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HomeMy WebLinkAboutNC0024406_Permit Modification_20020516J 'State' of North Carolina Department of Environment and Natural Resources Division of Water Quality Michael F. Easley, Governor William G. Ross, Jr., Secretary Gregory J. Thorpe, Ph.D., Acting Director May 16, 2002 Mr. Michael Ruhe Duke Energy Corporation 526 South Church Street Charlotte, North Carolina 28201-1944 Interoffice mail code: EC11E • NCDENR,-"',-- NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Subject: NPDES Permit modification Permit NCO024406 Belews Creek Steam Station Stokes County Dear Mr. Ruhe: On April 19, 2002, a final permit for the subject facility was sent to Duke Energy. On May 7, 2002, I spoke with Robert Wylie of Duke Energy and he informed me that the limits for total suspended solids and oil and grease appeared to be reversed. This was an inadvertent error and the limits have been changed to reflect the federal effluent guidelines expressed in 40 CFR 423. Please find enclosed the revised permit pages. The revised pages should be inserted into your permit. The old pages may then be discarded. All other terms and conditions contained in the original permit remain unchanged and in full effect. This permit modification is issued under the requirements of North Carolina General Statutes 143- 215.1 and the Memorandum of Agreement between North Carolina and the U. S. Environmental Protection Agency. If any parts, measurement frequencies or sampling requirements contained in this permit modification are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be a written petition conforming to Chapter 150B of the North Carolina General Statutes, filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding. If you have any questions concerning this permit modification, please contact Natalie Sierra at (919) 733-5083, extension 551. Sincerely, �(�Gregory J. Thorpe, Ph.D. cc: Winston-Salem Regional Office, Water Quality Section , NPDES Unit,..✓ Ms. Karrie jo Shell, US EPA Region 4 Point Source Compliance and Enforcement Unit Central Files 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Telephone (919) 733-5083 FAX (919) 733-0719 An Equal Opportunity Affirmative Action Employer VISIT US ON THE INTERNET @ http://h2o.enr.state.nc.us/NPDES Permit NCO024406 A. (2.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 003 (ash settling pond) to the Dan River. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT CHARACTERISTICS LIMITS MONITORING REQUIREMENTS Monthly : Daily -,'`' Measurement Sample Type Sample Location Avera 'e. _. = Maximum , . .Fre uenc Flow Weekly Pump logs or estimate Effluent Oil and Grease 15.0 m L 20.0 m L Quarterly' Grab Effluent Total Suspended Solids' 30.0 m L 100.0 m L Quarterly' Grab Effluent Total Arsenic Quarterly' Grab Effluent Total Selenium 26 /I 2/Month Grab Effluent Total Phosphorus Quarterly Grab Effluent Total Nitrogen (NO2+ NO3+ TKN Quarterly Grab Effluent Sulfates Monthly Grab Effluent Fluoride Quarterly' Grab Effluent Total Iron2 1.0 m /L Quarterly' Grab Effluent Total Co ere 1.0 m L Quarterly' Grab . Effluent Chronic Toxici 2 Quarter) l Grab Effluent Notes: 1. Quarterly monitoring for TSS, oil and grease and all toxicants shall be performed concurrently with the Chronic Toxicity test. 2. Monitoring for total iron and copper shall be performed quarterly and on occurrence of a chemical metal cleaning. Methods for determining "total metals" are defined in 40 CFR 136. 3. Whole Effluent Toxicity shall be monitored by chronic toxicity (Ceriodaphnia) P/F at 19%. Tests shall be conducted in February, May, August and November (see Part A.(6.) for details). The coal pile runoff and low volume wastes shall be discharged into the ash settling pond. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored 2/month at the confluence of the discharge and the receiving waters by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. 2 r WArFR Oen t' _ s� r NCDENR O '< Mr. Michael Rube Duke Energy Corporation 526 South Church Street Charlotte, North Carolina 28201-1944 Interoffice mail code: EC11E Dear Mr. Ruhe: Michael F. Easley Governor William G. Ross, Jr., Secretary North Carolina Department of Environment and Natural Resources Gregory J. Thorpe, Ph.D., Acting Director Division of Water Quality April 19, 2002 Subject: Issuance of NPDES Permit NCO024406 Belews Creek Steam Station Stokes County Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated May 9, 1994 (or as subsequently amended). The following changes have been made to the draft permit: • The address on the permit has been changed with the subject facility located in Belews Creek instead of Walnut Cove (permit cover sheet and supplement to the cover sheet). • The sulfate limit, which was given based on data that was over three (3) years old, has been removed. Using the most recent three years of sulfate data in a reasonable potential analysis resulted in a finding of no reasonable potential. In addition, the monitoring frequency has been changed to monthly. • The sample type for the chronic toxicity test has been changed to grab. This is consistent with the previous permit and accurately represents the ash basin discharge. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699- 6714). Unless such demand is made, this decision shall be final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, the Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning this. permit, please contact Natalie Sierra at telephone number (919) 733- 5083, extension 551. Sincerely, 0,g1nai Signeed BY Mfr d nooari h Y go r . Thorpe, Ph.D. cc: Central Files Winston-Salem Regional Office/Water Quality Section NPDES Unit 4 ' Technical Assistance & Certification Unit Aquatic Toxicology Unit EPA Region 4 DEH N. C. Division of Water Quality / NPDES Unit Phone: (919) 733-5083 1617 Mail Service Center, Raleigh, NC 27699-1617 fax: (919) 733-0719 Internet: h2o.enr.state.nc.us DENR Customer Service Center: 1800 623-7748 Permit NC0024406" STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Duke Energy Corporation is hereby authorized to discharge wastewater from a facility located at the Belews Creek Steam Station 3195 Pine Hall Road (NCSR 1908) Belews Creek Stokes County to receiving waters designated as the West Belews Creek/Belews Lake (outfall 00 1) and the Dan River (outfall 003) in the Roanoke River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV hereof. This permit shall become effective June 1, 2002. This permit and authorization to discharge shall expire at midnight on February 28, 2007. Signed this day April 19, 2002. Original Signed By David A. -Goodrich Gregory J. Thorpe, Ph.D., Acting Director Division of Water Quality By Authority of the Environmental Management Commission Permit NCO024406 SUPPLEMENT TO PERMIT COVER SHEET Duke Energy Corporation is hereby authorized to: 1. Continue to discharge: • Once through cooling water (outfall 00 1) consisting of intake screen backwash, recirculating cooling water, station equipment cooling water and once -through cooling water • Ash basin discharge (outfall 003) consisting of wastestreams from the power house and yard holding sumps, ash sluice lines, chemical holding pond, coal yard sumps, stormwater and remediated groundwater. From a facility located at Belews Creek Station, 3195 Pine Hall Road (NCSR 1908), Belews Creek in Stokes County, and 2. Discharge wastewater from said treatment works at the location specified on the attached map into West Belews Creek/Belews Lake (outfall 001) and the Dan River (outfall 003), which are classified C and WS -IV waters, respectively, in the Roanoke River Basin. 2 r � 4- � �\(� �v t� \ •v� ;,�.i� � • �`\l � �`Z (>r�� n\ lr /�•-� \, ) � -• �~�t'\ll� } \'.-., l � � ,� /�� `\ �<4� �rl �C .-'-•-�,, "`'_s\',✓r'1 � 1I•� � li�a���i .�' t;�J�\`y 1 � n: g-"\- �.i • � ` \ -"�y' � �--"J -V Vr/-f} 00it 3 ' 199q -------------- -_-_ - .T �p � \. ice`: a '� \ \ /'� ____ __ i �\ �T �•'�.1 r .'i (�` �..J'. , ; ( p ! ' / 3. 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' into �s � � i'�\ \L: '/(j �L'°�1 M�� _f "� /%���J r1 ,ti"1 � �\ ;y�_ -�� � ��f�'•.�i r� ��\,•� l i (�.�_....., �t� `, � )�rl • i�.�r (� U.` ` uar 1 w<` ,rl'� +,� —ts \J((-(-. \'����� <<N O f• •/ j! l_ _._� l\� \ C!/ `� Ccc 'S �..� l if! 1, rt �Zlt NCO024406 - Belews Creek Steam Station Latitude (001): 36016'49.5" Receiving Stream (001): Belews Lake Longitude (O011: 8003'39.8" Stream Class: C Latitude (002): 36018'22.0" Receiving Stream (003): Dan River Longitude(002): 8004'50.7" Stream Class: WS -1v uad #: B 18SE/Belews Lake, NC Sub -Basin: 03-02-01 Permitted Flow: n o limit Facility Location Y° '�•a'k Lk North Duke Energy- Belews Steam Station NCO024406 Map not to scale Permit NCO024406 c A. (1.) EFFLUENT LIMITATIONS AND (MONITORING REQUIREMENTS = FINAL During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge once -through cooling water and intake screen backwash from outfall 001. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS 'MONITORING REDUIR CHARACTERISTICS': Montfily ° .; Daily Measurement Sample Type Average Maximum . Fre uenc Flow Continuous Pump Logs Sample Loca Effluent Temperature OC OF Daily Recorder/Grab Upstream Temperature OC (OF)2 32-C 89.6 Daily Recorder/Grab Downstream Temperature oC °F Daily Recorder/Grab Effluent Notes: 1. Sampling locations: Upstream - Upstream at Southern Railroad crossing of Belews Creek OR East Belews Creek (site 405 or site 419), Downstream - Downstream at the discharge from the Dam. Upstream temperature samples are to be measured one foot below the surface. 2. In no case should the ambient temperature exceed 32oC (89.6oF) as a result of Belews Creek Steam Station operations. The ambient temperature shall be defined as the daily average downstream discharge water temperature. In cases where the Permittee experiences equipment problems and is unable to obtain daily temperatures from the existing temperature monitoring system, monitoring must be reestablished within five working days. Chlorination of the once through condenser cooling water and/or auxiliary cooling water, discharged through outfall 001, is not allowed under this .permit. Should Duke Power wish to chlorinate its condenser cooling water, a permit modification must be requested and received prior to commencing chlorination. There shall be no discharge of floating solids or visible foam in other than trace amounts. I 3 Permit NC0024406 A. (2.) EFFLUENT LINIITATIONS AND MONITORING REQUIREMENTS - FINAL During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 003 (ash settling pond) to the Dan River. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT'CHARACTERISTICS ' LIMIT -Sr'":', Monthly f)ai(y Average Maximum MONITORING REQUIREMENTS Measurement . Sample TYRe Sample Location: Frequency::, Flow Weekly Pump logs or estimate Effluent Oil and Grease 30.0 m L 100.0 m L Quarterly' Grab ' Effluent Total Suspended Solids' 15.0 m L 20.0 m L Quarterly' Grab Effluent Total Arsenic Quarterly' Grab Effluent Total Selenium 26 2/Month Grab Effluent Total Phosphorus Quarterly Grab Effluent Total Nitrogen (NO2+ NO3 + TKN , Quarterly Grab Effluent Sulfates Monthly Grab Effluent Fluoride Quarterly' Grab Effluent Total Iron2 1.0 m L Quarterly' Grab Effluent Total Co ere 1.0 m L Quarterly' Grab Effluent Chronic Toxicity2 Quarterly' Grab Effluent Notes: 1. Quarterly monitoring for TSS, oil and grease and all toxicants shall be performed concurrently with the Chronic Toxicity test. 2. Monitoring for total iron and copper shall be performed quarterly and on occurrence of a chemical metal cleaning. 3. Whole Effluent Toxicity shall be monitored by chronic toxicity (Ceriodaphnia) P/F at 19%. Tests shall be conducted in February, May, August and November (see Part A.(6.) for details). The coal pile runoff and low volume wastes shall be discharged into the ash settling pond. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored 2/month at the confluence of the discharge and the receiving waters by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. 4 Permit NCO024406 A.(3.) SPECIAL CONDITIONS The following special conditions are applicable to Belews Creek Steam Station under NCO024406: • There shall be no discharge of polychlorinated biphenyl compounds such as those commonly used for transformer fluid. • Outfall 006 - The monitoring requirements for this internal discharge have been relocated to the actual discharge location (outfall 003). as of the February 1, 1998 NPDES permit. This discharge must remain internal and discharge to the ash pond. If discharge to the. ash pond is relocated to surface waters of the state, then the monitoring requirements for this discharge will be reinstated. • Continued intake screen backwash and non -contact cooling water are permitted without limitations or monitoring requirements. • Nothing contained in this permit shall be construed as a waiver by the Permittee or any right to a hearing it may have pursuant to State or Federal laws or regulations. • The term "low volume waste sources" means, taken collectively as if from one source, wastewater from all sources except those for which specific limitations are otherwise established in this part. Low volume wastewater sources include, but are not limited to: wastewater from wet scrubber air pollution control systems, ion exchange water treatment system, water treatment evaporator blowdown, laboratory and sampling streams, boiler blowdown, floor drains, cooling tower basin cleaning wastes, and recirculating service water systems. Sanitary and air conditioning wastes are not included. • The term "chemical metal cleaning waste" means any wastewater resulting from cleaning any metal process equipment with chemical compounds, including, but not limited to, boiler tube cleaning. Chemical metal cleaning will be conducted according to Duke Power approved equivalency demonstration. • It has been determined from information submitted that the plans and procedures in place at Belews Creek Steam Station are equivalent to that of a BMP. • Discharge of any product registered under the Federal Insecticide, Fungicide, and Rodenticide Act to any waste stream which may ultimately be released to lakes, rivers, streams or other wasters of the United States is prohibited unless specifically authorized elsewhere in this permit. Discharge of chlorine from the use of chlorine gas, sodium hypochlorite, or other similar chlorination compounds for disinfection in the plant potable and service water systems and in sewage treatment is authorized. Use of restricted use pesticides for lake management purposes by applicators licensed by the N.C. Pesticide Board is allowed. • The Permittee shall report all visible discharges of floating materials, such as an oil sheen, to the Director when submitting DMRs • If the Permittee, after monitoring for at least six months, determines that the facility is consistently meeting the effluent limits contained herein, the Permittee may request of the Director that the monitoring requirements be reduced to a lesser frequency. • The Dan River Monitoring Plan, Phase III, as referred in the Engineering Report dated June 10, 1983 and submitted to. DWQ, shall continue to be conducted. R, Permit NCO024406 A.(4.) SPECIAL CONDITON - BOILER CLEANING WASTES It has been demonstrated that under certain conditions it is possible to reduce the concentration of metals in boiler cleaning wastes in the range of 92-99+ percent by treatment in ash ponds. Because of dilution problems and the existence of boundary interface layers at the extremities of the plume, it is difficult to prove beyond doubt that the quantity of iron and copper discharge will always be less than one milligram per liter times the flow of metal cleaning when treated in this manner. The application of physical/chemical methods of treating wastewater has also been demonstrated to be effective in the treatment of metal cleaning wastes. However, the effectiveness of ash pond treatment should be considered in relation to the small differences in effluent quality realized between the two methods. It has been demonstrated that the presence of ions of copper, iron, nickel and zinc in the ash pond waters was not measurably increased during the ash pond equivalency demonstration at the Duke Power Company's Belews Creek Steam Station. Therefore, when the .following conditions are implemented during metal cleaning procedures, effective treatment for metals canbe obtained at this facility: 1. Large ash basin providing potential reaction volumes in the ratio of 100 to 1. 2. Well-defined shallow ash delta near the ash basin influent. 3. Ash pond pHs of no less than 6.5 prior to metal cleaning waste addition. 4. Four days retention time in ash pond with effluent stopped. 5. Boiler volume less than 86,000 gallons. 6. Chemicals for cleaning to include only one or more of the following: a. Copper removal step- sodium bromate (NaBrO2), ammonium carbonate ((NH4)2CO3-H20, and ammonium hydroxide (NH40H). b. Iron removal step - hydrochloric acid (HCl), ammonium bifluoride ((NH4)HF2 and proprietary inhibitors. 7. Maximum dilution of wastewater before entering ash pond: 6 to 1. 8. If monitoring of basin effluents (as required by the permit) after. treatment of metal cleaning wastes reveals discharges outside the limits of the permit, Permittee will: 1) re -close the basin discharge, 2) conduct such in-basin,sampling as necessary to determine the cause of nonconformance, 3) take appropriate corrective actions, and 4) file a report with EPA including all pertinent data. A. (5.) SPECIAL CONDITION FOR DISCHARGE OF WASTEWATER Beginning on the effective date of this permit and lasting until expiration, there shall be no discharge of plant wastewater to the ash pond unless the Permittee provides and maintains at all times a minimum free water volume (between the top of the sediment level and the minimum discharge elevation) equivalent to the sum of the maximum 24-hour plant discharges plus all direct rainfall and all runoff flows to the pond resulting from a 10 -year, 24-hour rainfall event, when using a runoff coefficient of 1.0. During the term of the permit, the Permittee shall remove settled material from the ponds or otherwise enlarge the available storage capacities in order to maintain the required minimum volumes at all times. The Permittee shall determine and report to the permit issuing authority the following on an annual basis: 1) the actual free water volume of .the ash pond, 2) physical measurements of the dimensions of the free water volume in sufficient detail to allow . validation of the calculated volume, and 3) a certification that the required volume is available with adequate safety factor to include all solids expected to be deposited in the pond for the following year. Present information indicates a needed volume of 86.2 acre-feet in addition to solids that will be deposited to the ash pond; any change to plant operations affecting such certification shall be reported to: the Director within five days. NOTE: In the event that adequate volume has been certified to exist for .the term of the permit, periodic certification is not needed. 0 Permit NCO024406 A. (6.) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time ,exhibit observable .inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 19.0%. The permit holder shall perform at a minimum,guarterlu monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test. Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of February, May, August and November. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. H the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase 11 Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised - February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR -1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT -3 (original) is to be sent to the following address: Attention: North Carolina Division,.of Water (Quality Environmental Sciences Branch 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re- opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. 7 Permit NC00244061 A. (7.) BIOCIDE CONDITION The Permittee shall not use any biocides except those approved in conjunction with the permit application. The Permittee shall notify the Director in writing not later than ninety (90) days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Water Quality. Such notification shall include completion of Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. Completion of Biocide Worksheet Form 101 is not necessary for those outfalls containing toxicity testing. Division approval is not necessary for the introduction of a new biocide into an outfall currently being tested for toxicity. 3 Re: modified fact sheet for Belews Creek Subject: Re: modified fact sheet for Belews Creek Date: Tue, 02 Apr 2002 13:00:01 -0500 From: Shell.Karrie-Jo@epamail.epa.gov To: Natalie Sierra <Natalie.Sierra@ncmail.net> Thanks for the revised fact sheet. Finalize the permit. Karrie-Jo Robinson -Shell, P.E. 1 of 1 4/2/02 1:59 PM Re: comments on NC00024406 ` Subject: Re: comments on NC00024406 Date: Tue, 26 Mar 2002 07:41:49 -0500 From: Shell.Karrie-Jo@epamail.epa.gov To: Natalie Sierra <Natalie. Sierra@ ncmail.net> OK. I just overlooked this language during my review. Thanks for redoing the fact sheet for Belews. I think it will make things clearer. Karrie-Jo Robinson -Shell, P.E. Natalie Sierra <Natalie.Sierra@n To: cmail.net> cc: Subject 03/25/2002 05:23 PM Karrie-Jo Shell/R4/USEPA/US@EPA Re: comments on NC00024406 Karrie-Jo, In all the discussion of the sump overflows, I'm not sure I addressed some of your other comments. One comment that you had on all three Duke permits was that no BMPs were included. All three permits have as a special condition the statement, " It has been determined from information submitted that the plans and procedures in place at <Name> Steam Station are equivalent to BMPs." Moreover, it is the Division's position that the ash pond provides adequate treatment prior to discharge, and this constitutes a BMP. Another comment you had regarded a schedule of compliance. I believe that schedules of compliance are referenced in our boilerplate. I will send you a revised fact sheet for Belews Creek later this week, which will hopefully address your concerns such that we may issue that permit. -Natalie Shell.Karrie-Jo@epamail.epa.gov wrote: > Natalie, > Per my voice message to you today, I am forwarding draft comment on the > draft permit for Belews Creek Steam Station. I will try to call you > later for us to discuss these comments before I finalize my letter. > Karrie-Jo Robinson -Shell, P.E. > 404/562-9308 > (See attached file: NC24406.wpd) ------------------------------------------------------------------------ 1 of 2 4/2/02 4:28 PM UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 4 ATLANTA FEDERAL CENTER 61 FORSYTH STREET ATL ANTA_ GF0RGIA 9n3nS-asen March 11, 2002 Natalie Sierra North Carolina Department of Environment and Natural Resources Division of Water Quality NPDES Unit i61 / Mail Service Center Raleigh, NC 27699-1617 Subject: Draft NPDES Permit no. NCO022406 Belews Steam Power Plant Dear Ms. Sierra: I L FRIAR 1 3 2002 UENR - 1-'4 ITER QUALITY POINT SOURCE BRAPICH We have reviewed the draft permit and fact sheet for the above facility. The draft permit and fact sheet were submitted to EPA -Region 4 via letter dated February 13, 2002. My comments are as follows: 1. The version of the draft permit we received did not include Best Management Practices. Please forward this part of the permit to me. 2. In accordance with 40 CFR 423.12(a)(5) and (12 ), mass limits should be included for total iron and total copper for Outfall 003, rather than concentration limits. Chemical metal cleaning wastes are discharged via Internal Outfall 006 to the Ash Pond (Outfall 003). In addition to chemical metal cleaning wastes, the Ash Pond treats storin water, coal yard sump wastewater, yard sump wastewater, condensate feedwater, ash sluice water and wastewater from the power house sumps. Outfall 003 has a continuous discharge to Belews Lake. Per 40 CFR. 423.12 (a)(5), the quantity of pollutants discharged in chemical metal cleaning wastes shall not exceed the quantity determined by multiplying the flow of chemical metal cleaning waste times a concentration value of 1.0 mg/l, for both total iron and total copper. Additionally, 40 CFR 423.12(12) states that: "In the event that waste streams from various sources are combined for treatment or discharge, the quantity of each pollutant or pollutant property controlled in paragraphs Internet Address (URL) • http://www.epa.gov Recycled/Recyclable . Printed with Vegetable Oil Based Inks on Recycled Paper (Minimum 25% Postconsumer) M (b)(1) through (11) of this section attributable to each controlled waste source shall not exceed the specified limitations for that waste source." The flow diagram submitted with the NPDES permit application indicates the intermittent flow of chemical metal cleaning wastes is approximately 0.03 MGD. Based on this flow, the mass limit for both total iron and total copper from Outfall 003 is 0.25 pounds/day (0.03 MGD x 8.34 pound-liter/MG - mg x 1.0 mg/1). According to the information in the NPDES permit application, the mass of total iron from Outfall 003 was 12.9 pounds per day and the mass of total copper was 0.43 pounds per day. These amounts exceed the allowable mass concentration per the applicable effluent guidelines. Please forward the revised draft permit and fact sheet reflecting the above comments. If you have any questions or comment regarding my comments, please contact me by email at shell.karrie_jc @U. )a. ov,_ or by phone at 404/562-9308. cc: Mr. Michael Ruhe Duke Energy Corp. Yours truly, Karrie-Jo Robinson -Shell, P.E. Environmental Engineer Permits and Biosolids Section Permits, Grants and Technical Assistance Branch Water Management Division Puke Power. A Duke Energy Company March 22, 2002 Ms. Natalie Sierra North Carolina Department of Environment and Natural Resources Division of Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: Belews Creek Steam Station NPDES Permit NCO024406 Dear Ms. Sierra: Duke Power Company Fossil and Hydro Generation Department P.O. Box 1006 Charlotte, NC 28201-1006 p APR - 2 2002 DEAR - VIATER QUALITY POINT SOURCE BRANCH With reference to the draft subject permit that was issued by your office, Duke Energy Corporation offers the following comments: A.(2.) Effluent Limitations and Monitoring Requirements • It is requested that the limit for sulfate be removed and a monthly monitoring requirement be identified instead of twice per month. The reasonable potential calculation used data greater than three years old. One of these data points skewed the results and indicated the need for a limit. The attached table indicates the most recent data. Due to the large size of the ash basin, this treatment system has a relatively long retention time. It is therefore requested that sample type for the chronic toxicity be changed from composite to grab. A grab sample should be sufficient to represent the discharge. A. (6) Chronic Toxicity Pass/Fail Permit Limit • In the first sentence under section A. (6) it is requested that the terminology "observable" be changed to "unacceptable". The word "observable" could potentially be interpreted to mean that no level is acceptable in which the reproduction level in the treatment water is less than the control water. It is also requested that all of the pages in the permit be numbered. Duke Energy Corporation plans to respond to the recently received memo from the Environmental Protection Agency on this draft permit. Your office will be copied on any correspondence to the EPA associated with this permit. If you have questions or need additional information please contact Robert Wylie at (704) 382-4669. Sincerely, Michael A. Ruhe, Manager North American Support cc: Ms. Karrie-Jo Robinson -Shell, Environmental Protection Agency, Region IV Attachment Attachment ,Belews Creek Steam Station NPDES Permit NCO024406 Outfall 003 Sulfate Results Month/Year Sulfate Results (mg/1) for Outfall 003 Apr. 99 33.4 May 99 42.2 June 99 54.7 July 99 81.4 Aug. 99 38.1 Sept. 99 33.8 Oct. 99 33.1 Nov. 99 37.8 Dec. 99 37.6 Jan. 00 3 8.2 Feb. 00 37.6 Mar. 00 44.1 Apr. 00 42.0 May 00 43.3 June 00 41.9 July 00 43.4 Aug. 00 44.6 Sept. 00 41.6 Oct. 00 41.1 Nov.00 40.8 Dec.00 41.0 Jan. 01 39.9 Feb. 01 35.7 Mar. 01 36.5 Apr. 01 32.3 May 01 30.0 June 01 28.6 July 01 25.8 Aug. 01 26.4 Sept. 01 24.8 Oct. 01 25.5 Nov. 01 27.8 Dec. 01 33.7 Jan. 02 35.6 Feb. 02 34.5 Mar. 02 33.3 Average 37.8 mg/1 Max. Value 81.4 mg/l COMMENTS ON BELEWS CREEK Subject: COMMENTS ON BELEWS CREEK Date: Fri, 22 Mar 2002 15:52:58 -0500 From: 'Robert R Wylie" <rrwylie @ duke-energy.com> To: Natalie Sierra <Natalie.Sierra@ncmail.net> Natalie, I have sent to you a memo, signed by Michael Ruhe, with comments on Belews Creek's draft NPDES permit. I plan on addressing the EPA's comments next week. Hopefully we will have a chance to speak with them next week. I had a few minor comments that I did not include in my letter but I am noting below: The address for Belews Creek Steam Station has changed. Instead of Walnut Cove it should be Belews Creek. I saw that on the permit cover sheet and also the supplement to the cover sheet. I noticed under A(4) third paragraph, first sentence, a misspelled word "oat". I think it was meant to be "at". Under A(4) item 4 the misspelled word is "ahs". I think it was meant to be "ash". Robert 1 of 1 3/26/02 9:51 AM State of North Carolina Department of Environment • • and Natural Resources Division of Water Quality — — Michael F. Easley, Governor C D E R William G. Ross, Jr., Secretary Gregory J. Thorpe, Ph.D., Acting Director NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Febtuary 13, 2002 RErE$VED MEMORANDUM ,N.,r. Dept. of CHNR FEB 2 1 2002 To: Lee Spencer NC;DENR.%-DEH;% Regional -Engineer Winston-Salem W n-niton-S'alesm"116 onal Office��~ Regional I t llde From: Natalie Sierra NPDES Unit Subject: Review of Draft NPDES Permit NCO024406 Duke Energy - Belews Creek Steam Station Stokes County Please indicate below your agency's position or viewpoint on the draft permit and return this form by March 15, 2002. If you have any questions on the draft permit, please contact me at the telephone number or e-mail address listed at the bottom of this page. E C E E ==='1"w'�in' v�v�w�wn'wig/i'Oi'wiv�v''vii�i�i�ivnA0VA0Viv'ein'wiv�v'�i'wiv�v�i�w�iv�iv�w NvA" oVAoViv'�i/W RESPONSE: (Check one) I MAR - 5 2002 [jdConcur with the issuance of this permit provided the facility is operated aLdmistated effluent limits are met prior to discharge, and the discharge does no water quality standards. 1-1 Concurs with issuance of the above permit, provided the following conditions are met: F-1 Opposes the issuance of the above permit, based on reasons stated below, or attached: 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 919 733-5083, extension 551 (fax) 919 733-0719 VISIT US ON THE INTERNET @ http://h2o.enr.state.nc.us/NPDES Natalie.sierra@ ncmail.net Natalie, I've reviewed the subject draft permit for implementation of WET and have the following comments: The sample type for WET in the new permit is specified as "composite." Previously it was "grab." Is there a reason for the change in sample type. It looks like other toxic parameters (arsenic, selenium, fluoride, copper) use a grab in the draft. When I calculate the IWC based on the numbers from the "Reasonable Potential Summary" sheet (Qw=7.4 MGD and 7Q10=80 cfs) I get 12.5%. According to the 8/19/96 wasteload allocation, Mary Cates calculated IWC using Qw=8.1 and 7Q10=80 cfs to get IWC=19%. I understand that the Qw we're using here is based on average discharge and I have no problem using either IWC based on your best professional judgement. But I think it would be best to make the numbers we reference consistent to prevent confusion, particularly in the future, if someone tries to re -calculate the IWC based on the numbers from the RP sheet. Thanks for the opportunity to comment on the draft, Matt Matt Matthews NC DENR/Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, North Carolina 27699-1621 v-(919) 733-2136 f-(919) 733-9959 MailTo:Matt.Matthews @ ncmail. net o ^- � Q ,' ncn St, lco 0t3DIP ID Go co �y o m,. I • - -- �-�.-h C� � n � o ° b K °� coo � -� t ,m m m G oco oCD cn-� W j P S N G G o n f0 oCP r+ �. (p r m C N N `C v� O+ N G 10 C e co o d C v n aad�� �°Mo ONr' coo�oN'" coocoo p,' ; N Q' n H '�• �'r a` �D. `� a� , fi co p. o O o tr1 �, r> co coo t OH "fir N v'r `� fD H K ? j CD O N 4 N m •r NORTH CAROLINA STOKES COUNTY AFFIDAVIT OF PUBLICATION Before the undersigned, a Notary Public of said County and State, duly commissioned, qualified and authorized by law to administer oaths, personally appeared George W. Summerlin who being first duly sworn, deposes and says: that he (she) is Publisher (Publisher or other officer or employee authorized to make affidavit) of MOUNT AIRY NEWSPAPERS, INC., engaged in the publication of a newspaper known as KING TIMES NEWS, published, issued, and entered as periodicals class mail in the city of King in said County and State; that he (she) is authorized to make this affidavit and sworn statement; that the notice or other legal advertisement, a true copy of which is attached hereto, was published in KING TIMES NEWS on the following dates: z f z 1 12,o and that the said newspaper in which such notice, paper, document or legal advertisement was published was, at the time of each and every such publication, a newspaper meeting all of the requirements and qualifications of Section 1-597 of the General Statutes of North Carolina and was a qualified newspaper within the meaning of Section 1-597 of the General Statutes of North Carolina. This Z.I St day of 1%i , 2002 of person making affidavit Sworn to and subscribed before me, this 2.V*_ day of My 2002 Oftu A 0 / AA T� of ry Public PUBLIC NOTICE, State of North Carolina Environmental Management Commission/NPDES Unit 1617 Mail Service Center Raleigh, NC 27 9Lf_A-Tfq7 NOTIFICATION OF INTENT TO ISSUE A NPDES WASTEWATER PERMIT On the basis of thorough staff review and application of NC General Statute 143.21, Public law 92750o and other lawful standards and regula- tions, the North Carolina Environmental Management Commission proposes to issue a National Pollutant Discharge Elimination System (NPDES) wastewater discharge permit to the per- sons) listed below effective 45 days from the publish date of this notice. Written comments regard- ing the proposed permit will be accepted until 3o days after the publish date of this notice: All comments received prior to that date are considered in the final deter- minations regarding the pro- posed permit. The Director of the NC Division of Water Quality may decide to hold'a public meeting for the pro- posed permit should the Division receive a significant degree of public interest. Copies of the draft permit and other supporting infor- mation on file used to deter- mine conditions present in the draft permit are available upon request and payment of the costs of reproduction. Mail comments and/or requests for information to the NC Division of Water Quality at the above address or call Ms. Christie Jackson at (919) 733-5083, extension 538• Please include the NPDES per it number in any co 'nmunication. Interested pers ns may also visit the Division of Water Quality at 512 N. Salisbury Street, --Raleigh; NC 27604- 1148 between the hours of 8 a.m. and 5 p.m. to review information on file. 11 c NORTH CAROLINA STOKES COUNTY AFFIDAVIT OF PUBLICATION Before the undersigned, a Notary Public of said County and State, duly commissioned, qualified and authorized by law to administer oaths, personally appeared George W. Summerlin who being first duly sworn, deposes and says: that he (she) is Publisher (Publisher or other officer or employee authorized to make affidavit) of MOUNT AIRY NEWSPAPERS, INC., engaged in the publication of a newspaper known as DAN -BURY REPORTER, published, issued, and entered as periodicals class mail in the city of King in said County and State; that he (she) is authorized to make this affidavit and sworn statement; that the notice or other legal advertisement, a true copy of which is attached hereto, was published in DANBURY REPORTER on the following dates: 2 12-c 12-MZ- and zMZ and that the said newspaper in which such notice, paper, document or legal advertisement was published was, at the time of each and every such publication, a newspaper meeting all of the requirements and qualifications of Section 1-597 of the General Statutes of North Carolina and was a qualified newspaper within the meaning of Section 1-597 of the General Statutes of North Carolina. This 2_04`' day of 52002 of person making affidavit Sworn to and subscribed before me, this 2-0+1.— day of nU__J k_j , 2002 GZ1t,4 L_ N tary Public } My Commission expires: =-- OFFICIAL SEAL W Notary Public, North Caroli b�s COUNTY OF STOKES GARY WAYNE MARTIN My Commission Expires Sept. 26, 2004 , PUBLIC NOTICE e0fi�4,51ofi 4 State of arolina Environmental beeF Management Commission/NPDES Unit 2P 1617 Mail Service Center ! y Raleigh, NC 27699-1617 Notification of Intent to Issue A NPDES Wastewater Permit On the basis of thorough staff review and application of NC General Statute 143.21, Public law 92-500 and other lawful standards and regula- tions, the North Carolina Environmental Management Commission proposes to issue a National Pollutant Discharge ' Elimination System (NPDES) wastewater discharge permit to the per- son(s) listed below effective 45 days from the publish date of this notice. Written comments regard- ing the proposed permit will be accepted until 30 days after the publish date of this notice. All comments received prior to that date are considered in the final determinations regarding the . proposed permit. The Director of the NC Division of Water Quality may decide to hold a public meeting for the proposed permit should the Division receive a signifi- cant degree of public inter- est. Copies of the draft permit and other supporting infor- mation on file used to deter- mine conditions present in the draft permit are available upon request and payment of the costs of reproduction. Mail co 666r _ erits and / or requests for information to the NC Division of Water Quality at the above address =or. call Ms. Christie Jackson at_ (919) 733-5083, extension 538. Please include the NPDES permit number in'any com- miinicatinn_ interested ner- a DENR/DWQ AMENDEDFACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NCO024406 Receiving Stream Belews Lake (001) Regional Office; . ° ` Winston-Salem and Dan River (003) (WSRO) Strearn'Cla'ssification: '' ' " C (Belews Lake), State Grid [�USGS�Quad ` ` B18SE/Belews Lake WS -IV (Dan River) 3303(d) Listed?.'...'..,Belews Lake (fish Permit Writer Natalie Sierra advisory - selenium) Subbasin: 03-02-01 Dat'..,1/30/02 Drainage Area (mit) 501 (Dan River) , - Mn Summer 7Q10 (cfs) 80 (Dan River)�� _° Winter 7Q10 (cfs): 160 (Dan River) z4, 30Q2(cfs) 195 (Dan River) Average Flow (cfs) 576 (Dan River) IWC, (%) 19 ool: Lat. 36116' 49.5" N Long. 80° 03' 39.8" W 002: Lat. 36°18' 22.0" N Long. 80° 04' 50.7" W 006: Lat. 36° 17' 5.0" N Long. 80° 04' 18" W BACKGROUND Duke Energy's Belews Creek Steam Station is a coal fired steam electric plant in Stokes County. The facility has three permitted outfalls in the current NPDES discharge permit, issued in January 1998. The sources of wastewater for these outfalls include non -contact cooling water, ash basin discharge, sanitary waste, cleansing and polishing water and stormwater from process areas. In compliance inspection reports, the Winston-Salem Regional Office describes the facility as providing excellent treatment and as generally being well operated and maintained with few compliance problems. In addition to NPDES Permit NC0024406, the facility also ,holds the following permits: 01983R12 (air .permit), NCD000856591 (Hazardous wastes), 85-03 (industrial landfill), and WQ0005873 (spray irrigation permit). The current permit expires February 28, 2002. The outfalls are defined as follows (as per the 2002 permit application): 001: Condenser cooling water 001 discharges non -contact cooling water used to cool the equipment and condense exhaust steam from the turbines. No chemicals are added to the water. Non -contact cooling water for the station equipment, recirculated cooling water coolers and hydrogen and :oil coolers. Intake screen backwash (from which the debris has been collected and composted) is also discharged through this outfall. 001 discharges to Belews Lake. 003: Ash Basin 003 discharges the "process flow" that is regulated under federal effluent guidelines. This discharge consists of flow from the power house sumps, the yard holding sump, the ash sluice lines, the chemical holding pond, the coal yard sumps, groundwater remediation system, and run- off from the watershed of the basin. 003 discharges to the Dan River. Tact. Shz ceL NPDES NC00244. 6ftenevgal Ptloe 1 006: 006 discharges boiler and filter cleaning wastes on an as -needed basis. These wastes are sent to the chemical holding pond, which then discharges through 003. 006 is therefore an internal outfall, with limits being set at the point of discharge, outfall 003. This facility does not require a 316(a) variance. Permit Renewal Application: . The permittee submitted the following items for permit renewal: • EPA Form 1 • EPA Form 2E • EPA Form 2C (with a priority pollutant analysis) • Site Maps • Water Flow Diagram • Supplemental information The following changes for outfall 003 only were requested: • Reduction of total iron and total copper monitoring from monthly to only during chemical metals cleaning. • Change the oil and grease limit to a concentration based limit and reduce the sampling to semi-annually • Change the TSS limit to a concentration based limit and reduce the sampling to semi- annually • Reduce the total arsenic, sulfates, and fluoride monitoring to semi-annually. • Reduce pH monitoring to monthly The Permittee also requested some changes to the language of Part III.J.K. as regards chemical metal cleaning wastes. Instream Monitoring and Verification of Existing Conditions and DMR Data Review. This facility discharges to both Belews Lake (001) and the Dan River (003). Outfall 006 is an internal outfall discharging to the ash basin. Both are located within sub -basin 03-02-01 Belews Lake is 303(d) listed due to a fish advisory for selenium. The Division took measures to correct this by having Duke Energy move the ash basin discharge out of Belews Lake and into the Dan River in May, 1985. The 2001 Roanoke River Basin Report states that the concentrations of selenium in fish tissue in the lake have declined to levels considered safe for human consumption by the Department of Health and Human Services. The fish consumption advisory was lifted in August 2000. Moreover, data collected in the Dan River below the lake showed tissue concentrations ranging from 0.10 to 1.03ug/g, below the state's advisory criterion of 5 ug/g. The Dan River above Belews Lake is not listed as impaired[303 (d) -listed as of 20001. One of the permit requirements is to perform an assessment of balanced and indigenous populations in Belews Lake. This requires the Belews Creek Plant to a number of uplake, in -lake and downlake sampling sites. Three macroinvertebrate sampling stations are maintained in Belews Lake and three fish monitoring stations. The report was evaluated by the Division's Biological Assessment Unit and recommends: close monitoring of fish tissue to determine if selenium is being mobilized from sediments to the food chain (or by benthic disturbances) and monitoring of the Dan River to determine if there has been any increase in tissue concentrations of selenium. Discharge Monitoring Reports (DMRs) for the outfalls were reviewed from January 1999 November 2001. Outfall 006 is an internal outfall and, as specified under Special Condition F of the 1998 permit, no monitoring requirements are specified for this outfall. The facility reports the average flow as 0.03 MGD, though this outfall discharges only one day every four years. No discharges were noted between January 1999 and November 2001. Flow and temperature (effluent, upstream and downstream) are measured at outfall 001, a discharge consisting of once -through cooling water and miscellaneous equipment and non -contact cooling water; flow during this time averaged 701 MGD. In general, though the effluent temperature was several degrees higher than the upstream temperature, the downstream temperature was the same or nearly the same as the upstream temperature. No exceedences of the downstream temperature limit of 32°C were noted. Faci Sheet Noe 2 Outfall 003 consists of the ash basin discharge as well as flow from the power house and yard holding sumps; the chemical holding pond, coal yard sumps, groundwater remediation water and stormwater. The average flow from this outfall was 7.4 MGD with a high of 10.1 MGD. Selenium, iron, copper, arsenic, fluoride, sulfate, TSS, oil and grease, total nitrogen and total phosphorus are monitored at this outfall. The average TSS measurement in the outfall was 386.7 lbs./day, though the detection level was highly variable. The average oil and grease measurement in the outfall was 208.8 lbs./day, though, as with TSS, the detection level was variable. Average total nitrogen was 0.28 mg/L and average total phosphorus was 0.005 mg/L (with many of the samples resulting in non -detects). The average, maximum and minimum levels of toxicants are summarized in the table below: Sulfate Fluoride Arsenic Copper Iron Selenium (mg/L) (mg/L) (99/L) (mg/L) (mg/L) (999) Average 41.7 0.3 10.4 0.018 0.07 13.4 Maximum 81.4 1.1 17.7 0.030 0.18 22.1 Minimum 24.8 Non -detect 4.2 Non -detect 0.01 8.1 These data are analyzed in the Reasonable Potential Analysis section below. Correspondence. The Winston-Salem Regional Office (WSRO) conducted four site visits and submitted corresponding Compliance Evaluation Inspection Reports. The facility typically received satisfactory ratings on these reports and was described as well maintained with an effluent that showed no visible adverse impacts to the receiving stream. None of these inspections revealed a violation and no Notices of Violation (NOVs) were noted during the file review. No staff report was available for this renewal. In August 2001, the Technical Assistance and Certification Unit classified the plant as Class I. The plant will soon be required to have an ORC on-site with physical/chemical certification. PERMITTING STRATEGY Waste Load Allocation (WLA). The Division prepared the last WLA in 1996 for each of the outfalls using the updated streamflow data from the USGS' profile of the Roanoke. Mary Cabe of the NPDES unit used the facility's average flow to get the IWC on which the toxicity test is based. The previous and current effluent limits were based on guidelines and water quality standards. The Division has judged previous parameters and limits to be appropriate for renewal with some exceptions (see Reasonable Potential Analysis). Technology Based Limits: Outfall 003 has limits based upon the guidelines for low-volume waste sources as well as the chemical metals cleaning guidance. The iron and copper limits were placed in the permit as concentration based limits some time ago. This decision was based upon the large retention time of the ash pond, which could result in iron and copper from a single metals cleaning event being discharged over a long period of time. Since concentration based limits would be more environmentally conservative in this case (i.e. more difficult to meet than a pound per day value that could be modulated by varying the discharge volume), these were placed in the permit to be protective of the receiving stream. It is the permit writer's decision to keep these limits as concentration based for the protection of the aquatic environment. . Reasonable Potential Analysis (RPA). The Division conducted EPA -recommended analyses to determine the reasonable potential for toxicants to be discharged by this facility from outfall 003. No chemicals are added to the wastestream at 001 nor is Duke required to monitor for anything other than, flow and temperature at that outfall. The RPA which follows for 003 is based on nearly three years of DMR data (January 1999 — November 2001) for sulfate, fluoride, arsenic, copper, iron, selenium, TSS and oil and grease. Other data was taken from samples submitted with the facility's priority pollutant analysis (ppa). Calculations included: arsenic, barium, chromium, copper, fluoride, iron, oil and grease, selenium, sulfate and total suspended solids.. Fact Sheet NPDFS NC002 4406Re ew it Results suggest no reasonable potential for the facility to discharge arsenic, barium, chromium, copper, fluoride, iron, oil and grease, and'total suspended solids. Reasonable potential was demonstrated for selenium and sulfate. The selenium limit is based on the North Carolina water quality standard for freshwaters (5 gg/L) and the 7Q10 flow. The limit previously listed in the permit (23 gg/L) appears to be an error and shall be corrected to 26 gg/L in this permit. The sulfate limit is based on the North Carolina water quality standard for water supply waters (250000 gg/L) and the 7Q10 flow. During the draft period, the permittee protested imposition of a sulfate limit since the finding of reasonable potential was based upon a data point from March 1999. The analysis was re -run for data running from April 1999 through March 2002 and no reasonable potential was found. The limit for sulfate will therefore be removed and the monitoring frequency changed to monthly. Guidelines require that the NPDES permit limit iron, copper, TSS and oil and grease. Arsenic and fluoride, currently monitored monthly can now be monitored quarterly due to no finding of reasonable potential. Total copper, due to the fact that it was rarely detected and showed no reasonable potential, shall be monitored on a quarterly frequency. TSS and oil and grease can be reduced to a quarterly monitoring frequency. Concentration based limits (using average flow and 7Q10 streamflow) are permissible. 'Total iron, as an action level pollutant showing no reasonable potential, shall be monitored quarterly. Selenium and sulfate shall be assigned water quality limits with twice monthly monitoring. In conjunction with the RPA, the primary pollutant analysis was reviewed. The parameters detected at levels above the intake values are as follows: fluoride, sulfate, aluminum, barium, boron, iron, magnesium, molybdenum, chromium, copper and selenium,. Arsenic, fluoride, sulfate, selenium and iron are already monitored through the NPDES permit and data on these parameters was.analyzed above. For those compounds for which ambient concentrations are unknown (barium, chromium), the data provided in the ppa was used in the RPA. No reasonable potential was demonstrated for barium and chromium, so these do not need to be included in the effluent monitoring requirements. The aluminum sample taken for the analysis indicated an aluminum concentration around ambient stream levels. It was therefore determined that none of the parameters detected in the ppa (beyond those already in the permit) need to be added to the monitoring requirements. A similar analysis was performed for the ppa on outfall 001. Only sulfate and barium were detected at levels higher than the intake. These compounds were present in levels -that are comparable to ambient and well below water quality standards. Moreover, since no chemicals are added to the effluent at 001 and it consists entirely of non -contact cooling water, it is unlikely that, these toxicants would be present in any significant levels. SUMMARY OF PROPOSED CHANGES In keeping with Division policies the following will be incorporated into the permit: Reduce arsenic, fluoride, iron and copper monitoring to quarterly (iron and copper should also be monitored during metals cleaning). • Reduce TSS and oil and grease monitoring to quarterly (and during metals cleaning); change limits to concentration based. • Add/change selenium and sulfate limits, monitoring to be 2/month. pH will remain at twice monthly frequency. New Weekly Average and Daily Maximum limits are derived from the latest NC/EPA policies considering 1/2 FA Vs and allowable concentrations based' on reasonable potential. Since the release of the draft permit for public comment, the following changes have been made:. • Change of address: the facility is now listed as being in Belews Creek, not Walnut Cover, as specified on the cover sheet and supplement to the cover sheet. • Removal of sulfate limit based on updated data set (April 1999 -March 2002) which showed no reasonable potential. Monitoring frequency changed to monthly. • Chronic toxicity sample changed to grab for consistency with previous permit as well as nature of the discharge (ash basin has large retention time such that a grab sample is representative of the discharge). 17,)CL sht> et Pao" 4 ENCLOSURES: Reasonable Potential Analysis for outfall 003, primary pollutant analysis (ppa) for 003, aquatic toxicity data. Additional compliance data available upon request. PROPOSED SCHEDULE FOR PERMIT ISSUANCE Draft Permit to Public Notice: Permit Scheduled to Issue: February 13, 2002. April 2, 2002. NPDES DIVISION CONTACT If you have questions regarding any of the above information or on the attached permit, please contact Natalie Sierra at (919) 733-5083 ext. 551. NAME: DATE: Fact Shout Facility Name = Qw (MGD) _.7.4,= WWTP Classification' NPDES # = Receiving Stream IWC (%) = Deli ws !.,Creek -sit I Implementation 1 NM244 , Danju 19.00 easonable Potential Summary 70 20 30 40 Stream Classification - "WS 7QIOs (cfs)= 80:1 30Q2 (cfs) Qavg (cfs) Arsenic I Implementation I Max. Pred Cw 27.1 µgA jAre all reported values less than? No Limits No IMonitonn 9 Allowable Cw 266.9 µg/1 'Is the detection limit acceptable? "has, 'i Monitor? Yes 'FrequencyQrt1y , Barium. ;Implementation Max Pred. Cw 37.0 mg/L jAre all reported values less than? I Max. Pred Cw Not a POC µg/1 !Are all reported values less than? No Limit? Na Monitoring, Allowable Cw 5337.2 A µgacceptable?Yes IIs the detection limit .' `Monitor. No I Frequency None Chromium I Implementation I Max. Pred Cw 33.0 µg/1Are all reported values less than? No Limit? Na, Monitoring Allowable Cw 266.9 µg11 'Is [he detection limit acceptable? Yes Monitor? No „ .., Frequency None X12FAv 1022W/l' J .. Max. Pred Cw Allowable Cw ;Implementation 0.1 µg/1 !Are all reported values, less than? 37.4 µg11 [Is the detection limit acceptable? No Limit? Yes111_1 Monitor? No' Monitoring Yes [Frequency I Plouride Implementation Max Pred. Cw Max. Pred Cw 2.3 µgA ,Are all reported values less than? No Limit? Np ;Monitoring Allowable Cw 9607.0 µg/1 IIs the detection limit acceptable? Yes , ; Monitor? Yes I Frequency .Qrtty Iron I Implementation Max Pred. Cw 37.0 mg/L jAre all reported values less than? I Max. Pred Cw 0.5 µg/1 Are all reported values less than? No Limit? No' MOnitOfing TO, be Allowable Cw 5.3 µg/1 'Is the detection limit acceptable? iYes `iMonitor? Yes 'Frequency,deterrrlirlGd Oil & Grease Implementation Max. Pred Cw 18.4 mg/L !Are all reported values less than? No Limit? No Monitoring Tobe Allowable Cw 160.1 mg/L IIs the detection limit acceptable? 3Yes ,JMonitor? ._ Yes (Frequency deterrninedl Selenium I Implementation I Max. Pred Cw 32.6 µgA jAre all reported values less than? No Limit? Xes 1 Monitoring Allowable Cw 26.7 µgA ;Is the detection limit acceptable? =Yes_ > ,';Monitor? Yes ;FrequenCV2/MQnth~<.. JUIIQLC unptementanon Max Pred. Cw 322.60 mg1L Are all reported values less than? No Limit? Yes Monitoring Allowable Cw 300.30 mg1L IIs the detection limit acceptable? Yes -: ";Monitor? Yes I Frequency 2/Nlorjth° !° Total Suspended Solids Ivnplementation [ Max Pred. Cw 37.0 mg/L jAre all reported values less than? No Limit? No' Monitoring To be Allowable Cw 500.0 mg/L 'Is the detection limit acceptable? Yes ";" Monitor? Yes ' Frequency „deerrnifled NOTE: "Limit?" field indicates "Yes" *only* if the parameter should be monitored based on water quality standards If Monitoring Frequency indicates "To be determined," it is because that parameter has federal effluent guidelines associated with it. Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7QIOs (cfs)= 80 IWC (%) = 19.00 FINAL RESULTS Arsenic Max. Pred Cw 27.13 Allowable Cw 266.9 ESULTS J Dev. 3.9527 ean 10.4 V. 0.3790 Number of data points 35 Malt Factor = 1.53 Max. Value 17.7 µg/1 Max. Pred Cw 27.13 µg/1 Allowable Cw 266.9 µg/l Parameter = Arsenic Standard = 50.0 µg/l Date n < Actual Data BDL=1/2DL Jan -99 1 6.1 6.100 Feb -99 2 5.5 5.500 Mar -99 3 6.1 6.100 Apr -99 4 5.3 5.300 May -99 5 4.7 4.700 Jun -99 6 7.3 7.300 Jul -99 7 13.6 13.600 Aug -99 8 11.2 11.200 Sep -99 9 17.7 17.700 Oct -99 10 17 17.000 Nov -99 11 10.1 10.100 Dec -99 12 9.9 9.900 Jan -00 13 9.5 9.500 Feb -00 14 8.4 8.400 Mar -00 15 4.2 4.200 Apr -00 16 4.3 4.300 May -00 17 5.2 5.200 Jun -00 18 9 9.000 Jul -00 19 8.6 8.600 Aug -00 20 8.6 8.600 Sep -00 21 12.6 12.600 Oct -00 22 11.5 11.500 Nov -00 23 14.6 14.600 Dec -00 24 13.7 13.700 Jan -01 25 12.7 12.700 Feb -01 26 12.1 12.100 Mar-Ol 27 10.7 10.700 Apr -01 28 9.6 9.600 May -01 29 8.4 8.400 Jun -01 30 13.3 13.300 Jul -01 31 13.5 13.500 Aug -01 32 10.5 10.500 Sep -01 33 15.7 15.700 Oct -01 34 16.8 16.800 Nov -01 35 17 17.000 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7Q10s (cfs)= 80 Date IWC (%) = 19.00 ppa FINAL RESULTS Barium Max. Pred Cw 448.5111 Allowable Cw 5337.2 ESULTS d Dev. 1.0000 can 0.1 V. 11.4943 of data points 1 Mult Factor = 5155.30 Max. Value 0.1 µg/1 Max. Pred Cw 448.5111 pg/l Allowable Cw 5337.2 pg/l Parameter = Barium Standard = 1000:0 I µg/1 n < Actual Data BDL=1/2DL 1 0.1 0.1 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7QJOs (cfs)= 80 IWC (%) = 19.00 FINAL RESULTS Copper Max. Pred Cw 0.1 Allowable Cw 37.4 RESULTS n < Std Dev. 0.0047 Ian -99 Mean 0.0 0.005 C.V. 1.3866 2 Number 0.005 0.0025 of data points 23 < Malt Factor = 4.32 Apr -99 Max. Value 0.0 pgA Max. Pred Cw 0.1 pgA Allowable Cw 37.4 pgA Parameter = Co er Standard = 7.0 pgA Date n < Actual Data BDL=1/2DL Ian -99 1 < 0.005 0.0025 Feb -99 2 < 0.005 0.0025 Mar -99 3 < 0.005 0.0025 Apr -99 4 < 0.005 0.0025 May -99 5 < 0.005 0.0025 Jun -99 6 < 0.005 0.0025 Jul -99 7 < 0.005 0.0025 Aug -99 8 < 0.005 0.0025 Sep -99 9 < 0.005 0.0025 Oct -99 10 < 0.005 0.0025 Nov -99 11 < 0.005 0.0025 Dec -99 12 < 0.005 0.0025 Jan -00 13 < 0.005 0.0025 Feb -00 14 < 0.005 0.0025 Mar -00 15 < 0.005 0.0025 Apr -00 16 < 0.005 0.0025 May -00 17 < 0.005 0.0025 Jun -00 18 0.03 0.0300 Jul -00 19 < 0.005 0.0025 Aug -00 20 < 0.005 0.0025 Sep -00 21 < 0.005 0.0025 Oct -00 22 < 0.005 0.0025 Nov -00 23 < 0.005 0.0025 Dec -00 23 < 0.005 0.0025 Jan -01 23 < 0.005 0.0025 Feb -01 23 < 0.005 0.0025 Mar-Ol 23 < 0.005 0.0025 Apr-Ol 23 < 0.005 0.0025 May-Ol 23 < 0.005 0.0025 Jun -01 23 < 0.005 0.0025 Jul -01 23 < 0.005 0.0025 Aug -01 23 < 0.005 0.0025 Sep -01 23 < 0.005 0.0025 Oct -01 23 0.005 0.0050 Nov -O] 23 < 0.005 0.0025 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7Q10s (cfs)= 80 IWC (%) = 19.00 FINAL RESULTS Chromium Max. Pred Cw 33.0 Allowable Cw 266.9 RESULTS Std Dev. 1.0000 Mean 1.3 C.V. 0.8000 (Number of data points 1 Factor = 26.44 Value 1.3 µg/1 Pred Cw 33.0 µg/1 vable Cw 266.9 pg/l Parameter I Em!] Standard 119/1 Date n < Actual Data BDL=1/2DL ppa 1 1.3 1 1.3 Facility Name = Belews Creek Steam Station Parameter = Flouride NPDES # = NC0024406 Standard = 1800.0- µg/1 Qw (MGD) = 7.4 7QIOs (cfs)= 80 Date n < Actual Data BDL=1/2DL IWC (%) = 19.00 Jan -99 1 0.3 0.3 Feb -99 2 0.3 0.3 FINAL RESULTS Mar -99 3 0.2 0.2 Flouride Apr -99 4 0.2 0.2 Max. Pred Cw 2.3 May -99 5 0.3 0.3 Allowable Cw 9607.0 Jun -99 6 0.3 0.3 Jul -99 7 0.3 0.3 Aug -99 8 0.2 0.2 RESULTS Sep -99 9 0.2 0.2 Std Dev. 0.2374 Oct -99 10 0.3 0.3 Mean 0.3 Nov -99 11 0.5 0.5 C.V. 0.7161 Dec -99 12 0.3 0.3 Jan -00 13 0.3 0.3 Number Feb -00 14 0.2 0.2 of data points 35 Mar -00 15 1.1 1.1 Apr -00 16 0.3 0.3 Mult Factor = 2.12 May -00 17 0 0.0 Max. Value 1.1 µg/1 Jun -00 18 0.3 0.3 Max. Pred Cw 2.3 µg/1 Jul -00 19 0.3 0.3 Allowable Cw 9607.0 µg/1 Aug -00 20 0.5 0.5 Sep -00 21 0 0.0 Oct -00 22 0.3 0.3 Nov -00 23 0 0.0 Dec -00 24 0.3 0.3 Jan -01 25 0.5 0.5 Feb -01 26 0 0.0 Mar -01 27 0.4 0.4 Apr -01 28 0.3 0.3 May -01 29 0.3 0.3 Jun -01 30 1 1.0 Jul -01 31 0.7 0.7 Aug -01 32 0.4 0.4 Sep -01 33 0.6 0.6 Oct -01 34 0.2 0.2 Nov -01 35 0.2 0.2 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7QIOs (cfs)= 80 IWC (%) = 19.00 < Actual Data FINAL RESULTS Iron 1 Max. Pred Cw 0.5 Allowable Cw 5.3 RESULTS Std Dev. 0.0557 Mean 0.1 C.V. 0.8150 of data points 35 Mult Factor = 2.3 Max. Value 0.2 µg/I Max. Pred Cw 0.5 µg/1 Allowable Cw 5.3 pg/l Parameter Iron Standard 10 .,. mg/L Date n < Actual Data BDL=1/2DL Jan -99 1 0.2 0.200 Feb -99 2 0.04 0.040 Mar -99 3 0.15 0.150 Apr -99 4 0.2 0.200 May -99 5 0.07 0.070 Jun -99 6 0.07 0.070 Jul -99 7 0.03 0.030 Aug -99 8 0.03 0.030 Sep -99 9 0.05 0.050 Oct -99 10 0.02 0.020 Nov -99 11 0.18 0.180 Dec -99 12 0.03 0.030 Jan -00 13 0.1 0.100 Feb -00 14 0.09 0.090 Mar -00 15 0.16 0.160 Apr -00 16 0.05 0.050 May -00 17 0.06 0.060 Jun -00 18 0.03 0.030 Jul -00 19 0.15 0.150 Aug -00 20 0.03 0.030 Sep -00 21 0.02 0.020 Oct -00 22 0.02 0.020 Nov -00 23 0.02 0.020 Dec -00 24 0.06 0.060 Jan -01 25 0.06 0.060 Feb -01 26 0.04 0.040 Mar -01 27 0.07 0.070 Apr -01 28 0.07 0.070 May -01 29 0.13 0.130 Jun -01 30 0.06 0.060 Jul -01 31 0.03 0.030 Aug -01 32 0.02 0.020 Sep -01 33 0.02 0.020 Oct -01 34 0.01 0.010 Nov -01 35 0.02 0.020 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7Q10s (cfs)= 80 IWC (%) = 19.00 Feb -99 FINAL RESULTS Oil & Grease 1.022 Max. Pred Cw 18.4 Allowable Cw 160.1 RESULTS Std Dev. 1.2661 Mean 0.7 C.V. 1.7063 of data points 35 Factor = 3.90 Value 4.7 mg/L Pred Cw 18.4 mg/L vable Cw 160.1 mg/L Parameter = Oil & Grease Standard = 30.0 mg/L Date n < Actual Data BDL=1/2DL Jan -99 1 < 1.106 0.553 Feb -99 2 < 1.022 0.511 Mar -99 3 < 0.012 0.006 Apr -99 4 < 0.007 0.003 May -99 5 < 2.812 1.406 Jun -99 6 < 0.991 0.495 Jul -99 7 < 0.010 0.005 Aug -99 8 < 1.117 0.558 Sep -99 9 < 0.945 0.472 Oct -99 10 < 0.009 0.004 Nov -99 11 < 0.969 0.485 Dec -99 12 < 0.943 0.471 Jan -00 13 < 0.013 0.006 Feb -00 14 < 1.269 0.634 Mar -00 15 < 0.006 0.003 Apr -00 16 < 0.012 0.006 May -00 17 < 0.041 0.021 Jun -00 18 < 0.010 0.005 Jul -00 19 0.010 0.010 Aug -00 20 < 0.008 0.004 Sep -00 21 < 0.009 0.005 Oct -00 22 < 0.009 0.005 Nov -00 23 < 0.004 0.002 Dec -00 24 < 0.011 0.006 Jan -01 25 < 5.709 2.855 Feb -01 26 < 4.728 2.364 Mar -01 27 < 5.286 2.643 Apr -01 28 < 0.067 0.033 May -01 29 4.422 4.422 Jun -01 30 0.050 0.050 Jul -01 31 < 5.219 2.610 Aug -01 32 < 1.114 0.557 Sep -01 33 4.709 4.709 Oct -01 34 < 0.076 0.038 Nov -01 35 < 0.022 0.011 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 7QIOs (cfs)= 80 IWC (%) = 19.00 7.05 FINAL RESULTS Selenium 3 Max. Pred Cw 32.6 Allowable Cw 26.7 RESULTS Std Dev. 4.6291 Mean 13.4 C.V. 0.3442 Number of data points 35 Mult Factor = 1.48 Max. Value 22.1 µg/1 Max. Pred Cw 32.6 pg/l Allowable Cw 26.7 pg/l Parameter = Selenium Standard = '5.0 Ng/l Date n < Actual Data BDL=1/2DL Jan -99 1 5.45 5.5 Feb -99 2 7.05 7.1 Mar -99 3 7.25 7.3 Apr -99 4 9 9.0 May -99 5 8.55 8.6 Jun -99 6 13.8 13.8 Jul -99 7 16.95 17.0 Aug -99 8 16.05 16.1 Sep -99 9 11.7 11.7 Oct -99 10 11.8 11.8 Nov -99 11 10.6 10.6 Dec -99 12 10.6 10.6 Jan -00 13 11.05 11.1 Feb -00 14 12.55 12.6 Mar -00 15 11.5 11.5 Apr -00 16 11.6 11.6 May -00 17 12.9 12.9 Jun -00 18 17 17.0 Jul -00 19 17.6 17.6 Aug -00 20 16.9 16.9 Sep -00 21 18.8 18.8 Oct -00 22 17.4 17.4 Nov -00 23 18.45 18.5 Dec -00 24 19.7 19.7 Jan -01 25 21.9 21.9 Feb -01 26 22.1 22.1 Mar -01 27 21.05 21.1 Apr -01 28 17.7 17.7 May -01 29 15.35 15.4 Jun -01 30 13.8 13.8 Jul -01 31 11.1 11.1 Aug -01 32 9.1 9.1 Sep -01 33 8.15 8.2 Oct -01 34 8.05 8.1 Nov -01 35 8.1 8.1 Facility Name = Belews Creek Steam Station NPDES # = Nc0024406 Qw (MGD) = 7.4 Average Q (cfs)= 576 FINAL RESULTS Sulfate Max. Pred Cw 322.6 Allowable Cw 300.3 RESULTS n < Std Dev. 24.5864 Mean 41.7 C.V. 0.5898 Number 2 of data points 35 Mult Factor = 1.89 Max. Value 170.6 m Max. Pred Cw 322.6 m Allowable Cw 300.3 m Parameter = Sulfate Standard = 250.0 mg/L Date n < Actual Data BDL=1/2DL Jan -99 1 31.9 31.9 Feb -99 2 31.5 31.5 Mar -99 3 170.6 170.6 Apr -99 4 33.4 33.4 May -99 5 42.2 42.2 Jun -99 6 54.7 54.7 Jul -99 7 81.4 81.4 Aug -99 8 38.1 38.1 Sep -99 9 33.8 33.8 Oct -99 10 33.1 33.1 Nov -99 11 37.8 37.8 Dec -99 12 37.6 37.6 Jan -00 13 38.2 38.2 Feb -00 14 37.6 37.6 Mar -00 15 44.1 44.1 Apr -00 16 42 42.0 May -00 17 43.3 43.3 Jun -00 18 41.9 41.9 Jul -00 19 43.4 43.4 Aug -00 20 44.6 44.6 Sep -00 21 41.6 41.6 Oct -00 22 41.1 41.1 Nov -00 23 40.8 40.8 Dec -00 24 41 41.0 Jan -01 25 39.9 39.9 Feb -01 26 35.7 35.7 Mar -01 27 36.5 36.5 Apr -01 28 32.3 32.3 May -01 29 30 30.0 Jun -01 30 28.6 28.6 Jul -01 31 25.8 25.8 Aug -01 32 26.4 26.4 Sep -01 33 24.8 24.8 Oct -01 34 25.5 25.5 Nov -01 35 27.8 27.8 Facility Name = NPDES # = Qw (MCD) = 7QIOs (cfs)= !WC (%) = Belews Creek Steam Station Nc0024406 7.4 80 19.00 C.V. 1.5602 FINAL RESULTS TDS Max. Pred Cw Allowable Cw 37.0 500.0 RESULTS n < Std Dev. 2.3209 Mean 1.5 C.V. 1.5602 Number 2 < of data points 35 Malt Factor = 3.65 Max. Value 10.1 mg/L Max. Pred Cw 37.0 mg/L Allowable Cw 500.0 mg/L Parameter = TSS Standard = 500.0 Date n < Actual Data BDL=1/2DL Jan -99 1 7.728 7.728 Feb -99 2 < 4.089 2.044 Mar -99 3 < 0.049 0.024 Apr -99 4 0.049 0.049 May -99 5 < 0.703 0.352 Jun -99 6 < 3.963 1.981 Jul -99 7 < 0.040 0.020 Aug -99 8 < 4.466 2.233 Sep -99 9 < 3.779 1.889 Oct -99 10 < 0.035 0.017 Nov -99 11 3.594 3.594 Dec -99 12 < 3.769 1.885 Jan -00 13 0.103 0.103 Feb -00 14 10.129 10.129 Mar -00 15 < 0.024 0.012 Apr -00 16 < 0.049 0.024 May -00 17 < 0.010 0.005 Jun -00 18 < 0.040 0.020 Jul -00 19 0.040 0.040 Aug -00 20 < 0.033 0.016 Sep -00 21 < 0.036 0.018 Oct -00 22 < 0.037 0.018 Nov -00 23 < 0.037 0.019 Dec -00 24 < 0.045 0.023 Jan -01 25 < 4.568 2.284 Feb -01 26 < 3.779 1.889 Mar -01 27 < 4.229 2.114 Apr -01 28 0.054 0.054 May -01 29 5.310 5.310 Jun -01 30 0.040 0.040 Jul -01 31 < 4.183 2.092 Aug -01 32 < 4.462 2.231 Sep -01 33 3.767 3.767 Oct -01 34 < 0.061 0.030 Nov -01 35 < 0.018 0.009 mg/L Primary pollutant analysis results for Duke Energy's Belews Creek Steam Plant NC0024406 Outfall 003 Predicted conc. (RPA) 0.4485 33 lin permit in permit in permit in permit in permit red font indicates that all. Conc. Based upon EPA Rec. Criteria fields in bold (no highlighting) indicate that concentration detected is around ambient or tap water values (conversation with Roy Byrd, 10/24/01) fields with highlighting indicate those parameters that may require periodic monitoring to ensure that the discharge has no impact on the water quality of the receiving stream. BASED on 19% IWC CONCLUSION: None of the parameters detected in the ppa (beyond those already present in the permit) need be added to the permit monitoring requirements Parameter of concern Aluminum Barium Boron Chromium Magnesium Molybdenum " Arsenic °Fiuprlc(e-- .Sulcate, 5eleniutll iron (mg/L) (mg/L) (mg/L) (ug/L) (mg/L) (mg/L).' (u /L) _ ►ftg%L .(m L), {41L}(r[g1L Actual concentration 0.113 0.087 0.407 1.25 3.16 0.022 ..` 14.6 , 0.65 44 6 22 9 Allowable concentration 0.263 1.13 not a POC 56.5 not a POC not a POC � !65 .5; 2.034 250 Predicted conc. (RPA) 0.4485 33 lin permit in permit in permit in permit in permit red font indicates that all. Conc. Based upon EPA Rec. Criteria fields in bold (no highlighting) indicate that concentration detected is around ambient or tap water values (conversation with Roy Byrd, 10/24/01) fields with highlighting indicate those parameters that may require periodic monitoring to ensure that the discharge has no impact on the water quality of the receiving stream. BASED on 19% IWC CONCLUSION: None of the parameters detected in the ppa (beyond those already present in the permit) need be added to the permit monitoring requirements Whole Effluent Toxicity Testing Self -Monitoring Summary January 18, 2002 FACILITY REQUIREMENT YEAR JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC Dan River Inc. Harris Facility Penn chr lim: 0.75% 1998 >100 — >100 — -- >100 — — >100 -- -- >100 NCO093275/001 Bebdn:2/1/1999 Frequency: Q + Mar Jun Sep Dec + NonComp:Single 1999 — — Pass — — Pass -- — Pass — — Pass County: Rutherford Region: ARO Subbasin: BRD02 2000 — — Pass -- -- Pass -- — Pass — -- _ Pass PF: 0.91 Special 2001 _- — Pass — — Pass -- — Pass — — 7Q10: 186 IWC(%):0.75 Order: 2002 Dare County-(RO)/001 Perm 24hr p/fac monit: 90%mysid 1998 Pass -- — Fail,Pass -- — Fail,Pass -- — Pass — — NC0070157/001 Begin:5/1/1995 Frequency: Q Jan Apr Jul Oct NonComp: 1999 Pass — -- Pass -- — Pass — — Pass -- — County: Dare Region: WARO Subbasin: PAS56 2000 Bt Bt — Pass -- — Pass — — Pass — -- PF: NA Special 2001 pass — — Pass — — Pass — -- Pass — 7Q 10: 0 IWC('/.):NA Order: 2002 Dare County-(RO)/002 Perm 24hr p/f ac monit: 90% mysid 1998 Pass — -- Pass — — Pass — -- Pass -- -- NC0070157/002 Begin:5/1/1995 Frequency: Q P/F Jan Apr Jul Oct NonComp: 1999 Pass — -- Pass — -- Pass -- -- Pass -- -- County: Dare Region: WARD Subbasin: PAS56 2000 Bl -- — Fail Fail,Pass -- Pass --- -- Fail,Failt --- — PF: NA Special 2001 pass -- — Pass -- — Pass -- -- Pass — 7Q10:0 IWC(%):100 Order: 2002 Delta Mills P-2 perm chr lim: 11%; if exp I.5MGD chr lim 16% 1998 — — 31 — — 31 — — 31 — -- 16 NC0006190/001 Begin:3/1/1998 Frequency: Q Mar Jun Sep Dec + NonComp:ChV Avg 1999 — -- 16 — — at — — 15 — — 31 County: Catawba Region: MRO Subbasin: CTB35 2000 — -- 4.1 <3 Late 15.6,15.6 -- — 31 -- — 15.6 PF: 1.0 Special 2001 — — 31.1 — — 15.6 — -- 15.6 -- -- . 7Q 10: 12 1 WC(%):I I Order: 2002 Denton WWTP Perm chr lim: 90% 1998 -- Pass — -- Pass -- -- Pass -- -- , Fail,Pass -- NC0026689/001 Begin:4/1/2000 Frequency: Q Feb May Aug Nov + NonComp:Single 1999 -- Pass -- — >90 -- -- 51.9 73.48 >90 >90 — County: Davidson Region: WSRO Subbasin: YAD08 2000 — 21.2 >90 -- 36.7 >90 — Pass — -- Pass -- PF: 0.30 Special 2001 — Pass — — Pass — — Fail,>100 NR Pass Pass 7QI0:0.0 IWC(%):100 Order: 2002 Dixie Yarns, Inc. Perm chr lint: 90% (Grab) 1998 -- Pass — Pass — — Late Pass — Pass — -- NC0083763/001 Begin:5/1/2000 Frequency:Q Jan Apr Jul Oct + NonComp:Single 1999 Pass — — NR/Pass — -- Fail Pass — NR Pass — County: Stanly Region: MRO Subbasin: YADI2 2000 Fail Pass -- Pass — -- Fail >100 >100 NR Pass -- PF: 0.072 Special 2001 Fail >100 97.5 Late H H H — H Fail >100 7Q10:0 IWC(%):100 Order: 2002 Duke Power -Allen 002 Perm chr lim: 16% (Grab) 1998 Pass — -- Pass -- — Pass — -- Pass -- — NC0004979/002 Begin:10/1/1996 Frequency: Q P/F + Jan Apr Jul Oct NonComp: Single 1999 Pass — — Pass — — Pass — — Pass — — County: Gaston Region: MRO Subbasin: CTB34 2000 Pass — — at — -- Late Pass — Pass — -- PF: 11.6 Special 2001 Pass -- — Pass — — Pass -- — Fail >64 7Q10: 95.0 IWC( -/.):16 Order: 2002 Duke Power-Belews Creek/003 Perm chr lim: 19% (Grab) 1998 -- Pass — — Pass — -- Pass — -- Pass -- NC0024406/003 Begin:2/1/1998 Frequency: Q P/F + Feb May Aug Nov + NonComp:Single 1999 -- Pass -- — Pass — -- Pass — — Pass -- County: Stokes Region: WSRO Subbasin: ROA01 2000 -- Pass -- -- Pass — --- Late Pass — Pass -- PF: 7.7 Special 2001 _- Pass — — Pass -- -- Pass — — Pass 7Q10:24.0 IWC(%):33.0 Order: 2002 Duke Power -Buck Steam Perm chr lim: 0.7% (grab) 1998 — — >100 -- — >100 — — >100 — — >100 NC0004774/002 Begin:2/1/2000 Frequency: Q Mar Jun Sep Dec + NonComp:Single 1999 — -- >100 -- — >100 — — >100 -- — >100 County: Rowan Region: MRO Subbasin: YAD04 2000 — -- at -- — Pass — -- Pass — — Pass PF: NA Special 2001 __ — Pass — -- Pass -- — Pass — -- 7QI0:1030 IWC(%):0.598 Order: 2002 Duke Power-Cliffside Perm chr lion: 5.6% (Grab) 1998 — -- Pass --- -- Pass — -- Pass -- -- Pass NC0005088/002 Begin:3/1/1999 Frequency: Q P/F + Mar Jun Sep Dec + NonComp:Single 1999 -- — Pass -- -- Pass -- -- Pass -- — Pass County: Rutherford Region: ARO Subbasin: BRD02 2000 -- — at — — Pass — -- Pass — — Pass PF: 8.8 Special 2001 — — Pass — -- Pass -- — Pass — -- 7Q10:287 IWC(%):4.53 Order: 2002 Duke Power -Dan River Perm chr lim: 0.88% (Grab) 1998 — — Pass -- — Pass — — Pass -- — Pass NC0003468/002 Begin:6/1/1997 Frequency: Q + Mar Jun Sep Dec + NonComp:Single 1999 — — Pass — — Pass — -- Pass — •— Pass County: Rockingham Region: WSRO Subbasin: ROA03 2000 --- — Bt -- — Pass -- — Pass — — Pass PF: 1.8 Special 2001 — --- Pass -- — Pass -- --- Pass — -- 7Q10:314.0 IWC(0/,):0.879 Order: 2002 Y Pre 1998 Data Available LEGEND: PERM = Permit Requirement LET = Administrative Letter - Target Frequency = Monitoring frequency: Q- Quarterly; M- Monthly; BM- Bimonthly; SA- Semiannually; A- Annually; OWD- Only when discharging; D- Discontinued monitoring requirement Begin= First month required 7QI0 =Receiving stream low Flow criterion (cfs) + = quarterly monitoring increases to monthly upon failure or NR Months that testing must occur - ex. Jan, Apr, Jul, Oct NonComp = Current Compliance Requirement PF = Permitted Flow (MCD) IWC%= Instream waste concentration P/F = Paw/Fail test AC = Acute CHR = Chronic Data Notation: f - Fathead Minnow;' - Ceriodaphnia sp.; my - Mysid shrimp; ChV - Chronic value; P - Mortality of stated percentage at highest concentration; at - Performed by DWQ Aquatic Tox Unit; bt - Bad test Reporting Notation: --- = Data not required; NR - Not reported Facility Activity Status: 1 - Inactive, N - Newly Issued(To construct); H - Active but not discharging; t -More data available for month in question; • = ORC signature needed 16 0b J LL D 0 0 0 CJD o x N U O C U o Z pa rn w2 z Z O z U w a w LL IL U m R CL E n r D) n u) 0) It a0 N n m V (a N M N M w 0 0 a 1n M O r O LLJ M a1 r F' M N N cD n M aj V N ai f� In M N N POJ NNNNNCO O a0 N E ca rLLJ rr,: r POJ N N r N CLy Z) U aa) R CL N O FLO am v OR m CO 0) Cl) M n 00 M n V) CO n r in nM co N LLJ M n V) Ca n M (Ni V Ca W 6 a) N -4 O N M OO co Lo E ca d 'co rTr N N m N r r r r r N N N N r r r r V y 3 O O U N g Z m 5 m in v rn v in n m rn T m n v n 0 v m N M 0 n W M n N LO co 0 M 0 M co M O O to O to M N M n O aD ao V of t� W O n(�� M a r a) O N r N r Cl) V M f� E POPS� ( N N N C07 POJ M M V M M N N N N N C7 m C07 N C07 M co0N N N N N m M M V M C07 P.: M o ayi � w w 0 0 U � 0 M m LO m M v rn m n v rn m rn rn n m M > a n v> "' >> N N n n n M M n rno N 10 v �0 0� m rn n m° °° `m a, 3 co 3 n 3 3n m 0 m m M 3 3 a m m C9 rn rn rn n N r r 0 o c°Do r0i coo cM� 3 3 3 m io 0 n n m 0 in v n a 0 n m m m m M m °� rn rn a� 0 0 0 0 0 0 0 0 0 0 0 0 (P 9 m O O O O Q O O O O O O O O O O p O p r0 O O p OHID CL T m m0 o d m 0 0 n m>>mm � o ami �� m a m�� � p caii E � Q a CA O z o� LL 2 a - a M o z o A LL a a w 0 z Fa) E ca > > ca l m E m C N , O y N cL wwH of 7F - I I N O M O O Z O a a U o ayi � 0 U � O a d 0 CL E m m Fa) m Q m m LL rn � V M r O m N N O alea m C m c c Z c_ 0 'n0MZ �m� D - 0 C M 0 M a C M °< O v C 'O Q 7 O < O 'O CD C j .� 'O A��7 Q fM'�) < O v !� C 7 '0 N 6 7 m m o_0000000000666a6o0000006cbwcoo(bcococotococc) 9 0 0 0 0 0 0 0 0 0 0 0 o w w m m m m cD m m m w m ` A Cn aD V V J CSD -+ CD W CD W m m m V Cn O O m A W i m M V M m V J V W m V CO T Ctl IV 0 N W N m co O N o bo V o V m W vn W 07 W V W o o W N W o 07 m W W W 2. 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Un W J -+ V -,1 O W m -+ V N 0) CD n 3 7 P V O V' -f P A O A A A A A A A A A A A A A A A O A A A A A A A A A A A A A A A A A o O o O O O O O O o 0 0 o O o O O O o 0 o O O o 0 0 o O o 0 o O O O O O O o O o o o o o o o o o o o o o o o W o o o o o o o o o o o o o o o o 0 o CCn Cn m 0CnCOIL m m0 mm(.n m m m m mm mmCOIL m mm(0)7 m m N alN mCOi) m m � O D o C) c 0Oo z Ap p r { 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o a w O o 0 0 0 o 8 o o o o o o o o o Cn o o 0 1 0 1 0 1 0 0 0 0 0 o N 1 o N j O N. N N W m W J V A m m N N N. W W m Cn CD CD W CA N Cn GD W V V N A c � 3c � a N L 'A O W to oD fD 1 N s -+ -+ 1 1 -+ — 1 1 m O V J CJ) w f p ;1 i W CJl J N CD CD J W m J V N y 1 N i o o i m m W Cn Cn i W W J O b V A? W 0 M b 6 in Vn o 6 6 W v O W 0D W Cn m m Cn Cn N Cn cn Cn Cn c 3 N i 3 Oq N W N W W A W GD w N N N N N W W W W W W W N N N N N W W A W W W W N N N V O C)D O CD OD m Co W O CO A O W W V m Cn CO Cb m W A OD N W O co m O O W m A g +. W? W y W N i N o b LL 1 L) �l O W �J (D o A bO OD o 0) -+ V W N W to o Cn O o 'o OD co W m m m Cn N J W m J CD CD N m? CID J A J CD m J m N A co A cn a n w rt C n N A W m O O 1 a 4 ) C a A A N A A N CO CO A A A A A A A A N A A A A J Cn N A A A A A A N A A m y N m N N m co N W N co N N N N N m N CA N A N A 1 N N N N N A W N N O O m O V to O M A N m A0 m W W W O m W m W o J N m m m m W O m m i m O O W A W O W O O m m m O� 0 0 c O O O O O O A: O co o W •CNO D) (D (O (D 1 N m Q O -1 w A A CO A A CO CO A A A A A A A A A m A A A A A A A O A A A A A A A A A A o W N m Co N N A A Co A m N Cn cn m Cn m N m W CD m m m m m m m W m m W �.. N N Cn Oo Cn CD o O N N Cn C)o CD c0 oo Cn Cn Cn N N m CD O Cn cn Cn Cn CD J m Cn m Cn Cn W W A A Cn W A 1 1 W W W J m o a N. C co in Ul is in m in a fO,CO OD r O O 00 a o O O O O O O O O o O O z O' O, O W N N CWD N N Ul CO W N N W A :►.A !V 3 OOCyD , C O O O O O O O O O O O ro O_ 0 0 0 O O o C) 0 9 m00 W COn COn Con w m m G) O ZC C fA 0 m 16 ` —core/) z - 67A IbIm / IPA f S-( nPrm SST) 0 SAKES cotn\� VO �nWlj, 7k "91111� "I �111 PON -M 1-1 t�vvo%� Cv(u2�-i SCJ ytAt$C CL._� Permit NC0003719 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUAL/ITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General/Statute 143-215.1, other lawful standards and regula 'ons promulgated and adopted by the North Carolina Environmental Management 0kmmission, and the Federal Water Pollu�ion Control Act, as amended, Monsanto Company is hereby auth ' ed to discharge `fvastewater from a facility located at Monsa to - Fayetteville 68 ndar Creek Road ,Fayetteville C ;' erland County to receiving waters in accordance with effluent limitations, i conditions set forth in Part I, II, III and River in the Cape Fear River Basin f. requirements and other This permit shall become effective February 1, 2002. `• This permit and au zrization to discharge shall expire a�,xnidnight on October 31, 2006. Signed this day J uary 14, 2 1. \ 2©o Z' Gregory J. Thorpe, Ph.D., Acting Director Division of Water Quality By Authority of the Environmental Management Commission Xlr.&m 100 WJI / /� Oh,),r State of North Carolina Department of Environment and Natural Resources Division of Water Quality Michael F: Easley, Governor William G. Ross, Jr., Secretary Gregory J. Thorpe, Ph.D., Acting Director January 14, 2002 Ms. Deborah R. Small, Plant Monsanto Company P.O. Box 2307 Fayetteville, North Carolina 1 � • NCDENFI NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Subject: Issuance of NPDES Permit NC0003719 Mons nto - Fayetteville WWTP CuriZberland County Dear Ms. Small: Division personnel have reviewed and 1 approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute IA3-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Ag , cy dated May 9, 1994 (or as subsequently amended). The following changes have been made fromyour draft permit.. 14/9$ • The test organism for the whole effluent to 'city test has been changed from Ceriodaphnia dubia to fathead minnow. This correspop s to the toxicity language in your existing permit. • Effluent `conductivity monitoring �as,been removed from the permit. This requirement was not in your previous permit and `hasr'accidentally include d in the draft. • A footnote has been added to the glyphosate monitoring requirement specified in Part A. 1. This footnote specifies that after cleanup, glyphos to must be monitored six additional times between February 1 and October 1, 2002. Followin a series of both internal discussions and discussions with the EPA, it was determined that perio 'c monitoring of glyphosate is necessary to ensure that this contaminant is no longer being discharg from the site. If these samples indicate non -detects, then the Division can evaluate removal of glyp osate monitoring. In addition to the changes made above, Monsanto requested sever1 other changes to the draft permit. The Division regrets that we cannot comply with these requests; the followin explanations are offered: Following the flow reduction to 0.5 -MGD, quarterly toxicity onitoring must continue. All facilities discharging1"complex wastewater" in the state of North Carolina must have quarterly toxicity monitoring. Once Monsanto closes, there will still be a wast water discharge from the two adjacent OCPSFs. /The decision to continue toxicity monitoring is th efore made independent of WWTP class and is dependent on the wastewater source. The only time nual testing is allowed' is when the discharge is both sporadic and influenced largely by storm a ents. Please call Kevin Bowden of the Aquatic Toxicology Unit at (919) 733-2136 if you have any q stions. The new facility owner must submit both an ownership change formand a modification (which includes a description of the new process and a flow justification) s per condition A. (5.). The Division feels that since the permit requirements were developed on asite-specific basis for Monsanto, it is impossible to apply these limitations to a new, presumably diffe ent, industry. It is anticipated that the new owner would have different wastewater characteris 'cs that would require different permit conditions. Stormwater monitoring shall continue at SW -1. Since no separate stormwater pe it exists for the site, the existing stormwater monitoring requirements must remain in the permit. onsanto P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-071 An Equal Opportunity Affirmative Action Employer 50% recycled / 10% post -consumer paper /w, d" f, �, �, WN? 'N 9\o k6ep) h 9 �-p' S_�S-eery �u� v� ~-� -�-, LA -L- ,1c� �nC� uwqmalu ren om&; W4 OlIvA �� 1, eo0-X'; may request an alternative monitoring site for stormwater (following plant shutdown). In this case, the Division can make a minor modification to the permit to replace the existing monitoring site (SW-1)with a more appropriate one. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding. �11, Please note th�~at this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This pTnit does not affect the legal requirements to obtain oder permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, the Coastal Area Managemen{Act or any other Federal or Local governmental permit that ma} Kbe required. If you have any questions concerning this permit, please ' ntact Natalie Sierra at telephone number (919) 733-5083, extension 551. \ Gregory J. Thorpe, Ph.D. cc: Fayetteville Regional Office/Water Quality\E- NPDES Unit /f Point Source Compliance and Enforcement Technical Assistance and Certification Unit Mr. Roosevelt Childress, EPA Region IV Mr. Manhar Patel, Monsantd Company Ms. Hope Walters, Monsanto Company Fl� In 4 w-'p-cWyd Sa U VFb 3Q2M, &k4 wDQlo= (p -C) /WC Lnn 1wL fQ. ZZ4 ktJ4 'V17 'MW 9WA 'kVi4( Coffi�fla(�-i dNIH,6.' Permit NC0003719 A. (5.) SPECIAL CONDITION FOR TERMINATION OF MONSANTO The Monsanto Roundup plant portion of this discharge is expected to terminate within the first quarter of 2002. The Monsanto Company will retain control over the utilitie until such time as the facility and t%41ities are purchased. The allocation for this permitted discharge remains at 1..25 MGD. However, new permit for the discharge will be issued en 1hipi of the following take place: • Proof of change of o from Monsanto Company has b n furnished. The resulting name/owne ship change form shall be submitted�o the Division of Water Quality. • A new application for a 'scharge has been completed owner of the facility with request for a major modific • The request for a major mo, ification to NPD ES Pe include the appropriate feer such an action. • Completion of the application hall include a com et( proposed discharge and an Fn ' Alte ative When all of the above actions are complete, Division pages that are appropriate for the proposed dis barge o3 A. (6.) BIOCIDE CONDITION The permittee shall not use any biocides except permit application. The permittee shall notify t (90) days prior to instituting use of any additio may be toxic to aquatic life other than those re Quality. Such notification shall include co ple map locating the discharge point and rec wing submitted by the new y(ion of the NPDES permit. NC0003719 should flow justification for the Analysis (EAA) . I furnish new effluent limits of discharges. i\ofB roved in conjunction with the r in writing not later than ninety used in cooling systems which ported to the Division of Water cide Worksheet Form101 and a stream. A. (7.) DETECTION LEVELS FOR COMPLIANCE If the discharge limitation of a ven parameter is below quantitation limits, the measured quantity for the purposes of compliance evaluation is considered o be zero. Values that report below quantitation,level shall be deemed to be in compliance. 0,-A bell �l✓�f�� �2� Idl$942��� ► ql�� fc)14 c.6, fi_ alio Mall Low ,Z)OC-)1 10149 ch2&I �,d ��°2� �siqLhw ke—v� 2CY�s4jj & C0/ C °�. cxC).-), cia 0e- = 7,tl"c -t, /4' ca,�q A l� 9 , DENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NC0003875 BACKGROUND Occidental Chemical's Castle Hayne plant is the second largest producer of chromium based chemicals in the world; the major product at the facility is sodium dichromate. Process wastewater is discharged through outfall 001 and consists of groundwater remediation water, reject residue from the pH adjustment unit and recycle residue. Domestic wastewater is discharged through outfall 002; both outfalls discharge to the Northeast Cape Fear River. Outfall 003, which was used for the discharge of vehicle wastewater, was eliminated during this permit period. Waste sludge is disposed as slurry and sent to a quarry permitted under non -discharge permit WQ0001492. The domestic sludge is land applied under WQ000783. The facility has been issued one Authorization to Construct (ATC) in 2001 for the use of sulfur dioxide as an alternative reducing agent instead of spent pickle liquor. Instream Monitoring and Verification of Existing Conditions and DMR Data Review: This facility discharges to the Northeast Cape Fear River (classified B-Sw) in subbasin 03-06-23. As a member of the Lower Cape Fear monitoring coalition, the instream monitoring requirements have been waived. There is no appropriate upstream monitoring station on the Northeast Cape Fear, but data from station NCF117 was used to assess downstream impacts of the discharge. Available data was culled from the Coalition's water quality reports and shows most of the monitored parameters (temperature, turbidity, chlorophyll a, BOD, etc.) to be within acceptable ranges. There are a few data points for fecal coliform that approach or exceed 200 CFU/100 mL, but most data are below 100 CFU/100 mL. BOD and nutrient levels are fairly low. Fara Sheet NPDES NCO003875 Renewal Pa -e 1 Facllity I rmation Applicant/Facil ty' Name: _ Occidental Chemical Co oration — Castle Hayne Plant A licant Address: 5408 Holly Shelter Road; Castle Hayne, North Carolina 28249 Facility Address. 5408 Holly Shelter Road; Castle Hayne, North Carolina 28249 Permitted Flow`, 0.785 MGD (001) and 0.020MGD (002) T 00 of Waste: Industrial (001) and domestic (002) Facility/Permit Status:.; Class I (physical chemical) and Class II (biological)/Active; Renewal Primary SIC Code: 2819 Count New Hanover County Aseellaneous Receiving Stream:. Northeast Cape Regional Office: `Wilmington (WiRO) Fear River Stream Classification: B -Swamp State Grid / USGS Quad: J27NE/1\400retown, NC 303(d) listed., _ No Permit Writer: Natalie V. Sierra Subbasm 03-06-23 Date:. 14November0l Drainage Area- (iru2)`. " 1426 -,,,1 Summer7Q10.(cfs) 25 '�` l ffi. Winter7Q10„(cfs). 90 =���` �` `W ��.. 30Q2 (cfs) 150 �. ` Avera e "Flow (efs),: 1800 ... IWC (°Io} 4.6 001: Lat. 34° 22' 34” N Long. 77° 51' 55" W 002: Lat. 341 22' 34" N Long. 77° 51' 55" W BACKGROUND Occidental Chemical's Castle Hayne plant is the second largest producer of chromium based chemicals in the world; the major product at the facility is sodium dichromate. Process wastewater is discharged through outfall 001 and consists of groundwater remediation water, reject residue from the pH adjustment unit and recycle residue. Domestic wastewater is discharged through outfall 002; both outfalls discharge to the Northeast Cape Fear River. Outfall 003, which was used for the discharge of vehicle wastewater, was eliminated during this permit period. Waste sludge is disposed as slurry and sent to a quarry permitted under non -discharge permit WQ0001492. The domestic sludge is land applied under WQ000783. The facility has been issued one Authorization to Construct (ATC) in 2001 for the use of sulfur dioxide as an alternative reducing agent instead of spent pickle liquor. Instream Monitoring and Verification of Existing Conditions and DMR Data Review: This facility discharges to the Northeast Cape Fear River (classified B-Sw) in subbasin 03-06-23. As a member of the Lower Cape Fear monitoring coalition, the instream monitoring requirements have been waived. There is no appropriate upstream monitoring station on the Northeast Cape Fear, but data from station NCF117 was used to assess downstream impacts of the discharge. Available data was culled from the Coalition's water quality reports and shows most of the monitored parameters (temperature, turbidity, chlorophyll a, BOD, etc.) to be within acceptable ranges. There are a few data points for fecal coliform that approach or exceed 200 CFU/100 mL, but most data are below 100 CFU/100 mL. BOD and nutrient levels are fairly low. Fara Sheet NPDES NCO003875 Renewal Pa -e 1 Review of "Assessment of Balanced and Indigenous Populations in Belews Lake" Fisheries data: 1. Tables 4.2 and 4.3 compare 10 uplake sites with 10 downlake sites. What is -needed is to compare 10 uplake sites with 5 mid -lake sites (Site Nos. 1-5) and with 5 downlake (below old ash pond discharge) sites (Site Nos. 6-10). 2. Was the 2001 sampling conducted? If so, how did it compare to earlier data? If it was not conducted, then it is not appropriate to reduce monitoring to every two years (page 4-4) prior to our review of the 1994 - 2001 data. We would have to wait to see what the 2001 data look like before committing to a reduction in the monitoring program. We request that Duke analyze and summarize the 2001 data. Benthic macroinvertebrate data: This information is very hard to evaluate without more detailed information on study sites and sampling techniques. Since there are no standards/criteria given for a "balanced indigenous" benthic community in a piedmont lake, the whole process is meaningless without adequate control sites. There are no comparisons with other lakes and the limited within -lake comparisons are flawed. 1. There seem to only 3 sites (sampled once per year) to evaluate lake benthos. Why are there no samples taken from the discharge basin (above the canal). This should be the hottest part of the lake, and an area where there might be an interaction with selenium? Why is there no station near the old ash basin discharge? 2. It is not clear how samples were collected, other than that they were taken with ponar grabs. What is the depth of sampling? Was an attempt made to sample similar depths and -substrates at each site? 3. It is difficult to follow any changes over time with the present format of the tables. If we are looking for recovery, then we should follow a single site over time. 4. If we want to look at changes over time, then some comparison with the many "Weiss et al." reports should be consulted for some idea of invertebrate populations prior to the selenium impact. We would hope that Duke still has these reports on file. 5. It would appear that these Duke Power lake sites are not comparable. The "uplake" sample is dominated by Chaoborus, suggesting that samples were taken below the thermocline in a stratified area, while other samples appear to be above the thermocline. This negates the within -lake comparison used to deduce no impact. 6. While there seems to be some agreement that selenium levels are elevated, there is no comparison with literature values to determine if these levels are dangerous. Fish Tissue Data: 1. Biomass declines were noticeable in common carp during 1999-2000. The declines were attributed to natural mortality and poor recruitment, but selenium levels were reported as being highest in this species during the same time period. What data or observations are there that suggests that the carp decline is purely "natural" . I agree that close monitoring should continue to determine if selenium is being mobilized from sediments to the food chain or by benthic disturbances from a species like carp. 2. Close annual monitoring of the Dan River. is also warranted to determine if increases in selenium in catfish, suckers, and some sunfish continues. BELEWS CREEK STEAM STATION' 0&1 20 . mSELENIUM DATE 15 0 DAILY LIMIT XWQ S M 10 5 --xxxxxM XMW XRX Pxxx xxxxx,x w xx>oocg xxxx XXXORX xmxxxx w xxx>wx xxxx xxxxw XX>(NXX )m xx xx EME ■ 0 . . ..... LU C14 C-4 c)) 0) NN 0-5 Cr) 04 N CN 0) 0) a) CN 0) Cr) M 0-) (3) Cf) C7 CO 0) 0) 0) Cy) Cr) 0) Ce) CY) 't '9T M (M 0) M 0) (3) 0) 0) r a) Lr) 0) U-) Ocy) cq 04 Lo C) Q M co C) -- T- Mcf) 00 M (D Q G) r— C) ct) co 00 T- r- 'gr o t- M M T-- a). ce) (o 0) C) 04 c1r) -t-- V- N Lo cc) T- N 04 C f) DATE O DATE 2/11/92 3/28/92 5/13/92 6/28/92 8/13/92 9/28/92 11/13/92 12/29/92 2/13/93 3/31/93 5/16/93 7/1/93 n 8/16/93 m 10/1/93 11/16/93 1/1/94 2/16/94 4/3/94 5/19/94 7/4/94 8/19/94 10/4/94 11/19/94 1/4/95 2/19/95 4/6/95 SELENIUM (UG/1) � --► N N CTi O CT O C n v D Z m X cn --I m D cn D —I O Z o - co Mm m m D v D Z m X cn --I m D cn D —I O Z " 1y Puke Power® A Duke Energy Company August 20, 2001 Mr. Charles H. Weaver, Jr. State of North Carolina Department of Environment and Natural Resources Division of Water Quality NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1646 Subject: Duke Power — NPDES Permit Modification Belews Creek Steam Station - #NC0024406 Record #: DP -005157 Certified: 7000 1670 0001 5510 0340 Dear Mr. Weaver: Duke Power Group Environment, Health & Safety MG03A5 13339 Hagers Ferry Road Huntersville, NC 28078-7929 Duke Energy requests the subject permit be renewed and reissued. The above referenced permit expires February 28, 2002. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105 (e), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the renewal application, which includes the following items: EPA Form 1 EPA Form 2C — including Priority Pollutant Analysis Site Map Water Flow Diagram Supplemental Information Duke Energy requests notification that this application is complete. The following monitoring reductions at outfall #003 are requested based on historical monitoring data, which are attached. The frequencies were determined using the EPA guidelines for "Performance -Based Reduction of Monitoring Frequencies." The suggested methodology changes are based on the Steam Effluent Guideline in 40 CFR 423.12. 1 CZ) < Cv O� W Q a_ ^�- GJ G Duke Energy requests the subject permit be renewed and reissued. The above referenced permit expires February 28, 2002. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105 (e), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the renewal application, which includes the following items: EPA Form 1 EPA Form 2C — including Priority Pollutant Analysis Site Map Water Flow Diagram Supplemental Information Duke Energy requests notification that this application is complete. The following monitoring reductions at outfall #003 are requested based on historical monitoring data, which are attached. The frequencies were determined using the EPA guidelines for "Performance -Based Reduction of Monitoring Frequencies." The suggested methodology changes are based on the Steam Effluent Guideline in 40 CFR 423.12. • Reduction of monitoring of Total Iron and Total Copper from monthly to occurrence of a chemical metal cleaning. • Change Oil and Grease from a mass based to a concentration based limit, ea--�i e,-`7� reduce sampling frequency from monthly to once/per six months.�6„ • Change Total Suspended Solids from a mass based to a concentration -�- based limit, reduce sampling frequency from monthly to once/per six C rY �6I months. • Reduction of Total Arsenic from monthly to once/per six months. • Reduction of Sulfates from monthly to once/per six months. • Reduction of Fluoride from monthly to once/per six months. • Reduction of pH from twice/month to once/month. Duke Energy also requests that the definitions in the Special Conditions of this permit (see Part III.J.,K.) be revised as to read as follows: The term "metal cleaning waste" means any wastewater resulting from cleaning (with or without chemical cleaning componds) any metal process equipment including, but not limited to, boiler tube cleaning, boiler fireside cleaning, and air preheater cleaning. The term "chemical metal cleaning waste" means any wastewater resulting from the cleaning of any metal process equipment with chemical componds, including, but not limited to, boiler tube cleaning. Chemical metal cleaning will be conducted according to approved Duke Power equivalency demonstration. Thank you in advance for your assistance on this matter. Should you have questions regarding this application, please contact Allen Stowe at (704) 875-4655. Sincerely, i Michael A. Ruhe Manager, Water Compliance Group Environment, Health and Safety jas/bcsscovperappl 5a(o S, Cti-ti-S-l S k Monitoring Reductions Belews Creek Monitoring data June 1999 — May 2001 Attachment Parameters pH O&G TSS Arsenic Sulfates Fluoride Units SU Lbs/Day Lbs/Day ug/1 mg/1 mg/1 Permit or WQ Limits 6.0-9.0 989.0 1978.0 50.0 250 1.8 Average Effluent NA 16.4 103.6 10.4 41.3 0.3 Number of Measurements 107 24 24 24 24 24 * Ratio NA 1.7 5.2 20.8 16.5 16.7 *The ratio equals the long-term effluent average to the monthly average (or Water Quality) limit. Based on Table 1 of EPA's " Interim Guidance for Performance -Based Reduction of NPDES Permit Monitoring Frequencies" the following reductions are requested. • All parameters (except pH) ratio of effluent concentration to monthly average are less than 25 percent. Therefore a reduction from monthly to twice per year is requested. • A reduction for pH from twice per month to once per month is requested based on compliance history. 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Yr/✓' •7-�`_t ,:(r % C, ,! .,: 8005' 8004'30" 8004' 8003'30" 8003' 8002'30' 0 0.5 1 Kilometers N 0 0.5 1 Miles CONTOUR INTERVAL 20 FEET 00 0 W '0 0 OD W 0 W 0 W 0) 0 TWT V/ 0 0 W 0 0 Belews Creek Steam Station 0.35 mgd Intake Screen D BW m E N O 0 Belews Lake Station Intake Area Station Equip Cooling Water Condenser Cooling Water Water Treatment Ash Sluice Belews Creek Steam Station, Stokes County NPDES Permit # NCO024406 Page 1 of 1 pressure Cooler service water S stem Outfall 001 1056 mgd 0.08_ Belews Lake RCW Cooler mgd Stormwater Coal Yard Sumps 0.7 mgd Power House 3.85 Yard Holding 4.15 mgd Sump mgd Sump Condenser Outfall Feedwater 006 Ash Basin 0.03 mgd Chemical Holding Pond L_....= 0.019 mgd 0.44 mgd West Holding Pump Stormwater Outfall 003 -* Dan River 7.7 mgd Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 2 of 10 General Information Belews Creek (BC) Steam Station is a coal-fired electric generating plant operated by Duke Energy Corporation. BC is located on Belews Lake at NC County Road 1908 approximately eight miles northeast of Walnut Cove, NC in Stokes County. A schematic flow diagram of water use, treatment, and discharge is attached. A brief discussion of the individual waste streams follows. OUTFALL 001 — CONDENSER COOLING WATER (CCWJ Raw water from Belews Lake is passed through condensers and auxiliary equipment on a..'once- through" basis to cool equipment and condense exhaust steam from the turbines. Cooling water passes through a network of tubes in the condenser and selected heat exchangers (e.g., turbine lube oil coolers, condensate coolers, and miscellaneous closed system coolers). This raw water in the condenser tubes absorbs heat from a closed system of highly purified exhaust steam from the turbines and converts it back to water. The condensed exhaust steam is returned to the boilers and recycled in this loop a number of times. The raw cooling water is returned to the lake. No chemicals are added and only heat rejected from the condensers and auxiliary equipment is absorbed, hence the term 'once through, non -contact cooling water" is applied. The condensers at BC are cleaned mechanically. Normally, amertap balls clean the tubes on a continuous basis while the plant is operating. Periodically, metal scrapers, plastic scrapers or rubber plugs are forced through the tubes to rid them of scale or other deposits. Each unit at BC has four condenser cooling water (CCW) pumps. Pump capacities are listed in the table below. Normal plant operation of the CCW pumps is based on intake and discharge temperatures and unit load. The maximum pumping capacity is 1459 mgd and the average CCW flow is 1300 mgd. To avoid a system trip that would suddenly reduce the discharge flow at outfall 001, each unit is on an independent system. This practice leads to higher reliability factor for the units and protection of aquatic life taking refuge in the discharge canal during cold weather. yF a 'n ''k�.✓` ,:ii No. of Pumps In Operation F..R : �. #X :d.R t f ,. �.. ..:..n a Total Flow (gpm) fx 1 S"^` „i, ¢ .,� .+......o....exw..zw .. � u Intake Temperature (°F) 1 184,000 2 333,000 <61 3 444,000 61-69 4 506,000 >69 Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 3 of 10 Intake Screen Backwash Each unit has 4 stationary intake screens (18 ft x 23 ft) which are removed for cleaning. The intake screens are backwashed as needed at a rate of 500 gpm for approximately five minutes each. The total volume of water used is 0.02 mgd. This intake screen backwash is discharged back into the station intake. The debris is collected within a cleaning basin and consists mainly of twigs, leaves, and other material indigenous to Belews Lake. The collected debris is removed and composted. Recirculated Cooling Water (RCW) Coolers Depending on the temperature of the raw lake water and the operation of BC, once through non - contact condenser cooling water is passed through the RCW coolers to maintain the closed loop cooling water within the RCW system at <95°F. The RCW system supplies cooling water to various equipment and is composed of a storage tank, three 50% capacity RCW pumps, two 100% capacity heat exchangers (RCW coolers), and associated piping and valves for the two units. Recirculated cooling water is supplied from the CCW system to the RCW storage tank (capacity of 19,000 gallons) and makeup water is added, as required per tank level and temperature controls. _ The maximum flow of CCW through each of the two RCW coolers is 5360 gpm or 7.72 mgd. Non - contact cooling water discharged from the RCW coolers combines with the condenser cooling water and is discharged from outfall 001. Hydrogen and Oil Coolers Once through non -contact cooling water is supplied from the Low Pressure Service Water System that draws water from the CCW system to hydrogen and oil coolers. The system consists of two High Pressure Generator Hydrogen Coolers (maximum combined flow of 3,990 gpm), four Low Pressure Generator Hydrogen Coolers (maximum combined flow of 3520 gpm), and two Turbine Lube Oil Coolers (maximum combined flow of 7400 gpm) for each unit. A maximum of 43.0 mgd of cooling water can flow through these coolers when both BC units are operated at full load. Discharge from these coolers combines with the condenser cooling water flow and discharged at outfall 001. Station Equipment Cooling Water Once through non -contact cooling water is supplied from the Low and High Pressure Service Water System to the bearings of the induced draft (ID) fans to remove excess heat. No chemicals are added to the once through raw lake water discharged to Belews Lake. The rate of flow through the control equipment is approximately 0.86 mgd when both BC units are operated at full load. This effluent also includes chiller once through water. OUTFALL 003 - ASH BASIN The ash basin accommodates flows from the power house sumps, yard holding sump, ash sluice lines, the chemical holding pond, the coal yard sumps, and rainfall run-off from the watershed of the basin. Seepage from the toe -drains at the base of the ash basin dikes goes to the Dan River. The toe -drains are needed to allow, as designed, seepage to occur from the earthen dikes. This feature ensures the structural integrity of the dikes. Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 4 of 10 Yard Holding Sump Waste can accumulate in the yard holding sump from the power house sumps, the condenser feedwater system, and the coal yard sumps. During a boiler cleaning, these wastes accumulate in the yard holding sump and are then pumped to the chemical holding pond (Outfall oo6). Power House Sumps The Power House Sumps discharge to the yard holding sump and include wastewater from water treatment equipment, floor wash water, equipment cooling water, and miscellaneous leaks. The Power House Sump receives wastes from the following systems: • Water Treatment System The water treatment system consists of one retention tank, two pressure filters (diatomaceous earth), two activated carbon filters, and one set of makeup demineralizers. The pressure filters each have a capacity of 500 gpm. Filters are backwashed weekly with`approximately 220 lbs of diatomaceous earth going to Station sumps that discharge to the ash basin. Make up demineralizers are operated in sequence (one cell at a time). Regeneration of these cells is required approximately every other day. Each regeneration requires 60 gallons of 660 Be sulfuric acid and 300 gallons of 50% sodium hydroxide. An average dilute waste chemical and rinse flow of 0.17 mgd is realized (for one hour per regeneration). The diluted acid and caustic are discharged to the yard holding sump and then pumped to the ash basin. The useful life of the resin varies and when replacement is needed the spent resin is sluiced to the ash basin. • Condensate Feedwater System The condensate feedwater system provides continuous flow-through boiler feedwater to BC supercritical pressure boilers. Condensate polishing demineralizers of the powdered resin type are used to filter feedwater. The mixed anion -cation powdered resin provides filtering and ion exchange. Spent resins and associated wastes are pumped to the ash basin for treatment and disposal. • Evaporative Losses, Soot Blowing Exhaust steam from the turbine is used periodically to blow soot off the outside of the boiler tubes. Thus, some of the condensate feedwater is evaporated in the boiler. • Turbine and Boiler Room Drain System Turbine and boiler room drains receive flow from once through non -contact cooling water of the Station air conditioning system, the fire protection system, washdown, and miscellaneous Station uses: Station Air Conditioning Once through non -contact cooling water is supplied from the Low Pressure Service Water System to cool the Station air conditioning equipment. A maximum combined flow of 3.46 mgd of cooling water can flow through two chiller units. No chemicals are added to the once through raw lake water. The effluent drains to the Station sumps where it is pumped to the ash basin. Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 5 of 10 • Fire Protection, Washdown, and Miscellaneous Station uses The fire protection system, washdown, and miscellaneous station uses from closed system drainage, cleaning, and testing can contain: Corrosion inhibitors, (e.g., Calgon CS, Biocides, Calgon H-300 and H-510) Laboratory wastes Cleanings (e.g., small heat exchangers) Dispersant (e.g., polyacrylamide) Wetting agent (e.g., sodium lauryl sulfate) Detergent (e.g., tri -sodium phosphate) Leak testing (e.g., disodium fluorescing dye) Miscellaneous system leakage (pump packings and seals, valve seals, pipe connections) Moisture separators on air compressor precipitators Floor wash water Emergency fire fighting water and foaming agent Ash sluice system overflow Low Volume Wastewater. Groundwater (GW) Remediation A GW remediation is presently underway to recover free petroleum product that leaked from a underground storage tank. A total fluids recovery system is used to recover contaminated groundwater and free,product from the site. Remediation system equipment is used to remove the petroleum from the recovered groundwater, and the reclaimed petroleum is transported off-site for treatment while the treated wastewater is discharged to the ash basin via the power house sump. A maximum flow rate of approximately 0.03 mgd is discharged to the ash basin from the groundwater remediation system. Ash Sluice Electrostatic precipitators are used to remove fly ash from the stack gases. The ash is treated in the flue gas ductwork with S03 conditioning to improve removal efficiency. Typically, the dry -fly ash captured in these precipitators is collected in temporary storage silos for subsequent disposal in a permitted on-site landfill or for recycling in off-site ash utilization projects. If the system that collects the dry -fly ash is not operating, then the fly ash can be sluiced to the ash basin. Bottom ash from the boilers is usually water sluiced to holding cells for recycling activities per reuse permit #WQ0007211. In the case of equipment failure or immediately following an outage, service water is used to sluice the bottom ash to the ash basin. Electrostatic precipitators are normally cleaned by mechanically rapping the wires and the plates inside the precipitator. Before major precipitator work is performed they are cleaned by a wash down. The wash water is pumped to the ash basin from the yard drain sumps. Additional air pollution control devices may potentially be installed. Use of this equipment may entail use of or production of: calcium sulfite, ammonia, ammonia hydroxide, vanadium pentoxide, calcium carbonate and sulfur. Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 6 of 10 Coal Yard Sumps The coal yard covers approximately 51.5 acres. The average rainfall run-off is 0.08 mgd. This run- off is based on 40 inches of rain per year with 50% run-off. During winter, freeze conditioning agents (i.e., diethylene glycol) maybe added to coal by a vendor prior to shipment or sprayed on the coal pile to prevent freezing. A small percentage of a coal binder may potentially be added to the coal in the future. An on-site coal binder production facility is also being contemplated. Based on an application rate of two pints of 50 ppm diethylene glycol per ton of coal and 10,000 tons of coal per train load, the addition of freezing agents will not significantly alter the coal pile run-off wastestream and the discharge of the ash basin at outfall 003. Most of the coal yard drains into the ash basin near the point of ash influent. Floor washwater from equipment in the coal handling area and the remaining drainage from the coal yard flows to the coal yard sumps where it is then pumped to the ash basin. Ash Basin Run -Off Non -point sources of storm water to the ash basin include coal pile runoff and landfill. Based on forty inches of rain per year with fifty percent run-off, and the watershed area of the ash basin, the yearly average rainfall run-off to the ash basin is 0.47 mgd. OUTFALL 006 Boiler and Filter Cleaning Wastes BC has two supercritical boilers that are cleaned on an as needed basis. Tube inspections are done during outages to determine when cleaning is needed. The chemical cleaning wastes are pumped to the chemical holding pond. After proper treatment, the pond effluent is discharged into the ash basin at a controlled rate to provide further treatment. The chemicals and approximate amounts for one boiler cleaning is as follows: Boiler Cleaning Chemicals Amount Per Unit Hydroxyacetic acid 22,400 lbs Formic Acid* 11,200 lbs Ammonium Hydroxide*(260Be') 250 gal Ammonium Bifluoride* 2,800 lbs Hydrazine (54.4%)* 150 gal Corrosion Inhibitor* (Proprietary) 500 lbs * These chemicals are present in amounts greater than the reportable quantity as identified under CERCLA. If a spill of any of these chemicals were to occur, in most cases, the spill would be routed to the ash basin for treatment. These chemicals are being identified to qualify for the spill reporting exemption provided under 40 CFR 117 and CERCLA. * Hazardous substance as listed in 40 CFR 302.4 Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 7 of 10 Two auxiliary boilers are cleaned with an alkaline boilout. These cleanings are done on an infrequent basis. The alkaline cleaning wastes are pumped to the ash basin. Chemicals and approximate quantities for one auxiliary boiler alkaline boilout is listed below: ALKALINE BOILOUTS (ONLY AFTER MAJOR BOILER TUBE WORK Chemical Amount Soda Ash 300 Ib Triton X-100 Detergent (0.05%) 2 gal Antifoam Agent (0.025%) 1.5 gal The condensate polisher filters and filtered water system filter are cleaned with citric acid and sodium hydrosulfite on an as needed basis. The chemical and approximate quantity used per year for this cleaning are listed below: Chemical Amount Citric acid 600 lbs Sodium Hydrosulfite 15,000 lbs Sanitary Spray Irrigation System Sanitary waste is pumped to a spray irrigation system per permit #WQ0005873. The sanitary waste from the plant receives primary treatment in a 600,000 gallon capacity aerated lagoon. Drawoffs from the lagoon discharge to a concrete chlorine contact chamber. To polish the effluent, the spray irrigation system routes a circuit of water treated with chlorine over approximately seven acres of land divided into four vegetated plots, each with an area of 270 square feet. The yearly loading per plot averaged approximately 6.26 inches/acre. Storm Water Non -point sources of storm water to the yard drainage system is based on forty inches of rain per year with fifty percent run-off, and the yard watershed area, the yearly average rainfall run-off to Belews Lake is 0.08 mgd. • Yard Drainage to Intake Canal • Yard Drainage to Discharge Canal. BC has several storm water outfalls that discharge to the Dan River or Belews Lake. BC was included in the group application submitted to the Environmental Protection Agency in March 1991. Spill Prevention BC has one large above ground oil storage tank (260,000 gals). A dirt dike designed to contain the entire contents of the tank in the event of an accidental rupture surrounds this tank. All oil storage facilities are covered under the BC Spill Prevention Control and Countermeasure Plan. N Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 8 of 10 Hazardous and Toxic Substances Table 2c- 3: At Belews Creek Steam Station, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V -D of Form 2-C, the substances identified under Table 2c-3 that. may be in the discharge are as follows: Acetaldehyde, Asbestos, Benzoyl Chloride, Butyl Acetate, Cresol, Cyclohexane, Cyclohexanone, Epichlorohydrin, Formaldehyde, Furfural, Monoethyamine, Naphthenic Acid, Pyethrins, Stryrene, Triethanolamine, Vanadium, Vinyl Acetate, Xylene, and Zirconimum and also during the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will impact the toxicity limits of the ash basin since these concentrations are extremely low. 40 CFR 117 and CERCLA Hazardous Substances: The table below identifies hazardous substances located on-site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on-site that could be released at one time and sent to the ash basin. They do not reflect quantities that are discharged through typical use. CHEMICAL AMOUNT (Ibs) SOURCE Ammonia 7,421 General Site Benzene 834 Gasoline Tank Dibutyl Phthalate 22 Warehouse Mercuric Nitrate 10 Warehouse Methylenebisphenyl isocyanate 6,398 Flyash Dome Sodium 10 Warehouse Sodium Dodecylbenzenesulfonate 3,803 Coal Handling Area Sodium Hydroxide 25,520 Water Treatment Room Sodium Nitrite 924 Ash Landfill Sulfuric Acid 61,228 Water Treatment Room Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 9 of 10 Belews Lake Balanced and Indigenous Populations The attached report entitled, "Assessment of Balanced Indigenous Populations in Belews Lake Near Belews Creek Steam Station", indicates balanced and indigenous populations are recovering. Recovery of populations in Belews Lake is associated with a decrease of selenium bioaccumulation in populations of Belews Lake, following installation of a system to collect and landfill dry -fly ash in 1984 and reroute of the ash basin discharge from Belews Lake to the Dan River in 1985. The fish eating advisory on Belews Lake was recently lifted by the North Carolina Department of Environment, Health and Natural Resources. Duke Power continues to maintain an environmental monitoring program on Belews Lake and the Dan River to assess populations. Annual summary reports of environmental monitoring of the Dan River per Part III.S of the present NPDES permit indicates that reroute of the ash basin discharge from Belews Lake to the Dan River has had no adverse impact on the balanced and indigenous populations in the Dan River. Duke Power Company's operating experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC#0024406 substantiates for Belews Creek Steam Station that the "thermal component of the discharge assures the protection and propagation of shellfish, fish and wildlife in and on the receiving body of water." Per Part III.Q of the present permit, Duke Energy requests that the thermal monitoring and reporting requirements for lake samples be reduced to monitoring only at the present site downstream of the Dam. Ash Basin Capacity Part III Section R of the existing NPDES permit for BC requires the permittee to provide and maintain at all times a minimum free water volume (between the top of the sediment level and the minimum discharge elevation) equivalent to the sum of the maximum 24 hour plant discharges plus all direct rainfall and all runoff flows to the pond resulting from a 10 year, 24 hour rainfall event, when using a runoff coefficient of 1.0. Determination of Wet Weather Detention Volume: Wet Weather Detention Volume is the sum of the runoff accumulated in the ash basin which results from a 10 -yr 24 -hr storm (assuming 100% runoff) plus the maximum 24 -hr dry weather waste stream which discharges to the Ash Basin (refer to NPDES Permit NC0024406). I. Estimate Runoff to the Ash Basin from a 10 -yr 24 -hr storm: 1. Natural Drainage Area of Ash Basin = 655.0 Acres Station Yard Drainage Area Pumped to Ash Basin = 87.6 Acres Total = 742.6 Acres 2. Precipitation from 10 -yr 24 -hr storm = 5.1 Inches 3. Total Stormwater Runoff to Ash Basin = 315.61 Acre-feet (Assuming 100% runoff) IV Belews Creek Steam Station, Stokes County NPDES Permit #NC0024406 Page 10 of 10 Estimated Maximum 24 -hr Dry Weather Waste Stream Discharging to Ash Basin: 1. Maximum recorded Ash Basin Discharge = 2. Increase maximum daily discharge by 10% for conservatism and convert units to acre-feet = Wet Weather Detention Volume: Sum of Parts I. and II. _ 17,900,000 Gallons/day 60.42 Acre-feet 376.03 Acre-feet Estimated quantity of solids (ash) to be discharged to the Ash Basin through 2006. (Refer to Coal Consumption Data and ENPRO EN9706F1 Output - Base Fuel Consumption Forecast.) Time Period Esti. Total Ash Production (1000's tons) Esti. Fly Ash Utilization (1000's tons) Esti. Bottom Ash Utilization (1000's tons) Fly Ash Disposal to Landfill (1000's tons) Esti.Total Ash Sluiced to Basin (1000's tons) Esti.Total Ash Sluiced to Basin (acre -ft) 11/93 - 12/93 83.7 42.67 2.21 32.72 6.10 5.10 1994 495.10 290.76 18.86 154.83 30.65 25.59 1995 426.80 317.64 17.41 28.73 63.02 52.61 1996 466.10 361.50 8.72 41.29 54.59 45.57 1997 544.78 369.38 30.85 108.32 36.23 30.24 1998 563.94 393.41 22.08 82.65 65.80 54.93 1999 594.73 384.05 4.20 120.75 85.73 71.57 2000 517.42 336.73 12.57 158.21 9.91 8.27 1/01 -6/01 294.75 143.15 6.13 100.69 44.78 37.38 7/01-12/01 208.36 168.77 15.00 18.75 5.84 4.88 2002 422.33 375.00 30.00 5.10 12.23 10.21 2003 534.30 375.00 30.00 105.87 23.43 19.56 2004 544.50 375.00 30.00 115.05 24.45 20.41 2005 544.50 375.00 30.00 115.05 24.45 20.41 2006 544.50 375.00 30.00 115.05 24.45 20.41 2007 544.50 375.00 30.00 115.05 24.45 20.41 Total 7330.31 5058.06 318.03 1418.11 536.11 447.54 • Calculation assumes an in-place ash density of 55 lbs. per cubic foot. • ** Assumes 25% of yearly projection is consumed in January and February. Estimated Total Storage Volume Required for through 2007: Wet Weather Detention Volume = 376.0 Acre-feet Estimated Solids to Ash Basin = 447.5 Acre-feet Total = 823.6 Acre-feet Result: Available Storage based on most recent basin survey dated 11/3/93 and pond level at elevation 752+0 = 3876 Acre-feet Required Storage Volume through 2007: 823.6 Acre-feet Based on these calculations, there is sufficient capacity in the ash basin to provide the retention volume specified in the permit through the year 2007. c WATF I� Michael F. Easley �U QG D. Governor [51William1P G. Ross, Jr., Secretary Department of Environment and Natural Resources O C / Kerr T. Stevens, Director ' Division of Water Quality n C5,1J l! January 29, 2001 Mr. Michael A. Ruhe Manager, Water Compliance Duke Power - 00— 0\4qgo 1n 339 Hagers Ferry Road Huntersville, N C 28078-7929 e 5'.1 � x01l v (Z- biet') Dear Mr. Ruhe: � 4m1 'Dw� I We have received the McGuire Nuclear Station, Lake Norman: 1999 Summary Report, Environmental Monitoring Program as required by NPDES permit, and the Belews Creek Steam Station, 1999 Dan River Summary Report as required by NPDES permit. We have no comments on the Lake Norman report as conditions appear similar to prior years. In the Belews Creek report, Dave Lenat comments that the between -year changes in benthic macroinvertebrate data should be interpreted in relation to flow. Much of the variation can probably be explained in this way, otherwise the low number of EPT taxa collected at both locations is alarming. Concern is also raised by the higher selenium values found in the tissue of sunfish at locations 720 and 705 downstream of the plant, and by the continuedincrease of these values since 1997, regardless of the fact that they are below the. levels found during the failure of the fishery in Belews Lake in the 1970s. The same increasing trend is not found at location 710 above the plant. Our concern is further intensified by a similar pattern in' elenium concentrations of the invertebrates, where the difference in upstream and downstream concentrations was much greater than had been found previously. As noted in your report, such concentrations have been reported by some in the scientific literature as cause for concern. DWQ would recommend a meeting between DWQ and your staff to discuss possible reasons for the downstream increase, unless the 2000 data is available and it does .not show the same increasing trend. Please contact Mark Hale (919-733-6946) to set up a meeting or to provide him the 2000 fish tissue and invertebrate data. c Please also note that pages 3-1 through 3-6 of the Belews Creek report were duplicated in all three copies. Please contact Jimmie Overton (919-733-9960) if you have other questions about these comments or would like to discuss further the need to meet about the Belews Creek Steam Station discharge to the Dan River. Sincerely, Coleen Sullins U Water Quality Section Chief cc: Mark Haled FEB ' 5 2001 Jimmie Overton Rex Gleason, MRO w/ Lake Norman rpt Larry Coble, WSRO w/ Dan River rpt DEi R _ 01 -ER QU6,1.11Y SOII'R E� BRANCH NA `JTDE".:{ Customer Service 1 800 623-7748 Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 (919) 733-7015 i Duke Power A Dvk, E-W C mpa ry - October 29, 1999 NC Dept of Environment and Natural Resources Division of Water Quality Attention: Central Files 1617 Mail Service Center Raleigh, NC 27699-1617 Duke Power Group Environment, Health & Safety 13339 Hagers Ferry Road Huntersville, NC 28078-7929 U NOV ��SRR �uA�iGH Po��RCE "sou aR Subject: Duke Power Company NPDES Discharge Monitoring Report for: Allen Steam Station - NC0004979 - Gaston County Belews Creek Steam Station - NC0024406 - Stokes County Buck Steam Station - NC0004774 - Rowan County Cliffside Steam Station - NC0005088 - Rutherford County Dan River Steam Station - NC0003468 - Rockingham County Lincoln Combustion Turbine Station - NC0080781 - Lincoln County Marshall Steep Station - NC0004987 - Catawba County McGuire Nuclear Station - NC0024392 - Mecklenburg County Riverbend Steam Station - NC0004961 - Gaston County Record No. NC -004992 CERTIFIED: Z 335 554 736 In accordance with Part II, C(2) of the above referenced NPDES permits, duplicate copies of the monthly monitoring report for September 1999 are attached. At Belews Creek Steam Station, the six-month monitoring requirement of Toluene and Benzene has been completed and concentrations were below the detection level. Therefore, monitoring will be discontinued per agreement with NCDENR. e All values reported on the attached reports are dependent on the accuracy of approved analytical methods `l,° used to measure parameters. Please direct any correspondence or questions concerning the subject facility NPDES Program to Angela M. Grooms at (704) 875-5205. Very truly yours, Angela M. Grooms Manager, Water Protection AMG/phs Attachments EFFLUENT Page 2 of 2 WOES PERMIT No. N00024406 DISCHARGE NO. 003 MONTH September YEAR 1999 FACILITY NAME Belews Creek Steam Station CLASS 11 COUNTY Stokes OPERATOR IN RESPONSIBLE CHARGE (ORC) Randolph W. Price GRADE 11 PHONE 336-427-0274 CERTIFIED LABORATORIES (1) Duke Power Env. Services - 248 (2) WO OPJGINAL nd ONE COPY to: ATTN: CENTR AL FILES DMSION OF WATER QUALITY DERNR P.0 BOX 29M RALEIGH*. NC 27626-0535 :j �13 ®E Comp- (C) I Grab (G) A Monthly Limit I I I I Facility Status: (Please check one of the following) DEM Form MR -1 MM) All monitoring data and sampling frequencies meet permit requirements Compliant All monitoring data and sampling frequencies do NOT meet permit requirements Normmpifiant See Aftschmsent ry certify, oder penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the Informaboin submitted. Based on my Inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false infonnation, including the possibility of lines and Imprisonment for knowing violations." Angela M. Grooms AI�"Aov�— IOLL+ Peffnittee (Please print or type) Signature R Permittee" Date 13339 Hagers Ferry Road (MG03A5) Huntersville, NC 28078-7929 704-8755205 2128/02 Permittee Address Phone Number Permit Exp. Date *ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B). —if signed by otter than the Peffnidee, delegation of signatory authority must be on file with the state per I SA NCAC 28.0506(b)(2)(D). The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting facility's Permit for reporting data. Table 2. Water Quality Data -for'Dan River Sampling Locations Sampled November 28 & 29, 1994 LOCATION, COND. pH ALKALINITY NOTE: SHADED AREAS INDICATES DATA NOT COLLECTED OR AVAILABLE Page 1 SO4 �,�Se Cdj Cu Pb Zn 1UNITS us/ 11 ueq/Lmg/L 1 Ug/L] Ug/L CM SURFACE WATER DATA X LOCATION 1011111.11.11 DRSS INTAKE < 0 207 7.5 530 1.00 < 0.10 2.00 REECE'S LANDING 196 7.4 528 18.4 0.36 < 1.00 NEAR MW9 - 179, 7.5 488 17.8 0.49 < 1.00 < 1.00 < '0.10 < '0.10 2.10 < 2.00 11 NEAR MW10 168 7.4 412 14.7 0.42 < 1.00 < 1.00 < 0.10 1.80 < 2.00 8 NEAR MWI 1 157 7.5 388 14.4 0.77 < 1.00 < 1.00 0.20, 3. 2.80 35 ASH BASIN CONFLUENCE 165 7.4 492 15.2 0.4 < 1.00 IFIELDCREST 171 7.5 654 14.5 0.38 1.00 GROUND -WATER DATA M I M1N9 517 6 16 0.24 < 1.00 3.80 0.31 0.80 2.00 MW10 29 5.2 0.15 1.00 1.70 < 0.10 5.10 < 2.00 Mwi 1 E47 23 4.7 36 2.89 < 1.00 1.00 < 0.10 6.30 8.50 NOTE: SHADED AREAS INDICATES DATA NOT COLLECTED OR AVAILABLE Page 1