NC0000396_App B Lab Reports - CSA RND 4 Sampling - J16010461Report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010461
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:2/5/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 60
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016002228 ASHEVILLE 20-Jan-16 5:40 PM Bart M Fitzpatrick GW-2
2016002229 ASHEVILLE 21-Jan-16 10:13 AM Bart M Fitzpatrick ABMW-04
2016002230 ASHEVILLE 21-Jan-16 11:15 AM Bart M Fitzpatrick ABMW-04D
2016002231 ASHEVILLE 21-Jan-16 12:01 PM Bart M Fitzpatrick ABMW-02
2016002232 ASHEVILLE 21-Jan-16 12:13 PM Bart M Fitzpatrick ABMW-02S
2016002233 ASHEVILLE 21-Jan-16 1:01 PM Bart M Fitzpatrick GW-3
2016002234 ASHEVILLE 21-Jan-16 12:20 PM Bart M Fitzpatrick CB-09SL
2016002235 ASHEVILLE 21-Jan-16 11:37 AM Bart M Fitzpatrick CB-09
2016002236 ASHEVILLE 21-Jan-16 10:30 AM Bart M Fitzpatrick CB-09BR
2016002237 ASHEVILLE 21-Jan-16 12:20 PM Kyle Donovan CB-6
2016002238 ASHEVILLE 21-Jan-16 11:10 AM Kyle Donovan MW-20A
2016002239 ASHEVILLE 21-Jan-16 2:39 PM Kyle Donovan Filter Blank
2016002240 ASHEVILLE 21-Jan-16 2:39 PM Kyle Donovan Equipment Blank
13 Total Samples
Page 2 of 60
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Therona T James Date:2/5/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002228
Collection Date:20-Jan-16 5:40 PM
Site:GW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.502 mg-N/L EPA 353.2 01/25/2016 13:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 210 mg/L EPA 300.0 01/25/2016 20:39 BGN9034550
Sulfate 120 mg/L EPA 300.0 01/25/2016 20:39 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:22 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:49 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.143 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.005 1
Barium (Ba)0.209 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.005 1
Boron (B)1.69 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.05 1
Iron (Fe)0.077 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.01 1
Manganese (Mn)2.12 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.005 1
Strontium (Sr)0.658 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.005 1
Zinc (Zn)0.054 mg/L EPA 200.7 01/25/2016 09:57 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)113 mg/L EPA 200.7 01/25/2016 13:06 FCJORDA0.1 10
Magnesium (Mg)34.6 mg/L EPA 200.7 01/25/2016 13:06 FCJORDA0.05 10
Potassium (K)2.58 mg/L EPA 200.7 01/25/2016 13:06 FCJORDA110
Sodium (Na)6.83 mg/L EPA 200.7 01/25/2016 13:06 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.284 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.005 1
Barium (Ba)0.250 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.005 1
Boron (B)1.72 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.05 1
Iron (Fe)0.472 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.01 1
Manganese (Mn)2.14 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.005 1
Strontium (Sr)0.675 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.005 1
Zinc (Zn)0.053 mg/L EPA 200.7 01/26/2016 10:28 FCJORDA0.005 1
Page 4 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002228
Collection Date:20-Jan-16 5:40 PM
Site:GW-2
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Arsenic (As)1.70 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Chromium (Cr)2.85 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Cobalt (Co)10.7 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Nickel (Ni)11.8 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 22:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 22:31 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 22:31 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Arsenic (As)1.82 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Chromium (Cr)52.0 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Cobalt (Co)11.5 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Copper (Cu)1.66 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Molybdenum (Mo)1.29 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Nickel (Ni)29.3 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 00:43 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 00:43 MHALL30.2 1
Vanadium (V) Low Level 0.581 ug/L EPA 200.8 01/26/2016 00:43 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 660 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.205 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 5 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002229
Collection Date:21-Jan-16 10:13 AM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.046 mg-N/L EPA 353.2 01/25/2016 13:40 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 16 mg/L EPA 300.0 01/25/2016 20:56 BGN9034110
Sulfate 290 mg/L EPA 300.0 01/25/2016 20:56 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:24 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:51 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.060 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.005 1
Barium (Ba)0.158 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.005 1
Boron (B)3.50 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.05 1
Iron (Fe)0.286 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.01 1
Manganese (Mn)0.098 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.005 1
Strontium (Sr)3.60 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.005 1
Zinc (Zn)0.045 mg/L EPA 200.7 01/25/2016 10:08 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)130 mg/L EPA 200.7 01/25/2016 13:10 FCJORDA0.1 10
Magnesium (Mg)64.0 mg/L EPA 200.7 01/25/2016 13:10 FCJORDA0.05 10
Potassium (K)19.3 mg/L EPA 200.7 01/25/2016 13:10 FCJORDA110
Sodium (Na)50.8 mg/L EPA 200.7 01/25/2016 13:10 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.529 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.005 1
Barium (Ba)0.162 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.005 1
Boron (B)3.49 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.05 1
Iron (Fe)0.478 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.01 1
Manganese (Mn)0.093 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.005 1
Strontium (Sr)3.59 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.005 1
Zinc (Zn)0.045 mg/L EPA 200.7 01/26/2016 10:31 FCJORDA0.005 1
Page 6 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002229
Collection Date:21-Jan-16 10:13 AM
Site:ABMW-04
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)2.68 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Arsenic (As)791 ug/L EPA 200.8 01/25/2016 22:36 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Molybdenum (Mo)536 ug/L EPA 200.8 01/25/2016 22:36 MHALL31010
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 22:36 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 22:36 MHALL30.2 1
Vanadium (V) Low Level 5.69 ug/L EPA 200.8 01/25/2016 22:36 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)2.95 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Arsenic (As)812 ug/L EPA 200.8 01/26/2016 00:48 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Copper (Cu)1.02 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Molybdenum (Mo)533 ug/L EPA 200.8 01/26/2016 00:48 MHALL31010
Nickel (Ni)1.12 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 00:48 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 00:48 MHALL30.2 1
Vanadium (V) Low Level 7.11 ug/L EPA 200.8 01/26/2016 00:48 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 820 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.539 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 11 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 7 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002230
Collection Date:21-Jan-16 11:15 AM
Site:ABMW-04D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.017 mg-N/L EPA 353.2 01/25/2016 13:43 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 01/26/2016 15:48 BGN90340.2 2
Sulfate 120 mg/L EPA 300.0 01/26/2016 15:48 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:27 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:54 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.005 1
Barium (Ba)0.083 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.005 1
Boron (B)1.13 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.05 1
Iron (Fe)7.30 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.01 1
Manganese (Mn)5.98 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.005 1
Strontium (Sr)0.185 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.005 1
Zinc (Zn)0.085 mg/L EPA 200.7 01/25/2016 10:20 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)33.6 mg/L EPA 200.7 01/25/2016 13:21 FCJORDA0.01 1
Magnesium (Mg)13.5 mg/L EPA 200.7 01/25/2016 13:21 FCJORDA0.005 1
Potassium (K)1.91 mg/L EPA 200.7 01/25/2016 13:21 FCJORDA0.1 1
Sodium (Na)5.23 mg/L EPA 200.7 01/25/2016 13:21 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.364 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.005 1
Barium (Ba)0.083 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.005 1
Boron (B)1.11 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.05 1
Iron (Fe)7.63 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.01 1
Manganese (Mn)5.79 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.005 1
Strontium (Sr)0.181 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.005 1
Zinc (Zn)0.081 mg/L EPA 200.7 01/26/2016 10:35 FCJORDA0.005 1
Page 8 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002230
Collection Date:21-Jan-16 11:15 AM
Site:ABMW-04D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Arsenic (As)1.87 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Cobalt (Co)51.8 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Nickel (Ni)2.32 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 22:41 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 22:41 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 22:41 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Arsenic (As)2.21 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Chromium (Cr)1.15 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Cobalt (Co)50.4 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Molybdenum (Mo)1.12 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Nickel (Ni)2.62 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 00:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 00:53 MHALL30.2 1
Vanadium (V) Low Level 0.603 ug/L EPA 200.8 01/26/2016 00:53 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.511 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 9 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002231
Collection Date:21-Jan-16 12:01 PM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 01/25/2016 13:45 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.9 mg/L EPA 300.0 01/26/2016 17:33 BGN90340.5 5
Sulfate 200 mg/L EPA 300.0 01/26/2016 17:33 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:29 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:56 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.032 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.005 1
Barium (Ba)0.327 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.005 1
Boron (B)2.00 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.05 1
Iron (Fe)2.94 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.01 1
Manganese (Mn)2.00 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.005 1
Strontium (Sr)6.76 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 01/25/2016 10:23 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)190 mg/L EPA 200.7 01/25/2016 13:25 FCJORDA0.1 10
Magnesium (Mg)45.9 mg/L EPA 200.7 01/25/2016 13:25 FCJORDA0.05 10
Potassium (K)18.2 mg/L EPA 200.7 01/25/2016 13:25 FCJORDA110
Sodium (Na)26.0 mg/L EPA 200.7 01/25/2016 13:25 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.067 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.005 1
Barium (Ba)0.343 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.005 1
Boron (B)2.06 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.05 1
Iron (Fe)3.41 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.01 1
Manganese (Mn)2.07 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.005 1
Strontium (Sr)6.94 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/26/2016 10:39 FCJORDA0.005 1
Page 10 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002231
Collection Date:21-Jan-16 12:01 PM
Site:ABMW-02
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Arsenic (As)1490 ug/L EPA 200.8 01/25/2016 22:46 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Cobalt (Co)13.2 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Molybdenum (Mo)279 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Nickel (Ni)1.62 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 22:46 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 22:46 MHALL30.2 1
Vanadium (V) Low Level 1.90 ug/L EPA 200.8 01/25/2016 22:46 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Arsenic (As)1600 ug/L EPA 200.8 01/26/2016 00:57 MHALL31010
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Cobalt (Co)13.2 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Molybdenum (Mo)281 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Nickel (Ni)1.51 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 00:57 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 00:57 MHALL30.2 1
Vanadium (V) Low Level 2.97 ug/L EPA 200.8 01/26/2016 00:57 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 840 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.674 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 11 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002232
Collection Date:21-Jan-16 12:13 PM
Site:ABMW-02S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.497 mg-N/L EPA 353.2 01/25/2016 13:46 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 16 mg/L EPA 300.0 01/25/2016 21:13 BGN9034110
Sulfate 630 mg/L EPA 300.0 01/25/2016 21:13 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:31 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:23 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)14.5 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.005 1
Barium (Ba)0.017 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.005 1
Boron (B)0.912 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.05 1
Iron (Fe)0.028 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.01 1
Manganese (Mn)20.0 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.005 1
Strontium (Sr)0.355 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.005 1
Zinc (Zn)0.493 mg/L EPA 200.7 01/25/2016 10:27 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)92.5 mg/L EPA 200.7 01/25/2016 13:29 FCJORDA0.1 10
Magnesium (Mg)27.2 mg/L EPA 200.7 01/25/2016 13:29 FCJORDA0.05 10
Potassium (K)5.02 mg/L EPA 200.7 01/25/2016 13:29 FCJORDA110
Sodium (Na)16.2 mg/L EPA 200.7 01/25/2016 13:29 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)13.3 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.005 1
Boron (B)0.851 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.05 1
Iron (Fe)0.027 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.01 1
Manganese (Mn)18.4 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.005 1
Strontium (Sr)0.340 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.005 1
Zinc (Zn)0.435 mg/L EPA 200.7 01/26/2016 10:43 FCJORDA0.005 1
Page 12 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002232
Collection Date:21-Jan-16 12:13 PM
Site:ABMW-02S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Arsenic (As)23.5 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Beryllium (Be)11.7 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Cadmium (Cd)3.52 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Cobalt (Co)588 ug/L EPA 200.8 01/25/2016 22:50 MHALL31010
Copper (Cu)4.42 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Nickel (Ni)291 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Selenium (Se)2.52 ug/L EPA 200.8 01/25/2016 22:50 MHALL311
Thallium (Tl) Low Level 0.235 ug/L EPA 200.8 01/25/2016 22:50 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 22:50 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Arsenic (As)23.5 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Beryllium (Be)12.4 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Cadmium (Cd)3.48 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Cobalt (Co)589 ug/L EPA 200.8 01/26/2016 01:02 MHALL31010
Copper (Cu)4.61 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Molybdenum (Mo)1.05 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Nickel (Ni)286 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Selenium (Se)2.48 ug/L EPA 200.8 01/26/2016 01:02 MHALL311
Thallium (Tl) Low Level 0.258 ug/L EPA 200.8 01/26/2016 01:02 MHALL30.2 1
Vanadium (V) Low Level 0.364 ug/L EPA 200.8 01/26/2016 01:02 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 710 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.363 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 13 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002233
Collection Date:21-Jan-16 1:01 PM
Site:GW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.061 mg-N/L EPA 353.2 01/25/2016 13:47 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 17 mg/L EPA 300.0 01/26/2016 17:50 BGN90340.2 2
Sulfate 50 mg/L EPA 300.0 01/26/2016 17:50 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:39 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:37 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.005 1
Barium (Ba)0.091 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.005 1
Boron (B)0.678 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.05 1
Iron (Fe)0.491 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.01 1
Manganese (Mn)3.56 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.005 1
Strontium (Sr)0.435 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 01/25/2016 10:31 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)27.1 mg/L EPA 200.7 01/25/2016 13:33 FCJORDA0.01 1
Magnesium (Mg)9.07 mg/L EPA 200.7 01/25/2016 13:33 FCJORDA0.005 1
Potassium (K)2.88 mg/L EPA 200.7 01/25/2016 13:33 FCJORDA0.1 1
Sodium (Na)12.7 mg/L EPA 200.7 01/25/2016 13:33 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.182 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.005 1
Barium (Ba)0.072 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.005 1
Boron (B)0.477 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.05 1
Iron (Fe)0.955 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.01 1
Manganese (Mn)3.20 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.005 1
Strontium (Sr)0.316 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/26/2016 10:47 FCJORDA0.005 1
Page 14 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002233
Collection Date:21-Jan-16 1:01 PM
Site:GW-3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Cobalt (Co)44.6 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Nickel (Ni)2.34 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Selenium (Se)1.22 ug/L EPA 200.8 01/25/2016 22:55 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 22:55 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 22:55 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Cobalt (Co)51.5 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Nickel (Ni)2.41 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Selenium (Se)1.17 ug/L EPA 200.8 01/26/2016 01:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 01:07 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 01:07 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.757 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 15 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002234
Collection Date:21-Jan-16 12:20 PM
Site:CB-09SL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.262 mg-N/L EPA 353.2 01/25/2016 13:48 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.5 mg/L EPA 300.0 01/25/2016 19:48 BGN90340.1 1
Sulfate 0.24 mg/L EPA 300.0 01/25/2016 19:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:46 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:39 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.005 1
Barium (Ba)0.033 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.005 1
Strontium (Sr)0.026 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.005 1
Zinc (Zn)0.029 mg/L EPA 200.7 01/25/2016 10:35 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.14 mg/L EPA 200.7 01/25/2016 13:37 FCJORDA0.01 1
Magnesium (Mg)1.88 mg/L EPA 200.7 01/25/2016 13:37 FCJORDA0.005 1
Potassium (K)2.02 mg/L EPA 200.7 01/25/2016 13:37 FCJORDA0.1 1
Sodium (Na)3.00 mg/L EPA 200.7 01/25/2016 13:37 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.167 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.005 1
Barium (Ba)0.043 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.05 1
Iron (Fe)0.095 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.01 1
Manganese (Mn)0.015 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.005 1
Strontium (Sr)0.030 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.005 1
Zinc (Zn)0.022 mg/L EPA 200.7 01/26/2016 10:50 FCJORDA0.005 1
Page 16 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002234
Collection Date:21-Jan-16 12:20 PM
Site:CB-09SL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 22:11 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 22:11 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 22:11 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 01:12 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 01:12 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 01:12 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 41 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.152 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 17 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002235
Collection Date:21-Jan-16 11:37 AM
Site:CB-09
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.256 mg-N/L EPA 353.2 01/25/2016 13:49 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.9 mg/L EPA 300.0 01/25/2016 20:05 BGN90340.1 1
Sulfate 0.14 mg/L EPA 300.0 01/25/2016 20:05 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:49 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:42 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.01 1
Manganese (Mn)0.034 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.005 1
Strontium (Sr)0.007 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.005 1
Zinc (Zn)0.022 mg/L EPA 200.7 01/25/2016 10:39 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.463 mg/L EPA 200.7 01/25/2016 13:40 FCJORDA0.01 1
Magnesium (Mg)0.913 mg/L EPA 200.7 01/25/2016 13:40 FCJORDA0.005 1
Potassium (K)0.689 mg/L EPA 200.7 01/25/2016 13:40 FCJORDA0.1 1
Sodium (Na)3.89 mg/L EPA 200.7 01/25/2016 13:40 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.062 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.005 1
Barium (Ba)0.026 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.05 1
Iron (Fe)0.084 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.01 1
Manganese (Mn)0.036 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.005 1
Strontium (Sr)0.007 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 01/26/2016 10:54 FCJORDA0.005 1
Page 18 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002235
Collection Date:21-Jan-16 11:37 AM
Site:CB-09
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Nickel (Ni)1.09 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 23:29 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 23:29 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 23:29 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Nickel (Ni)1.28 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 01:17 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 01:17 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 01:17 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.143 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 19 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002236
Collection Date:21-Jan-16 10:30 AM
Site:CB-09BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.125 mg-N/L EPA 353.2 01/25/2016 13:51 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.4 mg/L EPA 300.0 01/25/2016 20:22 BGN90340.1 1
Sulfate 1.2 mg/L EPA 300.0 01/25/2016 20:22 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:51 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:44 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.05 1
Iron (Fe)0.103 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.01 1
Manganese (Mn)0.065 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.005 1
Strontium (Sr)0.068 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.005 1
Zinc (Zn)0.027 mg/L EPA 200.7 01/25/2016 10:43 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.5 mg/L EPA 200.7 01/25/2016 13:44 FCJORDA0.01 1
Magnesium (Mg)3.02 mg/L EPA 200.7 01/25/2016 13:44 FCJORDA0.005 1
Potassium (K)2.55 mg/L EPA 200.7 01/25/2016 13:44 FCJORDA0.1 1
Sodium (Na)3.47 mg/L EPA 200.7 01/25/2016 13:44 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.080 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.05 1
Iron (Fe)0.678 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.01 1
Manganese (Mn)0.070 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.005 1
Strontium (Sr)0.071 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.005 1
Zinc (Zn)0.032 mg/L EPA 200.7 01/26/2016 10:58 FCJORDA0.005 1
Page 20 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002236
Collection Date:21-Jan-16 10:30 AM
Site:CB-09BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 23:00 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 23:00 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 23:00 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Chromium (Cr)9.08 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Nickel (Ni)5.79 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 01:41 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 01:41 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 01:41 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 76 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.325 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 11 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 21 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002237
Collection Date:21-Jan-16 12:20 PM
Site:CB-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.018 mg-N/L EPA 353.2 01/25/2016 13:52 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 55 mg/L EPA 300.0 01/26/2016 18:07 BGN9034220
Sulfate 590 mg/L EPA 300.0 01/26/2016 18:07 BGN903420200
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:53 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:47 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)1.26 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.005 1
Barium (Ba)0.037 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.005 1
Boron (B)0.512 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.05 1
Iron (Fe)21.2 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.01 1
Manganese (Mn)12.2 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.005 1
Strontium (Sr)0.756 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 01/25/2016 10:46 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)144 mg/L EPA 200.7 01/25/2016 13:48 FCJORDA0.1 10
Magnesium (Mg)26.9 mg/L EPA 200.7 01/25/2016 13:48 FCJORDA0.05 10
Potassium (K)11.6 mg/L EPA 200.7 01/25/2016 13:48 FCJORDA110
Sodium (Na)41.0 mg/L EPA 200.7 01/25/2016 13:48 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.60 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.005 1
Barium (Ba)0.045 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.005 1
Boron (B)0.599 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.05 1
Iron (Fe)16.6 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.01 1
Manganese (Mn)14.3 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.005 1
Strontium (Sr)0.911 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 01/26/2016 11:21 FCJORDA0.005 1
Page 22 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002237
Collection Date:21-Jan-16 12:20 PM
Site:CB-6
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Cobalt (Co)22.3 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Copper (Cu)1.79 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Nickel (Ni)17.4 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 23:05 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 23:05 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 23:05 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Cobalt (Co)23.6 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Nickel (Ni)18.7 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 01:22 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 01:22 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 01:22 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 910 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 1.9 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 23 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002238
Collection Date:21-Jan-16 11:10 AM
Site:MW-20A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.126 mg-N/L EPA 353.2 01/25/2016 13:53 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 01/26/2016 18:40 BGN9034110
Sulfate 180 mg/L EPA 300.0 01/26/2016 18:40 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:56 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:49 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.753 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.005 1
Barium (Ba)0.037 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.005 1
Boron (B)0.613 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.05 1
Iron (Fe)6.72 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.01 1
Manganese (Mn)4.61 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.005 1
Strontium (Sr)0.261 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.005 1
Zinc (Zn)0.022 mg/L EPA 200.7 01/25/2016 10:58 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)32.9 mg/L EPA 200.7 01/25/2016 13:52 FCJORDA0.01 1
Magnesium (Mg)11.4 mg/L EPA 200.7 01/25/2016 13:52 FCJORDA0.005 1
Potassium (K)2.50 mg/L EPA 200.7 01/25/2016 13:52 FCJORDA0.1 1
Sodium (Na)12.4 mg/L EPA 200.7 01/25/2016 13:52 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.80 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.005 1
Boron (B)0.625 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.05 1
Iron (Fe)7.11 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.01 1
Manganese (Mn)4.61 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.005 1
Strontium (Sr)0.269 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 01/26/2016 11:10 FCJORDA0.005 1
Page 24 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002238
Collection Date:21-Jan-16 11:10 AM
Site:MW-20A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Cadmium (Cd)1.55 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Cobalt (Co)33.1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Nickel (Ni)9.04 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 23:10 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 23:10 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 23:10 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Cadmium (Cd)1.57 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Cobalt (Co)33.8 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Nickel (Ni)9.30 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Selenium (Se)1.19 ug/L EPA 200.8 01/26/2016 02:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 02:01 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 02:01 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 25 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002239
Collection Date:21-Jan-16 2:39 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/29/2016 15:52 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/25/2016 11:02 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 23:49 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 23:49 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 23:49 MHALL30.3 1
Page 26 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002240
Collection Date:21-Jan-16 2:39 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/25/2016 13:59 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/25/2016 22:21 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/25/2016 22:21 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:58 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 01/25/2016 13:56 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/25/2016 13:56 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/25/2016 13:56 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/25/2016 13:56 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/26/2016 11:23 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/26/2016 02:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/26/2016 02:06 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/26/2016 02:06 MHALL30.3 1
Page 27 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010461
2016002240
Collection Date:21-Jan-16 2:39 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/26/2016 15:53 CJELLIO251
Total Carbon
TOC 0.113 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/26/2016 09:45 CJELLIO51
Page 28 of 60
#=CL#
January 28, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92283994
92283994
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010461
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 25, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 31
Page 29 of 60
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92283994
J16010461
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 31
Page 30 of 60
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92283994
J16010461
Lab ID Sample ID Matrix Date Collected Date Received
92283994001 2016002228 Water 01/20/16 17:40 01/25/16 11:07
92283994002 2016002229 Water 01/21/16 10:13 01/25/16 11:07
92283994003 2016002230 Water 01/21/16 11:15 01/25/16 11:07
92283994004 2016002231 Water 01/21/16 12:01 01/25/16 11:07
92283994005 2016002232 Water 01/21/16 12:13 01/25/16 11:07
92283994006 2016002233 Water 01/21/16 13:01 01/25/16 11:07
92283994007 2016002234 Water 01/21/16 12:20 01/25/16 11:07
92283994008 2016002235 Water 01/21/16 11:37 01/25/16 11:07
92283994009 2016002236 Water 01/21/16 10:30 01/25/16 11:07
92283994010 2016002237 Water 01/21/16 12:20 01/25/16 11:07
92283994011 2016002238 Water 01/21/16 11:10 01/25/16 11:07
92283994012 2016002240 Water 01/21/16 14:39 01/25/16 11:07
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 31
Page 31 of 60
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283994
J16010461
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92283994001 2016002228 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994002 2016002229 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994003 2016002230 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994004 2016002231 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994005 2016002232 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994006 2016002233 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994007 2016002234 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994008 2016002235 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994009 2016002236 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994010 2016002237 RSK 175 1 PASI-MSTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 31
Page 32 of 60
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283994
J16010461
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994011 2016002238 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283994012 2016002240 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 31
Page 33 of 60
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283994
J16010461
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283994001 2016002228
Alkalinity,Bicarbonate (CaCO3)19.7 mg/L 01/26/16 12:415.0SM 2320B
Alkalinity, Total as CaCO3 19.7 mg/L 01/26/16 12:415.0SM 2320B
Chromium, Hexavalent 0.050 ug/L 01/28/16 10:36 M10.030EPA 218.7
92283994002 2016002229
Alkalinity,Bicarbonate (CaCO3)394 mg/L 01/26/16 13:185.0SM 2320B
Alkalinity, Total as CaCO3 394 mg/L 01/26/16 13:185.0SM 2320B
92283994003 2016002230
Alkalinity,Bicarbonate (CaCO3)51.2 mg/L 01/26/16 13:345.0SM 2320B
Alkalinity, Total as CaCO3 51.2 mg/L 01/26/16 13:345.0SM 2320B
92283994004 2016002231
Methane 26.8 ug/L 01/27/16 14:5410.0RSK 175
Alkalinity,Bicarbonate (CaCO3)524 mg/L 01/26/16 13:465.0SM 2320B
Alkalinity, Total as CaCO3 524 mg/L 01/26/16 13:465.0SM 2320B
92283994005 2016002232
Methane 13.0 ug/L 01/27/16 15:0310.0RSK 175
92283994006 2016002233
Alkalinity,Bicarbonate (CaCO3)43.5 mg/L 01/26/16 14:125.0SM 2320B
Alkalinity, Total as CaCO3 43.5 mg/L 01/26/16 14:125.0SM 2320B
92283994007 2016002234
Alkalinity,Bicarbonate (CaCO3)14.1 mg/L 01/26/16 14:435.0SM 2320B
Alkalinity, Total as CaCO3 14.1 mg/L 01/26/16 14:435.0SM 2320B
Chromium, Hexavalent 0.20 ug/L 01/28/16 11:410.030EPA 218.7
92283994008 2016002235
Chromium, Hexavalent 0.12 ug/L 01/28/16 11:540.060EPA 218.7
92283994009 2016002236
Alkalinity,Bicarbonate (CaCO3)38.3 mg/L 01/26/16 15:025.0SM 2320B
Alkalinity, Total as CaCO3 38.3 mg/L 01/26/16 15:025.0SM 2320B
Chromium, Hexavalent 0.068 ug/L 01/28/16 12:070.060EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 31
Page 34 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283994
J16010461
Method:
Client:Duke Energy
RSK 175
Date:January 28, 2016
Description:RSK 175 AIR Headspace
General Information:
12 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 31
Page 35 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283994
J16010461
Method:
Client:Duke Energy
SM 2320B
Date:January 28, 2016
Description:2320B Alkalinity
General Information:
12 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42677
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283994001,92283994011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1653211)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1653212)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 31
Page 36 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283994
J16010461
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 28, 2016
Description:4500S2D Sulfide Water
General Information:
12 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 31
Page 37 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283994
J16010461
Method:
Client:Duke Energy
EPA 218.7
Date:January 28, 2016
Description:Hexavalent Chromium by IC
General Information:
12 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/54288
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283994001,92283994011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1460290)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 31
Page 38 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002228 Lab ID:92283994001 Collected:01/20/16 17:40 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 14:30 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)19.7 mg/L 01/26/16 12:415.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 12:415.0 1
Alkalinity, Total as CaCO3 19.7 mg/L 01/26/16 12:415.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.050 ug/L 01/28/16 10:36 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 31
Page 39 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002229 Lab ID:92283994002 Collected:01/21/16 10:13 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 14:38 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)394 mg/L 01/26/16 13:185.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 13:185.0 1
Alkalinity, Total as CaCO3 394 mg/L 01/26/16 13:185.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/27/16 15:23 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 31
Page 40 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002230 Lab ID:92283994003 Collected:01/21/16 11:15 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 14:46 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)51.2 mg/L 01/26/16 13:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 13:345.0 1
Alkalinity, Total as CaCO3 51.2 mg/L 01/26/16 13:345.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/27/16 15:36 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 31
Page 41 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002231 Lab ID:92283994004 Collected:01/21/16 12:01 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 26.8 ug/L 01/27/16 14:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)524 mg/L 01/26/16 13:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 13:465.0 1
Alkalinity, Total as CaCO3 524 mg/L 01/26/16 13:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/28/16 11:15 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 31
Page 42 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002232 Lab ID:92283994005 Collected:01/21/16 12:13 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 13.0 ug/L 01/27/16 15:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/26/16 14:055.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 14:055.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/26/16 14:055.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/28/16 11:28 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 31
Page 43 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002233 Lab ID:92283994006 Collected:01/21/16 13:01 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 15:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)43.5 mg/L 01/26/16 14:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 14:125.0 1
Alkalinity, Total as CaCO3 43.5 mg/L 01/26/16 14:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/27/16 16:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 31
Page 44 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002234 Lab ID:92283994007 Collected:01/21/16 12:20 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 15:19 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)14.1 mg/L 01/26/16 14:435.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 14:435.0 1
Alkalinity, Total as CaCO3 14.1 mg/L 01/26/16 14:435.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.20 ug/L 01/28/16 11:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 31
Page 45 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002235 Lab ID:92283994008 Collected:01/21/16 11:37 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 15:27 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/26/16 14:545.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 14:545.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/26/16 14:545.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.12 ug/L 01/28/16 11:54 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 31
Page 46 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002236 Lab ID:92283994009 Collected:01/21/16 10:30 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 15:55 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)38.3 mg/L 01/26/16 15:025.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 15:025.0 1
Alkalinity, Total as CaCO3 38.3 mg/L 01/26/16 15:025.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.068 ug/L 01/28/16 12:07 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 31
Page 47 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002237 Lab ID:92283994010 Collected:01/21/16 12:20 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 16:12 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/26/16 15:145.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 15:145.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/26/16 15:145.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/27/16 17:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 31
Page 48 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002238 Lab ID:92283994011 Collected:01/21/16 11:10 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 16:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/26/16 15:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 15:205.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/26/16 15:20 M15.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/27/16 17:46 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 31
Page 49 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283994
J16010461
Sample:2016002240 Lab ID:92283994012 Collected:01/21/16 14:39 Received:01/25/16 11:07 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/27/16 16:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/26/16 15:535.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/26/16 15:535.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/26/16 15:535.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/28/16 12:20 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 31
Page 50 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283994
J16010461
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25094
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2181048
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/27/16 13:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2181049LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2181050
Methane ug/L 56.160.7 93 85-1159154.9 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283997001
2182260SAMPLE DUPLICATE:
Methane ug/L 1.5J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283994009
2182261SAMPLE DUPLICATE:
Methane ug/L 1.3J 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 31
Page 51 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283994
J16010461
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42677
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1653207
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/26/16 12:20
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/26/16 12:20
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/26/16 12:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1653208LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.550 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1653209MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283994001
1653210
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 96 80-12095 1 255019.7 67.7 67.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1653211MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283994011
1653212
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1507580-12075 1 2550ND41.7 42.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 31
Page 52 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283994
J16010461
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42680
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1653324
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/26/16 12:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1653325LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1653326MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283997001
1653327
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L H1.5 99 90-11099 0 10.5ND 0.50 0.50
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1653328MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283994001
1653329
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 108 90-110108 0 10.5ND 0.54 0.54
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 31
Page 53 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283994
J16010461
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/54288
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1460288
Associated Lab Samples:92283994001, 92283994002, 92283994003, 92283994004, 92283994005, 92283994006, 92283994007,
92283994008, 92283994009, 92283994010, 92283994011, 92283994012
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/27/16 14:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1460289LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.080.075 106 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1460290MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283994001
1460291
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 75 85-11588 4 20.0250.050 0.069 0.072
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1460292MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283994011
1460293
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 91 85-11589 2 20.075ND 0.068 0.067
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
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Huntersville, NC 28078
[phone]
Page 26 of 31
Page 54 of 60
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92283994
J16010461
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analysis conducted outside the EPA method holding time.H1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 31
Page 55 of 60
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283994
J16010461
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283994001 AIR/250942016002228RSK 175
92283994002 AIR/250942016002229RSK 175
92283994003 AIR/250942016002230RSK 175
92283994004 AIR/250942016002231RSK 175
92283994005 AIR/250942016002232RSK 175
92283994006 AIR/250942016002233RSK 175
92283994007 AIR/250942016002234RSK 175
92283994008 AIR/250942016002235RSK 175
92283994009 AIR/250942016002236RSK 175
92283994010 AIR/250942016002237RSK 175
92283994011 AIR/250942016002238RSK 175
92283994012 AIR/250942016002240RSK 175
92283994001 WET/426772016002228SM 2320B
92283994002 WET/426772016002229SM 2320B
92283994003 WET/426772016002230SM 2320B
92283994004 WET/426772016002231SM 2320B
92283994005 WET/426772016002232SM 2320B
92283994006 WET/426772016002233SM 2320B
92283994007 WET/426772016002234SM 2320B
92283994008 WET/426772016002235SM 2320B
92283994009 WET/426772016002236SM 2320B
92283994010 WET/426772016002237SM 2320B
92283994011 WET/426772016002238SM 2320B
92283994012 WET/426772016002240SM 2320B
92283994001 WET/426802016002228SM 4500-S2D
92283994002 WET/426802016002229SM 4500-S2D
92283994003 WET/426802016002230SM 4500-S2D
92283994004 WET/426802016002231SM 4500-S2D
92283994005 WET/426802016002232SM 4500-S2D
92283994006 WET/426802016002233SM 4500-S2D
92283994007 WET/426802016002234SM 4500-S2D
92283994008 WET/426802016002235SM 4500-S2D
92283994009 WET/426802016002236SM 4500-S2D
92283994010 WET/426802016002237SM 4500-S2D
92283994011 WET/426802016002238SM 4500-S2D
92283994012 WET/426802016002240SM 4500-S2D
92283994001 WETA/542882016002228EPA 218.7
92283994002 WETA/542882016002229EPA 218.7
92283994003 WETA/542882016002230EPA 218.7
92283994004 WETA/542882016002231EPA 218.7
92283994005 WETA/542882016002232EPA 218.7
92283994006 WETA/542882016002233EPA 218.7
92283994007 WETA/542882016002234EPA 218.7
92283994008 WETA/542882016002235EPA 218.7
92283994009 WETA/542882016002236EPA 218.7
92283994010 WETA/542882016002237EPA 218.7
92283994011 WETA/542882016002238EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283994
J16010461
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283994012 WETA/542882016002240EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/28/2016 05:10 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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