NC0000396_App B Lab Reports - WS Wells - J16050223rev1_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16050223
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:5/31/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:
Report Authorized By:
(Signature)
Program Comments:
The following report has been revised to reflect reanalysis results for low level Vanadium. Due to instrument contamination
during the original analysis, this constituent was detected in the method blank and associated samples (flagged B1). After
further investigation and reanalysis, the second data set has been reported.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 40
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016013087 ASHEVILLE 09-May-16 8:20 AM illegible AS-13
2016013088 ASHEVILLE 09-May-16 2:15 PM illegible AS-11
2 Total Samples
Duke Energy Analytical Lab
Page 2 of 40
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:5/23/2016
Electronic Data Deliverable (EDD) Sent Separately
Duke Energy Analytical Lab
Page 3 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050223
2016013087
Collection Date:09-May-16 8:20 AM
Site:AS-13
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 05/11/2016 11:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 85 mg/L EPA 300.0 05/10/2016 15:43 BGN9034110
Sulfate 420 mg/L EPA 300.0 05/10/2016 15:43 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/13/2016 13:26 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)137 mg/L EPA 200.7 05/12/2016 10:13M4 MHH71310.1 10
Magnesium (Mg)1.76 mg/L EPA 200.7 05/12/2016 10:13 MHH71310.005 1
Potassium (K)2.53 mg/L EPA 200.7 05/12/2016 10:13 MHH71310.1 1
Sodium (Na)74.5 mg/L EPA 200.7 05/12/2016 10:13 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.083 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.005 1
Barium (Ba)0.007 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.005 1
Boron (B)0.063 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.05 1
Iron (Fe)0.295 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.005 1
Strontium (Sr)0.373 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 05/16/2016 10:29 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Copper (Cu)11.6 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Molybdenum (Mo)9.69 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 18:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 18:07 MHALL30.2 1
Vanadium (V) Low Level 0.470 ug/L EPA 200.8 05/16/2016 18:07 MHALL30.3 1
Duke Energy Analytical Lab
Page 4 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050223
2016013087
Collection Date:09-May-16 8:20 AM
Site:AS-13
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 710 mg/L SM2540C 05/10/2016 15:06 PARMSTR251
Total Carbon
TOC 0.219 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/11/2016 10:06 PARMSTR51
Duke Energy Analytical Lab
Page 5 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050223
2016013088
Collection Date:09-May-16 2:15 PM
Site:AS-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 05/11/2016 11:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 54 mg/L EPA 300.0 05/10/2016 16:01 BGN9034110
Sulfate 320 mg/L EPA 300.0 05/10/2016 16:01 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 05/13/2016 13:28 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)102 mg/L EPA 200.7 05/12/2016 10:25 MHH71310.1 10
Magnesium (Mg)1.42 mg/L EPA 200.7 05/12/2016 10:25 MHH71310.005 1
Potassium (K)1.64 mg/L EPA 200.7 05/12/2016 10:25 MHH71310.1 1
Sodium (Na)64.6 mg/L EPA 200.7 05/12/2016 10:25 MHH71310.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.005 1
Barium (Ba)0.007 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.005 1
Boron (B)0.054 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.05 1
Iron (Fe)0.025 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.01 1
Manganese (Mn)0.010 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.005 1
Strontium (Sr)0.232 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 05/16/2016 10:42 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Molybdenum (Mo)7.66 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 05/16/2016 17:38 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/16/2016 17:38 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/16/2016 17:38 MHALL30.3 1
Duke Energy Analytical Lab
Page 6 of 40
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16050223
2016013088
Collection Date:09-May-16 2:15 PM
Site:AS-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 570 mg/L SM2540C 05/10/2016 15:06 PARMSTR251
Total Carbon
TOC 0.363 mg/L SM5310C/EPA9060A 05/17/2016 11:02 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 05/11/2016 10:06 PARMSTR51
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
Duke Energy Analytical Lab
Page 7 of 40
#=CL#
May 23, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92297001
92297001
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16050223
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on May 10, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 19
Duke Energy Analytical Lab
Page 8 of 40
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92297001
J16050223
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 19
Duke Energy Analytical Lab
Page 9 of 40
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92297001
J16050223
Lab ID Sample ID Matrix Date Collected Date Received
92297001001 2016013087 Water 05/09/16 08:20 05/10/16 14:20
92297001002 2016013088 Water 05/09/16 14:15 05/10/16 14:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 19
Duke Energy Analytical Lab
Page 10 of 40
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92297001
J16050223
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92297001001 2016013087 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92297001002 2016013088 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 19
Duke Energy Analytical Lab
Page 11 of 40
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92297001
J16050223
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92297001001 2016013087
Methane 3920 ug/L 05/16/16 11:1310.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)7.7 mg/L 05/13/16 00:185.0SM 2320B
Alkalinity, Total as CaCO3 7.7 mg/L 05/13/16 00:185.0SM 2320B
92297001002 2016013088
Methane 3800 ug/L 05/16/16 11:2810.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)13.4 mg/L 05/13/16 00:505.0SM 2320B
Alkalinity, Total as CaCO3 13.4 mg/L 05/13/16 00:505.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 19
Duke Energy Analytical Lab
Page 12 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297001
J16050223
Method:
Client:Duke Energy
RSK 175 Modified
Date:May 23, 2016
Description:RSK 175 Headspace
General Information:
2 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: GCV/10599
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92297090002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1734536)
• Methane
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 19
Duke Energy Analytical Lab
Page 13 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297001
J16050223
Method:
Client:Duke Energy
SM 2320B
Date:May 23, 2016
Description:2320B Alkalinity
General Information:
2 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 19
Duke Energy Analytical Lab
Page 14 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297001
J16050223
Method:
Client:Duke Energy
SM 4500-S2D
Date:May 23, 2016
Description:4500S2D Sulfide Water
General Information:
2 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 19
Duke Energy Analytical Lab
Page 15 of 40
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92297001
J16050223
Method:
Client:Duke Energy
EPA 218.7
Date:May 23, 2016
Description:Hexavalent Chromium by IC
General Information:
2 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 19
Duke Energy Analytical Lab
Page 16 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297001
J16050223
Sample:2016013087 Lab ID:92297001001 Collected:05/09/16 08:20 Received:05/10/16 14:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 3920 ug/L 05/16/16 11:13 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.7 mg/L 05/13/16 00:185.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/13/16 00:185.0 1
Alkalinity, Total as CaCO3 7.7 mg/L 05/13/16 00:185.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/12/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 05/22/16 19:47 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 19
Duke Energy Analytical Lab
Page 17 of 40
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92297001
J16050223
Sample:2016013088 Lab ID:92297001002 Collected:05/09/16 14:15 Received:05/10/16 14:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 3800 ug/L 05/16/16 11:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)13.4 mg/L 05/13/16 00:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 05/13/16 00:505.0 1
Alkalinity, Total as CaCO3 13.4 mg/L 05/13/16 00:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 05/12/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 05/22/16 20:00 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 19
Duke Energy Analytical Lab
Page 18 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297001
J16050223
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/10599
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92297001001, 92297001002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1734534
Associated Lab Samples:92297001001, 92297001002
Matrix:Water
Analyzed
Methane ug/L ND 10.0 05/16/16 10:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1734535LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 329396 83 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1734536MATRIX SPIKE SAMPLE:
MSSpike
Result
92297090002
Methane ug/L 263 M13966670-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92297090003
1734537SAMPLE DUPLICATE:
Methane ug/L 119 15 20139
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 19
Duke Energy Analytical Lab
Page 19 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297001
J16050223
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44844
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92297001001, 92297001002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1730752
Associated Lab Samples:92297001001, 92297001002
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 05/12/16 21:38
Alkalinity, Total as CaCO3 mg/L ND 5.0 05/12/16 21:38
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 05/12/16 21:38
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1730753LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 51.050 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1730754MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92296881001
1730755
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 102 80-120103 0 255022.2 73.5 73.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1730756MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297001001
1730757
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 102 80-120101 0 25507.7 58.7 58.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 19
Duke Energy Analytical Lab
Page 20 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297001
J16050223
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44863
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92297001001, 92297001002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1731783
Associated Lab Samples:92297001001, 92297001002
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 05/12/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1731784LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1731785MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92296881004
1731786
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 108 90-110108 0 10.5ND 0.54 0.54
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1731787MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92297090002
1731788
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 103 90-110103 0 10.5ND 0.52 0.52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 19
Duke Energy Analytical Lab
Page 21 of 40
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92297001
J16050223
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/58030
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92297001001, 92297001002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1582417
Associated Lab Samples:92297001001, 92297001002
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 05/22/16 14:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1582418LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.073.075 97 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1582419MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92296876002
1582420
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 92 85-115109 17 20.075ND 0.069 0.082
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1582421MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92296878006
1582422
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 94 85-115102 5 20.0250.012J 0.036 0.037
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 19
Duke Energy Analytical Lab
Page 22 of 40
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92297001
J16050223
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 19
Duke Energy Analytical Lab
Page 23 of 40
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92297001
J16050223
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92297001001 GCV/105992016013087RSK 175 Modified
92297001002 GCV/105992016013088RSK 175 Modified
92297001001 WET/448442016013087SM 2320B
92297001002 WET/448442016013088SM 2320B
92297001001 WET/448632016013087SM 4500-S2D
92297001002 WET/448632016013088SM 4500-S2D
92297001001 WETA/580302016013087EPA 218.7
92297001002 WETA/580302016013088EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 05/23/2016 02:05 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 19
Duke Energy Analytical Lab
Page 24 of 40
Page 18 of 19
Duke Energy Analytical Lab
Page 25 of 40
Page 19 of 19
Duke Energy Analytical Lab
Page 26 of 40

May 19, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 397181
SDG: J16050223

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on May 11, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 13
Duke Energy Analytical Lab
Page 27 of 40
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16050223 GEL Work Order: 397181
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 13
Duke Energy Analytical Lab
Page 28 of 40
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: May 19, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1566564
1566564
1566676
1565675
0853
0948
1424
0950
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
05/13/16
05/13/16
05/18/16
05/17/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
397181001
Water
09-MAY-16 08:20
11-MAY-16
2016013087 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"79 (15%-125%)
0.000067
0.00001
0.00001
0.00001
2.26
0.331
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 05/11/16 15665621730JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
0.830
NominalResult
RLDL
Notes:
Page 3 of 13
Duke Energy Analytical Lab
Page 29 of 40
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: May 19, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1566564
1566564
1566676
1565675
0859
0954
1424
0950
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
05/13/16
05/13/16
05/18/16
05/17/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
397181002
Water
09-MAY-16 14:15
11-MAY-16
2016013088 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"65.9 (15%-125%)
0.000067
0.00001
0.00001
0.00001
2.84
0.199
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 05/11/16 15665621730JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
3.14
0.728
NominalResult
RLDL
Notes:
Page 4 of 13
Duke Energy Analytical Lab
Page 30 of 40
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1566564Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
May 19, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 05/13/16 09:49
05/13/16 08:55
05/13/16 08:52
05/13/16 09:46
05/13/16 09:45
05/13/16 08:50
05/13/16 08:56
05/13/16 09:51
05/13/16 09:53
QC
ND
ND
ND
ND
0.0516
0.000525
0.000578
0.0049
ND
ND
ND
ND
0.0511
0.00054
0.000597
0.00488
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203546662 397181001
QC1203546661
QC1203546936
QC1203546660
QC1203546663 397181001
QC1203546937 397181001
QC1203546664 397181001
N/A
N/A
N/A
N/A
N/A
REC%
104
105
105
98.1
103
108
109
97.5
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
397181Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
Page 5 of 13
Duke Energy Analytical Lab
Page 31 of 40
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1566564
1566676
1565675
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
05/13/16 09:53
05/13/16 08:58
05/18/16 14:24
05/18/16 14:24
05/18/16 14:24
05/17/16 09:50
05/17/16 10:25
05/17/16 09:50
05/17/16 10:25
05/17/16 10:25
QC
ND
ND
ND
3.04
45.4
1.76
0.419
26.3
0.193
146
126
NOM Sample
ND
ND
ND
3.14
0.656
0.656
0.656
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
(0%-20%)
Qual
U
U
U
U
U
U
QC1203547030 397181002
QC1203547031
QC1203547029
QC1203544302 396687003
QC1203544305
QC1203544301
QC1203544303 396687003
QC1203544304 396687003
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
3.15
44
14.5
REC%
98.5
108
119
103
46.1
24.4
122
122
DUP
LCS
MB
DUP
LCS
MB
MS
MSD
397181Workorder:
**
<
>
BD
E
FA
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
U
U
U
RPD%
Notes:
Page 2 of 3
Page 6 of 13
Duke Energy Analytical Lab
Page 32 of 40
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
397181Workorder:
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 7 of 13
Duke Energy Analytical Lab
Page 33 of 40
Page 8 of 13
Duke Energy Analytical Lab
Page 34 of 40
Page 9 of 13
Duke Energy Analytical Lab
Page 35 of 40

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16050223
Work Order #: 397181

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1566564

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1566562
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
397181001 2016013087
397181002 2016013088
1203546660 Method Blank (MB)ICP-MS
1203546661 Laboratory Control Sample (LCS)
1203546936 Laboratory Control Sample (LCS)
1203546664 397181001(2016013087L) Serial Dilution (SD)
1203546662 397181001(2016013087D) Sample Duplicate (DUP)
1203546663 397181001(2016013087S) Matrix Spike (MS)
1203546937 397181001(2016013087S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1566676
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
397181001 2016013087
397181002 2016013088
1203547029 Method Blank (MB)
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1203547030 397181002(2016013088) Sample Duplicate (DUP)
1203547031 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Recounts
Samples were re-eluted due to a suspected blank false positive. The re-eluted counts are reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1565675
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
397181001 2016013087
397181002 2016013088
1203544301 Method Blank (MB)
1203544302 396687003(NonSDG) Sample Duplicate (DUP)
1203544303 396687003(NonSDG) Matrix Spike (MS)
1203544304 396687003(NonSDG) Matrix Spike Duplicate (MSD)
1203544305 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike and matrix spike duplicate, 1203544303 (Non SDG 396687003MS) and 1203544304 (Non
SDG 396687003MSD), aliquots were reduced to conserve sample volume.

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Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 19 May 2016
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Duke Energy Analytical Lab
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