NC0000396_App B Lab Reports - CSA RND 4 Sampling - J16020574report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J16020574
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:3/7/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:[phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 29
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016005300 ASHEVILLE 22-Feb-16 2:36 PM Bart M Fitzpatrick
(PACE)
MW-06BR
2016005301 ASHEVILLE 22-Feb-16 11:45 AM Bart M Fitzpatrick
(PACE)
Filter Blank
2016005302 ASHEVILLE 22-Feb-16 11:45 AM Bart M Fitzpatrick
(PACE)
Equipment Blank
3 Total Samples
Analytical Lab
Page 2 of 29
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:3/7/2016
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 29
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
2016005300
Collection Date:22-Feb-16 2:36 PM
Site:MW-06BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/26/2016 08:42 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.9 mg/L EPA 300.0 02/25/2016 20:15 BGN90340.1 1
Sulfate 48 mg/L EPA 300.0 02/25/2016 20:15 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/29/2016 12:07 LSTARL10.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/29/2016 12:39 LSTARL10.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.005 1
Barium (Ba)0.009 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.005 1
Boron (B)0.106 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.005 1
Strontium (Sr)0.034 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/25/2016 12:38 MHH71310.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.2 mg/L EPA 200.7 02/26/2016 10:31 JJMACKE0.01 1
Magnesium (Mg)0.544 mg/L EPA 200.7 02/26/2016 10:31 JJMACKE0.005 1
Potassium (K)1.82 mg/L EPA 200.7 02/26/2016 10:31 JJMACKE0.1 1
Sodium (Na)22.2 mg/L EPA 200.7 02/26/2016 10:31 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.078 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.005 1
Barium (Ba)0.011 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.005 1
Boron (B)0.112 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.05 1
Iron (Fe)0.025 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.005 1
Strontium (Sr)0.035 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/26/2016 13:39 JJMACKE0.005 1
Analytical Lab
Page 4 of 29
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
2016005300
Collection Date:22-Feb-16 2:36 PM
Site:MW-06BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Molybdenum (Mo)2.92 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 03/01/2016 13:51 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 03/01/2016 13:51 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 03/01/2016 13:51 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Molybdenum (Mo)2.97 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 03/01/2016 14:54 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 03/01/2016 14:54 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 03/01/2016 14:54 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 02/25/2016 13:59 CJELLIO251
Total Carbon
TOC 0.202 mg/L SM5310C/EPA9060A 02/27/2016 12:29 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/25/2016 11:52 CJELLIO51
Analytical Lab
Page 5 of 29
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
2016005301
Collection Date:22-Feb-16 11:45 AM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/29/2016 12:41 LSTARL10.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/25/2016 11:27 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 03/01/2016 14:15 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 03/01/2016 14:15 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 03/01/2016 14:15 MHALL30.3 1
Analytical Lab
Page 6 of 29
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
2016005302
Collection Date:22-Feb-16 11:45 AM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 02/26/2016 08:43 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 02/25/2016 19:26 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 02/25/2016 19:26 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 02/29/2016 12:10 LSTARL10.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 02/26/2016 10:42 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 02/26/2016 10:42 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 02/26/2016 10:42 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 02/26/2016 10:42 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 02/26/2016 13:42 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 03/01/2016 15:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 03/01/2016 15:14 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 03/01/2016 15:14 MHALL30.3 1
Analytical Lab
Page 7 of 29
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16020574
2016005302
Collection Date:22-Feb-16 11:45 AM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 02/25/2016 13:59 CJELLIO251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 02/27/2016 12:29 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 02/25/2016 11:52 CJELLIO51
Analytical Lab
Page 8 of 29
#=CL#
March 04, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92287711
92287711
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16020574
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on February 24, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 20
Analytical Lab
Page 9 of 29
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92287711
J16020574
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
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Kansas Certification #: E-10167
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Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
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Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
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Puerto Rico Certification
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Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20
Analytical Lab
Page 10 of 29
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92287711
J16020574
Lab ID Sample ID Matrix Date Collected Date Received
92287711001 2016005300 Water 02/22/16 14:36 02/24/16 16:00
92287711002 2016005302 Water 02/22/16 11:45 02/24/16 16:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 20
Analytical Lab
Page 11 of 29
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92287711
J16020574
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92287711001 2016005300 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92287711002 2016005302 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 20
Analytical Lab
Page 12 of 29
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92287711
J16020574
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92287711001 2016005300
Methane 27.9 ug/L 02/25/16 14:53 1g10.0RSK 175
Alkalinity,Bicarbonate (CaCO3)34.4 mg/L 02/29/16 20:285.0SM 2320B
Alkalinity, Total as CaCO3 34.4 mg/L 02/29/16 20:285.0SM 2320B
Sulfide 0.32 mg/L 02/26/16 14:300.10SM 4500-S2D
Chromium, Hexavalent 0.053 ug/L 03/01/16 13:020.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 20
Analytical Lab
Page 13 of 29
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92287711
J16020574
Method:
Client:Duke Energy
RSK 175
Date:March 04, 2016
Description:RSK 175 AIR Headspace
General Information:
2 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: AIR/25314
1g: Closing continuing calibration verification sample not analyzed due to instrument error. Data accepted based on LCS recovery
and sample duplicate.
• 2016005300 (Lab ID: 92287711001)
• Methane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 20
Analytical Lab
Page 14 of 29
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92287711
J16020574
Method:
Client:Duke Energy
SM 2320B
Date:March 04, 2016
Description:2320B Alkalinity
General Information:
2 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/43307
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92287592001,92287711002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1674894)
• Alkalinity, Total as CaCO3
• MS (Lab ID: 1674896)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1674895)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1674897)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Analytical Lab
Page 15 of 29
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92287711
J16020574
Method:
Client:Duke Energy
SM 4500-S2D
Date:March 04, 2016
Description:4500S2D Sulfide Water
General Information:
2 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 8 of 20
Analytical Lab
Page 16 of 29
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92287711
J16020574
Method:
Client:Duke Energy
EPA 218.7
Date:March 04, 2016
Description:Hexavalent Chromium by IC
General Information:
2 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/55437
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92287631001,92287761002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1492931)
• Chromium, Hexavalent
• MSD (Lab ID: 1492932)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 9 of 20
Analytical Lab
Page 17 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287711
J16020574
Sample:2016005300 Lab ID:92287711001 Collected:02/22/16 14:36 Received:02/24/16 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 27.9 ug/L 02/25/16 14:53 74-82-8 1g10.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)34.4 mg/L 02/29/16 20:285.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/29/16 20:285.0 1
Alkalinity, Total as CaCO3 34.4 mg/L 02/29/16 20:285.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide 0.32 mg/L 02/26/16 14:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.053 ug/L 03/01/16 13:02 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Analytical Lab
Page 18 of 29
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92287711
J16020574
Sample:2016005302 Lab ID:92287711002 Collected:02/22/16 11:45 Received:02/24/16 16:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 02/29/16 11:16 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 02/29/16 20:395.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 02/29/16 20:395.0 1
Alkalinity, Total as CaCO3 ND mg/L 02/29/16 20:39 M15.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 02/26/16 14:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 03/01/16 13:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 20
Analytical Lab
Page 19 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287711
J16020574
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25314
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92287711001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2198780
Associated Lab Samples:92287711001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 02/25/16 14:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2198781LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 63.560.7 105 85-115
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287719001
2200635SAMPLE DUPLICATE:
Methane ug/L 2.1J 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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Huntersville, NC 28078
[phone]
Page 12 of 20
Analytical Lab
Page 20 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287711
J16020574
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25338
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92287711002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2200637
Associated Lab Samples:92287711002
Matrix:Water
Analyzed
Methane ug/L ND 10.0 02/29/16 10:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2200638LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2200639
Methane ug/L 57.160.7 94 85-1159658.2 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92287645004
2200640SAMPLE DUPLICATE:
Methane ug/L 990 4 201030
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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Huntersville, NC 28078
[phone]
Page 13 of 20
Analytical Lab
Page 21 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287711
J16020574
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43307
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92287711001, 92287711002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1674892
Associated Lab Samples:92287711001, 92287711002
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 02/29/16 18:06
Alkalinity, Total as CaCO3 mg/L ND 5.0 02/29/16 18:06
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 02/29/16 18:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1674893LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.150 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1674894MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287592001
1674895
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M150380-1202 2550ND1.4J 1.1J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1674896MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287711002
1674897
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1501880-12018 1 2550ND9.1 9.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
Analytical Lab
Page 22 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287711
J16020574
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/43280
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92287711001, 92287711002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1674239
Associated Lab Samples:92287711001, 92287711002
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 02/26/16 14:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1674240LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1674241MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287719001
1674242
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 94 90-11094 0 10.5ND 0.47 0.47
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1674243MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287719002
1674244
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 99 90-11099 0 10.5ND 0.49 0.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
Analytical Lab
Page 23 of 29
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92287711
J16020574
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/55437
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92287711001, 92287711002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1492929
Associated Lab Samples:92287711001, 92287711002
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 03/01/16 11:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1492930LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.075.075 100 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1492931MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287631001
1492932
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 153 85-115153 0 20.025ND 0.038 0.038
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1492933MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92287761002
1492934
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .38 103 85-115101 1 20.380.60 0.98 0.98
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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[phone]
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Analytical Lab
Page 24 of 29
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92287711
J16020574
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Closing continuing calibration verification sample not analyzed due to instrument error. Data accepted based on LCS
recovery and sample duplicate.1g
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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[phone]
Page 17 of 20
Analytical Lab
Page 25 of 29
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92287711
J16020574
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92287711001 AIR/253142016005300RSK 175
92287711002 AIR/253382016005302RSK 175
92287711001 WET/433072016005300SM 2320B
92287711002 WET/433072016005302SM 2320B
92287711001 WET/432802016005300SM 4500-S2D
92287711002 WET/432802016005302SM 4500-S2D
92287711001 WETA/554372016005300EPA 218.7
92287711002 WETA/554372016005302EPA 218.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 03/04/2016 03:33 PM
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[phone]
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Analytical Lab
Page 26 of 29
Page 19 of 20
Analytical Lab
Page 27 of 29
Page 20 of 20
Analytical Lab
Page 28 of 29
Analytical Lab
Page 29 of 29