NC0000396_Water Sample Location_20161014

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Go gte-earth
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acmnalyiical
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November 03, 2016
Mr. Pete Harrison
Waterkeeper Alliance
17 Battery Place Ste 1329
Suite 1329
New York, NY 10004
RE: Project: ALN -10/14/2016
Pace Project No.: 92316174
Dear Mr. Harrison:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]r
Enclosed are the analytical results for sample(s) received by the laboratory on October 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Revised Report: Report revised to add requested metal
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
G�� 2
Chris Derouen
[e-mail]
Project Manager
Enclosures
cc: Larissa Liebmann, Waterkeeper Alliance
ESQ pCCR�c��
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REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 1 of 19

aceAnalytical
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Project: ALN -10/14/2016
Pace Project No.: 92316174
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH -0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Nebraska Certification: NE -OS -28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
ALN -10/14/2016
92316174
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92316174001
A -US -1-F
EPA 200.7
SH1
4
PASI-A
EPA 200.7
CKJ
2
PASI-O
Silica Calculation
SH1
1
PASI-A
EPA 200.8
JTJ
14
PASI-O
EPA 245.1
WAB
1
PASI-A
SM 2540C
MJS1
1
PASI-A
EPA 218.7
AEM
1
PASI-O
EPA 300.0
AES2
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 4500-P E
CJH1
1
PASI-A
92316174002
A -US -1-T
EPA 200.7
SH1
4
PASI-A
EPA 200.7
CKJ
2
PASI-O
Silica Calculation
SH1
1
PASI-A
EPA 200.8
JTJ
14
PASI-O
EPA 245.1
WAB
1
PASI-A
SM 2540C
MJS1
1
PASI-A
EPA 218.7
AEM
1
PASI-O
EPA 300.0
AES2
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 4500-P E
CJH1
1
PASI-A
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aceMalXical
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Project: ALN -10/14/2016
Pace Project No.: . 92316174
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: A -US -1-F
Lab ID: 92316174001 Collected:
10/14/16 14:24
Received: 10/14/16 16:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared
Analyzed
CAS No. Qua]
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Boron
1280 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:15
7440-42-8
Calcium
31200 ug/L
100
1
10/18/16 02:30
10/20/16 23:15
7440-70-2
Iron
704 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:15
7439-89-6
Silicon
11800 ug/L
500
5
10/18/16 02:30
10/21/16 14:13
7440-21-3
Lithium
ND ug/L
500
1
10/24/16 14:20
10/26/16 09:24
7439-93-2
Manganese
822 ug/L
5.0
1
10/24/16 14:20
10/26/16 09:24
7439-96-5
Silica Calculation
Analytical Method: Silica Calculation
Silica Calculation
25300 ug/L
214
1
10/21/16 17:24
7631-86-9 N2
200.8 MET ICPMS
Analytical Method: EPA 200.8 Preparation
Method: EPA 200.8
Aluminum
ND ug/L
10.0
1
10/24/1614:20
10/26/1612:02
7429-90-5
Antimony
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-36-0
Arsenic
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-38-2
Barium
53.1 ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-39-3
Beryllium
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:02
7440-41-7
Cadmium
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:02
7440-43-9
Chromium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-47-3
Cobalt
7.2 ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-48-4
Lead
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7439-92-1
Molybdenum
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7439-98-7
Selenium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7782-49-2
Strontium
223 ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-24-6
Thallium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-28-0
Vanadium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-62-2
245.1 Mercury
Analytical Method: EPA245.1 Preparation Method: EPA245.1
Mercury
ND ug/L
0.20
1
10/18/16 06:10
10/19/16 13:01
7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
206 mg/L
25.0
1
10/17/16 17:08
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
10/19/16 16:04
18540-29-9
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
93.7 mg/L
20.0
10
10/27/1611:39
14808-79-8
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
10.6 mg/L
1.0
1
10/20/16 20:19
16887-00-6
SM4500P-E, Phosphate, Ortho
Analytical Method: SM 4500-P E
Orthophosphate as P
ND mg/L
0.050
1
10/15/16 01:10
M1
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: ALN -10/14/2016
Pace Project No.: 92316174
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: A -US -1-T Lab ID: 92316174002 Collected: 10/14/16 14:34 Received: 10/14/16 16:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP
Boron
Calcium
Iron
Silicon
Lithium
Manganese
Silica Calculation
Silica Calculation
200.8 MET ICPMS
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Lead
Molybdenum
Nickel
Selenium
Strontium
Vanadium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
Hexavalent Chromium by IC
Chromium, Hexavalent
300.0 IC Anions 28 Days
Sulfate
4500 Chloride
Chloride
SM4500P-E, Phosphate, Ortho
Orthophosphate as P
Date: 11/03/2016 02:14 PM
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
1290 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:18
7440-42-8
31400 ug/L
100
1
10/18/16 02:30
10/20/16 23:18
7440-70-2
1110 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:18
7439-89-6
11500 ug/L
500
5
10/18/16 02:30
10/21/16 14:18
7440-21-3
ND ug/L
500
1
10/24/16 14:20
10/26/16 09:28
7439-93-2
846 ug/L
5.0
1
10/24/16 14:20
10/26/16 09:28
7439-96-5
Analytical Method: Silica Calculation
24700 ug/L
214
1
10/21/1617:24
7631-86-9 N2
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 '
35.7 ug/L
10.0
1
10/24/1614:20
10/26/1612:05
7429-90-5
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05.7440-36-0
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-38-2
54.3 ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-39-3
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:05
7440-41-7
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:05
7440-43-9
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-47-3
7.1 ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-48-4
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7439-92-1
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7439-98-7
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-02-0
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7782-49-2
220 ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-24-6
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-62-2
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1
ND ug/L
0.20
1
10/18/16 06:10
10/19/16 13:08
7439-97-6
Analytical Method: SM 2540C
202 mg/L
25.0
1
10/17/1617:08
Analytical Method: EPA 218.7
ND ug/L
0.030
1
10/19/1616:17
18540-29-9
Analytical Method: EPA 300.0
94.2 mg/L
20.0
10
10/28/16 02:34
14808-79-8 M6
Analytical Method: SM 4500 -CI -E
10.9 mg/L
1.0
.1
10/20/16 20:20
16887-00-6
Analytical Method: SM 4500-P E
ND mg/L
0.050
1
10/15/16 01:10
REPORT OF LABORATORY ANALYSIS
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aceAna1j&ca1
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Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333492
QC Batch Method: EPA 245.1
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1848121
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Mercury ug/L
LABORATORY CONTROL SAMPLE: 1848122
Parameter Units
Mercury ug/L
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 245.1
Analysis Description: 245.1 Mercury
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.20 10/19/1611:54
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.5 100 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848123 1848124
MS MSD
92316145003 Spike . Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 2.5 2.5 99 98 70-130 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848125 1848126
MS MSD
92316158004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 2.4 2.4 97 98 70-130 `1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
01
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333303 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1847176
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Calcium ug/L
Iron ug/L
Silicon ug/L
Matrix: Water
Blank Reporting
Result Limit Analyzed
ND 100 10/20/16 22:35
ND 50.0 10/20/16 22:35
ND 100 10/20/16 22:35
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE:
1847177
1847179
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Calcium
ug/L
5000
5130
103 85-115
Iron
ug/L
5000
4760
95 85-115
Silicon
ug/L
2500
2520
101 85-115
_ MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1847178
1847179
MS
MSD
92316149001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qua[
Calcium ug/L
3810
5000
5000
9040
9110
105
106
70-130
1
Iron ug/L
85.5
5000
5000
4890
4890
96
96
70-130
0
Silicon ug/L
5170
2500
2500
7760
7760
103
103
70-130
0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 19
Pace Analytical Services, LLC
aceMalXical ®
2225 Riverside Dr.
Asheville, NC 2880404
www.pscelab&com
[phone]
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 327776
Analysis Method:
EPA 200.8
QC Batch Method: EPA 200.8
Analysis Description:
200.8 MET
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1749996
Matrix: Water
Associated Lab Samples: 92316174001, 92316174002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Aluminum
ug/L
ND
10.0
10/26/1611:46
Antimony
ug/L
ND
1.0
10/26/1611:46
Arsenic
ug/L
ND
1.0
10/26/1611:46
Barium
ug/L
ND
1.0
10/26/1611:46
Beryllium
ug/L
ND
0.10
10/26/1611:46
Cadmium
ug/L
ND
0.10
10/26/1611:46
Chromium
ug/L
ND
1.0
10/26/1611:46
Cobalt
ug/L
ND
1.0
10/26/1611:46
Lead
ug/L
ND
1.0
10/26/1611:46
Molybdenum
ug/L
ND
1.0
10/26/1611:46
Nickel
ug/L
ND
1.0
10/26/1611:46
Selenium
ug/L
ND
1.0
10/26/1611:46
Strontium
ug/L
ND
1.0
10/26/1611:46
Thallium
ug/L
ND
1.0
10/26/1611:46
Vanadium
ug/L
ND
1.0
10/26/1611:46
LABORATORY CONTROL SAMPLE & LCSD:
1749998
1750295
Spike
LCS LCSD
LCS LCSD
% Rec
Max
Parameter
Units
Conc.
Result Result
% Rec % Rec
Limits RPD
RPD Qualifiers
Aluminum
ug/L
500
555
520
111 104
85-115
6 20
Antimony
ug/L
50
52.1
50.3
104 101
85-115
3 20
Arsenic
ug/L
50
53.6
52.4
107 105
85-115
2 20
Barium
ug/L
50
52.8
51.6
106 103
85-115
2 20
Beryllium
ug/L
5
5.6
5.5
111 109
85-115
2 20
Cadmium
ug/L
5
5.0
5.1
101 102
85-115
1 20
Chromium
ug/L
50
52.0
52.8
104 106
85-115
1 20
Cobalt
ug/L
50
53.9
53.3
108 107
85-115
1 20'
Lead
ug/L
50
51.7
51.0
103 102
85-115
1 20
Molybdenum
ug/L
50
51.6
51.5
103 103
85-115
0 20
Nickel
ug/L
50
55.1
53.6
1111 107
85-115
3 20
Selenium
ug/L
50
54.3
52.5
109 105
85-115
3 20
Strontium
ug/L
50
53.2
51.1
106 102
85-115
4 20
Thallium
ug/L
50
52.6
51.9
105 104
85-115
1 20
Vanadium
ug/L
50
52.3
52.1
105 104
85-115
0 20
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: ALN -10/14/2016
Pace Project No.: 92316174
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1749999
1750000
MS
MSD
92316911001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qua]
Aluminum
ug/L
88.8
500
500
651
663
112
115
70-130
2
Antimony
ug/L
3.6J
50
50
55.7
55.2
104
103
70-130
1
Arsenic
ug/L
85.1
50
50
136
138
102
105
70-130
1
Barium
ug/L
224
50
50
270
277
93
108
70-130
3
Beryllium
ug/L
0.028J
5
5
5.8
5.7
115
114
70-130
1
Cadmium,
ug/L
ND
5
5
5.0
5.1
101
101
70-130
0
Chromium
ug/L
ND
50
50
52.4
53.8
104
107
70-130
3
Cobalt
ug/L
0.33J
50
50
53.5
53.5
106
106
70-130
0
Lead
ug/L
ND
50
50
54.0
53.1
108
106
70-130
2
Molybdenum
ug/L
65.3
50
50
115
117
99
103
70-130
2
Nickel
ug/L
3.2J
50
50
55.8
56.6
105
107
70-130
1
Selenium
ug/L
11.0
50
50
62.3
61.3
102
100
70-130
2
Strontium
ug/L
1360
50
50
1390
1380
59
42
70-130
1 M1
Thallium
ug/L
0.26J
50
50
52.9
52.8
105
105
70-130
0
Vanadium
ug/L
19.6
50
50
72.9
74.4
107
110
70-130
2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1750001
1750002
MS
MSD
92316577002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
ug/L
0.011
500
500
591
603
116
118
70-130
2
mg/L
Antimony
ug/L
ND
50
50
52.0
50.8
104
102
70-130
2
Arsenic
ug/L
ND
50
50
52.8
52.9
104
104
70-130
0
Barium
ug/L
0.0021
50
50
56.4
55.7
109
107
70-130
1
mg/L
Beryllium
ug/L
ND
5
5
6.1
6.0
121
119
70-130
2
Cadmium
ug/L
ND
5
5
5.3
5.4
105
108
70-130
2
Chromium
ug/L
ND
50
50
54.4
53.7
108
107
70-130
1
Cobalt
ug/L
ND
50
50
52.9
52.8
106
106
70-130
0
Lead
ug/L
ND
50
50
52.4
52.0
105
104
70-130
1
Molybdenum
ug/L
0.0010
50
50
54.3
53.6
107
105
70-130
1
mg/L
Nickel
ug/L
ND
50
50
52.3
52.2
105
104
70-130
0
Selenium
ug/L
ND
50
50
52.2
52.9
104
106
70-130
1
Strontium
ug/L
0.32
50
50
366
367
92
95
70-130
0
mg/L
Thallium
ug/L
ND
50
50
53.5
53.0
107
106
70-130
1
Vanadium
ug/L
ND
50
50
54.3
53.8
107
107
70-130
1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 19

aceAnaljftal
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QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 333444
Analysis Method: SM 2540C
QC Batch Method: SM 2540C
—
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1847891
Matrix: Water
Associated Lab Samples: 92316174001, 92316174002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0
10/17/16 17:02
LABORATORY CONTROL SAMPLE:
1847892
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 238
95 90-110
SAMPLE DUPLICATE: 1847893
92316026004 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Dissolved Solids
mg/L
ND ND
SAMPLE DUPLICATE: 1847894
92316116001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Dissolved Solids
mg/L
3480 4010
14 D6
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
www.pacelabs.com
Project: -ALN-10/14/2016
Pace Project No.: 92316174
QC Batch: 326916
QC Batch Method: EPA 218.7
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1744556
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Chromium, Hexavalent ug/L
LABORATORY CONTROL SAMPLE: 1744557
Parameter `Units
Chromium, Hexavalent ug/L
QUALITY CONTROL DATA
Analysis Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Matrix: Water -
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.030 10/19/1614:59
Spike LCS
Conc. Result
.075 0.077
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS % Rec
% Rec Limits Qualifiers
102 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1744558 1744559
MS MSD
701993001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chromium, Hexavalent ug/L <0.030 .075 .075 0.079 0.076 85 80 85-115 5 H3,M1
Results presented on this page are In the units.indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 19

aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 334632
Analysis Method: EPA
300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0
IC Anions
Associated Lab Samples: 92316174001
METHOD BLANK: 1854981
Matrix: Water
Associated Lab Samples: 92316174001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Sulfate mg/L
ND 2.0
10/26/1616:23
LABORATORY CONTROL SAMPLE: 1854982
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Sulfate mg/L
20
18.9
94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1854983
1854984
MS
MSD
92316304002
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Sulfate mg/L 2.3
20
20 19.8
19.8 88 88
90-110
0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1854985
1854986
MS
MSD
92316826012
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Sulfate mg/L 6.1
20
20 24.5
24.5 92 92
90-110
0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 19

aceAnalj cal
www.pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 334732 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92316174002
METHOD BLANK: 1855484 Matrix: Water
Associated Lab Samples: 92316174002
Blank Reporting
Parameter Units Result Limit Analyzed
Sulfate mg/L ND 2.0 10/27/1612:33
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1855485
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 18.6 93 90-110
14
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1855486 1855487
MS MSD
92316174002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 94.2 20 20 110 110 78 - 79 90-110 0 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1855488 1855489
MS MSD
92316295003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 16700 20 20 37.2 37.2 102 103 90-110 0
ug/L
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 19

aceAnalyiical
wwpecelaftcom
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333557
QC Batch Method: SM 4500 -CI -E
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1848383
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Chloride mg/L
QUALITY CONTROL DATA
Analysis Method: SM 4500 -CI -E
Analysis Description: 4500 Chloride
Matrix: Water
Blank Reporting
Result Limit Analyzed
ND 1.0 10/20/16 20:14
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1848384
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chloride mg/L 20 21.2 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848385 1848386
MS MSD
92316010001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 2930 10 10 2960 3020 320 930 90-110 2 M6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11103/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 19

acmnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 1333286 Analysis Method: SM 4500-P E
QC Batch Method: SM 4500-P E Analysis Description: SM450OP-E Phosphorus, Ortho
Associated Lab Samples: 92316174001, 92316174002
Pace Analytical Services, LLC
2225 Riverside Dr. "
Asheville, NC 28804
[phone]
METHOD BLANK: 1847152 Matrix: Water
Associated Lab Samples: 92316174001, 92316174002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Orthophosphate as P mg/L ND 0.050 10/15/16 01:10
LABORATORY CONTROL SAMPLE: 1847153
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Orthophosphate as P mg/L .25 0.25 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1847154 1847155
MS MSD
92316174001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Orthophosphate as P mg/L ND .25 .25 0.32 0.32 121 121 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 19

Pace Analytical Services, LLC
aceMalXical ® hevi Riverside 04
Asheville, NC 28804
www.pacelabs.com [phone]
QUALIFIERS
Project: ALN -10/14/2016
Pace Project No.: 92316174
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D).- Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold NELAC/TNI accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
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Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 19

aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
ALN -10/14/2016
92316174
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92316174001
A -US -1-F
EPA 200.7
327775
EPA 200.7
327873
92316174001
A -US -1-F
EPA 200.7
333303
EPA 200.7
333572
92316174002
A -US -1-T
EPA 200.7
327775
EPA 200.7
327873
92316174002
A -US -1-T
EPA 200.7
333303
EPA 200.7
333572
92316174001
A -US -1-F
Silica Calculation
334146
92316174002
A -US -1-T
Silica Calculation
334146
92316174001
A -US -1-17
EPA 200.8
327776
EPA 200.8
327874
92316174002
A -US -1-T
EPA 200.8
327776
EPA 200.8
327874
92316174001
A -US -1-F
EPA 245.1
333492
EPA 245.1
333497
92316174002
A -US -1-T
EPA 245.1
333492
EPA 245.1
333497
92316174001
A -US -1-F
SM 2540C
333444
92316174002
A -US -1-T
SM 2540C
333444
92316174001
A -US -1-F
EPA 218.7
326916
92316174002
A -US -1-T
EPA 218.7
326916
92316174001
A -US -1-F
EPA 300.0
334632
92316174002
A -US -1-T
EPA 300.0
326819
92316174002
A -US -1-T
EPA 300.0
334732
92316174001
A -US -1-F
SM 4500 -CI -E
333557
92316174002
A -US -1-T
SM 4500 -CI -E
333557
92316174001
A -US -1-F
SM 4500-P E
333286
92316174002
A -US -1-T
SM 4500-P E
333286
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 19

•
OocumentName:
Document Revised: Sept. 21, 2016
SamplqConditionUpon•
Cllent Name:
e.
at;eAnalX101
Sample Condition Upon Recei t SCUR
Pae i of 2
1, '
Pro,
Issuing Authority:
ONO
.1
Document No:
Short Hold Time Anril tis (02 hr.)?
Courier:
diE
[:]Fed
LIP❑USPS Cllent
F•CAWCS 139-Rev.00 .
Pace Quality Office
❑Pace
r
Pace 2 of 2 for internal Use ONLY
SamplqConditionUpon•
Cllent Name:
Y s
WO## : 92316174
Receipt
1, '
Pro,
act #:
ONO
.1
2 -
Short Hold Time Anril tis (02 hr.)?
Courier:
diE
[:]Fed
LIP❑USPS Cllent
111111 II III II III�II III
❑ Commercial
❑Pace
[]Other:
92316174
Custody Seal Present?
❑Yes MNO
Seals Intact? ❑Y s �o
Nt-
Date/Initials Person Examining Contents: 10
Parking Material:
[]Bubble Wrap
[]Bubble Bags None ❑Other.
Thermometer:
d5
et ❑Blue
Type Of ka:
❑None MSamples on ke, tooling ocess has tiegun
No
❑ IR Gun ID:.
Correction Factor:
Cooler Temp Corrected ('C): i , V
Biological Tissue Frozen? []Yes
Temp should be above fir zing to 6'C
6.
- -Pace Containers Used?
USDA Regulated Still ( N/A, water sample)
Did samplqg originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
_
Did samples originate from a foreign source ((ntei tionalty,
r
CLIENTNOTIFICATION/RESOLUTION Held Date Required? []Yes []NO
Person Contacted:' _ Date/Time:
Comments/Sample
Discrepancy:
Project Manager SCURF Review: moi^ Oaten !
Project Manager SRF Review: Date: (5/115
Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be lent to the North Ca lin DEHNR Certification Office (Le.
Out of hold, incorrect preservative, out of temp, Incorrect containers)
Laboratory recelving.samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh[] Mechanlesville❑
Page 18 of 19
i` Comments/01screpancy.
Chain of Custody Present?
Y s
On
N/A
1, '
Samples Arrived within Hold Time?
Y s
ONO
QYLA
2 -
Short Hold Time Anril tis (02 hr.)?
esnNa
EINIA
3,
Rusts Turn Around Time Requested?
[]Yes
VN,
❑N/A
4.
Sufficient Volume?
JJVA
CdNb
❑N A
Correct Containers Used?Y
[]No❑N/A
6.
- -Pace Containers Used?
Y
No
N/A
Containers Intact?
VA.
FM
ON/A
7.
Samples Fleld.Flttered7
MYes
N/A
8. ' . Note if sediment is visible In the dissolved container
Sample Labels Match COC?
[:]Yes
No
[]'N/A
-Indudes date/TimeAD/Anal sis Matrix-
All containers needing acid/base preseNation have been
10.
checked and documented on page two of SCURF?
Yes
[]No
mN/A
Exceptions: VOA, Coliform, TOC, 011 and Grease, DRO/8015
:
(water) DOC, LLHS
u
Samples checked for dechlorinatlon? No ❑ /A
Heads ace in VOA Vials >S-6mm)?
Yes
ONO
N A
12. .
Trip Blank Present?
❑Yes
dNo
'EJy/A
13.
Trip Blank Custody Seals Present?
[-]Yes
❑Na
N/A
Pace Trip Blank Lotq Ifpurchased:
CLIENTNOTIFICATION/RESOLUTION Held Date Required? []Yes []NO
Person Contacted:' _ Date/Time:
Comments/Sample
Discrepancy:
Project Manager SCURF Review: moi^ Oaten !
Project Manager SRF Review: Date: (5/115
Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be lent to the North Ca lin DEHNR Certification Office (Le.
Out of hold, incorrect preservative, out of temp, Incorrect containers)
Laboratory recelving.samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh[] Mechanlesville❑
Page 18 of 19

(-0- ;a7w
Anal r:f `
Section A Seelion 8
CHAIN -OF -CUSTODY /Analytical Request.bocument
The ChairraFCustody is a LEGAL DOCUMENT. All relevant folds mist be completed accvratdy.
Section C
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