NC0000396_App B Lab Reports - CSA RND 4 Sampling - J16010355 Report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16010355
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pifer
Date:2/4/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone:
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pifer
Page 1 of 74
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016001809 ASHEVILLE 18-Jan-16 4:01 PM illegible CB-05
2016001810 ASHEVILLE 18-Jan-16 2:04 PM illegible MW-21D
2016001811 ASHEVILLE 18-Jan-16 12:08 PM illegible MW-22D
2016001812 ASHEVILLE 18-Jan-16 11:21 AM illegible MW-22BR
2016001813 ASHEVILLE 18-Jan-16 4:23 PM illegible MW-16A
2016001814 ASHEVILLE 18-Jan-16 3:25 PM illegible MW-15A
2016001815 ASHEVILLE 18-Jan-16 2:27 PM illegible MW-15D
2016001816 ASHEVILLE 18-Jan-16 1:22 PM illegible MW-11
2016001817 ASHEVILLE 18-Jan-16 12:18 PM illegible MW-11D
2016001818 ASHEVILLE 18-Jan-16 10:35 AM illegible MW-14BR
2016001819 ASHEVILLE 18-Jan-16 3:56 PM illegible GW-1BR
2016001820 ASHEVILLE 18-Jan-16 3:09 PM illegible GW-1
2016001821 ASHEVILLE 18-Jan-16 2:51 PM illegible GW-01D
2016001822 ASHEVILLE 18-Jan-16 11:35 AM illegible MW-01BR
2016001823 ASHEVILLE 18-Jan-16 10:44 AM illegible MW-01D
15 Total Samples
Page 2 of 74
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:2/4/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001809
Collection Date:18-Jan-16 4:01 PM
Site:CB-05
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.020 mg-N/L EPA 353.2 01/21/2016 10:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 22 mg/L EPA 300.0 01/20/2016 17:48 BGN9034110
Sulfate 48 mg/L EPA 300.0 01/20/2016 17:48 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 17:23 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 20:38 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.100 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.005 1
Boron (B)0.180 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.05 1
Iron (Fe)27.2 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.01 1
Manganese (Mn)0.616 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.005 1
Strontium (Sr)0.042 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 11:34 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.60 mg/L EPA 200.7 01/20/2016 15:02 FCJORDA0.01 1
Magnesium (Mg)5.42 mg/L EPA 200.7 01/20/2016 15:02 FCJORDA0.005 1
Potassium (K)0.833 mg/L EPA 200.7 01/20/2016 15:02 FCJORDA0.1 1
Sodium (Na)18.7 mg/L EPA 200.7 01/20/2016 15:02 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.105 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.005 1
Barium (Ba)0.021 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.005 1
Boron (B)0.186 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.05 1
Iron (Fe)26.9 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.01 1
Manganese (Mn)0.625 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.005 1
Strontium (Sr)0.042 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:20 FCJORDA0.005 1
Page 4 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001809
Collection Date:18-Jan-16 4:01 PM
Site:CB-05
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:15 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:15 MHALL30.2 1
Vanadium (V) Low Level 0.338 ug/L EPA 200.8 01/21/2016 17:15 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:01 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:01 MHALL30.2 1
Vanadium (V) Low Level 0.461 ug/L EPA 200.8 01/21/2016 20:01 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 7.9 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI110
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 5 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001810
Collection Date:18-Jan-16 2:04 PM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.042 mg-N/L EPA 353.2 01/21/2016 10:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 29 mg/L EPA 300.0 01/20/2016 16:57 BGN90340.5 5
Sulfate 29 mg/L EPA 300.0 01/20/2016 16:57 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 17:25 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 20:40 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.005 1
Barium (Ba)0.043 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.005 1
Boron (B)0.092 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.05 1
Iron (Fe)1.51 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.01 1
Manganese (Mn)0.647 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.005 1
Strontium (Sr)0.075 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 01/20/2016 11:38 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.46 mg/L EPA 200.7 01/20/2016 15:14 FCJORDA0.01 1
Magnesium (Mg)3.85 mg/L EPA 200.7 01/20/2016 15:14 FCJORDA0.005 1
Potassium (K)1.42 mg/L EPA 200.7 01/20/2016 15:14 FCJORDA0.1 1
Sodium (Na)15.1 mg/L EPA 200.7 01/20/2016 15:14 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.023 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.005 1
Barium (Ba)0.046 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.005 1
Boron (B)0.095 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.05 1
Iron (Fe)2.44 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.01 1
Manganese (Mn)0.645 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.005 1
Strontium (Sr)0.075 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:32 FCJORDA0.005 1
Page 6 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001810
Collection Date:18-Jan-16 2:04 PM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Cobalt (Co)1.28 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Nickel (Ni)1.01 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:34 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:34 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 17:34 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Cobalt (Co)1.09 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 19:42 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 19:42 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 19:42 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.257 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 7 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001811
Collection Date:18-Jan-16 12:08 PM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.444 mg-N/L EPA 353.2 01/21/2016 10:51 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 45 mg/L EPA 300.0 01/20/2016 18:05 BGN90340.5 5
Sulfate 10 mg/L EPA 300.0 01/20/2016 18:05 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 17:28 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 20:43 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.033 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.005 1
Barium (Ba)0.037 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.01 1
Manganese (Mn)0.116 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.005 1
Strontium (Sr)0.065 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 11:41 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.56 mg/L EPA 200.7 01/20/2016 15:33 FCJORDA0.01 1
Magnesium (Mg)5.57 mg/L EPA 200.7 01/20/2016 15:33 FCJORDA0.005 1
Potassium (K)1.59 mg/L EPA 200.7 01/20/2016 15:33 FCJORDA0.1 1
Sodium (Na)14.1 mg/L EPA 200.7 01/20/2016 15:33 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.065 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.005 1
Barium (Ba)0.040 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.05 1
Iron (Fe)0.039 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.01 1
Manganese (Mn)0.118 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.005 1
Strontium (Sr)0.065 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:40 FCJORDA0.005 1
Page 8 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001811
Collection Date:18-Jan-16 12:08 PM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Nickel (Ni)6.62 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:39 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:39 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 17:39 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Nickel (Ni)6.76 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:06 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:06 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 20:06 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 98 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.262 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 9 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001812
Collection Date:18-Jan-16 11:21 AM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 01/21/2016 10:55 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 51 mg/L EPA 300.0 01/21/2016 08:15 BGN9034110
Sulfate 20 mg/L EPA 300.0 01/21/2016 08:15 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 17:30 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 20:45 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.05 1
Iron (Fe)14.3 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.01 1
Manganese (Mn)0.259 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 11:45 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.6 mg/L EPA 200.7 01/20/2016 15:44 FCJORDA0.01 1
Magnesium (Mg)4.32 mg/L EPA 200.7 01/20/2016 15:44 FCJORDA0.005 1
Potassium (K)3.24 mg/L EPA 200.7 01/20/2016 15:44 FCJORDA0.1 1
Sodium (Na)17.0 mg/L EPA 200.7 01/20/2016 15:44 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.083 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.05 1
Iron (Fe)14.7 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.01 1
Manganese (Mn)0.262 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:44 FCJORDA0.005 1
Page 10 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001812
Collection Date:18-Jan-16 11:21 AM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:44 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:44 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 17:44 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:11 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:11 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 20:11 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 140 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.362 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 11 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001813
Collection Date:18-Jan-16 4:23 PM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.036 mg-N/L EPA 353.2 01/21/2016 10:56 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 140 mg/L EPA 300.0 01/20/2016 18:39 BGN9034220
Sulfate 59 mg/L EPA 300.0 01/20/2016 18:39 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 17:33 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 09:50 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.422 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.005 1
Barium (Ba)0.208 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.005 1
Boron (B)0.617 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.05 1
Iron (Fe)0.062 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.01 1
Manganese (Mn)2.24 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.005 1
Strontium (Sr)0.331 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 11:49 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)44.7 mg/L EPA 200.7 01/20/2016 15:56 FCJORDA0.01 1
Magnesium (Mg)15.8 mg/L EPA 200.7 01/20/2016 15:56 FCJORDA0.005 1
Potassium (K)2.95 mg/L EPA 200.7 01/20/2016 15:56 FCJORDA0.1 1
Sodium (Na)22.1 mg/L EPA 200.7 01/20/2016 15:56 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.260 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.005 1
Barium (Ba)0.162 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.005 1
Boron (B)0.524 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.05 1
Iron (Fe)0.096 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.01 1
Manganese (Mn)1.62 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.005 1
Strontium (Sr)0.275 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:47 FCJORDA0.005 1
Page 12 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001813
Collection Date:18-Jan-16 4:23 PM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Cobalt (Co)2.28 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:49 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:49 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 17:49 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Cobalt (Co)1.33 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:16 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:16 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 20:16 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 330 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.748 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 13 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001814
Collection Date:18-Jan-16 3:25 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.029 mg-N/L EPA 353.2 01/21/2016 10:57 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 43 mg/L EPA 300.0 01/20/2016 21:16 BGN90340.5 5
Sulfate 5.8 mg/L EPA 300.0 01/20/2016 21:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:01 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:00 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.112 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.005 1
Barium (Ba)0.090 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.005 1
Boron (B)0.058 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.05 1
Iron (Fe)0.037 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.01 1
Manganese (Mn)0.957 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.005 1
Strontium (Sr)0.101 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/20/2016 11:53 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.99 mg/L EPA 200.7 01/20/2016 16:00 FCJORDA0.01 1
Magnesium (Mg)4.19 mg/L EPA 200.7 01/20/2016 16:00 FCJORDA0.005 1
Potassium (K)0.948 mg/L EPA 200.7 01/20/2016 16:00 FCJORDA0.1 1
Sodium (Na)11.9 mg/L EPA 200.7 01/20/2016 16:00 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.132 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.005 1
Barium (Ba)0.092 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.005 1
Boron (B)0.060 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.05 1
Iron (Fe)0.043 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.01 1
Manganese (Mn)1.000 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.005 1
Strontium (Sr)0.100 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:51 FCJORDA0.005 1
Page 14 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001814
Collection Date:18-Jan-16 3:25 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:54 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:54 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 17:54 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:21 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:21 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 20:21 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 91 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.347 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 15 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001815
Collection Date:18-Jan-16 2:27 PM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.793 mg-N/L EPA 353.2 01/21/2016 10:59 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L EPA 300.0 01/21/2016 08:32 BGN90340.2 2
Sulfate 0.32 mg/L EPA 300.0 01/21/2016 08:32 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:09 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:02 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.005 1
Barium (Ba)0.064 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.005 1
Strontium (Sr)0.119 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 11:57 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.11 mg/L EPA 200.7 01/20/2016 16:04 FCJORDA0.01 1
Magnesium (Mg)2.50 mg/L EPA 200.7 01/20/2016 16:04 FCJORDA0.005 1
Potassium (K)2.68 mg/L EPA 200.7 01/20/2016 16:04 FCJORDA0.1 1
Sodium (Na)7.05 mg/L EPA 200.7 01/20/2016 16:04 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.070 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.005 1
Barium (Ba)0.059 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.05 1
Iron (Fe)0.143 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.01 1
Manganese (Mn)0.030 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.005 1
Strontium (Sr)0.118 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 15:55 FCJORDA0.005 1
Page 16 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001815
Collection Date:18-Jan-16 2:27 PM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 17:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 17:59 MHALL30.2 1
Vanadium (V) Low Level 0.561 ug/L EPA 200.8 01/21/2016 17:59 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:26 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:26 MHALL30.2 1
Vanadium (V) Low Level 0.736 ug/L EPA 200.8 01/21/2016 20:26 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 75 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.166 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 17 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001816
Collection Date:18-Jan-16 1:22 PM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.662 mg-N/L EPA 353.2 01/21/2016 11:01 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 01/21/2016 08:49 BGN9034220
Sulfate 30 mg/L EPA 300.0 01/21/2016 08:49 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:11 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:05 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.112 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.005 1
Barium (Ba)0.113 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.01 1
Manganese (Mn)0.259 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.005 1
Strontium (Sr)0.139 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 01/20/2016 12:03 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)26.6 mg/L EPA 200.7 01/20/2016 16:08 FCJORDA0.01 1
Magnesium (Mg)13.5 mg/L EPA 200.7 01/20/2016 16:08 FCJORDA0.005 1
Potassium (K)1.49 mg/L EPA 200.7 01/20/2016 16:08 FCJORDA0.1 1
Sodium (Na)40.1 mg/L EPA 200.7 01/20/2016 16:08 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.145 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.005 1
Barium (Ba)0.115 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.05 1
Iron (Fe)0.025 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.01 1
Manganese (Mn)0.239 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.005 1
Strontium (Sr)0.137 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 01/21/2016 15:59 FCJORDA0.005 1
Page 18 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001816
Collection Date:18-Jan-16 1:22 PM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Chromium (Cr)2.86 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Nickel (Ni)4.13 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 18:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 18:04 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 18:04 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Chromium (Cr)4.33 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Cobalt (Co)1.23 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Nickel (Ni)4.38 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:31 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:31 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 20:31 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 19 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001817
Collection Date:18-Jan-16 12:18 PM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)2.7 mg-N/L EPA 353.2 01/21/2016 11:07 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 150 mg/L EPA 300.0 01/20/2016 20:42 BGN90342.5 25
Sulfate 16 mg/L EPA 300.0 01/20/2016 20:42 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:14 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:07 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.106 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.005 1
Barium (Ba)0.287 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.005 1
Boron (B)0.054 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.01 1
Manganese (Mn)0.129 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.005 1
Strontium (Sr)0.307 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 12:07 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)30.4 mg/L EPA 200.7 01/20/2016 16:11 FCJORDA0.01 1
Magnesium (Mg)13.4 mg/L EPA 200.7 01/20/2016 16:11 FCJORDA0.005 1
Potassium (K)3.51 mg/L EPA 200.7 01/20/2016 16:11 FCJORDA0.1 1
Sodium (Na)39.3 mg/L EPA 200.7 01/20/2016 16:11 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.222 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.005 1
Barium (Ba)0.300 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.05 1
Iron (Fe)0.196 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.01 1
Manganese (Mn)0.134 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.005 1
Strontium (Sr)0.296 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 16:03 FCJORDA0.005 1
Page 20 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001817
Collection Date:18-Jan-16 12:18 PM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 18:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 18:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 18:09 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 20:36 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:36 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 20:36 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.409 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 21 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001818
Collection Date:18-Jan-16 10:35 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.621 mg-N/L EPA 353.2 01/21/2016 11:03 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.2 mg/L EPA 300.0 01/20/2016 20:59 BGN90340.5 5
Sulfate 190 mg/L EPA 300.0 01/20/2016 20:59 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:16 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:10 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.005 1
Barium (Ba)0.061 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.005 1
Boron (B)0.352 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.005 1
Strontium (Sr)0.282 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 12:11 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)81.0 mg/L EPA 200.7 01/20/2016 16:15 FCJORDA0.01 1
Magnesium (Mg)13.0 mg/L EPA 200.7 01/20/2016 16:15 FCJORDA0.005 1
Potassium (K)6.36 mg/L EPA 200.7 01/20/2016 16:15 FCJORDA0.1 1
Sodium (Na)8.99 mg/L EPA 200.7 01/20/2016 16:15 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.005 1
Barium (Ba)0.061 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.005 1
Boron (B)0.352 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.05 1
Iron (Fe)0.057 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.005 1
Strontium (Sr)0.282 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 16:07 FCJORDA0.005 1
Page 22 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001818
Collection Date:18-Jan-16 10:35 AM
Site:MW-14BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Molybdenum (Mo)3.87 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Selenium (Se)9.88 ug/L EPA 200.8 01/21/2016 18:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 18:14 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 18:14 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Molybdenum (Mo)4.11 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Selenium (Se)9.05 ug/L EPA 200.8 01/21/2016 20:40 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 20:40 MHALL30.2 1
Vanadium (V) Low Level 0.333 ug/L EPA 200.8 01/21/2016 20:40 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 390 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.708 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 23 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001819
Collection Date:18-Jan-16 3:56 PM
Site:GW-1BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 01/21/2016 11:04 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 1.5 mg/L EPA 300.0 01/20/2016 23:14 BGN90340.1 1
Sulfate 5.2 mg/L EPA 300.0 01/20/2016 23:14 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:18 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:12 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.005 1
Barium (Ba)0.011 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.05 1
Iron (Fe)0.897 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.01 1
Manganese (Mn)0.063 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.005 1
Strontium (Sr)0.087 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 12:22 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.8 mg/L EPA 200.7 01/20/2016 16:27 FCJORDA0.01 1
Magnesium (Mg)3.34 mg/L EPA 200.7 01/20/2016 16:27 FCJORDA0.005 1
Potassium (K)3.78 mg/L EPA 200.7 01/20/2016 16:27 FCJORDA0.1 1
Sodium (Na)7.28 mg/L EPA 200.7 01/20/2016 16:27 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.005 1
Barium (Ba)0.012 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.05 1
Iron (Fe)1.19 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.01 1
Manganese (Mn)0.065 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.005 1
Strontium (Sr)0.088 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 16:22 FCJORDA0.005 1
Page 24 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001819
Collection Date:18-Jan-16 3:56 PM
Site:GW-1BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Molybdenum (Mo)3.30 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 18:53 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 18:53 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 18:53 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Molybdenum (Mo)3.40 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 21:20 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 21:20 MHALL30.2 1
Vanadium (V) Low Level 0.317 ug/L EPA 200.8 01/21/2016 21:20 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.550 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 25 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001820
Collection Date:18-Jan-16 3:09 PM
Site:GW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)5.7 mg-N/L EPA 353.2 01/21/2016 11:10 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 5.5 mg/L EPA 300.0 01/21/2016 00:22 BGN90340.1 1
Sulfate 29 mg/L EPA 300.0 01/21/2016 00:22 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.19 ug/L EPA 245.1 01/26/2016 16:21B2 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:15 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.177 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.005 1
Barium (Ba)0.075 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.01 1
Manganese (Mn)0.716 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 01/20/2016 12:26 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.2 mg/L EPA 200.7 01/20/2016 16:31 FCJORDA0.01 1
Magnesium (Mg)8.70 mg/L EPA 200.7 01/20/2016 16:31 FCJORDA0.005 1
Potassium (K)0.693 mg/L EPA 200.7 01/20/2016 16:31 FCJORDA0.1 1
Sodium (Na)1.13 mg/L EPA 200.7 01/20/2016 16:31 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.276 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.005 1
Barium (Ba)0.073 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.05 1
Iron (Fe)0.104 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.01 1
Manganese (Mn)0.725 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 01/21/2016 16:33 FCJORDA0.005 1
Page 26 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001820
Collection Date:18-Jan-16 3:09 PM
Site:GW-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Chromium (Cr)1.05 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Cobalt (Co)6.44 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Copper (Cu)1.07 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Nickel (Ni)3.96 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Selenium (Se)1.47 ug/L EPA 200.8 01/21/2016 18:33 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 18:33 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 18:33 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Chromium (Cr)1.20 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Cobalt (Co)6.13 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Nickel (Ni)3.40 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Selenium (Se)1.53 ug/L EPA 200.8 01/21/2016 21:00 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 21:00 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 21:00 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 82 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.655 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 27 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001821
Collection Date:18-Jan-16 2:51 PM
Site:GW-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.646 mg-N/L EPA 353.2 01/21/2016 11:22 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 4.2 mg/L EPA 300.0 01/20/2016 22:23 BGN90340.1 1
Sulfate 1.4 mg/L EPA 300.0 01/20/2016 22:23 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.09 ug/L EPA 245.1 01/26/2016 16:23B2 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 21:17 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.021 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.005 1
Barium (Ba)0.031 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.01 1
Manganese (Mn)0.095 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.005 1
Strontium (Sr)0.024 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 12:30 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.66 mg/L EPA 200.7 01/20/2016 16:35 FCJORDA0.01 1
Magnesium (Mg)1.73 mg/L EPA 200.7 01/20/2016 16:35 FCJORDA0.005 1
Potassium (K)1.09 mg/L EPA 200.7 01/20/2016 16:35 FCJORDA0.1 1
Sodium (Na)2.09 mg/L EPA 200.7 01/20/2016 16:35 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.126 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.005 1
Barium (Ba)0.036 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.05 1
Iron (Fe)0.221 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.01 1
Manganese (Mn)0.097 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.005 1
Strontium (Sr)0.025 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 16:37 FCJORDA0.005 1
Page 28 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001821
Collection Date:18-Jan-16 2:51 PM
Site:GW-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Cobalt (Co)1.61 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 18:58 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 18:58 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 18:58 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Cobalt (Co)1.62 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Nickel (Ni)1.10 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 21:24 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 21:24 MHALL30.2 1
Vanadium (V) Low Level 0.339 ug/L EPA 200.8 01/21/2016 21:24 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 32 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.158 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 29 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001822
Collection Date:18-Jan-16 11:35 AM
Site:MW-01BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.013 mg-N/L EPA 353.2 01/21/2016 11:19M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 1.7 mg/L EPA 300.0 01/20/2016 23:48 BGN90340.1 1
Sulfate 7.5 mg/L EPA 300.0 01/20/2016 23:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/25/2016 20:45 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.05 1
Iron (Fe)2.68 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.01 1
Manganese (Mn)0.077 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.005 1
Strontium (Sr)0.064 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/20/2016 12:34 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.89 mg/L EPA 200.7 01/20/2016 16:38 FCJORDA0.01 1
Magnesium (Mg)2.68 mg/L EPA 200.7 01/20/2016 16:38 FCJORDA0.005 1
Potassium (K)2.93 mg/L EPA 200.7 01/20/2016 16:38 FCJORDA0.1 1
Sodium (Na)5.22 mg/L EPA 200.7 01/20/2016 16:38 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.05 1
Iron (Fe)3.02 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.01 1
Manganese (Mn)0.075 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.005 1
Strontium (Sr)0.063 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 16:41 FCJORDA0.005 1
Page 30 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001822
Collection Date:18-Jan-16 11:35 AM
Site:MW-01BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 19:03 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 19:03 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 19:03 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 21:29 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 21:29 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 21:29 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 56 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.113 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 31 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001823
Collection Date:18-Jan-16 10:44 AM
Site:MW-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.3 mg-N/L EPA 353.2 01/21/2016 11:26 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.6 mg/L EPA 300.0 01/21/2016 00:05 BGN90340.1 1
Sulfate 3.5 mg/L EPA 300.0 01/21/2016 00:05 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/26/2016 16:28 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 01/27/2016 14:33 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.018 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.01 1
Manganese (Mn)0.038 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.005 1
Strontium (Sr)0.030 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 01/20/2016 12:45 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.13 mg/L EPA 200.7 01/20/2016 16:42 FCJORDA0.01 1
Magnesium (Mg)2.37 mg/L EPA 200.7 01/20/2016 16:42 FCJORDA0.005 1
Potassium (K)1.11 mg/L EPA 200.7 01/20/2016 16:42 FCJORDA0.1 1
Sodium (Na)2.69 mg/L EPA 200.7 01/20/2016 16:42 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.028 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.05 1
Iron (Fe)0.071 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.01 1
Manganese (Mn)0.039 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.005 1
Strontium (Sr)0.028 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 01/21/2016 16:45 FCJORDA0.005 1
Page 32 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
2016001823
Collection Date:18-Jan-16 10:44 AM
Site:MW-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Cobalt (Co)2.83 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Copper (Cu)2.90 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Nickel (Ni)3.45 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 19:07 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 19:07 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 19:07 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Cobalt (Co)2.47 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Copper (Cu)2.68 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Nickel (Ni)2.56 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 01/21/2016 21:34 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 01/21/2016 21:34 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 01/21/2016 21:34 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 37 mg/L SM2540C 01/21/2016 14:35 CJELLIO251
Total Carbon
TOC 0.139 mg/L SM5310C/EPA9060A 01/20/2016 13:06 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 01/21/2016 09:09 CJELLIO51
Page 33 of 74
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16010355
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 34 of 74
#=CL#
January 26, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92283470
92283470
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16010355
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 19, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 39
Page 35 of 74
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92283470
J16010355
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Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 39
Page 36 of 74
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92283470
J16010355
Lab ID Sample ID Matrix Date Collected Date Received
92283470001 2016001809 Water 01/18/16 16:01 01/19/16 13:00
92283470002 2016001810 Water 01/18/16 14:04 01/19/16 13:00
92283470003 2016001811 Water 01/18/16 12:08 01/19/16 13:00
92283470004 2016001812 Water 01/18/16 11:21 01/19/16 13:00
92283470005 2016001813 Water 01/18/16 16:23 01/19/16 13:00
92283470006 2016001814 Water 01/18/16 15:25 01/19/16 13:00
92283470007 2016001815 Water 01/18/16 14:27 01/19/16 13:00
92283470008 2016001816 Water 01/18/16 13:22 01/19/16 13:00
92283470009 2016001817 Water 01/18/16 12:18 01/19/16 13:00
92283470010 2016001818 Water 01/18/16 10:35 01/19/16 13:00
92283470011 2016001819 Water 01/18/16 15:56 01/19/16 13:00
92283470012 2016001820 Water 01/18/16 15:09 01/19/16 13:00
92283470013 2016001821 Water 01/18/16 14:51 01/19/16 13:00
92283470014 2016001822 Water 01/18/16 11:35 01/19/16 13:00
92283470015 2016001823 Water 01/18/16 10:44 01/19/16 13:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 39
Page 37 of 74
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283470
J16010355
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92283470001 2016001809 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470002 2016001810 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470003 2016001811 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470004 2016001812 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470005 2016001813 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470006 2016001814 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470007 2016001815 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470008 2016001816 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470009 2016001817 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470010 2016001818 RSK 175 1 PASI-MSTV
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 39
Page 38 of 74
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92283470
J16010355
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470011 2016001819 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470012 2016001820 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470013 2016001821 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470014 2016001822 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92283470015 2016001823 RSK 175 1 PASI-MSTV
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 39
Page 39 of 74
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283470
J16010355
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283470001 2016001809
Methane 1100 ug/L 01/21/16 15:1110.0RSK 175
Alkalinity,Bicarbonate (CaCO3)36.4 mg/L 01/21/16 22:475.0SM 2320B
Alkalinity, Total as CaCO3 36.4 mg/L 01/21/16 22:475.0SM 2320B
92283470002 2016001810
Alkalinity,Bicarbonate (CaCO3)10.0 mg/L 01/21/16 22:575.0SM 2320B
Alkalinity, Total as CaCO3 10.0 mg/L 01/21/16 22:575.0SM 2320B
92283470003 2016001811
Chromium, Hexavalent 0.57 ug/L 01/21/16 09:030.15EPA 218.7
92283470004 2016001812
Alkalinity,Bicarbonate (CaCO3)15.7 mg/L 01/24/16 13:175.0SM 2320B
Alkalinity, Total as CaCO3 15.7 mg/L 01/24/16 13:175.0SM 2320B
92283470005 2016001813
Chromium, Hexavalent 0.034 ug/L 01/20/16 19:380.030EPA 218.7
92283470007 2016001815
Alkalinity,Bicarbonate (CaCO3)32.4 mg/L 01/24/16 13:465.0SM 2320B
Alkalinity, Total as CaCO3 32.4 mg/L 01/24/16 13:465.0SM 2320B
Chromium, Hexavalent 0.17 ug/L 01/20/16 20:040.030EPA 218.7
92283470008 2016001816
Alkalinity,Bicarbonate (CaCO3)29.5 mg/L 01/24/16 13:575.0SM 2320B
Alkalinity, Total as CaCO3 29.5 mg/L 01/24/16 13:575.0SM 2320B
Chromium, Hexavalent 0.48 ug/L 01/21/16 09:160.15EPA 218.7
92283470009 2016001817
Alkalinity,Bicarbonate (CaCO3)6.3 mg/L 01/24/16 14:275.0SM 2320B
Alkalinity, Total as CaCO3 6.3 mg/L 01/24/16 14:275.0SM 2320B
Chromium, Hexavalent 0.091 ug/L 01/20/16 20:300.030EPA 218.7
92283470010 2016001818
Alkalinity,Bicarbonate (CaCO3)98.6 mg/L 01/24/16 14:385.0SM 2320B
Alkalinity, Total as CaCO3 98.6 mg/L 01/24/16 14:385.0SM 2320B
Chromium, Hexavalent 0.15 ug/L 01/20/16 20:430.030EPA 218.7
92283470011 2016001819
Alkalinity,Bicarbonate (CaCO3)70.4 mg/L 01/24/16 14:495.0SM 2320B
Alkalinity, Total as CaCO3 70.4 mg/L 01/24/16 14:495.0SM 2320B
92283470012 2016001820
Alkalinity,Bicarbonate (CaCO3)5.5 mg/L 01/24/16 15:005.0SM 2320B
Alkalinity, Total as CaCO3 5.5 mg/L 01/24/16 15:005.0SM 2320B
Chromium, Hexavalent 0.87 ug/L 01/21/16 09:290.15EPA 218.7
92283470013 2016001821
Alkalinity,Bicarbonate (CaCO3)7.7 mg/L 01/24/16 15:105.0SM 2320B
Alkalinity, Total as CaCO3 7.7 mg/L 01/24/16 15:105.0SM 2320B
Chromium, Hexavalent 0.091 ug/L 01/20/16 22:400.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 6 of 39
Page 40 of 74
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92283470
J16010355
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92283470014 2016001822
Alkalinity,Bicarbonate (CaCO3)36.3 mg/L 01/24/16 15:405.0SM 2320B
Alkalinity, Total as CaCO3 36.3 mg/L 01/24/16 15:405.0SM 2320B
92283470015 2016001823
Alkalinity,Bicarbonate (CaCO3)10.3 mg/L 01/24/16 15:505.0SM 2320B
Alkalinity, Total as CaCO3 10.3 mg/L 01/24/16 15:505.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
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Page 7 of 39
Page 41 of 74
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283470
J16010355
Method:
Client:Duke Energy
RSK 175
Date:January 26, 2016
Description:RSK 175 AIR Headspace
General Information:
15 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 42 of 74
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283470
J16010355
Method:
Client:Duke Energy
SM 2320B
Date:January 26, 2016
Description:2320B Alkalinity
General Information:
15 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/42615
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35224916005,35224916019
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1651483)
• Alkalinity, Total as CaCO3
• MS (Lab ID: 1651485)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1651484)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1651486)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 9 of 39
Page 43 of 74
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283470
J16010355
Method:
Client:Duke Energy
SM 4500-S2D
Date:January 26, 2016
Description:4500S2D Sulfide Water
General Information:
15 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 39
Page 44 of 74
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92283470
J16010355
Method:
Client:Duke Energy
EPA 218.7
Date:January 26, 2016
Description:Hexavalent Chromium by IC
General Information:
15 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Page 45 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001809 Lab ID:92283470001 Collected:01/18/16 16:01 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 1100 ug/L 01/21/16 15:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)36.4 mg/L 01/21/16 22:475.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/21/16 22:475.0 1
Alkalinity, Total as CaCO3 36.4 mg/L 01/21/16 22:475.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 18:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 39
Page 46 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001810 Lab ID:92283470002 Collected:01/18/16 14:04 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 15:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.0 mg/L 01/21/16 22:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/21/16 22:575.0 1
Alkalinity, Total as CaCO3 10.0 mg/L 01/21/16 22:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 18:59 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 39
Page 47 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001811 Lab ID:92283470003 Collected:01/18/16 12:08 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 15:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 12:435.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 12:435.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 12:435.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.57 ug/L 01/21/16 09:03 18540-29-90.15 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 39
Page 48 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001812 Lab ID:92283470004 Collected:01/18/16 11:21 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 15:36 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.7 mg/L 01/24/16 13:175.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 13:175.0 1
Alkalinity, Total as CaCO3 15.7 mg/L 01/24/16 13:175.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 19:25 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 39
Page 49 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001813 Lab ID:92283470005 Collected:01/18/16 16:23 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 15:44 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 13:285.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 13:285.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 13:285.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.034 ug/L 01/20/16 19:38 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 39
Page 50 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001814 Lab ID:92283470006 Collected:01/18/16 15:25 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 16:30 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 01/24/16 13:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 13:375.0 1
Alkalinity, Total as CaCO3 ND mg/L 01/24/16 13:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 19:51 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 39
Page 51 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001815 Lab ID:92283470007 Collected:01/18/16 14:27 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 16:47 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)32.4 mg/L 01/24/16 13:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 13:465.0 1
Alkalinity, Total as CaCO3 32.4 mg/L 01/24/16 13:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.17 ug/L 01/20/16 20:04 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 39
Page 52 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001816 Lab ID:92283470008 Collected:01/18/16 13:22 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 16:55 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)29.5 mg/L 01/24/16 13:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 13:575.0 1
Alkalinity, Total as CaCO3 29.5 mg/L 01/24/16 13:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.48 ug/L 01/21/16 09:16 18540-29-90.15 5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 39
Page 53 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001817 Lab ID:92283470009 Collected:01/18/16 12:18 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 17:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)6.3 mg/L 01/24/16 14:275.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 14:275.0 1
Alkalinity, Total as CaCO3 6.3 mg/L 01/24/16 14:275.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.091 ug/L 01/20/16 20:30 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 39
Page 54 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001818 Lab ID:92283470010 Collected:01/18/16 10:35 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 17:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)98.6 mg/L 01/24/16 14:385.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 14:385.0 1
Alkalinity, Total as CaCO3 98.6 mg/L 01/24/16 14:385.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 15:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.15 ug/L 01/20/16 20:43 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 39
Page 55 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001819 Lab ID:92283470011 Collected:01/18/16 15:56 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 17:20 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)70.4 mg/L 01/24/16 14:495.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 14:495.0 1
Alkalinity, Total as CaCO3 70.4 mg/L 01/24/16 14:495.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 16:02 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 21:48 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 39
Page 56 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001820 Lab ID:92283470012 Collected:01/18/16 15:09 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 17:28 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)5.5 mg/L 01/24/16 15:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 15:005.0 1
Alkalinity, Total as CaCO3 5.5 mg/L 01/24/16 15:005.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 16:02 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.87 ug/L 01/21/16 09:29 18540-29-90.15 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 39
Page 57 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001821 Lab ID:92283470013 Collected:01/18/16 14:51 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 17:36 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.7 mg/L 01/24/16 15:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 15:105.0 1
Alkalinity, Total as CaCO3 7.7 mg/L 01/24/16 15:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 16:02 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.091 ug/L 01/20/16 22:40 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 39
Page 58 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001822 Lab ID:92283470014 Collected:01/18/16 11:35 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 17:44 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)36.3 mg/L 01/24/16 15:405.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 15:405.0 1
Alkalinity, Total as CaCO3 36.3 mg/L 01/24/16 15:405.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 16:02 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 22:53 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 39
Page 59 of 74
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92283470
J16010355
Sample:2016001823 Lab ID:92283470015 Collected:01/18/16 10:44 Received:01/19/16 13:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 01/21/16 18:09 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.3 mg/L 01/24/16 15:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 01/24/16 15:505.0 1
Alkalinity, Total as CaCO3 10.3 mg/L 01/24/16 15:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 01/20/16 16:02 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 01/20/16 23:06 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 39
Page 60 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25052
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283470001, 92283470002, 92283470003, 92283470004, 92283470005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2177725
Associated Lab Samples:92283470001, 92283470002, 92283470003, 92283470004, 92283470005
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/21/16 12:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2177726LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2177727
Methane ug/L 60.260.7 99 85-11510060.6 1 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10336339019
2178902SAMPLE DUPLICATE:
Methane ug/L 3.1J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283352007
2178903SAMPLE DUPLICATE:
Methane ug/L 2010 2 201970
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 39
Page 61 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25065
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92283470006, 92283470007, 92283470008, 92283470009, 92283470010, 92283470011, 92283470012,
92283470013, 92283470014, 92283470015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2178463
Associated Lab Samples:92283470006, 92283470007, 92283470008, 92283470009, 92283470010, 92283470011, 92283470012,
92283470013, 92283470014, 92283470015
Matrix:Water
Analyzed
Methane ug/L ND 10.0 01/21/16 16:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2178464LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2178465
Methane ug/L 60.660.7 100 85-11510261.6 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283470006
2179324SAMPLE DUPLICATE:
Methane ug/L 2J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92283470015
2179325SAMPLE DUPLICATE:
Methane ug/L 1.4J 20ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 39
Page 62 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42615
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92283470001, 92283470002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1651481
Associated Lab Samples:92283470001, 92283470002
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/21/16 17:12
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/21/16 17:12
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/21/16 17:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1651482LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.050 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1651483MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35224916005
1651484
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15099780-120989 1 2550215714710
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1651485MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35224916019
1651486
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M15099780-1201010 1 2550246744749
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 39
Page 63 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42616
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008, 92283470009,
92283470010, 92283470011, 92283470012, 92283470013, 92283470014, 92283470015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1651489
Associated Lab Samples:92283470003, 92283470004, 92283470005, 92283470006, 92283470007, 92283470008, 92283470009,
92283470010, 92283470011, 92283470012, 92283470013, 92283470014, 92283470015
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 01/24/16 12:21
Alkalinity, Total as CaCO3 mg/L ND 5.0 01/24/16 12:21
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 01/24/16 12:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1651490LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.850 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1651491MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283470003
1651492
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND53.1 53.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1651493MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283470013
1651494
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12096 1 25507.7 56.3 55.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 39
Page 64 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42590
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92283470001, 92283470002, 92283470003, 92283470004, 92283470005, 92283470006, 92283470007,
92283470008, 92283470009, 92283470010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1650677
Associated Lab Samples:92283470001, 92283470002, 92283470003, 92283470004, 92283470005, 92283470006, 92283470007,
92283470008, 92283470009, 92283470010
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/20/16 15:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1650678LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1650679MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283352001
1650680
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 98 90-11098 0 10.5ND 0.49 0.49
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1650681MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283470001
1650682
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 109 90-110109 0 10.5ND 0.54 0.54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 39
Page 65 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/42591
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92283470011, 92283470012, 92283470013, 92283470014, 92283470015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1650684
Associated Lab Samples:92283470011, 92283470012, 92283470013, 92283470014, 92283470015
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 01/20/16 16:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1650685LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1650686MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283470011
1650687
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 93 90-11093 0 10.5ND 0.55 0.55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/54049
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92283470001, 92283470002, 92283470003, 92283470004, 92283470005, 92283470006, 92283470007,
92283470008, 92283470009, 92283470010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1453501
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/20/16 13:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1453502LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.067.075 89 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1453503MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283352001
1453504
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 83 85-11578 4 20.025ND 0.035 0.034
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1453505MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283470001
1453506
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 109 85-11590 20 20.075ND 0.082 0.067
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 39
Page 67 of 74
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92283470
J16010355
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/54056
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92283470011, 92283470012, 92283470013, 92283470014, 92283470015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1453816
Associated Lab Samples:
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 01/20/16 21:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1453817LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.079.075 105 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1453818MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92283470011
1453819
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 91 85-11598 7 20.075ND 0.068 0.073
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 39
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92283470
J16010355
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 39
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283470
J16010355
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283470001 AIR/250522016001809RSK 175
92283470002 AIR/250522016001810RSK 175
92283470003 AIR/250522016001811RSK 175
92283470004 AIR/250522016001812RSK 175
92283470005 AIR/250522016001813RSK 175
92283470006 AIR/250652016001814RSK 175
92283470007 AIR/250652016001815RSK 175
92283470008 AIR/250652016001816RSK 175
92283470009 AIR/250652016001817RSK 175
92283470010 AIR/250652016001818RSK 175
92283470011 AIR/250652016001819RSK 175
92283470012 AIR/250652016001820RSK 175
92283470013 AIR/250652016001821RSK 175
92283470014 AIR/250652016001822RSK 175
92283470015 AIR/250652016001823RSK 175
92283470001 WET/426152016001809SM 2320B
92283470002 WET/426152016001810SM 2320B
92283470003 WET/426162016001811SM 2320B
92283470004 WET/426162016001812SM 2320B
92283470005 WET/426162016001813SM 2320B
92283470006 WET/426162016001814SM 2320B
92283470007 WET/426162016001815SM 2320B
92283470008 WET/426162016001816SM 2320B
92283470009 WET/426162016001817SM 2320B
92283470010 WET/426162016001818SM 2320B
92283470011 WET/426162016001819SM 2320B
92283470012 WET/426162016001820SM 2320B
92283470013 WET/426162016001821SM 2320B
92283470014 WET/426162016001822SM 2320B
92283470015 WET/426162016001823SM 2320B
92283470001 WET/425902016001809SM 4500-S2D
92283470002 WET/425902016001810SM 4500-S2D
92283470003 WET/425902016001811SM 4500-S2D
92283470004 WET/425902016001812SM 4500-S2D
92283470005 WET/425902016001813SM 4500-S2D
92283470006 WET/425902016001814SM 4500-S2D
92283470007 WET/425902016001815SM 4500-S2D
92283470008 WET/425902016001816SM 4500-S2D
92283470009 WET/425902016001817SM 4500-S2D
92283470010 WET/425902016001818SM 4500-S2D
92283470011 WET/425912016001819SM 4500-S2D
92283470012 WET/425912016001820SM 4500-S2D
92283470013 WET/425912016001821SM 4500-S2D
92283470014 WET/425912016001822SM 4500-S2D
92283470015 WET/425912016001823SM 4500-S2D
92283470001 WETA/540492016001809EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 39
Page 70 of 74
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92283470
J16010355
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92283470002 WETA/540492016001810EPA 218.7
92283470003 WETA/540492016001811EPA 218.7
92283470004 WETA/540492016001812EPA 218.7
92283470005 WETA/540492016001813EPA 218.7
92283470006 WETA/540492016001814EPA 218.7
92283470007 WETA/540492016001815EPA 218.7
92283470008 WETA/540492016001816EPA 218.7
92283470009 WETA/540492016001817EPA 218.7
92283470010 WETA/540492016001818EPA 218.7
92283470011 WETA/540562016001819EPA 218.7
92283470012 WETA/540562016001820EPA 218.7
92283470013 WETA/540562016001821EPA 218.7
92283470014 WETA/540562016001822EPA 218.7
92283470015 WETA/540562016001823EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 01/26/2016 11:42 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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