HomeMy WebLinkAboutWQ0028693_Monitoring - 11-2016_20170103r.
UNDWATER QUALITY MONITORING:
PLIANCE REPORT FORM
Name: Mountaintc
Name (if different): Mo
Address: PO Box 14
IGYC Ee'tS'EE'is
Golf & Lake Club
act Person: Bob Barr
Location/Site Name: MW -01R
or
Association Inc
SUBMI r FUKM UN YELLUW FAVLK UNLY
County Jackson
Telephone#: (828) 251-1900
No. of wells to be sampled: 3
RMIT Number: Expiration Date: 7/31/2014
n -Discharge WQ0028693 UIC
IDES Other
PE OF PERMITTED OPERATION BEING MONITORED
❑, Lagoon ❑ Remediation: Infiltration Gallery
® Spray Field ❑ (Remediation:
E Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
WELL ID NUMBER (from Permit): MW -01R
Well Depth: 25.6 ft.
Depth to Water Level: 14 ft. below measuring point
Measuring Point is 0 ft. above land surface
Volume of water pumped/bailed before sampling: -
Samples for metals were collected unfiltered: ❑YES
Date sample collected: 11-14=16
Well Diameter: 2 in.
Screened Interval: 15.6 ft. to 25.6 ft.
Relative M.P. Elevation: ft.
gallons
❑ NO and field acidified: ❑YES El NO
FIELD ANALYSES:
pH 6.4 units Temp. 16.1 °C
Spec. Cond. µMhos
Odor No Odor
Appearance Cloudy
WAS
DRY at
time of
sampling,
check
here: n
LABORATORY INFORMATION
Date sample analyzed: 11/14/16 to 12/2/16
p
Laboratory Name: Pace Analytical Services Inc Certification No. 40 Y��
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
40P
COD mg/I
Nitrite (NO2) as N
mg/I
Pb -Leat9 mg/I JAN a 4. 0111140 41490
Coliform: MF Fecal <4.0 1100ml
Nitrate (NOa) as N
<0.020 mg/I
Zn -Zinc mg/I
Coliform: MF Total 11GOrni
(Note: Use MPN method for highly turbid samples)
Phosphorus: Total as P
Orthophosphate
0.34 mg/i
mg/I
Other (Specify Compounds and r I t%
Dissolved Solids: Total 1CIA mg/l
Al -Aluminum
mg/I
.1
pH (when analyzed) units
Ba - Barium
mg/I
TOC 6.0 mg/i
Ca - Calcium
mg/I
9WR.�
39.8
Chloride mglt
Cd -Cadmium
mg/I
° oiq
INF�I7wnA7pj...�
Arsenic mg/I
Chromium: Total
mg/I
Grease and Oils mg/I
Cu - Copper
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Phenol mg/I
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate mg/I
Hg - Mercury
mg/I
Report Attached? IR Yes (1) ❑ No (0)
Specific Conductance µMhos
K - Potassium
mg/I
VOC method #
Total Ammonia 0.17 mg/t
Mg - Magnesium
mg/I
method #
(Ammonia. Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
_ _ _ , method. #
TKNas N mg/I
Ni - Nickel
mg/I
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Bob Barr, Authorized Agent
Permittee (or Authorized AAent) Name and Title - Please print or type
GW -59 Rev. 1/2007
Effluent..
I that the laboratory analytical data was produced using approved methods of analysis by a
y of fines and imprisonment for knoyn 'oi2tionss,
a
(if Permittee (or Authorized Aqent) •-
SUBMIT FORM ON YELLOW PAPER ONLY
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Bob Barr, Authorized Agent
Permittee (or Authorized Agent) Name and 'Tibe- Please print or type
GW -59 Rev. 1/2007
mg/L Effluent Total VOCs:
(or
mg/L VOC Removal%
3�I f
s •
p ARTiWF3+li £#F`E9i11 31iI�jlFhiT,& N TURA 1 �1URCES s �
ol�ssr�lc �� �P $
GROUNDWATER QUALITY MONITORING:
1tis�o� 01 wAT>~rt of I ITv tNI c �lAh� �l� u�l
COMPLIANCE REPORT FORM
• •
s�sn�l�v�cc+ir�ti ta€t;>s�czsss as „t ti�s3.Tazt
FACILITY INFORMATION Please Print Clearly or Tl
PERMIT Number: Expiration Date: 7/31/2014
Facility Name: Mountaintop Golf & Lake Club
Non -Discharge W00028693 UIC
Permit Name (if different): Mountaintop Community Association Inc
NPDES Other
Facility Address: PO Box 1460
TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC 28717 County Jackson
El Lagoon El Remediation: Infiltration Gallery
®Spray Field ❑ Remediation:
Contact Person: Bob Barr _
Telephone#: (828) 251-1900
❑ Rotary Distributor ❑ Land, Application of Sludge
Well Location/Site Name: MW -2
No. of wells to be sampled: 3
❑ Water Source Heat Pump ❑ Other:
from. Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW -2
Date sample collected: 11-14=16
FIELD ANALYSES:
WAS
Well Depth: 42 ft.
Well Diameter: 2 in.
pH 6.4 units Temp. 13.6 °C
DRY at
Depth to Water Level: 24.03 ft. below measuring point
Screened Interval: 42 ft..
to 32
ft. Spec. Cond. µMhos
time of
sampling,
Measuring Point is 0 ft. above land surface
Relative M.P. Elevation:
ft.
Odor No Odor
check
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
here: ❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: _ ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/14/16 to 12/2/16 _
Laboratory Name: Pace Analytical
Services Inc Certification No. 40
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I'
Nitrite (NO2) as N
mg/I
Pb - Lead mg/I
Coliform: MF Fecal <2.0 /100ml
Nitrate (NO3) as N
2,2 mg/I
Zn —Zinc mg/l
Coliform: MF Total /100ml
Phosphorus: Total as P <0.050 mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Other (Specify Compounds and Concentration Units):.
Dissolved Solids: Total 101 mg/l
Al -Aluminum
mg/I
pH (when analyzed) units
Ba - Barium
mg/I
TOC 1.2 rng/I
Ca - Calcium
mg/I
Chloride 6.8 mg/I
Cd - Cadmium
mg/I
Arsenic mg/I
Chromium: Total
mg/I
Grease and Oils mg/l
Cu - Copper
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Phenol mg/I
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate mg/l
Hg - Mercury
mg/I
Report Attached? 5d Yes (1) ❑ No (0)
Specific Conductance µMhos
K - Potassium
mg/I
VOC „ method #
Total Ammonia <0.10 mg/I
Mg -Magnesium
mg/I
method #
(Ammonia Nitrogen: NH3as N; Ammonia Nitrogen, Total)
Mn -Manganese
mg/I
_ ,method #
TKN as N mg/I
Ni - Nickel
mg/I
, method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Bob Barr, Authorized Agent
Permittee (or Authorized Agent) Name and 'Tibe- Please print or type
GW -59 Rev. 1/2007
mg/L Effluent Total VOCs:
(or
mg/L VOC Removal%
3�I f
SUBMIT FORM ON YELLOW PAPER ONLY
,TER QUALITY MONITORING:
E REPORT FORM
Name: Mountaintop Golf & Lake Club
Name (if different): Mountaintop Community Association Inc
Address PO Box 1460
iers
``"'e NC 28717 County Jackson
act. Person: Bob Barr Telephone#: (828) 251-1900
Location/Site Name: MW -3 No. of wells to be sampled: 3
L ID NUMBER (from Permit):: MW -3
Depth: 160 ft.
h to Water Level: 131.14 ft. below measuring point
wring Point is 0 ft. above land surface
Date sample collected: 11-1446
Well Diameter: 4 in.
Screened Interval: ft.
to
Relative M.P. Elevation: ft.
ne of water pumped/bailed before sampling: gallons
PERMIT Number: Expiration Date:
Non -Discharge W00028693 UIC
?DES Other
'PE OF PERMITTED OPERATION BEING MONITORED
EJ Lagoon El Remediation: Infiltration Gallery
® Spray Field ❑ Remediation:
❑ Rotary Distributor 0 Land Application of Sludge
El Water Source Heat Pump ❑ Other:
If WELL
FIELD ANALYSES: WAS;
pH 6.5 units Temp. 11.8 °C DRY at
ft: Spec. Conti. RMhos time ofsampling,
Odor No Odor check
Appearance Cloudy here:
FT
sample analyzed: 11-14-16 to 12-2-16 Laboratory Name: Pace Analytical Services Inc Certification No. 40
kMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD mgll Nitrite (NO2) as N mg/1 Pb - Lead mg/I
Coliform: MF Fecal' <1.0 /100ml Nitrate (NO3) as N 0,66 mg/1 Zn -Zinc mg/I
Coliform: MF Total /100m1 Phosphorus: Total as P 0.093 mg/I
(Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units):
Dissolved Solids: Total
49.0 mg/1
pH (when analyzed)
units
TOC
<1.0 mg/I
Chloride
4.0 mg/I
Arsenic
mg/I
Grease and Oils
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
µMhos
Total Ammonia
<0.10 mg/I
(Ammonia Nitrogen; NH3as N;. Ammonia Nitrogen; Total)
TKN as 'N mg/i
AI = Aluminum mg/I
Ba - Barium mg/I
Ca - Calcium mg/I
Cd - Cadmium
mg/I
Chromium: Total
mg/1
Cu - Copper
mg/I
Fe - Iron
-mg/1
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/I
Mn - Manganese
_ mg/I
Ni - Nickel
mg/I
ORGANICS: (by GC; GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Report Attached? ® Yes (1) ❑ No (0)
VOC , method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs:
Bob Barr, Authorized Agent
Permittee (or Authorized Agent) Name and Title = Please print or type
GW -59 Rev. 1/2007
, method #
method #
method #
VOC'Removal%
GW -59.A. COMPLIANCE IANCE .t .:EPt).RT FORM Permit # V &.00 2 ?'j 3
(.Subntit one each monitoring period with Gff-59 forms.)
GW -59A 1202003
Enter date monitoring results were due. ) Will this monitoring report (GW -59 and GW -59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW -59 report forms?
YES i
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Officefor guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
O
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES', list in the space provided below, each well with constituent(s) exceeding
standards, concentration (s) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES'; a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW -59A) of the monitoring report should sign below and submit this
form with GW -59 forms for required wells to the address provided at the top of the current GW -59 form.
I hereby acknowledge that the above tnfarmat)on was evaluated and the information,s,ubrnitted in this
repot„(Carnpliande Reporfi, li 19AJ e$ ect nd'csi ”" ileteto t99e laesfi, m .y riotsuledge ,. .
36 (�
Signature of Permittee (or Authorized Agent) bate
GW -59A 1202003
WeAnalytical
wvw.paaelabs.com
December 03, 2016
Mr. Robert Barr
RPB Systems Inc.
P.O. Box 1325
Asheville, NC 28802
RE: Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Dear Mr. Barr:
Enclosed are the analytical results for sample(s) received by the laboratory on November 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
DUAC.", I fai ere -MV _. .
Denise Trantham
denise.trantham @pacelabs.com
Project Manager
Enclosures
cc: Rick Swilling, RPB Systems Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
aceAnalXical
www.pacelabs.com
Rick Swilling
RPB Systems Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Pace Project Number: 92319593
Ar
aceAnalytical "
J www.paceiabs.com
SAMPLE ANALYTE COUNT
Project! Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92319593001
MW -01 R
SM 6200B
CAH
63
PASI-C
SM 2540C
MJSi
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
DMN
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
BRJ
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 5310B
AES2
1
PASI-A
92319593002
MW -2
SM 6200B
CAH
63
PASI-C
SM 2540C
MJSi
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
DMN
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
BRJ
1
PASI-A .
SM 4500 -CI -E
WRC
1
PASI-A
SM 53108
AES2
1
PASI-A
92319593003
MW -3
SM 6200B
CAH
63
PASI-C
SM 2540C
MJS1
1
PASI-A
SM 9222D
KDF1
1
PASI-A
EPA 350.1 1993 Rev 2.0
DMN
1
PASI-A
EPA 353.2
WRC
1
PASI-A
EPA 365.1
BRJ
1
PASI-A
SM 4500 -CI -E
WRC
1
PASI-A
SM 5310B
AES2
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC
11�AceAnaljftal'
www.pacelabs.com
I
Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
�;aoeAnalXical
www.par0gbS.WM
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Mtn Top MW
Pace Project No.: 92319593
Sample: MW -01R Lab ID: 92319593001 Collected: 11/14/1614:00 Received: 11/14/1616:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data Analytical Method
Collected By
Mark
1
11/18/16 09:13
Swann
Collected Date
11/14/2016
1
11/18/16 09:13
Collected Time
14:00
1
11/18/16 09:13
Field pH
6.4
Std. Units
0.10
1
11/18/16 09:13
Field Temperature
16.1
deg C
0.50
1
11/18/16 09:13
Static Water Level
14.00
feet
1
'11/18/16 09:13
Field Specific Conductance
314
umhos/cm
1.0
1
11/18/16 09:13
Total Well Depth
2.5 Gallons
feet
1
11/18/16 09:13
Turbidity
50.93
NTU
1.0
1
11/18/16-09:13
Odor
No odor
1
11/18/16 09:13
Appearance
cloudy
1
11/18/16 09:13
6200B MSV
Analytical Method: SM 6200B
Benzene
ND
ug/L
0.50
1.
11/16/1600:38 71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/16/16 00:38 108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/16/16 00:38 74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/16/16 00:38 75-27-4
Bromoform
ND
ug/L
0.50
1
11/16/16 00:38 75-25-2
Bromomethane
ND
ug/L
5.0
1
11/16/16 00:38 74-83-9
n-Butylbenzene
ND
ug/L
•0.50
1
11/16/16 00:38 104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/16/16 00:38 135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/16/16 00:38 98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/16/16 00:38 56-23-5
- ' Chlorobenzene
" "ND
ug/L
0.50
1
11/16/16 00:38 108-90-7
Chloroethane
ND
ug/L
1.0
1
11/16/16 00:38 75-00-3
Chloroform
ND
ug/L
0.50
1
11/16/16 00:38 67-66-3
Chloromethane
ND
ug/L
1.0
1
11/16/16 00:38 74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/16/16 00:38 95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/16/16 00:38 106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/16/1600:38 96-12-8
Dibromochloromethane
ND
ug/L
0.50.
1
11/16/16 00:38 124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/16/16 00:38 106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/16/16 00:38 74-95-3
1,2 -Dichlorobenzene
ND
ug/L
0.50
1
11/16/16 00:38 95-50-1
1,3 -Dichlorobenzene
ND
ug/L
0.50
1
11/16/16 00:38 541-73-1
1,4 -Dichlorobenzene
ND
ug/L
0.50 ,
1
11/16/16 00:38 106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/16/16 00:38 75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/16/1600:38 75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/16/16 00:38 107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/16/1600:38 75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/16/1600:38 156-59-2
trans- l,2-Dichloroethene
ND
ug/L
0.50
1
11/16/1600:38 156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/16/1600:38 78-87-5
1,3-Dichloropropane
ND
ug/L
0:50
1
11/16/1600:38 142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/16/16 00:38 594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/16/1600:38 563-58-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
/�aceAnalj&alc
www.pamwabs.com
ANALYTICAL RESULTS
Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: MW -01R Lab ID: 92319593001 Collected: 11/14/16 14:00 Received: 11/14/16 16:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
6200B MSV
cis-1,3-Dichloropropene
trans- l,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2 -Tetrachloroethane
1,1,2,2 -Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlo robe nzene
1,2,4-Trichlorobenzene
1,1,1 -Trichloroethane
1,1,2 -Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
113,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o -Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene -d8 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
Date: 12/03/2016 12:09 AM
Analytical Method: SM 6200B
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
2.0
ND
ug/L
0.50
ND
ug/L
2.0
ND
ug/L
0.50
ND
ug/L
2.0
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
0.50'
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
0.50
ND
ug/L
0.50
.ND
ug/L
0.50
ND
ug/L
1.0
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
0.50
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
0.50
91
%
70-130
98
%
70-130
98
%
70-130
Analytical Method: SM 2540C
194 mg/L 25.0
Analytical Method: SM 9222D
ND CFU/100 mL 4.0
Analytical Method: EPA 350.1 1993 Rev 2.0
0.17 mg/L 0.10
Analytical Method: EPA 353.2
ND mg/L 0.020
Analytical Method: EPA 365.1
0.34 mg/L 0.050
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/16/16 00:38 10061-01-5
11/16/16 00:38 10061-02-6
11/16/16 00:38 108-20-3
11/16/16 00:38 100-41-4
11/16/16 00:38 87-68-3
11/16/16 00:38 98-82-8
11/16/16 00:38 75-09-2
11/16/16 00:38 1634-04-4
11/16/16 00:38 91-20-3
11/16/16 00:38 103-65-1
11/16/16 00:38 100-42-5
11/16/16 00:38 630-20-6
11/16/16 00:38 79-34-5
11/16/16 00:38 127-18-4
11/16/16 00:38 108-88-3
11/16/16 00:38 87-61-6
11/16/16 00:38 120-82-1
11/16/1600:38 71-55-6
11/16/16 00:38 79-00-5
11/16/16 00:38 79-01-6
11/16/16 00:38 75-69-4
11/16/16 00:38 96-18-4
11/16/16 00:38 95-63-6
11/16/16 00:38 108-67-8
11/16/16 00:38 75-01-4
11/16/16 00:38 179601-23-1
11/16/16 00:38 95-47-6
11/16/1600:38 17060-07-0
11/16/1600:38 460-00-4
11 /16/16 00:38 2037-26-5
11/16/16 19:49
11/14/16 16:50
12/02/16 15:24 7664-41-7
11/14/16 23:11
11/18/1623:42 7723-14-0
/ 1!1;aceAnalXical'
r wwwAecelabs.com
I�
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Mtn Top MW
Pace Project No.: 92319593
Sample: MW -01R Lab ID: 92319593001 Collected: 11/14/16 14:00 Received: 11/14/16 16:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
4500 Chloride Analytical Method: SM 4500 -CI -E
Chloride 39.8 mg/L 1.0 1 11/21/1622:14 16887-00-6
53108 TOC Analytical Method: SM 531013
Total Organic Carbon 6.0 mg/L 1.0 1 11/30/16 19:12 7440-44-0
Date: 12/03/2016 12:09 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
aceAnaljNpal
{{ www,.p&cW&bs.com
1
Project: Mtn Top MW
Pace Project No.: 92319593
Sample: MW -2
Parameters
Monitoring Well Data
Collected By
Collected Date
Collected Time
Field pH
Field Temperature
Static Water Level
Field Specific Conductance
Total Well Depth
Turbidity
Odor
Appearance
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2 -Dichlorobenzene
1,3 -Dichlorobenzene
1,4 -Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans- 1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
Date: 12/03/2016 1 2:09 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
ANALYTICAL RESULTS
Lab ID: 92319593002
Results Units
Collected: 11/14/16 13:40
Report Limit DF
Received: 11/14/16 16:05 Matrix: Water
Prepared Analyzed CAS No. Qual
Analytical Method:
11/16/1600:55 71-43-2
ND
ug/L
Mark
1
1
11/18/16 09:16
Swann
0.50
1
11/16/16 00:55 74-97-5
11/14/2016
ug/L
1
11/18/16 09:16
14:00
ND
1
11/18/16 09:16
6.4 Std. Units
0.10
1
11/18/16 09:16
13.6 deg C
0.50
1
11/18/16 09:16
24.03 feet
0.50
1
11/18/16 09:16
140 umhos/cm
1.0
1 .
11/18/16 09:16
5.00 feet
ND
1
11/18/16 09:16
gallons
11/16/16 00:55 98-06-6
ND
ug/L
26.39 NTU
1.0
1
11/18/16 09:16
no odor
0.50
1
11/18/16 09:16
clear
ug/L
1
11/18/16 09:16
Analytical Method: SM 6200B
ND
ug/L
0.50
1
11/16/1600:55 71-43-2
ND
ug/L
0.50
1
11/16/16 00:55 108-86-1
ND
ug/L
0.50
1
11/16/16 00:55 74-97-5
ND
ug/L
0.50
1
11/16/16 00:55 75-27-4
ND
ug/L
0.50
1
11/16/16 00:55 75-25-2
ND
ug/L
5.0
1
11/16/16 00:55 74-83-9
ND
ug/L
0.50
1
11/16/16 00:55 104-51-8
ND
ug/L
0.50
1
11/16/16 00:55 135-98-8
ND
ug/L
0.50
1
11/16/16 00:55 98-06-6
ND
ug/L
0.50
1
11/16/16 00:55 56-23-5
ND
ug/L
0.50
1
11/16/16 00:55 108-90-7.
ND
ug/L
1.0
1
11/16/16 00:55 75-00-3
ND
ug/L
0.50
1
11/16/16 00:55 67-66-3
ND
ug/L
1.0
1
11/16/16 00:55 74-87-3
ND
ug/L
0.50
1
11/16/16 00:55 95-49-8
ND
ug/L
0.50
1
11/16/16 00:55 106-43-4
ND
ug/L
1.0
1
11/16/16 00:55 96-12-8
ND
ug/L
0.50
1
11/16/16 00:55 124-48-1
ND
ug/L
0.50
1
11/16/16 00:55 106-93-4
ND
ug/L
0.50
1
11/16/16 00:55 74-95-3
ND
ug/L
0.50
1
11/16/16 00:55 95-50-1
ND
ug/L
0.50
1
11/16/1600:55 541-73-1
ND
ug/L
0.50
1
11/16/16 00:55 106-46-7
ND
ug/L
0.50
1
11/16/16 00:55 75-71-8
ND
ug/L
0.50
1
11/16/16 00:55 75-34-3
ND
ug/L
0.50
1
11/16/16 00:55 107-06-2
ND
ug/L
0.50
1
11/16/16 00:55 75-35-4
ND
ug/L
0.50
1
11/16/16 00:55 156-59-2
ND
ug/L
0.50
1
11/16/16 00:55 156-60-5
ND
ug/L
0.50
1
11/16/16 00:55 78-87-5
ND
ug/L
0.50
1
11/16/16 00:55 142-28-9
ND
ug/L
0.50
1
11/16/16 00:55 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
aceAnalytical
www..pamwabs.com
ANALYTICAL RESULTS
Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: MW -2 Lab ID: 92319593002 Collected: 11/14/16 13:40 Received: 11/14/16 16:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
1,1-Dichloropropene
cis- 1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene.
1,1,1,2 -Tetrachloroethane
1,1,2,2 -Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1 -Trichloroethane
1,1,2 -Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o -Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene -d8 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350A Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2IN03 unpres
Nitrogen, Nitrate
Date: 12/03/2016 1 2:09 AM
Analytical Method: SM 6200B
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
91 %
96 %
100 %
Analytical Method: SM 2540C
101 mg/L
Analytical Method: SM 9222D
ND CFU/100 mL
0.50
1
11/16/16 00:55 563-58-6
0.50
1
11/16/16 00:55 10061-01-5
0.50
1
11/16/16 00:55 10061-02-6
0.50
1
11/16/16 00:55 108-20-3
0.50
1
11/16/16 00:55 100-41-4
2.0
1
11/16/16 00:55 87-68-3
0.50
1
11/16/16 00:55 98-82-8
2.0
1
11/16/16 00:55 75-09-2
0.50
1
11/16/16 00:55 1634-04-4
2.0
1
11/16/16 00:55 91-20-3
0.50
1
11/16/16 00:55 103-65-1
0.50
1
11/16/16 00:55 100-42-5
0.50
1
11/16/16 00:55 630-20-6
0.50
1
11/16/16 00:55 79-34-5
0.50
1
11/16/16 00:55 127-18-4
0.50
1
11/16/16 00:55 108-88-3
2.0
1
11/16/16 00:55 87-61-6
2.0
1
11/16/16 00:55 120-82-1
0.50
1
11/16/16 00:55 71-55-6
0.50
1
11/16/16 00:55 79-00-5
0.50
1
11/16/16 00:55 79-01-6
1.0
1
11/16/16 00:55 75-69-4
0.50
1
11/16/16 00:55 96-18-4
0.50
1
11/16/16 00:55 95-63-6
0.50
1
- 11/16/16 00:55 108-67-8
1.0
1
11/16/16 00:55 75-01-4
1.0
1
11/16/16 00:55 179601-23-1
0.50
1
11/16/16 00:55 95-47-6
70-130 1
70-130 1
70-130 1
25.0 1
2.0 2
Analytical Method: EPA 350.1 1993 Rev 2.0
ND mg/L 0.10 1
Analytical Method: EPA 353.2
2.2 mg/L 0.020 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/16/1600:55 17060-07-0
11/16/1600:55 460-00-4
11/16/1600:55 2037-26-5
11/16/16 19:50
11/14/16 16:50
12/02/16 15:25 7664-41-7
11/14/16 23:10
Pace Analytical Services, LLC
/{ / 2225 Riverside Dr.
aCeAnal ical o Asheville, NC 28804
www.pacelabs.com (828)254-7176
ANALYTICAL RESULTS
Project: Mtn Top MW
Pace Project No.: 92319593
Sample: MW -2
Parameters
Lab ID: 92319593002 Collected: 11/14/16 13:40
Results Units Report Limit DF
Received: 11/14/16 16:05 Matrix: Water
Prepared Analyzed CAS No. Qua[
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
ND mg/L
0.050 1
11/18/1623:43 7723-14-0
4500 Chloride
Analytical Method: SM 4500 -CI -E
Chloride
6.8 mg/L
1.0 1
11/21/1622:15 16887-00-6
5310B TOC
Analytical Method: SM 53108
Total Organic Carbon
1.2 mg/L
1.0 1
11/30/1620:22 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
acoAnalytical
www,pacelabs.com
3
Projects Mtn Top MW
Pace Project No.: 92319593
Sample: MW -3
Parameters
Monitoring Well Data
Collected By
Collected Date
Collected Time
Field pH
Field Temperature
Static Water Level
Field Specific Conductance
Total Well Depth
Turbidity
Odor
Appearance
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
- " Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2 -Dichlorobenzene
1,3 -Dichlorobenzene
1,4 -Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans- l,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2=Dichloropropane
1,1-Dichloropropene
Date: 12/03/2016 12:09 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NO 28804
(828)254-7176
ANALYTICAL RESULTS
Lab ID: 92319593003 Collected: 11/14/1614:10 Received: 11/14/1616:05 Matrix: Water
Results
Units
Analytical Method:
Mark
1
Swann
ug/L
11/14/2016
11/18/16 09:22.
14:40
1
6.5
Std. Units
11.8
deg C
131.14
feet
112
umhos/cm
24 Gallons
feet
46.50
NTU
No Ordor
Cloudy
Analytical Method: SM 6200B
Report Limit DF Prepared Analyzed CAS No. Qual
ND
1
11/18/16 09:22
1
1
11/18/16 09:22
ug/L
1
11/18/16 09:22.
0.10
1
11/18/16 09:22
0.50
1
11/18/16 09:22
ND
1
11/18/16 09:22
1.0
1
11/18/16 09:22
ug/L
1
11/18/16 09:22
1.0
1
11/18/16 09:22
5.0
1
11/18/16 09:22
.ND
1
11/18/16 09:22
ND
ug/L
0.50
1
11/16/16 01:12 71-43-2
ND
ug/L
0.50
1
11/16/16 01:12 108-86-1
ND
ug/L
0.50
1
11/16/16 01:12 74-97-5
ND
ug/L
0.50
1
11/16/16 01:12 75-27-4
ND
ug/L
0.50
1
11/16/16 01:12 75-25-2
ND
ug/L
5.0
1
11/16/16 01:12 74-83-9
.ND
ug/L
0.50
1
11/16/16 01:12 104-51-8
ND
ug/L
0.50
1
11/16/16 01:12 135-98-8
ND
ug/L
0.50
1
11/16/16 01:12 98-06-6
ND
ug/L
0.50
1
11/16/16 01:12 56-23-5
-ND
ug/L
0.50
1
11/16/16 01:12 108-90-7
ND
ug/L
1.0
1
11/16/16 01:12 75-00-3
ND
ug/L
0.50
1
11/16/16 01:12 67-66-3
ND
ug/L
1.0
1
11/16/16 01:12 74-87-3
ND
ug/L
0.50
1
11/16/16 01:12 95-49-8
ND
ug/L
0.50
1
11/16/16 01:12 106-43-4
ND
ug/L
1.0
1
11/16/16 01:12 96-12-8
ND
ug/L
0.50
1
11/16/16 01:12 124-48-1
ND
ug/L
0.50
1
11/16/1601:12 106-93-4
ND
ug/L
0.50
1
11/16/16 01:12 74-95-3
ND
ug/L
0.50
1
11/16/16 01:12 95-50-1
ND
ug/L
0.50
1
11/16/1601:12 541-73-1
ND
ug/L
0.50
1
11/16/16 01:12 106-46-7
ND
ug/L
0.50
1
11/16/1601:12 75-71-8
ND
ug/L
0.50
1
11/16/16 01:12 75-34-3
ND
ug/L
0.50
1
11/16/16 01:12 107-06-2
ND
ug/L
0.50
1.
11/16/16 01:12 75-35-4
ND
ug/L
0.50
1
11/16/16 01:12 156-59-2
ND
ug/L
0.50
1
11/16/16 01:12 156-60-5
ND
ug/L
0.50
1
11/16/16 01:12 78-87-5
ND
ug/L
0.50
1
11/16/16 01:12 142-28-9
ND
ug/L
0.50
1
11/16/16 01:12 594-20-7
ND
ug/L
0.50
1
11/16/16 01:12 563-58-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
aceAnaiyiical`�
f wwwpace1abs.com
i
ANALYTICAL RESULTS
Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: MW -3 Lab ID: 92319593003 Collected: 11/14/16 14:10 Received: 11/14/16 16:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
62008 MSV Analytical Method: SM 6200B
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/16/16 01:12 10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/16/16 01:12 10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/16/16 01:12 108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/16/16 01:12 100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/16/1601:12 87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/16/16 01:12 98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/16/16 01:12 75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/16/16 01:12 1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/16/1601:12 91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/16/16 01:12 103-65-1
Styrene
ND
ug/L
0.50
1
11/16/16 01:12 100-42-5
1,1,1,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/16/16 01:12 630-20-6
1,1,2,2 -Tetrachloroethane
ND
ug/L
0.50
1
11/16/16 01:12 79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/16/16 01:12 127-18-4
Toluene
ND
ug/L
0.50
1
11/16/16 01:12 108-88-3
1,2,3-Trichlorobenzene
ND
ug/L
2.0
1
11/16/1601:12 87-61-6
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
11/16/1601:12 120-82-1
1,1,1 -Trichloroethane
ND
ug/L
0.50
1
11/16/1601:12 71-55-6
1,1,2 -Trichloroethane
ND
ug/L
0.50
1
11/16/1601:12 79-00-5
Trichloroethene
ND
ug/L
0.50
1
11/16/16 01:12 79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
11/16/16 01:12 75-69-4
1,2,3-Trichloropropane
ND
ug/L
0.50
1
11/16/16 01:12 96-18-4
1,2,4-Trimethylbenzene
ND
ug/L
0.50
1
11/16/16 01:12 95-63-6
1,3,5-Trimethylbenzene
ND
ug/L
0.50
1
11/16/1601:12 108-67-8
Vinyl chloride
ND
ug/L
1.0
1
11/16/16 01:12 75-01-4
m&p-Xylene
ND
ug/L
1.0
1
11/16/1601:12 179601-23-1
o -Xylene
ND
ug/L
0.50
1
11/16/16 01:12 95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
90
%
70-130
1
11/16/16 01:12 17060-07-0
4-Bromofluorobenzene (S)
96
%
70-130
1
11/16/16 01:12 460-00-4
Toluene -d8 (S)
99
%
70-130
1
11/16/16 01:12 2037-26-5
2540C Total Dissolved Solids Analytical Method: SM 2540C
Total Dissolved Solids 49.0 mg/L 25.0 1 11/16/16 19:50
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D
Fecal Coliforms ND CFU/100 mL 1.0 1 11/14/16 16:50
350.1 Ammonia Analytical Method: EPA 350.1 1993 Rev 2.0
Nitrogen, Ammonia ND mg/L 0.10 1 12/02/16 15:27 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.66 mg/L 0.020 1 11/14/16 23:13
365.1 Phosphorus, Total Analytical Method: EPA 365.1
Phosphorus 0.093 mg/L 0.050 1 11/18/1623:43 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 1 2:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
/ www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Mtn Top MW
Pace Project No.: 92319593
Sample: MW -3 Lab ID: 92319593003 Collected: 11/14/16 14:10 Received: 11/14/16 16:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500 -CI -E
Chloride 4.0 mg/L 1.0 1 11/21/16 22:22 16887-00-6 M1
5310B TOC Analytical Method: SM 5310B
Total Organic Carbon ND mg/L 1.0 1 11/30/1620:55 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
�IlaceAnaljftal
wwwpacelabs.com
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 337000 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200B MSV
Associated Lab Samples: 92319593001, 92319593002, 92319593003
METHOD BLANK: 1868782 Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter Units Result Limit
Analyzed -
1,1,1,2 -Tetrachloroethane
ug/L
ND
0.50
11/16/16 00:04
1,1,1 -Trichloroethane
ug/L
ND
0.50
11/16/1600:04
1,1,2,2 -Tetrachloroethane
ug/L
ND
0.50
11/16/16 00:04
1,1,2 -Trichloroethane
ug/L
ND
0.50
11/16/1600:04
1,1-Dichloroethane
ug/L
ND
0.50
11/16/1600:04
1,1-Dichloroethene
ug/L
ND
0.50
11/16/1600:04
1,1-Dichloropropene
ug/L
ND
0.50
11/16/1600:04
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/16/16 00:04
1,2,3-Trichloropropane
ug/L
ND
0.50
11/16/16 00:04
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/16/16 00:04
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/16/16 00:04
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/16/16 00:04
1,2-Dibromoethane(EDB)
ug/L
ND
0.50
11/16/1600:04
1,2 -Dichlorobenzene
ug/L
ND
0.50
11/16/16 00:04
1,2-Dichloroethane
ug/L
ND
0.50
11/16/16 00:04
1,2-Dichloropropane
ug/L
ND
0.50
11/16/16 00:04
1,3,5 -Trim ethyl benzene
ug/L
ND
0.50
11/16/16 00:04
1,3 -Dichlorobenzene
ug/L
ND
0.50
11/16/16 00:04
1,3-Dichloropropane
ug/L
ND
0.50
11/16/1600:04
1,4 -Dichlorobenzene
ug/L
ND
0.50
11/16/1600:04
2,2-Dichloropropane
ug/L
ND
0.50
11/16/16 00:04
2-Chlorotoluene
ug/L
ND
0.50
11/16/16 00:04
4-Chlorotoluene
ug/L
ND
0.50
11/16/16 00:04
Benzene
ug/L
ND
0.50
11/16/16 00:04
Bromobenzene
ug/L
ND
0.50
11/16/16 00:04
Bromochloromethane
ug/L
ND
0.50
11/16/16 00:04
Bromodichloromethane
ug/L
ND
0.50
11/16/16 00:04
Bromoform
ug/L
ND
0.50
11/16/16 00:04
Bromomethane
ug/L
ND
5.0
11/16/16 00:04
Carbon tetrachloride
ug/L
ND
0.50
11/16/16 00:04
Chlorobenzene
ug/L
ND
0.50
11/16/16 00:04
Chloroethane
ug/L
ND
1.0
11/16/16 00:04
Chloroform
ug/L
ND
0.50
11/16/16 00:04
Chloromethane
ug/L
ND
1.0
11/16/16 00:04
cis-1,2-Dichloroethene
ug/L
ND
0.50
11/16/1600:04
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/16/1600:04
Dibromochloromethane
ug/L
ND
0.50
11/16/16 00:04
Dibromomethane
ug/L
ND
0.50
11/16/16 00:04
Dichlorodifluoromethane
ug/L
ND
0.50
11/16/16 00:04
Diisopropyl ether
ug/L
ND
0.50
11/16/16 00:04
Ethylbenzene
ug/L
ND
0.50
11/16/16 00:04
Qualifiers
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
/ www..pacelabs.com
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
METHOD BLANK: 1868782 Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter Units Result Limit
Analyzed
Hexachloro-1,3-butadiene
ug/L
ND
2.0
11/16/1600:04
Isopropylbenzene (Cumene)
ug/L
ND
0.50
11/16/16 00:04
m&p-Xylene
ug/L
ND
1.0
11/16/16 00:04
Methyl-tert-butyl ether
ug/L
ND
0.50
11/16/16 00:04
Methylene Chloride
ug/L
ND
2.0
11/16/16 00:04
n-Butylbenzene
ug/L
ND
0.50
11/16/16 00:04 .
n-Propylbenzene
ug/L
ND
0.50
11/16/16 00:04
Naphthalene
ug/L
ND
2.0
11/16/16 00:04
o -Xylene
ug/L
ND
0.50
11/16/16 00:04
sec-Butylbenzene
ug/L
ND
0.50
11/16/16 00:04
Styrene
ug/L
ND
0.50
11/16/16 00:04
tert-Butylbenzene
ug/L
ND
0.50
11/16/16 00:04
Tetrachloroethene
ug/L
ND
0.50
11/16/16 00:04
Toluene
ug/L
ND
0.50
11/16/16 00:04
trans-1,2-Dichloroethene
ug/L
ND
0.50
11/16/1600:04
trans-1,3-Dichloropropene
ug/L
ND
0.50
11/16/1600:04
Trichloroethene
ug/L
ND
0.50
11/16/16 00:04
Trichlorofluoromethane
ug/L
ND
1.0
11/16/16 00:04
Vinyl chloride
ug/L
ND
1.0
11/16/16 00:04
1,2-Dichloroethane-d4 (S)
%
94
70-130
11/16/16 00:04
4-Bromofluorobenzene (S)
%
98
70-130
11/16/16 00:04
Toluene -d8 (S)
%
97
70-130
11/16/16 00:04
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1868783
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2 -Tetrachloroethane
ug/L
50
45.4
91
60-140
1,1,1 -Trichloroethane
ug/L
50
43.6
87
60-140
1,1,2,2 -Tetrachloroethane
ug/L
50
44.2
88
60-140
1,1,2 -Trichloroethane
ug/L
50
43.9
88
60-140
1,1-Dichloroethane
ug/L
50
45.2
90
60-140
1,1-Dichloroethene
ug/L
50
49.3
99
60-140
1,1-Dichloropropene
ug/L
50
44.8
90
60-140
1,2,3-Trichlo robe nzene
ug/L
50
47.8
96
60-140
1,2,3-Trichloropropane
ug/L
50
41.4
83
60-140
1,2,4-Trichlorobenzene
ug/L
50
48.9
98
60-140
1,2,4-Trimethylbenzene
ug/L
50
45.7
91
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
42.4
85
60-140
1,2-Dibromoethane (EDB)
ug/L
50
45.4
91
60-140
1,2 -Dichlorobenzene
ug/L
50
46.7
93
60-140
1,2-Dichloroethane
ug/L
50
38.8
78
60-140
1,2-Dichloropropane
ug/L
50
43.2
86
60-140
1,3,5-Trimethylbenzene
ug/L
50
45.4
91
60-140
1,3 -Dichlorobenzene
ug/L
50
45.8
92
60-140
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
I�XalceAnalXicalo
/ www.pacelabs.com
I
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
LABORATORY CONTROL SAMPLE:
1868783
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
1,3-Dichloropropane
ug/L
50
43.1
86
60-140
1,4 -Dichlorobenzene
ug/L
50
44.7
89
60-140
2,2-Dichloropropane
ug/L
50
43.6
87
60-140
2-Chlorotoluene
ug/L
50
44.6
89
60-140
4-Chlorotoluene
ug/L
50
43.7
87
60-140
Benzene
ug/L
50
47.1
94
60-140
Bromobenzene
ug/L
50
44.2
88
60-140
Bromochloromethane
ug/L
50
46.6
93
60-140
Bromodichloromethane
ug/L
50
44.5
89
60-140
Bromoform
ug/L
50
44.2
88
60-140
Bromomethane
ug/L
50
42.3
85
60-140
Carbon tetrachloride
ug/L
50
46.2
92
60-140
Chlorobenzene
ug/L
50
43.2
86
60-140
Chloroethane
ug/L
50
41.5
83
60-140
Chloroform
ug/L
50
43.4
87
60-140
Chloromethane
ug/L
50
49.1
98
60-140
cis-1,2-Dichloroethene
ug/L
50
44.0
88
60-140
cis-1,3-Dichloropropene
ug/L
50
43.4
87
60-140
Dibromochloromethane
ug/L
50
45.8
92
60-140
Dibromomethane
ug/L
50
43.3
87
60-140
Dichlorodifluoromethane
ug/L
50
43.9
88
60-140
Diisopropyl ether
ug/L
50
49.6
99
60-140
Ethylbenzene
ug/L
50
45.0
90
60-140
Hexachloro-1,3-butadiene
ug/L
50
45.3.
91
60-140
Isopropylbenzene (Cumene)
ug/L
50
45.6
91
60-140
m&p-Xylene
ug/L
100
89.1
89
60-140
Methyl-tert-butyl ether
ug/L
50
48.1
96
60-140
Methylene Chloride
ug/L
50
53.6
107
60-140
n-Butylbenzene
ug/L
50
45.4
91
60-140
n-Propylbenzene
ug/L
50
46.1
92
60-140
Naphthalene
ug/L
50
46.3
93
60-140
o -Xylene
ug/L
50
43.7
87
60-140
sec-Butylbenzene
ug/L
50
45.6
91
60-140
Styrene
ug/L
50
45.2
90
60-140
tert-Butylbenzene
ug/L
50
39.4
79
60-140
Tetrachloroethene
ug/L
50
38.0
76
60-140
Toluene
ug/L
50
44.0
88
60-140
trans-1,2-Dichloroethene
ug/L
50
47.7
95
60-140
trans- l,3-Dich loropropene
ug/L
50
43.3
87
60-140
Trichloroethene
ug/L
50
43.3
87
60-140
Trichlorofluoromethane
ug/L
50
44.1
88
60-140
Vinyl chloride
ug/L
50
41.5
83
60-140
1,2-Dichloroethane-d4 (S)
%
91
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene -d8 (S)
%
98
70-130
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
wwN�pacelabs.ccm
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Mtn Top MW
Pace Project No.: 92319593
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1868784
1868785
MS
MSD
92319593003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,1,1,2 -Tetrachloroethane
ug/L
ND
20
20
19.9
21.2
100
106
60-140
6
1,1,1 -Trichloroethane
ug/L
ND
20
20
21.1
21.4
106
107
60-140
1
1,1,2,2 -Tetrachloroethane
ug/L
ND
20
20
18.7
21.0
94
105
60-140
12
1,1,2 -Trichloroethane
ug/L
ND
20
20
19.4
20.7
97
104
60-140
7
1,1-Dichloroethane
ug/L
ND
20
20
21.1
22.0
105
110
60-140
4
1,1-Dichloroethene
ug/L
ND
20
20
24.4
25.3
122
127
60-140
4
1,1-Dichloropropene
ug/L
ND
20
20
21.9
22.8
109
114
60-140
4
1,2,3-Trichlorobenzene
ug/L
ND
20
20
25.1
26.0
125
130
60-140
4
1,2,3-Trichloropropane
ug/L
ND
20
20
17.5
19.5
88
98
60-140
11
1,2,4-Trichlo robe nzene
ug/L
ND
20
20
23.2
24.3
116
122
60-140
5
1,2,4-Trimethylbenzene
ug/L
ND
20
20
21.1
22.3
105
112
60-140
6
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
18.5
20.9
93
104
60-140
12
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
19.7
21.1
99
106
60-140
7
1,2 -Dichlorobenzene
ug/L
ND
20
20
21.7
23.1
108
116
60-140
6
1,2-Dichloroethane
ug/L
ND
20
20
17.5
18.3
87
91
60-140
4
1,2-Dichloropropane
ug/L
ND
20
20
20.2
20.6
101
103
60-140
2
1,3,5-Trimethylbenzene
ug/L
ND
20
20
21.0
22.7
105
114
60-140
8
1,3 -Dichlorobenzene
ug/L
ND
20
20
21.3
22.5
107
112
60-140
5
1,3-Dichloropropane
ug/L
ND
20
20
18.8
20.2
94
101
60-140
7
1,4 -Dichlorobenzene
ug/L
ND
20
20
20.7
21.6
103
108
60-140
4
2,2-Dichloropropane
ug/L
ND
20
20
20.2
20.4
101
102
60-140
1
2-Chlorotoluene
ug/L
ND
20
20
20.9
22.5
105
113
60-140
7
4-Chlorotoluene
ug/L
ND
20
20
20.4
21.7
102
109
60-140
6
Benzene
ug/L
ND
20
20
21.7
22.7
108
114
60-140
5
Bromobenzene
ug/L
ND
20
20
20.3
21.7
101
108
60-140
-6
Bromochloromethane
ug/L
ND
20
20
20.9
21.6
105
108
60-140
3
Bromodichloromethane
ug/L
ND
20
20
20.0
21.3
100
107
60-140
6
Bromoform
ug/L
ND
20
20
18.1
20.1
91
100
60-140
10
Bromomethane
ug/L
ND
20
20
17.9
18.5
89
92
60-140
3
Carbon tetrachloride
ug/L
ND
20
20
22.6
23.4
113
117
60-140
3
Chlorobenzene
ug/L
ND,
20
20
20.2
21.5
101
107
60-140
6
Chloroethane
ug/L
ND
20
20
18.7
20.6
94
103
60-140
10
Chloroform
ug/L
ND
20
20
19.8
20.7
99
103
60-140
4
Chloromethane
ug/L
ND
20
20
23.4
23.9
115
118
60-140
2
cis- 1,2-Dichloroethene
ug/L
ND
20
20
20.7
21.0
103
105
60-140
1
cis- 1,3-Dichloropropene
ug/L
ND
20
20
19.3
20.4
97
102
60-140
6
Dibromochloromethane
ug/L
ND
20
20
19.9
20.9
100
104
60-140
5
Dibromomethane
ug/L
ND
20
20
19.2
20.6
96
103
60-140
7
Dichlorodifluoromethane
ug/L
ND
20
20
21.0
20.8
105
104
60-140
1
Diisopropyl ether
ug/L
ND
20
20
22.2
23.1
111
116
60-140
4
Ethylbenzene
ug/L
ND
20
20
21.1
22.3
105
111
60-140
6
Hexachloro-1,3-butadiene
ug/L
ND
20
20
23.7
25.5
119
127
60-140
7
Isopropylbenzene (Cumene)
ug/L
ND
20
20
21.1
22.7
106
114
60-140
7
m&p-Xylene
ug/L
ND
40
40
41.0
44.0
103
110
60-140
7
Methyl-tert-butyl ether
ug/L
ND
20
20
20.7
21.8
104
109
60-140
5
Methylene Chloride
ug/L
ND
20
20
21.2
22.8
106
114
60-140
7
Results presented on this page are in the
units indicated by the "Units"
column except where an alternate
unit is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
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I
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1868784
MSD
Result
MS
% Rec
MSD
% Rec
MS
RPD
92319593003
Spike
Parameter
Units Result
116
Conc.
n-Butylbenzene
ug/L
ND
20
n-Propylbenzene
ug/L
ND
20
Naphthalene
ug/L
ND
20
o -Xylene
ug/L
ND
20
sec-Butylbenzene
ug/L
ND
20
Styrene
ug/L
ND
20
tert-Butylbenzene
ug/L
ND
20
Tetrachloroethene
ug/L
ND
20
Toluene
ug/L
ND
20
trans-1,2-Dichloroethene
ug/L
ND
20
trans- 1,3-Dich loropropene
ug/L
ND
20
Trichloroethene
ug/L
ND
20
Trichlorofluoromethane
ug/L
ND
20
Vinyl chloride
ug/L
ND
20
1,2-Dichloroethane-d4 (S)
%
22.6
23.2
4-Bromofluorobenzene (S)
%
60-140
2
Toluene -d8 (S)
%
19.4
96
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
MSD
Spike
Conc.
1868785
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
20
22.0
23.2
110
116
60-140
5
20
22.0
23.3
110
117
60-140
6
20
23.2
23.6
116
118
60-140
2
20
19.9
21.4
99
107
60-140
7
20
22.1
23.5
111
118
60-140
6
20
19.9
21.8
100
109
60-140
9
20
18.8
20.0
94
100
60-140
7
20
18.5
18.9
92
94
60-140
2
20
20.5
21.2
103
106
60-140
3
20
22.6
23.2
113
116
60-140
2
20
19.1
19.4
96
97
60-140
2
20
20.5
21.3
103
107
60-140
4
20
22.5
23.1
112
115
60-140
3
20
20.2
20.8
101
104
60-140
3
90
93
70-130
97
100
70-130
98
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
Qua[
Ka0
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J
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 337261
Analysis Method: SM 2540C
QC Batch Method: SM 2540C
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92319593001, 92319593002, 92319593003
METHOD BLANK: 1870419
Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers .
Total Dissolved Solids
mg/L
ND 25.0 11/16/16 19:48
LABORATORY CONTROL SAMPLE:
1870420
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 234 94 90-110
SAMPLE DUPLICATE: 1870421
92319593001 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
194 192 1
SAMPLE DUPLICATE: 1870422
92319606007 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalXical
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QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 337013 Analysis Method:
QC Batch Method: SM 9222D Analysis Description:
Associated Lab Samples: 92319593001, 92319593002, 92319593003
METHOD BLANK: 1868875 Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 11/14/16 16:50
SM 9222D
9222D MBIO Fecal Coliform - AVL
SAMPLE DUPLICATE: 1868876
92319593002
Parameter Units Result
Fecal Coliforms CFU/100 mL ND
Dup
Result RPD Qualifiers
ND
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 338750
Analysis Method: EPA 350.1 1993 Rev 2.0
QC Batch Method: EPA 350.1 1993 Rev 2.0
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92319593001, 92319593002, 92319593003
METHOD BLANK: 1878245
Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L
ND 0.10
12/02/16 14:51
LABORATORY CONTROL SAMPLE: 1878246
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
5 5.0
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878247 1878248
MS MSD
92320294001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 5.4
5 5 10.3
10.2 97 96
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878249 1878250
MS MSD
92320310001
Spike Spike MS
MSD MS. MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L ND
5 5 5.0
5.0 99 98
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
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1
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 336884 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92319593001, 92319593002, 92319593003
METHOD BLANK: 1868107 Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.020 11/14/16 22:54
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE: 1868108
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 2.5 2.5 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1868109 1868110
MS MSD
92319559002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 18.2 2.5 2.5 21.4 21.9 130 152 90-110 3 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnalytical
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t
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 337075 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92319593001, 92319593002, 92319593003
METHOD BLANK: 1869261 Matrix: Water
Associated Lab Samples: 92319593001, 92319593002, 92319593003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/18/16 23:22
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville; NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE: 1869262
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869263 1869264
MS MSD
92319574001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 1.2 2.5 2.5 3.7 3.7 99 100 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1869265 1869266
MS MSD
92319749002 Spike Spike MS MSD MS MSD ' % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua]
Phosphorus mg/L ND 2.5 2.5 2.5 2.5 100 100 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
owl
117PaceAnalytical Q0
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QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QC Batch: 337875
Analysis Method: SM 4500 -CI -E
QC Batch Method: SM 4500 -CI -E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92319593001, 92319593002
METHOD BLANK: 1873963
Matrix: Water
Associated Lab Samples: 92319593001, 92319593002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
11/21/1621:44
LABORATORY CONTROL SAMPLE: 1873964
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Chloride mg/L
20
20.8
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873965
1873966
MS
MSD
92319352011
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Chloride mg/L 63.0
10
10 69.0
69.0 60 60
90-110
0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873967
1873968
MS
MSD
92319868003
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Chloride mg/L 3.4
10
10 13.6
13.6 102 102
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
• This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
11�aceAnalytical"
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/
i
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 337877 Analysis Method: SM 4500 -CI -E
QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride
Associated Lab Samples: 92319593003
METHOD BLANK: 1873973 Matrix: Water
Associated Lab Samples: 92319593003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 11/21/16 22:16
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE: 1873974
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.7 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873975 1873976
MS MSD
92319593003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 4.0 10 10 15.0 15.1 110 111 90-110 0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1873977 1873978
MS MSD
92319646001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 112 10 10 128 128 166 160 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
Ar A
aceAnalytical
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i
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QC Batch: 338727
Analysis Method: SM 5310B
QC Batch Method: SM 5310B
Analysis Description: 5310B TOC
Associated Lab Samples: 92319593001
METHOD BLANK: 1878104
Matrix: Water
Associated Lab Samples: 92319593001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Total Organic Carbon mg/L
ND 1.0
11/30/16 13:01
LABORATORY CONTROL SAMPLE: 1878105
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Total Organic Carbon mg/L
25 25.0
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878106 1878107
MS MSD
92320237029
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qua]
Total Organic Carbon mg/L ND
25 25 23.6
23.9 94 95 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878108 1878109
MS MSD
92320237039 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.7 24.6 99 98 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
• This report shall not be reproduced, except in full,
Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
71ceac,Analytical
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I `
QUALITY CONTROL DATA
Project: Mtn Top MW
Pace Project No.: 92319593
QC Batch: 338728 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: 5310B TOC
Associated Lab Samples: 92319593002, 92319593003
METHOD BLANK: 1878120 Matrix: Water
Associated Lab Samples: 92319593002, 92319593003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/30/16 19:33
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE: 1878121
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 25.6 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878122 1878123
MS MSD
92319593002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 1.2 25 25 25.9 25.4 99 97 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1878124 1878125
MS MSD
92320391009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.6 24.3 98 97 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
aceAnaIXical
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QUALIFIERS
Project: Mtn Top MW
Pace Project No.: 92319593
DEFINITIONS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
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Date: 12/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project:
Pace Project No.:
Mtn Top MW
92319593
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92319593001
MW -01R
92319593002
MW -2
92319593003
MW -3
92319593001
MW -01R
SM 6200B
337000
92319593002
MW -2
SM 6200B
337000
92319593003
MW -3
SM 62008
337000
92319593001
MW -01R
SM 2540C
337261
92319593002
MW -2
SM 2540C
337261
92319593003
MW -3
SM 2540C
337261
92319593001
MW -01 R
SM 9222D
337013
92319593002
MW -2
SM 9222D
337013
92319593003
MW -3
SM 9222D
337013
92319593001
MW -01 R
EPA 350.1 1993 Rev 2.0
338750
92319593002
MW -2
EPA 350.1 1993 Rev 2.0
338750
92319593003
MW -3
EPA 350.1 1993 Rev 2.0
338750
92319593001
MW -01 R
EPA 353.2
336884
92319593002
MW -2
EPA 353.2
336884
92319593003
MW -3
EPA 353.2
336884
92319593001
MW -01 R
EPA 365.1
337075
92319593002
MW -2
EPA 365.1
337075
92319593003
MW -3
EPA 365.1
337075
92319593001
MW -01R
SM 4500 -CI -E
337875
92319593002
MW -2
SM 4500 -CI -E
337875
92319593003
MW -3
SM 4500 -CI -E
337877
92319593001
MW -01 R
SM 5310B
338727
92319593002
MW -2
SM 5310B
338728
92319593003
MW -3
SM 53108
338728
REPORT OF LABORATORY ANALYSIS
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Date: 1(2/03/2016 12:09 AM without the written consent of Pace Analytical Services, LLC.
0
ceAnalytical °
CHAIN -OF -CUSTODY / Analytical. Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. Allrelevant fields must be completed.accurately.
"Important Note:,By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid within 30 days. a;,' F-ALL-Q-020reV.07, 15 -May -2007
Page: of
Section A Section B Section C
Required Client Information: Required Project Information: Invoice Information:
Company:/ {tReport To: P%
Instructions for completing Chain of Custody (COC)
1. Section A and D: Complete all Client infonnation at top of sheet: company name, address, phone, fax, contact (the person to contact if there are
`questions, and who will receive the final report.), e-mail address (if available), PO#, Project Name and/or Project Number as you would like to see it
appear on the report.
2. Section C: Invoice hifornation: Billing information is included in this section. This information should include the name and address of the person
receiving the invoice.
3. Quote Reference should be completed if a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completed by
Pace Analytical Services.
4. Site Location: A separate COC must be filled out for each day of sample collection. Record the two letter postal code for the US state in which the
samples were collected.
5. Regulatory Agency: List the program that is guiding the work to ensure proper regulations are followed.
6. Section D: Complete a Sample Description in the "SAMPLE ID' section as you would like it to appear on the laboratory report. The following
information should also be included: the sample matrix, sample type (G (grab) or C (composite). When collecting a composite, the start time and end
time should be documented in the respective boxes. The collection time for a grab (G) sample should be entered in the boxes marked `Composite
End/Grab'), Sample temp at collection (if required by state), the total number of containers, and preservative used.
7. Marls if the sample was filtered in the field by marking Y or N in 'Filtered' row by the Analysis requested
8. Requested Analysis: List the required analysis and methods on the lines provided and place a check in the column for the samples requiring the
analysis. Additional comments should be referenced in the bottom left hand comer or include attachments for extended lists of parameters.
9. The sampler should print their name in the space provided and sign their name followed by the date of the sampling event at the bottom of the COC in
the spaces designated for `SAMPLER NAME AND SIGNATURE'.
10. When relinquishing custody of the samples to a representative of the laboratory or other organization, indicate the Item Numbers of those samples
being transferred; sign relinquished by, date and time, and include your affiliation.
*Important Note:
Standard Turnaround Time is 2 Weeks/10 business days. Results will be delivered by end of business on the date due unless other arrangements
have been made with your project manager.
Special Project Requirements such as Low Level Detection Limits or level of QC reported must be included on the chain of custody in the Additional
Comments section.