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NC0038377_Update to Existing Application 2014_20141015
' VDUKE Mayo Steam Plant ENERGY. Duke Energy Progress ' PROGRESS 10660 Boston Road Roxboro, NC 27574 October 13, 2014 ��EIVE���EN�DWR ' Mr. Jeffrey O. Poupart R North Carolina Department of Environment and Natural Resources 5 �Qti4 North Carolina Division of Water Resources ' 1617 Mail Service Center water Quaoon Raleigh, NC 27699 -1617 ?8�0 ►n9 IFile: 12520B -1 Subject: Duke Energy Progress, Inc. Mayo Electric Generating Plant NPDES Permit No. NC0038377 Update to existing NPDES application and NPDES application under review Person County Dear Mr. Poupart: The current NPDES permit for the Mayo Electric Generating Plant (Mayo) located in Person County expired on March 31, 2012. Since the facility submitted a timely renewal request including EPA Form 1, EPA Form 2C and EPA Form 2F, all in triplicate, the site continues to operate under, and be covered by, an administratively extended NPDES permit. As several years have passed since the original submittal of NPDES permit renewal requests, Duke Energy Progress, Inc. (Duke) is providing this update to our active and pending NPDES applications. This update is in addition to the update provided on May 1, 2013. This update consists of: 1. An update to EPA Form 1 originally submitted on September 28, 2011. Duke Energy Progress, Inc. ( "Duke ") subsequently submitted a request for name change to NCDENR which was approved on July 10, 2013. 2. An updated line drawing in accordance with EPA Form 2C Item 11 -A (An update to attachment 2 in the renewal application submitted on September 28, 2011). This includes modifications to outfall 004, 005 and outfall 006. 3. An updated narrative description of wastewater treatment processes and disposal as required by EPA Form 2C Item II -B (An update to attachment 3 in the renewal application submitted on September 28, 2011. 4. An updated list of chemicals in accordance with EPA Form 2C Item VI "Potential Discharges not covered by analysis" (An update to attachment 4 in the renewal application submitted on September 28, 2011). 5. A seep characterization and monitoring plan for the site in accordance with the terms agreed upon between Duke and NC DENR. 6. A groundwater monitoring plan. 7. A groundwater receptor survey. 8. A generalized groundwater flow directional map. ' UPd ates to the application for storm water coverage currently P ermitted by the subject permit are ' being sent to staff of the North Carolina Division of Energy, Minerals and Land Resources. Since the last renewal submittal in 2011 Duke has made major investments in the site and has ' completed construction of a monofill to accept coal combustion products handled in dry form, completed upgrades to handle bottom ash in dry form and expects to soon commission a partial zero liquid discharge system (thermal evaporator) which will eliminate any discharge from the ' FGD blowdown system via outfall 009. As described in previous NPDES application update dated May 1, 2013, Duke requests that outfall 009 remain in the permit as a permitted outfall in case future technology allow for FGD wastewater to be treated to meet permit limits. If there are any questions regarding the enclosed information, please contact Shannon Langley at (919) 546 -2439. I certify, under penalty of law, that this document and all attachments were prepared under my ' direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons it-ho manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, ' and complete. 1 am aivare that there are significant penalties far submitting false information, including the possibility of f nes and imprisonment for knowing violations. Sincerely, William J. Thacker — Plant Manager Mayo Electric Generating Plant Attachments Update to Form submitted September 26, 2011 Plaaca nnnl nr I.- Iha unchartcvi areas nniv Form Aooroved OMB No 2040 -0086. FORM U S ENVIRONMENTAL PROTECTION AGENCY I EPA I D NUMBER 1 :.EPA GENERAL INFORMATION TA = F Consolidated Permits Program D GENERAL (Read the "(;e» era! Insimeiions" hefi)re sairring.) ,3 14 1 15 GENERAL INSTRUCTIONS LABEL ITEMS If a preprinted label has been provided affix it in the - -- - designated space Review the Information carefully if any of It is Incorrect cross through It and enter the correct data In the I. EPA LD NUMBER appropnate fill -In area below Also if any of the prepnnted data is absent (the area to the left or the label space lists the III. FACILITY NAME PLEASE PLACE LABEL IN THIS SPACE information that should appear) please provide It In the proper fill -In area(s) "low If the label Is complete and correct. you need not complete Items I. III. V and VI (except VI -B which V FACILITY MAILING ADDRESS must be completed regardless) Complete all Items If no label has been provided Refer to the instructions for detailed deco descnptions and for the legal authorizations under which this VI. FACILITY LOCATION data is collected. Il POLLUTANT CHARACTERISTICS INSTRUCTIONS Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer 'yes' to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question. Mark 'X' in the box in the third column if the supplemental form is attached If you answer 'no" to each question, you need not submit any of these forms You may answer 'no' If your activity is excluded from permit requirements.. see Section C of the instructions See also, Section D of the instructions for definitions of bold -faced terms WNW Mark •x- SPECIFIC QUESTIONS YES NO ATTAACHED SPECIFIC QUESTIONS ves NO ATTAc ED A Is this facility a publicly owned treatment works which results in a discharge to waters of the U.S." �FORM 2A) X B Does or will this facility (either existing or proposed) include a concentrated animal feeding operation or aquatic animal production facility which results in a g discharge to waters of the U.S.? (FORM 28) C Is this a facility which currently results in discharges to �/ X �/ X D Is this a proposed facility (other than those described in A X waters of the U.S. other than those described in A or B or B above) which will result in a discharge to waters of above (FORM 2C) Z, the U.S.1 (FORM 2D) E Does or will this facility treat store or dispose of F Do you or will you inject at this facility industrial or hazardous wastes? (FORM 3) X municipal effluent below the lowermost stratum X containing within one quarter mile of the well bore g x underground sources of drinking water? (FORM 4) r n G Do you or will you inject at this facility any produced water H Do you or will you inject at this facility fluids for special or other fluids which are brought to the surface in processes such as mining of sulfur by the Frasch process, connection with conventional oil or natural gas production, X solution mining of minerals in situ combustion of fossil X inject fluids used for enhanced recovery of oil or natural fuel, or recovery of geothermal energy) (FORM 41 gas or inject fluids for storage of liquid hydrocarbons" (FORM 4) F e I. Is this facility a proposed stationary source which is one J Is this facility a proposed stationary source which is of the 28 industrial categories listed in the instructions and �/ X NOT one of the 28 industrial categones listed in the �/ X which will potentially emit 100 tons per year of any air instructions and which will potentially emit 250 tons per pollutant regulated under the Clean Air Act and may affect year of any air pollutant regulated under the Clean Air Act 41 U ` or be located in an attainment area? (FORM 5) and may affect or be located in an attainment area? (FORM 5) III NAME OF FACILITY 1 SKIP Mayo Electric Generating Plant IV FACILITY CONTACT A. NAME & TITLE (imi. first (Y rife) 8 PHONE (area c(xte & na ) 2 1111111111111111111 T acker, William J. - Plant Manager 1 ( 3 1 5 9 -0 1 1s ie xe e xa xo s1 s- ss V FACILTY MAILING ADDRESS A STREET OR P 0 BOX J3 10660 Boston Road B CITY OR TOWN C STATE D ZIP CODE 2404 4 17 51 J4 Roxboro C 1C 11 C VI FACILITY LOCATION A STREET ROUTE NO OR OTHER SPECIFIC IDENTIFIER 5 1 660 Boston Roa B COUNTY NAME Person C CITY OR TOWN D STATE E ZIP CODE F COUNTY CODE (,14 s R oro 11C -- 4 EPA Form 3510 -1 (8-90) CONTINUE ON REVERSE 1 CONTINUED FROM THE FRONT VII SIC CODES 4-di it. in order of non A FIRST B SECOND = ( specify) E_—ric 7 6rec!h') 7 4911 q C THIRD D FOURTH VIII OPERATOR INFORMATION A. NAME B Is the name listed in Item VIII -A also the owner? a Duke Energy Progress, Inc. AYES ONO C STATUS OF OPERATOR (linter the appropriate letter auo then isirerbor. of "Other "specify.) D PHONE (area,ale & nu ) F = FEDERAL M = PUBLIC (other than federal or state) P (spec1h) JA S = STATE O = OTHER (,peof ) P = PRIVATE se I to ir. :! Im :e E STREET OR P.O BOX I I I I I I I I I I I I I IJ 4101 South i mington Street F CITY OR TOWN G STATE H. ZIP CODE JIX INDIAN LAND Is the facility located on Indian lands" g Raleigh NC 27601 ❑ YES ❑ NO 4^ a' 51 4' X EXISTING ENVIRONMENTAL PERMITS D PSD .air F.mi.ssrons ni Pro aed.krurces A. NPDES Dischar j.s to Sur ace Water g N NCO038377 g FPTI 8. UIC I ndert;row II i ecnun olTlualc E OTHER s ee'i i) t 0 3 g 8 3 9 (spe1•th) Title v air permit 9 U 9 •e +a x 15 !e +e � C RCRA H+cardwi. W'asres) E OTHER ,err ) c j (gpectft) state nor. discharge permit for ash 9 R NCD000830612 g WQ0000020 reuse n !e ++ +e » 1s is +a n XI MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility. the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage or disposal facilities and each well where it injects fluids underground Include all springs rivers, and other surface water bodies in the map area See instructions for precise requirements XII NATURE OF BUSINESS (provide a briefdescnpbon) The Mayo Electric Generating Plant (Mayo) is a dual boiler coal fired electric generating plant with a net generating capacity of 745 megawatts. XIII CERTIFICATION (see instructions) 1 certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that. based on my inquiry of those persons immediately responsible for obtaining the information contained in the application. I believe that the information is true accurate. and complete I am aware that there are significant penalties for submitting false information including the possibility of fine and imprisonment. A. NAME & OFFICIAL TITLE (ripe or print) B William Thacker SIGNATURE C DATE SIGNED Plant Manager COMMENTS FOR OFFICIAL USE ONLY C s a EPA Form 3510 -1 ( 8-90) 16 Outfall 002 Evaporation 11 Cooling Towers 10 Mayo Reservoir Outfall 001 14 2 1 14 Misc. Equipment Heat 18 Intake Structure Exchangers 13 Alternate 26 Ash Sluice � Water 112 Condensers Fire Protection Boiler & Turbine Condensate -� Storage Evap and seepage Ash Basin Outfall Gypsum and See Page 009 Limestone Pile 2 and 3 of 7 23 15 Runoff 17 Coal Pile Access Road Storm Secondary Containment rFGD Blowdown Runoff Water, Power block SW, For anhydrous ammonia Highway 501 runoff, tanks rainfall 5 Storm water 3 Raw Water Treatment 4 Water Storage Ion Exchange Potable water from City of Roxboro Potable & Sanitary Svstems Sewage treatment Oily Waste Treatment --17 8 Misc. low Volume Duke Energy Progress, Inc. Mayo Steam Electric Plant Person County, NC Schematic of Water Flow Page 1 of 7 October 2014 Water balance detail for FGD WW treatment system (bioreactor) and Cooling System only A Mayo Reservoir Ash basin FFGD Make -up Pumps , , o' `t 27 >' O. > 28 c Evaporation FGD System N , m, E, W , Excess Monofill leachate Settling Pond Bottom Ash Silo 1 30 , , , , , 36 ; , , 38 (alternate) Dry bottom ash seal water in , 37 , , Cooling Towers , , 33 , Fly Ash Silos 34 Thermal Evaporator 32 Demin- Bioler 31 Clean Distillate Make-up (Conditioning Water) p 35 Cooling water Monofill Dust Rainfall suppression 38 Proposed Water balance detail for thermal evaporator and Dry bottom Ash system 38 A Potential Dust Groundwater suppression Storm water irrigation Outfall 004 Storm water Mayo Reservoir Switchyard Outfalls runoff to 006a 006a, b, c, d and e Potential Cooling Tower Drift Outfall 005 Potential Dust Groundwater • suppression Storm water irrigation Duke Energy Progress, Inc. Proposed Water balance detail Mayo Steam Electric Plant for thermal evaporator Person County, NC and Dry bottom Ash system Schematic of Water Flow Page 4 of 7 October 2014 ' Duke Energy Progress, Inc. Mayo Electric Generating Plant ' National Pollutant Discharge Elimination System Permit Number NC0038377 Attachment 2 Page 5 of 7 I Form 2C - Item II -A Flows, Sources of Pollution, and Treatment Technologies (Table Corresponds to Page 1 of 7) Stream Estimated Average Flow Comments 1 19 MGD Make up water from Mayo Reservoir. 2 13.7 MGD Cooling Tower make up. 3 0.36 MGD Raw Water treatment 4 0.002 MGD Sewage treatment plant 5 0.00175 MGD Raw water treatment backwash 6 0.36 MGD Treated water to water storage 7 300 GPM (Max. rate) Oily waste (infrequent) to ash pond 8 1.5 MGD Low volume waste to ash pond 9 0.05 MGD at start up Boiler blowdown to ash pond 10 2 MG /event 1 /yr. Cooling Tower basin drain to Mayo Reservoir 11 9 MGD Evaporation from Cooling Tower 12 3.9 MGD Ash Transport (limited) /Cooling Tower Blowdown 13 Variable as needed Intermittent blowdown of circulating (blowdown) water from heat exchangers 14 8.5 MGD (re- circulating flow) Heat exchanger (primary route) 15 0.0135 MGD (annual daily Coal pile Runoff average) 16 10.2 MGD Outfall 002 discharge to Mayo Reservoir. Secondary containment for SCR 17 chemicals 18 11.1 MGD Make up Water to Heat Exchangers 23 0.20 MGD Bioreactor Discharge to Polishing Pond October 2014 Duke Energy Progress, Inc. Mayo Electric Generating Plant National Pollutant Discharge Elimination System Permit Number NC0038377 26 variable Cooling Tower Blowdown * - The Facility was constructed to utilize either Stream 12 or 26 for cooling tower blowdown. Currently, Stream 12 is used because this flow path allows for the sluicing of ash with the cooling tower blowdown water. In the future when the facility goes to dry ash handling Stream 26 will be used for cooling tower blowdown, occasional wet sluicing of fly ash will occur during periods of maintenance on the dry fly ash handling system. October 2014 Duke Energy Progress, Inc. Mayo Electric Generating Plant ' National Pollutant Discharge Elimination System Permit Number NC0038377 ' Attachment 2 Page 6 of 7 ' Form 2C - Item II -A Proposed Flows, Sources of Pollution, and Treatment Technologies (Table Corresponds to Page 2 of 6) Stream Estimated Average Flow Comments 2 13.7 MGD Current Cooling Tower Make Up 10 2 MG /event 1 /yr. Cooling Tower basin drain to Mayo Reservoir 11 9 MGD Evaporation from Cooling Tower 12 3.9 MGD Ash Transport (limited) 13 Variable as needed (blowdown) Intermittent blowdown of circulating water from heat exchangers 14 8.5 MGD (re- circulating flow) Heat exchanger (primary route) 16 10.2 MGD Outfall 002 discharge to Mayo Reservoir. 18 11.1 MGD Make up Water to Heat Exchangers 19 1.9 MGD Make up Water to FGD System 20 1.55 MGD Evaporation from FGD System 21 0.35 MGD FGD Blowdown to Settling Pond 22 0.35 MGD Bioreactor Intake from Settling Pond 23 0.35 MGD Bioreactor Discharge to Polishing Pond 24 2.6 MGD Proposed Cooling Tower make up. 25 19.0 MGD Make up water from Mayo Reservoir. 26 Variable Cooling Tower Blowdown* * - The Facility was constructed to utilize either Stream 12 or 26 for cooling tower blowdown. Currently, Stream 12 is used because this flow path allows for the sluicing of ash with the cooling tower blowdown water. In the future when the facility goes to dry ash handling Stream 26 will be used for cooling tower blowdown, occasional wet sluicing of fly ash will occur during periods of maintenance on the dry fly ash handling system. October 2014 j' Duke Energy Progress, Inc. Mayo Electric Generating Plant ' National Pollutant Discharge Elimination System Permit Number NC0038377 ' Attachment 2 Page 7 of 7 Form 2C - Item II -A Proposed Flows, Sources of Pollution, and Treatment Technologies Future FGD Waste water System Flow Schematic (Table Corresponds to Page 3 of 7) Stream Estimated Average Flow Comments 27 1.9 MGD Make -up to FGD System 28 1.55 MGD Evaporation 29 0.35 MGD FGD System Blowdown to FGD Settling Pond 30 0.35 MGD Intake to ZLD System 31 0.4 MGD Clean Distillate Discharge to Boiler Water Make -up 32 0.4 MGD Clean Distillate Discharge to Cooling Tower or FGD System 33 0.04 MGD Brine Solution to Ash Silo to condition dry ash for transport to monofill 34 seasonal variability Monofill leachate to FGD settling pond 35 seasonal variability Stormwater from ZLD Island 36 3000 gpm ZLD cooling water 37 600 gpm Max Dry bottom ash seal water 38 600 gpm Max Bottom ash conditioning or sent to scrubber October 2014 ' Duke Energy Progress, Inc. Mayo Electric Generating Plant National Pollutant Discharge Elimination System Permit Number NCO038377 1 Attachment 3 ' Form 2C - Item II -B Flows, Sources of Pollution, and Treatment Technologies The Mayo Electric Generating Plant is a coal -fired electric generating plant with one unit rated at a maximum dependable capacity of 745 mw. The plant is located in Person County, North Carolina and uses No. 2 fuel oil for start up and stabilization of the boiler flame. Water is withdrawn from the Mayo ' Reservoir as required to make up evaporative losses from the cooling tower, FGD Scrubber and boiler water needs. Makeup pumping rates from the reservoir are highly variable depending upon natural weather conditions, generation load, plant operations, and evaporative loss. ' Chemical constituents contained in the discharges from this facility will, in part, be representative of the naturally occurring chemical quality of the intake water. The discharges will also have chemical constituents of such quality and quantity associated with similar discharges for fossil generating facilities ' of this size, type, and in this geographical location. Either all or part of the elements enumerated in the Periodic Table, either singularly or in any combination, may from time to time be contained in this discharge. More detailed descriptions of the individual discharges described below. OUTFALL 001 - COOLING TOWER SYSTEM Approximately once per year the cooling tower basin and closed cycle cooling water system is drained to dewater the system for maintenance. The majority of the water is pumped to the ash pond. Also approximately 2 MG is drained to the reservoir to dewater the system for maintenance. That discharge is monitored and reported to the state through the monthly Discharge Monitoring Report (DMR) (Outfall 001). OUTFALL 002 — ASH POND TREATMENT SYSTEM The ash pond receives ash transport water, coal pile runoff, various storm water flows, cooling tower blowdown, and various low volume wastes such as boiler blowdown, air pre- heater wash water, boiler wash water, precipitator wash, oily waste treatment, wastes /backwash water from water treatment processes, plant area wash down water, and equipment heat exchanger water. The sewage treatment plant also discharges to the ash pond. The ash pond provides treatment by sedimentation, oxidation, neutralization, equalization, and adsorption. A standpipe allows for overflow release to a small secondary - settling basin for release into Mayo Reservoir. Due to alga blooms, the pH of ash pond discharge canal is adjusted at the standpipe as needed. Vacuumed sediments from catch basins and sumps may be transferred to the ash basin. There are engineered toe drains from the ash pond dam. Ash Transport Water — During the brief and infrequent time the dry fly ash handling system may be out of service, water for sluicing fly ash and bottom ash to the ash pond is withdrawn from the closed cycle cooling water system. The water in the closed cycle cooling water system is treated with a dispersant for protection of the cooling tower fill. Y ASH HANDLING Dry Fly Ash Handling The plant has made an upgrade converting from primarily wet sluicing fly ash to primarily dry handling of fly ash. Dry fly ash handling is the primary method of fly ash disposal. Fly ash is handled dry by a pneumatic system and sent to the ash silo. After being stored in the silo for a October 2014 Mayo Electric Generating Plant Page 1 Duke Energy Progress, Inc. Mayo Electric Generating Plant National Pollutant Discharge Elimination System Permit Number NCO038377 short period of time the dry fly ash is loaded into trucks and is transported offsite to a permitted monofill. If the dry ash handling system is out of service during plant operation periods, fly ash will be sent to the ash pond via the ash sluice system until the dry system is restored. Such occurrences are infrequent and brief. A project is scheduled to be completed in 2016 to provide redundancy to the Dry Flay ash handling facility eliminating all wet sluicing of fly ash in the future. Dry Bottom Ash Handlinq The plant has converted the bottom ash handling system from a wet sluicing system to a system for handling bottom ash dry. Bottom ash is handled dry by a pneumatic system and sent to the ash silo. After being stored in the silo for a short period of time the dry bottom ash is loaded onto trucks and is transported offsite to a permitted monofill. Coal Pile Runoff — The coal pile runoff is routed to the ash pond. Flow volumes are related to rainfall frequency and intensity. The annual daily average flow is based on a coal pile area of 30 acres, an annual average rainfall of 44 inches and a runoff coefficient of 0.85. Cooling Tower Blowdown — Historically, ash transport water withdrawal from the closed cycle cooling water system was sufficient to control total dissolved solids JDS) in the cooling water and served as cooling tower blowdown. Going forward, with the conversion to dry ash handling, Cooling tower blowdown rates will be determined by the rate needed to maintain desired water chemistry in the cooling water. Also during periods of maintenance, the cooling tower basin is drained to the reservoir (See outfall 001). Limestone and Gypsum Piles — Storm water that falls on the limestone and gypsum storage piles is directed to the ash pond. Low Volume Wastes — ' Oily Wastes — Drains containing oily wastes or water are routed to the oily waste basin. The discharge from the oily waste basin is routed through the oil —water separator where the oil is removed and contained. The treated water is then discharged to the ash pond. The fuel oil storage tank is in a containment area with a valve drain. The drain is routed to the oily waste basin. The collected oil is then managed and burned as used oil according to the requirements of the facilities Title V Air Permit. Boiler Blowdown — The boiler water is treated with ammonia continuously when the boilers are in service. Sodium hydroxide is used when needed during abnormal conditions. Boiler blowdown is routed to the ash pond via the low- volume waste conveyance. Water Treatment Wastes — Boiler make -up water and water for other uses is withdrawn from the lake, treated by various processes, including clarification, sand filtration, carbon filtration, and demineralization / reverse osmosis. Finished water is stored in tanks until needed. Various wastes generated from the water treatment such as filter backwash, and spent regeneration chemicals such as sulfuric acid and sodium hydroxide are routed to the ash pond via the low volume waste conveyance. The plant's Reverse Osmosis system produces a reject waste stream of approximately 150 gpm. Miscellaneous — Other miscellaneous sources such as wash -down water, water from various plant drains, secondary containment drains, laundry activity and temporary hand washing stations are routed to the ash pond via the low volume waste conveyance. October 2014 Mayo Electric Generating Plant Page 2 ' Duke Energy Progress, Inc. Mayo Electric Generating Plant ' National Pollutant Discharge Elimination System Permit Number NCO038377 Miscellaneous equipment heat exchanger water can be routed to the ash pond via the alternate cooling tower blowdown line if needed. The air pre- heaters and boilers are water washed infrequently. The wastewater from the air pre- heaters wash and boiler wash activity is discharged to the ash pond. During periods of maintenance, some ' molybdate waste from the closed cycle cooling water system is routed to the ash pond. Flue Gas Desulfurization Blowdown (Existing) — The Flue Gas Desulfurization (FGD) ' system directs flue gas into an absorber where limestone (calcium carbonate) slurry is sprayed. Sulfur dioxide in the flue gas reacts with the limestone slurry to produce calcium sulfate (gypsum). This system reclaims any unreacted limestone slurry to be ' reused in the absorber. A small blowdown stream is used to maintain the chloride concentration in the reaction tank. The blowdown stream is discharged to a FGD settling pond where suspended solids are reduced prior to entering a bioreactor. The bioreactor utilizes microbes to reduce soluble contaminants to insoluble forms that then precipitate ' from solution. The treated wastewater (bioreactor effluent Outfall 009) enters the ash pond secondary settling pond prior to outfall 002. An emergency overflow from the FGD settling pond to the ash pond exists. ' Flue Gas Desulfurization Blowdown (future) — The Flue Gas Desulfurization (FGD) system directs flue gas into an absorber where limestone (calcium carbonate) slurry is sprayed. Sulfur dioxide in the flue gas reacts with the limestone slurry to produce ' calcium sulfate (gypsum). This system reclaims any unreacted limestone slurry to be reused in the absorber. A small blowdown stream is used to maintain the chloride concentration in the reaction tank. The blowdown stream will be discharged to the FGD settling pond where suspended solids are reduced. The discharge of the settling pond ' will be treated in a thermal evaporation, partial zero liquid discharge (ZLD) system. The ZLD concentrates the wastewater stream through the use of both mechanical and steam energy to evaporate the water. The concentrated wastewater will be ' used for moisture conditioning of fly ash prior to being sent to a landfill. Clean distillate from the process will be utilized within the plant to partially replace water withdraw from Mayo Lake. The ZLD system will remove the FGD blowdown stream from outfall 002. An emergency overflow from the FGD settling pond to the ash pond ' exists. Sewage Treatment Plant (STP) — Sanitary wastes are treated on -site by an extended aeration ' treatment plant. The plant is designed for 0.0125 MGD and consists of a screen, commutator, surge tank, aeration tank, clarifier, chlorine contact chamber, and a sludge holding tank. Flow from the system is dependent upon fluctuating demand due to variations in the number of personnel on site. When needed, residuals are disposed of off -site by a licensed contract ' disposal firm. The STP effluent is routed to the ash pond via the alternate cooling tower blowdown line. ' Miscellaneous Storm water- Various storm water flows from the generating facility are routed to the ash pond. These include storm water from the power block, the rail line and the newly constructed back access road. ' ASH MANAGEMENT AND RECLAMATION From time to time fly and bottom ash in the ash pond may be stacked or relocated within the diked boundary of the ash pond system to optimize treatment and storage. ' October 2014 Mayo Electric Generating Plant Page 3 Duke Energy Progress, Inc. Mayo Electric Generating Plant National Pollutant Discharge Elimination System Permit Number NCO038377 structural steel and concrete truck washout area. The concrete truck washout area is controlled to ensure no free flowing liquid leaves the area or come in contact with any storm drains. Once the washed out concrete is cured /dried, the cured concrete is properly disposed. Due to mobile equipment utilization there is a potential for petroleum release. Additionally, groundwater flow and potentially flows from dust suppression activities may flow to outfall 004. Outfall 005 — Drainage from Industrial Area — Main Outfall 005 is located on the northeast side of the facility and is the end point of the plant's primary storm sewer system that drains the "power house block" of the plant using catch basins, storm sewer and vegetated conveyance. This drainage area includes areas around the boilers and turbine buildings (both are open, no roof or walls), precipitators, and the roofs of the machine shops, administrative buildings, warehouse, parking lot, and miscellaneous support facilities, such as the water supply treatment, ash storage silos, selective catalytic reduction (SCR) and transformers. Also draining to this outfall through sewers is the grassed area intended for Unit 2 at some time in the future. The grassed Unit 2 area is sometimes utilized for fabrication of structural steel for construction / maintenance projects. This area consists of gravel and grass areas. For outfall 005 the potential pollutants could be coal, coal ash, sediment, and the chemical make -up of the rain water. Due to mobile equipment utilization there is a potential for petroleum release. Additionally, groundwater flow and potentially flows from dust suppression activities may flow to outfall 005. Outfall 006x, b, c, d, e, - Cooling Tower Area Outfall 006 is located at the eastern end of the site and drains the area around the cooling tower, ' including the roof of the chemical feed building and associated roads and parking areas using catch basins, storm sewer and vegetative conveyance. In the cooling tower area, there are five separate outfalls. These outfalls involve catch basins and storm sewers that drain to swales and then to reservoir. For this outfall the potential pollutants could include sediment, mist from the cooling tower and chemical make -up of the rainwater. A malfunction of the cooling tower basin level and / or the cooling tower make -up system could result in a potential release of cooling tower water. Due to mobile equipment utilization there is a potential for petroleum release. On ' rare occasions herbicides are used for ground maintenance at the cooling towers. Additionally, groundwater flow and potentially very small flows from cooling tower drift may flow to outfall 006. Flow from the switchyard may reach outfall 006a. 1 ' October 2014 Mayo Electric Generating Plant Page 5 ' Duke Energy Progress, Inc. Mayo Electric Generating Plant ' National Pollutant Discharge Elimination System Permit Number NCO038377 Form 2C — Item VI — Potential Discharges Not Covered By Analysis Chemical Estimated Average Frequency Purpose Annual Usage Aluminum sulfate 1,000 gals. As required Improve clarifier floc Polymer 100 lbs. As required Improve clarifier floc Sodium hydroxide 275,000- 715,000 As required pH Control 15 -50% gallons. Sodium molybdate 1,100 tbs. As required Corrosion control Aqua ammonia 25,000 lbs. As required Boiler water H control Sodium bicarbonate 10,000 tbs. As required pH control Water based non- 7,000 lbs. As required Biofouling control oxidizing agent Silicone or organic 100,000 — 350,000 As required Defoamer treatment based gals. Antifoam defoamer /antifoam Dispersant (acrylic 17,000 lbs. As required Biofouling control acid polymer) Anhydrous 450,000 gals. As required Air pollution Ammonia treatments stem Sulfuric acid 50,000 lbs. As required pH control Sanuril Chlorine 100 tbs. Continuous Sewage plant Tablets effluent treatment Limestone (Calcium 270,400 tons Continuous Flue Gas Carbonate) Desulfuization Dispersant 1,275 gals. Continuous Corrosion control hos honic acid) Water Treatment 1,400 gals. As required Metals Precipitation Additive (Metclear) Magnesium 10 lbs /ton of coal As required Boiler Slagging Hydroxide Calcium Carbonate 10 lbs /ton of coal As required Boiler Slagging Kleen MCT 103 50 gals. As required R.O. system cleaning Kleen MCT 411 50 gals. As required R.O. system cleaning ' October 2014 Page 1 Duke Energy Progress, Inc. Mayo Electric Generating Plant ' National Pollutant Discharge Elimination System Permit Number NCO038377 ' October 2014 Page 2 Chemical Estimated Average Frequency Purpose Annual Usage Kleen MCT 511 50 gals. As required R.O. system cleaning Hypersperse MDC 450 gals. As required R.O. system 150 treatment Hydrated Lime 1,875 tons As required Air pollution treatment system / Corrosion Control Inhibitor 6,000 gals. As required FGD scale control Dis erant 3,000 gals. As required FGD scale control Mercontrol 8034 Variable As required Hg re- emission control Mercontrol 8034 Variable As required Hg re- emission Plus control Clean Coal Approximately Continuous Nitrous Oxide 0.4% per ton of coal control M45 -PC Additive A Clean Coal Approximately Continuous Mercury control M45 -PC Additive B 0.0005% per ton of coal Tetrasodium EDTA 10,000- 25,000 As required 30 -60% gallons Dibasic Acid (added Variable — As As required Maintain FGD May 2013) needed wastewater ORP Activated Carbon Variable — As As required Hg re- emission (added May 2013) needed mitigation Anhydrous calcium 10,000 - 50,000 lbs. As required Thermal evaporator sulfate operations. Sodium Sulfite 5- 40,000- 100,000 As required 50% gallons Sodium Bisulfite 5- 40,000- 100,000 As required Chlorine Scavenger 60% gallons 93 -98% Sulfuric 30,000- 45,000 As required Thermal evaporator Acid gallons NALCO OOPGO07 ? ? ? ?? As required Antifoam Antiscalant — Polymer 60,000- 90,000 As required Thermal evaporator blend of sodium salt gallons Scale control of phosphonomethylated diamine ' October 2014 Page 2 41P synTerra SEEP MONITORING REPORT - AUGUST 2014 FOR MAYO STEAM ELECTRIC PLANT 10600 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 PERSON COUNTY NPDES PERMIT #NC0038377 PREPARED FOR DUKE ENERGY PROGRESS, INC. RALEIGH, NORTH CAROLINA j DUKE 7 ENERGY. PROGRESS SUBMITTED: OCTOBER 2014 SEAL 1425 O �F c1- OG�S Oh,a ,,,0%. SEAL S X328 N \N. '""NiSM , NC PG 1425 ject Geologist S NC PG 1328 roject Manager Seep Monitoring Report October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra TABLE OF CONTENTS SECTION PAGE EXECUTIVE SUMMARY 1.0 Introduction ....................................................................................... ..............................1 2.0 Seep Monitoring ............................................................................... ............................... 2 2.1 Seep Identification ...................................................................... ............................... 2 2.2 Seep Flow Measurement ............................................................ ............................... 2 2.3 Seep Sample Collection .............................................................. ............................... 3 3.0 Recommendations ............................................................................. ..............................4 List of Figures Figure 1- Site Location Map Figure 2 - Identified Seeps and Water Quality Sample Locations List of Tables Table 1 - Seep Locations and Descriptions Table 2 - Seep Flows and Analytical Results Table 3 - Analytical Parameters /Methods List of Appendices Appendix A - Analytical Sample Handling, Preservation and Holding Time Requirements Page P: \Duke Energy Progress.1026 \ALL NC SITES\NPDES Permit Deliverables\ Mayo\ Seep Report \Mayo Seep Monitoring Report.doxx Seep Monitoring Report October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra EXECUTIVE SUMMARY The following report summarizes an evaluation of the Mayo Steam Electric Plant (Mayo Plant) seepage flow surrounding the ash basin toward Crutchfield Branch and Mayo Lake. The evaluation included a detailed site reconnaissance to identify potential seeps followed by the collection of flow measurements and representative water quality samples at select locations. The site reconnaissance was conducted during March 2014. Representative seep locations were evaluated for water quality and flow rates on August 27, 2014. Wastewater discharges from the ash basin are permitted by the North Carolina Department of Environment and Natural Resources (NCDENR) Division of Water Resources (DWR) under National Pollution Discharge Elimination System (NPDES) Permit NC0038377. The purpose of the evaluation was to determine additional potential outfalls for inclusion within the permit. Five seep locations were identified during wet weather conditions in early spring of 2014. Two of these locations are the west and east toe drains. The remaining three identified seep locations were dry in August 2014 and could not be sampled. Two additional samples were collected downstream of the two toe drain locations in August 2014. One additional sample was collected from wastewater in the active ash basin. One additional sample was collected from an upstream surface water body which flows to Hyco Lake. The low volume of water characteristic of the seeps coupled with the relatively low constituent concentrations in the samples, suggest that there is little potential to influence water quality of Crutchfield Branch and Mayo Lake. If reasonable potential analyses demonstrate that there is no potential to exceed water quality standards, then Duke Energy proposes to re- evaluate the seep locations listed in this document annually over the next five -year permit cycle. These annual evaluations would be documented and would verify the condition of the existing seeps and determine the presence of new seeps. DWR will be promptly notified if any new seeps are identified or any significant changes are observed for the existing seeps. If any existing or newly identified seeps are determined to reach Crutchfield Branch and Mayo Lake and the seepage has reasonable potential to exceed a water quality standard, Duke Energy will take measures to either (1) stop the seepage, (2) capture and route the seep so that it is discharged through a NPDES permitted outfall, or (3) address the seep using Best Management Plans approved by DWR. P: \Duke Energy Progress.1026 \ALL NC STIES \NPDES Permit Deliverables \Mayo \Seep Report \Mayo Seep Monitoring Report.docc Seep Monitoring Report October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 1.0 INTRODUCTION Duke Energy Progress, Inc. owns and operates the Mayo Steam Electric Plant (Mayo Plant) located on approximately 2,200 acres in northern North Carolina near Roxboro, North Carolina. A large portion of the plant acreage encompasses Mayo Lake, a reservoir formed when Mayo Creek was dammed. The Mayo Plant is located in Person County along the west bank of Mayo Lake, north of Roxboro, east of Boston Road, and south of the North CarohnaNirginia state border. The site location is shown on Figure 1. The Mayo Plant began operations in 1983 with a single -unit, coal -fired steam turbine. Ash generated from coal combustion has been stored on -site in an ash basin. Dry ash has also been transported to the Roxboro Plant for disposal in a lined landfill. It is anticipated that beginning in Fall 2014, dry ash will be placed on -site in a lined landfill. ' Wastewater discharges from the ash basin are permitted by the North Carolina Department of Environment and Natural Resources (NCDENR) Division of Water ' Quality (DWQ) under National Pollution Discharge Elimination System (NPDES) Permit NC0038377. This report summarizes an evaluation of seepage flows associated with the Mayo Plant ' ash basin. The evaluation included a detailed site reconnaissance to identify potential seeps, flow measurements of identified seeps, and collection of seep water and other surface water with chemical analysis of collected samples. The site reconnaissance was conducted in March 2014. Seep sampling and flow measurements were conducted on ' August 27, 2014. 1 Page 1 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ Seep Report \Mayo Seep IMonitoring Report.docx Seep Monitoring Report October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 2.0 SEEP MONITORING 2.1 Seep Identification A detailed reconnaissance of the outside perimeter of the ash basin present at the Mayo Plant was conducted in March 2014 for the purpose of identifying and locating potential seeps originating from the ash basin. Identified seeps were described, photographed, noted on a field map, and surveyed as to location using GPS (Table 1). Identified seeps were further evaluated on August 27, 2014. During the August evaluation, it was observed that three of the seeps identified in February 2014 were dry, reflecting an intermittent or seasonal nature. The locations of seeps identified are presented on Figure 2. 2.2 Seep Flow Measurement Flow measurements were made in August 2014 at water - bearing seep locations using either a Son -Tek F1owTracker ® Acoustic Doppler Velodmeter or the timed - volumetric method. The F1owTracker® measures stream velocity and discharge using sound waves. The timed- volumetric method was used at four locations where the flow was constrained in a location that prevented the F1owTracker® from recording a signal without interference. ' The timed- volumetric method was employed by collecting a volume of water from the discharge of the seep directly into an appropriately sized container (graduated cylinder or bucket). The entire seep flow was routed to the container. The amount of time (in ' seconds) required to collect a known volume of water was recorded. A minimum of five timed volumes were recorded and the flow rate for the seep was calculated based on an average of the timed volume measurements. The F1owTracker® was used to measure seep flows at two locations. The method is designed for streams that can be waded following established procedures such as the U.S. Geological Survey standards. Use of the FlowTracker® was generally limited to channels of sufficient width (approximately 0.5 feet or greater) and depth (approximately 0.17 feet or greater). Flow measurements (water velocity and depth) within quality control bounds of the instrument were recorded manually for estimation of discharge at a seep. Locations were selected where channel banks were fairly parallel. The channel width was measured at the water line and recorded. If the channel width was less than one foot, the average depth was recorded and three velocity measurements were taken. The average of the three velocity measurements and the channel volume (depth and width) were used to calculate the flow rate at a given location. Page 2 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo\ Seep Report\Mayo Seep Monitoring Report.docx Seep Monitoring Report October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra If the channel width at the water line was between 1.0 and 2.5 feet, velocity and depth were recorded at a minimum of three locations spaced evenly across the channel. If the channel width was between 2.5 and 5 feet, velocity and depth were recorded at a ' minimum of five evenly spaced locations. Consistent with USGS methodology, velocity measurements were collected at 60% of water depth. The averages of the calculated flows (in MGD) for seeps with measurable flow in ' August 2014 are included in Table 2. Seepage flow is generally variable. Flow may increase or decrease depending on the amount of rainfall, groundwater levels, weather conditions, and other variables. ' 2.3 Seep Sample Collection Six locations with sufficient water for sample recovery were sampled during August ' 2014 for water quality analysis. The sample locations are described in Table 1 and shown on Figure 2. ' To prevent dilution from stormwater runoff into seep flows, samples were collected during a period preceded by low precipitation. For the week preceding the August ' sample collection, 0.37 inches of rain fell in the area as recorded at the Person County Airport (Roxboro, NC), located about fifteen miles south of the Mayo Plant. ' Samples were collected from the seep flows directly into sample containers with the exception of the sample from location 5-04. A peristaltic pump and disposable tubing were used to sample S -04 to sample turbidity at this location. For the directly sampled locations, care was taken to avoid disturbing and entraining particulate soil and sediment. During sample collection, in -situ field parameters (temperature, pH, and ' specific conductance) were measured utilizing a YSI Pro Plus multi- function meter. Turbidity was also measured in the field using a Hach 2100P turbidimeter. ' Laboratory analyses were conducted by Duke Energy Analytical Laboratory and Pace Analytical Laboratories (NC Wastewater Certifications #248 and 12). A summary of the laboratory and field data is provided in Table 2. A listing of analytical parameters and ' associated methods are included in Table 3. Sample handling, storage, and preservation methods are summarized in Appendix A. 1 Page 3 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ Seep Report\Mayo Seep IMonitoring Report.dooc Seep Monitoring Report October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 3.0 RECOMMENDATIONS The very low flow of water characteristic of each seep location suggests minimal potential to influence water quality in Crutchfield Branch and Mayo Lake. If ongoing analyses demonstrates that there is no potential to exceed water quality standards, Duke Energy proposes to re- evaluate the identified seep locations listed in this document annually over the next five -year permit cycle. These annual evaluations would be documented and would verify the condition of the existing seeps and determine the presence of any newly developed seeps. DWR will be promptly notified if new seeps are identified or any significant changes are observed for the existing seeps. If any existing or newly identified seeps are determined to reach Crutchfield Branch or Mayo Lake and the seepage has reasonable potential to exceed a water quality standard, Duke Energy will take measures to either (1) stop the seepage, (2) capture and route the seep so that it is discharged through a NPDES permitted outfall, or (3) address the seep using Best Management Plans approved by DWR. I Page 4 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ Seep Report\Mayo Seep Monitoring Report.docx FIGURES rjl _ PROPERTY BOUNDARY pr hr ti > Z, pp �� y �,J �'�� � -�," 1 'i 1. � =rte.,.- ..�,�-, mot` ` - �_C 1'� "'� J.. ��. 1 •�;, � ,� �, I - - '��{• --� `."7ii -i ?Uf 1 � • � � 446 WASTE i�4P ter 1 BOUNDARY : 500' COMPLIANCE BOUNDARY r 1 •. I -_ `• . sp.'s . _ i ,�.. - - 14, "mac; r� �g --� � � - ~`-'....�.•''Y�I_ / `+c. � , ��. � �' 3 , r �,..� � .. \ I - jam' � � �, -.. t I ' - • Syr �. _ � ��• �'�il '`�.- 1 ~:\ 1„t,�- �y';`;> : <a r� i J t+1 � .,�� "\ ,may •/ -� Paf: y 1 `, `1 _..il J - ���� �� -�\ 'l � °tl' \�� =ff. `, .' � �' `S.j�.s � )t •� . z "� y� -. f _ SOURCE: uSGS TOPOGRAPHIC MAP OBTAINED FROM THE NRCS GEOSPATIAL DATA ? GATEWAY AT http>7datagateway rres.usda gov' -�= _- MAYO LMCE POWER PLANT ' PERSON NTY FIGURE 1 SITE LOCATION MAP MAYO STEAM ELECTRIC PLANT 10600 BOSTON RD 1 Terra CLU STER ROXBORO, NORTH CAROLINA SPRINGS, VA QUADRANGLE 143 RIVER STREET. SUITE 220 GREENVILLE. SOUTH CAROLINA PRAWN Sv s MANAGER KATHY COTE Yv1a10-08 GRAPHIC SCALE ' PHONE 864421- 9999 PROJECT F* I kSlT NA N, MAP DA CONTOUR i 1987 ,L sore 1000 0 1000 2000 www.synterracorp.com uvouT `Ta s,sPeuxwlioR� MAP b11E suet Y as Sae ard. rtasva '�1 11. . TABLES = = = = M = M M = = = = = = = = s TABLE 1 SEEP LOCATIONS AND DESCRIPTIONS MAYO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, INC., ROXBORO, NORTH CAROLINA SEEP ID LATITUDE LONGITUDE FLOW DESCRIPTION DESCRIPTION Outfall 004 36.52931 - 78.88899 Continuous Stormwater Outfall 004; appears to flow towards Mayo Lake, Outfall 005 36.52775 - 78.88810 Continuous Stormwater Outfall 005; appears to flow towards Mayo Lake. S -01 36.53890 - 78.89351 Continuous West toe drain; appears to flow towards Crutchfield Branch. S -02 36.53890 - 78.89341 Continuous East toe drain; appears to flow towards Crutchfield Branch. S -02A 36.53801 - 78.89161 Intermittent Seepage area about 20 feet upslope from east toe drain; flowing in March, no flow in August; some iron staining. S -02B 36.53800 - 78.89137 Intermittent Seepage and runoff area upslope from east toe drain where water flows beaneath rip rap along tree line; flowin in March; no flow in August. S -03 36.53865 - 78.89071 Continuous Flow from channel downstream of East toe drain; appears to flow towards Crutchfield Branch. S -04 36.53890 - 78.89341 Continuous Flow from channel downstream of West toe drain; appears to flow towards Crutchfield Branch. S -06 36.52197 - 78.88526 Continuous Flow that originates south of plant; appears to flow towards Mayo Lake. S -07 36.52180 - 78.89215 Intermittent Seepage area downslope from former production well location; flow present In March, no flow present in August; flow towards southeast where it appears to merge with flow towards Mayo Lake (S -06). WASTEWATER SAMPLE ID LATITUDE LONGITUDE FLOW DESCRIPTION DESCRIPTION S -05 36.535039 - 78.891693 F Ash Basin Water sample collected from southeast side of ash basin. Pranararl hv' lAW Checked bv: KWW Page 1 of 1 i,: \Duke Energy Progress. 1026\ALL NC SITES \NPDES Permit Dehverdbles \Mayo \Seep Report\Tables \Table 1 - Seep Locations and Descriptions TABLE 2 SEEP FLOWS AND ANALYTICAL RESULTS, AUGUST 27, 2014 MAYO STEAM ELECTRIC PLANT ROXBORO, NORTH CAROLINA NM - Not Measured NF - Flow not present during this sampling event or too low to be measured TV - Timed Volume AV - Area Velocity MGD - Million Gallons Per Day =Appears to flow to Crutchfield Branch Appears to flow to Mayo lake P: \Duke Energy Progress.1026\ALL NC SITES \NPDES Pennit Deliverables \Mayo \Seep Report\Tables \Table 2 - Seeps Analytical Rleglisl4ifid MAP ID S -01 S -02 S -02 Duplicate 5-03 S -04 S -OS Flow MGD 0.00106 0.05261 0.00410 0.00362 0.00362 0.02456 NF NM U.O110Z Flow Measurement Method TV TV TV TV TV AV -- -- AV Od & Grease mg /L < 5.0 < 5.0 5.0 < 5.0 5.0 < 5.0 COD mg /L 20 mg /L 58 mg/l. 0.15 1 20 < 20 20 < 20 < 20 Chloride Fluoride 95 < 0.1 95 0.1 66 0.14 52 0.16 94 0.30 Sulfate mg/ L 46 47 47 36 41 61 Mercury (Hg) Aluminum (Al) ug /L < 0.05 mg /L 0.020 0.05 0.009 < 0.05 0.008 0.05 0.066 0.05 0.124 < 0.05 0.021 Barium (be) mg /L 0.126 0.165 0.161 0.067 0.144 0.073 Boron (B) mg /L 1.51 1.67 1.63 1.34 1.28 2.13 Calcium (Ca) mg /L 23.2 mg /L(CaCO3) 90.0 31.9 139 31.4 137 29.6 120 22.2 86.9 48.6 187 Hardness Iron (Fe) mg /L 13.4 4.08 3.97 0.485 11.4 0.028 Magnesium (Mg) mg /L 7.80 14.5 14.1 11.3 7.65 15.9 Manganese (Mn) mg /L 2.78 2.37 2.32 1.07 3.18 0.020 0.005 1 Zinc (Zn) mg /L < 0.005 0.014 0.013 < 0.005 0.005 Antimony (Sb) ug /L < 1 < 1 1 1 1 Arsenic (AS) Cadmium (Cd) uq /L 2.64 ug /L < 1 < 1 < 1 1 1 < 1 < 1 1.97 1 3.03 1 1 Chromium (Cr) ug /L < 1 < 1 < 1 1 1 -Copper (Cu) ug /L < 1 1 1 1 1 1.56 Lead (Pb) ug /L < 1 ug /L < 1 < 1 1 < 1 1 1 Molybdenum (Mo) < 1 1 1 - 1 14.0 Nickel (NI) ug /L 1.20 2.41 2.04 1 1.37 1 Selenlum (Se) ug /L 1 ug /L < 0.2 < 1 1 1 1 1 Thallium (TI) Low Level < 0.2 1 0.2 0.2 1 0.2 < 0.2 IDS mq /L 270 330 330 250 250 380 TSS mq /L 7.0 5 5 5 22 5 PH Temperature Specific conductance s.u. b.2 °C 19 US /cm 447 S.7 17 477 5.7 17 477 6.4 19 396 6.3 25 405 8.4 27 514 Tur6ldlty NTU 1.21 1.87 1.87 3.25 12.4 1.81 NM - Not Measured NF - Flow not present during this sampling event or too low to be measured TV - Timed Volume AV - Area Velocity MGD - Million Gallons Per Day =Appears to flow to Crutchfield Branch Appears to flow to Mayo lake P: \Duke Energy Progress.1026\ALL NC SITES \NPDES Pennit Deliverables \Mayo \Seep Report\Tables \Table 2 - Seeps Analytical Rleglisl4ifid TABLE 3 SEEP ANALYTICAL METHODS MAYO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, INC., ROXBORO, NORTH CAROLINA PARAMETER METHOD REPORTING LIMIT UNITS LAB COD HACH 8000 20 mg /L Duke Energy Aluminum (Al) EPA 200.7 0.005 mg /L Duke Energy Antimony (Sb) EPA 200.8 1 ug /L Duke Energy Arsenic (As) EPA 200.8 1 ug /L Duke Energy Barium (Ba) EPA 200.7 0.005 mg /L Duke Energy Boron (B) EPA 200.7 0.05 mg /L Duke Energy Cadmium (Cd) EPA 200.8 1 ug /L Duke Energy Calcium (Ca) EPA 200.7 0.1 mg /L Duke Energy Chloride EPA 300.0 5 mg /L Duke Energy Chromium (Cr) EPA 200.8 1 ug /L Duke Energy Copper (Cu) EPA 200.8 1 ug /L Duke Energy Fluoride EPA 300.0 1 mg /L Duke Energy Hardness EPA 200.7 0.19 mg /L (CaCO3) Duke Energy Iron (Fe) EPA 200.7 0.01 mg /L Duke Energy Lead (Pb) EPA 200.8 1 ug /L Duke Energy Magnesium (Mg) EPA 200.7 0.05 mg /L Duke Energy Manganese (Mn) EPA 200.7 0.005 mg /L Duke Energy Mercury (Hg) EPA 245.1 0.05 ug /L Duke Energy Molybdenum (Mo) EPA 200.8 1 ug /L Duke Energy Nickel (Ni) EPA 200.8 1 ug /L Duke Energy Oil and Grease EPA 1664B 5.0 mg /L Pace Analytical Selenium (Se) EPA 200.8 1 ug /L Duke Energy Sulfate EPA 300.0 5 mg /L Duke Energy TDS SM2540C 25 mg /L Duke Energy Thallium (TI) Low Level EPA 200.8 0.2 ug /L Duke Energy TSS SM2540D 5 mg /L Duke Energy Zinc (Zn) EPA 200.7 0.005 mg /L Duke Energy Prepared By: RBI Checked By: KWW P: \Duke Energy Progress.1026\ALL NC SITES \NPDES Permit Deliverables \Mayo \Seep Report\Tables \Table 3 - Analytical Methods Page 1 of 1 APPENDIX A ' ANALYTICAL SAMPLE HANDLING, ' PRESERVATION, AND HOLDING TIME REQUIREMENTS Parameter name Containerl Preservation 3 Maximum holding time' Table IB— Inorganic Tests: 1. Acidity P FP, G Cool. :56 'C'" 14 days 2. Alkalinity P, FP, G Cool, 56 'Cte 14 days. 4. Ammonia P FP G Cool. 56 'C".. HSO, to pH <2 28 days 9. Biochemical oxygen demand P, FP, G Cool. 56 'C18 48 hours. 10. Boron P FP, or Quartz HNO3 to pH <2 6 months 11. Bromide P, FP, G None required 28 days. 14. Biochemical oxygen demand, carbonaceous P FP G Cool. 56 'C" 48 hours 15. Chemical oxygen demand P, FP, G Cool, 56'C78, H2SO4 to pH <2 28 days. 16. Chloride P, FP, G None required 28 days. 17. Chlorine, total residual P, G None required Analyze within 15 minutes. 21. Color P. FP, G Cool. 56 'C" 48 hours. 23 -24. Cyanide, total or available (or CATC) and free P, FP, G Cool, :56 'C18, NaOH to pH >105 14 days. 8, reducing agent if oxidizer present 25. Fluoride P None required 28 days 27. Hardness P, FP, G HNO3 or H2SO4 to pH <2 6 months. 28. Hydrogen ion (pH) R FP, G None required Analyze within 15 minutes 31, 43. Kjeldahl and organic N P, FP, G Cool, 56'C18, H2SO4 to pH <2 28 days. Table IB— Metals:' 18. Chromium VI P, FP, G Cool, 56'C18, pH = 9.3-9 72' 28 days. 35. Mercury (CVAA) P. FP G HNO3 to pH <2 28 days 35. Mercury (CVAFS) FP, G; and FP- 5 mUL 12N HCl or 5 mUL BrCI" 90 days." lined cap" 3, 5 -8, 12, 13, 19, 20, 22, 26, 29, 30, 32 -34, 36, 37, 45, P FP. G HNO3 to pH <2, or at least 24 6 months 47, 51, 52, 58 -60, 62, 63, 70 -72, 74, 75. Metals, except hours prior to analysis" boron, chromium VI, and mercury 38. Nitrate P. FP, G Cool, 56'C18 48 hours. 39. Nitrate - nitrite P, FP, G Cool. 56 'C' ", HSO, to pH <2 28 days. 40. Nitrite P, FP, G Coot, so °�," 48 hours. 41. Oil and grease G Cool to 56'C' ". HCI or H2SO, to 28 days PH <2 42. Organic Carbon P, FP, G Cool to 56'Ct8, HCl, H,SO4, or 28 days. H3PO4 to pH <2 44. Orthophosphate P FP. G Cool. to <6 C"" Filter within 15 minutes Analyze within 48 hours. 46. Oxygen, Dissolved Probe G. Bottle and top None required Analyze within 15 minutes. 47. Winkler G Bottle and top Fix on site and store in dark 8 hours 48. Phenols G Cool, 56 °C", H2SO4 to pH <2 28 days. 49. Phosphorous (elemental) G Cool. 56 'C" 48 hours 50. Phosphorous, total P, FP, G Cool, 56 'C18, H2SO4 to pH <2 28 days. 53. Residue, total P FP, G Cool. 56 '0 7 days. 54. Residue, Filterable P, FP, G Cool, 56 °C1O 7 days. 55. Residue, Nonfilterable (TSS) P. FP, G Cool, :56 'C" 7 days. 56. Residue, Settleable P, FP, G Cool, 56 'C1e 48 hours. 57. Residue, Volatile P. FP, G Cool. 56 'C" 7 days 61. Silica P or Quartz Cool, <_6 °C18 28 days. 64. Specific conductance P, FP, G Cool. 56 'C" 28 days. 65. Sulfate P, FP, G Cool, :56 'C78 28 days. 66. Sulfide P, FP, G Cool. 56 'C", add zinc acetate 7 days. plus sodium hydroxide to pH >9 67. Sulfite P, FP, G None required Analyze within 15 minutes. 68. Surfactants P, FP, G Cool. <_6 'C" 48 hours 69. Temperature P, FP, G None required Analyze. 73. Turbidity P, FP, G Cool. 56 C" 48 hours ' "P" is for polyethylene, "FP" is fluoropolymer (polytetrafluoroethylene (PTFE); Teflon "). or other fluoropolymer, unless stated otherwise in this Table 11, "G" is glass, "PA' is any plastic that is made of a sterilizable material (polypropylene or other autoclavable plastic), "LDPE" is low density polyethylene 'Except where noted in this Table II and the method for the parameter. preserve each grab sample within 15 minutes of collection For a composite sample collected with an automated sample (e.g , using a 24 -hour composite sample, see 40 CFR 122.21(g)(7)(i) or 40 CFR Part 403 Appendix E), refrigerate the sample at 56 'C during collection unless specified otherwise in this Table II or in the method(s). For a composite sample to be split into separate aliquots for preservation and/or analysis. maintain the sample at 56 'C. unless specified otherwise in this Table 11 or in the method(s). until collection. splitting and preservation is completed Add the preservative to the sample container prior to sample collection when the preservative will not compromise the integrity of a grab sample. a composite sample. or aliquot split from a composite sample within 15 minutes of collection If a composite measurement is required but a composite sample would compromise sample integrity individual grab samples must be collected at prescribed time intervals (e.g 4 samples over the course of a day. at 6 -hour intervals) Grab samples must be analyzed separately and the concentrations averaged Alternatively. grab samples may be collected in the field and composited in the laboratory if the compositing procedure produces results equivalent to results produced by arithmetic averaging of results of analysis of individual grab samples. For examples of laboratory compositing procedures. see EPA Method 1664 Rev A (oil and grease) and the procedures at 40 CFR 141.34(f)(14)(iv) and (v) (volatile organics). 'When any sample is to be shipped by common carrier or sent via the U S Postal Service, it must comply with the Department of Transportation Hazardous Materials Regulations (49 CFR part 172). The person offering such material for transportation is responsible for ensuring such compliance. For the preservation requirement of Table 11, the Office of Hazardous Materials. Materials Transportation Bureau. Department of Transportation has determined that the Hazardous Materials Regulations do not apply to the following materials: Hydrochloric acid (HCI) in water solutions at concentrations of 0.04% by weight or less (pH about 1.96 or greater, Nitric acid (HNO,) in water solutions at concentrations of 0.15% by weight or less (pH about 1 62 or greater): Sulfuric acid (H2SO,) in water solutions at concentrations of 0 35% by weight or less (pH about 1.15 or greater): and Sodium hydroxide (NaOH) in water solutions at concentrations of 0.080% by weight or less (pH about 12.30 or less). °Samples should be analyzed as soon as possible after collection. The times listed are the maximum times that samples may be held before the start of analysis and still be considered valid. Samples may be held for longer periods only if the permittee or monitoring laboratory has data on file to show that, for the specific types of samples under study, the analytes are stable for the longer time, and has received a variance from the Regional Administrator under Sec. 136.3(e). For a grab sample, the holding time begins at the time of collection. For a composite sample collected with an automated sampler (e g., using a 24 -hour composite sampler, see 40 CFR 122.21(g)(7)(i) or 40 CFR part 403, Appendix E). the holding time begins at the time of the end of collection of the composite sample. For a set of grab samples composited in the field or laboratory, the holding time begins at the time of collection of the last grab sample in the set. Some samples may not be stable for the maximum time period given in the table. A permittee or monitoring laboratory is obligated to hold the sample for a shorter time if it knows that a shorter time is necessary to maintain sample stability. See 136.3(e) for details. The date and time of collection of an individual grab sample is the date and time at which the sample is collected For a set of grab samples to be composited. and that are all collected on the same calendar date, the date of collection is the date on which the samples are collected. For a set of grab samples to be composited, and that are collected across two calendar dates, the date of collection is the dates of the two days: e.g., November 14 -15 For a composite sample collected automatically on a given date, the date of collection is the date on which the sample is collected For a composite sample collected automatically, and that is collected across two calendar dates, the date of collection is the dates of the two days: e g . November 14- 15. For static - renewal toxicity tests. each grab or composite sample may also be used to prepare test solutions for renewal at 24 h, 48 h, and /or 72 h after first use, if stored at 0-6 'C, with minimum head space. 'ASTM D7365 -09a specifies treatment options for samples containing oxidants (e.g., chlorine). Also. Section 9060A of Standard Methods for the Examination of Water and Wastewater (20th and 21 st editions) addresses dechlorination procedures. 'Sampling, preservation and mitigating interferences in water samples for analysis of cyanide are described in ASTM D7365 -09a. There may be interferences that are not mitigated by the analytical test methods or D7365 -09a. Any technique for removal or suppression of interference may be employed, provided the laboratory demonstrates that it more accurately measures cyanide through quality control measures described in the analytical test method Any removal or suppression technique not described in D7365 -09a or the analytical test method must be documented along with supporting data. 'For dissolved metals filter grab samples within 15 minutes of collection and before adding preservatives. For a composite sample collected with an automated sampler (e.g . using a 24 -hour composite sampler. see 40 CFR 122.21(g)(7)(1) or 40 CFR Part 403, Appendix E), filter the sample within 15 minutes after completion of collection and before adding preservatives. If it is known or suspected that dissolved sample integrity will be compromised during collection of a composite sample collected automatically over time (e.g., by interchange of a metal between dissolved and suspended forms). collect and filter grab samples to be composited (footnote 2) in place of a composite sample collected automatically. 'Guidance applies to samples to be analyzed by GC, LC, or GC /MS for specific compounds. 91f the sample is not adjusted to pH 2, then the sample must be analyzed within seven days of sampling. 10The pH adjustment is not required if acrolein will not be measured Samples for acrolein receiving no pH adjustment must be analyzed within 3 days of sampling. "When the extractable analytes of concern fall within a single chemical category, the specified preservative and maximum holding times should be observed for optimum safeguard of sample integrity (i.e., use all necessary preservatives and hold for the shortest time listed). When the analytes of concern fall within two or more chemical categories, the sample may be preserved by cooling to 56 'C, reducing residual chlorine with 0.008% sodium thiosulfate. storing in the dark. and adjusting the pH to 6 -9: samples preserved in this manner may be held for seven days before extraction and for forty days after extraction. Exceptions to this optional preservation and holding time procedure are noted in footnote 5 (regarding the requirement for thiosulfate reduction), and footnotes 12, 13 (regarding the analysis of benzidine) 121f 1,2- diphenylhydrazine is likely to be present, adjust the pH of the sample to 4.0 ±0.2 to prevent rearrangement to benzidine. "Extracts may be stored up to 30 days at <0 'C. "For the analysis of diphenylnitrosamine, add 0.008% NaS203 and adjust pH to 7 -10 with NaOH within 24 hours of sampling ''The pH adjustment may be performed upon receipt at the laboratory and may be omitted if the samples are extracted within 72 hours of collection. For the analysis of aldrin, add 0.008% Na2S203 1pPlace sufficient ice with the samples in the shipping container to ensure that ice is still present when the samples arrive at the laboratory. However. even if ice is present when the samples arrive, immediately measure the temperature of the samples and confirm that the preservation temperature maximum has not been exceeded In the isolated cases where it can be documented that this holding temperature cannot be met, the permittee can be given the option of on -site testing or can request a variance. The request for a variance should include supportive data which show that the toxicity of the effluent samples is not reduced because of the increased holding temperature Aqueous samples must not be frozen. Hand - delivered samples used on the day of collection do not need to be cooled to 0 to 6 'C prior to test initiation. "Samples collected for the determination of trace level mercury ( <100 ng /L) using EPA Method 1631 must be collected in tightly - capped fluoropolymer or glass bottles and preserved with BrCI or HCI solution within 48 hours of sample collection. The time to preservation may be extended to 28 days if a sample is oxidized in the sample bottle. A sample collected for dissolved trace level mercury should be filtered in the laboratory within 24 hours of the time of collection. However, if circumstances preclude overnight shipment, the sample should be filtered in a designated clean area in the field in accordance with procedures given in Method 1669. If sample integrity will not be maintained by shipment to and filtration in the laboratory. the sample must be filtered in a designated clean area in the field within the time ' period necessary to maintain sample integrity A sample that has been collected for determination of total or dissolved trace level mercury must be analyzed within 90 days of sample collection "Aqueous samples must be preserved at 56 'C. and should not be frozen unless data demonstrating that sample freezing does not adversely impact sample integrity is maintained on file and accepted as valid by the regulatory authority Also. for purposes of NPDES monitoring. the specification of °5'C is used in place of the "4 'C" and '<4 'C" sample temperature requirements listed in some methods. It is not necessary to measure the sample temperature to three significant figures (1 /100th of 1 degree): rather, three significant figures are specified so that rounding down to 6 'C may not be used to meet the 56 C requirement. The preservation temperature does not apply to samples that are analyzed immediately (less than 15 minutes) "`An aqueous sample may be collected and shipped without acid preservation. However, acid must be added at least 24 hours before analysis to dissolve any metals that adsorb to the container walls. If the sample must be analyzed within 24 hours of collection. add the acid ' immediately (see footnote 2). Soil and sediment samples do not need to be preserved with acid The allowances in this footnote supersede the preservation and holding time requirements in the approved metals methods 2"To achieve the 28 -day holding time. use the ammonium sulfate buffer solution specified in EPA Method 218.6 The allowance in this footnote supersedes preservation and holding time requirements in the approved hexavalent chromium methods. unless this supersession ' would compromise the measurement, in which case requirements in the method must be followed 21Holding time is calculated from time of sample collection to elution for samples shipped to the laboratory in bulk and calculated from the time of sample filtration to elution for samples filtered in the field. 22 Sample analysis should begin as soon as possible after receipt sample incubation must be started no later than 8 hours from time of collection. ' 23For fecal coliform samples for sewage sludge (biosolids) only. the holding time is extended to 24 hours for the following sample types using either EPA Method 1680 (LTB -EC) or 1681 (A -1): Class A composted, Class B aerobically digested. and Class B anaerobically digested. 2'The immediate filtration requirement in orthophosphate measurement is to assess the dissolved or bio-available form of orthophosphorus (i.e., that which passes through a 0.45 - micron filter), hence the requirement to filter the sample immediately upon collection (i.e., within 15 minutes of collection). ' [38 FR 28758 Oct 16, 1973 410 syn,T(erra GROUNDWATER MONITORING PROGRAM SAMPLING, ANALYSIS, AND REPORTING PLAN FOR MAYO STEAM ELECTRIC PLANT 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 NPDES PERMIT #NC0038377 PREPARED FOR DUKE ENERGY PROGRESS, INC. RALEIGH, NORTH CAROLINA DUKE ENERGY. PROGRESS SUBMITTED: OCTOBER 2014 J 7- SEAL w. . �yy11111111il", `�,:•o�N CARp���, =� r J�EHS 4S s SEAL 1425 P i 10t 0 4 �t m Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra TABLE OF CONTENTS SECTION PAGE 1.0 Introduction .................................................................................................... ..............................1 2.0 Site Description .............................................................................................. ..............................2 2.1 Plant and Ash Basin Areas ...................................................................... ..............................2 2.2 Ash Basin Description ............................................................................. ............................... 2 3.0 Site Geology and Hydrogeology ................................................................. ..............................3 3.1 Geologic Framework ............................................................................... ............................... 3 3.2 Hydrogeologic Framework ..................................................................... ..............................4 4.0 Monitoring Program ..................................................................................... ............................... 5 4.1 Regulatory Requirements for Groundwater Monitoring ................... ..............................5 4.2 Description of Groundwater Monitoring System ................................ ..............................6 4.3 Monitoring Frequency ............................................................................ ............................... 7 4.4 Sample Parameters and Methods .......................................................... ............................... 7 4.5 Data Quality Objectives .......................................................................... ............................... 7 5.0 Sampling Procedures .................................................................................... ............................... 8 5.1 Sampling Equipment and Cleaning Procedures .................................. ..............................8 5.2 Groundwater Sampling ........................................................................... ..............................8 5.2.1 Development of Monitoring Wells ................................................. ............................... 8 5.2.2 Groundwater Level and Total Depth Measurements .................. ............................... 8 5.2.3 Well Purging and Sampling ............................................................ ............................... 9 5.3 Sample Collection .................................................................................... .............................10 5.4 Sample Containers, Volume, Preservation, and Holding Time ........ .............................10 5.5 Sample Tracking ...................................................................................... .............................10 5.6 Sample Labeling ...................................................................................... .............................10 5.7 Field Documentation ............................................................................. ............................... 11 5.8 Chain -of- Custody Record ....................................................................... .............................12 5.9 Sample Custody, Shipment, and Laboratory Receipt ........................ .............................12 6.0 Analytical Procedures .................................................................................. .............................14 7.0 Internal Quality Control Checks ................................................................ .............................15 8.0 Validation of Field Data Package .............................................................. .............................17 9.0 Validation of Laboratory Data .................................................................... .............................18 10.0 Report Submittal ........................................................................................... .............................19 11.0 References .................................................................................................... ............................... 20 Page i P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NC0038377 SynTerra List of Figure 1. Figure 2. Figure 3. Figure 4. Figure 5. Figure 6. Figure 7. Figures Site Location Map Sample Location Map Typical Monitoring Well Construction Details Example Groundwater Monitoring Data Sheet Example Field Sampling Calibration Form Chain -of- Custody Record and Analysis Request Form North Carolina Groundwater Sampling Checklist ' List of Tables Table 1. Monitoring Well Information Table 2. Sample Parameters, Analytical Methods, Containers, Preservatives, and ' Holding Times List of Appendices ' Appendix A Boring Logs and Well Construction Records Appendix B Permit Condition A (9) Attachment XX, Version 1.0, dated March 17, 2011 1 Page ii P: \ Duke Energy Progress.1026 \ ALL NC SITES\ NPDES Permit Deliverables \ Mayo \ GW Monitoring Plan \ Mayo IGW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 1.0 INTRODUCTION This Groundwater Monitoring Program Sampling, Analysis, and Reporting Plan (Plan) is developed to support the Duke Energy Progress, Inc. (Duke Energy) requirement for groundwater monitoring around the Mayo Steam Electric Plant (Mayo Plant) ash basin operated under NPDES Permit NC0038377. This Plan describes the groundwater monitoring network, methodologies of field sampling, record - keeping protocols, analytical procedures, data quality objectives, data validation, and reporting that will be used for the Mayo Plant ash basin groundwater monitoring program. Page 1 P: \Duke Energy Progress.1026 \ALL NC STIES \NPDES Permit Deliverables\ Mayo\ GW Monitoring Plan \Mayo GW Monitoring Plan.dw( Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' 2.0 SITE DESCRIPTION 2.1 Plant and Ash Basin Areas ' Duke Energy Progress, Inc. owns and operates the Mayo Plant located on approximately 2,200 acres in northern North Carolina near Roxboro, North Carolina. A large portion of the plant acreage encompasses the Mayo reservoir. The Mayo Plant is ' located in Person County along the west bank of Mayo Lake, north of Roxboro, east of Boston Road, and south of the North CarohnaNirginia state border. The site location is shown on Figure 1. The Mayo Plant began operations in 1983 with a single -unit, coal -fired steam turbine. Ash generated from coal combustion has been stored on -site in an ash basin. Dry ash has also been transported to the Roxboro Plant for disposal in a lined landfill. It is anticipated that beginning in Fall 2014, dry ash will be disposed on -site in a lined landfill. 2.2 Ash Basin Description Ash generated from coal combustion at the Mayo Plant has been stored in an on -site ash basin. The ash basin was constructed and began receiving ash in 1983. The ash basin is located north of the plant operational area and west of Mayo Lake. A former permitted landfill is located on the east side of the ash basin. The 500 -foot compliance boundary encircles the ash basin as shown on Figure 2. Wastewater discharges from the ash basin are permitted by the North Carolina Department of Environment and Natural Resources (NCDENR) Division of Water Resources (DWR) under National Pollution Discharge Elimination System (NPDES) Permit NC0038377. Permitted outfall locations are shown on Figure 2. Page 2 P:\Duke Energy Progress.1026 \ ALL NC SITES \NPDES Permit Deliverables \ Mayo\GW Monitoring Plan\Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 3.0 SITE GEOLOGY AND HYDROGEOLOGY 3.1 Geologic Framework The Mayo Plant is situated in the eastern Piedmont Region of north - central North Carolina. The Piedmont is characterized by well - rounded hills and rolling ridges cut by small streams and drainages. Elevations in the area of the Mayo Plant range between 570 feet above mean sea level (msl) near the Plant entrance along Boston Road to 360 feet msl in the Crutchfield Branch stream area on the north side of the Plant. Geologically, the Plant is located at the contact between two regional zones of metamorphosed intrusive rocks: the Carolina Slate Belt (now referred to as Carolina Terrane) on the east and the Charlotte Belt (or Charlotte Terrane) to the west. The majority of the Mayo Plant, including the largest portion of the ash basin and Mayo Lake are situated in the Carolina Terrane (USGS, 2007). The characteristics and genesis of the rocks within these regional metamorphic belts have been the subject of intense study to describe the geology in tectonic, structural, and /or litho- stratigraphic terms (Hibbard, et. al., 2001). Rocks of Charlotte Terrane are characterized by strongly foliated felsic mica gneiss and schist and metamorphosed intrusive rocks. Carolina Terrane rocks in the vicinity of the Plant are typically felsic meta- volcanics and meta - argillites. This is consistent with the description of the geologic nature of the area according to the Geologic Map of North Carolina (1985). The Geologic Map of North Carolina describes the felsic meta - volcanic rock as metamorphosed dacitic to rhyolitic flows and tuffs, light gray to greenish gray; interbedded with mafic and intermediate volcanic rock, meta - argillite and meta - mudstone. The felsic mica gneiss of the Charlotte Terrane is described as being interlayered with biotite and hornblende schist. These general observations are consistent with site - specific observations from well logs for the Mayo Plant. Previous site work indicates that the bedrock encountered in the northwestern portion of the compliance boundary is intermediate meta - volcanic rock and the bedrock of the remainder of the site is felsic meta- volcanics or meta- argillites. Rocks of the region, except where exposed in road cuts, stream channels, and steep hillsides, are covered with unconsolidated material formed from the in -situ chemical and physical breakdown of the bedrock. This unconsolidated material is referred to as saprolite or residuum. Direct observations at the Mayo Plant confirm the presence of residuum, developed above the bedrock, which is generally 10 to 30 feet thick. The residuum extends from the ground surface (soil zones) downward, transitioning through a zone comprised of unconsolidated silt and sand, downward through a Page 3 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo \GW Monitoring Plan\Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' transition zone of partially weathered rock in a silt /sand matrix, down to the contact with competent bedrock. ' 3.2 Hydrogeologic Framework Based on previous activities at the site, subsurface lithology beneath the Plant area is comprised of tan, brown to orange sandy silt and fine to coarse sands grading into ' partially weathered rock and then competent bedrock. The first occurrence of groundwater tends to be within the partially weathered rock or competent bedrock at ' depths ranging from nine to 20 feet below land surface (bls) along the downgradient compliance boundary and greater than 30 feet bls upgradient of the ash basin. Groundwater within the area exists under unconfined, also known as water table, conditions within the residuum and /or saprolite zones and in the fractures and joints of the underlying bedrock. The water table and bedrock aquifers are interconnected. The residuum acts as a reservoir for water supply to the fractures and joints in the underlying bedrock. Shallow groundwater generally flows from local recharge zones in topographically high areas, such as ridges, toward groundwater discharge zones, such as stream valleys. Ridge and topographic high areas may serve as groundwater recharge zones. Groundwater flow patterns in recharge areas tend to develop a somewhat radial pattern from the center of the recharge area outward toward the discharge areas and are expected to mimic surface topography. The closest surface water discharge for the plant is to the north- northeast at Crutchfield Branch and, for the eastern portions of the property, to the east and Mayo Lake. Routine water level measurements and corresponding elevations from the compliance monitoring well network indicate that groundwater flows from upland areas (southwestern portion of the property) towards the northeast and Crutchfield Branch. The approximate groundwater gradient for July 2014 data was 135 feet (vertical change) over 5,500 feet (horizontal distance) or 24.5 feet /1,000 feet as measured from upgradient background well BG -2 to downgradient well CW -2. Groundwater elevation data collected from the two well pairs indicate the vertical gradient tends to be downward or neutral between the transition zone and upper bedrock. Page 4 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo\ GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 4.0 MONITORING PROGRAM 4.1 Regulatory Requirements for Groundwater Monitoring The NPDES program regulates wastewater discharges to surface waters to ensure that surface water quality standards are maintained. The Mayo Plant operates under NPDES Permit NCO038377 which authorizes discharge as follows: Cooling Tower System ( Outfall 001): Less than once per year the cooling towers and circulating water system are drained by gravity and discharged directly to Mayo Lake. Ash Basin Treatment System ( Outfall 002): Outfall 002 discharges directly to Mayo Lake. The ash basin receives ash transport water, coal pile runoff, stormwater runoff, cooling tower blowdown, and various low volume wastes such as boiler blowdown, oily waste treatment, wastes/backwash from the water treatment processes including Reverse - Osmosis (RO) wastewater, plant area wash down water, equipment heat exchanger water, and treated domestic wastewater. Internal Outfall 008: Cooling tower blowdown is directly discharged to the ash basin. Cooling tower blowdown is usually mixed with ash sluice water prior to discharge to the ash basin. Cooling tower blowdown is indirectly discharged to Mayo Lake via the ash basin treatment system ( Outfall 002). Internal Outfall 009: Discharge from the FGD blowdown treatment system. FGD blowdown is indirectly discharged to Mayo Lake via the ash basin treatment system ( Outfall 002). Stormwater Discharge System: The facility is permitted to discharge stormwater to Mayo Lake through the following outfalls: — Outfall 004: Drainage from the outside storage area. — Outfall 005: Drainage from the industrial area and the oil/bottled gas storage area. — Outfalls 006a, 006b, 006c, 006d, and 006e: Drainage from the cooling tower(s) chemical feed building structure and the cooling tower area. — Outfall 010: Drainage from haul road for coal ash, limestone, gypsum, and gaseous anhydrous ammonia. Page 5 P: \ Duke Energy Progress. 1026 \ ALL NC SITES \ NPDES Permit Deliverables\ Mayo \ GW Monitoring Plan \ Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit k NC0038377 SynTerra In addition to surface water monitoring, the NPDES permit requires groundwater monitoring. Permit Condition A (6) Attachment XX, Version 1.0, dated March 17, 2011, lists the groundwater monitoring wells to be sampled, the parameters and constituents to be measured and analyzed, and the requirements for sampling frequency and results reporting. Attachment XX also provides requirements for well location and well construction. The as -built well information is summarized in Table 1 and the constituent list, analytical methods, preservatives and holding times are summarized in Table 2. The well logs for the listed wells are provided in Appendix A. A copy of Attachment XX is included as Appendix B. The compliance boundary for groundwater quality associated with the Mayo Plant ash ' basin is defined in accordance with 15A NCAC 02L .0107(a) as being established at either 500 feet from the waste boundary or at the property boundary, whichever is closer. In accordance with the March 17, 2011 Groundwater Monitoring Plan, analytical results have been submitted to the Department of Water Resources (DWR) before the last day of the month following the date of sampling. In the future, analytical results will be submitted to the DWR within 60 days of the date of sampling. 4.2 Description of Groundwater Monitoring System The current groundwater monitoring plan for the Mayo Plant includes the sampling of 10 wells. These 10 wells include two background wells and eight downgradient wells. The locations of the monitoring wells, the waste boundary, and the compliance boundary are shown on Figure 2. Well construction data is provided in Table 1 and Appendix A. Figure 3 is an example of the construction of a typical monitoring well. Based on water levels measured from site wells, the general direction of groundwater flow is to the northeast, toward Crutchfield Branch. The compliance monitoring wells provide data for the groundwater downgradient of the ash basin. The compliance monitoring network includes two background monitoring wells, BG -1 and BG -2, and eight monitoring wells located in side - gradient and downgradient positions along the compliance boundary. Wells CW -ID and CW -21) were installed in the upper bedrock and were paired with shallow wells CW -1 and CW -2, which were installed above the bedrock, to monitor the vertical hydraulic gradient in the area and aquifer conditions within the shallow bedrock. The remainder of the compliance boundary wells, CW -3, CW -4, CW -5, and CW -6, were installed in the saprolite or residuum, above bedrock. Page 6 P:\Duke Energy Progress. 1026 \ ALL NC SITES\ NPDES Permit Deliverables \ Mayo \ GW Monitoring Plan\ Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 4.3 Monitoring Frequency The monitoring wells will be sampled three times per year in April, July, and November. 4.4 Sample Parameters and Methods The monitoring program consists of sampling and analysis for parameters and constituents identified in Permit Condition A (6), Attachment XX of the NPDES permit (Appendix B). The parameters and the analytical methods are presented in Table 2. It is proposed that monitoring for aluminum be discontinued. Aluminum is a very common, naturally - occurring element in soil and rocks of the area. A preliminary statistical evaluation indicates that aluminum concentrations in site groundwater were determined not to be a statistically significant increase over the background well data set. Further, aluminum is not consistently monitored across the entirety of Duke Energy facilities, and there is no 2L Standard for aluminum. The analytical results for the compliance monitoring program will be compared to the NC 2L Standards or site - specific background concentrations. 4.5 Data Quality Objectives The overall Quality Assurance (QA) objective is to ensure that reliable data of known and acceptable quality are provided. All measurements will be documented to yield results that are representative of the groundwater quality. Data will be calculated and reported in units as required by the North Carolina Department of Environment and Natural Resources (NCDENR). The analytical QA objectives for precision, accuracy, and completeness have been established by the laboratory(s) in accordance with the Environmental Protection Agency (EPA) or other accepted agencies for each measurement variable where possible. The objectives are outlined in the Duke Energy Analytical Laboratory Procedures Manual and are available upon request. Appropriate methods have been selected to meet applicable standards for groundwater quality. Instances may occur, however, in which the condition of the sample will not allow detection of the desired limits for various parameters either because of matrix interference or high analyte concentrations requiring sample dilution. The laboratory(s) will provide sufficient documentation with each data package to notify reviewers about any analytical problems with the data, if needed. Page 7 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo \GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 5.0 SAMPLING PROCEDURES 5.1 Sampling Equipment and Cleaning Procedures Development and sampling equipment shall be selected to ensure that materials are compatible with the sample parameters and comply with state and federal regulatory requirements for sampling. New disposable sampling equipment (peristaltic pump tubing) or a decontaminated stainless steel variable flow submersible pump with new disposable tubing is used for low -flow well sampling. For the non - dedicated equipment used, such as water level tapes and submersible pumps, the equipment is cleaned before and after each use in accordance with standard EPA - approved cleaning procedures for field equipment. This standard is outlined in the Standard Operating Procedures and Quality Assurance Manual, Engineering Support Branch, EPA Region IV, February 1, 1991 as revised December 20, 2011. 5.2 Groundwater Sampling 5.2.1 Development of Monitoring Wells Monitoring wells addressed in this sampling plan have been developed. If new monitoring wells are installed, they will be developed prior to initial sampling. Development removes silt that has settled into the bottom of the well following installation and removes fine silt and clay particles from the well screen and sand -pack surrounding the screen. Well development is necessary to eliminate potential clogging and enhance well performance. Development involves removing an estimated ten or more well volumes from the well using a submersible pump with up- and -down agitation to loosen particles from the well screen. If the turbidity for a well increases over time, the well may be re- developed to restore conditions. 5.2.2 Groundwater Level and Total Depth Measurements Water level measurements are collected and recorded to determine the groundwater elevation and flow direction. Site monitoring wells have been surveyed to determine the elevation of the top of the well casing (TOC). Water level measurements are referenced to the TOC and recorded to the nearest one- hundredth of a foot. Water level measurements are made with an electronic measuring device consisting of a spool of dual- conductor wire and sensor. When the sensor comes Page 8 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo \GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitorine Pro Mayo Steam Electric Plant, NPDES Permit # NCO038377 October 2014 SynTerra in contact with water, the circuit is closed and a meter light and /or buzzer attached to the spool signal the contact. When the signal is sounded, the water level is recorded on the Groundwater Monitoring Data Sheet (Figure 4). To minimize sample turbidity, low flow sample methods are used whenever possible. Using low -flow sampling techniques, the volume of the stagnant water in the well is not calculated and the total well depth is not routinely measured to avoid disturbing the bottom sediments. If conditions indicate a possible problem with the integrity of a well, the total well depth may be measured. 5.2.3 Well Purging and Sampling The selection of purging technique is dependent on the hydrogeologic properties of the aquifer and hydraulic characteristics of each well. Hydraulic conductivity, water column, well volume, screen length, and other information are evaluated to select the purging technique to acquire groundwater representative of the aquifer conditions. At the Mayo Plant, the low -flow purging technique has been selected as the most appropriate method to minimize sample turbidity. During low -flow purging and sampling, groundwater is pumped into a flow - through chamber at flow rates that minimize or stabilize water level drawdown within the well. At the Mayo Plant, low -flow sampling is conducted using a peristaltic pump or low -flow submersible pump with new tubing. The intake for the tubing or pump intake is lowered to the mid -point of the screened interval. A multi - parameter water quality monitoring instrument is used to measure field indicator parameters within the flow - through chamber during purging. Measurements include pH, specific conductance, and temperature. Indicator parameters are measured over time (usually at 3 -5 minute intervals). When parameters have stabilized within ±0.2 pH units and ±10 percent for temperature and specific conductivity over three consecutive readings, representative groundwater has been achieved for sampling. Turbidity is not a required stabilization parameter, however turbidity levels of 10 NTU or less are targeted. The Groundwater Monitoring Data Sheet (Figure 4) is used to record purge data and field measurements. Instrument calibration is performed and documented before the beginning of the sampling event, at midday, and after each sampling event. The pH subsystem is calibrated with three pH standards (pH 4.0, 7.0, and 10.0) bracketing the expected groundwater pH. The pH calibration is then verified using a different Page 9 P:\Duke Energy Progress.1026 \ALL NC SITES\NPDES Permit Deliverables\ Mayo \GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SvnTerra pH 7.0 buffer. The specific conductance subsystem is calibrated using one standard and verified using a different specific conductance buffer. Calibration results are recorded on a Field Sampling Calibration Form (Figure 5). ' 5.3 Sample Collection Groundwater samples are collected after the indicator parameters have stabilized. ' Sampling personnel wear new, clean, disposable, non - powdered nitrite gloves at each location. Samples are collected in the order of the volatilization sensitivity of the ' parameters: • Metals, metalloids, and selenium ' • Sulfate, nitrate and chloride • Total dissolved solids ' Groundwater samples are preserved and stored according to parameter - specific methods and delivered to the laboratory under proper Chain -of- Custody (COC) ' procedures. All pertinent notations, water -level measurements, removed well volumes, and indicator parameters are documented on the Groundwater Monitoring Data Sheet ' (Figure 4). 5.4 Sample Containers, Volume, Preservation, and Holding Time Sample containers supplied by the laboratory shall be new and pre- cleaned as approved by EPA procedures appropriate for the parameters of interest. Table 2 summarizes the sample containers, sample volume, preservation procedures, and holding times required for each type of sample and parameter for the monitoring program. Sample containers will be kept closed until used. Sample containers will be provided by Duke Energy or vendor laboratories. 5.5 Sample Tracking The COC procedures allow for tracking the possession and handling of individual samples from the time of field collection through laboratory analysis and report preparation. Samples are logged by the laboratory with a unique tracking number for ' each sample. An example of the COC Record is provided as Figure 6. 5.6 Sample Labeling ' Sample containers shall be pre - labeled and organized prior to field activities as part of the pre - sampling staging process. As samples are collected, the sampling personnel write the following information directly on the label: sampling date and time, and ' Page 10 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo\ GW Monitoring Plan \Mayo ' GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra initials of sample collector. This information is also recorded on the Groundwater Monitoring Data Sheet (Figure 4) and the COC Record (Figure 6). 5.7 Field Documentation Field documentation from each sampling event is recorded on the Groundwater Monitoring Data Sheets (Figure 4), the Field Sampling Calibration Form (Figure 5), and the Chain -of- Custody Record (Figure 6). Additionally, a Groundwater Sampling Site Checklist (Figure 7), or equivalent, is completed indicating information about the monitoring wells such as proper identification (ID) tag and condition of protective casing and pad. Field notations shall be made during the course of the field work to document the following information: • Identification of well • Well depth • Static water level depth and measurement technique • Well yield - high or low • Purge volume or pumping rate • Sample identification numbers • Well evacuation procedure /equipment • Sample withdrawal procedure /equipment • Date and time of collection • Types of sample containers used • Identification of replicates or blind samples • Preservative(s) used • Parameters requested for analysis • Field analysis data and methods • Sample distribution and transporter • Field observations during sampling event • Name of sample collector(s) • Climatic conditions including estimate of air temperature The Groundwater Monitoring Data Sheet, Field Sampling Calibration Form, and COC Record and Analysis Request Form will be filed by project and date. Recorded entries Page 11 P: \Duke Energy Progress. 1026 \ALL NC STIES \NPDES Permit Deliverables \Mayo\ GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' will be made on electronic forms or on paper forms in indelible ink. Errors on paper documents will be corrected by drawing a line through the error, initialing and dating the correction, and starting a new entry on the next line (if necessary). ' 5.8 Chain -of- Custody Record The COC Record (Figure 6) accompanies the sample(s), traces sample possession from ' time of collection to delivery to the laboratory(s), and clearly identifies which sample containers have been designated for each requested analysis. The record includes the following types of information: • Sample identification number ' • Signature of collector • Date and time of collection ' • Sample type (e.g., groundwater, immiscible layer) • Identification of well ' • Number of containers • Parameters requested for analysis ' • Preservative(s) used • Signature of persons involved in the chain of possession ' • Inclusive dates of possession 5.9 Sample Custody, Shipment, and Laboratory Receipt ' For the purpose of these procedures, a sample is considered in custody if it is: • In actual possession of the responsible person ' • In view, after being in physical possession • Locked or sealed in a manner so that no one can tamper with it after having been ' in physical custody or in a secured area restricted to authorized personnel. Samples shall be maintained in the custody of the sampling crew during the sampling ' event. At the end of each sampling day and prior to the transfer of the samples off site, entries shall be completed on the COC form for all samples. Upon transfer of custody, ' the COC form is signed by a sampling crew member, including the date and time. If outside vendor laboratories are utilized, samples shall be delivered to these facilities by Duke Energy personnel or courier. Page 12 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ GW Monitoring Plan\Mayo ' GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra COC forms received by the laboratory(s) shall be signed and dated by the respective supervising scientist(s) or their designee (at the Duke Energy Analytical Laboratory) or the laboratory sample custodian (at vendor labs) immediately following receipt by the laboratory. The analysts at the laboratory(s) maintain a sample tracking record that will follow each sample through all stages of laboratory processing. The sample tracking records show the date of sample extraction or preparation and analysis. These records are used to determine compliance with holding time limits during lab audits and data validation. Custody procedures followed by Duke Energy Analytical Laboratory personnel are described in detail in the Duke Energy Analytical Laboratory Procedures Manual. Page 13 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo\ GW Monitoring Plan\Mayo GW Monitoring Plan.docx 1 Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' 6.0 ANALYTICAL PROCEDURES The main analytical laboratory used in this program is the Duke Energy Analytical ' Laboratory: N.C. Drinking Water (NC37804) and Wastewater ( #248) Certifications. The organizational structure and staff qualifications of the laboratory are discussed in its generic Quality Assurance Program (QAP). The QAP and the Analytical Laboratory ' Procedures Manual are available for review upon request. ' Vendor laboratories that meet EPA and North Carolina certification requirements may be used for analyses with approval by Duke Energy. ' The analytical procedures used for the samples analyzed for this Groundwater Monitoring Program are listed in Table 2. Specific conductance, field pH, and temperature are measured in the field according to the Duke Energy Groundwater Monitoring and Sample Collection Procedure or the instrument manufacturer instructions. Page 14 PADuke Energy Progress. 1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo\ GW Monitoring Plan \Mayo IGW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 7.0 INTERNAL QUALITY CONTROL CHECKS Internal laboratory quality control (QC) checks used by the laboratories are described in each laboratory's generic QAP and procedures manual. Using the internal laboratory QC checks, the laboratories demonstrate the ability to produce acceptable results using the methods specified. Internal quality control checks for sampling procedures and laboratory analyses will be conducted with each sampling event. These checks will consist of the preparation and submittal of field blanks, trip (travel) blanks, and /or field replicates for analysis of all parameters at frequencies described in the laboratory(s) procedures manuals. The field QC blanks and replicates that may be included as internal QC checks are described below. The specific type and number of blanks used may vary depending on the sampling event and will be determined by the Duke Energy field sampling personnel: • Field Blanks: A field blank consists of a sample container filled in the field with organic free, deionized, or distilled water prepared and preserved in the same manner as the samples. The field blank is transported to the laboratory with the samples and analyzed along with the field samples for the constituents of interest to check for contamination imparted to the samples by the sample container, preservative, or other exogenous sources. Field blanks are typically utilized for each sampling event. The field blanks are typically analyzed for major anions, cations and metals. • Trip Blanks: A trip (travel) blank is a sample container filled with organic -free water in the laboratory that travels unopened with the sample bottles. Trip blanks are typically utilized when sampling for volatile organic compounds. The trip blank is returned to the laboratory with the field samples and analyzed along with the field samples for parameters of interest. Equipment Blanks: If non - dedicated equipment is used, it is recommended that equipment blanks be collected. The field equipment is cleaned following documented cleaning protocols. An aliquot of the final control rinse water is passed over the cleaned equipment directly into a sample container and submitted for analyses. Page 15 P: \Duke Energy Progress. 1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo \GW Monitoring Plan \Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NC0038377 SynTerra ' • Field Replicates: A field replicate is a duplicate sample prepared at the sampling locations from equal portions of all sample aliquots combined to make the sample. Both the field replicate and the sample are collected at the same time, in ' the same container type, preserved in the same way, and analyzed by the same laboratory as a measure of sampling and analytical precision. Page 16 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo \GW Monitoring Plan \Mayo IGW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 8.0 VALIDATION OF FIELD DATA PACKAGE The field data package includes all of the field records and measurements developed by the sampling team personnel. The field data package validation will be performed by Duke Energy personnel. The procedure for validation consists of the following: • A review of field data contained on the Groundwater Monitoring Data Sheets for completeness. • Verification that equipment blanks, field blanks, and trip blanks were properly prepared, identified, and analyzed. • A check of the Field Sampling Calibration Form for equipment calibration and instrument conditions. • A review of the COC Record for proper completion, signatures of field personnel and the laboratory sample custodian, dates and times, and for verification that the correct analyses were specified. Page 17 P: \Duke Energy Progress.1026\ALL NC SITES \NPDES Permit Deliverables\ Mayo\ GW Monitoring Plan\Mayo GW Monitoring Plan.docx Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra The laboratory will perform a validation review of the submitted samples and ' analytical results to ensure that the laboratory QA /QC requirements are acceptable. Page 18 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Pem-dt Deliverables \Mayo\ GW Monitoring Plan \Mayo IGW Monitoring Plan.docx Groundwater Monitoring Program October 2014 Mavo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' 10.0 REPORT SUBMITTAL Two copies of the report of the monitoring results for the compliance wells will be submitted to the DWR within 60 days of the date of sampling. The monitoring results ' will be submitted on NCDENR Form GW- 59CCR. The DWR will be notified in the event that vendor lab analyses have not been ' completed within this time frame. Groundwater Monitoring Data Sheets, Field Calibration Forms, Chain -of- Custody Records, Laboratory QA data, and Data ' Validation Checklists shall be kept on file by Duke Energy and are available upon request. Page 19 ' P:\Duke Energy Progress.1026 \ ALL NC SITES\ NPDES Pernut Deliverables \ Mayo \ GW Monitoring Plan \ Mayo GW Monitoring Plan.docx I Groundwater Monitoring Program October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' 11.0 REFERENCES Hibbard, James P., Edward F. Stoddard, Donald T. Secor, and Allen J. Dennis, 2002, The Carolina Zone: overview of Neoproterozoic to Early Paleozoic peri- Gondzvanan terranes along the eastern Flank of the soitthern Appalachians: Earth Science Reviews, v. 57. North Carolina Geological Survey, 1985, Geologic map of North Carolina: North Carolina Geological Survey, General Geologic Map, scale 1:500000. USGS, December 2007, (Dicken, Connie L., Suzanne W. Nicholson, John D. Horton, Michael P. Foose, and Julia A.L. Mueller), Preliminary integrated geologic map databases for the United States — Alabama, Florida, Georgia, Mississippi, North Carolina, and South Carolina, Version 1.1: United States Geological Survey, USGS Open File Report 2005 -1323, < http : / /pubs.usgs.gov /of/2005/1323 >. IPage 20 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ GW Monitoring Plan\Mayo IGW Monitoring Plan.do" FIGURES 1 -- - rl ., r t�/ O � 4 ,his .ur •a ,f t PROPERTY BOUNDARY _ HALiFA?I CAA — _ — HA1J pp �/` 1 t s y ,;t � � • C�-,.i l '+x111' ✓� - fir Lti ; ';I } . • WASTE f i 446 `1' BOUNDARY S00' COMPLIANCE b - l J BOUNDARY � ` I - w t 1 ' t- i t �{�•, _ f 1 f� v '. f� *� '�3 x,c�.r .! J /_-.ti„ „S�` :•� Yr Y,` � i jr `fir. �, '�,`Y i 1. ! tt _ y�,,�t .� 11F' `ii 1i ` i•;''•��r��N,.� A !r�" f `t *�`1R��'-�- �l�;t+ 11 � if J�r _ ,,,'`r 3� -L¢1s �1 , ;'�_�-� /. jtl.� , �' �•:1 � � �'; '� � -- eta '� 2` �NfC / 0 =�� 597- 1 l} i � .,, ••,,�� �) ,•, �.J. s c .fit•: 1 �• 1 '� ��� t,,� `1'Y�' L.1� t'• -_'�' : •.�� ° ,�- -- - Rt - .+ru __�( �r i r •C> �7 1 7 r SOURCE: USGS TOPOGRAPHIC MAP 08TAINEO FROM THE NRCS GEOSPATIAL DATA v. r GATE WAY AT ht (p. /,datagateway.rres.usda (r 1 gov/ �.'r -x`Ey -_ - _ MAYO LANE NTY POWER PLANT PERSON FIGURE 1 SITE LOCATION MAP MAYO STEAM ELECTRIC PLANT 10600 BOSTON RD synTerra - ROXBORO, NORTH CAROLINA CLUSTER SPRINGS, VA QUADRANGLE 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA DRAWN BY S ARLEDGE DATE 2014 10-08 GRAPHIC SCALE PHONE 864-421-9999 PROJECT MANAGER "THY WEBB CONTOUR INTERVAL SOR 1000 0 1000 2000 WwW.synterracorp.com LAYOUT FIG I(SITE LOCATION) MAP DATE 1987 1;610 NC atp �1, A.J. X11 ''��N- IN FEET FIGURE Receptor Survey October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra within 0.5 mile radius of the compliance boundary that appeared to be developed and in -use (occupied) with no apparent municipal water supply were assumed to have private water supply wells (PRW). These properties are noted on Figure 1. 4.5 Summary of Receptor Survey Findings A summary of the receptor survey is discussed below. The suspected water supply well locations shown on Figure 1 are based upon field observations, EDR, and NCDENR information. The suspected well locations are numbered on the map to cross - reference information provided in Table 1. The table summarizes property location and site information where a water supply well may be present based upon drive -by observations or EDR information. • No wellhead protection areas were identified within a 0.5 mile radius of the compliance boundary; • Approximately 21 possible private water supply wells are assumed to be located within 0.5 mile radius of the compliance boundary; • One water well was identified by EDR (Attachment 1). The well is located on the Mayo plant property just to the west of monitoring well CW -5. EDR reports that the well is 87 feet deep, but no other specific information was reported. Prior to receiving the EDR report, the well had been noted during field work; • The EDR report identified the Mayo Plant's surface water intake structure on Mayo Reservoir (Figure 1); • Three water supply wells are located on the plant property south of the ash pond. The three wells are no longer in use; however, well piping, well pumps, and appurtenances remain in place. The three former plant water supply wells are located upgradient of the ash pond; • Several small surface water features, including Crutchfield Branch to the northeast, are present within the 0.5 mile radius of the compliance boundary. Crutchfield Branch originates near the base of the ash basin and flows towards the north /northeast, crossing into Virginia, and eventually merging with Mayo Creek; A portion of Mayo Reservoir is located within the survey radius (Figure 1). Page 6 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \Mayo\ Receptor Survey \Mayo Receptor Survey.docx Receptor Survey October 2014 ' Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra ' 4.0 FINDINGS 4.1 NCDENR Records ' No public water supply wells were identified in the Public Water Supply Water Sources GIS point data set (obtained from NC OneMap GeoSpatial Portal) or on the NCDENR SWAP online database within a 0.5 mile radius of the ash basin compliance boundary. In addition, no wellhead protection areas were identified on the NCDENR SWAP online database within a 0.5 mile radius of the compliance boundary. ' The Water Distribution Map Service (WDMS) data set obtained from the NC OneMap GeoSpatial Portal, did not identify municipal water supply lines located within the 0.5 mile radius of the compliance boundary. 4.2 Environmental Data Resources, Inc. Records The EDR report identified one water supply well located within 0.5 mile radius of the ash basin compliance boundary. According to the EDR report, the well is approximately 87 feet deep and screened felsic gneiss. The well is located northwest of the ash basin compliance boundary. A copy of the EDR Report is provided in Appendix A. The EDR report identified the Mayo Plant's surface water intake structure on Mayo Reservoir (Figure 1). 4.3 USGS Hydrography Review According to the USGS Hydrography map, the Mayo Reservoir is a major surface water body located within the survey radius (Figure 1). In addition to the reservoir, several small surface water features, including Crutchfield Branch to the northeast, are present within the 0.5 mile radius of the compliance boundary. Crutchfield Branch originates near the base of the ash basin and flows towards the north /northeast, crossing into Virginia, and eventually merging with Mayo Creek. 4.4 SynTerra Field Survey SynTerra conducted a visual reconnaissance of the survey area by driving public road- ways and noting properties that appeared to be developed or occupied. Municipal water lines are present just beyond the 0.5 mile radius of the compliance boundary to the southwest along Boston Road (US Hwy 501). A fire hydrant located at the plant entrance is the termination of the water line along Boston Road (Figure 1). Structures resembling water supply wells or well houses were noted where visible and are shown on Figure 1 as reported /observed water supply wells (DW). Properties Page 5 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables \ Mayo\Receptor Survey \Mayo Receptor Survey.dooc Receptor Survey October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 3.2 County GIS The location of a City of Roxboro water line and a fire hydrant, just south of the plant's entrance road is based upon Person County, North Carolina on -line GIS information. These locations are shown on Figure 1. The Halifax County, Virginia GIS information does not indicate the presence of public water utilities in this part of the county. 3.3 Environmental Data Resources, Inc. Records Review A review of public database information provided by Environmental Data Resources, Inc. (EDR) was also conducted. The public water well information reported for the surrounding area (North Carolina and Virginia) has been incorporated in the summary table (Table 1) and on Figure 1. A copy of the EDR report is included as Appendix A. 3.4 USGS Hydrography Review SynTerra reviewed the United States Geological Survey (USGS) National Hydrography Dataset (NHD) obtained from the USGS National Map Viewer ( http: / /viewer.nationalmap.gov /viewers to identify surface waters within a 0.5 mile radius of the compliance boundary. Hydrography data obtained from the USGS NHD is included on Figure 1. 3.5 SynTerra Field Survey During March, 2014, SynTerra personnel conducted a vehicular survey along public roads located within 0.5 mile radius of the compliance boundary in North Carolina and Virginia. Observations on property use, apparent proximity to available municipal water lines and structures that may represent potential water supply wells were noted. Page 4 P: \Duke Energy Progress.1026 \ALL NC SUES \NPDESPermit Deliverables\ Mayo\ Receptor Survey \Mayo Receptor Survey.docx Receptor Survey October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 3.0 RECEPTOR SURVEY ACTIVITIES 3.1 State Records Review ' SynTerra reviewed the NCDENR Department of Environmental Health (DEH) Public Water Supply Section's (PWSS) Public Water Supply Water Sources Geographic Information System (GIS) point data set (pwsws.shp) and the Water Distribution Map ' Service (WDMS) data set obtained from the NC OneMap GeoSpatial Portal (http: // data. nconemap. com /geoportal /catalog /main/home.page) to identify public water supply sources and water supply lines within a 0.5 mile radius of the Mayo Plant ' compliance boundary. According to the NC OneMap website, the Public Water Supply Water Sources point data was current through November 18, 2009, and that it is the most current GIS data set of public water supply locations available from North Carolina state agencies. The ' GIS point data for the public water supply wells includes, but is not limited to information such as public water supply (PWS) system identification numbers, ownership information, PWS source type, well depth, and well yield. The WDMS data ' set contains information on municipal water lines and other appurtenances. On June 24, 2014, SynTerra reviewed the NCDENR Division of Water Resources (DWR) ' Source Water Assessment Program (SWAP) online database for public water supply sources to identify wells located within a 0.5 mile radius of the compliance boundary; to ' confirm the location of wells included in the Public Water Supply Water Sources GIS point data set, and to identify any wellhead protection areas located within a 0.5 mile radius of the compliance boundary. The NCDENR SWAP database provides detailed ' assessments of all public drinking water intakes and wellhead protection areas in North Carolina. The website address is: (http: / /swap.ncwater.org /website /swap /viewer.htm). ' Virginia's (VA) Department of Environmental Quality (DEQ) maintains a GIS database called "VEGIS" ( http: / /www.deq. virginia. gov/ ConnectWithDEQ NEGISNEGISDatasets.aspx) which includes many types of geo- spatial information. The VEGIS database was reviewed, and it appears that it does not contain a database of water wells in the state. Virginia ' DEQ personnel were contacted to verify that the state does not currently maintain a publicly available searchable database of wells. I Page 3 P: \Duke Energy Progress.1026 \ALL NC SITES \NPDES Permit Deliverables\ Mayo\ Receptor Survey \Mayo IReceptor Survey.docx Receptor Survey October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra 2.0 BACKGROUND 2.1 Plant and Ash Basin Area Description The Mayo Plant is a coal -fired electricity- generating facility located in Person County, North Carolina, near the city of Roxboro. The location of the plant is shown on Figure 1. The Mayo Plant started operations in 1983. The plant is located on Boston Road (US Highway 501) north of Roxboro. The northern plant property line extends to the North Carolina/Virginia state line. The overall topography of the Plant generally slopes toward the east (Mayo Reservoir) and northeast (Crutchfield Branch). The Mayo Plant ash basin is approximately 153 acres in size with an earthen dike. Ash generated from the plant's coal combustion is contained in the ash basin. The Mayo Plant NPDES permit (NC0038377) authorizes two discharges to Mayo Lake. Outfall 001 discharges cooling tower water and circulating water system discharge water. Outfall 002 is comprised of a number of streams including internal outfall 008 (cooling tower blowdown), internal outfall 009 (FGD blowdown), ash transport water, coal pile runoff, and other sources including water from wastewater treatment processes. Four stormwater outfalls are also authorized for Mayo Plant. 2.2 Description of Surrounding Properties Properties located within a 0.5 mile radius of the Mayo Plant compliance boundary are located in Pearson County, North Carolina and Halifax County, Virginia. The properties uses include residential, commercial, industrial, and agricultural. Figure 1 depicts the properties surrounding the Mayo Plant. Page 2 P:\Duke Energy Progress.1026\ALL NC SUES \NPDES Permit Deliverables \Mayo\ Receptor Survey\Mayo Receptor Survey.docx Receptor Survey October 2014 Mayo Steam Electric Plant, NPDES Permit x NCO038377 SynTerra 1.0 INTRODUCTION Duke Energy Progress, Inc. (Duke Energy), owns and operates the Mayo Steam Electric Plant (Mayo Plant), located near Roxboro, in Person County, North Carolina. The Plant is a single unit, coal -fired electricity- generating facility. Coal combustion residuals (CCR) have historically been managed at the Plant's on -site ash basin. Dry ash has been hauled and disposed in the lined landfill located at the nearby Roxboro Steam Electric Plant (near Semora, NC). It is anticipated that beginning in Fall 2014, CCR from the Plant will be managed in a newly constructed on -site landfill. Figure 1 is a map showing the site and surrounding area. Discharge from the ash basin is permitted by the North Carolina Department of Environment and Natural Resources (NCDENR) Division of Water Resources (DWR) under the National Pollution Discharge Elimination System (NPDES) Permit NC0038377. SynTerra has completed a receptor survey to identify water supply wells, public water supplies, surface water bodies, and wellhead protection areas (if present) within a 0.5 mile radius of the Mayo Plant ash basin compliance boundary (Figure 1). The compliance boundary for groundwater quality in relation to the ash basin is defined in accordance with 15A NCAC 02L .0107(a) as being established at either 500 feet from the waste boundary or at the property boundary, whichever is closer to the source. The survey scope and findings are presented in the following sections. Page 1 P:\ Duke Energy Progress. 1026 \ ALL NC STIES \ NPDES Permit Deliverables \ Mayo \ Receptor Survey \ Mayo Receptor Survey.docx Receptor Survey October 2014 Mayo Steam Electric Plant, NPDES Permit # NCO038377 SynTerra TABLE OF CONTENTS SECTION PAGE 1.0 Introduction ....................................................................................... ..............................1 2.0 Background ....................................................................................... ............................... 2 2.1 Plant and Ash Basin Area Description ..................................... ............................... 2 2.2 Description of Surrounding Properties ................................... ............................... 2 3.0 Receptor Survey Activities ............................................................. ............................... 3 3.1 State Records Review ................................................................. ............................... 3 3.2 County GIS ................................................................................... ............................... 4 3.3 Environmental Data Resources, Inc. Records Review ........... ............................... 4 3.4 USGS Hydrography Review ..................................................... ............................... 4 3.5 SynTerra Field Survey ................................................................ ............................... 4 4.0 Findings ............................................................................................. ............................... 5 4.1 NCDENR Records ....................................................................... ............................... 5 4.2 Environmental Data Resources, Inc. Records ......................... ............................... 5 4.3 USGS Hydrography Review ..................................................... ............................... 5 4.4 SynTerra Field Survey ................................................................ ............................... 5 4.5 Summary of Receptor Survey Findings ................................... ............................... 6 List of Figures Figure 1. Receptor Survey Map List of Tables Table 1. Public and Private Water Supply Wells List of Appendices Appendix A EDR Report Page P: \Duke Energy Progress.1026 \ALL NC STIES \NPDES Permit Deliverables \Mayo\ Receptor Survey \Mayo Receptor Survey.docx 161p syn,T(erra RECEPTOR SURVEY FOR MAYO STEAM ELECTRIC PLANT 10600 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 NPDES PERMIT #NC0038377 PREPARED FOR DUKE ENERGY PROGRESS, INC. RALEIGH, NORTH CAROLINA f DUKE ENERGY. PROGRESS SUBMITTED: OCTOBER 2014 • ' SEA IL r 3 yN+0.. W C +AR � �GENSE�'9 _ SEAL 1425 tiFot oG�S~�ry ;Ol O gI ,S�'>>r ++t.ttti�N� . '1328 nager fUYirf 1filrJfiY1 �■ l bYfl'1)1l U..Vla 3W'8S* onosefro.r° VV drl, Y�DLIOJ Y]1rM°4f1GY� nF� r� phi a tf€ a 3 0 n. �l�( fj �� � • � ,!� �,,a`i ATTACHMENT XX — GROUNDWATER MONITORING PLAN Permit Number: NCO038377 Version 1.0 WELL PARAMETER DESCRIPTION FREQUENCY NOMENCLATURE Aluminum Chloride Mercury TAS Monitoring Wells: Antimony Chromium__ _ Nickel Thallium C1d' -1, CW -1D. CW -2, Arsenic _ C_ op per Nitrate Water Level April. Jule, CW -21D, C1W -3. CW -4, Cam'- Barium V_ Iron pH I Zinc November 5. CW -6, BG -1. BG -2 Baron Lead Selenium Cadmium Manganecj Sulfate — Note 1: For locations of monitoring wells, see attached map. Note 2: Monitoring revisions may be considered, as applicable, if there are no significant detections prior to permit renewal. N00038377 - Mayo Steam Station Groundwater Monitoring Plan Page 4 of 4 3,11 Tl 1 ' 4. COMPLIANCE BOUNDARY. The compliance boundary for the disposal system shall be specified in accordance with 15A NCAC 02L .0107(a). This disposal system was individually permitted prior to December 30, 1983; therefore, the compliance boundary is established at either 500 feet from the effluent disposal area, or at the property boundary, whichever is closest to the effluent disposal area, An exceedance of groundwater standards at or beyond the compliance boundary is subject to remediation ' action according to 15A NCAC 02L .0106(c) as well as enforcement actions in accordance with North Carolina General Statute 143- 215.6A through 143- 215.6C. ' NC0038377 — Mayo Stcam Station Groundwater Mr nitoring Plan Page 3 of 4 3 X17/11 g. The monitoring wells shall be regularly maintained, Such maintenance shall include ensuring that the well caps are rust -free and locked at all times, the outer casing is upright and undamaged, and the well does not serve as a conduit for contamination. 3. GROUNDWATER SAMPLING AND COMPLIANCE. Monitoring wells shall be sampled after construction and thereafter at the frequencies and for the parameters as specified in Attachment XX. All maps, well construction forms, well abandonment forms and monitoring data shall refer to the permit number and the well nomenclature as provided on Attachment XX, a. Per 15A NCAC 02H .0800, a Division certified laboratory shall conduct all laboratory analyses for the required effluent, groundwater or surface water parameters. b. The measurement of water levels shall be made prior to purging the wells. The depth to water in each well shall be measured from the surveyed point on the top of the casing. The measurement of pH shall be made after purging and prior to sampling for the remaining parameters. C. The measuring points (top of well casing) of all monitoring wells shall be surveyed to provide the relative elevation of the measuring point for each monitoring well. The measuring points (top of casing) of all monitoring wells shall be surveyed relative to a common datum. d. For monitoring wells that are not located at the Compliance Boundary, the Compliance Monitoring Form (GW- 59CCR) is not required. However, predictive calculations or modeling shall be submitted to the Regional Office annually (i.e. 12 months after permit issuance) demonstrating groundwater quality standards at the Compliance Boundary, e. Two copies of the monitoring well sampling shall be submitted on a Compliance Monitoring Form (GW- 59CCR), and received no later than the last working day of the month following the sampling month. Copies of the laboratory analyses shall be kept on site, and made available upon request. The Compliance Monitoring Form (GW- 59CCR) shall include this permit number and the appropriate well Identification number. All information shall be submitted to the following address: Division of Water Quality Information Processing Unit 1617 Mail Service Center Raleigh, North Carolina 27699 -1617 For groundwater samples that exceed the ground water quality standards in 15A NCAC 02L .0202, the Regional Office shall be contacted within 30 days after submission of the groundwater monitoring report; an evaluation may be required to determine the Impact of the waste disposal activities. Failure to do so may subject the permittee to a Notice of Violation, fines, and /or penalties. N0O038377 — Mayo Steam Station Groundwater Monitoring Plan Page'_ of 4 3'1 7!1 1 A. (6) GROUNDWATER MONITORING WELL CONSTRUCTION AND SAMPLING 1. The permittee shall conduct groundwater monitoring as may be required to determine the compliance of this NPDES permitted facility with the current groundwater Standards found under 15A NCAC 2L,0200 2. WELL CONSTRUCTION. Within 120 days of permit issuance, monitoring wells, as proposed on Attachment XX, shall be Installed to monitor groundwater quality. a. Monitoring wells shall be constructed in accordance with 15A NCAC 02C .0108 (Standards of Construction for Wells Other than Water Supply) and any other jurisdictional laws and regulations pertaining to well construction. The general locations for all monitoring wells are indicated on Attachment XX. b. Within 30 days of completion of well construction, a completed Well Construction Record (Form GW -1) must be submitted for each monitoring well to Division of Water Quality, Aquifer Protection Section, 1636 Mail Service Center, Raleigh, NC 27699 -1636. C. The Raleigh Regional Office, telephone number (919) 791 -4200 shall approve the location of new monitoring wells prior to installation. The regional office shall be notified at least 48 hours prior to the construction of any monitoring well and such notification to the Aquifer Protection Section's regional supervisor shall be made from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. d. Within 60 days of completion of the monitoring wells, the Permittee shall submit two original copies of a site map with a scale no greater than 1 -inch equals 500 feet. At a minimum, the map shall include the following information: i. The location and identity of each monitoring well. ii. The location of major components of the waste disposal system. iii. The location of property boundaries within 500 feet of the disposal areas. iv. The latitude and longitude of the established horizontal control monument. V. The elevation of the top of the well casing (i.e., measuring point) relative to a common datum. vi. The depth of water below the measuring point at the time the measuring point is established. vii. The location of compliance and review boundaries. viii. The date the map is prepared and /or revised. ix. Topographic contours in no more than ten (10) foot intervals e. The above information should be overlaid on the most recent aerial photograph taken of the site. Control monuments shall be installed in such a manner and made of such materials that the monument will not be destroyed due to activities taking place on the property. The map and any supporting documentation shall be sent to the Division of Water Quality, Aquifer Protection Section, 1636 Mail Service Center, Raleigh, NC 27699 -1636. f. The well(s) must be constructed by a North Carolina Certified Well Contractor, the property owner, or the property lessee according to General Statutes 87- 98.4. If the construction is not performed by a certified well contractor, the property owner or lessee, provided they are a natural person, must physically perform the actual well construction activities. NCO038377 - Mayo Steam Station Groundwater Monitoring, Plan Page I of 3/17!1 1 i 1 NC®ENR , North Carolina Department of Environment and Natural Resources Division of water Quality Beverly Eaves Perdue Coleen H Sullins Dee Freeman , Governor Director Secretary March 17, 2011 RE�E/ CEO i Mr. John Toepfer � 7011 Senior Environmental Technical Specialist ' Progress Energy Service Company, LLC 410 South Wilmington Street PEB 4 1 Raleigh, North Carolina 27601 Subject: Progress Energy's North Carolina Ash Pond Facilities Final Groundwater Monitoring Plans and Maps 1 Dear Mr, Toepfer: Attached are the final Groundwater Monitoring Plans and maps for the Asheville, Cape Fear, 1 Lee, Mayo, Roxboro, Sutton, and Weatherspoon facilities. These plans and maps will be incorporated in each facility's NPDES permits, Please note some minur 'additions and 1 corrections to the individual Groundwater Monitoring Plans. If you have any questions, please feel free to contact Eric Smith at (919) 715 -6196 or me at (919) 715 -6699. 1 Sincerely, 1 4�, -)v Debra J. Watts 1 Supervisor — Groundwater Protection Unit Attachments 1 cc: APS Central Office Files w/ attachments 1 SWP — NPDES (Sergei Chemikov) w/ attachments Regional Offices — APS , A010--ER PROTECTION SEC7101, 1636 MaJ Serve Center, Ralegt,, Nosh CsuoMna 27599 -163£ One Location. 2728 Caoilal Bouevard Raieq- Nont, CamWia 276tk Noi- t`lCaroll I Ills Phone. 915- 73i32211 FAX 1 919 - 71508% FAx2.! ', "1r. EN? 1. 1,ustoae'Sefvic 1.8 -" 623.6745 Inlemel wwwsrwatemuatiN ora An °_aid . 1 APPENDIX B I MAYO STEAM ELECTRIC POWER PLANT PERMIT CONDITION A(6) ATTACHMENT XX, VERSION 1.0 MARCH 17, 2011 I' `;~ ��� \rrr th t��i Ulnl.t !1Cp111fnt•nt nt F.r:U rn.r .c r.l �� 11 F:I -L CON I•R C 1'ttlt t 1. 1011' 1. WELL CONTRACTOR: .tames D. Barker Well Cortractpr (hltl v1dual) Name OtianlPx Inc. viell Contractor Company Narrie STREETADIDRESS P.O. Box41673 Raleigh, NC 27.629 City or Town State - - -_ Z•p Code------ - ( 919 _r 219 9604 Area code - Phone comber 2 WE LL INFORMATION: SITE WELL ID +qtr a<.j%cat+r) NA WELL CONSTRUCTION PERMI TN(a e.a.rvrt NA `" OTHER ASSOCIATED PERMiTNI .fapoicabie)_NA i_ WoLL Ltge tr•ngoq Arp! :•�hte Bex; Mo ^.•!CnngQ A1urs:Gp9!'P'a4;,r.,' Induslrlal/C:omimcrcialO Agmultura.0 RecoveryO In)ecliorfl Irrigalipd3l O1her(3 Ibsl use) _ __ DATE DRILLED 10-15 -0$ TIME COMPLETED AMD PKIN 4 WELLLOCAT :ON CITY Roxboro COUNTY Person 10660 Boston Road, Roxboro, NC 27573 iStraN N:wne. lh.mber,. Community. Subeiwval. Lit( P.O. P „fcc Zip Codc i TOPOGRAPI IIC h LAND SETTING 0 Slope 0 Valley Jb Flal D Ridge 0 Other (:Ix 1:A ,ipj;f C.7f.�IC CDC) � . 1 ila) th' rrr •I,•+;rlYti ! I ATITI)r)F N ta�3F�4ros rrnlidr'+ ,run, 1. rrr LONGITUCL E ?— �323T1•G m�ciatrt! :xrnn Litutudeilc+naludcunncc SGPS 13 Iupopaphiunwp (ICcabon N we)) must be shown rn a US(-,S f'>lo Map :tnd affachrd to flits Fran? if not us,ng GIPS) 5 FACIUTY nit•t farm Ar,ti Iner-ra w-f exit +.trt q �: r•rr: FACILITY ID Nfd applicable) _NA NAMF Or FACILITY Progress Energy Maw Plant STRFCTADDRESS 10660130SIOnRoad Roxboro NC 27573 C,ly or Torn Slate Lu C•A:e CcNVTACT PERSON Tim Silar MAILING Ar)ORFSS 10660 Boston Road Roxboro NC Cuy or Tarn State Z a Cu1a I F NA Area code - Phone number 6 WELL DETAILS: f a TOTAL DEPTH: 5 Z h DOES WELL REPLACE EXISTING WELL? YESL7 W41 ��CCr c WATER LEVEL Selow Tnp of C.asinq TJ FT (Use '- -dAf,r eTopofL•usvgl Mw- W 6.1,1. ( ON &I Illy( t'IUN It t.CURI) AY,rer rl Hcxn ills Un r.r.,n of \1'arrr Ou.th'r _ t� �'I'IOti p 3'06 - F TOP C -F CASING IS 28” _ F T Above I. arxt Surface' _ - -Top of casxx) b;rmiilalbd 84 "W OtflOVr tared Surfi e,roy rc4ofe a van nice nt accordance vvth 1SA NCAC 2C or 1A e. YIELL (gpm) NA __ METHOD OF TEST NA r. DISINFECTION: Type _NA _ _ Amount NA — g. WATER ZONES (depth Fran_47t To 4 From _ 10 From _ To_ From To From TO From TO 7. CASING Depth Ciameler rt:r koe> pvrr:gm NWterial t r From ) To 4Z- Ft 2" sch40 PVC From —_ To Ft From - -- To FI B GROUT'. Depth Matanal Method From_ O To 3gr Ft Neal Cement Pour From—n' To q0_ FL BentOnit@ _ Place From To FL 9 SCREEN: Depth Diameter Slot Silo Material F,,,_4' To r7Z rt 2" fn 0 010 it, PVC ` From To_ --_ —FI In _ In _ -- From To FI in in 10 SAND(C RAVEL PACK: Depth f Size Malertaf From _f'}Or To Ft #2 Silica Sand From— TO _ Ft pram_ To Ft 11 DRILUNG LOG Fran To, F rrt>ab Dc Cr tliln _C, �1� 5r47�wfa _ I r _ 1 ri 2 !`4rnt'6Z GIL I 12 REMARKS y%-,V' r (:.:. y'Er' r.^. � r.�..r t��r: G.:.tsn <t..:•tvrut :�.rl:rs,•.I l: !• ••�I. L. :I f'7 . C'G` .FK. $ 1•.0 tart r. ;• ♦ +f 1 /01 67 Strh0, URR_CXCLRTIFIFDYJELL CON IRA6014 D• Tc Jam S D Barker _ PRINTED N AN1E OF PF RSt)N CCN•rS f R UC TING T NF N& L Submit the original to the Division of Water Quality within 30 days t.nn: Information Mgt.. Farm CV'e-11) 1617 Mail Service Center - Raleigh, NC 27699.1617 Phone No. (9I9) 733 "7315 ext 568 Rev t7107 NONRESIDENTIAL n E:LI, CONS-1 RI crtox RECORD \,wit t arolirr.I 1 erannrcnl ul- I n% iruumcnl rnd \;Rural Re iurce Dix ision or H aier Qualit% N1 ELI. ('O\'rRA(" 1'OR ('L R] I FK'Arion o •3106 =AA - -- -� 1. WELL CONTRACTOR: James D. Barker well Conga- tar (Individual) Name Quantex, Inc. Well Contractor Company Name P.Q. Box 41673 R- IFaIJn;gg NC 27629 Raleigh Clly or TL,-j, Slate Zip Code 1919 .21-9-9604 Anti M.,? Ph-ule h, —jnlbh r 2. WELL INFORMATION: N111i r:+)rv� IRU.;TION PERR'iT# NA OTFIER A3SCi ,':IAI EO PERIAII rr aap +-cable) NA SITE V4L•LL 10 4,1 a,µ _aete BG -2 ��_ 3. WELL USE ,Chock One Box) Mondortn �! g MunicipallPubbc r Indu,toa6i;cnmk rcral Agricultural [- Recovery. Injection , Ong 51 dr. Other 11,5t u5ei DATE DRILLED 9128/10 4. WELL LOCATION: 1066_0 Boston Road Hwy. 501 27573 ; jrr ?Bi Nan'•, .lrT.tr.,t �. TTUmA SirGl y-'-..Let No Parcel Zip Code; City Roxboro COUNTY Person TOPOGRAPHIC /LAND SETTING lcherx appropriate boo Mope Vall,:, 'Fiat Ridge Other LATITUDE 3`� ^ PNIS N 36.521225 DD LONGII UDE '[' _ ' DMS W 78.90114B 00 Latit ude IL,rgrurle source V;ps F Top og.aphic map itaca1!on or .;el,' must oe st)ott r1 ort a USGS ropo map andatlached ro :hfs farm if no! using GPSI 5. FACILITYiName of the busioeSs Miele the yell Is located I Progress Energy Mayo Plant Facilitq• Name Facility IDS (if applicable) 10660 Boston Road Sacet Address Roxboro NC 27573 City 01 Trw.n State Zip Code Progress Energy Mayo Plant Conla'.-I Flamm. 10660 Boston Road r:laliln3 Aylicss Roxboro NC 27573 City or Irrn•rn Stale Zip Code NA �:Ig;l CG9C � IurK nwr�r - -- 6. WELL DETAILS: a. TOTAL DEPTH: b. DOES WELL REPLACE EXISTING WELL? YFS' % NO ✓ c. WATER LEVEL[3elov lo),ol Casing NA FT (U:.v • it Above Top of Casing) d. TOP OF CASING IS 2S FT Above Land Surface' 'Top of casing terminated arJor below land ;urface ntay require a variance in accordance vAh 15A NCAC 2C 0118 e. YIELD (gpm) NA METHOD OF TEST NA : I. DISINFECTION: Type NA Amount NA :g. WATER ZONES (depth) Top 38' Bottom 43 Top_ Bottom Top_ Bollom Top Bottom_,--__ Top Bottom Top Bottom Thickness/ • 7. CASING: Depth Diameter Weight Material Top 0' Bottom Fl. 2" sch40 —PVC : Top Bottom_ FI Top Bottom Fl 8 GROUT Depth Material Metnod Top 0' , Bottom Ft Neat Cement Pump Top_ Bottom Ft Benlonite Pour Top Bottom Fl :9. SCREEN: Depth Diameter Slot Size Material Top` Bottom Fl 2" in. 0.010 in PVC _ Top_- Bottom FI m to Top Bollom FI m. in 10. SANDIGRAVEL PACK: Depth Size Material Top Bottom 45' Ft. X12 Silica Sand Top Bolton Fl. Top Bollom Fl. 11. DRILLING LOG Top Bolton Formation Description 0' 1 12' Sandy Silt 12' 1 53' Wethered Rock, Granitic Multiple Fractures / 1 1 r r : 12. REMARKS: ID7NFI! HIrCERT'17' THA - T VF,' LN: asCJF :SIR1:CrEnino :000PLU"CEA-TH 1SA II(::, 2' 'l.E GV+ STR Cr IT IAN:)kROS AND Tw+T ACOPY' OF IHS REC'R7 5ert PiynvltreP TH VELLOVF4SR 1 ut_, _ ll i— !(_L ,r c 9128/10 SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE James D. Barker PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of Completion to: Division of Water Quality • Information Processing, F Reev v 2109 2JO9 A 1617 Mail Service Center, Raleigh, NC 27699 -161, Phone : (919) 807 -6300 W 1. WELL CONTRACTOR: Thomas Whitehead Well Contractor (Individual) Name SWE. Inc. Well Contractor Company Name 3201 SDdna Forest Road Street Address Raleiah NC 27616 Cdy or Town state Zip Code 9� 19 t 872 -2660 Area code Phone number 2. WELL INFORMATION: 1 r ONRESIDENTL9L WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 2907 WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT( epptirade) SITE WELL ID ca applicable) CW-6 3. WELL USE (Check One Box) Monitoring 3( Municipal/Public ❑ Industrial/Commeraal ❑ Agricultural ❑ Recovery ❑ Injection ❑ Irrigation❑ Other ❑ (list use) DATE DRILLED 11 -15 -10 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name, Number, Community, Subdivision, Lot No., Parwl, Zip Code) CITY: Roxboro COUNTY Person TOPOGRAPHIC/ LAND SETTING. (&4Kk appropriate box) ❑Slope []Valley JiFlat ❑Ridge ❑Other LATITUDE 36 • 32 - 166600 ^ DMS OR 3x.xxxxxxxxx DO LONGITUDE 78 53 ' 16.1300 " DMS OR 7x.xxxxxxxxx DD Latitudellongitude source. WPS Qropographic map (location of well must be shown on a USGS topo map andattached to this form if not using GPS) 6. FACILITY (Name of the business where the well is located.) Prnar .cs Enerav C arnlinas Facility Name Facility IDS (if applicable) 10660 Rnstnn RI Street Address Rnxhnrn NG 2757' City or Town State Zip Code _.1 hen Tr>Ptfer Contact Name 410 S Wjlminotnn St_ PPR 4A Mailing Address RaIA4rih NC; 27601 City or Town State Zip Code ( 9198 546 -7863 Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 76.9` b. DOES WELL REPLACE EXISTING WELL7 YES p NO IV d. TOP OF CASING IS 2.5 FT. Above Land Surface' 'Top of casing terminated atlor below land surface may require a variance in accordance with 15A NCAC 2C .0118 e. YIELD (gpm): METHOD OF TEST I. DISINFECTION: Type Amount g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness! 7. CASING: Depth Diameter Weight Material Top -2,39 Bottom 72.1 Ft. 2" sch 40 PVC Top Bottom Fl. Top Bottom Ft. • 8 GROUT: Depth Material Method Top 0 Bottom 62.7 FL Portland Pour Top 62.7 Bottom 68.7 Ft Bentonite Pour Top Bottom Fl. 9. SCREEN: Depth Diameter Slot Size Material Top 72.1 Bottom 76.9 FL 2 in .010 In. PVC Top Bottom Ft in, in. Toll Bottom FL in. in 10. SANDJGRAVEL PACK: Depth Size Material Top 68.7 Bottom 77.4 Ft Coarse Sand Top Bottom Ft Top Bottom Ft. 11. DRILLING LOG Top Bottom Formation Description _0 /_4.5 Sandy Clay 4.5 / 15 Weathered Rock 15 77.4 Rock I I 1 1 12. REMARKS: 100 HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS E51iMD HAS BEEN PROVIDED TO THE WELL OWNER SIG OF CERTIFIED WELL lCOTT 0-0R DATE c. WATER LEVEL Below Top of Casing: 14.33 FT. : Thomas Whitehead (Use - +' Ii Above Top of Casing) : PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of completion to: Dlvlslon of Water Quality Form J09 Y P ty - Infomtatlon Processing, Rev. 2109 1617 Mall Service Center, Raleigh, NC 27699 -161, Phone :(919) 807.6300 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION q 2907 1. WELL CONTRACTOR: Thomas Whitehead Well Contractor (individual) Name SWE. Inc. Well Contractor Company Name 3201 Snfina Forest Road Street Address Raleioh NC 27616 City or Town State Zip Code 9( 19 ) 872 -2660 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMITS(( applcable) SITE WELL ID #(M appOcable) CW-5 3. WELL USE (Check One Box) Monitoring N( Municipal/Public ❑ Industrial/Commercial ❑ Agricultural ❑ Recovery ❑ Injection ❑ Irrigation❑ Other ❑ (list use) DATE DRILLED 11- 15-1.4 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name, Numbers, Community, Subdivision, Lot No, Porce4, Zip Code) CITY: Roxboro COUNTY Person TOPOGRAPHIC / LAND SET71NG (check appropriate box) ❑Scope ❑Valley W(Flat ❑Ridge ❑Other LATITUDE 36 -32 ' 20.6400 " DMS OR 3X.XXXXXXXXX DD LONGITUDE 78 ' 54 ' 2.4600 " DIMS OR 7X.XXXXXXXxX DD Latiludellongitude source: BPS []Topographic map (location of well must be shown on a USGS topo map andattached to this lam Ynot using GPS) 6. FACILITY (Name of the business where the well is located ) PrrxlrPSS Fnerav Carnlinns Facility Name Facility ID/ (if applicable) 10860 Rnstnn Rnari Street Address Rnxharo NC 2`7573 City or Town State Zip Code Jahn Tnetfer Contact Name 410 S. Wilminatnn St_ PFR 4A Mailing Address Raleioh NC 27601 City or Town State Zip Code ( 9198 546 -7863 Area code Phone number d. TOP OF CASING IS 2.5 FT. Above Land Surface' `Top of casing terminated at/or below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm) METHOD OF TEST_ I. DISINFECTION: T1roe Amount S. WATER ZONES (depth) Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top -2.39 Bottom 35.3 Ft. 2" sch 4 PVC Top Bottom Ft. Top Bottom Ft. 8 GROUT, Depth Material Method Top 0 Bottom 8 Ft. Portland Pour Top 8 Bottom 33.9 Ft. Bentonite Pour Top Bottom Ft. 0. SCREEN: Depth Diameter Slot Slze Material Top 35 Bottom 39.8 Ft. 2 in. .010 In. PVC Top Bottom Ft.__in. in. Top Bottom Ft. in. in. 10. SAND /GRAVEL PACK: Depth Size Material Top 33 Bottom 43 Ft. Coarse Sand Top Bottom Ft. Top Bottom Fl. 11. DRILLING LOG Top Bottom Formation Description 0 - / 2.5 Sandy Clay 2.5 / 12 Weathered Rock 1_/ 43 Rock 1 / 12. REMARKS: B. WELL DETAILS: ; i DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WTH 15A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS a. TOTAL DEPTH: 39.8 RE HAS BEEN PROVIDED TO THE WELL OMdER_ b. DOES WELL REPLACE EXISTING WELL? YES NO d 12 -21 -10 SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing: 10.69 FT Thomas Whitehead (Use " +' if Above Top of Casing) PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of completion to: Division of Water Quality Information Proceael Form tO9 aY P tY ' �� Rev. 2109 1617 Mall Service Center, Raleigh, NC 27699 -161, Phone :(M) 907.6300 � J 1. WELL CONTRACTOR: Thomas Whitehead Well Contractor (IndAdual) Name SAME, Inc. Well Contractor Company Name 3201 Sndna Forest Road Street Address Raleigh NC 27616 City or Town Stale Zip Code 9c 19 ► 872 -2660 Area code Phone number NONRESIDENTML WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 2907 2. WELL INFORMATION: WELL CONSTRUCTION PERMITS OTHER ASSOCIATED PERMrrCrf appicable) SITE WELL ID #<if.pplreble) CW-4 3. WELL USE (Check One Box) Monitoring 3( Municipal/Public O Industrial /Commercial D Agricultural D Recovery O Injection L) I"ationD Other D (list use) DATE DRILLED 11-12-10 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name, Numbers, Community, Subdivision, Lot No, Parcel, Zip Code) CITY: Roxboro COUNTY Person TOPOGRAPHIC I LAND SETTING: (check appropriate box) OSlope OValley Flat ORldge []Other LATITUDE 36 -32 1282400 " DMS OR 3X.XXXXXXXXX DD LONGITUDE 78 ' 63 , 47.0800 ' DMS OR 7X.xxxxxxxxx DD Latitudellongitude 6ource: WPS Dropographic map (location of well must he shown on a USGS topo map andatteched to this form if not using GPS) S. FACILITY (Name of the business where the well is located ) Pronress Fnernv Carolinas Facility Name Facility ID# (if applicable) 1 Min Rnctnn Rnad Street Address Roxhoro NC 97573 City or Town Stale Zip Code John Topffer Contact Name 410 S. Wilminntnn St_ PER 4A Mailing Address RalPinh NC 27601 City or Town State Zip Code ( 919 546 -7863 Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 40.3' b. DOES WELL REPLACE EXISTING WELL? YES O NO Ly d. TOP OF CASING is 2.5 FT. Above Land Surface' 'Top of casing terminated attor below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): METHOD OF TEST L DISINFECTION: Type Amount 9. WATER ZONES (depth) Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top. -2.55 Bottom 35 Ft. 2,, sch 40 PVC Top Bottom Ft. Top Bottom Ft. 8 GROUT: Depth Material Method Topes_ Bottom_ Ft. Portland Pour Topes_ Bottom 33.9 Ft. Bentonite Pour Top Bottom Ft. 8. SCREEN: Depth Diameter Slot Size Material Top 35 Bottom 39.8 Ft. 2 in .010 in PVC Top Bottom Ft. in in Top Bottom Ft. in. in. 10. SAND /GRAVEL PACK: Depth Size Material Top 33_9 Bottom 40.3 R. Coarse Sand Top Bottom Ft Top Bottom Ft. 11. DRILLING LOG Top Bottom Formation Description 0 7.5 Sandy Clay 7.5 /22 Weathered Rock 22 —/ 40.3 Rock r /T 12. REMARKS: r DO HERESY CERTIFY THAT THIS WELL WAS C.ONSTRUCTEO ,N ACCORLNNCE WITH 1 SA NCAC YC, WELL CONSTRUCTION STANDARDS, AND TMAT A COPY of THIS RE=ADEJ TO THE WELL OWNER ilLf2t 12 -21 -10 SIGNATURE OF CERTIrIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing: 97 53 FT Thomas Whitehead (Use ' +' if Above Top of Casing) : PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 dap of completion to: Division of Water Quality Form 109 aY p ty - Infotmadon Processing, Rev. 2os 1617 Mall Service Center, Raleigh, NC 27699-161, Phone : (919) 807 -6300 ..sear, �d ✓ r NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality •��,,,,�• WELL CONTRACTOR CERTIFICATION k 2907 1. WELL CONTRACTOR: Thomas Whitehead Well Contractor Qndivldual) Name SWE. Inc. WON Contractor Company Name 3201 Solina Forest Road Street Address Raleiah NC 27616 City or Town State Zip Code 9( 19 ) 872 -2660 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMrT#(if applicable) SITE WELL ID #(if .pplcable) CW-3 J 3. WELL USE (Check One Box) Monitoring Ifr MunicipaUPublic ❑ IndustriallCommerclal ❑ Agricultural O Recovery ❑ Injection Ct Imgation❑ Other p (list use) DATE DRILLED 11-16-10 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name. Numbers. Community, SuWinsion, Lot No., Parcel, Zip Code) CITY. Roxboro COUNTY Person TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑Slope ❑Valley Flat []Ridge 00ther LATITUDE 36 22 25.8200 ° OMS OR 3x.xXXXXXXXX DO LONGITUDE 78 • 53 ' 36.7700 1) MS OR 7x.xXxxxxxxx DO LatitudeAongitude source: UiPS []Topographic map (location of well must be shown on a USGS topo map andattachad to this form if not using GPS) 6. FACILITY (Name of the business where the well is located ) d. TOP OF CASING IS _ 2.5 FT. Above Land Surface' -Top of casing terminated attor below land surface may require a variance in accordance with 15A NCAC 2C .0118 e. YIELD (gpm) METHOD OF TEST f. DISINFECTION: Type Amount V. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Street Address Thickness( 7. CASING: Depth Diameter Weight Material Top-2.41 Bottom 17 Ft.2' sch 4 PVC Top Bottom Fl. Top Bottom Ft 8. GROUT: Depth Material Method Top Q Bottom 7 Ft. Portland Pour Top 7 Bottom 15 Ft. Bentonite Pour Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 17 Bottom 31.8 Ft. 2 ___ in .010 in. PVC Top Bottom Ft. in. in. Top Bottom Ft. in in. 10. SANDlGRAVEL PACK: Depth Size Material Top 15 _Bottom 32.3 Ft. Coarse Sand Top Bottom FI. Top Bottom FI 11. DRILLING LOG Top Bottom Formation Description Emaress Fneray .;Imlinns 0 5.25 Facility Name Facility IDS (if applicable) 5.25 / 30.5 ' 9_QfifiD Rnstnn Rnxi 315 1 32.3 Street Address I Rnxhnrn N 7573 1 City or Town State Zip Code / .lohn TnetFer / Contact Name 410 R Wilmington St PFR 4A / Mailing Address / ' Rnleinh NC 27601 / City or Town State Zip Code : 12. REMARKS: t 9194 _546 -7863 Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 31.8' b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO I� .a mw - •., 1 DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORD ANCE WITH 15A NCAC 2C. WELL CONSTRUCTION STANDARDS. AND THAT A COPY OF THIS R HAS BEEN PROVIDED TO THE WELL OWNER. nn _ .1.22110 SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing: 16.09 FT Thomas Whitehead (Use ' +" if Above Top of Casing) : PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW -1b Submit within 30 days of completion to: Division of Water Quality - Intonnation Processing, Rev. 2109 1617 Malt Service Center, Raleigh, NC 27999 -161, Phone: (919) 8074300 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality •� ,�• WELL CONTRACTOR CFRTIFICATiON # Z907 1. WELL CONTRACTOR: Thomas Whitehead Well Contractor (Individual) Name SWE. Inc. Well Contractor Company Name 3201 Soring Forest Road Street Address Raleigh NC 27616 City or Town State Zip Code 9c 19 ) 872 -2660 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMITS OTHER ASSOCIATED PERMITS(if applicable) SITE WELL ID #0f applicable) CW-201 J S. WELL USE (Check One Box) Monitoring t y MunicipallPublic ❑ Industrial/Commercial ❑ Agricultural p Recovery p Injection ❑ Irrigationo Other ❑ (list use) DATE DRILLED 11 -1 1 -10 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name, Numbers, Com(ftnity . Subdiviaon, Lot No , Parcel. Zip Code) CITY Roxboro COUNTY Person TOPOGRAPHIC I LAND SETTING: (check appropriate box) ❑Slope CIValley Rat ORidge COther LATITUDE 36 •32 • 19.6700 ^ DMS OR 3x.n0=XXXX DO LONGITUDE 78 53 24 9400 "DIMS OR 7x.xxxxxxxxx DD Lalitudeflongitude source: V,PS Qropographlc map potation of well must be shown on a USGS tope map andattached to this 1wm if not using GPS) 5. FACILITY (Name of the business where the well is located.) Prmrpss Fnprnv Carnlinas Facility Name Facility IDS (if applicable) 10660 Rnsten Road Street Address Roxhorn NC 27573 City or Town State Zip Code John Tnetfpr Contact Name 410 S Wilminatnn St_ PER 4A Mailing Address Ralpinh NC 27601 City or Town State Zip Cade ( 9198 546 -7863 Area code Phone number 6. WELL DETAILS: e. TOTAL DEPTH: 55 -4' b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO uI d. TOP OF CASING IS 2.5 FT. Above Land Surface' 'Top of casing terminated aVor below land surface may require a variance in accordance with 15A NCAC 2C.01 18 e. YIELD (gpm): METHOD OF TEST_ f. DISINFECTION: Type Amount 9. WATER ZONES (depth). Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom : Top Thickness/ 7. CASING: Depth Diameter Weight Material : Top -2.6 Bottom 45.6 Ft- 2" sch 40 PVC : Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Material Method : Top 0 Bottom 38 Ft. Portland Pour : Top 38 _._ Bottom 44 Ft. Bentonite Pour Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 45.6 Bottom 55.4 Fl. 2 in. .010 in. PVC Top Bottom Ft. in in. Top Bottom Ft. In in 10. SANDIGRAVEL PACK: Depth Size Material Top 44 Bottom 56 FL Coarse Sand Top Bottom Ft. Top Bottom Ft. 11. DRILLING LOG Top Bottom 0 /8 8 18 8 55.9 12. REMARKS: Formation Description 1 DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C. WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF T4S RECORD HAS BEEN PROVIDED TOe THE WELL OWNER. ,J• _ 12 -21 -10 SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing: 14.39 FT Thomas Whitehead (Use' *' if Above Top of Casing) : PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit Within 30 tie of completion to: Division of Water Quality Infotrntatlon Processing, Form GW 1b i$ P �Y - ngr Rev 2109 1617 Mall Service Center, Raleigh, NC 27699 -161, Phone : (919) 807 -SM s-10MVPs� 1. WELL CONTRACTOR: Thomas Whitehead Wait Contractor (Individual) Name SWE, Inc. Well Contractor Company Name 3201 SOrina Forest Road Street Address Raleiah NC 27616 City or Town State Zip Code 9t 19 ) 872 -2660 Area code Phone number 2. WELL INFORMATION: NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 2907 WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(4 applicable) SITE WELL ID 0(ir applicable) CW -2 J 3. WELL USE (Check One Box) Monitoring ly Municipal/Public ❑ IndustrlallCommercial ❑ Agricultural ❑ Recovery C Injection L) Irrigation❑ Other ❑ (list use) DATE DRILLED 11 -1 1-10 4. WELL LOCATION: 10660 Boston Rd, 27573 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: Roxboro COUNTY Person TOPOGRAPHIC 1 LAND SETTING. (check appropriate box) ❑Slope ❑Valley VFlat ❑Ridge ❑Other LATITUDE 36 •32 '196700 • DMS OR 3X.XXXXXXXXX DO LONGITUDE 76 • 53 , 24.9401 • DMS OR 7x.XXXXXXXXX DO LalitudeAcngitude source. 03PS 17ropographic map (location of well must be shown on a USGS topo map andettached to this form if not using GPS) 5. FACILITY (Name of the business where the well is located.) Prrtnrt?ss F_nPrnv Carolinas Facility Name Facility ID# (if applicable) 10660 Rnstnn Road Street Address Rnxhnrn NC 97573 City or Town State Zip Code John TrtPtfar Contact Name 410 S_ Wilminntnn St_ PFR 4A Mailing Address RAPinh NG, 27601 City or Town State Zip Code (( 919 546 -7863 Area code Phone number S. WELL DETAILS: a. TOTAL DEPTH: 17.5' b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO U/ d. TOP OF CASING IS 2.5 FT Above Land Surface' 'Top of casing terminated aVor below land sun" may require a variance in accordance with 15A NCAC 2C .0116 a. YIELD (gpm): METHOD OF TEST _ f. DISINFECTION: Type Amount U. WATER ZONES (depth): Top Bottom Top_ Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness] 7. CASING. Depth Diameter Weight Material Top -2.49 Bottom 7.7 F1 -2"- sch 40 PVC Top Bottom Ft Top Bottom Ft. 6 GROUT: Depth Material Method Top 0 Bottom _b FL Portland Pour Topes_ Bottom 6.4 _ Fl._E�gntonile Pouf Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 7.7 Bottom 17.5 Ft. 2 _.in 010 in PVC Top Bottom — Ft—in. in Top Bottom Ft in in. 10. SANDfGRAVEL PACK: Depth S40 Material Top 6.4 Bottom 18 -- Ft. Coarse Sand Top Bottom Ft. Top Bottom Ft. 11 DRILLING LOG Top Bottom Formation Description 0 /_ 6 6 18 _ / 12. REMARKS: I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 1SA NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COP/ OF THIS RE FiA,S BEEN PROVIDED TO THE WELL OWNER ( . ill paJ 12 -21 -10 SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing: 13.86 FT. Thomas Whitehead (Use - +• it Above Top of Casing) PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW -1b Submit within 30 days of completion to: Division of Water Quality - Infortnation Processing, Rev. 2,09 1617 Mail Service Center, Raleigh, NC 27699 -161, Phone :(919) 807 -6300 y r� I. WELL CONTRACTOR: Thomas Whitehead Well Contractor (Individual) Name Inc Well Contractor Company Name 3201 Sorina Forest Road Street Address E3aleiah NC 27616 City or Town State ZIP Code 9( 19 ) 872 -2660 Area code Phone number NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICA'T'ION # 2907 2. WELL INFORMATION: WELL CONSTRUCTION PERMITS OTHER ASSOCIATED PERMITS(if applicable) SITE WELL ID Oil applicable) CW -1 3. WELL USE (Check One Box) Monitoring V Municipal/Public ❑ IndustriaYCommercial ❑ Agricultural ❑ Recovery ❑ Injector ❑ Irrigation❑ Otter ❑ Cis[ use) DATE DRILLED 11 -8-10 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name. Numbers, Community, Subdivision, Lot No, Parcel, Zip Code) CITY Roxboro COUNTY Person TOPOGRAPHIC/ LAND SETTING' (check appropriate box) ❑Slope ❑Valley Flat ❑Ridge ❑Otter LATITUDE 36 ' 91 -56,4900 - DMS OR 3x.XXXXXXXXX DD LONGITUDE 78 53 , 192200 "DMS OR 7x.XXXXXXXXX DD LatiludeAongitude source: W3PS aopographic map (location of wetl must be shown on a USGS topo map andatfached to this form if not us,ng GPS) S. FACILITY (Name of tie business where the well is located) Prnnil Fnernv Carolinas Facility Name Facility IDS (if applicable) 10660 Rnston Road Street Address Rnxhnro NC 27573 City or Town State Zip Code John TnetfPr Contact Name 410 S Wilmington St PFR 4A Mailing Address Raleinh NC 27601 City or Town State Zip Code ( 9198 546 -7863 Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 39.9' b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO L1/ d. TOP OF CASING IS 2.5 FT, Above Land Surface' 'Top of casing terminated atior below lend surface may require a variance In accordance with 15A NCAC 2C .0118 e. YIELD (gpml METHOD OF TEST t. DISINFECTION: Type Amount g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top -2.65 Bottom 30.1 FL 2" sch 40 PVC Top Bottom FL Top Bottom FL 8. GROUT Depth Material Method Top 0 Bottom 8 Ft Portland Pour Top $_ Bottom 29 Ft. Bentonile Pour Top Bottom Ft 9. SCREEN: Depth Diameter Slot Size Material Top 30.1 Bottom 39.9 Ft 2 in .010 in. PVC Top Bottom Ft, in in Top Bottom Ft in in. 10. SAND /GRAVEL PACK: Depth Size Material Top 29 Bottom 40.75 Ft. Coarse Sand Top Bottom Ft. Top Bottom Ft. 11. DRILLING LOG Top Bottom Formation Description 0 if 5 Sandy Clay 5 1 14 Weathered Rock 4 140.40 Rock if if / / / 12. REMARKS: 1 DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NGC 21— WELL CONSTRUCTION STANDARDS, ANO THAT A COPY OF THIS R O HAS BEEN PROVIDED TO THE WELL OWNER. �CERTIFIED 1+61014 12 -21 -1D SIGNATURE WELL CONTRACTOR DATE e. WATER LEVEL Below Top of Casing- 18.64 FT. Thomas Whitf1head (Use '+' ff Above lop of Casing) PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form Submit within 30 days of completion to: Division of Water Quality Information Processing, Rev. )09 Y P KY - g Rev. 2109 1617 Mali Service Center, Raleigh, NC 27699 -161, Phone : (919) 807 -6300 s'`SWt° 1. WELL CONTRACTOR: Thomas Whitehead Well Contractor (Individual) Name SWE, Inc. Well Contractor Company Name 3201 Spring Forest Road Street Address Raleiah NC 27616 Cily or Town State Zip Code 9( 19 ) 872 -2660 Area code Phone number 2. WELL INFORMATION: NONRESIDENTIAL WELLCONSTRUCr1ON RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 2907 WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMTTi(7 applicable) SITE WELL ID #(if applicable) CW -1 J 3. WELL USE (Check One Box) Monitoring (y Municipal/Public p Industrial/Commercial ❑ Agricultural O Recovery ❑ Injection O Irrigationo Other ❑ (list use) DATE DRILLED_ 11-9-10 4. WELL LOCATION: 10660 Boston Rd. 27573 (Street Name, Numbers, Community, Subdrvialon, Lot No, Paroel, Zip Code) crTY: Roxboro COUNTY Person TOPOGRAPHIC I LAND SETTING' (check appropriate box) ❑Slope ❑Valley JiFlat ❑Ridge ❑Other LATITUDE 36 '31 ' 58.4300 "DMS OR 3x.xxxxxxxxx DO LONGITUDE 78 ' 53 192200 "DMS OR 7x.xxxxxxxxx DD Latnude/longitude source: W3PS Oropographtc map (location of well must be shown on a USGS fopo map andattached to this fom+ifnot using GPS) S. FACILITY (Name of the business where the well is located ) Pronriptsq FnPrav .arnlinas Facility Name Facility IDO (If applicable) 10660 Rnstnn Rnari Street Address Rnxhnrn NC 27573 City or Town State Zip Code .Inhn Tnetfar Contact Name 4101 S_ Wilminatnn St PFR 4A Mailing Address Raleigh NC 27901 City or Town Stale Zip Code ( 919 546 -7863 Area code Phone number d. TOP OF CASING Is 2_5 FT. Above Land Surface' 'Top of casing terminated at/or below land surface may require a vanance in accordance with 15A NCAC 2C.01 18 a. YIELD (gpm) METHOD OF TEST_ f. DISINFECTION: Type Amount g. WATER ZONES (depth) Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom_ Top Bottom Thickness! 7. CASING: Depth Diameter Weight Material Top -2_92 Bottom 15.5 Ft. 2 ' sch 40 PVC Top Bottom Ft. Top Bottom Ft 8. GROUT: Depth Material Method Topes_ Bottoms_ Ft. Portland Pour Top S_ Bottom 14 Ft. Bentonite Pour Top Bottom_ Ft. 9. SCREEN: Depth Diameter Slot Slza Material Top 15.5 Bottom- 25 Ft. 2 in. _QJJ In. PVC Top Bottom Fl. _in in. Top Bottom Ft. in in 10. SAND /GRAVEL PACK: Depth Size Material Top-11--Bottom 255 Fl. COarsB Sand Top Bottom Ft. Top Bottom Ft. 11 DRILLING LOG Top Bottom Formation Description 0 /5 5 /20 20 25.5 / 12. REMARKS E . • • -. a' -• -', - -- - -- 6. WELL DETAILS: : I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH • 1SA NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THAT A COPY OF THIS a. TOTAL DEPTH: 25' - RECORD HAS BEEN PROVIDED TO THE WELL OWNER. 12 -21 -16 b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO Cif SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing. _19.84 FT Thomas Whitehead (Use' *' it Above Top of Casing) : PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW•1b Submit within 30 daysof completion to: Division of Water Quality - Information Procaesing, Rev. 2109 1617 Mall Servleu C•ntic Raleigh, NC 27699 -161, Phone : (919) 607 -6300 BORRIG LOG ' SS. Drill Rig. GGO ' Pro �;� Date Drilled. 1015 %$ By L/ 5Logged - -- 'bbll��y Ll inches Boring Vumber MW ' t Bonng Dia: .� Counts Completion �� Lithology Description , m M 0 $� f�.tn Orgy• C11-we p s►1f 10 i, 's' r5�•ao' 41iuc c.l� Y s ,1 �, � ,., , t:ti /�-y I�el�a�. 0 7 1 ,;51-301 i 3v•3S� � ah ` , 3 o 35-- 52 ' f plc �cl�, le) o'- Z v 6ro' S }'O 'lif- 521 tISS 35 bys, sty ►�, ' - ->_ G -r Completion Notes. L '�vL 5t"rewe S°''k dram "7 ''lL� Site. 'L 's" �S. w� 0. o 10 " s to gy s c.ri 3 e,n . / F< �r nsw�. 4Y -301 o x r11 C f, 52 _ '46, 'b r.Is, owi7r P,—.c (, _ S t tt a c fi ra � �j CIA, ( , of ac4 r^ ro7G C. b. l l (,.r(,.r- I'll It,- — C. n ) ' — - —� 2��wc� 37. si S . P oled No Page 1 COMPLETION REPORT OF WELL No. 13G -2 Sheet 1 o11 PROJECT. Progress Energy - Mayo Steam Station PROJECT NO: 1584 -10 -027 WATER LEVEL Depth to water 35.57 feet PROJECT LOCATION: Person County - 2.82 -25.4 below top of casing Type: LATITUDE' Interval: 0 -21 SEAL LONGITUDE Type. DRILLING CONTRACTOR. Quantex 21 -23 TOP OF CASING ELEVATION DRILLING METHOD 4" Air Hammer 542.66 DATUM . � DATE DRILLED 9128110 MSL LOGGED BY. L. Butler STRATA WELL = 0 C DESCRIPTION m M DETAILS wr Uj ; c c 3 c c a s C COMPLETION REPORT OF WELL No. CW -6 sheet I of 1 PROJECT: Progress Energy - Mayo Steam Station PROJECT NO 1584 -10 -027 WATER LEVEL' Depth t0 water 14.33 feet PROJECT LOCATION Person County DESCRIPTION below top of casing tL pv LATITUDE: LONGITUDE DRILLING CONTRACTOR T. Whitehead TOP OF CASING ELEVATION: DRILLING METHOD: 4" Air Hammer DATUM 462.83 DATE DRILLED 11/11/10 LOGGED BY: Ill 435.27 Diameter: Type TOPSOIL with sand L. Butler STRATA WELL DETAILS w = o � J 0 J Lu WELL CONSTRUCTION DETAILS DESCRIPTION m U) tL pv PROTECTIVE CASING 0 0.00 GS 435.27 Diameter: Type TOPSOIL with sand 000 CG 435 27 silt matrix 5 Interval: Moist Light Brown Orange Sandy SILT with small angular rock fragments in the matrix 10 t RISER CASING Diameter: 2 Type PVC Dense Light Brown Orange Sandy SILT Dry, saprolite with iron fairing on relict 15 Interval: +2.88 -72.1 structure 20 GROUT Type. Cement switch to air hammer Tilling only yeilding a dry, colored sandy silt rock flour 25 Interval. 0 -62.7 Rock mos8y grey pink black granitic rock, SEAL with a softer, darker more mafc -rich zone between 20' to 22' bg. 30 Type Bentonite Interval- 62.7 -68.7 approximate 6 " 35 fracture zone to 28" g. all dry with no FILTERPACK igns of water. 40 Type: #2 Sand Interval 68.7 -77.4 Granitic Rock felsic cuttings with mafic seams from 47' to 51' 45 and from 66' to 77' fractures at 40', 41', SCREEN 65', dry : observed water at 71', observed abundunt water at 76' 50 55 Diameter. 2 Type: 0.010 Interval. 72.1 -76.9 60 62.70 BS 1372.57 LEGEND 65 FI FILTER PACK 70 68.70 FP 366.57 ■ BENTONITE TOC TOP OF CASING CEMENT GROUT GS GROUND SURFACE BS BENTONITE SEAL ® CUTTINGS / BACKFILL FP FILTER PACK 72.10 TSC 363 17 75 76.90 BSC 1 35837 TSC TOP OF SCREEN STATIC WATER LEVEL BSC BOTTOM OF SCREEN TD TOTAL DEPTH CG CEMENT GROUT 77.40 1 ID I 35T137- -- COMPLETION REPORT OF #SME WELL No. CW-6 ENGINEERING • TESTING Sheet 1 of 1 ENVIRONMENTAL SERVICES COMPLETION REPORT OF WELL No. CW -5 Sheet I of l PROJECT: Progress Energy - Mayo Steam Station PROJECT NO: 1584 -10 -027 WATER LEVEL: Depth t0 water 10.69 feet PROJECT LOCATION: Person County 0.00 below top of casing 507.21 Diameter: LATITUDE FILTER PACK 0.00 Type LONGITUDE: STATIC WATER LEVEL DRILLING CONTRACTOR. T. Whitehead TOP OF CASING ELEVATION: TD DRILLING METHOD 4" Air Hammer CG 509.60 DATE DRILLED 11/15/10 DATUM: MSL LOGGED BY: L. Butler STRATA WELL a I, o m �_ DETAILS a 0 §� WELL CONSTRUCTION DETAILS DESCRIPTION a x 0 W W VI 0 vl J W ReSicluum: Orange Brown Fine to Coarse ery Sandy SILT an Brown Very silty (Fine to Coarse SAND Partially Weathered Rock sampled as Gray Silty Fine to oarse SAND Rock earn from 3.5' to 5' Rock - Felsic to Intermediate Metavolcanic weathered zones 16' to 17', 20' to 22, 32 5' to 33, 34.5' to 36', fractures at 24', 38' and 40' no signs of water observed prior to 38' bg �I s d n SCREEN Diameter. 2 Type: 0.010 Interval: 36.341.1 LEGEND FILTER PACK . BENTONITE TOC TOP OF CASING PROTECTIVE CASING 0 0.00 GS 507.21 Diameter: CG 507.21 FILTER PACK 0.00 Type TOP OF SCREEN STATIC WATER LEVEL BSC Interval 5 TD TOTAL DEPTH CG = 800 BS 499.21 RISER CASING 10 Diameter: 2 Type: PVC 15 Interval: - 2.39 -36.3 20 GROUT Type Cement Interval: 0 -8 25 SEAL 3o Type Bentonite 33.00 FP 474.21 Interval 8 -33 1 35 36.30 TSC 1 470.91 FILTERPACK 40 41.10 BSC 466.11 Type: #2 Sand Interval: 33 -43.0 43.00 464.21 SCREEN Diameter. 2 Type: 0.010 Interval: 36.341.1 LEGEND FILTER PACK . BENTONITE TOC TOP OF CASING GS GROUND SURFACE ® CEMENT GROUT BS BENTONITE SEAL ® CUTTINGS / BACKFILL FP FILTER PACK TSC TOP OF SCREEN STATIC WATER LEVEL BSC BOTTOM OF SCREEN TD TOTAL DEPTH CG CEMENT GROUT COMPLETION REPORT OF WELL No. CW -5 Z ENGINEERING - TESTING Sheet 1 of 1 f ENVIRONMENTAL SERVICES c ii PROJECT Progress Energy - Mayo Steam Station Person County BORING LOG CW -B4 1584 -10 -027 NOTES No water in boring after 24 hours DATE DRILLED: 11112110 ELEVATION DRILLING METHOD 4" Air Hammer BORING DEPTH 22.5 LOGGED BY: L. Butler WATER LEVEL Dry DRILLER T. Whitehead DRILL RIG U J w p w ui STANDARD PENETRATION TEST DATA w = a (7 o MATERIAL DESCRIPTION LH o ii a t blowslft) a (� w w J a Z Z w V 10 20 3.0 60 80 5 Residuum: Tan Brown Fine to Coarse Very Sandy SILT 10 - Partially Weathered Rock: sampled as Tan Silty Fine to 15 Coarse SAND _ Tan Brown Fine to Coarse Very Sandy SILT Partially Weathered Rock sampled as Tan Silty Silty Fine 20 to Coarse SAND Rock - Intermediate Metavolcanic NOTES: HI L G IS ONLY A PORTION OF A REPORT FOR THE NAMED PROJECT AND MUST ONLY BE USED TOGETHER WITH THAT REPORT 2 BORING, SAMPLING AND PENETRATION TEST DATA IN GENERAL ACCORDANCE WITH ASTM D -1586 3 STRATIFICATION AND GROUNDWATER DEPTHS ARE NOT EXACT 4 WATER LEVEL IS AT TIME OF EXPLORATION AND WILL VARY Page 1 of 1 *S&ME ENGINEERING • TESTING ENVIRONMENTAL SERVICES STRATA COMPLETION REPORT OF WELL No. CW-4 Sheet 1 of 1 PROJECT. Progress Energy - Mayo Steam Station 0 PROJECT NO: 1584 -10 -027 WATER LEVEL Depth to water 22.53 feet PROJECT LOCATION: Person County below top of casing Type LATITUDE omi w LONGITUDE WELL CONSTRUCTION DETAILS DRILLING CONTRACTOR T. Whitehead a� TOTAL DEPTH TOP OF CASING ELEVATION CG DRILLING METHOD 4" Air Hammer 451.31 DATE DRILLED DATUM 11/12/10 III LOGGED BY L. Butler STRATA WELL TOP OF CASING o 0 GS 448 76 Diameter: _ CG 448.76 Type DETAILS omi w ; o' s n f 0 0 i C COMPLETION REPORT OF WELL No. CW -3 Sheet 1 of 1 PROJECT Progress Energy - Mayo Steam Station PROJECT NO 1584 -10 -027 WATER LEVEL: Depth to water 16.09 feet PROJECT LOCATION. Person County m° g U) below top of casing LATITUDE: LONGITUDE. DRILLING CONTRACTOR: T. Whitehead TOP OF CASING ELEVATION DRILLING METHOD 4° Air Hammer DATUM: DATE DRILLED. 11116110 LOGGED BY: MSL MSL Diameter: Type: Interval: Topsoil L_ Butler STRATA WELL DETAILS w o o w 0 ; WELL CONSTRUCTION DETAILS J w DESCRIPTION m° g U) a O PROTECTIVE CASING 0 000 GS 435.27 Diameter: Type: Interval: Topsoil 000 CG 435 27 Residuum Orange Brown Slightly Clayey Fine Sandy SILT 5 10 t15 3E 7.00 BS 428.27 RISER CASING Diameter: 2 Type PVC Interval +2.41 -17.0 Gray Orange Fine to Coarse Very Sandy I LT 15.00 FP 420.27 Orange Brown Silty Fine to Coarse SAND `Probe refusal at 5 5 17.00 TSC 418.27 feet 20 GROUT Type. Cement Partially Weathered Rock: sampled as Silty Fine to Coarse Interval 0 -7 SAND ;rock seam 25 from 20 - 21 feet; first apparent water at 26 SEAL feet 30 31.80 BSC 403.47 Type. Bentonite Interval 7 -15 FILTERPACK Rock Felsic Meta - volcanic Type: #2 Sand Interval: 15 -32.3 SCREEN Diameter: 2 Type 0.010 Interval. 17.0 -31.8 LEGEND FILTER PACK ■ BENTONITE TOC TOP OF CASING ® CEMENT GROUT GS GROUND SURFACE BS BENTONITE SEAL ® CUTTINGS I BACKFILL FP FILTER PACK TSC TOP OF SCREEN t STATIC WATER LEVEL BSC BOTTOM OF SCREEN TD TOTAL DEPTH CG CEMENT GROUT COMPLETION REPORT OF #SWE WELL No. CW -3 ENGINEERING . TESTING Sheet 1 of 1 ENVIRONMENTAL SERVICES STRATA COMPLETION REPORT OF WELL No. CW -2D Sneet 1 of 1 PROJECT: Progress Energy - Mayo Steam Station = PROJECT NO: 1584 -10 -027 WATER LEVEL: Depth to water14.39 feet PROJECT LOCATION: Person County below top of casing LATITUDE J m LONGITUDE: DETAILS DRILLING CONTRACTOR T. Whitehead ; COMPLETION REPORT OF WELL No. CW -2 Sheet 1 of 1 PROJECT: Progress Energy - Mayo Steam Station PROJECT NO: 1584.10 -027 WATER LEVEL: Depth to water13.86 feet PROJECT LOCATION: Person County 0 below top of casing LATITUDE: m = LONGITUDE w� DRILLING CONTRACTOR, T. Whitehead TOP OF CASING ELEVATION DESCRIPTION 2 o- 389.00 DRILLING METHOD: J DATUM: DATE DRILLED: 11/11/10 LOGGED BY: MSL w PROTECTIVE CASING L. Butler STRATA WELL o 0 LEGEND m = DETAILS w� w >� WELL CONSTRUCTION DETAILS DESCRIPTION 2 o- FILTER PACK w J to pV ■ BENTONITE TOC TOP OF CASING w PROTECTIVE CASING GS GROUNDSURFACE o 0 ® CEMENT GROUT SEAL 0.00 GS 386.56 Diameter: Type: Residuum: ® FP FILTER PIACK CUTTINGS / BACKFILL 000 CG 386.56 Brown- Orange Fine TSC TOP OF SCREEN Interval: Sandy SILT 5 5.00 BS 381.56 6 40 FR 39016 Tan - Orange Very Silty L CG CEMENT GROUT T— R Fine to Medium RISER CASING AND 10 Diameter: 2 Partially Weathered Rock: sampled as Type PVC Tan - Orange Silty Fine t5 Interval +2,44 -7,7 to Coarse SAND 17.75 BSC 368 81 GROUT 1800 TD 368 56 Type. Cement Interval. 0 -5 SEAL Type Bentonite Interval. 5 -6.4 FILTERPACK Type. #2 Sand Interval. 6.4 -18 SCREEN Diameter: 2 Type 0.010 Interval 7.7 -17.5 COMPLETION REPORT OF SWE WELL No. CW -2 ENGINEERING - TESTING Sheet 1 of 1 ENVIRONMENTAL SERVKES LEGEND FILTER PACK e ■ BENTONITE TOC TOP OF CASING GS GROUNDSURFACE o ® CEMENT GROUT SEAL ® FP FILTER PIACK CUTTINGS / BACKFILL r TSC TOP OF SCREEN 1 STATIC WATER LEVEL BSC BOTTOM OF SCREEN TD TOTAL DEPTH CG CEMENT GROUT T— R COMPLETION REPORT OF SWE WELL No. CW -2 ENGINEERING - TESTING Sheet 1 of 1 ENVIRONMENTAL SERVKES r 1 1 1 1 r 1 c u k u 0 c C c 0 U U u 0 a r 9 e 5 r C C COMPLETION REPORT OF WELL No. CW -1 D Sheet 1 of 1 PROJECT: Progress Energy - Mayo Steam Station PROJECT NO- 1584 -10 -027 PROJECT LOCATION: Person County DRILLING CONTRACTOR T. Whitehead DRILLING METHOD 4'/4" H.S.A., 4" Air Hammer DATE DRILLED 1118110 WATER LEVEL Depth to water 18.64 Feet STRATA below top of casing LATITUDE WELL LONGITUDE 0 TOP OF CASING ELEVATION. 490.96 DATUM °m MSL LOGGED BY: >- WELL CONSTRUCTION DETAILS I Rifflar STRATA WELL o 0 °m DETAILS a 0 >- WELL CONSTRUCTION DETAILS DESCRIPTION g a.,t� O J J of o v w PROTECTIVE CASING 0 0.00 1 GS 488.31 1 Diameter: Type: Interval: TOPSOIL 0.00 CG 488.31 Residuum Dry Gray Orange Slightly 5 Clayey Fine Sandy SILT 8.00 BS 480.31 RISER CASING Dry Light Gray Fine 10 Diameter 2 Very Sandy SILT with Rock Fragments 15 Type PVC Interval +2.65 -30.1 Dry Light Gray Very Silty Fine to Medium Sandy SAND (probe refusal -4') 20 GROUT Type: Cement Partially Weathered Rock: sampled as Interval: 0-8 Green Silty Fine to 25 Coarse SAND 30 29.00 FP 459.31 SEAL Type Bentonite eta - argillite Rock - meta argillite 3010 Green Brown SILT Interval 8.29 Micaceous 35 FILTERPACK Meta - argillite Meta - argillite Green Brown SILT 40 39 90 BSC 448.41 Type #2 Sand caceous Interval: 29 -10.75 SCREEN Meta - argillite with Mi Diameter 2 Type: 0.010 interval: 30.1 -39.9 LEGEND FILTER PACK ■ BENTONITE TOC TOP OF CASING GS GROUND SURFACE ® CEMENT GROUT BS BENTONITE SEAL ® CUTTINGS / BACKFILL FP FILTER PACK TSC TOP OF SCREEN = STATIC WATER LEVEL BSC BOTTOM OF SCREEN TD TOTAL DEPTH CG CEMENT GROUT COMPLETION REPORT OF WELL No. CW -1D ENGINEERING • TESTING Sheet 1 Of 1 ENNRONMENUL SERVICES I t. I-tenriques STRATA WELL o 0 T� DETAILS C_ >- WELL CONSTRUCTION DETAILS DESCRIPTION M o- o W W V1 0 J w TOPSOIL COMPLETION REPORT OF WELL No. CW -1 Sheet 1 of 1 PROJECT. Progress Energy - Mayo Steam Station 0.00 PROJECT NO. 1584 -10 -027 WATER LEVEL Depth to water 19.84 feet PROJECT LOCATION: Person County below top of casing artiallered LATITUDE. 463,96 10 LONGITUDE: BSC DRILLING CONTRACTOR T. Whitehead TOP OF CASING ELEVATION: 15 DRILLING METHOD 4" Air Hammer DATUM. DATE DRILLED 11/9/10 1 nnrcn Ry. MSL MSL t. I-tenriques STRATA WELL o 0 T� DETAILS C_ >- WELL CONSTRUCTION DETAILS DESCRIPTION M o- o W W V1 0 J w TOPSOIL TOC 0 PROTECTIVE CASING 0.00 Dry Light Gray Fine Sandy SILT with Rock ragments j Diameter: Type: 5 CG 486 -96 artiallered ock s as :Green-G:ra:ySand y 463,96 10 _ STATIC WATER LEVEL BSC ILT RISER CASING 15 , Partially Weathered 14.00 FP Rock sampled as Type: PVC Interval: +2.92 -15.5 1550 TSC 47 Green -Gray SILT Hard Drilling 20 Green -Gray Sandy SILT BSC 461.96 Intervai 0 -3 SEAL I-A-25 Meta- argillite Rock: 461 46 (sampled as Green -Gray Sandy SILT Hard drillina *SM ENGINEERING • TESTING ENVIRONMENTAL SERVICES SCREEN Diameter: 2 Type 0.010 Interval 15.5 -25.0 LEGEND FILTER PACK ■ BENTONITE TOC TOP OF CASING PROTECTIVE CASING 0.00 GS 486.96 Diameter: Type: 000 CG 486 -96 3 08 BS 463,96 Interval. _ STATIC WATER LEVEL BSC BOTTOM OF SCREEN RISER CASING TD TOTAL DEPTH Diameter 2 14.00 FP 472.96 Type: PVC Interval: +2.92 -15.5 1550 TSC 47 GROUT Type Cement 25.00 BSC 461.96 Intervai 0 -3 SEAL 75.50 TD 461 46 Type: Bentonite Interval. 3 -14 FILTERPACK i Type #2 Sand Interval 14 -25.5 SCREEN Diameter: 2 Type 0.010 Interval 15.5 -25.0 LEGEND FILTER PACK ■ BENTONITE TOC TOP OF CASING GS GROUND SURFACE ® CEMENT GROUT BS BENTONITE SEAL ® CUTTINGS / BACKFILL FP FILTER PACK TSC TOP OF SCREEN _ STATIC WATER LEVEL BSC BOTTOM OF SCREEN TD TOTAL DEPTH CG CEMENT GROUT COMPLETION REPORT OF WELL No. CW -1 Sheet 1 of 1 APPENDIX A ' BORING LOGS AND MONITORING WELL ' CONSTRUCTION LOGS TABLE 2 SAMPLE PARAMETERS, ANALYTICAL METHODS, CONTAINERS, PRESERVATIVES AND HOLDING TIMES MAYO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, INC., ROXBORO, NORTH CAROLINA PARAMETERS UNITS CONTAINERS PRESERVATIVES HOLDING TIMES ANALYTICAL METHOD Field Parameters Field pH SU Flow- through Cell None Analyze Immediately YSI 556 Multi -Meter Specific Conductivity mmhos/cm Flow- through Cell None Analyze Immediately YSI 556 Multi -Meter Temperature C Flow- through Cell None Analyze Immediately YSI 556 Multi -Meter Water Level ft - - - Water Level Meter Laboratory Analysis Aluminum mg/L 500 ml HDPE pH < 2 HNO, 6 months TRM i EPA 200.7 Antimony µg/L 500 ml HDPE pH < 2 HNO3 6 months TRM! EPA 200.8 Arsenic µg/L 500 ml HDPE pH < 2 HNO, 6 months TRM / EPA 200.8 Barium mgrL 500 ml HDPE pH < 2 HNO3 6 months TRM / EPA 200.7 Boron mgiL 500 ml HDPE pH < 2 HNO, 6 months TRM / EPA 200.7 Cadmium µg /L 500 ml HDPE pH < 2 HNO; 6 months TRM / EPA 200.8 Chloride mg/L 125 ml HDPE Cool 4 C 28 days EPA 300.0 Chromium (total) mg/L 500 ml HDPE pH < 2 HNO, 6 months TRM / EPA 200.7 Copper mg /L 500 ml HDPE pH < 2 HNC; 6 months TRM / EPA 200.7 Iron mgiL 500 ml HDPE pH < 2 HNO3 6 months TRM / EPA 200.7 Lead µg /L 500 ml HDPE pH < 2 HNO, 6 months TRM / EPA 200.8 Manganese mgiL 500 ml HDPE pH < 2 HNO3 6 months TRM / EPA 200.7 Mercury µg/L 500 ml HDPE pH < 2 HNO3 6 months EPA 245.1 Nickel mgiL 500 ml HDPE pH < 2 HNO3 6 months TRM / EPA 200.7 Nitrate (as Nitrogen) mgiL 125 ml HDPE Cool 4' C 48 hours EPA 300.0 Selenium µgL 500 ml HDPE pH < 2 HNO3 6 months TRM ! EPA 200.8 Sulfate mgiL 125 ml HDPE Cool 4 C 28 days EPA 300.0 Total Dissolved Solids mg /L 250 ml HDPE Cool 4 C 28 days SM 2540C Thallium µg/L 500 ml HDPE pH < 2 HNO, 6 months TRM / EPA 200.8 Zinc mgiL 500 ml HDPE PH < 2 HNO, 6 months TRM,' EPA 200.7 Prepared tly HJr cneCKeo by JA)'I Notes SU - Standard Units mSicm - micro siemen per centimeter It - feet my - milli volts mgiL - milligrams per liter µg/L - micrograms per liter NTU - NephelomeMC Turbidity Units TRM - Total Recoverable Metals EPA - Environmental Protection Agency SM - Standard Method P \puke Energy Progress. 1026WLL NC SITESWPDES Pemnt Deliveraoles\Mayo\GW Monitoring Plan \Tables \Tab(es i and 2 TABLE 1 MONITORING WELL INFORMATION MAYO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, INC., ROXBORO, NORTH CAROLINA WELL ID DATE INSTALLED NORTHING EASTING USE TYPE OF CASING WELL DIAMETER (inches) TOP OF CASING ELEVATION (NAVD 88) WELL DEPTH* (TOC) WELL SCREEN INTERVAL* (feet BGS) SCREEN LENGTH (feet) BG -1 10/15/2008 1012000.52 2028480.40 Background PVC 2.0 54011 55.43 42-52 10 BG -2 9/28/2010 1010809.99 2028799.48 Background PVC 2.0 542.66 48.36 25.4-44.9 19.5 CW -1 11/9/2010 1012696.54 2032714.46 Compliance PVC 2.0 489.88 29.11 15.5-25.0 9.5 CW -1D 11/8/2010 1012703.55 2032715.65 Compliance PVC 2.0 490.96 43.65 30.1 -39.9 9.8 CW -2 11/11/2010 1015043.98 2032238.71 Compliance PVC 2.0 389.00 20.50 7.7-17.5 9.8 CW -2D 11/11/2010 1015046.88 2032245.02 Compliance PVC 2.0 389.53 58.85 45.6-55.4 9.8 CW -3 11/16/2010 1015647.59 2031278.02 Compliance PVC 2.0 437.68 35.01 17.0-31.8 14.8 CW -4 11/12/2010 1015911.44 2030436.27 Compliance PVC 2.0 451.31 43.08 35.0-39.8 4.8 CW -5 11/15/2010 1015162.23 2029182.29 Compliance PVC 2.0 509.60 44.28 36.3-41.1 4.8 CW -6 11/11/2010 1014743.82 2033046.08 Compliance PVC 2.0 462.83 80.58 72.1 -76.9 4.8 Prepared fay: AJY Checked fay: LL Notes: TOC - Top of Casing BGS - Below Ground Surface NAVD 88 - A vertical control datum in the United States by the general adjustment of 1988 - Well depths are based upon field observations. Screen intervals are based on well instalation logs. N \Dukn Energy Progress. 102MALL NC SITES\NPOES Pertrut OebverablestMayo\GW Monitoring Plan \Tables \Tables 1 and 2 Page 1 of 1 TABLES v n E 0 U N E m E 0 U CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Duke _ _ _ _ _._._._._._._._._._._. r --------------------------------------------------------•-•------- Duke Energy Analytical Lab Services j j Analytical Laboratory Use Dint i Energy Mail Code 9 Hager (Building 7405) ! !LIMB # NC \ "Page 1 TI 1 1 I Originating 1 DISTRIBUTION 13339 Hagers Ferry Rd 1 i From SC i Huntersville, N. C. 28078 i 'Logged te & Time SAMPLE PROGRAM I For Detailed Instructions, see ORIGINAL to LAB. (704) 875 -5245 j j gg ed B y i COPY to CLIENT http / /dewww /essenv /coc/ Groundwater Fax: 704 875 -5038 1 i i 1)Project Name 2)Phone No: 3)Client 4)Fax No: 5)Business Unit: 20036 6)Process: 7)Resp. To: 8)Project ID: 9)Activity ID: 10)Mail Code: i LAB USE ONLY I 'Chem Desktop 1 "Lab ID I No. I- - -i I t 0 I I N I 1 E — o 1 ly 1 I .n I to a a 1 1 v a 1 1 a I to U O E i i0 N 1 I � ;U le Descriation or ID vendor u ystomer to 51 n d UGIC —VW Date/Time Drinking Water _ 1 1 Date/Time UST j Cooler Temp C 1 jPO # 15Preserv.:1 =HCL N Relinquished By DatelTime Accepted B P Y DatelTime o .0 E o _ A 14 Days '7 Days Relinquished By Date/Time Accepted By Date/Time 2 =H2S0° 3 =HNO, 23)Seal /Locked By DatelTime SealedlLock Opened By DatelTime o .' 4 =Ice 5 =None N, � N U A 'Other :MR # FIGURE 6 a Add. Cost Will Apply v o C —� U NON- SHADED w u m 0 r E 14 Collection Information Date Time Sionature ^ 9 P 21)Relinquished By u ystomer to 51 n d UGIC —VW Date/Time Accepted By Date/Time a„ _ za Requested Turnaround N Relinquished By DatelTime Accepted B P Y DatelTime o .0 E o _ A 14 Days '7 Days Relinquished By Date/Time Accepted By Date/Time 23)Seal /Locked By DatelTime SealedlLock Opened By DatelTime o .' N, � N U A 'Other 24)Comments FIGURE 6 a Add. Cost Will Apply L7 synTerra Instrument ID: YSI- 556 -NIPS Analyst: Instrument Calibration Log SynTerra Corporation 148 River Street, Suite 220 Greenville, South Carolina 29601 NC Field Parameter Certification No. 5591 Date: Location: pH Initial Calibration (standard units) Reference Method: SW846 9040C Cal. Time Cal. Buffer 4.0 Cal. Buffer 7.0 Cal Buffer 10.0 *Check Buffer 7.0 -pH butter checks are to be wlttun t U.1 ptl units of the standards true value 4 Buffer Reference: 10 Buffer Reference: 7 Buffer Reference: Check Buffer Reference: pH Calibration Check {standard units) I Time I Check Buffer True Value I *Check Buffer Measured Value Mid -Day End -of -Day Other 'pH butler checks are to be witfun t 0.1 pH units of the standards true value Check Buffer Reference: Action Required: Specific Conductance (umhos /cm) Rpfprpnrp Mathnrl- cwlzar, onsne Time Calibration Std 1413 Verification Std 1413 Initial Cal Meter DO Reading (mg/L Correction Factor Theoretical DO m /L Mid -Day Not Applicable End -of -Day Not Applicable Mid -Day -venricanon standard t lu percent of the standards true value Calibration Standard Reference: Verification Standard Reference: Action Required: Dissolved Oxygen (mg /L) Rpfprpnrp Mpthnel- SM arnn n r -7nn7 ucvicu m w - U<g nurn uissuneu V\ygen meter l.altoratlon venrlcatlon i able at anDlent temp X Correction f actor at Baromehic Pressure Theoretical DO and Meter DO reading within _ 0 5 mE I, if not calibrate meter Action Required: _ FIGURE 5 - EXAMPLE FIELD SAMPLING CALIBRATION FORM Time Temp °C Barometric Pressure mm H Meter DO Reading (mg/L Correction Factor Theoretical DO m /L Initial Mid -Day End -of -Day ucvicu m w - U<g nurn uissuneu V\ygen meter l.altoratlon venrlcatlon i able at anDlent temp X Correction f actor at Baromehic Pressure Theoretical DO and Meter DO reading within _ 0 5 mE I, if not calibrate meter Action Required: _ FIGURE 5 - EXAMPLE FIELD SAMPLING CALIBRATION FORM FIGURE 4 LOW FLOW SAMPLING LOG DUKE ENERGY PROGRESS. INC 0 FIELD PERSONNEL: synTerm WEATHER: ❑ SUNNY ❑ OVERCAST Cl RAIN TEMPERATURE (APPROXI 148 River Street, Suite 220 NOTES: Greenville. South Carolina 29601 (864) 421 -9999. 18641 421 -9909 Fax vnvw. synTerracorp. corn WELL ID: PUMP/TUBING INTAKE DEPTH: IFT) START PURGE TIME: MEASURING POINT: START PURGE DATE: END PURGE TIME: WELL DIAMETER: (IN) END PURGE DATE: FINAL READING TIME: WELL DEPTH: (FT) TOTAL VOLUME PURGED: (GAL1 DEPTH TO WATER: (FT r SAMPLE DATE: SAMPLE COLLECTION TIME: PURGE METHOD: ❑ Grundfos Pump ❑ 12 Volt Pump ❑ Peristaltic Pump ❑ Dedicated Pump ❑ Teflon Bailer ❑ Polyethylene Bailer SAMPLE METHOD: ❑ Grundfos Pump ❑ 12 Volt Pump ❑ Peristaltic Pump ❑ Dedicated Pump ❑ Teflon Bailer ❑ Polyethylene Bailer COMMENTS: FIELD VEHICLE ACCESSIBLE ❑ YES ❑ NO Associated midday /end -of -day pH check within ±0.1 std unts? ❑ YES ❑ No If NO, pH data reported on this sheet should be considered as flagged accordingly ' SynTerra is not NC- certified for these parameters. Data collected for information purposes only WELL TAG PROTECTIVE CASING LOCK CAP CONCRETE PAD ] GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONI WATER LEVEL FLOW RATE TEMPERATURE CONDUCTANCE DO pH ORP' TURBIDITY' TIME (FT) (mL /min) (° Celsius) (µS /cm) (mg/U (su) (mv) (NTU) NOTES W z W J W J vVi vVi vVi � � W W p O g U V a a a w z Z > £ E o E E E 8 = CONSTITUENTS SAMPLED COMMENTS: FIELD VEHICLE ACCESSIBLE ❑ YES ❑ NO Associated midday /end -of -day pH check within ±0.1 std unts? ❑ YES ❑ No If NO, pH data reported on this sheet should be considered as flagged accordingly ' SynTerra is not NC- certified for these parameters. Data collected for information purposes only WELL TAG PROTECTIVE CASING LOCK CAP CONCRETE PAD ] GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONI NUMBER OF CONTAINERS PRESERVATION W z W J W J vVi vVi vVi � � W W p O g U V a a a w z Z > £ E o E E E 8 = CONSTITUENTS SAMPLED $ ^�' _ m _ Z o COMMENTS: FIELD VEHICLE ACCESSIBLE ❑ YES ❑ NO Associated midday /end -of -day pH check within ±0.1 std unts? ❑ YES ❑ No If NO, pH data reported on this sheet should be considered as flagged accordingly ' SynTerra is not NC- certified for these parameters. Data collected for information purposes only WELL TAG PROTECTIVE CASING LOCK CAP CONCRETE PAD ] GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONE ❑ GOOD ❑ BAD ❑ NONI ABOVEGROUND WELL PROTECTOR (L INCH X L INCH X 5 FOOT STEEL CASING WITH HINGED LOCKABLE LID) 2' -6" TO 3'-0" (NOMINAL.) STICK -UP NEAT CEMENT OR NEAT CEMENT BENTONITE MIX FROM BENTONITE SEAL TO GROUND SURFACE -C::::, WELL SCREEN (0 -010" MANUFACTURED SLOTS, TYPICAL) WELL PACKING (TYP. #1 OR #2 SAND) MALE PVC PLUG DRILL i" DIAMETER VENT HOLE BELOW PLUG 2' DIA. PVC WELL CASING i- GROUND SURFACE CONCRETE PAD MIN. 2 FT X 2 FT SQUARE BORING (8" NOMINAL DIAMETER) - - - - -- BENTONITE SEAL 2' -0" (MINIMUM) 2' -0" (MINIMUM) SCREEN LENGTH VARIES (5' TO 15' TYP.) G_L' OF WELL SAND ical Well Construction Details (no scale) INFORMATION PROVIDED BY DUKE ENERGY CAROLINAS, LLC FIGURE 3 GENERALIZED WELL SCHEMATIC 148 RIVER STREET. SUITE 220 GREENVILLE. SOUTH CAROLINA 29601 PHONE (864) 421 -9999 it? http Uwww. synte mworp. com H Frank Date 8/212014 synTerra PR PROJECT MINA GER. Kathy Nebb FIGURE 3 GENERALIZED WELL SCHEMATIC TABLE Q z z J Z 0 j m U J W x W U F 3a�0 J J Z Z 7oMCt N U U_ O C z X <�n�0 Q Q J 3 m J m x W U FFamz N K O W a 0 a z o > O U a m J (7 N W a c w ? W Y r Q 3 u o - � a � a m v � c > O � 0 o U v i 2 D d a m da 3 = Cc °c r o o cN oa 03 `3 0 O G E T� dd q �3 d C y aC 0o c .v c — t O yr jy u° a .tea, o D c a ad � o r dTE a z _° v ° � Z nD O rc i"ti ° °o E m a N m o`a sq - ° -EN w AEA ME 1; ; 1 q °v ed y v 3 cv Jpiy NONN C 2 y N u C O g 3 O g D u 3 D d d O d T t L 2 3� � v o D D v i n 0 0 — m a o 0 0 = 0 0 a 3 3 E E E = v ; E E $ °c °c °c c° t c° c° a n o 0 0 ° U i2 E n c° c° d z n O v v a ° °a va ; ; ; c 'c c c c c E v o c d C q q E E E E E E a E v E c o a u '^ " u y o ?+ s m a o o c o °c c .. c o o o c o 0 r c° Ti c m n O O O O O c O o c C o = = 3: v C 2 = 2 r ►W1 IL « d « d « d d d C o a 'E a d d a O O n d d 0 0 o 3 o E D = o D E o = v ° a - D S E a v 3 3 3 3 3 c c c ° i i c > d °c c d v- o a 0 a 0 d 0 d o d o a o c a w a ° o 0 o d d L O d N c c° .. v v v O > > d N ° d d D D O d a d a n o t o s r t; a$ o 2 o L'i 4 _ _ N d 2a _ _ O O V ° d d d d d d a o a V O d d d V V y d yoy C O d U Y O 0 0 3 3 3 3 3 3 3 m o A 3 3 3 0 o o 3 o 3 o 0 P X Q M M Q v 0 c p o > i a Q M > p x u m m O �'� V z V ? N N 0 Oa a a goo u = v ? u Z > > v Z v v v v 3 IT 3 > 3 U U U U U = _ ? ? _ _ 03 °m z z z z z = ZN x a z z z z 8 8 8 £ 8 y z z z ? ? z z z z z G O O N N 0 0 0 0 0 zi > G G Z N = N G G G G G O 0 O O m O m 'n = O O O O 0 O 0 0 o O v o P f E E F f O O N rPi rPi m 0 0 0 I N N o 0 o a 6 ry 0 N 0 N o P n M n Y n I ? n Y n Y n ^ a a ^ 0 0 Q N N N N M IA N N N N N N N N N N N N N N N N N N N n n N N ry H u u u U U u u u u u u U u u U U U u u u a Q a t z z z z z z z z z z z z z z z z > > z z z z > > > C o 0 0 0 0 0 0 0 0 0 0 W r o 0 0 0 o 0 O 0 O 0 O 0 o0 00 0 0 0 0 v v ° m u°i o m M P o N n O n P P P n P m N N J O O O O O O O p 0 N N N N N W O O O O O O 0 O O O O O O O O O M O N N O N O O N O N N N N N N t O O o O 0 O 0 O 0 O 0 O 0 00 00 O 0 O 0 O 0 O 0 O 0 3� P m •.• o e in M ry .. .. N M � n P w � ^ u� c M � N ,., 0 O 0 D O 0 O O o a a O cl y n s a O a O a u o - � a � a m v � c > O � 0 o U v i 2 D d a m da 3 = Cc °c r o o cN oa 03 `3 0 O G E T� dd q �3 d C y aC 0o c .v c — t O yr jy u° a .tea, o D c a ad � o r dTE a z _° v ° � Z nD O rc i"ti ° °o E m a N m o`a sq - ° -EN w AEA ME 1; ; 1 q °v ed y v 3 cv Jpiy NONN C 2 y N u C O g 3 O g D u 3 D d d O d T t L 2 3� � APPENDIX A EDR REPORT Duke Energy - Mayo 10600 Boston Rd. Roxboro, NC 27574 Inquiry Number: 3887559.1s March 21, 2014 6 Armstrong Road, 4th Floor Shelton, CT 06484 (rEDR'5 E nvironmental Data ReSollr -eS Inc Toll Free 800.352.0050 www.edrnet.com FORM- NULL -CCA TABLE OF CONTENTS SECTION PAGE GEOCHECK ADDENDUM Physical Setting Source Addendum____________ ____________________________ A -1 Physical Setting Source Summary ___________ _______________________________ A -2 Physical Setting Source Map__________________ ___________ A -7 Physical Setting Source Map Findings --------- ______________________________ A -8 Physical Setting Source Records Searched ____ _______________________________ A -17 Thank you for your business. Please contact EDR at 1- 800 - 352 -0050 with any questions or comments. Disclaimer - Copyright and Trademark Notice This Report contains certain information obtained from a variety of public and other sources reasonably availablege to Eppnvironmental Data other sources cNO WARRANTY EXPRESSED OR IMPLIED, IS MADE WHATSOEVER IN CONNECTION WITH STHISuREPORToEN IIRONMENTALexist from DATA RESOURCES, INC. SPECIFICALLY DISCLAIMS THE MAKING OF ANY SUCH WARRANTIES, INCLUDING WITHOUT LIMITATION, MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR PURPOSE. ALL RISK IS ASSUMED BY THE USER. IN NO EVENT SHALL ENVIRONMENTAL DATA RESOURCES, INC. BE LIABLE TO ANYONE, WHETHER ARISING OUT OF ERRORS OR OMISSIONS, NEGLIGENCE, ACCIDENT OR ANY OTHER CAUSE, FOR ANY LOSS OF DAMAGE, INCLUDING, WITHOUT LIMITATION, SPECIAL, INCIDENTAL, CONSEQUENTIAL, OR EXEMPLARY DAMAGES. ANY LIABILITY ON THE PART OF ENVIRONMENTAL DATA RESOURCES, INC. IS STRICTLY LIMITED TO A REFUND OF THE AMOUNT PAID FOR THIS REPORT. Purchaser accepts this Report "AS IS ". Any analyses, estimates, ratings, environmental risk levels or risk codes provided in this Report are provided for illustrative purposes only, and are not intended to provide, nor should they be interpreted as providing any facts regarding, or prediction or forecast of, any environmental risk for any property. Only a Phase I Environmental Site Assessment performed by an environmental professional can provide information regarding the environmental risk for any property Additionally, the information provided in this Report is not to be construed as legal advice. Copyright 2014 by Environmental Data Resources, Inc. All rights reserved. Reproduction in any media or format, in whole or in part, of any report or map of Environmental Data Resources. Inc. or its affiliates, is prohibited without prior written permission EDR and its logos (including Sanborn and Sanborn Map) are trademarks of Environmental Data Resources. Inc. or its affiliates. All other trademarks used herein are the property of their respective owners. TC3887559.1 s Page 1 GEOCHECFC" - PHYSICAL SETTING SOURCE REPORT TARGET PROPERTY ADDRESS DUKE ENERGY - MAYO 10600 BOSTON RD. ROXBORO, NC 27574 TARGET PROPERTY COORDINATES Latitude (North): 36.5353 - 36° 32'7-08" Longitude (West): 78.8957 - 78' 53'44.52" Universal Tranverse Mercator: Zone 17 UTM X (Meters): 688382.6 UTM Y (Meters): 4045181.8 Elevation: 478 ft. above sea level USGS TOPOGRAPHIC MAP Target Property Map: 36078 -E8 CLUSTER SPRINGS, VA NC Most Recent Revision: 1987 EDR's GeoCheck Physical Setting Source Addendum is provided to assist the environmental professional in forming an opinion about the impact of potential contaminant migration. Assessment of the impact of contaminant migration generally has two principal investigative components: 1. Groundwater flow direction, and 2. Groundwater flow velocity. Groundwater flow direction may be impacted by surface topography, hydrology, hydrogeology, characteristics of the soil, and nearby wells. Groundwater flow velocity is generally impacted by the nature of the geologic strata. TC3887559.1 s Page 1 GEOCHECK' - PHYSICAL SETTING SOURCE SUMMARY GROUNDWATER FLOW DIRECTION INFORMATION Groundwater flow direction for a particular site is best determined by a qualified environmental professional using site - specific well data. If such data is not reasonably ascertainable, it may be necessary to rely on other sources of information, such as surface topographic information, hydrologic information, hydrogeologic data collected on nearby properties, and regional groundwater Flow information (from deep aquifers). TOPOGRAPHIC INFORMATION Surface topography may be indicative of the direction of surficial groundwater flow. This information can be used to assist the environmental professional in forming an opinion about the impact of nearby contaminated properties or, should contamination exist on the target property, what downgradient sites might be impacted. TARGET PROPERTY TOPOGRAPHY General Topographic Gradient: General SE SURROUNDING TOPOGRAPHY: ELEVATION PROFILES r C o N Uj North TP 2 DJ A 00 m m W � N South West I East TP 0 1/2 1 Miles Target Property Elevation: 478 ft. Source: Topography has been determined from the USGS 7.5' Digital Elevation Model and should be evaluated on a relative (not an absolute) basis. Relative elevation information between sites of close proximity should be field verified. TC3887559.1s Page 2 GEOCHECK" - PHYSICAL SETTING SOURCE SUMMARY HYDROLOGIC INFORMATION Surface water can act as a hydrologic barrier to groundwater flow. Such hydrologic information can be used to assist the environmental professional in forming an opinion about the impact of nearby contaminated properties or, should contamination exist on the target property, what downgradient sites might be impacted. Refer to the Physical Setting Source Map following this summary for hydrologic information (major waterways and bodies of water). FEMA FLOOD ZONE FEMA Flood Target Property County Electronic Data PERSON, NC YES - refer to the Overview Map and Detail Map Flood Plain Panel at Target Property: 37145C - FEMA DFIRM Flood data Additional Panels in search area: 51083C FEMA DFIRM Flood data NATIONAL WETLAND INVENTORY NWI Quad at Target Property CLUSTER SPRINGS HYDROGEOLOGIC INFORMATION NWI Electronic Data Coverage YES - refer to the Overview Map and Detail Map Hydrogeologic information obtained by installation of wells on a specific site can often be an indicator of groundwater flow direction in the immediate area. Such hydrogeologic information can be used to assist the environmental professional in forming an opinion about the impact of nearby contaminated properties or, should contamination exist on the target property, what downgradient sites might be impacted. AQUIFLOW Search Radius: 1.000 Mile. EDR has developed the AQUIFLOW Information System to provide data on the general direction of groundwater flow at specific points. EDR has reviewed reports submitted by environmental professionals to regulatory authorities at select sites and has extracted the date of the report, groundwater flow direction as determined hydrogeologically, and the depth to water table. LOCATION GENERAL DIRECTION MAP ID FROM TP GROUNDWATER FLOW Not Reported TC3887559 1s Page 3 ' GEOCHECW - PHYSICAL SETTING SOURCE SUMMARY ' GROUNDWATER FLOW VELOCITY INFORMATION Groundwater flow velocity information for a particular site is best determined by a qualified environmental professional using site specific geologic and soil strata data. If such data are not reasonably ascertainable, it may be necessary to rely on other sources of information, including geologic age identification, rock stratigraphic unit and soil characteristics data collected on nearby properties and regional soil information. In general, contaminant plumes move more quickly through sandy - gravelly types of soils than silty- clayey types of soils. ' GEOLOGIC INFORMATION IN GENERAL AREA OF TARGET PROPERTY Geologic information can be used by the environmental professional in forming an opinion about the relative speed at which contaminant migration may be occurring. ' ROCK STRATIGRAPHIC UNIT GEOLOGIC AGE IDENTIFICATION Era: Paleozoic Category: Volcanic Rocks System: Cambrian Series: Cambrian volcanic rocks Code: Cv (decoded above as Era. System 8 Series) Geologic Age and Rock Stratigraphic Unit Source: P.G. Schruben, R.E. Arndt and W.J. Bawiec, Geology ' of the Conterminous U.S- at 1:2,500,000 Scale - a digital representation of the 1974 P.B. King and H.M. Beikman Map, USGS Digital Data Series DDS - 11 (1994). DOMINANT SOIL COMPOSITION IN GENERAL AREA OF TARGET PROPERTY ' The U.S. Department of Agriculture's (USDA) Soil Conservation Service (SCS) leads the National Cooperative Soil Survey (NCSS) and is responsible for collecting, storing, maintaining and distributing soil survey information for privately owned lands in the United States. A soil map in a soil survey is a representation of soil patterns in a landscape. Soil maps for STATSGO are compiled by generalizing more detailed (SSURGO) soil survey maps. ' The following information is based on Soil Conservation Service STATSGO data. Soil Component Name: IREDELL Soil Surface Texture: loam Hydrologic Group: Class CID - Drained /undrained hydrology class of soils that can be drained and classified. ' Soil Drainage Class: Not reported Hydric Status: Soil does not meet the requirements for a hydric soil. ' Corrosion Potential - Uncoated Steel: HIGH Depth to Bedrock Min: > 60 inches ' Depth to Bedrock Max: > 60 inches TC3887559.1 s Page 4 GEOCHECK" - PHYSICAL SETTING SOURCE SUMMARY Soil Layer Information Boundary Classification Layer Upper Lower Soil Texture Class AASHTO Group Unified Soil Permeability Soil Reaction Rate (in/hr) (pH) 1 0 inches 7 inches loam Silt -Clay FINE - GRAINED Max: 2.00 Max: 7.30 Materials (more SOILS, Silts and Min: 0.60 Min: 5.10 than 35 pct. Clays (liquid passing No. limit less than 200). Silty 50 %), silt. Soils. 2 7 inches 24 inches clay Silt -Clay FINE- GRAINED Max: 0 20 Max: 7.30 Materials (more SOILS, Silts and Min: 0.06 Min: 5.60 than 35 pct. Clays (liquid passing No. limit 50% or 200), Clayey more), Fat Clay. Soils. 3 24 inches 27 inches loam Silt -Clay FINE - GRAINED Max: 0.20 Max: 7.80 Materials (more SOILS, Silts and Min: 0.06 Min: 6.10 than 35 pct. Clays (liquid passing No. limit less than 200), Clayey 50 %). Lean Clay Soils. 4 27 inches 62 inches variable Not reported Not reported Max: 0.00 Max: 0.00 Min: 0.00 1 Min: 0.00 OTHER SOIL TYPES IN AREA Based on Soil Conservation Service STATSGO data, the following additional subordinant soil types may appear within the general area of target property. Soil Surface Textures: fine sandy loam silt loam channery - silt loam Surficial Soil Types: fine sandy loam silt loam channery - silt loam Shallow Soil Types: clay loam sandy clay sandy loam silt loam sandy clay loam very channery - silt loam Deeper Soil Types: sandy loam unweathered bedrock TC3887559.1s Page 5 GEOCHECW - PHYSICAL SETTING SOURCE SUMMARY LOCAL ! REGIONAL WATER AGENCY RECORDS EDR Local /Regional Water Agency records provide water well information to assist the environmental professional in assessing sources that may impact ground water flow direction, and in forming an opinion about the impact of contaminant migration on nearby drinking water wells. WELL SEARCH DISTANCE INFORMATION DATABASE SEARCH DISTANCE (miles) Federal USGS 1.000 Federal FRDS PWS 1.000 State Database 1.000 FEDERAL USGS WELL INFORMATION LOCATION MAP ID WELL ID FROM TP 1 USGS40000897734 1/4 - 112 Mile NW FEDERAL FRDS PUBLIC WATER SUPPLY SYSTEM INFORMATION LOCATION MAP ID WELL ID FROM TP 2 NCO273427 112 - 1 Mile ESE Note: PWS System location is not always the same as well location. STATE DATABASE WELL INFORMATION LOCATION MAP ID WELL ID FROM TP No Wells Found OTHER STATE DATABASE INFORMATION NORTH CAROLINA WILDLIFE RESOURCES COMMISSION GAME LANDS DATABASE Site Name NC30000006 NC30000008 N C30000009 NC30000013 TC3887559.1s Page 6 PHYSICAL SETTING SOURCE MAP - 3887559.1s Al County Boundary Major Roads Contour Lines A" Power transmission lines OEarthquake epicenter. Richter 5 or greater ® Water Wells © Public Water Supply Wells 0 Cluster of Multiple Icons a w !9 vV Groundwater Flow Direction Wildlife Areas G I Indeterminate Groundwater Flow at Location ED Natural Areas Cv Groundwater Flow Varies at Location Rare & Endangered Species 100 -year flood zone 500 -year flood zone ■ National Wetland Inventory SITE NAME: Duke Energy - Mayo CLIENT: SynTerra ADDRESS: 10600 Boston Rd. CONTACT: Richard Jacobs Roxboro NC 27574 INQUIRY #: 3887559.18 LAT /LONG: 36.5353/78.8957 DATE: March 21, 2014 11:15 am Copyright 7 2014 EDR, Inc. 'c 2010 Tole Atlas Pal. 972009. GEOCHECK x - PHYSICAL SETTING SOURCE MAP FINDINGS ITC3887559.1 s Page 8 Map ID ' Direction Distance Elevation Database EDR ID Number 'Higher NW FED USGS USGS40000897734 114 - 112 Mile Org.ldentifier: USGS -NC Formal name: USGS North Carolina Water Science Center ' Monloc Identifier: USGS- 363220078540501 Monloc name: PS -004 Monloc type. Well Monloc desc: Not Reported Huc code: Not Reported Drainagearea value: Not Reported Drainagearea Units: Not Reported Contrib drainagearea: Not Reported Contrib drainagearea units: Not Reported Latitude: 36.5390292 Longitude: - 78.9011203 Sourcemap scale: Not Reported Horiz Acc measure: 1 Horiz Acc measure units: seconds Horiz Collection method: Interpolated from map Horiz coord refsys: NAD83 Vert measure val. Not Reported Vert measure units: Not Reported Vertacc measure val: Not Reported Vert accmeasure units: Not Reported Vertcollection method: Not Reported Vert coord refsys: Not Reported Countrycode: US Aquifername: Piedmont and Blue Ridge crystalline -rock aquifers Formation type: Felsic Gneiss Aquifer type. Not Reported Construction date: Not Reported Welldepth: 87 Welldepth units: ft Wellholedepth: Not Reported Wellholedepth units: Not Reported ' Ground -water levels, Number of Measurements: 0 2 ' ESE FRDS PWS NCO273427 112 - 1 Mile Lower Pwsid NCO273427 Epa region: 04 ' State: NC County: Person Pws name: CP &L -MAYO ELEC GEN PLANT Population Served: 70 Pwssvcconn: 6 PWS Source: Surface water Pws type: NTNCWS Status: Active Owner type Private Facility id: 50740 Facility name: DISTRIBUTION SYSTEM ' Facility type: Distribution_system_zone Treatment process: sedimentation Treatment objective: disinfection by- products control Contact name: BEASLEY, ROBERT E Original name: BEASLEY, ROBERT E Contact phone: 336 - 599 -0218 Contact address 1: 10660 BOSTON ROAD Contact address2: Not Reported Contact city: ROXBORO Contact zip: 27573 ITC3887559.1 s Page 8 GEOCHECK' - PHYSICAL SETTING SOURCE MAP FINDINGS Facility id: 39229 Facility name: MAYO LAKE Facility type Intake Treatment process Treatment objective: disinfection by- products control Facility id. 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_zone Treatment process: Treatment objective: disinfection by- products control Facility id: 5655 Facility name: TREATMENT—PLT—MAYO STEAM PLT Facility type: Treatment_plant Treatment process: Treatment objective: disinfection by- products control Facility id: 1184 Facility name: STORAGE—GROUND-1 Facility type: Storage Treatment process: Treatment objective: disinfection by- products control Facility id: 3150 Facility name: STORAGE—HYDRO-1 Facility type: Storage Treatment process. Treatment objective: disinfection by- products control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process: Treatment objective: disinfection by- products control Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_zone Treatment process: Treatment objective: disinfection by- products control Facility id: 5655 Facility name: TREATMENT—PLT—MAYO STEAM PLT Facility type: Treatment _plant Treatment process: Treatment objective: disinfection by- products control Facility id: 1184 Facility name STORAGE_GROUND_1 Facility type: Storage Treatment process: Treatment objective: disinfection by- products control Facility id: 3150 Facility name: STORAGE—HYDRO-1 Facility type: Storage Treatment process: Treatment objective: disinfection by- products control Facility id 39229 Facility name: MAYO LAKE Facility type Intake Treatment process: Treatment objective: disinfection by- products control activated carbon, granular activated carbon, granular activated carbon, granular coagulation coagulation coagulation coagulation coagulation filtration, pressure sand filtration, pressure sand filtration, pressure sand TC38875591s Page 9 TC3887559.1s Page 10 GEOCHECK9- PHYSICAL SETTING SOURCE MAP FINDINGS Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_zone Treatment process: filtration, pressure sand Treatment objective: disinfection by- products control Facility id 5655 Facility name: TREATMENT—PLT—MAYO STEAM PLT Facility type: Treatment plant Treatment process filtration, pressure sand Treatment objective: disinfection by- products control Facility id: 1184 Facility name: STORAGE—GROUND-1 Facility type: Storage Treatment process: sedimentation Treatment objective: disinfection by- products control Facility id: 3150 Facility name: STORAGE—HYDRO-1 Facility type: Storage Treatment process: sedimentation Treatment objective: disinfection by- products control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process sedimentation Treatment objective: disinfection by- products control Facility id: 5655 Facility name: TREATMENT—PLT—MAYO STEAM PLT Facility type: Treatment_ plant Treatment process: sedimentation Treatment objective: disinfection by- products control Facility id: 1184 Facility name: STORAGE—GROUND-1 Facility type: Storage Treatment process: ph adjustment, post Treatment objective: disinfection by- products control Facility id: 3150 Facility name: STORAGE—HYDRO-1 Facility type: Storage Treatment process: ph adjustment, post Treatment objective: disinfection by- products control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process: ph adjustment, post Treatment objective: disinfection by- products control Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_ zone Treatment process: ph adjustment, post Treatment objective: disinfection by- products control Facility id: 5655 Facility name: TREATMENT—PLT—MAYO STEAM PLT Facility type Treatment_plant Treatment process: ph adjustment, post Treatment objective: disinfection by- products control TC3887559.1s Page 10 GEOCHECK1- PHYSICAL SETTING SOURCE MAP FINDINGS Facility id: 1184 Facility name: STORAGE_GROUND_t Facility type: Storage Treatment process: Treatment objective disinfection by- products control Facility id 3150 Facility name: STORAGE—HYDRO-1 Facility type: Storage Treatment process: Treatment objective: disinfection by- products control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process: Treatment objective: disinfection by- products control Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_ zone Treatment process: Treatment objective: disinfection by- products control Facility id: 1184 Facility name: STORAGE—GROUND-1 Facility type: Storage Treatment process: Treatment objective: organics removal Facility id: 3150 Facility name: STORAGE_HYDRO_1 Facility type Storage Treatment process: Treatment objective: organics removal Facility id: 5655 Facility name: TREATMENT_PLT_MAYO STEAM PLT Facility type: Treatment plant Treatment process: Treatment objective: disinfection by- products control Facility id: 1184 Facility name: STORAGE—GROUND-1 Facility type: Storage Treatment process: Treatment objective: corrosion control Facility id: 3150 Facility name: STORAGE—HYDRO-1 Facility type: Storage Treatment process: Treatment objective corrosion control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process: Treatment objective: corrosion control Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_ zone Treatment process: Treatment objective: corrosion control ph adjustment. pre ph adjustment, pre ph adjustment, pre ph adjustment, pre flocculation flocculation ph adjustment, pre inhibitor, polyphosphate inhibitor, polyphosphate inhibitor, polyphosphate inhibitor. polyphosphate TC3887559 1s Page 11 GEOCHECK9- PHYSICAL SETTING SOURCE MAP FINDINGS Facility id: 5655 Facility name: TREATMENT-PLT-MAYO STEAM PLT Facility type: Treatment _plant Treatment process Treatment objective: corrosion control Facility id: 1184 Facility name: STORAGE_GROUND_1 Facility type: Storage Treatment process: Treatment objective: corrosion control Facility id: 3150 Facility name: STORAGE-HYDRO-1 Facility type: Storage Treatment process: Treatment objective: corrosion control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process Treatment objective: corrosion control Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_zone Treatment process: Treatment objective: corrosion control Facility id: 5655 Facility name: TREATMENT-PLT-MAYO STEAM PLT Facility type: Treatment_plant Treatment process: Treatment objective: corrosion control Facility id: 1184 Facility name: STORAGE-GROUND-1 Facility type: Storage Treatment process: Treatment objective: corrosion control Facility id: 3150 Facility name: STORAGE-HYDRO-1 Facility type: Storage Treatment process: Treatment objective: corrosion control Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process Treatment objective corrosion control Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_ zone Treatment process: Treatment objective corrosion control Facility id: 5655 Facility name: TREATMENT-PLT-MAYO STEAM PLT Facility type: Treatment _plant Treatment process: Treatment objective: corrosion control inhibitor, polyphosphate ph adjustment ph adjustment ph adjustment ph adjustment ph adjustment ph adjustment, post ph adjustment, post ph adjustment, post ph adjustment, post ph adjustment, post TC3887559 1s Page 12 GEOCHECK - PHYSICAL SETTING SOURCE MAP FINDINGS Facility id: 3150 Facility name: STORAGE_HYDRO_1 Facility type: Storage Treatment process: Treatment objective: manganese removal Facility id: 39229 Facility name: MAYO LAKE Facility type: Intake Treatment process: Treatment objective: manganese removal Facility id: 50740 Facility name: DISTRIBUTION SYSTEM Facility type: Distribution_system_ zone Treatment process: Treatment objective: manganese removal Facility id: 5655 Facility name: TREATMENT_PLT_MAYO STEAM PLT Facility type: Treatmentplant Treatment process: Treatment objective: manganese removal Facility id: 1184 Facility name: STORAGE—GROUND-1 Facility type: Storage Treatment process: Treatment objective: manganese removal PWS ID: NCO273427 Date Initiated: 8001 Date Deactivated: Not Reported PWS Name: MAYO STEAM PLANT ROXBORO, NC 27562 Addressee / Facility: System Owner /Responsible Party MARSHALL LUNDSFORD OR MANAGER RT 1 BOX 327 NEW HILL, NC 27562 Addressee / Facility: System Owner /Responsible Party CAROLINA POWER & LIGHT CO PO BOX 1551 RALEIGH, NC 27602 sedimentation sedimentation sedimentation sedimentation sludge treatment Facility Latitude: 3631 40 Facility Longitude: 078 52 50 Facility Latitude: 36 23 36 Facility Longitude: 078 58 59 City Served: ROXBORO Treatment Class: Treated Population: 00000067 PWS currently has or had major violation(s) or enforcement YES N150 WIN d Eel i"112,[Me : &L'ure k►F Violation ID: 9403206 Source ID Not Reported PWS Phone: Vic. beginning Date: 11/01/93 Vio. end Date: 11/30/93 Vio. Period: Num required Samples: Not Reported Number of Samples Taken: Not Reported Analysis Result: Not Reported Maximum Contaminant Level: Not Reported Analysis Method Not Reported Violation Type: Monitoring, Routine /Repeat (SWTR- Filter) Contaminant: Not Reported Vio. Awareness Date Not Reported Not Reported 001 Months TC3887559 1s Page 13 GEOCHECK8- PHYSICAL SETTING SOURCE MAP FINDINGS ENFORCEMENT INFORMATION System Name CP &L -MAYO ELEC GEN PLANT Violation Type: Monitoring, Routine Major (TCR) Contaminant: COLIFORM (TCR) Compliance Period: 1/1/2004 0:00:00 - 1/31/2004 0:00:00 Violation ID: 304 Enforcement Date: 3/10/2004 0:00:00 Enf. Action: State Formal NOV Issued System Name CP &L -MAYO ELEC GEN PLANT Violation Type: Monitoring, Routine Major (TCR) Contaminant: COLIFORM (TCR) Compliance Period: 1/1/2004 0:00:00 - 1/31/2004 0:00:00 Violation ID: 304 Enforcement Date: 3/10/2004 0:00:00 Enf. Action: State Public Notif Requested System Name: CP &L -MAYO ELEC GEN PLANT Violation Type. Monitoring, Routine Major (TCR) Contaminant: COLIFORM (TCR) Compliance Period: 1/1/2004 0:00:00 - 1/31/2004 0:00:00 Violation ID: 304 Enforcement Date: 3/16/2004 0:00:00 Enf. Action: State Compliance Achieved System Name: CP &L -MAYO ELEC GEN PLANT Violation Type. Monitoring, Routine Major (TCR) Contaminant: COLIFORM (TCR) Compliance Period 1/1/2004 0:00:00 - 1/31/2004 0:0000 Violation ID: 304 Enforcement Date: 3/10/2004 0:00:00 Enf. Action: State Formal NOV Issued System Name: CP &L -MAYO ELEC GEN PLANT Violation Type: Monitoring, Routine Major (TCR) Contaminant: COLIFORM (TCR) Compliance Period: 1/1/2004 0:00:00 - 1/31/2004 0:00:00 Violation ID: 304 Enforcement Date: 3/10/2004 0:00:00 Enf Action: State Public Notif Requested System Name CP &L -MAYO ELEC GEN PLANT Violation Type Monitoring, Routine Major (TCR) Contaminant: COLIFORM (TCR) Compliance Period: 1/1/2004 0:00:00 - 1/31/2004 0:00:00 Violation ID: 304 Enforcement Date: 3/16/2004 0:00:00 Enf. Action: State Compliance Achieved TC3887559.1 s Page 14 GEOCHECK ,V- PHYSICAL SETTING SOURCE MAP FINDINGS Map ID Direction Distance Databas . PnR ID N imb r Site Name: Owner: Site Type Status: Mayo Carolina Power & Light Game Land PRV Acres: County: NC—WILD 1242.84973144531 PERSON NC30000006 NC—WILD NC30000008 Site Name: Mayo Owner Carolina Power & Light Site Type: Game Land Acres: 4166.9736328125 Status: PRV County: PERSON NC—WILD NC30000009 Site Name: Mayo Owner: Carolina Power & Light Site Type: Safety Zone Acres: 1029.91821289063 Status: PRV County: PERSON NC—WILD NC30000013 Site Name: Mayo Owner: Carolina Power & Light Site Type: Game Land Acres: 29.5865421295166 Status: PRV County: PERSON TC3887559.1s Page 15 GEOCHECK - PHYSICAL SETTING SOURCE MAP FINDINGS RADON AREA RADON INFORMATION State Database: NC Radon Radon Test Results Num Results Avg pCi /L Min pCi /L Max pCi /L 2 0.95 0.8 1.1 Federal EPA Radon Zone for PERSON County: 3 Note: Zone 1 indoor average level > 4 pCi /L. Zone 2 indoor average level >= 2 pCi /L and <= 4 pCi /L. Zone 3 indoor average level < 2 pCi /L. Federal Area Radon Information for PERSON COUNTY, NC Number of sites tested: 1 Area Average Activity % <4 pCi /L Living Area - 1st Floor 1.200 pCi /L 100% Living Area - 2nd Floor Not Reported Not Reported Basement Not Reported Not Reported % 4 -20 pCi /L % >20 pCi /L 0% 0% Not Reported Not Reported Not Reported Not Reported TC3887559.1s Page 16 PHYSICAL SETTING SOURCE RECORDS SEARCHED TOPOGRAPHIC INFORMATION USGS 7.5' Digital Elevation Model (DEM) Source: United States Geologic Survey EDR acquired the USGS 7.5' Digital Elevation Model in 2002 and updated it in 2006. The 7.5 minute DEM corresponds to the USGS 1:24,000- and 1:25,000 -scale topographic quadrangle maps. The DEM provides elevation data with consistent elevation units and projection. HYDROLOGIC INFORMATION Flood Zone Data This data, available in select counties across the country, was obtained by EDR in 2003 & 2011 from the Federal Emergency Management Agency (FEMA). Data depicts 100 -year and 500 -year flood zones as defined by FEMA. NWI National Wetlands Inventory. This data. available in select counties across the country, was obtained by EDR in 2002, 2005 and 2010 from the U.S. Fish and Wildlife Service. State Wetlands Data Wetlands Inventory Source: Department of Environment & Natural Resources Telephone: 919- 733 -2090 HYDROGEOLOGIC INFORMATION AQUIFLOWR Information System Source: EDR proprietary database of groundwater flow information EDR has developed the AQUIFLOW Information System (AIS) to provide data on the general direction of groundwater flow at specific points. EDR has reviewed reports submitted to regulatory authorities at select sites and has extracted the date of the report, hydrogeologically determined groundwater flow direction and depth to water table information. GEOLOGIC INFORMATION Geologic Age and Rock Stratigraphic Unit Source: P.G. Schruben, R.E. Arndt and W.J. Bawiec. Geology of the Conterminous U.S. at 1:2,500,000 Scale - A digital representation of the 1974 P.B. King and H.M. Beikman Map. USGS Digital Data Series DDS - 11 (1994). STATSGO State Soil Geographic Database Source: Department of Agriculture, Natural Resources Conservation Services The U.S. Department of Agriculture's (USDA) Natural Resources Conservation Service (NRCS) leads the national Conservation Soil Survey (NCSS) and is responsible for collecting, storing. maintaining and distributing soil survey information for privately owned lands in the United States. A soil map in a soil survey is a representation of soil patterns in a landscape. Soil maps for STATSGO are compiled by generalizing more detailed ( SSURGO) soil survey maps SSURGO: Soil Survey Geographic Database Source: Department of Agriculture, Natural Resources Conservation Services (NRCS) Telephone: 800 - 672 -5559 SSURGO is the most detailed level of mapping done by the Natural Resources Conservation Services mapping scales generally range from 1:12,000 to 1:63,360. Field mapping methods using national standards are used to construct the soil maps in the Soil Survey Geographic ( SSURGO) database. SSURGO digitizing duplicates the original soil survey maps. This level of mapping is designed for use by landowners, townships and county natural resource planning and management. TC38875591s Page A -17 PHYSICAL SETTING SOURCE RECORDS SEARCHED ' LOCAL / REGIONAL WATER AGENCY RECORDS FEDERAL WATER WELLS PWS Public Water Systems Source: EPA/Office of Drinking Water Telephone: 202 - 564 -3750 Public Water System data from the Federal Reporting Data System A PWS is any water system which provides water to at least 25 people for at least 60 days annually PWSs provide water from wells. rivers and other sources. PWS ENF: Public Water Systems Violation and Enforcement Data Source: EPA/Office of Drinking Water ' Telephone: 202 - 564 -3750 Violation and Enforcement data for Public Water Systems from the Safe Drinking Water Information System (SDWIS) after August 1995. Prior to August 1995, the data came from the Federal Reporting Data System (FRDS). ' USGS Water Wells: USGS National Water Inventory System (NWIS) This database contains descriptive information on sites where the USGS collects or has collected data on surface water and /or groundwater. The groundwater data includes information on wells. springs, and other sources of groundwater. STATE RECORDS North Carolina Public Water Supply Wells Source: Department of Environmental Health ' Telephone: 919- 715 -3243 OTHER STATE DATABASE INFORMATION ' NC Natural Areas: Significant Natural Heritage Areas Source: Center for Geographic Information and Analysis Telephone: 919- 733 -2090 A polygon converage identifying sites (terrestrial or aquatic that have particular biodiversity significance. ' A site's significance may be due to the presenceof rare species, rare or hight quality natural communities, or other important ecological features. NC Game Lands: Wildlife Resources Commission Game Lands ' Source: Center for Geographic Information and Analysis Telephone: 919- 733 -2090 All publicly owned game lands managed by the North Carolina Wildlife Resources Commission and as listed in Hunting and Fishing Maps ' NC Natural Heritage Sites: Natural Heritage Element Occurrence Sites Source: Center for Geographic Information and Analysis Telephone: 919- 733 -2090 A point coverage identifying locations of rare and endangered species, occurrences of exemplary or unique natural ecosystems (terrestrial or aquatic), and special animal habitats (e g.. colonial waterbird nesting sites). RADON State Database: NC Radon Source: Department of Environment & Natural Resources Telephone: 919- 733 -4984 Radon Statistical and Non Statiscal Data Area Radon Information Source: USGS Telephone: 703 - 356 -4020 The National Radon Database has been developed by the U S Environmental Protection Agency (USEPA) and is a compilation of the EPA/State Residential Radon Survey and the National Residential Radon Survey The study covers the years 1986 - 1992. Where necessary data has been supplemented by information collected at private sources such as universities and research institutions TC3887559 1s Page A -18 PHYSICAL SETTING SOURCE RECORDS SEARCHED EPA Radon Zones Source: EPA Telephone: 703 - 356 -4020 Sections 307 & 309 of IRAA directed EPA to list and identify areas of U S with the potential for elevated indoor radon levels. OTHER Airport Landing Facilities: Private and public use landing facilities Source: Federal Aviation Administration, 800- 457 -6656 Epicenters: World earthquake epicenters, Richter 5 or greater Source: Department of Commerce, National Oceanic and Atmospheric Administration Earthquake Fault Lines: The fault lines displayed on EDR's Topographic map are digitized quaternary faultlines. prepared in 1975 by the United State Geological Survey STREET AND ADDRESS INFORMATION © 2010 Tele Atlas North America, Inc. All rights reserved. This material is proprietary and the subject of copyright protection and other intellectual property rights owned by or licensed to Tele Atlas North America, Inc. The use of this material is subject to the terms of a license agreement. You will be held liable for any unauthorized copying or disclosure of this material. TC3887559 1 s Page A -19 I m 1 VAk 4 41 1A . . . . . . . . . . . . . . . . 10, 4�1 61 A4 0800000890 YIIIF ISBN