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HomeMy WebLinkAboutNC0024406_Ash Basin Discharge to The Dan River_19950525Duke Power Company _ Electric System Support Depottment ` 13339 Haggis Ferry Road Huntersoille, NC28078-7929 4�ZEN3Nq. sFavtic� May 25, 1995 North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management P.O. Box 29535 Raleigh, North Carolina 27626-0535 Re: Belews Creek Steam Station Ash Basin Discharge to The Dan River Mr Juan Mangles: Per our telephone conversation of May 25, please find enclosed the above referenced Engineering Report dated June 10, 1983 and letter concerning the plan for Phase III monitoring of the Dan River. If you have any further questions or need additional information, please contact me at (704)875-5973. -311LL8/lA� Susan P Covington Assistant Scientist Water Protection Printed on recycled paper 6r Duke Power Company Fossil Production Department P 0. Bm• 3.31:5.9 ` 922 South Church Street Charlotte, N.C. =82.12 DUKE POWER October 3, 1989 Mr. R. Paul Wilms, Director North Carolina Division of Environmental Management P. O. Box 27687 Raleigh, North Carolina 27611-7687 Subject: Duke Power Company/Belews Creek Steam Station Public Notice Comments/NPDES No. NCO024406 File: BC -704.21 Dear Sir: i (704).773-4011 Duke Power has reviewed the September 7, 1989 public notice and draft NPDES permit proposed for issuance to the above referenced facility. We submit the following comments for consideration in final determinations regarding the proposed permit. Duke Power objects to the note at the end of the toxicity testing section which reads "Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environ- mental controls, shall constitute an invalid test and will require immediate retesting (within 30 days of initial monitoring event). Failure to submit suitable test results.will constitute non-compliance with monitoring require- ments." As presently worded, the Department would attempt to penalize a permittee, without any evidence that the permittee's effluent is toxic, merely because the permittee has been unable to conduct a valid test. The unfairness of this is even more apparent when one considers the fact that most permittees will probably be using third -party laboratories to conduct these tests. All laboratories that are conducting these tests should be certified by the State of North Carolina. Thus, North Carolina has another mechanism to address its concern regarding valid monitoring 'results. Its avenue is through the labora- tory certification. However, it is manifestly unfair to penalize a permittee, without any evidence that its effluent is toxic or is otherwise not in compli- ance, when the permittee has done all that is within its ability to conduct a valid test and to submit valid test results. While the State of North Carolina may feel quite comfortable in the reproducibility of the acute and chronic toxicity testing, there have. been a number of studies that show at the very least that the reproducibility of this type of monitoring is less than the reproducibility of other monitoring requirements'appearing in the NPDES permit. Where the Department has chosen to employ a test which is dependent, in part, upon the survival and procreation of organisms very sensitive to even minor changes in their environment, the State should recognize that good faith efforts on the part of permittees to comply with monitoring requirements should not subject the permittee to the possibility of non-compliance. ` Mr. R. Paul Wilms October 3, 1989 Page two If the permittee has chosen to use a certified and reputable laboratory for its testing, and if the permittee has diligently attempted to retest within the 30 -day period, and if there is no 'evidence that the permittee's effluent is not in compliance, then there should be no sanction against the permittee. Even if the laboratory is responsible for the invalid test, the State's recourse should be against the laboratory and not against the permittee who has been diligent and responsible in this manner. Thus, Duke reiterates its position that the most appropriate resolution of this' matter would be to strike in its entirety the final sentence of the note which follows the toxicity testing portions in these permits. However, as an alternative, Duke proposes the following language: "Fail- ure to achieve test conditions as .specified in the cited document, such as minimum control organisms survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting (within 30 days of initial monitoring event). Failure to submit suitable test results will constitute non-compliance with monitoring requirements, but willnot subject the permittee to civil penalty if permittee has diligently attempted to conduct a suitable retest and.has engaged the services of a laboratory with valid certification under North Carolina's laboratory certification program." With regard to Part II, paragraph 8 in the "boiler plate" 'language, it conflicts with North .Carolina General Statute 150B-9, which provides,for the continuation of the license or permit if the application to renew was timely filed and the agency has not made a final decision on the application. Thus, this provision.should be rewritten to conform to state law. Condition U of . the draft permit requires submittal of a study plan for Phase III monitoring of the Dan River. We have attached with these comments ,our proposed sampling regime for your approval, to begin upon issuance of the subject NPDES permit. This sampling plan is essentially identical to the monitoring plan recommended in the August 11, 1988 letter from Steve Tedder. Thank you for the opportunity to comment during this proceeding. Very truly yours, 90, . Fayssoux, Manager Fossil Technical Services RSC/JOF:mp bac w/enclosure Belews Creek Steam Station G. S. Rice W. T. Horton Sampling Regime for Dan River (Phase III) PARAMETERS LOCATIONS FREQUENCY 710 720 731 732 WATER CHEMISTRY X X X X Quarterly In-situ: Temp, DO, pH, sp cond Elemental Analyses: As, Cd, Cu. Se, Zn Other: Ca, TSS, Alk, SO SEDIMENT CHEMISTRY X X X X Annually CSpring) Elemental Analvses: As. Se MACAOINVERTEERATES- X X Annually CSummer) Community Composition Elemental Analyses: As, Cu, Se, Zn F I SH (Red breast Sunfish, Golden X X X A n n u a I I y Redhorser- Catfish) (Fa I I ) Elemental Analyses: Se, Zn Cin muscle) • MAW POWER COMP -ANY 3189 GE' NE,I?Al. 01elpi( ,j'i�s TELEPHONE, AREA 704 422SOUTH CHURCH STREET 373.4011 C1-1ARL0'1'rE,. N. C. 28242 June 10, 1983 at,. PRO041 �O IME HOZ Mr. Russell D. Radford JUN 13 1983 p n Q N. C. Division of Environmental Management 5 8003 North Point Boulevard Winston-Salem, North Carolina 27106 �� SEFOJ%Oge Re: Belews Creek Steam Station Engineering Report File Nos: BC -1407.08, GAH-0207 Dear Mr. Radford: Please find attached the above referenced Engineering Report addressing the engineering and environmental matters discussed in our meeting of May 5, 1983. Per our telephone conversation of June 6, 1983, we are presently evaluating the acid addition treatment question, and we will forward our evaluation of this to you by June 30, 1983. Please note that the NPDES application is being sent to you under separate cover. If you have any questions regarding this matter, please feel free to contact Matt LaRocque at (704)373-8057. Yours truly, S. B. Hager, Chief Engineer Civil/Environmental Division &I ju� By: J. R. Hendricks Principal Engineer JRH/MGL/mdc Attachments cc w/atts: Mr. Bi l l Mil.ls �C .I. c kkaw-' Mr. Steve Tedder Mr. B. E. Davis 6°wn Mr. W. D. Adair Mr. R. F. Edmonds .). Mr. D. W. Anderson Mr. M. G. LaRocque ENGINEERING REPORT Belews Creek Steam Station Ash Basin Discharge To The Dan River Duke Power Company Design Engineering Charlotte, NC planned for.installation between Precipitator 2A and the storage silos. The location of the storage silos and piping can be seen in the attached Figure 1. Combined storage silo capacity of 3000 tons would be installed between Precipitator 2A and the existing fly ash sales silos. These silos would be cone -bottomed and of steel construction with individual ash conditioners elevated for direct loading into dump trucks. Arrangement would also provide for parallel traffic flow from each disposal silo and from the sales facility. The silo facility would be equipped with sufficient baghouse venting capability to receive fly ash from all four precipitator sections simultaneously. The design for each of the four fly ash conveying pipelines would incorporate sufficient valves and connections to allow the reception of fly ash from any precipitator section into either of the new silos or directly into the existing sales silos. Plant fly ash control systems would be modified to allow selective collection and segregation of ash into the silos while at the.same time maintaining the flexibility of continuous removal of fly ash from the precipitators. The new silo facility will incorporate intersilo transfer equipment to further enhance reliability and allow the future possibility of loading fly ash from the vent disposal silos into dry bulk tankers for railcars. All fly ash for disposal would be dampened using conventional pre -wetter systems to mix the fly ash and water. The fly ash would then be loaded at approximately 15% - 20% moisture into large off-road vehicles. These vehicles are expected to carry approximately 30 - 35 tons each. Trucks would turn around at the silos and out to cross Route 1809. All trucks would then continue along a road to be built on Duke property, parallel to Route.1809. Fly ash will be hauled on a one to two shift basis, as needed, depending on plant load. Further, all_ roads will be upgraded. The in -plant roads and the road leading to the intersection will be upgraded by the application of an additional four inches of asphalt. The intersection of the main highway will be covered in concrete, thus ensuring the county and state a minimal problem from crossing traffic. The road leading across Duke property to the landfill will be constructed by stabilizing 24 inches of fly ash and soil. The road will be maintained with a bottom ash cover. The new landfill will include cofferdams which serve to control water runoff from the area during landfill construction and will become the final toe of the landfill upon closure and coverage with soil. The site will be cleared and prepared in sections with full upgrading of each area for operation as a landfill. A well or. other.water source will be maintained to control dust in the landfill. The conversion from a wet sluice system to a damp disposal system offers the advantage of having no excess water to be treated and discharged. The only water used in the system will be totally contained within the landfill, thus minimizing any potential environmental problems. 'In addition, this type of landfilling technique requires the minimum amount of land to.dispose of the maximum quantity of fly ash possible. New Discharge Tower and Disposition of Old Tower The proposed method of discharging the ash basin effluent to the Dan River consists of a new conventional ash discharge tower (Figure 2) containing a 30" diameter sluice gate with an invert elevation of approximately E1. 734+6. Water levels would be controlled by stoplogs and maximum flow would.be controlled by the sluice gate. The sluice gate would also allow the discharge to be withheld. To prevent floating ash from discharging to the river, a skimmer would be provided. The discharge would be routed around the western end of the ash dam, to a stilling basin, and finally to the Dan River by way of an effluent channel. (Figure 3) A parshall flume would be provided after the stilling basin for flow measurement. Also, riprap would be provided for approximately the first 100 feet of the effluent channel. It is proposed that the present system of ash basin discharge to i3elews Lake be maintained until such time that Se levels are reduced to acceptable levels. .Also, this discharge is necessary to serve as an emergency spillway for flood conditions, and to allow infrequent discharge to the lake should severe and prolonged drought conditions require such a release to maintain minimum water levels in the lake. Water Chemistry Description. 1. Ash Basin Water .Quality Historical data for the Belews Creek ash basin indicate that levels of most constituents are within water quality standards in the effluent. Only arsenic -and selenium have consistently exceeded standards: levels of these elements have ranged near 20-60 ug/l and 80-130 ug/1, respectively since installation of the sulfur -trioxide fl.ue gas conditioning system at Belews Creek in 1978-1979 (Cumbie, 1980). Therefore,.further discussion will be limited to these substances. After the dry fly ash system begins operation,the influent to the ash basin will be bottom ash sluice water and yard sump water. Therefore, the character of the basin will change to become basically that of a' bottom ash settling basin. Due to the coarse, sand -like nature of the bottom ash, little or no chemical leaching.by sluice water occurs. The chemistry of the bottom ash sluice water is almost entirely dictated by the Belews Lake water used for sluicing purposes. Belews Lake water currently contains some 8-12 ug/l selenium. This concentration should decline to undetectable levels over a 2-3 year period following removal of ash basin effluent from the reservoir. Therefore, the ultimate selenium concentration in the ash pond should be below 10 ug/1. For conservatism, projections are based on the assumption that the ash basin should stabilize near 10 ug/l total selenium. Although arsenic concentrations in Belews Creek ash basin effluent have historically ranged as high as 200 ug/l or more, arsenic has been even more strongly.affected by the sulfur -trioxide system than selenium, and current levels are near 25 ug/1. Since bottom ash sluice water should not contain appreciable quantities of arsenic, and arsenic is barely detectable in Belews Lake water, we project that -arsenic concentrations in the ash basin will approach zero when the dry fly ash system begins operation, and this element will not be considered further. 2. Selenium Mass Discharges - Ash Basi.n During the period immediately following operation of the dry fly ash system; selenium concentrations in the ash basin should decline from an -initial value near 130 pg/l to an assumed equilibrium value near 10 ug/1. Assumption of a simple first -order decay process leads to the concentration decay curves in Figure 4, which indicate that the 10 ug/l concentration should be reached within some 250-350 days after operation of the dry system, under average operating conditions. Curves shown in Figure 4 for decay were calculated assuming that loss of selenium from the system occurs by 1) a com- bination of discharge in the effluent and sorption/sedimentation loss to sed.i.- ments (solid curve) or 2) by discharge in the effluent only, with no loss by sorption/sedimentation (broken curve). Rate constants for these decay curves were derived based on historical ash basin and effluent monitoring data. Discharge Scenarios - Transition Period Two scenarios have been developed for handling the ash basin effluent discharge during this.transition period from the mixed wet fly ash/bottom ash system to the wet bottom ash/dry fly ash system. These are summarized as follows: Scenario 1: Ash basin effluent would be immediately discharged to Dan River. Initial selenium concentration - 130 ug/1, declining to -10 ug/l in -250 days. Selenium mass to the river �p would be ,3 x present load over same time period from Belews n Lake dam X(60 cfs at 7.5 ug/1). Scenario 2: Discharge remains to Belews Lake until the ash basin selenium concentration and the concentration of selenium in Belews Lake decline in concert to values such that the combined load to the Dan River from the ash basin plus the dam would not significantly exceed the previously experienced load from the dam discharge alone.. The maximumload to the Dan River occurred in 1977 at a lake selenium concentration of approximately 20 ug/l. Assuming a 66 cfs average flow at 20 ug/l gives a maximum daily load of 3.2 kg/day. Table 1 shows the selenium concentration trends in the ash basin and in Belews Lake. These projections indicate that, assuming the dry fly ash system goes into operation in the fall when the water column becomes mixed in Belews Lake due to the fall overturn (November), a combination of daily mass discharges not exceeding 3.2 kg/day is reached after about 90 days. This scenario would call for initial discharge to the Dan River in early March of the following year. Approximately 267 kg of selenium, or 0.11x the present annual load of 2438 kg, would. enter Belews Lake during the 90 days, assuming that the ash basin concentration is 130 ug/l at t = o in November. Alternatively, the sustained load to the Dan River during the period 1978 -present has resulted from summer mean Belews Lake selenium concentrations of about 12 ug/1, or a daily load of approximately 1.9 kg/day._ From Table 1, it is. -seen that a combination of daily mass discharges not exceeding 1.9 kg/day would be reached after about 220 days. This scenario would thus call for initial discharge of ash basin effluent to the Dan River by June of -the following year. 'This would result in discharge o -f- approximately 400 kg of selenium to Belews Lake during the 220 days, or about 0.16x the present annual load again assuming the ash basin concentration is 130 ug/l at t = o. It is important to note that, since.both the ash basin and lake concentrations would continue to decline, the load to the Dan River would be further reduced after March or June. Also, when the lake concentration approaches a postulated equilibrium at or near background (less than 1 ug/1), the ash basin effluent concentration could increase to approximately.50 to 100 ug/l without exceeding the previous 1977 or 1978-1983 loading levels from the Belews Lake dam. Selenium mass discharges to Belews Lake and to the Dan River under each of these scenarios are summarized in Table 2. Selection of the appropriate strategy will be made after consultation with NCDEM staff concerning the relative.significance of discharge impact in the two receiving water systems. 3. Upset Conditions No major failures in the dry ash handling system preventing ash removal are anticipated. Due to the redundant design of the system, either unit can feed to either silo. There will also be a two day silo -storage buffer capacity. A spare parts inventory of all major valves will be maintained. The four to six hour hopper.storage capacity should allow adequate time to perform emergency repairs. All other routine maintenance will be coordinated with station outages. Excursions of water quality variables may occur, however, when or if the wet fly ash sluice system is operated as back-up during repairs to the dry fly ash system. However, our calculations indicate that these excursions for elements of concern (selenium and arsenic) will not exceed approximately 10-15 ug/l (above a postulated 10 ug/l operating level for selenium) for several days operation. The NPDES permit should allow for these minor excursions and require notification of the state when they occur. Water Budget Considerations Since the proposed action would result in a net withdrawal of water from Belews Lake, a water budget was calculated to determine the impact of this water loss on the lake. Operation 'of Belews Creek Steam Station is limited when lake levels drop below elevation 720. The lowest lake level experienced to date is approximately elevation 722. Information used to derive monthly values of discharge per square mile for the period of January 1949 to December 1978 was taken from Wentworth, North Carolina, USGS gage and was adjusted for the drainage area of the Belews Lake basin. This data, together with data from the Greensboro, North Carolina weather station (including precipitation), was used in the MIT model (Ryan and Harleman 1973) for cooling pond behavior already adopted and verified for Belews Lake. Using the computer model with a simulated discharge of 23 cfs (13 cfs - non fly ash sluice water plus 10 cfs - dam release requirement), -there is approximately a one in five years chance that the lake elevation will drop to a level which will require that the ash basin discharge be rerouted. Every year that a return flow is required, the discharge back to the lake will be necessary for an average length of two months. Also, the computer results for the five year lowest flow period (1966-1970) indicate that the lake elevation was drawn down below 722 one time with a 23 cfs discharge. Duke Power Company proposes that the ash basin effluent discharge be credited against the required 10.cfs release to the Dan River from the Belews Lake dam. Using the computer model with a simulated discharge of 13 cfs (10 cfs dam release excluded),.no return flow is anticipated. The computer results for the five year lowest flow period (1966-1970) indicate that the 13 cfs discharge never imposed a threat to station operation. During actual station operation, the model predicts that the years 1977 and 1981 would have posed significant problems. In 1977, the calculated lake level would have fallen below the actual recorded value if the station was requi-red ,to.release 23 cfs even during low lake level periods. In 1981, the calculated lake level would have fallen below the actual recorded value throughout the year if the station were subjected to the same conditions. Under the proposed plan, the required discharge will be provided through the new ash basin discharge location approximately 3.5 miles upstream of the Belews Creek confluence with the Dan River. Normal Belews Lake overflow will continue to discharge through the existing spillway structure along with associated seepage from the dam, thus resulting .in approximately 1 to 2 cfs minimum flow. In addition, Duke Power owns all the land along Belews Creek from the dam to the Dan River. Regarding impact of reduced flow on fish populations, a reduction of the minimum low flow in Belews Creek below the Belews Lake dam from 10 cfs (based on.the present minimum release requirement) to a value of 1 to 2 cfs (from dam leakage and minor tributary flow) would reduce .the habitability of the stream for fish in a segment of approximately 0.1 mi length, extending from the dam spillway to a point near the Highway 1138 bridge. A reconnaisance electroshocking effort in this area on July 30, 1981, resulted in collection of a total'of 36 individual fish of 13 different species. This indicated presence of a diverse, indigenous fish community in this stream segment which consists.of a series of.riffles and pools. Four sun- fish beds were also observed. Fish standing crops are undoubtedly maintained by movement of fish up from the.lower section of Belews Creek and from the Dan River.. Although reduced minimum flow would restrict the available habitat in the 0.1 mi segment, refuge pools would still be. available, and stagnation would not occur due to the assured dam leakage flow. This transient loss of marginal habitat would not have an important impact on the fishable population in Belews Creek between the dam and the Dan River, since the river itself maintains water levels in the stream and deep pools exist below the 1138 bridge. Therefore, it is concluded that the proposed flow reduction would have negligible impact on fishery resources in Belews Creek:\ With the concurrence of DEM and the NCWRC, Duke proposes to experimentally reduce the Belews Lake dam discharge to 5 cfs and zero cfs during brief periods during the summer of 1983 in order to better define the impact of minimum flow reductions in Belews Creek. The results of these trials would assist in the -resolution of this question. Effluent Channel From the Ash Basin to the Dan River In order for this channel to be classified as an effluent channel, Duke must meet the conditions of .land ownership, prevention of offensive conditions, and prevention of fish attraction upstream. Duke Power Company owns all the land along the that one site is above the ash basin effluent, and three sites are below. The final site is to be located at the Virginia state line. The proposed monitoring plan will involve Phases I -III. Phase I will encompass baseline sampling for the Dan River prior to discharge of bottom ash sluice water. Phase II will encompass 'monitoring.of the Dan River for two years after ash basin effluent is discharged to the River. Phase III will be determined based on results of Phase II monitoring and consultation with NCDNRCD. Conclusions 0 1. Duke Power proposes to install dry fly ash handling facilities at Belews Creek Steam Station along with a provision for ash disposal by landfill. 2. Duke Power proposes a new ash discharge tower for ultimate discharge to the Dan River. It is also proposed that the present system of ash discharge to Belews Lake be maintained if necessary. 3. Both of the initial discharge proposals in Scenario 2 would result in selenium loading (1.9 to 3.2 kg/day) which are near the natural background load in the Dan River (approximately 1 to 2 kg/day at 1 ug/l, 500 cfs average flow). Our experience with Belews Lake has shown that extreme retention time and localized accumulation in sediments, coupled with increased loading at 30 to 40 times natural loads, are system properties which made, the lake respond as it did to ash basin selenium input. The Dan River does not possess these properties.- The projected selenium loads, even at the initial discharge concentrations, will not greatly exceed natural background, and will decline further over time. Therefore, initial discharge to the Dan River at 90 days, the option which will result in the .minimum load to the more sensitive Belews Lake system, is the preferred option. 4. Duke Power proposes a condition for upsets in the NPDES'permit to allow for minor excursions. 5. Duke Power proposes that the new ash basin effluent discharge be credited against the required 10 cfs release to the Dan River from the Belews Lake dam. Normal Belews Lake overflow will continue to discharge through the existing spillway structure along with associated seepage from.the dam, thus resulting in approximately 1 to 2 cfs minimum flow. This minimum flow would have negligible impact on fishery resources in Belews Creek. Also, Duke proposes to experimentally reduce the Belews Lake dam discharge to 5 cfs and zero cfs during brief periods of the summer of 1983 in order to better define the minimum flow reduction impact in Belews Creek. 6. Duke Power proposes that the channel from the ash basin to the Dan River be classified as an effluent channel. 7. Duke Power proposes a monitoring plan for the Dan River to include four sites with one site being upstream and three sites downstream. The final site is to be located at the Virginia state line. Literature - Cited Cumbie, P.M. 1978. Belews Lake Environmental Study Report: Selenium and Arsenic Accumulation. Duke Power Company Tech. Rep. Ser. No. 78-04. Duke Power Company, Charlotte, North Carolina. 64 pp. Cumbie, P.M. 1980. Effects of pH Adjustment and SO Fly Ash Conditioning on the Belews Creek Steam Station Ash Basin Effluent. Duke Power Company Tech. Rep. Ser. No. 80-01. Duke Power Company, Charlotte, North Carolina. 62 pp. Ryan, P.J. and D.R.F. Harleman. 1973. An Analytical and Experimental Study of Transient Cooling Pond Behavior, Report 161, Ralph M. Parson Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts. 439 pp. I- EXIST. ASH LINE AND 5 -NEW ASH LINES IN TRENCH 2 -EXIST. 12" DIA. METER SILOS EXIST. TRUCK SCALE 2. -NEW 1500 TON CAPACITY STORAGE SILOS WITH ASH CONDITIONING UNLOADERS - -- - FIGURE LOCATION OF LOADOUT SILO FOR BELEWS CREEK DRY FLY ASH DISPOSAL FACILITY 30°,� RC u E .770+ EL. 769 +6 761 EL. 744+4 30"R( RCP � � B INV. EL. F 736+6 EL. 736 +0 EL.734+6 SLUICE GATE STOP LOG 7/SLUICE GATE "STOP LOG B SECTION FIGURE 2 NEW ASH BASIN DISCHARGE TOWER 19�9 �G S�Pg�a PROPOSED DISCHARGE TOWER GAP g ASH BASIN ASH DIKE MAX.W.S. EL. 760 SLUCE LINE NORTH 0 1000 2000 r I ACCESS4c� SCALE-FEET COAL ROADry S HARGETOWER AND FF UENT RETURN BELEWS LAKE FIGURE 3 LAYOUT OF ASH BASIN WITH PROPOSED DISCHARGE TOWER 130 100 E W Figure 4 : Selenium concentration in Belews Creek ash basin effluent as a function of time after initial operation of the dry fly ash system, assuming losses from both discharged effluent and sorption/sedimentation (solid line) or assuming loss from discharged effluent.only (broken line). 50 100 150 200 Days -T 250 300 NCI VA W J cr. W = ZO > Ill o W DAN RIVER Y a w /STEAM 0 0 � o STATION a DAN RIVER 710.0j 720.0 730.0.732.0 PROPOSED 713.0 ASH BASIN DISCHARGE POINT -i NC I V A KILOMETER 0 10 20 30 40 m Figure 5 SCHEMATIC DIAGRAM OF THE DAN RIVER AND PROPOSED SAMPLING LOCATIONS. Table 1. Calculated selenium concentrations in Belews Lake and the Belews Creek ash basin as a function of time in days following initial operation of the dry fly ash system, assumed to begin at the time of the fall over- turn in Belews -Lake. 1 Assume 14 cfs discharge, (Se)o' ='130 pg/l,(Se)final = 10 ug/l 2'Assume 66 cfs average discharge, (Se )o 9. ug/1, (Se)final = natural background equilibrium at t = Co. Ash Basin 1 Belews Lake 2 t, days (Se),ug/.l Se mass/day. t, days (Se), ug/l Se mass/day discharged, kg discharged, kg 0 130. 4.45 0 9.2 1.49 35 90 3.08 30 = 9.3 1.50 90 50 1.71 90 9.4 1.52 120 40 1.37 120 9.3 1.49 150 30 1..03 .150 9.1 1.46 190 20 0.68 180 8.8 1.43 220 15 0.51 210 8.6 1.39 260 10 0.34 240 8.4 1.35 1 Assume 14 cfs discharge, (Se)o' ='130 pg/l,(Se)final = 10 ug/l 2'Assume 66 cfs average discharge, (Se )o 9. ug/1, (Se)final = natural background equilibrium at t = Co. TABLE 3 CODE TO VARIABLES TO BE ANALYZED, SAMPLING -FREQUENCY ABBREVIATIONS, AND DESCRIPTIONS OF PROPOSED SAMPLING LOCATIONS. Code to Variables Analyzed Sediment -Total Se and As Water Chemistry - Temperature; Dissolved Oxygen; pH; Specific Conductance, Re Total and Soluble Se and As, Total -Cd, Cu, Zn; Total Suspen a Solids Body Burdens - Total As, Se , Cd, Cu, Zn Samplinq Frequency Abbreviations F = Fall SP = Spring 0'10, BM = Bi -monthly (every other month) J: in , yn'j t4 List of Sampling Locations with Descriptions Location Description 710.0 Near U.S. - 311 Bridge (upstream of discharge) 713.0 — ''�� Proposed ash basin discharge stream from BCSS 720.0 Backwater area above low head dam near Madison, NC. _water intake (or below dam for fish if electrofishing boat cannot be launched at this site) 730.0 Near Dan River Plant Intake 732.0 Mayfield, NC, USGS Gaging Station near NC/VA border. PHASE I. BASELINE DAN RIVER SAMPLING PRIOR TO DISCHARGE OF BCSS 730.0 BOTTOM ASH SLUICE WATER TO THE RIVER. Sp/F Sp/F Sp/F 710:0 720.0 730.0 732.0 Sediments Sp/F Sp/F Sp/F Sp/F Water Chemistry B.M. B.M. B.M./M* B.M. Benthos and Fish Benthos and Fish Body Burdens Sp/F Sp/F Sp/F Sp/F Benthos and Fish *Belews Creek Plant Ash Basin NPDES Effluent Data Including.Total Qualitative Data Sp/F Sp/F Sp/F Sp/F *Dan River Plant NPDES In.take Parameters Including Total Se and As. PHASE II. MONITORING PROGRAM OF DAN RIVER FOR TWO -(2) YEARS AFTER BCSS ASH BASIN EFFLUENT IS DISCHARGED TO THE RIVER. PHASE III. DEPENDING ON RESULTS OF PHASE II MONITORING AND CONSULTATION WITH N.C. REPRESENTATIVES, THE NECESSITY OF AN EXTENT OF.MONITORING THE DAN RIVER BEYOND PHASE II WILL BE DETERMINED. 710.0 713.0 720.0 730.0 732.0 Sediments Sp/F Sp/F Sp/F Sp/F Water Chemistry B.M. B.M./M* B.M. B.M./M** B.M. Benthos and ,Fish Body Burden Sp/F Sp/F Sp/F Sp/F Benthos and Fish Qualitative Data Sp/F Sp/F. Sp/F Sp/F *Belews Creek Plant Ash Basin NPDES Effluent Data Including.Total Se and As **Dan River Plant Intake NPDES Parameters Including Total.Se and As. PHASE III. DEPENDING ON RESULTS OF PHASE II MONITORING AND CONSULTATION WITH N.C. REPRESENTATIVES, THE NECESSITY OF AN EXTENT OF.MONITORING THE DAN RIVER BEYOND PHASE II WILL BE DETERMINED.