NC0000396_App B Lab Reports - CSA RND 4 Sampling - J16010376-F_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010376
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:2/5/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 75
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016001905 ASHEVILLE 19-Jan-16 3:55 PM illegible MW-10
2016001907 ASHEVILLE 19-Jan-16 2:44 PM illegible AMW-2A
2016001908 ASHEVILLE 19-Jan-16 1:27 PM illegible MW-24S
2016001909 ASHEVILLE 19-Jan-16 10:58 AM illegible MW-23DL
2016001910 ASHEVILLE 19-Jan-16 10:35 AM illegible MW-23DU
2016001911 ASHEVILLE 19-Jan-16 3:12 PM illegible CB-4
2016001912 ASHEVILLE 19-Jan-16 3:45 PM illegible CB-4B
2016001913 ASHEVILLE 19-Jan-16 11:14 AM illegible MW-05D
2016001914 ASHEVILLE 19-Jan-16 11:58 AM illegible MW-05BR
2016001915 ASHEVILLE 19-Jan-16 4:28 PM illegible MW-18D
2016001916 ASHEVILLE 19-Jan-16 3:20 PM illegible MW-18BR
2016001917 ASHEVILLE 19-Jan-16 12:08 PM illegible MW-17A
2016001918 ASHEVILLE 19-Jan-16 10:20 AM illegible MW-16BR
2016001919 ASHEVILLE 19-Jan-16 4:15 PM illegible FILTER BLANK
2016001920 ASHEVILLE 19-Jan-16 4:15 PM illegible EQUIPMENT BLANK
2016001921 ASHEVILLE 19-Jan-16 10:35 AM illegible MW-23DU DUP
2016001922 ASHEVILLE 19-Jan-16 2:23 PM illegible CB-07
17 Total Samples
Page 2 of 75
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/5/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001905
Collection Date:19-Jan-16 3:55 PM
Site: MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.099 mg-N/L EPA 353.2 01/21/2016 11:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 01/21/2016 11:37 BGN90340.5 5
Sulfate 0.29 mg/L EPA 300.0 01/21/2016 11:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.10 ug/L EPA 245.1 01/26/2016 17:13 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:41 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.038 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.05 1
Iron (Fe)0.056 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.01 1
Manganese (Mn)0.196 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.005 1
Strontium (Sr)0.026 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.005 1
Zinc (Zn)0.022 mg/L EPA 200.7 01/20/2016 13:08 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.32 mg/L EPA 200.7 01/20/2016 16:46 FCJORDA0.01 1
Magnesium (Mg)2.80 mg/L EPA 200.7 01/20/2016 16:46 FCJORDA0.005 1
Potassium (K)1.35 mg/L EPA 200.7 01/20/2016 16:46 FCJORDA0.1 1
Sodium (Na)4.85 mg/L EPA 200.7 01/20/2016 16:46 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.044 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.005 1
Barium (Ba)0.054 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.05 1
Iron (Fe)0.063 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.01 1
Manganese (Mn)0.185 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.005 1
Strontium (Sr)0.025 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 01/21/2016 12:37 FCJORDA0.005 1
Page 4 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001905
Collection Date:19-Jan-16 3:55 PM
Site: MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Cobalt (Co)3.03 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Nickel (Ni)3.08 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:28 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:28 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:28 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Cobalt (Co)2.99 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Nickel (Ni)2.78 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:13 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:13 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:13 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 40 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.625 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 5 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001907
Collection Date:19-Jan-16 2:44 PM
Site: AMW-2A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.018 mg-N/L EPA 353.2 01/21/2016 11:28 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.7 mg/L EPA 300.0 01/21/2016 11:54 BGN9034110
Sulfate 51 mg/L EPA 300.0 01/21/2016 11:54 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:20 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:43 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.040 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.005 1
Barium (Ba)0.047 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.005 1
Boron (B)0.121 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.05 1
Iron (Fe)23.6 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.01 1
Manganese (Mn)2.84 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.005 1
Strontium (Sr)0.161 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:24 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.9 mg/L EPA 200.7 01/20/2016 16:50 FCJORDA0.01 1
Magnesium (Mg)5.17 mg/L EPA 200.7 01/20/2016 16:50 FCJORDA0.005 1
Potassium (K)3.17 mg/L EPA 200.7 01/20/2016 16:50 FCJORDA0.1 1
Sodium (Na)9.34 mg/L EPA 200.7 01/20/2016 16:50 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.049 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.005 1
Barium (Ba)0.055 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.005 1
Boron (B)0.132 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.05 1
Iron (Fe)25.7 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.01 1
Manganese (Mn)3.11 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.005 1
Strontium (Sr)0.174 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 12:48 FCJORDA0.005 1
Page 6 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001907
Collection Date:19-Jan-16 2:44 PM
Site: AMW-2A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Cobalt (Co)21.3 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Nickel (Ni)2.46 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:33 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:33 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Cobalt (Co)20.5 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Nickel (Ni)2.21 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 14:32 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 14:32 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 14:32 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 2.1 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 7 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001908
Collection Date:19-Jan-16 1:27 PM
Site: MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.1 mg-N/L EPA 353.2 01/21/2016 11:29 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 01/25/2016 10:31 BGN9034110
Sulfate 0.66 mg/L EPA 300.0 01/25/2016 10:31 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:23 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:46 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.005 1
Barium (Ba)0.051 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.01 1
Manganese (Mn)0.146 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.005 1
Strontium (Sr)0.037 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:35 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.03 mg/L EPA 200.7 01/20/2016 16:54 FCJORDA0.01 1
Magnesium (Mg)3.65 mg/L EPA 200.7 01/20/2016 16:54 FCJORDA0.005 1
Potassium (K)1.49 mg/L EPA 200.7 01/20/2016 16:54 FCJORDA0.1 1
Sodium (Na)3.31 mg/L EPA 200.7 01/20/2016 16:54 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.038 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.005 1
Barium (Ba)0.056 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.01 1
Manganese (Mn)0.150 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.005 1
Strontium (Sr)0.037 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 12:52 FCJORDA0.005 1
Page 8 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001908
Collection Date:19-Jan-16 1:27 PM
Site: MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:38 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:38 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:38 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Cobalt (Co)1.06 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Nickel (Ni)1.02 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:03 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:03 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:03 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 36 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.193 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 9 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001909
Collection Date:19-Jan-16 10:58 AM
Site: MW-23DL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.020 mg-N/L EPA 353.2 01/21/2016 11:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.0 mg/L EPA 300.0 01/21/2016 14:42 BGN90340.1 1
Sulfate 22 mg/L EPA 300.0 01/21/2016 14:42 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:25 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:48 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.026 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.005 1
Barium (Ba)0.014 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.05 1
Iron (Fe)10.7 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.01 1
Manganese (Mn)0.082 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.005 1
Strontium (Sr)0.114 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:39 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)34.5 mg/L EPA 200.7 01/20/2016 16:58 FCJORDA0.01 1
Magnesium (Mg)4.17 mg/L EPA 200.7 01/20/2016 16:58 FCJORDA0.005 1
Potassium (K)3.19 mg/L EPA 200.7 01/20/2016 16:58 FCJORDA0.1 1
Sodium (Na)6.85 mg/L EPA 200.7 01/20/2016 16:58 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.026 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.005 1
Barium (Ba)0.014 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.05 1
Iron (Fe)11.6 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.01 1
Manganese (Mn)0.087 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.005 1
Strontium (Sr)0.119 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 12:56 FCJORDA0.005 1
Page 10 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001909
Collection Date:19-Jan-16 10:58 AM
Site: MW-23DL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Nickel (Ni)10.7 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:43 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:43 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:43 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:08 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:08 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:08 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.179 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 22 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 11 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001910
Collection Date:19-Jan-16 10:35 AM
Site: MW-23DU
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.454 mg-N/L EPA 353.2 01/21/2016 11:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.0 mg/L EPA 300.0 01/21/2016 14:59 BGN90340.1 1
Sulfate 20 mg/L EPA 300.0 01/21/2016 14:59 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:28 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:50 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.005 1
Barium (Ba)0.034 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.005 1
Boron (B)0.080 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.01 1
Manganese (Mn)0.265 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.005 1
Strontium (Sr)0.037 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:43 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.25 mg/L EPA 200.7 01/20/2016 17:02 FCJORDA0.01 1
Magnesium (Mg)3.20 mg/L EPA 200.7 01/20/2016 17:02 FCJORDA0.005 1
Potassium (K)1.48 mg/L EPA 200.7 01/20/2016 17:02 FCJORDA0.1 1
Sodium (Na)8.62 mg/L EPA 200.7 01/20/2016 17:02 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.005 1
Boron (B)0.084 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.05 1
Iron (Fe)0.478 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.01 1
Manganese (Mn)0.301 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.005 1
Strontium (Sr)0.038 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:00 FCJORDA0.005 1
Page 12 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001910
Collection Date:19-Jan-16 10:35 AM
Site: MW-23DU
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Cobalt (Co)4.20 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Nickel (Ni)3.49 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:48 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:48 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:48 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Cobalt (Co)4.57 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Nickel (Ni)1.17 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:18 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:18 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:18 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 67 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.162 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 13 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001911
Collection Date:19-Jan-16 3:12 PM
Site: CB-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.290 mg-N/L EPA 353.2 01/21/2016 11:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 2.2 mg/L EPA 300.0 01/21/2016 15:16 BGN90340.2 2
Sulfate 100 mg/L EPA 300.0 01/21/2016 15:16 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:30 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:53 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.005 1
Barium (Ba)0.052 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.005 1
Boron (B)0.378 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.05 1
Iron (Fe)0.050 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.01 1
Manganese (Mn)0.393 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.005 1
Strontium (Sr)0.134 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:47 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.8 mg/L EPA 200.7 01/20/2016 17:13 FCJORDA0.01 1
Magnesium (Mg)3.72 mg/L EPA 200.7 01/20/2016 17:13 FCJORDA0.005 1
Potassium (K)2.22 mg/L EPA 200.7 01/20/2016 17:13 FCJORDA0.1 1
Sodium (Na)14.9 mg/L EPA 200.7 01/20/2016 17:13 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.029 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.005 1
Barium (Ba)0.054 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.005 1
Boron (B)0.378 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.05 1
Iron (Fe)0.010 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.01 1
Manganese (Mn)0.382 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.005 1
Strontium (Sr)0.136 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:03 FCJORDA0.005 1
Page 14 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001911
Collection Date:19-Jan-16 3:12 PM
Site: CB-4
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Cobalt (Co)1.07 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Selenium (Se)7.31 ug/L EPA 200.8 01/21/2016 22:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:53 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:53 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Cobalt (Co)1.05 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Selenium (Se)7.36 ug/L EPA 200.8 01/21/2016 15:22 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:22 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:22 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 120 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.129 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 15 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001912
Collection Date:19-Jan-16 3:45 PM
Site: CB-4B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/21/2016 11:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.6 mg/L EPA 300.0 01/21/2016 15:32 BGN90340.2 2
Sulfate 69 mg/L EPA 300.0 01/21/2016 15:32 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:32 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:55 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.05 1
Iron (Fe)0.369 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.01 1
Manganese (Mn)0.065 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.005 1
Strontium (Sr)0.130 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:51 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)22.0 mg/L EPA 200.7 01/20/2016 17:17 FCJORDA0.01 1
Magnesium (Mg)3.50 mg/L EPA 200.7 01/20/2016 17:17 FCJORDA0.005 1
Potassium (K)5.94 mg/L EPA 200.7 01/20/2016 17:17 FCJORDA0.1 1
Sodium (Na)18.2 mg/L EPA 200.7 01/20/2016 17:17 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.005 1
Barium (Ba)0.013 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.05 1
Iron (Fe)1.24 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.01 1
Manganese (Mn)0.067 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.005 1
Strontium (Sr)0.129 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:07 FCJORDA0.005 1
Page 16 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001912
Collection Date:19-Jan-16 3:45 PM
Site: CB-4B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Molybdenum (Mo)4.15 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:57 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:57 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:57 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Molybdenum (Mo)6.60 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:27 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:27 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:27 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.520 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 17 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001913
Collection Date:19-Jan-16 11:14 AM
Site: MW-05D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.933 mg-N/L EPA 353.2 01/21/2016 11:41M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.6 mg/L EPA 300.0 01/21/2016 15:49 BGN90340.5 5
Sulfate 190 mg/L EPA 300.0 01/21/2016 15:49 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:35 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:58 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.643 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.005 1
Boron (B)0.600 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.05 1
Iron (Fe)2.36 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.01 1
Manganese (Mn)0.469 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.005 1
Strontium (Sr)0.296 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.005 1
Zinc (Zn)0.030 mg/L EPA 200.7 01/20/2016 13:54 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)27.5 mg/L EPA 200.7 01/20/2016 17:21 FCJORDA0.01 1
Magnesium (Mg)8.11 mg/L EPA 200.7 01/20/2016 17:21 FCJORDA0.005 1
Potassium (K)2.73 mg/L EPA 200.7 01/20/2016 17:21 FCJORDA0.1 1
Sodium (Na)21.5 mg/L EPA 200.7 01/20/2016 17:21 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.714 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.005 1
Boron (B)0.638 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.05 1
Iron (Fe)2.44 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.01 1
Manganese (Mn)0.494 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.005 1
Strontium (Sr)0.305 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.005 1
Zinc (Zn)0.026 mg/L EPA 200.7 01/21/2016 13:11 FCJORDA0.005 1
Page 18 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001913
Collection Date:19-Jan-16 11:14 AM
Site: MW-05D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Cobalt (Co)24.0 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Copper (Cu)7.13 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Nickel (Ni)18.8 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Selenium (Se)3.42 ug/L EPA 200.8 01/21/2016 23:02 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 23:02 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 23:02 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Cobalt (Co)24.3 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Copper (Cu)6.91 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Nickel (Ni)17.5 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Selenium (Se)3.96 ug/L EPA 200.8 01/21/2016 15:32 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:32 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:32 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 240 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.147 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 19 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001914
Collection Date:19-Jan-16 11:58 AM
Site: MW-05BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.017 mg-N/L EPA 353.2 01/21/2016 11:45M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.9 mg/L EPA 300.0 01/21/2016 16:06 BGN90340.2 2
Sulfate 120 mg/L EPA 300.0 01/21/2016 16:06 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:37 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:00 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.046 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.005 1
Boron (B)0.349 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.05 1
Iron (Fe)28.7 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.01 1
Manganese (Mn)0.214 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.005 1
Strontium (Sr)0.207 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 13:58 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)25.4 mg/L EPA 200.7 01/20/2016 17:25 FCJORDA0.01 1
Magnesium (Mg)4.73 mg/L EPA 200.7 01/20/2016 17:25 FCJORDA0.005 1
Potassium (K)3.31 mg/L EPA 200.7 01/20/2016 17:25 FCJORDA0.1 1
Sodium (Na)16.9 mg/L EPA 200.7 01/20/2016 17:25 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.059 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.005 1
Barium (Ba)0.017 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.005 1
Boron (B)0.360 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.05 1
Iron (Fe)29.8 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.01 1
Manganese (Mn)0.221 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.005 1
Strontium (Sr)0.211 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:15 FCJORDA0.005 1
Page 20 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001914
Collection Date:19-Jan-16 11:58 AM
Site: MW-05BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 23:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 23:07 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 23:07 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Molybdenum (Mo)1.04 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:37 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:37 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:37 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 230 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.185 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 31 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 21 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001915
Collection Date:19-Jan-16 4:28 PM
Site: MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.077 mg-N/L EPA 353.2 01/21/2016 11:46 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 97 mg/L EPA 300.0 01/21/2016 14:09 BGN9034550
Sulfate 300 mg/L EPA 300.0 01/21/2016 14:09 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:40 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:16 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.005 1
Boron (B)0.837 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.05 1
Iron (Fe)1.99 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.01 1
Manganese (Mn)1.29 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.005 1
Strontium (Sr)0.276 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 01/20/2016 14:02 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)104 mg/L EPA 200.7 01/20/2016 17:29 FCJORDA0.1 10
Magnesium (Mg)26.0 mg/L EPA 200.7 01/20/2016 17:29 FCJORDA0.05 10
Potassium (K)6.95 mg/L EPA 200.7 01/20/2016 17:29 FCJORDA110
Sodium (Na)12.1 mg/L EPA 200.7 01/20/2016 17:29 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.013 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.005 1
Barium (Ba)0.053 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.005 1
Boron (B)0.884 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.05 1
Iron (Fe)1.84 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.01 1
Manganese (Mn)1.29 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.005 1
Strontium (Sr)0.290 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 01/21/2016 13:19 FCJORDA0.005 1
Page 22 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001915
Collection Date:19-Jan-16 4:28 PM
Site: MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Cobalt (Co)4.43 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Lead (Pb)1.27 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Nickel (Ni)2.79 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 23:12 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 23:12 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 23:12 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Cobalt (Co)4.44 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Nickel (Ni)2.49 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 15:42 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 15:42 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 15:42 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 610 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.289 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 23 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001916
Collection Date:19-Jan-16 3:20 PM
Site: MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.277 mg-N/L EPA 353.2 01/21/2016 11:47 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 99 mg/L EPA 300.0 01/21/2016 18:05 BGN9034550
Sulfate 290 mg/L EPA 300.0 01/21/2016 18:05 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:52 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:23 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.005 1
Barium (Ba)0.037 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.005 1
Boron (B)0.859 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.01 1
Manganese (Mn)0.204 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.005 1
Strontium (Sr)0.394 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 01/20/2016 14:14 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)120 mg/L EPA 200.7 01/20/2016 17:33 FCJORDA0.1 10
Magnesium (Mg)27.3 mg/L EPA 200.7 01/20/2016 17:33 FCJORDA0.05 10
Potassium (K)8.53 mg/L EPA 200.7 01/20/2016 17:33 FCJORDA110
Sodium (Na)14.0 mg/L EPA 200.7 01/20/2016 17:33 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.005 1
Boron (B)0.974 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.05 1
Iron (Fe)0.010 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.01 1
Manganese (Mn)0.221 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.005 1
Strontium (Sr)0.436 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 01/21/2016 13:31 FCJORDA0.005 1
Page 24 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001916
Collection Date:19-Jan-16 3:20 PM
Site: MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Nickel (Ni)4.11 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 22:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 22:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 22:09 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Nickel (Ni)4.16 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 16:21 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 16:21 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 16:21 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 630 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.219 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 25 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001917
Collection Date:19-Jan-16 12:08 PM
Site: MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.014 mg-N/L EPA 353.2 01/21/2016 11:49 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 410 mg/L EPA 300.0 01/21/2016 17:14 BGN903410100
Sulfate 170 mg/L EPA 300.0 01/21/2016 17:14 BGN903410100
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 17:59 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:26 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.117 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.005 1
Barium (Ba)0.128 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.005 1
Boron (B)1.82 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.05 1
Iron (Fe)23.8 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.01 1
Manganese (Mn)6.33 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.005 1
Strontium (Sr)0.584 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 01/20/2016 14:18 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)172 mg/L EPA 200.7 01/20/2016 17:36 FCJORDA0.1 10
Magnesium (Mg)54.4 mg/L EPA 200.7 01/20/2016 17:36 FCJORDA0.05 10
Potassium (K)4.27 mg/L EPA 200.7 01/20/2016 17:36 FCJORDA110
Sodium (Na)14.1 mg/L EPA 200.7 01/20/2016 17:36 FCJORDA0.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.091 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.005 1
Barium (Ba)0.134 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.005 1
Boron (B)1.94 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.05 1
Iron (Fe)24.2 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.01 1
Manganese (Mn)6.42 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.005 1
Strontium (Sr)0.602 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 01/21/2016 13:42 FCJORDA0.005 1
Page 26 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001917
Collection Date:19-Jan-16 12:08 PM
Site: MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Chromium (Cr)30.4 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Cobalt (Co)22.4 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Nickel (Ni)33.8 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 23:32 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 23:32 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 23:32 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Chromium (Cr)4.18 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Cobalt (Co)22.4 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Nickel (Ni)6.10 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 16:02 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 16:02 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 16:02 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 1100 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 1.5 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 13 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 27 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001918
Collection Date:19-Jan-16 10:20 AM
Site: MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.013 mg-N/L EPA 353.2 01/21/2016 11:50 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 130 mg/L EPA 300.0 01/21/2016 18:21 BGN9034220
Sulfate 39 mg/L EPA 300.0 01/21/2016 18:21 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:01 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:28 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.106 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.005 1
Barium (Ba)0.304 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.005 1
Boron (B)0.198 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.05 1
Iron (Fe)56.9 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.1 10
Manganese (Mn)0.776 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.005 1
Strontium (Sr)0.288 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 14:21 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)22.1 mg/L EPA 200.7 01/20/2016 17:40 FCJORDA0.01 1
Magnesium (Mg)5.05 mg/L EPA 200.7 01/20/2016 17:40 FCJORDA0.005 1
Potassium (K)3.29 mg/L EPA 200.7 01/20/2016 17:40 FCJORDA0.1 1
Sodium (Na)20.2 mg/L EPA 200.7 01/20/2016 17:40 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.100 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.005 1
Barium (Ba)0.296 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.005 1
Boron (B)0.216 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.05 1
Iron (Fe)58.2 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.01 1
Manganese (Mn)0.757 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.005 1
Strontium (Sr)0.278 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:46 FCJORDA0.005 1
Page 28 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001918
Collection Date:19-Jan-16 10:20 AM
Site: MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Cobalt (Co)1.11 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Nickel (Ni)1.68 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 23:51 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 23:51 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 23:51 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 16:26 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 16:26 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 16:26 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.394 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 29 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001919
Collection Date:19-Jan-16 4:15 PM
Site: FILTER BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:31 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 14:30 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 23:56 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 23:56 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 23:56 MHALL30.3 1
Page 30 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001920
Collection Date:19-Jan-16 4:15 PM
Site: EQUIPMENT BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/21/2016 11:53 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 01/21/2016 18:38 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 01/21/2016 18:38 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:04 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 01/20/2016 17:44 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 01/20/2016 17:44 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 01/20/2016 17:44 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 01/20/2016 17:44 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:50 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 16:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 16:31 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 16:31 MHALL30.3 1
Page 31 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001920
Collection Date:19-Jan-16 4:15 PM
Site: EQUIPMENT BLANK
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 32 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001921
Collection Date:19-Jan-16 10:35 AM
Site: MW-23DU DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.450 mg-N/L EPA 353.2 01/21/2016 11:55 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 8.4 mg/L EPA 300.0 01/21/2016 20:54 BGN90340.1 1
Sulfate 20 mg/L EPA 300.0 01/21/2016 20:54 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:06 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:33 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.005 1
Barium (Ba)0.034 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.005 1
Boron (B)0.079 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.01 1
Manganese (Mn)0.251 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.005 1
Strontium (Sr)0.036 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 15:17 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.24 mg/L EPA 200.7 01/20/2016 17:48 FCJORDA0.01 1
Magnesium (Mg)3.18 mg/L EPA 200.7 01/20/2016 17:48 FCJORDA0.005 1
Potassium (K)1.46 mg/L EPA 200.7 01/20/2016 17:48 FCJORDA0.1 1
Sodium (Na)8.56 mg/L EPA 200.7 01/20/2016 17:48 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.005 1
Boron (B)0.083 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.05 1
Iron (Fe)0.429 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.01 1
Manganese (Mn)0.297 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.005 1
Strontium (Sr)0.038 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 13:54 FCJORDA0.005 1
Page 33 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001921
Collection Date:19-Jan-16 10:35 AM
Site: MW-23DU DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Cobalt (Co)3.73 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Nickel (Ni)1.11 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/22/2016 00:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 00:01 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 00:01 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Cobalt (Co)4.68 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Nickel (Ni)1.14 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 16:36 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 16:36 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 16:36 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 83 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.166 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 34 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001922
Collection Date:19-Jan-16 2:23 PM
Site: CB-07
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.035 mg-N/L EPA 353.2 01/21/2016 11:56 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 65 mg/L EPA 300.0 01/21/2016 19:12 BGN9034110
Sulfate 31 mg/L EPA 300.0 01/21/2016 19:12 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 18:09 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 15:35 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.005 1
Boron (B)0.122 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.05 1
Iron (Fe)0.010 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.01 1
Manganese (Mn)0.015 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.005 1
Strontium (Sr)0.316 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.005 1
Zinc (Zn)0.073 mg/L EPA 200.7 01/20/2016 14:38 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)27.6 mg/L EPA 200.7 01/20/2016 18:00 FCJORDA0.01 1
Magnesium (Mg)5.20 mg/L EPA 200.7 01/20/2016 18:00 FCJORDA0.005 1
Potassium (K)7.61 mg/L EPA 200.7 01/20/2016 18:00 FCJORDA0.1 1
Sodium (Na)14.0 mg/L EPA 200.7 01/20/2016 18:00 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.005 1
Boron (B)0.121 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.05 1
Iron (Fe)0.044 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.01 1
Manganese (Mn)0.014 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.005 1
Strontium (Sr)0.318 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.005 1
Zinc (Zn)0.086 mg/L EPA 200.7 01/21/2016 13:58 FCJORDA0.005 1
Page 35 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
2016001922
Collection Date:19-Jan-16 2:23 PM
Site: CB-07
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Chromium (Cr)1.29 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Nickel (Ni)1.07 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Selenium (Se)8.28 ug/L EPA 200.8 01/22/2016 00:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/22/2016 00:06 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/22/2016 00:06 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Molybdenum (Mo)1.02 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Selenium (Se)8.13 ug/L EPA 200.8 01/21/2016 16:41 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 16:41 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 16:41 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 200 mg/L SM2540C 01/24/2016 15:28 CJELLIO251
Total Carbon
TOC 0.993 mg/L SM5310C/EPA9060A 01/26/2016 12:01 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/24/2016 12:45 CJELLIO51
Page 36 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010376
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 37 of 75
#=CL#
January 25, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92283619
92283619
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010376
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 20, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 37
Page 38 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92283619
J16010376
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 37
Page 39 of 75
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92283619
J16010376
Lab ID Sample ID Matrix Date Collected Date Received
92283619001 2016001905 Water 01/19/16 15:55 01/20/16 11:40
92283619002 2016001907 Water 01/19/16 14:44 01/20/16 11:40
92283619003 2016001908 Water 01/19/16 13:27 01/20/16 11:40
92283619004 2016001909 Water 01/19/16 10:58 01/20/16 11:40
92283619005 2016001910 Water 01/19/16 10:35 01/20/16 11:40
92283619006 2016001911 Water 01/19/16 15:12 01/20/16 11:40
92283619007 2016001912 Water 01/19/16 15:45 01/20/16 11:40
92283619008 2016001913 Water 01/19/16 11:14 01/20/16 11:40
92283619009 2016001914 Water 01/19/16 11:58 01/20/16 11:40
92283619010 2016001915 Water 01/19/16 16:28 01/20/16 11:40
92283619011 2016001916 Water 01/19/16 15:20 01/20/16 11:40
92283619012 2016001922 Water 01/19/16 14:23 01/20/16 11:40
92283619013 2016001917 Water 01/19/16 12:08 01/20/16 11:40
92283619014 2016001918 Water 01/19/16 10:20 01/20/16 11:40
92283619015 2016001920 Water 01/19/16 16:15 01/20/16 11:40
92283619016 2016001921 Water 01/19/16 10:35 01/20/16 11:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 37
Page 40 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283619
J16010376
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92283619001 2016001905 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619002 2016001907 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619003 2016001908 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619004 2016001909 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619005 2016001910 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619006 2016001911 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619007 2016001912 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619008 2016001913 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619009 2016001914 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619010 2016001915 RSK 175 1 PASI-MSTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 37
Page 41 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283619
J16010376
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619011 2016001916 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619012 2016001922 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619013 2016001917 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619014 2016001918 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619015 2016001920 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283619016 2016001921 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 37
Page 42 of 75
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283619
J16010376
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283619001 2016001905
Methane 71.8 ug/L 01/21/16 19:1410.0RSK 175
Alkalinity,Bicarbonate (CaCO3)6.3 mg/L 01/24/16 17:505.0SM 2320B
Alkalinity, Total as CaCO3 6.3 mg/L 01/24/16 17:505.0SM 2320B
Chromium, Hexavalent 0.17 ug/L 01/22/16 09:55 M10.030EPA 218.7
92283619002 2016001907
Methane 1040 ug/L 01/21/16 19:2210.0RSK 175
Alkalinity,Bicarbonate (CaCO3)72.8 mg/L 01/24/16 18:255.0SM 2320B
Alkalinity, Total as CaCO3 72.8 mg/L 01/24/16 18:255.0SM 2320B
92283619003 2016001908
Alkalinity,Bicarbonate (CaCO3)7.1 mg/L 01/24/16 18:375.0SM 2320B
Alkalinity, Total as CaCO3 7.1 mg/L 01/24/16 18:375.0SM 2320B
Chromium, Hexavalent 0.31 ug/L 01/22/16 14:540.060EPA 218.7
92283619004 2016001909
Alkalinity,Bicarbonate (CaCO3)92.4 mg/L 01/24/16 18:465.0SM 2320B
Alkalinity, Total as CaCO3 92.4 mg/L 01/24/16 18:465.0SM 2320B
92283619005 2016001910
Alkalinity,Bicarbonate (CaCO3)15.4 mg/L 01/24/16 18:585.0SM 2320B
Alkalinity, Total as CaCO3 15.4 mg/L 01/24/16 18:585.0SM 2320B
Chromium, Hexavalent 0.15 ug/L 01/22/16 11:130.030EPA 218.7
92283619007 2016001912
Alkalinity,Bicarbonate (CaCO3)39.0 mg/L 01/24/16 19:365.0SM 2320B
Alkalinity, Total as CaCO3 39.0 mg/L 01/24/16 19:365.0SM 2320B
92283619009 2016001914
Alkalinity,Bicarbonate (CaCO3)28.7 mg/L 01/24/16 19:535.0SM 2320B
Alkalinity, Total as CaCO3 28.7 mg/L 01/24/16 19:535.0SM 2320B
92283619010 2016001915
Alkalinity,Bicarbonate (CaCO3)32.4 mg/L 01/24/16 20:055.0SM 2320B
Alkalinity, Total as CaCO3 32.4 mg/L 01/24/16 20:055.0SM 2320B
92283619011 2016001916
Alkalinity,Bicarbonate (CaCO3)26.8 mg/L 01/24/16 20:165.0SM 2320B
Alkalinity, Total as CaCO3 26.8 mg/L 01/24/16 20:165.0SM 2320B
Chromium, Hexavalent 0.056 ug/L 01/22/16 12:57 M10.030EPA 218.7
92283619012 2016001922
Alkalinity,Bicarbonate (CaCO3)29.1 mg/L 01/24/16 20:525.0SM 2320B
Alkalinity, Total as CaCO3 29.1 mg/L 01/24/16 20:525.0SM 2320B
92283619014 2016001918
Methane 12.9 ug/L 01/21/16 21:5010.0RSK 175
Alkalinity,Bicarbonate (CaCO3)12.3 mg/L 01/24/16 21:125.0SM 2320B
Alkalinity, Total as CaCO3 12.3 mg/L 01/24/16 21:125.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 37
Page 43 of 75
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283619
J16010376
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283619016 2016001921
Alkalinity,Bicarbonate (CaCO3)15.7 mg/L 01/24/16 21:515.0SM 2320B
Alkalinity, Total as CaCO3 15.7 mg/L 01/24/16 21:515.0SM 2320B
Chromium, Hexavalent 0.13 ug/L 01/22/16 14:280.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 37
Page 44 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283619
J16010376
Method:
Client:Duke Energy
RSK 175
Date:January 25, 2016
Description:RSK 175 AIR Headspace
General Information:
16 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 37
Page 45 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283619
J16010376
Method:
Client:Duke Energy
SM 2320B
Date:January 25, 2016
Description:2320B Alkalinity
General Information:
16 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 37
Page 46 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283619
J16010376
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 25, 2016
Description:4500S2D Sulfide Water
General Information:
16 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 37
Page 47 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283619
J16010376
Method:
Client:Duke Energy
EPA 218.7
Date:January 25, 2016
Description:Hexavalent Chromium by IC
General Information:
16 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 37
Page 48 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001905 Lab ID:92283619001 Collected:01/19/16 15:55 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 71.8 ug/L 01/21/16 19:14 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)6.3 mg/L 01/24/16 17:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 17:505.0 1
Alkalinity, Total as CaCO3 6.3 mg/L 01/24/16 17:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.17 ug/L 01/22/16 09:55 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 37
Page 49 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001907 Lab ID:92283619002 Collected:01/19/16 14:44 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 1040 ug/L 01/21/16 19:22 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)72.8 mg/L 01/24/16 18:255.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 18:255.0 1
Alkalinity, Total as CaCO3 72.8 mg/L 01/24/16 18:255.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 10:34 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 37
Page 50 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001908 Lab ID:92283619003 Collected:01/19/16 13:27 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 19:47 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.1 mg/L 01/24/16 18:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 18:375.0 1
Alkalinity, Total as CaCO3 7.1 mg/L 01/24/16 18:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.31 ug/L 01/22/16 14:54 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 37
Page 51 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001909 Lab ID:92283619004 Collected:01/19/16 10:58 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)92.4 mg/L 01/24/16 18:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 18:465.0 1
Alkalinity, Total as CaCO3 92.4 mg/L 01/24/16 18:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 11:00 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 37
Page 52 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001910 Lab ID:92283619005 Collected:01/19/16 10:35 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.4 mg/L 01/24/16 18:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 18:585.0 1
Alkalinity, Total as CaCO3 15.4 mg/L 01/24/16 18:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.15 ug/L 01/22/16 11:13 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 37
Page 53 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001911 Lab ID:92283619006 Collected:01/19/16 15:12 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 19:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 19:095.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 19:095.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 11:26 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 37
Page 54 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001912 Lab ID:92283619007 Collected:01/19/16 15:45 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)39.0 mg/L 01/24/16 19:365.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 19:365.0 1
Alkalinity, Total as CaCO3 39.0 mg/L 01/24/16 19:365.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 11:39 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 37
Page 55 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001913 Lab ID:92283619008 Collected:01/19/16 11:14 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:36 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 19:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 19:475.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 19:475.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 11:52 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 37
Page 56 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001914 Lab ID:92283619009 Collected:01/19/16 11:58 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:44 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)28.7 mg/L 01/24/16 19:535.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 19:535.0 1
Alkalinity, Total as CaCO3 28.7 mg/L 01/24/16 19:535.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 12:05 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 37
Page 57 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001915 Lab ID:92283619010 Collected:01/19/16 16:28 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 20:53 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)32.4 mg/L 01/24/16 20:055.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 20:055.0 1
Alkalinity, Total as CaCO3 32.4 mg/L 01/24/16 20:055.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 12:18 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 37
Page 58 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001916 Lab ID:92283619011 Collected:01/19/16 15:20 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 21:01 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)26.8 mg/L 01/24/16 20:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 20:165.0 1
Alkalinity, Total as CaCO3 26.8 mg/L 01/24/16 20:165.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.056 ug/L 01/22/16 12:57 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 37
Page 59 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001922 Lab ID:92283619012 Collected:01/19/16 14:23 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 21:25 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)29.1 mg/L 01/24/16 20:525.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 20:525.0 1
Alkalinity, Total as CaCO3 29.1 mg/L 01/24/16 20:525.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 13:36 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 37
Page 60 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001917 Lab ID:92283619013 Collected:01/19/16 12:08 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 21:42 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 21:045.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 21:045.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 21:045.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 13:49 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 37
Page 61 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001918 Lab ID:92283619014 Collected:01/19/16 10:20 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 12.9 ug/L 01/21/16 21:50 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)12.3 mg/L 01/24/16 21:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 21:125.0 1
Alkalinity, Total as CaCO3 12.3 mg/L 01/24/16 21:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 14:02 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 37
Page 62 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001920 Lab ID:92283619015 Collected:01/19/16 16:15 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 21:58 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 21:425.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 21:425.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 21:425.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/22/16 14:15 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 37
Page 63 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283619
J16010376
Sample:2016001921 Lab ID:92283619016 Collected:01/19/16 10:35 Received:01/20/16 11:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 22:06 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.7 mg/L 01/24/16 21:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 21:515.0 1
Alkalinity, Total as CaCO3 15.7 mg/L 01/24/16 21:515.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/21/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.13 ug/L 01/22/16 14:28 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 37
Page 64 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283619
J16010376
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25065
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283619001, 92283619002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2178463
Associated Lab Samples:92283619001, 92283619002
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/21/16 16:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2178464LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2178465
Methane ug/L 60.660.7 100 85-11510261.6 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283470006
2179324SAMPLE DUPLICATE:
Methane ug/L 2J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283470015
2179325SAMPLE DUPLICATE:
Methane ug/L 1.4J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 37
Page 65 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283619
J16010376
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25069
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008, 92283619009,
92283619010, 92283619011, 92283619012, 92283619013, 92283619014, 92283619015, 92283619016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2178774
Associated Lab Samples:92283619003, 92283619004, 92283619005, 92283619006, 92283619007, 92283619008, 92283619009,
92283619010, 92283619011, 92283619012, 92283619013, 92283619014, 92283619015, 92283619016
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/21/16 19:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2178775LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2178776
Methane ug/L 61.660.7 102 85-1159557.9 6 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283619003
2179332SAMPLE DUPLICATE:
Methane ug/L 1.2J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283619012
2179333SAMPLE DUPLICATE:
Methane ug/L 1.3J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 37
Page 66 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283619
J16010376
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42634
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007,
92283619008, 92283619009, 92283619010, 92283619011, 92283619012, 92283619013, 92283619014,
92283619015, 92283619016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1652087
Associated Lab Samples:92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007,
92283619008, 92283619009, 92283619010, 92283619011, 92283619012, 92283619013, 92283619014,
92283619015, 92283619016
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/24/16 17:31
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/24/16 17:31
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/24/16 17:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1652088LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.250 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1652089MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283619001
1652090
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 80-12099 0 25506.3 55.8 55.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1652091MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283619011
1652092
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 101 80-12098 2 255026.8 77.2 75.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 37
Page 67 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283619
J16010376
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42614
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007,
92283619008, 92283619009, 92283619010, 92283619011, 92283619012, 92283619013, 92283619014,
92283619015, 92283619016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1651471
Associated Lab Samples:92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007,
92283619008, 92283619009, 92283619010, 92283619011, 92283619012, 92283619013, 92283619014,
92283619015, 92283619016
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/21/16 15:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1651472LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1651473MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283619001
1651474
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 93 90-11093 0 10.5ND 0.47 0.47
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1651475MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283619011
1651476
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 96 90-11096 0 10.5ND 0.48 0.48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 37
Page 68 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283619
J16010376
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/54135
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92283619001, 92283619002, 92283619003, 92283619004, 92283619005, 92283619006, 92283619007,
92283619008, 92283619009, 92283619010, 92283619011, 92283619012, 92283619013, 92283619014,
92283619015, 92283619016
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1456413
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/22/16 09:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1456414LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.081.075 108 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1456415MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283619001
1456416
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 87 85-115127 5 20.0250.17 0.19 0.20
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1456417MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283619011
1456418
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 84 85-11577 5 20.0750.056 0.12 0.11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 37
Page 69 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92283619
J16010376
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 37
Page 70 of 75
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283619
J16010376
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283619001 AIR/250652016001905RSK 175
92283619002 AIR/250652016001907RSK 175
92283619003 AIR/250692016001908RSK 175
92283619004 AIR/250692016001909RSK 175
92283619005 AIR/250692016001910RSK 175
92283619006 AIR/250692016001911RSK 175
92283619007 AIR/250692016001912RSK 175
92283619008 AIR/250692016001913RSK 175
92283619009 AIR/250692016001914RSK 175
92283619010 AIR/250692016001915RSK 175
92283619011 AIR/250692016001916RSK 175
92283619012 AIR/250692016001922RSK 175
92283619013 AIR/250692016001917RSK 175
92283619014 AIR/250692016001918RSK 175
92283619015 AIR/250692016001920RSK 175
92283619016 AIR/250692016001921RSK 175
92283619001 WET/426342016001905SM 2320B
92283619002 WET/426342016001907SM 2320B
92283619003 WET/426342016001908SM 2320B
92283619004 WET/426342016001909SM 2320B
92283619005 WET/426342016001910SM 2320B
92283619006 WET/426342016001911SM 2320B
92283619007 WET/426342016001912SM 2320B
92283619008 WET/426342016001913SM 2320B
92283619009 WET/426342016001914SM 2320B
92283619010 WET/426342016001915SM 2320B
92283619011 WET/426342016001916SM 2320B
92283619012 WET/426342016001922SM 2320B
92283619013 WET/426342016001917SM 2320B
92283619014 WET/426342016001918SM 2320B
92283619015 WET/426342016001920SM 2320B
92283619016 WET/426342016001921SM 2320B
92283619001 WET/426142016001905SM 4500-S2D
92283619002 WET/426142016001907SM 4500-S2D
92283619003 WET/426142016001908SM 4500-S2D
92283619004 WET/426142016001909SM 4500-S2D
92283619005 WET/426142016001910SM 4500-S2D
92283619006 WET/426142016001911SM 4500-S2D
92283619007 WET/426142016001912SM 4500-S2D
92283619008 WET/426142016001913SM 4500-S2D
92283619009 WET/426142016001914SM 4500-S2D
92283619010 WET/426142016001915SM 4500-S2D
92283619011 WET/426142016001916SM 4500-S2D
92283619012 WET/426142016001922SM 4500-S2D
92283619013 WET/426142016001917SM 4500-S2D
92283619014 WET/426142016001918SM 4500-S2D
92283619015 WET/426142016001920SM 4500-S2D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 37
Page 71 of 75
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283619
J16010376
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283619016 WET/426142016001921SM 4500-S2D
92283619001 WETA/541352016001905EPA 218.7
92283619002 WETA/541352016001907EPA 218.7
92283619003 WETA/541352016001908EPA 218.7
92283619004 WETA/541352016001909EPA 218.7
92283619005 WETA/541352016001910EPA 218.7
92283619006 WETA/541352016001911EPA 218.7
92283619007 WETA/541352016001912EPA 218.7
92283619008 WETA/541352016001913EPA 218.7
92283619009 WETA/541352016001914EPA 218.7
92283619010 WETA/541352016001915EPA 218.7
92283619011 WETA/541352016001916EPA 218.7
92283619012 WETA/541352016001922EPA 218.7
92283619013 WETA/541352016001917EPA 218.7
92283619014 WETA/541352016001918EPA 218.7
92283619015 WETA/541352016001920EPA 218.7
92283619016 WETA/541352016001921EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/25/2016 11:40 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 37
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