NC0000396_App B Lab Reports - WS Wells - J16020326report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16020326
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:2/24/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 35
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016004243 ASHEVILLE 11-Feb-16 10:45 AM BMT DW-3
2016004244 ASHEVILLE 11-Feb-16 9:48 AM BMT DW-4
2016004245 ASHEVILLE 11-Feb-16 1:17 PM BMT DW-5
2016004246 ASHEVILLE 11-Feb-16 12:27 PM BMT DW-6
4 Total Samples
Page 2 of 35
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/24/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004243
Collection Date:11-Feb-16 10:45 AM
Site:DW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.402 mg-N/L EPA 353.2 02/18/2016 10:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 60 mg/L EPA 300.0 02/12/2016 14:28 BGN9034110
Sulfate 12 mg/L EPA 300.0 02/12/2016 14:28 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 14:40 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/19/2016 15:30N1 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.039 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.005 1
Barium (Ba)0.048 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.01 1
Manganese (Mn)0.040 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.005 1
Strontium (Sr)0.077 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 02/15/2016 12:14 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.29 mg/L EPA 200.7 02/16/2016 16:17 MHALL30.01 1
Magnesium (Mg)5.19 mg/L EPA 200.7 02/16/2016 16:17 MHALL30.005 1
Potassium (K)1.61 mg/L EPA 200.7 02/16/2016 16:17 MHALL30.1 1
Sodium (Na)27.9 mg/L EPA 200.7 02/16/2016 16:17 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.078 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.005 1
Barium (Ba)0.048 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.05 1
Iron (Fe)0.369 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.01 1
Manganese (Mn)0.038 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.005 1
Strontium (Sr)0.075 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2016 10:50 MHH71310.005 1
Page 4 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004243
Collection Date:11-Feb-16 10:45 AM
Site:DW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Nickel (Ni)7.52 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/16/2016 14:12 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Nickel (Ni)7.21 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/19/2016 15:30 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 02/15/2016 11:39 JASTOWE251
Total Carbon
TOC 0.366 mg/L SM5310C/EPA9060A 02/17/2016 13:10 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/15/2016 09:20 CJELLIO51
Page 5 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004244
Collection Date:11-Feb-16 9:48 AM
Site:DW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.296 mg-N/L EPA 353.2 02/18/2016 10:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 76 mg/L EPA 300.0 02/12/2016 14:45 BGN9034110
Sulfate 84 mg/L EPA 300.0 02/12/2016 14:45 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 14:42 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 15:28 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)1.25 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.005 1
Barium (Ba)0.046 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.01 1
Manganese (Mn)1.83 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.005 1
Strontium (Sr)0.198 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.005 1
Zinc (Zn)0.083 mg/L EPA 200.7 02/15/2016 12:18 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)21.4 mg/L EPA 200.7 02/16/2016 16:21 MHALL30.01 1
Magnesium (Mg)9.67 mg/L EPA 200.7 02/16/2016 16:21 MHALL30.005 1
Potassium (K)4.52 mg/L EPA 200.7 02/16/2016 16:21 MHALL30.1 1
Sodium (Na)39.0 mg/L EPA 200.7 02/16/2016 16:21 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.42 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.005 1
Barium (Ba)0.046 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.05 1
Iron (Fe)2.45 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.01 1
Manganese (Mn)1.88 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.005 1
Strontium (Sr)0.203 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.005 1
Zinc (Zn)0.093 mg/L EPA 200.7 02/15/2016 10:55 MHH71310.005 1
Page 6 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004244
Collection Date:11-Feb-16 9:48 AM
Site:DW-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Arsenic (As)1.45 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Beryllium (Be)1.62 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Cobalt (Co)127 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Nickel (Ni)42.6 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/16/2016 14:17 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Arsenic (As)1.62 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Beryllium (Be)1.04 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Cobalt (Co)128 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Nickel (Ni)42.1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/19/2016 16:00 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 02/15/2016 11:39 JASTOWE251
Total Carbon
TOC 0.385 mg/L SM5310C/EPA9060A 02/17/2016 13:10 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 02/15/2016 09:20 CJELLIO51
Page 7 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004245
Collection Date:11-Feb-16 1:17 PM
Site:DW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/18/2016 10:35 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 56 mg/L EPA 300.0 02/12/2016 15:02 BGN9034110
Sulfate 19 mg/L EPA 300.0 02/12/2016 15:02 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 14:45 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 15:31 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.005 1
Barium (Ba)0.009 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.005 1
Boron (B)0.079 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.05 1
Iron (Fe)14.4 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.01 1
Manganese (Mn)0.501 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.005 1
Strontium (Sr)0.120 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 02/15/2016 12:22 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)34.2 mg/L EPA 200.7 02/16/2016 16:25 MHALL30.01 1
Magnesium (Mg)4.29 mg/L EPA 200.7 02/16/2016 16:25 MHALL30.005 1
Potassium (K)3.00 mg/L EPA 200.7 02/16/2016 16:25 MHALL30.1 1
Sodium (Na)15.9 mg/L EPA 200.7 02/16/2016 16:25 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.031 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.005 1
Barium (Ba)0.008 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.005 1
Boron (B)0.079 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.05 1
Iron (Fe)17.3 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.01 1
Manganese (Mn)0.491 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.005 1
Strontium (Sr)0.116 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2016 10:59 MHH71310.005 1
Page 8 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004245
Collection Date:11-Feb-16 1:17 PM
Site:DW-5
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/16/2016 15:25 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/19/2016 16:19 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 02/15/2016 11:39 JASTOWE251
Total Carbon
TOC 0.255 mg/L SM5310C/EPA9060A 02/17/2016 13:10 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 25 mg/L SM2540D 02/15/2016 09:20 CJELLIO51
Page 9 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004246
Collection Date:11-Feb-16 12:27 PM
Site:DW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/18/2016 10:38 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 1.6 mg/L EPA 300.0 02/15/2016 08:55 BGN90340.1 1
Sulfate 0.46 mg/L EPA 300.0 02/15/2016 08:55 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 14:47 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/16/2016 15:33 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.005 1
Barium (Ba)0.016 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.05 1
Iron (Fe)19.7 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.01 1
Manganese (Mn)0.586 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.005 1
Strontium (Sr)0.094 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2016 12:34 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.20 mg/L EPA 200.7 02/16/2016 16:28 MHALL30.01 1
Magnesium (Mg)2.24 mg/L EPA 200.7 02/16/2016 16:28 MHALL30.005 1
Potassium (K)2.37 mg/L EPA 200.7 02/16/2016 16:28 MHALL30.1 1
Sodium (Na)7.71 mg/L EPA 200.7 02/16/2016 16:28 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.044 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.005 1
Barium (Ba)0.018 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.05 1
Iron (Fe)28.0 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.01 1
Manganese (Mn)0.607 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.005 1
Strontium (Sr)0.094 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/15/2016 11:03 MHH71310.005 1
Page 10 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
2016004246
Collection Date:11-Feb-16 12:27 PM
Site:DW-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/16/2016 15:30 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Copper (Cu)1.11 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 02/19/2016 16:24 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 68 mg/L SM2540C 02/15/2016 11:39 JASTOWE251
Total Carbon
TOC 0.296 mg/L SM5310C/EPA9060A 02/17/2016 13:10 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 51 mg/L SM2540D 02/15/2016 09:20 CJELLIO51
Page 11 of 35
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020326
N1 - Insufficient sample volume to perform the dissolved metals analysis from the original container. As a result, the
TSS sample was filtered in-house on 2/17/16 using a 0.45 micron filter and analyzed as HG 245.1 Dissolved.
-- Additional Information --
Qualifiers:
N1 See additional information listed below.
Page 12 of 35
#=CL#
February 17, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92286451
92286451
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16020326
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 12, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 22
Page 13 of 35
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92286451
J16020326
Minnesota Certification IDs
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Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
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Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 22
Page 14 of 35
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92286451
J16020326
Lab ID Sample ID Matrix Date Collected Date Received
92286451001 2016004243 Water 02/11/16 10:45 02/12/16 12:38
92286451002 2016004244 Water 02/11/16 09:48 02/12/16 12:38
92286451003 2016004245 Water 02/11/16 13:17 02/12/16 12:38
92286451004 2016004246 Water 02/11/16 12:27 02/12/16 12:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 22
Page 15 of 35
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92286451
J16020326
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92286451001 2016004243 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92286451002 2016004244 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92286451003 2016004245 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92286451004 2016004246 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
Page 4 of 22
Page 16 of 35
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92286451
J16020326
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92286451001 2016004243
Alkalinity,Bicarbonate (CaCO3)5.4 mg/L 02/15/16 13:565.0SM 2320B
Alkalinity, Total as CaCO3 5.4 mg/L 02/15/16 13:565.0SM 2320B
Chromium, Hexavalent 0.38 ug/L 02/15/16 14:220.060EPA 218.7
92286451003 2016004245
Alkalinity,Bicarbonate (CaCO3)51.9 mg/L 02/15/16 14:145.0SM 2320B
Alkalinity, Total as CaCO3 51.9 mg/L 02/15/16 14:145.0SM 2320B
92286451004 2016004246
Methane 3150 ug/L 02/15/16 21:1310.0RSK 175
Alkalinity,Bicarbonate (CaCO3)48.3 mg/L 02/15/16 14:265.0SM 2320B
Alkalinity, Total as CaCO3 48.3 mg/L 02/15/16 14:265.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
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[phone]
Page 5 of 22
Page 17 of 35
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92286451
J16020326
Method:
Client:Duke Energy
RSK 175
Date:February 17, 2016
Description:RSK 175 AIR Headspace
General Information:
4 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 6 of 22
Page 18 of 35
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92286451
J16020326
Method:
Client:Duke Energy
SM 2320B
Date:February 17, 2016
Description:2320B Alkalinity
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
Page 7 of 22
Page 19 of 35
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92286451
J16020326
Method:
Client:Duke Energy
SM 4500-S2D
Date:February 17, 2016
Description:4500S2D Sulfide Water
General Information:
4 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 22
Page 20 of 35
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92286451
J16020326
Method:
Client:Duke Energy
EPA 218.7
Date:February 17, 2016
Description:Hexavalent Chromium by IC
General Information:
4 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/55037
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92286451002,92286457003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1480049)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 22
Page 21 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286451
J16020326
Sample:2016004243 Lab ID:92286451001 Collected:02/11/16 10:45 Received:02/12/16 12:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 02/15/16 20:48 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)5.4 mg/L 02/15/16 13:565.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/15/16 13:565.0 1
Alkalinity, Total as CaCO3 5.4 mg/L 02/15/16 13:565.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/16/16 15:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.38 ug/L 02/15/16 14:22 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 10 of 22
Page 22 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286451
J16020326
Sample:2016004244 Lab ID:92286451002 Collected:02/11/16 09:48 Received:02/12/16 12:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 02/15/16 20:56 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 02/15/16 14:065.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/15/16 14:065.0 1
Alkalinity, Total as CaCO3 ND mg/L 02/15/16 14:065.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/16/16 15:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/16/16 12:00 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
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[phone]
Page 11 of 22
Page 23 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286451
J16020326
Sample:2016004245 Lab ID:92286451003 Collected:02/11/16 13:17 Received:02/12/16 12:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 02/15/16 21:04 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)51.9 mg/L 02/15/16 14:145.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/15/16 14:145.0 1
Alkalinity, Total as CaCO3 51.9 mg/L 02/15/16 14:145.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/16/16 15:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/16/16 12:39 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 12 of 22
Page 24 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92286451
J16020326
Sample:2016004246 Lab ID:92286451004 Collected:02/11/16 12:27 Received:02/12/16 12:38 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 3150 ug/L 02/15/16 21:13 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)48.3 mg/L 02/15/16 14:265.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/15/16 14:265.0 1
Alkalinity, Total as CaCO3 48.3 mg/L 02/15/16 14:265.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/16/16 15:15 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 02/16/16 12:52 18540-29-91.5 50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 13 of 22
Page 25 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286451
J16020326
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25221
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92286451001, 92286451002, 92286451003, 92286451004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2191768
Associated Lab Samples:92286451001, 92286451002, 92286451003, 92286451004
Matrix:Water
Analyzed
Methane ug/L ND 10.0 02/15/16 18:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2191769LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2191770
Methane ug/L 55.360.7 91 85-1158752.8 5 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286145002
2192335SAMPLE DUPLICATE:
Methane ug/L 6.6J 206.9J
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92286457006
2192336SAMPLE DUPLICATE:
Methane ug/L 1.1J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
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[phone]
Page 14 of 22
Page 26 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286451
J16020326
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43044
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92286451001, 92286451002, 92286451003, 92286451004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1666285
Associated Lab Samples:92286451001, 92286451002, 92286451003, 92286451004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 02/15/16 12:58
Alkalinity, Total as CaCO3 mg/L ND 5.0 02/15/16 12:58
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 02/15/16 12:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1666286LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.050 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1666287MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286448001
1666288
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12097 1 2550ND49.2 48.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1666289MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286457005
1666290
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120100 0 2550ND52.3 52.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 22
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286451
J16020326
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43068
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92286451001, 92286451002, 92286451003, 92286451004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1666880
Associated Lab Samples:92286451001, 92286451002, 92286451003, 92286451004
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/16/16 15:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1666881LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1666882MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286122003
1666883
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 102 90-110102 0 10.5ND 0.51 0.51
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1666884MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286122004
1666885
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 92 90-11092 0 10.5ND 0.46 0.46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 22
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286451
J16020326
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/55036
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92286451001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1480042
Associated Lab Samples:92286451001
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 02/15/16 11:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1480043LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.072.075 96 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1480044MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92285911002
1480045
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .75 100 85-115107 2 20.751.6 2.3 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 22
Page 29 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92286451
J16020326
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/55037
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92286451002, 92286451003, 92286451004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1480046
Associated Lab Samples:92286451002, 92286451003, 92286451004
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 02/16/16 11:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1480047LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 98 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1480048MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286451002
1480049
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 98 85-11576 14 20.025ND 0.042 0.037
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1480050MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92286457003
1480051
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 101 85-11593 6 20.0750.034 0.11 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 22
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92286451
J16020326
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92286451
J16020326
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92286451001 AIR/252212016004243RSK 175
92286451002 AIR/252212016004244RSK 175
92286451003 AIR/252212016004245RSK 175
92286451004 AIR/252212016004246RSK 175
92286451001 WET/430442016004243SM 2320B
92286451002 WET/430442016004244SM 2320B
92286451003 WET/430442016004245SM 2320B
92286451004 WET/430442016004246SM 2320B
92286451001 WET/430682016004243SM 4500-S2D
92286451002 WET/430682016004244SM 4500-S2D
92286451003 WET/430682016004245SM 4500-S2D
92286451004 WET/430682016004246SM 4500-S2D
92286451001 WETA/550362016004243EPA 218.7
92286451002 WETA/550372016004244EPA 218.7
92286451003 WETA/550372016004245EPA 218.7
92286451004 WETA/550372016004246EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 02/17/2016 12:52 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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