NC0004979_Pace Analytical_20161014

0
J
2000 ft
v
A
N

aceAnaljdical
www.pacelabs.com
November 03, 2016
Mr. Pete Harrison
Waterkeeper Alliance
17 Battery Place Ste 1329
Suite 1329
New York, NY 10004
RE: Project: ALN -10/14/2016
Pace Project No.: 92316174
Dear Mr. Harrison:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on October 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Revised Report: Report revised to add requested metal
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
Project Manager
Enclosures
cc: Larissa Liebmann, WaterkeeperAlliance
Q pCCgF�'
`9eORA��.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 19

Pace Analytical Services, LLC
2225 Riverside Dr.
acmnalXical Asheville, NC 28804
www.pacelabs.com
[phone]
CERTIFICATIONS
Project: ALN-10/14/2016
Pace Project No.: 92316174
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH -0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification M 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity -
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Asheville Certification IDs
2225 Riverside Dfive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Nebraska Certification: NE -OS -28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification M 12710
Oklahoma Certification M D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification M FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification M 9962C
Wisconsin Certification M 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification M 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 19

aceAnalytical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
ALN -10/14/2016
92316174
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92316174001
A -US -1-F
EPA 200.7
SH1
4
PASI-A
EPA 200.7
CKJ
2
PASI-O
Silica Calculation
SH1
1
PASI-A
EPA 200.8
JTJ
14
PASI-O
EPA 245.1
WAB
1
PASI-A
SM 2540C
MJS1
1
PASI-A
EPA 218.7
AEM
1
PASI-O
EPA 300.0
AES2
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 4500-P E
CJH1
1
PASI-A
92316174002
A -US -1-T
EPA 200.7
SH1
4
PASI-A
EPA 200.7
CKJ
2
PASI-O
Silica Calculation
SH1
1
PASI-A
EPA 200.8
JTJ
14
PASI-O
EPA 245.1
WAB
1
PASI-A
SM 2540C
MJS1
1
PASI-A
EPA 218.7
AEM
1
PASI-O
EPA 300.0
AES2
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 4500-P E
CJH1
1
PASI-A
REPORT OF LABORATORY ANALYSIS
. This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 19

aceAnalytical ®
www.pacelabs.com
Project: ALN -10/14/2016
Pace Project No.: 92316174
ANALYTICAL RESULTS
Pace Analytical Services, LLC
Asheville, NC 28804
hevi Riverside 04
[phone]
Sample: A -US -1-F
Lab ID: 92316174001 Collected:
10/14/16 14:24
Received: 10/14/16 16:30 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared
Analyzed
CAS No. Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Boron
1280 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:15
7440-42-8
Calcium
31200 ug/L
100
1
10/18/16 02:30
10/20/16 23:15
7440-70-2
Iron
704 ug/L
50.0
1
10/18/1.6 02:30
10/20/16 23:15
7439-89-6
Silicon
11800 ug/L
500
5
10/18/16 02:30
10/21/16 14:13
7440-21-3
Lithium
ND ug/L
500
1
10/24/16 14:20
10/26/16 09:24
7439-93-2
Manganese
822 ug/L
5.0
1
10/24/16 14:20
10/26/16 09:24
7439-96-5
Silica Calculation
Analytical Method: Silica Calculation
Silica Calculation
25300 ug/L
214
1
10/21/16 17:24
7631-86-9 N2
200.8 MET ICPMS
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8
Aluminum
ND ug/L
10.0
1
10/24/1614:20
10/26/1612:02
7429-90-5
Antimony
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-36-0
Arsenic
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-38-2
Barium
53.1 ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-39-3
Beryllium
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:02
7440-41-7
Cadmium
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:02
7440-43-9
Chromium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-47-3
Cobalt
7.2 ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-48-4
Lead
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7439-92-1
Molybdenum
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7439-98-7
Selenium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7782-49-2
Strontium
223 ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-24-6
Thallium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-28-0
Vanadium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:02
7440-62-2
245.1 Mercury
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 I
Mercury
ND ug/L
0.20
1
10/18/16 06:10
10/19/16 13:01
7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
206 mg/L
25.0
1
10/17/16 17:08
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent -
ND ug/L
0.030
1
10/19/16 16:04
18540-29-9
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
93.7 mg/L
20.0
10
10/27/1611:39
14808-79-8
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
10.6 mg/L
1.0
1
10/20/16 20:19
16887-00-6
SM4500P-E, Phosphate, Ortho
Analytical Method: SM 4500-P E
Orthophosphate as P
ND mg/L
0.050
1
10/15/16 01:10
M1
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM
without the written consent of Pace Analytical Services, LLC.
Page 4 of 19
4

ANALYTICAL RESULTS
Project:. ALN -10/14/2016
Pace Project No.: 92316174
Sample: A -US -1-T Lab ID: 92316174002 Collected: 10/14/16 14:34 Received: 10/14/1616:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP
Pace Analytical Services, LLC
Analytical ®
2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com
[phone]
ANALYTICAL RESULTS
Project:. ALN -10/14/2016
Pace Project No.: 92316174
Sample: A -US -1-T Lab ID: 92316174002 Collected: 10/14/16 14:34 Received: 10/14/1616:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Boron
1290 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:18
7440-42-8
Calcium
31400 ug/L
100
1
10/18/16 02:30
10/20/16 23:18
7440-70-2
Iron
1110 ug/L
50.0
1
10/18/16 02:30
10/20/16 23:18
7439-89-6
Silicon
11500 ug/L
500
5
10/18/16 02:30
10/21/16 14:18
7440-21-3
Lithium
ND ug/L
500
1
10/24/16 14:20
10/26/16 09:28
7439-93-2
Manganese
846 ug/L
5.0
1
10/24/16 14:20
10/26/16 09:28
7439-96-5
Silica Calculation
Analytical Method: Silica Calculation
Silica Calculation
24700 ug/L
214
1
10/21/1617:24
7631-86-9 N2
200.8 MET ICPMS
Analytical Method: EPA 200.8 Preparation Method: EPA 200.8
Aluminum
35.7 ug/L
10.0
1
10/24/1614:20
10/26/1612:05
7429-90-5
Antimony
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05.7440-36-0
Arsenic
ND ug/L
1.0
1
10/24/161420
10/26/1612:05
7440-38-2
Barium
54.3 ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-39-3
Beryllium
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:05
7440-41-7
Cadmium
ND ug/L
0.10
1
10/24/1614:20
10/26/1612:05
7440-43-9
Chromium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-47-3
Cobalt
7.1 ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-48-4
Lead
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7439-92-1
Molybdenum
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7439-98-7
Nickel
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-02-0
Selenium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7782-49-2
Strontium
220 ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-24-6
Vanadium
ND ug/L
1.0
1
10/24/1614:20
10/26/1612:05
7440-62-2
245.1 Mercury
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1
Mercury
ND ug/L
0.20
1
10/18/16 06:10
10/19/16 13:08
7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
202 mg/L
25.0
1
10/17/16 17:08
Hexavalent Chromium by IC
Analytical Method: EPA 218.7
Chromium, Hexavalent
ND ug/L
0.030
1
10/19/16 16:17
18540-29-9
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
94.2 mg/L
20.0
10
10/28/16 02:34
14808-79-8 M6
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
10.9 mg/L
1.0
1
10/20/16 20:20
16887-00-6
SM4500P-E, Phosphate, Ortho
Analytical Method: SM 4500-P E
Orthophosphate as P
ND mg/L
0.050
1
10/15/16 01:10
Date: 11/03/2016 02:14 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 19

aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333492 Analysis Method: EPA 245.1
QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury
Associated Lab Samples: 92316174001, 92316174002
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
METHOD BLANK: 1848121
Matrix: Water
Associated Lab Samples: 92316174001, 92316174002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
ug/L
ND 0.20
10/19/1611:54
LABORATORY CONTROL SAMPLE:
1848122
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Mercury
ug/L
2.5 2.5
100 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848123 1848124
MS MSD
92316145003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Mercury ug/L ND 2.5 2.5 2.5 2.5 99 98 70-130 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848125 1848126
MS MSD
92316158004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 2.4 2.4 97 98 70-130 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 19

Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 19
laceMalyfical"
Pace Analytical Services, LLC
2225 Riverside
Asheville, NC 2880404
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333303
Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7
Analysis Description: 200.7 MET
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1847176
Matrix: Water
Associated Lab Samples: 92316174001, 92316174002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Calcium
ug/L
ND 100
10/20/16 22:35
Iron
ug/L
ND 50.0
10/20/16 22:35
Silicon
ug/L
ND 100
10/20/16 22:35
LABORATORY CONTROL SAMPLE:
1847177
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Calcium
ug/L
5000 5130
103 85-115
Iron
ug/L
5000 4760
95 85-115
Silicon
ug/L
2500 2520
101 85-115
_ MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1847178 1847179
MS MSD
92316149001
Spike Spike MS
MSD MS MSD
% Rec
Parameter
Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Calcium
ug/L 3810
5000 5000 9040
9110 105 106
70-130 1
Iron
ug/L 85.5
5000 5000 4890
4890 96 96
70-130 0
Silicon
ug/L 5170
2500 2500 7760
7760 103 103
70-130 0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 19

aceAnalytical
www,pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 327776 Analysis Method: EPA 200.8
QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1749996
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
10/26/1611:46
Antimony
ug/L
ND
1.0
10/26/1611:46
Arsenic
ug/L
ND
1.0
10/26/1611:46
Barium
ug/L
ND
1.0
10/26/1611:46
Beryllium
ug/L
ND
0.10
10/26/1611:46
Cadmium
ug/L
ND
0.10
10/26/1611:46
Chromium
ug/L
ND
1.0
10/26/1611:46
Cobalt
ug/L
ND
1.0
10/26/1611:46
Lead
ug/L
ND
1.0
10/26/1611:46
Molybdenum
ug/L
ND
1.0
10/26/1611:46
Nickel
ug/L
ND
1.0
10/26/1611:46
Selenium
ug/L
ND
1.0
10/26/1611:46
Strontium
ug/L
ND
1.0
10/26/1611:46
Thallium
ug/L
ND
1.0
10/26/1611:46
Vanadium
ug/L
ND
1.0
10/26/1611:46
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE & LCSD:
Parameter
1749998
Units
Spike
Conc.
1750295
LCS LCSD
Result Result
LCS
% Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD Qualifiers
Aluminum
ug/L
500
555
520
111
104
85-115
6
20
Antimony
ug/L
50
52.1
50.3
104
101
85-115
3
20
Arsenic
ug/L
50
53.6
52.4
107
105
85-115
2
20
Barium
ug/L
50
52.8
51.6
106
103
85-115
2
20
Beryllium
ug/L
5
5.6
5.5
111
109
85-115
2
20
Cadmium
ug/L
5
5.0
5.1
101
102
85-115
1
20
Chromium
ug/L
50
52.0
52.8
104
106
85-115
1
20
Cobalt
ug/L
50
53.9
53.3
108
107
85-115
1
20
Lead
ug/L
50
51.7
51.0
103
102
85-115
1
20
Molybdenum
ug/L
50
51.6
51.5
103
103
85-115
0
20
Nickel
ug/L
50
55.1
53.6
110
107
85-115
3
20
Selenium
ug/L
50
54.3
52.5
109
105
85-115
3
20
Strontium
ug/L
50
53.2
51.1
106
102
85-115
4
20
Thallium
ug/L
50
52.6
51.9
105
104
85-115
1
20
Vanadium
ug/L
50
52.3
52.1
105
104
85-115
0
20
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 19

laceAnalyfical"
www.Pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1749999
1750000
MS
MSD
92316911001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
ug/L
88.8
500
500
651
663
112
115
70-130
2
Antimony
ug/L
3.6J
50
50
55.7
55.2
104
103
70-130
1
Arsenic
ug/L
85.1
50
50
136
138
102
105
70-130
1
Barium
ug/L
224
50
50
270
277
93
108
70-130
3
Beryllium
ug/L
0.028J
5
5
5.8
5.7
115
114
70-130
1
Cadmium,
ug/L
ND
5
5
5.0
5.1
101
101
70-130
0
Chromium
ug/L
ND
50
50
52.4
53.8
104
107
70-130
3
Cobalt
ug/L
0.33J
50
50
53.5
53.5
106
106
70-130
0
Lead
ug/L
ND
50
50
54.0
53.1
108
106
70-130
2
Molybdenum
ug/L
65.3
50
50
115
117
99
103
70-130
2
Nickel
ug/L
3.2J
50
50
55.8
56.6
105
107
70-130
1
Selenium
ug/L
11.0
50
50
62.3
61.3
102
100
70-130
2
Strontium
ug/L
1360
50
50
1390
1380
59
42
70-130
1 M1
Thallium
ug/L
0.26J
50
50
52.9
52.8
105
105
70-130
0
Vanadium
ug/L
19.6
50
50
72.9
74.4
107
110
70-130
2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1750001
1750002
MS
MSD
92316577002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual .
Aluminum
ug/L
0.011
500
500
591
603
116
118
70-130
2
mg/L
Antimony
ug/L
ND
50
50
52.0
50.8
104
102
70-130
2
Arsenic
ug/L
ND
50
50
52.8
52.9
104
104
70-130
0
Barium
ug/L
0.0021
50
50
56.4
55.7
109
107
70-130
1
mg/L
Beryllium
ug/L
ND
5
5
6.1
6.0
121
119
70-130
2
Cadmium
ug/L
ND
5
5
5.3
5.4
105
108
70-130
2
Chromium
ug/L
ND
50
50
54.4
53.7
108
107
70-130
1
Cobalt
ug/L
ND
50
50
52.9
52.8
106
106
70-130
0
Lead
ug/L
ND
50
50
52.4
52.0
105
104
70-130
1
Molybdenum
ug/L
0.0010
50
50
54.3
53.6
107
105
70-130
1
mg/L ,
Nickel
ug/L
ND
50
50
52.3
52.2
105
104
70-130
0
Selenium
ug/L
ND
50
50
52.2
52.9
104
106
70-130
1
Strontium
ug/L
0.32
50
50
366
367
92
95
70-130
0
mg/L
Thallium
ug/L
ND
50
50
53.5
53.0
107
106
70-130
1
Vanadium
ug/L
ND
50
50
54.3
53.8
107
107
70-130
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 19

acmnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 333444
Analysis Method: SM 2540C
QC Batch Method: SM 2540C
—
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1847891
Matrix: Water
Associated Lab Samples: 92316174001, 92316174002
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0 10/17/16 17:02
LABORATORY CONTROL SAMPLE:
1847892
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 238 95 90-110
SAMPLE DUPLICATE: 1847893
92316026004 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
ND ND
SAMPLE DUPLICATE: 1847894
92316116001 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
3480 4010 14 D6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 19

aceAnalytical
www.pacelabs.com
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 326916
QC Batch Method: EPA 218.7
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1744556
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Chromium, Hexavalent ug/L
LABORATORY CONTROL SAMPLE: 1744557
Parameter Units
Chromium, Hexavalent ug/L
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.030 10/19/1614:59
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
.075 0.077 102 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1744558 1744559
MS MSD
701993001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chromium, Hexavalent ug/L <0.030 .075 .075 0.079 0.076 85 80 85-115 5 H3,M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 19

aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 334632 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92316174001
METHOD BLANK: 1854981 Matrix: Water
Associated Lab Samples: 92316174001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 2.0 10/26/1616:23
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1854982
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 18.9 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1854983 1854984
MS MSD
92316304002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 2.3 20 20 19.8 19.8 88 88 90-110 0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1854985 1854986
MS MSD
92316826012 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 6.1 20 20 24.5 24.5 92 92 90-110 0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 19

7aceAnalytical
www.pacelabs.com
r
QUALITY CONTROL DATA
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 334732 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92316174002
METHOD BLANK: 1855484 Matrix: Water
Associated Lab Samples: 92316174002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 2.0 10/27/1612:33
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1855485
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
% Rec
Limits
Qualifiers
Sulfate mg/L
20
18.6
93
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1855486
1855487
MS
MSD
92316174002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Sulfate mg/L 94.2
20
20
110
110
78
79
90-110
0 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1855488
1855489
MS
MSD
92316295003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Sulfate mg/L 16700
20
20
37.2
37.2
102
103
90-110
0
ug/L
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 19

aceAnalytical
www.paoelabs.com
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333557
QC Batch Method: SM 4500 -CI -E
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1848383
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Chloride mg/L
QUALITY CONTROL DATA
Analysis Method: SM 4500 -CI -E
Analysis Description: 4500 Chloride
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 10/20/16 20:14
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 1848384
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 21.2 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848385 1848386
MS MSD
92316010001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Chloride mg/L 2930 10 10 2960 3020 320 930 90-110 2 M6
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 19

aceAnaljftal
www.pacelabs.com
Project: ALN -10/14/2016
Pace Project No.: 92316174
QC Batch: 333286
QC Batch Method: SM 4500-P E
Associated Lab Samples: 92316174001, 92316174002
METHOD BLANK: 1847152
Associated Lab Samples: 92316174001, 92316174002
Parameter Units
Orthophosphate as P mg/L
LABORATORY CONTROL SAMPLE: 1847153
Parameter Units
Orthophosphate as P mg/L
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 4500-P E
Analysis Description: SM450OP-E Phosphorus, Ortho
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 10/15/16 01:10
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
.25 0.25 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1847154 1847155
MS MSD
92316174001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Orthophosphate as P mg/L ND .25 .25 0.32 0.32 121 121 90-110 0 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 19

acmnalytical
mvw.pacelabs.cam
QUALIFIERS
Project: ALN -10/14/2016
Pace Project No.: 92316174
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold NELAC/TNI accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 19

Pace Analytical Services, LLC
aceMaIXical ® Ashhevievi Riverside lle; NC 2880404
wwwpacelab&com
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
ALN -10/14/2016
92316174
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92316174001
A -US -1-F
EPA 200.7
327775
EPA 200.7
327873
92316174001
A -US -1-F
EPA 200.7
333303
EPA 200.7
333572
92316174002
A -US -1-T
EPA 200.7
.327775
EPA 200.7
327873
92316174002
A -US -1-T
EPA 200.7
333303
EPA 200.7
333572
92316174001
A -US -1-F
Silica Calculation
334146
92316174002
A -US -1-T
Silica Calculation
334146
92316174001
A -US -1-F
EPA 200.8
327776
EPA 200.8
327874
92316174002
A -US -1-T
EPA 200.8
327776
EPA 200.8
327874
92316174001
A -US -1-F
EPA 245.1
333492
EPA 245.1
333497
92316174002
A -US -1-T
EPA 245.1
333492
EPA 245.1
333497
92316174001
A -US -1-F
SM 2540C
333444
92316174002
A -US -1-T
SM 2540C
333444
92316174001
A -US -1-F
EPA 218.7
326916
92316174002
A -US -1-T
EPA 218.7
326916
92316174001
A -US -1-F
EPA 300.0
334632
92316174002
A -US -1-T
EPA 300.0
326819
92316174002
A -US -1-T
EPA 300.0
334732
92316174001
A -US -1-17
SM 4500 -CI -E
333557
92316174002
A -US -1-T
SM 4500 -CI -E
333557
92316174001
A -US -1-F
SM 4500-P E
333286
92316174002
A -1.116-1-T
SM 4500-P E
333286
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/03/2016 02:14 PM without the written consent of Pace Analytical Services, LLC.
�.
Page 17 of 19

aeeAnalXtal
Document Name:
Sample Condition Upon Recelpt(SCURI
Document Revised: Sept. 21, 2016
Pae i of 2
Document No.:
F-CAWCS-033-Rev.00
Issuing Authority:
Pace Qualft.y Office
Pace 2 of 2 for Internal Use ONLY
Sample • Clletrt Name:
Project #: WO# : 92316174
Receipt i
�.1n,rK�e2�J la-il� z. 1111111111111111111111Goutier: Fed Ex UPS USPS Client
❑ Commercial DPace ❑Other: 92316174
Custody Seal Present? Dyes LtaNa Seals Intact? ❑Y s [l� No RL
Date/Initials Person Examining CortWnts: '1q'
116
Packing Material: [:]Bubble Wrap []Bubble Bags one ❑Other.
Thermometer:et []Blue❑None Samples on ke, tooling aeess has Veeon
`
❑ IR Gun ID.. us Type of led:
Correction Factor: Cooler Temp Corrected ('C): )(l• 5( Biological Tissue Frozen? []Yes No
Temp should be above fr zing to 6'C
USDA Regulated Sall ( N/A, water sample)
Did sampy originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did sia4!es originate from a foreign source (Inter tionally,
_-.. �.__ u.......0 ....d fl • ". ar.,.b r•-tvee lultin
les -Y��w
--- - ----- —
i Comments/Dlscre nc :
Chain of Custody Present?
oNo
N/A
1,
Samples Arrived within Hold Time?1f
s
QNo
N A
2.
Short Hold lime Anii sis (42 hr.)?
.V es
QNoEl
/A
3,
Rush Turn Around Time Requested?
Dyes
o
❑N/A
4.
SiufficlentVolume?
OYA
CdNb
❑N A
5.
M `7yr'1 0
Correct ContainersUsedlVY-U
- -Pace Containers Used?
❑No
No
❑N/A
ONIA
6.
Containers Intact?
es
❑N
DN/A
7.
Samples Fleld Flitered?
QYes
N/A
8.
' . Note If sedlment Is visible In the dissolved container
Sample Labels Match COC?
-Includes date/Time/ID/Analysis Matrix: 1411
❑Yes
MI
❑N/A
All containers needing acid/base preservation have beenlU.
checked and documented on page two of SCURF?
Exceptions: VOA, Coliform, TOC, 011 and Grease, DRO/8015
(water) DOC, LLHg
Sam ies checked for dechlorinatlon?
Yes
❑No
r3No
(DN/A
❑ /A
11.
Heads ace in VOA Vials >5-6mm ?
MYes
DNO
N A
12.
Trip Blank Present?
Trip Blank Custody Seals Present?
Pace Trip Blank Lot q (If purchased): _
Dyes
Dyes
LIN,
ONO
❑y(A
N/A
13.
QIENT NOTIFICATION/RESOLUTION
Person Contacted:'
Comments/Sample
Discrepancy:
bate/Time:
Field Date Required? UYes UNo
Project Manager SCURF Review: ri, oke: 1194t. !
Project Manager SRF Review: Defe: r5
Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be lent to the North 6 Iln DEHNR Certifl6tion Office (i.e.
Out of hold, Incorrect preservative, out of temp, Incorrect containers)
Laboratory receiving.samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Rale(gh❑ Mechanicsville❑
Page 18 of 19

w
CHAIN -OF -CUSTODY / Analytical Request.bocument
The Chah-ai;Custody is a LEGAL DOCUMENT. All mlmnt Wds must be complsted accurdsly.
/om.�pwuNDrrnm
Section A Section 8 Section C Pace: = at 1
GemPa+Y.W40onTo: PasrHatdecfLptertison�wDtedoeaPer�of9 'on' RddwlCookfwek*wstwkwW.crg
ems: 1S0MdAentcneS1e60:1 CDpyTo, ComPeR0Nmle: W ArkeepwAnonce
AEGULl1TORYAGEN4Y."
NawY^NY10M Addrew+eow M1.14806MWRIYet.Nrlows
iX NPDE3 i GROUNDWATER {" DRMNGWA7ER
r– ST I` RCRA I OTHER
EmaoTo: p�� ow D r0 Puchaeo0niorNo aee�D
Phone:528ffi-02 — 212747-0611 PmjadName:AIN-10742016 Paw Pmm,ld ChdDemen(AaeyaNC)
••SiteLOCation
•. ;STATE:
PIC
geMnsled Due Doe)TAT. "ect Number. Paw Pmts.?
_ FI64"sWd
Andys)a
Filtered
(v/N)
-;
g23j`i7Y
0: Paw Pro tatH N0J Lab LD.
]
�u
C
R�ledGadMomm'af NatrL*CDdee
%WJ"d0
ow,amwAlm -PwWATGR WT
WACI£WATPA WW
' PROMW P
9otUDoITD L
SAMPLE ID 6 juq °
(A•Z, bB /.) OTMR CT
Semple IDs MUST BE UNIQUE TM&x 16
y
'IDS
�p
O.
Li]
�'
W
COLLECTED
O
,�K7,
¢
i
Q
&'��__.�g�m
x_*
Preservatives
y UU
S 2 O
a
•••
►
a,
.~�
e
y
m
-
@
c�-
9
z
�.
1
a
-
�'
2
go
Q
.R
26
fi
G"j
`
N
Q.
DdpcalrE
oT
Co1.PDSRs
ENocAAe
DATE TME
DATE TIME
�'•
A•US-1-F
1CM4n8 1424
6.
.
ti:
✓
✓
✓-
✓
✓
✓
✓
✓
Da
2
AJJS-1 7
lanale 1414
6
✓
✓
✓
✓
✓
✓
3
5
6'
3'
7
•B
10•.
'12'
--—
ADDrirONAL:CQ41ME41TS -' ' pWNt7018NED8Y/AlCfiL4TbN, :-':. '•:.t1dTE .'
71NE '•
. '
11CCEPIED.BY1'AFfIL]11710►J.' ,
DATE
':: i11AE':..
SAMPLE CONDMONS
Catawba Riverkeeper Foundation 10/14116
BkOLER'NAYEAND 0NATURE.` "` .,;;;.
PAWNahrdBA:i+LE(r: Spen=6amuelPerlins
1ATESI
StONATUFiEdaAYPLEJ� . DATESIynod 10114/16
o
-- a aD rn
•� Nof,c By ela.irgdie feta, youam.aa^pir0 Pea1a NET 3o day Inym.rlteaes •nd epewir0 b ba dA� Df USX pu muE, far any ferolca� sol t� �7fu,7o days
d
F-ALL-0.020MV-08, 12-0d-2007