NC0000396_App B Lab Reports - WS Wells - J16050329report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16050329
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:6/1/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:
Report Authorized By:
(Signature)
Program Comments:
As per groundwater assessment plan, all sampling wells should be accompanied by an equipment and filter blank. Additionally,
a separate chain of custody document should be provided for private wells and surface waters. For the surface waters included
in this work order, volume for Hg 1631 should have been collected.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 50
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016013510 ASHEVILLE 11-May-16 7:48 AM TDP AS-14
2016013517 ASHEVILLE 11-May-16 10:30 AM TDP SW-100
2016013518 ASHEVILLE 11-May-16 11:05 AM TDP SW-101
2016013519 ASHEVILLE 11-May-16 11:45 AM TDP SW-102
2016013520 ASHEVILLE 11-May-16 12:30 PM TDP SW-103
5 Total Samples
Duke Energy Analytical Lab
Page 2 of 50
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:5/27/2016
Electronic Data Deliverable (EDD) Sent Separately
Duke Energy Analytical Lab
Page 3 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013510
Collection Date:11-May-16 7:48 AM
Site:AS-14
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.036 mg-N/L EPA 353.2 05/16/2016 11:16 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.5 mg/L EPA 300.0 05/16/2016 19:17 BGN90340.5 5
Sulfate 250 mg/L EPA 300.0 05/16/2016 19:17 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:26 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)114 mg/L EPA 200.7 05/17/2016 14:27M4 MHH71310.1 10
Magnesium (Mg)13.9 mg/L EPA 200.7 05/17/2016 14:27 MHH71310.005 1
Potassium (K)4.46 mg/L EPA 200.7 05/17/2016 14:27 MHH71310.1 1
Sodium (Na)19.2 mg/L EPA 200.7 05/17/2016 14:27 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.005 1
Barium (Ba)0.029 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.005 1
Boron (B)0.339 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.05 1
Iron (Fe)0.695 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.01 1
Manganese (Mn)0.221 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.005 1
Strontium (Sr)0.480 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 05/16/2016 10:46 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Copper (Cu)2.04 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Lead (Pb)1.25 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Molybdenum (Mo)2.49 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 18:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 18:14 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/16/2016 18:14 MHALL30.3 1
Duke Energy Analytical Lab
Page 4 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013510
Collection Date:11-May-16 7:48 AM
Site:AS-14
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 510 mg/L SM2540C 05/16/2016 14:36 PARMSTR251
Total Carbon
TOC 0.347 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/13/2016 11:08 PARMSTR51
Duke Energy Analytical Lab
Page 5 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013517
Collection Date:11-May-16 10:30 AM
Site:SW-100
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 05/16/2016 11:17 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 300.0 05/17/2016 23:12 BGN90340.1 1
Sulfate 2.0 mg/L EPA 300.0 05/17/2016 23:12 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:28 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:43 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.055 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.05 1
Iron (Fe)1.70 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.01 1
Manganese (Mn)0.703 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.005 1
Strontium (Sr)0.036 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 05/18/2016 09:16 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.92 mg/L EPA 200.7 05/17/2016 14:39 MHH71310.01 1
Magnesium (Mg)2.84 mg/L EPA 200.7 05/17/2016 14:39 MHH71310.005 1
Potassium (K)1.22 mg/L EPA 200.7 05/17/2016 14:39 MHH71310.1 1
Sodium (Na)2.15 mg/L EPA 200.7 05/17/2016 14:39 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.215 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.005 1
Barium (Ba)0.041 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.05 1
Iron (Fe)4.06 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.01 1
Manganese (Mn)0.748 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.005 1
Strontium (Sr)0.036 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 05/16/2016 10:50 MHH71310.005 1
Duke Energy Analytical Lab
Page 6 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013517
Collection Date:11-May-16 10:30 AM
Site:SW-100
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Cobalt (Co)4.30 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 15:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 15:53 MHALL30.2 1
Vanadium (V) Low Level 0.567 ug/L EPA 200.8 05/16/2016 15:53 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Cobalt (Co)4.63 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 18:21 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 18:21 MHALL30.2 1
Vanadium (V) Low Level 1.58 ug/L EPA 200.8 05/16/2016 18:21 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 60 mg/L SM2540C 05/16/2016 14:36 PARMSTR251
Total Carbon
TOC 8.9 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.5 5
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L SM2540D 05/13/2016 11:08 PARMSTR51
Duke Energy Analytical Lab
Page 7 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013518
Collection Date:11-May-16 11:05 AM
Site:SW-101
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)3.0 mg-N/L EPA 353.2 05/16/2016 11:25 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.1 mg/L EPA 300.0 05/17/2016 23:30 BGN90340.1 1
Sulfate 0.86 mg/L EPA 300.0 05/17/2016 23:30 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:30 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:45 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.005 1
Strontium (Sr)0.051 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/18/2016 09:29 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.42 mg/L EPA 200.7 05/17/2016 14:43 MHH71310.01 1
Magnesium (Mg)2.52 mg/L EPA 200.7 05/17/2016 14:43 MHH71310.005 1
Potassium (K)1.25 mg/L EPA 200.7 05/17/2016 14:43 MHH71310.1 1
Sodium (Na)3.02 mg/L EPA 200.7 05/17/2016 14:43 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.264 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.005 1
Barium (Ba)0.040 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.05 1
Iron (Fe)0.281 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.01 1
Manganese (Mn)0.015 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.005 1
Strontium (Sr)0.050 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/16/2016 10:54 MHH71310.005 1
Duke Energy Analytical Lab
Page 8 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013518
Collection Date:11-May-16 11:05 AM
Site:SW-101
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 16:21 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 16:21 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/16/2016 16:21 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 18:28 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 18:28 MHALL30.2 1
Vanadium (V) Low Level 0.850 ug/L EPA 200.8 05/16/2016 18:28 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 30 mg/L SM2540C 05/16/2016 14:36 PARMSTR251
Total Carbon
TOC 0.371 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 65 mg/L SM2540D 05/13/2016 11:08 PARMSTR51
Duke Energy Analytical Lab
Page 9 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013519
Collection Date:11-May-16 11:45 AM
Site:SW-102
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.7 mg-N/L EPA 353.2 05/16/2016 11:19 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.2 mg/L EPA 300.0 05/17/2016 23:47 BGN90340.1 1
Sulfate 1.7 mg/L EPA 300.0 05/17/2016 23:47 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:33 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:52 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.005 1
Barium (Ba)0.035 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.05 1
Iron (Fe)0.095 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.01 1
Manganese (Mn)0.301 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.005 1
Strontium (Sr)0.053 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/18/2016 09:33 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.06 mg/L EPA 200.7 05/17/2016 14:47 MHH71310.01 1
Magnesium (Mg)2.53 mg/L EPA 200.7 05/17/2016 14:47 MHH71310.005 1
Potassium (K)1.20 mg/L EPA 200.7 05/17/2016 14:47 MHH71310.1 1
Sodium (Na)3.12 mg/L EPA 200.7 05/17/2016 14:47 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.89 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.005 1
Barium (Ba)0.046 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.05 1
Iron (Fe)2.50 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.01 1
Manganese (Mn)0.330 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.005 1
Strontium (Sr)0.055 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 05/16/2016 10:58 MHH71310.005 1
Duke Energy Analytical Lab
Page 10 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013519
Collection Date:11-May-16 11:45 AM
Site:SW-102
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Cobalt (Co)1.23 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 16:28 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 16:28 MHALL30.2 1
Vanadium (V) Low Level 0.394 ug/L EPA 200.8 05/16/2016 16:28 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Cobalt (Co)1.76 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 18:35 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 18:35 MHALL30.2 1
Vanadium (V) Low Level 2.14 ug/L EPA 200.8 05/16/2016 18:35 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 05/16/2016 14:36 PARMSTR251
Total Carbon
TOC 2.0 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 36 mg/L SM2540D 05/13/2016 11:08 PARMSTR71
Duke Energy Analytical Lab
Page 11 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013520
Collection Date:11-May-16 12:30 PM
Site:SW-103
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.222 mg-N/L EPA 353.2 05/16/2016 11:21 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 1.0 mg/L EPA 300.0 05/18/2016 00:05 BGN90340.1 1
Sulfate 0.54 mg/L EPA 300.0 05/18/2016 00:05 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 13:35 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/18/2016 14:00 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.05 1
Iron (Fe)0.053 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.01 1
Manganese (Mn)0.028 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.005 1
Strontium (Sr)0.014 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/18/2016 09:37 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.38 mg/L EPA 200.7 05/17/2016 14:51 MHH71310.01 1
Magnesium (Mg)0.726 mg/L EPA 200.7 05/17/2016 14:51 MHH71310.005 1
Potassium (K)0.840 mg/L EPA 200.7 05/17/2016 14:51 MHH71310.1 1
Sodium (Na)1.28 mg/L EPA 200.7 05/17/2016 14:51 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.752 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.005 1
Barium (Ba)0.027 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.05 1
Iron (Fe)1.07 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.01 1
Manganese (Mn)0.054 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.005 1
Strontium (Sr)0.016 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 05/16/2016 11:02 MHH71310.005 1
Duke Energy Analytical Lab
Page 12 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
2016013520
Collection Date:11-May-16 12:30 PM
Site:SW-103
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 16:35 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 16:35 MHALL30.2 1
Vanadium (V) Low Level 0.530 ug/L EPA 200.8 05/16/2016 16:35 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 18:42 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 18:42 MHALL30.2 1
Vanadium (V) Low Level 0.980 ug/L EPA 200.8 05/16/2016 18:42 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 05/16/2016 14:36 PARMSTR251
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 19 mg/L SM2540D 05/13/2016 11:08 PARMSTR51
Duke Energy Analytical Lab
Page 13 of 50
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050329
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Duke Energy Analytical Lab
Page 14 of 50
#=CL#
May 25, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92297390
92297390
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16050329
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on May 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
Duke Energy Analytical Lab
Page 15 of 50
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92297390
J16050329
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
Duke Energy Analytical Lab
Page 16 of 50
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92297390
J16050329
Lab ID Sample ID Matrix Date Collected Date Received
92297390001 2016013510 Water 05/11/16 07:48 05/12/16 12:10
92297390002 2016013517 Water 05/11/16 10:30 05/12/16 12:10
92297390003 2016013518 Water 05/11/16 11:05 05/12/16 12:10
92297390004 2016013519 Water 05/11/16 11:45 05/12/16 12:10
92297390005 2016013520 Water 05/11/16 12:30 05/12/16 12:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
Duke Energy Analytical Lab
Page 17 of 50
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92297390
J16050329
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92297390001 2016013510 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92297390002 2016013517 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92297390003 2016013518 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92297390004 2016013519 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92297390005 2016013520 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
Duke Energy Analytical Lab
Page 18 of 50
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92297390
J16050329
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92297390001 2016013510
Methane 15.5 ug/L 05/18/16 19:2410.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)113 mg/L 05/17/16 02:455.0SM 2320B
Alkalinity, Total as CaCO3 113 mg/L 05/17/16 02:455.0SM 2320B
92297390002 2016013517
Alkalinity,Bicarbonate (CaCO3)28.0 mg/L 05/17/16 02:575.0SM 2320B
Alkalinity, Total as CaCO3 28.0 mg/L 05/17/16 02:575.0SM 2320B
92297390003 2016013518
Alkalinity,Bicarbonate (CaCO3)10.0 mg/L 05/17/16 03:075.0SM 2320B
Alkalinity, Total as CaCO3 10.0 mg/L 05/17/16 03:075.0SM 2320B
Chromium, Hexavalent 0.22 ug/L 05/24/16 23:490.030EPA 218.7
92297390004 2016013519
Methane 14.6 ug/L 05/18/16 20:1010.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)15.2 mg/L 05/17/16 03:365.0SM 2320B
Alkalinity, Total as CaCO3 15.2 mg/L 05/17/16 03:365.0SM 2320B
92297390005 2016013520
Alkalinity,Bicarbonate (CaCO3)6.5 mg/L 05/17/16 03:465.0SM 2320B
Alkalinity, Total as CaCO3 6.5 mg/L 05/17/16 03:465.0SM 2320B
Chromium, Hexavalent 0.038 ug/L 05/25/16 00:150.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 23
Duke Energy Analytical Lab
Page 19 of 50
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297390
J16050329
Method:
Client:Duke Energy
RSK 175 Modified
Date:May 25, 2016
Description:RSK 175 Headspace
General Information:
5 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 23
Duke Energy Analytical Lab
Page 20 of 50
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297390
J16050329
Method:
Client:Duke Energy
SM 2320B
Date:May 25, 2016
Description:2320B Alkalinity
General Information:
5 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 23
Duke Energy Analytical Lab
Page 21 of 50
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297390
J16050329
Method:
Client:Duke Energy
SM 4500-S2D
Date:May 25, 2016
Description:4500S2D Sulfide Water
General Information:
5 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/44948
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92297312001,92297313004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1734646)
• Sulfide
• MSD (Lab ID: 1734647)
• Sulfide
QC Batch: WET/44990
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92297358002,92297390003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1736143)
• Sulfide
• MSD (Lab ID: 1736144)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 23
Duke Energy Analytical Lab
Page 22 of 50
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297390
J16050329
Method:
Client:Duke Energy
EPA 218.7
Date:May 25, 2016
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/58068
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92297079007,92297083007
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1583596)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 23
Duke Energy Analytical Lab
Page 23 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297390
J16050329
Sample:2016013510 Lab ID:92297390001 Collected:05/11/16 07:48 Received:05/12/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 15.5 ug/L 05/18/16 19:24 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)113 mg/L 05/17/16 02:455.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/17/16 02:455.0 1
Alkalinity, Total as CaCO3 113 mg/L 05/17/16 02:455.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/17/16 14:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 05/24/16 23:23 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 23
Duke Energy Analytical Lab
Page 24 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297390
J16050329
Sample:2016013517 Lab ID:92297390002 Collected:05/11/16 10:30 Received:05/12/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 05/18/16 19:39 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)28.0 mg/L 05/17/16 02:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/17/16 02:575.0 1
Alkalinity, Total as CaCO3 28.0 mg/L 05/17/16 02:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/17/16 14:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 05/24/16 23:36 18540-29-90.60 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 23
Duke Energy Analytical Lab
Page 25 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297390
J16050329
Sample:2016013518 Lab ID:92297390003 Collected:05/11/16 11:05 Received:05/12/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 05/18/16 19:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.0 mg/L 05/17/16 03:075.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/17/16 03:075.0 1
Alkalinity, Total as CaCO3 10.0 mg/L 05/17/16 03:075.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/18/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.22 ug/L 05/24/16 23:49 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
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Duke Energy Analytical Lab
Page 26 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297390
J16050329
Sample:2016013519 Lab ID:92297390004 Collected:05/11/16 11:45 Received:05/12/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 14.6 ug/L 05/18/16 20:10 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.2 mg/L 05/17/16 03:365.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/17/16 03:365.0 1
Alkalinity, Total as CaCO3 15.2 mg/L 05/17/16 03:365.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/18/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 05/25/16 00:02 18540-29-90.60 20
REPORT OF LABORATORY ANALYSIS
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Duke Energy Analytical Lab
Page 27 of 50
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297390
J16050329
Sample:2016013520 Lab ID:92297390005 Collected:05/11/16 12:30 Received:05/12/16 12:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 05/18/16 20:25 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)6.5 mg/L 05/17/16 03:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/17/16 03:465.0 1
Alkalinity, Total as CaCO3 6.5 mg/L 05/17/16 03:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/18/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.038 ug/L 05/25/16 00:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
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Duke Energy Analytical Lab
Page 28 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297390
J16050329
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/10609
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92297390001, 92297390002, 92297390003, 92297390004, 92297390005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1736465
Associated Lab Samples:92297390001, 92297390002, 92297390003, 92297390004, 92297390005
Matrix:Water
Analyzed
Methane ug/L ND 10.0 05/18/16 19:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1736466LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 334396 84 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1736467MATRIX SPIKE SAMPLE:
MSSpike
Result
92297493001
Methane ug/L 372396 94 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92297493004
1736468SAMPLE DUPLICATE:
Methane ug/L ND 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
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[phone]
Page 15 of 23
Duke Energy Analytical Lab
Page 29 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297390
J16050329
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44950
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92297390001, 92297390002, 92297390003, 92297390004, 92297390005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1734692
Associated Lab Samples:92297390001, 92297390002, 92297390003, 92297390004, 92297390005
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 05/16/16 23:39
Alkalinity, Total as CaCO3 mg/L ND 5.0 05/16/16 23:39
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 05/16/16 23:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1734693LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 47.050 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1734694MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297313001
1734695
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 95 80-120101 2 255081.3 129 132
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1734696MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297314008
1734697
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12098 1 2550ND48.5 49.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 23
Duke Energy Analytical Lab
Page 30 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297390
J16050329
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44948
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92297390001, 92297390002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1734644
Associated Lab Samples:92297390001, 92297390002
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 05/17/16 14:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1734645LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1734646MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297312001
1734647
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 111 90-110111 0 10.5ND 0.55 0.55
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1734648MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297313004
1734649
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 96 90-11096 0 10.5ND 0.48 0.48
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 23
Duke Energy Analytical Lab
Page 31 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297390
J16050329
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44990
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92297390003, 92297390004, 92297390005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1736139
Associated Lab Samples:92297390003, 92297390004, 92297390005
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 05/18/16 17:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1736140LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1736141MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297390003
1736142
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 101 90-110101 0 10.5ND 0.51 0.51
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1736143MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297358002
1736144
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 84 90-11084 0 10.5ND 0.42 0.42
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 18 of 23
Duke Energy Analytical Lab
Page 32 of 50
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297390
J16050329
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/58068
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92297390001, 92297390002, 92297390003, 92297390004, 92297390005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1583594
Associated Lab Samples:92297390001, 92297390002, 92297390003, 92297390004, 92297390005
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 05/24/16 19:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1583595LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.077.075 103 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1583596MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297079007
1583597
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 84 85-11591 7 20.075ND 0.073 0.078
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1583598MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297083007
1583599
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 94 85-11596 1 20.025ND 0.030 0.030
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
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Duke Energy Analytical Lab
Page 33 of 50
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92297390
J16050329
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
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Duke Energy Analytical Lab
Page 34 of 50
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92297390
J16050329
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92297390001 GCV/106092016013510RSK 175 Modified
92297390002 GCV/106092016013517RSK 175 Modified
92297390003 GCV/106092016013518RSK 175 Modified
92297390004 GCV/106092016013519RSK 175 Modified
92297390005 GCV/106092016013520RSK 175 Modified
92297390001 WET/449502016013510SM 2320B
92297390002 WET/449502016013517SM 2320B
92297390003 WET/449502016013518SM 2320B
92297390004 WET/449502016013519SM 2320B
92297390005 WET/449502016013520SM 2320B
92297390001 WET/449482016013510SM 4500-S2D
92297390002 WET/449482016013517SM 4500-S2D
92297390003 WET/449902016013518SM 4500-S2D
92297390004 WET/449902016013519SM 4500-S2D
92297390005 WET/449902016013520SM 4500-S2D
92297390001 WETA/580682016013510EPA 218.7
92297390002 WETA/580682016013517EPA 218.7
92297390003 WETA/580682016013518EPA 218.7
92297390004 WETA/580682016013519EPA 218.7
92297390005 WETA/580682016013520EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 05/25/2016 04:13 PM
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Duke Energy Analytical Lab
Page 35 of 50
Page 22 of 23
Duke Energy Analytical Lab
Page 36 of 50
Page 23 of 23
Duke Energy Analytical Lab
Page 37 of 50

May 26, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 397335
SDG: J16050329

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on May 12, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 12
Chelsea Seagle for
Duke Energy Analytical Lab
Page 38 of 50
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16050329 GEL Work Order: 397335
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 12
Duke Energy Analytical Lab
Page 39 of 50
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: May 26, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1567103
1567103
1569379
1567059
1558
0118
0947
1025
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
05/13/16
05/18/16
05/26/16
05/16/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
397335001
Water
11-MAY-16 07:48
12-MAY-16
2016013510 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"93.8 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.69
0.730
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 05/13/16 15671020827SXW1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000765
ND
ND
ND
8.47
8.58
NominalResult
RLDL
Notes:
Page 3 of 12
Duke Energy Analytical Lab
Page 40 of 50
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1567103Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
May 26, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 05/18/16 01:20
05/13/16 16:00
05/13/16 15:57
05/18/16 01:17
05/18/16 01:15
05/13/16 15:55
05/13/16 16:01
05/18/16 01:21
05/18/16 01:23
QC
ND
ND
ND
0.000742
0.0519
0.000496
0.000589
0.00472
ND
ND
ND
ND
0.0528
0.000604
0.000619
0.00492
ND
NOM Sample
ND
ND
ND
0.000765
0.000765
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203548262 397335001
QC1203548260
QC1203548261
QC1203548259
QC1203548263 397335001
QC1203548264 397335001
QC1203548265 397335001
N/A
N/A
N/A
3.16
N/A
REC%
105
99.2
107
94.4
105
121
113
98.3
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
397335Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
Page 1 of 3
Page 4 of 12
Duke Energy Analytical Lab
Page 41 of 50
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1567103
1569379
1567059
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
05/18/16 01:23
05/13/16 16:03
05/26/16 09:47
05/26/16 09:47
05/26/16 09:47
05/16/16 10:55
05/16/16 10:55
05/16/16 10:55
05/16/16 10:55
05/16/16 10:55
QC
ND
ND
0.155
8.02
38.5
0.266
3.53
28.1
0.513
122
107
NOM Sample
ND
ND
0.765
8.47
3.45
2.07
2.07
Range
(0%-10%)
(0%-10%)
(0%-20%)
(75%-125%)
(0%-20%)
(75%-125%)
(75%-125%)
(0%-20%)
Qual
U
U
J
U
U
QC1203554034 397335001
QC1203554035
QC1203554033
QC1203548273 397302001
QC1203548115
QC1203548112
QC1203548114 397309001
QC1203548272 397309001
The Qualifiers in this report are defined as follows:
N/A
N/A
1.27
5.44
2.29
13.1
REC%
83.8
115
98
85.7
45.9
24.4
122
122
DUP
LCS
MB
DUP
LCS
MB
MS
MSD
397335Workorder:
**
<
>
BD
E
FA
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
U
U
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
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Units Anlst Date TimeQCNOMSampleRangeQualREC%
397335Workorder:
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16050329
Work Order #: 397335

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1567103

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1567102
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
397335001 2016013510
1203548259 Method Blank (MB)ICP-MS
1203548260 Laboratory Control Sample (LCS)
1203548261 Laboratory Control Sample (LCS)
1203548265 397335001(2016013510L) Serial Dilution (SD)
1203548262 397335001(2016013510D) Sample Duplicate (DUP)
1203548263 397335001(2016013510S) Matrix Spike (MS)
1203548264 397335001(2016013510S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1569379
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
397335001 2016013510
1203554033 Method Blank (MB)
1203554034 397335001(2016013510) Sample Duplicate (DUP)
1203554035 Laboratory Control Sample (LCS)
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The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Sample Re-prep/Re-analysis
Samples were reprepped due to low recovery. The re-analysis is being reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1567059
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
397335001 2016013510
1203548112 Method Blank (MB)
1203548114 397309001(NonSDG) Matrix Spike (MS)
1203548115 Laboratory Control Sample (LCS)
1203548272 397309001(NonSDG) Matrix Spike Duplicate (MSD)
1203548273 397302001(NonSDG) Sample Duplicate (DUP)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike and matrix spike duplicate, 1203548114 (Non SDG 397309001MS) and 1203548272 (Non
SDG 397309001MSD), aliquots were reduced to conserve sample volume.

Certification Statement

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Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 26 May 2016
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