NC0000396_App B Lab Reports - CAMA BKGD - J16070281report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070281
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:8/3/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Dissolved gases: The instrument QC (CCV) associated with the equipment blank in this sample set recovered outside method
limits and may bias methane results low. Reanalysis was not performed due to insufficient volume, however data has been
qualified accordingly.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 68
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016021267 ASHEVILLE 11-Jul-16 1:52 PM Synterra ABMW-11BR
2016021268 ASHEVILLE 11-Jul-16 10:28 AM Synterra CB-9SL
2016021269 ASHEVILLE 11-Jul-16 4:00 PM Synterra Filter Blank
2016021270 ASHEVILLE 11-Jul-16 4:00 PM Synterra Equipment Blank
4 Total Samples
Duke Energy Analytical Lab
Page 2 of 68
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:8/3/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021267
Collection Date:11-Jul-16 1:52 PM
Site:ABMW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/19/2016 14:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.4 mg/L EPA 300.0 07/18/2016 14:13 BGN90340.1 1
Sulfate 36 mg/L EPA 300.0 07/18/2016 14:13 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:13 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:08 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.052 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.005 1
Barium (Ba)0.014 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.05 1
Iron (Fe)0.140 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.01 1
Manganese (Mn)0.094 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.005 1
Strontium (Sr)0.102 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.005 1
Zinc (Zn)0.005 mg/L EPA 200.7 07/14/2016 14:16 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)28.2 mg/L EPA 200.7 07/13/2016 13:29 JJMACKE0.01 1
Magnesium (Mg)3.05 mg/L EPA 200.7 07/13/2016 13:29 JJMACKE0.005 1
Potassium (K)13.2 mg/L EPA 200.7 07/13/2016 13:29 JJMACKE0.1 1
Sodium (Na)16.5 mg/L EPA 200.7 07/13/2016 13:29 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.159 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.005 1
Barium (Ba)0.015 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.05 1
Iron (Fe)0.766 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.01 1
Manganese (Mn)0.098 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.005 1
Strontium (Sr)0.102 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 07/18/2016 13:23 MHH71310.005 1
Duke Energy Analytical Lab
Page 4 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021267
Collection Date:11-Jul-16 1:52 PM
Site:ABMW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Molybdenum (Mo)13.5 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Nickel (Ni)1.22 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN30.2 1
Vanadium (V) Low Level 0.300 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Chromium (Cr)11.1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Copper (Cu)1.39 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Molybdenum (Mo)13.6 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Nickel (Ni)10.1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN311
Thallium (Tl) Low Level 0.396 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN30.2 1
Vanadium (V) Low Level 0.690 ug/L EPA 200.8 07/15/2016 04:00 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 170 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 5 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021267
Collection Date:11-Jul-16 1:52 PM
Site:ABMW-11BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 6 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021268
Collection Date:11-Jul-16 10:28 AM
Site:CB-9SL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.279 mg-N/L EPA 353.2 07/19/2016 14:23 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.3 mg/L EPA 300.0 07/19/2016 08:45 BGN90340.1 1
Sulfate 0.72 mg/L EPA 300.0 07/19/2016 08:45 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:16 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:21 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.005 1
Barium (Ba)0.036 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.05 1
Iron (Fe)0.089 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.005 1
Strontium (Sr)0.027 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 07/14/2016 14:34 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.27 mg/L EPA 200.7 07/13/2016 13:33 JJMACKE0.01 1
Magnesium (Mg)1.90 mg/L EPA 200.7 07/13/2016 13:33 JJMACKE0.005 1
Potassium (K)1.53 mg/L EPA 200.7 07/13/2016 13:33 JJMACKE0.1 1
Sodium (Na)3.27 mg/L EPA 200.7 07/13/2016 13:33 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.055 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.005 1
Barium (Ba)0.037 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.05 1
Iron (Fe)0.158 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.01 1
Manganese (Mn)0.013 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.005 1
Strontium (Sr)0.027 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 07/18/2016 13:11 MHH71310.005 1
Duke Energy Analytical Lab
Page 7 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021268
Collection Date:11-Jul-16 10:28 AM
Site:CB-9SL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Chromium (Cr)1.28 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Lead (Pb)2.06 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Nickel (Ni)7.09 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/19/2016 19:58 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Chromium (Cr)19.3 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Lead (Pb)4.89 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Nickel (Ni)12.4 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN30.2 1
Vanadium (V) Low Level 0.392 ug/L EPA 200.8 07/15/2016 12:35 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 43 mg/L SM2540C 07/14/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 8 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021268
Collection Date:11-Jul-16 10:28 AM
Site:CB-9SL
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.252 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 9 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021269
Collection Date:11-Jul-16 4:00 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:23 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.009 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/14/2016 14:37 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Copper (Cu)3.72 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/19/2016 20:05 JAHERMA0.3 1
Duke Energy Analytical Lab
Page 10 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021270
Collection Date:11-Jul-16 4:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.025 mg-N/L EPA 353.2 07/19/2016 14:28 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/18/2016 15:16 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 07/18/2016 15:16 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:18 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.017 mg/L EPA 200.7 07/13/2016 13:36 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/13/2016 13:36 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/13/2016 13:36 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 07/13/2016 13:36 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 13:27 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 04:13 CWSPEN30.3 1
Duke Energy Analytical Lab
Page 11 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
2016021270
Collection Date:11-Jul-16 4:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.282 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 12 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070477 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
-0.0004 mg-N/L -1-0.0004 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0005 mg-N/L -10.0005 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0003 mg-N/L -10.0003 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.298 3.01 99.1mg-N/L -11090102.98
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.294 3.01 97.6mg-N/L -11090102.94
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.294 3.01 97.6mg-N/L -11090102.94
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021268
Nitrite + Nitrate
(Colorimetric)
0.523 0.25 97.6mg-N/L -1109010.523
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021268
Nitrite + Nitrate
(Colorimetric)
0.523 0.25 97.8 0.205mg-N/L -1109010.523
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021853
Nitrite + Nitrate
(Colorimetric)
0.203 0.25 82.4mg-N/L -1109010.203
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021853
Nitrite + Nitrate
(Colorimetric)
0.203 0.25 82.4 0.0486mg-N/L -1109010.203
Duke Energy Analytical Lab
Page 13 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070477 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Nitrite + Nitrate
(Colorimetric)
0.468 0.25 95.7mg-N/L -1109010.468
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070399 -- 2016021854
Nitrite + Nitrate
(Colorimetric)
0.464 0.25 93.9 1.9mg-N/L -1109010.464
Duke Energy Analytical Lab
Page 14 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070395 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride mg/L -1-0.002 0.1 < 1/2 RDL
Sulfate mg/L -1-0.041 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5 102mg/L -1208015.46
Sulfate 5 97.3mg/L -1208018.43
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5 102 0.176mg/L -1208015.46
Sulfate 5 97.3 0.0822mg/L -1208018.44
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 5 99.7mg/L -1208016.41
Sulfate 5 96.9mg/L -1208018.54
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 5 99.5 0.201mg/L -1208016.4
Sulfate 5 97 0.144mg/L -1208018.54
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5 103mg/L -1208015.13
Sulfate 5 103mg/L -1208015.13
Duke Energy Analytical Lab
Page 15 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070616 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.003 ug/L -10.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.01 1 100ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.991 1 98.2 1.92ug/L -1307010.991
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.994 1 97.3ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1 1 97.9 0.615ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.5ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.9ug/L -1158511.88
Duke Energy Analytical Lab
Page 16 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070618 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.003 ug/L -10.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.5ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.9ug/L -1158511.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Mercury (Hg) 0.983 1 97.2ug/L -1307010.983
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Mercury (Hg) 1.01 1 99.5 2.34ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Mercury (Hg) 1.01 1 100ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Mercury (Hg) 0.991 1 98.2 1.92ug/L -1307010.991
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020920
Mercury (Hg) 0.994 1 97.3ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020920
Mercury (Hg) 1 1 97.9 0.615ug/L -1307011
Duke Energy Analytical Lab
Page 17 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000029 mg/L -10.000029 0.005 < 1/2 RDL
Barium (Ba) 0.00006 mg/L -10.00006 0.005 < 1/2 RDL
Boron (B) 0.000281 mg/L -10.000281 0.05 < 1/2 RDL
Iron (Fe) -0.000508 mg/L -1-0.000508 0.01 < 1/2 RDL
Manganese (Mn) -0.000329 mg/L -1-0.000329 0.005 < 1/2 RDL
Strontium (Sr) 0.000134 mg/L -10.000134 0.005 < 1/2 RDL
Zinc (Zn) -0.000785 mg/L -1-0.000785 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Aluminum (Al) -0.000007 mg/L -1-0.000007 0.005 < 1/2 RDL
Barium (Ba) 0.000039 mg/L -10.000039 0.005 < 1/2 RDL
Boron (B) 0.00088 mg/L -10.00088 0.05 < 1/2 RDL
Iron (Fe) -0.000931 mg/L -1-0.000931 0.01 < 1/2 RDL
Manganese (Mn) -0.000163 mg/L -1-0.000163 0.005 < 1/2 RDL
Strontium (Sr) 0.000104 mg/L -10.000104 0.005 < 1/2 RDL
Zinc (Zn) -0.000664 mg/L -1-0.000664 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.09 2 105mg/L -1158512.09
Barium (Ba) 0.985 1 98.5mg/L -1158510.985
Boron (B) 1.98 2 99.2mg/L -1158511.98
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.982 1 98.2mg/L -1158510.982
Strontium (Sr) 1.91 2 95.5mg/L -1158511.91
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Aluminum (Al) 2.1 2 105mg/L -1158512.1
Barium (Ba) 0.991 1 99.1mg/L -1158510.991
Boron (B) 2.01 2 100mg/L -1158512.01
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.989 1 98.9mg/L -1158510.989
Strontium (Sr) 1.92 2 96.2mg/L -1158511.92
Zinc (Zn) 1.03 1 103mg/L -1158511.03
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Aluminum (Al) 5.53 5 109mg/L -1307015.53
Duke Energy Analytical Lab
Page 18 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Barium (Ba) 5.26 5 104mg/L -1307015.26
Boron (B) 10.7 5 93.7mg/L -13070110.7
Iron (Fe) 5.3 5 101mg/L -1307015.3
Manganese (Mn) 7.89 5 96.8mg/L -1307017.89
Strontium (Sr) 7.3 5 102mg/L -1307017.3
Zinc (Zn) 5.21 5 104mg/L -1307015.21
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021471
Aluminum (Al) 5.63 5 111 1.83mg/L -1307015.63
Barium (Ba) 5.35 5 105 1.65mg/L -1307015.35
Boron (B) 10.9 5 97.5 4mg/L -13070110.9
Iron (Fe) 5.39 5 103 1.86mg/L -1307015.39
Manganese (Mn) 8.03 5 99.5 2.77mg/L -1307018.03
Strontium (Sr) 7.37 5 104 1.32mg/L -1307017.37
Zinc (Zn) 5.29 5 106 1.64mg/L -1307015.29
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.43 5 108mg/L -1307015.43
Barium (Ba) 5.17 5 103mg/L -1307015.17
Boron (B) 5.11 5 102mg/L -1307015.11
Iron (Fe) 5.69 5 99.5mg/L -1307015.69
Manganese (Mn) 5.57 5 105mg/L -1307015.57
Strontium (Sr) 5.35 5 99.9mg/L -1307015.35
Zinc (Zn) 5.13 5 103mg/L -1307015.13
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070300 -- 2016021339
Aluminum (Al) 5.52 5 110 1.74mg/L -1307015.52
Barium (Ba) 5.27 5 105 2.02mg/L -1307015.27
Boron (B) 5.22 5 104 2.23mg/L -1307015.22
Iron (Fe) 5.81 5 102 2.32mg/L -1307015.81
Manganese (Mn) 5.67 5 107 1.98mg/L -1307015.67
Strontium (Sr) 5.43 5 102 1.71mg/L -1307015.43
Zinc (Zn) 5.24 5 105 2.04mg/L -1307015.24
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Aluminum (Al) 5.52 5 110mg/L -1307015.52
Barium (Ba) 5.23 5 104mg/L -1307015.23
Duke Energy Analytical Lab
Page 19 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070341 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Boron (B) 5.09 5 102mg/L -1307015.09
Iron (Fe) 5.09 5 102mg/L -1307015.09
Manganese (Mn) 5.4 5 107mg/L -1307015.4
Strontium (Sr) 5.08 5 100mg/L -1307015.08
Zinc (Zn) 5.29 5 106mg/L -1307015.29
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021448
Aluminum (Al) 5.52 5 110 0.0725mg/L -1307015.52
Barium (Ba) 5.24 5 104 0.211mg/L -1307015.24
Boron (B) 5.11 5 102 0.294mg/L -1307015.11
Iron (Fe) 5.12 5 102 0.431mg/L -1307015.12
Manganese (Mn) 5.42 5 108 0.41mg/L -1307015.42
Strontium (Sr) 5.09 5 101 0.139mg/L -1307015.09
Zinc (Zn) 5.31 5 106 0.246mg/L -1307015.31
Duke Energy Analytical Lab
Page 20 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.000804 mg/L -10.000804 0.01 < 1/2 RDL
Magnesium (Mg) -0.000016 mg/L -1-0.000016 0.005 < 1/2 RDL
Potassium (K) 0.0121 mg/L -10.0121 0.1 < 1/2 RDL
Sodium (Na) -0.0204 mg/L -1-0.0204 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.0025 mg/L -10.0025 0.01 < 1/2 RDL
Magnesium (Mg) 0.000113 mg/L -10.000113 0.005 < 1/2 RDL
Potassium (K) 0.00296 mg/L -10.00296 0.1 < 1/2 RDL
Sodium (Na) -0.0187 mg/L -1-0.0187 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.5mg/L -1158513.98
Sodium (Na) 8.29 8.1 102mg/L -1158518.29
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.07 2 103mg/L -1158512.07
Magnesium (Mg) 2.01 2 101mg/L -1158512.01
Potassium (K) 4.01 4 100mg/L -1158514.01
Sodium (Na) 8.36 8.1 103mg/L -1158518.36
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 179 5 0mg/L -130701179
Magnesium (Mg) 6.53 5 100mg/L -1307016.53
Potassium (K) 148 5 272mg/L -130701148
Sodium (Na) 460 5 0mg/L -130701460
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 178 5 0 0mg/L -130701178
Magnesium (Mg) 6.49 5 99.2 0.763mg/L -1307016.49
Potassium (K) 146 5 246 10mg/L -130701146
Sodium (Na) 457 5 0 0mg/L -130701457
Duke Energy Analytical Lab
Page 21 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 102mg/L -13070112
Magnesium (Mg) 11.5 5 96mg/L -13070111.5
Potassium (K) 6.76 5 103mg/L -1307016.76
Sodium (Na) 14 5 82.3mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 101 0.0197mg/L -13070112
Magnesium (Mg) 11.5 5 96 0.0208mg/L -13070111.5
Potassium (K) 6.78 5 103 0.331mg/L -1307016.78
Sodium (Na) 14 5 82 0.438mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104mg/L -13070110.6
Magnesium (Mg) 9.21 5 106mg/L -1307019.21
Potassium (K) 6.52 5 105mg/L -1307016.52
Sodium (Na) 16.4 5 88.3mg/L -13070116.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104 0.154mg/L -13070110.6
Magnesium (Mg) 9.17 5 105 0.797mg/L -1307019.17
Potassium (K) 6.5 5 105 0.325mg/L -1307016.5
Sodium (Na) 16.2 5 86.3 2.36mg/L -13070116.2
Duke Energy Analytical Lab
Page 22 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070383 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000579 mg/L -10.000579 0.005 < 1/2 RDL
Barium (Ba) -0.00005 mg/L -1-0.00005 0.005 < 1/2 RDL
Boron (B) -0.00017 mg/L -1-0.00017 0.05 < 1/2 RDL
Iron (Fe) 0.00114 mg/L -10.00114 0.01 < 1/2 RDL
Manganese (Mn) 0.000146 mg/L -10.000146 0.005 < 1/2 RDL
Strontium (Sr) 0.000141 mg/L -10.000141 0.005 < 1/2 RDL
Zinc (Zn) 0.000484 mg/L -10.000484 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.85 5 97.1mg/L -1158514.85
Barium (Ba) 5.14 5 103mg/L -1158515.14
Boron (B) 5.05 5 101mg/L -1158515.05
Iron (Fe) 5.15 5 103mg/L -1158515.15
Manganese (Mn) 5.09 5 102mg/L -1158515.09
Strontium (Sr) 5.07 5 101mg/L -1158515.07
Zinc (Zn) 5.08 5 102mg/L -1158515.08
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021268
Aluminum (Al) 4.75 5 93.9mg/L -1307014.75
Barium (Ba) 5.04 5 100mg/L -1307015.04
Boron (B) 4.95 5 98.8mg/L -1307014.95
Iron (Fe) 5.14 5 99.6mg/L -1307015.14
Manganese (Mn) 4.95 5 98.8mg/L -1307014.95
Strontium (Sr) 4.97 5 98.9mg/L -1307014.97
Zinc (Zn) 4.89 5 97.7mg/L -1307014.89
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021268
Aluminum (Al) 4.83 5 95.4 1.56mg/L -1307014.83
Barium (Ba) 5.08 5 101 0.796mg/L -1307015.08
Boron (B) 4.97 5 99.3 0.565mg/L -1307014.97
Iron (Fe) 5.2 5 101 1.16mg/L -1307015.2
Manganese (Mn) 5 5 99.8 0.967mg/L -1307015
Strontium (Sr) 4.97 5 99 0.0202mg/L -1307014.97
Zinc (Zn) 4.95 5 98.8 1.1mg/L -1307014.95
Duke Energy Analytical Lab
Page 23 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070350 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.058 ug/L -10.058 1 < 1/2 RDL
Arsenic (As) 0.036 ug/L -10.036 1 < 1/2 RDL
Beryllium (Be) 0.0261 ug/L -10.0261 1 < 1/2 RDL
Cadmium (Cd) -0.0072 ug/L -1-0.0072 1 < 1/2 RDL
Chromium (Cr) -0.015 ug/L -1-0.015 1 < 1/2 RDL
Cobalt (Co) -0.0129 ug/L -1-0.0129 1 < 1/2 RDL
Copper (Cu) 0.0286 ug/L -10.0286 1 < 1/2 RDL
Lead (Pb) -0.004 ug/L -1-0.004 1 < 1/2 RDL
Molybdenum (Mo) 0 ug/L -10 1 < 1/2 RDL
Nickel (Ni) -0.376 ug/L -1-0.376 1 < 1/2 RDL
Selenium (Se) 0.0244 ug/L -10.0244 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0061 ug/L -10.0061 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0235 ug/L -10.0235 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.4 50 98.8ug/L -11585149.4
Arsenic (As) 51.7 50 103ug/L -11585151.7
Beryllium (Be) 52.3 50 105ug/L -11585152.3
Cadmium (Cd) 48.4 50 96.9ug/L -11585148.4
Chromium (Cr) 51.6 50 103ug/L -11585151.6
Cobalt (Co) 52.2 50 104ug/L -11585152.2
Copper (Cu) 50 50 100ug/L -11585150
Lead (Pb) 49 50 98.1ug/L -11585149
Molybdenum (Mo) 48.1 50 96.1ug/L -11585148.1
Nickel (Ni) 51.4 50 103ug/L -11585151.4
Selenium (Se) 52.3 50 105ug/L -11585152.3
Thallium (Tl) Low Level 44.9 50 89.8ug/L -11585144.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021267
Antimony (Sb) 51.7 50 103ug/L -13070151.7
Arsenic (As) 54.3 50 108ug/L -13070154.3
Beryllium (Be) 52.7 50 105ug/L -13070152.7
Cadmium (Cd) 48.8 50 97.6ug/L -13070148.8
Chromium (Cr) 53.4 50 106ug/L -13070153.4
Cobalt (Co) 51.8 50 103ug/L -13070151.8
Copper (Cu) 51 50 102ug/L -13070151
Lead (Pb) 48.9 50 97.8ug/L -13070148.9
Molybdenum (Mo) 62.4 50 97.9ug/L -13070162.4
Duke Energy Analytical Lab
Page 24 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070350 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021267
Nickel (Ni) 51.8 50 101ug/L -13070151.8
Selenium (Se) 51.6 50 103ug/L -13070151.6
Thallium (Tl) Low Level 43.9 50 87.8ug/L -13070143.9
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070281 -- 2016021267
Antimony (Sb) 50.1 50 99.8 3.21ug/L -13070150.1
Arsenic (As) 53.5 50 106 1.36ug/L -13070153.5
Beryllium (Be) 51.6 50 103 1.97ug/L -13070151.6
Cadmium (Cd) 48 50 96 1.69ug/L -13070148
Chromium (Cr) 52.2 50 104 2.23ug/L -13070152.2
Cobalt (Co) 50.2 50 100 3.06ug/L -13070150.2
Copper (Cu) 50.7 50 101 0.513ug/L -13070150.7
Lead (Pb) 48.6 50 97.2 0.656ug/L -13070148.6
Molybdenum (Mo) 61.8 50 96.6 1.36ug/L -13070161.8
Nickel (Ni) 53 50 104 2.46ug/L -13070153
Selenium (Se) 52.9 50 106 2.53ug/L -13070152.9
Thallium (Tl) Low Level 43.8 50 87.6 0.182ug/L -13070143.8
Duke Energy Analytical Lab
Page 25 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0234 ug/L -1-0.0234 1 < 1/2 RDL
Arsenic (As) 0.0143 ug/L -10.0143 1 < 1/2 RDL
Beryllium (Be) 0.0062 ug/L -10.0062 1 < 1/2 RDL
Cadmium (Cd) 0.0007 ug/L -10.0007 1 < 1/2 RDL
Chromium (Cr) -0.0808 ug/L -1-0.0808 1 < 1/2 RDL
Cobalt (Co) 0.0068 ug/L -10.0068 1 < 1/2 RDL
Copper (Cu) -0.141 ug/L -1-0.141 1 < 1/2 RDL
Lead (Pb) 0.0024 ug/L -10.0024 1 < 1/2 RDL
Molybdenum (Mo) 0.0014 ug/L -10.0014 1 < 1/2 RDL
Nickel (Ni) -0.0172 ug/L -1-0.0172 1 < 1/2 RDL
Selenium (Se) -0.0861 ug/L -1-0.0861 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0237 ug/L -1-0.0237 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0239 ug/L -10.0239 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.4 50 101ug/L -11585150.4
Arsenic (As) 48.3 50 96.7ug/L -11585148.3
Beryllium (Be) 53.9 50 108ug/L -11585153.9
Cadmium (Cd) 49.7 50 99.4ug/L -11585149.7
Chromium (Cr) 51 50 102ug/L -11585151
Cobalt (Co) 48.2 50 96.4ug/L -11585148.2
Copper (Cu) 48.6 50 97.2ug/L -11585148.6
Lead (Pb) 50.3 50 101ug/L -11585150.3
Molybdenum (Mo) 49.8 50 99.7ug/L -11585149.8
Nickel (Ni) 48.3 50 96.5ug/L -11585148.3
Selenium (Se) 47.1 50 94.2ug/L -11585147.1
Thallium (Tl) Low Level 49.6 50 99.1ug/L -11585149.6
Vanadium (V) Low Level 50.5 50 101ug/L -11585150.5
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021446
Antimony (Sb) 51.5 50 103ug/L -13070151.5
Arsenic (As) 50.9 50 99.2ug/L -13070150.9
Beryllium (Be) 50.3 50 100ug/L -13070150.3
Cadmium (Cd) 48.7 50 97.3ug/L -13070148.7
Chromium (Cr) 50 50 99.4ug/L -13070150
Cobalt (Co) 63.1 50 92.3ug/L -13070163.1
Copper (Cu) 46.8 50 93.3ug/L -13070146.8
Lead (Pb) 50.1 50 100ug/L -13070150.1
Duke Energy Analytical Lab
Page 26 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021446
Molybdenum (Mo) 50.1 50 99.9ug/L -13070150.1
Nickel (Ni) 51.5 50 95.7ug/L -13070151.5
Selenium (Se) 48 50 96ug/L -13070148
Thallium (Tl) Low Level 44.8 50 89.6ug/L -13070144.8
Vanadium (V) Low Level 50.7 50 101ug/L -13070150.7
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070325 -- 2016021446
Antimony (Sb) 51.5 50 103 0.118ug/L -13070151.5
Arsenic (As) 51.1 50 99.6 0.412ug/L -13070151.1
Beryllium (Be) 49.6 50 98.6 1.55ug/L -13070149.6
Cadmium (Cd) 49.4 50 98.8 1.49ug/L -13070149.4
Chromium (Cr) 51.2 50 102 2.41ug/L -13070151.2
Cobalt (Co) 63.8 50 93.7 1.48ug/L -13070163.8
Copper (Cu) 47.3 50 94.4 1.15ug/L -13070147.3
Lead (Pb) 50.3 50 100 0.456ug/L -13070150.3
Molybdenum (Mo) 50.9 50 102 1.68ug/L -13070150.9
Nickel (Ni) 50.8 50 94.5 1.33ug/L -13070150.8
Selenium (Se) 48.2 50 96.4 0.383ug/L -13070148.2
Thallium (Tl) Low Level 46.9 50 93.9 4.66ug/L -13070146.9
Vanadium (V) Low Level 51.7 50 103 1.99ug/L -13070151.7
Duke Energy Analytical Lab
Page 27 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070302 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070328 -- 2016021493
TDS 2.03mg/L -1293
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070328 -- 2016021494
TDS 0mg/L -1377
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16070367 -- 2016021648
TDS 0.533mg/L -1188
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 95mg/L -11090195
Duke Energy Analytical Lab
Page 28 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070374 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.023 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.04 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208012.46
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 102 3.1mg/L -1208012.39
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 89.7mg/L -1208014.61
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 92.3 2.8mg/L -1208014.66
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 95.8mg/L -1208013.89
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 99.5 3.84mg/L -1208013.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 101mg/L -1158512.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 104mg/L -1158512.98
Duke Energy Analytical Lab
Page 29 of 68
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070281
Q16070215 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060267 -- 2016016733
TSS 0mg/L -116
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060267 -- 2016016734
TSS 0mg/L -110
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 99.2mg/L -11090149.6
Duke Energy Analytical Lab
Page 30 of 68
#=CL#
July 22, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92304787
92304787
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070281
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bishop for
[e-mail]
HORIZON Database Administrator
Kevin Herring
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
Duke Energy Analytical Lab
Page 31 of 68
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92304787
J16070281
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 24
Duke Energy Analytical Lab
Page 32 of 68
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92304787
J16070281
Lab ID Sample ID Matrix Date Collected Date Received
92304787001 2016021267 Water 07/11/16 13:52 07/12/16 14:06
92304787002 2016021268 Water 07/11/16 10:28 07/12/16 14:06
92304787003 2016021270 Water 07/11/16 16:00 07/12/16 14:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 24
Duke Energy Analytical Lab
Page 33 of 68
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304787
J16070281
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92304787001 2016021267 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304787002 2016021268 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304787003 2016021270 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AMLS
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
Duke Energy Analytical Lab
Page 34 of 68
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92304787
J16070281
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92304787001 2016021267
Methane 109 ug/L 07/15/16 21:5210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)105 mg/L 07/16/16 12:345.0SM 2320B
Alkalinity, Total as CaCO3 105 mg/L 07/16/16 12:345.0SM 2320B
92304787002 2016021268
Alkalinity,Bicarbonate (CaCO3)15.4 mg/L 07/16/16 12:455.0SM 2320B
Alkalinity, Total as CaCO3 15.4 mg/L 07/16/16 12:455.0SM 2320B
Chromium, Hexavalent 0.23 ug/L 07/15/16 12:410.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 24
Duke Energy Analytical Lab
Page 35 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304787
J16070281
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 22, 2016
Description:RSK 175 Headspace
General Information:
3 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 322053
CL: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased low.
• 2016021270 (Lab ID: 92304787003)
• Methane
• BLANK (Lab ID: 1784702)
• Methane
• LCS (Lab ID: 1784703)
• Methane
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321519
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304098010
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1783837)
• Methane
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 24
Duke Energy Analytical Lab
Page 36 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304787
J16070281
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 22, 2016
Description:RSK 175 Headspace
Analyte Comments:
QC Batch: 322053
P2: Re-extraction or re-analysis could not be performed due to insufficient sample amount.
• 2016021270 (Lab ID: 92304787003)
• Methane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 24
Duke Energy Analytical Lab
Page 37 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304787
J16070281
Method:
Client:Duke Energy
SM 2320B
Date:July 22, 2016
Description:2320B Alkalinity
General Information:
3 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 24
Duke Energy Analytical Lab
Page 38 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304787
J16070281
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 22, 2016
Description:4500S2D Sulfide Water
General Information:
3 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321058
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304497002,92304520001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1779226)
• Sulfide
• MS (Lab ID: 1779228)
• Sulfide
• MSD (Lab ID: 1779227)
• Sulfide
• MSD (Lab ID: 1779229)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 24
Duke Energy Analytical Lab
Page 39 of 68
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304787
J16070281
Method:
Client:Duke Energy
EPA 218.7
Date:July 22, 2016
Description:Hexavalent Chromium by IC
General Information:
2 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 24
Duke Energy Analytical Lab
Page 40 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304787
J16070281
Sample:2016021267 Lab ID:92304787001 Collected:07/11/16 13:52 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 109 ug/L 07/15/16 21:52 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)105 mg/L 07/16/16 12:345.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 12:345.0 1
Alkalinity, Total as CaCO3 105 mg/L 07/16/16 12:345.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/15/16 12:02 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 24
Duke Energy Analytical Lab
Page 41 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304787
J16070281
Sample:2016021268 Lab ID:92304787002 Collected:07/11/16 10:28 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/20/16 15:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.4 mg/L 07/16/16 12:455.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 12:455.0 1
Alkalinity, Total as CaCO3 15.4 mg/L 07/16/16 12:455.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.23 ug/L 07/15/16 12:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 24
Duke Energy Analytical Lab
Page 42 of 68
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304787
J16070281
Sample:2016021270 Lab ID:92304787003 Collected:07/11/16 16:00 Received:07/12/16 14:06 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/18/16 12:50 74-82-8 CL,P210.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/16/16 12:565.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/16/16 12:565.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/16/16 12:565.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 24
Duke Energy Analytical Lab
Page 43 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321404
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304787001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781373
Associated Lab Samples:92304787001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/15/16 16:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781374LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1781376
Methane ug/L 369 N23969370-13093367 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 24
Duke Energy Analytical Lab
Page 44 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321519
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304787002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781804
Associated Lab Samples:92304787002
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/20/16 14:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781805LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 454 N239611570-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1783837MATRIX SPIKE SAMPLE:
MSSpike
Result
92304098010
Methane ug/L 10700 H5,M1,N239614370-13010100
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92304098012
1783838SAMPLE DUPLICATE:
Methane ug/L 7530 H5,N211208380
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 24
Duke Energy Analytical Lab
Page 45 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
322053
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304787003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1784702
Associated Lab Samples:92304787003
Matrix:Water
Analyzed
Methane ug/L ND 10.0 CL,N207/18/16 11:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1784703LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 350 CL,N23968870-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 24
Duke Energy Analytical Lab
Page 46 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321461
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304787001, 92304787002, 92304787003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781594
Associated Lab Samples:92304787001, 92304787002, 92304787003
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/16/16 11:44
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/16/16 11:44
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/16/16 11:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781595LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 52.050 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781596MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304785006
1781597
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND48.3 48.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1781598MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304863002
1781599
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 255037.1 85.7 85.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 24
Duke Energy Analytical Lab
Page 47 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321058
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304787001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779224
Associated Lab Samples:92304787001
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/13/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779225LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779226MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304497002
1779227
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 125 90-110125 0 10.5ND 0.63 0.63
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779228MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520001
1779229
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 113 90-110113 0 10.5ND 0.59 0.59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 24
Duke Energy Analytical Lab
Page 48 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321059
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304787002, 92304787003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779249
Associated Lab Samples:92304787002, 92304787003
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/13/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779250LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779251MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304787002
1779252
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 110 90-110110 0 10.5ND 0.56 0.56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 24
Duke Energy Analytical Lab
Page 49 of 68
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304787
J16070281
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
309009
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92304787001, 92304787002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1638251
Associated Lab Samples:92304787001, 92304787002
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/15/16 10:24
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1638252LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1638253MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304787001
1638254
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 106 85-115105 1 20.075ND 0.11 0.11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 24
Duke Energy Analytical Lab
Page 50 of 68
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92304787
J16070281
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased
low.CL
Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.H5
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
Re-extraction or re-analysis could not be performed due to insufficient sample amount.P2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 24
Duke Energy Analytical Lab
Page 51 of 68
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304787
J16070281
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92304787001 3214042016021267RSK 175 Modified
92304787002 3215192016021268RSK 175 Modified
92304787003 3220532016021270RSK 175 Modified
92304787001 3214612016021267SM 2320B
92304787002 3214612016021268SM 2320B
92304787003 3214612016021270SM 2320B
92304787001 3210582016021267SM 4500-S2D
92304787002 3210592016021268SM 4500-S2D
92304787003 3210592016021270SM 4500-S2D
92304787001 3090092016021267EPA 218.7
92304787002 3090092016021268EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/22/2016 09:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 24
Duke Energy Analytical Lab
Page 52 of 68
Page 23 of 24
Duke Energy Analytical Lab
Page 53 of 68
Page 24 of 24
Duke Energy Analytical Lab
Page 54 of 68

July 25, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 401375
SDG: J16070281

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 12, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 13
Duke Energy Analytical Lab
Page 55 of 68
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16070281 GEL Work Order: 401375
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 13
Duke Energy Analytical Lab
Page 56 of 68
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581244
1537
1021
1416
0950
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/22/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401375001
Water
11-JUL-16 13:52
12-JUL-16
201601267 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.547
0.266
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000357
ND
ND
ND
ND
0.739
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"69.1 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 13
Duke Energy Analytical Lab
Page 57 of 68
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581244
1538
1022
1416
0950
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/22/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401375002
Water
11-JUL-16 10:28
12-JUL-16
201601268 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.539
0.395
1
2
3
4
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000788
ND
ND
ND
ND
1.30
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"65 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 13
Duke Energy Analytical Lab
Page 58 of 68
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1581172Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 25, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/14/16 09:52
07/15/16 15:06
07/15/16 15:03
07/14/16 09:49
07/14/16 09:47
07/15/16 15:01
07/15/16 15:07
07/14/16 09:53
07/14/16 09:55
QC
ND
ND
ND
0.000212
0.0537
0.000552
0.000563
0.00527
ND
ND
ND
ND
0.0523
0.000566
0.000572
0.00545
ND
NOM Sample
ND
ND
ND
0.000241
0.000241
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203583453 401373001
QC1203583452
QC1203583456
QC1203583451
QC1203583454 401373001
QC1203583457 401373001
QC1203583455 401373001
N/A
N/A
N/A
13
N/A
REC%
108
110
102
105
105
113
104
109
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
401375Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
Page 1 of 3
Page 5 of 13
Duke Energy Analytical Lab
Page 59 of 68
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1581172
1581279
1581244
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
07/14/16 09:55
07/15/16 15:09
07/22/16 14:14
07/22/16 14:08
07/22/16 14:14
07/22/16 11:40
07/22/16 10:25
07/22/16 09:50
07/22/16 11:40
QC
ND
ND
ND
-0.0123
15.3
0.334
0.518
23.1
0.432
93.2
NOM Sample
ND
ND
0.241
0.696
0.280
0.280
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
QC1203583705 401373008
QC1203583706
QC1203583704
QC1203583628 401285001
QC1203583630
QC1203583627
QC1203583629 401285001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
207
59.4
REC%
102
94.5
76.4
15.0
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
401375Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
U
*
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
401375Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070281
Work Order #: 401375

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1581172

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1581171
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401375001 201601267
401375002 201601268
1203583451 Method Blank (MB)ICP-MS
1203583452 Laboratory Control Sample (LCS)
1203583456 Laboratory Control Sample (LCS)
1203583455 401373001(2016021083L) Serial Dilution (SD)
1203583453 401373001(2016021083D) Sample Duplicate (DUP)
1203583454 401373001(2016021083S) Matrix Spike (MS)
1203583457 401373001(2016021083S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1581279
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401375001 201601267
401375002 201601268
1203583704 Method Blank (MB)
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1203583705 401373008(2016021090) Sample Duplicate (DUP)
1203583706 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The sample and the
duplicate, 1203583705 (2016021090DUP) , did not meet the relative percent difference requirement; however,
they do meet the relative error ratio requirement with a value of 2.1481.

Technical Information

Recounts
Samples were re-eluted due to high relative percent difference/relative error ratio. The re-eluted counts are
reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1581244
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401375001 201601267
401375002 201601268
1203583627 Method Blank (MB)
1203583628 401285001(NonSDG) Sample Duplicate (DUP)
1203583629 401285001(NonSDG) Matrix Spike (MS)
1203583630 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
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All of the QC samples meet the required acceptance limits with the following exceptions: The blank result
1203583627 (MB) is greater than the MDC but less than the required detection limit.

Technical Information

Recounts
Sample 1203583629 (Non SDG 401285001MS) was recounted due to low recovery. The recount is reported.
Sample 1203583628 (Non SDG 401285001DUP) was recounted due to high relative percent difference/relative
error ratio. The recount is reported.

Miscellaneous Information

Additional Comments
The matrix spike, 1203583629 (Non SDG 401285001MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 25 July 2016
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