NC0004979_Permit Modification_19950811

• 04/10/03 09:55 0704 382 6240
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DPCO ENV ENGR X001
A Duke Energy Compally.
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Fax:— f Pages:
Phone: Date:
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❑ Urgent ❑ For RevieW ❑ Please Comment ❑ Please Reply ❑ Pieas4 Recycle
+ Comments

13

04/10/03 09:55 $704382 6240 DPCO ENV ENGR I 1@002
State of North Carolina
Department of Environment,
Health and Natural Resources
Division of Environmental ManagernLant
James B- Hunt, Jr-, Governor
Jonathan B. Howes, Secretary
A. Preston Howard, Jr., P.E., Director
Mr- John Carter, TechtliCal SYStemS MaltagCr
Duke Power CoMpany
mwtric System Support Department
13339 Hagers Ferry Rom
Hun[ersville, Nortb Carolina 2801!8-7929
Dear W. Carter:
August 11, 1995
W
411"'3 Y 5 11995
Q ILE
C7 `"•�
Q!1i -IF
Subiecc NPDES Permit Modification p Dpy
NPDLS PCrittit No. NC0M91"9 �.
Duke Puwu' CQmpan7
Allen Steam Station [t 0 L! TE' —
Gaston County
In accordance with your permit modification application recoived.nn 7aly 26, 1994, we ere fo arding herewith the
modified subject stats - NPDES pormit YOU requested that outfall U01 fie, subject to a monthly averdg Ili(: nud limit as had
been included in Previous hermits instead of the daily avcta a thermal Bruit included in the permit iwd, MarCh 9, 1995. Wt
have evaluated your request and concur that a monthly average the Built is approp h=•
Please fuid eneloSed aWeLided outfa11!001 dffldcntlimitutions and aP0nit0#ng,regttireAnents page w ''h shouldbe lnsu[c(1
into your permit. The old par4 should bo discarded.. U ether terms and conditions contained in the Of i9inal permit remain
unchanged Anil in full effect_ These permit modifications arc issued pursuant tp the requirements of Ni r{h Carolina General
Statutes 143-215.1 and the Memomudum of Agreement between North Carotiha and the U. S. Euvi Inntental Protection
Agency. _
Tf any of the modified pflrLS, measurement frcyacmCies or wi milling roquirement� ;contained in this 't are unacceptable
to you, you have the right to an adjudicatory bearing upory written request within tl'iirty (30) days fol wing receipt of thiq
letter. This request must be in the farm of a'Written petition, Cppforming to Chapter 1505 of the N rth Carolina Geneml
Statutes, and fried with the ()Rice of Adrninisttative Hearings, fust Office Drawer 27447, Raleigh, IN 3rth Carolina 27611-
7447. Unless such demand is made, this &,cisicni shall be final and bindiuA,
if you have any questions concerning, these permil. tnoditications, please, contact Dana Bolden at telephone nurikr
9191133-508$, extension 518-
Sincercly yonrs,
74
r'
A. Preston is [ow.>rd,1r., P.E.
CC: central Files
MoomsviAe Regional Office
Perth its and>rmgineerin¢ Unit i
Facilities Asseemietlt Unit
P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone [phone] FAQ 919-733-9919
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% past -consumer p er

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A. (), EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NC0004 79
During tate period beginning on the effective. -date of the permit and lasting until expiration, the PenniMe is authorized to discharge from
outfall(s) serial number='. Such discharges shall be limited and monitored by the permittee as speeified b•.-10 •:
a
Elfluent Characteristics 131scharae Limitations Monitoring Requiremenis,
Lbeids Units �specifyl Measurement Sample *SOMPIe
Moir.. Aver, DallyM-ax PAon.Aygt Daily Max. Freauena 1-" o 'o
Flow gaily Pump Logs or E p)
Temperature` Dally Grab E
W
N
0
a
ho
r�
0
* Sample locations. E - Effluent. �
Temperature shall notexceed 35 `"C (95 °'F) during the period October 1 through May 31 and 35.9 °C (102.0 °F) during the pn iod June 1
through September 30.
*** The Regional- Administratorhas determined pursuant to Section 316(a) of the Act that the thermal component of the discharge assures the
protection and propagation of a balanced, indigenous papulation of shellfish, fish and wildlife in and on the receiving body of water.
Chlorination of the once through cooling water, discharged through outfall 001, is not allowed under this permit, Should Dine Power wish to
chlorinate its once through cooling eater, a permit modification must be, requested and received prior to commencing chlorination.
10
0
0
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04/10/03 09:56 $704 382 6240 DPCO ENV ENGR
Dirk Pouter COTOMY
61e6tric501ein suAPorr&parlmenr
IYUY 1lgrjen rprry Rend
flun(ers-Ole. X -78ORN029
,f i DUIEEPOWER '
July 25, 1995
Mn David Goodrich
North Carolina DepaMnent of Environment
Health and Natural Resources
1'_ O. Box 29535
Raleigh, NC 27626-0535
Subject: Duke Power Company
Minor Modification to Plant Allen NPDES Permit
NPDES # NCO004979
File: PA• -702.1
Dear Mr. Goodrich:
Per your telephone conversation with Ron Lewis, we are requesting a minor
modification to the Plant Allen NPDLS permit_ This modification request is due to an
oversight of the change in the thermal limit requirement for outfall 001 in the present
permit f 0111 the previous permit. We request the permit's thermal limit be c gcd from
a daily maximum limit to a monthly average limit, as stated in the provious pcf nit -
Please see the attached copies of outfall 001 of both the present and previous p rmits.
Enclosed is a check ($100.00) for the minor modification fee. if you he any
questions plme call Ron Lewis (704-875-5968) or Jolui Mease (704-875-534 )_
Sincerely,
ohn Catc;r, Technical y'stems anagcr
Wator Protection
f 5� fm! r d• n4_Zr,•ep,r n q •. •r
U004

'�Feseyt t re& -M IT
A. (). EFFLUFNTLDAITATIONS AND MQNITCIRIINd REQUIREMEN'T'S FINAL PennitND. hC0004979
During the period beginning on the effective date of thepermit and lasting until expiation, the Petrnittee is authorized to discharge from
outfalls) serial number 001. Such discharges shall be ]muted and monitored by the permittee as specified below:
Emuent C arectarist cs Disch raB LI Itotions
1-beldaw Units (epeclfu� Measurement Sarnnl_e_ *Semcls
M n'__ . [Ajb Max Mon. Ava. aajb tt't .& Freauenca IY21 Location
Daily Pomp Logs or E
Flaw
Temperature'"' daily Grab �
�
* Sample locations: E - Effluent.
A.t Temperature shall not exceed 35 °C (95 °F) during the. pezod Oc-tober 1 through May 31 -and 38.9 °C (102D °F) during the period June 1
through September 30.
** The Regional A.drninistratar has determined p=liant to Section 316(x) of the .Act thatthe thermal component of the discharge assures the
protection and propagation of a balanced, indigenous population of shellfish, fish and wildlife in and on the receiving body of water.
Chlorination of the once through cooling water, discharged d rough outfall 003, is not allowed under this permit. Sbould Duke Power wish to
chlorinate its once though cooling water, a permit modification must be requested and received prior to co=encmg chlorination,
s -
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0
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2

Pe rrA
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P
(1) . EFFIXF.Rl' LIMITATIONS AND MONITORING REQUIREMENTS Final NPDES No. NC0004579
Daring the period beginning an the effective date of the permit and lasting until expiration the
om
Permittee is authorized to discharge from outfall(s) serial ziumber(s) 001.
Such discharges sWI be
limited and monitored by the Permittee as specified below: f
CO
Effluent Characteristics Discharge Limitations Monitoring Requirements
Q
Lbs da Other Units (Specifp Measurement
Sample *S.aurple
y
Monthly Avg. Daily Max. Monthly Avg. Daily Max_ Frequency
Tie Location
_
N
Fldw _ Daily
Pump log or E
similar reading
o
Temperature*** - 35(95)** Daily
Grab E
d
�u
0
Sample locations: E - Effluent
M
** During the period June 1 to September 3C, 3a.9 C (102.0 F) is permitted.
�y
-
z
*** The Regional Administrator has determined pursuant to Section 316(a) of the Act that the thermal component
of the discharge assures tine protection and propagation of a balanced, indigenous
papulation of shellfish,
fish, and wildlife in and on the receiving body of water.
Chlorination of the once-through cooling water is not allowed under this permit.
Should Duke Power wish
to chlorinate its once through cooling water, a permit modification must be requested
and received prior to
commencing chlorination.

2

07/22/2003 12:12 704-382-9840
DUKE PWR PWR GEN
F
Go.
Duke
Pept, f r py r.,
L�
f�q!
Powen
A Duke Energy Company
,i'��
July 22, 2003
Mr. Rex Gleason
Watcr Quality Supervisor
North Carolina Depmi mint of
Natural Resources
919 North Main Street
Mooresville, NC 28115
Subject; Allewt Steam Station
NPD1;S Pemait NCO004979
Pilot Test for Selenium. R.cduction
Dcar Mr_ Gleasom
PAGE 01
FOSSIL -HYDRO GENERATION
Duke Power
E01IE / 526 South Church Street
Charlotte, NC 28202-1802
Post-Itn' brand fax transmittal memo 7M #otPag§S 0, %
Ira i�
From
Go.
Co.
Pept, f r py r.,
L�
f�q!
Phone 7C
Fax ii T /
� VL!
FaxB-7O'
Per our conversation with you, Mr. Mike Parker and Mr. Richard Bridgeman of your office and Mr. Tom Belnicic
and Mr. Daviel Goodrich of the Raleigh offico on July 21, 2003, a descriptiort.of the proposed pilot test to reduce the
selenium concentration in the wastewatcr of the Allen Steam Station ash basin follows for your review and approval.
Currently stop logs have been added to block the discharge flow from the ash basin tower to Lake Wylie due to the
selenium concentration exceeding the 31 gg/L maximum daily limit on July 1.5, 2003. The proposed pilot test
protocol to reduce the selenium concentration includes several options-
Dump wastewater from the vegetated ash delta, where the selenium concentration is currently less than
3 pg/L, to the ash basin discharge tower (see line! diagram)
+ Add ferric sulfate at 100 gallons per 5 MGD of effluent upstream of the vegetated ash delta to ezabanee
precipitation of srlenium (see attached line diagram aradMSDS sheet),
+ Possibly utilize tlwe old ash basin. for additional retention time acrd treatment in the vegetated deltas,
then pump back to the currently permitted ash basin discharge tower
Excavation of ash to form, additional, ash berms and increase the retention time within the ash basin is scheduled to
begin July 22, 2003. Also preparations arc underway to pump wastewater frown the vegetated ash delta within the
ash basin,, where rhe selenium concentration is currently less than 3 ug/L, to the ash basin discharge tower. The
additional proposed treatment optiowts will be utilized as needed upon your approval. '1}lrc anticipate completion of
the proposed pilot test by September 30, 2003 _
Since the ash basin is nearing the full poxwd elevation, your immediate review and approval of the suggested pilot test
options is requested, If you have additional suggestions or need to discuss further, please contact rrre (704) 373-
3231 or Ron Lewis [phone].
Sincerely,
Michael A. R11he, Manager
$nvironmental Support
Attachments
cc: Mr. David Goodrich, NCDENR _ Raleigh
www. dune-enerBY. tom

M

6712212663 12:12 764-382-9846 DUKE PWR PWR GEN
Old Yard ALLEN STEAM STATION
Ash, Sumps ASH BASIN
Towex
` pump from Ash Delta to Tower
ischo
Tower
Vegetated
A rh Delta
Add FeSO4
Vegetated Ash Benra
Units 4&5
Pump Ash SIuioe � •...,
to Old •
r .
}
Ash •
Basin
Vegetated Vegetated
Deltas -
Ash Delta
(Drainage
area of 65
acres)
• f
r ■
• � Y
Units 1, 2, & t
3 Ash Sluice J
PAGE 62

AF'

• 07/22/2003 12:12 704-382-9846 DUKE PWR PWR GEN PAGE 03
• • ` 07/21/03
XON 16:07 FAX [phone] ALLEN ADMIN OFF 'm Ly VA
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68= -� XOO
71 �.Ja_oo3 11:39 PAGL 1.15
* Mataria(1 safety Data sbeeb **
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u.a,#. a' USA Imp.
woo, Conlon Point
tWA 96031
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DUKE ENGiGY CORP 1
PAN
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i7w-uo-2370 y
MARSHALL GORE; at UNiVAR USA
F.om
fax direct
Total pag" (Ind, this ono)
5
Fsutioct
i your ratermoco
MSOS -FERRIC SULFA -51Y
F mil siroeR
ta�mhona Brea V&Wvad, WA. x8033
A
rar emergency assistdrtcc involving Chemicals, call CHEMTtiEC-009)4: —9300
A* z4ate"a.1 Safety Data Sheet dye
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0712212003 12:12 704-382-9840 DUKE PWR PWR GEN PAGE 04
-- • •— ALLEN ADDSIN OFF
07!21103 MON 16:07 FAX [phone]
f f r -, --IV— h "t ..air l+AVr L/ .? 1tiYSh'Gi �y6'
\'aW✓ 1 c
aa8 oaf19/4a FERRIC SW --ATP- 504
PRODUCT NAME: n-3 - FERRIC STIL-RATE 50-%
MSDS# : P1697V's
WE ISSUED;
SUPERBSbras - NEW r
ZSSi7ED BY: 0 0 67 0
6, r
Menu as r+srar s
Maine: Fe -3, X -Ac -
$usi.n�ss Rt. 289 North
Celina, 'texas 75909
F,agu,lar Teiaphoxse [phone] _
8tner mnay Telephone No. (SQO) �2 -9300
Tracie Nam=- re 3
Synonyms: *VBpRF IC SULFATE 50= 109
gh;ippxng Name; DO'S_ CORROSIVE LIQUID, N-'Q.S. CORRASISY� Ad2'1RtERIIIL
(LIQUID EI F=U SU11rZ.TE -- 5" WATER NA 176"
xT. jMZ3=0US INCREDZENTS
Material or Component ('lypioal) L'as No.
Ferries Sulfate 1.0023-22-5 49-0
Hazard Data: Product; iO toxi&- cra1.1Y, , is oorxos've to the eye, and will
bursa the gk i n -
Free Sulfurla AcJ-d, '1664-93-9
Water (balance o:E formuIati0n)
;1quatla tox1o;Lty: rargIc s -.)Nate i.X li oted ao •tvN:ic tO Ag0Mt10 lips,
Category C. 40 CFR Parts 116 -118 -
Ill. P9TSZCA1 DATA
Dvxling Pole+--= 750 mm hg: Approx.• 212' deg F
Freczin,g Polpt: Roes not freeze at 0 deg F
gpad:Lgi.o Grav-x'ty (020=1): 1.400 to 1.455
Vapor•Pressure: DU
vapor. Density (Air=x) : NA
Solubility in. R2a-% by Wt_: infinite
% Volatiles by Vol.; NA'
9vaparation'Fate (Buty1 Acetate 1)
A-ppeaXanpe and Qdor: Red -Brown solution, No detectAble odor.
Ph (as 36) ApPrOxlmatel;t': 1-0
Rh (ist s41ni ,App=*xj nate1y: 4. B
IV. FIR'S AND EXPLOSION DATA
Flaah point (Teat Mothod) t N.A.
autoigAition TemperatUre: N.Pr.
naimma'ble Limits in Air, -% by Vol,; 7,ower N' -A.- Y3gger N.A.
Extin,g j.-. :LMg me -&La: Px04uCt dons not CbuurncoX maPPbetused, IixIf prodat uct is
present in a, fire, water, CO2 or dry �'
bighly acidi,o and If in open contaa-Uam avoid aplaahing.
SFeoial r:,re righting Prot - : 'Dc not allow product or Water containing
1,radne� to ,aster a navigabla stream_ 1�.t temperatures above $00 deg C,
product decomposes to iron oxide and 6nr'fnr tr!aX;Ldee.
UnUaUal Fire a Exploai,oA Hazard: Norte known.
V. HEALTE HAZZaW INF0RMXT10N
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07/2212003 12:12 704-382-9840 DUKE PWR PWR GEN
ori21iO3 xON 18:07 FAX 40,18292370 ALLN asunv o�F
$ .2g HIM= DILM
Route of E,rpoauza: i3�halat:Lan
Sazard Class�f7 =ate-¢� t Not datexmi-ned, but acted to be 10V due td
other t=:Lcolog cdI tests phy:�;ical and chemical cha:Cacter9 std c5.
Basis for Cla6SifiCation: NA
6ourae: N&
Route of Exposure: Skx,n Coutaot
gh1n Contact: Not a primary skin irrltaht by VUSA Standards
Basis for classifioatiov' Primary dermal Irritatlom index - 0.0 'fvr 24
and 12 hours.
$Qurae. baboratory test iu accord. with Fg$A pxocedura.
route aE Exposure: Skin AbBQxptian
Skin ]8}sorption; Not tonic dermally by FDsA statldards
basik for Classi£icatlon: Est. dermal I.ri50 (PAbbit)= (Male) Greater than
2.13 glkg body Weight (Female) Greater t'tan 2.0 g/kg body Weight.
Sourpe: Labaratory',test in accord with rush Procedure -
Route of Lsp4Sure; Eve Contact
Hazard Cl.assificatiou; C0rsos3.ve to the -yam by FFSA standards.
Basis for Clasnification: ERya irritation Scores:
24 'tours 45.2
48 hours 55.2
72 hours $8.3
7 day6 63.4
Source: Laboratory test in accord with MA pxocedura-
Route of Exl,asure: Istgmstion
Hazard Classification: *XoMio by' FESk standards.
Basis for Classification: Oral W50 (Rats -male) _ Botwmon 2.5 and 5-6 g/kg
body wa ght_ (Rat-Eemnle) = AQtween 2.5 and 5.O g/kj body Weight.
Sc=aa: Labaratary 'tosts accord With FESIIprrocedure.
HBTECTS OF 4'omxPOSURE:
,out& 4Ve4rexPo15ure: None known except as jisted Ju Maction 4 above.
chronic rnrezeyrnesura: None known except as Itsted iu 5ecti.ota V above.
ARG ,WCX AND rMABT AID PROMDOM6
BV8 Immediately .irrigate -W.Ith larger amounts of water fox at least is
m3,nutes. U01d eyelids apart during irrigation, Send patient to a Phpsioian
immediately.
SKLN plush with Watar wbile raWV'ing clothing and shoes. Continue to flush
for at least LS tuix+utce. Call a phya3.c3an. Wash clothes before reuse.
INRUJITION Remove from area and Clive arti:Ejeial respiration if needed and
weak medioal assistance.
INGESTION Txaat as a corrosive liquid- prink large quantities of Water or
all4k to reduce concentration aud heutralize aciel. De not induce vomiting.
Call physiCia&% imaediatwly.
VI. rMACTTVIR'Y DATA
CONDl$IONS CONTRIBUTING TO INEXABILITT:
None Xmmlwa-
INQC"A,TI5IZI3.'Y :
Product solution is corrosive to Mild, steel, coppar, capper alloys and
galvanized ,steel. May be corrosive to pajmts, enamels, and concrete-
r.aa,ata with k3m$ and ather 15aEir materials to form ;.nsol,uble iron salts_
HAZAMOUS q COME'OSITxON �RDDYJG�S:
PAGE 05

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0712212003 12:12 704-382-9B40 DUKE PWR PWR'GEN PAGE 07
,• •�• — — — -- —
07/z1/03 RON 1$to8 FA% 1048292310 ALa,EN AaMIIs OFF
USDA. 4
F
CPSC:
X
TSCA: S® tlsi ' prod�rat, or all, its ir4red,ients, beiUg cezti£ied dor
inclusion on the Toxic Substances Control Act inventory of aheml=2
substanCes4 Y$5.
OTHER- The fers�-o sulfata meets the AWWA standard Ivr Ferxlc 5-0-fnte it
potable watv--X. 6taz%dssd--XWXL 8806-87 -
OSSA: Product i5 a haxardou$ material as defined by 29 CFR Fatragrapb 1910,
1200 NationalaToxiColo4y Program. theInteraationallle CYC' ct is Agenayclisted by the
for
1jesearch on CauOex, noX the RegistXY of `.6'C=XQ Ef£ect8 of dh--m'am'
Subat-aucee (198182) as a,. oascinoyen or Potential carcinogen.
SARA. TITLE 111, Froduat contains the f09.10irih9r.1"ta3 tox,ie ek2tn!Lcal5
whish ase subjact to the .reporting requirments of Section 313 of MIA
9o(the
Uer;EndAma�ntszaoritatIOR Act o£
185ST)lPart3?2
Liated UuXi.a CheMidal CAS
4-•93-g max °3 By xzgt.
Sulfuric Acid
- FO$L ADDITToluz IXFORNMION---^------- ----- ------
COI�'ACT: MEDSC00RDINATOR UNIVAR USA INC.
Dmur, wgiNESS HOURS, PMIVIC TIML [phone]
-- NOTICE — --------------- — - — -- — -
f*fi t** tse QNIZJAR [ISA INC (°UNIVARI') 8XFlZESSLY DISC-T.AZW --- - - --
-------- —'—�------.-----.- I-----�—w+ ----- ..sans----rte.----I �.r�--n�----.--.I —� ..
ALL EXPRESS OR IMPLIED 41 NTSES 01` bdERCBAt�TASTT.ITy AND rIVESS FOR A
PARTICULAR VURPOSZ, WITH paSPECT I'0 T9E PRWUCT OR INFOMWION MOMED HERZ3N,
------------ ---- -.------- --------------------------------
AND Sg= UNDER NO CTRCUXST.�XCES SE I,27d8'LE FOR INCIDENTAL OR CO1TSEQG8=m
DMGES . **
---------••-------------------------
Do NOT MY. iNG)kEDIRNT INFORMATION ANDIOR 190-REDIMT PERCENTAGZS Ila T31S MSDS
AS A PRODUCT SPECxF=I0N_ FOR PRODUCT BPECIFICR.'TZON INFORt+SjLTION REFER TO A
PRODYJCM SPECIFICATION SHEET AND/OR A C gR7.'IFICATE OF Amalyars . TOE99 CAN SE
ORTATWD PROM YOUR LOM UNIVAItt SALZO OFFICE,
AT,L INFOR OLTXON AFPExittNG RE=IN IS BASED UPON mlik OBTAINED FRM THE
bDiDiiYFACTM= ANDIOR RECOGNIZED TB=TCAL 90U=S, WHILE TER ZNF0PMP'T1GN IS
RELTZM TO BE ACCURAM, UNIVAR M25ICES NO REFRESW=IONS AS TO IT'D ACCUr&ar OR
,SLTFIC1?,XG5'. COROXTIONS OP -Vr-E ARL BEYOND UNIV.8R5 COSTR L AND THEREFGRE USERS
ARE IMSPONSIBLE TO V'ERIT'Y TRIS DATA, MER THEX i OWN ORSR=ING CONDITIONS TO
DETEBNINF, 'KHEWWREX THE FXQDVCT IS WMABLE FOR TVXXI PI1Wlea"AR pUAP4$R3 AND Tarry
ASSOM ALL RiSRS OF TEEIR. USE, HANDT.IA rw, AND DYSPOSa OV THE PRODUCT, OR FRAM
TSI: nBAICATrON OR USE OF, OR RELIANCE UPON , INFOWATION CONTAINED ZDt.
THIS ii ORL4A2`ZdN RELATES ONLY To TUE PRADuCT DESIG1,i IR.RD 9MIN, AND .DOES NCS
RETIA % TO ITS UgE IN COMBINATION WITH ANY OTHER N2aERIAL OR IN ANY OTHER
FROCHBS.
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