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HomeMy WebLinkAboutWQ0035784_Monitoring - 10-2016_20170103SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: NEEMM t£fA:.9�atFitti3t:IfNBTriTr$eiTLiRPg[ JilS afJii�3CaS r a', i1t1St 1 ad t P 1Tv t14 , now COMPLIANCE REPORTFORM • • • wE f61T Af v _raTAR,tzA t a tso s rs? ,art ie t taf7 s :,: FACILITY INFORMATION Please-RrintcrearryorType PERMIT Number: Expiration Date: 4/30/17 Facility Name: Cottages of Boone Non -Discharge WQ0035784 {SIC Permit Name (if different): Capstone Collegiate'Communities, LLC NPDES Other Facility Address: 615 FaIIview'Lane TYPE OF PERMITTED OPERATION BEING MONITORED Boone NC 286107 County Watauga g El Lagoon ❑ Remediation, -'Infiltration Gallery ®Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#:' 628-251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: MW -1p No. of wells to be sampled: 3 Water Source Heat Pum p El Other: - (from PerrniY _ - - - -- SAMPLING INFORMATION if WELL WELL ID NUMBER (from Permit): MW -1 Date sample collected: 10-12-16 FIELD ANALYSES: WAS Well Depth: 20 ft. Well Diameter: 2 in. pH 00400: units Temp, 0oo10: _ °C DRY at Depth to Water Level 82546: ft. below measuring point Screened Interval 10 ft. to 20 ft: Spee. Cond. 00o9a: IzMhos ft time of Measuring Point is 3 ft. above land surface Relative M.P. Elevation: 3438 f{. Odor 000m check Volume of water pumped/bailed before sampling: gallons Appearance _ here: Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 8115113 - 8/20113 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD' 00335 mg/L Nitrite (NO2) as N 00615' mg/L Pb - Lead 01051g $t /L WG Coliform: MF Fecal' 91313 /100rnL Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L � /^ 9 Coliform: MF Total 31504 /100mL Phosphorus: Total as P o0665 a' mg/L „� !t A 06 �► 6 (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 V Y $.ii � mg/L Other (Specify Compou t'I (ts): issolved Solids:Total 70300 mg/L AI -Aluminum 01105 mg/L -tl n 1)n,-, pH (Lab) 00403 units Be - Barium 01007 ug/L TOC o068o mglL Ca - Calcium 00916 mg/L _DV�R fi Cr�If Chloride 00940 mg/L Cd - Cadmium 01027 ug/L INFORMATION PROCESSINGI Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 _ mg/L ORGANICS: (by GC, GC/MIS, HPLC) Phenol 3273o ug/L Fe - iron 01045 ug/L (Specify test and method #. ATTACK LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lacs Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 pMhos K - Potassium 00937 mg/L VOC 78732: method # Total Ammonia ooslo mg/L Mg- Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH,,as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 uglL method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # r Only -VOCs: 1 certify that, to the best of my knowledge and belief; the information submitted in this report is true;, acc DWQ-certified laboratory. I am aware that there are s gnificant,penaliies for submitting false informiatioi mg/L Effluent Total VOCs: Permittee (or Authorized Agent) Name and Title - Please printf or type Signature of Permittee (or Authorized Agent) GW -59 Rev. 212010 mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM C9Cn ITV idicr1G1ipwrirw Please Facility Name: Cottages of Boone Permit Name (if different): Capstone Collegiate Communities, LLC Facility Address 615 Fallview Lane Boone (Street" NC 28607 County Watauga act Person: Bob Barr Telephone#: 828-251-1900 Location/Site Name: MW -2 No. of wells to be sampled: 3 ID NUMBER (from Permit): MW -2 Depth: 19, ft. i to Water Level 82546:14.6 ft. below measuring point luring Point is 3 ft. above land surface Date sample collected: 10-12-16 Well Diameter: 2 in. Screened Interval: 5ft. to 19 ft. Relative M.P. Elevation: 3380 ft. of water pumped/bailed before sampling: gallons s for metals were collected unfiltered: ❑ YES ❑ NO 'YES tte sample analyzed: lo -l2 -1a-10-19-16 Laboratory Name: Pace Analytical tRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00336 mg/L Nitrite (NO2) as N oom5 mg/L Coliform: MF Fecal 31616 <4 1100mL Nitrate (NO3) as N 00620 0.42 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00565 3.6 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L solved Solids:Total 7o3oo 62.0 mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC omiao 4.4 mg/L Ca - Calcium oo9is mg/L Chloride oo940 7.3 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe = Iron 01045 ug/L Sulfate oo945 mg/L Hg - Mercury 71900 _ ug/L ecific Conductance 00095 µMhos K = Potassium 00937 mg/L Total Ammonia omio <0.10 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; N%as N: Ammonia Nitrogen,Total) Mn Manganese 01055 Ug/L TKN as N 00625 mg/L Ni -Nickel 01067 ug/L Number: Expiration Date: harae W00035784 UIC 'DES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ® Remediation _ ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other.- FIELD ther: FIELD ANALYSES: WAS pH 00400: 61 units Temp. 00010: 11.9 °C DRY at Spec. Cond. 00094: µMhos time of sampling, Odor 00085: None check Appearance Muddy to Cloudy here: Pb - Lead olos1 Certification No. 40 ug/L Zn— Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GCIMS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ® Yes (1) ,❑ No (0) VQC 75732: , method # method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Robert Barr/Authorized Agent Permittee (or Authorized -Agent) Name and Title - Please print or type GW -59 Rev. 2/2010 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Pnnt Clearly or Type Facility Name: Cottages of Boone Permit Name (if different): Capstone Collegiate Communities, LLC Facility Address: 615 Fallview Lane Boone ` r `" NC 28607 County Watauga act Person: Bob Barr Telephone#: 828-251-1900 Location/Site Name: MW -3 No. of wells to be sampled: 3 L ID NUMBER (from Permit): MW -3 Date sample collected: 10-12-16 Depth: 26 ft. Well Diameter: 2 in. i to Water Level 82546: N/A ft. below measuring point Screened Interval: 16 ft. to 26 fL luring Point is 3 ft. above land surface Relative M.P. Elevation: 3520 ft. ne of water pumped/bailed before. sampling: gallons )les for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO !lSION OF INATER t; UALITif-INFORMATION PROCESSING UNIT 17 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phdlte: (919) 733322' ;RMIT Number: Expiration Date: 4/30/17 in -Discharge WQ0035784 UIC 'DES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery © Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: FIELD ANALYSES: pH 0o4o0: units Spec. Cond. 00094: Odor 0008s: Aooearance If WELL Temp. 000lo: °C DRY at µMhos time of ate sample analyzed: Laboratory Name: Watertech Labs Certification No. 50 \RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 . /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate. 70507 mg/L Other (Specify Compounds and Concentration Units): solved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/l­ Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method A ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) ecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 78732: method # Total Ammonia o0610 mg/l­ Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports) Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Z GW -59 Rev. 2/2010 GLV-i9A. COMPLIANCE REPORT .RT FORM Permit #WQW-39-�L0 4 (Submit one each monitoring period with GW --59 forms.) 101. 1 Enter date monitoring results were due. ( 1111 Will this monitoring report (GW -59 and GW -59A) YES O be submitted after the established due date? 2 Was any required information missing on the GW -59 report forms? YES N IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YE O identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentrations) reported, and sample collection date for each occurrence (for the last two years). 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? if the answer to question 7 is "YES" describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. g The person completing this portion (GIN -59A) of the monitoring report should sign below and submit this form with GW -59 forms for required wells to the address provided at the top of the current GW -59 form. ereby acknowledge chat the above information vias evaluated anti the inartnat%n su�6rtt" its In this „and cnmplwee toe fest of tm .Yk'�p'_ ` :_ . report"�Cornpliance Rprart Gift -9A) rs"true-AIUQ-� Signature of Permittee (or Authorized Agent) Date GW -59A 12/8/2003 aceAnalytical rt www.pacelabs.com 1 . October 20, 2016 Mr. Robert Barr RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Boone Cottages 10/12 Pace Project No.: 92315715 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Dear Mr. Barr: Enclosed are the analytical results for sample(s) received by the laboratory on October 12, 2016. The results relate only to the samples included in this report. Results reported her conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Denise Trantham denise.trantham @ pacelabs.com Project Manager Enclosures cc: Rick Swilling, RPB Systems Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalXical www.pacelabs.com i Project: Boone Cottages 10/12 Pace Project No.: 92315715 Pace Analytical ServlceS, LLU 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalj cal l wwwpacelebs.cam SAMPLE ANALYTE COUNT Project: Boone Cottages 10/12 Pace Project No.: 92315715 Mace Anaiyucai services, LLc 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92315715001 MW -2 EPA 8260 GAW 71 PASI-C SM 2540C MJS1 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 BRJ 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 SER 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 5310B AES2 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC 1!2cce Analytical l www.Pacelabs.com r I ANALYTICAL RESULTS Pace Analyucal serviceS, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Boone Cottages 10/12 Pace Project No.: 92315715 Sample: MW -2 Lab ID: 92315715001 Collected: 10/12/1610:30 Received: 10/12/1613:58 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 8260 MSV Analytical Method: EPA 8260 Acetone ND ug/L 25.0 1 10/19/1614:07 67-64-1 Benzene ND ug/L 5.0 1 10/19/1614:07 71-43-2 Bromobenzene ND ug/L 5.0 1 10/19/1614:07 108-86-1 Bromochloromethane ND ug/L 5.0 1 10/19/1614:07 74-97-5 Bromod ichloromethane ND ug/L 5.0 1 10/19/1614:07 75-27-4 Bromoform ND ug/L 5.0 1 10/19/1614:07 75-25-2 Bromomethane ND ug/L 10.0 1 10/19/1614:07 74-83-9 2-Butanone (MEI) ND ug/L 10.0 1 10/19/16 14:07 78-93-3 tert-Butyl Alcohol ND ug/L 100 1 10/19/16 14:07 75-65-0 n-Butylbenzene ND ug/L 5.0 1 10/19/1614:07 104-51-8 sec -Butyl benzene ND ug/L 5.0 1 10/19/1614:07 135-98-8 tert-Butylbenzene ND ug/L 5.0 1 10/19/1614:07 98-06-6 Carbon tetrachloride ND ug/L 5.0 1 10/19/16 14:07 56-23-5 Chlorobenzene ND ug/L 5.0 1 10/19/1614:07 108-90-7 Chloroethane ND ug/L 10.0 1 10/19/1614:07 75-00-3 Chloroform ND ug/L 5.0 1 10/19/1614:07 67-66-3 Chloromethane ND ug/L 5.0 1 10/19/1614:07 74-87-3 2-Chlorotoluene ND ug/L 5.0 1 10/19/1614:07 95-49-8 4-Chlorotoluene ND ug/L 5.0 1 10/19/1614:07 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 10/19/16 14:07 96-12-8 Dibromochloromethane ND ug/L 5.0 1 10/19/1614:07 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1 10/19/16 14:07 106-93-4 Dibromomethane ND ug/L 5.0 1 10/19/1614:07 74-95-3 1,2 -Dichlorobenzene ND ug/L 5.0 1 10/19/1614:07 95-50-1 1,3 -Dichlorobenzene ND ug/L 5.0 1 10/19/1614:07 541-73-1 1,4 -Dichlorobenzene ND ug/L 5.0 1 10/19/1614:07 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1 10/19/1614:07 75-71-8 1,1-Dichloroethane ND ug/L 5.0 1 10/19/1614:07 75-34-3 1,2-Dichloroethane ND ug/L 5.0 1 10/19/1614:07 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 1 10/19/16 14:07 540-59-0 1,1-Dichloroethene ND ug/L 5.0 1 10/19/1614:07 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 1 10/19/1614:07 156-59-2 trans- 1,2-Dichloroethene ND ug/L 5.0 1 10/19/1614:07 156-60-5 1,2-Dichloropropane ND ug/L 5.0 1 10/19/1614:07 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1 10/19/1614:07 142-28-9 2,2-Dichloropropane ND ug/L 5.0 1 10/19/1614:07 594-20-7 1,1-Dichloropropene ND ug/L 5.0 1 10/19/1614:07 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 1 10/19/1614:07 10061-01-5 trans-1,3-Dichloropropene ND ug/L 5.0 1 10/19/1614:07 10061-02-6 Diisopropyl ether ND ug/L 5.0 1 10/19/16 14:07 108-20-3 Ethylbenzene ND ug/L 5.0 1 10/19/1614:07 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 10/19/1614:07 87-68-3 2-Hexanone ND ug/L 10.0 1 10/19/1614:07 591-78-6 Isopropylbenzene (Cumene) ND ug/L 5.0 1 10/19/16 14:07 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1 10/19/1614:07 99-87-6 Methylene Chloride ND ug/L 5.0 1 10/19/16 14:07 75-09-2 4-Methyl-2-pentanone (MIBI) ND ug/L 10.0 1 10/19/1614:07 108-10-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalXical r wwwpacelebs,com If Project: Boone Cottages 10/12 Pace Project No.: 92315715 Sample: MW -2 Parameters 8260 MSV Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1 -Trichloroethane 1,1,2 -Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o -Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) - Toluene -d8 (S) - ' 2540C Total Dissolved Solids Total Dissolved Solids MB10 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 5310B TOC Total Organic Carbon Daie: 10/20/2016 12:57 PM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92315715001 Collected: 10/12/1610:30 Received: 10/12/1613:58 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Analytical Method: EPA 8260 62.0 mg/L 25.0 Analytical Method: SM 9222D ND ug/L 5.0 1 10/19/1614:07 1634-04-4 ND ug/L 5.0 1 10/19/1614:07 91-20-3 ND ug/L 5.0 1 10/19/1614:07 103-65-1 ND ug/L 5.0 1 10/19/1614:07 100-42-5 ND ug/L 5.0 1 10/19/1614:07 630-20-6 ND ug/L 5.0 1 10/19/1614:07 79-34-5 ND ug/L 5.0 1 10/19/1614:07 127-18-4 ND ug/L 5.0 1 10/19/1614:07 108-88-3 ND ug/L 5.0 1 10/19/1614:07 87-61-6 ND ug/L 5.0 1 10/19/1614:07 120-82-1 ND ug/L 5.0 1 10/19/1614:07 71-55-6 ND ug/L 5.0 1 10/19/1614:07 79-00-5 ND ug/L 5.0 1 10/19/1614:07 79-01-6 ND ug/L 10.0 1 10/19/1614:07 75-69-4 ND ug/L 5.0 1 10/19/1614:07 96-18-4 ND ug/L 5.0 1 10/19/1614:07 95-63-6 ND ug/L 5.0 1 10/19/1614:07 108-67-8 ND ug/L 10.0 1 10/19/1614:07 108-05-4 ND ug/L 5.0 1 10/19/1614:07 75-01-4 ND ug/L 10.0 1 10/19/1614:07 179601-23-1 ND ug/L 5.0 1 10/19/1614:07 95-47-6 96 % 70-130 100 % 70-130 110 % 70-130 Analytical Method: SM 2540C 62.0 mg/L 25.0 Analytical Method: SM 9222D ND CFU/100 mL 4.0 Analytical Method: EPA 350.1 1993 Rev 2.0 ND mg/L 0.10 Analytical Method: EPA 353.2 0.42 mg/L 0.020 Analytical Method: EPA 365.1 3.6 mg/L 0.050 Analytical Method: SM 4500 -CI -E 7.3 mg/L 1.0 Analytical Method: SM 5310B 4.4 mg/L 1.0 1 10/19/1614:07 460-00-4 1 10/19/16 14:07 17060-07-0 1 10/19/1614:07 2037-26-5 1 10/12/16 17:38 4 10/12/16 14:53 1 10/19/16 04:40 7664-41-7 1 10/13/16 22:35 1 10/19/16 04:15 7723-14-0 1 10/14/1623:00 16887-00-6 1 10/19/16 02:04 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Without the written consent of Pace Analytical Services, LLC. Qual _ aceAnalyficai'm www.pacelabs.com 1 QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333748 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 92315715001 METHOD BLANK: 1849587 Associated Lab Samples: 92315715001 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed 1,1,1,2 -Tetrachloroethane ug/L ND 5.0 10/19/1613:34 1,1,1 -Trichloroethane ug/L ND 5.0 10/19/1613:34 1,1,2,2 -Tetrachloroethane ug/L ND 5.0 10/19/1613:34 1,1,2 -Trichloroethane ug/L ND 5.0 10/19/1613:34 1,1-Dichloroethane ug/L ND 5.0 10/19/1613:34 1,1-Dichloroethene ug/L ND 5.0 10/19/1613:34 1,1-Dichloropropene ug/L ND 5.0 10/19/1613:34 1,2,3-Trichlorobenzene ug/L ND 5.0 10/19/1613:34 1,2,3-Trichloropropane ug/L ND 5.0 10/19/1613:34 1,2,4-Trichlorobenzene ug/L ND 5.0 10/19/1613:34 1,2,4-Trimethylbenzene ug/L ND 5.0 10/19/1613:34 1,2-Dibromo-3-chloropropane ug/L ND 2.0 10/19/1613:34 1,2-Dibromoethane (EDB) ug/L ND 5.0 10/19/16 13:34 1,2 -Dichlorobenzene ug/L ND 5.0 10/19/1613:34 1,2-Dichloroethane ug/L ND 5.0 10/19/1613:34 1,2-Dichloroethene (Total) ug/L ND 5.0 10/19/16 13:34 1,2-Dichloro propane ug/L ND 5.0 10/19/1613:34 1,3,5-Trimethylbenzene ug/L ND 5.0 10/19/1613:34 1,3 -Dichlorobenzene ug/L ND 5.0 10/19/1613:34 1,3-Dichloropropane ug/L ND 5.0 10/19/1613:34 1,4 -Dichlorobenzene ug/L ND 5.0 10/19/1613:34 2,2-Dichloropropane ug/L ND 5.0 10/19/1613:34 2-Butanone (MEK) ug/L ND 10.0 10/19/16 13:34 2-Chlorotoluene ug/L ND 5.0 10/19/1613:34 2-Hexanone ug/L ND 10.0 10/19/1613:34 4-Chlorotoluene ug/L ND 5.0 10/19/1613:34 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 10/19/16 13:34 Acetone ug/L ND 25.0 10/19/1613:34 Benzene ug/L ND 5.0 10/19/1613:34 Bromobenzene ug/L ND 5.0 10/19/1613:34 Bromochloromethane ug/L ND 5.0 10/19/1613:34 Bromodichloromethane ug/L ND 5.0 10/19/1613:34 Bromoform ug/L ND 5.0 10/19/1613:34 Bromomethane ug/L ND 10.0 10/19/1613:34 Carbon tetrachloride ug/L ND 5.0 10/19/16 13:34 Chlorobenzene ug/L ND 5.0 10/19/1613:34 Chloroethane ug/L ND 10.0 10/19/1613:34 Chloroform ug/L ND 5.0 10/19/1613:34 Chloromethane ug/L ND 5.0 10/19/1613:34 cis-1,2-Dichloroethene ug/L ND 5.0 10/19/1613:34 cis-1,3-Dichloropropene ug/L ND 5.0 10/19/1613:34 Qualifiers Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NG28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. acmnalytical www.pecalabs.com 1 - 1 QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 METHOD BLANK: 1849587 Associated Lab Samples: 92315715001 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed Dibromochloromethane ug/L ND 5.0 10/19/1613:34 Dibromomethane ug/L ND 5.0 10/19/1613:34 Dichlorodifluoromethane ug/L ND 5.0 10/19/1613:34 Diisopropyl ether ug/L ND 5.0 10/19/16 13:34 Ethylbenzene ug/L ND 5.0 10/19/1613:34 Hexachloro-1,3-butadiene ug/L ND 5.0 10/19/1613:34 Isopropylbenzene (Cumene) ug/L ND 5.0 10/19/16 13:34 m&p-Xylene ug/L ND 10.0 10/19/1613:34 Methyl-tert-butyl ether ug/L ND 5.0 10/19/16 13:34 Methylene Chloride ug/L ND 5.0 10/19/16 13:34 n-Butylbenzene ug/L ND 5.0 10/19/1613:34 n-Propylbenzene ug/L ND 5.0 10/19/1613:34 Naphthalene ug/L ND 5.0 10/19/1613:34 o -Xylene ug/L ND 5.0 10/19/1613:34 p-Isopropyltoluene ug/L ND 5.0 10/19/1613:34 sec-Butylbenzene ug/L ND 5.0 10/19/1613:34 Styrene ug/L ND 5.0 10/19/1613:34 tert-Butyl Alcohol ug/L ND 100 10/19/16 13:34 tert-Butyl benzene ug/L ND 5.0 10/19/1613:34 Tetrachloroethene ug/L ND 5.0 10/19/1613:34 Toluene ug/L ND 5.0 10/19/1613:34 trans- 1,2-Dichloroethene ug/L ND 5.0 10/19/1613:34 trans- l,3-Dichloropropene ug/L ND 5.0 10/19/1613:34 Trichloroethene ug/L ND 5.0 10/19/1613:34 Trichlorofluoromethane ug/L ND 10.0 10/19/1613:34 Vinyl acetate ug/L ND 10.0 10/19/16 13:34 Vinyl chloride ug/L ND 5.0 10/19/16 13:34 1,2-Dichloroethane-d4 (S) % 98 70-130 10/19/16 13:34 4-Bromofluorobenzene (S) % 98 70-130 10/19/16 13:34 Toluene -d8 (S) % 108 70-130 10/19/16 13:34 Qualifiers Face Analytical services, ILLE; 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1849588 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2 -Tetrachloroethane ug/L 50 52.1 104 80-125 1,1,1 -Trichloroethane ug/L 50 53.7 107 71-129 1,1,2,2 -Tetrachloroethane ug/L 50 48.9 98 79-124 1,1,2 -Trichloroethane ug/L 50 53.3 107 85-125 1,1-Dichloroethane ug/L 50 54.2 108 73-126 1,1-Dichloroethene ug/L 50 55.5 111 66-135 1,1-Dichloropropene ug/L 50 57.4 115 74-135 1,2,3-Trichlorobenzene ug/L 50 53.7 107 73-135 1,2,3-Trichloropropane ug/L 50 47.7 95 75-130 1,2,4-Trichlorobenzene ug/L 50 53.9 108 75-134 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dafe: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. acemalxical® / www.pacelabs.com 1 I Project: Boone Cottages 10/12 Pace Project No.: 92315715 QUALITY CONTROL DATA vace Analytical 5ervlces, LLL; 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1849588 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trimethylbenzene ug/L 50 51.5 103 79-125 1,2-Dibromo-3-chloropropane ug/L 50 53.3 107 71-133 1,2-Dibromoethane (EDB) ug/L 50 57.5 115 83-124 1,2-Dichlorobenzene ug/L 50 51.9 104 80-133 1,2-Dichloro ethane ug/L 50 50.1 100 67-128 1,2-Dichloroethene (Total) ug/L 100 110 110 73-128 1,2-Dichloropropane ug/L 50 53.7 107 75-132 1,3,5-Trimethylbenzene ug/L 50 51.6 103 79-123 1,3-Dichlorobenzene ug/L 50 51.2 102 77-130 1,3-Dichloropropane ug/L 50 52.6 105 76-131 1,4-Dichlorobenzene ug/L 50 49.8 100 78-130 2,2-Dichloropropane ug/L 50 56.5 113 40-160 2-Butanone (MEK) ug/L 100 114 114 61-144 2-Chlorotoluene ug/L 50 52.2 104 74-132 2-Hexanone ug/L 100 115 115 68-143 4-Chlorotoluene ug/L 50 51.8 104 76-133 4-Methyl-2-pentanone (MIRK) ug/L 100 112 112 72-135 Acetone ug/L 100 116 116 48-146 Benzene ug/L 50 55.4 111 80-125 Bromobenzene ug/L 50 52.9 106 75-125 Bromochloromethane ug/L 50 52.9 106 71-125 Bromodichloromethane ug/L 50 50.9 102 78-124 Bromoform ug/L 50 42.9 86 71-128 Bromomethane ug/L 50 39.9 80 40-160 Carbon tetrachloride ug/L 50 52.3 105 69-131 Chlorobenzene ug/L 50 50.6 101 81-122 Chloroethane ug/L 50 53.5 107 39-148 Chloroform ug/L 50 51.7 103 73-127 Chloromethane ug/L 50 46.9 94 44-146 cis-1,2-Dichloroethene ug/L 50 54.1 108 74-124 cis- 1,3-Dichloropropene ug/L 50 56.2 112 72-132 Dibromochloromethane ug/L 50 48.0 96 78-125 Dibromomethane ug/L 50 48.9 98 82-120 Dichlorodifluoromethane ug/L 50 55.9 112 34-157 Diisopropyl ether ug/L 50 64.8 130 69-135 Ethylbenzene ug/L 50 49.8 100 79-121 Hexachloro-1,3-butadiene ug/L 50 54.1 108 72-131 Isopropyl benzene (Cumene) ug/L 50 49.2 98 81-132 m&p-Xylene ug/L 100 98.6 99 81-124 Methyl-tert-butyl ether ug/L 50 64.2 128 74-131 Methylene Chloride ug/L 50 59.2 118 64-133 n-Butylbenzene ug/L 50 52.9 106 78-127 n-Propylbenzene ug/L 50 50.3 101 78-130 Naphthalene ug/L 50 51.9 104 73-133 o-Xylene ug/L 50 49.6 99 79-131 p-I sopropyltoluene ug/L 50 52.0 104 80-131 sec-Butylbenzene ug/L 50 50.9 102 80-133 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 10/20/2016 12:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 1!;alcle 1 ' www.pacelabs.corn r _ QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 . LABORATORY CONTROL SAMPLE: 1849588 Pace Analytical services, i -i -c; 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 10/20/2016 1 2:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Styrene ug/L 50 52.5 105 84-126 tert-Butyl Alcohol ug/L 500 537 107 36-136 tert-Butylbenzene ug/L 50 41.9 84 77-133 Tetrachloroethene ug/L 50 46.4 93 78-122 Toluene ug/L 50 49.3 99 80-121 trans-1,2-Dichloroethene ug/L 50 55.8 112 71-127 trans-1,3-Dichloropropene ug/L 50 53.4 107 69-141 Trichloroethene ug/L 50 53.2 106 78-122 Trichlorofluoromethane ug/L 50 50.3 101 53-137 Vinyl acetate ug/L 100 109 109 40-160 Vinyl chloride ug/L 50 42.9 86 58-137 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene -d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: 1849590 92316157005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2 -Tetrachloroethane ug/L ND 20 20.9 105 70-130. 1,1,1 -Trichloroethane ug/L ND 20 24.9 124 70-130 1,1,2,2 -Tetrachloroethane ug/L ND 20 21.4 107 70-130 1,1,2 -Trichloroethane ug/L ND 20 23.0 115 70-130 1,1-Dichloroethane ug/L ND 20 25.4 127 70-130 1,1-Dichloroethene ug/L ND 20 25.2 126 65-160 1,1-Dichloropropene ug/L ND 20 24.7 123 70-130 1,2,3-Trichlorobenzene ug/L ND 20 21.5 108 70-130 1,2,3-Trichloropropane ug/L ND 20 22.0 110 70-130 1,2,4-Trichlorobenzene ug/L ND 20 21.3 106 70-130 1,2,4-Trimethylbenzene ug/L ND 20 21.6 108 70-130 1,2-Dibromo-3-ch loropropane ug/L ND 20 24.0 120 70-130 1,2-Dibromoethane (EDB) ug/L ND 20 23.8 119 60-139 1,2 -Dichlorobenzene ug/L ND 20 22.8 114 70-130 1,2-Dichloroethane ug/L ND 20 23.5 117 70-130 1,2-Dichloropropane ug/L ND 20 24.0 120 70-130 1,3,5-Trimethylbenzene ug/L ND 20 21.4 107 70-130 1,3 -Dichlorobenzene ug/L ND 20 22.3 112 70-130 1,3-Dichloropropane ug/L ND 20 22.1 110 70-130 1,4 -Dichlorobenzene ug/L ND 20 21.8 109 70-130 2,2-Dichloropropane ug/L ND 20 24.7 123 70-130 2-Butanone (MEK) ug/L ND 40 50.7 127 70-130 2-Chlorotoluene ug/L ND 20 23.0 115 70-130 2-Hexanone ug/L ND 40 52.3 131 70-130 M1 4-Chlorotoluene ug/L ND 20 22.7 114 70-130 4-Methyl-2-pentanone (MIBK) ug/L ND 40 50.6 127 70-130 Acetone ug/L ND 40 55.3 138 70-130 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 10/20/2016 1 2:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical services, LLc 2225 Riverside Dr. aceAnalytical Asheville, NC 28804 www.pamwabs.com (828)254-7176 1 1 QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 MATRIX SPIKE SAMPLE: Parameter 1849590 Units 92316157005 Result Spike Cone. MS Result MS % Rec % Rec Limits Qualifiers Benzene ug/L ND 20 25.0 125 58-162 Bromobenzene ug/L ND 20 22.7 113 70-130 Bromochloromethane ug/L ND 20 24.6 123 70-130 Bromodichloromethane ug/L ND 20 23.1 115 70-130 Bromoform ug/L ND 20 18.7 93 70-130 Bromomethane ug/L ND 20 20.8 104 70-130 Carbon tetrachloride ug/L ND 20 24.4 122 70-130 Chlorobenzene ug/L ND 20 22.6 113 70-138 Chloroethane ug/L ND 20 22.8 114 70-130 Chloroform ug/L ND 20 24.4 122 70-130 Chloromethane ug/L ND 20 23.4 117 70-130 cis-1,2-Dichloroethene ug/L ND 20 24.6 123 70-130 cis-1,3-Dichloropropene ug/L ND 20 22.6 113 70-130 Dibromochloromethane ug/L ND 20 19.5 97 70-130 Dibromomethane ug/L ND 20 23.1 115 70-130 Dichlorodifluoromethane ug/L ND 20 19.8 99 70-130 Diisopropyl ether ug/L ND 20 25.7 128 70-130 Ethylbenzene ug/L ND 20 22.4 112 22-189 Hexachloro-1,3-butadiene ug/L ND 20 27.7 139 70-130 M1 Isopropylbenzene (Cumene) ug/L ND 20 21.5 108 70-130 m&p-Xylene ug/L ND 40 45.2 113 32-193 Methyl-tert-butyl ether ug/L ND 20 24.5 123 37-169 Methylene Chloride ug/L ND 20 29.2 146 70-130 M1 n-Butylbenzene ug/L ND 20 22.5 112 70-130 n-Propylbenzene ug/L ND 20 22.0 110 70-130 Naphthalene ug/L ND 20 20.9 105 19-212 o -Xylene ug/L ND 20 22.3 112 70-135 p-Isopropyltoluene ug/L ND 20 22.0 110 70-130 sec-Butylbenzene ug/L ND 20 22.1 111 70-130 Styrene ug/L ND 20 23.3 116 70-130 tert-Butyl Alcohol ug/L ND 200 297 148 70-130 M1 tert-Butyl benzene ug/L ND 20 18.1 90 70-130 Tetrachloroethene ug/L ND 20 19.9 99 70-130 Toluene ug/L ND 20 23.0 115 65-152 trans- l,2-Dichloroethene ug/L ND 20 25.6 128 70-130 trans-1,3-Dichloropropene ug/L ND 20 22.1 111 70-130 Trichloroethene ug/L ND 20 23.6 118 70-142 Trichlorofluoromethane ug/L ND 20 22.9 115 70-130 Vinyl acetate ug/L ND 40 36.8 92 70-130 Vinyl chloride ug/L ND 20 18.6 93 70-130 1,2-Dichloroethane-d4 (S) % 107 70-130 4-Bromofluorobe nzene (S) % 97 70-130 Toluene -d8 (S) % 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical v / www.pacelabs.com QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 SAMPLE DUPLICATE: 1849589 Parameter Units 92315715001 Result Dup Result 1,1,1,2 -Tetrachloroethane ug/L ND ND 1,1,1 -Trichloroethane ug/L ND ND 1,1,2,2 -Tetrachloroethane ug/L ND ND 1,1,2 -Trichloroethane ug/L ND ND 1,1-Dichloroethane ug/L ND ND 1,1-Dichloroethene ug/L ND ND 1,1-Dichloropropene ug/L ND ND 1,2,3-Trichlorobenzene ug/L ND ND 1,2,3-Trichloropropane ug/L ND ND 1,2,4-Trichlorobenzene ug/L ND ND 1,2,4-Trimethylbenzene ug/L ND ND 1,2-Dibromo-3-chloropropane ug/L ND ND 1,2-Dibromoethane (EDB) ug/L ND ND 1,2 -Dichlorobenzene ug/L ND ND 1,2-Dichloroethane ug/L ND ND 1,2-Dichloroethene (Total) ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,3,5-Trimethylbenzene ug/L ND ND 1,3 -Dichlorobenzene ug/L ND ND 1,3-Dichloropropane ug/L ND ND 1,4 -Dichlorobenzene ug/L ND ND 2,2-Dichloropropane ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Chlorotoluene ug/L ND ND 2-Hexanone ug/L ND ND 4-Chlorotoluene ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Benzene ug/L ND ND Bromobenzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Dichlorodifluoromethane ug/L ND ND Diisopropyl ether ug/L ND ND Ethylbenzene ug/L ND ND Hexachloro-1,3-butadiene ug/L ND ND RPD Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical f www.pacelabs.com QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 SAMPLE DUPLICATE: 1849589 Parameter Units 92315715001 Result Dup Result Isopropyl benzene (Cumene) ug/L ND ND m&p-Xylene ug/L ND ND Methyl-tert-butyl ether ug/L ND ND Methylene Chloride ug/L ND ND n-Butylbenzene ug/L ND ND n-Propylbenzene ug/L ND ND Naphthalene ug/L ND ND o -Xylene ug/L ND ND p-Isopropyltoluene ug/L ND ND sec-Butylbenzene ug/L ND ND Styrene ug/L ND ND tert-Butyl Alcohol ug/L ND ND tert-Butylbenzene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans-1,3-Dichloropropene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND 1,2-Dichloroethane-d4 (S) % 100 100 4-Bromofluorobenzene (S) % 96 102 Toluene -d8 (S) % 110 110 RPD Qualifiers 0 7 1 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. _ aceAnalj cal® www.pa6slabs.com i QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 332887 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92315715001 METHOD BLANK: 1844758 Matrix: Water Associated Lab Samples: 92315715001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 10/12/16 17:31 LABORATORY CONTROL SAMPLE: 1844759 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 260 104 90-110 SAMPLE DUPLICATE:. 1844760 92314813025 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 589 586 1 SAMPLE DUPLICATE: 1844761 92315610001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 145 144 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. _ aceAnalytical" / www.pacetgbs.com i QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333032 Analysis Method: SM 9222D QC Batch Method: SM 9222D Analysis Description: 9222D MBIO Fecal Coliform - AVL Associated Lab Samples: 92315715001 METHOD BLANK: 1845596 Matrix: Water Associated Lab Samples: 92315715001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 10/12/16 14:53 SAMPLE DUPLICATE: 1845597 Parameter Fecal Coliforms 92315634005 Dup Units Result Result CFU/100 mL 172 182 RPD Qualifiers 6 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2547176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/2012016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. or I aceAnalyticalo / www.pacelabs.com i i Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333659 QC Batch Method: EPA 350.1 1993 Rev 2.0 Associated Lab Samples: 92315715001 METHOD BLANK: 1849093 Associated Lab Samples: 92315715001 Parameter Units Nitrogen, Ammonia mg/L QUALITY CONTROL DATA Analysis Method: EPA 350.1 1993 Rev 2.0 Analysis Description: 350.1 Ammonia Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 10/19/16 04:22 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NO 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1849094 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1849095 1849096 MS MSD 92314905001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.0 5.0 100 100 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1849097 1849098 MS MSD 92315828001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.9 4.9 97 97 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 12:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalftal l www.pacelabs.com f i QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333116 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92315715001 METHOD BLANK: 1846030 Associated Lab Samples: 92315715001 Parameter Units Nitrogen, Nitrate mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.020 10/13/16 22:26 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (628)254-7176 LABORATORY CONTROL SAMPLE: 1846031 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1846032 1846033 MS MSD 92315731001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.91 2.5 2.5 3.4 3.4 100 101 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1846034 1846035 MS MSD 92315978005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 4.4 2.5 2.5 7.5 7.5 123 125 90-110 1 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalXical www.pacWabs.com QUALITY CONTROL DATA Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333466 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92315715001 METHOD BLANK: 1848042 Matrix: Water Associated Lab Samples: 92315715001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 10/19/16 03:58 Pace Analyocai services, SLG 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1848043 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848044 1848045 MS MSD 92315615001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1.9 2.5 2.5 4.4 4.5 98 102 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848046 1848047 MS MSD 92315719001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1.3 2.5 2.5 1.3 1.3 1 1 90-110 0 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 12:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalj&al / www.pacebbs.com i Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333004 QC Batch Method: SM 4500 -CI -E Associated Lab Samples: 92315715001 METHOD BLANK: 1845449 Associated Lab Samples: 92315715001 Parameter Units Chloride mg/L LABORATORY CONTROL SAMPLE: 1845450 Parameter Units Chloride mg/L race Analyucal serVlceS, LLG 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Analysis Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 10/14/16 22:28 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 20 20.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1845451 1845452 MS MSD 92314876005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 1690 10 10 12.2 12.2 105 105 90-110 0 ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1845453 1845454 MS MSD 92315606001 Spike ' -Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 4.8 10 10 15.0 15.0 102 102 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. aceAnalj&al � vrwa!pacelabs.catr t 1 Project: Boone Cottages 10/12 Pace Project No.: 92315715 QC Batch: 333636 QC Batch Method:, SM 5310B Associated Lab Samples: 92315715001 METHOD BLANK: 1848804 Associated Lab Samples: 92315715001 Parameter Units Total Organic Carbon mg/L QUALITY CONTROL DATA Analysis Method: SM 5310B Analysis Description: 5310B TOC Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 10/19/16 00:10 Pace Analytical SerVICeS, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 i LABORATORY CONTROL SAMPLE: 1848805 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.1 92 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1848806 1848807 MS MSD 92315319008 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 8.4 25 25 32.2 32.8 95 98 90-110 2 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, •D,%te: 10/20/2016 12:57 PM without the written consent of Pace Analytical Services, LLC. 00*7 aCeAna1Xica1 / www.peaWsbscom QUALIFIERS Project: Boone Cottages 10/12 Pace Project No.: 92315715 DEFINITIONS Pace Analyrlcal services, LLG 2225 Riverside Dr. DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. Asheville, NC 28804 (828)254-7176 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/20/2016 12:57 PM without the written consent of Pace Analytical Services, LLC. ace AnalXical .�� www.Pacelebs.cm QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Boone Cottages 10/12 Pace Project No.: 92315715 Pace Anaiyucat services, LLc 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 A REPORT OF LABORATORY ANALYSIS • This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92315715001 MW -2 EPA 8260 333748 92315715001 MW -2 SM 2540C 332887 92315715001 MW -2 SM 9222D 333032 92315715001 MW -2 EPA 350.1 1993 Rev 2.0 333659 92315715001 MW -2 EPA 353.2 333116 92315715001 MW -2 EPA 365.1 333466 92315715001 MW -2 SM 4500 -CI -E 333004 92315715001 MW -2 SM 5310B 333636 A REPORT OF LABORATORY ANALYSIS • This report shall not be reproduced, except in full, Date: 10/20/2016 1 2:57 PM without the written consent of Pace Analytical Services, LLC. /.,PaceAna1ytJca1 e www.pacelahs.com CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Page: of Required Client Information: Required Project Information: Invoice Information: Company: 4 r 'i Report To: Attention:j.,� . � r 11 f a VA 6' Address: Copy To: Company Name: REGULATORY AGENCY Address: r NPDES (� GROUND WATER F- DRINKING WATER r UST r RCRA r OTHER Email To: Purchase Order No.: Pace Quote Reference: Phone: Project Name: Pace ProjectF Site Location Manager: STATE.- TATE:Requested Requested Due DaterrAT: Project Number: G'• Pace Profile#: Requested Analysis Filtered (Y/N) Section D Matrix Codes 2~ Required Client Information MATRIX I CODE m O COLLECTED Preservatives N _ Drinking Water DW -. U z Water WT e U O i - Waste Water WW .� COMPOSITE COMPOSITE W Product P Q START ENn/GRAB -� Z Sol] lSolid SL f7 OL SAMPLE ID wi t W a WID (A -Z, 0-9! ;) Air AR 0 w a Z [— -. ti• p Sample IDS MUST BE UNIQUE Tissue TS O C) (L m y 2 t t.) �p ; kj� Other OT X. W WO Z Z N n O , .r a a E x m to tw ¢ ¢ c z 2 U m to DATE TIME TIME DdATE��, in � � X 2 Z Z � O —11, Pace Project No./ Lab I.D. 1 d 1 ` / I i 3 4 Y', 5 _ /i X y 6 Y® I`., 7 r �T X 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY/ AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DAi E TIME SAMPLE CONDITIONS ��, i - i } r �r / , r SAMPLER NAME AND SIGNATURE '"a`•a=t 6 a 02, M 0;9 .202 ? PRINT Name of SAMPLER: _d(77-7 f-- t r 4 E .� � .�` _F i3 k SIGNATURE of SAMPLER: E i f, `, DATE Signed ) 4r, •{ r �l f j F U m s (MMIDDIYY): m ;:tmponant Note: tjy signing tors torn you are accepting F'ece's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any involces not paid within 30 days. F-ALL-Q-020reV.07, 15 -May -2007 �