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HomeMy WebLinkAboutNC0039586_Environmental Monitoring Report_20021218v� CP&L A Progress Energy Company DEC 1 8 2002 Mr. Alan Klimek, Director Division of Water Quality N. C. Department of Environment and Natural Resources 1617 Mail Service Center Raleigh, NC 27699-1617 aue- F 3t1o3 SERIAL: HNP -02-166 Subject: Harris Nuclear Plant 2001 Environmental Monitoring Report Dear Mr. Klimek: s� co"-��o Enclosed are three copies of the Harris Nuclear Plant 2001 Environmental Monitoring Report. The report summarizes the results of water quality monitoring conducted by Carolina Power & Light Company at the Harris Reservoir during 2001. During 2001, operational effects of the Harris Nuclear Plant on the water quality and aquatic life continued to be minimal. Nutrient concentrations, including total phosphorus and total nitrogen concentrations, remained stable for the reporting period (1997-2001). The concentrations of most chemical constituents did not exhibit any consistent temporal trends. Please contact Mr. R. T. Wilson at (919) 362-2444 if you have any questions concerning this report or if you have a need for additional information. Sincerely, 011�� B. C. Wald1Qp Plant General Manager Harris Nuclear Plant MGW Enclosure c: Mr. D. Goodrich — NCDWQ I Mr. F. A. Harris — NCWRC DEC D 3 D 2002 Ms. C. Sullins - NCDWQ I' Harris Nuclear Plant _ 5413 Shearon Harris Road z - New Hill, NC 27562 HARRIS NUCLEAR PLANT 2001 ENVIRONMENTAL MONITORING REPORT October 2002 Environmental Services Section CP&L — A Progress Energy Company New Hill, North Carolina e Harris Nuclear Plant 2001 Environmental Mon Preface This copy of the report is not a conti olled document as detailed in Environmental Services Section Biology Program Procedures aid Quality Assurance Manual. Any changes made to the original of this report subsequent to the late of issuance can be obtained from: Director Enviro mental Services Section CP&L — A. Progress Energy Company 3932 New Hill -Holleman Road New Hill, orth Carolina 27562-0327 Carolina Power & Light Company I Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Table of Contents Page Preface................................................. :................................................................................... i Listof Tables......:..................................................:................................................................. iii List of Figures.....................................................................................:................................... Listof Appendices................................::................................................................................. ui Metric -English Conversion and Units of Measure.......................................:........................... iv Water Chemistry Abbreviations.......:...........................................:....................:..................... iv EXECUTIVESUMMARY.............................::...................................................................... v HARRIS NUCLEAR PLANT 2000 ENVIRONMENTAL MONITORING REPORT ReservoirDescription........................................................................................................ 1 - Objectives:.. _ . _ _ - : ............................. Methods............................................................................................................................. 2 RESULTS OF ENVIRONMENTAL MONITORING AT HARRIS RESERVOIR DURING 2000 - Limnology..................................... :................................................................................... 7 Temperature and Dissolved Oxygen.....:..................................................................... 7 WaterClarity...........................................................................................................:... 7 Chlorophylla:...............................................:.....................:........................................ 7 Nutrients and Total Organic Carbon........................................................................... 8 Specific Conductance, Ions and Hardness..............................................:.................... 8 pHand Total Alkalinity..................................................... :......................................... 8 Trace Metals and Metalloids ................. :...................................... ................... ............ 9 Biofouling Monitoring Surveys ...................................... ................... :.................................. 9 AquaticVegetation............................................................................................................ 9 CONCLUSIONS......................................................................................::............................. 10 REFERENCES................. :........................................................................... :.......................... 11 Carolina Power & Light Company ii Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Repo List of Tables Table Page 1 Environmental monitoring pr gram at Harris Reservoir for 2001 .......................... 4 2 Field sampling and laboratory methods followed in the 2001 environmental monitoring program at Harris eservoir.................................................................. 5 3 Statistical analyses performed on data collected for the 2001 environmental monitoring program at Harris eservoir........:...................:................................ 6 List of Figures Figure Page 1 Sampling areas and stations at Harris Reservoir during 2001 .................................. 3 Appendix 1 Water temperature, dissoly transparency data collected 2 Means, ranges, and spatial from the surface waters of l 3 Annual mean water chemis of Harris Reservoir 1997-21 4 Concentrations of chemical Carolina Power & Light Company t of Appendices Page oxygen, conductivity, pH, and Secchi disk :)m Harris Reservoir during 2001 ......................... A-1 nds of selected limnological variables rris Reservoir during 2001 ................................... A-2 variables from the surface waters 1............................................................................ A-3 riables in Harris Reservoir during 2001 .............. A-4 iii Environmental Services Section Harris Nuclear Plant 2007 Environmental Monitoring Report Metric -English Conversion and Units of Measure Length 1 micron (um) = 4.0 x 10-5 inch 1 millimeter (mm) = 1000 Aim =-0.04 inch 1 centimeter (cm) = 10 mm = 0.4 inch 1 meter (m) = 100 cm = 3.28 feet 1 kilometer (km) = 1000 m = 0.62 mile Area 1 square meter (m2) = 10.76 square feet 1 hectare (ha) = 10,000 m2 = 2.47 acres Volume 1 milliliter (ml) = 0.034 fluid ounce 1 liter = 1000 ml = 0.26 gallon 1 cubic meter = 35.3 cubic feet Cl- - Chloride SO4 - Sulfate Ca2' - Total calcium Weight 1 microgram (,ug) = 10"3 mg or 10-6 g = 3.5 x 10-8 ounce 1 milligram (mg) = 3.5 x 10-5 ounce 1 gram (g) = 1000 mg = 0.035 ounce- - — - 1 kilogram (kg) = 1000 g = 2.2 pounds 1 metric ton = 1000 kg = 1.1 tons 1 kg/hectare = 0.89 pound/acre- Temperature- Degrees Celsius ('C) = 5/9 (°17-32) Specific conductance gS/cm = Microsiemens/centimeter Turbidity NTU = Nephelometric Turbidity Unit Water Chemistry Abbreviations Mg 2+ - Total magnesium Na' - Total sodium TN - Total nitrogen NH3-N - Ammonia -nitrogen NO3 + NO2 - N - Nitrate + nitrite -nitrogen TP - Total phosphorus TOC - Total organic carbon TS - Total solids TDS - Total dissolved solids TSS - Total suspended solids Al - Total aluminum Cd - Total cadmium Cu - Total copper Hg - Total mercury Carolina Power & Light Company iv Environmental Services Section Harris Nuclear Plant Harris Reservoir supplies makeup Plant. The Harris Nuclear Plant volume waste discharges into the i Nutrient concentrations, including tots stable for the reporting period (1997 - reservoir in this area. The concentra consistent statistically significant temp detrimental to the biological communit Hydrilla stands reaching the surface Reservoir during 2001. However, no f of hydrilla were observed in the littora to control hydrilla in the auxiliary rese and 1997 appears to have been effe vegetation. Carolina Power & Light Company 2001 Environmental Monitoring Report I SUMMARY to the closed -cycle cooling system for the Harris Nuclear primarily cooling tower blowdown along with low near the main dam. phosphorus and total nitrogen concentrations, -remained- - - - - )01) and were in an acceptable range for a productive Dns of most chemical constituents did not exhibit any -al changes and were in ranges that were not considered - the water were observed in the intake canal in Harris ing of the plant intake screens has occurred. No stands zone of the auxiliary reservoir during 2001. The attempt voir by releasing grass carp in the autumn of 1994, 1996, Ive in reducing the quantity and area covered by this V Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report HARRIS NUCLEAR PLANT 2001 ENVIRONMENTAL MONITORING REPORT Reservoir Description Harris Reservoir, located in Chatham and Wake, Counties, North Carolina, was created by impounding Buckhorn Creek, a tributary of the Cape Fear River (Figure 1). The main body of Harris Reservoir has a surface area of 1680 ha; the auxiliary reservoir has a surface area of 130 ha. The main reservoir has a maximum depth of 18 in, a mean depth of 5.3 in, a volume of 8.9 x 1W m3, a full -pool 'elevation of 67.1 m National Geodetic Vertical Datum (NGVD), and an average residence time of 28 months. The reservoir began -filling in December 1980 and full -pool elevation was reached in February 1983. The 64.5 -km shoreline is mostly wooded and the 183.9 -km2 drainage area is mostly rolling hills with land used primarily for forestry and agriculture. The conversion of areas from forestry or agricultural purposes to residential uses continues in many areas of the drainage. Harris Reservoir was constructed to supply cooling tower makeup and auxiliary reservoir makeup water to the 900 -MW Harris Nuclear Plant, which began commercial operation in May 1987. In 1986 the bottom waters of the reservoir near the main dam began receiving National Pollutant Discharge Elimination System (NPDES)-permitted wastewater discharges from the power plant. -cooling tower. Tributaries also receive NPDES-permitted discharges from the Harris Energy and Environmental Center and from wastewater treatment plants at Apex and Holly Springs. The reservoir is a source of drinking water for some CP&L employees. Objectives The primary objectives of the 2001 Harris Nuclear Plant non -radiological environmental monitoring program were to: (1) assess the reservoir's overall water quality, (2) identify any natural or power plant -induced effects on the water quality in the reservoir, and (3) document the introduction and expansion of nonnative plant and animal populations in the reservoir. These objectives have also been addressed in previous annual monitoring reports with the most recent detailed in CP&L 1997, 1998, 1999, 2000, and 2001. Carolina Power & Light Company 1 Environmental Services Section Harris Nuclear Plant The 2001 environmental program characteristics (water quality, water vegetation, and (3) possible introduce methods, data summaries, and statist those used for data collected during data were evaluated for the most rece 2001 Environmental Monitoring Report Methods monitoring the reservoir's: (1) limnological tmistry, and chlorophyll a), (2) distribution of aquatic is of the zebra mussel and the quagga mussel. Sampling 1 analyses for data collected during 2001 were similar to )0 (CP&L 2001) (Tables 2 and 3). Trend analyses of the five years of monitoring (1997-2001) for most programs. Supporting data summaries and. appr priate statistical analyses were used to describe and interpret the environmental quality of th,e reservoir (Table 3). _ All analytical testing, except total phosphorus analyses, completed in support of the Harris Reservoir environmental monitoring program was performed by testing laboratories that are certified by the N. C. Division of Water Quality's Laboratory Certification Program to perform water and wastewater testing. Perkin Limnological Consulting, LLC, a vendor approved by CP&L for this testing, conducted total phosphorus analysis. The accuracy and precision of laboratory analyses of water chemistry data were determined with analytical standards, spikes, and replicates. Quality assurance info ation including the accuracy and percent recovery of water chemistry standards are available upon request. In this report where concentrations were less than the laboratory -reporting limit the concentrations were assumed _to be at one-half the reporting limit for the calculation of the mean. Where statistically significant -results were reported, a Type I error rate of 5% (« L 0.05) was used and Fisher's protected least significant difference test was applied to determine]where significant differences in mean values occurred. Carolina Power & Light Company 2 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Tom Jack - Thomas y; P 2 t f �dClt€S��e IDtake I Auxiliary Cf07 Canal:. Reservoir 49 (MI) Z DikeBoat R \Outfall. Ramp 006 r -Emergency y Figure 1. Sampling areas and stations at Harris Reservoir during 2001. Carolina Power & Light Company 3 Environmental Services Section Service. Water.lntake P 2 t Holl s Cf07 r - Boa 4A. Figure 1. Sampling areas and stations at Harris Reservoir during 2001. Carolina Power & Light Company 3 Environmental Services Section Harris Nuclear Plant' AAAA C�.....�.�...�.�i..l ■■�.�7i�..7.��. []L:��..i Table 1. Environmental monitoring program at Harris Reservoir for 2001. Program Frequency Location Water quality January, May, July, November Stations E2, H2, P2, and S2 (surface to bottom at 1-m intervals) - Water chemistry January, May, July, November Stations E2, H2, P3, and S2 (surface samples at all stations) Plankton+ January, May, July, November Stations E2, H2,.P3, and S2 Biofouling monitoring -_ Zebra mussel surveys January; May, July, November Areas E, P or -Q, and -V - - Aquatic vegetation survey Once per calendar year (Fall) Areas MI and Z +Plankton included phytoplankton (algae) and chlorophyll a samples. Phytoplankton samples were collected and preserved but were not identified because all sampled chlorophyll a concentrations were < 40 ,ug/L. Carolina Power & Light Company 1 4 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Table 2. Field sampling and laboratory methods followed in the 2001 environmental monitoring program at Harris Reservoir. Program Method Water quality Temperature, dissolved oxygen, pH, and specific conductance were measured with calibrated YSI@ multiparameter instruments and YSIo dissolved oxygen meters. Measurements were taken from surface to bottom at 1-m intervals. Water clarity was measured with a Secchi disk. Water chemistry Surface (Stations E2, H2, P2, and S2) and bottom samples (Station E2) were collected in appropriate containers, transported to the laboratory on ice, and analyzed according - - - - to -accepted -laboratory methods.- Phytoplankton Equal amounts of water from the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth were obtained with a Van Dorn sampler and mixed in a plastic container. A 250-m1 sub sample was taken -and preserved with 5 ml of "MY fixative. Chlorophyll a Equal amounts of water from the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth were obtained with a Van Dorn sampler, placed in a plastic container and mixed, then a 1000-m1 sub sample was collected in a dark bottle. All samples were placed on ice and returned to the laboratory. In the laboratory a 250-m1 sub sample was analyzed according to Strickland and Parsons (1972) and APHA (1995). Zebra mussel The dock at the Holleman's boat ramp, or water quality station marker buoys were visually inspected for the presence of mussels during routine water quality monitoring. Aquatic Portions of the shoreline and/or littoral zone of the Harris Plant main reservoir intake vegetation canal and auxiliary reservoir were systematically surveyed by boat to document the survey presence of aquatic vegetation, specifically --hydrilla- and creeping water primrose. Carolina Power & Light Company 5 Environmental Services Section Harris Nuclear Plant 2001 Environmental Table 3. Statistical analyses perfo�med on data collected for the 2001 environmental monitoring program at Harris Reservoir. Transfor- Statistical Main Program Variable mation Test/model' effect(s) Water quality Specific conductance Secchi disk transpare Specific conductance Secchi disk transpare Water chemistry _Select_monitoring var Select monitoring var Phytoplankton Chlorophyll a Chlorophyll a None One-way, block on month Station None Two-way, block on month Station, year None _ One -way, -block on -month Station None Two-way, block on month Station, year None One-way, block on month Station None Two-way, block on month Station, year +Statistical tests used were one-way and two-way analysis of variance models. A Type I error rate of 5% (a = 0.05) was used to judge the significance of all tests. Fisher's protected least significant difference (LSD) test was applied to determine where differences in means occurred. Carolina Power & Light Company 6 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report RESULTS OF ENVIRONMENTAL MONITORING AT HARRIS RESERVOIR DURING 2001 Limnology Temperature and Dissolved Oxygen • Reservoir waters were stratified at all stations during May and July and were either well mixed or very weakly stratified during January and November, 2001 (Appendix 1). During May and July, portions of the hypolimnion were anoxic (i.e., conditions where dissolved oxygen concentrations are less than 1 mg/liter) at Stations E2, H2, P2, and S2 (Appendix 1). A bottom -water oxygen decline is typical at the deeper stations during the warm -summer months in Harris Reservoir and in other productive southeastern water bodies when well- defined thermoclines develop. Water Clarity (Secchi disk transparency, Solids, and Turbidity) • The Secchi disk transparency depth (a water clarity indicator) generally increased with linear distance from the headwater region (Station S2) to the dam during May and July 2001 (Appendix 1). However, headwaters were much clearer than downstream stations during January and November of 2001. Although there were monthly spatial differences, there were no significant differences in the annual mean Secchi disk transparencies between stations during 2001 (Appendix 2). Neither were there any significant differences in the reservoir -wide annual mean Secchi disk transparency values during the period 1997 to 2001 (Appendix 3). • There were no significant spatial trends for solids (i.e., total solids and total suspended solids) or turbidity except for total dissolved solids during 2001 (Appendix 2). • The annual mean total solids and total dissolved solids were statistically variable during the 1997 through 2001 observation period (Appendix 3). biologically important. Chlorophyll a These minor fluctuations were not • During 2001, mean chlorophyll a concentrations (an indicator of algal biomass) in Harris Carolina Power & Light Company 7 Environmental Services Section Harris Nuclear Plant Reservoir continued to be indicative unlike concentrations measured in 1 the North Carolina water quality star were no significant spatial differ (Appendix 2). 2001 Environmental Monitoring Report of moderate to high biological productivity. However, 97 and 1998, no chlorophyll a concentration exceeded lard of 40 µg/liter during 2001 (NCDEM 1992). There nces in chlorophyll a concentrations during 2001 - Annual mean chlorophyll a concen tions observed during 2001 were significantly less than during 1997 and 1998 (Appendi)c 3). Nutrients and Total Organic Carbon ( urface waters) • There were no significant spatial differences among stations for mean nutrient (i.e., phosphorus, ammonia -N, nitrate + trite -N, and total nitrogen) and total organic carbon concentrations in Harris Reservoir d 'ng 2001 (Appendix 2). • Statistically significant temporal tre ds were detected only for nitrate + nitrite -N and total organic carbon from "1997 to 2001 Appendix .3). However, these differences were not considered biologically important. Specific Conductance, Ions, and K • There were no significant spatial during 2001 (Appendix 2). • The annual mean chloride concent concentrations during 1997- 1999. ( and sulfate were also greater during these values represent relatively sm • The annual mean reservoir conducti, the previous four years (Appendix 3). Carolina Power & Light Company waters in conductivity, ion- concentration or hardness ion significantly increased during 2001 compared to pendix 3). The annual mean concentrations of sodium D1 compared to one or more previous years. However, increases. was significantly higher during 2001 compared to 8 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report pH and Total Alkalinity e Similar to 2000, the median pH in the surface waters of Harris Reservoir was 7.2 during 2001 (Appendix 1).. e In 2001 total alkalinity concentrations were not statistically different among stations (Appendix 2). The annual mean total alkalinity concentrations fluctuated significantly but with no consistent pattern during the 1997 to 2001 comparison period (Appendix 3). Trace Metals and -Metalloids (surface waters) e Overall, concentrations of trace elements in Harris Reservoir were generally low in 2001 with most concentrations less than or near their respective laboratory reporting limits (Appendices 2 and 4). No spatial trends for any measured trace elements were observed during 2001 (Appendix 2). Aluminum concentrations ranged from < 50 to 92 jig/liter during 2001 with the greater value recorded in a headwater region where aluminum concentrations may have been influenced by upstream watershed sources (Appendices 2 and 4). e Copper exhibited statistically significant variations in surface waters but no true temporal trend was observed during the 1997 to 2001 comparison period (Appendix 3). Aluminum also exhibited statistically significant variations in surface waters. The mean aluminum concentration measured during 1999 was significantly greater than alLother-years from 1997 - to 2001. No other temporal differences were observed among trace element concentrations in the surface waters of Harris Reservoir for the period 1997 to 2001 (Appendices 3 and 4). Biofouling Monitoring Surveys e No zebra mussels (Dreissena polymorpha) or quagga mussels (D. bugensis), potentially serious biofouling organisms to power plant operations, were found in Harris Reservoir or the auxiliary reservoir during 2001. Zebra mussels and quagga mussels are not expected to thrive in Harris Reservoir because concentrations of alkalinity, calcium, total hardness, and pH are sub -optimal for mussel growth and reproduction (Claudi and Mackie 1993). Carolina Power & Light Company 9 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Aquatic Vegetation • A visual survey for troublesome aq atic vegetation was conducted in the Harris Auxiliary Reservoir on October 15, 2001. The survey included traveling by boat along the reservoir and intake canal shorelines looking r topped -out stands of hydrilla (Hydrilla verticillata) as well as visiting shoreline locations where stands of hydrilla had previously grown. No hydrilla was observed in the auxili reservoir. These observations indicate that stocking grass carp effectively reduced the abi ndance of hydrilla. A similar aquatic vegetation survey was conducted the same'day; in areas -just outside -of and - in theHarris Reservoir main intake canal. This survey indicated the presence of hydrilla growing in the main intake canal. Both shorelines of the main intake canal were covered with dense stands of water primros (Jussiaea repens) and smartweed (Polygonum spp.). These stands appeared to be similar in. density and coverage area to stands seen in previous years. Hydrilla in the intake canald in the Thomas Creek area just outside the intake canal was relatively more abundant in 200 than during 2000 due to the mild winter and warm, dry summer. Similar levels of hydrillaowth have been observed in the past with no effect on Harris Plant operations. • No impacts to Harris Nuclear Plant operations from aquatic vegetation occurred during 2001. NCLUSIONS During 2001, the Harris Reservoir continued to show characteristics of a typical biologically productive southeastern, reservoir with sasonally occurring oxygen -deficient subsurface waters, elevated nutrient concentrations, and abu dant rooted, shallow -water aquatic plants. The environmental monitoring program conducted during 2001 continued to provide an assessment of the effects of the Harris Nuclear Plant's operation on the various components of the aquatic environment. Most key indicators of the environmental quality in Harris Reservoir were unchanged from the previous five ears. Nutrient concentrations have been a concern in Harris Reservoir since phosphorous annitrogen concentrations increased rapidly in the late 1980s and early 1990s. Water quality as essments determined that nutrient concentrations have remained stable since 1995 and at lev is acceptable for productive, southeastern reservoirs. Carolina Power & Light Company 10 Environmental Services Section Hams Nuclear Plant 2001 Environmental Monitoring Report Assessments of other water quality parameters, including solids, turbidity, total organic carbon, ions (calcium, chloride, magnesium, sodium, and sulfate), total alkalinity, hardness, and metals, indicate few if any consistent, statistically significant spatial or temporal trends. None of these variables were at concentrations that would be detrimental to the aquatic community. No nuisance algal blooms, as indicated by chlorophyll a concentrations, or exotic mussels were detected in the main reservoir during 2001. Reservoir -wide chlorophyll a concentrations demonstrated no consistent statistically significant increasing trend for the period 1997-2001. Hydrilla was relatively more abundant in the intake canal during 2001 compared to 2000. The reduced size and extent of aquatic vegetation stands in the auxiliary reservoir indicates that grass carp released in the fall of 1994, 1996, and 1997 continued to control the amount and area coverage of hydrilla during 2001. No operational impacts have occurred at the Harris Nuclear Plant because of aquatic vegetation biofouling. REFERENCES APHA. 1995. Standard methods for the examination of water and wastewater. 19th ed. American Public Health Association, Washington, DC. CP&L. 1997. Shearon Harris Nuclear Power Plant 1996 annual environmental monitoring report. Carolina Power & Light Company, New Hill, NC. 1998. Shearon Harris Nuclear Power Plant 1997 annual environmental monitoring report. Carolina Power & Light Company, New Hill, NC. 1999. Shearon Harris Nuclear Power Plant 1998 annual environmental monitoring report. Carolina Power & Light Company, New Hill, NC. 2000. Shearon Harris Nuclear Power Plant 1999 annual environmental monitoring report. Carolina Power & Light Company, New Hill, NC. 2001. Shearon Harris Nuclear Power Plant 2000 annual environmental monitoring report. Carolina Power & Light Company, New Hill, NC. Claudi, R., and G. L. Mackie. 1993. Practical manual for zebra mussel monitoring and control. Lewis Publishers, Boca Raton, FL. NCDEM. .1992. North Carolina lake assessment report. Report No. 92-02. Water Quality Section, Division of Environmental Management, North Carolina Department of Environment, Health, and Natural Resources, Raleigh, NC. 1994. Administrative code. Classification and water quality standards applicable to Carolina Power & Light Company 11 Environmental Services Section Harris Nuclear Plant surface waters of North Management, Department of Strickland, J. D. H., and T. R. Paj Bulletin No. 167 (2nd ed.). F 2001 Environmental Monitoring Report ina. North Carolina Division of Environmental onment, Health, and Natural Resources, Raleigh, NC. 1972. A practical handbook of seawater analysis. Research Board of Canada. Carolina Power & Light Company 12 Environmental Services Section ' Harris Nuclear Plant 24.6 25.3 24.6 2001 Environmental Monitoring Report Appendix 1. Water temperature, dissolved oxygen, conductivity, pH, and Secchi disk 23.6 23.8 23.5 transparency data collected from Harris Reservoir during 2001. 22.8 23.4 23.2 4.0 23.1 21.7 January 23, 2001 1.4 5.0 Depth Temperature Dissolved oxygen Conductivity pH Secchi disk depth (m) 19.6 (°C) 19.7 0.2 (mg/L) (/,,S/cm) 18.5 (m) E2 H2 P2 -S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 0.2 6.2 6.8 5.9 6.8 12.1 13.0 12.5 10.9 81 73 73 89 6.9 6.9 6.7 6.5 1.4 1.8 1.5 1.8 1.0 6.2 6.8 5.9 6.8 12.1 13.0 12.4 10.9 81 73 73 89 6.9 6.9 6.7 6.5 13.0 2.0 6.2 6.4 5.9 6.7 12.1 13.0 12.3 10.8 81 72 73 92 6.9 6.9 6.7 6.5 3.0 6.1 6.3 5.9 6.7 12.1 13.0 12.3 10.3 81 72 73 93 6.9 6.9 6.7 6.5 4.0 6.1 6.3 5.8 12.1 13.0 12.3 81 72 73 6.9 6.9 6.7 5.0 - 6:1 _6.3 -5.8-- • .12.1 -13.0. 12:2 81 72 73 -6.9 -6:9- - 6.7- - 6.0 6.1 6.3 5.8 12.1 12.9 12.2 81 72 73 6.9 6.8 6.7 7.0 6.1 6.2 5.8 12.1 12.8 12.2 81 72 73 6.9 6.8 6.7 8.0 6.1 6.2 5.8 12.1 12.5 12.2 81 72 73 6.9 6.8 6.7 9.0 6.1 12.1 81 6.9 10.0 6.1 12.1 81 6.9 11.0 6.1 12.1 81 6.9 12.0 6.1 12.1 81 6.9 13.0 6.1 12.1 81 6.9 14.0 6.1 12.1 81 6.9 15.0 6.0 11.9 81 6.8 May 30, 2001 Depth Temperature Dissolved oxygen Conductivity pH Secchi disk depth (m) (°C) (mom) (PS/cm) (m) E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 0.2 24.6 25.3 24.6 24.6 1.0 24.2 24.2 24.2 24.0 2.0 23.6 23.8 23.5 23.8 3.0 23.5 22.8 23.4 23.2 4.0 23.1 21.7 22.8 1.4 5.0 21.4 20.6 20.8 0.3 6.0 19.6 20.1 19.7 0.2 7.0 18.2 18.5 18.3 8.0 17.8 17.5 17.7 0.1 9.0 17.3 17.2 0.1 10.0 16.6 0.1 11.0 16.0 12.0 15.4 0.0 13.0 14.9 0.0 14.0 14.1 15.0 13.6 16.0 13.6 17.0 13.5 12.1 11.7 11.0 10.2 12.4 12.2 11.2 9.6 12.6 12.2 11.2 9.2 12.1 8.4 10.2 1.2 10.4 5.3 8.2 5.9 1.3 3.2 1.4 0.8 1.3 0.3 0.3 0.4 0.2 0.1 0.2 0.2 0.1 0.2 0.1 0.1 0.1 0.1 0.0 0.0 0.0 171 120 122 123 122 118 121 121 119 117 119 120 119 117 118 124 118 117 118 118 116 119 121 117 118 124 120 119 124 126 121 121 128 119 118 117 118 122 124 126 129 7.8 7.7 6.7 6.3 7.9 7.7 6.9 6.5 8.0 7.7 6.9 6.5 7.9 7.7 6.9 6.4 7.7 7.6 6.8 7.7 7.4 6.8 7.5 7.3 6.7 7.5 7.2 6.7 7.4 7.1 6.6 7.3 7.0 7.3 7.2 7.2 7.1 7.0 7.0 6.9 6.9 1.4 1.4 1.2 0.9 Carolina Power & Light Company A-1 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Appendix 1 (continued) July 2, 2001 Depth Temperature Dissolved oxyg�n Conductivity pH Secchi disk depth (m) (°C) (mg/L) (,US/cm) (m) E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 0.2 28.5 30.9 30.1 30.6 8.4 9.2 8.4 8.9 119 123 123 119 6.7 6.8 6.7 6.3 1.3 1.2 1.2 1.1 1.0 28.5 30.3 30.1 30.4 8.5 9.4 8.6 9.1 119 122 123 119 6.8 6.9 6.8 6.5 2.0 28.5 30.2 30.0 30.2 8.6 9.5 8.8 9.0 119 121 123 119 6.8 6.9 6.8 6.5 3.0 28.2 28.9 29.5 29.5 8.2 7.9 8.5 4.6 118 117 122 115 6.8 6.9 6.8 6.5 4.0 27.8 24.6 25.2 27.9 6.9 1.0 0.2 0.5 117 111 121 115 6.8 7.0 6.8 6.4 5.0 26.4 22.8 21.4 --1-.7 0.2 0.1 115 .119 130 6.8 -6.8 6.6 6.0 21.7 20.5 20.8 0.1 0.1 0.1 141 131 132 6.8 6.7 6.5 7.0 20.9 19.9 19.9 0.1 0.1 0.1 144 136 133 6.6 6.6 6.4 8.0 19.9 19.3 19.0 0.0 0.1 0.0 142 138 136 6.4 6.5 6.3 9.0 19.4 19.1 18.9 0.0 0.1 0.0 141 139 137 6.3 6.3 6.3 10.0 19.4 18.4 0.0 0.0 136 141 6.3 6.2 11.0 17.7 0.0 134 6.3 12.0 17.1 0.0 133 6.2 13.0 16.1 0.0 134 6.2 14.0 14.7 0.0 146 6.2 15.0 14.5 0.0 148 6.2 16.0 14.3 0.0 154 6.1 November 29, 2001 Depth Temperature Dissolved oxyg n Conductivity pH Secchi disk depth (m) (°C) (mg/L) (YS/cm) (m) E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 E2 H2 P2 S2 0.2 15.0 17.1 16.6 16.8 8.6 11.2 10.8 10.8 89 92 88 93 7.5 7.5 7.5 7.7 1.3 1.6 1.7 2.0 1.0 14.8 16.9 16.2 16.8 7.8 11.0 10.6 10.7 89 91 92 92 7.4 7.5 7.5 7.7 2.0 14.6 16.2 15.9 15.8 7.5 10.8 10.3 10.5 89 90 90 92 7.3 7.5 7.5 7.8 3.0 14.5 15.0 15.4 14.0 7.0 10.0 9.5 8.1 88 86 89 98 7.3 7.4 7.5 7.2 4.0 14.4 14.5 14.8 13.2 6.8 8.3 8.2 7.5 89 86 89 109 7.2 7.4 7.4 7.1 5.0 14.4 14.2 14.4 6.6 7.6 7.4 88 86 87 7.2 7.3 7.3 6.0 14.3 14.0 14.0 6.4 6.7 6.3 88 86 88 7.2 7.3 7.2 7.0 14.3 13.9 14.0 6.4 5.5 5.7 89 86 88 7.2 7.2 7.2 8.0 14.3 13.9 14.0 6.4 5.0 5.4 88 86 89 7.2 7.2 7.1 9.0 14.2 13.8 14.0 6.3 3.9 4.9 88 86 90 7.1 7.0 7.1 10.0 14.2 6.0 88 7.1 11.0 14.1 5.8 89 7.1 12.0 14.1 5.6 89 7.1 13.0 14.1 5.0 93 7.0 14.0 14.1 4.1 93 7.1 Carolina Power & Light Company A-2 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Appendix 2. Means, ranges, and spatial trends of selected limnological variables from the surface waters of Harris Reservoir during 2001.+ Carolina Power & Light Company A-3 Environmental Services Section Station E2 H2 P2 S2 Variable Solids (mg/liter) Total 82 76 75 82 (52-94) (37-94) (38-91) 42-98) Total dissolved; 7ab� 5 ;67bb 69;; a 82 (69 $3) (48 80)h (47'82) (76 89) Total suspended 3.9 2.6 2.1(3-.T-5.0) (< 5-5)--- _ - (<-5--2.3) - (< 5-4.2) - Turbidity (NTU) 4.3 4.2 4.5 6.0 (2.8-6.6) (2.3-6.1) (3.2-5.8) (4.9-7.2) Secchi disk transparency (m) 1.6 1.5 1.4 1.5 (1.3-1.4) (1.2-1.8) (1.2-1.7) (0.9-2.0) Chlorophyll a (µg/liter) 15 17 12 8.9 (9.0-22) (9.0-31) (7.5-22) (4.8-13) Nutrients (mg/liter) Ammonia -N 0.08 <0.10 0.11, 0.11 (< 0.05-0.13) (<0.02-0.16) (< 0.02-0.19) (< 0.02-0.24) Nitrate + Nitrite -N 0.04 0.02 0.03 0.02 (< 0.02-0.13) (< 0.02-0.04) (< 0.02-0.10) (< 0.02-0.03) Total nitrogen 0.67 0.65 0.61 0.61 (0.52-0.87) (0.54- 0.79) (0.48-0.75) (0.47-0.72) Total phosphorus 0.042 0.026 0.025 0.031 (0.026-0.074) (0.021-0.030) (0.020-0.030) (0.017-0.039) Total organic carbon (mg/liter) 8.5 8.4 8.2 8.6 (7.5-9.3) (7.4-8.8) (7.4-8.7) (7.2-9.6) Ions (mg/liter) Calcium 3.8 3.7 3.6 4.1 (3.5-4.1) (3.3-3.9) (2.9-4.4) (3.45.2) Chloride 10 10 11 12 (12-14) (9.0-11) (10-12) (9.2-14) Magnesium 1.6 1.6 1.5 1.7 (1.0-2.0) (1.1-1.8) (<1.0-1.8) (1.0-2.1) Sodium12 11 11 12 (11-14) (8.9-12) (10-12) (11-14) Sulfate 16 15 15 15 (14-17) (10-12) (14-18) (14-17) 12 14 14 16 Total alkalinity (mg/liter as CaCO3) (7.0-15) (13-15) (12-15) (12-23) Hardness (calculated as mg 16 15 13 17 equivalents CaCO3/liter) (13-18) (14-17) (3.1-18) (14-22) Conductivity (µS/cm) 103 102 102 106 (81-123) (73-123) (73-123) (89-123) Carolina Power & Light Company A-3 Environmental Services Section Harris Nuclear Plant Appendix 2 (continued) 2001 Environmental Monitoring Report +Fisher's protected least significant difference test was applied only if the overall F test for the treatment was significant. Me s followed by the same superscript were not significantly different (P > 0.05)—see shad d row. Sample size equaled 4 for all variables unless otherwise noted. The mean seplaration technique may yield separations that are obscured by data rounding. if This value is an action level, not substances, which are generall, life because of chemical forr characteristics (NCDEM 1994) NA = All measured values were less tr Carolina Power & Light Company r water quality standard. An action level is for toxic not bioaccumulative and have variable toxicity to aquatic , solubility, stream characteristics, or associated waste yIan the laboratory lower reporting limit. A-4 Environmental Services Section N.C. water Station quality Variable standard E4 H2 P2 S2 Metals (µg/liter) Aluminum None < 5< 50 <50 50 N NA NA (< 50-92) Cadmium 2 < 015 < 0.5 < 0.5 < 0.5 NA NA NA NA Copper 711 2. 1.3 1.5 1.4 (1.2- .0) (< 1.0-3.0) (< 1.0-2.0) (< 1.0-2.0) Mercury 0.012 < 0{2 < 0.2 < 0.2 < 0.2 NA NA NA NA +Fisher's protected least significant difference test was applied only if the overall F test for the treatment was significant. Me s followed by the same superscript were not significantly different (P > 0.05)—see shad d row. Sample size equaled 4 for all variables unless otherwise noted. The mean seplaration technique may yield separations that are obscured by data rounding. if This value is an action level, not substances, which are generall, life because of chemical forr characteristics (NCDEM 1994) NA = All measured values were less tr Carolina Power & Light Company r water quality standard. An action level is for toxic not bioaccumulative and have variable toxicity to aquatic , solubility, stream characteristics, or associated waste yIan the laboratory lower reporting limit. A-4 Environmental Services Section Harris Nuclear Plant 2001 Environmental Monitoring Report Appendix 3. Annual mean water chemistry variables from the surface waters of Harris Reservoir 1997-2001.+ Variable Solids (mg/liter) Total Total dissolved Total suspended¶ Turbidity (NTU) Secchi disk transparency (m) Chlorophyll a (µg/liter) Nutrients (mg/liter) Year 1997 1998 20 17 1999 2000 2001 _ `$.lbr _ . . _ . 7'66~ 85b.. Metals (µg/liter) 54b 68a -:76a -5 'b 78a Aluminum 76b... Cadmium 54b 69a 73a 58b 73a <6 4 3. Sa' 2 6 ."k 1 `Cb <5 <5 <5 5.7 5.8 Mercury 8.9 6.2 4.8 1.3 1.2 1.3 1.5 1.4 2?__�._.14b.� 20abj 13b .,_. Ammonia -N. < 0.07 0.05 < 0.05 < 0.05. 0.10 Nitrate +nitrite -N O OSab O 04ab 0 08w U.03 0 03b Total nitrogen 0.74 0.56 0.62 0.58 0.63 Total phosphorus Total organic carbon (mg/liter) Ions (mg/liter) Calcium Chloride Magnesium Sodium Sulfate - Total alkalinity (mg/liter as CaCO3) 0.034 0.034 0.033 0.032 0.031 72bc s 7 Bab 8 3a 8 4a 3.7 5.3 3.9 3.6 3.8 866. 93b12a lla F 1.7 1.6 1.7 1.6 1.9 Hardness (mg equivalents CaCO3/liter) 16 20 17 16 16 Conductivity {µS/cm) _ `$.lbr _ . . _ . 7'66~ 85b.. Metals (µg/liter) Aluminum 76b... Cadmium < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 Copper 3. Sa' 2 6 ."k 1 `Cb Mercury < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 +Fisher's protected least significant difference test was applied only if the overall F test for the treatment was significant. Means followed by the same superscript were not significantly different (P > 0.05) -see shaded rows. Data were rounded to conform to significant digit requirements. The mean separation technique may yield separations that are obscured by data rounding. ¶In June 1998, the lower reporting limits (LRLs) changed for total suspended solids from 6 to 3 mg/L and in 1999, the LRLs changed for total suspended solids from 3 to 5 mg/l. fie Carolina Power & Light Company A-5 Environmental Services Section t 'a ci z z N C, I- N mrnItt- F rn0O(7%V) � N 00 00 CT M U mNrnN b C) Uo, o -, O -. N � oo z O o 0 Z N F C 0000 v v v z 00 cn 00 \.D O CT M In + F ���t--: � z Cd 0000 v v v -o 00 00 06 r w 'G7, ny F. N- F 0000 F 0000 d' Z in o m to N N N N ��� z O000 q -I --.0 N N N N 0000 0000 ►� Jy O O O O 04 N N N N z v x 0000 z VN vv -�� O Oo00 z oo t-v)in p OOO N 0000 E-4 0000 U Nr,cq +R 0000 " In In � V �n 'O z V O O O z z .--� O O N 0C) _N � v'v v v y + Nu V V V V Q O o O O in in In 000000 V) N -4 -. -. v v v v .� z Nl0Nif) N 0 0 0 z IqIq kn CV -,icM M 0 0 0 Nro 0000 U -� (V.-. --. N W U C;m U --. CV (V - A roM�rn ,O n [- oo � �o z V] N C, I- N mrnItt- F rn0O(7%V) H 00 00 CT M U mNrnN b X00-tm Uo, o -, O -. N � oo 7 Z N F y z 00 cn 00 \.D O CT M In + F ���t--: � 0000�� Cd 0000 v v v py 00 00 06 r w 'G7, ny rN CO - m � M M N r— F 0000 F 0000 d' p' Z z mrnItt- z H 00 00 CT M .N 7 NN 00 tf) N v1 Uo, o -, O -. N � oo 7 Z N 0 o0o y z o F + 0000 v v 'tIDin. Q 0000�� Cd 0000 v v v py 00 00 06 r Cv pr F CqCf) Ln w 0 0 0 0 F 0000 z p' Z N N N N ��� z O000 Cd N N N N 0000 F [zi Z o�ocqN z o�NN -�� O Oo00 0000 x 0000 x o00o x 0000 " z V z v v x 0 0 0 v V V V V ��� kr) z p N 0 0 0 z IqIq p M 0 0 0 E.I 0000 U -� (V.-. --. [� 0000 U --. CV (V - v +� n +R Vi Vi Iq to z N O O 'b U 0 0 0 0 v v v z cq 'b v 0 0 0 0 .v :cq0 v v v v +0 NU d� 0 0 0 �n tf) W) in + NU o O O O o0 .--� C` r- 00 O 00 C` v v v V' ,� v v v v NM N v^ W O�O�ooO QI OOONO + Vj kn(V M.� + viN-:CV N� %C mF V F V U mMMM .� V MC � Ca C� C/� A 'o000N� �0Non d �00in T > T > .1z tiz co Q mrnItt- 0000 CTM H 00 00 CT M 00 tf) N v1 Uo, o -, O -. :'d -• m tet; .. 7 �o Cil M in y F y d 'tIDin. Q 0000�� Cd F 00 00 06 r �a pr MNNN CqCf) Ln w 0 0 0 0 0000 p' O It oo M N N N ��� F' O000 Cd – 0000 � �z , ,z T > T > .1z tiz co Q 0000 CTM w 00 tf) N v1 •-r •-• •-•--� � V1 M m V1 7 F y -Z F 00 o0 oo t kC �a pr MNNN CqCf) Ln F 0 0 0 0 0000 T > T > .1z tiz co Q Harris Nuclear Plant 2001 Environmental Monitoring Report Appendix 4 (continued) +Units are in mg/L except for trace elements (tg/L), turbidity (NTU), total alkalinity (mg/L as CaCO3), and hardness (calculated as mg equivalents CaCO3/Q. Carolina Power & Light Company A-7 Environmental Services Section Station S2 Month Alkalinity Hardness CI SO4 Cat+ Mgt+ Na+ TN NH3-N NO3 + NO2 -N Jan 23 22 14 14 5.2 2.1 14 0.69 0.07 0.03 May 14 14 12 17 3.8 1.0 13 0.72 0.24 < 0.02 Jul 12 17 9.2 14 3.9 1.7 11 0.54 0.12 < 0.02 Nov 14 16 12 15 3,4 1.8 11 0.47 < 0.02 < 0.02 Month TP TOC Turbidity TS TDS TSS Al Cd Cu Hg TN:TP Jan 0.036 8.5 5.4 92 84 < 5.0 <50 <0.5 < 1.0 -< 0.20 19 May 0.039 9.2 6.5 98 89 4.2 92 < 0.5 2.0 < 0.20 18 - Jul 0.030 9.6 4.9 95 80 3.6 57 < 0.5 2.0 =<=0.20 18 Nov 0.017 7.2 7.2 - 42 76 2.2 <50 < 0.5 1.1 < 0.20 28 +Units are in mg/L except for trace elements (tg/L), turbidity (NTU), total alkalinity (mg/L as CaCO3), and hardness (calculated as mg equivalents CaCO3/Q. Carolina Power & Light Company A-7 Environmental Services Section T3