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HomeMy WebLinkAboutNC0004979_Fact Sheet_20011017t w DENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NC0004979 erry xoau; tiuntersvtiie, Prim.SlC Code: 4911 Fork Catawba Rivers no one given/ tz4 9 A IM NO a N one given/309, R w , ).. /806 BACKGROUND Duke Energy's Allen Steam Station is a coal fired steam electric plant in Gaston County. The facility has four permitted outfalls in the current NPDES discharge permit, issued in September 1996. The sources of wastewater for these outfalls include non -contact cooling water, ash basin discharge, sanitary waste, cleansing and polishing water and stormwater from process areas. The facility has requested a fifth permitted outfall in the renewal application to cover weekly cleaning of intake screens, which trap debris and Asiatic clams. In compliance inspection reports, the Mooresville Regional Office describes the facility as well maintained with few compliance problems. In addition to NPDES Permit NC0004979, the facility also holds the; foFlo`_w_ing- pefrriits: 03757 (air permit), NCD043678937 (Hazardous wastes), and WQ0003255 (ash -reuse permit). r� Permit Renewal Application: The permittee submitted the following items for permit renewal: j 0 4' • EPA Form 1 • EPA Form 2E • EPA Form 2C (with a priority pollutant analysis). c N • Site Maps I Water Flow Diagram L • Supplemental information a The following changes were requested: • Deletion of the oil and grease monitoring requirement at outfalls 602-aAd:00-4_ a ;� • Deletion of naphthalene, phenol and chromium monitoring at outfall 002 • Reduction of fecal and BOD monitoring from monthly to semi-annually • Reduction of TSS monitoring from monthly to quarterly • Make the iron and copper limits applicable only during a chemical metals cleaning The permittee also requested a continuation of the 316(a) variance for temperature based on the submitted aquatic life data. The permittee also requested the addition of a fifth outfall Fact Sheet NPDES NC0004979Renewal Page 1 I kw 1 , • ' from which intake screen washwater would be discharged once a week with a total flow of about 3000 gpd. Instream Monitoring and Verification of Existing Conditions and DMR Data Review. This facility discharges to both the South Fork Catawba River (001) and the Catawba River (002-004). Both are located within sub -basin 03-08-36 and neither is listed as an impaired stream [303 (d) -listed as of 2000]. One of the permit requirements is to perform an assessment of balanced and indigenous populations in downstream Lake Wylie. This requires Plant Allen to maintain three macroinvertebrate sampling stations in Lake Wylie (2 m. depth) and three fish monitoring stations (one upstream of the Plant Allen intake). The report was submitted by the permittee and is attached. The report states that "Macroinvertebrate data show no adverse impact of the heated discharge; on the macroinvertebrate fauna in Lake Wylie." It also states that Lake Wylie has a diverse fish community that is not experiencing atypical levels of stress. The sampling indicates that the fish avoid the Plant Allen discharge in the summer but seem to show a preference for that location in the spring. Other than the aquatic life data, no other instream data are collected Discharge Monitoring Reports (DMRs) for outfalls 001-004 were reviewed from January 1999 -August 2001. Flow and temperature are measured at outfall 001, a discharge consisting of condenser cooling water; flow during this time averaged 721 MGD. Outfalls 003 discharges miscellaneous equipment cooling and seal water to the condenser cooling water discharge canal; average flow at this outfall was 6 MGD. Outfall 004 discharges equipment cooling water and intake screen backwash. Oil and grease and flow are measured at this outfall. Oil and grease has not been detected in effluent discharges over the past two years, flow was an average of 8 MGD. Outfall 002 discharges wastewater from a wide variety of sources including stormwater runoff from the coal pile area, ash sluice, recirculating !water system, heat exchanger cleaning water, condensate polishing water, condensate leakage testing water, yard drain sump water, water treatment system, preheater washes, lab wastes and the powerhouse sumps. The following table summarizes the effluent data results at outfall 002. In addition to the aforementioned outfalls, there are two sump overflow outfalls — 002A and 002B, the coal yard sump overflow and powerhouse sump overflow, respectively. These discharge to the Catawba River in the event that all pumps in the sump fail. Both were approved in May 15, 2000. Outfall 002, has only discharged once in the last five years; outfall 002B has discharged twice in the last five years. Correspondence. The Mooresville Regional Office (MRO) conducted six site visits and submitted corresponding Compliance Evaluation Inspection Reports. The facility typically received satisfactory ratings on these reports and was described as well maintained with an effluent that showed no visible adverse impacts to the receiving stream. Two inspections did reveal violations of the iron daily maximum limit: — one Notice of Violation (NOV) was issued for this exceedence in October 2000. The facility has also received an NOV for a toxicity test failure (January 1997) and a Notice of Deficiency (NOD) for unacceptable solids storage (January 1997). Three compliance biomonitoring inspections were also conducted during the permit period; the facility passed all three. The 2001 staff report prepared for this renewal recommends the following: • Reduce (but not eliminate) oil and grease monitoring at outfalls 002 and 004 • Remove naphthalene, phenol and chromium monitoring at 002. • Reduce BOD, TSS, and fecal coliform monitoring at 002. Fact Sheet NPDES NC0004979Renewal Page 2 MONITORED PARAMETERS Flow BOD TSS (MGD) (mg/L) (mglL) Fecal Coliform #1100 mL) Oil and Total Total Grease Nitrogen Phosphorus (mg/L) ((mg/L mg/L Average <5 037 0.07 Maximum 17<0.28 Minimum 8.23 0< In addition to the aforementioned outfalls, there are two sump overflow outfalls — 002A and 002B, the coal yard sump overflow and powerhouse sump overflow, respectively. These discharge to the Catawba River in the event that all pumps in the sump fail. Both were approved in May 15, 2000. Outfall 002, has only discharged once in the last five years; outfall 002B has discharged twice in the last five years. Correspondence. The Mooresville Regional Office (MRO) conducted six site visits and submitted corresponding Compliance Evaluation Inspection Reports. The facility typically received satisfactory ratings on these reports and was described as well maintained with an effluent that showed no visible adverse impacts to the receiving stream. Two inspections did reveal violations of the iron daily maximum limit: — one Notice of Violation (NOV) was issued for this exceedence in October 2000. The facility has also received an NOV for a toxicity test failure (January 1997) and a Notice of Deficiency (NOD) for unacceptable solids storage (January 1997). Three compliance biomonitoring inspections were also conducted during the permit period; the facility passed all three. The 2001 staff report prepared for this renewal recommends the following: • Reduce (but not eliminate) oil and grease monitoring at outfalls 002 and 004 • Remove naphthalene, phenol and chromium monitoring at 002. • Reduce BOD, TSS, and fecal coliform monitoring at 002. Fact Sheet NPDES NC0004979Renewal Page 2 PERMITTING STRATEGY Waste Load Allocation (WI,A). The Division prepared the last WLA in 1996 for each of the outfalls. The previous and current effluent limits were based on guidelines and water quality standards. The Division has judged previous parameters and limits to be appropriate for renewal with some exceptions (see Reasonable Potential Analysis). This renewal contains a request to discharge debris and Asiatic clams from the intake screens back into the Catawba River. I spoke with the Division of Fisheries and the Division of Wildlife and both agencies saw no problems with this discharge, provided that no additional detergents or chemicals were added to the effluent. Wayne Jones, a biologist with the Division of Wildlife stated that since Asiatic clams and natural river debris (twigs, etc) are present in the river normally, there should be no problem returning these materials to the river. Since there are no parameters to be monitored for this discharge, it will be treated as a special condition to the permit which specifies that while the permittee may wash the intake screens and send the debris and Asiatic clams back to the river, they may not add any detergents or chemicals to the wastestream without Division ,approval. Reasonable Potential Analysis (RPA). The Division conducted EPA -recommended analyses to determine the reasonable potential for toxicants to be discharged by this facility from outfall 002, based on two and a half years of DMR data (1999 — August 2001). Calculations included: arsenic (As), chromium (Cr), lead (Pb), selenium (Se), copper (Cu), iron (Fe) and oil and grease (O & G). Results suggest no reasonable potential for the facility to discharge As, Cr, Fe and oil and grease. Reasonable potential was demonstrated for Cu and Se. Guidelines require that the NPDES permit (see Guidelines section below) limit Fe, Cu and oil and grease. Arsenic, limited in the current permit, can be monitored monthly now due to no finding of reasonable potential. Arsenic can be reduced to monthly monitoring. Chromium shall remain at a quarterly monitoring frequency and oil and -grease can be reduced to a quarterly monitoring frequency. Phenol and naphthalene, which were not detected during the time period January 1999 -August 2001, shall have their monitoring frequencies reduced to quarterly. In addition, the primary pollutant analysis was reviewed. 001 discharges non -contact cooling water and thus no primary pollutant analysis was performed on effluent from this outfall. The following were detected at outfall 002: aluminum, barium, boron, iron, magnesium, molybdenum, manganese, titanium, antimony, arsenic, sulfate, copper, nickel, selenium, zinc, cyanide and cadmium. Several routes were pursued in the determination of monitoring requirements for these parameters. First, the allowable instream concentrations for all those parameters with criteria (both NC and EPA recommended criteria) were determined. These allowable concentrations were compared against the detected concentrations. The only parameter for which the value of the measured concentration exceeded the allowable concentrator was selenium. This is anticipated, since this comes from coal, and the parameter is currently monitored in the NPDES permit. I then called Roy Byrd of the NC Division of Water Quality Laboratory section in order to determine whether or not the concentrations detected were comparable to those seen in the environment. Mr. Byrd confirmed that the concentrations detected for aluminum, magnesium, manganese, titanium, antimony, copper, zinc and cadmium are either below or in the range of ambient values. Moreover, given the facility's excellent toxicity record, there is little :reason for concern about the impact of these toxicants on the receiving stream. With the exception of zinc, these parameters shall not have monitoring requirements associated with'them beyond what it already present in the NPDES permit. Copper (already monitored in the NPDES permit) and zinc are now required monitoring parameters for all major industries (at outfalls with toxicity test requirements) in North Carolina as per the Division's Action Level policy. To determine how the remainder of the parameters would be treated, I spoke with Marcus Zobrist of EPA Central (10/24/01). He confirmed that if water quality standards are not present, no limits should be included. However, he did recommend (for those parameters with water Fact Sheet NPDES NC0004979Renewal Page 3 quality criteria associated with them) a short term monitoring program. This would apply to barium, arsenic, sulfate, nickel, cyanide, iron and cadmium. Arsenic and iron are already in the current NPDES permit, those monitoring requirements and limits will continue to apply. Quarterly monitoring is recommended for barium, sulfate, nickel, cyanide and cadmium. If the permittee wishes to submit 10-12 samples for re-evaluation of the monitoring requirements, this is permitted under Division policy. A similar procedure was followed for outfall 003. Aluminum, barium, iron, magnesium, molybdenum, manganese, titanium, sulfate, copper and zinc were detected. Aluminum, iron, manganese, copper and zinc were all detected at levels below or similar to ambient. Barium was detected at 0.022 mg/1 with an allowable concentration of 11.2 mg/L, which does not justify a monitoring requirement. Sulfate and iron will be included as new monitored parameters at this outfall, with analyses to be performed on a quarterly basis. For outfall 004, aluminum, barium, iron, magnesium, manganese, titanium, sulfate, copper and zinc were detected. Aluminum, manganese, copper and zinc were detected at levels at or below ambient concentrations for those pollutants. Barium was detected at 0.019 mg/l, a level significantly below the allowable concentration of 8.6 mg/L. Since magnesium and titanium do not have criteria associated with them, iron and sulfate are the only parameters that will be monitored at this outfall. Monitoring will be done on quarterly basis. SUMMARY OF PROPOSED CHANGES In keeping with Division policies the following will be incorporated into the permit: • Reduction of phenol, naphthalene, oil and grease monitoring to quarterly at outfall 002. • Remove arsenic limit, reduce monitoring frequency to monthly • Maintain total copper, total iron and total selenium limits. Twice monthly monitoring for copper and selenium as per Division policy for Class I facilities. Monthly monitoring for total iron. • Reduce BOD and fecal coliform monitoring to quarterly. Due to frequency of detects, maintain TSS monitoring at monthly. • Reduce oil and grease monitoring at 004 to quarterly due to non -detects. • Add quarterly zinc monitoring to outfall 002. • Add quarterly barium, sulfate, nickel, cyanide and cadmium monitoring to outfall 002. • Add quarterly sulfate and iron monitoring to 003 and 004. Include note in cover letter that permittee may wish to test the source water to ensure that it is not the source of these pollutants New Weekly Average and Daily Maximum limits are derived from the latest NC/EPA policies considering V2 FA.Vs and allowable concentrations based on reasonable potential. ENCLOSURES: Reasonable Potential Analysis for outfall 002, primary pollutant analysis (ppa) for 002-004, aquatic toxicity data, Mooresville Regional Office staff report. Additional compliance data available upon request. PROPOSED SCHEDULE FOR PERMIT ISSUANCE Draft Permit to Public Notice: November 7, 2001. Permit Scheduled to Issue: January 7, 2002. NPDES DIVISION CONTACT If you have questions regarding any of the above information or on the attached permit, please contact Natalie Sie33-504 ext. 551. NAME: l DATE: Fact Sheet NPDES NC0004979Renewal Page 4 REGIONAL OFFICE COMMENTS et,✓ �jP.IJ— GC J NAME: 4 4�1a—1 DATE: l � SUPERVISOR: ��%� DATE:T� Fact Sheet NPDES NC0004979Renewal Page 5 Facility Name = Qw (MGD) = WWTP Classification NPDES # = Receiving Stream IWC (%) = Final Results 16.00 Reasonable Potential Summary 10 20 30 40 —777 Stream Classification 7Q] Os (cfs)= 95 30Q2 av cfs' Arsenic I Implementation 1 Max. Pred Cw 168.3 µg/1 lAre all reported values less than? No Limit? No I Monitoring Allowable Cw 312.5 µg/1IIs the detection limit acceptable? Ycs Monitor? Yes Frequency Monthly Chromium IImplementation Max. Pred Cw 2.0 µg/l Are all reported values less than? Yes Limit? No 1 Monitoring Allowable Cw 312.5 µg/l IIs the detection limit acceptable? . Yes x_ 'Monitor? No l Frequency None I!2 FAU: S h 1022 ug/# , 1 I Copper, IImplementation Max. Pred Cw . 53.2 µg/1. 'Are all reported values less than? No Limit? No :'Monitoring Allowable Cw 43.8 µg/l !Is the detection limit acceptable? Yes „Monitor? Yes Frequency Monthly Ill FAVP1 U2 PAU 5 8g/1 1 Iron 'Implementation IAre ' + Max. Pred Cw 1.5 µg/1 all reported values less than? No Limit? No '� Monitoring Allowable Cw 6.3 µg/1 IIs the detection limit acceptable? �Yes_ , Monitor? Yes I Frequency Monthly Lead I Implementation I Max. Pred Cw 5.0 µg/1 IAre all reported values less than? Yes Limit? No I Monitoring Allowable Cw 156.3 µg/1 IIs the detection limit acceptable? 1, 7 Monitor? No 1 Frequency None $ . b .55 f . ' a .. _ , "1 11 µgib 1 y -:3 I Oil & Grease IImplementation I Max. Pred Cw 2.5 mg/L Are all reported values less than? Yes Limit? No ' Monitoring Allowable Cw 187.5 mg/L !Is the detection limit acceptable? sds =Monitor? No !Frequency None Selenium lImplementation Max. Pred Cw 38.6 µg/1 IAre all reported values less than? No Limit? Yes I Monitoring Allowable Cw 31.3 µg/1 'Is the detection limit acceptable? i(es Monitor? Yes ' Frequency 2/Month Facility Name = Duke Power - Allen Steam Station NPDES # = NC0004979 Qw (MGD) = 25.7 7Q] Os (cfs)= 95 IWC (%) = 16.00 of data points FINAL RESULTS Arsenic 2.01 Max. Pred Cw 168.3405758 Allowable Cw 312.5 Allowable Cw 312.5 µg/1 RESULTS Arsenic Std Dev. 26.9466 Mean 43.1 C.V. 0.6255 Number 48.700 of data points 32 Mult Factor = 2.01 Max. Value 83.6 µg/1 Max. Pred Cw 168.3405758 µg/1 Allowable Cw 312.5 µg/1 Date n < Jan -99 1 Feb -99 2 Mar -99 3 Apr -99 4 May -99 5 Jun -99 6 Jul -99 7 Aug -99 8 Sep -99 9 Oct -99 10 Nov -99 11 < Dec -99 12 Jan -00 13 Feb -00 14 Mar -00 15 Apr -00 16 May -00 17 Jun -00 18 Jul -00 19 Aug -00 20 Sep -00 21 Oct -00 22 Nov -00 23 Dec -00 24 Jan -01 25 Feb -01 26 Mar -01 27 Apr -01 28 May -01 29 Jun -01 30 Jul -01 31 Aug -01 32 Parameter = Arsenic Standard = 50 0 µg/1 Actual Data BDL=1/2DL 48.7 48.700 24.4 24.400 20.2 20.200 63 63.000 83.6 83.600 56.2 56.200 62.6 62.600 79.8 79.800 55 55.000 39.9 39.900 2 1.000 20.3 20.300 5.3 5.300 15.9 23.1 32.4 20.5 17.1 23 19.1 3.5 5.7 3.4 3.9 13 4.5 4.7 14.4 10.4 13.2 16.6 .. 9.2 Facility Name = NPDES # = Qw (MGD) = 7QIOs (cfs)= IWC (%) = Duke Power - Allen Steam Station NC0004979 25.7 95 16.00 Max. Pred Cw 53.2 FINAL RESULTS Copper Max. Pred Cw Allowable Cw 53.2 43.8 µg/1 3 Std Dev. 6.4943 Mean 12.2 C.V. 0.5314 of data points 32 tifult Factor = 1.84 Parameter Copper Standard = w7 0� µg/1 Actual Data BDL=1/2DL Max. Value 29.0 µg/1 Max. Pred Cw 53.2 µg/l Allowable Cw 43.8 µg/1 Date n < Parameter Copper Standard = w7 0� µg/1 Actual Data BDL=1/2DL Jan -99 1 12.50 12.5 Feb -99 2 9.00 9.0 Mar -99 3 7.00 7.0 Apr -99 4 6.00 6.0 May -99 5 9.60 9.6 Jun -99 6 6.00 6.0 Jul -99 7 11.00 11.0 Aug -99 8 5.00 5.0 Sep -99 9 9.00 9.0 Oct -99 10 7.00 7.0 Nov -99 11 7.00 -7.0 Dec -99 12 20.00 20.0 Jan -00 13 25.00 25.0 Feb -00 14 14.00 14.0 Mar -00 15 13.00 13.0 Apr -00 16 7.00 7.0 May -00 17 2.00 2.0 Jun -00 18 5.00 5.0 Jul -00 19 9.00 9.0 Aug -00 20 12.00 12.0 Sep -00 21 29.00 29.0 Oct -00 22 23.00 23.0 Nov -00 23 16.00 16.0 Dec -00 24 21.00 21.0 Jan -01 25 10.00 10.0 Feb -01 26 13.00 13.0 Mar -01 27 22.00 22.0 Apr -01 28 15.00 15.0 May -01 29 17.00 17.0 Jun -01 30 11.00 11.0 Jul -01 31 8.00 8.0 Aug -01 32 10.00 10.0 Facility Name = NPDES # = Qw (MGD) = 7QIOs (cfs)= IWC (%) = Duke Power - Allen Steam Station NC0004979 25.7 95 16.00 2 < FINAL RESULTS Chromium Max. Pred Cw Allowable Cw 2.0 312.5 RESULTS Std Dev. 0.0000 Mean 2.0 C.V. 0.0000 lof data points 14 Mult Factor = 1,00 Max. Value 2.0 µg/l Max. Pred Cw 2.0 µg/l Allowable-Cw 312.5 µg/1 Parameter = IChromium Standard= Date n < Actual Data BDL=1/2DL Feb -99 1 < 4 2.0 May -99 2 < 4 2.0 Aug -99 3 < 4 2.0 Nov -99 4 < 4 2.0 Feb -00 5 < 4 2.0 May -00 6 < 4 2.0 Aug -00 7 < 4 2.0 NOV-00 8 < 4 2.0 Feb -01 11 < 4 2.0 Apr -01 12 < 4 2.0 Jun -01 13 < 4 2.0 Aug -01 14 < 4 2.0 Facility Name = Duke Power - Allen Steam Station NPDES # = NC0004979 Qw (MGD) = 25.7 7Q] Os (cfs)= 95 IWC (%) = 16.00 0.3 FINAL RESULTS Iron 0.295 Max. Pred Cw 1.5 Allowable Cw 6.3 Std Dev. 0.1501 Mean 0.2 C.V. 0.6153 of data points 32 Mult Factor = 2.01 Max. Value 0.7 µg/I Max. Pred Cw 1.5 µg/1 Allowable Cw 6.3 µg/1 Date n Parameter= Iron Standard = 10 < Actual Data BDL=1/2DL Jan -99 1 0.5433 0.5 Feb -99 2 0.265 0.3 Mar -99 3 0.295 0.3 Apr -99 4 0.27 0.3 May -99 5 0.4333 0.4 Jun -99 6 0.2 0.2 Jul -99 7 0.25 0.3 Aug -99 8 0.255 0.3 Sep -99 9 0.275 0.3 Oct -99 10 0.31 0.3 Nov -99 11 0.36 0.4 Dec -99 12 0.255 0.3 Jan -00 13 0.315 0.3 Feb -00 14 0.425 0.4 Mar -00 15 0.7466 0.7 Apr -00 16 0.17 0.2 May -00 17 0.1333 0.1 Jun -00 18 0.105 0.1 Jul -00 19 0.105 0.1 Aug -00 20 0.09 0.1 Sep -00 21 0.1 0.1 Oct -00 22 0.165 0.2 Nov -00 23 0.105 0.1 Dec -00 24 0.155 0.2 Jan -01 .25 0.08 0.1 Feb -01 26 0.15- 0.2 Mar -01 27 0.38 0.4 Apr -01 28 0.35 0.4 May -01 29 0.19 0.2 Jun -01 30 0.1 0.1 Jul -01 31 0.14 0.1 Aug -01 32 0.09 0.1 Facility Name = Duke Power - Allen Steam Station NPDES # = NC0004979 Qw (MGD) = 25.7 7QIOs (cfs)= 95 IWC (%) = 16.00 FINAL RESULTS Lead Max. Pred Cw 5.0 Allowable Cw 0.0 RESULTS n < Std Dev. 0.0000 Apr -99 Mean 5.0 10.0 C.V. 0.0000 2 Number 10.0 5.0 of data points 24 < Mult Factor = 1.00 Jul -99 Max. Value 5.0 µg/I Max. Pred Cw 5.0 µg/1 Allowable Cw 156.3 µg/l Parameter = Lead Standard = 25.0 µg/1 Date n < Actual Data BDL=1/2DL Apr -99 1 < 10.0 5.0 May -99 2 < 10.0 5.0 Jun -99 3 < 10.0 5.0 Jul -99 4 < 10.0 5.0 Sep -99 5 < 10.0 5.0 Oct -99 6 < 10.0 5.0 Nov -99 7 < 10.0 5.0 Dec -99 8 < 10.0 5.0 Jan -00 9 < 10.0 5.0 Feb -00 10 < 10.0 5.0 Mar -00 11 < 10.0 5.0 Apr -00 12 < 10.0 5.0 May -00 13 < 10.0 5.0 - Jun -00 14 < 10.0 5.0 Jul -00 15 < 10.0 5.0 Aug -00 16 < 10.0 5.0 Sep -00 17 < 10.0 5.0 Oct -00 18 < 10.0 5.0 Nov -00 19 < 10.0 5.0 Dec -00 20 < 10.0 5.0 Jan -01 21 < 10.0 5.0 Feb -01 22 < 10.0 5.0 Mar -01 23 < 10.0 5.0 Apr -01 24 < 10.0 5.0 Facility Name = Duke Power - Allen Steam Station 1.59. NPDES # = NC0004979 24.2 µg/1 Qw (MGD) = 25.7 38.6 µg/1 7QIOs (cfs)= 95 31.3 µg/1 IWC (%) = 16.00 3 FINAL RESULTS 10.3 Selenium 4 Max. Pred Cw 38.6 21.5 Allowable Cw 31.3 5 20.5 RESULTS Std Dev. 5.2260 Mean 13.2 C.V. 0.3972 of data points 32 Mult Factor = 1.59. Max. Value 24.2 µg/1 Max. Pred Cw 38.6 µg/1 Allowable Cw 31.3 µg/1 Parameter =I Selenium Standard Date n < Actual Data BDL=1/2DL Jan -99 1 14.3 14.3 Feb -99 2 10.7 10.7 Mar -99 3 10.3 10.3 Apr -99 4 21.5 21.5 May -99 5 20.5 20.5 Jun -99 6 20.4 20.4 Jul -99 7 22.7 22.7 Aug -99 8 24.2 24.2 Sep -99 9 20 20.0 Oct -99 10 11.9 11.9 Nov -99 11 < 2.0000 1.0 Dec -99 12 9 9.0 Jan -00 13 5.7 5.7 Feb -00 14 9.2 9.2 Mar -00 15 11.9 11.9 Apr -00 16 11.3 11.3 May -00 17 12.3 12.3 Jun -00 18 16.9 16.9 Jul -00 19 17.4 17.4 Aug -00 20 16.9 16.9 Sep -00 21 11.4 11.4 Oct -00 22 9.8 9.8 Nov -00 23 9.1 9.1 Dec -00 24 8.6 8.6 Jan -01 25 14.8 14.8 Feb -01 26 9.3 9.3 Mar -01 27 8.4 8.4 Apr -01 28 12 12.0 May -01 29 10 10.0 Jun -01 30 12.2 12.2 Jul -01 31 12.9 12.9 Aug -01 32 14.4 14.4 Primary pollutant analysis results for Duke Energy's Allen Steam Plant NC0004979 Outfall 002 Parameter of concern Aluminum Barium Iron Magnesium Manganese Titanium Sulfa#e, Copper Zinc (ng/L) (m9/1) L..(m9EA) ,°: (mg/L) (mg/L) (mg/L) (rrt9/L)' (ug/L) (mg/L) Actual concentration 0.4 0.019 01&" , 2 0.056 0.019 18 3 �. 0.009 0.007 Allowable concentration 4.69 8.66 8 6i` not a POC 1.73 not a POC 2 t65, 60.6 0.433 red font indicates that all. Conc. Based upon EPA Rec. Criteria fields in bold (no highlighting) indicate that concentration detected is around ambient or tap water values (conversation with Roy Byrd, 10/24/01) fields with highlighting indicate those parameters that will require periodic monitoring to ensure that the discharge has no impact on the water quality of the receiving stream. Parameter of concern Parameter of concern Aluminum >aum Boron IYon Magnesium Molybdenum Manganese Titanium Antimony Arsenrc Iron Magnesium (mg/L) CgFI (n►9/L) €....(9f}.,,. . (m9IL) (m9/L) (mg/L) (mg/L) (ug/L)(�!9/�-).,:' Actual concentration 0.208 W'468 0.363 125 2.48 0.083 0.11 0.011 7.12 32 4 Allowable concentration • 4.69 6„��5, x not a POC��3 4 ,,a not a POC not a POC 0.677 not a POC not a POC X69 2 Parameter of concern Sulfate Copper I Nickel Selenium Zinc Cyanide Cadmium 0.04 0.018 (u9/L) ()�g/L) (u91L)...` (mg/L) (mg/L) (ug/L) Allowable concentration 10.75 14.33; 14 3�� not a POC not a POC 2.87 not a POC Actual concentration 49 4 0.029 x 12.8 17 0.024 0.0025 0.52 Allowable concentration �g ;, •84'6 -„M 23.7 8 4, : 1 9 0.1692 0.0169 6.8 Outfall 003 Parameter of concern Aluminum Barium Iron Magnesium Manganese Titanium Sulfa#e, Copper Zinc (ng/L) (m9/1) L..(m9EA) ,°: (mg/L) (mg/L) (mg/L) (rrt9/L)' (ug/L) (mg/L) Actual concentration 0.4 0.019 01&" , 2 0.056 0.019 18 3 �. 0.009 0.007 Allowable concentration 4.69 8.66 8 6i` not a POC 1.73 not a POC 2 t65, 60.6 0.433 red font indicates that all. Conc. Based upon EPA Rec. Criteria fields in bold (no highlighting) indicate that concentration detected is around ambient or tap water values (conversation with Roy Byrd, 10/24/01) fields with highlighting indicate those parameters that will require periodic monitoring to ensure that the discharge has no impact on the water quality of the receiving stream. Parameter of concern Aluminum Barium Iron Magnesium Molybdenum Manganese Titanium Sulfate Copper Zinc (ng/L) (mg/1) {mgll? (mg/L) (mg/L) (mg/L) (mg/L) (rig/L) (ug/L) (mg/L) Actual concentration 0.304 0.022 0 537 1.91 0.04 0.018 0.018 14 4 0.014 0.008 Allowable concentration 10.75 14.33; 14 3�� not a POC not a POC 2.87 not a POC 100.3 0.717 Outfall 004 Parameter of concern Aluminum Barium Iron Magnesium Manganese Titanium Sulfa#e, Copper Zinc (ng/L) (m9/1) L..(m9EA) ,°: (mg/L) (mg/L) (mg/L) (rrt9/L)' (ug/L) (mg/L) Actual concentration 0.4 0.019 01&" , 2 0.056 0.019 18 3 �. 0.009 0.007 Allowable concentration 4.69 8.66 8 6i` not a POC 1.73 not a POC 2 t65, 60.6 0.433 red font indicates that all. Conc. Based upon EPA Rec. Criteria fields in bold (no highlighting) indicate that concentration detected is around ambient or tap water values (conversation with Roy Byrd, 10/24/01) fields with highlighting indicate those parameters that will require periodic monitoring to ensure that the discharge has no impact on the water quality of the receiving stream. y .' . Duke Power - Allen Steam Station NC0004979 DMR data review for outfalls 001-004 by: Natalie Sierra 10/15/01 Outfall 002 - Date Flow BOD TSS Fecal Coliform Oil and Grease Total N Total P Arsenic Chromium Copper Iron Selenium Phenols Napthalene (MGD) (mg/L) (mg/L) (#/100 mL) (mg/L) (mg/L) (mg/L) (ug/L) (ug/L) (mg/L) (mg/L) (ug/L) (ug/L) (ug/L) Jan -99 8.2333 0 25 13 0 48.7 0.0125 0.5433 14.3 <10 <10 Feb -99 8.525 13 7 4 0 0.4 0.28 24.4 <4 0.009 0.265 10.7 <10 <10 Mar -99 20.12 0 8 2 0 20.2 0.007 0.295 10.3 <10 <10 Apr -99 16.475 2 8 2 0 63 0.006 0.27 21.5 <10 <10 May -99 14.02 0 15.7 2 0 83.6 <4 0.0096 0.4333 20.5 <10 <10 Jun -99 18.72 0 8 2 0 56.2 0.006 0.2 20.4 <10 <10 Jul -99 16.725 0 23 4 0 62.6 0.011 0.25 22.7 <10 <10 Aug -99 15.76 0 20 4 0 0.26 0.109 79.8 <4 0.005 0.255 24.2 <10 <10 Sep -99 17.5 0 13 7 0 55 0.009 0.275 20 <10 <10 Oct -99 16.625 0 12 2 0 39.9 0.007 0.31 11.9 <10 <10 Nov -99 21.66 0 26 4 0 0.34 0.069 0 <4 0.007 0.36 0 <10 <10 Dec -99 24.475 4.4 23 0 0 20.3 0.02 0.255 9 <10 <10 Jan -00 22.05 0 4 0 0 5.3 ' 0.025 0.315 5.7 <10 <10 Feb -00 21.5 0 27.6 4 0 0.39 0.031 15.9 <4 0.014 0.425 9.2 <10 <10 Mar -00 18.95 7.5 23 2 0 23.1 0.013 0.7466 11.9 <10 <10 Apr -00 21.625 3.7 7 0 0 32.4 0.007 0.17 11.3 <10 <10 May -00 20.88 4.8 10 0 0 20.5 <4 0.002 0.1333 12.3 <10 <10 Jun -00 20.972 0 5 17 0 17.1 0.005 0.105 16.9 <10 <10 Jul -00 18.875 0 7 0 0 23 0.009 0.105 17.4 <10 <10 Aug -00 19.94 26 8 0 0 19.1 <4 0.012 0.09 16.9 <10 <10 Sep -00 20.775 0 5 0 0 3.5 0.029 0.1 11.4 <10 <10 Oct -00 14.5 0 6 0 0 5.7 0.023 0.165 9.8 <10 <10 Nov -00 17.55 0 5 0 0 0.53 0.008 3.4 <4 0.016 0.105 9.1 <10 <10 Dec -00 20.225 2.8 0 0 0 3.9 0.021 0.155 8.6 <10 <10 Jan -01 21.42 2.2 6 0 0 13 0.01 0.08 14.8 <10 <10 Feb -01 20.5 0 10 0 0 0.4 0.011 4.5 <4 0.013 0.15 9.3 <10 <10 Mar -01 23.12 0 7 0 0 4.7 0.022 0.38 8.4 <10 <10 Apr -01 20.4 0 22 4 0 14.4 <4 0.015 0.35 12 <10 <10 May -01 24.62 0 4 2 0 10.4 0.017 0.19 10 <10 <10 Jun -01 22.05 0 7 0 0 13.2 <4 0.011 0.1 12.2 <10 <10 Jul -01 25.02 0 14 2 0 16.6 0.008 0.14 12.9 <10 <10 Aug -01 25.775 0 11 0 0 0.24 0 9.2 <4 0.01 0.09 14.4 <10 <10 Aver�l9?r. ., .... , X19 36 2 08 11.79..u.. .,.. , . `,.. 2 41_ _ _ _i ..._, 4 00..�.a; .0 37 _ .. 0 Q , , 25:3 0 t.... .0.24,a,.�, ..�-13 5 tQ b..;,.k > <10 ..'. max 25.775 26 27.6 17 0 0.53 0.28 83.6 min 8.2333 0 0 0 0 0.24 0 0 D.L. D.L. 2.0 mg/L 5.0 mg/L y �, NC0004979 DMR data review for outfalls 001-004 by: Natalie Sierra 10/15/01 Outfall 001 Date Date Flow Temperature Jan -99 (MGD) (deg .C) Jan -99 224.8741 52.89 Feb -99 194.0178 May -99 Mar -99 544.8903 6 Apr -99 444.47 Aug -99 May -99 619.2838 6 Jun -99 731.9266 38.9 Jul -99 770.8225 6 Aug -99 774.7612 Feb -00 Sep -99 637.8233 6 Oct -99 500.529 35 Nov -99 491.333 6 Dec -99 505.087 Aug -00 Jan -00 405.1451 56.5 Feb -00 365.2827 Nov -00 Mar -00 382.0903 6 Apr -00 413.55 Feb -01 May -00 577.7612 6 Jun -00 766.07 38.9 Jul -00 764.0741 6 Aug -00 780.9354 Aug -01 Sep -00 698.71 Oct -00 448.9096 35 Nov -00 539.8266 Dec -00 584.7903 Jan -01 530.7838 56.76 Feb -01 382.3392 Mar -01 5533.806 Apr -01 531.333 May -01 663.5677 Jun701 741:3966 38.9 Jul -01 759.3677 Aua-01 777.3419 Outfall 003 Date Flow (MGD) Jan -99 6 Feb -99 6 Mar -99 6 Apr -99 6 May -99 6 Jun -99 6 Jul -99 6 Aug -99 6 Sep -99 6 Oct -99 6 Nov -99 6 Dec -99 6 Jan -00 6 Feb -00 6 Mar -00 6 Apr -00 6 May -00 6 Jun -00 6 Jul -00 6 Aug -00 6 Sep -00 6 Oct -00 6 Nov -00 6 Dec -00 6 Jan -01 6„ Feb -01 6 Mar -01 6 Apr -01 6 May -01 6 Jun -01 6 Jul -01 6 Aug -01 6 AveFage 6 004 (MGD) Jan -99 8 Feb -99 8 Mar -99 8 Apr -99 8 May -99 8 Jun -99 8 Jul -99 8 Aug -99 8 Sep -99 8 Oct -99 8 Nov -99 8 Dec -99 8 Jan -00 8 Feb -00 8 Mar -00 8 Apr -00 8 May -00 8 Jun -00 8 Jul -00 8 Aug -00 8 Sep -00 8 Oct -00 8 Nov -00 8 Dec -00 8 Jan -01 8 Feb -01 8 Mar -01 8 Apr -01 8 May -01 8 Jun -01 8 Jul -01 8 Aug -01 8 (mg/L) <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 Whole Effluent Toxicity Testing Self -Monitoring Summary FACILITY REQUIREMENT YEAR JAN FEB MAR APR MAY JUN JUL AUG SEP OCT September 25, 2001 NOV DEC Cyprus Foote Mineral CoAOI Perm 24hrp/fac monit: 90%fthd (grab) 1997 — — — — — Pass — — — — — — NC0033570/001 Begin: 1 /1/1999 Frequency: A NonComp: 1998 — — — — — Pass — — — — — — County: Cleveland Region: MRO Subbasin: BRD05 — NR 1999 -- — — — — Fail — Fail,Pass Pass — — — PF: NA Special 2001 Fail 2000 — Pass — — — -- — — — — — — 7Q10:0.9 IWC(%):17 Order: Pass 2001 — — Pass — — — — — Pass -• -- Pass -- -- Pass Dan River Inc. Harris Facility Perm chr tun: 0.75% County: Gaston Region: MRO Subbasin: CTB34 1997 — -- >100 — — >100 — — >100 — — Late NCO083275/001 Begim2/1/1999 Frequency:Q + Mar Jun Sep Dec + NonComp:Single 1998 >100 — >100 — — >100 — — >100 — — >100 ' County: Rutherford Region: ARO Subbasin: BRD02 1999 — — Pass — — Pass — — Pass — — Pass PF: 0.91 Special 1995 — 2000 — — Pass — — Pass — — Pass — — Pass 7Q10:186 IWC(%):0.75 Order: — 2001 — — Pass — — Pass — — — Pass — — Late Pass — Dare County-(RO)/001 Penn 24hr p/fac monit: 90%mysid 7Q10:24.0 IWC(%):33.0 Order: 1997 Poss(s) — — Pass — — Pass — — Feil,Pass — — NC0070157/001 13egin:5/1/1995 Frequency: Q Jan Apr Jul Oct NonComp: 1998 Pass — — Fail,Pass — -- Fail,Pass — — Pass — — County: Dare Region: WARO Subbasin: PAS56 1999 Pass — — Pass — -- Pass — — Pass -- — PF: NA Special 2000 at at — Pass — -- Pass — •- Pass — — 7QI0:0 IWC(%)NA Order: 2001 Pass — — Pass — — Pass Dare County-(RO)/002 Perm 24hr p/fac monit: 90% mysid 1997 Fail(s).Pass -- — Pass — — Pass — — Fail,Pass — — NC0070157/002 Begin:5/l/1995 Frequency: Q P/F Jan Apr Jul Oct NonComp: 1998 Pass — — Pass — — Pass — — Pass — — County: Dare Region: WARO Subbasin: PAS56 1999 Pass — — Pass — — Pass — — Pass — — PF: NA Special 2000 at — — Fail Fail,Pass — Pass — — Fail,Failt — — 7QI0:0 IWC(%):100 Order: 2001 Pass — — Pass — — Pass Delta Mills P2 -perm chr lim: 11%; if exp 1.5MGD chr lim 16% 1997 — — 16 — — 16 — — Late 31 — >44 NC0006190/001 Begin:3/1/1998 Frequency: Q Mar Jun Sep Dec + NonComp:ChV Avg 1998 — — 31 — — 31 — 31 — — 16 County: Catawba Region: MRO Subbasin: CTB35 1999 — — 16 — — at — — 15 — — 31 PF: 1.0 Special 2000 — -- 4.1 <3 Late 15.6,15.6 — — 31 — — 15.6 7QI0: 12 IWC(,/.):Il Order: 2001 — -- 31.1 — — 15.6 — Denton WWTP Perm car lim: 90% 1997 Fell Pass — — Pass — — Fail Pass — Pass — NC0026689/001 Begin:4/1/2000 Frequency: Q Feb May Aug Nov + NonComp:Single 1998 — Pass — — Pass — — Pass — — Fail,Pass — County: Davidson Region: WSRO Subbasin: YAD08 1899 — Pass — — >90 — — 51.9 73.48 >90 >90 -- PF: 0.30 Special 2000 — 21.2 >90 -- 36.7 >90 — Pass — — Pass — 7Q10:0.0 IWC(%):100 Order: 2001 — Pass — — Pass — — Dixie Yarns, Inc. Perm chr lim: 90% (Grab) 1997 — — 1997 Pass — — Pass — — Pass — — Pass — -- NC0083763/001 Begin:5/1/2000 Frequency:Q Jan Apr Jul Oct + NonComp:Single 1998 — Pass — Pass — — Late Pass — Pass — — County: Stanly Region: MRO Subbasin: YAD12 — Pass — 1999 Pass — — NR/Pass — — Fall Pass — NR Pass — PF: 0.072 Special 1997 — — 2000 Fall Pass — Pass — — Fall >100 >100 NR Pass — 7Q10:0 iWC(%):100 Order: — Pass 2001 Fail >100 97.5 Lela H H H — Pass PF: 8.8 Special 2000 — — Duke Power -Allen 002 Perm chr lim: 16% (Grab) -- Pass — 1997 Fall FaiV Pass Pass -- — Pass — -- Pass — — NC0004979/002 Begin: l0/1/1996 Frequency: Q P/F + Jan Apr Jul Oct NonComp:Single 6 1998 Pass — — Pass -• -- Pass -- -- Pass — — County: Gaston Region: MRO Subbasin: CTB34 1999 Pass -- — Pass -- — Pass — — Pass — — PF: 11.6 Special 2000 Pass — — Bl — -- Late Pass — Pass — — 7Q10:95.0 IWC(%):16,� Order: 2001 Pass — — Pass — — Pass Duke Power-Belews Creek/003 Perm chr lim: 19% (Grab) 1997 — Pass — — Pass — -- Pass — — Fail,Pass — NC0024406/003 Begin:2/I/1998 Frequency: Q P/F + Feb May Aug Nov + NonComp:Single 1995 — Pass — — Pass — — Pass — — Pass — County: Stokes Region: WSRO Subbasin: ROA01 1999 — Pass — — Pass — — Pass — — Pass — PF: 7.7 Special 2000 — Pass — — Pass — — Late Pass — Pass — 7Q10:24.0 IWC(%):33.0 Order: 2001 — Pass — — Pass — — Duke Power -Buck Steam Perm chr lim: 0.7% (grab) 1997 — — >100 — — >100 — — >100 — — >100 NC0004774/002 Begin:2/1/2000 Frequency: Q Mar Jun Sep Dec + NonComp:Single 1998 — — >100 — — >100 — — >100 -- — >100 County: Rowan Region: MRO Subbasim YAD04 1999 — — >100 — — >100 — — >100 — — >100 PF: NA Special 2000 — — BI — — Pass — — Pass — — Pass 7QI0: 1030 IWC(%):0.598 Order: 2001 — — Pass — — Pass -- Duke Power-CBfisidePearn chr am: 5.6% (Grab) 1997 — — Pass — — Pass — — Pass — — Pass NC0005088/002 Begin:3/1/1999 Frequency: Q P/F + Mar Jun Sep Dec + NonComp:Single 1998 — — Pass — — Pass — — Pass — — Pass County: Rutherford Region: ARO Subbasin: BRD02 1999 — — Pass -- — Pass -- — Pass — — Pass PF: 8.8 Special 2000 — — at — -- Pass — — Pass -- — Pass 7Q10:287 IWC(%):4.53 Order: 2001 — — Pass — — Pass — LEGEND: PERM - Permit Requirement LET = Administrative Letter - Target Frequency = Monitoring frequency: Q• Quarterly; M- Monthly; BM- Bimonthly; SA- Semiannually; A- Annually; OWD- Only when discharging, D- Discontinued monitoring requirement Begin= First month required 7Q10 = Receiving stream low flow criterion (cfs) += quarterly monitoring increases to monthly upon failure or NR Months that testing must occur -ex. Jan, Apr, Jul, Oct NonComp = Current Compliance Requirement PF = Permitted flow (MGD) 1 WC% = ]nstream waste concentration P/F = Pass/Fa0 test AC = Acute CHR = Chronic Data Notation: f - Fathead Minnow; • - Ceriodaphnia sp.; my - Mysid shrimp; ChV - Chronic value; P - Mortality of stated percentage at highest concentration; at - Performed by DWQ Aquatic Tox Unit; bt - Bad test Reporting Notation: --- = Data not required; NR - Not reported Facility Activity Status: I - Inactive, N - Newly lssued(To construct); H - Active but not discharging; t -More data available for month in question; • = ORC signature needed 16 t' Z' - Intake vs 002 Fe 111cr000 q Subject: Intake vs 002 Fe Date: Tue, 4 Dec 200109:47:25 -0500 From: "John R Mease" <jrmease@duke-energy.com> To: Natalie.Sierra@ncmail.net CC: 'Donald L Scruggs" <dlscrugg@duke-energy.conl> Natalie, Thanks for "meeting" with us yesterday, you we -re very helpful. Below is the iron data that we discussed concerning the intake vs ash basin at Plant Allen. Let me know if you have questions. Thanks for your help! John ----- Forwarded by John R Mease/Gen/DukePower on 12/04/2001 09:30 AM ----- Donald L Scruggs To: John R Mease/Gen/DukePower@DukePower, Robert R Wylie/Gen/DukePower@DukePower 11/29/2001 cc: 10:31 AM bcc: Subject: Intake vs 002 Fe Attached is spreadsheet with 1999-2001 intake Fe concentration vs 002 Fe concentration. (See attached file: allenintake.xls) Name: allenintake.xls [Mallenintake.xls Type: Microsoft Excel Worksheet (application/vnd.ms-excel) Encoding: base64 1 of 1 1/7/02 4:55 PM 'L� Y T M N M Q C O N Mm O O6 co z y O O Cfl M N O co CD -t w 0 0 0 0 0 Y O M00 co N T O Ca I- N O C T O O O O 6 cr c U) C r N M d 0) 0) 0) m c� cd c� cd N p r' 0 (` 0 O O ti r M r M r M CD It d' CD N It N It r N r CO O 1,-T r r t\ O T T O T O"t T M m r O N 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O ,Y *' O GOO O O T T i co i M CD O f, CO CA N Ln r r It d' (� N N N N r� M 0 N M M r M N N N Ln M� L(j 0 N 0 0 0 0 0 0 ,M 0 0 0 6 0 0 0 0 0 0 6 O O Cl co M t- CD tST O d' MN M M r 0 0 OJ O r N Ln O r CA N CO o O p N 0 Lp 0 LO 0 N 0 d cD N r N 0 r 0 r 0 r 0 O 0 r 0 r 0 r 0 0 0 0 0 0 0 r 0 r 0 r 0 r 0 r 0 O 0 N 0 N O Y O O CD co f- d. d D) in C) O M j CD €� T [ Ln M N `. M I,- co CD N r N �t Ln r M 00 M d M I� N Ln Cfl N 00 i- C? 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W W W V O --4 N O N Q. CD "'I O .-t O 0 O 0 CD ZIh O VJ r Re: Draft Permit -Duke Energy Allen Steam Station-NC0004979 Subject: Re: Draft Permit -Duke Energy Allen Steam Station-NC0004979 Date: Wed, 7 Nov 2001 15:51:42 -0500 From: "Matt Matthews" <matt.matthews@ncmail.net> W.To: "Natalie Sierra" <Natalie.Sierra@ncmail.net> Natalie, I've pasted the text into this message and also attached the text in a word document. Hopefully, you can read one or the other. Matt Natalie and Dave, Thanks for the opportunity to review the subject draft permit. Everything in the permit looks good from the tox standpoint. The question I have is concerning the cover letter. The fifth bullet implies that every facility conducting WET testing should also get copper and zinc monitoring per the Action Level Policy. This is not my understanding of how things should work. I thought that Cu and/or Zn monitoring only was required when there was a reasonable potential to exceed the action level standard based on analysis of previous data; once the RP was established, the monitoring requirement was placed in the permit in concert with the WET test. Based on my understanding, there could be facilities with WET testing that do not monitor for copper or zinc. Have I misunderstood something? Let me know what y'all think, Matt Matt Matthews NC DENR/Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, North Carolina 27699-1621 v-(919) 733-2136 f-(919) 733-9959 MailTo:Matt.Matthews@ncmail.net ----- Original Message ----- From: "Natalie Sierra" <Natalie.Sierra@ncmail.net> To: "Matt Matthews" <matt.matthews@ncmail.net> Sent: Wednesday, November 07, 2001 3:30 PM Subject: Re: Draft Permit -Duke Energy Allen Steam Station-NC0004979 > Matt- > For some reason, the letters in your message transmitted in a very > jumbled fashion - I'm not sure what happened. Can you try to send it > again? > Thanks, > Natalie > Matt Matthews wrote: > > Part 1.1 Type: Plain Text (text/plain) > > Encoding: quoted -printable 1 of 2 inm 4:55 PM Review of "Assessment of Balanced and Indigenous Populations in Lake Wylie Near Plant Allen Macroinvertebrate Data Lake Wylie is an intensively" studied system, with data going back many years to 1972. The 1972 data found'very limited -effects, and there appears to have been very few changes in the benthos since that time. Comparison of data from the intake and discharge locations suggests few significant differences, in spite of the fact that we would expect lower water quality in the South Fork arm of the lake. The "downlake" location often has higher taxa richness, but this area has more diverse substrate and (probably) better water quality. We would like the data examined in greater detail in a few ways, and suggest a small additional project for Lake Wylie. Deducing the impact of Plant Allen requires that we first understand other stress factors in Lake Wylie. -Is there any water quality data that would support greatest problems in the South Fork arm? Dissolved oxygen, conductivity, etc.? -We are limited to five years of data for this report, but there is a much longer data set for these locations. We would like to see Table 3-1 (page 3-9) extended back for the entire data set, just for taxa richness values. This would allow a better statistical analysis of between - site differences in water quality. This analysls)is difficult for the small data set presented in this report, due to high variability at the individual sites. Several years, however, suggest a depression in taxa richness at the discharge site (1996. 1998). -Key taxa should be discussed in more detail, especially analysisof fish stomach contents gives you clues to the more important species. We would like to see better than "Oligochaeta" as an identification. *Corbicula is important in many ways, including regulating the flow of energy through the entire benthic community. Does the power plant still influence the distribution of Corbicula as described in Lenat and Weiss (1973)? Is Corbicula still of concern in power plant operation? *Hexagenia is one of the largest organisms in the Lake Wylie benthic community, and is likely to be important as fish food. -The maintenance of rare species should be included in a discussion of "balanced and indigenous" populations. Quickly scanning these species lists, I can see several taxa of note, including Microchironomus, Lipiniella, and Zalutschia zalutschicola. The entire data set should be scanned for this type of species, and we would like to confirm these IDs for our records. -Analysis is basically limited to taxa richness. Has anything else been tried? Biotic Indices? -We would like to see an analysis of midge deformity rates in various portions of the lake. This would need ponar sampling in deeper water to obtain 20-25 Chironomus larvae per site; sites should include areas on both branches of the lake (including above and below the discharge to the South Fork arm), as well as control sites on other arms of the lake. Fisheries Tables 3-4 to 3-9 show a seasonal avoidance of the discharge area as reflected in CPUE and species diversity. The fish avoid the discharge in the summer (how long?) and are attracted to the warmer water during the spring (and presumably the winter). Thus, -this part of the reservoir _does.not support a natural fish community. In the spring electrofishing study discharge? Ten additional sites below the discharge. 1, why are the 10 "reference" sites all located below the the discharge) should be added to compare above, at, and Table 3-13 shows a reservoirwide decline in the forage fish population (primarily threadfin shad, an exotic species) from 230 million tc 54 million to 14 million between 1995 and 1997, yet no explanation for the decline is given. finalized in March 2001.] Is this just a reliable tool for determining a balanic adequacy of a forage fish population o show that the threadfin_shad is found predators in the reference area. This o indigenous fish population: ote: 1999 data were not available when the report was ampling variability? If so, then this would not seem to be ed and indigenous fish population and to determine the the limnetic predators. Tables 3-11 and 3-13 clearly my in the heated area and is not available to the 4imnetic.:' es not support one of their contentions for a balanced and County Gaston NPDES Permit Number NC0004979, Duke Energy Corporation - Allen Steam Station, 13339 Hagers Ferry Road, Huntersville, NC 28078 has applied for a permit renewal for a facility located in Gaston County discharging treated wastewater into Catawba and South Fork Catawba Rivers' in the Catawba River Basin. Currently selenium and iron are water quality limited. This discharge may affect future allocations in this portion of the receiving stream. Wednesday, October 31, 2001 1617 Mail Service Center, Raliegh, North Carolina 27699-1617 -Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer - 50% Recycled / 10% post -consumer paper � �I � �• � / //i/, off � j. ✓� i, � t ' ► � � RI � ,n"w N'o <�sv <%- NULI MN UNm (2LL f-"TVk-tM)-A d Qo + Z,0.' .�" �}v ��� �oL••� �7� �.O �, � �Z� Q I Lb ho:�� ?N I' a<� -k- � vo9 — -T- Permit NC0003719 Methyl Chlorid 0.345 0.156 Annual Grab E Methylene Chlon a 0.162 0.073 Annual Grab E Naphthalene 0.107 0.040 Annual Grab Nitrobenzene 0.124 0.049 Annual Grab 2-Nitrophenol 0.125 0.075 Annual Grab E 4-Nitrophenol 0.225 0.131 Annual Grab E Phenanthrene 0.107 0.040 Annual Grab E Phenol 0.047 0.027 Annual Gr E Pyrene 0.122 0.045 Annual ab E Tetrachloroethylene 102 0.040 Annual Grab E Toluene 0.1 5 0.047 Annual Grab E Total Chromium 5.03 2.017 Quarterly Grab E Total Copper 6.142 1 2.635 Quarte)rf Grab E Total Cyanide 2.181 0.763 Quqjerly Grab E Total Lead 1.254 0.582 arterl Grab E Total Nickel 7.233 3.071 Quarterl Grab E Total Zinc Qu Grab E 1,2,4-Trichlorobenzene 0.254 0.124 Annual Grab E 1,1,1 -Trichloroethane 0.098 0.038 Annual Grab E 1,1,2 -Trichloroethane 0.098 038 Annual Grab E Trichloroethylene 0.098 0. X8 Annual Grab E Vinvl Chloride 1 0.487 1018 Annual Grab E Total PAHsz 1 6940 0 uarterly I Co osite I E Hexachlorobenzene 1.73 1 Quarterly I Comp site I E Notes: N 1. Sample Loca ' n: E - Effluent, I - In uent 2. Total PAHs e comprised of Benzo( )anthracene; Benzo Benzo(k) oranthene; Chrysene; Di enz(a,h)anthracene Note: Com osite samples must be refrigerated 3, 4-B enzofluoranthene; o (1, 2, 3-ed)pyrnene. \ G4vem Z, coo e w x/ 6774 TY,, 6,77 ) 7ry GKEX88/MPI 10/12/2001 COMPLIANCE EVALUATION ANALYSIS REPOT PAGE 1 PERMIT--NC00049'9 PIPE --002 REPORT PERIOD: 9901-9912 FACILITY--DUKE POWER - ALLEN S.E. DESIGN FLOW- 10.000SS--1 LOCATION--BELMONT REGION/COUNTY--03 GASTON /TOTAL 50050 0031 00530 31616 TGP3B 0400 000600 MONTH Q/MGD BOD RES/TSS FEC COLI CERI7DPF PH OIL-G N LIMIT NOL NOL 30.0 NOL NOL 9. 6.0 F 15.NOL 99/01 8.2333 .00 25.0 13.0 1 7.)--7.1 .000 99/02 8.5250 13.00 7.0 4.0 8.)-7.0 .000 .400 99/03 20.1200 .00 0 2.0 8. -7.5 .000 99/04 16.4750 2.00 8.0 2.0 1 6.)_ 5 .000 99/05 14.0200 .00 15.7 2.0 8. -8.0 .000 99/06 18.7200 .00 8.0 2.0 9.)-7.4 .000 99/07 16.7250 .00 23.0 .0 8.7-7.4 .000 99/08 15.7600 .00 20.0 4. 9.)-7.5 .000 .260 99/09 17.5000 .00 13.0 7.0 7.3-7.0 .000 99/10 16.6250 .00 12.0 2.0 1 7.3-6.5 .000 99/11 21.6600 .00 26.0 .0 7.3-6.7 .000 .340 99/12 24.4750 4.40 23.0 .0 7.2-G.8 .000 AVERAGE 16.5698 1.61 15.7 3.8 1 .000 .333 MAXIMUM 25.0000 13.00 26.0 13.0 1 .400 MINIMUM 3.7000 LESSTHAN 7. 2'.0 1 6.500 .260 UNIT MGD MG/L MG /L #/100ML PASS/FAI I SU MG/L MG/L -C)91� hmo c A : r\jcoc�o y 917? C) "jw 'IPS c3D -rll\ �-=�, `'...� ��► crYv� � o� Ply" �� .ems ice =+�, IU 5CIA - mccLt3 WANT lb Cav-19LvANc--- IPT-- �Elaf 5 o( qW-vb dUl)? �p 51ao -mot_ L-1t�S SNC e GKEX88/MP 10/12/2001 COMPLIANCE EVALUATON ANALYSIS REPORT PAGE 2 PERMIT--NC0004979 PIPE --002 R PORT PERIOD: 0001-0012 LOC ---E FACILITY --DUKE POWER - ALLEN S.E. DESIGN FLOW-- 10.0000 CLASS, --1 LOCATION--BELMONT EGION/COUNTY--03 GASTON 00665 01002 01034 0 042 01045 01147 32730 34696 MONTH PHOS -TOT ARSENIC HROMIUM COPPER IRON SELENIUM PHENOLS THALE LIMIT NOL NOL 00/01 5.300 .0250 .3150 5.7000 .0000/7 .0000 LIMIT NOL NOL NO,L NOL 00/02 .0310 15.900 000' .0140 .4250 9.2000 .0�0 .0000 00/03 23.100 .0130 .7466 11.9000 ✓0000 .0000 00/04 32.400 .0070 .1700 11.3000 .0000 .0000 00/05 20.500 .0000 .0020 .1333 12.37 0000 .0000 00/06 17.100 050 .1050 16.9000 .0000 .0000 00/07 23.000 .0 90 .1050 17.4000 .0000 00/08 19.100 .0000 .012 .0900 16.9000 .0000 .0000 00/09 3.500 .0290 .1000 11.4000 .0000 .0000 00/10 5.700 .0230 .1650 9.8000 .0000 .0000 00/11 .0080 3.400 .0000 .0160 .1050 9.1000 .0000 .0000 00/12 3.900 .021/0 1550 8.6000 .0000 .0000 AVERAGE .0195 14.408 .0000 .'146 179 11.7083 .0000 .0000 MAXIMUM .0310 32.400 0290 1.2 00 17.4000 MINIUM .0080UNITM MG/L .400 �/L .0050 AMG/L MGY L 5.7000 UG/L UG/1, UGlL Q k4bh00o?N 71.4,�-�'�� -,/4 1 06 --VD -b &)b- b -L) WRJ- ' ij,) GKEX88/MP 10/12/2001 COMPLIANCE EVALUATION ANALYSIS REPORT PAGE 1 PERMIT --NCO 04979 PIPE --002 REPORT PERIOD: 0103-0112- LOC ---E FACILITY --DUKE PO R - ALLEN S.E. DESIGN FLOW- 10.0000 CLASS --1 LOCATION--BELMONT REGION/COUNTY--03 GASTON / 50050 310 00530 31616 TGP3B C0400 00556 001 00 MONTH Q/MGD OD RES/TSS FEC COLI CERI7DPF PH OIL-GRSE TO N LIMIT NOL L F 30.0 NOL NOL 9./150 O1/01 21.4200 2.2 6.0 .0 1 7.'-:-6.600 LIMIT NOL NOL F 30.0 NOL NOL 9.0 NOL 01/02 20.5000 .00 10.0 .0 7.",-7.1.400 01/03 23.1200 .00 7.0 .0 7.,-6.600 01/04 20.4000 .00 2 .0 4.0 1 7. 00 01/05 24.6200 .00 4. 2.0 7. 0001/06 22.0500 .00 7.0 .0 7. ..00 01/07 25.0200 .00 14.0 2.0 1 7.3-7.0 .000 01/08 25.7750 .00 11.0 .0 7. -6.8 .000 .240 AVERAGE 22.8631 .27 10.1 1. 1 1 .000 .320 MAXIMUM 26.5000 2.20 22.0 4.0 1 -. 400 MINIMUM 18.7000 LESSTHAN 4.0 2.0 1 .500 240 UNIT MGD MG/L MG/L #/100ML �P SS/FAI SU �fUT/L MG/L I =�-s0-_- I '�Drlu� NO (aANI � J Vl� v v GKEX88/MP 10/12/2001 COMPLIANCE EVALUA ION ANALYSIS REPORT PAGE 1 RMIT--NC0004979 PIPE --004 EPORT PERIOD: 0101-0108 LOC ---E FACILIT DUKE POWER - ALLEN S.E. DESIGN FLOW-- 10.0000 CLASS --1 LOCATIONS ELMONT REGION/COUNTY--03 GASTON �O10 00556 MONTH Q/MG' OIL-GRSE ; LIMIT NOL F 5.000 01/01 8.0000 .000 01/02 8.0000 .0 f 01/03 8.0000 .000 / 01/04 8.0000 .000 01/05 8.0000 .000 01/06 8.0000 .000 01/07 8.0000 .000 01/08 8.0000 .000 AVERAGE 8.0000 .000 MAXIMUM 8.0000 MINIMUM 8.0000 UNIT MGD MGjL V. -OW � w Primary pollutant analysis results for Duke Energy's Allen Steam Plt�s NC0004979 cl Outfall 002 1 S� tl � rU \Y Pf 1 IL q parameter of con n Parameter of concern r Aluminum Barium Boron Iron Magnesium MolybdIffurn Manganese Titanium Antimonyr(ug/L) rsenic (mg/L) (ug/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (ug/L) Actual concentration 0.208 168 0.363 1.29 2.48 0.083 0.11 0.011 7.12 32.4 1 Allowable concentration not a POC 3384.8 not a POC 3.4 not a POC not a POC 0.677 not a POC not a POC 169.2 � IkLj n � � s21° DD N 10 cec Parameter of concern Sulfate Copper Nick -' Selenium Zinc Cyanide Cadmium (mg/L) (ug/L) (ug/L) (ug/L) (mg/L) (mg/L) (ug/L) Actual concentration 49.4 0.029 12.8 1 17.4 0.024 0.0025 0.52Feil b-(0� Allowable concentration 846.21 2 .7 84.6 16.9 0.1,\692 0.0169 6.8 Outfall 003 Parameter of concern Aluminum Barium Iron agnesium Molybdenum Manganese Titanium Sulfate Copper Zinc (mg/L) (ug/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (ug/L) (mg/L) Actual concentration 0.304 0.022 0.537 1.91 0.04 0.018 0.018 14.4 0.014 0.008 Allowable concentration nota POC 11215.1 11.2 not a POC not a POC 2243 not a POC 2803.76 5.8 0.067 � IkLj n � � s21° DD N 10 cec -1 �, 'k 7 m r qowo,6 2? , (--'I »—j UCS yp/t-n kirr aux -!P" AL -24-)y --G.md 3�pc S:2-/P/v 3,f (,TO REASONAI American Truetzschler, Inc NCO085928 Time Period Jan 1998 thru Oct 2000 Ow (MGD) 0.05 70 10S (cfs) 0 30Q2 (cfs) 0 g. Stream Flow, QA (cfs) ;0 Rec'ving Stream UT to Catawba River STANDARDS & f I REA PARAMETER TYPE* - CRITERIA PQ CI PO NCWQS 1/2 FAV RI .E POTENTIAL ANALYSIS << For Instructions, See RED TAB (cell Al). WWTP Class 2 IWC (%) @ 7Q10S 100.0 @ 30Q2 100.0 QA 100.0 Stream Class WS -1V , EiONABLE PRELIMINARY TENTIAL RESULTS :SULTS n= 27 MaxPredCw >> Allowable Cw 1,1-DCE� C 0.057 Max Pred Cw 33.1 f s Allowable Cw (acute) N/A MONITOR? Allowable Cw (chronic) 0.057 WK. AVG. LIMIT n — 26 I MaxPredCw << Allowable Cw 1,2 -DCA a C 0.38 99 IMax Pred Cw 0.5 I Allowable Cw (a ute) 99.000 MONITOR? aAllowable Cw (c roni0 WK. AVG. LIMIT n = 26 -o MaxPredCw << Allowable Cw TCE C 3.1 '--- 92 --�T--Max Pred Cw- 0.5 ;Allowable Cw (alute) 92 MONITOR? --- --� k Allowable Cw (c ironic) 3 MONITOR? — ... _ ___ n 26 1,1 -DCA C Max Pred Cw 0.5 9# no criteria Allowable Cw (a ute) N/A MONITOR? Allowable Cw (cl ironic) 0 I n=26 1,1,1 -TCA C Max Pred Cw 10.4 ! no criteria Allowable Cw (a ute) N/A MONITOR? t Allowable Cw (cironic) 0 n= 26 P MaxPredCw < Allowable Cw PCE - C 0.8 5 Max Pred Cw 1.3 Allowable Cw (a ute) N/A MONITOR? Allowable Cw (c ronic) 1 _ WK. AVG. LIMIT *Legend. ** Freshwater Discharge C = Carcinogenic NC = Non -carcinogenic A = Aesthetic NC0085928_RPA, X- MGD 6/12/01 /SIN � +mowoe cy cKsl �'u e h(X The inspection reports describe the facility as well maintained with toxicity problems in the effluent. The facility has received an NOV following a 2000 inspection, largely for deficiencies in self-monitoring (viol tion of the daily maximum limit for 1,1-dichloroethene and six failures of the chronic toxicity t st). In January 1999 and March 2000, the facility received NOVs and was eventually assessel civil penalties for toxicity violations. Correspondence between the Aquatic Toxicity Unit (ATU) and the permittee indicates that the source of the toxicity is in all likelihood, elevated zinc concentrations. ATU suggests that this may come from piping within the system. The 2001,ATC allowed treatment improvements that were to remove zinc and reduce toxicity. Included with the renewal application was an Engineering Alternatives Analysis (EAA) evaluating discharge alternatives. Given the urban location of the facility, surface water discharge appears to be the most feasible option at this time. PERMITTING STRATEGY AND SUMMARY OF PROPOSED CHANGES No changes are proposed to this permit. The facility will e -advised via cover letter that should toxicity problems persist, a more comprehensive EAA should be performed to evaluate non -discharge alternatives. PROPOSED SCHEDULE FOR PEBMT ISSUANCE Draft Permit to Public Notice: June 27, 2001 Permit Scheduled to Issue: August 20, 2001 NPDES DIVISION CONTACT If you have questions regarding any of the above information or on the attached permit, please contact Natalie Sierra at (919) 733-5083 ext. 551. NAME: _I_DATE: REGIONAL OFFICE COMMENTS NAME: SUPERVISOR: DATE: DATE: Fact Sheet NPDES NCO085928 Renewal Page 2. It The inspection reports descr: the effluent. The facility has recf deficiencies in self-monitoring (viol; six failures of the chronic toxicity to NOVs and was eventually assesse between the Aquatic Toxicity Unit toxicity is in all likelihood, elevated piping within the system. The 2001 zinc and reduce toxicity. Included with the renewal a] evaluating discharge alternatives. discharge appears to be the most fea; PERMITTING STRATEGY ANI; No changes are proposed to t should toxicity problems persist, a rr non -discharge alternatives. PROPOSED SCHEDULE FOR Draft Permit to Public Notice: Permit Scheduled to Issue: NPDES DIVISION CONTACT )e the facility as well maintained with toxicity problems in ived an NOV following a 2000 inspection, largely for tion of the daily maximum limit for 1,1-dichloroethene and ;t). In January 19991 and March 2000, the facility received I civil penalties for toxicity violations. Correspondence (ATU) and the permittee indicates that the source of the :inc concentrations. ATU suggests that this may come from ATC allowed treatment improvements that were to remove )lication was an Engineering Alternatives Analysis (EAA) Given the urban location of the facility, surface water ble option at this time. )ermit. The facility will e advised via cover letter that comprehensive EAA should be performed to evaluate ISSUANCE June 27, 2001 August 20, 2001 If you have questions regarding any og the above information or on the attached permit, please contact Natalie Sierra at (919) 733-5083 ext. 551. NAME: REGIONAL OFFICE COMMENTS NAME: SUPERVISOR: DATE: DATE: DATE: Fact Sheet NPDES NCO085928 Renewal Page 2 Duke (Energy® December 5, 2001 Ms. Natalie Sierra North Carolina Department of Environment and Natural Resources NPDES Unit 1618 Mail Service Center Raleigh, NC 27699-1618 SUBJECT: Addendum to the NPDES Permit Renewal Supplement Allen Steam Station NPDES Permit # NC0004979 Record Number: NC -005157 Certified: 7000 1670 0001 5505 9624 Dear Ms. Sierra: Duke Energy Corporation EH&S Services 13339 Hagers Ferry Road Huntersville, NC 28078 The description of the air pollution control systems that Plant Allen uses was inadvertently left out of the supplemental. Attached is a copy of the updated supplemental, see the Ash Sluice section on page 4 for the description. Three copies of the updated supplemental are attached for your files. If you need further information, please contact John Mease at (704) 875-5347. Sincerely, Michael A. Ruhe, Manager Water Compliance cc: Mike Parker — NCDENR, Mooresville Regional Office � r C=) . ...: r� o o CV Lo rL c3 'V3 (� U W O Q� NPDES Supplemental Information For Allen Steam Station NPDES Permit # NC0004979 February 26, 2001 Plant Allen, Gaston County NPDES Permit # NC0004979 Page 2 of 12 General Information Plant Allen utilizes waters from the Catawba River for condenser cooling and service water requirements. A brief discussion of each discharge follows. A schematic flow diagram of water use, treatment, and discharges indicating typical (average) flow rates for individual waste streams at Plant Allen is attached. All flows are based on historical data where possible or pump design capacities and normal run-times. Outfall 001 - Condenser Cooling Water (CCW) The CCW system is a once -through, non -contact cooling water system that removes heat rejected from the condensers and other selected heat exchangers and then discharges into the South Fork River. Each of the 5 units at Plant Allen has two condenser cooling pumps. The number of pumps used is dependent on unit load and intake temperatures with more pumps running with higher loads and intake temperatures. Units 1 and 2 share a common cooling water supply tunnel served by a total of 4 CCW pumps. Units 3 and 4 also share a tunnel and 4 CCW. pumps. Unit 5 has a separate tunnel and 2 CCW pumps. The common tunnel design enables three pumps to give Units 1 and 2 or 3 and 4 the equivalent of 1 1/2 pump operation. The 1 1/2 pumps operation adds an economical range or flexibility when units are on partial load and when intake water temperatures are minimal. Unit No. 1 -Pump GPM 1.5 -Pum GPM 2 -Pump GPM 1 55,500 74,800 83,500 2 55,500 74,800 83,500 3 83,000 111,200 126,000 4 83,000 111,200 126,000 5 83,000 126,000 All condenser tubes at Plant Allen are cleaned manually with metal or rubber plugs. Mechanical cleaning is required once a year for most units. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 3 of 12 Outfall 002 - Ash Basin Boiler Cleaning All five boilers at Plant Allen are chemically cleaned with the next cleaning as needed. The volume of the boilers determines the quantity of chemicals required for a cleaning. Boilers #1 and #2 each have a waterside volume of 26,700 gallons. The volume of boilers #3, #4, and #5 is 40,100 gallons each. The volume of dilute waste chemical discharged from unit #1 or #2 during a cleaning is 294,000 gallons. The volume of diluted waste chemicals drained from #3, #4 and #5 totals 450,000 gallons each. These wastes are drained through temporary piping to the permanent ash removal lines, which flow to the ash basin. Immediately prior to the beginning of a boiler chemical cleaning procedure, additional stop logs are added to the ash basin discharge structure. This assures longer retention time of the chemical wastes for proper treatment through dilution, neutralization, precipitation, and ion - exchange as documented in the Ash Basin Equivalency Demonstration (October 1976). A list of the chemicals and amounts required to clean the boilers at Plant Allen follows: CLEANING CHEMICALS Sodium bromate Ammonium carbonate Ammonium hydroxide* Hydrochloric acid* Thiourea* Citric acid Sodium Sulfite Ammonium bifluoride Detergent (Triton —X) Antifoam agent AMOUNT USED PER UNIT Boiler #1 and #2 550 lbs 1000 lbs 850 gal 3700 gal 1680 lbs 300 lbs 100 lbs 1100 lbs 20 gal 10 gal Boiler #3, #4 & #5 550 lbs 1000 lbs 950 gal 5500 gal 2010 lbs 400 lbs 100 lbs 1700 lbs 20 gal 10 gal * During a chemical metals cleaning these chemicals are present in amounts greater than the reportable quantity as identified under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). If a spill of any these chemicals were to occur, in most cases, it would be routed to the ash basin for treatment. Stormwater run-off #1 The normal rainfall run-off plus ground water seepage from the coal pile area is routed to the coal yard sump via the coal handling sumps. Perforated pipes beneath the coal Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 4 of 12 pile convey the effluent to the coal handling sumps. The total average flow to the coal yard sump is calculated to be 0.058 MGD. Drinking Water A well supplies the drinking water requirements of Plant Allen. Plant Allen is a non- transient, non -community drinking water system and it's ID # is 01-36-704 in the state's drinking water database. Sanitary Wastes Sanitary waste at Plant Allen is treated in a septic tank with the effluent from the septic tank being discharged to the Ash Basin via the Coal Yard sump. Approximately 150 people are responsible for the load on this system. An average flow of 4850 GPD is treated by the system. Ash Sluice Plant Allen utilizes electrostatic precipitators to remove fly ash from its stack gases. These precipitators require approximately 10.0 MGD for fly ash sluicing to the ash basin. Bottom ash sluicing to the basin requires approximately 6.0 MGD for a total average ash removal flow of 16.0 MGD. Plant Allen presently has additional air pollution control systems installed on two units. Use of these systems entails the use of low concentrations of ammonia and sulfur compounds. Additional air pollution control systems (ie. for SO2 and NOx treatment) may be added in the future. Recirculating Water System Plant Allen has 2 recirculating water systems (RCW): a chiller system and a pump cooling water system. Both systems use the biocide H-550 or similar products. In addition, the corrosion inhibitor CS or similar product is used. Generally, these systems are closed loop, but may need to be drained occasionally. All such water would enter the floor drains and then be discharged to the ash basin. Miscellaneous Waste Streams Turbine Non-destructive Testing: Approximately once per year, one turbine is tested for cracks in the generator shaft using an ultrasonic nondestructive test. During the process a maximum of 400 gal of demineralized water mixed with 4 gal of corrosion inhibitor is used and discharged to the ash basin. Heat Exchanger Cleaning: From time to time, it may be necessary to clean the small heat exchangers with polyacrylamide, polyacrylate, sodium laurylsulfate and tri -sodium phosphate. All wastes would be routed to the ash basin. Condensate Polishers: Plant Allen utilizes condensate polishers which divert a portion of the normal condensate (closed system) flow through one of two cells per unit. The polishers provide filtration as well as ion exchange functions to remove or substantially reduce Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 5 of 12 dissolved solids and suspended matter present in the condensate stream. The polishers require precoating with a combination of anion and cation resin. To facilitate precoating, 125-150 mL of a solution of polyacrylic acid (25%) is added to the precoat slurry. Upon exhaustion, the precoat is removed from the filters by water/ air blasting and flushed to the ash basin via sumps. Condensate water is used to remove the exhausted precoat at the rate of: Unit 1 & 2 - 1558 gal/precoat Units 3, 4, & 5 2090 gal/precoat. A total average waste flow of approximately 980 GPD to the ash basin is realized. Condenser Leakage Testing: Fluorescing Dye. Method Approximately 1 Ib. of a disodium fluorescing dye added to 280,000 gals of demineralized water is used occasionally to test the condensers for leakage. All wastes from the testing would be routed to the ash basin. Sulfur Hexafluoride Method: Periodically, sulfur hexafluoride is injected into the condenser tubes to locate condenser tube leaks. Sulfur hexafluoride is a chemically inert, nonflammable, nontoxic gas with an extremely low water solubility. It is estimated that 150 grams of sulfur hexafluoride would be used during the leak detection process. Most of the sulfur hexafluoride would be volatilized during the process. Ash Basin Treatment CO2 Injection System: During warmer periods of the year, algae blooms occur in the ash basin causing pH levels to rise. A CO2 system is utilized during these events to maintain the pH level below 9.0 standard units. Acid Injection System: An acid injection system utilizing 78-80 % sulfuric acid is maintained as back-up to the CO2 system for pH adjustment Sodium Hydroxide System: A sodium hydroxide injection system utilizing 50% sodium hydroxide is maintained for low pH treatment. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 6 of 12 Yard Drain Sump The yard drain sump is a large concrete structure that has three level controlled pumps, which pump wastewater from Plant Allen to the ash basin. These pumps are operated on a rotating basis. The combined average flow from all sources tied to the yard drain sump is approximately 4.0 MGD. Below is a description of wastes going to the yard drain sump: Storm Water run-off #2 The ash basin accommodates flows from the yard drain sump, coal yard sump, ash removal lines and rainfall run-off from the basin watershed area. The average rainfall run-off flows are based on 47 inches of rain per year with 100% run-off from pond surfaces and 50% run-off from other areas. The average run-off for the ash basin watershed area is 0.57 MGD. Average run-off to the yard drain sump is calculated to be 0.018 MGD. Oil Storage Run -Off Plant Allen has an above ground oil storage tank with a capacity of 100,000 gallons, an above ground 4,500 gallon used oil storage tank and one above ground gas tank with a 550 gallon capacity. A dike surrounds the 100,000 gallon above ground tank for the purpose of providing secondary containment. The 4,500 and 550 gallon tanks have an additional outer tank for secondary containment. Any spills not contained within dike or outer tank secondary containment will be routed to the ash basin through the yard sumps. If a spill did occur efforts will be taken to contain and cleanup the spill. All storage facilities are presently covered under the Spill Prevention Control and. Countermeasure Plan. Floor Drains (Units 1-4) Wastes, which enter the floor drains, accumulate in the boiler room sumps and turbine room sumps. Boiler Room Sumps (Units 1-4) The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage (refer to the attached schematic of water flow for individual flows). The effluent from the units 1 through 4 boiler room sumps is flushed to the yard drain sump. The effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. Turbine Room Sumps The turbine room sumps accommodate flows from floor washing, leakage, and occasional condenser water box drainage. Effluent from units 1 through 5 turbine room sumps is flushed to the yard drain sump. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 7 of 12 Water Treatment System The water treatment wastes consist of sedimentation, filter backwash, reverse osmosis (RO) concentrate, demineralizer regeneration wastes and boiler blowdown. The make-up water treatment system is compromised of a clarifier, two pressure filters, two activated carbon filters, two garnet filters, a reverse osmosis machine and one set of demineralizers. Make-up water is used in the boilers and closed cooling systems. Clarifier: The clarifier has an average production of 0.252 MGD. Alum and caustic are used to affect precipitation and thus remove suspended solids from the raw river water. Desludging of the clarifier takes place approximately 8% of the unit run- time with an average volume of 2300 GPD going to the ash basin. Pressure Filters: There are two pressure filters which follow the clarifier in the water treatment process. These filters are backwashed once per week with a waste flow of 11,000 gallons per backwash. Each pressure vessel will contain 84 ft3 of anthracite, 50 ft3 of quartz, 25 ft3 of garnet and 41 ft3 of garnet/quartz support media. Each vessel will use product water to backwash at a rate of 750 gpm. On average, both vessels will backwash once per week. The contents of the pressure filters will be changed out, as internal maintenance requires, and the used filter medium will be disposed of in the ash basin. Activated Carbon Filters: In addition to the pressure filters, there are two activated carbon filters. These filters are backwashed twice per month. Approximately 30,000 gallons of water are required to backwash each of these filters. The activated carbon filters are composed of approximately 250 ft3 of granular activated carbon (coal). The spent filter medium is changed out yearly and is disposed of in the ash basin. RO Prefilters: There are 2 RO prefilter vessels containing garnet, which are used to filter suspended solids. Both filters are backwashed once per week with the backwashed material routed to the ash basin. Total waste for both filters is 4500 gallons per week. RO Unit: A RO unit is used to decrease the conductivity in the filtered water, thereby increasing the efficiency of the demineralizers and reducing the amount of chemical needed for demineralizer regeneration. During operation, the unit has a continual blowdown of 60 gal/min, which is discharged, to the ash basin. The RO unit is cleaned on a quarterly basis with the waste going to the yard drains and eventually the ash basin. During a cleaning, approximately 30 lbs of the cleaner OSMO AD -20 (containing sulfamic acid) along with 5 gallons of biocide, 40 lbs of trisodiurn phosphate and 0.5 gallons of sodium lauryl sulfate is used. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 8 of 12 Demineralizer: The demineralizer consists of two mixed -bed cells. Only one of these cells is operated at any one time. The cell which is in operation is regenerated approximately once every 7- 14 days of operation. A regeneration requires 42 gallons of sulfuric acid (78-80%) and 150 gallons of 50% sodium hydroxide. An average dilute waste chemical and rinse flow of 20,000 gal is realized. The dilute acid and caustic are discharged to the floor drains simultaneously through the same header for neutralization purposes. All regeneration wastes are flushed to the ash basin. The demineralizer resin is changed out approximately once every 10 years with the spent resin going to the ash basin. Approximately 1 mL of the surfactant Triton CF -54 or similar product is added to the new resin to improve separation. Boiler Blowdown: Each of the five boilers at Plant Allen blowdown at an average rate of approximately 500 lbs. of steam per hour. The blowdown is allowed to flash in a blowdown tank. Most of the blowdown is vented to the atmosphere with a minimal amount of condensate discharged to the boiler room sump. The average condensate flow to this sump is 0.004 MGD. Hydrazine is maintained at a concentration of 25 ppb in the condensate system for deoxygenation. A minute amount of hydrazine (<10 ppb) may be present in the condensate flow to the boiler room sump. Preheater Washes Preheaters are backwashed with raw water approximately 2 times per year to remove ash and corrosion products. There are 12 preheaters at Allen that would require approximately 100,000 gallons of backwash water each. The backwash water is routed to the ash basin through the yard drain sump. Laboratory Wastes The chemistry lab on site performs a variety of water analyses and routine sample collections. Therefore several chemicals are used in the lab in small quantities for sample preservation, bottle rinsing, equipment calibration, conductivity analyses, etc. The wastes are flushed down the sink and discharged into the yard drain sump and then pumped to the ash basin. Some of the laboratory chemicals are as follows: Ammonia molybdate, Acetic acid, Ferric sulfate, Hydrochloric acid, Monoethylamine, Nitric acid and Potassium hydroxide. Power House Sump (Unit 5) The wastes, which enter the floor drains at Plant Allen, accumulate in the boiler room sumps and turbine room sumps. The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous 'leakage. Effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. This sump also collects stormwater from various drains located on the north end of the powerhouse. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 9 of 12 Outfall 002A — Coal Yard Sump Overflow An overflow pipe that directs flow from the sump to the Catawba River was included in the construction of the yard sumps. This was done to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. This has occurred approximately one time in the past 5 years. Observations and monitoring of effluent during events have indicated no impact to water quality. Outfall 002B — Power House Sump Overflow An overflow pipe that directs flow from the sump to the ground was included in the construction of the yard sumps. This was done to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. If enough water overflows, the waste could potentially get to the Catawba River. This has occurred approximately twice in the past 5 years. Observations and monitoring of effluent during events have indicated no noticeable impact to water quality. Outfall 003 — Misc Equipment Cooling & Seal Water Outfall 003 discharges into the CCW discharge canal. The discharge consists of cooling water from units 4 and 5 boiler feedpump hydraulic coupling coolers and other miscellaneous equipment cooling. This water is once -through, non -contact cooling water withdrawn from the service water system. Outfall 004 Equip. Cooling & Intake Screen Backwash Equipment Cooling Water Cooling water for units 1,2 & 3 boiler feed pump hydraulic coupling coolers and other miscellaneous equipment is discharged through outfall 004. This water is once - through, non -contact water drawn from the service water system. In addition, water from a vehicle rinse -down area is directed to this outfall. The rinse water contains no soaps or other additives. Intake Screen Backwash The intake screens at Plant Allen are flushed on an "as needed" basis. Backwash usually averages 2 hours per shift. The average volume required is 0.053 MGD. The large debris floating on the river is caught on the parallel bar screens. This trash is collected and disposed of in a landfill. The silt, twigs, leaves and other light debris collected on the rotating screens are indigenous to the river and are therefore flushed back with no harmful environmental consequences. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 10 of 12 Outfall 005 — Asiatic Clam/Debris Filter Backwash Water for the Unit 5 CCW water is filtered for any twigs, leaves and other light debris which passed through the intake screens. Asiatic clams, which are common in Lake Wylie and can clog the condenser tubes, are also captured in this filter. This filter is backwashed once a week for 15 minutes. A maximum flow of 3000 GPD is realized. No other additives are in the backwash water. The twigs, leaves, clams and other light. debris collected in the debris filter are indigenous to the river and are therefore flushed back with no harmful environmental consequences. Storm Water General Description As previously discussed much of the storm water runoff is directed to the ash basin (outfall 002). There are several other storm water outfalls at Plant Allen. These drains either discharge into the Catawba River or into the South Fork River via the outfall 001 discharge canal. Plant Allen was included in the storm water group application submittal (March 1991) to the Environmental Protection Agency for several Duke Power Company locations. Plant Allen 316(a) Determination Duke Power Company's 316(a) demonstration (March 1976) concluded that the "heated discharge from Plant Allen is such that the protection and propagation of a balanced indigenous aquatic community in and on Lake Wylie is assured." Duke's operation experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC0004979 substantiates the above conclusion and further supports Duke's belief that the operating characteristics of the station have a minimal effect of the aquatic environment of Lake Wylie. Surveys of the aquatic community in Lake Wylie demonstrate that a Balanced Indigenous Population exists in Lake Wylie. Accordingly, Duke requests a 316(a) variance and further requests that the thermal limitations imposed in the permit be continued. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 11 of 12 Hazardous and Toxic Substances Hazardous and Toxic Substances Table 2c- 3 At Plant Allen, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V -D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Acetaldehyde, Aniline, Asbestos, Butyl Acetate, Cresol, Cyclohexane, Formaldehyde, Monoethylamine, Naphthenic Acid, Propylene Oxide, Pyrethrins, Styrene, Triethanolamine, Vanadium, Vinyl Acetate, Xylene and Zirconium. Other - During the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will impact the ash basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. 40 CFR 117 and CERCLA Hazardous Substances The following table identifies hazardous substances located on-site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on-site that could be released at one time and sent to the ash basin. They do not reflect quantities that are discharged through typical use. SUBSTANCE Ammonia (aqueous) Benzene Hydrazine Sodium Hydroxide Sodium Nitrite Sulfuric Acid QUANTITY (lbs.) SOURCE 9452 Storage Tank 166 Gas Storage Tank 944 Warehouse/Third floor of Powerhouse 15,566 Warehouse 2034 Warehouse and/or Mezzanine Floor 30724 Warehouse Catawba 550 .0 River/—MGD Plant Allen Water Schematic Condenser Cooling Outfall 001 520.0 MGD Water Sanitary Waste Coal Handling Coal Yard Sumps Sump Ash Sluice Water Treatment Boiler Rm Sumps Intake screen Backwash%.° Atm Boiler Powerhouse Sump Turbine Rm Sumps Misc Equip Cooling & Seals Plant Allen, Gaston County NPDES Permit # NC0004979 Page 12 of 12 South Fork 10 River Outfall 002A --------- ------- 0. Catawba River Stormwater #1 Ash Basin Outfall 002 Catawba 20.05 MGD* River Yard Drainage Stormwater #2 Sump Outfall 003 4.5 MGD south Fork River ..-._._.... Outfall 002B ----•--•----------•- Catawba '-'-'♦ River Outfall 004 Catawba 6.5 MGD River Outfall 005 Catawba 0.003 MGD River To: Permits and Engineering Unit Water Quality Section Attention: Valery Stephens SOC PRIORITY PROJECT: No Date: May 10, 2001 NPDES STAFF REPORT AND RECOMMENDATIONS County: Gaston NP_ DES Permit No.: NC0004979 MRO No.: 01-49 PART I - GENERAL INFORMATION 1. Facility and address: Allen Steam Station c/o Duke Power Company 13339 Hagers Ferry Road Huntersville, N.C. 28078 2. Date of investigation: May 2, 2001 LI M Ay 1 5 2001 1 Report prepared by: Michael L. Parker, Environmental Engineer II 4. Person contacted and telephone number: John Mease, Tel#(704) 875-5347 5. Directions to site: From the jct. of Hwy. 7 and SR 2525 (South Point Rd.) in the Town of Belmont, travel south on SR 2525 = 2.5 miles. The entrance to the Allen Steam Plant is on the left (east) side of SR 2525. 6. Discharge point(s), List for all discharge points: - outfall 001 outfall 002 outfall 002A outfall 002B Latitude: 350 11' 23" 350 10' 30" 350 11'17" 350 11' 15" Longitude: 81 ° 00' 45" 810 00' 23" 81' 00' 46" 81' 00' 22" outfall 003 outfall 004 outfall 005 Latitude: 350 11' 24" 350 11'15" 350 11' 24" Longitude: 81 ° 00' 46" 81 ° 00' 22" 81 ° 00' 45" Attach a US GS Map Extract and indicate treatment plant site and discharge point on map. USGS Quad No.: G 14 NE 7. Site size and expansion area consistent with application: Yes. There is additional area available for expansion, if necessary.. Page Two 8. Topography (relationship to flood plain included): The site was graded considerably when built, which removed existing contours. The steam plant is constructed above the high water elevation of Lake Wylie (the receiving stream). The surrounding area has gently rolling topography (slopes <10%). 9. Location of nearest dwelling: Approx. 1000+ feet from the steam plant site. 10. Receiving stream or affected surface waters: Catawba River (Lake Wylie) -outfalls 002, 002A, 002B, 004 & 005. South Fork Catawba River (Lake Wylie) -outfalls 001 & 003. a. Classification: Catawba River, WS -IV & B; South Fork Catawba River, WS -V. b. River Basin and Subbasin No.: Catawba 030834 C. Describe receiving stream features and pertinent downstream uses: Outfalls 002, 002A, 002B, 004 & 005 enter the main segment of the Catawba River (Lake Wylie), which is used for primary and secondary recreation and as a receiving stream for point source (NPDES) discharges both upstream and downstream of the steam plant. There are no known municipal water intakes located above or below these outfalls. Outfalls 001 & 003 enter a manmade discharge canal located west of the steam plant. This canal travels for a distance of z 1.2 miles where it enters the South Fork Catawba River (an arm of Lake Wylie). This -area is also used for primary and secondary recreation and there are no known water intakes from the point of discharge to the mouth of the South Fork of the Catawba River. PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS Outfall 001 002 002A 002B 003 004 005 a. Volume of wastewater (MGD): 784.8 11.6 N/A N/A 6.3 8.0 0.003 b. What is the current permitted capacity: No flow limit for any outfall in Permit. C. Actual treatment capacity of current facility (current design capacity): N/A d. Date(s) and construction activities allowed by previous ATCs issued in the previous two years: N/A Description of existing or substantially, constructed WWT facilities: outfall 001- no existing WWT facilities. Waste stream consists of Condenser Cooling Water (CCW). Duke Power has submitted a request to perform a pilot study at this outfall using portable cooling towers. In full operation, the towers will remove = 15% of the CCW water from the discharge pipe. The cooled water will then be returned to the discharge canal. This Office has reviewed Duke's request to conduct this pilot study and has no objections pending a final review by the NPDES Unit. Page Three outfall 002 - Ash Basin. The only existing treatment facility discharging into the Ash Basin is a septic tank that receives all the plant's domestic wastewater. This domestic wastewater enters the existing ash basin where additional treatment occurs. pH adjustment (carbon dioxide, sulfuric acid, and sodium hydroxide) is available at the effluent, if needed. Other wastewater sources entering the ash basin and discharge at outfall 002 include: stormwater runoff from the coal pile area, ash sluice, recirculating water system, turbine non-destructive testing, heat exchanger cleaning, condensate polishers, condensate leakage testing, yard drain sump, water treatment system, preheater washes, laboratory wastes, and the power house sump (unit 5), outfall 002A - Coal yard sump overflow. No existing WWT facilities. An overflow pipe directs flow directly to the Catawba River in the event that all pumps in the coal yard sump failed or redundant power supply could not be restored in a timely manner. This overflow pipe was approved by the Division in a letter dated May 15, 2000. Only one discharge has occurred from this outfall in the past five years. outfall 002B - Power House Sump Overflow. No existing WWT facilities. An overflow pipe directs flow directly to the Catawba River in the event that all pumps in the yard sump failed or redundant power supply could not be restored in a timely manner. This overflow pipe was approved by the Division in a letter dated May 15, 2000. Only two (2) discharges have occurred from this outfall in the past five years. outfall 003 - Miscellaneous Equipment Cooling and Seal Water. No existing WWT facilities. Discharge is to the CCW discharge canal. outfall 004 - Equipment Cooling and Intake Screen Backwash. No existing WWT facilities. outfall 005 - Asiatic Clam/Debris Filter Backwash. No existing WWT facilities. f. Description of proposed WWT facilities: There are no proposed WWT facilities. g. Possible toxic impacts to surface waters: This facility has consistently passed toxicity tests required at outfall 002. Various chemicals are used during the cleaning and maintenance of equipment (see list provided with the application package). h.. Pretreatment Program (POTWs only): Not Needed. 2. Residual handling and utilization/disposal scheme: Septage generated in the septic tank is removed as needed by Cline Septic Tank Services (permit# 00136). With the exception of fly ash, no other residuals generation is expected. Duke Power Company has obtained a non -discharge Permit (WQ0003255) for the disposal of fly ash. PDuke Power. A Luke EuV Compa17 May 9, 2001 Mr. David Goodrich State of North Carolina Department of Environment and Natural Resources Division of Water Quality NPDES Unit 1617.Mail Service Center Raleigh, North Carolina 27699-1646 Subject: Duke Power Company — NPDES Permit Modification Allen Steam Station - # NC0004979 Belews Creek Steam Station - #NC0024406 Buck Steam Station — #NC0004774 Cliffside Steam Station — #NC0005088 Dan River Steam Station - #NC0033468 Marshall Steam Station - #NCb004b87 Riverbend Steam Station — #NC0004961 Record #: DP -005157 Certified: 7000 1670 0003 3252 8202 Dear Mr. Goodrich: Duke Power Group Environment, Health 6- Safety MG03A5 13339 Ha ers_Ferry-Road As a followup .to a telephone conversation between Allen Stowe and Mr. Mike Templeton of your office on April 27, 2001; Duke Power requests that the definitions in the Special Conditions of the forenamed permits be revised as boiler plate language to read as follows: The term "metal cleaning waste" means any wastewater resulting from cleaning (with or without chem icaLcleaning componds) any metal process equipment including, but not limited to, boiler tube cleaning,, boiler. fireside cleaning; and air preheater cleaning. The term "chemical metal cleaning waste" means any wastewater resulting from'the cleaning of any meta( process equipment with chemical componds, including, but riot limited. to, boiler tube cleaning. Chemical metal cleaning will be conducted according to approved Duke Power equivalency demonstration. a C CO a_ W z� ZE 4 As a followup .to a telephone conversation between Allen Stowe and Mr. Mike Templeton of your office on April 27, 2001; Duke Power requests that the definitions in the Special Conditions of the forenamed permits be revised as boiler plate language to read as follows: The term "metal cleaning waste" means any wastewater resulting from cleaning (with or without chem icaLcleaning componds) any metal process equipment including, but not limited to, boiler tube cleaning,, boiler. fireside cleaning; and air preheater cleaning. The term "chemical metal cleaning waste" means any wastewater resulting from'the cleaning of any meta( process equipment with chemical componds, including, but riot limited. to, boiler tube cleaning. Chemical metal cleaning will be conducted according to approved Duke Power equivalency demonstration. Duke Power also requests that monitoring for iron and copper only be required when a, chemical metal cleaning is conducted. The Steam Effluent Guidelines in 40 CFR 423.13 (e) list limits for copper and iron concentrations when chemical metal cleanings are conducted. The compliance history of these facilities is supportive of this request. Currently, Cliffside Steam Station is the sole facility that monitors for iron and copper only when chemical metal cleanings are performed. Several other Duke facilities have submitted this monitoring frequency reduction as part of their NPDES permit application. Duke Power also requests that required metal analyses be changed from a "Total Metal" method to a "Total Recoverable Metal' method to align with the EPA Form 2C instructions and with 40 CFR 122.45 (c). Should you have questions regarding this report, please contact Allen Stowe at (704) 875-4655. Sincerely, Michael Ruhe Manager, Water Compliance Group Environment, Health and Safety jas '� xc: Mr. Mike Templeton - NCDENR Division of Water Quality Duke Power. A Duke Energy Company February 26, 2001 Mr. Charles H. Weaver, Jr. NC DENR/Water Quality/NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: NPDES Permit Renewal, NC0004961 Allen Steam Station, Gaston County File: AS -006121 Certified: 7099 3400 0015 4643 8357 Dear Mr. Weaver: Duke Power Group Environment, Health 6- Safety MG03A5 13339 Hagers Ferry Road Huntersville, NC 28078-7929 ® EC EOWE WI-1 M01 DENR-WATER QUALITY POINT SOURCE BRANCH Duke Power requests the subject permit be renewed and reissued. The above referenced permit expires August 31, 2001. As required by North Carolina Administrative Code (15A NCAC 2H.0105(e)), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the application for renewal, which includes the following items: • EPA Form 1 • EPA Form 2C - Including Priority Pollutant Analysis • EPA Form 2E • Site maps • Water flow diagram and supplemental information. Duke Power requests notification that the application is complete. The following monitoring reductions at outfall #002 are requested based on historical monitoring data, see attached. The frequencies were determined using the EPA guidelines for "Performance -Base Reduction of Monitoring Frequencies". • Deletion of monitoring for oil & grease at outfall #002 and #004. Analytical results for the last two years have all been below detection. • Deletion of monitoring for naphthalene, phenol and chromium at outfall #002. Analytical results for the last two years have all been below detection. • Reduction of fecal & BOD monitoring from monthly to once/six months. • Reduction of TSS monitoring from monthly to quarterly. The Steam Electric Effluent Guidelines (40 CFR 423) restricts iron and copper, during a chemical metals cleaning, to 1.0 mg/I above background levels. It is requested that the iron and copper limitation for outfall #002 only apply during a chemical metals cleaning. - � u' � �. r' �P � � f _ .�_. _ i ��� i �N 9� 1 �. i �,.7 �� '; Plant Allen requests a continuation of the 316(a) variance. The on-going studies show the balanced indigenous aquatic community in the Catawba River is being maintained under the current limits. Thank you for your assistance with this permitting request. Should you have questions or need additional information, please contact Susan Robinson at (704) 875-5973. Sincerely, Michael A Ruhe Manager, Water Compliance Attachments cc w/Attachments: Mr. Rex Gleason, NCDENR, Mooresville, N.C. D 0 n 7- cn (D 7 D C 9 `C— C c 7 9 N 'G cc 0 D -a T p p v m m y cQ CD 0 c C O v 7 7 :F ? m O 6 CC) 6 m (n cn CO en CO CO CO CO en rn rn en CO (fl CO CO rn rn rn rn C O A A A A A A A A A A A A A A A A A A A A A A A A O i i i i i i i i i i i i i i i i i i i i i i i i M G G) o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o c o o c o 0 o G7 z O G 0 n 7- cn (D 7 D C 9 `C— C c 7 9 N 'G D -0 7 E w 7 m CD d' C— v 7 o CD n O O O O O O O O O O O CO O O O (n c"] C-1 c'] e'] CN cl c") cn A A A A A A A A A A A A A A A A A A A A A A A A i i i i i i i i i i i i i i i i i i i i i i i i C7 O O O O Q O Co O C7 C7 O O O O O O O O O O O O Q Jan -00 Feb -00 Mar -00 Apr -00 May -00 Jun -00 Jul -00 Aug -00 Sep -00 Oct -00 Nov -00 <1.0 4.0 <10.0 <10.0 <2.0 <2.0 <1.0 36.0 <10.0 <10.0 <0.04 4.0 <2.0 23.0 24.0 <1.0 23.0 <10.0 <10.0 2.0 7.5 <1.0 7.0 <10.0 <10.0 <2.0 3.7 <1.0 10.0 <10.0 <10.0 <0.04 <2.0 4.8 <1.0 5.0 <10.0 <10.0 17.0 <2.0 <1.0 7.0 <10.0 <10.0 <2.0 <2.0 <1.0 8.0 <10.0 <10.0 <0.04 <2.0 26.0 <1.0 <1.0 5.0 <10.0 <10.0 <2.0 <2.3 <1.0 6.0 <10.0 <10.0 <2.0 <2.2 <1.0 5.0 <10.0 <10.0 <0.04 <2.0 <6.7 O&G TSS Phenol Napthtalen Chromium Fecal BOD Average 0.0 14.1 0.0 0.0 0.0 3.2 2.6 Allen Parameter History December 1998 - November 2000 (Outfall 002) bate O&G TSS Phenol Napthtalen Chromium Fecal BOD Dec -98 Jan -99 Feb -99 Mar -99 Apr -99 May -99 Jun -99 Jul -99 Aug -99 Sep -99 Oct -99 Nov -99 Dec -99 <1.0 10.0 <10.0 <10.0 8.0 <2.0 <1.0 25.0 <10.0 <10.0 13.0 <2.0 <1.0 7.0 <10.0 <10.0 <0.04 4.0 13.0 <1.0 8.0 <10.0 <10.0 2.0 <2.0 <1.0 8.0 <10.0 <10.0 2.0 2.0 <1.0 20.0 <10.0 <10.0 <0.04 2.0 <2.0 12.0 20.0 11.0 <1.0 8.0 <10.0 <10.0 2.0 <2.0 <1.0 23.0 <10.0 <10.0 4.0 <2.0 <1.0 20.0 <10.0 <10.0 <0.04 4.0 <2.0 <1.0 13.0 <10.0 <10.0 7.0 <2.0 <1.0 12.0 <10.0 <10.0 2.0 -<2.0 <1.0 26.0 <10.0 <10.0 <0.04 4.0 <2.0 <1.0 23.0 <10.0 <10.0 <2.0 4.4 NPDES Supplemental Information For Allen Steam Station NPDES Permit # NC0004979 February 26, 2001 L E G E N D 0 o a v o PLANT DRAINAGE DISCHARGE PDIWS c:\dan\ai-nodes.dan Feb. 08. 2001 10:36:15 aKE 0 20 SCALE 1" = 20' Plant Allen, Gaston County NPDES Permit # NC0004979 Page 2 of 12 ,General Information Plant Allen utilizes waters from the Catawba River for condenser cooling and service water requirements. A brief discussion of each discharge follows. A schematic flow diagram of water use, treatment, and discharges indicating typical (average) flow rates for individual waste streams at Plant Allen is attached. All flows are based on historical data where possible or pump design capacities and normal run-times. Outfall 001 - Condenser Cooling Water (CCWJ The CCW system is a once -through, non -contact cooling water system that removes heat rejected from the condensers and other selected heat, exchangers and then discharges into the South Fork River. Each of the 5 units at Plant Allen has two condenser cooling pumps. The number of pumps used is dependent on unit load and intake temperatures with more pumps running with higher loads and intake temperatures. Units 1 and 2 share a common cooling water supply tunnel served by a total of 4 CCW pumps. Units 3 and 4 also share a tunnel and 4 CCW pumps. Unit 5 has a separate tunnel and 2 CCW pumps. The common tunnel design enables three pumps to give Units 1 and 2 or 3 and 4 the equivalent of 1 '/ pump operation. The 1 '/ pumps operation adds an economical range or flexibility when units are on partial load and when intake water temperatures are minimal. Unit No. 1 -Pump GPM 1.5 -Pump GPM 2 -Pump GPM 1 55,500 74,800 83,500 2 55,500 74,800 83,500 3 83,000 111,200 126,000 4 83,000 111,200 126,000 5 83,000 126,000 All condenser tubes at Plant Allen are cleaned manually with metal or rubber plugs. Mechanical cleaning is required once a year for most units. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 3 of 12 Outfall 002 - Ash Basin Boiler Cleaning All five boilers at Plant Allen are chemically cleaned with the next cleaning as needed. The volume of the boilers determines the quantity of chemicals required for a cleaning. Boilers #1 and #2 each have a waterside volume of 26,700 gallons. The volume of boilers #3, #4, and #5 is 40,100 gallons each. The volume of dilute waste chemical discharged from unit #1 or #2 during a cleaning is 294,000 gallons. The volume of diluted waste chemicals drained from #3, #4 and #5 totals 450,000 gallons each. These wastes are drained through temporary piping to the permanent ash removal lines, which flow to the ash basin. Immediately prior to the beginning of a boiler chemical cleaning procedure, additional stop -logs are added to the ash basin discharge structure. This assures longer retention time of the chemical wastes for proper treatment through dilution, neutralization, precipitation, and ion-. exchange as documented in the Ash Basin Equivalency Demonstration (October 1976). A list of the chemicals and amounts required to clean the boilers at Plant Allen follows: CLEANING CHEMICALS Sodium bromate Ammonium carbonate Ammonium hydroxide* Hydrochloric acid* Thiourea* Citric acid Sodium Sulfite Ammonium bifluoride Detergent (Triton —X) Antifoam agent AMOUNT USED PER UNIT Boiler #1 and #2 550 lbs 1000 lbs 850 gal 3700 gal 1680 lbs 300 lbs 100 lbs 1100 lbs 20 gal 10 gal Boiler #3, #4 & #5 550 lbs 1000 lbs 950 gal 5500 gal 2010 lbs 400 lbs 100 lbs 1700 lbs 20 gal 10 gal * During a chemical metals cleaning these chemicals are present in amounts greater than the reportable quantity as identified under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). If a spill of any these chemicals were to occur, in most cases, it would be routed to the ash basin for treatment. Stormwater run-off #1 The normal rainfall run-off plus ground water seepage from the coal pile area is routed to the coal yard sump via the coal handling sumps. Perforated pipes beneath the coal Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 4 of 12 pile convey the effluent to the coal handling sumps. The total average flow to the coal yard sump is calculated to be 0.058 MGD. Drinking Water A well supplies the drinking water requirements of Plant Allen. Plant Allen is a non- transient, non -community drinking water system and it's ID # is 01-36-704 in the state's drinking water database. Sanitary Wastes Sanitary waste at Plant Allen is treated in a septic tank with the effluent from the septic tank being discharged to the Ash Basin via the Coal Yard sump. Approximately 150 people are responsible for the load on this system. An average flow of 4850 GPD is treated by the system. Ash Sluice Plant Allen utilizes electrostatic precipitators to remove fly ash from its stack gases. These precipitators require approximately 10.0 MGD for fly ash sluicing to the ash basin. Bottom ash sluicing to the basin requires approximately 6.0 MGD for a total average ash removal flow of 16.0 MGD. Recirculating Water System Plant Allen has 2 recirculating water systems (RCW): a chiller system and a pump cooling water system. Both systems use the biocide H-550 or similar products. In addition, the corrosion inhibitor CS or similar product is used. Generally, these systems are closed loop, but may need to be drained occasionally. All such water would enter the floor drains and then be discharged to the ash basin. Miscellaneous Waste Streams Turbine Non-destructive Testing: Approximately once per year, one turbine is tested for cracks in the generator shaft using an ultrasonic nondestructive test. During the process a maximum of 400 gal of demineralized water mixed with 4 gal of corrosion inhibitor is used and discharged to the ash basin. Heat Exchanger Cleaning: From time to time, it may be necessary to clean the small heat exchangers with polyacrylamide, polyacrylate, sodium laurylsulfate and tri -sodium phosphate. All wastes would be routed to the ash basin. Condensate Polishers: Plant Allen utilizes condensate polishers which divert a portion of the normal condensate (closed system) flow through one of two cells per unit. The polishers provide filtration as well as ion exchange functions to remove or substantially reduce dissolved solids and suspended matter present in the condensate stream. The polishers require precoating with a combination of anion and cation resin. To Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 5 of 12 facilitate precoating, 125-150 mL of a solution of polyacrylic acid (25%) is added to the precoat slurry. Upon exhaustion, the precoat is removed from the filters by water / air blasting and flushed to the ash basin via sumps. 'Condensate water is used to remove the exhausted precoat at the rate of: Unit 1 & 2 - 1558 gal/precoat Units 3, 4, & 5 - 2090 gal/precoat. A total average waste flow of approximately 980 GPD to the ash basin is realized. Condenser Leakage Testing: Fluorescing Dye Method. Approximately 1 Ib. of a disodium fluorescing dye added to 280,000 gals of demineralized water is used occasionally to test the condensers for leakage. All wastes from the testing would be routed to the ash basin. Sulfur Hexafluoride Method: Periodically, sulfur hexafluoride is injected into the condenser tubes to locate condenser tube leaks. Sulfur hexafluoride is a chemically inert, nonflammable, nontoxic gas with an extremely low water solubility. It is estimated that 150 grams of sulfur hexafluoride would be used during the leak detection process. Most of the sulfur hexafluoride would be volatilized during the process. Ash Basin Treatment CO2 Injection System: ` During warmer periods of the year, algae .blooms occur in the ash basin causing --pH levels -to rise. A CO2 system is utilized during these events to maintain the pH level below 9.0 standard units. Acid Injection System: An acid injection system utilizing 78-80 % sulfuric acid is maintained as back-up to the CO2 system for pH adjustment Sodium Hydroxide System: A sodium hydroxide injection system utilizing 50% sodium hydroxide is maintained for low pH treatment. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 6 of 12 Yard Drain Sump The yard drain sump is a large concrete structure that has three level controlled pumps, which pump wastewater from Plant Allen to the ash basin. These pumps are operated on a rotating basis. The combined average flow from all sources tied to the yard drain sump is approximately 4.0 MGD. Below is a description of wastes going to the yard drain sump: Storm Water run-off #2 The ash basin accommodates flows from the yard drain sump, coal yard sump, ash removal lines and rainfall run-off from the basin watershed area. The average rainfall run-off flows are based on 47 inches of rain per year with 100% run-off from pond surfaces and 50% run-off from other areas. The average run-off for the ash basin watershed area is 0.57 MGD. Average run-off to the yard drain sump is, calculated to be 0.018 MGD. Oil Storage Run -Off Plant Allen has an above ground oil storage tank with a capacity of 100,000 gallons, an above ground 4,500 gallon used oil storage tank and one above ground gas tank with a 550 gallon capacity. A dike surrounds the 100,000 gallon above ground tank for the purpose of providing secondary containment. The 4,500 and 550 gallon tanks have an additional outer tank for secondary containment. Any spills not contained within dike or outer tank secondary containment will be routed to the ash basin through the yard sumps. If a spill did occur efforts will be taken to contain and cleanup the spill. All storage facilities are presently covered under the Spill Prevention Control and Countermeasure Plan. Floor Drains (Units 1-4) Wastes, which enter the floor drains, accumulate in the boiler room sumps and turbine room sumps. Boiler Room Sumps (Units 1-4) The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage (refer to the attached schematic of water flow for individual flows). The effluent from the units 1 through 4 boiler room sumps is flushed to the yard drain sump. The effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. Turbine Room Sumps The turbine room sumps accommodate flows from floor washing, leakage, and occasional condenser water box drainage. Effluent from units 1 through 5 turbine room sumps is flushed to the yard drain sump. Plant Allen, Gaston County NPDES Permit No.'NC0004979 Page 7 of 12 Water Treatment System The water treatment wastes consist of sedimentation, filter backwash, reverse osmosis (RO) concentrate, demineralizer regeneration wastes and boiler blowdown. The make-up water treatment system is compromised of a clarifier, two pressure filters, two activated carbon filters, two garnet filters, a reverse osmosis machine and one set of demineralizers. Make-up water is used in the boilers and closed cooling systems. Clarifier: The clarifier has an average production of 0.252 MGD. Alum and caustic are used to affect precipitation and thus remove suspended solids from the raw river water. Desludging of the clarifier takes place approximately 8% of the unit run- time with an average volume of 2300 GPD going to the ash basin. Pressure Filters: F, There are two pressure filters which follow the clarifier in the water treatment process. These filters are backwashed once per week with a waste flow of 11,000 gallons per backwash. Each pressure vessel will contain 84 ft3, of anthracite, 50 ft3 of quartz, 25 ft3 of garnet and 41 ft3 of garnet/quartz support media. Each vessel will use product water to backwash at a rate of 750 gpm. On average, both vessels will backwash once per week. The contents,ofthe pressure filters will be changed out, as internal maintenance requires,, and the used filter medium will be disposed of in the ash basin. Activated Carbon Filters: In addition to the pressure filters, there are two activated carbon filters. These filters are backwashed twice per month. Approximately 30,000 gallons of water are required to backwash each of these filters. The activated carbon filters are composed of approximately 250 ft3 of granular activated carbon (coal). The spent filter medium is changed out yearly and is disposed of in the ash basin. RO Prefilters: There are 2 RO prefilter vessels containing garnet, which are used to filter suspended solids. Both filters are backwashed once per week with the backwashed material routed to the ash basin. Total waste for both filters is 4500 gallons per week. RO Unit: A RO unit is used to decrease the conductivity in the filtered water, thereby increasing the efficiency of the demineralizers and reducing the amount of chemical needed for demineralizer regeneration. During operation, the unit has a continual blowdown of 60 gal/min, which is discharged, to the ash basin. The RO unit is cleaned on a quarterly basis with the waste going to the yard drains and eventually the ash basin. During a cleaning, approximately 30 lbs of the cleaner OSMO AD -20 (containing sulfamic acid) along with 5 gallons of biocide, 40 lbs of trisodium phosphate and 0.5 gallons of sodium lauryl sulfate is used. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 8 of 12 Demineralizer: The demineralizer consists of two mixed -bed cells. Only one of these cells is operated at any one time. The cell which is in operation is regenerated approximately once every 7- 14 days of operation. A regeneration requires 42 gallons of sulfuric acid (78-80%) and 150 gallons of 50% sodium hydroxide. An average dilute waste chemical and rinse flow of 20,000 gal is realized. The dilute acid and caustic are discharged to the floor drains simultaneously through the same header for neutralization purposes. All regeneration wastes are flushed to the ash basin. The demineralizer resin is changed out approximately once every 10 years with the spent resin going to the ash basin. Approximately 1 mL of the surfactant Triton CF -54 or similar product is added to the new resin to improve separation. Boiler Blowdown: Each of the five boilers at Plant Allen blowdown at an average rate of approximately 500 lbs. of steam per hour. The blowdown is allowed to flash in a blowdown tank. Most of the blowdown is vented to the atmosphere with a minimal amount of condensate discharged to the boiler room sump. The average condensate flow to this sump is 0.004 MGD. Hydrazine is maintained at a concentration of 25 ppb in the condensate system for deoxygenation. A minute amount of hydrazine (<10 ppb) may be present in the condensate flow to the boiler room sump. Preheater Washes Preheaters are backwashed with raw water approximately 2 times per year to remove ash and corrosion products. There are 12 preheaters at Allen that would require approximately 100,000 gallons of backwash water each.. The backwash water is routed to the ash basin through the yard drain sump. Laboratory Wastes The chemistry lab on site performs a variety of water analyses and routine sample collections. Therefore several chemicals are used in the lab in small quantities for sample preservation, bottle rinsing, equipment calibration, conductivity analyses, etc. The wastes are flushed down the sink and discharged into the yard drain sump and then pumped to the ash basin. Some of the laboratory chemicals are as follows: Ammonia molybdate, Acetic acid, Ferric sulfate, Hydrochloric acid, Monoethylamine, Nitric acid and Potassium hydroxide. Power House Sump (Unit 5) , The wastes, which enter the floor drains at Plant Allen, accumulate in the boiler room sumps and turbine room sumps. The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage. Effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. This sump also collects stormwater from various drains located on the north end of the powerhouse. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 9 of 12 Outfall 002A — Coal Yard Sump Overflow An overflow pipe that directs flow from the sump to the Catawba River was included in the construction of the yard sumps. This was done to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. This has occurred approximately one time in the past 5 years. Observations and monitoring of effluent during events have indicated no impact to water quality. Outfall 002B — Power House Sump Overflow An overflow pipe that directs flow from the sump to the ground was included in the construction of the yard sumps. This was done to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. If enough water overflows, the waste could potentially get to the Catawba River. This has occurred approximately twice in the past 5 years. Observations and monitoring of effluent during events have indicated no noticeable impact to water quality. Outfall 003 — Misc Equipment Cooling & Seal Water Outfall 003 discharges into the CCW discharge canal. The discharge consists of cooling water from units 4 and 5 boiler feedpump hydraulic coupling coolers and other miscellaneous equipment cooling. This water is once -through, non -contact cooling water withdrawn from the service water system. Outfall 004 Equip. Cooling & Intake Screen Backwash Equipment Cooling Water Cooling water for units 1,2 & 3 boiler feed pump hydraulic coupling coolers and other miscellaneous equipment is discharged through outfall 004. This water is once - through, non -contact water drawn from the service water system. In addition, water from a vehicle rinse -down area is directed to this outfall. The rinse water contains no soaps or other additives. Intake Screen Backwash The intake screens at Plant Allen are flushed on an "as needed" basis. Backwash usually averages 2 hours per shift. The average volume required is 0.053 MGD. The large debris floating on the river is caught on the parallel bar screens. This trash is collected and disposed of in a landfill. The silt, twigs, leaves and other light debris collected on the rotating screens are indigenous to the river and are therefore flushed back with no harmful environmental consequences. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 10 of 12 Outfall 005 — Asiatic Clam/Debris Filter Backwash Water for the Unit 5 CCW water is filtered for any twigs, leaves and other light debris which passed through the intake screens. Asiatic clams, which are common in Lake Wylie and can clog the condenser tubes, are also captured in this filter. This filter is backwashed once a week for 15 minutes. A maximum flow of 3000 GPD is realized. No other additives are in the backwash water. The twigs, leaves, clams and other light debris collected in the debris filter are indigenous to the river and are therefore flushed back with no harmful environmental consequences. Storm Water General Description As previously discussed much of the storm water runoff is directed to the ash basin (outfall 002). There are several other storm water outfalls at Plant Allen. These drains either discharge into the Catawba River or into the South Fork River via the outfall 001 discharge canal. Plant Allen was included in the storm water group application submittal (March 1991) to the Environmental Protection Agency for several Duke Power Company locations. Plant Allen 316(a) Determination Duke Power Company's 316(a) demonstration (March 1976) concluded that the "heated discharge from Plant Allen is such that the protection and propagation of a balanced indigenous aquatic community in and on Lake Wylie is assured." Duke's operation experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC0004979 substantiates the above conclusion and further supports Duke's belief that the operating characteristics of the station have a minimal effect of the aquatic environment of Lake Wylie. Surveys of the aquatic community in Lake Wylie demonstrate that a Balanced Indigenous Population exists in Lake Wylie. Accordingly, Duke requests a 316(a) variance and further requests that the thermal limitations imposed in the permit be continued. Plant Allen, Gaston County NPDES Permit No. NC0004979 Page 11 of 12 Hazardous and Toxic Substances Hazardous and Toxic Substances Table 2c- 3 At Plant Allen, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V -D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Acetaldehyde, Aniline, Asbestos, Butyl Acetate, Cresol, Cyclohexane, Formaldehyde, Monoethylamine, Naphthenic Acid, Propylene Oxide, Pyrethrins, Styrene, Triethanolamine, Vanadium, Vinyl Acetate, Xylene and Zirconium. Other - During the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will impact the ash basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. 40 CFR 117 and CERCLA Hazardous Substances The following table identifies hazardous substances located on-site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on-site that could be released at one time and sent to the ash basin. They do not reflect quantities that are discharged through typical use. SUBSTANCE Ammonia (aqueous) Benzene Hydrazine Sodium Hydroxide Sodium Nitrite Sulfuric Acid QUANTITY (Ibs.) SOURCE 9452 Storage Tank 166 Gas Storage Tank 944 Warehouse/Third floor of Powerhouse 15,566 Warehouse 2034 Warehouse and/or Mezzanine Floor 30724 Warehouse Catawba 550 .0 River/—MGD Plant Allen Water Schematic Ash Sluice Atm I IF Water Boiler Turbine Rm Treatment k---O.F Sumps Boiler Rm Sumps Intake screen Backwash AsiaticClam/ Debris Filter Backwash Powerhouse Sump Misc Equip Cooling & Seals Plant Allen, Gaston County NPDES Permit # NCO004979 Page 12 of 12 South Fork 10 River r---------------- Outfall 002A -------------- loo- Catawba i River i Coal Yard ��Sto�rmwater�#1 Sump Ash Basin- Outfall 002 Catawba 20.05 MGD* River State of North Carolina Department of Environment and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Bill Holman, Secretary Kerr T. Stevens, Director May 15, 2000 Ms. Angela M. Grooms, Manager Water Protection Duke Power Group Environment, Health & Safety 13339 Hagers Ferry Road Huntersville, North Carolina 28078-7929 • � A4 &v=1k ��� NCDENR NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Subject: NPDES Permit Modification Dan River — Permit No. NC0003468 Allen — Permit No.;NC0004979 �, Marshall — Permit No. NC0004987 Riverbend — Permit No. NC0004961 Dear Nis. Grooms: The Division issued NPDES permit numbers NC0003468. NC0004979, NC0004987, and NC0004961 on April 25, 1997. September 4, 1996, August 31. 1995, and July 29, 1996 respectively. The Division has reviewed your request for permit modification at the subject facilities. Specifically, you requested that all sump overflows as outlined in your December 1, 1999 correspondence be permitted as individual outfalls. In accordance with your permit modification request the Division is forwarding herewith modifications to the subject permits. These permit modifications incorporate effluent sampling requirements for sump overflows in accordance with the permitting strategy developed for Buck Steam Station. Enclosed please find the modified NPDES permit pages. These pages should be inserted into the respective permits and the old ones discarded. These permit modifications are issued pursuant to the requirements of North Carolina General Statute 145-215.1 and the Memorandum of Agreement between North Carolina and the U. S. Environmental Protection Agency dated December 6. 1983. Please take notice that these permits are not transferable. Part 11, E.4. addresses the requirements to be followed in case of change in ownership or control of this discharge. These permits do not affect the legal requirement to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act or any other Federal or Local government permit that may be required. 1617 MAIL SERVICE CENTER. RALEIGH, NORTH CAROLINA 27699-1617 - TELEPHONE 919-733-5083/FAX 919-733-0719 AN EQUAL OPPORTUNITY AFFIRMATIVE ACTION EMPLOYER - $O% RECYCLED/ 10% POST -CONSUMER PAPER If you have any questions concerning these modifications, please contact Mr. Mark McIntire at telephone number (919) 755-5085, extension 555. Sincerely 7d' /l err T. Stevens Enclosures: modified permit pages Cc: Central Files (correspondence, letter, modified permit pages) NPDES Permit File<y(correspondence, letter, modified permit pages) Mooresville Regional Office (letter, modified permit pages) Winston-Salem Regional Office (letter, modified permit pages) Point Source Compliance/Enforcement Unit (letter) m A. NCDENR/DIVISION OF WATER QUALITY Water Quality Section/NPDES Unit October 9, 1998 MEMORANDUM To: Dave Goodrich From: Mark McIntire Subject: Sump Overflows Duke Power Fossil Plants I have been in discussions for quite some time with John Mease and Angela Grooms of Duke Power Company regarding sump overflow issues_ NPDES permits for Allen, Buck, Dan River, Marshall, and Riverbend steam stations do not currently accommodate these overflows. Our discussions have been aimed at finding a practical, protective way of handling these situations. Earlier in the year. I instructed Duke Power to grab a series of eight samples from the sump at Buck Steam Station over a two week period (these sumps are those that deliver wastewater to the ash basins). Duke collected the samples and subsequently forwarded the results, attached, to our office on March 27, 1998. The data is indicative of an ash basin discharge with the exception of relatively high solids and iron. Incidents of high iron and TSS were likely due to heavy rains agitating sediment prior to raw water intake. These sump overflows occur in small volumes and on rare occasions. In light of the very high stream flows associated with the streams into which Duke discharges, the impact from these sump overflows is very likely minimal to zero. As such, I recommend permitting these sump overflows as a serial numbered outfall with appropriate monitoring installed typical of that required at ash basin discharges. Furthermore, as these sump overflows are relatively consistent from facility to facility, I do not think it's necessary to require characterization of the other four facilities_ Attached is a letter to Duke Power to that affect. As this proposition would involve the permitting of -an additional outfall, we would likely need to proceed with the major modification route_ In addition to monitoring for these overflows, I propose that we require Duke Power to make every reasonable attempt to minimize the occurrence of these overflows. We should also require Duke to make every reasonable attempt to redirect these overflows to the respective ash basins. ff Re: Duke Power Sump,Overflow... U Subject: Re: Duke Power Sump Overflow... Date: Mon, 01 May 2000 13:46:41 -0400 From: Larry Coble <larry.coble@ncmail.net> Organization: NC DENR Water Quality To: Mark McIntire <mark.mcintire@ncmail.net> This sounds fine to the WSRO. Mark Mcintire wrote: Gentlemen, You may remember corresponding with me about sump overflows at Duke Power fossil plants. Working with Duke Power at Buck Steam Station, we developed a strategy for permitting the yard sump overflows they were experiencing. These overflows occur very rarely (perhaps once per year) and typically involve de minimus flows. However, given the current legal and third part climate, Duke would like to have these overflows permitted at Allen, Dan River, Riverbend, and Marshall as well. As a refresher, we required episodic sampling for pH, TSS, fecal coliform, and iron. Episodic being defined as any overflow lasting longer than 1 hour. All overflows will be reported to regional office staff within the required timeframe. Iron will be analyzed if the TSS sample is reported as greater than or equal to 100 mg/L. Fecal coliform will only be required for those yard sumps receiving sanitary wastewater. The ultimate goal is to eliminate all overflows completely. Until that time, permitting these as outfalls with analytical requirements provides Duke with a level of comfort in the context of third party litigation and the Division's new overflow policy. Let me know if you have concerns regarding this matter. My plan is to handle these as minor modifications to the fossil plant permits referenced above. Thanks for your assistance. Mark Mark D. McIntire Environmental Engineer NPDES Unit - Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 (919) 733-5083, extension 553 mailto:mark.mcintire@ncmail.net wd- t �f '7 nsrnQi*?nnn In -;n e n Duke Power, A Duke En gy Company December 1, 1999 Mr. David A. Goodrich NCDENR/NPDES Unit Water Quality Section 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Permitting Sump Overflow Pipes Plant Allen Permit No. NC0004979 Dan River Steam Station Permit No. NC0003468 Marshall Steam Station Permit No. NCO004987 Riverbend Steam Station Permit No. NC0004961 Record #: NC -005157 Certified: Z 335 554 746 Dear Mr. Goodrich: Duke Power Group Environment, Health 6 Safety 13339 Hagers Ferry Road Huntersville, NC 28078-7929 Duke Power requests that the overflow pipes for the yard sumps listed below be permitted in the same manner as detailed in the draft NPDES permit (NC0004774) for Buck Steam Station Outfall #002A. That outfall page is attached. Plant Allen's coal yard sump and Riverbend Steam Station's yard sump are the only sumps containing sanitary waste. Duke Power requests that only these two sumps be required to monitor for fecal. Station Sump New Outfall Number Allen Coal yard #002A Power House #0028 Dan River Yard #002A Marshall Sump 1 #002A Sump 2 #0026 Riverbend Yard #002A See the attached site maps for location of the sump overflow discharges. Should you have questions or need additional information, please contact John Mease at (704) 875- 5347. Sincerely, i Angela M. Grooms Manager, Water Protection j rm cc: Mr. Rex Gleason, NCDENR, Mooresville, N.C. Mr. Larry Coble, NCDENR, Winston-Salem, N.C. 00,) a w SUPPLEMENT TO PERMIT COVER SHEET Duke Power Company is hereby authorized to: Permit No. NC0004979 Continue to discharge once -through, non -contact cooling water (outfall 001), operate a septic tank/sand filter and ash pond with pH adjustment (outfall 002), discharge coal yard sump overflows (outfall 002A), discharge power house sump overflows (outfall 002B), discharge miscellaneous non -contact cooling waters (outfall 003) and discharge miscellaneous non -contact cooling water, vehicle washwater, intake screen and filter backwash (outfall 004) from a facility located at Plant Allen, NCSR 2525, South of Belmont in Gaston County (See Part III of this Permit), and 2. After receiving an Authorization to Construct from the Division of Water Quality, construct and operate a groundwater remediation system discharging into the ash pond (outfall 002), and 3. Discharge from said treatment works at the location specified on the attached map into the Catawba River (outfalls 002, 002A, 002B, and 004) and the South Fork Catawba River (outfalls 001 and 003) which are classified Class WS -IV & B CA and WS -V waters, respectively, in the Catawba River Basin. A (3). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0004979 During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 002A — Coal Yard Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: - EFF°L' UENT .CHARACTERISTICS ;`' e aIS:CHARGE L=IMITATIONS '°;' MO:NITQRING :RE.QUIRENIENTS IVlontltl'y. Average, ,. "Dally: aximum Me,asu.rement Sample Frequency' : Sample Type Location s Flow (MGD) Episodic Estimate E pH Episodic Grab E Total Suspended Solids Episodic Grab E Fecal Coliform Episodic Grab E Iron See Footnote 2 Grab E THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS. ALL FLOWS WILL BE REPORTED ON MONTHLY DMRS. SHOULD NO FLOW OCCUR DURING A GIVEN MONTH-, THE WORDS "NO FLOW" SHOULD BE CLEARLY WRITTEN ON THE FRONT OF THE DMR: EPISODIC SAMPLING 15 REQUIRED PER OCCURRENCE WHEN SUMP OVERFLOWS OCCUR FOR LONGER THAN ONE HOUR. ALL SAMPLES SHALL BE OF A REPRESENTATIVE -DISCHARGE. NOTES: I Sample Locations: E — Effluent; Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2 Sampling for iron is required when TSS is reported as greater than 100 mg/L. A (4). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0004979 - During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from outfalls) serial number 002A — Power House Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT, CHARACTERISTICS. _. DISCHARGE LIIVIITATI;ONS, 1VMONITORING REQUIREMENTS 1Vlorithly-Average Datly,Maximum. Meastirernent Sample :. ,°Fre,Quency Sanlgle Type Locationl Flow (MGD) Episodic Estimate E pH Episodic Grab E Total Suspended Solids Episodic Grab E Fecal Coliform Episodic Grab E Iron See Footnote 2 Grab E THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS. ALL FLOWS WILL BE REPORTED ON MONTHLY DMRS. SHOULD NO FLOW OCCUR DURING A GIVEN MONTH, THE WORDS "NO FLOW" SHOULD BE CLEARLY WRITTEN ON THE FRONT OF THE MIR. EPISODIC SAMPLING IS REQUIRED PER OCCURRENCE WHEN SUMP OVERFLOWS OCCUR FOR LONGER THAN ONE HOUR. ALL SAMPLES SHALL BE OF A REPRESENTATIVE DISCHARGE. NOTES: I Sample Locations; E — Effluent; Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2 Sampling for iron is required when TSS is reported as greater than 100 mg/L. A. (5). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Permit No. NC0004979 During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 003. Such discharges shall be limited and monitored by the Permittee as specified below: Effluent Characteristics Discharge Limitations Monitoring Requirements Lbs/day Units (specify) Measurement Sample Samplel Mon. Avg. Daily Max. Mon. Ave. Daily Max. Frequency Tvpe Location Flow Weekly Estimate E Notes: I Sample Locations: E - Effluent Chlorination of the once through cooling water, discharged through outfall 003, is not allowed under this permit. Should Duke Power wish to chlorinate its once through cooling water, a permit modification must be requested and received prior to commencing chlorination. A. (6). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Permit No. NC0004979 During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 004. Such discharges shall be limited and monitored by the Permittee as specified below: Effluent Characteristics Discharge Limitations Monitoring Requirements Lbs/day Units (specify) Measurement Sample Samplel Mon. Ave. Daily Max. Mon. Avg. Daily Max. Frequency Type Location Flow Weekly Estimate E Oil and Grease 15.0 m /l 20.0 m /l 2/Month Grab E Notes: 1 Sample Locations: E - Effluent Chlorination of the once through cooling water, discharged through outfall 004, is not allowed under this permit. Should Duke Power wish to chlorinate its once through cooling water, a permit modification must be requested and received prior to commencing chlorination. ow... Subject: Re: Duke Power Sump Overflow... Date: Mon, 01 May 2000 13:46:41 -0400 lk From: Larry Coble <larry.coble@ncmail.net> anization: NC DENR Water Quality To: Mark Mcintire <mark.mcintire@ncmail.net> This sounds fine to the WSRO. Mark Mcintire wrote: Gentlemen, You may remember corresponding with me about sump overflows at Duke Power fossil plants. Working with Duke Power at Buck Steam Station, we developed a strategy for permitting the yard sump overflows they were experiencing. These overflows occur very rarely (perhaps once per year) and typically involve de minimus flows. However, given the current legal and third part climate, Duke would like to have these overflows permitted at Allen, Dan River, Riverbend, and Marshall as well. As a refresher, we required episodic sampling for pH, TSS, fecal coliform, and iron. Episodic being defined as any overflow lasting longer than 1 hour. All overflows will be reported to regional office staff within the required timeframe. Iron will be analyzed if the TSS sample is reported as greater than or equal to 100 mg/L. Fecal coliform will only be required for those yard sumps receiving sanitary wastewater. The ultimate goal is to eliminate all overflows completely. Until that time, permitting these as outfalls with analytical requirements provides Duke with a level of comfort in the context of third party litigation and the Division's new overflow policy. Let me know if you have concerns regarding this matter. My plan is to handle these as minor modifications to the fossil plant permits ,referenced above. Thanks for your assistance. A4 f GtJa j ltoL Mark �lNo 1, C.a�_ ► tA l Mark D. McIntire Environmental Engineer NPDES Unit - Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 (919) 733-5083, extension 553 maiIto:mark.mcintire@ncmall.net NCDENR/DIVISION OF WATER QUALITY Water Quality Section/NPDES Unit e Goodrich k McIntire Subiect: Sump 'Overflows Duke Power Fossil Plants October 9, 1998 I have been in discussions for quite some time with John Mease and Angela Grooms of Duke Power Company regarding sump overflow issues. NPDES permits for Allen, Buck, Dan River, Marshall, and Riverbend steam stations do not currently accommodate these overflows. Our discussions have been aimed at finding a practical, protective way of handling these situations. Earlier in the year. I instructed Duke Power to grab a series of eight samples from the sump at Buck Steam Station over a two week period (these sumps are those that deliver wastewater to the ash basins). Duke collected the samples and subsequently forwarded the results, attached, to our office on March 27, 1998. The data is indicative of an ash basin discharge with the exception of relatively high solids and iron. Incidents of high iron and TSS were likely due to heavy rains agitating sediment prior to raw water intake_ These sump overflows occur in small volumes and on rare occasions. In light of the very high stream flows associated with the streams into which Duke discharges, the impact from these sump overflows is very likely minimal to zero. As such, I recommend permitting these sump overflows as a serial nuinhered outfall with appropriate monitoring installed typical of that required at ash basin discharges. Furthermore, as these sump overflows are relatively consistent from facility to facility, I do not think it's necessary to require characterization of the other four facilities. Attached is a letter to Duke Power to that affect. As this proposition would involve ,the permitting of -an additional outfall, we would likely need to proceed with the major modification route_ In addition to monitoring for these overflows, I propose that we require Duke Power to make every reasonable attempt to minimize the occurrence of these. overflows. We should also require Duke to make every reasonable attempt to redirect these overflows to the respective ash basins_ Iv V In \IV Page Four 3. Treatment plant classification: Class I for outfall 002. Outfalls 001, 003 and 004 do not meet the minimum criteria for a class I rating. 4. SIC Code(s): 4911 Wastewater Code(s): 68,66 MTU Code(s): 50002 PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grant Funds or are any public monies involved (municipals only)? No 2. Special monitoring or limitations (including toxicity) requests: a. Permittee has requested that monitoring for oil and grease (O/G) be deleted at outfalls 002 & 004. Rationale: analytical results for the past two (2) years have all been below detection. MRO staff can support a reduction in the monitoring frequency, however, the potential exists for O/G to enter this waste stream, therefore, complete removal of this parameter is not recommended. Defer to the NPDES Unit for review and comment. b. Permittee has requested the deletion of monitoring for naphthalene, phenol, and chromium at outfall 002. Rationale: analytical results for the past two (2) years have all been below detection. Upon review of the analytical testing for these parameters, MRO staff can support the removal of all three (3) parameters, pending concurrence by the NPDES Unit. C. Permittee requests the reduction of fecal coliform & BODS monitoring from monthly to semi-annually, and TSS monitoring from monthly to quarterly. Rational: none given. Concurrence with the reduction in monitoring for fecal coliform and BODS is recommended based on a review of available analytical data. A reduction in the monitoring frequency for TSS is not recommended at this time. d. Permittee requests that the iron and copper limitation in the permit be restricted to periods only when chemical metal cleaning is occurring. Rationale: 40 CFR 423 (Steam Electric Guidelines) restricts iron and copper during a chemical metals cleaning to 1.0 mg/1 above background levels. Defer to the NPDES Unit for review and comment. 3. Important SOC/JOC or Compliance Schedule dates: N/A 4. Alternative Analysis Evaluation: There are no practicable alternatives for the elimination of any of the existing waste streams. Page Five PART IV - EVALUATION AND RECOMMENDATIONS The permittee is requesting renewal of the subject permit. There have been no changes to the facility and/or the permit since the last renewal. Changes requested by Duke for this renewal are discussed in Part III, No. 2 above. Pending review and approval of the WLA and review and approval by P & E, it is recommended that the Permit be renewed as requested. Signature of Report Preparer Date ,U, � -/ el-%�--� S'/0/0 / Water Quality Re nal Supervisor Date h:\dsr\dsrO l \al I en. dsr