NC0000396_App B Lab Reports - WS Wells - J16060136report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16060136
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:6/29/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 4500S2D: Matrix spike/spike duplicate associated with 2016016104 recovered low due to matrix interference. Batch QC
including LCS were acceptable.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 47
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016016104 ASHEVILLE 06-Jun-16 11:15 AM C.E.AS-20
1 Total Samples
Duke Energy Analytical Lab
Page 2 of 47
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:6/29/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
2016016104
Collection Date:06-Jun-16 11:15 AM
Site:AS-20
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.019 mg-N/L EPA 353.2 06/13/2016 13:44 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 20 mg/L EPA 300.0 06/09/2016 10:43 BGN9034110
Sulfate 150 mg/L EPA 300.0 06/09/2016 10:43 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2016 13:50 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)61.4 mg/L EPA 200.7 06/08/2016 14:34 MHH71310.01 1
Magnesium (Mg)5.06 mg/L EPA 200.7 06/08/2016 14:34 MHH71310.005 1
Potassium (K)3.95 mg/L EPA 200.7 06/08/2016 14:34 MHH71310.1 1
Sodium (Na)22.6 mg/L EPA 200.7 06/08/2016 14:34 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.056 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.005 1
Barium (Ba)0.038 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.005 1
Boron (B)0.108 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.05 1
Iron (Fe)1.63 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.01 1
Manganese (Mn)0.033 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.005 1
Strontium (Sr)0.275 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/13/2016 09:44 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
2016016104
Collection Date:06-Jun-16 11:15 AM
Site:AS-20
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Copper (Cu)5.74 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Molybdenum (Mo)1.61 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/10/2016 16:50 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 320 mg/L SM2540C 06/09/2016 12:15 PARMSTR251
Total Carbon
TOC 0.201 mg/L SM5310C/EPA9060A 06/07/2016 15:41 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L SM2540D 06/10/2016 11:30 PARMSTR51
Duke Energy Analytical Lab
Page 5 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060338 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0012 mg-N/L -1-0.0012 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0006 mg-N/L -10.0006 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0028 mg-N/L -10.0028 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
1.01 1.25 105mg-N/L -55.04
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
1.01 1.25 105 0.0762mg-N/L -55.04
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.7mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.3 3.01 99.8mg-N/L -11090103
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 100mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16050325 -- 2016013494
Nitrite + Nitrate
(Colorimetric)
0.224 0.25 96.3mg-N/L -1109010.224
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16050325 -- 2016013494
Nitrite + Nitrate
(Colorimetric)
0.227 0.25 97.2 0.992mg-N/L -1109010.227
Duke Energy Analytical Lab
Page 6 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060338 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16060240 -- 2016016646
Nitrite + Nitrate
(Colorimetric)
0.112 0.25 57.1mg-N/L -1109010.112
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16060240 -- 2016016646
Nitrite + Nitrate
(Colorimetric)
0.112 0.25 57.1 0.0701mg-N/L -1109010.112
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16060079 -- 2016015881
Nitrite + Nitrate
(Colorimetric)
1.59 0.25 102mg-N/L -1109011.59
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16060079 -- 2016015881
Nitrite + Nitrate
(Colorimetric)
1.58 0.25 97.3 4.54mg-N/L -1109011.58
Duke Energy Analytical Lab
Page 7 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060187 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0319 mg/L -10.0319 0.1 < 1/2 RDL
Sulfate 0.0081 mg/L -10.0081 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 6.15 5 102mg/L -1208016.15
Sulfate 7.98 5 99.8mg/L -1208017.98
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 6.17 5 102 0.39mg/L -1208016.17
Sulfate 8 5 100 0.282mg/L -1208018
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.1 5 102mg/L -1208015.1
Sulfate 5.05 5 101mg/L -1208015.05
Duke Energy Analytical Lab
Page 8 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060438 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.014 ug/L -10.014 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.016 ug/L -10.016 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Mercury (Hg) 0.019 ug/L -10.019 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.02 2 101ug/L -1158512.02
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 2.06 2 103ug/L -1158512.06
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Mercury (Hg) 2.07 2 103ug/L -1158512.07
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16050050 -- 2016012389
Mercury (Hg) 0.985 1 97.1ug/L -1307010.985
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16050050 -- 2016012389
Mercury (Hg) 0.963 1 94.9 2.29ug/L -1307010.963
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16050050 -- 2016012390
Mercury (Hg) 0.975 1 96.1ug/L -1307010.975
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16050050 -- 2016012390
Mercury (Hg) 0.988 1 97.4 1.34ug/L -1307010.988
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16050050 -- 2016012392
Mercury (Hg) 1.03 1 102ug/L -1307011.03
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16050050 -- 2016012392
Mercury (Hg) 1.01 1 100 1.69ug/L -1307011.01
Duke Energy Analytical Lab
Page 9 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060207 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00209 mg/L -10.00209 0.01 < 1/2 RDL
Magnesium (Mg) -0.000099 mg/L -1-0.000099 0.005 < 1/2 RDL
Potassium (K) -0.00154 mg/L -1-0.00154 0.1 < 1/2 RDL
Sodium (Na) 0.00251 mg/L -10.00251 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 1.97 2 98.5mg/L -1158511.97
Magnesium (Mg) 1.93 2 96.7mg/L -1158511.93
Potassium (K) 3.89 4 97.2mg/L -1158513.89
Sodium (Na) 8.03 8.1 99.1mg/L -1158518.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060079 -- 2016015871
Calcium (Ca) 50.6 5 101mg/L -13070150.6
Magnesium (Mg) 17.6 5 108mg/L -13070117.6
Potassium (K) 6.57 5 109mg/L -1307016.57
Sodium (Na) 18.5 5 104mg/L -13070118.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060079 -- 2016015871
Calcium (Ca) 50.8 5 105 4.08mg/L -13070150.8
Magnesium (Mg) 17.6 5 110 1.12mg/L -13070117.6
Potassium (K) 6.58 5 109 0.147mg/L -1307016.58
Sodium (Na) 18.5 5 105 1.36mg/L -13070118.5
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16060079 -- 2016015881
Calcium (Ca) 33.6 5 102mg/L -13070133.6
Magnesium (Mg) 11.9 5 105mg/L -13070111.9
Potassium (K) 7.15 5 107mg/L -1307017.15
Sodium (Na) 53 5 109mg/L -13070153
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16060079 -- 2016015881
Calcium (Ca) 33.4 5 98.8 2.97mg/L -13070133.4
Magnesium (Mg) 11.9 5 104 1.82mg/L -13070111.9
Potassium (K) 7.1 5 106 0.958mg/L -1307017.1
Sodium (Na) 52.8 5 106 3.39mg/L -13070152.8
Duke Energy Analytical Lab
Page 10 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060269 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.0008 mg/L -10.0008 0.005 < 1/2 RDL
Barium (Ba) 0.00003 mg/L -10.00003 0.005 < 1/2 RDL
Boron (B) 0.000286 mg/L -10.000286 0.05 < 1/2 RDL
Iron (Fe) 0.000759 mg/L -10.000759 0.01 < 1/2 RDL
Manganese (Mn) -0.000268 mg/L -1-0.000268 0.005 < 1/2 RDL
Strontium (Sr) -0.000247 mg/L -1-0.000247 0.005 < 1/2 RDL
Zinc (Zn) 0.000099 mg/L -10.000099 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.8 5 96.1mg/L -1158514.8
Barium (Ba) 5.03 5 101mg/L -1158515.03
Boron (B) 5.02 5 100mg/L -1158515.02
Iron (Fe) 5.11 5 102mg/L -1158515.11
Manganese (Mn) 5.06 5 101mg/L -1158515.06
Strontium (Sr) 4.94 5 98.7mg/L -1158514.94
Zinc (Zn) 5.07 5 101mg/L -1158515.07
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060190 -- 2016016362
Aluminum (Al) 4.76 5 94.5mg/L -1307014.76
Barium (Ba) 5.15 5 99.4mg/L -1307015.15
Boron (B) 5.03 5 100mg/L -1307015.03
Iron (Fe) 5.45 5 101mg/L -1307015.45
Manganese (Mn) 5.09 5 99.7mg/L -1307015.09
Strontium (Sr) 5.01 5 97.7mg/L -1307015.01
Zinc (Zn) 5 5 99.7mg/L -1307015
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060190 -- 2016016362
Aluminum (Al) 4.8 5 95.4 0.948mg/L -1307014.8
Barium (Ba) 5.17 5 99.9 0.462mg/L -1307015.17
Boron (B) 5.07 5 101 0.834mg/L -1307015.07
Iron (Fe) 5.5 5 102 1.05mg/L -1307015.5
Manganese (Mn) 5.12 5 100 0.52mg/L -1307015.12
Strontium (Sr) 5.04 5 98.3 0.551mg/L -1307015.04
Zinc (Zn) 5.04 5 101 0.899mg/L -1307015.04
Duke Energy Analytical Lab
Page 11 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060276 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0845 ug/L -1-0.0845 1 < 1/2 RDL
Arsenic (As) 0.0063 ug/L -10.0063 1 < 1/2 RDL
Beryllium (Be) 0.0228 ug/L -10.0228 1 < 1/2 RDL
Cadmium (Cd) -0.0005 ug/L -1-0.0005 1 < 1/2 RDL
Chromium (Cr) -0.0787 ug/L -1-0.0787 1 < 1/2 RDL
Cobalt (Co) -0.0002 ug/L -1-0.0002 1 < 1/2 RDL
Copper (Cu) -0.0275 ug/L -1-0.0275 1 < 1/2 RDL
Lead (Pb) -0.0017 ug/L -1-0.0017 1 < 1/2 RDL
Molybdenum (Mo) 0.0069 ug/L -10.0069 1 < 1/2 RDL
Nickel (Ni) -0.0166 ug/L -1-0.0166 1 < 1/2 RDL
Selenium (Se) -0.0284 ug/L -1-0.0284 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0142 ug/L -1-0.0142 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.0109 ug/L -1-0.0109 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.1 50 98.2ug/L -11585149.1
Arsenic (As) 48.2 50 96.3ug/L -11585148.2
Beryllium (Be) 50.3 50 101ug/L -11585150.3
Cadmium (Cd) 48.1 50 96.3ug/L -11585148.1
Chromium (Cr) 47.7 50 95.4ug/L -11585147.7
Cobalt (Co) 47.9 50 95.8ug/L -11585147.9
Copper (Cu) 47.7 50 95.3ug/L -11585147.7
Lead (Pb) 49.2 50 98.4ug/L -11585149.2
Molybdenum (Mo) 48.7 50 97.4ug/L -11585148.7
Nickel (Ni) 47.9 50 95.8ug/L -11585147.9
Selenium (Se) 47.1 50 94.2ug/L -11585147.1
Thallium (Tl) Low Level 47.5 50 95.1ug/L -11585147.5
Vanadium (V) Low Level 47.4 50 94.9ug/L -11585147.4
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060136 -- 2016016104
Antimony (Sb) 49.1 50 98.3ug/L -13070149.1
Arsenic (As) 48.8 50 97.4ug/L -13070148.8
Beryllium (Be) 50.6 50 101ug/L -13070150.6
Cadmium (Cd) 48 50 96ug/L -13070148
Chromium (Cr) 47.9 50 95.5ug/L -13070147.9
Cobalt (Co) 47.7 50 95.3ug/L -13070147.7
Copper (Cu) 53 50 94.5ug/L -13070153
Lead (Pb) 49.5 50 97.3ug/L -13070149.5
Duke Energy Analytical Lab
Page 12 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060276 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060136 -- 2016016104
Molybdenum (Mo) 50.9 50 98.5ug/L -13070150.9
Nickel (Ni) 47.8 50 95.3ug/L -13070147.8
Selenium (Se) 47.9 50 95.6ug/L -13070147.9
Thallium (Tl) Low Level 48.2 50 96.4ug/L -13070148.2
Vanadium (V) Low Level 48.3 50 96.1ug/L -13070148.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060136 -- 2016016104
Antimony (Sb) 48.6 50 97.2 1.1ug/L -13070148.6
Arsenic (As) 48.3 50 96.4 0.998ug/L -13070148.3
Beryllium (Be) 49.4 50 98.3 2.44ug/L -13070149.4
Cadmium (Cd) 47.6 50 95.2 0.814ug/L -13070147.6
Chromium (Cr) 46.8 50 93.2 2.34ug/L -13070146.8
Cobalt (Co) 46.8 50 93.6 1.83ug/L -13070146.8
Copper (Cu) 52.4 50 93.4 1.2ug/L -13070152.4
Lead (Pb) 49.5 50 97.5 0.139ug/L -13070149.5
Molybdenum (Mo) 50.4 50 97.5 0.986ug/L -13070150.4
Nickel (Ni) 47.3 50 94.3 0.979ug/L -13070147.3
Selenium (Se) 47.2 50 94.3 1.42ug/L -13070147.2
Thallium (Tl) Low Level 47.9 50 95.8 0.636ug/L -13070147.9
Vanadium (V) Low Level 47.3 50 94.2 2.01ug/L -13070147.3
Duke Energy Analytical Lab
Page 13 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060232 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060136 -- 2016016104
TDS 1.25mg/L -1317
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060180 -- 2016016295
TDS 4.56mg/L -1897
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16060180 -- 2016016296
TDS 1.73mg/L -1401
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 97mg/L -11090197
Duke Energy Analytical Lab
Page 14 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060149 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.027 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208015.68
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 87 18.6mg/L -1208015.33
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 100mg/L -1208013
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 97.2 2.89mg/L -1208012.94
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 103mg/L -1158512.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 104mg/L -1158512.99
Duke Energy Analytical Lab
Page 15 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16060136
Q16060265 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -1-0.2 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16050321 -- 2016013478
TSS 8mg/L -12.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16050321 -- 2016013479
TSS 0mg/L -10
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16050331 -- 2016013521
TSS 0mg/L -14.4
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 95.2mg/L -147.6
Duke Energy Analytical Lab
Page 16 of 47
#=CL#
June 22, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92300360
92300360
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16060136
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on June 06, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
Page 1 of 18
Duke Energy Analytical Lab
Page 17 of 47
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92300360
J16060136
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 2 of 18
Duke Energy Analytical Lab
Page 18 of 47
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92300360
J16060136
Lab ID Sample ID Matrix Date Collected Date Received
92300360001 2016016104 Water 06/06/16 11:15 06/06/16 14:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 19 of 47
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92300360
J16060136
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92300360001 2016016104 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
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Duke Energy Analytical Lab
Page 20 of 47
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92300360
J16060136
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92300360001 2016016104
Methane 174 ug/L 06/09/16 17:1610.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)56.7 mg/L 06/09/16 23:305.0SM 2320B
Alkalinity, Total as CaCO3 56.7 mg/L 06/09/16 23:305.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 18
Duke Energy Analytical Lab
Page 21 of 47
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92300360
J16060136
Method:
Client:Duke Energy
RSK 175 Modified
Date:June 22, 2016
Description:RSK 175 Headspace
General Information:
1 sample was analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 18
Duke Energy Analytical Lab
Page 22 of 47
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92300360
J16060136
Method:
Client:Duke Energy
SM 2320B
Date:June 22, 2016
Description:2320B Alkalinity
General Information:
1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 18
Duke Energy Analytical Lab
Page 23 of 47
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92300360
J16060136
Method:
Client:Duke Energy
SM 4500-S2D
Date:June 22, 2016
Description:4500S2D Sulfide Water
General Information:
1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/45493
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92300360001
M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences.
• MS (Lab ID: 1754330)
• Sulfide
• MSD (Lab ID: 1754331)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 18
Duke Energy Analytical Lab
Page 24 of 47
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92300360
J16060136
Method:
Client:Duke Energy
EPA 218.7
Date:June 22, 2016
Description:Hexavalent Chromium by IC
General Information:
1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 18
Duke Energy Analytical Lab
Page 25 of 47
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92300360
J16060136
Sample:2016016104 Lab ID:92300360001 Collected:06/06/16 11:15 Received:06/06/16 14:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 174 ug/L 06/09/16 17:16 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)56.7 mg/L 06/09/16 23:305.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 06/09/16 23:305.0 1
Alkalinity, Total as CaCO3 56.7 mg/L 06/09/16 23:305.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 06/13/16 14:20 18496-25-8 M10.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 06/09/16 18:19 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 18
Duke Energy Analytical Lab
Page 26 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92300360
J16060136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/10669
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92300360001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1751911
Associated Lab Samples:92300360001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 06/09/16 17:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1751912LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 411396 104 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1751913MATRIX SPIKE SAMPLE:
MSSpike
Result
92300456001
Methane ug/L 481396 121 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92300456002
1751915SAMPLE DUPLICATE:
Methane ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 11 of 18
Duke Energy Analytical Lab
Page 27 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92300360
J16060136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/45399
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92300360001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1750844
Associated Lab Samples:92300360001
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 06/09/16 21:07
Alkalinity, Total as CaCO3 mg/L ND 5.0 06/09/16 21:07
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 06/09/16 21:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1750845LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.350 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1750846MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92300104001
1750847
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 92 80-120100 4 255046.3 92.2 96.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1750848MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92300237002
1750849
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12098 0 255035.4 84.3 84.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
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Duke Energy Analytical Lab
Page 28 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92300360
J16060136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/45493
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92300360001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1754328
Associated Lab Samples:92300360001
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 06/13/16 14:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1754329LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.46.5 92 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1754330MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92300360001
1754331
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M3.5 57 90-11057 0 10.5ND 0.33 0.33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
Pace Analytical Services, Inc.
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[phone]
Page 13 of 18
Duke Energy Analytical Lab
Page 29 of 47
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92300360
J16060136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/58556
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92300360001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1599710
Associated Lab Samples:92300360001
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 06/09/16 10:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1599711LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.075.075 100 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1599712MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92300115001
1599713
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 91 85-11586 5 20.0750.013J 0.082 0.078
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
Pace Analytical Services, Inc.
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Duke Energy Analytical Lab
Page 30 of 47
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92300360
J16060136
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
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Duke Energy Analytical Lab
Page 31 of 47
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92300360
J16060136
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92300360001 GCV/106692016016104RSK 175 Modified
92300360001 WET/453992016016104SM 2320B
92300360001 WET/454932016016104SM 4500-S2D
92300360001 WETA/585562016016104EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 06/22/2016 11:45 AM
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Page 17 of 18
Duke Energy Analytical Lab
Page 33 of 47
Page 18 of 18
Duke Energy Analytical Lab
Page 34 of 47

June 17, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 398833
SDG: J16060136

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 07, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 12
Chelsea Seagle for
Duke Energy Analytical Lab
Page 35 of 47
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16060136 GEL Work Order: 398833
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
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Duke Energy Analytical Lab
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Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: June 17, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1572936
1572936
1573005
1573912
0922
1100
1447
0905
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
06/16/16
06/16/16
06/13/16
06/17/16
SKJ
SKJ
AXM6
LXP1
0.00005
0.00005
0.00005
0.0002
1.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
398833001
Water
06-JUN-16 11:15
07-JUN-16
2016016104 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"88.1 (15%-125%)
0.00001
0.00001
0.00001
0.000067
0.550
0.562
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/08/16 15729350835JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
0.000614
6.72
8.38
NominalResult
RLDL
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1572936Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
June 17, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 06/16/16 09:23
06/16/16 11:01
06/16/16 10:58
06/16/16 09:20
06/16/16 09:19
06/16/16 10:57
06/16/16 11:03
06/16/16 09:25
06/16/16 09:26
QC
ND
ND
ND
0.000751
0.052
0.000557
0.000634
0.0052
ND
ND
ND
ND
0.0533
0.000573
0.000643
0.00537
ND
NOM Sample
ND
ND
ND
0.000614
0.000614
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203563246 398833001
QC1203563245
QC1203563301
QC1203563244
QC1203563247 398833001
QC1203563302 398833001
QC1203563248 398833001
N/A
N/A
N/A
20.1
N/A
REC%
105
111
115
104
106
115
117
107
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
398833Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1572936
1573005
1573912
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
06/16/16 09:26
06/16/16 11:04
06/13/16 14:47
06/13/16 14:47
06/13/16 14:47
06/17/16 10:05
06/17/16 10:05
06/17/16 10:05
06/17/16 10:05
QC
ND
ND
0.129
4.70
14.4
-0.248
0.256
26.9
0.216
97.9
NOM Sample
ND
ND
0.614
6.72
0.505
0.505
Range
(0%-10%)
(0%-10%)
(0%-20%)
(75%-125%)
N/A
(75%-125%)
(75%-125%)
Qual
U
U
J
U
U
U
QC1203563453 398833001
QC1203563454
QC1203563452
QC1203565720 398747001
QC1203565722
QC1203565719
QC1203565721 398747001
The Qualifiers in this report are defined as follows:
N/A
N/A
5.44
35.4
N/A
REC%
94.5
110
80.3
15.2
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
398833Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
U
*
RPD%
Notes:
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Duke Energy Analytical Lab
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
398833Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16060136
Work Order #: 398833

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1572936

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1572935
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
398833001 2016016104
1203563244 Method Blank (MB)ICP-MS
1203563245 Laboratory Control Sample (LCS)
1203563301 Laboratory Control Sample (LCS)
1203563248 398833001(2016016104L) Serial Dilution (SD)
1203563246 398833001(2016016104D) Sample Duplicate (DUP)
1203563247 398833001(2016016104S) Matrix Spike (MS)
1203563302 398833001(2016016104S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1573005
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
398833001 2016016104
1203563452 Method Blank (MB)
1203563453 398833001(2016016104) Sample Duplicate (DUP)
1203563454 Laboratory Control Sample (LCS)
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The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The sample and the
duplicate, 1203563453 (2016016104DUP) and 398833001 (2016016104), did not meet the relative percent
difference requirement; however, they do meet the relative error ratio requirement with a value of 1.6925.

Technical Information

Recounts
Samples 1203563453 (2016016104DUP) and 398833001 (2016016104) were re-eluted to verify the results. The
original counts are reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1573912
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
398833001 2016016104
1203565719 Method Blank (MB)
1203565720 398747001(NonSDG) Sample Duplicate (DUP)
1203565721 398747001(NonSDG) Matrix Spike (MS)
1203565722 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203565721 (Non SDG 398747001MS), aliquot was reduced to conserve sample volume.

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Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 17 June 2016
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Duke Energy Analytical Lab
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