NC0001422_App A Analytical Data_20160201

WELL ABANDONMENT RECORD
This form can he used for single or multiple wells
I. Well Contractor Information:
-j 1gocS Nq// ,..if,
Well Cantracmr Nam, (or well owner pets ... Ily abandoning well on his/Imr property)
3.�2y,4-
NC Well Contractor Cendi.mion Number
For hucasi l Use ONLY:
WELL ABANDONMENT DETAILS
71. Number of wells being abandoned: /
For mull/plc im"I on or non-uvler supple' wells ONLY h,oh the same
mrruraedoNnbandornneru, Vmr mnsubmiI caejrm.
7b. Approximate volume of water remaining in well(s):
Cascade Drilling, LP FOR WATER SUPPLY WELLS ONLY:
Company Name lc. Type of disinfectant used:
2. Well Construction Permit 9:
Livall applicable,em/ permits (r.e. Camay, Slate, t a.....c" bJectien, etc.J orAmmrm
7d. Amount of disinfectant used:
3. Well use (check well use):
ElAgriculmral
OGeolhennal (Heating/Cooling Supply)
Olndustrial/Commercial
OAquifer Recharge
OAquifer Storage and Recovery
OAquifer Test
OExperimental Technology
OGeothermal (Closed Loop)
❑Geothermal (Heating/Coaling
OMunicipal/Public
❑Residential Water Supply (single)
DResidential Water Supply (shared)
OGroundwi ter Remediation
CSaliniiy Barrier
❑Smrmwater Drainage
❑Subsidence Control
OTracer
❑Other (explain under
J. Dale well(s) abandoned: /0 rdD r/5'
So. Well location:
Duke Energy Progress
Facility/Owner Name
Facility fife (ifopplie.ble)
801 Sutton Steam Plant Road, Wilmington, NC 28401
Physical Address, City, and Zip
New Hanover County
County Parcel identification No. (PIN)
Sb. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(ifwell field, one Imt/I ng is sufficient)
CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED
Auach .roll cmsslrudimr recarJ(sJ if arailuble. Far nm/tip/e injection or nor-mnur suppfj•
ire//s ONLY a fth the same coiuul=l im✓bmrdannmrrl, you can subunit are j -oL
6a. Well IDq:amD
,�/�l'V1 — 0.1 b
/t
/
6b. Total well depth: //0 (ft.)
6c. Borehole diameter: (in.)
6d. Water level below ground surface: (ft.)
7e. Sealing materials used (check all that apply):
❑ Neat Cement Grout ❑ Benlonile Chips or Pellets
❑ Sand Cement Grout
❑ Dry Clay
❑ Concrete Grout
❑ Drill Cuttings
❑ Specialty Grout
❑ Gravel
Aentonite Slurry
❑ Other (explain under 7g)
IT. For each material selected above, provide amount of materials used:
c;1)
f
7g. Provide a brief description of the abandonment procedure:
tl. Cerercat-pn:
Siermt ono for r Well Owner Date
By signing this form, I hereby certify that the well(s) was (here) abandoned in
accordance with 15A NGIC 02C .0100 or 2C .0200 Well Construction Smadards
and that a copy of this record has been provided io lite well owner.
9. Site diagram or additional well details:
You may use the back of flux page to provide additional well site details or well
abandonment details. You may also attach additional pages if necessary.
His. Far All Wells: Submit this form within 30 days of completion of well
abandonment to die following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
10b. For Infection Wells: In addition to sending the form to die address in 10a
above, also submit one copy of this form within 30 days of completion of well
abandonment to die following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
6e. Outer casing length (if known): ((t.) SOc. For Water Sunniv & Infection Wells: In addition to sending the form to
the addresses) above, also submit one copy of this farm within 30 days of
completion of well abandonment to the county health department of the county
6L Inner casing/tubing length (if brown): (fL) where abandoned.
6g. Screen length (if known): (R)
Farm GW-30 North Coolim Depalmcia of Enviraamenl and Nmurd Resources- Division of Water Resoaaes Revised August 2013

WELL ABANDONMENT RECORD
This form can be used for single or multiple wells
1. Well Contractor Information:
Well Criterion., N... ((t r well owner personally abmdoainl; well on hisA¢r property)
3o(A! /%
NC Wdl Coaaactar Cenifiwtian Number
For hncrnal Us. ONLY:
WELL ABANDONMENT DETAILS /
7a. Number of wells being abandoned: I
Far rorInInk nrj,Mro or non -outer soppir ,rdls ONLY with the soar.
eomsmmnoo,obondoumens, You con suhm.I onef rat.
7b. Approximate volume of water remaining in weli(s): (gal.)
Cascade Drilling, LP FOR WATER SUPPLY WELLS ONLY
Cowpony Name 7c. Type of disinfectant used:
2. Well Construction Permit 4:
l ist nl1 applicnhle rrelf pearl[, (i. e. Cnunp, State, Varim¢x•, Injediun, etc.) fknmrn 7d. Amount of disinfectant used:
3. Well use (check well use):
OAgricullural
OGeolhemad (Heating/Cooting Supply)
❑ Industrial/Commercial
OAquilcr Recharge
OAquifer Storage and Recovery
OAquifer Test
OExperimental Technology
❑Geotheroal(Closed Loop)
❑Geothermal (Ideating/Cooling
OMunicipal/Public
OResidential Water Supply (single)
OResidential Water Supply (shared)
❑Groundwater Remediation
❑Salinity Barrier
❑Sto rnwater Drainage
❑Subsidence Control
OTmcer
COther(explain under
4. Date well(s) abandoned: M AIC
5a. Well location
Duke Energy Progress
Facility/Owner Nan,e Facility IDU (if applicable)
801 Sutton Steam Plant Road, Wilmington, NC 28401
Physical Address, City, and Zip
New Hanover County
County
Parcel Identification No. (PIN)
5b. Latitude and longitude in degreestminutes/seconds or decimal degrees:
(ifwell Geld, one loulong is suB3cicia)
W
CONSTRUCTION DETAILS OF WELL(S) BEING ABANDONED
Antioch well canrtructinn remnift) if aruilub1,r Far multiple inwarmr nr nun-,eahm supply
wills ONLYuin, the scone�rioeavud�iorrt ah�nnyrlonmenn, you can suhrnit one faun
6a. WcII lDq: , A fr/ W' (I1
6b. Total well depth: —3-5_(B.)
6c. Borehole diameter: (in.)
6d. Winer level below ground surface:
7c. Scaling materials used (check all that apply)
❑ Neal Cement Grout
❑ Bentonite Chips or Pellets
❑ Sand Cement Grout
0 Dry Clay
❑ Concrete Grout
❑ Drill Cuttings
❑ Specially Grout
❑ Gravel
rBemmnite Slurry
❑ Other (explain under 7g)
I. For each material selected above, provide amount of materials used:
D® ggl5
r
7g. Provide:, brief description of the abandonment procedure:
S. Certification:
Signora. face' .naac rot Vell Owner Dare
By signing this form, I hereby cerlijj, that the ivell(s) was (mere) abandoned in
accordance with 15A NCAC 02C.0100 or 2C.0200 Well Consawchan Smndards
and that a copy offlus record has been provided to the well owner.
9. Site diagram or additional well details:
You may use the back of this page to provide additional well site details or well
abandonment details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
10a. Far All Wells: Submit this form within 30 days of completion of well
abandonment to die following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
10h. Far Inieclion Wells: In addition to sending die form to die address in IDo
above, also submit one copy of this form within 30 days of completion of well
abandonment to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
10e. For Water Supply 3e Imeclion Wells: In addition to sending the form to
6e. Outer casing length (if known); (fL the address(es) above, also submit one copy of this form within 30 days of
completion of well abandonment to the county health department of the county
6f. Inner casing/tubing length (iflmmvn): (ft.) where abandoned.
6g. Screen length (if [mown): Ift.)
Form OW-30 North Carolina Depanmerl ofEnvironmenl and Natural Resources- Division of Water Res.nrcrs Revised August 2013

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15120102
Project Name:SUTTON - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:12/18/2015
Customer Address:
Customer Name(s):Perry Waldrep, Tim Hunsucker,Brandon Russo, Kathy Webb, John Toepfer
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
1 of 157
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015037888 Sutton 03-Dec-15 11:36 AM ILLEGIBLE AW-5B
2015037889 Sutton 03-Dec-15 12:52 PM ILLEGIBLE AW-5C
2015037890 Sutton 03-Dec-15 3:45 PM ILLEGIBLE AW-5D
2015037891 Sutton 03-Dec-15 12:00 PM ILLEGIBLE SMW-01C
2015037892 Sutton 03-Dec-15 11:50 AM ILLEGIBLE SMW-1B
2015037893 Sutton 03-Dec-15 2:20 PM ILLEGIBLE SMW-2B
2015037894 Sutton 03-Dec-15 2:20 PM ILLEGIBLE SMW-2C
2015037895 Sutton 03-Dec-15 3:01 PM ILLEGIBLE AW-8B
2015037896 Sutton 03-Dec-15 3:55 PM ILLEGIBLE AW-08C
2015037897 Sutton 03-Dec-15 12:48 PM ILLEGIBLE AW-06D
2015037898 Sutton 03-Dec-15 1:24 PM ILLEGIBLE AW-06E
2015037899 Sutton 03-Dec-15 11:17 AM ILLEGIBLE AW-06B
2015037900 Sutton 03-Dec-15 11:25 AM ILLEGIBLE AW-09D
2015037901 Sutton 03-Dec-15 11:57 AM ILLEGIBLE AW-09C
2015037902 Sutton 03-Dec-15 5:00 PM ILLEGIBLE Filter Blank
2015037903 Sutton 03-Dec-15 5:00 PM ILLEGIBLE Equipment Blank
2015037904 Sutton 03-Dec-15 1:05 PM ILLEGIBLE AW-9B
2015037905 Sutton 03-Dec-15 4:05 PM ILLEGIBLE MW-37B
2015037906 Sutton 03-Dec-15 3:10 PM ILLEGIBLE MW-37C
2015037907 Sutton 03-Dec-15 11:57 AM ILLEGIBLE AW-09C DUP
20 Total Samples
2 of 157
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:12/11/2015
Electronic Data Deliverable (EDD) Sent Separately
3 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037888
Collection Date:03-Dec-15 11:36 AM
Site:AW-5B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.325 mg-N/L EPA 353.2 12/08/2015 16:00M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.1 mg/L EPA 300.0 12/05/2015 22:29 BGN90340.1 1
Sulfate 32 mg/L EPA 300.0 12/05/2015 22:29 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:10 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 10:54 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.113 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.005 1
Barium (Ba)0.065 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.05 1
Iron (Fe)0.607 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.01 1
Manganese (Mn)0.157 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.005 1
Strontium (Sr)0.030 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 11:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.80 mg/L EPA 200.7 12/09/2015 15:00 FCJORDA0.01 1
Magnesium (Mg)0.145 mg/L EPA 200.7 12/09/2015 15:00 FCJORDA0.005 1
Potassium (K)1.84 mg/L EPA 200.7 12/09/2015 15:00 FCJORDA0.1 1
Sodium (Na)1.33 mg/L EPA 200.7 12/09/2015 15:00 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.162 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.005 1
Barium (Ba)0.070 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.05 1
Iron (Fe)0.907 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.01 1
Manganese (Mn)0.165 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.005 1
Strontium (Sr)0.032 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/09/2015 11:09 MHH71310.005 1
4 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037888
Collection Date:03-Dec-15 11:36 AM
Site:AW-5B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Cobalt (Co)1.65 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Nickel (Ni)4.67 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:12 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:12 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 17:12 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Cobalt (Co)1.93 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Nickel (Ni)5.23 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 13:25 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 13:25 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 13:25 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 57 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.504 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
5 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037888
Collection Date:03-Dec-15 11:36 AM
Site:AW-5B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
6 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037889
Collection Date:03-Dec-15 12:52 PM
Site:AW-5C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.472 mg-N/L EPA 353.2 12/08/2015 16:04 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.4 mg/L EPA 300.0 12/05/2015 22:47 BGN90340.1 1
Sulfate 15 mg/L EPA 300.0 12/05/2015 22:47 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:13 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:01 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.102 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.005 1
Barium (Ba)0.025 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.01 1
Manganese (Mn)0.017 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.005 1
Strontium (Sr)0.035 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 12/08/2015 11:19 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.64 mg/L EPA 200.7 12/09/2015 15:03 FCJORDA0.01 1
Magnesium (Mg)0.500 mg/L EPA 200.7 12/09/2015 15:03 FCJORDA0.005 1
Potassium (K)0.881 mg/L EPA 200.7 12/09/2015 15:03 FCJORDA0.1 1
Sodium (Na)2.11 mg/L EPA 200.7 12/09/2015 15:03 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.148 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.005 1
Barium (Ba)0.026 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.05 1
Iron (Fe)0.051 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.01 1
Manganese (Mn)0.017 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.005 1
Strontium (Sr)0.034 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 11:21 MHH71310.005 1
7 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037889
Collection Date:03-Dec-15 12:52 PM
Site:AW-5C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Copper (Cu)9.74 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:33 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 17:33 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 13:46 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 13:46 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 13:46 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.554 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
8 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037889
Collection Date:03-Dec-15 12:52 PM
Site:AW-5C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
9 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037890
Collection Date:03-Dec-15 3:45 PM
Site:AW-5D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:05 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 85 mg/L EPA 300.0 12/05/2015 20:23 BGN9034110
Sulfate 22 mg/L EPA 300.0 12/05/2015 20:23 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 07:57 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:03 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.005 1
Barium (Ba)0.008 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.005 1
Boron (B)0.279 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.05 1
Iron (Fe)0.018 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.01 1
Manganese (Mn)0.029 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.005 1
Strontium (Sr)0.087 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 11:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)13.0 mg/L EPA 200.7 12/09/2015 15:15 FCJORDA0.01 1
Magnesium (Mg)5.21 mg/L EPA 200.7 12/09/2015 15:15 FCJORDA0.005 1
Potassium (K)8.79 mg/L EPA 200.7 12/09/2015 15:15 FCJORDA0.1 1
Sodium (Na)90.8 mg/L EPA 200.7 12/09/2015 15:15 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.226 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.005 1
Barium (Ba)0.008 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.005 1
Boron (B)0.269 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.05 1
Iron (Fe)0.380 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.01 1
Manganese (Mn)0.030 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 11:25 MHH71310.005 1
10 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037890
Collection Date:03-Dec-15 3:45 PM
Site:AW-5D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Arsenic (As)1.50 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Molybdenum (Mo)39.7 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:40 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 17:40 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Arsenic (As)1.44 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Chromium (Cr)2.38 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Molybdenum (Mo)42.8 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 13:51 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 13:51 MHALL30.2 1
Vanadium (V) Low Level 0.893 ug/L EPA 200.8 12/09/2015 13:51 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 290 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 1.8 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
11 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037890
Collection Date:03-Dec-15 3:45 PM
Site:AW-5D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
12 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037891
Collection Date:03-Dec-15 12:00 PM
Site:SMW-01C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:06 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 55 mg/L EPA 300.0 12/05/2015 23:04 BGN9034110
Sulfate 140 mg/L EPA 300.0 12/05/2015 23:04 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:15 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:05 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.131 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.005 1
Barium (Ba)0.030 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.005 1
Boron (B)0.720 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.05 1
Iron (Fe)0.518 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.01 1
Manganese (Mn)0.767 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.005 1
Strontium (Sr)0.426 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 12/08/2015 11:34 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)33.1 mg/L EPA 200.7 12/09/2015 15:19 FCJORDA0.01 1
Magnesium (Mg)7.28 mg/L EPA 200.7 12/09/2015 15:19 FCJORDA0.005 1
Potassium (K)5.04 mg/L EPA 200.7 12/09/2015 15:19 FCJORDA0.1 1
Sodium (Na)38.4 mg/L EPA 200.7 12/09/2015 15:19 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.183 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.005 1
Barium (Ba)0.028 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.005 1
Boron (B)0.674 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.05 1
Iron (Fe)0.532 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.01 1
Manganese (Mn)0.705 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.005 1
Strontium (Sr)0.400 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 12/09/2015 11:30 MHH71310.005 1
13 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037891
Collection Date:03-Dec-15 12:00 PM
Site:SMW-01C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)7.36 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Cobalt (Co)2.16 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:47 MHALL30.2 1
Vanadium (V) Low Level 0.941 ug/L EPA 200.8 12/08/2015 17:47 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Cobalt (Co)2.51 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Nickel (Ni)1.01 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 13:57 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 13:57 MHALL30.2 1
Vanadium (V) Low Level 1.26 ug/L EPA 200.8 12/09/2015 13:57 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.426 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
14 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037891
Collection Date:03-Dec-15 12:00 PM
Site:SMW-01C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
15 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037892
Collection Date:03-Dec-15 11:50 AM
Site:SMW-1B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.962 mg-N/L EPA 353.2 12/08/2015 16:07 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 12/05/2015 20:59 BGN9034110
Sulfate 44 mg/L EPA 300.0 12/05/2015 20:59 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/06/2015 12:08 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:08 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.005 1
Barium (Ba)0.030 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.005 1
Boron (B)0.147 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.005 1
Strontium (Sr)0.079 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.005 1
Zinc (Zn)0.036 mg/L EPA 200.7 12/08/2015 11:38 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)21.5 mg/L EPA 200.7 12/09/2015 15:22 FCJORDA0.01 1
Magnesium (Mg)1.28 mg/L EPA 200.7 12/09/2015 15:22 FCJORDA0.005 1
Potassium (K)2.04 mg/L EPA 200.7 12/09/2015 15:22 FCJORDA0.1 1
Sodium (Na)8.89 mg/L EPA 200.7 12/09/2015 15:22 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.062 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.005 1
Barium (Ba)0.033 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.005 1
Boron (B)0.141 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.05 1
Iron (Fe)0.041 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.005 1
Strontium (Sr)0.074 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.005 1
Zinc (Zn)0.037 mg/L EPA 200.7 12/09/2015 11:34 MHH71310.005 1
16 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037892
Collection Date:03-Dec-15 11:50 AM
Site:SMW-1B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 17:54 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 17:54 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 17:54 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:04 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 14:04 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 95 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 1.5 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
17 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037892
Collection Date:03-Dec-15 11:50 AM
Site:SMW-1B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
18 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037893
Collection Date:03-Dec-15 2:20 PM
Site:SMW-2B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:09 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 300.0 12/07/2015 09:11 BGN90340.1 1
Sulfate 19 mg/L EPA 300.0 12/07/2015 09:11 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 07:59 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:10 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.031 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.05 1
Iron (Fe)7.09 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.01 1
Manganese (Mn)0.101 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.005 1
Strontium (Sr)0.056 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 11:41 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)30.1 mg/L EPA 200.7 12/09/2015 15:35 FCJORDA0.01 1
Magnesium (Mg)1.04 mg/L EPA 200.7 12/09/2015 15:35 FCJORDA0.005 1
Potassium (K)1.16 mg/L EPA 200.7 12/09/2015 15:35 FCJORDA0.1 1
Sodium (Na)7.19 mg/L EPA 200.7 12/09/2015 15:35 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.045 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.005 1
Barium (Ba)0.019 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.05 1
Iron (Fe)5.99 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.01 1
Manganese (Mn)0.085 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.005 1
Strontium (Sr)0.055 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 11:38 MHH71310.005 1
19 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037893
Collection Date:03-Dec-15 2:20 PM
Site:SMW-2B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Chromium (Cr)3.66 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Molybdenum (Mo)1.19 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 18:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 18:01 MHALL30.2 1
Vanadium (V) Low Level 1.97 ug/L EPA 200.8 12/08/2015 18:01 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Chromium (Cr)3.96 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Molybdenum (Mo)2.58 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:12 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:12 MHALL30.2 1
Vanadium (V) Low Level 2.25 ug/L EPA 200.8 12/09/2015 14:12 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 8.9 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
20 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037893
Collection Date:03-Dec-15 2:20 PM
Site:SMW-2B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
21 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037894
Collection Date:03-Dec-15 2:20 PM
Site:SMW-2C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:10M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 34 mg/L EPA 300.0 12/05/2015 21:35 BGN9034110
Sulfate 72 mg/L EPA 300.0 12/05/2015 21:35 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:06 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:12 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.322 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.005 1
Barium (Ba)0.053 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.005 1
Boron (B)0.533 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.05 1
Iron (Fe)0.240 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.01 1
Manganese (Mn)0.460 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.005 1
Strontium (Sr)0.355 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 12/08/2015 11:45 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)23.8 mg/L EPA 200.7 12/09/2015 15:38 FCJORDA0.01 1
Magnesium (Mg)3.59 mg/L EPA 200.7 12/09/2015 15:38 FCJORDA0.005 1
Potassium (K)3.98 mg/L EPA 200.7 12/09/2015 15:38 FCJORDA0.1 1
Sodium (Na)22.5 mg/L EPA 200.7 12/09/2015 15:38 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.190 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.005 1
Barium (Ba)0.062 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.005 1
Boron (B)0.402 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.05 1
Iron (Fe)0.558 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.01 1
Manganese (Mn)0.280 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.005 1
Strontium (Sr)0.291 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 11:42 MHH71310.005 1
22 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037894
Collection Date:03-Dec-15 2:20 PM
Site:SMW-2C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Chromium (Cr)1.47 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Cobalt (Co)13.3 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 18:08 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 18:08 MHALL30.2 1
Vanadium (V) Low Level 0.703 ug/L EPA 200.8 12/08/2015 18:08 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Chromium (Cr)1.05 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Cobalt (Co)11.8 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:19 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:19 MHALL30.2 1
Vanadium (V) Low Level 0.819 ug/L EPA 200.8 12/09/2015 14:19 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.578 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
23 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037894
Collection Date:03-Dec-15 2:20 PM
Site:SMW-2C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
24 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037895
Collection Date:03-Dec-15 3:01 PM
Site:AW-8B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:13 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.9 mg/L EPA 300.0 12/05/2015 16:07 BGN90340.1 1
Sulfate 8.2 mg/L EPA 300.0 12/05/2015 16:07 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:13 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:15 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.201 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.05 1
Iron (Fe)2.83 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.01 1
Manganese (Mn)0.026 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.005 1
Strontium (Sr)0.007 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 12/08/2015 11:49 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.727 mg/L EPA 200.7 12/09/2015 15:42 FCJORDA0.01 1
Magnesium (Mg)0.346 mg/L EPA 200.7 12/09/2015 15:42 FCJORDA0.005 1
Potassium (K)0.685 mg/L EPA 200.7 12/09/2015 15:42 FCJORDA0.1 1
Sodium (Na)1.11 mg/L EPA 200.7 12/09/2015 15:42 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.198 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.005 1
Barium (Ba)0.018 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.05 1
Iron (Fe)2.64 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.01 1
Manganese (Mn)0.024 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.005 1
Strontium (Sr)0.006 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 12/09/2015 11:46 MHH71310.005 1
25 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037895
Collection Date:03-Dec-15 3:01 PM
Site:AW-8B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Cobalt (Co)1.62 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 18:15 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 18:15 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 18:15 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Cobalt (Co)1.61 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:26 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:26 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 14:26 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.947 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
26 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037895
Collection Date:03-Dec-15 3:01 PM
Site:AW-8B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
27 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037896
Collection Date:03-Dec-15 3:55 PM
Site:AW-08C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.325 mg-N/L EPA 353.2 12/08/2015 16:15 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.7 mg/L EPA 300.0 12/05/2015 15:17 BGN90340.5 5
Sulfate 10 mg/L EPA 300.0 12/05/2015 15:17 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:16 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:17 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.005 1
Barium (Ba)0.043 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.05 1
Iron (Fe)0.056 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.005 1
Strontium (Sr)0.033 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 11:53 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.28 mg/L EPA 200.7 12/09/2015 15:46 FCJORDA0.01 1
Magnesium (Mg)1.58 mg/L EPA 200.7 12/09/2015 15:46 FCJORDA0.005 1
Potassium (K)1.24 mg/L EPA 200.7 12/09/2015 15:46 FCJORDA0.1 1
Sodium (Na)5.66 mg/L EPA 200.7 12/09/2015 15:46 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.228 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.005 1
Barium (Ba)0.044 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.05 1
Iron (Fe)0.376 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.01 1
Manganese (Mn)0.024 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.005 1
Strontium (Sr)0.031 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 11:50 MHH71310.005 1
28 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037896
Collection Date:03-Dec-15 3:55 PM
Site:AW-08C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 18:22 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 18:22 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 18:22 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:34 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:34 MHALL30.2 1
Vanadium (V) Low Level 0.577 ug/L EPA 200.8 12/09/2015 14:34 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 31 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.216 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
29 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037896
Collection Date:03-Dec-15 3:55 PM
Site:AW-08C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
30 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037897
Collection Date:03-Dec-15 12:48 PM
Site:AW-06D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:16 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 180 mg/L EPA 300.0 12/05/2015 18:39 BGN9034550
Sulfate 3.5 mg/L EPA 300.0 12/05/2015 18:39 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:18 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:19 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.005 1
Boron (B)1.04 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.05 1
Iron (Fe)0.037 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.005 1
Strontium (Sr)0.092 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:00 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.64 mg/L EPA 200.7 12/09/2015 15:54 FCJORDA0.1 10
Magnesium (Mg)4.09 mg/L EPA 200.7 12/09/2015 15:54 FCJORDA0.05 10
Potassium (K)8.48 mg/L EPA 200.7 12/09/2015 15:54 FCJORDA110
Sodium (Na)243 mg/L EPA 200.7 12/09/2015 15:54 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.384 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.005 1
Barium (Ba)0.016 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.005 1
Boron (B)0.990 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.05 1
Iron (Fe)0.558 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.005 1
Strontium (Sr)0.086 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 11:54 MHH71310.005 1
31 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037897
Collection Date:03-Dec-15 12:48 PM
Site:AW-06D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Arsenic (As)1.06 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Molybdenum (Mo)9.23 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 18:29 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 18:29 MHALL30.2 1
Vanadium (V) Low Level 0.557 ug/L EPA 200.8 12/08/2015 18:29 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Arsenic (As)1.34 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Chromium (Cr)1.08 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Molybdenum (Mo)12.8 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:39 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:39 MHALL30.2 1
Vanadium (V) Low Level 0.924 ug/L EPA 200.8 12/09/2015 14:39 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 650 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 2.4 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 12 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
32 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037897
Collection Date:03-Dec-15 12:48 PM
Site:AW-06D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
33 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037898
Collection Date:03-Dec-15 1:24 PM
Site:AW-06E
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:23M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 500 mg/L EPA 300.0 12/05/2015 18:56 BGN903410100
Sulfate 110 mg/L EPA 300.0 12/05/2015 18:56 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:20 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:27 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.023 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.005 1
Boron (B)2.51 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.05 1
Iron (Fe)0.023 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.01 1
Manganese (Mn)0.012 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.005 1
Strontium (Sr)0.164 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:03 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.77 mg/L EPA 200.7 12/09/2015 16:09 FCJORDA0.1 10
Magnesium (Mg)9.73 mg/L EPA 200.7 12/09/2015 16:09 FCJORDA0.05 10
Potassium (K)43.3 mg/L EPA 200.7 12/09/2015 16:09 FCJORDA110
Sodium (Na)524 mg/L EPA 200.7 12/09/2015 16:09 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.056 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.005 1
Barium (Ba)0.007 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.005 1
Boron (B)2.43 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.05 1
Iron (Fe)0.099 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.01 1
Manganese (Mn)0.012 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.005 1
Strontium (Sr)0.156 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 12/09/2015 12:06 MHH71310.005 1
34 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037898
Collection Date:03-Dec-15 1:24 PM
Site:AW-06E
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Molybdenum (Mo)6.94 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 18:57 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 18:57M2 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 18:57 MHALL30.2 1
Vanadium (V) Low Level 0.323 ug/L EPA 200.8 12/08/2015 18:57 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Molybdenum (Mo)6.75 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:22 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:22 MHALL30.2 1
Vanadium (V) Low Level 0.583 ug/L EPA 200.8 12/09/2015 15:22 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 1500 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.421 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
35 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037898
Collection Date:03-Dec-15 1:24 PM
Site:AW-06E
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
36 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037899
Collection Date:03-Dec-15 11:17 AM
Site:AW-06B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.078 mg-N/L EPA 353.2 12/08/2015 16:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 300.0 12/05/2015 19:13 BGN90340.1 1
Sulfate 8.0 mg/L EPA 300.0 12/05/2015 19:13 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:23 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:34 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.005 1
Barium (Ba)0.028 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.01 1
Manganese (Mn)0.014 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.005 1
Strontium (Sr)0.053 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.23 mg/L EPA 200.7 12/09/2015 16:21 FCJORDA0.01 1
Magnesium (Mg)0.177 mg/L EPA 200.7 12/09/2015 16:21 FCJORDA0.005 1
Potassium (K)0.568 mg/L EPA 200.7 12/09/2015 16:21 FCJORDA0.1 1
Sodium (Na)1.24 mg/L EPA 200.7 12/09/2015 16:21 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.265 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.005 1
Barium (Ba)0.027 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.05 1
Iron (Fe)0.081 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.01 1
Manganese (Mn)0.013 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.005 1
Strontium (Sr)0.046 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:19 MHH71310.005 1
37 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037899
Collection Date:03-Dec-15 11:17 AM
Site:AW-06B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 19:19 MHALL311
Thallium (Tl) Low Level 0.375 ug/L EPA 200.8 12/08/2015 19:19 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 19:19 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:03 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:03 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 15:03 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 42 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.804 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
38 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037899
Collection Date:03-Dec-15 11:17 AM
Site:AW-06B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
39 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037900
Collection Date:03-Dec-15 11:25 AM
Site:AW-09D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:28 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 240 mg/L EPA 300.0 12/05/2015 19:30 BGN9034550
Sulfate 40 mg/L EPA 300.0 12/05/2015 19:30 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:25 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:36 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.005 1
Barium (Ba)0.009 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.005 1
Boron (B)0.639 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.05 1
Iron (Fe)0.116 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.01 1
Manganese (Mn)0.051 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.005 1
Strontium (Sr)0.136 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:11 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.0 mg/L EPA 200.7 12/09/2015 16:28 FCJORDA0.1 10
Magnesium (Mg)10.0 mg/L EPA 200.7 12/09/2015 16:28 FCJORDA0.05 10
Potassium (K)9.43 mg/L EPA 200.7 12/09/2015 16:28 FCJORDA110
Sodium (Na)212 mg/L EPA 200.7 12/09/2015 16:28 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.071 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.005 1
Barium (Ba)0.009 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.005 1
Boron (B)0.625 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.05 1
Iron (Fe)0.354 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.01 1
Manganese (Mn)0.055 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.005 1
Strontium (Sr)0.129 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:23 MHH71310.005 1
40 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037900
Collection Date:03-Dec-15 11:25 AM
Site:AW-09D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Molybdenum (Mo)7.45 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 19:26 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 19:26 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 19:26 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Molybdenum (Mo)6.59 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:29 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:29 MHALL30.2 1
Vanadium (V) Low Level 0.307 ug/L EPA 200.8 12/09/2015 15:29 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 630 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 2.3 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
41 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037900
Collection Date:03-Dec-15 11:25 AM
Site:AW-09D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
42 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037901
Collection Date:03-Dec-15 11:57 AM
Site:AW-09C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.6 mg-N/L EPA 353.2 12/08/2015 16:29 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 300.0 12/05/2015 19:47 BGN9034110
Sulfate 29 mg/L EPA 300.0 12/05/2015 19:47 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:27 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:38 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.034 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.005 1
Boron (B)0.153 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.01 1
Manganese (Mn)0.074 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.005 1
Strontium (Sr)0.070 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.24 mg/L EPA 200.7 12/09/2015 16:32 FCJORDA0.01 1
Magnesium (Mg)1.79 mg/L EPA 200.7 12/09/2015 16:32 FCJORDA0.005 1
Potassium (K)2.20 mg/L EPA 200.7 12/09/2015 16:32 FCJORDA0.1 1
Sodium (Na)7.39 mg/L EPA 200.7 12/09/2015 16:32 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.069 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.005 1
Barium (Ba)0.042 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.005 1
Boron (B)0.149 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.05 1
Iron (Fe)0.098 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.01 1
Manganese (Mn)0.071 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.005 1
Strontium (Sr)0.067 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:27 MHH71310.005 1
43 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037901
Collection Date:03-Dec-15 11:57 AM
Site:AW-09C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 19:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 19:33 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 19:33 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:37 MHALL30.2 1
Vanadium (V) Low Level 0.329 ug/L EPA 200.8 12/09/2015 15:37 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 67 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.261 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
44 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037901
Collection Date:03-Dec-15 11:57 AM
Site:AW-09C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
45 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037902
Collection Date:03-Dec-15 5:00 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:41 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 12/08/2015 12:26 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 19:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 19:40 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 19:40 MHALL30.3 1
46 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037903
Collection Date:03-Dec-15 5:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 12/05/2015 15:00 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 12/05/2015 15:00 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:30 TLINN0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 12/09/2015 16:36 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 12/09/2015 16:36 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 12/09/2015 16:36 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 12/09/2015 16:36 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:31 MHH71310.005 1
47 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037903
Collection Date:03-Dec-15 5:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:44 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:44 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 15:44 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.126 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
48 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037904
Collection Date:03-Dec-15 1:05 PM
Site:AW-9B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.084 mg-N/L EPA 353.2 12/08/2015 16:34 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 3.2 mg/L EPA 300.0 12/05/2015 20:04 BGN90340.1 1
Sulfate 11 mg/L EPA 300.0 12/05/2015 20:04 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:32 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:43 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.944 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.005 1
Barium (Ba)0.014 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.01 1
Manganese (Mn)0.008 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.005 1
Strontium (Sr)0.012 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:30 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.993 mg/L EPA 200.7 12/09/2015 16:40 FCJORDA0.01 1
Magnesium (Mg)0.247 mg/L EPA 200.7 12/09/2015 16:40 FCJORDA0.005 1
Potassium (K)0.355 mg/L EPA 200.7 12/09/2015 16:40 FCJORDA0.1 1
Sodium (Na)1.86 mg/L EPA 200.7 12/09/2015 16:40 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.19 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.005 1
Barium (Ba)0.014 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.05 1
Iron (Fe)0.108 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.01 1
Manganese (Mn)0.007 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.005 1
Strontium (Sr)0.011 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:35 MHH71310.005 1
49 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037904
Collection Date:03-Dec-15 1:05 PM
Site:AW-9B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 19:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 19:47 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 19:47 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:51 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:51 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 15:51 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.743 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
50 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037904
Collection Date:03-Dec-15 1:05 PM
Site:AW-9B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
51 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037905
Collection Date:03-Dec-15 4:05 PM
Site:MW-37B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.088 mg-N/L EPA 353.2 12/08/2015 16:35 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.2 mg/L EPA 300.0 12/05/2015 18:06 BGN90340.1 1
Sulfate 5.1 mg/L EPA 300.0 12/05/2015 18:06 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:44 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:45 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.541 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.005 1
Barium (Ba)0.008 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.05 1
Iron (Fe)0.048 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:34 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.550 mg/L EPA 200.7 12/09/2015 16:43 FCJORDA0.01 1
Magnesium (Mg)0.131 mg/L EPA 200.7 12/09/2015 16:43 FCJORDA0.005 1
Potassium (K)0.235 mg/L EPA 200.7 12/09/2015 16:43 FCJORDA0.1 1
Sodium (Na)1.80 mg/L EPA 200.7 12/09/2015 16:43 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.575 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.005 1
Barium (Ba)0.008 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.05 1
Iron (Fe)0.092 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:39 MHH71310.005 1
52 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037905
Collection Date:03-Dec-15 4:05 PM
Site:MW-37B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 19:54 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 19:54 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 19:54 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:59 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 15:59 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.610 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
53 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037905
Collection Date:03-Dec-15 4:05 PM
Site:MW-37B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
54 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037906
Collection Date:03-Dec-15 3:10 PM
Site:MW-37C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/08/2015 16:36 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.3 mg/L EPA 300.0 12/05/2015 22:02 BGN90340.1 1
Sulfate 6.0 mg/L EPA 300.0 12/05/2015 22:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:51 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:48 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.05 1
Iron (Fe)7.00 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.01 1
Manganese (Mn)0.113 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.005 1
Strontium (Sr)0.016 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 12/08/2015 12:38 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.93 mg/L EPA 200.7 12/09/2015 16:47 FCJORDA0.01 1
Magnesium (Mg)1.07 mg/L EPA 200.7 12/09/2015 16:47 FCJORDA0.005 1
Potassium (K)3.02 mg/L EPA 200.7 12/09/2015 16:47 FCJORDA0.1 1
Sodium (Na)2.01 mg/L EPA 200.7 12/09/2015 16:47 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.005 1
Barium (Ba)0.022 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.05 1
Iron (Fe)7.39 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.01 1
Manganese (Mn)0.103 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.005 1
Strontium (Sr)0.015 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 12/09/2015 12:43 MHH71310.005 1
55 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037906
Collection Date:03-Dec-15 3:10 PM
Site:MW-37C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Arsenic (As)2.61 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Cobalt (Co)1.66 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 20:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 20:01 MHALL30.2 1
Vanadium (V) Low Level 0.906 ug/L EPA 200.8 12/08/2015 20:01 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Arsenic (As)2.64 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Cobalt (Co)1.63 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 16:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 16:06 MHALL30.2 1
Vanadium (V) Low Level 0.918 ug/L EPA 200.8 12/09/2015 16:06 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 46 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 4.9 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
56 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037906
Collection Date:03-Dec-15 3:10 PM
Site:MW-37C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
57 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037907
Collection Date:03-Dec-15 11:57 AM
Site:AW-09C DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.6 mg-N/L EPA 353.2 12/08/2015 16:37 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 7.9 mg/L EPA 300.0 12/06/2015 00:34 BGN9034110
Sulfate 29 mg/L EPA 300.0 12/06/2015 00:34 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 08:53 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/09/2015 11:50 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.005 1
Boron (B)0.164 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.01 1
Manganese (Mn)0.078 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.005 1
Strontium (Sr)0.075 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 12:42 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.27 mg/L EPA 200.7 12/09/2015 16:51 FCJORDA0.01 1
Magnesium (Mg)1.79 mg/L EPA 200.7 12/09/2015 16:51 FCJORDA0.005 1
Potassium (K)2.22 mg/L EPA 200.7 12/09/2015 16:51 FCJORDA0.1 1
Sodium (Na)7.41 mg/L EPA 200.7 12/09/2015 16:51 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.060 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.005 1
Barium (Ba)0.042 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.005 1
Boron (B)0.147 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.05 1
Iron (Fe)0.076 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.01 1
Manganese (Mn)0.071 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.005 1
Strontium (Sr)0.067 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:47 MHH71310.005 1
58 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037907
Collection Date:03-Dec-15 11:57 AM
Site:AW-09C DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Copper (Cu)1.20 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/08/2015 20:08 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/08/2015 20:08 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/08/2015 20:08 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 16:12 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 16:12 MHALL30.2 1
Vanadium (V) Low Level 0.326 ug/L EPA 200.8 12/09/2015 16:12 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 53 mg/L SM2540C 12/08/2015 15:25 CJELLIO251
Total Carbon
TOC 0.254 mg/L SM5310C/EPA9060A 12/08/2015 13:49 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/08/2015 10:44 CJELLIO51
59 of 157
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120102
2015037907
Collection Date:03-Dec-15 11:57 AM
Site:AW-09C DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
60 of 157
#=CL#
December 11, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278969
92278969
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120102 REV
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 09, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bishop for
[e-mail]
HORIZON Database Administrator
Kevin Herring
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 38
61 of 157
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278969
J15120102 REV
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 38
62 of 157
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278969
J15120102 REV
Lab ID Sample ID Matrix Date Collected Date Received
92278969001 2015037888 Water 12/03/15 11:36 12/09/15 09:38
92278969002 2015037889 Water 12/03/15 12:52 12/09/15 09:38
92278969003 2015037890 Water 12/03/15 15:45 12/09/15 09:38
92278969004 2015037891 Water 12/03/15 12:00 12/09/15 09:38
92278969005 2015037892 Water 12/03/15 11:50 12/09/15 09:38
92278969006 2015037893 Water 12/03/15 14:20 12/09/15 09:38
92278969007 2015037894 Water 12/03/15 14:20 12/09/15 09:38
92278969008 2015037895 Water 12/03/15 15:01 12/09/15 09:38
92278969009 2015037896 Water 12/03/15 15:55 12/09/15 09:38
92278969010 2015037897 Water 12/03/15 12:48 12/09/15 09:38
92278969011 2015037898 Water 12/03/15 13:29 12/09/15 09:38
92278969012 2015037899 Water 12/03/15 11:17 12/09/15 09:38
92278969013 2015037900 Water 12/03/15 11:25 12/09/15 09:38
92278969014 2015037901 Water 12/03/15 11:57 12/09/15 09:38
92278969015 2015037903 Water 12/03/15 17:00 12/09/15 09:38
92278969016 2015037904 Water 12/03/15 13:05 12/09/15 09:38
92278969017 2015037905 Water 12/03/15 16:05 12/09/15 09:38
92278969018 2015037906 Water 12/03/15 15:10 12/09/15 09:38
92278969019 2015037907 Water 12/03/15 11:57 12/09/15 09:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 38
63 of 157
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278969
J15120102 REV
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278969001 2015037888 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969002 2015037889 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969003 2015037890 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969004 2015037891 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969005 2015037892 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969006 2015037893 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969007 2015037894 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969008 2015037895 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969009 2015037896 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969010 2015037897 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969011 2015037898 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969012 2015037899 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969013 2015037900 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969014 2015037901 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969015 2015037903 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278969016 2015037904 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AEWS
92278969017 2015037905 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AEWS
92278969018 2015037906 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AEWS
92278969019 2015037907 RSK 175 1 PASI-MDR1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 38
64 of 157
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278969
J15120102 REV
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AEWS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 38
65 of 157
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278969
J15120102 REV
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278969003 2015037890
Alkalinity,Bicarbonate (CaCO3)115 mg/L 12/10/15 06:055.0SM 2320B
Alkalinity, Total as CaCO3 115 mg/L 12/10/15 06:055.0SM 2320B
92278969004 2015037891
Methane 10.6 ug/L 12/10/15 19:5110.0RSK 175
92278969005 2015037892
Alkalinity,Bicarbonate (CaCO3)15.0 mg/L 12/10/15 06:245.0SM 2320B
Alkalinity, Total as CaCO3 15.0 mg/L 12/10/15 06:245.0SM 2320B
92278969006 2015037893
Methane 1310 ug/L 12/10/15 20:0810.0RSK 175
Alkalinity,Bicarbonate (CaCO3)68.9 mg/L 12/10/15 06:355.0SM 2320B
Alkalinity, Total as CaCO3 68.9 mg/L 12/10/15 06:355.0SM 2320B
92278969007 2015037894
Alkalinity,Bicarbonate (CaCO3)10.0 mg/L 12/10/15 07:115.0SM 2320B
Alkalinity, Total as CaCO3 10.0 mg/L 12/10/15 07:115.0SM 2320B
92278969008 2015037895
Methane 19.2 ug/L 12/10/15 20:5710.0RSK 175
92278969010 2015037897
Methane 521 ug/L 12/10/15 20:3210.0RSK 175
Alkalinity,Bicarbonate (CaCO3)272 mg/L 12/10/15 08:115.0SM 2320B
Alkalinity, Carbonate (CaCO3)21.0 mg/L 12/10/15 08:115.0SM 2320B
Alkalinity, Total as CaCO3 293 mg/L 12/10/15 08:115.0SM 2320B
92278969011 2015037898
Alkalinity,Bicarbonate (CaCO3)273 mg/L 12/10/15 08:415.0SM 2320B
Alkalinity, Carbonate (CaCO3)187 mg/L 12/10/15 08:415.0SM 2320B
Alkalinity, Total as CaCO3 460 mg/L 12/10/15 08:415.0SM 2320B
92278969012 2015037899
Alkalinity,Bicarbonate (CaCO3)10.4 mg/L 12/10/15 10:165.0SM 2320B
Alkalinity, Total as CaCO3 10.4 mg/L 12/10/15 10:165.0SM 2320B
92278969013 2015037900
Alkalinity,Bicarbonate (CaCO3)180 mg/L 12/10/15 10:265.0SM 2320B
Alkalinity, Total as CaCO3 182 mg/L 12/10/15 10:265.0SM 2320B
92278969018 2015037906
Methane 25.5 ug/L 12/10/15 22:4410.0RSK 175
Alkalinity,Bicarbonate (CaCO3)40.5 mg/L 12/10/15 00:475.0SM 2320B
Alkalinity, Total as CaCO3 40.5 mg/L 12/10/15 00:475.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 38
66 of 157
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278969
J15120102 REV
Method:
Client:Duke Energy
RSK 175
Date:December 11, 2015
Description:RSK 175 AIR Headspace
General Information:
19 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 38
67 of 157
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278969
J15120102 REV
Method:
Client:Duke Energy
SM 2320B
Date:December 11, 2015
Description:2320B Alkalinity
General Information:
19 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/41868
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92278969016,92278975007
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1624762)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1624763)
• Alkalinity, Total as CaCO3
R1: RPD value was outside control limits.
• MSD (Lab ID: 1624761)
• Alkalinity, Total as CaCO3
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 8 of 38
68 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037888 Lab ID:92278969001 Collected:12/03/15 11:36 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 18:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 05:305.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 05:305.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 05:305.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 9 of 38
69 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037889 Lab ID:92278969002 Collected:12/03/15 12:52 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 19:34 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 05:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 05:575.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 05:575.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 38
70 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037890 Lab ID:92278969003 Collected:12/03/15 15:45 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 19:43 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)115 mg/L 12/10/15 06:055.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 06:055.0 1
Alkalinity, Total as CaCO3 115 mg/L 12/10/15 06:055.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 11 of 38
71 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037891 Lab ID:92278969004 Collected:12/03/15 12:00 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 10.6 ug/L 12/10/15 19:51 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 06:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 06:165.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 06:165.0 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 12 of 38
72 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037892 Lab ID:92278969005 Collected:12/03/15 11:50 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 19:59 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.0 mg/L 12/10/15 06:245.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 06:245.0 1
Alkalinity, Total as CaCO3 15.0 mg/L 12/10/15 06:245.0 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 13 of 38
73 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037893 Lab ID:92278969006 Collected:12/03/15 14:20 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 1310 ug/L 12/10/15 20:08 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)68.9 mg/L 12/10/15 06:355.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 06:355.0 1
Alkalinity, Total as CaCO3 68.9 mg/L 12/10/15 06:355.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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[phone]
Page 14 of 38
74 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037894 Lab ID:92278969007 Collected:12/03/15 14:20 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 20:49 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.0 mg/L 12/10/15 07:115.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 07:115.0 1
Alkalinity, Total as CaCO3 10.0 mg/L 12/10/15 07:115.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 15 of 38
75 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037895 Lab ID:92278969008 Collected:12/03/15 15:01 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 19.2 ug/L 12/10/15 20:57 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 07:225.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 07:225.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 07:225.0 1
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 16 of 38
76 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037896 Lab ID:92278969009 Collected:12/03/15 15:55 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 21:05 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 07:305.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 07:305.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 07:305.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 17 of 38
77 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037897 Lab ID:92278969010 Collected:12/03/15 12:48 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 521 ug/L 12/10/15 20:32 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)272 mg/L 12/10/15 08:115.0 1
Alkalinity, Carbonate (CaCO3)21.0 mg/L 12/10/15 08:115.0 1
Alkalinity, Total as CaCO3 293 mg/L 12/10/15 08:115.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 18 of 38
78 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037898 Lab ID:92278969011 Collected:12/03/15 13:29 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 21:13 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)273 mg/L 12/10/15 08:415.0 1
Alkalinity, Carbonate (CaCO3)187 mg/L 12/10/15 08:415.0 1
Alkalinity, Total as CaCO3 460 mg/L 12/10/15 08:415.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 19 of 38
79 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037899 Lab ID:92278969012 Collected:12/03/15 11:17 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 21:21 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.4 mg/L 12/10/15 10:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 10:165.0 1
Alkalinity, Total as CaCO3 10.4 mg/L 12/10/15 10:165.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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Huntersville, NC 28078
[phone]
Page 20 of 38
80 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037900 Lab ID:92278969013 Collected:12/03/15 11:25 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 21:30 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)180 mg/L 12/10/15 10:265.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 10:265.0 1
Alkalinity, Total as CaCO3 182 mg/L 12/10/15 10:265.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 38
81 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037901 Lab ID:92278969014 Collected:12/03/15 11:57 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 21:38 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 10:385.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 10:385.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 10:385.0 1
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 22 of 38
82 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037903 Lab ID:92278969015 Collected:12/03/15 17:00 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 21:46 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 10:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 10:465.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 10:465.0 1
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 23 of 38
83 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037904 Lab ID:92278969016 Collected:12/03/15 13:05 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 22:27 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 00:47 R15.0 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 24 of 38
84 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037905 Lab ID:92278969017 Collected:12/03/15 16:05 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 22:36 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 00:475.0 1
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 25 of 38
85 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037906 Lab ID:92278969018 Collected:12/03/15 15:10 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 25.5 ug/L 12/10/15 22:44 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)40.5 mg/L 12/10/15 00:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Total as CaCO3 40.5 mg/L 12/10/15 00:475.0 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 26 of 38
86 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278969
J15120102 REV
Sample:2015037907 Lab ID:92278969019 Collected:12/03/15 11:57 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 22:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/10/15 00:475.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/10/15 00:475.0 1
REPORT OF LABORATORY ANALYSIS
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Page 27 of 38
87 of 157
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278969
J15120102 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24819
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92278969001, 92278969002, 92278969003, 92278969004, 92278969005, 92278969006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2154693
Associated Lab Samples:92278969001, 92278969002, 92278969003, 92278969004, 92278969005, 92278969006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 12/10/15 17:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2154694LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2154695
Methane ug/L 53.460.7 88 85-1159054.7 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278953009
2154696SAMPLE DUPLICATE:
Methane ug/L 11.7 0 2011.7
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278969001
2154697SAMPLE DUPLICATE:
Methane ug/L 1.5J 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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[phone]
Page 28 of 38
88 of 157
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278969
J15120102 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24820
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92278969007, 92278969008, 92278969009, 92278969010, 92278969011, 92278969012, 92278969013,
92278969014, 92278969015, 92278969016, 92278969017, 92278969018, 92278969019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2154698
Associated Lab Samples:92278969007, 92278969008, 92278969009, 92278969010, 92278969011, 92278969012, 92278969013,
92278969014, 92278969015, 92278969016, 92278969017, 92278969018, 92278969019
Matrix:Water
Analyzed
Methane ug/L ND 10.0 12/10/15 20:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2154699LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2154700
Methane ug/L 54.760.7 90 85-1159255.7 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278969010
2154701SAMPLE DUPLICATE:
Methane ug/L 510 2 20521
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278969019
2154702SAMPLE DUPLICATE:
Methane ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 29 of 38
89 of 157
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278969
J15120102 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41860
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278969001, 92278969002, 92278969003, 92278969004, 92278969005, 92278969006, 92278969007,
92278969008, 92278969009, 92278969010, 92278969011, 92278969012, 92278969013, 92278969014,
92278969015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1624391
Associated Lab Samples:92278969001, 92278969002, 92278969003, 92278969004, 92278969005, 92278969006, 92278969007,
92278969008, 92278969009, 92278969010, 92278969011, 92278969012, 92278969013, 92278969014,
92278969015
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/10/15 03:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1624392LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 51.250 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624393MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278965007
1624394
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 104 90-110101 1 45088.0 140 138
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624395MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278969006
1624396
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 90-11094 3 45068.9 119 116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278969
J15120102 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41868
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278969016, 92278969017, 92278969018, 92278969019
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1624758
Associated Lab Samples:92278969016, 92278969017, 92278969018, 92278969019
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/10/15 00:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1624759LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 53.850 108 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624760MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278969016
1624761
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L R15010490-11097 6 450ND51.9 48.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1624762MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278975007
1624763
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1501990-11022 1 450229238240
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278969
J15120102 REV
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278969
J15120102 REV
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278969001 AIR/248192015037888RSK 175
92278969002 AIR/248192015037889RSK 175
92278969003 AIR/248192015037890RSK 175
92278969004 AIR/248192015037891RSK 175
92278969005 AIR/248192015037892RSK 175
92278969006 AIR/248192015037893RSK 175
92278969007 AIR/248202015037894RSK 175
92278969008 AIR/248202015037895RSK 175
92278969009 AIR/248202015037896RSK 175
92278969010 AIR/248202015037897RSK 175
92278969011 AIR/248202015037898RSK 175
92278969012 AIR/248202015037899RSK 175
92278969013 AIR/248202015037900RSK 175
92278969014 AIR/248202015037901RSK 175
92278969015 AIR/248202015037903RSK 175
92278969016 AIR/248202015037904RSK 175
92278969017 AIR/248202015037905RSK 175
92278969018 AIR/248202015037906RSK 175
92278969019 AIR/248202015037907RSK 175
92278969001 WET/418602015037888SM 2320B
92278969002 WET/418602015037889SM 2320B
92278969003 WET/418602015037890SM 2320B
92278969004 WET/418602015037891SM 2320B
92278969005 WET/418602015037892SM 2320B
92278969006 WET/418602015037893SM 2320B
92278969007 WET/418602015037894SM 2320B
92278969008 WET/418602015037895SM 2320B
92278969009 WET/418602015037896SM 2320B
92278969010 WET/418602015037897SM 2320B
92278969011 WET/418602015037898SM 2320B
92278969012 WET/418602015037899SM 2320B
92278969013 WET/418602015037900SM 2320B
92278969014 WET/418602015037901SM 2320B
92278969015 WET/418602015037903SM 2320B
92278969016 WET/418682015037904SM 2320B
92278969017 WET/418682015037905SM 2320B
92278969018 WET/418682015037906SM 2320B
92278969019 WET/418682015037907SM 2320B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:20 PM
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#=CL#
December 10, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278483
92278483
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120102
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 04, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278483
J15120102
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278483
J15120102
Lab ID Sample ID Matrix Date Collected Date Received
92278483001 2015037888 Water 12/03/15 11:36 12/04/15 11:20
92278483002 2015037889 Water 12/03/15 12:52 12/04/15 11:20
92278483003 2015037890 Water 12/03/15 15:45 12/04/15 11:20
92278483004 2015037891 Water 12/03/15 12:00 12/04/15 11:20
92278483005 2015037892 Water 12/03/15 11:50 12/04/15 11:20
92278483006 2015037893 Water 12/03/15 14:20 12/04/15 11:20
92278483007 2015037894 Water 12/03/15 14:20 12/04/15 11:20
92278483008 2015037895 Water 12/03/15 15:01 12/04/15 11:20
92278483009 2015037896 Water 12/03/15 15:55 12/04/15 11:20
92278483010 2015037897 Water 12/03/15 12:48 12/04/15 11:20
92278483011 2015037898 Water 12/03/15 13:24 12/04/15 11:20
92278483012 2015037899 Water 12/03/15 11:17 12/04/15 11:20
92278483013 2015037903 Water 12/03/15 17:00 12/04/15 11:20
92278483014 2015037905 Water 12/03/15 16:05 12/04/15 11:20
92278483015 2015037906 Water 12/03/15 15:10 12/04/15 11:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 3 of 28
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278483
J15120102
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278483001 2015037888 EPA 218.7 1 PASI-OTK1
92278483002 2015037889 EPA 218.7 1 PASI-OTK1
92278483003 2015037890 EPA 218.7 1 PASI-OTK1
92278483004 2015037891 EPA 218.7 1 PASI-OTK1
92278483005 2015037892 EPA 218.7 1 PASI-OTK1
92278483006 2015037893 EPA 218.7 1 PASI-OTK1
92278483007 2015037894 EPA 218.7 1 PASI-OTK1
92278483008 2015037895 EPA 218.7 1 PASI-OTK1
92278483009 2015037896 EPA 218.7 1 PASI-OTK1
92278483010 2015037897 EPA 218.7 1 PASI-OTK1
92278483011 2015037898 EPA 218.7 1 PASI-OTK1
92278483012 2015037899 EPA 218.7 1 PASI-OTK1
92278483013 2015037903 EPA 218.7 1 PASI-OTK1
92278483014 2015037905 EPA 218.7 1 PASI-OTK1
92278483015 2015037906 EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278483
J15120102
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278483003 2015037890
Chromium, Hexavalent 0.043 ug/L 12/09/15 19:150.030EPA 218.7
92278483006 2015037893
Chromium, Hexavalent 0.035 ug/L 12/09/15 19:540.030EPA 218.7
92278483009 2015037896
Chromium, Hexavalent 0.048 ug/L 12/09/15 20:330.030EPA 218.7
92278483012 2015037899
Chromium, Hexavalent 0.058 ug/L 12/09/15 21:380.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278483
J15120102
Method:
Client:Duke Energy
EPA 218.7
Date:December 10, 2015
Description:Hexavalent Chromium by IC
General Information:
15 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037888 Lab ID:92278483001 Collected:12/03/15 11:36 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/08/15 00:50 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037889 Lab ID:92278483002 Collected:12/03/15 12:52 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 18:36 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037890 Lab ID:92278483003 Collected:12/03/15 15:45 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.043 ug/L 12/09/15 19:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037891 Lab ID:92278483004 Collected:12/03/15 12:00 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 19:28 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037892 Lab ID:92278483005 Collected:12/03/15 11:50 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 19:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037893 Lab ID:92278483006 Collected:12/03/15 14:20 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.035 ug/L 12/09/15 19:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037894 Lab ID:92278483007 Collected:12/03/15 14:20 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 20:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037895 Lab ID:92278483008 Collected:12/03/15 15:01 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 20:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037896 Lab ID:92278483009 Collected:12/03/15 15:55 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.048 ug/L 12/09/15 20:33 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037897 Lab ID:92278483010 Collected:12/03/15 12:48 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 20:46 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037898 Lab ID:92278483011 Collected:12/03/15 13:24 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 20:59 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037899 Lab ID:92278483012 Collected:12/03/15 11:17 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.058 ug/L 12/09/15 21:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 28
116 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037903 Lab ID:92278483013 Collected:12/03/15 17:00 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 22:17 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 28
117 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037905 Lab ID:92278483014 Collected:12/03/15 16:05 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 22:30 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 28
118 of 157
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278483
J15120102
Sample:2015037906 Lab ID:92278483015 Collected:12/03/15 15:10 Received:12/04/15 11:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/09/15 22:43 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 28
119 of 157
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278483
J15120102
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52785
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278483001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1412718
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/07/15 18:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1412719LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.078.075 104 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1412720MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278325003
1412721
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.38 70 85-11545 16 20.380.40 0.66 0.57
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1412722MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278323014
1412723
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 116 85-115115 1 20.075ND 0.087 0.086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 28
120 of 157
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278483
J15120102
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52801
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278483002, 92278483003, 92278483004, 92278483005, 92278483006, 92278483007, 92278483008,
92278483009, 92278483010, 92278483011, 92278483012, 92278483013, 92278483014, 92278483015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1413191
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/09/15 18:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1413192LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.071.075 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1413193MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278483002
1413194
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 80 85-11587 5 20.025ND 0.038 0.040
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1413195MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278483012
1413196
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 99 85-115107 4 20.0750.058 0.13 0.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 28
121 of 157
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278483
J15120102
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 28
122 of 157
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278483
J15120102
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278483001 WETA/527852015037888EPA 218.7
92278483002 WETA/528012015037889EPA 218.7
92278483003 WETA/528012015037890EPA 218.7
92278483004 WETA/528012015037891EPA 218.7
92278483005 WETA/528012015037892EPA 218.7
92278483006 WETA/528012015037893EPA 218.7
92278483007 WETA/528012015037894EPA 218.7
92278483008 WETA/528012015037895EPA 218.7
92278483009 WETA/528012015037896EPA 218.7
92278483010 WETA/528012015037897EPA 218.7
92278483011 WETA/528012015037898EPA 218.7
92278483012 WETA/528012015037899EPA 218.7
92278483013 WETA/528012015037903EPA 218.7
92278483014 WETA/528012015037905EPA 218.7
92278483015 WETA/528012015037906EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/10/2015 12:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 28
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13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J15120105
Project Name:SUTTON - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:12/18/2015
Customer Address:
Customer Name(s):Perry Waldrep, Tim Hunsucker,Brandon Russo, Kathy Webb, John Toepfer
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
1 of 170
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015037942 Sutton 04-Dec-15 9:20 AM Daniel Youngblood MW-5C
2015037943 Sutton 04-Dec-15 9:20 AM Daniel Youngblood MW-5B
2015037944 Sutton 04-Dec-15 10:15 AM Daniel Youngblood MW-5A
2015037945 Sutton 04-Dec-15 12:15 PM Daniel Youngblood AW-7D
2015037946 Sutton 04-Dec-15 12:26 PM Daniel Youngblood MW-31B
2015037947 Sutton 04-Dec-15 1:10 PM Daniel Youngblood MW-31C
2015037948 Sutton 04-Dec-15 3:55 PM Daniel Youngblood ABMW-2D
2015037949 Sutton 04-Dec-15 2:36 PM Daniel Youngblood MW-16D
2015037950 Sutton 04-Dec-15 3:55 PM Daniel Youngblood MW-16
2015037951 Sutton 04-Dec-15 12:20 PM Daniel Youngblood MW-4A
2015037952 Sutton 04-Dec-15 12:20 PM Daniel Youngblood MW-4A DUP
2015037953 Sutton 04-Dec-15 11:05 AM Daniel Youngblood MW-4B
2015037954 Sutton 04-Dec-15 8:57 AM Daniel Youngblood AW-5E
2015037955 Sutton 04-Dec-15 12:02 PM Daniel Youngblood MW-23B
2015037956 Sutton 04-Dec-15 12:49 PM Daniel Youngblood MW-23C
2015037957 Sutton 04-Dec-15 10:51 AM Daniel Youngblood MW-23E
2015037958 Sutton 04-Dec-15 3:45 PM Daniel Youngblood AW-4B
2015037959 Sutton 04-Dec-15 2:42 PM Daniel Youngblood AW-4C
2015037960 Sutton 04-Dec-15 11:10 AM Daniel Youngblood PZ-10D
2015037961 Sutton 04-Dec-15 12:54 PM Daniel Youngblood MW-36B
2015037962 Sutton 04-Dec-15 3:10 PM Daniel Youngblood MW-27C
2015037963 Sutton 04-Dec-15 10:00 AM Daniel Youngblood PZ-6D
2015037964 Sutton 04-Dec-15 2:39 PM Daniel Youngblood MW-36C
2015037965 Sutton 04-Dec-15 3:00 PM Daniel Youngblood ABMW-2S
2015037966 Sutton 04-Dec-15 2:39 PM Daniel Youngblood MW-36C DUP
2015037967 Sutton 04-Dec-15 11:30 AM Daniel Youngblood MW-4
2015037968 Sutton 04-Dec-15 3:40 PM Daniel Youngblood Filter Blank
2015037969 Sutton 04-Dec-15 3:40 PM Daniel Youngblood Equipment Blank
28 Total Samples
2 of 170
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:12/11/2015
Electronic Data Deliverable (EDD) Sent Separately
3 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037942
Collection Date:04-Dec-15 9:20 AM
Site:MW-5C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.136 mg-N/L EPA 353.2 12/10/2015 12:16 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 12/07/2015 22:00 BGN90340.5 5
Sulfate 11 mg/L EPA 300.0 12/07/2015 22:00 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:10 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:44 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.01 1
Manganese (Mn)0.328 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.005 1
Strontium (Sr)0.022 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/09/2015 11:28 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.21 mg/L EPA 200.7 12/10/2015 11:08 FCJORDA0.01 1
Magnesium (Mg)2.05 mg/L EPA 200.7 12/10/2015 11:08 FCJORDA0.005 1
Potassium (K)1.18 mg/L EPA 200.7 12/10/2015 11:08 FCJORDA0.1 1
Sodium (Na)11.5 mg/L EPA 200.7 12/10/2015 11:08 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.005 1
Barium (Ba)0.034 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.05 1
Iron (Fe)0.021 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.01 1
Manganese (Mn)0.212 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.005 1
Strontium (Sr)0.023 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:43 MHH71310.005 1
4 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037942
Collection Date:04-Dec-15 9:20 AM
Site:MW-5C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:23 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:23 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 14:23 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Cobalt (Co)2.21 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 18:50 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 18:50 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 18:50 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 56 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.252 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
5 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037943
Collection Date:04-Dec-15 9:20 AM
Site:MW-5B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.093 mg-N/L EPA 353.2 12/10/2015 12:25 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 1.8 mg/L EPA 300.0 12/08/2015 09:48 BGN90340.1 1
Sulfate 7.5 mg/L EPA 300.0 12/08/2015 09:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:17 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:51 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.278 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.01 1
Manganese (Mn)0.008 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 12/09/2015 11:40 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.256 mg/L EPA 200.7 12/10/2015 11:24 FCJORDA0.01 1
Magnesium (Mg)0.109 mg/L EPA 200.7 12/10/2015 11:24 FCJORDA0.005 1
Potassium (K)0.224 mg/L EPA 200.7 12/10/2015 11:24 FCJORDA0.1 1
Sodium (Na)0.984 mg/L EPA 200.7 12/10/2015 11:24 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.431 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.005 1
Barium (Ba)0.013 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.05 1
Iron (Fe)0.181 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.01 1
Manganese (Mn)0.006 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/08/2015 08:57 MHH71310.005 1
6 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037943
Collection Date:04-Dec-15 9:20 AM
Site:MW-5B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:30 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:30 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 14:30 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 19:25 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 19:25 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 19:25 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.290 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
7 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037944
Collection Date:04-Dec-15 10:15 AM
Site:MW-5A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.107 mg-N/L EPA 353.2 12/10/2015 12:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.5 mg/L EPA 300.0 12/08/2015 10:06 BGN90340.1 1
Sulfate 14 mg/L EPA 300.0 12/08/2015 10:06 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:19 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:53 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.410 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.01 1
Manganese (Mn)0.019 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.005 1
Strontium (Sr)0.006 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.005 1
Zinc (Zn)0.016 mg/L EPA 200.7 12/09/2015 11:51 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.353 mg/L EPA 200.7 12/10/2015 11:36 FCJORDA0.01 1
Magnesium (Mg)0.262 mg/L EPA 200.7 12/10/2015 11:36 FCJORDA0.005 1
Potassium (K)0.423 mg/L EPA 200.7 12/10/2015 11:36 FCJORDA0.1 1
Sodium (Na)1.09 mg/L EPA 200.7 12/10/2015 11:36 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.480 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.005 1
Barium (Ba)0.015 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.05 1
Iron (Fe)0.118 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.01 1
Manganese (Mn)0.017 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.005 1
Strontium (Sr)0.005 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:14 MHH71310.005 1
8 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037944
Collection Date:04-Dec-15 10:15 AM
Site:MW-5A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:37 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 14:37 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 19:32 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 19:32 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 19:32 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.544 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
9 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037945
Collection Date:04-Dec-15 12:15 PM
Site:AW-7D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 12:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 12/08/2015 00:41 BGN90342.5 25
Sulfate 1.8 mg/L EPA 300.0 12/08/2015 00:41 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:22 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:56 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.005 1
Boron (B)0.801 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.05 1
Iron (Fe)0.037 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.01 1
Manganese (Mn)0.013 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.005 1
Strontium (Sr)0.085 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 12/09/2015 12:02 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.28 mg/L EPA 200.7 12/10/2015 11:48 FCJORDA0.1 10
Magnesium (Mg)4.80 mg/L EPA 200.7 12/10/2015 11:48 FCJORDA0.05 10
Potassium (K)6.00 mg/L EPA 200.7 12/10/2015 11:48 FCJORDA110
Sodium (Na)126 mg/L EPA 200.7 12/10/2015 11:48 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.048 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.005 1
Boron (B)0.792 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.05 1
Iron (Fe)0.094 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.01 1
Manganese (Mn)0.013 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.005 1
Strontium (Sr)0.082 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:18 MHH71310.005 1
10 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037945
Collection Date:04-Dec-15 12:15 PM
Site:AW-7D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Molybdenum (Mo)4.57 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 14:44 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 14:44 MHALL30.2 1
Vanadium (V) Low Level 0.426 ug/L EPA 200.8 12/09/2015 14:44 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Molybdenum (Mo)5.92 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 19:39 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 19:39 MHALL30.2 1
Vanadium (V) Low Level 0.767 ug/L EPA 200.8 12/09/2015 19:39 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 490 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 6.6 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
11 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037946
Collection Date:04-Dec-15 12:26 PM
Site:MW-31B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 12:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 5.3 mg/L EPA 300.0 12/07/2015 23:11 BGN90340.1 1
Sulfate 11 mg/L EPA 300.0 12/07/2015 23:11 BGN90340.2 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:24 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:58 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.005 1
Barium (Ba)0.010 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.05 1
Iron (Fe)4.10 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.01 1
Manganese (Mn)0.040 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.005 1
Strontium (Sr)0.071 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 12/09/2015 12:06 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.75 mg/L EPA 200.7 12/10/2015 11:51 FCJORDA0.01 1
Magnesium (Mg)0.903 mg/L EPA 200.7 12/10/2015 11:51 FCJORDA0.005 1
Potassium (K)0.834 mg/L EPA 200.7 12/10/2015 11:51 FCJORDA0.1 1
Sodium (Na)2.97 mg/L EPA 200.7 12/10/2015 11:51 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.005 1
Barium (Ba)0.011 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.05 1
Iron (Fe)4.42 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.01 1
Manganese (Mn)0.036 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.005 1
Strontium (Sr)0.070 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:22 MHH71310.005 1
12 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037946
Collection Date:04-Dec-15 12:26 PM
Site:MW-31B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:12 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:12 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 15:12 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 19:46 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 19:46 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 19:46 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 28 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
13 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037947
Collection Date:04-Dec-15 1:10 PM
Site:MW-31C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
14 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037948
Collection Date:04-Dec-15 3:55 PM
Site:ABMW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 12:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 43 mg/L EPA 300.0 12/07/2015 23:29 BGN9034110
Sulfate 89 mg/L EPA 300.0 12/07/2015 23:29 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:26 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:01 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.005 1
Barium (Ba)0.062 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.005 1
Boron (B)0.676 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.05 1
Iron (Fe)1.30 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.01 1
Manganese (Mn)0.137 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.005 1
Strontium (Sr)1.22 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:10 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)34.6 mg/L EPA 200.7 12/10/2015 11:55 FCJORDA0.01 1
Magnesium (Mg)11.8 mg/L EPA 200.7 12/10/2015 11:55 FCJORDA0.005 1
Potassium (K)9.13 mg/L EPA 200.7 12/10/2015 11:55 FCJORDA0.1 1
Sodium (Na)44.8 mg/L EPA 200.7 12/10/2015 11:55 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.005 1
Barium (Ba)0.062 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.005 1
Boron (B)0.682 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.05 1
Iron (Fe)1.29 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.01 1
Manganese (Mn)0.135 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.005 1
Strontium (Sr)1.19 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:26 MHH71310.005 1
15 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037948
Collection Date:04-Dec-15 3:55 PM
Site:ABMW-2D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Arsenic (As)168 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Cobalt (Co)2.44 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Molybdenum (Mo)129 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Nickel (Ni)3.01 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:33 MHALL30.2 1
Vanadium (V) Low Level 0.442 ug/L EPA 200.8 12/09/2015 15:33 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Arsenic (As)172 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Cobalt (Co)2.68 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Molybdenum (Mo)132 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Nickel (Ni)2.89 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 19:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 19:53 MHALL30.2 1
Vanadium (V) Low Level 0.687 ug/L EPA 200.8 12/09/2015 19:53 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
16 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037949
Collection Date:04-Dec-15 2:36 PM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 12:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 130 mg/L EPA 300.0 12/08/2015 10:42 BGN9034220
Sulfate 140 mg/L EPA 300.0 12/08/2015 10:42 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:29 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:03 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.121 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.005 1
Boron (B)0.452 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.05 1
Iron (Fe)1.14 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.01 1
Manganese (Mn)0.242 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.005 1
Strontium (Sr)0.158 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.005 1
Zinc (Zn)0.055 mg/L EPA 200.7 12/09/2015 12:14 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.8 mg/L EPA 200.7 12/10/2015 11:59 FCJORDA0.01 1
Magnesium (Mg)5.64 mg/L EPA 200.7 12/10/2015 11:59 FCJORDA0.005 1
Potassium (K)4.55 mg/L EPA 200.7 12/10/2015 11:59 FCJORDA0.1 1
Sodium (Na)88.9 mg/L EPA 200.7 12/10/2015 11:59 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.136 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.005 1
Barium (Ba)0.050 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.005 1
Boron (B)0.445 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.05 1
Iron (Fe)1.63 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.01 1
Manganese (Mn)0.232 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.005 1
Strontium (Sr)0.157 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.005 1
Zinc (Zn)0.048 mg/L EPA 200.7 12/08/2015 09:30 MHH71310.005 1
17 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037949
Collection Date:04-Dec-15 2:36 PM
Site:MW-16D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Cobalt (Co)5.53 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Nickel (Ni)2.23 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:40 MHALL30.2 1
Vanadium (V) Low Level 0.932 ug/L EPA 200.8 12/09/2015 15:40 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Cobalt (Co)5.75 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Nickel (Ni)2.28 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 20:00 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 20:00 MHALL30.2 1
Vanadium (V) Low Level 2.76 ug/L EPA 200.8 12/09/2015 20:00 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 370 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.847 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
18 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037950
Collection Date:04-Dec-15 3:55 PM
Site:MW-16
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 12:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 12/08/2015 00:05 BGN9034110
Sulfate 12 mg/L EPA 300.0 12/08/2015 00:05 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:31 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:05 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.069 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.005 1
Boron (B)0.114 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.05 1
Iron (Fe)0.119 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.01 1
Manganese (Mn)0.009 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.005 1
Strontium (Sr)0.067 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:18 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)4.55 mg/L EPA 200.7 12/10/2015 12:03 FCJORDA0.01 1
Magnesium (Mg)2.28 mg/L EPA 200.7 12/10/2015 12:03 FCJORDA0.005 1
Potassium (K)3.82 mg/L EPA 200.7 12/10/2015 12:03 FCJORDA0.1 1
Sodium (Na)12.4 mg/L EPA 200.7 12/10/2015 12:03 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)2.00 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.005 1
Barium (Ba)0.018 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.005 1
Boron (B)0.109 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.05 1
Iron (Fe)0.874 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.005 1
Strontium (Sr)0.065 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:34 MHH71310.005 1
19 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037950
Collection Date:04-Dec-15 3:55 PM
Site:MW-16
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Arsenic (As)2.94 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Molybdenum (Mo)9.19 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:48 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 15:48 MHALL30.2 1
Vanadium (V) Low Level 0.392 ug/L EPA 200.8 12/09/2015 15:48 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Arsenic (As)3.31 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Chromium (Cr)1.23 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Molybdenum (Mo)9.86 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 20:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 20:07 MHALL30.2 1
Vanadium (V) Low Level 2.36 ug/L EPA 200.8 12/09/2015 20:07 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 75 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 4.9 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
20 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037951
Collection Date:04-Dec-15 12:20 PM
Site:MW-4A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)5.2 mg-N/L EPA 353.2 12/10/2015 12:36 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.1 mg/L EPA 300.0 12/08/2015 11:11 BGN9034110
Sulfate 140 mg/L EPA 300.0 12/08/2015 11:11 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:34 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:08 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)1.46 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.005 1
Barium (Ba)0.136 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.005 1
Boron (B)0.064 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.05 1
Iron (Fe)0.028 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.01 1
Manganese (Mn)0.141 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)20.1 mg/L EPA 200.7 12/10/2015 12:07 FCJORDA0.1 10
Magnesium (Mg)6.56 mg/L EPA 200.7 12/10/2015 12:07 FCJORDA0.05 10
Potassium (K)33.8 mg/L EPA 200.7 12/10/2015 12:07 FCJORDA110
Sodium (Na)7.51 mg/L EPA 200.7 12/10/2015 12:07 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.38 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.005 1
Barium (Ba)0.126 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.005 1
Boron (B)0.065 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.05 1
Iron (Fe)0.111 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.01 1
Manganese (Mn)0.112 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.005 1
Strontium (Sr)0.085 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:38 MHH71310.005 1
21 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037951
Collection Date:04-Dec-15 12:20 PM
Site:MW-4A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Copper (Cu)1.18 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Nickel (Ni)2.75 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 15:55 MHALL311
Thallium (Tl) Low Level 0.381 ug/L EPA 200.8 12/09/2015 15:55 MHALL30.2 1
Vanadium (V) Low Level 1.78 ug/L EPA 200.8 12/09/2015 15:55 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Nickel (Ni)2.59 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 20:49 MHALL311
Thallium (Tl) Low Level 0.420 ug/L EPA 200.8 12/09/2015 20:49 MHALL30.2 1
Vanadium (V) Low Level 2.63 ug/L EPA 200.8 12/09/2015 20:49 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 7.7 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
22 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037952
Collection Date:04-Dec-15 12:20 PM
Site:MW-4A DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)4.8 mg-N/L EPA 353.2 12/10/2015 12:37 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.1 mg/L EPA 300.0 12/08/2015 11:28 BGN9034110
Sulfate 150 mg/L EPA 300.0 12/08/2015 11:28 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:36 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:10 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)1.44 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.005 1
Barium (Ba)0.131 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.005 1
Boron (B)0.067 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.05 1
Iron (Fe)0.027 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.01 1
Manganese (Mn)0.129 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.005 1
Strontium (Sr)0.097 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:25 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)19.9 mg/L EPA 200.7 12/10/2015 12:11 FCJORDA0.1 10
Magnesium (Mg)6.58 mg/L EPA 200.7 12/10/2015 12:11 FCJORDA0.05 10
Potassium (K)33.5 mg/L EPA 200.7 12/10/2015 12:11 FCJORDA110
Sodium (Na)7.49 mg/L EPA 200.7 12/10/2015 12:11 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.36 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.005 1
Barium (Ba)0.127 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.005 1
Boron (B)0.066 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.05 1
Iron (Fe)0.072 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.01 1
Manganese (Mn)0.113 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.005 1
Strontium (Sr)0.086 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:59 MHH71310.005 1
23 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037952
Collection Date:04-Dec-15 12:20 PM
Site:MW-4A DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Nickel (Ni)2.51 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 16:02 MHALL311
Thallium (Tl) Low Level 0.407 ug/L EPA 200.8 12/09/2015 16:02 MHALL30.2 1
Vanadium (V) Low Level 1.79 ug/L EPA 200.8 12/09/2015 16:02 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Nickel (Ni)2.54 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 21:10 MHALL311
Thallium (Tl) Low Level 0.409 ug/L EPA 200.8 12/09/2015 21:10 MHALL30.2 1
Vanadium (V) Low Level 2.31 ug/L EPA 200.8 12/09/2015 21:10 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 7.6 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
24 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037953
Collection Date:04-Dec-15 11:05 AM
Site:MW-4B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 12:38 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 12/07/2015 23:16 BGN90340.5 5
Sulfate 11 mg/L EPA 300.0 12/07/2015 23:16 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:43 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:17 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.005 1
Barium (Ba)0.075 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.05 1
Iron (Fe)3.36 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.01 1
Manganese (Mn)0.092 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.005 1
Strontium (Sr)0.138 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/09/2015 12:37 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)61.9 mg/L EPA 200.7 12/10/2015 12:23 FCJORDA0.01 1
Magnesium (Mg)2.35 mg/L EPA 200.7 12/10/2015 12:23 FCJORDA0.005 1
Potassium (K)2.58 mg/L EPA 200.7 12/10/2015 12:23 FCJORDA0.1 1
Sodium (Na)6.38 mg/L EPA 200.7 12/10/2015 12:23 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.005 1
Barium (Ba)0.081 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.05 1
Iron (Fe)3.79 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.01 1
Manganese (Mn)0.097 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.005 1
Strontium (Sr)0.142 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 09:47 MHH71310.005 1
25 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037953
Collection Date:04-Dec-15 11:05 AM
Site:MW-4B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 16:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 16:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 16:09 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 21:17 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 21:17 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 21:17 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 210 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 9.0 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
26 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037954
Collection Date:04-Dec-15 8:57 AM
Site:AW-5E
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 16:22 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 570 mg/L EPA 300.0 12/08/2015 02:39 BGN903410100
Sulfate 38 mg/L EPA 300.0 12/08/2015 02:39 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:50 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:24 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.005 1
Barium (Ba)0.008 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.005 1
Boron (B)1.88 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.005 1
Strontium (Sr)0.157 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:41 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)4.25 mg/L EPA 200.7 12/10/2015 12:26 FCJORDA0.1 10
Magnesium (Mg)11.6 mg/L EPA 200.7 12/10/2015 12:26 FCJORDA0.05 10
Potassium (K)55.2 mg/L EPA 200.7 12/10/2015 12:26 FCJORDA110
Sodium (Na)567 mg/L EPA 200.7 12/10/2015 12:26 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.005 1
Barium (Ba)0.009 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.005 1
Boron (B)1.91 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.05 1
Iron (Fe)0.052 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.005 1
Strontium (Sr)0.164 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 10:11 MHH71310.005 1
27 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037954
Collection Date:04-Dec-15 8:57 AM
Site:AW-5E
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Arsenic (As)1.15 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Molybdenum (Mo)22.2 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 13:05 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 13:05 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 13:05 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Arsenic (As)1.19 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Chromium (Cr)1.22 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Molybdenum (Mo)23.9 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Nickel (Ni)1.01 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 21:24 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 21:24 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 21:24 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 1500 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 5.2 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
28 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037955
Collection Date:04-Dec-15 12:02 PM
Site:MW-23B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
29 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037956
Collection Date:04-Dec-15 12:49 PM
Site:MW-23C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
30 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037957
Collection Date:04-Dec-15 10:51 AM
Site:MW-23E
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
31 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037958
Collection Date:04-Dec-15 3:45 PM
Site:AW-4B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.045 mg-N/L EPA 353.2 12/10/2015 16:25 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.1 mg/L EPA 300.0 12/08/2015 00:57 BGN90340.1 1
Sulfate 7.7 mg/L EPA 300.0 12/08/2015 00:57 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:52 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:26 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.005 1
Barium (Ba)0.011 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.05 1
Iron (Fe)0.012 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.005 1
Strontium (Sr)0.010 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.005 1
Zinc (Zn)0.013 mg/L EPA 200.7 12/09/2015 12:44 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.16 mg/L EPA 200.7 12/10/2015 12:30 FCJORDA0.01 1
Magnesium (Mg)0.398 mg/L EPA 200.7 12/10/2015 12:30 FCJORDA0.005 1
Potassium (K)0.836 mg/L EPA 200.7 12/10/2015 12:30 FCJORDA0.1 1
Sodium (Na)1.28 mg/L EPA 200.7 12/10/2015 12:30 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.005 1
Barium (Ba)0.013 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.05 1
Iron (Fe)0.043 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.005 1
Strontium (Sr)0.010 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 10:15 MHH71310.005 1
32 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037958
Collection Date:04-Dec-15 3:45 PM
Site:AW-4B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 01:57 MHALL311
Thallium (Tl) Low Level 0.380 ug/L EPA 200.8 12/10/2015 01:57 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 01:57 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 21:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 21:31 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/09/2015 21:31 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.386 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
33 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037959
Collection Date:04-Dec-15 2:42 PM
Site:AW-4C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 16:26 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 55 mg/L EPA 300.0 12/08/2015 01:14 BGN9034220
Sulfate 150 mg/L EPA 300.0 12/08/2015 01:14 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:55 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:29 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.005 1
Barium (Ba)0.032 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.005 1
Boron (B)1.32 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.05 1
Iron (Fe)1.60 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.01 1
Manganese (Mn)0.711 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.005 1
Strontium (Sr)0.901 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:48 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)40.4 mg/L EPA 200.7 12/10/2015 12:34 FCJORDA0.01 1
Magnesium (Mg)7.26 mg/L EPA 200.7 12/10/2015 12:34 FCJORDA0.005 1
Potassium (K)7.83 mg/L EPA 200.7 12/10/2015 12:34 FCJORDA0.1 1
Sodium (Na)44.6 mg/L EPA 200.7 12/10/2015 12:34 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.005 1
Barium (Ba)0.033 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.005 1
Boron (B)1.31 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.05 1
Iron (Fe)1.40 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.01 1
Manganese (Mn)0.742 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.005 1
Strontium (Sr)0.876 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 10:19 MHH71310.005 1
34 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037959
Collection Date:04-Dec-15 2:42 PM
Site:AW-4C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Cobalt (Co)4.87 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 02:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 02:04 MHALL30.2 1
Vanadium (V) Low Level 0.398 ug/L EPA 200.8 12/10/2015 02:04 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Cobalt (Co)6.15 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 21:38 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 21:38 MHALL30.2 1
Vanadium (V) Low Level 0.557 ug/L EPA 200.8 12/09/2015 21:38 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.926 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
35 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037960
Collection Date:04-Dec-15 11:10 AM
Site:PZ-10D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 16:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 150 mg/L EPA 300.0 12/08/2015 01:31 BGN9034220
Sulfate 30 mg/L EPA 300.0 12/08/2015 01:31 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:57 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:31 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.005 1
Barium (Ba)0.053 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.005 1
Boron (B)0.373 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.05 1
Iron (Fe)0.240 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.01 1
Manganese (Mn)0.051 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.005 1
Strontium (Sr)0.108 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:52 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.1 mg/L EPA 200.7 12/10/2015 12:38 FCJORDA0.1 10
Magnesium (Mg)7.91 mg/L EPA 200.7 12/10/2015 12:38 FCJORDA0.05 10
Potassium (K)5.78 mg/L EPA 200.7 12/10/2015 12:38 FCJORDA110
Sodium (Na)140 mg/L EPA 200.7 12/10/2015 12:38 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.190 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.005 1
Barium (Ba)0.055 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.005 1
Boron (B)0.449 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.05 1
Iron (Fe)0.570 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.01 1
Manganese (Mn)0.050 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.005 1
Strontium (Sr)0.114 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 10:23 MHH71310.005 1
36 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037960
Collection Date:04-Dec-15 11:10 AM
Site:PZ-10D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Molybdenum (Mo)2.64 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 02:11 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 02:11 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 02:11 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Arsenic (As)1.38 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Molybdenum (Mo)4.20 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 21:45 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 21:45 MHALL30.2 1
Vanadium (V) Low Level 0.511 ug/L EPA 200.8 12/09/2015 21:45 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 390 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
37 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037961
Collection Date:04-Dec-15 12:54 PM
Site:MW-36B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.4 mg-N/L EPA 353.2 12/10/2015 16:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.6 mg/L EPA 300.0 12/08/2015 11:45 BGN90340.1 1
Sulfate 14 mg/L EPA 300.0 12/08/2015 11:45 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 08:59 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:33 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.005 1
Barium (Ba)0.028 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.005 1
Boron (B)0.119 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.005 1
Strontium (Sr)0.171 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 12:56 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)15.6 mg/L EPA 200.7 12/10/2015 12:42 FCJORDA0.01 1
Magnesium (Mg)1.78 mg/L EPA 200.7 12/10/2015 12:42 FCJORDA0.005 1
Potassium (K)3.22 mg/L EPA 200.7 12/10/2015 12:42 FCJORDA0.1 1
Sodium (Na)3.69 mg/L EPA 200.7 12/10/2015 12:42 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.209 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.005 1
Barium (Ba)0.029 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.005 1
Boron (B)0.118 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.05 1
Iron (Fe)0.116 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.005 1
Strontium (Sr)0.173 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 10:28 MHH71310.005 1
38 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037961
Collection Date:04-Dec-15 12:54 PM
Site:MW-36B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)5.21 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Molybdenum (Mo)78.4 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Selenium (Se)7.06 ug/L EPA 200.8 12/10/2015 02:18 MHALL311
Thallium (Tl) Low Level 0.339 ug/L EPA 200.8 12/10/2015 02:18 MHALL30.2 1
Vanadium (V) Low Level 1.00 ug/L EPA 200.8 12/10/2015 02:18 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)5.05 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Molybdenum (Mo)79.9 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Selenium (Se)6.94 ug/L EPA 200.8 12/09/2015 21:52 MHALL311
Thallium (Tl) Low Level 0.256 ug/L EPA 200.8 12/09/2015 21:52 MHALL30.2 1
Vanadium (V) Low Level 1.59 ug/L EPA 200.8 12/09/2015 21:52 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 73 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 1.0 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
39 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037962
Collection Date:04-Dec-15 3:10 PM
Site:MW-27C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.422 mg-N/L EPA 353.2 12/10/2015 16:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 60 mg/L EPA 300.0 12/08/2015 12:02 BGN9034110
Sulfate 110 mg/L EPA 300.0 12/08/2015 12:02 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:02 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:36 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.116 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.005 1
Barium (Ba)0.033 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.005 1
Boron (B)0.509 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.01 1
Manganese (Mn)0.215 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.005 1
Strontium (Sr)0.248 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.005 1
Zinc (Zn)0.026 mg/L EPA 200.7 12/09/2015 13:00 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)22.1 mg/L EPA 200.7 12/10/2015 12:46 FCJORDA0.01 1
Magnesium (Mg)5.67 mg/L EPA 200.7 12/10/2015 12:46 FCJORDA0.005 1
Potassium (K)8.66 mg/L EPA 200.7 12/10/2015 12:46 FCJORDA0.1 1
Sodium (Na)44.6 mg/L EPA 200.7 12/10/2015 12:46 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.299 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.005 1
Barium (Ba)0.035 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.005 1
Boron (B)0.542 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.05 1
Iron (Fe)0.108 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.01 1
Manganese (Mn)0.224 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.005 1
Strontium (Sr)0.267 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 12/08/2015 10:32 MHH71310.005 1
40 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037962
Collection Date:04-Dec-15 3:10 PM
Site:MW-27C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Cobalt (Co)1.73 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Nickel (Ni)1.03 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Selenium (Se)65.8 ug/L EPA 200.8 12/10/2015 02:25 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 02:25 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 02:25 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Cobalt (Co)1.84 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Selenium (Se)65.3 ug/L EPA 200.8 12/09/2015 21:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 21:59 MHALL30.2 1
Vanadium (V) Low Level 0.383 ug/L EPA 200.8 12/09/2015 21:59 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.593 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
41 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037963
Collection Date:04-Dec-15 10:00 AM
Site:PZ-6D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.050 mg-N/L EPA 353.2 12/10/2015 16:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 160 mg/L EPA 300.0 12/08/2015 12:19 BGN9034550
Sulfate 38 mg/L EPA 300.0 12/08/2015 12:19 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:04 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:38 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.005 1
Boron (B)0.709 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.05 1
Iron (Fe)0.100 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.01 1
Manganese (Mn)0.033 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.005 1
Strontium (Sr)0.125 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 12/09/2015 13:03 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)15.6 mg/L EPA 200.7 12/10/2015 12:49 FCJORDA0.1 10
Magnesium (Mg)6.73 mg/L EPA 200.7 12/10/2015 12:49 FCJORDA0.05 10
Potassium (K)6.85 mg/L EPA 200.7 12/10/2015 12:49 FCJORDA110
Sodium (Na)159 mg/L EPA 200.7 12/10/2015 12:49 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.460 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.005 1
Barium (Ba)0.049 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.005 1
Boron (B)0.670 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.05 1
Iron (Fe)0.956 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.01 1
Manganese (Mn)0.065 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.005 1
Strontium (Sr)0.125 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 12/08/2015 10:36 MHH71310.005 1
42 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037963
Collection Date:04-Dec-15 10:00 AM
Site:PZ-6D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Arsenic (As)1.34 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Molybdenum (Mo)13.7 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 02:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 02:33 MHALL30.2 1
Vanadium (V) Low Level 0.482 ug/L EPA 200.8 12/10/2015 02:33 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Arsenic (As)2.39 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Chromium (Cr)1.89 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Molybdenum (Mo)17.2 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/09/2015 22:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/09/2015 22:06 MHALL30.2 1
Vanadium (V) Low Level 1.72 ug/L EPA 200.8 12/09/2015 22:06 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 500 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 2.4 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
43 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037964
Collection Date:04-Dec-15 2:39 PM
Site:MW-36C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.259 mg-N/L EPA 353.2 12/10/2015 16:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 51 mg/L EPA 300.0 12/08/2015 15:46 BGN9034110
Sulfate 110 mg/L EPA 300.0 12/08/2015 15:46 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:06 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:40 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.032 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.005 1
Barium (Ba)0.026 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.005 1
Boron (B)0.529 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.01 1
Manganese (Mn)0.385 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.005 1
Strontium (Sr)0.325 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 12/09/2015 13:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.7 mg/L EPA 200.7 12/10/2015 12:53 FCJORDA0.01 1
Magnesium (Mg)6.58 mg/L EPA 200.7 12/10/2015 12:53 FCJORDA0.005 1
Potassium (K)8.61 mg/L EPA 200.7 12/10/2015 12:53 FCJORDA0.1 1
Sodium (Na)43.2 mg/L EPA 200.7 12/10/2015 12:53 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)2.15 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.005 1
Barium (Ba)0.032 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.005 1
Boron (B)0.522 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.05 1
Iron (Fe)1.52 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.01 1
Manganese (Mn)0.378 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.005 1
Strontium (Sr)0.329 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.005 1
Zinc (Zn)0.021 mg/L EPA 200.7 12/08/2015 10:40 MHH71310.005 1
44 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037964
Collection Date:04-Dec-15 2:39 PM
Site:MW-36C
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Cobalt (Co)21.0 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Nickel (Ni)1.77 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Selenium (Se)42.3 ug/L EPA 200.8 12/10/2015 02:40 MHALL311
Thallium (Tl) Low Level 0.276 ug/L EPA 200.8 12/10/2015 02:40 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 02:40 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Chromium (Cr)2.38 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Cobalt (Co)22.3 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Copper (Cu)1.10 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Lead (Pb)1.32 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Nickel (Ni)3.18 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Selenium (Se)42.0 ug/L EPA 200.8 12/10/2015 00:26 MHALL311
Thallium (Tl) Low Level 0.566 ug/L EPA 200.8 12/10/2015 00:26 MHALL30.2 1
Vanadium (V) Low Level 4.59 ug/L EPA 200.8 12/10/2015 00:26 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 1.3 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS 55 mg/L SM2540D 12/09/2015 10:21 CJELLIO101
45 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037965
Collection Date:04-Dec-15 3:00 PM
Site:ABMW-2S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 16:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.5 mg/L EPA 300.0 12/08/2015 15:10 BGN90340.1 1
Sulfate 0.10 mg/L EPA 300.0 12/08/2015 15:10 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:09 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:43 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.005 1
Barium (Ba)1.78 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.005 1
Boron (B)0.245 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.05 1
Iron (Fe)14.1 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.01 1
Manganese (Mn)0.664 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.005 1
Strontium (Sr)1.64 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 13:11 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)57.8 mg/L EPA 200.7 12/10/2015 12:57 FCJORDA0.01 1
Magnesium (Mg)7.43 mg/L EPA 200.7 12/10/2015 12:57 FCJORDA0.005 1
Potassium (K)8.68 mg/L EPA 200.7 12/10/2015 12:57 FCJORDA0.1 1
Sodium (Na)23.8 mg/L EPA 200.7 12/10/2015 12:57 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.005 1
Barium (Ba)1.77 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.005 1
Boron (B)0.239 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.05 1
Iron (Fe)13.2 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.01 1
Manganese (Mn)0.677 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.005 1
Strontium (Sr)1.67 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 10:44 MHH71310.005 1
46 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037965
Collection Date:04-Dec-15 3:00 PM
Site:ABMW-2S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Arsenic (As)24.9 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Molybdenum (Mo)1.95 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 01:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 01:37 MHALL30.2 1
Vanadium (V) Low Level 0.720 ug/L EPA 200.8 12/10/2015 01:37 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Arsenic (As)24.0 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Molybdenum (Mo)2.00 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 00:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 00:06 MHALL30.2 1
Vanadium (V) Low Level 0.689 ug/L EPA 200.8 12/10/2015 00:06 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 3.9 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 28 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
47 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037966
Collection Date:04-Dec-15 2:39 PM
Site:MW-36C DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.258 mg-N/L EPA 353.2 12/10/2015 16:35 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 51 mg/L EPA 300.0 12/08/2015 16:04 BGN9034110
Sulfate 120 mg/L EPA 300.0 12/08/2015 16:04 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:21 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:50 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.033 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.005 1
Barium (Ba)0.027 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.005 1
Boron (B)0.526 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.01 1
Manganese (Mn)0.385 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.005 1
Strontium (Sr)0.326 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 12/09/2015 13:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.9 mg/L EPA 200.7 12/10/2015 13:13 FCJORDA0.01 1
Magnesium (Mg)6.63 mg/L EPA 200.7 12/10/2015 13:13 FCJORDA0.005 1
Potassium (K)8.66 mg/L EPA 200.7 12/10/2015 13:13 FCJORDA0.1 1
Sodium (Na)43.2 mg/L EPA 200.7 12/10/2015 13:13 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.96 mg/L EPA 200.7 12/08/2015 11:04M1 MHH71310.005 1
Barium (Ba)0.032 mg/L EPA 200.7 12/08/2015 11:04 MHH71310.005 1
Boron (B)0.528 mg/L EPA 200.7 12/08/2015 11:04 MHH71310.05 1
Iron (Fe)1.42 mg/L EPA 200.7 12/08/2015 11:04 MHH71310.01 1
Manganese (Mn)0.378 mg/L EPA 200.7 12/08/2015 11:04 MHH71310.005 1
Strontium (Sr)0.332 mg/L EPA 200.7 12/08/2015 11:04 MHH71310.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 12/08/2015 11:04 MHH71310.005 1
48 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037966
Collection Date:04-Dec-15 2:39 PM
Site:MW-36C DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Cobalt (Co)21.3 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Nickel (Ni)1.77 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Selenium (Se)42.1 ug/L EPA 200.8 12/10/2015 02:47 MHALL311
Thallium (Tl) Low Level 0.271 ug/L EPA 200.8 12/10/2015 02:47 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 02:47 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Chromium (Cr)2.42 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Cobalt (Co)22.5 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Copper (Cu)1.28 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Lead (Pb)1.27 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Nickel (Ni)3.31 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Selenium (Se)43.4 ug/L EPA 200.8 12/10/2015 00:33 MHALL311
Thallium (Tl) Low Level 0.362 ug/L EPA 200.8 12/10/2015 00:33 MHALL30.2 1
Vanadium (V) Low Level 4.35 ug/L EPA 200.8 12/10/2015 00:33 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.874 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 50 mg/L SM2540D 12/09/2015 10:21 CJELLIO6.3 1
49 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037967
Collection Date:04-Dec-15 11:30 AM
Site:MW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.110 mg-N/L EPA 353.2 12/10/2015 16:46 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.1 mg/L EPA 300.0 12/08/2015 16:22 BGN90340.1 1
Sulfate 54 mg/L EPA 300.0 12/08/2015 16:22 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:28 TLINN0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:57 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.209 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.005 1
Barium (Ba)0.044 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.05 1
Iron (Fe)0.622 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.01 1
Manganese (Mn)0.049 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.005 1
Strontium (Sr)0.055 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 12/09/2015 13:26 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)21.5 mg/L EPA 200.7 12/10/2015 13:16 FCJORDA0.01 1
Magnesium (Mg)2.42 mg/L EPA 200.7 12/10/2015 13:16 FCJORDA0.005 1
Potassium (K)3.07 mg/L EPA 200.7 12/10/2015 13:16 FCJORDA0.1 1
Sodium (Na)5.90 mg/L EPA 200.7 12/10/2015 13:16 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.233 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.005 1
Barium (Ba)0.051 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.05 1
Iron (Fe)0.416 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.01 1
Manganese (Mn)0.052 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.005 1
Strontium (Sr)0.057 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 11:17 MHH71310.005 1
50 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037967
Collection Date:04-Dec-15 11:30 AM
Site:MW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 15:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 15:31 MHALL30.2 1
Vanadium (V) Low Level 1.81 ug/L EPA 200.8 12/10/2015 15:31 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 00:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 00:40 MHALL30.2 1
Vanadium (V) Low Level 2.61 ug/L EPA 200.8 12/10/2015 00:40 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 4.4 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
51 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037968
Collection Date:04-Dec-15 3:40 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 10:59 TLINN0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/09/2015 13:30 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Copper (Cu)2.55 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 02:54 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 02:54 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 02:54 MHALL30.3 1
52 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037969
Collection Date:04-Dec-15 3:40 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_Pace
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 12/10/2015 16:42 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 12/08/2015 12:29 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 12/08/2015 12:29 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 12/10/2015 09:30 TLINN0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 12/10/2015 13:20 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 12/10/2015 13:20 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 12/10/2015 13:20 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 12/10/2015 13:20 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 12/08/2015 11:21 MHH71310.005 1
53 of 170
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120105
2015037969
Collection Date:04-Dec-15 3:40 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 12/10/2015 00:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 12/10/2015 00:47 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 12/10/2015 00:47 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Methane (CH4)Complete Vendor Method V_Pace
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 12/09/2015 15:20 CJELLIO251
Total Carbon
TOC 0.336 mg/L SM5310C/EPA9060A 12/10/2015 13:42 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 12/09/2015 10:21 CJELLIO51
Qualifiers:
M1 Matrix spike recovery was High: the associated Laboratory Control Spike (LCS) was acceptable.
54 of 170
#=CL#
December 11, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278948
92278948
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120105 REV
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 09, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 45
55 of 170
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278948
J15120105 REV
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 45
56 of 170
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278948
J15120105 REV
Lab ID Sample ID Matrix Date Collected Date Received
92278948001 2015037966 Water 12/04/15 14:39 12/09/15 09:38
92278948002 2015037967 Water 12/04/15 11:30 12/09/15 09:38
92278948003 2015037969 Water 12/04/15 15:40 12/09/15 09:38
92278948004 2015037942 Water 12/04/15 09:20 12/09/15 09:38
92278948005 2015037943 Water 12/04/15 09:20 12/09/15 09:38
92278948006 2015037944 Water 12/04/15 10:15 12/09/15 09:38
92278948007 2015037945 Water 12/04/15 12:15 12/09/15 09:38
92278948008 2015037946 Water 12/04/15 12:26 12/09/15 09:38
92278948009 2015037948 Water 12/04/15 15:55 12/09/15 09:38
92278948010 2015037949 Water 12/04/15 14:36 12/09/15 09:38
92278948011 2015037950 Water 12/04/15 15:55 12/09/15 09:38
92278948012 2015037951 Water 12/04/15 12:20 12/09/15 09:38
92278948013 2015037952 Water 12/04/15 12:20 12/09/15 09:38
92278948014 2015037953 Water 12/04/15 11:05 12/09/15 09:38
92278948015 2015037954 Water 12/04/15 08:57 12/09/15 09:38
92278948016 2015037958 Water 12/04/15 15:45 12/09/15 09:38
92278948017 2015037959 Water 12/04/15 14:42 12/09/15 09:38
92278948018 2015037960 Water 12/04/15 11:10 12/09/15 09:38
92278948019 2015037961 Water 12/04/15 12:54 12/09/15 09:38
92278948020 2015037962 Water 12/04/15 15:10 12/09/15 09:38
92278948021 2015037963 Water 12/04/15 10:00 12/09/15 09:38
92278948022 2015037964 Water 12/04/15 14:39 12/09/15 09:38
92278948023 2015037965 Water 12/04/15 15:00 12/09/15 09:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 45
57 of 170
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278948
J15120105 REV
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278948001 2015037966 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948002 2015037967 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948003 2015037969 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948004 2015037942 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948005 2015037943 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948006 2015037944 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948007 2015037945 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948008 2015037946 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948009 2015037948 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948010 2015037949 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948011 2015037950 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948012 2015037951 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948013 2015037952 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948014 2015037953 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948015 2015037954 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948016 2015037958 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948017 2015037959 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948018 2015037960 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948019 2015037961 RSK 175 1 PASI-MDR1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 45
58 of 170
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278948
J15120105 REV
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
92278948020 2015037962 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948021 2015037963 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948022 2015037964 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
92278948023 2015037965 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 45
59 of 170
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278948
J15120105 REV
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278948001 2015037966
Alkalinity,Bicarbonate (CaCO3)8.1 mg/L 12/09/15 14:075.0SM 2320B
Alkalinity, Total as CaCO3 8.1 mg/L 12/09/15 14:075.0SM 2320B
92278948002 2015037967
Methane 106 ug/L 12/10/15 00:0610.0RSK 175
Alkalinity,Bicarbonate (CaCO3)13.1 mg/L 12/09/15 14:405.0SM 2320B
Alkalinity, Total as CaCO3 13.1 mg/L 12/09/15 14:405.0SM 2320B
92278948004 2015037942
Alkalinity,Bicarbonate (CaCO3)9.9 mg/L 12/09/15 14:595.0SM 2320B
Alkalinity, Total as CaCO3 9.9 mg/L 12/09/15 14:595.0SM 2320B
92278948007 2015037945
Methane 125 ug/L 12/10/15 00:4810.0RSK 175
Alkalinity,Bicarbonate (CaCO3)261 mg/L 12/09/15 15:455.0SM 2320B
Alkalinity, Total as CaCO3 261 mg/L 12/09/15 15:455.0SM 2320B
92278948008 2015037946
Alkalinity,Bicarbonate (CaCO3)9.4 mg/L 12/09/15 15:585.0SM 2320B
Alkalinity, Total as CaCO3 9.4 mg/L 12/09/15 15:585.0SM 2320B
92278948009 2015037948
Methane 43.8 ug/L 12/10/15 01:2010.0RSK 175
Alkalinity,Bicarbonate (CaCO3)101 mg/L 12/09/15 16:085.0SM 2320B
Alkalinity, Total as CaCO3 101 mg/L 12/09/15 16:085.0SM 2320B
92278948011 2015037950
Methane 47.1 ug/L 12/10/15 01:4510.0RSK 175
Alkalinity,Bicarbonate (CaCO3)19.4 mg/L 12/09/15 16:295.0SM 2320B
Alkalinity, Total as CaCO3 19.4 mg/L 12/09/15 16:295.0SM 2320B
92278948014 2015037953
Methane 197 ug/L 12/10/15 02:1010.0RSK 175
Alkalinity,Bicarbonate (CaCO3)177 mg/L 12/09/15 17:165.0SM 2320B
Alkalinity, Total as CaCO3 177 mg/L 12/09/15 17:165.0SM 2320B
92278948015 2015037954
Methane 479 ug/L 12/10/15 02:1810.0RSK 175
Alkalinity,Bicarbonate (CaCO3)358 mg/L 12/09/15 17:495.0SM 2320B
Alkalinity, Carbonate (CaCO3)138 mg/L 12/09/15 17:495.0SM 2320B
Alkalinity, Total as CaCO3 495 mg/L 12/09/15 17:495.0SM 2320B
92278948017 2015037959
Methane 14.5 ug/L 12/10/15 08:1910.0RSK 175
Alkalinity,Bicarbonate (CaCO3)15.9 mg/L 12/09/15 18:205.0SM 2320B
Alkalinity, Total as CaCO3 15.9 mg/L 12/09/15 18:205.0SM 2320B
92278948018 2015037960
Alkalinity,Bicarbonate (CaCO3)153 mg/L 12/09/15 18:315.0SM 2320B
Alkalinity, Total as CaCO3 153 mg/L 12/09/15 18:315.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 45
60 of 170
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278948
J15120105 REV
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278948019 2015037961
Alkalinity,Bicarbonate (CaCO3)32.6 mg/L 12/09/15 18:425.0SM 2320B
Alkalinity, Total as CaCO3 32.6 mg/L 12/09/15 18:425.0SM 2320B
92278948021 2015037963
Alkalinity,Bicarbonate (CaCO3)168 mg/L 12/09/15 19:415.0SM 2320B
Alkalinity, Total as CaCO3 168 mg/L 12/09/15 19:41 M15.0SM 2320B
92278948022 2015037964
Alkalinity,Bicarbonate (CaCO3)8.4 mg/L 12/09/15 20:215.0SM 2320B
Alkalinity, Total as CaCO3 8.4 mg/L 12/09/15 20:215.0SM 2320B
92278948023 2015037965
Methane 4110 ug/L 12/10/15 11:1710.0RSK 175
Alkalinity,Bicarbonate (CaCO3)253 mg/L 12/09/15 20:325.0SM 2320B
Alkalinity, Total as CaCO3 253 mg/L 12/09/15 20:325.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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61 of 170
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278948
J15120105 REV
Method:
Client:Duke Energy
RSK 175
Date:December 11, 2015
Description:RSK 175 AIR Headspace
General Information:
23 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
Page 8 of 45
62 of 170
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278948
J15120105 REV
Method:
Client:Duke Energy
SM 2320B
Date:December 11, 2015
Description:2320B Alkalinity
General Information:
23 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/41850
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92278948021,92278953008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1623788)
• Alkalinity, Total as CaCO3
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 45
63 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037966 Lab ID:92278948001 Collected:12/04/15 14:39 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/09/15 23:58 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)8.1 mg/L 12/09/15 14:075.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 14:075.0 1
Alkalinity, Total as CaCO3 8.1 mg/L 12/09/15 14:075.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 45
64 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037967 Lab ID:92278948002 Collected:12/04/15 11:30 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 106 ug/L 12/10/15 00:06 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)13.1 mg/L 12/09/15 14:405.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 14:405.0 1
Alkalinity, Total as CaCO3 13.1 mg/L 12/09/15 14:405.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 45
65 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037969 Lab ID:92278948003 Collected:12/04/15 15:40 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 00:15 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 14:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 14:515.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 14:515.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 45
66 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037942 Lab ID:92278948004 Collected:12/04/15 09:20 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 00:23 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)9.9 mg/L 12/09/15 14:595.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 14:595.0 1
Alkalinity, Total as CaCO3 9.9 mg/L 12/09/15 14:595.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 45
67 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037943 Lab ID:92278948005 Collected:12/04/15 09:20 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 00:31 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 15:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 15:105.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 15:105.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 45
68 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037944 Lab ID:92278948006 Collected:12/04/15 10:15 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 00:39 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 15:185.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 15:185.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 15:185.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 45
69 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037945 Lab ID:92278948007 Collected:12/04/15 12:15 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 125 ug/L 12/10/15 00:48 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)261 mg/L 12/09/15 15:455.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 15:455.0 1
Alkalinity, Total as CaCO3 261 mg/L 12/09/15 15:455.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 45
70 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037946 Lab ID:92278948008 Collected:12/04/15 12:26 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 00:56 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)9.4 mg/L 12/09/15 15:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 15:585.0 1
Alkalinity, Total as CaCO3 9.4 mg/L 12/09/15 15:585.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 45
71 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037948 Lab ID:92278948009 Collected:12/04/15 15:55 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 43.8 ug/L 12/10/15 01:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)101 mg/L 12/09/15 16:085.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 16:085.0 1
Alkalinity, Total as CaCO3 101 mg/L 12/09/15 16:085.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 45
72 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037949 Lab ID:92278948010 Collected:12/04/15 14:36 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 01:37 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 16:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 16:205.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 16:205.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 45
73 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037950 Lab ID:92278948011 Collected:12/04/15 15:55 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 47.1 ug/L 12/10/15 01:45 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)19.4 mg/L 12/09/15 16:295.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 16:295.0 1
Alkalinity, Total as CaCO3 19.4 mg/L 12/09/15 16:295.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 45
74 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037951 Lab ID:92278948012 Collected:12/04/15 12:20 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 01:53 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 17:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 17:005.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 17:005.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 45
75 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037952 Lab ID:92278948013 Collected:12/04/15 12:20 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 02:02 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 17:085.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 17:085.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 17:085.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 45
76 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037953 Lab ID:92278948014 Collected:12/04/15 11:05 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 197 ug/L 12/10/15 02:10 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)177 mg/L 12/09/15 17:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 17:165.0 1
Alkalinity, Total as CaCO3 177 mg/L 12/09/15 17:165.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 45
77 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037954 Lab ID:92278948015 Collected:12/04/15 08:57 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 479 ug/L 12/10/15 02:18 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)358 mg/L 12/09/15 17:495.0 1
Alkalinity, Carbonate (CaCO3)138 mg/L 12/09/15 17:495.0 1
Alkalinity, Total as CaCO3 495 mg/L 12/09/15 17:495.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 45
78 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037958 Lab ID:92278948016 Collected:12/04/15 15:45 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 02:26 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 18:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 18:125.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 18:125.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 45
79 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037959 Lab ID:92278948017 Collected:12/04/15 14:42 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 14.5 ug/L 12/10/15 08:19 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.9 mg/L 12/09/15 18:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 18:205.0 1
Alkalinity, Total as CaCO3 15.9 mg/L 12/09/15 18:205.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 45
80 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037960 Lab ID:92278948018 Collected:12/04/15 11:10 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 10:27 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)153 mg/L 12/09/15 18:315.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 18:315.0 1
Alkalinity, Total as CaCO3 153 mg/L 12/09/15 18:315.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 45
81 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037961 Lab ID:92278948019 Collected:12/04/15 12:54 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 10:44 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)32.6 mg/L 12/09/15 18:425.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 18:425.0 1
Alkalinity, Total as CaCO3 32.6 mg/L 12/09/15 18:425.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 45
82 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037962 Lab ID:92278948020 Collected:12/04/15 15:10 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 10:52 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 12/09/15 18:535.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 18:535.0 1
Alkalinity, Total as CaCO3 ND mg/L 12/09/15 18:535.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 45
83 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037963 Lab ID:92278948021 Collected:12/04/15 10:00 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 11:00 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)168 mg/L 12/09/15 19:415.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 19:415.0 1
Alkalinity, Total as CaCO3 168 mg/L 12/09/15 19:41 M15.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 45
84 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037964 Lab ID:92278948022 Collected:12/04/15 14:39 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 12/10/15 11:08 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)8.4 mg/L 12/09/15 20:215.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 20:215.0 1
Alkalinity, Total as CaCO3 8.4 mg/L 12/09/15 20:215.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278948
J15120105 REV
Sample:2015037965 Lab ID:92278948023 Collected:12/04/15 15:00 Received:12/09/15 09:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 4110 ug/L 12/10/15 11:17 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)253 mg/L 12/09/15 20:325.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 12/09/15 20:325.0 1
Alkalinity, Total as CaCO3 253 mg/L 12/09/15 20:325.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278948
J15120105 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24811
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92278948001, 92278948002, 92278948003, 92278948004, 92278948005, 92278948006, 92278948007,
92278948008, 92278948009, 92278948010, 92278948011, 92278948012, 92278948013, 92278948014,
92278948015, 92278948016, 92278948017
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2154076
Associated Lab Samples:92278948001, 92278948002, 92278948003, 92278948004, 92278948005, 92278948006, 92278948007,
92278948008, 92278948009, 92278948010, 92278948011, 92278948012, 92278948013, 92278948014,
92278948015, 92278948016, 92278948017
Matrix:Water
Analyzed
Methane ug/L ND 10.0 12/09/15 23:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2154077LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2154078
Methane ug/L 53.860.7 89 85-1158652.2 3 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278948009
2154079SAMPLE DUPLICATE:
Methane ug/L 41.6 5 2043.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278887026
2154145SAMPLE DUPLICATE:
Methane ug/L 1.2J 201.5J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278948
J15120105 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/24812
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92278948018, 92278948019, 92278948020, 92278948021, 92278948022, 92278948023
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2154496
Associated Lab Samples:92278948018, 92278948019, 92278948020, 92278948021, 92278948022, 92278948023
Matrix:Water
Analyzed
Methane ug/L ND 10.0 12/10/15 10:19
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2154497LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2154498
Methane ug/L 52.260.7 86 85-1159054.9 5 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278948018
2154499SAMPLE DUPLICATE:
Methane ug/L 3.2J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92278965005
2154500SAMPLE DUPLICATE:
Methane ug/L 19.4 5 2020.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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Huntersville, NC 28078
[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278948
J15120105 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41849
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278948001, 92278948002, 92278948003, 92278948004, 92278948005, 92278948006, 92278948007,
92278948008, 92278948009, 92278948010, 92278948011, 92278948012, 92278948013, 92278948014,
92278948015, 92278948016, 92278948017, 92278948018, 92278948019, 92278948020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1623772
Associated Lab Samples:92278948001, 92278948002, 92278948003, 92278948004, 92278948005, 92278948006, 92278948007,
92278948008, 92278948009, 92278948010, 92278948011, 92278948012, 92278948013, 92278948014,
92278948015, 92278948016, 92278948017, 92278948018, 92278948019, 92278948020
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/09/15 13:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1623773LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.150 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623774MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278948001
1623775
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 90-11099 0 4508.1 57.5 57.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623776MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278948011
1623777
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 107 90-110103 3 45019.4 72.8 70.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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Huntersville, NC 28078
[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278948
J15120105 REV
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/41850
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92278948021, 92278948022, 92278948023
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1623785
Associated Lab Samples:92278948021, 92278948022, 92278948023
Matrix:Water
Analyzed
Alkalinity, Total as CaCO3 mg/L ND 5.0 12/09/15 19:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1623786LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 51.350 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623787MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278948021
1623788
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15010390-110113 2 450168219224
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1623789MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278953008
1623790
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 90-110104 2 45031.7 81.8 83.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278948
J15120105 REV
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278948
J15120105 REV
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278948001 AIR/248112015037966RSK 175
92278948002 AIR/248112015037967RSK 175
92278948003 AIR/248112015037969RSK 175
92278948004 AIR/248112015037942RSK 175
92278948005 AIR/248112015037943RSK 175
92278948006 AIR/248112015037944RSK 175
92278948007 AIR/248112015037945RSK 175
92278948008 AIR/248112015037946RSK 175
92278948009 AIR/248112015037948RSK 175
92278948010 AIR/248112015037949RSK 175
92278948011 AIR/248112015037950RSK 175
92278948012 AIR/248112015037951RSK 175
92278948013 AIR/248112015037952RSK 175
92278948014 AIR/248112015037953RSK 175
92278948015 AIR/248112015037954RSK 175
92278948016 AIR/248112015037958RSK 175
92278948017 AIR/248112015037959RSK 175
92278948018 AIR/248122015037960RSK 175
92278948019 AIR/248122015037961RSK 175
92278948020 AIR/248122015037962RSK 175
92278948021 AIR/248122015037963RSK 175
92278948022 AIR/248122015037964RSK 175
92278948023 AIR/248122015037965RSK 175
92278948001 WET/418492015037966SM 2320B
92278948002 WET/418492015037967SM 2320B
92278948003 WET/418492015037969SM 2320B
92278948004 WET/418492015037942SM 2320B
92278948005 WET/418492015037943SM 2320B
92278948006 WET/418492015037944SM 2320B
92278948007 WET/418492015037945SM 2320B
92278948008 WET/418492015037946SM 2320B
92278948009 WET/418492015037948SM 2320B
92278948010 WET/418492015037949SM 2320B
92278948011 WET/418492015037950SM 2320B
92278948012 WET/418492015037951SM 2320B
92278948013 WET/418492015037952SM 2320B
92278948014 WET/418492015037953SM 2320B
92278948015 WET/418492015037954SM 2320B
92278948016 WET/418492015037958SM 2320B
92278948017 WET/418492015037959SM 2320B
92278948018 WET/418492015037960SM 2320B
92278948019 WET/418492015037961SM 2320B
92278948020 WET/418492015037962SM 2320B
92278948021 WET/418502015037963SM 2320B
92278948022 WET/418502015037964SM 2320B
92278948023 WET/418502015037965SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 03:05 PM
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Huntersville, NC 28078
[phone]
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#=CL#
December 11, 2015
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92278703
92278703
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J15120105
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 07, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92278703
J15120105
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92278703
J15120105
Lab ID Sample ID Matrix Date Collected Date Received
92278703001 2015037942 Water 12/04/15 09:20 12/07/15 15:05
92278703002 2015037943 Water 12/04/15 09:20 12/07/15 15:05
92278703003 2015037944 Water 12/04/15 10:15 12/07/15 15:05
92278703004 2015037945 Water 12/04/15 12:15 12/07/15 15:05
92278703005 2015037946 Water 12/04/15 12:26 12/07/15 15:05
92278703006 2015037947 Water 12/04/15 13:10 12/07/15 15:05
92278703007 2015037948 Water 12/04/15 15:55 12/07/15 15:05
92278703008 2015037949 Water 12/04/15 14:36 12/07/15 15:05
92278703009 2015037950 Water 12/04/15 15:55 12/07/15 15:05
92278703010 2015037951 Water 12/04/15 12:20 12/07/15 15:05
92278703011 2015037952 Water 12/04/15 12:20 12/07/15 15:05
92278703012 2015037953 Water 12/04/15 11:05 12/07/15 15:05
92278703013 2015037954 Water 12/04/15 08:57 12/07/15 15:05
92278703014 2015037955 Water 12/04/15 12:02 12/07/15 15:05
92278703015 2015037956 Water 12/04/15 12:49 12/07/15 15:05
92278703016 2015037957 Water 12/04/15 10:51 12/07/15 15:05
92278703017 2015037958 Water 12/04/15 15:45 12/07/15 15:05
92278703018 2015037959 Water 12/04/15 14:42 12/07/15 15:05
92278703019 2015037960 Water 12/04/15 11:10 12/07/15 15:05
92278703020 2015037961 Water 12/04/15 12:54 12/07/15 15:05
92278703021 2015037962 Water 12/04/15 15:10 12/07/15 15:05
92278703022 2015037963 Water 12/04/15 10:00 12/07/15 15:05
92278703023 2015037964 Water 12/04/15 14:39 12/07/15 15:05
92278703024 2015037965 Water 12/04/15 15:00 12/07/15 15:05
92278703025 2015037966 Water 12/04/15 14:39 12/07/15 15:05
92278703026 2015037967 Water 12/04/15 11:30 12/07/15 15:05
92278703027 2015037969 Water 12/04/15 15:40 12/07/15 15:05
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92278703
J15120105
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92278703001 2015037942 EPA 218.7 1 PASI-OTK1
92278703002 2015037943 EPA 218.7 1 PASI-OTK1
92278703003 2015037944 EPA 218.7 1 PASI-OTK1
92278703004 2015037945 EPA 218.7 1 PASI-OTK1
92278703005 2015037946 EPA 218.7 1 PASI-OTK1
92278703006 2015037947 EPA 218.7 1 PASI-OTK1
92278703007 2015037948 EPA 218.7 1 PASI-OTK1
92278703008 2015037949 EPA 218.7 1 PASI-OTK1
92278703009 2015037950 EPA 218.7 1 PASI-OTK1
92278703010 2015037951 EPA 218.7 1 PASI-OTK1
92278703011 2015037952 EPA 218.7 1 PASI-OTK1
92278703012 2015037953 EPA 218.7 1 PASI-OTK1
92278703013 2015037954 EPA 218.7 1 PASI-OTK1
92278703014 2015037955 EPA 218.7 1 PASI-OTK1
92278703015 2015037956 EPA 218.7 1 PASI-OTK1
92278703016 2015037957 EPA 218.7 1 PASI-OTK1
92278703017 2015037958 EPA 218.7 1 PASI-OTK1
92278703018 2015037959 EPA 218.7 1 PASI-OTK1
92278703019 2015037960 EPA 218.7 1 PASI-OTK1
92278703020 2015037961 EPA 218.7 1 PASI-OTK1
92278703021 2015037962 EPA 218.7 1 PASI-OTK1
92278703022 2015037963 EPA 218.7 1 PASI-OTK1
92278703023 2015037964 EPA 218.7 1 PASI-OTK1
92278703024 2015037965 EPA 218.7 1 PASI-OTK1
92278703025 2015037966 EPA 218.7 1 PASI-OTK1
92278703026 2015037967 EPA 218.7 1 PASI-OTK1
92278703027 2015037969 EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92278703
J15120105
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92278703001 2015037942
Chromium, Hexavalent 0.19 ug/L 12/10/15 15:540.030EPA 218.7
92278703006 2015037947
Chromium, Hexavalent 0.044 ug/L 12/10/15 17:250.030EPA 218.7
92278703010 2015037951
Chromium, Hexavalent 0.033 ug/L 12/10/15 18:170.030EPA 218.7
92278703013 2015037954
Chromium, Hexavalent 0.16 ug/L 12/10/15 19:480.030EPA 218.7
92278703014 2015037955
Chromium, Hexavalent 0.12 ug/L 12/10/15 20:010.030EPA 218.7
92278703016 2015037957
Chromium, Hexavalent 0.11 ug/L 12/10/15 20:310.030EPA 218.7
92278703021 2015037962
Chromium, Hexavalent 0.12 ug/L 12/10/15 22:270.030EPA 218.7
92278703022 2015037963
Chromium, Hexavalent 0.040 ug/L 12/10/15 23:060.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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104 of 170
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92278703
J15120105
Method:
Client:Duke Energy
EPA 218.7
Date:December 11, 2015
Description:Hexavalent Chromium by IC
General Information:
27 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 40
105 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037942 Lab ID:92278703001 Collected:12/04/15 09:20 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.19 ug/L 12/10/15 15:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 40
106 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037943 Lab ID:92278703002 Collected:12/04/15 09:20 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 16:33 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 40
107 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037944 Lab ID:92278703003 Collected:12/04/15 10:15 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 16:46 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 9 of 40
108 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037945 Lab ID:92278703004 Collected:12/04/15 12:15 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 16:59 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 10 of 40
109 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037946 Lab ID:92278703005 Collected:12/04/15 12:26 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 17:12 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 11 of 40
110 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037947 Lab ID:92278703006 Collected:12/04/15 13:10 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.044 ug/L 12/10/15 17:25 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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[phone]
Page 12 of 40
111 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037948 Lab ID:92278703007 Collected:12/04/15 15:55 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 17:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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Page 13 of 40
112 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037949 Lab ID:92278703008 Collected:12/04/15 14:36 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 17:51 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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Page 14 of 40
113 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037950 Lab ID:92278703009 Collected:12/04/15 15:55 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 18:04 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 40
114 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037951 Lab ID:92278703010 Collected:12/04/15 12:20 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.033 ug/L 12/10/15 18:17 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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[phone]
Page 16 of 40
115 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037952 Lab ID:92278703011 Collected:12/04/15 12:20 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 18:56 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 17 of 40
116 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037953 Lab ID:92278703012 Collected:12/04/15 11:05 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 19:35 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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Page 18 of 40
117 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037954 Lab ID:92278703013 Collected:12/04/15 08:57 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.16 ug/L 12/10/15 19:48 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 19 of 40
118 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037955 Lab ID:92278703014 Collected:12/04/15 12:02 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.12 ug/L 12/10/15 20:01 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 20 of 40
119 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037956 Lab ID:92278703015 Collected:12/04/15 12:49 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 20:14 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 40
120 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037957 Lab ID:92278703016 Collected:12/04/15 10:51 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.11 ug/L 12/10/15 20:31 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 40
121 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037958 Lab ID:92278703017 Collected:12/04/15 15:45 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 20:43 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 40
122 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037959 Lab ID:92278703018 Collected:12/04/15 14:42 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 20:56 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 40
123 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037960 Lab ID:92278703019 Collected:12/04/15 11:10 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 21:09 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 40
124 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037961 Lab ID:92278703020 Collected:12/04/15 12:54 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 21:22 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 40
125 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037962 Lab ID:92278703021 Collected:12/04/15 15:10 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.12 ug/L 12/10/15 22:27 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 27 of 40
126 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037963 Lab ID:92278703022 Collected:12/04/15 10:00 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.040 ug/L 12/10/15 23:06 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 28 of 40
127 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037964 Lab ID:92278703023 Collected:12/04/15 14:39 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 23:19 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 29 of 40
128 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037965 Lab ID:92278703024 Collected:12/04/15 15:00 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 23:32 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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Page 30 of 40
129 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037966 Lab ID:92278703025 Collected:12/04/15 14:39 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 23:45 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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[phone]
Page 31 of 40
130 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037967 Lab ID:92278703026 Collected:12/04/15 11:30 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/10/15 23:58 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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[phone]
Page 32 of 40
131 of 170
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92278703
J15120105
Sample:2015037969 Lab ID:92278703027 Collected:12/04/15 15:40 Received:12/07/15 15:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 12/11/15 00:11 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 33 of 40
132 of 170
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278703
J15120105
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52916
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278703001, 92278703002, 92278703003, 92278703004, 92278703005, 92278703006, 92278703007,
92278703008, 92278703009, 92278703010, 92278703011, 92278703012, 92278703013, 92278703014,
92278703015, 92278703016, 92278703017, 92278703018, 92278703019, 92278703020
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1417246
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/10/15 21:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1417247LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.078.075 105 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1417248MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278703001
1417249
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 89 85-115101 3 20.0750.19 0.26 0.26
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1417250MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278703011
1417251
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 76 85-11563 10 20.025ND 0.036 0.033
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
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Page 34 of 40
133 of 170
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92278703
J15120105
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/52917
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92278703021, 92278703022, 92278703023, 92278703024, 92278703025, 92278703026, 92278703027
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1417380
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 12/11/15 01:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1417381LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.076.075 101 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1417382MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278703021
1417383
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 96 85-115102 3 20.0750.12 0.19 0.19
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1417384MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92278705004
1417385
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 63 85-11555 1 20.0250.15 0.17 0.17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 40
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92278703
J15120105
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 40
135 of 170
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92278703
J15120105
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92278703001 WETA/529162015037942EPA 218.7
92278703002 WETA/529162015037943EPA 218.7
92278703003 WETA/529162015037944EPA 218.7
92278703004 WETA/529162015037945EPA 218.7
92278703005 WETA/529162015037946EPA 218.7
92278703006 WETA/529162015037947EPA 218.7
92278703007 WETA/529162015037948EPA 218.7
92278703008 WETA/529162015037949EPA 218.7
92278703009 WETA/529162015037950EPA 218.7
92278703010 WETA/529162015037951EPA 218.7
92278703011 WETA/529162015037952EPA 218.7
92278703012 WETA/529162015037953EPA 218.7
92278703013 WETA/529162015037954EPA 218.7
92278703014 WETA/529162015037955EPA 218.7
92278703015 WETA/529162015037956EPA 218.7
92278703016 WETA/529162015037957EPA 218.7
92278703017 WETA/529162015037958EPA 218.7
92278703018 WETA/529162015037959EPA 218.7
92278703019 WETA/529162015037960EPA 218.7
92278703020 WETA/529162015037961EPA 218.7
92278703021 WETA/529172015037962EPA 218.7
92278703022 WETA/529172015037963EPA 218.7
92278703023 WETA/529172015037964EPA 218.7
92278703024 WETA/529172015037965EPA 218.7
92278703025 WETA/529172015037966EPA 218.7
92278703026 WETA/529172015037967EPA 218.7
92278703027 WETA/529172015037969EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 12/11/2015 09:49 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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