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HomeMy WebLinkAboutWQ0028693_Monitoring - 11-2016_20170103r. UNDWATER QUALITY MONITORING: PLIANCE REPORT FORM Name: Mountaintc Name (if different): Mo Address: PO Box 14 IGYC Ee'tS'EE'is Golf & Lake Club act Person: Bob Barr Location/Site Name: MW -01R or Association Inc SUBMI r FUKM UN YELLUW FAVLK UNLY County Jackson Telephone#: (828) 251-1900 No. of wells to be sampled: 3 RMIT Number: Expiration Date: 7/31/2014 n -Discharge WQ0028693 UIC IDES Other PE OF PERMITTED OPERATION BEING MONITORED ❑, Lagoon ❑ Remediation: Infiltration Gallery ® Spray Field ❑ (Remediation: E Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): MW -01R Well Depth: 25.6 ft. Depth to Water Level: 14 ft. below measuring point Measuring Point is 0 ft. above land surface Volume of water pumped/bailed before sampling: - Samples for metals were collected unfiltered: ❑YES Date sample collected: 11-14=16 Well Diameter: 2 in. Screened Interval: 15.6 ft. to 25.6 ft. Relative M.P. Elevation: ft. gallons ❑ NO and field acidified: ❑YES El NO FIELD ANALYSES: pH 6.4 units Temp. 16.1 °C Spec. Cond. µMhos Odor No Odor Appearance Cloudy WAS DRY at time of sampling, check here: n LABORATORY INFORMATION Date sample analyzed: 11/14/16 to 12/2/16 p Laboratory Name: Pace Analytical Services Inc Certification No. 40 Y�� PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. 40P COD mg/I Nitrite (NO2) as N mg/I Pb -Leat9 mg/I JAN a 4. 0111140 41490 Coliform: MF Fecal <4.0 1100ml Nitrate (NOa) as N <0.020 mg/I Zn -Zinc mg/I Coliform: MF Total 11GOrni (Note: Use MPN method for highly turbid samples) Phosphorus: Total as P Orthophosphate 0.34 mg/i mg/I Other (Specify Compounds and r I t% Dissolved Solids: Total 1CIA mg/l Al -Aluminum mg/I .1 pH (when analyzed) units Ba - Barium mg/I TOC 6.0 mg/i Ca - Calcium mg/I 9WR.� 39.8 Chloride mglt Cd -Cadmium mg/I ° oiq INF�I7wnA7pj...� Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate mg/I Hg - Mercury mg/I Report Attached? IR Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia 0.17 mg/t Mg - Magnesium mg/I method # (Ammonia. Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I _ _ _ , method. # TKNas N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Bob Barr, Authorized Agent Permittee (or Authorized AAent) Name and Title - Please print or type GW -59 Rev. 1/2007 Effluent.. I that the laboratory analytical data was produced using approved methods of analysis by a y of fines and imprisonment for knoyn 'oi2tionss, a (if Permittee (or Authorized Aqent) •- SUBMIT FORM ON YELLOW PAPER ONLY For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Bob Barr, Authorized Agent Permittee (or Authorized Agent) Name and 'Tibe- Please print or type GW -59 Rev. 1/2007 mg/L Effluent Total VOCs: (or mg/L VOC Removal% 3�I f s • p ARTiWF3+li £#F`E9i11 31iI�jlFhiT,& N TURA 1 �1URCES s � ol�ssr�lc �� �P $ GROUNDWATER QUALITY MONITORING: 1tis�o� 01 wAT>~rt of I ITv tNI c �lAh� �l� u�l COMPLIANCE REPORT FORM • • s�sn�l�v�cc+ir�ti ta€t;>s�czsss as „t ti�s3.Tazt FACILITY INFORMATION Please Print Clearly or Tl PERMIT Number: Expiration Date: 7/31/2014 Facility Name: Mountaintop Golf & Lake Club Non -Discharge W00028693 UIC Permit Name (if different): Mountaintop Community Association Inc NPDES Other Facility Address: PO Box 1460 TYPE OF PERMITTED OPERATION BEING MONITORED Cashiers NC 28717 County Jackson El Lagoon El Remediation: Infiltration Gallery ®Spray Field ❑ Remediation: Contact Person: Bob Barr _ Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land, Application of Sludge Well Location/Site Name: MW -2 No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑ Other: from. Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW -2 Date sample collected: 11-14=16 FIELD ANALYSES: WAS Well Depth: 42 ft. Well Diameter: 2 in. pH 6.4 units Temp. 13.6 °C DRY at Depth to Water Level: 24.03 ft. below measuring point Screened Interval: 42 ft.. to 32 ft. Spec. Cond. µMhos time of sampling, Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Odor No Odor check Volume of water pumped/bailed before sampling: gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: _ ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/14/16 to 12/2/16 _ Laboratory Name: Pace Analytical Services Inc Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I' Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal <2.0 /100ml Nitrate (NO3) as N 2,2 mg/I Zn —Zinc mg/l Coliform: MF Total /100ml Phosphorus: Total as P <0.050 mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units):. Dissolved Solids: Total 101 mg/l Al -Aluminum mg/I pH (when analyzed) units Ba - Barium mg/I TOC 1.2 rng/I Ca - Calcium mg/I Chloride 6.8 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/l Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate mg/l Hg - Mercury mg/I Report Attached? 5d Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC „ method # Total Ammonia <0.10 mg/I Mg -Magnesium mg/I method # (Ammonia Nitrogen: NH3as N; Ammonia Nitrogen, Total) Mn -Manganese mg/I _ ,method # TKN as N mg/I Ni - Nickel mg/I , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Bob Barr, Authorized Agent Permittee (or Authorized Agent) Name and 'Tibe- Please print or type GW -59 Rev. 1/2007 mg/L Effluent Total VOCs: (or mg/L VOC Removal% 3�I f SUBMIT FORM ON YELLOW PAPER ONLY ,TER QUALITY MONITORING: E REPORT FORM Name: Mountaintop Golf & Lake Club Name (if different): Mountaintop Community Association Inc Address PO Box 1460 iers ``"'e NC 28717 County Jackson act. Person: Bob Barr Telephone#: (828) 251-1900 Location/Site Name: MW -3 No. of wells to be sampled: 3 L ID NUMBER (from Permit):: MW -3 Depth: 160 ft. h to Water Level: 131.14 ft. below measuring point wring Point is 0 ft. above land surface Date sample collected: 11-1446 Well Diameter: 4 in. Screened Interval: ft. to Relative M.P. Elevation: ft. ne of water pumped/bailed before sampling: gallons PERMIT Number: Expiration Date: Non -Discharge W00028693 UIC ?DES Other 'PE OF PERMITTED OPERATION BEING MONITORED EJ Lagoon El Remediation: Infiltration Gallery ® Spray Field ❑ Remediation: ❑ Rotary Distributor 0 Land Application of Sludge El Water Source Heat Pump ❑ Other: If WELL FIELD ANALYSES: WAS; pH 6.5 units Temp. 11.8 °C DRY at ft: Spec. Conti. RMhos time ofsampling, Odor No Odor check Appearance Cloudy here: FT sample analyzed: 11-14-16 to 12-2-16 Laboratory Name: Pace Analytical Services Inc Certification No. 40 kMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mgll Nitrite (NO2) as N mg/1 Pb - Lead mg/I Coliform: MF Fecal' <1.0 /100ml Nitrate (NO3) as N 0,66 mg/1 Zn -Zinc mg/I Coliform: MF Total /100m1 Phosphorus: Total as P 0.093 mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 49.0 mg/1 pH (when analyzed) units TOC <1.0 mg/I Chloride 4.0 mg/I Arsenic mg/I Grease and Oils mg/I Phenol mg/I Sulfate mg/I Specific Conductance µMhos Total Ammonia <0.10 mg/I (Ammonia Nitrogen; NH3as N;. Ammonia Nitrogen; Total) TKN as 'N mg/i AI = Aluminum mg/I Ba - Barium mg/I Ca - Calcium mg/I Cd - Cadmium mg/I Chromium: Total mg/1 Cu - Copper mg/I Fe - Iron -mg/1 Hg - Mercury mg/I K - Potassium mg/I Mg - Magnesium mg/I Mn - Manganese _ mg/I Ni - Nickel mg/I ORGANICS: (by GC; GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Report Attached? ® Yes (1) ❑ No (0) VOC , method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: Bob Barr, Authorized Agent Permittee (or Authorized Agent) Name and Title = Please print or type GW -59 Rev. 1/2007 , method # method # method # VOC'Removal% GW -59.A. COMPLIANCE IANCE .t .:EPt).RT FORM Permit # V &.00 2 ?'j 3 (.Subntit one each monitoring period with Gff-59 forms.) GW -59A 1202003 Enter date monitoring results were due. ) Will this monitoring report (GW -59 and GW -59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW -59 report forms? YES i NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Officefor guidance. 4 Are any monitored constituents equal to or above the established standards? YES O If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES', list in the space provided below, each well with constituent(s) exceeding standards, concentration (s) reported, and sample collection date for each occurrence (for the last two years). 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES'; a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. g The person completing this portion (GW -59A) of the monitoring report should sign below and submit this form with GW -59 forms for required wells to the address provided at the top of the current GW -59 form. I hereby acknowledge that the above tnfarmat)on was evaluated and the information,s,ubrnitted in this repot„(Carnpliande Reporfi, li 19AJ e$ ect nd'csi ”" ileteto t99e laesfi, m .y riotsuledge ,. . 36 (� Signature of Permittee (or Authorized Agent) bate GW -59A 1202003 WeAnalytical wvw.paaelabs.com December 03, 2016 Mr. Robert Barr RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Dear Mr. Barr: Enclosed are the analytical results for sample(s) received by the laboratory on November 14, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, DUAC.", I fai ere -MV _. . Denise Trantham denise.trantham @pacelabs.com Project Manager Enclosures cc: Rick Swilling, RPB Systems Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalXical www.pacelabs.com Rick Swilling RPB Systems Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Project Number: 92319593 Ar aceAnalytical " J www.paceiabs.com SAMPLE ANALYTE COUNT Project! Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92319593001 MW -01 R SM 6200B CAH 63 PASI-C SM 2540C MJSi 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 DMN 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 BRJ 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 5310B AES2 1 PASI-A 92319593002 MW -2 SM 6200B CAH 63 PASI-C SM 2540C MJSi 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 DMN 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 BRJ 1 PASI-A . SM 4500 -CI -E WRC 1 PASI-A SM 53108 AES2 1 PASI-A 92319593003 MW -3 SM 6200B CAH 63 PASI-C SM 2540C MJS1 1 PASI-A SM 9222D KDF1 1 PASI-A EPA 350.1 1993 Rev 2.0 DMN 1 PASI-A EPA 353.2 WRC 1 PASI-A EPA 365.1 BRJ 1 PASI-A SM 4500 -CI -E WRC 1 PASI-A SM 5310B AES2 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC 11�AceAnaljftal' www.pacelabs.com I Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. �;aoeAnalXical www.par0gbS.WM ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Mtn Top MW Pace Project No.: 92319593 Sample: MW -01R Lab ID: 92319593001 Collected: 11/14/1614:00 Received: 11/14/1616:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method Collected By Mark 1 11/18/16 09:13 Swann Collected Date 11/14/2016 1 11/18/16 09:13 Collected Time 14:00 1 11/18/16 09:13 Field pH 6.4 Std. Units 0.10 1 11/18/16 09:13 Field Temperature 16.1 deg C 0.50 1 11/18/16 09:13 Static Water Level 14.00 feet 1 '11/18/16 09:13 Field Specific Conductance 314 umhos/cm 1.0 1 11/18/16 09:13 Total Well Depth 2.5 Gallons feet 1 11/18/16 09:13 Turbidity 50.93 NTU 1.0 1 11/18/16-09:13 Odor No odor 1 11/18/16 09:13 Appearance cloudy 1 11/18/16 09:13 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1. 11/16/1600:38 71-43-2 Bromobenzene ND ug/L 0.50 1 11/16/16 00:38 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/16/16 00:38 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/16/16 00:38 75-27-4 Bromoform ND ug/L 0.50 1 11/16/16 00:38 75-25-2 Bromomethane ND ug/L 5.0 1 11/16/16 00:38 74-83-9 n-Butylbenzene ND ug/L •0.50 1 11/16/16 00:38 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/16/16 00:38 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/16/16 00:38 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/16/16 00:38 56-23-5 - ' Chlorobenzene " "ND ug/L 0.50 1 11/16/16 00:38 108-90-7 Chloroethane ND ug/L 1.0 1 11/16/16 00:38 75-00-3 Chloroform ND ug/L 0.50 1 11/16/16 00:38 67-66-3 Chloromethane ND ug/L 1.0 1 11/16/16 00:38 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/16/16 00:38 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/16/16 00:38 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/16/1600:38 96-12-8 Dibromochloromethane ND ug/L 0.50. 1 11/16/16 00:38 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/16/16 00:38 106-93-4 Dibromomethane ND ug/L 0.50 1 11/16/16 00:38 74-95-3 1,2 -Dichlorobenzene ND ug/L 0.50 1 11/16/16 00:38 95-50-1 1,3 -Dichlorobenzene ND ug/L 0.50 1 11/16/16 00:38 541-73-1 1,4 -Dichlorobenzene ND ug/L 0.50 , 1 11/16/16 00:38 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/16/16 00:38 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/16/1600:38 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/16/16 00:38 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/16/1600:38 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/16/1600:38 156-59-2 trans- l,2-Dichloroethene ND ug/L 0.50 1 11/16/1600:38 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/16/1600:38 78-87-5 1,3-Dichloropropane ND ug/L 0:50 1 11/16/1600:38 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/16/16 00:38 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/16/1600:38 563-58-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. /�aceAnalj&alc www.pamwabs.com ANALYTICAL RESULTS Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW -01R Lab ID: 92319593001 Collected: 11/14/16 14:00 Received: 11/14/16 16:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] 6200B MSV cis-1,3-Dichloropropene trans- l,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlo robe nzene 1,2,4-Trichlorobenzene 1,1,1 -Trichloroethane 1,1,2 -Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 113,5-Trimethylbenzene Vinyl chloride m&p-Xylene o -Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene -d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus Date: 12/03/2016 12:09 AM Analytical Method: SM 6200B ND ug/L 0.50 ND ug/L 0.50 ND ug/L 0.50 ND ug/L 0.50 ND ug/L 2.0 ND ug/L 0.50 ND ug/L 2.0 ND ug/L 0.50 ND ug/L 2.0 ND ug/L 0.50 ND ug/L 0.50 ND ug/L 0.50 ND ug/L 0.50' ND ug/L 0.50 ND ug/L 0.50 ND ug/L 2.0 ND ug/L 2.0 ND ug/L 0.50 ND ug/L 0.50 .ND ug/L 0.50 ND ug/L 1.0 ND ug/L 0.50 ND ug/L 0.50 ND ug/L 0.50 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 0.50 91 % 70-130 98 % 70-130 98 % 70-130 Analytical Method: SM 2540C 194 mg/L 25.0 Analytical Method: SM 9222D ND CFU/100 mL 4.0 Analytical Method: EPA 350.1 1993 Rev 2.0 0.17 mg/L 0.10 Analytical Method: EPA 353.2 ND mg/L 0.020 Analytical Method: EPA 365.1 0.34 mg/L 0.050 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 4 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/16/16 00:38 10061-01-5 11/16/16 00:38 10061-02-6 11/16/16 00:38 108-20-3 11/16/16 00:38 100-41-4 11/16/16 00:38 87-68-3 11/16/16 00:38 98-82-8 11/16/16 00:38 75-09-2 11/16/16 00:38 1634-04-4 11/16/16 00:38 91-20-3 11/16/16 00:38 103-65-1 11/16/16 00:38 100-42-5 11/16/16 00:38 630-20-6 11/16/16 00:38 79-34-5 11/16/16 00:38 127-18-4 11/16/16 00:38 108-88-3 11/16/16 00:38 87-61-6 11/16/16 00:38 120-82-1 11/16/1600:38 71-55-6 11/16/16 00:38 79-00-5 11/16/16 00:38 79-01-6 11/16/16 00:38 75-69-4 11/16/16 00:38 96-18-4 11/16/16 00:38 95-63-6 11/16/16 00:38 108-67-8 11/16/16 00:38 75-01-4 11/16/16 00:38 179601-23-1 11/16/16 00:38 95-47-6 11/16/1600:38 17060-07-0 11/16/1600:38 460-00-4 11 /16/16 00:38 2037-26-5 11/16/16 19:49 11/14/16 16:50 12/02/16 15:24 7664-41-7 11/14/16 23:11 11/18/1623:42 7723-14-0 / 1!1;aceAnalXical' r wwwAecelabs.com I� ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Mtn Top MW Pace Project No.: 92319593 Sample: MW -01R Lab ID: 92319593001 Collected: 11/14/16 14:00 Received: 11/14/16 16:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 39.8 mg/L 1.0 1 11/21/1622:14 16887-00-6 53108 TOC Analytical Method: SM 531013 Total Organic Carbon 6.0 mg/L 1.0 1 11/30/16 19:12 7440-44-0 Date: 12/03/2016 12:09 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnaljNpal {{ www,.p&cW&bs.com 1 Project: Mtn Top MW Pace Project No.: 92319593 Sample: MW -2 Parameters Monitoring Well Data Collected By Collected Date Collected Time Field pH Field Temperature Static Water Level Field Specific Conductance Total Well Depth Turbidity Odor Appearance 6200B MSV Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2 -Dichlorobenzene 1,3 -Dichlorobenzene 1,4 -Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans- 1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane Date: 12/03/2016 1 2:09 AM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92319593002 Results Units Collected: 11/14/16 13:40 Report Limit DF Received: 11/14/16 16:05 Matrix: Water Prepared Analyzed CAS No. Qual Analytical Method: 11/16/1600:55 71-43-2 ND ug/L Mark 1 1 11/18/16 09:16 Swann 0.50 1 11/16/16 00:55 74-97-5 11/14/2016 ug/L 1 11/18/16 09:16 14:00 ND 1 11/18/16 09:16 6.4 Std. Units 0.10 1 11/18/16 09:16 13.6 deg C 0.50 1 11/18/16 09:16 24.03 feet 0.50 1 11/18/16 09:16 140 umhos/cm 1.0 1 . 11/18/16 09:16 5.00 feet ND 1 11/18/16 09:16 gallons 11/16/16 00:55 98-06-6 ND ug/L 26.39 NTU 1.0 1 11/18/16 09:16 no odor 0.50 1 11/18/16 09:16 clear ug/L 1 11/18/16 09:16 Analytical Method: SM 6200B ND ug/L 0.50 1 11/16/1600:55 71-43-2 ND ug/L 0.50 1 11/16/16 00:55 108-86-1 ND ug/L 0.50 1 11/16/16 00:55 74-97-5 ND ug/L 0.50 1 11/16/16 00:55 75-27-4 ND ug/L 0.50 1 11/16/16 00:55 75-25-2 ND ug/L 5.0 1 11/16/16 00:55 74-83-9 ND ug/L 0.50 1 11/16/16 00:55 104-51-8 ND ug/L 0.50 1 11/16/16 00:55 135-98-8 ND ug/L 0.50 1 11/16/16 00:55 98-06-6 ND ug/L 0.50 1 11/16/16 00:55 56-23-5 ND ug/L 0.50 1 11/16/16 00:55 108-90-7. ND ug/L 1.0 1 11/16/16 00:55 75-00-3 ND ug/L 0.50 1 11/16/16 00:55 67-66-3 ND ug/L 1.0 1 11/16/16 00:55 74-87-3 ND ug/L 0.50 1 11/16/16 00:55 95-49-8 ND ug/L 0.50 1 11/16/16 00:55 106-43-4 ND ug/L 1.0 1 11/16/16 00:55 96-12-8 ND ug/L 0.50 1 11/16/16 00:55 124-48-1 ND ug/L 0.50 1 11/16/16 00:55 106-93-4 ND ug/L 0.50 1 11/16/16 00:55 74-95-3 ND ug/L 0.50 1 11/16/16 00:55 95-50-1 ND ug/L 0.50 1 11/16/1600:55 541-73-1 ND ug/L 0.50 1 11/16/16 00:55 106-46-7 ND ug/L 0.50 1 11/16/16 00:55 75-71-8 ND ug/L 0.50 1 11/16/16 00:55 75-34-3 ND ug/L 0.50 1 11/16/16 00:55 107-06-2 ND ug/L 0.50 1 11/16/16 00:55 75-35-4 ND ug/L 0.50 1 11/16/16 00:55 156-59-2 ND ug/L 0.50 1 11/16/16 00:55 156-60-5 ND ug/L 0.50 1 11/16/16 00:55 78-87-5 ND ug/L 0.50 1 11/16/16 00:55 142-28-9 ND ug/L 0.50 1 11/16/16 00:55 594-20-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalytical www..pamwabs.com ANALYTICAL RESULTS Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW -2 Lab ID: 92319593002 Collected: 11/14/16 13:40 Received: 11/14/16 16:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV 1,1-Dichloropropene cis- 1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene. 1,1,1,2 -Tetrachloroethane 1,1,2,2 -Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1 -Trichloroethane 1,1,2 -Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o -Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene -d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350A Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2IN03 unpres Nitrogen, Nitrate Date: 12/03/2016 1 2:09 AM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 91 % 96 % 100 % Analytical Method: SM 2540C 101 mg/L Analytical Method: SM 9222D ND CFU/100 mL 0.50 1 11/16/16 00:55 563-58-6 0.50 1 11/16/16 00:55 10061-01-5 0.50 1 11/16/16 00:55 10061-02-6 0.50 1 11/16/16 00:55 108-20-3 0.50 1 11/16/16 00:55 100-41-4 2.0 1 11/16/16 00:55 87-68-3 0.50 1 11/16/16 00:55 98-82-8 2.0 1 11/16/16 00:55 75-09-2 0.50 1 11/16/16 00:55 1634-04-4 2.0 1 11/16/16 00:55 91-20-3 0.50 1 11/16/16 00:55 103-65-1 0.50 1 11/16/16 00:55 100-42-5 0.50 1 11/16/16 00:55 630-20-6 0.50 1 11/16/16 00:55 79-34-5 0.50 1 11/16/16 00:55 127-18-4 0.50 1 11/16/16 00:55 108-88-3 2.0 1 11/16/16 00:55 87-61-6 2.0 1 11/16/16 00:55 120-82-1 0.50 1 11/16/16 00:55 71-55-6 0.50 1 11/16/16 00:55 79-00-5 0.50 1 11/16/16 00:55 79-01-6 1.0 1 11/16/16 00:55 75-69-4 0.50 1 11/16/16 00:55 96-18-4 0.50 1 11/16/16 00:55 95-63-6 0.50 1 - 11/16/16 00:55 108-67-8 1.0 1 11/16/16 00:55 75-01-4 1.0 1 11/16/16 00:55 179601-23-1 0.50 1 11/16/16 00:55 95-47-6 70-130 1 70-130 1 70-130 1 25.0 1 2.0 2 Analytical Method: EPA 350.1 1993 Rev 2.0 ND mg/L 0.10 1 Analytical Method: EPA 353.2 2.2 mg/L 0.020 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/16/1600:55 17060-07-0 11/16/1600:55 460-00-4 11/16/1600:55 2037-26-5 11/16/16 19:50 11/14/16 16:50 12/02/16 15:25 7664-41-7 11/14/16 23:10 Pace Analytical Services, LLC /{ / 2225 Riverside Dr. aCeAnal ical o Asheville, NC 28804 www.pacelabs.com (828)254-7176 ANALYTICAL RESULTS Project: Mtn Top MW Pace Project No.: 92319593 Sample: MW -2 Parameters Lab ID: 92319593002 Collected: 11/14/16 13:40 Results Units Report Limit DF Received: 11/14/16 16:05 Matrix: Water Prepared Analyzed CAS No. Qua[ 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus ND mg/L 0.050 1 11/18/1623:43 7723-14-0 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 6.8 mg/L 1.0 1 11/21/1622:15 16887-00-6 5310B TOC Analytical Method: SM 53108 Total Organic Carbon 1.2 mg/L 1.0 1 11/30/1620:22 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. acoAnalytical www,pacelabs.com 3 Projects Mtn Top MW Pace Project No.: 92319593 Sample: MW -3 Parameters Monitoring Well Data Collected By Collected Date Collected Time Field pH Field Temperature Static Water Level Field Specific Conductance Total Well Depth Turbidity Odor Appearance 6200B MSV Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride - " Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2 -Dichlorobenzene 1,3 -Dichlorobenzene 1,4 -Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans- l,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2=Dichloropropane 1,1-Dichloropropene Date: 12/03/2016 12:09 AM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NO 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92319593003 Collected: 11/14/1614:10 Received: 11/14/1616:05 Matrix: Water Results Units Analytical Method: Mark 1 Swann ug/L 11/14/2016 11/18/16 09:22. 14:40 1 6.5 Std. Units 11.8 deg C 131.14 feet 112 umhos/cm 24 Gallons feet 46.50 NTU No Ordor Cloudy Analytical Method: SM 6200B Report Limit DF Prepared Analyzed CAS No. Qual ND 1 11/18/16 09:22 1 1 11/18/16 09:22 ug/L 1 11/18/16 09:22. 0.10 1 11/18/16 09:22 0.50 1 11/18/16 09:22 ND 1 11/18/16 09:22 1.0 1 11/18/16 09:22 ug/L 1 11/18/16 09:22 1.0 1 11/18/16 09:22 5.0 1 11/18/16 09:22 .ND 1 11/18/16 09:22 ND ug/L 0.50 1 11/16/16 01:12 71-43-2 ND ug/L 0.50 1 11/16/16 01:12 108-86-1 ND ug/L 0.50 1 11/16/16 01:12 74-97-5 ND ug/L 0.50 1 11/16/16 01:12 75-27-4 ND ug/L 0.50 1 11/16/16 01:12 75-25-2 ND ug/L 5.0 1 11/16/16 01:12 74-83-9 .ND ug/L 0.50 1 11/16/16 01:12 104-51-8 ND ug/L 0.50 1 11/16/16 01:12 135-98-8 ND ug/L 0.50 1 11/16/16 01:12 98-06-6 ND ug/L 0.50 1 11/16/16 01:12 56-23-5 -ND ug/L 0.50 1 11/16/16 01:12 108-90-7 ND ug/L 1.0 1 11/16/16 01:12 75-00-3 ND ug/L 0.50 1 11/16/16 01:12 67-66-3 ND ug/L 1.0 1 11/16/16 01:12 74-87-3 ND ug/L 0.50 1 11/16/16 01:12 95-49-8 ND ug/L 0.50 1 11/16/16 01:12 106-43-4 ND ug/L 1.0 1 11/16/16 01:12 96-12-8 ND ug/L 0.50 1 11/16/16 01:12 124-48-1 ND ug/L 0.50 1 11/16/1601:12 106-93-4 ND ug/L 0.50 1 11/16/16 01:12 74-95-3 ND ug/L 0.50 1 11/16/16 01:12 95-50-1 ND ug/L 0.50 1 11/16/1601:12 541-73-1 ND ug/L 0.50 1 11/16/16 01:12 106-46-7 ND ug/L 0.50 1 11/16/1601:12 75-71-8 ND ug/L 0.50 1 11/16/16 01:12 75-34-3 ND ug/L 0.50 1 11/16/16 01:12 107-06-2 ND ug/L 0.50 1. 11/16/16 01:12 75-35-4 ND ug/L 0.50 1 11/16/16 01:12 156-59-2 ND ug/L 0.50 1 11/16/16 01:12 156-60-5 ND ug/L 0.50 1 11/16/16 01:12 78-87-5 ND ug/L 0.50 1 11/16/16 01:12 142-28-9 ND ug/L 0.50 1 11/16/16 01:12 594-20-7 ND ug/L 0.50 1 11/16/16 01:12 563-58-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnaiyiical`� f wwwpace1abs.com i ANALYTICAL RESULTS Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW -3 Lab ID: 92319593003 Collected: 11/14/16 14:10 Received: 11/14/16 16:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 6200B cis-1,3-Dichloropropene ND ug/L 0.50 1 11/16/16 01:12 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/16/16 01:12 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/16/16 01:12 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/16/16 01:12 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/16/1601:12 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/16/16 01:12 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/16/16 01:12 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/16/16 01:12 1634-04-4 Naphthalene ND ug/L 2.0 1 11/16/1601:12 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/16/16 01:12 103-65-1 Styrene ND ug/L 0.50 1 11/16/16 01:12 100-42-5 1,1,1,2 -Tetrachloroethane ND ug/L 0.50 1 11/16/16 01:12 630-20-6 1,1,2,2 -Tetrachloroethane ND ug/L 0.50 1 11/16/16 01:12 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/16/16 01:12 127-18-4 Toluene ND ug/L 0.50 1 11/16/16 01:12 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/16/1601:12 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/16/1601:12 120-82-1 1,1,1 -Trichloroethane ND ug/L 0.50 1 11/16/1601:12 71-55-6 1,1,2 -Trichloroethane ND ug/L 0.50 1 11/16/1601:12 79-00-5 Trichloroethene ND ug/L 0.50 1 11/16/16 01:12 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/16/16 01:12 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/16/16 01:12 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/16/16 01:12 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/16/1601:12 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/16/16 01:12 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/16/1601:12 179601-23-1 o -Xylene ND ug/L 0.50 1 11/16/16 01:12 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 11/16/16 01:12 17060-07-0 4-Bromofluorobenzene (S) 96 % 70-130 1 11/16/16 01:12 460-00-4 Toluene -d8 (S) 99 % 70-130 1 11/16/16 01:12 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 49.0 mg/L 25.0 1 11/16/16 19:50 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 11/14/16 16:50 350.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0 Nitrogen, Ammonia ND mg/L 0.10 1 12/02/16 15:27 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Nitrogen, Nitrate 0.66 mg/L 0.020 1 11/14/16 23:13 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Phosphorus 0.093 mg/L 0.050 1 11/18/1623:43 7723-14-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 1 2:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical / www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Mtn Top MW Pace Project No.: 92319593 Sample: MW -3 Lab ID: 92319593003 Collected: 11/14/16 14:10 Received: 11/14/16 16:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500 -CI -E Chloride 4.0 mg/L 1.0 1 11/21/16 22:22 16887-00-6 M1 5310B TOC Analytical Method: SM 5310B Total Organic Carbon ND mg/L 1.0 1 11/30/1620:55 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. �IlaceAnaljftal wwwpacelabs.com QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 337000 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92319593001, 92319593002, 92319593003 METHOD BLANK: 1868782 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed - 1,1,1,2 -Tetrachloroethane ug/L ND 0.50 11/16/16 00:04 1,1,1 -Trichloroethane ug/L ND 0.50 11/16/1600:04 1,1,2,2 -Tetrachloroethane ug/L ND 0.50 11/16/16 00:04 1,1,2 -Trichloroethane ug/L ND 0.50 11/16/1600:04 1,1-Dichloroethane ug/L ND 0.50 11/16/1600:04 1,1-Dichloroethene ug/L ND 0.50 11/16/1600:04 1,1-Dichloropropene ug/L ND 0.50 11/16/1600:04 1,2,3-Trichlorobenzene ug/L ND 2.0 11/16/16 00:04 1,2,3-Trichloropropane ug/L ND 0.50 11/16/16 00:04 1,2,4-Trichlorobenzene ug/L ND 2.0 11/16/16 00:04 1,2,4-Trimethylbenzene ug/L ND 0.50 11/16/16 00:04 1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/16/16 00:04 1,2-Dibromoethane(EDB) ug/L ND 0.50 11/16/1600:04 1,2 -Dichlorobenzene ug/L ND 0.50 11/16/16 00:04 1,2-Dichloroethane ug/L ND 0.50 11/16/16 00:04 1,2-Dichloropropane ug/L ND 0.50 11/16/16 00:04 1,3,5 -Trim ethyl benzene ug/L ND 0.50 11/16/16 00:04 1,3 -Dichlorobenzene ug/L ND 0.50 11/16/16 00:04 1,3-Dichloropropane ug/L ND 0.50 11/16/1600:04 1,4 -Dichlorobenzene ug/L ND 0.50 11/16/1600:04 2,2-Dichloropropane ug/L ND 0.50 11/16/16 00:04 2-Chlorotoluene ug/L ND 0.50 11/16/16 00:04 4-Chlorotoluene ug/L ND 0.50 11/16/16 00:04 Benzene ug/L ND 0.50 11/16/16 00:04 Bromobenzene ug/L ND 0.50 11/16/16 00:04 Bromochloromethane ug/L ND 0.50 11/16/16 00:04 Bromodichloromethane ug/L ND 0.50 11/16/16 00:04 Bromoform ug/L ND 0.50 11/16/16 00:04 Bromomethane ug/L ND 5.0 11/16/16 00:04 Carbon tetrachloride ug/L ND 0.50 11/16/16 00:04 Chlorobenzene ug/L ND 0.50 11/16/16 00:04 Chloroethane ug/L ND 1.0 11/16/16 00:04 Chloroform ug/L ND 0.50 11/16/16 00:04 Chloromethane ug/L ND 1.0 11/16/16 00:04 cis-1,2-Dichloroethene ug/L ND 0.50 11/16/1600:04 cis-1,3-Dichloropropene ug/L ND 0.50 11/16/1600:04 Dibromochloromethane ug/L ND 0.50 11/16/16 00:04 Dibromomethane ug/L ND 0.50 11/16/16 00:04 Dichlorodifluoromethane ug/L ND 0.50 11/16/16 00:04 Diisopropyl ether ug/L ND 0.50 11/16/16 00:04 Ethylbenzene ug/L ND 0.50 11/16/16 00:04 Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical / www..pacelabs.com QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 METHOD BLANK: 1868782 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Hexachloro-1,3-butadiene ug/L ND 2.0 11/16/1600:04 Isopropylbenzene (Cumene) ug/L ND 0.50 11/16/16 00:04 m&p-Xylene ug/L ND 1.0 11/16/16 00:04 Methyl-tert-butyl ether ug/L ND 0.50 11/16/16 00:04 Methylene Chloride ug/L ND 2.0 11/16/16 00:04 n-Butylbenzene ug/L ND 0.50 11/16/16 00:04 . n-Propylbenzene ug/L ND 0.50 11/16/16 00:04 Naphthalene ug/L ND 2.0 11/16/16 00:04 o -Xylene ug/L ND 0.50 11/16/16 00:04 sec-Butylbenzene ug/L ND 0.50 11/16/16 00:04 Styrene ug/L ND 0.50 11/16/16 00:04 tert-Butylbenzene ug/L ND 0.50 11/16/16 00:04 Tetrachloroethene ug/L ND 0.50 11/16/16 00:04 Toluene ug/L ND 0.50 11/16/16 00:04 trans-1,2-Dichloroethene ug/L ND 0.50 11/16/1600:04 trans-1,3-Dichloropropene ug/L ND 0.50 11/16/1600:04 Trichloroethene ug/L ND 0.50 11/16/16 00:04 Trichlorofluoromethane ug/L ND 1.0 11/16/16 00:04 Vinyl chloride ug/L ND 1.0 11/16/16 00:04 1,2-Dichloroethane-d4 (S) % 94 70-130 11/16/16 00:04 4-Bromofluorobenzene (S) % 98 70-130 11/16/16 00:04 Toluene -d8 (S) % 97 70-130 11/16/16 00:04 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1868783 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2 -Tetrachloroethane ug/L 50 45.4 91 60-140 1,1,1 -Trichloroethane ug/L 50 43.6 87 60-140 1,1,2,2 -Tetrachloroethane ug/L 50 44.2 88 60-140 1,1,2 -Trichloroethane ug/L 50 43.9 88 60-140 1,1-Dichloroethane ug/L 50 45.2 90 60-140 1,1-Dichloroethene ug/L 50 49.3 99 60-140 1,1-Dichloropropene ug/L 50 44.8 90 60-140 1,2,3-Trichlo robe nzene ug/L 50 47.8 96 60-140 1,2,3-Trichloropropane ug/L 50 41.4 83 60-140 1,2,4-Trichlorobenzene ug/L 50 48.9 98 60-140 1,2,4-Trimethylbenzene ug/L 50 45.7 91 60-140 1,2-Dibromo-3-chloropropane ug/L 50 42.4 85 60-140 1,2-Dibromoethane (EDB) ug/L 50 45.4 91 60-140 1,2 -Dichlorobenzene ug/L 50 46.7 93 60-140 1,2-Dichloroethane ug/L 50 38.8 78 60-140 1,2-Dichloropropane ug/L 50 43.2 86 60-140 1,3,5-Trimethylbenzene ug/L 50 45.4 91 60-140 1,3 -Dichlorobenzene ug/L 50 45.8 92 60-140 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. I�XalceAnalXicalo / www.pacelabs.com I QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 LABORATORY CONTROL SAMPLE: 1868783 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits 1,3-Dichloropropane ug/L 50 43.1 86 60-140 1,4 -Dichlorobenzene ug/L 50 44.7 89 60-140 2,2-Dichloropropane ug/L 50 43.6 87 60-140 2-Chlorotoluene ug/L 50 44.6 89 60-140 4-Chlorotoluene ug/L 50 43.7 87 60-140 Benzene ug/L 50 47.1 94 60-140 Bromobenzene ug/L 50 44.2 88 60-140 Bromochloromethane ug/L 50 46.6 93 60-140 Bromodichloromethane ug/L 50 44.5 89 60-140 Bromoform ug/L 50 44.2 88 60-140 Bromomethane ug/L 50 42.3 85 60-140 Carbon tetrachloride ug/L 50 46.2 92 60-140 Chlorobenzene ug/L 50 43.2 86 60-140 Chloroethane ug/L 50 41.5 83 60-140 Chloroform ug/L 50 43.4 87 60-140 Chloromethane ug/L 50 49.1 98 60-140 cis-1,2-Dichloroethene ug/L 50 44.0 88 60-140 cis-1,3-Dichloropropene ug/L 50 43.4 87 60-140 Dibromochloromethane ug/L 50 45.8 92 60-140 Dibromomethane ug/L 50 43.3 87 60-140 Dichlorodifluoromethane ug/L 50 43.9 88 60-140 Diisopropyl ether ug/L 50 49.6 99 60-140 Ethylbenzene ug/L 50 45.0 90 60-140 Hexachloro-1,3-butadiene ug/L 50 45.3. 91 60-140 Isopropylbenzene (Cumene) ug/L 50 45.6 91 60-140 m&p-Xylene ug/L 100 89.1 89 60-140 Methyl-tert-butyl ether ug/L 50 48.1 96 60-140 Methylene Chloride ug/L 50 53.6 107 60-140 n-Butylbenzene ug/L 50 45.4 91 60-140 n-Propylbenzene ug/L 50 46.1 92 60-140 Naphthalene ug/L 50 46.3 93 60-140 o -Xylene ug/L 50 43.7 87 60-140 sec-Butylbenzene ug/L 50 45.6 91 60-140 Styrene ug/L 50 45.2 90 60-140 tert-Butylbenzene ug/L 50 39.4 79 60-140 Tetrachloroethene ug/L 50 38.0 76 60-140 Toluene ug/L 50 44.0 88 60-140 trans-1,2-Dichloroethene ug/L 50 47.7 95 60-140 trans- l,3-Dich loropropene ug/L 50 43.3 87 60-140 Trichloroethene ug/L 50 43.3 87 60-140 Trichlorofluoromethane ug/L 50 44.1 88 60-140 Vinyl chloride ug/L 50 41.5 83 60-140 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene -d8 (S) % 98 70-130 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical wwN�pacelabs.ccm QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Mtn Top MW Pace Project No.: 92319593 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1868784 1868785 MS MSD 92319593003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2 -Tetrachloroethane ug/L ND 20 20 19.9 21.2 100 106 60-140 6 1,1,1 -Trichloroethane ug/L ND 20 20 21.1 21.4 106 107 60-140 1 1,1,2,2 -Tetrachloroethane ug/L ND 20 20 18.7 21.0 94 105 60-140 12 1,1,2 -Trichloroethane ug/L ND 20 20 19.4 20.7 97 104 60-140 7 1,1-Dichloroethane ug/L ND 20 20 21.1 22.0 105 110 60-140 4 1,1-Dichloroethene ug/L ND 20 20 24.4 25.3 122 127 60-140 4 1,1-Dichloropropene ug/L ND 20 20 21.9 22.8 109 114 60-140 4 1,2,3-Trichlorobenzene ug/L ND 20 20 25.1 26.0 125 130 60-140 4 1,2,3-Trichloropropane ug/L ND 20 20 17.5 19.5 88 98 60-140 11 1,2,4-Trichlo robe nzene ug/L ND 20 20 23.2 24.3 116 122 60-140 5 1,2,4-Trimethylbenzene ug/L ND 20 20 21.1 22.3 105 112 60-140 6 1,2-Dibromo-3-chloropropane ug/L ND 20 20 18.5 20.9 93 104 60-140 12 1,2-Dibromoethane (EDB) ug/L ND 20 20 19.7 21.1 99 106 60-140 7 1,2 -Dichlorobenzene ug/L ND 20 20 21.7 23.1 108 116 60-140 6 1,2-Dichloroethane ug/L ND 20 20 17.5 18.3 87 91 60-140 4 1,2-Dichloropropane ug/L ND 20 20 20.2 20.6 101 103 60-140 2 1,3,5-Trimethylbenzene ug/L ND 20 20 21.0 22.7 105 114 60-140 8 1,3 -Dichlorobenzene ug/L ND 20 20 21.3 22.5 107 112 60-140 5 1,3-Dichloropropane ug/L ND 20 20 18.8 20.2 94 101 60-140 7 1,4 -Dichlorobenzene ug/L ND 20 20 20.7 21.6 103 108 60-140 4 2,2-Dichloropropane ug/L ND 20 20 20.2 20.4 101 102 60-140 1 2-Chlorotoluene ug/L ND 20 20 20.9 22.5 105 113 60-140 7 4-Chlorotoluene ug/L ND 20 20 20.4 21.7 102 109 60-140 6 Benzene ug/L ND 20 20 21.7 22.7 108 114 60-140 5 Bromobenzene ug/L ND 20 20 20.3 21.7 101 108 60-140 -6 Bromochloromethane ug/L ND 20 20 20.9 21.6 105 108 60-140 3 Bromodichloromethane ug/L ND 20 20 20.0 21.3 100 107 60-140 6 Bromoform ug/L ND 20 20 18.1 20.1 91 100 60-140 10 Bromomethane ug/L ND 20 20 17.9 18.5 89 92 60-140 3 Carbon tetrachloride ug/L ND 20 20 22.6 23.4 113 117 60-140 3 Chlorobenzene ug/L ND, 20 20 20.2 21.5 101 107 60-140 6 Chloroethane ug/L ND 20 20 18.7 20.6 94 103 60-140 10 Chloroform ug/L ND 20 20 19.8 20.7 99 103 60-140 4 Chloromethane ug/L ND 20 20 23.4 23.9 115 118 60-140 2 cis- 1,2-Dichloroethene ug/L ND 20 20 20.7 21.0 103 105 60-140 1 cis- 1,3-Dichloropropene ug/L ND 20 20 19.3 20.4 97 102 60-140 6 Dibromochloromethane ug/L ND 20 20 19.9 20.9 100 104 60-140 5 Dibromomethane ug/L ND 20 20 19.2 20.6 96 103 60-140 7 Dichlorodifluoromethane ug/L ND 20 20 21.0 20.8 105 104 60-140 1 Diisopropyl ether ug/L ND 20 20 22.2 23.1 111 116 60-140 4 Ethylbenzene ug/L ND 20 20 21.1 22.3 105 111 60-140 6 Hexachloro-1,3-butadiene ug/L ND 20 20 23.7 25.5 119 127 60-140 7 Isopropylbenzene (Cumene) ug/L ND 20 20 21.1 22.7 106 114 60-140 7 m&p-Xylene ug/L ND 40 40 41.0 44.0 103 110 60-140 7 Methyl-tert-butyl ether ug/L ND 20 20 20.7 21.8 104 109 60-140 5 Methylene Chloride ug/L ND 20 20 21.2 22.8 106 114 60-140 7 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical www.pectlabs.com i I QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1868784 MSD Result MS % Rec MSD % Rec MS RPD 92319593003 Spike Parameter Units Result 116 Conc. n-Butylbenzene ug/L ND 20 n-Propylbenzene ug/L ND 20 Naphthalene ug/L ND 20 o -Xylene ug/L ND 20 sec-Butylbenzene ug/L ND 20 Styrene ug/L ND 20 tert-Butylbenzene ug/L ND 20 Tetrachloroethene ug/L ND 20 Toluene ug/L ND 20 trans-1,2-Dichloroethene ug/L ND 20 trans- 1,3-Dich loropropene ug/L ND 20 Trichloroethene ug/L ND 20 Trichlorofluoromethane ug/L ND 20 Vinyl chloride ug/L ND 20 1,2-Dichloroethane-d4 (S) % 22.6 23.2 4-Bromofluorobenzene (S) % 60-140 2 Toluene -d8 (S) % 19.4 96 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MSD Spike Conc. 1868785 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD 20 22.0 23.2 110 116 60-140 5 20 22.0 23.3 110 117 60-140 6 20 23.2 23.6 116 118 60-140 2 20 19.9 21.4 99 107 60-140 7 20 22.1 23.5 111 118 60-140 6 20 19.9 21.8 100 109 60-140 9 20 18.8 20.0 94 100 60-140 7 20 18.5 18.9 92 94 60-140 2 20 20.5 21.2 103 106 60-140 3 20 22.6 23.2 113 116 60-140 2 20 19.1 19.4 96 97 60-140 2 20 20.5 21.3 103 107 60-140 4 20 22.5 23.1 112 115 60-140 3 20 20.2 20.8 101 104 60-140 3 90 93 70-130 97 100 70-130 98 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. Qua[ Ka0 / �wwwpecolabs.com J QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 337261 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92319593001, 92319593002, 92319593003 METHOD BLANK: 1870419 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers . Total Dissolved Solids mg/L ND 25.0 11/16/16 19:48 LABORATORY CONTROL SAMPLE: 1870420 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 234 94 90-110 SAMPLE DUPLICATE: 1870421 92319593001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 194 192 1 SAMPLE DUPLICATE: 1870422 92319606007 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalXical www.pecalabs.com QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 337013 Analysis Method: QC Batch Method: SM 9222D Analysis Description: Associated Lab Samples: 92319593001, 92319593002, 92319593003 METHOD BLANK: 1868875 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 11/14/16 16:50 SM 9222D 9222D MBIO Fecal Coliform - AVL SAMPLE DUPLICATE: 1868876 92319593002 Parameter Units Result Fecal Coliforms CFU/100 mL ND Dup Result RPD Qualifiers ND Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical J www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 338750 Analysis Method: EPA 350.1 1993 Rev 2.0 QC Batch Method: EPA 350.1 1993 Rev 2.0 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92319593001, 92319593002, 92319593003 METHOD BLANK: 1878245 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 12/02/16 14:51 LABORATORY CONTROL SAMPLE: 1878246 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878247 1878248 MS MSD 92320294001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 5.4 5 5 10.3 10.2 97 96 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878249 1878250 MS MSD 92320310001 Spike Spike MS MSD MS. MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.0 5.0 99 98 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical www pacelabs.com 1 QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 336884 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92319593001, 92319593002, 92319593003 METHOD BLANK: 1868107 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 11/14/16 22:54 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1868108 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1868109 1868110 MS MSD 92319559002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 18.2 2.5 2.5 21.4 21.9 130 152 90-110 3 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical / www.pacelabs.com t QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 337075 Analysis Method: EPA 365.1 QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92319593001, 92319593002, 92319593003 METHOD BLANK: 1869261 Matrix: Water Associated Lab Samples: 92319593001, 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 11/18/16 23:22 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville; NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1869262 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869263 1869264 MS MSD 92319574001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1.2 2.5 2.5 3.7 3.7 99 100 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869265 1869266 MS MSD 92319749002 Spike Spike MS MSD MS MSD ' % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua] Phosphorus mg/L ND 2.5 2.5 2.5 2.5 100 100 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. owl 117PaceAnalytical Q0 ( www.pecolabs.com QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 337875 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92319593001, 92319593002 METHOD BLANK: 1873963 Matrix: Water Associated Lab Samples: 92319593001, 92319593002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 11/21/1621:44 LABORATORY CONTROL SAMPLE: 1873964 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.8 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873965 1873966 MS MSD 92319352011 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 63.0 10 10 69.0 69.0 60 60 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873967 1873968 MS MSD 92319868003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 3.4 10 10 13.6 13.6 102 102 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS • This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. 11�aceAnalytical" www.pacelabs.com / i QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 337877 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92319593003 METHOD BLANK: 1873973 Matrix: Water Associated Lab Samples: 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 11/21/16 22:16 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1873974 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.7 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873975 1873976 MS MSD 92319593003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 4.0 10 10 15.0 15.1 110 111 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873977 1873978 MS MSD 92319646001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 112 10 10 128 128 166 160 90-110 0 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. Ar A aceAnalytical • www.pacelabs.com i QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 338727 Analysis Method: SM 5310B QC Batch Method: SM 5310B Analysis Description: 5310B TOC Associated Lab Samples: 92319593001 METHOD BLANK: 1878104 Matrix: Water Associated Lab Samples: 92319593001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 11/30/16 13:01 LABORATORY CONTROL SAMPLE: 1878105 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878106 1878107 MS MSD 92320237029 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Total Organic Carbon mg/L ND 25 25 23.6 23.9 94 95 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878108 1878109 MS MSD 92320237039 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 24.7 24.6 99 98 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS • This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. 71ceac,Analytical / www.pacelabs.com I ` QUALITY CONTROL DATA Project: Mtn Top MW Pace Project No.: 92319593 QC Batch: 338728 Analysis Method: SM 5310B QC Batch Method: SM 5310B Analysis Description: 5310B TOC Associated Lab Samples: 92319593002, 92319593003 METHOD BLANK: 1878120 Matrix: Water Associated Lab Samples: 92319593002, 92319593003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 11/30/16 19:33 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 1878121 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.6 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878122 1878123 MS MSD 92319593002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 1.2 25 25 25.9 25.4 99 97 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878124 1878125 MS MSD 92320391009 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 24.6 24.3 98 97 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS • This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnaIXical www.pacelabs.com QUALIFIERS Project: Mtn Top MW Pace Project No.: 92319593 DEFINITIONS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical www.pecolabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Pace Project No.: Mtn Top MW 92319593 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92319593001 MW -01R 92319593002 MW -2 92319593003 MW -3 92319593001 MW -01R SM 6200B 337000 92319593002 MW -2 SM 6200B 337000 92319593003 MW -3 SM 62008 337000 92319593001 MW -01R SM 2540C 337261 92319593002 MW -2 SM 2540C 337261 92319593003 MW -3 SM 2540C 337261 92319593001 MW -01 R SM 9222D 337013 92319593002 MW -2 SM 9222D 337013 92319593003 MW -3 SM 9222D 337013 92319593001 MW -01 R EPA 350.1 1993 Rev 2.0 338750 92319593002 MW -2 EPA 350.1 1993 Rev 2.0 338750 92319593003 MW -3 EPA 350.1 1993 Rev 2.0 338750 92319593001 MW -01 R EPA 353.2 336884 92319593002 MW -2 EPA 353.2 336884 92319593003 MW -3 EPA 353.2 336884 92319593001 MW -01 R EPA 365.1 337075 92319593002 MW -2 EPA 365.1 337075 92319593003 MW -3 EPA 365.1 337075 92319593001 MW -01R SM 4500 -CI -E 337875 92319593002 MW -2 SM 4500 -CI -E 337875 92319593003 MW -3 SM 4500 -CI -E 337877 92319593001 MW -01 R SM 5310B 338727 92319593002 MW -2 SM 5310B 338728 92319593003 MW -3 SM 53108 338728 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 1(2/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC. 0 ceAnalytical ° CHAIN -OF -CUSTODY / Analytical. Request Document The Chain -of -Custody is a LEGAL DOCUMENT. Allrelevant fields must be completed.accurately. "Important Note:,By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid within 30 days. a;,' F-ALL-Q-020reV.07, 15 -May -2007 Page: of Section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Company:/ {tReport To: P% Instructions for completing Chain of Custody (COC) 1. Section A and D: Complete all Client infonnation at top of sheet: company name, address, phone, fax, contact (the person to contact if there are `questions, and who will receive the final report.), e-mail address (if available), PO#, Project Name and/or Project Number as you would like to see it appear on the report. 2. Section C: Invoice hifornation: Billing information is included in this section. This information should include the name and address of the person receiving the invoice. 3. Quote Reference should be completed if a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completed by Pace Analytical Services. 4. Site Location: A separate COC must be filled out for each day of sample collection. Record the two letter postal code for the US state in which the samples were collected. 5. Regulatory Agency: List the program that is guiding the work to ensure proper regulations are followed. 6. Section D: Complete a Sample Description in the "SAMPLE ID' section as you would like it to appear on the laboratory report. The following information should also be included: the sample matrix, sample type (G (grab) or C (composite). When collecting a composite, the start time and end time should be documented in the respective boxes. The collection time for a grab (G) sample should be entered in the boxes marked `Composite End/Grab'), Sample temp at collection (if required by state), the total number of containers, and preservative used. 7. Marls if the sample was filtered in the field by marking Y or N in 'Filtered' row by the Analysis requested 8. Requested Analysis: List the required analysis and methods on the lines provided and place a check in the column for the samples requiring the analysis. Additional comments should be referenced in the bottom left hand comer or include attachments for extended lists of parameters. 9. The sampler should print their name in the space provided and sign their name followed by the date of the sampling event at the bottom of the COC in the spaces designated for `SAMPLER NAME AND SIGNATURE'. 10. When relinquishing custody of the samples to a representative of the laboratory or other organization, indicate the Item Numbers of those samples being transferred; sign relinquished by, date and time, and include your affiliation. *Important Note: Standard Turnaround Time is 2 Weeks/10 business days. Results will be delivered by end of business on the date due unless other arrangements have been made with your project manager. Special Project Requirements such as Low Level Detection Limits or level of QC reported must be included on the chain of custody in the Additional Comments section.