NC0000396_App B Lab Reports - CSA RND 4 Sampling - J16010397report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010397
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:2/5/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 81
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016001989 ASHEVILLE 20-Jan-16 9:34 AM illegible AMW-1B
2016001990 ASHEVILLE 20-Jan-16 9:34 AM illegible AMW-1B DUP
2016001991 ASHEVILLE 20-Jan-16 10:49 AM illegible AMW-3B
2016001992 ASHEVILLE 20-Jan-16 1:28 PM illegible CB-01
2016001993 ASHEVILLE 20-Jan-16 2:16 PM illegible CB-01D
2016001994 ASHEVILLE 20-Jan-16 4:05 PM illegible MW-13D
2016001995 ASHEVILLE 20-Jan-16 3:52 PM illegible MW-13BR
2016001996 ASHEVILLE 20-Jan-16 11:22 AM illegible PZ-17S
2016001997 ASHEVILLE 20-Jan-16 3:20 PM illegible PZ-17D
2016001998 ASHEVILLE 20-Jan-16 11:16 AM illegible MW-3D
2016001999 ASHEVILLE 20-Jan-16 1:50 PM illegible MW-12D
2016002000 ASHEVILLE 20-Jan-16 4:40 PM illegible CB-08
2016002001 ASHEVILLE 20-Jan-16 3:28 PM illegible CB-08BR
2016002002 ASHEVILLE 20-Jan-16 12:33 PM illegible MW-08S
2016002003 ASHEVILLE 20-Jan-16 4:45 PM illegible Filter Blank
2016002004 ASHEVILLE 20-Jan-16 4:45 PM illegible Equipment Blank
2016002005 ASHEVILLE 20-Jan-16 11:03 AM illegible MW-09S
2016002006 ASHEVILLE 20-Jan-16 9:45 AM illegible MW-09D
2016002007 ASHEVILLE 20-Jan-16 9:20 AM illegible MW-09BR
19 Total Samples
Page 2 of 81
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:2/5/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001989
Collection Date:20-Jan-16 9:34 AM
Site:AMW-1B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.019 mg-N/L EPA 353.2 01/25/2016 13:00 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.8 mg/L EPA 300.0 01/22/2016 02:49 BGN90340.5 5
Sulfate 120 mg/L EPA 300.0 01/22/2016 02:49 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:11 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:38 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.005 1
Boron (B)0.396 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.05 1
Iron (Fe)6.78 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.01 1
Manganese (Mn)0.355 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 01/21/2016 10:49 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)45.9 mg/L EPA 200.7 01/25/2016 11:27M4 FCJORDA0.01 1
Magnesium (Mg)2.32 mg/L EPA 200.7 01/25/2016 11:27 FCJORDA0.005 1
Potassium (K)1.98 mg/L EPA 200.7 01/25/2016 11:27 FCJORDA0.1 1
Sodium (Na)21.2 mg/L EPA 200.7 01/25/2016 11:27M4 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.053 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.005 1
Boron (B)0.393 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.05 1
Iron (Fe)8.11 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.01 1
Manganese (Mn)0.332 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 01/21/2016 17:11 FCJORDA0.005 1
Page 4 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001989
Collection Date:20-Jan-16 9:34 AM
Site:AMW-1B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Molybdenum (Mo)2.02 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 19:50 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 19:50 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 19:50 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Molybdenum (Mo)2.12 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 01:00 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:00 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:00 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 250 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.265 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 17 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 5 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001990
Collection Date:20-Jan-16 9:34 AM
Site:AMW-1B DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.021 mg-N/L EPA 353.2 01/25/2016 13:02 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.9 mg/L EPA 300.0 01/22/2016 03:05 BGN90340.5 5
Sulfate 130 mg/L EPA 300.0 01/22/2016 03:05 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:14 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:40 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.005 1
Boron (B)0.401 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.05 1
Iron (Fe)6.62 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.01 1
Manganese (Mn)0.354 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 01/21/2016 11:00 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)48.7 mg/L EPA 200.7 01/25/2016 11:38M4 FCJORDA0.01 1
Magnesium (Mg)2.45 mg/L EPA 200.7 01/25/2016 11:38 FCJORDA0.005 1
Potassium (K)2.08 mg/L EPA 200.7 01/25/2016 11:38 FCJORDA0.1 1
Sodium (Na)22.2 mg/L EPA 200.7 01/25/2016 11:38M4 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.064 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.005 1
Boron (B)0.402 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.05 1
Iron (Fe)7.58 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.01 1
Manganese (Mn)0.353 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.005 1
Strontium (Sr)0.083 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 01/21/2016 17:23 FCJORDA0.005 1
Page 6 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001990
Collection Date:20-Jan-16 9:34 AM
Site:AMW-1B DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Molybdenum (Mo)2.09 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 19:55 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 19:55 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 19:55 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Molybdenum (Mo)2.07 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 00:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 00:40 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 00:40 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 260 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.279 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 15 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 7 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001991
Collection Date:20-Jan-16 10:49 AM
Site:AMW-3B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.250 mg-N/L EPA 353.2 01/25/2016 12:57 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.61 mg/L EPA 300.0 01/22/2016 03:22 BGN90340.1 1
Sulfate 1.3 mg/L EPA 300.0 01/22/2016 03:22 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:16 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:43 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.005 1
Strontium (Sr)0.058 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 01/21/2016 11:11 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.15 mg/L EPA 200.7 01/25/2016 11:50 FCJORDA0.01 1
Magnesium (Mg)1.85 mg/L EPA 200.7 01/25/2016 11:50 FCJORDA0.005 1
Potassium (K)1.57 mg/L EPA 200.7 01/25/2016 11:50 FCJORDA0.1 1
Sodium (Na)5.05 mg/L EPA 200.7 01/25/2016 11:50 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.05 1
Iron (Fe)0.020 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.005 1
Strontium (Sr)0.058 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 17:27 FCJORDA0.005 1
Page 8 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001991
Collection Date:20-Jan-16 10:49 AM
Site:AMW-3B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 20:00 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:00 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:00 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 01:05 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:05 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:05 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 47 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.221 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 9 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001992
Collection Date:20-Jan-16 1:28 PM
Site:CB-01
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.436 mg-N/L EPA 353.2 01/25/2016 13:03 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 300.0 01/21/2016 23:09 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/21/2016 23:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:18 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:58 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.050 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.005 1
Barium (Ba)0.015 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.01 1
Manganese (Mn)0.022 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 01/21/2016 11:15 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.041 mg/L EPA 200.7 01/25/2016 12:01 FCJORDA0.01 1
Magnesium (Mg)0.383 mg/L EPA 200.7 01/25/2016 12:01 FCJORDA0.005 1
Potassium (K)0.373 mg/L EPA 200.7 01/25/2016 12:01 FCJORDA0.1 1
Sodium (Na)1.03 mg/L EPA 200.7 01/25/2016 12:01 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.336 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.05 1
Iron (Fe)0.279 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.01 1
Manganese (Mn)0.028 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.005 1
Zinc (Zn)0.020 mg/L EPA 200.7 01/21/2016 17:30 FCJORDA0.005 1
Page 10 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001992
Collection Date:20-Jan-16 1:28 PM
Site:CB-01
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Cobalt (Co)1.90 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Nickel (Ni)1.13 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 20:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:04 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:04 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Cobalt (Co)2.10 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Nickel (Ni)1.53 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 01:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:09 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.101 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 11 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001993
Collection Date:20-Jan-16 2:16 PM
Site:CB-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.093 mg-N/L EPA 353.2 01/25/2016 13:04 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.83 mg/L EPA 300.0 01/21/2016 23:59 BGN90340.1 1
Sulfate 3.2 mg/L EPA 300.0 01/21/2016 23:59 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:06 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.005 1
Barium (Ba)0.010 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.05 1
Iron (Fe)0.142 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.01 1
Manganese (Mn)0.148 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.005 1
Strontium (Sr)0.014 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 01/21/2016 11:19 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.53 mg/L EPA 200.7 01/25/2016 12:05 FCJORDA0.01 1
Magnesium (Mg)0.873 mg/L EPA 200.7 01/25/2016 12:05 FCJORDA0.005 1
Potassium (K)0.861 mg/L EPA 200.7 01/25/2016 12:05 FCJORDA0.1 1
Sodium (Na)1.78 mg/L EPA 200.7 01/25/2016 12:05 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.094 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.005 1
Barium (Ba)0.011 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.05 1
Iron (Fe)0.269 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.01 1
Manganese (Mn)0.151 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.005 1
Strontium (Sr)0.014 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 01/21/2016 17:34 FCJORDA0.005 1
Page 12 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001993
Collection Date:20-Jan-16 2:16 PM
Site:CB-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Cobalt (Co)2.48 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Nickel (Ni)2.23 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 20:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:09 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Chromium (Cr)1.83 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Cobalt (Co)2.34 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Nickel (Ni)2.72 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 01:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:14 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:14 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.112 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 13 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001994
Collection Date:20-Jan-16 4:05 PM
Site:MW-13D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.053 mg-N/L EPA 353.2 01/25/2016 13:05 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.6 mg/L EPA 300.0 01/22/2016 00:16 BGN90340.1 1
Sulfate 1.2 mg/L EPA 300.0 01/22/2016 00:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:33 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:08 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.05 1
Iron (Fe)2.63 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.01 1
Manganese (Mn)0.625 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.005 1
Strontium (Sr)0.214 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 11:23 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)15.6 mg/L EPA 200.7 01/25/2016 12:09 FCJORDA0.01 1
Magnesium (Mg)1.76 mg/L EPA 200.7 01/25/2016 12:09 FCJORDA0.005 1
Potassium (K)3.86 mg/L EPA 200.7 01/25/2016 12:09 FCJORDA0.1 1
Sodium (Na)5.59 mg/L EPA 200.7 01/25/2016 12:09 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.095 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.005 1
Barium (Ba)0.021 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.05 1
Iron (Fe)3.27 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.01 1
Manganese (Mn)0.747 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.005 1
Strontium (Sr)0.265 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 17:38 FCJORDA0.005 1
Page 14 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001994
Collection Date:20-Jan-16 4:05 PM
Site:MW-13D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Cobalt (Co)5.20 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Molybdenum (Mo)2.60 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 20:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:14 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:14 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Cobalt (Co)4.69 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Molybdenum (Mo)2.46 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 01:19 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:19 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:19 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 69 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.483 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 15 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001995
Collection Date:20-Jan-16 3:52 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.624 mg-N/L EPA 353.2 01/25/2016 13:09 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 5.0 mg/L EPA 300.0 01/22/2016 00:33 BGN90340.1 1
Sulfate 1.8 mg/L EPA 300.0 01/22/2016 00:33 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:35 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:11 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.035 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.005 1
Barium (Ba)0.028 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.01 1
Manganese (Mn)0.026 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.005 1
Strontium (Sr)0.017 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/21/2016 11:27 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.22 mg/L EPA 200.7 01/25/2016 12:13 FCJORDA0.01 1
Magnesium (Mg)2.14 mg/L EPA 200.7 01/25/2016 12:13 FCJORDA0.005 1
Potassium (K)0.934 mg/L EPA 200.7 01/25/2016 12:13 FCJORDA0.1 1
Sodium (Na)2.26 mg/L EPA 200.7 01/25/2016 12:13 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.005 1
Barium (Ba)0.028 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.05 1
Iron (Fe)0.022 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.01 1
Manganese (Mn)0.025 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.005 1
Strontium (Sr)0.016 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 17:42 FCJORDA0.005 1
Page 16 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001995
Collection Date:20-Jan-16 3:52 PM
Site:MW-13BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 20:19 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:19 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:19 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 01:24 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:24 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:24 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.158 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 17 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001996
Collection Date:20-Jan-16 11:22 AM
Site:PZ-17S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.281 mg-N/L EPA 353.2 01/25/2016 13:10 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 1.8 mg/L EPA 300.0 01/22/2016 02:32 BGN90340.1 1
Sulfate 14 mg/L EPA 300.0 01/22/2016 02:32 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:38 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:13 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.005 1
Barium (Ba)0.061 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.01 1
Manganese (Mn)0.018 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.005 1
Zinc (Zn)0.030 mg/L EPA 200.7 01/21/2016 11:31 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.28 mg/L EPA 200.7 01/25/2016 12:17 FCJORDA0.01 1
Magnesium (Mg)0.722 mg/L EPA 200.7 01/25/2016 12:17 FCJORDA0.005 1
Potassium (K)2.55 mg/L EPA 200.7 01/25/2016 12:17 FCJORDA0.1 1
Sodium (Na)2.62 mg/L EPA 200.7 01/25/2016 12:17 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.068 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.005 1
Barium (Ba)0.063 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.05 1
Iron (Fe)0.040 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.01 1
Manganese (Mn)0.019 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.005 1
Strontium (Sr)0.096 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 17:46 FCJORDA0.005 1
Page 18 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001996
Collection Date:20-Jan-16 11:22 AM
Site:PZ-17S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Copper (Cu)1.66 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Nickel (Ni)1.44 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Selenium (Se)7.59 ug/L EPA 200.8 01/25/2016 20:24 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:24 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:24 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Copper (Cu)1.75 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Nickel (Ni)1.37 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Selenium (Se)6.48 ug/L EPA 200.8 01/22/2016 01:29 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:29 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:29 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 35 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.181 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 19 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001997
Collection Date:20-Jan-16 3:20 PM
Site:PZ-17D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.490 mg-N/L EPA 353.2 01/25/2016 13:11 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.5 mg/L EPA 300.0 01/22/2016 03:39 BGN90340.5 5
Sulfate 150 mg/L EPA 300.0 01/22/2016 03:39 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:40 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:15 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.005 1
Boron (B)0.847 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.05 1
Iron (Fe)0.028 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.005 1
Strontium (Sr)0.284 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.005 1
Zinc (Zn)0.129 mg/L EPA 200.7 01/21/2016 11:34 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)56.9 mg/L EPA 200.7 01/25/2016 12:21 FCJORDA0.01 1
Magnesium (Mg)8.96 mg/L EPA 200.7 01/25/2016 12:21 FCJORDA0.005 1
Potassium (K)7.32 mg/L EPA 200.7 01/25/2016 12:21 FCJORDA0.1 1
Sodium (Na)10.1 mg/L EPA 200.7 01/25/2016 12:21 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.087 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.005 1
Boron (B)0.846 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.05 1
Iron (Fe)0.363 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.01 1
Manganese (Mn)0.031 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.005 1
Strontium (Sr)0.281 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.005 1
Zinc (Zn)0.131 mg/L EPA 200.7 01/21/2016 17:49 FCJORDA0.005 1
Page 20 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001997
Collection Date:20-Jan-16 3:20 PM
Site:PZ-17D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Nickel (Ni)6.92 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Selenium (Se)20.9 ug/L EPA 200.8 01/25/2016 19:30 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 19:30 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 19:30 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Chromium (Cr)47.5 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Cobalt (Co)1.19 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Copper (Cu)2.07 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Molybdenum (Mo)1.37 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Nickel (Ni)30.3 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Selenium (Se)20.3 ug/L EPA 200.8 01/22/2016 01:34 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:34 MHALL30.2 1
Vanadium (V) Low Level 0.427 ug/L EPA 200.8 01/22/2016 01:34 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 290 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.236 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 21 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001998
Collection Date:20-Jan-16 11:16 AM
Site:MW-3D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)16 mg-N/L EPA 353.2 01/25/2016 13:06 LSTARL10.2 20
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 10 mg/L EPA 300.0 01/22/2016 03:56 BGN90340.5 5
Sulfate 190 mg/L EPA 300.0 01/22/2016 03:56 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:43 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:18 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)1.40 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.005 1
Barium (Ba)0.053 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.005 1
Boron (B)0.637 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.05 1
Iron (Fe)1.28 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.01 1
Manganese (Mn)2.56 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.005 1
Strontium (Sr)0.569 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.005 1
Zinc (Zn)0.125 mg/L EPA 200.7 01/21/2016 11:38 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)40.4 mg/L EPA 200.7 01/25/2016 12:24 FCJORDA0.01 1
Magnesium (Mg)8.75 mg/L EPA 200.7 01/25/2016 12:24 FCJORDA0.005 1
Potassium (K)10.6 mg/L EPA 200.7 01/25/2016 12:24 FCJORDA0.1 1
Sodium (Na)17.6 mg/L EPA 200.7 01/25/2016 12:24 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.82 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.005 1
Barium (Ba)0.053 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.005 1
Boron (B)0.639 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.05 1
Iron (Fe)1.54 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.01 1
Manganese (Mn)2.62 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.005 1
Strontium (Sr)0.583 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.005 1
Zinc (Zn)0.139 mg/L EPA 200.7 01/21/2016 17:53 FCJORDA0.005 1
Page 22 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001998
Collection Date:20-Jan-16 11:16 AM
Site:MW-3D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Beryllium (Be)1.23 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Cobalt (Co)84.8 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Copper (Cu)36.0 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Nickel (Ni)47.1 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Selenium (Se)5.82 ug/L EPA 200.8 01/25/2016 20:29 MHALL311
Thallium (Tl) Low Level 0.617 ug/L EPA 200.8 01/25/2016 20:29 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:29 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Beryllium (Be)1.58 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Chromium (Cr)1.20 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Cobalt (Co)85.2 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Copper (Cu)40.0 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Nickel (Ni)47.3 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Selenium (Se)5.01 ug/L EPA 200.8 01/22/2016 01:39 MHALL311
Thallium (Tl) Low Level 0.802 ug/L EPA 200.8 01/22/2016 01:39 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:39 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.252 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 23 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001999
Collection Date:20-Jan-16 1:50 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.4 mg-N/L EPA 353.2 01/25/2016 13:18 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.8 mg/L EPA 300.0 01/25/2016 15:18 BGN90340.2 2
Sulfate 7.1 mg/L EPA 300.0 01/25/2016 15:18 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:45 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:20 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.005 1
Barium (Ba)0.052 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.05 1
Iron (Fe)0.014 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.01 1
Manganese (Mn)0.124 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.005 1
Strontium (Sr)0.022 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.005 1
Zinc (Zn)0.036 mg/L EPA 200.7 01/21/2016 11:50 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.43 mg/L EPA 200.7 01/25/2016 12:36 FCJORDA0.01 1
Magnesium (Mg)2.34 mg/L EPA 200.7 01/25/2016 12:36 FCJORDA0.005 1
Potassium (K)0.859 mg/L EPA 200.7 01/25/2016 12:36 FCJORDA0.1 1
Sodium (Na)3.79 mg/L EPA 200.7 01/25/2016 12:36 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.220 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.05 1
Iron (Fe)0.207 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.01 1
Manganese (Mn)0.123 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.005 1
Strontium (Sr)0.021 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 01/21/2016 18:08 FCJORDA0.005 1
Page 24 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016001999
Collection Date:20-Jan-16 1:50 PM
Site:MW-12D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Cobalt (Co)1.20 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Nickel (Ni)2.04 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 21:08 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:08 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:08 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Chromium (Cr)10.2 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Cobalt (Co)1.23 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Nickel (Ni)6.62 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 02:18 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:18 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:18 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 32 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.149 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 25 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002000
Collection Date:20-Jan-16 4:40 PM
Site:CB-08
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.6 mg-N/L EPA 353.2 01/25/2016 13:22 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 200 mg/L EPA 300.0 01/25/2016 12:30 BGN9034550
Sulfate 120 mg/L EPA 300.0 01/25/2016 12:30 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.10 ug/L EPA 245.1 01/26/2016 18:48 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:23 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.129 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.005 1
Barium (Ba)0.159 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.005 1
Boron (B)2.36 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.01 1
Manganese (Mn)1.22 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.005 1
Strontium (Sr)0.578 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.005 1
Zinc (Zn)0.016 mg/L EPA 200.7 01/21/2016 11:55 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)97.9 mg/L EPA 200.7 01/25/2016 12:39 FCJORDA0.1 10
Magnesium (Mg)35.6 mg/L EPA 200.7 01/25/2016 12:39 FCJORDA0.05 10
Potassium (K)2.31 mg/L EPA 200.7 01/25/2016 12:39 FCJORDA110
Sodium (Na)7.14 mg/L EPA 200.7 01/25/2016 12:39 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.148 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.005 1
Barium (Ba)0.161 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.005 1
Boron (B)2.30 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.05 1
Iron (Fe)0.016 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.01 1
Manganese (Mn)1.20 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.005 1
Strontium (Sr)0.567 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 01/21/2016 18:20 FCJORDA0.005 1
Page 26 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002000
Collection Date:20-Jan-16 4:40 PM
Site:CB-08
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Cobalt (Co)4.20 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Nickel (Ni)2.23 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Selenium (Se)16.5 ug/L EPA 200.8 01/25/2016 21:13 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:13 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:13 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Cobalt (Co)4.23 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Nickel (Ni)2.39 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Selenium (Se)15.4 ug/L EPA 200.8 01/22/2016 01:58 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 01:58 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 01:58 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 580 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.738 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 27 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002001
Collection Date:20-Jan-16 3:28 PM
Site:CB-08BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.014 mg-N/L EPA 353.2 01/25/2016 13:23N1 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 01/25/2016 13:37 BGN9034110
Sulfate 26 mg/L EPA 300.0 01/25/2016 13:37 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:50 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:25 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.005 1
Boron (B)0.091 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.05 1
Iron (Fe)0.590 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.01 1
Manganese (Mn)0.477 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.005 1
Strontium (Sr)0.153 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 11:59 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)37.0 mg/L EPA 200.7 01/25/2016 12:43 FCJORDA0.01 1
Magnesium (Mg)4.44 mg/L EPA 200.7 01/25/2016 12:43 FCJORDA0.005 1
Potassium (K)3.34 mg/L EPA 200.7 01/25/2016 12:43 FCJORDA0.1 1
Sodium (Na)7.45 mg/L EPA 200.7 01/25/2016 12:43 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.130 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.005 1
Boron (B)0.087 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.05 1
Iron (Fe)0.897 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.01 1
Manganese (Mn)0.452 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.005 1
Strontium (Sr)0.148 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/21/2016 18:24 FCJORDA0.005 1
Page 28 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002001
Collection Date:20-Jan-16 3:28 PM
Site:CB-08BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Molybdenum (Mo)1.42 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 21:18 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:18 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:18 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Molybdenum (Mo)1.33 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 02:23 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:23 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:23 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 180 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.167 mg/L SM5310C/EPA9060A 01/29/2016 12:21N1 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 29 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002002
Collection Date:20-Jan-16 12:33 PM
Site:MW-08S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.144 mg-N/L EPA 353.2 01/25/2016 13:25 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 420 mg/L EPA 300.0 01/25/2016 13:54 BGN903410100
Sulfate 260 mg/L EPA 300.0 01/25/2016 13:54 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:05 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:32 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.005 1
Barium (Ba)0.180 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.005 1
Boron (B)6.05 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.01 1
Manganese (Mn)2.82 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.005 1
Strontium (Sr)3.62 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 01/21/2016 12:03 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)231 mg/L EPA 200.7 01/25/2016 12:47 FCJORDA0.1 10
Magnesium (Mg)79.5 mg/L EPA 200.7 01/25/2016 12:47 FCJORDA0.05 10
Potassium (K)1.71 mg/L EPA 200.7 01/25/2016 12:47 FCJORDA110
Sodium (Na)14.3 mg/L EPA 200.7 01/25/2016 12:47 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.005 1
Barium (Ba)0.184 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.005 1
Boron (B)6.14 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.05 1
Iron (Fe)0.015 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.01 1
Manganese (Mn)2.92 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.005 1
Strontium (Sr)3.54 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.005 1
Zinc (Zn)0.032 mg/L EPA 200.7 01/21/2016 18:28 FCJORDA0.005 1
Page 30 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002002
Collection Date:20-Jan-16 12:33 PM
Site:MW-08S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Cobalt (Co)2.96 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Molybdenum (Mo)3.45 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Nickel (Ni)1.58 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Selenium (Se)1.05 ug/L EPA 200.8 01/25/2016 21:22 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:22 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:22 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Cobalt (Co)2.75 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Molybdenum (Mo)3.72 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Nickel (Ni)1.56 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Selenium (Se)1.13 ug/L EPA 200.8 01/22/2016 02:28 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:28 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:28 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.189 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 31 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002003
Collection Date:20-Jan-16 4:45 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:39 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 12:06 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 21:27 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:27 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:27 MHALL30.3 1
Page 32 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002004
Collection Date:20-Jan-16 4:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/25/2016 13:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/25/2016 14:10 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/25/2016 14:10 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:53 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 01/25/2016 12:51 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/25/2016 12:51 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/25/2016 12:51 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/25/2016 12:51 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 18:31 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 02:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:33 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:33 MHALL30.3 1
Page 33 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002004
Collection Date:20-Jan-16 4:45 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 34 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002005
Collection Date:20-Jan-16 11:03 AM
Site:MW-09S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.749 mg-N/L EPA 353.2 01/25/2016 13:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 530 mg/L EPA 300.0 01/25/2016 14:27 BGN903410100
Sulfate 290 mg/L EPA 300.0 01/25/2016 14:27 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.09 ug/L EPA 245.1 01/26/2016 19:12 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:42 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.005 1
Barium (Ba)0.148 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.005 1
Boron (B)5.57 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.05 1
Iron (Fe)0.068 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.01 1
Manganese (Mn)3.45 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.005 1
Strontium (Sr)2.62 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.005 1
Zinc (Zn)0.013 mg/L EPA 200.7 01/21/2016 12:10 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)250 mg/L EPA 200.7 01/25/2016 12:55 FCJORDA0.1 10
Magnesium (Mg)84.0 mg/L EPA 200.7 01/25/2016 12:55 FCJORDA0.05 10
Potassium (K)3.66 mg/L EPA 200.7 01/25/2016 12:55 FCJORDA110
Sodium (Na)17.0 mg/L EPA 200.7 01/25/2016 12:55 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.040 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.005 1
Barium (Ba)0.147 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.005 1
Boron (B)5.56 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.05 1
Iron (Fe)0.078 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.01 1
Manganese (Mn)3.41 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.005 1
Strontium (Sr)2.60 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 01/21/2016 18:35 FCJORDA0.005 1
Page 35 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002005
Collection Date:20-Jan-16 11:03 AM
Site:MW-09S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Chromium (Cr)13.1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Cobalt (Co)3.95 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Nickel (Ni)10.8 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Selenium (Se)35.4 ug/L EPA 200.8 01/25/2016 20:48 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 20:48M2 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 20:48 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Chromium (Cr)16.1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Cobalt (Co)3.64 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Nickel (Ni)9.71 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Selenium (Se)34.0 ug/L EPA 200.8 01/22/2016 02:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:37 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:37 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 1500 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.273 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 36 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002006
Collection Date:20-Jan-16 9:45 AM
Site:MW-09D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.417 mg-N/L EPA 353.2 01/25/2016 13:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 510 mg/L EPA 300.0 01/25/2016 14:44 BGN903410100
Sulfate 280 mg/L EPA 300.0 01/25/2016 14:44 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:14 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:44 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.005 1
Barium (Ba)0.146 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.005 1
Boron (B)5.19 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.05 1
Iron (Fe)17.1 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.01 1
Manganese (Mn)3.90 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.005 1
Strontium (Sr)1.74 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 12:14 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)235 mg/L EPA 200.7 01/25/2016 12:58 FCJORDA0.1 10
Magnesium (Mg)82.3 mg/L EPA 200.7 01/25/2016 12:58 FCJORDA0.05 10
Potassium (K)4.91 mg/L EPA 200.7 01/25/2016 12:58 FCJORDA110
Sodium (Na)30.0 mg/L EPA 200.7 01/25/2016 12:58 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.005 1
Barium (Ba)0.127 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.005 1
Boron (B)5.54 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.05 1
Iron (Fe)0.278 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.01 1
Manganese (Mn)3.66 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.005 1
Strontium (Sr)1.74 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 01/21/2016 18:39 FCJORDA0.005 1
Page 37 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002006
Collection Date:20-Jan-16 9:45 AM
Site:MW-09D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Cobalt (Co)1.12 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Nickel (Ni)1.06 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 21:32 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:32 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:32 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Cobalt (Co)7.06 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Nickel (Ni)4.46 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Selenium (Se)20.7 ug/L EPA 200.8 01/22/2016 02:42 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:42 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:42 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 1400 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.231 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 38 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002007
Collection Date:20-Jan-16 9:20 AM
Site:MW-09BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.018 mg-N/L EPA 353.2 01/25/2016 13:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 300 mg/L EPA 300.0 01/26/2016 15:31 BGN9034550
Sulfate 120 mg/L EPA 300.0 01/26/2016 15:31 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 19:17 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 16:47 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.005 1
Barium (Ba)0.116 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.005 1
Boron (B)1.20 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.05 1
Iron (Fe)9.70 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.01 1
Manganese (Mn)0.649 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.005 1
Strontium (Sr)1.14 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 01/21/2016 12:18 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)167 mg/L EPA 200.7 01/25/2016 13:02 FCJORDA0.1 10
Magnesium (Mg)31.4 mg/L EPA 200.7 01/25/2016 13:02 FCJORDA0.05 10
Potassium (K)19.3 mg/L EPA 200.7 01/25/2016 13:02 FCJORDA110
Sodium (Na)30.9 mg/L EPA 200.7 01/25/2016 13:02 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.069 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.005 1
Barium (Ba)0.116 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.005 1
Boron (B)1.16 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.05 1
Iron (Fe)7.74 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.01 1
Manganese (Mn)0.631 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.005 1
Strontium (Sr)1.10 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 01/21/2016 18:43 FCJORDA0.005 1
Page 39 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
2016002007
Collection Date:20-Jan-16 9:20 AM
Site:MW-09BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Molybdenum (Mo)4.09 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/25/2016 21:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/25/2016 21:37 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/25/2016 21:37 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Molybdenum (Mo)4.79 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Nickel (Ni)1.42 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 02:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 02:47 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 02:47 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 890 mg/L SM2540C 01/25/2016 15:00 CJELLIO251
Total Carbon
TOC 0.568 mg/L SM5310C/EPA9060A 01/29/2016 12:21 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 20 mg/L SM2540D 01/25/2016 09:41 CJELLIO51
Page 40 of 81
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010397
N1--The TOC and NO2NO3 samples for CB-08BR were received unpreserved and do not meet preservation
requirements per 40 CFR 136 (ph<2). Acid was added to the samples and the data has been flagged. If this data is
to be reported on a DMR, the data must be flagged with an explanation.
-- Additional Information --
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.
N1 See additional information listed below.
Page 41 of 81
#=CL#
January 27, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92283899
92283899
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010397
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 21, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bishop for
[e-mail]
HORIZON Database Administrator
Kevin Herring
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 39
Page 42 of 81
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92283899
J16010397
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 39
Page 43 of 81
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92283899
J16010397
Lab ID Sample ID Matrix Date Collected Date Received
92283899001 2016001989 Water 01/20/16 09:34 01/21/16 13:00
92283899002 2016001990 Water 01/20/16 09:34 01/21/16 13:00
92283899003 2016001991 Water 01/20/16 10:49 01/21/16 13:00
92283899004 2016001992 Water 01/20/16 13:28 01/21/16 13:00
92283899005 2016001993 Water 01/20/16 14:16 01/21/16 13:00
92283899006 2016001994 Water 01/20/16 16:05 01/21/16 13:00
92283899007 2016001995 Water 01/20/16 15:52 01/21/16 13:00
92283899008 2016001996 Water 01/20/16 11:22 01/21/16 13:00
92283899009 2016001997 Water 01/20/16 15:20 01/21/16 13:00
92283899010 2016001998 Water 01/20/16 11:16 01/21/16 13:00
92283899011 2016001999 Water 01/20/16 13:50 01/21/16 13:00
92283899012 2016002000 Water 01/20/16 16:40 01/21/16 13:00
92283899013 2016002001 Water 01/20/16 15:28 01/21/16 13:00
92283899014 2016002002 Water 01/20/16 12:33 01/21/16 13:00
92283899015 2016002004 Water 01/20/16 16:45 01/21/16 13:00
92283899016 2016002005 Water 01/20/16 11:03 01/21/16 13:00
92283899017 2016002006 Water 01/20/16 09:45 01/21/16 13:00
92283899018 2016002007 Water 01/20/16 09:20 01/21/16 13:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 39
Page 44 of 81
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283899
J16010397
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92283899001 2016001989 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899002 2016001990 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899003 2016001991 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899004 2016001992 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899005 2016001993 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899006 2016001994 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899007 2016001995 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899008 2016001996 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899009 2016001997 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899010 2016001998 RSK 175 1 PASI-MSTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 39
Page 45 of 81
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283899
J16010397
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899011 2016001999 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899012 2016002000 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899013 2016002001 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899014 2016002002 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899015 2016002004 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899016 2016002005 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899017 2016002006 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283899018 2016002007 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 39
Page 46 of 81
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283899
J16010397
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283899001 2016001989
Methane 20.6 ug/L 01/22/16 12:5510.0RSK 175
Alkalinity,Bicarbonate (CaCO3)52.2 mg/L 01/25/16 15:475.0SM 2320B
Alkalinity, Total as CaCO3 52.2 mg/L 01/25/16 15:475.0SM 2320B
92283899002 2016001990
Methane 21.3 ug/L 01/22/16 13:0310.0RSK 175
Alkalinity,Bicarbonate (CaCO3)52.8 mg/L 01/25/16 16:205.0SM 2320B
Alkalinity, Total as CaCO3 52.8 mg/L 01/25/16 16:205.0SM 2320B
92283899003 2016001991
Alkalinity,Bicarbonate (CaCO3)31.8 mg/L 01/25/16 16:315.0SM 2320B
Alkalinity, Total as CaCO3 31.8 mg/L 01/25/16 16:315.0SM 2320B
Chromium, Hexavalent 0.18 ug/L 01/25/16 13:260.030EPA 218.7
92283899005 2016001993
Alkalinity,Bicarbonate (CaCO3)7.8 mg/L 01/25/16 16:515.0SM 2320B
Alkalinity, Total as CaCO3 7.8 mg/L 01/25/16 16:515.0SM 2320B
92283899006 2016001994
Methane 102 ug/L 01/22/16 13:3610.0RSK 175
Alkalinity,Bicarbonate (CaCO3)58.0 mg/L 01/25/16 17:025.0SM 2320B
Alkalinity, Total as CaCO3 58.0 mg/L 01/25/16 17:025.0SM 2320B
92283899007 2016001995
Alkalinity,Bicarbonate (CaCO3)9.0 mg/L 01/25/16 17:335.0SM 2320B
Alkalinity, Total as CaCO3 9.0 mg/L 01/25/16 17:335.0SM 2320B
Chromium, Hexavalent 0.25 ug/L 01/25/16 14:180.030EPA 218.7
92283899008 2016001996
Chromium, Hexavalent 0.12 ug/L 01/25/16 14:310.030EPA 218.7
92283899009 2016001997
Alkalinity,Bicarbonate (CaCO3)62.1 mg/L 01/25/16 17:535.0SM 2320B
Alkalinity, Total as CaCO3 62.1 mg/L 01/25/16 17:535.0SM 2320B
Chromium, Hexavalent 0.12 ug/L 01/25/16 14:440.030EPA 218.7
92283899011 2016001999
Chromium, Hexavalent 0.076 ug/L 01/25/16 15:36 M10.030EPA 218.7
92283899012 2016002000
Alkalinity,Bicarbonate (CaCO3)12.9 mg/L 01/25/16 18:425.0SM 2320B
Alkalinity, Total as CaCO3 12.9 mg/L 01/25/16 18:425.0SM 2320B
Chromium, Hexavalent 0.27 ug/L 01/25/16 16:150.030EPA 218.7
92283899013 2016002001
Alkalinity,Bicarbonate (CaCO3)91.0 mg/L 01/25/16 18:535.0SM 2320B
Alkalinity, Total as CaCO3 91.0 mg/L 01/25/16 18:535.0SM 2320B
92283899014 2016002002
Alkalinity,Bicarbonate (CaCO3)81.0 mg/L 01/25/16 19:065.0SM 2320B
Alkalinity, Total as CaCO3 81.0 mg/L 01/25/16 19:065.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 39
Page 47 of 81
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283899
J16010397
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283899016 2016002005
Alkalinity,Bicarbonate (CaCO3)39.4 mg/L 01/25/16 19:465.0SM 2320B
Alkalinity, Total as CaCO3 39.4 mg/L 01/25/16 19:465.0SM 2320B
Chromium, Hexavalent 0.50 ug/L 01/26/16 09:100.15EPA 218.7
92283899017 2016002006
Alkalinity,Bicarbonate (CaCO3)36.8 mg/L 01/25/16 19:585.0SM 2320B
Alkalinity, Total as CaCO3 36.8 mg/L 01/25/16 19:585.0SM 2320B
92283899018 2016002007
Alkalinity,Bicarbonate (CaCO3)109 mg/L 01/25/16 20:105.0SM 2320B
Alkalinity, Total as CaCO3 109 mg/L 01/25/16 20:105.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 7 of 39
Page 48 of 81
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283899
J16010397
Method:
Client:Duke Energy
RSK 175
Date:January 27, 2016
Description:RSK 175 AIR Headspace
General Information:
18 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 8 of 39
Page 49 of 81
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283899
J16010397
Method:
Client:Duke Energy
SM 2320B
Date:January 27, 2016
Description:2320B Alkalinity
General Information:
18 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 9 of 39
Page 50 of 81
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283899
J16010397
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 27, 2016
Description:4500S2D Sulfide Water
General Information:
18 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42660
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283899001,92283899011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1652670)
• Sulfide
• MSD (Lab ID: 1652671)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 10 of 39
Page 51 of 81
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283899
J16010397
Method:
Client:Duke Energy
EPA 218.7
Date:January 27, 2016
Description:Hexavalent Chromium by IC
General Information:
18 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/54232
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92283899001,92283899011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1458496)
• Chromium, Hexavalent
• MSD (Lab ID: 1458497)
• Chromium, Hexavalent
• MSD (Lab ID: 1458499)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 39
Page 52 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001989 Lab ID:92283899001 Collected:01/20/16 09:34 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 20.6 ug/L 01/22/16 12:55 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)52.2 mg/L 01/25/16 15:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 15:475.0 1
Alkalinity, Total as CaCO3 52.2 mg/L 01/25/16 15:475.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 12:34 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 39
Page 53 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001990 Lab ID:92283899002 Collected:01/20/16 09:34 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 21.3 ug/L 01/22/16 13:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)52.8 mg/L 01/25/16 16:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 16:205.0 1
Alkalinity, Total as CaCO3 52.8 mg/L 01/25/16 16:205.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 13:13 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 39
Page 54 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001991 Lab ID:92283899003 Collected:01/20/16 10:49 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 13:12 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)31.8 mg/L 01/25/16 16:315.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 16:315.0 1
Alkalinity, Total as CaCO3 31.8 mg/L 01/25/16 16:315.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.18 ug/L 01/25/16 13:26 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 39
Page 55 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001992 Lab ID:92283899004 Collected:01/20/16 13:28 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 13:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/25/16 16:435.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 16:435.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/25/16 16:435.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 13:39 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 39
Page 56 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001993 Lab ID:92283899005 Collected:01/20/16 14:16 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 13:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.8 mg/L 01/25/16 16:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 16:515.0 1
Alkalinity, Total as CaCO3 7.8 mg/L 01/25/16 16:515.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 13:52 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 39
Page 57 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001994 Lab ID:92283899006 Collected:01/20/16 16:05 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 102 ug/L 01/22/16 13:36 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)58.0 mg/L 01/25/16 17:025.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 17:025.0 1
Alkalinity, Total as CaCO3 58.0 mg/L 01/25/16 17:025.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 14:05 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 39
Page 58 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001995 Lab ID:92283899007 Collected:01/20/16 15:52 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 14:05 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)9.0 mg/L 01/25/16 17:335.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 17:335.0 1
Alkalinity, Total as CaCO3 9.0 mg/L 01/25/16 17:335.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.25 ug/L 01/25/16 14:18 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
Page 18 of 39
Page 59 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001996 Lab ID:92283899008 Collected:01/20/16 11:22 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 14:21 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/25/16 17:445.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 17:445.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/25/16 17:445.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.12 ug/L 01/25/16 14:31 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 39
Page 60 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001997 Lab ID:92283899009 Collected:01/20/16 15:20 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 14:29 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)62.1 mg/L 01/25/16 17:535.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 17:535.0 1
Alkalinity, Total as CaCO3 62.1 mg/L 01/25/16 17:535.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.12 ug/L 01/25/16 14:44 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 39
Page 61 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001998 Lab ID:92283899010 Collected:01/20/16 11:16 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 14:37 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/25/16 18:055.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 18:055.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/25/16 18:055.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 14:57 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 39
Page 62 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016001999 Lab ID:92283899011 Collected:01/20/16 13:50 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 14:45 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/25/16 18:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 18:125.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/25/16 18:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-8 M10.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.076 ug/L 01/25/16 15:36 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 39
Page 63 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002000 Lab ID:92283899012 Collected:01/20/16 16:40 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 14:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)12.9 mg/L 01/25/16 18:425.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 18:425.0 1
Alkalinity, Total as CaCO3 12.9 mg/L 01/25/16 18:425.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.27 ug/L 01/25/16 16:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 39
Page 64 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002001 Lab ID:92283899013 Collected:01/20/16 15:28 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 15:02 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)91.0 mg/L 01/25/16 18:535.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 18:535.0 1
Alkalinity, Total as CaCO3 91.0 mg/L 01/25/16 18:535.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 16:28 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 39
Page 65 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002002 Lab ID:92283899014 Collected:01/20/16 12:33 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 15:10 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)81.0 mg/L 01/25/16 19:065.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 19:065.0 1
Alkalinity, Total as CaCO3 81.0 mg/L 01/25/16 19:065.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 16:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 39
Page 66 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002004 Lab ID:92283899015 Collected:01/20/16 16:45 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 15:18 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/25/16 19:385.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 19:385.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/25/16 19:385.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 16:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 39
Page 67 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002005 Lab ID:92283899016 Collected:01/20/16 11:03 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 15:56 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)39.4 mg/L 01/25/16 19:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 19:465.0 1
Alkalinity, Total as CaCO3 39.4 mg/L 01/25/16 19:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.50 ug/L 01/26/16 09:10 18540-29-90.15 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 39
Page 68 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002006 Lab ID:92283899017 Collected:01/20/16 09:45 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 16:05 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)36.8 mg/L 01/25/16 19:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 19:585.0 1
Alkalinity, Total as CaCO3 36.8 mg/L 01/25/16 19:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 17:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 39
Page 69 of 81
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283899
J16010397
Sample:2016002007 Lab ID:92283899018 Collected:01/20/16 09:20 Received:01/21/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/22/16 16:13 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)109 mg/L 01/25/16 20:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/25/16 20:105.0 1
Alkalinity, Total as CaCO3 109 mg/L 01/25/16 20:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/26/16 12:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/25/16 17:33 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 39
Page 70 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283899
J16010397
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25074
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2179438
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/22/16 12:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2179439LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2179440
Methane ug/L 60.960.7 100 85-1159154.9 10 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283758001
2179569SAMPLE DUPLICATE:
Methane ug/L 1.3J 201.5J
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283899007
2179570SAMPLE DUPLICATE:
Methane ug/L 2.7J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 39
Page 71 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283899
J16010397
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25075
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283899016, 92283899017, 92283899018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2179443
Associated Lab Samples:92283899016, 92283899017, 92283899018
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/22/16 15:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2179444LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2179445
Methane ug/L 54.960.7 91 85-1159960.0 9 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283899016
2180110SAMPLE DUPLICATE:
Methane ug/L 1.1J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 39
Page 72 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283899
J16010397
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42657
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015, 92283899016, 92283899017, 92283899018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1652541
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015, 92283899016, 92283899017, 92283899018
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/25/16 15:25
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/25/16 15:25
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/25/16 15:25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1652542LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.150 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1652543MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283899001
1652544
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-12095 3 255052.2 102 99.5
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1652545MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283899011
1652546
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND53.0 53.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 39
Page 73 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283899
J16010397
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42660
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015, 92283899016, 92283899017, 92283899018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1652666
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015, 92283899016, 92283899017, 92283899018
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/26/16 12:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1652667LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1652668MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283899001
1652669
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 108 90-110108 0 10.5ND 0.54 0.54
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1652670MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283899011
1652671
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 87 90-11087 0 10.5ND 0.43 0.43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 39
Page 74 of 81
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283899
J16010397
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/54232
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015, 92283899016, 92283899017, 92283899018
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1458494
Associated Lab Samples:92283899001, 92283899002, 92283899003, 92283899004, 92283899005, 92283899006, 92283899007,
92283899008, 92283899009, 92283899010, 92283899011, 92283899012, 92283899013, 92283899014,
92283899015, 92283899016, 92283899017, 92283899018
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/25/16 11:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1458495LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 98 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1458496MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283899001
1458497
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 139 85-115125 11 20.025ND 0.035 0.031
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1458498MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283899011
1458499
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 88 85-11583 2 20.0750.076 0.14 0.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 39
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92283899
J16010397
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 39
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283899
J16010397
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283899001 AIR/250742016001989RSK 175
92283899002 AIR/250742016001990RSK 175
92283899003 AIR/250742016001991RSK 175
92283899004 AIR/250742016001992RSK 175
92283899005 AIR/250742016001993RSK 175
92283899006 AIR/250742016001994RSK 175
92283899007 AIR/250742016001995RSK 175
92283899008 AIR/250742016001996RSK 175
92283899009 AIR/250742016001997RSK 175
92283899010 AIR/250742016001998RSK 175
92283899011 AIR/250742016001999RSK 175
92283899012 AIR/250742016002000RSK 175
92283899013 AIR/250742016002001RSK 175
92283899014 AIR/250742016002002RSK 175
92283899015 AIR/250742016002004RSK 175
92283899016 AIR/250752016002005RSK 175
92283899017 AIR/250752016002006RSK 175
92283899018 AIR/250752016002007RSK 175
92283899001 WET/426572016001989SM 2320B
92283899002 WET/426572016001990SM 2320B
92283899003 WET/426572016001991SM 2320B
92283899004 WET/426572016001992SM 2320B
92283899005 WET/426572016001993SM 2320B
92283899006 WET/426572016001994SM 2320B
92283899007 WET/426572016001995SM 2320B
92283899008 WET/426572016001996SM 2320B
92283899009 WET/426572016001997SM 2320B
92283899010 WET/426572016001998SM 2320B
92283899011 WET/426572016001999SM 2320B
92283899012 WET/426572016002000SM 2320B
92283899013 WET/426572016002001SM 2320B
92283899014 WET/426572016002002SM 2320B
92283899015 WET/426572016002004SM 2320B
92283899016 WET/426572016002005SM 2320B
92283899017 WET/426572016002006SM 2320B
92283899018 WET/426572016002007SM 2320B
92283899001 WET/426602016001989SM 4500-S2D
92283899002 WET/426602016001990SM 4500-S2D
92283899003 WET/426602016001991SM 4500-S2D
92283899004 WET/426602016001992SM 4500-S2D
92283899005 WET/426602016001993SM 4500-S2D
92283899006 WET/426602016001994SM 4500-S2D
92283899007 WET/426602016001995SM 4500-S2D
92283899008 WET/426602016001996SM 4500-S2D
92283899009 WET/426602016001997SM 4500-S2D
92283899010 WET/426602016001998SM 4500-S2D
92283899011 WET/426602016001999SM 4500-S2D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 39
Page 77 of 81
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283899
J16010397
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283899012 WET/426602016002000SM 4500-S2D
92283899013 WET/426602016002001SM 4500-S2D
92283899014 WET/426602016002002SM 4500-S2D
92283899015 WET/426602016002004SM 4500-S2D
92283899016 WET/426602016002005SM 4500-S2D
92283899017 WET/426602016002006SM 4500-S2D
92283899018 WET/426602016002007SM 4500-S2D
92283899001 WETA/542322016001989EPA 218.7
92283899002 WETA/542322016001990EPA 218.7
92283899003 WETA/542322016001991EPA 218.7
92283899004 WETA/542322016001992EPA 218.7
92283899005 WETA/542322016001993EPA 218.7
92283899006 WETA/542322016001994EPA 218.7
92283899007 WETA/542322016001995EPA 218.7
92283899008 WETA/542322016001996EPA 218.7
92283899009 WETA/542322016001997EPA 218.7
92283899010 WETA/542322016001998EPA 218.7
92283899011 WETA/542322016001999EPA 218.7
92283899012 WETA/542322016002000EPA 218.7
92283899013 WETA/542322016002001EPA 218.7
92283899014 WETA/542322016002002EPA 218.7
92283899015 WETA/542322016002004EPA 218.7
92283899016 WETA/542322016002005EPA 218.7
92283899017 WETA/542322016002006EPA 218.7
92283899018 WETA/542322016002007EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/27/2016 01:24 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 39
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