 ug/L 1 1 < 1/2 RDL Cadmium (Cd) 0 013 0 013 ug/L 1 1 < 1/2 RDL Chromium (Cr) 0 031 0 031 ug/L 1 1 < 1/2 RDL Copper (Cu) -0028 -0028 ug/L 1 1 < 1/2 RDL Lead (Pb) 0 012 0 012 ug/L 1 1 < 1/2 RDL Molybdenum (Mo) 0 006 0 006 ug/L 1 1 < 1/2 RDL Nickel (Ni) -0029 -0029 ug/L 1 1 < 1/2 RDL Selenium (Se) 0 014 0 014 ug/L 1 1 < 1/2 RDL Thallium (TI) Low Level -0007 -0007 ug/L 1 0 2 < 1/2 RDL LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 48 9 489 ug/L 1 50 979 85 115 Arsenic (As) 494 494 ug/L 1 50 988 85 115 Cadmium (Cd) 502 502 ug/L 1 50 100 85 115 Chromium (Cr) 509 509 ug/L 1 50 102 85 115 Copper (Cu) 501 501 ug/L 1 50 100 85 115 Lead (Pb) 494 494 ug/L 1 50 98 8 85 115 Molybdenum (Mo) 50 4 504 ug/L 1 50 101 85 115 Nickel (Ni) 497 497 ug/L 1 50 994 85 115 Selenium (Se) 488 488 ug/L 1 50 977 85 115 Thallium (TI) Low Level 489 489 ug/L 1 50 979 85 115 MS #1 Parent Sample J17050090 -- 2017014781 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 505 506 ug/L 1 500 101 70 130 Arsenic (As) 51 4 514 ug/L 1 500 102 70 130 Cadmium (Cd) 485 485 ug/L 1 500 97 70 130 Chromium (Cr) 48 9 489 ug/L 1 500 975 70 130 Copper (Cu) 491 491 ug/L 1 500 978 70 130 Lead (Pb) 50 500 ug/L 1 500 999 70 130 Molybdenum (Mo) 253 2530 ug/L 1 2500 933 70 130 Nickel (Ni) 499 499 ug/L 1 500 989 70 130 Selenium (Se) 154 1540 ug/L 1 500 120 70 130 Thallium (TI) Low Level 461 461 ug/L 1 500 922 70 130 MSD #1 Parent Sample J17050090 -- 2017014781 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 48 480 ug/L 1 500 95 9 70 130 526 Certificate of Laboratory Analysis This report shall not be reproduced, except In full Order # J17060014 Level II QC Summary Q17060220 IMS_TRM TOTAL RECOVERABLE METALS BY ICP -MS MSD #1 Parameter Measured Final Units Dil Spike Arsenic (As) 489 489 ug/L 1 500 Cadmium (Cd) 461 461 ug/L 1 500 Chromium (Cr) 464 464 ug/L 1 500 Copper (Cu) 464 464 ug/L 1 500 Lead (Pb) 473 473 ug/L 1 500 Molybdenum (Mo) 244 2440 ug/L 1 2500 Nickel (Ni) 473 473 ug/L 1 500 Selenium (Se) 146 1460 ug/L 1 500 Thallium (TI) Low Level 445 445 ug/L 1 500 Page 15 of 36 Parent Sample J17050090 -- 2017014781 % Recovery LCL UCL RPD Qualifier 975 70 130 496 921 70 130 518 925 70 130 527 925 70 130 557 946 70 130 544 897 70 130 391 937 70 130 539 104 70 130 141 89 70 130 352 Certificate of Laboratory Analysis Page 16 of 36 This report shall not be reproduced, except In full Order # J17060014 Level II QC Summary Q17060061 TDS TOTAL DISSOLVED SOLIDS Blank # 1 Dil RDL Parameter Measured Final TDS 0 0 Blank # 2 Units Dil Parameter Measured Final TDS 0 0 Duplicate # 1 Parameter Measured Final TDS 140 140 Duplicate # 2 RPD Qualifier Parameter Measured Final TDS 53 53 Duplicate # 3 Parent Sample Parameter Measured Final TDS 140 140 LCS #1 1 Parameter Measured Final TDS 103 103 Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Parent Sample J17050329 -- 2017015953 Units Dil RPD Qualifier mg/L 1 0 717 Parent Sample J17050329 -- 2017015954 Units Dil RPD Qualifier mg/L 1 784 Parent Sample J17050329 -- 2017015955 Units Dil RPD Qualifier mg/L 1 1 42 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 100 103 90 110 Certificate of Laboratory Analysis Page 17 of 36 This report shall not be reproduced, except in full. Order # J17060014 Level II QC Summary Q17060035 TSS TOTAL SUSPENDED SOLIDS Blank #I Parameter Measured Final TSS 0 0 Blank # 2 Dil RDL Parameter Measured Final TSS 0 0 Duplicate # 1 Parameter Measured Final TSS 46 46 Duplicate # 2 RPD Qualifier mg/L Parameter Measured Final TSS 28 28 Duplicate # 3 Parent Sample J17050779 -- 2017018053 Parameter Measured Final TSS 28 28 LCS #1 Parameter Measured Final TSS 472 472 Units Dil RDL Relative Concentration mg/L 1 5 < 1/2 RDL Qualifier Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL Parent Sample J17040222 -- 2017011810 Units Dil RPD Qualifier mg/L 1 833 Parent Sample J17050779 -- 2017018053 Units Dil RPD Qualifier mg/L 1 0 Parent Sample J17050779 2017018054 Units Dil RPD Qualifier mg/L 1 194 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 944 90 110 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersvllle, NC 28078 Attention: Mary Ann Ogle Project Name. Belews Creek NPDES AOW Project Number J17060014 Lot Number SF02014 Date Completed 06/11/2017 Grant Wilton Project Manager LABORATORY +� ACCREDITATION B�UR(EA�Uq/�an@b�,d.Gi N��'ld LY3lY �i.Y S.kvli1Ji12: This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc The following non -paginated documents are considered part of this report Chain of Custody Record and Sample Receipt Checklist Shealy Environmental Services, Inc Page 1 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No 32010 NELAC No E87653 NC DENR No 329 NC Field Parameters No 5639 Case Narrative Duke Energy Lot Number SF02014 Project Name Belews Creek NPDES AOW Project Number J17060014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented In the header Information associated with each sample All results listed In this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed In accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies Any exceptions to the NELAC standards, the CAMP, SOPS or policies are qualified on the results page or discussed below If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Low Level Mercury Analysis - Method 1631 E Sample -001 The sample, MS and MSD were run straight and twice at an 8x dilution The maxtrix spike was recovered below the control limit in each of the three runs A blank was analyzed between the sample, the MS and MSD for the second 8X dilution run Shealy Environmental Services, Inc Page 2 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number SF02014 Project Name Belews Creek NPDES AOW Project Number. J17060014 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017018245 Aqueous 05/31/20171245 06/02/2017 002 2017018246 Aqueous 05/31/20171350 06/02/2017 003 2017018247 Aqueous 05/31/2017 1350 06/02/2017 (3 samples) Shealy Environmental Services, Inc Page 3 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com (3 detections) Shealy Environmental Services, Inc Page 4 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number SF02014 Project Name Belews Creek NPDES AOW Project Number J17060014 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017018245 Aqueous Alkalinity SM 23206- 17 mg/L 5 001 2017018245 Aqueous Bicarbonate Alkalinity SM 23206- 17 mg/L 5 001 2017018245 Aqueous Mercury (CVAFS) 1631E 645 S ng/L 6 (3 detections) Shealy Environmental Services, Inc Page 4 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SF02014-001 Description 2017018245 Matrix Aqueous Date Sampled 05/31/2017 1245 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/06/2017 1041 BWS 43560 1 (Bicarbonate ) SM 2320B-2011 1 06/06/2017 1041 BWS 1 (Carbonate Al) SM 2320B-2011 1 06/06/2017 1041 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2: MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a `W" S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 17 10 mg/L 1 Bicarbonate Alkalinity SM 23208-20 17 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2: MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a `W" S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SF02014-001 Description 2017018245 Matrix Aqueous Date Sampled 05/31/2017 1245 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 1631E 8 06/08/2017 1950 SLS 06/02/2017 2324 43419 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 645 S 400 ng/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W' S = MS/MSD failure Shealy Environmental Services, Inc Page 6 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SF02014-002 Description 2017018246 Matrix Aqueous Date Sampled 05/31/2017 1350 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 06/06/2017 2207 SLS 06/02/2017 2324 43419 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 7 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SF02014-003 Description 2017018247 Matrix Aqueous Date Sampled 05/31/2017 1350 Project Name Belews Creek NPDES AOW Date Received 06/02/2017 Project Number J17060014 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 06/06/2017 2211 SLS 06/02/2017 2324 43419 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cnteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W° S = MS/MSD failure Shealy Environmental Services, Inc Page 8 of 8 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com QC Summary Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - MB Sample ID SQ43560-001 Matrix Aqueous Batch 43560 Analytical Method SM 23208-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 06/06/2017 0917 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W° Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - LCS Sample ID SQ43560-002 Matrix Aqueous Batch 43560 Analytical Method SM 23208-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 98 1 98 90-110 06/06/2017 0924 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W' Note. Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791.9700 Fax (803) 791-9111 vvvvvv shealylab com Mercury (CVAFS) - MB Sample ID SQ43419-001 Matrix Aqueous Batch 43419 Prep Method 1631 E Analytical Method 1631E Prep Date 06/02/2017 2324 Parameter Result Q DO PQL Units Analysis Date Mercury (CVAFS) ND 1 0 500 ng/L 06/06/2017 2055 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - LCS Sample ID SQ43419-002 Matrix Aqueous Batch 43419 Prep Method 1631E Analytical Method 1631E Prep Date 06/02/2017 2324 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 500 493 1 99 75-125 06/06/2017 2104 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a °W" Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MS Sample ID SF02014-001MS Matrix Aqueous Batch 43419 Prep Method 1631E Analytical Method 1631E Prep Date 06/02/2017 2324 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q DO % Rec Limit Analysis Date Mercury (CVAFS) 645 400 338 N 8 68 71-125 06/08/2017 1955 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and a MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - MSD Sample ID SF02014-001MD Matrix Aqueous Batch 43419 Prep Method 1631 E Analytical Method 1631E Prep Date 06/02/2017 2324 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q DII % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 645 400 378 8 78 11 71-125 24 06/08/2017 1959 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W° Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SF02014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com oC C, CD d� � m d< m - � o o ID o� d < m m cD c(D m N n o n C 3 V) n to CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM I�__ Duko 9»rW Amlocal Lat-or*wry : yhlcwl tab�xito -the - -- - - I X11%dit �fleroy Pops t— of —S I An ticel LsSo "Ac i smo3 x is mmgTzo"t warm— Matrix NPD53m - T01ofY naniamma-ofjun �t "'"""�'s"r~� tom^ ;DtStft18tf11af1 ORlGIk4L 1 clwn of C+tsoodY a �" ps�uo,s " : mw Ry n SAMPM Paocnar, 1a tAa. QDPY CL Tar S&Wle Lepra al �M J r " % 6tarnllv,hr� vYOE3t f �r.wcrr„r.—NPDES- AG74 YMM ex a d�.7 �ih70'7 i t— °hl°r9 Vln�aon�wwla Pzw u5r —� if- z Client 5021013 nlen (GAS txn) � Unhlmftd � --- � {� Basleeea vromta "° ° pfft 'stivm ,mew I" k. t, 11111 NA rtitra n — W -- ,saa m _ w`sa.e {I Canlainsr Valtmu M41 TSSU wao xLi S00 250 F1fiL0 MEASIlREIENTs 4D 5od nriasodn Y�, !�F La I CongtnerTYPm Q49s P8- PeT PET 1¢4 ' ' Gta.`r� tmxr In SBmp40 QeSefil:3lan Or CuTftmor to GA�Aroh mBappte,QtisM re '" rL o uatt.styeltda+a+e, s, v ---I r}''� �: �. j ,°'- z^ UI'a - w uceewt T , LDcetlan ID GPs Loeran Coltae6fln tnfamm�on_ , t .r o : -b a to I , d r t mp, LMi10 Heal -nrm sk"At w T!,22 U Q V x 'rtr '. '�• F- Ot} - 7 A V 1r. f+J r Id 0 I r D D �t 0 1 aTrlp Sink- 5 ! y 1 i _ _ - p- - ----- 2 I" Rolmmltet�etl • Dot% t y�/4c Acceprtedw. Datef[mx GQ �v Rnquea,odTumatau.� Tetal 1S 1 Rd tliiwd mr 1 ou — ` 'ld DAYS � RNlrraulaHsd�It�Stf,� /fl�Je � A BY --- f m 7 Daya gilal 531 g '.16Hi ,••••ter ELLW9IlT5 by ICP fdS iD3Beftd•TRP4, As, Cd. Cr. c1u. mo, ,CK w So (CRC Metbnd) TI cow 5ve11 Tcw Flmrdtress ELEMEM by CCP lfteedld TRM4- Al, Ca, 9a, B. Ts, Mg. Ffi, K. W. Zn Piotue ea Py Tmn Nunsuckmr an ucof EUD res,tlta 'Add Coat WR Apmb SHEALY ENVIRONMENTAL SERVICES, INC. S6.11) 1•nvmmmmolEenices, Inc, Pa;, I oCl taicumL7�lNurntar hiEr101K(; 1� 6(;cctiveDatv0Ii 4,417 Brim,: Date 03107^_Q22 Sample Receipt Checklist (SRC:) Clime i/d Cooler InspectedbyMzte: 1 s6r— ! Lot ;V:5FO��lc( Mafmsofreceipr ❑ SCSI ❑ Client r I,ps ❑ 1`edEx )d Oilier ec(4t' tell Ye -q rl No 1, Wei a cu%Tody seals present on the cat)]L!r? Yes ❑ No ❑ NA,�i 2, If custody seals were prescut v,cre they intact and unbrolceu?� pH strip TT): 0 strip ID: _ Cooler ID.'t?riginal terapt:roture upon receiplfD_rivcd (corrected) rempera;ure upon receipt: i .!� AS, c — 1 J r 'C ! t VL Method: a 'Temperature Blank pJ Against Bottles IR Gun ID: tIR Gun Correction Faclor: �C Mctltodofcoolxnt: 0 WeticeoAlli4 Bluelec ❑ Dry lee Z None -cLifter Yeti ❑ Nn ❑ hAa. if lemperature of any cooler exceeded 6.00C, was Project Manager Notified? VIM was Nod lied br: phone 1 entail ? facc-to-face (circle one). 3 c9 ❑ Nur V _ f- is the commercial couriers packing slip at7ac:hed to this form? Yrs Aro cl 5. Were proper custody prooceduws (rclinauished received) fol lotivecl? v Yes n No © 6. Were sample IDs listed on the COC? Ycsp No ❑ 7, Were sample IDs Ilsl:d on all sample containers? Y.SA No u 8. Was collection date & time listed on the COC? Y� leo ❑ 9. Was Collection date & fline listed on all sample. contahlers? Yes.6 Na a 10. Did all container label information (ID. date, tune) agree mrith the COC? ` (:Sj 1 No ❑ 11, Were te.,ts to be purformcd listed on the COC? Yes ❑ N , - :r' l�, Did all sainptes arrive in the pioper coruxiners for each test and•+oi in gt-A)d Condition (w -n, lirl-i on, ctc,)? Yes No ❑ 13 Was adeguatc sample volumo mailable:' 'fes a' No ❑ lel. V4'ere all suinptl,�� receivedtiaithm'' Ilse holding Cirm; or 48 hours, whicbcver conies iirq? Yes ❑ No,- 15- Were am. samples Mnlaincrs rnissingiexcess (circle one) Satnpics Not listed on COC? Yrs © oo ❑ NA Ib. Fere bubbles present>`•pra-size" (!4'ot 6mm in diameter) in anv VOA vials? Yes 0 No Q N,1 pr 17 Wei; all DRO,'metals+nutrient samples reeeive.l fit a pH of<' 2" Ycs ❑ No ❑ t LA pr 18, Were at] cyanide -amplos received at a pH > 12 and Sulfid4 simples received at a pH > 99 Yes ❑ Nu ❑ NA� 14, Were all applicabia NI-13:TMeykinidiniphenolIBNA (r 0.5mg+L) samples free ofiesidual chlarine? Ycs ei No ❑ NAJn 29. Wurc collection temperatures documented on the COC for NC samples? Yes c No ❑ NA 21. Were clien( rcmar4irequests (i.e. iequested dilutions, MS,;MSD designation,,, etc:,,. ) correctly tm.ynscribed Crum the COC 111W the comment section in LIMS? Yes ❑ Nur , 22, Wo the quote number used take.l from the container label? Sample h-mrvation (Mutt he completed for any Sirnpl s) incorrectly preserved or with hoe& ace.) Sarriple(s)— were received itiwrrccdy preserved and were adjtmled accordingly in sant plc receivingwith riT2SO4, H.NO,, HCJ, MOH) using SR # santple(s) ___ were receitied with bubblc5 >6 inin in diameter. Y 5tmpics(s) were received wish TRC > 0.3 mg,'L (if V'21 is No) and were adiusted acwrdi�mple receiving with sodium thlosultate (Na:S103) widt Slicxla ID: SC Drinking Water Project Sample(s) pH verified to be r- 2 by Date. _ sample(s) were Not received ata PH of -2 an ~rere adjusted acccirrlin [y usin Sit# Sam le labels applid�l by: � __ 1�'eril:ed by• Dxle• [F z ! Colnmanjs: _--rb'l E VI(},l__cF ri r�i',ro; al pita{ J� fit;, 'a4r( edit _Uc. Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com '*MAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORMjugAnalytical Laboratory A </ GC_ DISMISILITION ORIG11',1MI L to LAB. COPY to CLIEN'tNPDES- WIN RCRA Witals COC REV DATEClientpreawwatwe NABusiness Unit: R—P r.Contminvorvokinto(roLl 1250 iom 250 300 2so FIELD MEASUREMENTS 40 5130MirContalnerTy" 01aws P0 PET PET HDPEV C - Sample Description or ID z '12 i -h rrufflomw 1b co"PW. AN13 :izicLocedon K) GPS Location Date 0PLO L ----'Field Stank L— TOTAL 0 Amep7 fly; 77, J, Dat�rrfrri� ZA Ac, at ELEMENTS by ?CF TRMI Al. Co. Pei, 8, F*. M9, Mn, K, ka, Za Masao copy Tim HunsuMefoo 4=01 EOD r*11411th - u _ « _ � _ _ " m TOW[13] DUKEa ENERGY Analytical Laboratory 13339 Hagers Ferry Road Huntersvllle, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone 980-875-5245 Fax 980-875-4349 Order Summary Report Order Number: J17050567 Project Name ROXBORO - NPDES - AOW Customer Name(s) Ross Hartfield, Craig Eady, Tim Hunsucker, Kathy Webb, Brandon Russo, Chris Customer Address Roxboro Steam Station 1700 Dunnaway Road Semora,NC 27343 Lab Contact Mary Ann Ogle Phone 980-875-5274 Report Authorized By: Date: 6/5/2017 (Signature) Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report Data Flags & Calculations: Analytical lab Page 1 of 52 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading All results are reported on a dry weight basis unless otherwise noted Subcontracted data included on the Duke Certificate of Analysis is to be used as information only Certified vendor results can be found in the subcontracted lab final report Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative An estimation of the uncertainty of measurement for the results in the report is available upon request This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory Please contact the Analytical laboratory with any questions The order of individual sections within this report is as follows Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications North Carolina (DEN R) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005 Contact the Analytical Laboratory for definitive information about the certification status of specific methods Analytical lab Sample ID's & Descriptions: Page 2 of 52 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2017017103 Roxboro 18 -May -17 11 22 AM Kaitlyn Fox S-21 2017017104 Roxboro 18 -May -17 10 15 AM Kaitlyn Fox S-14 2017017105 Roxboro 18 -May -17 12 22 PM Kaitlyn Fox S-09 2017017106 Roxboro 18 -May -17 9 45 AM Kaitlyn Fox S-13 2017017107 Roxboro 18 -May -17 9 45 AM Kaitlyn Fox S-14 Duplicate 2017017108 Roxboro 18 -May -17 2 20 PM Kaitlyn Fox FIELD BLANK 2017017109 Roxboro 18 -May -17 2 20 PM Kaitlyn Fox TRIP BLANK 7 Total Samples Technical Validation Review Checklist: COC and pdf report are In agreement with sample totals ❑/ Yes ❑ No and analyses (compliance programs and procedures) All Results are less than the laboratory reporting limits ❑ Yes FV_1 No All laboratory QA/QC requirements are acceptable ❑� Yes ❑ No Report Sections Included: ❑d Job Summary Report Sample Identification ❑d Technical Validation of Data Package ❑� Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Analytical lab Page 3 of 52 ❑d Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑� Chain of Custody 0 Electronic Data Deliverable (EDD) Sent Separate[ Reviewed By Mary Ann Ogle Date 6/5/2017 Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17050667 Site S-21 Collection Date 18 -May -17 1122 AM Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 1 Vendor Parameter Complete JASTOWE 5 NITRITE + NITRATE (COLORIMETRIC) 05/22/2017 14 24 BGN9034 Nitrite + Nitrate (Colonmetnc) 009 mg-N/L 001 INORGANIC IONS BY IC EPA 300 0 05/22/2017 14 24 BGN9034 Chloride 30 mg/L 05 Fluoride < 0.5 mg/L 05 Sulfate 150 mg/L 25 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 06/02/2017 11 07 Vendor Parameter Complete EPA 200 7 06/02/2017 11 07 TOTAL RECOVERABLE METALS BY ICP 1 EPA 200 7 Aluminum (AI) 0 093 mg/L B2 0 005 Barium (Ba) 0.072 mg/L 0 005 Boron (B) 1.17 mg/L 005 Calcium (Ca) 631 mg/L B2 001 Iron (Fe) 1.84 mg/L 001 Magnesium (Mg) 29.7 mg/L 0 005 Manganese (Mn) 436 mg/L 0 005 Potassium (K) 1 64 mg/L 01 Sodium (Na) 356 mg/L 005 Total Hardness (Ca and Mg) 280 mg/L 019 05/31/2017 13 06 CWSPEN3 (CaCO3) EPA 200 8 Zinc (Zn) < 0.005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS CWSPEN3 1 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 145 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0 2 ug/L 02 Sample #: 2017017103 Matrix NPDES Analytical lab Page 4 of 52 DF Method Analysis Date/Time Analyst 1 EPA 1664B 05/25/2017 08 30 CJELLIO Vendor Method V_SHEALY 1 EPA 353 2 06/03/2017 12 28 JASTOWE 5 EPA 300 0 05/22/2017 14 24 BGN9034 5 EPA 300 0 05/22/2017 14 24 BGN9034 25 EPA 300 0 05/22/2017 14 24 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 7 06/02/2017 11 07 MHH7131 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 1 EPA 200 8 05/31/2017 13 06 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 5 of 52 This report shall not be reproduced, except in full Order # J17060567 Site S-21 Collection Date 18 -May -17 11 22 AM Sample #: Matrix 2017017103 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 6.46 SI Units 1 Field Work Temperature 169 °C 1 Field Work Specific Conductance 675 us/cm 1 Field Work Turbidity 6.49 NTU 1 Field Work Flow NM cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 450 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 7 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17050567 Site S-14 Sample #: 2017017104 Collection Date 18 -May -17 10 15 AM Matrix NPDES Analyte Result Units Qualifiers RDL OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION EPA 1664B Oil and Grease < 5 mg/L 5 ALKALINITY - (Analysis Performed by Shealy Labs) 1 Vendor Parameter Complete JASTOWE 10 NITRITE + NITRATE (COLORIMETRIC) 05/22/2017 13 22 BGN9034 Nitrite + Nitrate (Colorimetric) < 0 01 mg-N/L 001 INORGANIC IONS BY IC EPA 300 0 05/22/2017 13 22 BGN9034 Chloride 52 mg/L 1 Fluoride < 1 mg/L 1 Sulfate 370 mg/L 10 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 06/02/2017 11 20 Vendor Parameter Complete EPA 200 7 06/02/2017 11 20 TOTAL RECOVERABLE METALS BY ICP 1 EPA 200 7 Aluminum (AI) 0.089 mg/L B2 0 005 Barium (Ba) 0 057 mg/L 0 005 Boron (B) 0 500 mg/L 005 Calcium (Ca) 148 mg/L B2 01 Iron (Fe) 1 26 mg/L 001 Magnesium (Mg) 226 mg/L 0 005 Manganese (Mn) 242 mg/L 0 005 Potassium (K) 3.75 mg/L 01 Sodium (Na) 13.0 mg/L 005 Total Hardness (Ca and Mg) 463 mg/L 019 06/02/2017 20 10 CWSPEN3 (CaCO3) EPA 200 8 Zinc (Zn) < 0 005 mg/L 0 005 TOTAL RECOVERABLE METALS BY ICP -MS CWSPEN3 1 Antimony (Sb) < 1 ug/L 1 Arsenic (As) 3.29 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 11 3 ug/L 1 Nickel (Ni) 1.10 ug/L 1 Selenium (Se) < 5 ug/L 5 Thallium (TI) Low Level < 0.2 ug/L 0 2 Analytical lab Page 6 of 52 DF Method Analysis Date/Time Analyst 1 EPA 1664B 05/25/2017 08 30 CJELLIO Vendor Method V_SHEALY 1 EPA 353 2 06/03/2017 12 42 JASTOWE 10 EPA 300 0 05/22/2017 13 22 BGN9034 10 EPA 300 0 05/22/2017 13 22 BGN9034 100 EPA 300 0 05/22/2017 13 22 BGN9034 Vendor Method V_SHEALY 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 10 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 7 06/02/2017 11 20 MHH7131 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 1 EPA 200 8 06/02/2017 20 10 CWSPEN3 lab Certificate of Laboratory Analysis Paget7 olf 52 This report shall not be reproduced, except in full Order # J17050567 Site S-14 Sample #: 2017017104 Collection Date 18 -May -17 10 15 AM Matrix NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 6.80 SI Units 1 Field Work Temperature 17.8 °C 1 Field Work Specific Conductance 860 us/cm 1 Field Work Turbidity 267 NTU 1 Field Work Flow 0.0400 cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 660 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 8 of 52 This report shall not be reproduced, except in full Order # J17050567 Site S-09 Collection Date 18 -May -17 12 22 PM Sample #: Matrix 2017017105 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 05/25/2017 08 30 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colonmetnc) 0.01 mg-N/L 001 1 EPA 353 2 06/03/2017 12 44 JASTOWE INORGANIC IONS BY IC Chloride 33 mg/L 01 1 EPA 300 0 05/22/2017 14 57 BGN9034 Fluoride 013 mg/L 01 1 EPA 300 0 05/22/2017 14 57 BGN9034 Sulfate 48 mg/L 2 20 EPA 300 0 05/22/2017 14 57 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0 526 mg/L B2 0 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 Barium (Ba) 0 037 mg/L 0 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 Boron (B) 1 26 mg/L 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 Calcium (Ca) 188 mg/L B2 001 1 EPA 200 7 06/02/2017 11 25 MHH7131 Iron (Fe) 1 26 mg/L 001 1 EPA 200 7 06/02/2017 11 25 MHH7131 Magnesium (Mg) 735 mg/L 0 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 Manganese (Mn) 0.998 mg/L 0 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 Potassium (K) 256 mg/L 01 1 EPA 200 7 06/02/2017 11 25 MHH7131 Sodium (Na) 944 mg/L 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 Total Hardness (Ca and Mg) 77.3 mg/L 019 1 EPA 200 7 06/02/2017 11 25 MHH7131 (CaCO3) Zinc (Zn) < 0 005 mg/L 0 005 1 EPA 200 7 06/02/2017 11 25 MHH7131 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Arsenic (As) 102 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Copper (Cu) 1 36 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Lead (Pb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Molybdenum (Mo) 45.8 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Nickel (Ni) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Selenium (Se) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Thallium (TI) Low Level < 0.2 ug/L 02 1 EPA 200 8 05/31/2017 13 14 CWSPEN3 Certificate of Laboratory Analysis Analytical lab y Page 9 of 52 This report shall not be reproduced, except in full Order # J17050567 Site S-09 Collection Date 18 -May -17 12 22 PM Sample #: Matrix 2017017105 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst Field Parameters (certification not covered under DPAL certification) pH 7.10 SI Units 1 Field Work Temperature 290 °C 1 Field Work Specific Conductance 282 us/cm 1 Field Work Turbidity 140 NTU 1 Field Work Flow NM cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 140 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS 8 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 10 of 52 This report shall not be reproduced, except in full Order # J17050567 Site S-13 Sample #: 2017017106 Collection Date 18 -May -17 9 45 AM Matrix NPDES Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Chromium (Cr) Vendor Parameter Complete 2.70 Lead (Pb) NITRITE + NITRATE (COLORIMETRIC) Molybdenum (Mo) 50.1 Nitrite + Nitrate (Colonmetnc) 002 mg-N/L 001 INORGANIC IONS BY IC < 0.2 1 EPA 200 8 Chloride 59 mg/L 05 Fluoride < 0 5 mg/L 05 Sulfate 75 mg/L 25 MERCURY IN WATER - (Analysis Performed by Shealy Labs) ug/L Vendor Parameter Complete EPA 200 8 05/31/2017 13 22 TOTAL RECOVERABLE METALS BY ICP ug/L 1 Aluminum (AI) 0.112 mg/L B2 0 005 Barium (Ba) 0.039 mg/L 0 005 Boron (B) 0.662 mg/L 005 Calcium (Ca) 29.8 mg/L B2 001 Iron (Fe) 0 801 mg/L 001 Magnesium (Mg) 122 mg/L 0 005 Manganese (Mn) 0.423 mg/L 0 005 Potassium (K) 316 mg/L 01 Sodium (Na) 10.9 mg/L 005 Total Hardness (Ca and Mg) 125 mg/L 019 Zinc (Zn) 0 007 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 Arsenic (As) 1.90 Cadmium (Cd) < 1 Chromium (Cr) < 1 Copper (Cu) 2.70 Lead (Pb) < 1 Molybdenum (Mo) 50.1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 DF Method Analysis Date/Time Analyst Vendor Method 1 EPA 353 2 5 5 25 1 1 1 1 1 1 1 1 1 1 EPA 300 0 EPA 300 0 EPA 300 0 Vendor Method EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 EPA 200 7 V_SHEALY 06/03/2017 12 45 JASTOWE 05/22/2017 13 53 BGN9034 05/22/2017 13 53 BGN9034 05/22/2017 13 53 BGN9034 V SHEALY 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 06/02/2017 11 29 MHH7131 (CaCO3) mg/L 0 005 1 EPA 200 7 06/02/2017 11 29 MHH7131 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 1 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 ug/L 02 1 EPA 200 8 05/31/2017 13 22 CWSPEN3 Certificate of Laboratory Analysis Analytical lab y Page 11 of 52 This report shall not be reproduced, except In full Order # J17050567 Site S-13 Collection Date 18 -May -17 9 45 AM Sample #: Matrix 2017017106 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Field Parameters (certification not covered under DPAL certification) pH 7.39 SI Units 1 Field Work Temperature 21.2 °C 1 Field Work Specific Conductance 302 us/cm 1 Field Work Turbidity 5.12 NTU 1 Field Work Flow NM cfs 1 Field Work TOTAL DISSOLVED SOLIDS TDS 200 mg/L 25 1 SM2540C 05/22/2017 15 00 MGIGANT TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/19/2017 10 00 MGIGANT Analytical lab Certificate of Laboratory Analysis Page 12 of 52 This report shall not be reproduced, except in full Order # J17060567 Site S-14 Duplicate Collection Date 18 -May -17 9 45 AM Sample #: Matrix 2017017107 NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L 5 1 EPA 1664B 05/25/2017 08 30 CJELLIO ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 001 1 EPA 353 2 06/03/2017 12 46 JASTOWE INORGANIC IONS BY IC Chloride 5.3 mg/L 1 10 EPA 300 0 05/22/2017 14 08 BGN9034 Fluoride < 1 mg/L 1 10 EPA 300 0 05/22/2017 14 08 BGN9034 Sulfate 380 mg/L 10 100 EPA 300 0 05/22/2017 14 08 BGN9034 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.085 mg/L B2 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Barium (Ba) 0 057 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Boron (B) 0.500 mg/L 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Calcium (Ca) 148 mg/L B2 01 10 EPA 200 7 06/02/2017 11 33 MHH7131 Iron (Fe) 1 26 mg/L 001 1 EPA 200 7 06/02/2017 11 33 MHH7131 Magnesium (Mg) 228 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Manganese (Mn) 243 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Potassium (K) 3.80 mg/L 01 1 EPA 200 7 06/02/2017 11 33 MHH7131 Sodium (Na) 13.0 mg/L 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 Total Hardness (Ca and Mg) 463 mg/L 019 1 EPA 200 7 06/02/2017 11 33 MHH7131 (CaCO3) Zinc (Zn) < 0 005 mg/L 0 005 1 EPA 200 7 06/02/2017 11 33 MHH7131 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Arsenic (As) 314 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Cadmium (Cd) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Chromium (Cr) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Copper (Cu) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Lead (Pb) < 1 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Molybdenum (Mo) 113 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Nickel (Ni) 1 07 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Selenium (Se) 141 ug/L 1 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Thallium (TI) Low Level < 0 2 ug/L 02 1 EPA 200 8 05/31/2017 13 29 CWSPEN3 Analytical lab Certificate of Laboratory Analysis Page 13 of 52 This report shall not be reproduced, except /n full Order # J17050567 Site S-14 Duplicate Sample #: 2017017107 Collection Date 18 -May -17 945 AM Matrix NPDES Analyte Result Units Qualifiers RDL Field Parameters (certification not covered under DPAL certification) pH 680 SI Units Temperature 178 °C Specific Conductance 860 us/cm Turbidity 267 NTU Flow 00400 cfs TOTAL DISSOLVED SOLIDS TDS 660 mg/L 25 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 T 1 1 1 1 1 Method Analysis Date/Time Analyst Field Work Field Work Field Work Field Work Field Work SM2540C 05/22/2017 15 00 MGIGANT SM2540D 05/19/2017 10 00 MGIGANT Certificate of Laboratory Analysis This report shall not be reproduced, except In full Order # J17060567 Site FIELD BLANK Sample #: 2017017108 Collection Date 18 -May -17 2 20 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Analytical lab Page 14 of 52 Method Analysis Date/Time Analyst Vendor Method V_SHEALY Analytical lab Certificate of Laboratory Analysis Page 15 of 52 This report shall not be reproduced, except in full Order # A7060667 Site TRIP BLANK Sample #: 2017017109 Collection Date 18 -May -17 2 20 PM Matrix NPDES Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY Qualifiers: B2 Target analyte was detected in Method Blank(s) at a concentration greater than '% the reporting limit but less than the reporting limit Analyte concentration in sample is valid and may be used for compliance purposes Analytical lab Certificate of Laboratory Analysis Page 16 of 52 This report shall not be reproduced, except in full Order # A 7050567 Level II QC Summary Q17050612 1664—SPE OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Blank # 1 Parameter Measured Final Oil and Grease 0 LCS # 1 Parameter Measured Final Oil and Grease 344 NIS #I Parameter Measured Final Oil and Grease 304 Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL Units Dil Spike % Recover/ LCL UCL Qualifier mg/L 1 369208 933 78 114 - Parent Sample J17040260 -- 2017011969 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 337866 90 78 114 Analytical lab Certificate of Laboratory Analysis Page 17 of 52 This report shall not be reproduced, except in full Order # J17050567 Level II QC Summary Q17060054 C NO2NO3 NITRITE + NITRATE (COLORIMETRIC) Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Nitrite + Nitrate 00048 00048 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 2 Parameter Measured Final Units Dil RDL Relative Concentration Nitrite + Nitrate 00043 00043 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 3 Parameter Measured Final Units Dil RDL Relative Concentration Nitrite + Nitrate 00046 00046 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 4 Parameter Measured Final Units Dil RDL Relative Concentration Nitrite + Nitrate 0 0 mg-N/L 1 001 < 1/2 RDL (Colorimetric) Blank # 5 Parameter Measured Final Units Dil RDL Relative Concentration Nitrite + Nitrate -00002 -00002 mg-N/L 1 001 < 1/2 RDL (Colorimetric) LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Nitrite + Nitrate 0 295 295 mg-N/L 10 301 981 90 110 (Colorimetric) LCS # 2 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Nitrite + Nitrate 0 292 292 mg-N/L 10 301 971 90 110 (Colorimetric) LCS # 3 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Nitrite + Nitrate 029 29 mg-N/L 10 301 965 90 110 (Colorimetric) LCS # 4 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Nitrite + Nitrate 0 291 2 91 mg-N/L 10 301 967 90 110 (Colorimetric) LCS #5 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Nitrite + Nitrate 0 289 29 mg-N/L 10 301 962 90 110 (Colorimetric) Qualifier Qualifier Qualifier Qualifier Qualifier Qualifier Qualifier Qualifier Qualifier Qualifier Analytical lab Certificate of Laboratory Analysis Page 18 of 52 This report shall not be reproduced, except /n full Order # J17060667 Level II QC Summary Q17060054 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) MS #1 Parent Sample J17040263 -- 2017011984 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 261 0 261 mg-N/L 1 025 964 90 110 - (Colorimetric) MSD #1 Parent Sample J17040263 -- 2017011984 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 261 0 261 mg-N/L 1 025 964 90 110 00767 - (Colonmetnc) MS #2 Parent Sample J17050035 -- 2017014449 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 417 0 417 mg-N/L 1 025 98 90 110 - (Colorimetric) MSD #2 Parent Sample J17050035 -- 2017014449 Parameter Measured Final Units DO Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 412 0 412 mg-N/L 1 025 963 90 110 104 - (Colorimetric) MS #3 Parent Sample J17050232 -- 2017015526 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 407 0 407 mg-N/L 1 025 962 90 110 (Colorimetric) MSD #3 Parent Sample J17050232 -- 2017015526 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 414 0 414 mg-N/L 1 025 99 90 110 1 73 (Colorimetric) MS #4 Parent Sample J17050576 -- 2017017130 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 254 0 254 mg-N/L 1 025 94 3 90 110 (Colorimetric) MSD #4 Parent Sample J17050576 -- 2017017130 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 255 0 255 mg-N/L 1 025 946 90 110 0 314 - (Colorimetric) MS #5 Parent Sample J17050694 -- 2017017659 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0 249 0 249 mg-N/L 1 025 966 90, 110 - (Colorimetric) MSD #5 Parent Sample J17050694 -- 2017017659 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0 247 0 247 mg-N/L 1 025 959 90 110 0 725 (Colorimetric) Analytical lab Certificate of Laboratory Analysis Page 19 of 52 This report shall not be reproduced, except /n full Order # J17060667 Level II QC Summary Q17050522 Dionex INORGANIC IONS BY IC Blank # 1 Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Chloride 0 039 0 039 mg/L 1 01 < 1/2 RDL - Fluoride 00431 00431 mg/L 1 01 < 1/2 RDL - Sulfate 00061 00061 mg/L 1 01 < 1/2 RDL Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 548 274 mg/L 50 250 964 80 120 - Fluoride 482 241 mg/L 50 250 954 80 120 - Sulfate 913 457 mg/L 50 250 948 80 120 - ISD #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 552 276 mg/L 50 250 972 80 120 0 864 - Fluoride 484 242 mg/L 50 250 959 80 120 0 523 - Sulfate 918 459 mg/L 50 250 957 80 120 0 943 - LCS #1 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 468 468 mg/L 1 5 935 90 110 - Fluoride 469 469 mg/L 1 5 93 7 90 110 - Sulfate 469 469 mg/L 1 5 939 90 110 - MS #1 Parent Sample J17040141 -- 2017011488 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Chloride 548 274 mg/L 50 250 958 80 120 - Fluoride 482 241 mg/L 50 250 80 120 - Sulfate 913 457 mg/L 50 250 94 8 80 120 - MSD #1 Parent Sample J17040141 -- 2017011488 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 552 276 mg/L 50 250 966 80 120 0 869 - Fluoride 484 242 mg/L 50 250 80 120 - Sulfate 918 459 mg/L 50 250 957 80 120 0 943 Analytical lab Certificate of Laboratory Analysis Page 20 of 52 This report shall not be reproduced, except in full Order # J17060667 Level II QC Summary Q17050687 ICP_TRM TOTAL RECOVERABLE METALS BY ICP Blank # 1 Parameter Measured Final Units Dd RDL Relative Concentration Qualifier Aluminum (AI) 000715 000715 mg/L 1 0 005 > RDL - Barium (Ba) -0000053 -0000053 mg/L 1 0 005 < 1/2 RDL - Boron (B) -000187 -000187 mg/L 1 005 < 1/2 RDL - Calcium (Ca) 00114 00114 mg/L 1 001 > RDL - Iron (Fe) 000107 000107 mg/L 1 001 < 1/2 RDL - Magnesium (Mg) 0 001 0 001 mg/L 1 0 005 < 1/2 RDL - Manganese (Mn) 0000078 0000078 mg/L 1 0 005 < 1/2 RDL - Potassium (K) -000222 -000222 mg/L 1 01 < 1/2 RDL - Sodium (Na) 00138 00138 mg/L 1 005 < 1/2 RDL - Zinc (Zn) -0000373 -0000373 mg/L 1 0 005 < 1/2 RDL - LCS #1 Parameter Measured Final Units Dd Spike % Recovery LCL UCL Qualifier Aluminum (AI) 485 485 mg/L 1 5 97 85 115 Barium (Ba) 494 494 mg/L 1 5 988 85 115 Boron (B) 494 494 mg/L 1 5 988 85 115 Calcium (Ca) 497 497 mg/L 1 5 994 85 115 Iron (Fe) 497 497 mg/L 1 5 993 85 115 - Magnesium (Mg) 495 495 mg/L 1 5 989 85 115 - Manganese (Mn) 496 496 mg/L 1 5 992 85 115 - Potassium (K) 489 489 mg/L 1 5 977 85 115 - Sodium (Na) 488 488 mg/L 1 5 976 85 115 - Zinc (Zn) 5 5 mg/L 1 5 100 85 115 - MS #1 Parent Sample J17050567 -- 2017017103 Parameter Measured Final Units Dd Spike % Recovery LCL UCL Qualifier Aluminum (AI) 501 501 mg/L 1 5 983 70 130 - Barium (Ba) 509 509 mg/L 1 5 100 70 130 - Boron (B) 625 625 mg/L 1 5 102 70 130 - Calcium (Ca) 676 676 mg/L 1 5 90 70 130 - Iron (Fe) 671 671 mg/L 1 5 975 70 130 - Magnesium (Mg) 346 346 mg/L 1 5 98 70 130 - Manganese (Mn) 934 934 mg/L 1 5 995 70 130 - Potassium (K) 665 665 mg/L 1 5 100 70 130 - Sodium (Na) 406 406 mg/L 1 5 100 70 130 - Zinc (Zn) 491 491 mg/L 1 5 982 70 130 - MSD # 1 Parent Sample J17050567 -- 2017017103 Parameter Measured Final Units Dd Spike % Recovery LCL UCL RPD Qualifier Aluminum (Al) 471 471 mg/L 1 5 923 70 130 636 - Certificate of Laboratory Analysis This report shall not be reproduced, except /n full Order # J17050567 Level II QC Summary Q17050687 ICP TRM TOTAL RECOVERABLE METALS BY ICP MSD #1 Parameter Measured Final Units Dil Spike Barium (Ba) 475 475 mg/L 1 5 Boron (B) 595 595 mg/L 1 5 Calcium (Ca) 674 674 mg/L 1 5 Iron (Fe) 64 64 mg/L 1 5 Magnesium (Mg) 344 344 mg/L 1 5 Manganese (Mn) 902 902 mg/L 1 5 Potassium (K) 633 633 mg/L 1 5 Sodium (Na) 404 404 mg/L 1 5 Zinc (Zn) 46 46 mg/L 1 5 Analytical lab Page 21 of 52 Parent Sample J17050567 -- 2017017103 % Recovery LCL UCL RPD Qualifier 937 70 130 689 - 95 6 70 130 602 - 86 7 70 130 374 - 91 2 70 130 67 - 93 8 70 130 444 - 93 70 130 675 - 93 9 70 130 651 - 95 1 70 130 5 - 92 70 130 648 - Analytical lab Certificate of Laboratory Analysis Page 22 of 52 This report shall not be reproduced, except in full Order # J17060667 Level II QC Summary Q17050692 IMS TRM TOTAL RECOVERABLE METALS BY ICP -MS Blank # 1 Measured Final Units Dil Spike % Recovery Parameter Measured Final Units Dil RDL Relative Concentration Qualifier Antimony (Sb) -0007 -0007 ug/L 1 1 < 1/2 RDL Arsenic (As) 0 037 0 037 ug/L 1 1 < 1/2 RDL - Cadmium (Cd) 0 014 0 014 ug/L 1 1 < 1/2 RDL - Chromium (Cr) 0 163 0 163 ug/L 1 1 < 1/2 RDL - Copper (Cu) 0 001 0 001 ug/L 1 1 < 1/2 RDL - Lead (Pb) 0 017 0 017 ug/L 1 1 < 1/2 RDL - Molybdenum (Mo) 0 017 0 017 ug/L 1 1 < 1/2 RDL - Nickel (Ni) 025 025 ug/L 1 1 < 1/2 RDL - Selenium (Se) 0 032 0 032 ug/L 1 1 < 1/2 RDL - Thallium (TI) Low Level 0 016 0 016 ug/L 1 02 < 1/2 RDL - LCS 91 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 474 474 ug/L 1 50 948 85 115 - Arsenic (As) 491 491 ug/L 1 50 982 85 115 - Cadmium (Cd) 492 492 ug/L 1 50 985 85 115 - Chromium (Cr) 481 481 ug/L 1 50 963 85 115 - Copper (Cu) 488 488 ug/L 1 50 977 85 115 - Lead (Pb) 485 485 ug/L 1 50 971 85 115 - Molybdenum (Mo) 488 488 ug/L 1 50 976 85 115 - Nickel (Ni) 492 492 ug/L 1 50 985 85 115 - Selenium (Se) 49 49 ug/L 1 50 993 85 115 - Thallium (TI) Low Level 471 471 ug/L 1 50 942 85 115 - MS #1 Parent Sample J17050567 -- 2017017104 Parameter Measured Final Units Dil Spike % Recovery LCL UCL Qualifier Antimony (Sb) 485 485 ug/L 1 50 967 70 130 Arsenic (As) 51 9 51 9 ug/L 1 50 972 70 130 Cadmium (Cd) 476 476 ug/L 1 50 952 70 130 Chromium (Cr) 479 479 ug/L 1 50 95 70 130 - Copper(Cu) 48 48 ug/L 1 50 946 70 130 - Lead (Pb) 48 48 ug/L 1 50 959 70 130 - Molybdenum (Mo) 60 60 ug/L 1 50 975 70 130 - Nickel (Ni) 49 6 49 6 ug/L 1 50 97 70 130 - Selenium (Se) 469 469 ug/L 1 50 903 70 130 - Thallium (TI) Low Level 476 476 ug/L 1 50 951 70 130 - MSD #1 Parent Sample J17050567 -- 2017017104 Parameter Measured Final Units Dil Spike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 471 471 ug/L 1 50 938 70 130 3 07 Certificate of Laboratory Analysis This report shall not be reproduced, except in full Order # J17060567 Level II QC Summary Q17050692 IMS_TRM TOTAL RECOVERABLE METALS BY ICP -MS MSD #1 Parameter Measured Final Units Dil Spike Arsenic (As) 505 505 ug/L 1 50 Cadmium (Cd) 463 463 ug/L 1 50 Chromium (Cr) 467 467 ug/L. 1 50 Copper (Cu) 461 461 ug/L 1 50 Lead (Pb) 461 461 ug/L 1 50 Molybdenum (Mo) 588 58 8 ug/L 1 50 Nickel (Ni) 476 476 ug/L 1 50 Selenium (Se) 44 8 448 ug/L 1 50 Thallium (TI) Low Level 457 457 ug/L. 1 50 Analytical lab Page 23 of 52 Parent Sample J17050567 -- 2017017104 % Recovery LCL UCL RPD Qualifier 944 70 130 296 926 70 130 275 - 92 5 70 130 263 - 90 7 70 130 421 - 92 1 70 130 401 - 95 1 70 130 25 - 93 70 130 429 - 86 2 70 130 468 - 91 3 70 130 407 - Analytical lab Certificate of Laboratory Analysis Page 24 of 52 Th►s report shall not be reproduced, except ►n full Order # J17060667 Level II QC Summary Q17050525 TDS TOTAL DISSOLVED SOLIDS Blank # 1 Dil RDL Parameter Measured Final TDS 0 0 Blank # 2 Units Dil Parameter Measured Final TDS 0 0 Duplicate # 1 Parameter Measured Final TDS 17700 17700 Duplicate # 2 RPD Qualifier Parameter Measured Final TDS 303 303 Duplicate # 3 Parent Sample Parameter Measured Final TDS 44 44 LCS #1 Parameter Measured Final TDS 103 103 Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL - Units Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1/2 RDL Parent Sample J17040141 -- 2017011490 Units Dil RPD Qualifier mg/L 1 0 113 - Parent Sample J17040141 -- 2017011491 Units Dil RPD Qualifier mg/L 1 0 - Parent Sample J17050012 -- 2017014343 Units Dil RPD Qualifier mg/L 1 465 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 100 103 90 110 Analytical lab Certificate of Laboratory Analysis Page 25 of 52 This report shall not be reproduced, except in full Order # A 7050567 Level II QC Summary Q17050493 TSS TOTAL SUSPENDED SOLIDS Blank # 1 Parameter Measured Final TSS 0 0 LCS #1 Parameter Measured Final TSS 50 50 LCSD # 1 Parameter Measured Final TSS 496 496 LCS # 2 Dil RDL Relative Concentration Parameter Measured Final 1 TSS 504 504 LCSD #2 - Units Dil Parameter Measured Final UCL TSS 48 48 LCS # 3 50 100 90 110 Parameter Measured Final Dil TSS 496 496 LCSD #3 RPD Qualifier mg/L 1 Parameter Measured Final 110 TSS 496 496 LCS # 4 Parameter Measured Final TSS 484 484 LCSD # 4 Parameter Measured Final TSS 488 488 Units Dil RDL Relative Concentration Qualifier mg/L 1 5 < 1/2 RDL - Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 100 90 110 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg/L 1 50 992 90 110 0 803 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 101 90 110 - Units Dil Spike % Recovery LCL UCL RPD Qualifier mg/L 1 50 96 90 110 4 88 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 992 90 110 Units Dil Spike % Recovery LCL UCL RPD Qualifier mg/L 1 50 992 90 110 0 Units Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 96 8 90 110 - Units Dil Spike % Recovery LCL UCL RPD Qualifier mg/L 1 50 976 90 110 0 823 - SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersvllle, NC 28078 Attention: Mary Ann Ogle Project Name: Roxboro NPDES AOW Project Number J17050567 Lot Number SE19042 Date Completed.05/23/2017 Grant Wilton Project Manager �� LABORATORY ACCREDITATION ,ByUREj(AU)y��-a.,�mq��.i1 f R:+i'ti �.-�'J Ff�C�V]L�7i�'J4'3i93`i6°rC930S3 `BAJtt1��'" This report shall not be reproduced, except In Its entirety, without the written approval of Shealy Environmental Services, Inc The following non -paginated documents are considered part of this report Chain of Custody Record and Sample Receipt Checklist Shealy Environmental Services, Inc Page 1 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No 32010 NELAC No E87653 NC DENR No 329 NC Field Parameters No 5639 Case Narrative Duke Energy Lot Number SE19042 Project Name Roxboro NPDES AOW Project Number J17050567 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative The sample receiving date is documented in the header information associated with each sample All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed In accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc Page 2 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number SE19042 Project Name Roxboro NPDES AOW Project Number J17050567 Sample Number Sample ID Matrix Date Sampled Date Received 001 2017017103 Aqueous 05/18/20171122 05/19/2017 002 2017017104 Aqueous 05/18/20171015 05/19/2017 003 2017017105 Aqueous 05/18/20171222 05/19/2017 004 2017017106 Aqueous 05/18/2017 0945 05/19/2017 005 2017017107 Aqueous 05/18/2017 0945 05/19/2017 006 2017017108 Aqueous 05/18/20171420 05/19/2017 007 2017017109 Aqueous 05/18/20171420 05/19/2017 (7 samples) Shealy Environmental Services, Inc Page 3 Of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number SE19042 Project Name Roxboro NPDES AOW Project Number J17050567 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2017017103 Aqueous Alkalinity SM 23208- 160 mg/L 5 001 2017017103 Aqueous Bicarbonate Alkalinity SM 232013- 160 mg/L 5 001 2017017103 Aqueous Mercury (CVAFS) 1631E 576 ng/L 6 002 2017017104 Aqueous Alkalinity SM 23206- 82 mg/L 7 002 2017017104 Aqueous Bicarbonate Alkalinity SM 2320B- 82 mg/L 7 002 2017017104 Aqueous Mercury (CVAFS) 1631E 11 6 ng/L 8 003 2017017105 Aqueous Alkalinity SM 232013- 40 mg/L 9 003 2017017105 Aqueous Bicarbonate Alkalinity SM 2320B- 40 mg/L 9 003 2017017105 Aqueous Mercury (CVAFS) 1631E 595 ng/L 10 004 2017017106 Aqueous Alkalinity SM 232013- 62 mg/L 11 004 2017017106 Aqueous Bicarbonate Alkalinity SM 23206- 62 mg/L 11 004 2017017106 Aqueous Mercury (CVAFS) 1631E 1 55 ng/L 12 005 2017017107 Aqueous Alkalinity SM 23206- 81 mg/L 13 005 2017017107 Aqueous Bicarbonate Alkalinity SM 23208- 81 mg1L 13 005 2017017107 Aqueous Mercury (CVAFS) 1631E 11 6 ng/L 14 (15 detections) Shealy Environmental Services, Inc Page 4 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax(803)791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-001 Description 2017017103 Matrix Aqueous Date Sampled 05/18/2017 1122 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1841 BWS 42563 1 (Bicarbonate) SM 2320B-2011 1 05/22/2017 1841 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/22/2017 1841 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvww shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 160 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 160 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 5 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvww shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-001 Description 2017017103 Matrix Aqueous Date Sampled 05/18/2017 1122 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1706 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 576 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 6 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-002 Description 2017017104 Matrix Aqueous Date Sampled 05/18/2017 1015 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1846 BWS 42563 1 (Bicarbonate ) SM 2320B-2011 1 05/22/2017 1846 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/22/2017 1846 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a W S = MS/MSD failure Shealy Environmental Services, Inc Page 7 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 82 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 82 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a W S = MS/MSD failure Shealy Environmental Services, Inc Page 7 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-002 Description 201 701 71 04 Matrix Aqueous Date Sampled 05/18/2017 1015 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1719 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 11 6 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W' S = MS/MSD failure Shealy Environmental Services, Inc Page 8 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 wwvv shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-003 Description 201 701 71 05 Matrix Aqueous Date Sampled 05/18/2017 1222 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1852 BWS 42563 1 (Bicarbonate ) SM 2320B-2011 1 05/22/2017 1852 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/22/2017 1852 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 40 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 40 10 mg/L 1 Carbonate Alkalinity SM 23208-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 9 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-003 Description 2017017105 Matrix Aqueous Date Sampled 05/18/2017 1222 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1723 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 595 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W S = MS/MSD failure Shealy Environmental Services, Inc Page 10 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-004 Description 2017017106 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1857 BWS 42563 1 (Bicarbonate ) SM 2320B-2011 1 05/22/2017 1857 BWS 1 (Carbonate AI) SM 23208-2011 1 05/22/2017 1857 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and a MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cnteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 62 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 62 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and a MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cnteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 11 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-004 Description 2017017106 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1728 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 1 55 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W S = MS/MSD failure Shealy Environmental Services, Inc Page 12 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals Client Duke Energy Laboratory ID SE19042-005 Description 201 701 71 07 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/22/2017 1902 BWS 42563 1 (Bicarbonate ) SM 2320B-2011 1 05/22/2017 1902 BWS 1 (Carbonate AI) SM 2320B-2011 1 05/22/2017 1902 BWS PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W° S = MS/MSD failure Shealy Environmental Services, Inc Page 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 81 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 81 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W° S = MS/MSD failure Shealy Environmental Services, Inc Page 13 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-005 Description 201 701 71 07 Matrix Aqueous Date Sampled 05/18/2017 0945 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1741 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E 11 6 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 14 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-006 Description 2017017108 Matrix Aqueous Date Sampled 05/18/2017 1420 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/20/2017 1746 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of cntena L = LCS/LCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MSIMSD failure Shealy Environmental Services, Inc Page 15 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) Client Duke Energy Laboratory ID SE19042-007 Description 2017017109 Matrix Aqueous Date Sampled 05/18/2017 1420 Project Name Roxboro NPDES AOW Date Received 05/19/2017 Project Number J17050567 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/20/2017 1750 SLS 05/20/2017 0024 42512 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0 500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure NO = Not detected at or above the PQL J = Estimated result < PQL and> MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCSILCSD failure Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure Shealy Environmental Services, Inc Page 16 of 16 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com QC Summary Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - MB Sample ID SQ42563-001 Matrix Aqueous Batch 42563 Analytical Method SM 2320B-2011 Parameter Result Q DII PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/22/20171803 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and : MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Inorganic non-metals - LCS Sample ID SQ42563-002 Matrix Aqueous Batch 42563 Analytical Method SM 23208-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 100 1 100 90-110 05/22/20171809 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and a MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn Mercury (CVAFS) - MB Sample ID SQ42512-001 Matrix Aqueous Batch 42512 Prep Method 1631E Analytical Method 1631E Prep Date 05/20/2017 24 Parameter Result Q DO PQL Units Analysis Date Mercury (CVAFS) ND 1 0 500 ng/L 05/20/2017 1657 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a °W" Note Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Mercury (CVAFS) - LCS Sample ID SQ42512-002 Matrix Aqueous Batch 42512 Prep Method 1631E Analytical Method 1631E Prep Date 05/20/2017 24 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 500 483 1 97 75-125 05/20/2017 1701 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and 2: MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Sample ID SE19042-001MS Batch 42512 Mercury (CVAFS) - MS Matrix Aqueous Prep Method 1631 E Analytical Method 1631E Prep Date 05/20/2017 24 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q DII % Rec Limit Analysis Date Mercury (CVAFS) 576 500 105 1 95 71-125 05/20/2017 1710 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a 'W' N = Recovery is out of criteria + = RPD is out of criteria Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 uvww shealylab com Mercury (CVAFS) - MSD Sample ID SE19042-001MD Matrix Aqueous Batch 42512 Prep Method 1631 E Analvtical Method 1631E Prep Date 05/20/2017 24 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q DII % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 576 500 103 1 91 20 71-125 24 05/20/2017 1715 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria No = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" Note Calculations are performed before rounding to avoid round -off errors In calculated results Shealy Environmental Services, Inc QC Data for Lot Number SE19042 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com Chain of Custody .1. Miscellaneous Documents Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab com o � n 0 0 3 d N n N N co 0 cD J 0 X c 0 J N S (D c Q 0 0 Cir - -quite Ener" as duke 6wW AmSj*W r..bwmn � Amm"i al Lsboralmy61I O N & of Cuwody ti runr r+.w Ka oats I sarepH inp samprtr Dmcrgmn or I rwpmrwxr Lnr�tlonln CiP� Lvcstlon I 1 i3s If IL 6 4 �leld�een�I jjIQq TrfpHIS nk VAIN OF CUSTODY RECORD AND ANALYSIS REOLEST FORM Aa >:M uaonaa U» On �i Aaenpto,t6yr ( a� �...¢K, b wu til r ^f % / J' /Y9a.r1W r-nI0 Tumsraw�d Irrl.rtk. RiHlMq stWVy posiniat. rdirlk NtR NPDp 0' Dyb e+praar� Ik I Peeve-f—ar-3- ac� a x +- m •CICT"UTM SAMPL9 PR06XMt ' C>aI:INt1 ao LAE. eoPv Lo cu tr t '• 9 1°wQ'dLpYnhi 3-r""e Cuum+'N.hr uPDbs USt� ° 'AdI Cost W[ Appy SHEALY ; PC) 6021013 UnAkend I�I��Illlllll�ill�llal�l�� 're�ruaf5re mm Im Ira am M"A SEI 9042 _ Gnrdal�rVoh,rrroprzl} 12dll 1C�p SBO :ta0 F1�i.D11EASlliiEM�Ni3 �pmintrTypt er.. rrEr rer et>f xxe emsomsrroca n7a m ib FA R� nc&disd.rlamst v~. IL ^ S�'y' a eel 0 w � = arl $Q Aaenpto,t6yr ( a� �...¢K, b wu til r ^f % / J' /Y9a.r1W r-nI0 Tumsraw�d Irrl.rtk. RiHlMq stWVy posiniat. Acctpbdgyr DOAMm -- gcc.pad r: ouwiil,A Fi ar Iv- — a x +- f s t '• 9 - i q r'"'°'" Kmwm by LCr MS p]rgxsErd TFNN� M, Cd, Cr, Lir, Yo, Wt Ob, 8b, St (CAC o* TI parr btto Toted Htrdmest BL.FAmm by 1cp jnk a4a nw A1, Cm, Oil H, Pe, ft Ms, &its, Z0 Pima copy Tlm Ifurrauder on erne! EDD multi 'AdI Cost W[ Appy arl $Q Aaenpto,t6yr ( a� �...¢K, b wu til r ^f % / J' /Y9a.r1W Tumsraw�d Irrl.rtk. RiHlMq stWVy posiniat. Acctpbdgyr DOAMm -- gcc.pad r: ouwiil,A ® F `+A Oara 1 }-1 5-i l -E �� Q �� _ , tf� ? �l I I�I _ _ mer I5 'ABIV 'Oltrer r'"'°'" Kmwm by LCr MS p]rgxsErd TFNN� M, Cd, Cr, Lir, Yo, Wt Ob, 8b, St (CAC o* TI parr btto Toted Htrdmest BL.FAmm by 1cp jnk a4a nw A1, Cm, Oil H, Pe, ft Ms, &its, Z0 Pima copy Tlm Ifurrauder on erne! EDD multi 'AdI Cost W[ Appy -Olt °c - cel IiL 12 Trnsi 1s SHEALY ENVIRONMENTAL SERVICES, INC. $'-7gp1yFinjmnmenU.'t!rv1ees tno 1ub:,dnten1Kwnber ME8418C-03 1122e I ftf I Efts" Daw GY37 2017 hLFtry13uLa U3-C171=L2:! Sample Receipt Checklist (SRC} Pq- Client.- yule f5nt Gti Cooler Inspected by/dare: / Cdt 9: �� e Meanticif=eipt:1❑ SES[ Client In UFS ❑ Pedfsx ❑ Other El-!:10: No pf 1. Were custody seals present on the cooler? Yes ❑ 1 Iva ❑ NA 2, It custody seals were present, wcrc they intact and unbroken? pH strip ID. - Cl strip ID; Cooler U ' as ,mperature n e1 Menved (corrected) temperature upon r"eipt: .e 1Method: n Temperature Blank Against Bottles IR Curt If]: J IR Gun Correction Factor: D °C Method of coolant: Wet lcc ❑ Blue Ice E3Ory ice None Ycs 13No C NA 3. If temperature of any coo er exceeded 6,0°C, was f'rolcct kla wber Notified? PM was Notified by: hone ! email f face-to-face (circle vile). Yes 103 NO 131N 4 is the wirrimercial courier's packing slip attached to this form? Yes;(No 135. Were proper custody procedures (relinquishedheceived) follDwed? Yes No ❑ 6. Wcrc swnplc IDs listed on the COC? Yes No ❑ 7. Were sample IDs listed on all sample} containers? Yes No ❑ S. Was collection date fir. time listed on the CUGd Yes No 119. Was collection date & tine listed on all sample containers? Yes No ❑ 10, Did all container label information (ID, date. time) agree with the CHIC? Yes No a 11. Were tests to be performed listed on the COC? Yes No ❑ 12. Die] all samples arrive in the proper containers for each test and/or in good condition (unbroken, lids on, etc.)? Yes No ❑ 13. Wns adequate sample volume available? i Yes No ❑ 14. Were a)I sate les received within 14 the holding time or 48 hours, whichever cordes first? Ycs ❑ t<o 15. Were any samples conldincrs missing+excess (circle one) samples Not listed on COG? Yes ❑ No ❑ NA 16. Were bubbics prescnl ="pea -size" (11."or 6mm in diameter) ut any VOA vials? Yes ❑ No ❑ NA 17. Were all DROhnetaWnuirient samples received at a pH of < 2? Yes ❑ No ❑ NA V 18. Were all cyanide sam les received at u pH > 12 mid sulfide samples received ata pH > 9? Yes 11 No ❑ NA.41 19. Were all applicable NH3+TKNlcyanide+phenol?RNA (< [?-5mp/L) samples free of residual chlorine? Yes ❑ No ❑ NA 20. Were collection tem eraWras documented on the COC for NC samples? Yes u No ❑ NA 21 • Fere client rcanarkslrequect,s (i a. requested dilutions, M&NISD dcsignalions, etc,,.) correcrly transcribed from the COC into the comment section in MIS? Yes ❑ NnV 22. Was the quote number used taken from the: container label? Sample Pr ervation (Must be complcicd for uny sarnple(s) hicorrecd ' 2reserved or with headspaee.) Sem pie{s) were received incorrectly preserved and were adjusted 4ccordingly in sam to receiving with_ (HISCIs, HNO3, KC1, Na01-1) using SR 4 Sdm Ic(b) were received with bubbics --6 mm in diameter. Sarrsples(s) were received with TRC > 0.5 rugfL (If 421 is No) and were adjusted accordingly in sample receiving with sodium Ihiosulfate Na, -S;0, with Shealy ID - SC Drinking Water Project Sample(s) pH verified to be < 2 by Late: -- Sampl s were jot r t 1-ai H H of a 2 and were adjusted accordin usin SR#>' sample(s) Sample labels applied bi � Vetitied by. Date: _ Comments' Shealy Environmental Services, Inc 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www shealylab corn CHAIN OF CUSTODY RECORD AND ANALYSIS REOLEST FORM Analytical lab Page 52 of 52 Page —3 Duke Energy Ye Nc —1 of f,..a. Moc,3ajl JHM.g T401 Ord Dow ORIGINAL AnaiytWal Laboratory ChaMft of Custody ..W—AW'N C. MT& By a Ti" !AMPLE PROM" to LAB, COPY to CLIENT CVA 1'5 -11 -1 114 Sample Log -P U19 3 SHEALY C' -.4w rr tCj,. ......... PO 50 aflon (0.46 um21013 unfiltered 113ummess Unit: Preservative k. INN fts Mer W ;�-- 7-i Boo Container Volume (ml-) '1200 ' '1000 250 300 '50 FIELD MEASUREME Contah" PET PEI 14 IWE PET 0 petelTyma perMTMne ELEMENTS by ICP _U$ [Digested -TRV): As. Cd, Cc, Cu, Mo. NI, Pb, Sb. SO 11CRC method) T1 Ikm Woq ToW Hordr"t r. a. a r. &a, me K Na. 7n please copy Ton Hunstittlat Ott excel FDO results I*,eques"4 Turnaround ' 48 Hr 10ther - Add. Coal W4 A ppty Total F, 3