NC0000396_App B Lab Reports - CAMA BKGD - J16070225report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070225
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:8/2/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 2320: The matrix spike duplicate sample associated with MW-24S recovered outside method limits. As a result, the
relative percent difference calculated between MS and MSD was greater than 20%. Overall batch quality as evaluated by a
passing LCS was acceptable.
Method SM4500S2D: The matrix spike and spike duplicate samples associated with CB-01D were outside method limits. Batch
quality as evaluated by passing LCS was acceptable. Data has been qualified accordingly.
Method 218.7: The matrix spike and spike duplicate samples associated with MW-15D were outside method limits. Batch quality
as evaluated by passing LCS was acceptable. Data has been qualified accordingly.
Please note that the dionex parent-duplicate relationship between CB-01D and CB-01Ddup are not within 20% RPD. The
chloride and sulfate results reported for each have been confirmed by reanalysis.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 116
Duke Energy Analytical Lab
Page 2 of 116
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016021083 ASHEVILLE 08-Jul-16 10:38 AM BD CB-01D
2016021084 ASHEVILLE 08-Jul-16 2:45 PM BD AMW-03B
2016021085 ASHEVILLE 08-Jul-16 2:23 PM BD MW-10
2016021086 ASHEVILLE 08-Jul-16 1:20 PM BD MW-24S
2016021087 ASHEVILLE 08-Jul-16 9:28 AM BD MW-11
2016021088 ASHEVILLE 08-Jul-16 9:57 AM BD MW-11D
2016021089 ASHEVILLE 08-Jul-16 12:08 PM BD MW-15A
2016021090 ASHEVILLE 08-Jul-16 12:30 PM BD MW-15D
2016021091 ASHEVILLE 08-Jul-16 1:53 PM BD MW-16A
2016021092 ASHEVILLE 08-Jul-16 2:17 PM BD MW-16BR
2016021093 ASHEVILLE 08-Jul-16 10:38 AM BD CB-01D DUP
2016021094 ASHEVILLE 08-Jul-16 11:40 AM BD Filter Blank
2016021095 ASHEVILLE 08-Jul-16 11:40 AM BD Equipment Blank
13 Total Samples
Duke Energy Analytical Lab
Page 3 of 116
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:7/29/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 4 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021083
Collection Date:08-Jul-16 10:38 AM
Site:CB-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.208 mg-N/L EPA 353.2 07/11/2016 11:17 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.96 mg/L EPA 300.0 07/12/2016 19:34 BGN90340.1 1
Sulfate 2.1 mg/L EPA 300.0 07/12/2016 19:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:19 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:08 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.005 1
Barium (Ba)0.009 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.05 1
Iron (Fe)0.088 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.01 1
Manganese (Mn)0.061 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.005 1
Strontium (Sr)0.012 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 07/11/2016 13:10 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.42 mg/L EPA 200.7 07/13/2016 11:06 JJMACKE0.01 1
Magnesium (Mg)0.693 mg/L EPA 200.7 07/13/2016 11:06 JJMACKE0.005 1
Potassium (K)0.749 mg/L EPA 200.7 07/13/2016 11:06 JJMACKE0.1 1
Sodium (Na)2.48 mg/L EPA 200.7 07/13/2016 11:06 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.239 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.005 1
Barium (Ba)0.012 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.05 1
Iron (Fe)0.193 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.01 1
Manganese (Mn)0.070 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.005 1
Strontium (Sr)0.014 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.005 1
Zinc (Zn)0.009 mg/L EPA 200.7 07/18/2016 09:26 MHH71310.005 1
Duke Energy Analytical Lab
Page 5 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021083
Collection Date:08-Jul-16 10:38 AM
Site:CB-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Cobalt (Co)2.17 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Copper (Cu)9.91 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Lead (Pb)1.03 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Nickel (Ni)1.96 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 14:56 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Cobalt (Co)2.33 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Copper (Cu)1.41 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Nickel (Ni)2.32 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 12:06 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 6 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021083
Collection Date:08-Jul-16 10:38 AM
Site:CB-01D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.201 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 17 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 7 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021084
Collection Date:08-Jul-16 2:45 PM
Site:AMW-03B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.222 mg-N/L EPA 353.2 07/11/2016 11:18 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.65 mg/L EPA 300.0 07/12/2016 19:50 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 07/12/2016 19:50 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:22 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:51 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.005 1
Strontium (Sr)0.057 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 07/11/2016 13:21 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.04 mg/L EPA 200.7 07/13/2016 11:10 JJMACKE0.01 1
Magnesium (Mg)1.78 mg/L EPA 200.7 07/13/2016 11:10 JJMACKE0.005 1
Potassium (K)1.63 mg/L EPA 200.7 07/13/2016 11:10 JJMACKE0.1 1
Sodium (Na)5.12 mg/L EPA 200.7 07/13/2016 11:10 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.005 1
Barium (Ba)0.007 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.05 1
Iron (Fe)0.013 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.005 1
Strontium (Sr)0.057 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 09:38 MHH71310.005 1
Duke Energy Analytical Lab
Page 8 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021084
Collection Date:08-Jul-16 2:45 PM
Site:AMW-03B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Copper (Cu)7.07 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 15:24 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA0.2 1
Vanadium (V) Low Level 0.385 ug/L EPA 200.8 07/20/2016 11:38 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 67 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 9 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021084
Collection Date:08-Jul-16 2:45 PM
Site:AMW-03B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.192 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 10 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021085
Collection Date:08-Jul-16 2:23 PM
Site:MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.094 mg-N/L EPA 353.2 07/11/2016 11:19 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 07/12/2016 20:53 BGN90340.2 2
Sulfate 0.30 mg/L EPA 300.0 07/12/2016 20:53 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.05 ug/L EPA 245.1 07/15/2016 12:24 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:58 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.040 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.005 1
Barium (Ba)0.055 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.05 1
Iron (Fe)0.017 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.01 1
Manganese (Mn)0.172 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.005 1
Strontium (Sr)0.025 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 07/11/2016 13:25 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.44 mg/L EPA 200.7 07/13/2016 11:14 JJMACKE0.01 1
Magnesium (Mg)2.82 mg/L EPA 200.7 07/13/2016 11:14 JJMACKE0.005 1
Potassium (K)1.55 mg/L EPA 200.7 07/13/2016 11:14 JJMACKE0.1 1
Sodium (Na)5.64 mg/L EPA 200.7 07/13/2016 11:14 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.045 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.005 1
Barium (Ba)0.056 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.05 1
Iron (Fe)0.031 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.01 1
Manganese (Mn)0.175 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.005 1
Strontium (Sr)0.026 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 07/18/2016 09:42 MHH71310.005 1
Duke Energy Analytical Lab
Page 11 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021085
Collection Date:08-Jul-16 2:23 PM
Site:MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Cobalt (Co)2.84 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Nickel (Ni)2.66 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 15:31 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Cobalt (Co)2.95 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Nickel (Ni)1.86 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 12:13 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 53 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 12 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021085
Collection Date:08-Jul-16 2:23 PM
Site:MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.679 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 13 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021086
Collection Date:08-Jul-16 1:20 PM
Site:MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.3 mg-N/L EPA 353.2 07/11/2016 11:20 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 07/12/2016 21:09 BGN90340.2 2
Sulfate 0.62 mg/L EPA 300.0 07/12/2016 21:09 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:26 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:25 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.033 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.01 1
Manganese (Mn)0.135 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.005 1
Strontium (Sr)0.039 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/11/2016 13:29 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.20 mg/L EPA 200.7 07/13/2016 11:28 JJMACKE0.01 1
Magnesium (Mg)3.70 mg/L EPA 200.7 07/13/2016 11:28 JJMACKE0.005 1
Potassium (K)1.60 mg/L EPA 200.7 07/13/2016 11:28 JJMACKE0.1 1
Sodium (Na)3.35 mg/L EPA 200.7 07/13/2016 11:28 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.041 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.005 1
Barium (Ba)0.058 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.01 1
Manganese (Mn)0.136 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.005 1
Strontium (Sr)0.040 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 09:46 MHH71310.005 1
Duke Energy Analytical Lab
Page 14 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021086
Collection Date:08-Jul-16 1:20 PM
Site:MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Copper (Cu)6.55 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 15:38 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 12:20 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 52 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 15 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021086
Collection Date:08-Jul-16 1:20 PM
Site:MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.281 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 16 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021087
Collection Date:08-Jul-16 9:28 AM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.030 mg-N/L EPA 353.2 07/11/2016 11:22 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 110 mg/L EPA 300.0 07/12/2016 21:25 BGN9034220
Sulfate 30 mg/L EPA 300.0 07/12/2016 21:25 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:29 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:32 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.063 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.005 1
Barium (Ba)0.078 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.05 1
Iron (Fe)0.019 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.01 1
Manganese (Mn)0.097 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.005 1
Strontium (Sr)0.146 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 07/11/2016 13:33 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)24.9 mg/L EPA 200.7 07/13/2016 11:31 JJMACKE0.01 1
Magnesium (Mg)11.2 mg/L EPA 200.7 07/13/2016 11:31 JJMACKE0.005 1
Potassium (K)0.990 mg/L EPA 200.7 07/13/2016 11:31 JJMACKE0.1 1
Sodium (Na)47.0 mg/L EPA 200.7 07/13/2016 11:31 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.005 1
Barium (Ba)0.078 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.05 1
Iron (Fe)0.061 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.01 1
Manganese (Mn)0.113 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.005 1
Strontium (Sr)0.138 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 09:50 MHH71310.005 1
Duke Energy Analytical Lab
Page 17 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021087
Collection Date:08-Jul-16 9:28 AM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Chromium (Cr)2.03 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Copper (Cu)5.22 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 15:45 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Chromium (Cr)9.26 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Nickel (Ni)5.29 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 12:27 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 18 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021087
Collection Date:08-Jul-16 9:28 AM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.906 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 19 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021088
Collection Date:08-Jul-16 9:57 AM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)3.1 mg-N/L EPA 353.2 07/11/2016 11:28 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 160 mg/L EPA 300.0 07/13/2016 22:30 BGN90342.5 25
Sulfate 16 mg/L EPA 300.0 07/13/2016 22:30 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:31 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:10 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.111 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.005 1
Barium (Ba)0.299 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.005 1
Boron (B)0.069 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.01 1
Manganese (Mn)0.144 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.005 1
Strontium (Sr)0.357 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 07/11/2016 13:37 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)35.2 mg/L EPA 200.7 07/13/2016 11:35 JJMACKE0.01 1
Magnesium (Mg)14.6 mg/L EPA 200.7 07/13/2016 11:35 JJMACKE0.005 1
Potassium (K)4.00 mg/L EPA 200.7 07/13/2016 11:35 JJMACKE0.1 1
Sodium (Na)43.4 mg/L EPA 200.7 07/13/2016 11:35 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.141 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.005 1
Barium (Ba)0.317 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.05 1
Iron (Fe)0.076 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.01 1
Manganese (Mn)0.149 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.005 1
Strontium (Sr)0.356 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 09:54 MHH71310.005 1
Duke Energy Analytical Lab
Page 20 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021088
Collection Date:08-Jul-16 9:57 AM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Copper (Cu)6.87 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Lead (Pb)1.19 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 15:52 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Copper (Cu)1.01 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA0.2 1
Vanadium (V) Low Level 0.354 ug/L EPA 200.8 07/20/2016 12:34 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 440 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 21 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021088
Collection Date:08-Jul-16 9:57 AM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.433 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 22 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021089
Collection Date:08-Jul-16 12:08 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.1 mg-N/L EPA 353.2 07/11/2016 11:24 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 41 mg/L EPA 300.0 07/13/2016 22:46 BGN9034110
Sulfate 5.1 mg/L EPA 300.0 07/13/2016 22:46 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:34 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:13 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.163 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.005 1
Barium (Ba)0.127 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.005 1
Boron (B)0.128 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.05 1
Iron (Fe)0.035 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.01 1
Manganese (Mn)0.520 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.005 1
Strontium (Sr)0.117 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.005 1
Zinc (Zn)0.011 mg/L EPA 200.7 07/11/2016 13:51 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.95 mg/L EPA 200.7 07/13/2016 11:39 JJMACKE0.01 1
Magnesium (Mg)6.67 mg/L EPA 200.7 07/13/2016 11:39 JJMACKE0.005 1
Potassium (K)1.64 mg/L EPA 200.7 07/13/2016 11:39 JJMACKE0.1 1
Sodium (Na)9.87 mg/L EPA 200.7 07/13/2016 11:39 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.201 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.005 1
Barium (Ba)0.137 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.005 1
Boron (B)0.132 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.05 1
Iron (Fe)0.125 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.01 1
Manganese (Mn)0.385 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.005 1
Strontium (Sr)0.118 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 09:58 MHH71310.005 1
Duke Energy Analytical Lab
Page 23 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021089
Collection Date:08-Jul-16 12:08 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Copper (Cu)4.85 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 15:59 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA0.2 1
Vanadium (V) Low Level 0.373 ug/L EPA 200.8 07/20/2016 12:41 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 110 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 24 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021089
Collection Date:08-Jul-16 12:08 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.304 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 25 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021090
Collection Date:08-Jul-16 12:30 PM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.2 mg-N/L EPA 353.2 07/11/2016 11:25 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 13 mg/L EPA 300.0 07/13/2016 23:02 BGN90340.5 5
Sulfate 0.24 mg/L EPA 300.0 07/13/2016 23:02 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:36 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:15 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.005 1
Barium (Ba)0.070 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.01 1
Manganese (Mn)0.015 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.005 1
Strontium (Sr)0.119 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 07/11/2016 13:55 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)7.44 mg/L EPA 200.7 07/13/2016 11:51 JJMACKE0.01 1
Magnesium (Mg)2.39 mg/L EPA 200.7 07/13/2016 11:51 JJMACKE0.005 1
Potassium (K)2.21 mg/L EPA 200.7 07/13/2016 11:51 JJMACKE0.1 1
Sodium (Na)7.05 mg/L EPA 200.7 07/13/2016 11:51 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.036 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.005 1
Barium (Ba)0.068 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.05 1
Iron (Fe)0.052 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.005 1
Strontium (Sr)0.114 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 10:02 MHH71310.005 1
Duke Energy Analytical Lab
Page 26 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021090
Collection Date:08-Jul-16 12:30 PM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Copper (Cu)6.78 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA0.2 1
Vanadium (V) Low Level 0.684 ug/L EPA 200.8 07/20/2016 16:41 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA0.2 1
Vanadium (V) Low Level 0.639 ug/L EPA 200.8 07/20/2016 12:49 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 82 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 27 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021090
Collection Date:08-Jul-16 12:30 PM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.179 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 28 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021091
Collection Date:08-Jul-16 1:53 PM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.046 mg-N/L EPA 353.2 07/11/2016 11:26 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 100 mg/L EPA 300.0 07/13/2016 23:17 BGN9034220
Sulfate 69 mg/L EPA 300.0 07/13/2016 23:17 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 12:39 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:18 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.317 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.005 1
Barium (Ba)0.151 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.005 1
Boron (B)0.519 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.01 1
Manganese (Mn)1.61 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.005 1
Strontium (Sr)0.219 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 07/11/2016 13:59 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)36.5 mg/L EPA 200.7 07/13/2016 11:54 JJMACKE0.01 1
Magnesium (Mg)13.1 mg/L EPA 200.7 07/13/2016 11:54 JJMACKE0.005 1
Potassium (K)2.62 mg/L EPA 200.7 07/13/2016 11:54 JJMACKE0.1 1
Sodium (Na)19.3 mg/L EPA 200.7 07/13/2016 11:54 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.327 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.005 1
Barium (Ba)0.150 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.005 1
Boron (B)0.517 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.05 1
Iron (Fe)0.171 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.01 1
Manganese (Mn)1.64 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.005 1
Strontium (Sr)0.228 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 10:22 MHH71310.005 1
Duke Energy Analytical Lab
Page 29 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021091
Collection Date:08-Jul-16 1:53 PM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Cobalt (Co)1.92 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Copper (Cu)7.12 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Lead (Pb)1.22 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 16:06 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Cobalt (Co)1.81 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 12:56 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 360 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 30 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021091
Collection Date:08-Jul-16 1:53 PM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.843 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 31 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021092
Collection Date:08-Jul-16 2:17 PM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/11/2016 11:32M2 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 07/13/2016 23:33 BGN9034220
Sulfate 41 mg/L EPA 300.0 07/13/2016 23:33 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:01 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:35 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.079 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.005 1
Barium (Ba)0.286 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.005 1
Boron (B)0.140 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.05 1
Iron (Fe)53.3 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.1 10
Manganese (Mn)0.728 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.005 1
Strontium (Sr)0.273 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 07/11/2016 14:02 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)22.5 mg/L EPA 200.7 07/13/2016 11:58 JJMACKE0.01 1
Magnesium (Mg)4.83 mg/L EPA 200.7 07/13/2016 11:58 JJMACKE0.005 1
Potassium (K)3.39 mg/L EPA 200.7 07/13/2016 11:58 JJMACKE0.1 1
Sodium (Na)21.8 mg/L EPA 200.7 07/13/2016 11:58 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.098 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.005 1
Barium (Ba)0.283 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.005 1
Boron (B)0.150 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.05 1
Iron (Fe)59.0 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.05 5
Manganese (Mn)0.753 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.005 1
Strontium (Sr)0.280 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 10:06 MHH71310.005 1
Duke Energy Analytical Lab
Page 32 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021092
Collection Date:08-Jul-16 2:17 PM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Cobalt (Co)2.11 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Copper (Cu)3.10 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 16:13 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 13:24 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 300 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 33 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021092
Collection Date:08-Jul-16 2:17 PM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.531 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 34 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021093
Collection Date:08-Jul-16 10:38 AM
Site:CB-01D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.206 mg-N/L EPA 353.2 07/11/2016 11:36 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.5 mg/L EPA 300.0 07/13/2016 22:14 BGN90340.1 1
Sulfate 5.6 mg/L EPA 300.0 07/13/2016 22:14 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:03 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:37 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.005 1
Barium (Ba)0.009 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.05 1
Iron (Fe)0.088 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.01 1
Manganese (Mn)0.062 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.005 1
Strontium (Sr)0.012 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 07/11/2016 14:33 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)1.32 mg/L EPA 200.7 07/13/2016 12:02 JJMACKE0.01 1
Magnesium (Mg)0.698 mg/L EPA 200.7 07/13/2016 12:02 JJMACKE0.005 1
Potassium (K)0.705 mg/L EPA 200.7 07/13/2016 12:02 JJMACKE0.1 1
Sodium (Na)2.10 mg/L EPA 200.7 07/13/2016 12:02 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.195 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.005 1
Barium (Ba)0.011 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.05 1
Iron (Fe)0.163 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.01 1
Manganese (Mn)0.068 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.005 1
Strontium (Sr)0.014 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/18/2016 10:34 MHH71310.005 1
Duke Energy Analytical Lab
Page 35 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021093
Collection Date:08-Jul-16 10:38 AM
Site:CB-01D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Cobalt (Co)2.11 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Copper (Cu)10.4 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Lead (Pb)1.10 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Nickel (Ni)1.60 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 17:10 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Cobalt (Co)2.03 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Copper (Cu)1.39 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Nickel (Ni)1.85 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 13:52 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 36 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021093
Collection Date:08-Jul-16 10:38 AM
Site:CB-01D DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.184 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS 11 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Duke Energy Analytical Lab
Page 37 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021094
Collection Date:08-Jul-16 11:40 AM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:40 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/11/2016 14:37 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Copper (Cu)2.17 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 17:17 JAHERMA0.3 1
Duke Energy Analytical Lab
Page 38 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021095
Collection Date:08-Jul-16 11:40 AM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/11/2016 11:37 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/13/2016 13:14 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 07/13/2016 13:14 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/15/2016 13:05 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 07/13/2016 12:16 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/13/2016 12:16 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/13/2016 12:16 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 07/13/2016 12:16 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/18/2016 10:38 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/20/2016 13:59 JAHERMA0.3 1
Duke Energy Analytical Lab
Page 39 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
2016021095
Collection Date:08-Jul-16 11:40 AM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.163 mg/L SM5310C/EPA9060A 07/15/2016 14:37 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/12/2016 10:05 PARMSTR51
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Duke Energy Analytical Lab
Page 40 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070193 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.001 mg-N/L -10.001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0033 mg-N/L -10.0033 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0018 mg-N/L -10.0018 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.295 3.01 98.2mg-N/L -11090102.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.8mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.29 3.01 96.3mg-N/L -11090102.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060269 -- 2016016737
Nitrite + Nitrate
(Colorimetric)
0.237 0.25 92.6mg-N/L -1109010.237
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060269 -- 2016016737
Nitrite + Nitrate
(Colorimetric)
0.238 0.25 92.9 0.345mg-N/L -1109010.238
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Nitrite + Nitrate
(Colorimetric)
0.0712 0.25 25.3mg-N/L -1109010.0712
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Nitrite + Nitrate
(Colorimetric)
0.0712 0.25 25.3 0mg-N/L -1109010.0712
Duke Energy Analytical Lab
Page 41 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070193 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021093
Nitrite + Nitrate
(Colorimetric)
0.461 0.25 102mg-N/L -1109010.461
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021093
Nitrite + Nitrate
(Colorimetric)
0.458 0.25 101 1.11mg-N/L -1109010.458
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021005
Nitrite + Nitrate
(Colorimetric)
0.237 0.25 92mg-N/L -1109010.237
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021005
Nitrite + Nitrate
(Colorimetric)
0.233 0.25 90.5 1.67mg-N/L -1109010.233
Duke Energy Analytical Lab
Page 42 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070247 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0054 mg/L -10.0054 0.1 < 1/2 RDL
Sulfate -0.0355 mg/L -1-0.0355 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.37 5 99.5mg/L -1208015.37
Sulfate 5.74 5 97.5mg/L -1208015.74
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.39 5 99.9 0.365mg/L -1208015.39
Sulfate 5.76 5 97.9 0.399mg/L -1208015.76
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.39 5 98.7mg/L -1208016.39
Sulfate 4.96 5 98.7mg/L -1208014.96
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.39 5 98.8 0.152mg/L -1208016.39
Sulfate 4.97 5 98.8 0.103mg/L -1208014.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.17 5 103mg/L -1208015.17
Sulfate 5.13 5 103mg/L -1208015.13
Duke Energy Analytical Lab
Page 43 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070263 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0108 mg/L -10.0108 0.1 < 1/2 RDL
Sulfate -0.0459 mg/L -1-0.0459 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 5.42 5 103mg/L -1208015.42
Sulfate 7.51 5 96.2mg/L -1208017.51
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 5.4 5 102 0.424mg/L -1208015.4
Sulfate 7.49 5 95.7 0.561mg/L -1208017.49
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Chloride 6.35 5 102mg/L -1208016.35
Sulfate 8.49 5 97.3mg/L -1208018.49
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Chloride 6.34 5 102 0.157mg/L -1208016.34
Sulfate 8.48 5 97.1 0.198mg/L -1208018.48
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.08 5 102mg/L -1208015.08
Sulfate 5.05 5 101mg/L -1208015.05
Duke Energy Analytical Lab
Page 44 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070364 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.01 1 99.5ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.997 1 97.7 1.83ug/L -1307010.997
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.967 1 96.1ug/L -1307010.967
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.96 1 95.4 0.731ug/L -1307010.96
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
Mercury (Hg) 0.999 1 98.7ug/L -1307010.999
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1 1 98.8 0.101ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.97 2 98.5ug/L -1158511.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.8ug/L -1158511.88
Duke Energy Analytical Lab
Page 45 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070366 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.001 ug/L -10.001 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.006 ug/L -10.006 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.97 2 98.5ug/L -1158511.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.8ug/L -1158511.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Mercury (Hg) 1.01 1 99.5ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Mercury (Hg) 0.997 1 97.7 1.83ug/L -1307010.997
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021005
Mercury (Hg) 0.967 1 96.1ug/L -1307010.967
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021005
Mercury (Hg) 0.96 1 95.4 0.731ug/L -1307010.96
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021084
Mercury (Hg) 0.999 1 98.7ug/L -1307010.999
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021084
Mercury (Hg) 1 1 98.8 0.101ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021086
Mercury (Hg) 0.948 1 94.3ug/L -1307010.948
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021086
Mercury (Hg) 0.935 1 93 1.39ug/L -1307010.935
Duke Energy Analytical Lab
Page 46 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070211 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000647 mg/L -1-0.000647 0.005 < 1/2 RDL
Barium (Ba) -0.000142 mg/L -1-0.000142 0.005 < 1/2 RDL
Boron (B) -0.00238 mg/L -1-0.00238 0.05 < 1/2 RDL
Iron (Fe) -0.00117 mg/L -1-0.00117 0.01 < 1/2 RDL
Manganese (Mn) -0.000442 mg/L -1-0.000442 0.005 < 1/2 RDL
Strontium (Sr) 0.00006 mg/L -10.00006 0.005 < 1/2 RDL
Zinc (Zn) -0.000932 mg/L -1-0.000932 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.06 2 103mg/L -1158512.06
Barium (Ba) 1 1 100mg/L -1158511
Boron (B) 2.02 2 101mg/L -1158512.02
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.99 1 99mg/L -1158510.99
Strontium (Sr) 1.93 2 96.3mg/L -1158511.93
Zinc (Zn) 1.04 1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.53 5 110mg/L -1307015.53
Barium (Ba) 5.34 5 107mg/L -1307015.34
Boron (B) 5.2 5 104mg/L -1307015.2
Iron (Fe) 5.23 5 103mg/L -1307015.23
Manganese (Mn) 5.5 5 109mg/L -1307015.5
Strontium (Sr) 5.11 5 102mg/L -1307015.11
Zinc (Zn) 5.34 5 107mg/L -1307015.34
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.52 5 110 0.145mg/L -1307015.52
Barium (Ba) 5.31 5 106 0.677mg/L -1307015.31
Boron (B) 5.2 5 104 0mg/L -1307015.2
Iron (Fe) 5.23 5 103 0mg/L -1307015.23
Manganese (Mn) 5.49 5 109 0.184mg/L -1307015.49
Strontium (Sr) 5.12 5 102 0.137mg/L -1307015.12
Zinc (Zn) 5.35 5 107 0.0751mg/L -1307015.35
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Aluminum (Al) 5.49 5 108mg/L -1307015.49
Duke Energy Analytical Lab
Page 47 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070211 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Barium (Ba) 5.58 5 106mg/L -1307015.58
Boron (B) 5.31 5 103mg/L -1307015.31
Iron (Fe) 5.73 5 79.6mg/L -130701057.3
Manganese (Mn) 6.14 5 108mg/L -1307016.14
Strontium (Sr) 5.37 5 102mg/L -1307015.37
Zinc (Zn) 5.26 5 105mg/L -1307015.26
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Aluminum (Al) 5.48 5 108 0.203mg/L -1307015.48
Barium (Ba) 5.61 5 107 0.678mg/L -1307015.61
Boron (B) 5.32 5 104 0.174mg/L -1307015.32
Iron (Fe) 5.76 5 85.5 7.17mg/L -130701057.6
Manganese (Mn) 6.11 5 108 0.445mg/L -1307016.11
Strontium (Sr) 5.39 5 102 0.372mg/L -1307015.39
Zinc (Zn) 5.24 5 105 0.286mg/L -1307015.24
Duke Energy Analytical Lab
Page 48 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.000804 mg/L -10.000804 0.01 < 1/2 RDL
Magnesium (Mg) -0.000016 mg/L -1-0.000016 0.005 < 1/2 RDL
Potassium (K) 0.0121 mg/L -10.0121 0.1 < 1/2 RDL
Sodium (Na) -0.0204 mg/L -1-0.0204 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.0025 mg/L -10.0025 0.01 < 1/2 RDL
Magnesium (Mg) 0.000113 mg/L -10.000113 0.005 < 1/2 RDL
Potassium (K) 0.00296 mg/L -10.00296 0.1 < 1/2 RDL
Sodium (Na) -0.0187 mg/L -1-0.0187 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.5mg/L -1158513.98
Sodium (Na) 8.29 8.1 102mg/L -1158518.29
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.07 2 103mg/L -1158512.07
Magnesium (Mg) 2.01 2 101mg/L -1158512.01
Potassium (K) 4.01 4 100mg/L -1158514.01
Sodium (Na) 8.36 8.1 103mg/L -1158518.36
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 179 5 0mg/L -130701179
Magnesium (Mg) 6.53 5 100mg/L -1307016.53
Potassium (K) 148 5 272mg/L -130701148
Sodium (Na) 460 5 0mg/L -130701460
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 178 5 0 0mg/L -130701178
Magnesium (Mg) 6.49 5 99.2 0.763mg/L -1307016.49
Potassium (K) 146 5 246 10mg/L -130701146
Sodium (Na) 457 5 0 0mg/L -130701457
Duke Energy Analytical Lab
Page 49 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 102mg/L -13070112
Magnesium (Mg) 11.5 5 96mg/L -13070111.5
Potassium (K) 6.76 5 103mg/L -1307016.76
Sodium (Na) 14 5 82.3mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 101 0.0197mg/L -13070112
Magnesium (Mg) 11.5 5 96 0.0208mg/L -13070111.5
Potassium (K) 6.78 5 103 0.331mg/L -1307016.78
Sodium (Na) 14 5 82 0.438mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104mg/L -13070110.6
Magnesium (Mg) 9.21 5 106mg/L -1307019.21
Potassium (K) 6.52 5 105mg/L -1307016.52
Sodium (Na) 16.4 5 88.3mg/L -13070116.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104 0.154mg/L -13070110.6
Magnesium (Mg) 9.17 5 105 0.797mg/L -1307019.17
Potassium (K) 6.5 5 105 0.325mg/L -1307016.5
Sodium (Na) 16.2 5 86.3 2.36mg/L -13070116.2
Duke Energy Analytical Lab
Page 50 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070382 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.00106 mg/L -10.00106 0.005 < 1/2 RDL
Barium (Ba) 0.00003 mg/L -10.00003 0.005 < 1/2 RDL
Boron (B) 0.00157 mg/L -10.00157 0.05 < 1/2 RDL
Iron (Fe) 0.00113 mg/L -10.00113 0.01 < 1/2 RDL
Manganese (Mn) 0.00046 mg/L -10.00046 0.005 < 1/2 RDL
Strontium (Sr) 0.000511 mg/L -10.000511 0.005 < 1/2 RDL
Zinc (Zn) 0.000765 mg/L -10.000765 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 4.95 5 98.9mg/L -1158514.95
Barium (Ba) 5.18 5 104mg/L -1158515.18
Boron (B) 5.03 5 101mg/L -1158515.03
Iron (Fe) 5.24 5 105mg/L -1158515.24
Manganese (Mn) 5.15 5 103mg/L -1158515.15
Strontium (Sr) 5.03 5 101mg/L -1158515.03
Zinc (Zn) 5.14 5 103mg/L -1158515.14
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.84 5 112mg/L -1307015.84
Barium (Ba) 5.19 5 104mg/L -1307015.19
Boron (B) 5.04 5 101mg/L -1307015.04
Iron (Fe) 5.51 5 106mg/L -1307015.51
Manganese (Mn) 5.21 5 103mg/L -1307015.21
Strontium (Sr) 5.06 5 101mg/L -1307015.06
Zinc (Zn) 5.12 5 102mg/L -1307015.12
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.74 5 110 1.91mg/L -1307015.74
Barium (Ba) 5.15 5 103 0.659mg/L -1307015.15
Boron (B) 5.03 5 100 0.0995mg/L -1307015.03
Iron (Fe) 5.44 5 105 1.29mg/L -1307015.44
Manganese (Mn) 5.17 5 102 0.957mg/L -1307015.17
Strontium (Sr) 5.05 5 101 0.218mg/L -1307015.05
Zinc (Zn) 5.08 5 101 0.825mg/L -1307015.08
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021091
Aluminum (Al) 5.04 5 94.3mg/L -1307015.04
Duke Energy Analytical Lab
Page 51 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070382 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021091
Barium (Ba) 5.18 5 101mg/L -1307015.18
Boron (B) 5.48 5 99.3mg/L -1307015.48
Iron (Fe) 5.21 5 101mg/L -1307015.21
Manganese (Mn) 6.6 5 99.2mg/L -1307016.6
Strontium (Sr) 5.13 5 98mg/L -1307015.13
Zinc (Zn) 4.91 5 98.1mg/L -1307014.91
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021091
Aluminum (Al) 5.13 5 96.1 1.95mg/L -1307015.13
Barium (Ba) 5.29 5 103 2.01mg/L -1307015.29
Boron (B) 5.58 5 101 1.93mg/L -1307015.58
Iron (Fe) 5.32 5 103 2.08mg/L -1307015.32
Manganese (Mn) 6.7 5 101 1.98mg/L -1307016.7
Strontium (Sr) 5.2 5 99.5 1.44mg/L -1307015.2
Zinc (Zn) 5.01 5 100 2.14mg/L -1307015.01
Duke Energy Analytical Lab
Page 52 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070416 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.0817 ug/L -10.0817 1 < 1/2 RDL
Arsenic (As) 0.0042 ug/L -10.0042 1 < 1/2 RDL
Beryllium (Be) 0 ug/L -10 1 < 1/2 RDL
Cadmium (Cd) -0.0134 ug/L -1-0.0134 1 < 1/2 RDL
Chromium (Cr) 0.0112 ug/L -10.0112 1 < 1/2 RDL
Cobalt (Co) -0.0042 ug/L -1-0.0042 1 < 1/2 RDL
Copper (Cu) -0.0383 ug/L -1-0.0383 1 < 1/2 RDL
Lead (Pb) -0.0092 ug/L -1-0.0092 1 < 1/2 RDL
Molybdenum (Mo) 0.0164 ug/L -10.0164 1 < 1/2 RDL
Nickel (Ni) -0.156 ug/L -1-0.156 1 < 1/2 RDL
Selenium (Se) 0.0127 ug/L -10.0127 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0935 ug/L -1-0.0935 0.2 < 1/2 RDL
Vanadium (V) Low Level -0.018 ug/L -1-0.018 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 52.4 50 105ug/L -11585152.4
Arsenic (As) 50.8 50 102ug/L -11585150.8
Beryllium (Be) 50.8 50 102ug/L -11585150.8
Cadmium (Cd) 49.4 50 98.9ug/L -11585149.4
Chromium (Cr) 52 50 104ug/L -11585152
Cobalt (Co) 52.2 50 104ug/L -11585152.2
Copper (Cu) 50.5 50 101ug/L -11585150.5
Lead (Pb) 50.8 50 102ug/L -11585150.8
Molybdenum (Mo) 50.7 50 101ug/L -11585150.7
Nickel (Ni) 51.3 50 103ug/L -11585151.3
Selenium (Se) 51.4 50 103ug/L -11585151.4
Thallium (Tl) Low Level 47.6 50 95.2ug/L -11585147.6
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Antimony (Sb) 51.6 50 103ug/L -13070151.6
Arsenic (As) 50.4 50 100ug/L -13070150.4
Beryllium (Be) 49.6 50 99.3ug/L -13070149.6
Cadmium (Cd) 48.8 50 97.6ug/L -13070148.8
Chromium (Cr) 49.8 50 99.5ug/L -13070149.8
Cobalt (Co) 51.6 50 98.9ug/L -13070151.6
Copper (Cu) 58.7 50 97.5ug/L -13070158.7
Lead (Pb) 50.5 50 98.9ug/L -13070150.5
Molybdenum (Mo) 48.2 50 96ug/L -13070148.2
Duke Energy Analytical Lab
Page 53 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070416 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Nickel (Ni) 51.8 50 99.7ug/L -13070151.8
Selenium (Se) 50.9 50 102ug/L -13070150.9
Thallium (Tl) Low Level 45 50 90.2ug/L -13070145
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Antimony (Sb) 50.7 50 101 1.86ug/L -13070150.7
Arsenic (As) 49.9 50 99.4 1.02ug/L -13070149.9
Beryllium (Be) 47.9 50 95.8 3.55ug/L -13070147.9
Cadmium (Cd) 49.7 50 99.3 1.73ug/L -13070149.7
Chromium (Cr) 49.3 50 98.5 0.99ug/L -13070149.3
Cobalt (Co) 51.5 50 98.6 0.263ug/L -13070151.5
Copper (Cu) 58.9 50 97.9 0.43ug/L -13070158.9
Lead (Pb) 50.8 50 99.6 0.665ug/L -13070150.8
Molybdenum (Mo) 49.1 50 97.7 1.8ug/L -13070149.1
Nickel (Ni) 52.5 50 101 1.39ug/L -13070152.5
Selenium (Se) 50.9 50 102 0.0983ug/L -13070150.9
Thallium (Tl) Low Level 46.1 50 92.2 2.24ug/L -13070146.1
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021090
Antimony (Sb) 49.9 50 99.7ug/L -13070149.9
Arsenic (As) 51 50 102ug/L -13070151
Beryllium (Be) 48.8 50 97.5ug/L -13070148.8
Cadmium (Cd) 48.5 50 97.1ug/L -13070148.5
Chromium (Cr) 50.4 50 100ug/L -13070150.4
Cobalt (Co) 50 50 99.9ug/L -13070150
Copper (Cu) 55.2 50 96.9ug/L -13070155.2
Lead (Pb) 50.6 50 99.3ug/L -13070150.6
Molybdenum (Mo) 49.1 50 98.1ug/L -13070149.1
Nickel (Ni) 50.4 50 101ug/L -13070150.4
Selenium (Se) 51.1 50 102ug/L -13070151.1
Thallium (Tl) Low Level 45.2 50 90.6ug/L -13070145.2
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021090
Antimony (Sb) 49.8 50 99.5 0.241ug/L -13070149.8
Arsenic (As) 50.5 50 101 1.14ug/L -13070150.5
Beryllium (Be) 48.5 50 97 0.535ug/L -13070148.5
Cadmium (Cd) 48.2 50 96.4 0.703ug/L -13070148.2
Duke Energy Analytical Lab
Page 54 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070416 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021090
Chromium (Cr) 50.6 50 101 0.398ug/L -13070150.6
Cobalt (Co) 49.8 50 99.6 0.361ug/L -13070149.8
Copper (Cu) 57.1 50 101 3.87ug/L -13070157.1
Lead (Pb) 50.8 50 99.7 0.482ug/L -13070150.8
Molybdenum (Mo) 49.1 50 98.2 0.102ug/L -13070149.1
Nickel (Ni) 48.7 50 98 3.41ug/L -13070148.7
Selenium (Se) 50.8 50 101 0.746ug/L -13070150.8
Thallium (Tl) Low Level 45.5 50 91.2 0.638ug/L -13070145.5
Duke Energy Analytical Lab
Page 55 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070386 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0183 ug/L -1-0.0183 1 < 1/2 RDL
Arsenic (As) 0.018 ug/L -10.018 1 < 1/2 RDL
Beryllium (Be) 0 ug/L -10 1 < 1/2 RDL
Cadmium (Cd) -0.0134 ug/L -1-0.0134 1 < 1/2 RDL
Chromium (Cr) 0.133 ug/L -10.133 1 < 1/2 RDL
Cobalt (Co) -0.0001 ug/L -1-0.0001 1 < 1/2 RDL
Copper (Cu) 0.0222 ug/L -10.0222 1 < 1/2 RDL
Lead (Pb) -0.0131 ug/L -1-0.0131 1 < 1/2 RDL
Molybdenum (Mo) 0.0121 ug/L -10.0121 1 < 1/2 RDL
Nickel (Ni) 0.179 ug/L -10.179 1 < 1/2 RDL
Selenium (Se) -0.0004 ug/L -1-0.0004 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0441 ug/L -1-0.0441 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0284 ug/L -10.0284 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.8 50 99.6ug/L -11585149.8
Arsenic (As) 48.4 50 96.9ug/L -11585148.4
Beryllium (Be) 47.1 50 94.3ug/L -11585147.1
Cadmium (Cd) 49.2 50 98.4ug/L -11585149.2
Chromium (Cr) 49 50 98ug/L -11585149
Cobalt (Co) 47.6 50 95.3ug/L -11585147.6
Copper (Cu) 50.6 50 101ug/L -11585150.6
Lead (Pb) 49.9 50 99.9ug/L -11585149.9
Molybdenum (Mo) 49.3 50 98.6ug/L -11585149.3
Nickel (Ni) 49.8 50 99.6ug/L -11585149.8
Selenium (Se) 50.5 50 101ug/L -11585150.5
Thallium (Tl) Low Level 47.5 50 95ug/L -11585147.5
Vanadium (V) Low Level 50 50 99.9ug/L -11585150
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021084
Antimony (Sb) 49.2 50 98.4ug/L -13070149.2
Arsenic (As) 48.3 50 96.5ug/L -13070148.3
Beryllium (Be) 47.5 50 95ug/L -13070147.5
Cadmium (Cd) 48.7 50 97.4ug/L -13070148.7
Chromium (Cr) 48.6 50 96.6ug/L -13070148.6
Cobalt (Co) 47.9 50 95.5ug/L -13070147.9
Copper (Cu) 48.7 50 96.9ug/L -13070148.7
Lead (Pb) 48.8 50 97.6ug/L -13070148.8
Duke Energy Analytical Lab
Page 56 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070386 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021084
Molybdenum (Mo) 48.3 50 96.1ug/L -13070148.3
Nickel (Ni) 47.7 50 94ug/L -13070147.7
Selenium (Se) 49 50 97.9ug/L -13070149
Thallium (Tl) Low Level 47.9 50 95.8ug/L -13070147.9
Vanadium (V) Low Level 47.4 50 94ug/L -13070147.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021084
Antimony (Sb) 49.2 50 98.5 0.102ug/L -13070149.2
Arsenic (As) 47.8 50 95.5 1.04ug/L -13070147.8
Beryllium (Be) 49.4 50 98.8 3.92ug/L -13070149.4
Cadmium (Cd) 48.8 50 97.6 0.267ug/L -13070148.8
Chromium (Cr) 48.1 50 95.8 0.873ug/L -13070148.1
Cobalt (Co) 48.5 50 96.6 1.17ug/L -13070148.5
Copper (Cu) 48.5 50 96.5 0.476ug/L -13070148.5
Lead (Pb) 49.2 50 98.4 0.837ug/L -13070149.2
Molybdenum (Mo) 48.6 50 96.7 0.623ug/L -13070148.6
Nickel (Ni) 48.9 50 96.5 2.56ug/L -13070148.9
Selenium (Se) 48.3 50 96.5 1.4ug/L -13070148.3
Thallium (Tl) Low Level 48.5 50 97 1.29ug/L -13070148.5
Vanadium (V) Low Level 48.4 50 96.1 2.19ug/L -13070148.4
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Antimony (Sb) 50.5 50 101ug/L -13070150.5
Arsenic (As) 51 50 101ug/L -13070151
Beryllium (Be) 49.6 50 99.2ug/L -13070149.6
Cadmium (Cd) 48.7 50 97.4ug/L -13070148.7
Chromium (Cr) 50.1 50 100ug/L -13070150.1
Cobalt (Co) 49.9 50 98.1ug/L -13070149.9
Copper (Cu) 49.3 50 98.1ug/L -13070149.3
Lead (Pb) 49.5 50 99ug/L -13070149.5
Molybdenum (Mo) 49.7 50 98.6ug/L -13070149.7
Nickel (Ni) 50.9 50 102ug/L -13070150.9
Selenium (Se) 49.7 50 99.2ug/L -13070149.7
Thallium (Tl) Low Level 44.3 50 88.8ug/L -13070144.3
Vanadium (V) Low Level 51.8 50 103ug/L -13070151.8
Duke Energy Analytical Lab
Page 57 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070386 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Antimony (Sb) 49.5 50 98.8 1.96ug/L -13070149.5
Arsenic (As) 51.8 50 103 1.59ug/L -13070151.8
Beryllium (Be) 52.8 50 106 6.25ug/L -13070152.8
Cadmium (Cd) 49.5 50 99 1.67ug/L -13070149.5
Chromium (Cr) 50.7 50 101 1.25ug/L -13070150.7
Cobalt (Co) 50.2 50 98.7 0.671ug/L -13070150.2
Copper (Cu) 49.8 50 99.2 1.14ug/L -13070149.8
Lead (Pb) 49.9 50 99.8 0.784ug/L -13070149.9
Molybdenum (Mo) 51.6 50 102 3.86ug/L -13070151.6
Nickel (Ni) 49.6 50 99.8 2.53ug/L -13070149.6
Selenium (Se) 51.5 50 103 3.7ug/L -13070151.5
Thallium (Tl) Low Level 45.2 50 90.6 2.01ug/L -13070145.2
Vanadium (V) Low Level 50.7 50 101 2.15ug/L -13070150.7
Duke Energy Analytical Lab
Page 58 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070252 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070200 -- 2016020918
TDS 6.9mg/L -184
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070200 -- 2016020919
TDS 2.48mg/L -1637
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16070200 -- 2016020920
TDS 1.07mg/L -1649
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 103mg/L -110901103
Duke Energy Analytical Lab
Page 59 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070294 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.025 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.049 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 96.6mg/L -1208013.68
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 103 6.85mg/L -1208013.82
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208012.39
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 103 2.69mg/L -1208012.33
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 98.8mg/L -1208012.82
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 103 4.31mg/L -1208012.9
Final QualifierDilMeasuredUnits:Parameter
IS # 4
% Recovery LCL UCLSpike
TOC 2 102mg/L -1208013.46
Final QualifierDilMeasuredUnits:Parameter
ISD # 4
RPD% Recovery LCL UCLSpike
TOC 2 99.3 2.29mg/L -1208013.41
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.92
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 102mg/L -1158512.93
Duke Energy Analytical Lab
Page 60 of 116
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070225
Q16070215 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060267 -- 2016016733
TSS 0mg/L -116
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16060267 -- 2016016734
TSS 0mg/L -110
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 99.2mg/L -11090149.6
Duke Energy Analytical Lab
Page 61 of 116
#=CL#
July 19, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92304520
92304520
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070225
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 11, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Bishop for
[e-mail]
HORIZON Database Administrator
Kevin Herring
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 32
Duke Energy Analytical Lab
Page 62 of 116
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92304520
J16070225
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 32
Duke Energy Analytical Lab
Page 63 of 116
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92304520
J16070225
Lab ID Sample ID Matrix Date Collected Date Received
92304520001 2016021083 Water 07/08/16 10:38 07/11/16 10:05
92304520002 2016021084 Water 07/08/16 14:45 07/11/16 10:05
92304520003 2016021085 Water 07/08/16 14:23 07/11/16 10:05
92304520004 2016021086 Water 07/08/16 13:20 07/11/16 10:05
92304520005 2016021087 Water 07/08/16 09:28 07/11/16 10:05
92304520006 2016021088 Water 07/08/16 09:57 07/11/16 10:05
92304520007 2016021089 Water 07/08/16 12:08 07/11/16 10:05
92304520008 2016021090 Water 07/08/16 12:30 07/11/16 10:05
92304520009 2016021091 Water 07/08/16 13:53 07/11/16 10:05
92304520010 2016021092 Water 07/08/16 14:17 07/11/16 10:05
92304520011 2016021093 Water 07/08/16 10:38 07/11/16 10:05
92304520012 2016021095 Water 07/08/16 11:40 07/11/16 10:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 32
Duke Energy Analytical Lab
Page 64 of 116
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304520
J16070225
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92304520001 2016021083 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520002 2016021084 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520003 2016021085 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520004 2016021086 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520005 2016021087 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520006 2016021088 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520007 2016021089 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520008 2016021090 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520009 2016021091 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520010 2016021092 RSK 175 Modified 1 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 32
Duke Energy Analytical Lab
Page 65 of 116
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304520
J16070225
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520011 2016021093 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304520012 2016021095 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 32
Duke Energy Analytical Lab
Page 66 of 116
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92304520
J16070225
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92304520001 2016021083
Alkalinity,Bicarbonate (CaCO3)7.7 mg/L 07/14/16 19:445.0SM 2320B
Alkalinity, Total as CaCO3 7.7 mg/L 07/14/16 19:445.0SM 2320B
92304520002 2016021084
Alkalinity,Bicarbonate (CaCO3)33.0 mg/L 07/14/16 19:535.0SM 2320B
Alkalinity, Total as CaCO3 33.0 mg/L 07/14/16 19:535.0SM 2320B
Chromium, Hexavalent 0.22 ug/L 07/14/16 15:430.030EPA 218.7
92304520003 2016021085
Methane 62.3 ug/L 07/15/16 17:4810.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)10.6 mg/L 07/14/16 22:285.0SM 2320B
Alkalinity, Total as CaCO3 10.6 mg/L 07/14/16 22:285.0SM 2320B
Chromium, Hexavalent 0.14 ug/L 07/14/16 15:560.030EPA 218.7
92304520004 2016021086
Alkalinity,Bicarbonate (CaCO3)7.8 mg/L 07/15/16 15:125.0SM 2320B
Alkalinity, Total as CaCO3 7.8 mg/L 07/15/16 15:125.0SM 2320B
Chromium, Hexavalent 0.26 ug/L 07/14/16 16:090.030EPA 218.7
92304520005 2016021087
Methane 28.8 ug/L 07/15/16 18:1810.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)26.1 mg/L 07/15/16 15:465.0SM 2320B
Alkalinity, Total as CaCO3 26.1 mg/L 07/15/16 15:465.0SM 2320B
Chromium, Hexavalent 0.26 ug/L 07/14/16 16:220.030EPA 218.7
92304520006 2016021088
Alkalinity,Bicarbonate (CaCO3)9.8 mg/L 07/15/16 15:585.0SM 2320B
Alkalinity, Total as CaCO3 9.8 mg/L 07/15/16 15:585.0SM 2320B
Chromium, Hexavalent 0.28 ug/L 07/14/16 16:350.030EPA 218.7
92304520008 2016021090
Alkalinity,Bicarbonate (CaCO3)23.4 mg/L 07/15/16 16:185.0SM 2320B
Alkalinity, Total as CaCO3 23.4 mg/L 07/15/16 16:185.0SM 2320B
Chromium, Hexavalent 0.24 ug/L 07/14/16 17:27 M10.030EPA 218.7
92304520009 2016021091
Chromium, Hexavalent 0.048 ug/L 07/14/16 18:060.030EPA 218.7
92304520010 2016021092
Methane 40.0 ug/L 07/15/16 19:3410.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)24.4 mg/L 07/15/16 16:575.0SM 2320B
Alkalinity, Total as CaCO3 24.4 mg/L 07/15/16 16:575.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 32
Duke Energy Analytical Lab
Page 67 of 116
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304520
J16070225
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 19, 2016
Description:RSK 175 Headspace
General Information:
12 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below
or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 32
Duke Energy Analytical Lab
Page 68 of 116
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304520
J16070225
Method:
Client:Duke Energy
SM 2320B
Date:July 19, 2016
Description:2320B Alkalinity
General Information:
12 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321304
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304520004,92304603002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1780687)
• Alkalinity, Total as CaCO3
R1: RPD value was outside control limits.
• MSD (Lab ID: 1780687)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 32
Duke Energy Analytical Lab
Page 69 of 116
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304520
J16070225
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 19, 2016
Description:4500S2D Sulfide Water
General Information:
12 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321058
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304497002,92304520001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1779226)
• Sulfide
• MS (Lab ID: 1779228)
• Sulfide
• MSD (Lab ID: 1779227)
• Sulfide
• MSD (Lab ID: 1779229)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 32
Duke Energy Analytical Lab
Page 70 of 116
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304520
J16070225
Method:
Client:Duke Energy
EPA 218.7
Date:July 19, 2016
Description:Hexavalent Chromium by IC
General Information:
11 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 308763
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304517001,92304520008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1636585)
• Chromium, Hexavalent
• MSD (Lab ID: 1636586)
• Chromium, Hexavalent
Additional Comments:
Analyte Comments:
QC Batch: 308763
D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.
• 2016021092 (Lab ID: 92304520010)
• Chromium, Hexavalent
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• MS (Lab ID: 1636583)
• Chromium, Hexavalent
• MSD (Lab ID: 1636584)
• Chromium, Hexavalent
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 32
Duke Energy Analytical Lab
Page 71 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021083 Lab ID:92304520001 Collected:07/08/16 10:38 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 17:17 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.7 mg/L 07/14/16 19:445.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 19:445.0 1
Alkalinity, Total as CaCO3 7.7 mg/L 07/14/16 19:445.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-8 M10.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/14/16 15:30 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 32
Duke Energy Analytical Lab
Page 72 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021084 Lab ID:92304520002 Collected:07/08/16 14:45 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 17:32 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)33.0 mg/L 07/14/16 19:535.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 19:535.0 1
Alkalinity, Total as CaCO3 33.0 mg/L 07/14/16 19:535.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.22 ug/L 07/14/16 15:43 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 32
Duke Energy Analytical Lab
Page 73 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021085 Lab ID:92304520003 Collected:07/08/16 14:23 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 62.3 ug/L 07/15/16 17:48 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.6 mg/L 07/14/16 22:285.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 22:285.0 1
Alkalinity, Total as CaCO3 10.6 mg/L 07/14/16 22:285.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.14 ug/L 07/14/16 15:56 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 13 of 32
Duke Energy Analytical Lab
Page 74 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021086 Lab ID:92304520004 Collected:07/08/16 13:20 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 18:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.8 mg/L 07/15/16 15:125.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 15:125.0 1
Alkalinity, Total as CaCO3 7.8 mg/L 07/15/16 15:125.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.26 ug/L 07/14/16 16:09 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 14 of 32
Duke Energy Analytical Lab
Page 75 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021087 Lab ID:92304520005 Collected:07/08/16 09:28 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 28.8 ug/L 07/15/16 18:18 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)26.1 mg/L 07/15/16 15:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 15:465.0 1
Alkalinity, Total as CaCO3 26.1 mg/L 07/15/16 15:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.26 ug/L 07/14/16 16:22 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 32
Duke Energy Analytical Lab
Page 76 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021088 Lab ID:92304520006 Collected:07/08/16 09:57 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 18:33 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)9.8 mg/L 07/15/16 15:585.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 15:585.0 1
Alkalinity, Total as CaCO3 9.8 mg/L 07/15/16 15:585.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.28 ug/L 07/14/16 16:35 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 32
Duke Energy Analytical Lab
Page 77 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021089 Lab ID:92304520007 Collected:07/08/16 12:08 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 18:49 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/15/16 16:095.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 16:095.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/15/16 16:095.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/14/16 16:48 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 32
Duke Energy Analytical Lab
Page 78 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021090 Lab ID:92304520008 Collected:07/08/16 12:30 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 19:04 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)23.4 mg/L 07/15/16 16:185.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 16:185.0 1
Alkalinity, Total as CaCO3 23.4 mg/L 07/15/16 16:185.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.24 ug/L 07/14/16 17:27 18540-29-9 M10.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 32
Duke Energy Analytical Lab
Page 79 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021091 Lab ID:92304520009 Collected:07/08/16 13:53 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 19:19 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/15/16 16:295.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 16:295.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/15/16 16:295.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.048 ug/L 07/14/16 18:06 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 32
Duke Energy Analytical Lab
Page 80 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021092 Lab ID:92304520010 Collected:07/08/16 14:17 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 40.0 ug/L 07/15/16 19:34 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)24.4 mg/L 07/15/16 16:575.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 16:575.0 1
Alkalinity, Total as CaCO3 24.4 mg/L 07/15/16 16:575.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/14/16 18:19 18540-29-9 D30.60 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 32
Duke Energy Analytical Lab
Page 81 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021093 Lab ID:92304520011 Collected:07/08/16 10:38 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 19:50 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/15/16 17:085.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 17:085.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/15/16 17:085.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/14/16 18:32 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 32
Duke Energy Analytical Lab
Page 82 of 116
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304520
J16070225
Sample:2016021095 Lab ID:92304520012 Collected:07/08/16 11:40 Received:07/11/16 10:05 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/15/16 20:05 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/15/16 17:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/15/16 17:165.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/15/16 17:165.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 32
Duke Energy Analytical Lab
Page 83 of 116
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304520
J16070225
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321404
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304520001, 92304520002, 92304520003, 92304520004, 92304520005, 92304520006, 92304520007,
92304520008, 92304520009, 92304520010, 92304520011, 92304520012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1781373
Associated Lab Samples:92304520001, 92304520002, 92304520003, 92304520004, 92304520005, 92304520006, 92304520007,
92304520008, 92304520009, 92304520010, 92304520011, 92304520012
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/15/16 16:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1781374LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1781376
Methane ug/L 369 N23969370-13093367 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 32
Duke Energy Analytical Lab
Page 84 of 116
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304520
J16070225
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321132
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304520001, 92304520002, 92304520003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779577
Associated Lab Samples:92304520001, 92304520002, 92304520003
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/14/16 17:06
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/14/16 17:06
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/14/16 17:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779578LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.450 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779579MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304420005
1779580
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 85 80-12087 1 255036.9 79.6 80.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779581MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520002
1779582
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 91 80-12090 1 255033.0 78.5 78.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 32
Duke Energy Analytical Lab
Page 85 of 116
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304520
J16070225
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321304
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304520004, 92304520005, 92304520006, 92304520007, 92304520008, 92304520009, 92304520010,
92304520011, 92304520012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1780682
Associated Lab Samples:92304520004, 92304520005, 92304520006, 92304520007, 92304520008, 92304520009, 92304520010,
92304520011, 92304520012
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/15/16 14:50
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/15/16 14:50
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/15/16 14:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1780683LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.750 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1780684MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520004
1780685
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 95 80-12092 2 25507.8 55.1 54.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1780686MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304603002
1780687
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1,R1509380-120130 33 2550ND46.3 65.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 32
Duke Energy Analytical Lab
Page 86 of 116
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304520
J16070225
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321058
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304520001, 92304520002, 92304520003, 92304520004, 92304520005, 92304520006, 92304520007,
92304520008, 92304520009, 92304520010, 92304520011, 92304520012
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779224
Associated Lab Samples:92304520001, 92304520002, 92304520003, 92304520004, 92304520005, 92304520006, 92304520007,
92304520008, 92304520009, 92304520010, 92304520011, 92304520012
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/13/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779225LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779226MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304497002
1779227
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 125 90-110125 0 10.5ND 0.63 0.63
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779228MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520001
1779229
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 113 90-110113 0 10.5ND 0.59 0.59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 32
Duke Energy Analytical Lab
Page 87 of 116
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304520
J16070225
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
308763
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92304520001, 92304520002, 92304520003, 92304520004, 92304520005, 92304520006, 92304520007,
92304520008, 92304520009, 92304520010, 92304520011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1636581
Associated Lab Samples:92304520001, 92304520002, 92304520003, 92304520004, 92304520005, 92304520006, 92304520007,
92304520008, 92304520009, 92304520010, 92304520011
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/14/16 13:59
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1636582LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.075.075 101 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1636583MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304517001
1636584
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L E.075 93 85-11597 1 20.0750.28 0.35 0.35
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1636585MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520008
1636586
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 156 85-115125 3 20.0250.24 0.27 0.27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
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[phone]
Page 27 of 32
Duke Energy Analytical Lab
Page 88 of 116
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92304520
J16070225
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 32
Duke Energy Analytical Lab
Page 89 of 116
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304520
J16070225
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92304520001 3214042016021083RSK 175 Modified
92304520002 3214042016021084RSK 175 Modified
92304520003 3214042016021085RSK 175 Modified
92304520004 3214042016021086RSK 175 Modified
92304520005 3214042016021087RSK 175 Modified
92304520006 3214042016021088RSK 175 Modified
92304520007 3214042016021089RSK 175 Modified
92304520008 3214042016021090RSK 175 Modified
92304520009 3214042016021091RSK 175 Modified
92304520010 3214042016021092RSK 175 Modified
92304520011 3214042016021093RSK 175 Modified
92304520012 3214042016021095RSK 175 Modified
92304520001 3211322016021083SM 2320B
92304520002 3211322016021084SM 2320B
92304520003 3211322016021085SM 2320B
92304520004 3213042016021086SM 2320B
92304520005 3213042016021087SM 2320B
92304520006 3213042016021088SM 2320B
92304520007 3213042016021089SM 2320B
92304520008 3213042016021090SM 2320B
92304520009 3213042016021091SM 2320B
92304520010 3213042016021092SM 2320B
92304520011 3213042016021093SM 2320B
92304520012 3213042016021095SM 2320B
92304520001 3210582016021083SM 4500-S2D
92304520002 3210582016021084SM 4500-S2D
92304520003 3210582016021085SM 4500-S2D
92304520004 3210582016021086SM 4500-S2D
92304520005 3210582016021087SM 4500-S2D
92304520006 3210582016021088SM 4500-S2D
92304520007 3210582016021089SM 4500-S2D
92304520008 3210582016021090SM 4500-S2D
92304520009 3210582016021091SM 4500-S2D
92304520010 3210582016021092SM 4500-S2D
92304520011 3210582016021093SM 4500-S2D
92304520012 3210582016021095SM 4500-S2D
92304520001 3087632016021083EPA 218.7
92304520002 3087632016021084EPA 218.7
92304520003 3087632016021085EPA 218.7
92304520004 3087632016021086EPA 218.7
92304520005 3087632016021087EPA 218.7
92304520006 3087632016021088EPA 218.7
92304520007 3087632016021089EPA 218.7
92304520008 3087632016021090EPA 218.7
92304520009 3087632016021091EPA 218.7
92304520010 3087632016021092EPA 218.7
92304520011 3087632016021093EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 32
Duke Energy Analytical Lab
Page 90 of 116
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304520
J16070225
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/19/2016 08:29 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 32
Duke Energy Analytical Lab
Page 91 of 116
Page 31 of 32
Duke Energy Analytical Lab
Page 92 of 116
Page 32 of 32
Duke Energy Analytical Lab
Page 93 of 116

July 25, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 401373
SDG: J16070225

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 12, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 22
Duke Energy Analytical Lab
Page 94 of 116
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16070225 GEL Work Order: 401373
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 22
Duke Energy Analytical Lab
Page 95 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1504
0950
1409
0833
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373001
Water
08-JUL-16 10:38
12-JUL-16
2016021083 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.842
0.355
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000241
ND
ND
ND
ND
1.30
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"82.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 22
Duke Energy Analytical Lab
Page 96 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1515
0956
1409
0833
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373002
Water
08-JUL-16 14:45
12-JUL-16
2016021084 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.470
0.407
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.53
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"84.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 22
Duke Energy Analytical Lab
Page 97 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1516
1002
1409
0833
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373003
Water
08-JUL-16 14:23
12-JUL-16
2016021085 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.563
0.438
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
0.787
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"81.8 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 22
Duke Energy Analytical Lab
Page 98 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1518
1004
1409
0833
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373004
Water
08-JUL-16 13:20
12-JUL-16
2016021086 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.638
0.420
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.09
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"78.8 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 22
Duke Energy Analytical Lab
Page 99 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1519
1005
1409
0833
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373005
Water
08-JUL-16 09:28
12-JUL-16
2016021087 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.630
0.307
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
0.929
0.682
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"77.6 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 7 of 22
Duke Energy Analytical Lab
Page 100 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1521
1007
1409
0833
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373006
Water
08-JUL-16 09:57
12-JUL-16
2016021088 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.844
0.416
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.70
0.953
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"74.6 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 8 of 22
Duke Energy Analytical Lab
Page 101 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1525
1008
1409
0908
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373007
Water
08-JUL-16 12:08
12-JUL-16
2016021089 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.612
0.374
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.20
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"70.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 9 of 22
Duke Energy Analytical Lab
Page 102 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1526
1010
1416
0908
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373008
Water
08-JUL-16 12:30
12-JUL-16
2016021090 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.595
0.411
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
0.696
1.13
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 10 of 22
Duke Energy Analytical Lab
Page 103 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1528
1016
1409
0908
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373009
Water
08-JUL-16 13:53
12-JUL-16
2016021091 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.709
0.386
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.11
0.621
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"54.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 11 of 22
Duke Energy Analytical Lab
Page 104 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1534
1018
1416
0908
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373010
Water
08-JUL-16 14:17
12-JUL-16
2016021092 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.657
0.439
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.33
1.14
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"73.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 12 of 22
Duke Energy Analytical Lab
Page 105 of 116
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 25, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1581172
1581172
1581279
1581245
1535
1019
1416
0908
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/15/16
07/14/16
07/22/16
07/21/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401373011
Water
08-JUL-16 10:38
12-JUL-16
2016021093 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.416
0.460
1
2
3
4
J
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000131
ND
ND
ND
0.594
1.76
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/13/16 15811710733SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 13 of 22
Duke Energy Analytical Lab
Page 106 of 116
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1581172Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 25, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/14/16 09:52
07/15/16 15:06
07/15/16 15:03
07/14/16 09:49
07/14/16 09:47
07/15/16 15:01
07/15/16 15:07
07/14/16 09:53
07/14/16 09:55
QC
ND
ND
ND
0.000212
0.0537
0.000552
0.000563
0.00527
ND
ND
ND
ND
0.0523
0.000566
0.000572
0.00545
ND
NOM Sample
ND
ND
ND
0.000241
0.000241
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203583453 401373001
QC1203583452
QC1203583456
QC1203583451
QC1203583454 401373001
QC1203583457 401373001
QC1203583455 401373001
N/A
N/A
N/A
13
N/A
REC%
108
110
102
105
105
113
104
109
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
401373Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
Page 1 of 3
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Duke Energy Analytical Lab
Page 107 of 116
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1581172
1581279
1581245
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
07/14/16 09:55
07/15/16 15:09
07/22/16 14:14
07/22/16 14:08
07/22/16 14:14
07/21/16 09:50
07/21/16 09:50
07/21/16 09:50
07/21/16 12:20
07/21/16 09:50
QC
ND
ND
ND
-0.0123
15.3
0.334
0.650
24.5
0.271
151
115
NOM Sample
ND
ND
0.241
0.696
1.07
1.07
1.07
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
(0%-20%)
Qual
U
U
U
U
U
U
QC1203583705 401373008
QC1203583706
QC1203583704
QC1203583632 401313003
QC1203583635
QC1203583631
QC1203583633 401313003
QC1203583634 401313003
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
207
48.9
27.2
REC%
102
100
123
93
15.0
24.4
122
122
DUP
LCS
MB
DUP
LCS
MB
MS
MSD
401373Workorder:
**
<
>
BD
E
FA
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
U
U
*
*
RPD%
Notes:
Page 2 of 3
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Duke Energy Analytical Lab
Page 108 of 116
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
401373Workorder:
FB
H
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Page 18 of 22
Duke Energy Analytical Lab
Page 111 of 116

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070225
Work Order #: 401373

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1581172

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1581171
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401373001 2016021083
401373002 2016021084
401373003 2016021085
401373004 2016021086
401373005 2016021087
401373006 2016021088
401373007 2016021089
401373008 2016021090
401373009 2016021091
401373010 2016021092
401373011 2016021093
1203583451 Method Blank (MB)ICP-MS
1203583452 Laboratory Control Sample (LCS)
1203583456 Laboratory Control Sample (LCS)
1203583455 401373001(2016021083L) Serial Dilution (SD)
1203583453 401373001(2016021083D) Sample Duplicate (DUP)
1203583454 401373001(2016021083S) Matrix Spike (MS)
1203583457 401373001(2016021083S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Page 19 of 22
Duke Energy Analytical Lab
Page 112 of 116
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1581279
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401373001 2016021083
401373002 2016021084
401373003 2016021085
401373004 2016021086
401373005 2016021087
401373006 2016021088
401373007 2016021089
401373008 2016021090
401373009 2016021091
401373010 2016021092
401373011 2016021093
1203583704 Method Blank (MB)
1203583705 401373008(2016021090) Sample Duplicate (DUP)
1203583706 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The sample and the
duplicate, 1203583705 (2016021090DUP) and 401373008 (2016021090) , did not meet the relative percent
difference requirement; however, they do meet the relative error ratio requirement with a value of 2.1481.

Technical Information

Recounts
Samples were re-eluted due to high relative percent difference/relative error ratio. The re-eluted counts are
reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1581245
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
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Duke Energy Analytical Lab
Page 113 of 116
401373001 2016021083
401373002 2016021084
401373003 2016021085
401373004 2016021086
401373005 2016021087
401373006 2016021088
401373007 2016021089
401373008 2016021090
401373009 2016021091
401373010 2016021092
401373011 2016021093
1203583631 Method Blank (MB)
1203583632 401313003(NonSDG) Sample Duplicate (DUP)
1203583633 401313003(NonSDG) Matrix Spike (MS)
1203583634 401313003(NonSDG) Matrix Spike Duplicate (MSD)
1203583635 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The MS and the MSD,
1203583633 (Non SDG 401313003MS) and 1203583634 (Non SDG 401313003MSD), did not meet the relative
percent difference requirement; however, they both meet the recovery requirement.

Technical Information

Recounts
Sample 1203583633 (Non SDG 401313003MS) was recounted due to high recovery. The recount is reported.

Miscellaneous Information

Additional Comments
The matrix spike and matrix spike duplicate, 1203583633 (Non SDG 401313003MS) and 1203583634 (Non
SDG 401313003MSD), aliquots were reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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Duke Energy Analytical Lab
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 25 July 2016
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Duke Energy Analytical Lab
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