NC0000396_App B Lab Reports - CAMA BKGD - J16070325report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070325
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:8/2/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Page 1 of 75
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016021445 ASHEVILLE 12-Jul-16 10:30 AM illegible MW-18BRL
2016021446 ASHEVILLE 12-Jul-16 9:05 AM illegible MW-17A
2016021447 ASHEVILLE 12-Jul-16 2:04 PM illegible CB-9BR
2016021448 ASHEVILLE 12-Jul-16 2:04 PM illegible CB-9BR Dup
2016021449 ASHEVILLE 12-Jul-16 1:50 PM illegible Filter Blank
2016021450 ASHEVILLE 12-Jul-16 1:50 PM illegible Equipment Blank
6 Total Samples
Page 2 of 75
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:8/2/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021445
Collection Date:12-Jul-16 10:30 AM
Site:MW-18BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.012 mg-N/L EPA 353.2 07/18/2016 13:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 9.4 mg/L EPA 300.0 07/14/2016 21:50 BGN9034110
Sulfate 260 mg/L EPA 300.0 07/14/2016 21:50 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 13:51 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/18/2016 15:49 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.007 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.005 1
Barium (Ba)0.021 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.005 1
Boron (B)0.081 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.01 1
Manganese (Mn)0.407 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.005 1
Strontium (Sr)0.354 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/14/2016 13:40 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)93.2 mg/L EPA 200.7 07/19/2016 13:32 JJMACKE0.01 1
Magnesium (Mg)6.26 mg/L EPA 200.7 07/19/2016 13:32 JJMACKE0.005 1
Potassium (K)7.92 mg/L EPA 200.7 07/19/2016 13:32 JJMACKE0.1 1
Sodium (Na)26.9 mg/L EPA 200.7 07/19/2016 13:32 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.053 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.005 1
Barium (Ba)0.029 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.005 1
Boron (B)0.077 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.05 1
Iron (Fe)0.016 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.01 1
Manganese (Mn)0.387 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.005 1
Strontium (Sr)0.350 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 12:32 JJMACKE0.005 1
Page 4 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021445
Collection Date:12-Jul-16 10:30 AM
Site:MW-18BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Arsenic (As)1.21 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Copper (Cu)6.97 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Molybdenum (Mo)4.25 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Nickel (Ni)1.82 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN30.2 1
Vanadium (V) Low Level 1.84 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Arsenic (As)1.20 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Molybdenum (Mo)4.17 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Nickel (Ni)1.50 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN30.2 1
Vanadium (V) Low Level 1.74 ug/L EPA 200.8 07/15/2016 04:20 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 460 mg/L SM2540C 07/18/2016 14:26 PARMSTR501
Page 5 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021445
Collection Date:12-Jul-16 10:30 AM
Site:MW-18BRL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 4.0 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Page 6 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021446
Collection Date:12-Jul-16 9:05 AM
Site:MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.016 mg-N/L EPA 353.2 07/18/2016 13:34 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 430 mg/L EPA 300.0 07/14/2016 23:02 BGN903410100
Sulfate 190 mg/L EPA 300.0 07/14/2016 23:02 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 13:54 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)208 mg/L EPA 200.7 07/19/2016 13:36 JJMACKE0.1 10
Magnesium (Mg)63.3 mg/L EPA 200.7 07/19/2016 13:36 JJMACKE0.05 10
Potassium (K)4.53 mg/L EPA 200.7 07/19/2016 13:36 JJMACKE0.1 1
Sodium (Na)14.8 mg/L EPA 200.7 07/19/2016 13:36 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.119 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.005 1
Barium (Ba)0.127 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.005 1
Boron (B)2.47 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.05 1
Iron (Fe)35.5 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.01 1
Manganese (Mn)5.04 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.005 1
Strontium (Sr)0.648 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 13:04 JJMACKE0.005 1
Page 7 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021446
Collection Date:12-Jul-16 9:05 AM
Site:MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Arsenic (As)1.26 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Cobalt (Co)17.0 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Nickel (Ni)3.61 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 12:28 CWSPEN30.3 1
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 1300 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Total Carbon
TOC 1.6 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 7.8 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Page 8 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021447
Collection Date:12-Jul-16 2:04 PM
Site:CB-9BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.131 mg-N/L EPA 353.2 07/18/2016 13:35 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.4 mg/L EPA 300.0 07/14/2016 23:25 BGN90340.1 1
Sulfate 1.3 mg/L EPA 300.0 07/14/2016 23:25 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 13:56 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/18/2016 15:58 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.01 1
Manganese (Mn)0.039 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.005 1
Strontium (Sr)0.064 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 13:44 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.24 mg/L EPA 200.7 07/19/2016 13:39 JJMACKE0.01 1
Magnesium (Mg)3.08 mg/L EPA 200.7 07/19/2016 13:39 JJMACKE0.005 1
Potassium (K)2.31 mg/L EPA 200.7 07/19/2016 13:39 JJMACKE0.1 1
Sodium (Na)4.27 mg/L EPA 200.7 07/19/2016 13:39 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.107 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.005 1
Barium (Ba)0.025 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.05 1
Iron (Fe)0.236 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.01 1
Manganese (Mn)0.043 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.005 1
Strontium (Sr)0.065 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 13:08 JJMACKE0.005 1
Page 9 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021447
Collection Date:12-Jul-16 2:04 PM
Site:CB-9BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Chromium (Cr)1.50 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Nickel (Ni)1.69 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN30.2 1
Vanadium (V) Low Level 0.318 ug/L EPA 200.8 07/15/2016 04:26 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 67 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Page 10 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021447
Collection Date:12-Jul-16 2:04 PM
Site:CB-9BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.238 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Page 11 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021448
Collection Date:12-Jul-16 2:04 PM
Site:CB-9BR Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.131 mg-N/L EPA 353.2 07/18/2016 13:41 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.4 mg/L EPA 300.0 07/14/2016 23:41 BGN90340.1 1
Sulfate 1.3 mg/L EPA 300.0 07/14/2016 23:41 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 14:30 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/18/2016 16:01 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.005 1
Barium (Ba)0.023 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.01 1
Manganese (Mn)0.040 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.005 1
Strontium (Sr)0.064 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 07/14/2016 14:01 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.70 mg/L EPA 200.7 07/19/2016 13:43 JJMACKE0.01 1
Magnesium (Mg)2.99 mg/L EPA 200.7 07/19/2016 13:43 JJMACKE0.005 1
Potassium (K)2.34 mg/L EPA 200.7 07/19/2016 13:43 JJMACKE0.1 1
Sodium (Na)3.47 mg/L EPA 200.7 07/19/2016 13:43 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.096 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.005 1
Barium (Ba)0.025 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.05 1
Iron (Fe)0.214 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.01 1
Manganese (Mn)0.042 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.005 1
Strontium (Sr)0.065 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 13:12 JJMACKE0.005 1
Page 12 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021448
Collection Date:12-Jul-16 2:04 PM
Site:CB-9BR Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Copper (Cu)8.07 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Lead (Pb)1.11 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Chromium (Cr)1.85 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Nickel (Ni)1.85 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 04:33 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 83 mg/L SM2540C 07/18/2016 14:26 PARMSTR251
Page 13 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021448
Collection Date:12-Jul-16 2:04 PM
Site:CB-9BR Dup
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.221 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Page 14 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021449
Collection Date:12-Jul-16 1:50 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/18/2016 16:03 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 14:12 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Copper (Cu)2.81 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/14/2016 21:24 CWSPEN30.3 1
Page 15 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021450
Collection Date:12-Jul-16 1:50 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/18/2016 13:45 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/26/2016 12:38 BGN90340.1 1
Sulfate 0.40 mg/L EPA 300.0 07/26/2016 12:38 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 14:32 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 07/19/2016 13:49 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/19/2016 13:49 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/19/2016 13:49 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 07/19/2016 13:49 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/23/2016 13:15 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 04:39 CWSPEN30.3 1
Page 16 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
2016021450
Collection Date:12-Jul-16 1:50 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.228 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/18/2016 09:55 PARMSTR51
Page 17 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0016 mg-N/L -1-0.0016 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0007 mg-N/L -1-0.0007 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0005 mg-N/L -10.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 4
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0009 mg-N/L -10.0009 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 99.9mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.301 3.01 99.9mg-N/L -11090103.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 99mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 4
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.296 3.01 98.2mg-N/L -11090102.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060271 -- 2016016749
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 101mg-N/L -1109010.253
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060271 -- 2016016749
Nitrite + Nitrate
(Colorimetric)
0.253 0.25 101 0.278mg-N/L -1109010.253
Page 18 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070429 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070367 -- 2016021651
Nitrite + Nitrate
(Colorimetric)
0.258 0.25 102mg-N/L -1109010.258
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070367 -- 2016021651
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101 0.709mg-N/L -1109010.256
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Nitrite + Nitrate
(Colorimetric)
0.364 0.25 93.4mg-N/L -1109010.364
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Nitrite + Nitrate
(Colorimetric)
0.366 0.25 94.2 0.853mg-N/L -1109010.366
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070132 -- 2016021202
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101mg-N/L -1109010.256
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070132 -- 2016021202
Nitrite + Nitrate
(Colorimetric)
0.256 0.25 101 0.0395mg-N/L -1109010.256
Page 19 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070340 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride -0.0034 mg/L -1-0.0034 0.1 < 1/2 RDL
Sulfate -0.0384 mg/L -1-0.0384 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Chloride 4.29 mg/L -14.29 0.1
Sulfate 1.91 mg/L -11.91 0.1
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 9.09 5 96.1mg/L -1208019.09
Sulfate 6.71 5 96.1mg/L -1208016.71
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 9.1 5 96.3 0.179mg/L -1208019.1
Sulfate 6.71 5 96.1 0.0166mg/L -1208016.71
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.25 5 105mg/L -1208015.25
Sulfate 5.23 5 105mg/L -1208015.23
Page 20 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070552 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Mercury (Hg) 0.0922 ug/L -201.84 0.05
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 2
Mercury (Hg) 0.0171 ug/L -200.343 0.05
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.953 20 86ug/L -130702019.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.951 20 85.9 0.175ug/L -130702019
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.941 20 92.4ug/L -130702018.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.949 20 93.1 0.809ug/L -130702019
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.97 2 98.3ug/L -1158511.97
Page 21 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070437 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Mercury (Hg) 0.012 ug/L -10.012 0.05
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.04 1 103ug/L -1307011.04
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1.01 1 100 2.47ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 2.02 2 101ug/L -1158512.02
Page 22 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000029 mg/L -10.000029 0.005 < 1/2 RDL
Barium (Ba) 0.00006 mg/L -10.00006 0.005 < 1/2 RDL
Boron (B) 0.000281 mg/L -10.000281 0.05 < 1/2 RDL
Iron (Fe) -0.000508 mg/L -1-0.000508 0.01 < 1/2 RDL
Manganese (Mn) -0.000329 mg/L -1-0.000329 0.005 < 1/2 RDL
Strontium (Sr) 0.000134 mg/L -10.000134 0.005 < 1/2 RDL
Zinc (Zn) -0.000785 mg/L -1-0.000785 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) -0.000007 mg/L -1-0.000007 0.005 < 1/2 RDL
Barium (Ba) 0.000039 mg/L -10.000039 0.005 < 1/2 RDL
Boron (B) 0.00088 mg/L -10.00088 0.05 < 1/2 RDL
Iron (Fe) -0.000931 mg/L -1-0.000931 0.01 < 1/2 RDL
Manganese (Mn) -0.000163 mg/L -1-0.000163 0.005 < 1/2 RDL
Strontium (Sr) 0.000104 mg/L -10.000104 0.005 < 1/2 RDL
Zinc (Zn) -0.000664 mg/L -1-0.000664 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.09 2 105mg/L -1158512.09
Barium (Ba) 0.985 1 98.5mg/L -1158510.985
Boron (B) 1.98 2 99.2mg/L -1158511.98
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.982 1 98.2mg/L -1158510.982
Strontium (Sr) 1.91 2 95.5mg/L -1158511.91
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.1 2 105mg/L -1158512.1
Barium (Ba) 0.991 1 99.1mg/L -1158510.991
Boron (B) 2.01 2 100mg/L -1158512.01
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.989 1 98.9mg/L -1158510.989
Strontium (Sr) 1.92 2 96.2mg/L -1158511.92
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Aluminum (Al) 5.53 5 109mg/L -1307015.53
Page 23 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Barium (Ba) 5.26 5 104mg/L -1307015.26
Boron (B) 10.7 5 93.7mg/L -13070110.7
Iron (Fe) 5.3 5 101mg/L -1307015.3
Manganese (Mn) 7.89 5 96.8mg/L -1307017.89
Strontium (Sr) 7.3 5 102mg/L -1307017.3
Zinc (Zn) 5.21 5 104mg/L -1307015.21
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Aluminum (Al) 5.63 5 111 1.83mg/L -1307015.63
Barium (Ba) 5.35 5 105 1.65mg/L -1307015.35
Boron (B) 10.9 5 97.5 4mg/L -13070110.9
Iron (Fe) 5.39 5 103 1.86mg/L -1307015.39
Manganese (Mn) 8.03 5 99.5 2.77mg/L -1307018.03
Strontium (Sr) 7.37 5 104 1.32mg/L -1307017.37
Zinc (Zn) 5.29 5 106 1.64mg/L -1307015.29
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.43 5 108mg/L -1307015.43
Barium (Ba) 5.17 5 103mg/L -1307015.17
Boron (B) 5.11 5 102mg/L -1307015.11
Iron (Fe) 5.69 5 99.5mg/L -1307015.69
Manganese (Mn) 5.57 5 105mg/L -1307015.57
Strontium (Sr) 5.35 5 99.9mg/L -1307015.35
Zinc (Zn) 5.13 5 103mg/L -1307015.13
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.52 5 110 1.74mg/L -1307015.52
Barium (Ba) 5.27 5 105 2.02mg/L -1307015.27
Boron (B) 5.22 5 104 2.23mg/L -1307015.22
Iron (Fe) 5.81 5 102 2.32mg/L -1307015.81
Manganese (Mn) 5.67 5 107 1.98mg/L -1307015.67
Strontium (Sr) 5.43 5 102 1.71mg/L -1307015.43
Zinc (Zn) 5.24 5 105 2.04mg/L -1307015.24
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Aluminum (Al) 5.52 5 110mg/L -1307015.52
Barium (Ba) 5.23 5 104mg/L -1307015.23
Page 24 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Boron (B) 5.09 5 102mg/L -1307015.09
Iron (Fe) 5.09 5 102mg/L -1307015.09
Manganese (Mn) 5.4 5 107mg/L -1307015.4
Strontium (Sr) 5.08 5 100mg/L -1307015.08
Zinc (Zn) 5.29 5 106mg/L -1307015.29
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Aluminum (Al) 5.52 5 110 0.0725mg/L -1307015.52
Barium (Ba) 5.24 5 104 0.211mg/L -1307015.24
Boron (B) 5.11 5 102 0.294mg/L -1307015.11
Iron (Fe) 5.12 5 102 0.431mg/L -1307015.12
Manganese (Mn) 5.42 5 108 0.41mg/L -1307015.42
Strontium (Sr) 5.09 5 101 0.139mg/L -1307015.09
Zinc (Zn) 5.31 5 106 0.246mg/L -1307015.31
Page 25 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.00129 mg/L -10.00129 0.01 < 1/2 RDL
Magnesium (Mg) 0.000115 mg/L -10.000115 0.005 < 1/2 RDL
Potassium (K) -0.00152 mg/L -1-0.00152 0.1 < 1/2 RDL
Sodium (Na) -0.00992 mg/L -1-0.00992 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.00148 mg/L -10.00148 0.01 < 1/2 RDL
Magnesium (Mg) 0.000217 mg/L -10.000217 0.005 < 1/2 RDL
Potassium (K) 0.00492 mg/L -10.00492 0.1 < 1/2 RDL
Sodium (Na) -0.0117 mg/L -1-0.0117 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.6mg/L -1158513.98
Sodium (Na) 8.38 8.1 103mg/L -1158518.38
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.14 2 107mg/L -1158512.14
Magnesium (Mg) 2.08 2 104mg/L -1158512.08
Potassium (K) 4.21 4 105mg/L -1158514.21
Sodium (Na) 8.85 8.1 109mg/L -1158518.85
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Calcium (Ca) 104 5 0mg/L -130701104
Magnesium (Mg) 21.2 5 88.2mg/L -13070121.2
Potassium (K) 15.9 5 93.2mg/L -13070115.9
Sodium (Na) 38.3 5 106mg/L -13070138.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Calcium (Ca) 104 5 204 200mg/L -130701104
Magnesium (Mg) 21.1 5 88 0.25mg/L -13070121.1
Potassium (K) 16 5 94 0.876mg/L -13070116
Sodium (Na) 38.3 5 107 0.981mg/L -13070138.3
Page 26 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070475 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Calcium (Ca) 19.1 5 93.9mg/L -13070119.1
Magnesium (Mg) 7.69 5 104mg/L -1307017.69
Potassium (K) 10.1 5 98.1mg/L -13070110.1
Sodium (Na) 51.5 5 71.7mg/L -13070151.5
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021340
Calcium (Ca) 19.3 5 97.7 3.97mg/L -13070119.3
Magnesium (Mg) 7.78 5 105 1.66mg/L -1307017.78
Potassium (K) 10.2 5 101 3.07mg/L -13070110.2
Sodium (Na) 52.1 5 83.3 14.9mg/L -13070152.1
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Calcium (Ca) 25.9 5 102mg/L -13070125.9
Magnesium (Mg) 7.35 5 113mg/L -1307017.35
Potassium (K) 12.9 5 102mg/L -13070112.9
Sodium (Na) 22.6 5 107mg/L -13070122.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070378 -- 2016021704
Calcium (Ca) 26 5 104 1.61mg/L -13070126
Magnesium (Mg) 7.39 5 114 0.671mg/L -1307017.39
Potassium (K) 13 5 104 1.83mg/L -13070113
Sodium (Na) 22.8 5 110 2.73mg/L -13070122.8
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Calcium (Ca) 65.4 5 83.2mg/L -13070165.4
Magnesium (Mg) 18.6 5 95.7mg/L -13070118.6
Potassium (K) 11 5 110mg/L -13070111
Sodium (Na) 25.6 5 103mg/L -13070125.6
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Calcium (Ca) 65.8 5 91 8.91mg/L -13070165.8
Magnesium (Mg) 18.6 5 96.6 1.02mg/L -13070118.6
Potassium (K) 11 5 110 0.4mg/L -13070111
Sodium (Na) 25.7 5 105 1.9mg/L -13070125.7
Page 27 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070518 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00109 mg/L -10.00109 0.005 < 1/2 RDL
Barium (Ba) 0.000186 mg/L -10.000186 0.005 < 1/2 RDL
Boron (B) -0.000474 mg/L -1-0.000474 0.05 < 1/2 RDL
Iron (Fe) 0.000233 mg/L -10.000233 0.01 < 1/2 RDL
Manganese (Mn) -0.000141 mg/L -1-0.000141 0.005 < 1/2 RDL
Strontium (Sr) 0.000099 mg/L -10.000099 0.005 < 1/2 RDL
Zinc (Zn) 0.000136 mg/L -10.000136 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.47 5 109mg/L -1158515.47
Barium (Ba) 4.99 5 99.7mg/L -1158514.99
Boron (B) 4.98 5 99.6mg/L -1158514.98
Iron (Fe) 4.93 5 98.6mg/L -1158514.93
Manganese (Mn) 5.16 5 103mg/L -1158515.16
Strontium (Sr) 4.94 5 98.8mg/L -1158514.94
Zinc (Zn) 5.03 5 101mg/L -1158515.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021445
Aluminum (Al) 5.4 5 107mg/L -1307015.4
Barium (Ba) 5 5 99.5mg/L -1307015
Boron (B) 5.08 5 100mg/L -1307015.08
Iron (Fe) 4.91 5 97.8mg/L -1307014.91
Manganese (Mn) 5.46 5 101mg/L -1307015.46
Strontium (Sr) 5.25 5 98.1mg/L -1307015.25
Zinc (Zn) 4.86 5 97.1mg/L -1307014.86
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021445
Aluminum (Al) 5.49 5 109 1.65mg/L -1307015.49
Barium (Ba) 5.08 5 101 1.59mg/L -1307015.08
Boron (B) 5.18 5 102 1.96mg/L -1307015.18
Iron (Fe) 4.98 5 99.2 1.42mg/L -1307014.98
Manganese (Mn) 5.54 5 103 1.49mg/L -1307015.54
Strontium (Sr) 5.33 5 99.6 1.54mg/L -1307015.33
Zinc (Zn) 4.91 5 98.2 1.09mg/L -1307014.91
Page 28 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070304 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.091 ug/L -1-0.091 1 < 1/2 RDL
Arsenic (As) 0.0151 ug/L -10.0151 1 < 1/2 RDL
Beryllium (Be) 0.0675 ug/L -10.0675 1 < 1/2 RDL
Cadmium (Cd) 0.0121 ug/L -10.0121 1 < 1/2 RDL
Chromium (Cr) -0.0814 ug/L -1-0.0814 1 < 1/2 RDL
Cobalt (Co) 0.0099 ug/L -10.0099 1 < 1/2 RDL
Copper (Cu) -0.11 ug/L -1-0.11 1 < 1/2 RDL
Lead (Pb) 0.0068 ug/L -10.0068 1 < 1/2 RDL
Molybdenum (Mo) 0.0034 ug/L -10.0034 1 < 1/2 RDL
Nickel (Ni) -0.0029 ug/L -1-0.0029 1 < 1/2 RDL
Selenium (Se) -0.081 ug/L -1-0.081 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0346 ug/L -1-0.0346 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0426 ug/L -10.0426 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 52.3 50 105ug/L -11585152.3
Arsenic (As) 51.1 50 102ug/L -11585151.1
Beryllium (Be) 50 50 100ug/L -11585150
Cadmium (Cd) 51.4 50 103ug/L -11585151.4
Chromium (Cr) 51.8 50 104ug/L -11585151.8
Cobalt (Co) 50.7 50 101ug/L -11585150.7
Copper (Cu) 50.7 50 101ug/L -11585150.7
Lead (Pb) 52 50 104ug/L -11585152
Molybdenum (Mo) 51.7 50 103ug/L -11585151.7
Nickel (Ni) 51.4 50 103ug/L -11585151.4
Selenium (Se) 49.1 50 98.1ug/L -11585149.1
Thallium (Tl) Low Level 49.6 50 99.1ug/L -11585149.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Antimony (Sb) 51.8 50 103ug/L -13070151.8
Arsenic (As) 50.6 50 101ug/L -13070150.6
Beryllium (Be) 55.5 50 111ug/L -13070155.5
Cadmium (Cd) 50 50 100ug/L -13070150
Chromium (Cr) 51.6 50 102ug/L -13070151.6
Cobalt (Co) 49.8 50 96.7ug/L -13070149.8
Copper (Cu) 48.9 50 97.5ug/L -13070148.9
Lead (Pb) 50.8 50 101ug/L -13070150.8
Molybdenum (Mo) 54.2 50 102ug/L -13070154.2
Page 29 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070304 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Nickel (Ni) 53.3 50 97.7ug/L -13070153.3
Selenium (Se) 48.2 50 96.5ug/L -13070148.2
Thallium (Tl) Low Level 48.4 50 96.8ug/L -13070148.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Antimony (Sb) 52.5 50 104 1.42ug/L -13070152.5
Arsenic (As) 51.2 50 102 1.23ug/L -13070151.2
Beryllium (Be) 54.1 50 108 2.64ug/L -13070154.1
Cadmium (Cd) 50.8 50 102 1.66ug/L -13070150.8
Chromium (Cr) 52 50 103 0.773ug/L -13070152
Cobalt (Co) 50.4 50 98 1.33ug/L -13070150.4
Copper (Cu) 49.4 50 98.5 1.04ug/L -13070149.4
Lead (Pb) 51.1 50 102 0.572ug/L -13070151.1
Molybdenum (Mo) 54.4 50 102 0.412ug/L -13070154.4
Nickel (Ni) 54.5 50 100 2.42ug/L -13070154.5
Selenium (Se) 48.8 50 97.8 1.3ug/L -13070148.8
Thallium (Tl) Low Level 49.5 50 99 2.25ug/L -13070149.5
Page 30 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0234 ug/L -1-0.0234 1 < 1/2 RDL
Arsenic (As) 0.0143 ug/L -10.0143 1 < 1/2 RDL
Beryllium (Be) 0.0062 ug/L -10.0062 1 < 1/2 RDL
Cadmium (Cd) 0.0007 ug/L -10.0007 1 < 1/2 RDL
Chromium (Cr) -0.0808 ug/L -1-0.0808 1 < 1/2 RDL
Cobalt (Co) 0.0068 ug/L -10.0068 1 < 1/2 RDL
Copper (Cu) -0.141 ug/L -1-0.141 1 < 1/2 RDL
Lead (Pb) 0.0024 ug/L -10.0024 1 < 1/2 RDL
Molybdenum (Mo) 0.0014 ug/L -10.0014 1 < 1/2 RDL
Nickel (Ni) -0.0172 ug/L -1-0.0172 1 < 1/2 RDL
Selenium (Se) -0.0861 ug/L -1-0.0861 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0237 ug/L -1-0.0237 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0239 ug/L -10.0239 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.4 50 101ug/L -11585150.4
Arsenic (As) 48.3 50 96.7ug/L -11585148.3
Beryllium (Be) 53.9 50 108ug/L -11585153.9
Cadmium (Cd) 49.7 50 99.4ug/L -11585149.7
Chromium (Cr) 51 50 102ug/L -11585151
Cobalt (Co) 48.2 50 96.4ug/L -11585148.2
Copper (Cu) 48.6 50 97.2ug/L -11585148.6
Lead (Pb) 50.3 50 101ug/L -11585150.3
Molybdenum (Mo) 49.8 50 99.7ug/L -11585149.8
Nickel (Ni) 48.3 50 96.5ug/L -11585148.3
Selenium (Se) 47.1 50 94.2ug/L -11585147.1
Thallium (Tl) Low Level 49.6 50 99.1ug/L -11585149.6
Vanadium (V) Low Level 50.5 50 101ug/L -11585150.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021446
Antimony (Sb) 51.5 50 103ug/L -13070151.5
Arsenic (As) 50.9 50 99.2ug/L -13070150.9
Beryllium (Be) 50.3 50 100ug/L -13070150.3
Cadmium (Cd) 48.7 50 97.3ug/L -13070148.7
Chromium (Cr) 50 50 99.4ug/L -13070150
Cobalt (Co) 63.1 50 92.3ug/L -13070163.1
Copper (Cu) 46.8 50 93.3ug/L -13070146.8
Lead (Pb) 50.1 50 100ug/L -13070150.1
Page 31 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021446
Molybdenum (Mo) 50.1 50 99.9ug/L -13070150.1
Nickel (Ni) 51.5 50 95.7ug/L -13070151.5
Selenium (Se) 48 50 96ug/L -13070148
Thallium (Tl) Low Level 44.8 50 89.6ug/L -13070144.8
Vanadium (V) Low Level 50.7 50 101ug/L -13070150.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021446
Antimony (Sb) 51.5 50 103 0.118ug/L -13070151.5
Arsenic (As) 51.1 50 99.6 0.412ug/L -13070151.1
Beryllium (Be) 49.6 50 98.6 1.55ug/L -13070149.6
Cadmium (Cd) 49.4 50 98.8 1.49ug/L -13070149.4
Chromium (Cr) 51.2 50 102 2.41ug/L -13070151.2
Cobalt (Co) 63.8 50 93.7 1.48ug/L -13070163.8
Copper (Cu) 47.3 50 94.4 1.15ug/L -13070147.3
Lead (Pb) 50.3 50 100 0.456ug/L -13070150.3
Molybdenum (Mo) 50.9 50 102 1.68ug/L -13070150.9
Nickel (Ni) 50.8 50 94.5 1.33ug/L -13070150.8
Selenium (Se) 48.2 50 96.4 0.383ug/L -13070148.2
Thallium (Tl) Low Level 46.9 50 93.9 4.66ug/L -13070146.9
Vanadium (V) Low Level 51.7 50 103 1.99ug/L -13070151.7
Page 32 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070415 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070325 -- 2016021447
TDS 4.38mg/L -170
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070325 -- 2016021448
TDS 4.94mg/L -179
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 102mg/L -110901102
Page 33 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070294 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.025 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.049 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
TOC mg/L -11.75 0.1
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 2
TOC mg/L -10.281 0.1
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 3
TOC mg/L -10.84 0.1
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 4
TOC mg/L -11.43 0.1
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 96.6mg/L -1208013.68
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 103 6.85mg/L -1208013.82
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208012.39
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 103 2.69mg/L -1208012.33
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 98.8mg/L -1208012.82
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 103 4.31mg/L -1208012.9
Page 34 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070294 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
IS # 4
% Recovery LCL UCLSpike
TOC 2 102mg/L -1208013.46
Final QualifierDilMeasuredUnits:Parameter
ISD # 4
RPD% Recovery LCL UCLSpike
TOC 2 99.3 2.29mg/L -1208013.41
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.92
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.93
Page 35 of 75
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070325
Q16070396 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060373 -- 2016017127
TSS 10.5mg/L -12
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060373 -- 2016017128
TSS 0mg/L -10
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 102mg/L -11090151.2
Page 36 of 75

July 29, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 401638
SDG: J16070325

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 14, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 15
Chelsea Seagle for
Page 37 of 75
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16070325 GEL Work Order: 401638
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 15
Page 38 of 75
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0936
0940
1534
1005
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401638001
Water
12-JUL-16 10:30
14-JUL-16
2016021445 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.818
0.474
1
2
3
4
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0241
ND
ND
ND
3.13
3.39
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"63.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 15
Page 39 of 75
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0938
0941
1534
1005
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401638002
Water
12-JUL-16 09:05
14-JUL-16
2016021446 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.996
0.471
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.96
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"54.8 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 15
Page 40 of 75
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0939
0943
1534
1005
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401638003
Water
12-JUL-16 14:04
14-JUL-16
2016021447 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.592
0.560
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
2.60
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"96 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 15
Page 41 of 75
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 29, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581994
1581994
1582445
1583317
0941
0944
1534
1035
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/28/16
07/29/16
07/28/16
07/27/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401638004
Water
12-JUL-16 14:04
14-JUL-16
2016021448 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.633
0.405
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.21
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"88.9 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/15/16 15819930642SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 15
Page 42 of 75
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1581994Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 29, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/29/16 09:21
07/28/16 09:20
07/28/16 09:05
07/29/16 08:20
07/29/16 08:18
07/28/16 09:04
07/28/16 09:22
07/29/16 09:23
07/29/16 09:24
QC
ND
ND
ND
0.000177
0.0535
0.00055
0.000545
0.00518
ND
ND
ND
ND
0.0526
0.000536
0.000547
0.00533
ND
NOM Sample
ND
ND
ND
0.000158
0.000158
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
J
U
U
U
U
U
QC1203585489 401636001
QC1203585487
QC1203585488
QC1203585486
QC1203585490 401636001
QC1203585491 401636001
QC1203585492 401636001
N/A
N/A
N/A
10.9
N/A
REC%
108
110
99.1
104
106
107
99.5
107
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
401638Workorder:
Mail Code: MGO3A2
U
U
U
J
J
U
U
U
U
^
RPD%
Page 1 of 3
Page 7 of 15
Page 43 of 75
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1581994
1582445
1583317
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
07/29/16 09:24
07/28/16 09:23
07/28/16 15:34
07/28/16 15:34
07/28/16 15:34
07/27/16 11:20
07/27/16 11:55
07/27/16 10:35
07/27/16 11:20
QC
ND
ND
ND
0.148
11.7
0.0413
0.957
24.9
0.387
113
NOM Sample
ND
ND
0.158
0.111
0.719
0.719
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203586579 401638004
QC1203586580
QC1203586578
QC1203588597 401821001
QC1203588599
QC1203588596
QC1203588598 401821001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
28.4
REC%
78.3
102
92.4
15.0
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
401638Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
J
U
RPD%
Notes:
Page 2 of 3
Page 8 of 15
Page 44 of 75
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
401638Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 9 of 15
Page 45 of 75
Page 10 of 15
Page 46 of 75
Page 11 of 15
Page 47 of 75

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070325
Work Order #: 401638

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1581994

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1581993
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401638001 2016021445
401638002 2016021446
401638003 2016021447
401638004 2016021448
1203585486 Method Blank (MB)ICP-MS
1203585487 Laboratory Control Sample (LCS)
1203585488 Laboratory Control Sample (LCS)
1203585492 401636001(2016021471L) Serial Dilution (SD)
1203585489 401636001(2016021471D) Sample Duplicate (DUP)
1203585490 401636001(2016021471S) Matrix Spike (MS)
1203585491 401636001(2016021471S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1582445
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401638001 2016021445
Page 12 of 15
Page 48 of 75
401638002 2016021446
401638003 2016021447
401638004 2016021448
1203586578 Method Blank (MB)
1203586579 401638004(2016021448) Sample Duplicate (DUP)
1203586580 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1583317
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401638001 2016021445
401638002 2016021446
401638003 2016021447
401638004 2016021448
1203588596 Method Blank (MB)
1203588597 401821001(NonSDG) Sample Duplicate (DUP)
1203588598 401821001(NonSDG) Matrix Spike (MS)
1203588599 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203588598 (Non SDG 401821001MS), aliquot was reduced to conserve sample volume.

Page 13 of 15
Page 49 of 75
Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 14 of 15
Page 50 of 75
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 29 July 2016
Page 15 of 15
Page 51 of 75
#=CL#
July 21, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92304968
92304968
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070325
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 13, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
Page 52 of 75
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92304968
J16070325
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
Page 53 of 75
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92304968
J16070325
Lab ID Sample ID Matrix Date Collected Date Received
92304968001 2016021445 Water 07/12/16 10:30 07/13/16 12:15
92304968002 2016021446 Water 07/12/16 09:05 07/13/16 12:15
92304968003 2016021447 Water 07/12/16 14:04 07/13/16 12:15
92304968004 2016021448 Water 07/12/16 14:04 07/13/16 12:15
92304968005 2016021450 Water 07/12/16 13:50 07/13/16 12:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
Page 54 of 75
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304968
J16070325
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92304968001 2016021445 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304968002 2016021446 SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304968003 2016021447 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304968004 2016021448 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304968005 2016021450 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
Page 55 of 75
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92304968
J16070325
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92304968001 2016021445
Methane 81.5 ug/L 07/20/16 17:3310.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)69.9 mg/L 07/16/16 22:235.0SM 2320B
Alkalinity, Total as CaCO3 69.9 mg/L 07/16/16 22:235.0SM 2320B
92304968002 2016021446
Alkalinity,Bicarbonate (CaCO3)13.9 mg/L 07/16/16 22:345.0SM 2320B
Alkalinity, Total as CaCO3 13.9 mg/L 07/16/16 22:345.0SM 2320B
92304968003 2016021447
Alkalinity,Bicarbonate (CaCO3)41.6 mg/L 07/16/16 23:045.0SM 2320B
Alkalinity, Total as CaCO3 41.6 mg/L 07/16/16 23:045.0SM 2320B
Chromium, Hexavalent 0.14 ug/L 07/18/16 21:070.030EPA 218.7
92304968004 2016021448
Alkalinity,Bicarbonate (CaCO3)35.9 mg/L 07/16/16 23:165.0SM 2320B
Alkalinity, Total as CaCO3 35.9 mg/L 07/16/16 23:165.0SM 2320B
Chromium, Hexavalent 0.13 ug/L 07/18/16 21:200.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 23
Page 56 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304968
J16070325
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 21, 2016
Description:RSK 175 Headspace
General Information:
4 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321519
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304098010
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1783837)
• Methane
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 23
Page 57 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304968
J16070325
Method:
Client:Duke Energy
SM 2320B
Date:July 21, 2016
Description:2320B Alkalinity
General Information:
5 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 23
Page 58 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304968
J16070325
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 21, 2016
Description:4500S2D Sulfide Water
General Information:
5 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321606
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304968001,92304968002
M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences.
• MS (Lab ID: 1782276)
• Sulfide
• MSD (Lab ID: 1782277)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 23
Page 59 of 75
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304968
J16070325
Method:
Client:Duke Energy
EPA 218.7
Date:July 21, 2016
Description:Hexavalent Chromium by IC
General Information:
4 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 309440
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304976001,92304981001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1640510)
• Chromium, Hexavalent
• MSD (Lab ID: 1640511)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 23
Page 60 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304968
J16070325
Sample:2016021445 Lab ID:92304968001 Collected:07/12/16 10:30 Received:07/13/16 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 81.5 ug/L 07/20/16 17:33 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)69.9 mg/L 07/16/16 22:235.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 22:235.0 1
Alkalinity, Total as CaCO3 69.9 mg/L 07/16/16 22:235.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/18/16 20:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 23
Page 61 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304968
J16070325
Sample: 2016021446 Lab ID: 92304968002 Collected: 07/12/16 09:05 Received: 07/13/16 12:15 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)13.9 mg/L 07/16/16 22:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 22:345.0 1
Alkalinity, Total as CaCO3 13.9 mg/L 07/16/16 22:345.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-8 M30.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/18/16 20:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 23
Page 62 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304968
J16070325
Sample:2016021447 Lab ID:92304968003 Collected:07/12/16 14:04 Received:07/13/16 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/20/16 17:48 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)41.6 mg/L 07/16/16 23:045.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 23:045.0 1
Alkalinity, Total as CaCO3 41.6 mg/L 07/16/16 23:045.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.14 ug/L 07/18/16 21:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 23
Page 63 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304968
J16070325
Sample:2016021448 Lab ID:92304968004 Collected:07/12/16 14:04 Received:07/13/16 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/20/16 18:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)35.9 mg/L 07/16/16 23:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 23:165.0 1
Alkalinity, Total as CaCO3 35.9 mg/L 07/16/16 23:165.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.13 ug/L 07/18/16 21:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 23
Page 64 of 75
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304968
J16070325
Sample:2016021450 Lab ID:92304968005 Collected:07/12/16 13:50 Received:07/13/16 12:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/20/16 18:18 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/17/16 12:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/17/16 12:505.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/17/16 12:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/18/16 21:20 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 23
Page 65 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304968
J16070325
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321519
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304968001, 92304968003, 92304968004, 92304968005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781804
Associated Lab Samples:92304968001, 92304968003, 92304968004, 92304968005
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/20/16 14:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781805LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 454 N239611570-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1783837MATRIX SPIKE SAMPLE:
MSSpike
Result
92304098010
Methane ug/L 10700 H5,M1,N239614370-13010100
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92304098012
1783838SAMPLE DUPLICATE:
Methane ug/L 7530 H5,N211208380
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 23
Page 66 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304968
J16070325
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321462
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304968001, 92304968002, 92304968003, 92304968004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781600
Associated Lab Samples:92304968001, 92304968002, 92304968003, 92304968004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/16/16 16:55
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/16/16 16:55
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/16/16 16:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781601LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 52.850 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781602MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304866003
1781603
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 96 80-12094 2 25501.4J 49.4 48.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781604MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304966005
1781605
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 82 80-120100 3 2550238279288
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 23
Page 67 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304968
J16070325
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321477
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304968005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781655
Associated Lab Samples:92304968005
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/17/16 12:29
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/17/16 12:29
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/17/16 12:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781656LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 52.550 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781657MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304968005
1781658
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 80-12098 1 2550ND49.5 49.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781659MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304981007
1781660
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 80-12098 1 2550ND49.7 49.1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 23
Page 68 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304968
J16070325
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321606
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304968001, 92304968002, 92304968003, 92304968004, 92304968005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1782272
Associated Lab Samples:92304968001, 92304968002, 92304968003, 92304968004, 92304968005
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/18/16 21:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1782273LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.50.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1782274MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304968001
1782275
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 97 90-11097 0 10.5ND 0.49 0.49
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1782276MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304968002
1782277
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M3.5 26 90-11026 0 10.5ND 0.22 0.22
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 23
Page 69 of 75
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304968
J16070325
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
309440
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92304968001, 92304968002, 92304968003, 92304968004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1640506
Associated Lab Samples:92304968001, 92304968002, 92304968003, 92304968004
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/18/16 18:31
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1640507LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.072.075 96 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1640508MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304981001
1640509
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 106 85-115100 5 20.075ND 0.079 0.075
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1640510MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304976001
1640511
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M6114785-115158 1 2016.1 7.6 7.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
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[phone]
Page 19 of 23
Page 70 of 75
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92304968
J16070325
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.H5
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304968
J16070325
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92304968001 3215192016021445RSK 175 Modified
92304968003 3215192016021447RSK 175 Modified
92304968004 3215192016021448RSK 175 Modified
92304968005 3215192016021450RSK 175 Modified
92304968001 3214622016021445SM 2320B
92304968002 3214622016021446SM 2320B
92304968003 3214622016021447SM 2320B
92304968004 3214622016021448SM 2320B
92304968005 3214772016021450SM 2320B
92304968001 3216062016021445SM 4500-S2D
92304968002 3216062016021446SM 4500-S2D
92304968003 3216062016021447SM 4500-S2D
92304968004 3216062016021448SM 4500-S2D
92304968005 3216062016021450SM 4500-S2D
92304968001 3094402016021445EPA 218.7
92304968002 3094402016021446EPA 218.7
92304968003 3094402016021447EPA 218.7
92304968004 3094402016021448EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/21/2016 04:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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