The URL can be used to link to this page

Home My WebLink AboutNC0001422_Laboratory COCs - S3-Envirochem-FR_20150805Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) $M 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Duke Energy -Laboratory Date of Report: Apr 20, 2015 1339 Hagers Ferry Road/Bid 7405 MG03A2 Customer PO #: Huntersville NC 28078 Customer ID: 15030001 Attention: Report #: 2015-02482 Project ID: Ash Pond Investigation Lab ID Sample ID: Duke Energy -Ash Pond Collect Date/Time Matrix Sampled by Investigation 15-05546 Site: Ezzell Trucking/Sutton Lake 3/2/2015 2:45 PM DW jay baker/envirochem Road Test Method Results Date Analyzed Bicarbonate as CaCO3 Bicarbonate as CaCO3 3.00 mg/L 03/19/2015 Carbonate as CaCO3 Carbonate as CaCO3 <1 mg/L 03119/2015 Aluminum EPA200.7 0.042mg/L 03/11/2015 Boron EPA200.7 0.60 mg/L 03/11/2015 Calcium EPA200.7 21.4mg/L 03/05/2015 Iron EPA200.7 0.189mg/L 03/11/2015 Magnesium EPA200.7 3.43mg/L 03/05/2015 Molybdenum EPA200.7 <0.000744mg/L 03/24/2015 Nickel EPA200.7 0.00221Jmg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Potassium EPA200.7 4.11 mg/L 03/05/2015 Sodium EPA200.7 20.2mg/L 03/05/2015 Strontium EPA200.7 0.302mg/L 03/11/2015 Zinc EPA200.7 0.00769J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Antimony EPA 200.8 <0.0000989mg/L 03/11/2015 Arsenic EPA 200.8 0.000446 J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Barium EPA 200.8 < 0.400 mg/L 03/17/2015 Beryllium EPA 200.8 <0.000146mg/L 03/10/2015 Cadmium EPA 200.8 <0.0000967mg/L 03/11/2015 Chromium EPA 200.8 0.000254 J mg/L 03/10/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Cobalt EPA 200.8 0.002 mg/L 03/1112015 Copper EPA 200.8 0.001 mg/L 03/10/2015 Lead EPA 200.8 0.000661 J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Report #:: 2015-02482 Page 1 of 2 Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) SM 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Duke Energy -Laboratory Date of Report: Apr 20, 2015 1339 Hagers Ferry Road/Bid 7405 MG03A2 Customer PO #: Huntersville NC 28078 Customer ID: 15030001 Attention: Report #: 2015-02482 Project ID: Ash Pond Investigation Manganese EPA200.8 0.274mg/L 03/11/2015 Selenium EPA200.8 < 0.010 mg/L 03/17/2015 Thallium EPA200.8 <0.0000878mg/L 03/11/2015 Vanadium EPA 200.8 0.000197 J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Hexavalent Chromium EPA 218.7 <0.02 pg/L 03/09/2015 Mercury EPA 245.1 <0.0004 mg/L 03/03/2015 Sulfate EPA300.0 76mg/L 03/04/2015 Turbidity SM 2130 B 0.5 NTU 03/0312015 Field Turbidity 1.5 NTU. Alkalinity SM2320B 3mg/L 03109/2015 Conductivity SM2510B 291 umho/cm 03/05/2015 Total Dissolved Solids (TDS) SM 2540 C 185 mg/L 03103/2015 Residue Suspended (TSS) SM2540D <3.1 mg/L 03/03/2015 Temperature SM 2550 B 20.4 C 03/02/2015 Chloride SM 4500 CI B 20 mg/L 03/04/2015 pH SM 4500 H B 6.38 units 03/02/2015 Dissolved Oxygen SM45000G 5.09mg/L 03/02/2015 Comment: Turbidity, temperature, pH and dissolved oxygen measured in field at sample collection. All non - detects for metals reported to MDL. Reviewed by Report #:: 2015-02482 Page 2 of 2 Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 25405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) SM 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 QC for Duke Energy - 2015-02482 LCS Parameter True Value m 2 Result m %True Value Limits Alkalinity 50 54 108 90-110 Aluminum 0.05 0.05 100 90-110 Antimony 0.01 0.01 100 90-110 Arsenic 0.01 0.01 100 90-110 Barium 0.01 0.01 100 90-110 Beryllium 0.01 0.01 100 90-110 Boron 0.05 0.05 100 90-110 Cadmium 0.01 0.01 100 90-110 Calcium 0.5 0.5 100 90-110 Chloride 50 48 96 90-110 Chromium 0.01 0.01 100 90-110 Cobalt 0.01 0.01 100 90-110 Conductivity 10000 99800 99.8 90-110 Copper 0.01 0.01 100 90-110 Iron 0.05 0.05 100 90-110 Lead 0.01 0.01 100 90-110 Magnesium 0.5 0.5 100 90-110 Manganese 0.01 0.01 100 90-110 Mercury 0.0040 0.0038 95 90-110 Molybdenum 0.05 0.05 100 90-110 Nickel 0.05 0.05 100 90-110 Potassium 0.5 0.5 100 90-110 TSS 248.8 274.4 110 90-110 Selenium 0.01 0.01 100 90-110 Sodium 0.5 0.5 100 90-110 Strontium 0.05 0.05 100 90-110 Sulfate 50 49 98 90-110 Thallium 0.01 0.01 100 90-110 TDS 600 600 100 ±10 Turbidity N/A N/A N/A N/A Vanadium 0.01 0.01 100 90-110 Zinc 0.05 0.05 100 90-110 MS/MSD Parameter True Value mg/L Result mg/L % Recovery % Difference Limits % Recovery Limits % Difference Alkalinity N/A N/A N/A N/A N/A N/A Aluminum 0.100 0.099/0.100 99/100 1 80-120 <_20 Antimony 0.025 0.027/0.026 108/104 4 80-120 < 20 Arsenic 0.025 0.029/0.029 116/116 0 80-120 <20 Barium 0.025 0.025/0.026 100/104 4 80-120 :5 20 Beryllium 0.025 0.029/0.029 116/116 0 80-120 <20 Boron 0.100 0.097/0.095 97/95 2 80-120 :5 20 Cadmium 0.025 0.027/0.026 108/104 4 80-120 <20 Calcium 1.0 1.0/1.0 100/100 0 80-120 <_ 20 Chloride N/A N/A N/A N/A N/A N/A Chromium 0.025 0.024/0.025 96/100 4 80-120 <_ 20 Cobalt 0.025 0.024/0.023 96/92 4 80-120 <20 Conductivity N/A N/A N/A N/A N/A N/A Copper 0.025 0.027/0.028 108/112 4 80-120 <20 Iron 0.100 0.098/0.100 98/100 2 80-120 :5 20 Lead 0.025 0.024/0.023 96/92 4 80-120 <20 Magnesium 1.0 1.0/1.0 100/100 0 80-120 <_ 20 Manganese 0.025 0.023/0.023 92/92 0 80-120 :5 20 Mercury 0.0020 0.0020/0.0018 100/90 10 80-120 <20 Molybdenum 0.100 0.100/0.099 100/99 1 80-120 <20 Nickel 0.100 0.098/0.099 98/99 1 80-120 :5 20 Potassium 1.0 1.0/1.0 100/100 0 80-120 <20 TSS N/A N/A N/A N/A N/A N/A Selenium 0.025 0.02910.026 116/104 11 80-120 <_ 20 Sodium 1.0 1.0/1.0 100/100 0 80-120 <20 Strontium 0.100 0.098/0.105 98/105 7 80-120 :5 20 Sulfate 10.0 10.5/10.9 105/109 4 80-120 5-20 Thallium 0.025 0.024/0.024 96/96 0 80-120 5 20 TDS N/A N/A N/A N/A N/A N/A Turbidity N/A N/A N/A N/A N/A N/A Vanadium 0.025 0.024/0.025 96/100 4 80-120 <_ 20 Zinc 0.100 0.099/0.102 99/102 3 80-120 <20 DUPLICATE SAMPLES Parameter Results mg/L % Difference Limits Alkalinity 176 177 1 < 10 Aluminum N/A N/A N/A N/A Antimony N/A N/A N/A N/A Arsenic N/A N/A N/A N/A Barium N/A N/A N/A N/A Beryllium N/A N/A N/A N/A Boron N/A N/A N/A N/A Cadmium N/A N/A N/A N/A Calcium N/A N/A N/A N/A Chloride 6 6 0 < 10 Chromium N/A N/A N/A N/A Cobalt N/A N/A N/A N/A Conductivity 2145 2145 0 < 10 Copper N/A N/A N/A N/A Iron N/A N/A N/A N/A Lead N/A N/A N/A N/A Magnesium N/A N/A N/A N/A Manganese N/A N/A N/A N/A Mercury N/A N/A N/A N/A Molybdenum N/A N/A N/A N/A Nickel N/A N/A N/A N/A Potassium N/A N/A N/A N/A TSS 24.7 23.3 6 < 10 Selenium N/A N/A N/A N/A Sodium N/A N/A N/A N/A Strontium N/A N/A N/A N/A Sulfate 19 20 5 <_10 Thallium N/A N/A N/A N/A TDS 1460 1483 2 <_ 10 Turbidity 0.39 0.39 0 < 10 Vanadium N/A N/A N/A N/A Zinc N/A N/A N/A N/A BLANKS Parameter Rmg�r Limit, mg/L Alkalinity <0.5 0.5 Aluminum <0.005 0.005 Antimony <0.0005 0.0005 Arsenic <0.0005 0.0005 Barium <0.0005 0.0005 Beryllium <0.0005 0.0005 Boron <0.005 0.005 Cadmium <0.0005 0.0005 Calcium <0.5 0.5 Chloride <2.5 2.5 Chromium <0.0005 0.0005 Cobalt <0.0005 0.0005 Conductivity <5 5 Copper <0.0005 0.0005 Iron <0.005 0.005 Lead <0.0005 0.0005 Magnesium <0.5 0.5 Manganese <0.0005 0.0005 Mercury <0.0002 0.0002 Molybdenum <0.005 0.005 Nickel <0.005 0.005 Potassium <0.5 0.5 TSS <2.5 2.5 Selenium <0.0005 0.0005 Sodium <0.5 0.5 Strontium <0.005 0.005 Sulfate <2.5 2.5 Tballium <0.0005 0.0005 TDS <2.5 2.5 Turbidity N/A N/A Vanadium <0.0005 0.0005 Zinc <0.005 0.005 el, elementOne FINAL REPORT OF ANALYSES Element One Inc. 6319-D Carolina Beach Rd. Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 ellab@eliab.com Ray Porter March 09, 2015 Environmental Chemists, Inc. Client Project Name: 66002 Windmill Way Client Project Number: Wilmington, NC 28405 E1 Project Number e24189 Sample # Sample ID 15-05546 Sample Matrix DW Sample Type Date Received 03/06/2015 Date Sampled 03/02/2015 Time Sampled 1445 Time Received 0810 Delivered by Client Sampler Received by KMS E1 Sample # 24189-1 Parameter Result Unit Dilution DL Method Date Chromium VI < 0.02 pg/L 1 0.02 EPA 218.7 03/09/2015 KeA Smith, Laboratory Director 24189 Envirochem Cr6+Report Compiled by—L�3 NC Certifications: DW 37788 and DWQ DENR 604 m r� M L u W wF W C! W m T z `1 a NMUO T m Z OIH1 O 0 H Q HOtlN U w LLI £ONH W Q y W 4OSZH dIOH 3NON 2138wnN Ol 9Vl d J/6w ouuolyp R 0 (DJad) a Ur a O a 0 d 0 d U' m O a 0 m 0 m 0 m 0 JouleWoo .o C) (D (D 0 (D (D C) (D C) 0 000 000 e4lsodwoo adRl oldweg CL m r d F A N m � a c O = (D o U m � M O a`, V < � )to LT (D w 4; C i= 0 z 7 O z Z H s\®®ƒ }){§ (/\ /&7&z �©\{) §�(\ / \}{/ ! _ ®f 2 n � /[2 �$ 3 A L V V V V V V V V V V V V L J2 M tD N Ln O o0 N N O lfl 0) a ^ 0o O N 1, to tD to O N M Il 0) M V 00 a-i M N O N (n 0) tD m N J Q 0) V W 0 ei IT ^ N m Ol -zr I, m m Ol 0) O m O m N VT N tD tD tD m oo m m m ci CT M d' 1, CT 00 a} O Ln N Ol tD 01 Ol V 00 N N tD N ^ (n ^ r in m tD � m d' O `~ 3 �n N Ol O O at N (l O O O O O O O O O O O O O 0) m N O O O al N M iy m c-I ^ M^^ CF N Z ci ci N V V m M M V d' V V' Ct [F V V V V V M M M a V V m V C^ c-I Ln 00 tD W y^ooavvvvvvvvvvvv�vvvvavv^vvwr, t, t, D`l m ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ kDmr, ti ^ a � ^ a Ln .1O- m O m0 U U o U s m m m m (D m ,w ^ ^ ^ ^ ^ ^ ^ ^ ^ n ^ m oo oo oo m m oo oo oo oo oo oo oD ^ .-� O m m m U 0 m U m O p m o o o o o o o o o o o o o o o o O o o o o O O O W M 0 0 0 0 0 0 0 0 0 0 C 00055000000000000000000 0 ti c1' O M N c V' V' m O O O -fl O N N N N N N N N N N N N N N N N N N N N N N N N N N M `~ N m NGG m Nc m NGG m Ncc M Nc m M m �cc u Q Q Q Q Q Q Q Q Q Q Q Q¢ Q Q Q Q Q Q Q Q Q Q Q Q Q Q c c c�c c�c m U W W W W W W W W W W W W W W W W W W W w W W W W W W W W W N VI VI to m N In N N N 0 � O O �_ v O c� m U E O a m mm U r a v o�q C m m E U >, > a N X Q °"' E E E v 0 3 7 O 7 CD E c E E amp E E E > a' N v m m— —'0 O L: C E '^ m a— rn E 7 p U E_ 7 7 •— a.+ L C m 7 7— m i m a+ = C V .— 0 m �. W a 0> 01 m 7 V c Y o u p 7 a a m m x a o o m O U a N m L m m m 7 7 y 0 0 m m 2 N m U Q m U O< c c G Z 0- lO N N Q¢ m m V U V U J N H_ M H¢ U f- K �- U U a 0 N 0 H lg� m M O M a U O p v a. t° } m U t a N E u > a d X M E 'R 6 7 7 O o c E c v E '" p c E>? E yCL 3 a> 7 .m. a 3 Q v v u w c X v .E `m 7 0 o m o o o `m v m s` o o O m m BU¢muo_in Ln iv¢¢mmuUUU��NH>2 v7iH¢UFp-�F�v a0 Lm a E z Z m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m OVI VI VI 1A m N N N VI m N VI N H Vf Vl N m N m Vl m N m VI m Vl VI VI N N V1 N VI Vf h N� A Y 7 C L m a E Z d m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m m N VI N N N V1 N to m VI y V1 N VI N N N N VI N VI N to m Vf N V1 m N VI m VI N N N N N m 01 O Y 7 C d w a J J J J J J J J J J J J J J J J J J J J J J J J J J J J J J V J J J\\\\'oUE 00 00 00 00 00 Z E E E E E E E E E E E E E E E E E E E E E E E E E E E Etxo E E E E E E EE E E E E E E jbf 0 0 0 0 0 0 N r ti ti v a-1 a-1 O '"� '�+ "� 0 0 `~ N `� � a 0 O� 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0� 0 '�'"� 0 O `'"� C 0 0 0 0 ' 0 0 0 0 0 0 o c o 0 0 0 o p o o p o Y = J J JJ J J JJ-\ \ \ \ \ \�UN IV E E E E E E E E E E E E E E E E E E E E E E E Y E E Z E E E E 3 E z 3 0 e N d' O V Ol M -�T `" ci N N , 00 in� d' tD Ln N i-1 V e-1 to "' N d' to to M c-I Ln ci CD00 Ol O tD 00 `~ V V c-I N 0 M^ tD V O a 0't m 0 0 0 0 c-I tD 1, N O O n O O 0 n O 01 N 00 M N N M O y M O N M^ N' I `~ ul O W(n 0 O `~ O II1 O O 0 O O O O cnCD 0 F, D O O p 0 00 O � O O O CD CD^ O p 0 O 0) 0 0 0) O O 00 0 6 6 O 6